The material described by VN is gamma CuTi structured and crystallizes in the tetragonal P4/nmm space group. V(1) is bonded to six equivalent N(1) atoms to form a mixture of corner and edge-sharing VN6 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. N(1) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing NV6 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. is represented by the CIF card [CIF]
data_VN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.878
_cell_length_b   2.878
_cell_length_c   4.245
_cell_angle_alpha   89.988
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   35.148
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.250  0.750  0.782  1.0
  V  V1  1  0.750  0.250  0.218  1.0
  N  N2  1  0.250  0.750  0.266  1.0
  N  N3  1  0.750  0.250  0.734  1.0
[/CIF]
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The material described by VN is gamma CuTi structured and crystallizes in the tetragonal P4/nmm space group. V(1) is bonded to six equivalent N(1) atoms to form a mixture of corner and edge-sharing VN6 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. N(1) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing NV6 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. is represented by the CIF card [CIF]
data_VN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.878
_cell_length_b   2.878
_cell_length_c   4.245
_cell_angle_alpha   89.988
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   35.148
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.250  0.750  0.782  1.0
  V  V1  1  0.750  0.250  0.218  1.0
  N  N2  1  0.250  0.750  0.266  1.0
  N  N3  1  0.750  0.250  0.734  1.0
[/CIF]
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