The compound described by RbWSbO6 crystallizes in the orthorhombic Imma space group. Rb(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form RbO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-72°. W(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Rb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-72°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with six equivalent Rb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-69°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Rb(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent W(1) atoms. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one W(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_RbSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.376
_cell_length_b   7.411
_cell_length_c   7.292
_cell_angle_alpha   90.000
_cell_angle_beta   60.378
_cell_angle_gamma   120.155
_symmetry_Int_Tables_number   1
_cell_volume   282.770
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.731  0.361  0.384  1.0
  Rb  Rb1  1  0.269  0.630  0.616  1.0
  Sb  Sb2  1  0.000  0.996  0.500  1.0
  Sb  Sb3  1  0.000  0.996  0.000  1.0
  W  W4  1  0.500  0.496  1.000  1.0
  W  W5  1  0.500  0.996  0.000  1.0
  O  O6  1  0.850  0.921  0.325  1.0
  O  O7  1  0.617  0.304  0.941  1.0
  O  O8  1  0.254  0.929  0.934  1.0
  O  O9  1  0.254  0.316  0.312  1.0
  O  O10  1  0.254  0.316  0.934  1.0
  O  O11  1  0.254  0.929  0.312  1.0
  O  O12  1  0.150  0.071  0.675  1.0
  O  O13  1  0.383  0.687  0.059  1.0
  O  O14  1  0.746  0.063  0.066  1.0
  O  O15  1  0.746  0.675  0.688  1.0
  O  O16  1  0.746  0.675  0.066  1.0
  O  O17  1  0.746  0.063  0.688  1.0
[/CIF]
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The compound described by RbWSbO6 crystallizes in the orthorhombic Imma space group. Rb(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form RbO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-72°. W(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Rb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-72°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with six equivalent Rb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-69°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Rb(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent W(1) atoms. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one W(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_RbSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.376
_cell_length_b   7.411
_cell_length_c   7.292
_cell_angle_alpha   90.000
_cell_angle_beta   60.378
_cell_angle_gamma   120.155
_symmetry_Int_Tables_number   1
_cell_volume   282.770
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.731  0.361  0.384  1.0
  Rb  Rb1  1  0.269  0.630  0.616  1.0
  Sb  Sb2  1  0.000  0.996  0.500  1.0
  Sb  Sb3  1  0.000  0.996  0.000  1.0
  W  W4  1  0.500  0.496  1.000  1.0
  W  W5  1  0.500  0.996  0.000  1.0
  O  O6  1  0.850  0.921  0.325  1.0
  O  O7  1  0.617  0.304  0.941  1.0
  O  O8  1  0.254  0.929  0.934  1.0
  O  O9  1  0.254  0.316  0.312  1.0
  O  O10  1  0.254  0.316  0.934  1.0
  O  O11  1  0.254  0.929  0.312  1.0
  O  O12  1  0.150  0.071  0.675  1.0
  O  O13  1  0.383  0.687  0.059  1.0
  O  O14  1  0.746  0.063  0.066  1.0
  O  O15  1  0.746  0.675  0.688  1.0
  O  O16  1  0.746  0.675  0.066  1.0
  O  O17  1  0.746  0.063  0.688  1.0
[/CIF]
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