The material described by WBiSbO6 crystallizes in the monoclinic C2 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 22-23°. In the second W site, W(2) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form distorted corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 22-23°. Bi(1) is bonded in a 5-coordinate geometry to one O(2), one O(5), one O(6), and two equivalent O(1) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(5), one O(6), and two equivalent O(2) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Bi(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Bi(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1), one Bi(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(2), one Bi(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_BiSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.802
_cell_length_b   8.802
_cell_length_c   5.414
_cell_angle_alpha   89.305
_cell_angle_beta   89.305
_cell_angle_gamma   36.279
_symmetry_Int_Tables_number   1
_cell_volume   248.199
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.283  0.376  0.029  1.0
  Bi  Bi1  1  0.624  0.717  0.971  1.0
  Sb  Sb2  1  0.773  0.876  0.460  1.0
  Sb  Sb3  1  0.124  0.227  0.540  1.0
  W  W4  1  0.513  0.487  0.500  1.0
  W  W5  1  0.010  0.990  0.000  1.0
  O  O6  1  0.523  0.996  0.211  1.0
  O  O7  1  0.004  0.477  0.789  1.0
  O  O8  1  0.005  0.504  0.297  1.0
  O  O9  1  0.496  0.995  0.703  1.0
  O  O10  1  0.323  0.720  0.251  1.0
  O  O11  1  0.280  0.677  0.749  1.0
  O  O12  1  0.819  0.224  0.244  1.0
  O  O13  1  0.776  0.181  0.756  1.0
  O  O14  1  0.475  0.311  0.416  1.0
  O  O15  1  0.689  0.525  0.584  1.0
  O  O16  1  0.966  0.820  0.093  1.0
  O  O17  1  0.180  0.034  0.907  1.0
[/CIF]
.
The material described by WBiSbO6 crystallizes in the monoclinic C2 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 22-23°. In the second W site, W(2) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form distorted corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 22-23°. Bi(1) is bonded in a 5-coordinate geometry to one O(2), one O(5), one O(6), and two equivalent O(1) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(5), one O(6), and two equivalent O(2) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Bi(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Bi(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1), one Bi(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(2), one Bi(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_BiSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.802
_cell_length_b   8.802
_cell_length_c   5.414
_cell_angle_alpha   89.305
_cell_angle_beta   89.305
_cell_angle_gamma   36.279
_symmetry_Int_Tables_number   1
_cell_volume   248.199
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.283  0.376  0.029  1.0
  Bi  Bi1  1  0.624  0.717  0.971  1.0
  Sb  Sb2  1  0.773  0.876  0.460  1.0
  Sb  Sb3  1  0.124  0.227  0.540  1.0
  W  W4  1  0.513  0.487  0.500  1.0
  W  W5  1  0.010  0.990  0.000  1.0
  O  O6  1  0.523  0.996  0.211  1.0
  O  O7  1  0.004  0.477  0.789  1.0
  O  O8  1  0.005  0.504  0.297  1.0
  O  O9  1  0.496  0.995  0.703  1.0
  O  O10  1  0.323  0.720  0.251  1.0
  O  O11  1  0.280  0.677  0.749  1.0
  O  O12  1  0.819  0.224  0.244  1.0
  O  O13  1  0.776  0.181  0.756  1.0
  O  O14  1  0.475  0.311  0.416  1.0
  O  O15  1  0.689  0.525  0.584  1.0
  O  O16  1  0.966  0.820  0.093  1.0
  O  O17  1  0.180  0.034  0.907  1.0
[/CIF]
.