The material structure described by ZnSb2(PO5)2 crystallizes in the orthorhombic Fdd2 space group. Zn(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form ZnO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra and corners with two equivalent Sb(1)O5 trigonal bipyramids. Sb(1) is bonded to one O(1), one O(4), one O(5), and two equivalent O(2) atoms to form distorted SbO5 trigonal bipyramids that share  a cornercorner with one Zn(1)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and corners with two equivalent Sb(1)O5 trigonal bipyramids. P(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra and corners with three equivalent Sb(1)O5 trigonal bipyramids. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one Sb(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. is represented by the CIF card [CIF]
data_ZnSb2(PO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.250
_cell_length_b   9.030
_cell_length_c   7.414
_cell_angle_alpha   76.416
_cell_angle_beta   58.907
_cell_angle_gamma   44.677
_symmetry_Int_Tables_number   1
_cell_volume   403.019
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.965  0.535  0.535  1.0
  Zn  Zn1  1  0.715  0.285  0.285  1.0
  Sb  Sb2  1  0.339  0.367  0.901  1.0
  Sb  Sb3  1  0.392  0.901  0.367  1.0
  Sb  Sb4  1  0.883  0.911  0.858  1.0
  Sb  Sb5  1  0.349  0.858  0.911  1.0
  P  P6  1  0.935  0.436  0.027  1.0
  P  P7  1  0.814  0.315  0.648  1.0
  P  P8  1  0.602  0.027  0.436  1.0
  P  P9  1  0.223  0.648  0.315  1.0
  O  O10  1  0.446  0.232  0.610  1.0
  O  O11  1  0.326  0.856  0.661  1.0
  O  O12  1  0.431  0.536  0.298  1.0
  O  O13  1  0.640  0.538  0.804  1.0
  O  O14  1  0.751  0.042  0.232  1.0
  O  O15  1  0.454  0.066  0.376  1.0
  O  O16  1  0.394  0.924  0.092  1.0
  O  O17  1  0.158  0.661  0.856  1.0
  O  O18  1  0.589  0.092  0.924  1.0
  O  O19  1  0.208  0.499  0.275  1.0
  O  O20  1  0.712  0.610  0.232  1.0
  O  O21  1  0.018  0.275  0.499  1.0
  O  O22  1  0.975  0.232  0.042  1.0
  O  O23  1  0.184  0.796  0.145  1.0
  O  O24  1  0.105  0.376  0.066  1.0
  O  O25  1  0.874  0.145  0.796  1.0
  O  O26  1  0.952  0.516  0.819  1.0
  O  O27  1  0.734  0.298  0.536  1.0
  O  O28  1  0.018  0.804  0.538  1.0
  O  O29  1  0.714  0.819  0.516  1.0
[/CIF]
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The material structure described by ZnSb2(PO5)2 crystallizes in the orthorhombic Fdd2 space group. Zn(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form ZnO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra and corners with two equivalent Sb(1)O5 trigonal bipyramids. Sb(1) is bonded to one O(1), one O(4), one O(5), and two equivalent O(2) atoms to form distorted SbO5 trigonal bipyramids that share  a cornercorner with one Zn(1)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and corners with two equivalent Sb(1)O5 trigonal bipyramids. P(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra and corners with three equivalent Sb(1)O5 trigonal bipyramids. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one Sb(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. is represented by the CIF card [CIF]
data_ZnSb2(PO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.250
_cell_length_b   9.030
_cell_length_c   7.414
_cell_angle_alpha   76.416
_cell_angle_beta   58.907
_cell_angle_gamma   44.677
_symmetry_Int_Tables_number   1
_cell_volume   403.019
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.965  0.535  0.535  1.0
  Zn  Zn1  1  0.715  0.285  0.285  1.0
  Sb  Sb2  1  0.339  0.367  0.901  1.0
  Sb  Sb3  1  0.392  0.901  0.367  1.0
  Sb  Sb4  1  0.883  0.911  0.858  1.0
  Sb  Sb5  1  0.349  0.858  0.911  1.0
  P  P6  1  0.935  0.436  0.027  1.0
  P  P7  1  0.814  0.315  0.648  1.0
  P  P8  1  0.602  0.027  0.436  1.0
  P  P9  1  0.223  0.648  0.315  1.0
  O  O10  1  0.446  0.232  0.610  1.0
  O  O11  1  0.326  0.856  0.661  1.0
  O  O12  1  0.431  0.536  0.298  1.0
  O  O13  1  0.640  0.538  0.804  1.0
  O  O14  1  0.751  0.042  0.232  1.0
  O  O15  1  0.454  0.066  0.376  1.0
  O  O16  1  0.394  0.924  0.092  1.0
  O  O17  1  0.158  0.661  0.856  1.0
  O  O18  1  0.589  0.092  0.924  1.0
  O  O19  1  0.208  0.499  0.275  1.0
  O  O20  1  0.712  0.610  0.232  1.0
  O  O21  1  0.018  0.275  0.499  1.0
  O  O22  1  0.975  0.232  0.042  1.0
  O  O23  1  0.184  0.796  0.145  1.0
  O  O24  1  0.105  0.376  0.066  1.0
  O  O25  1  0.874  0.145  0.796  1.0
  O  O26  1  0.952  0.516  0.819  1.0
  O  O27  1  0.734  0.298  0.536  1.0
  O  O28  1  0.018  0.804  0.538  1.0
  O  O29  1  0.714  0.819  0.516  1.0
[/CIF]
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