The material described by WMoO6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 18°. Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 18°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.425
_cell_length_b   5.365
_cell_length_c   9.326
_cell_angle_alpha   54.859
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   221.939
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.000  0.500  0.000  1.0
  Mo  Mo1  1  0.500  0.500  0.500  1.0
  W  W2  1  0.000  0.000  0.500  1.0
  W  W3  1  0.500  0.000  0.000  1.0
  O  O4  1  0.277  0.750  0.528  1.0
  O  O5  1  0.777  0.250  0.972  1.0
  O  O6  1  0.723  0.250  0.472  1.0
  O  O7  1  0.223  0.750  0.028  1.0
  O  O8  1  0.224  0.306  0.472  1.0
  O  O9  1  0.724  0.694  0.028  1.0
  O  O10  1  0.776  0.694  0.528  1.0
  O  O11  1  0.276  0.306  0.972  1.0
  O  O12  1  0.494  0.195  0.749  1.0
  O  O13  1  0.994  0.805  0.751  1.0
  O  O14  1  0.006  0.195  0.249  1.0
  O  O15  1  0.506  0.805  0.251  1.0
[/CIF]
.
The material described by WMoO6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 18°. Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 18°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.425
_cell_length_b   5.365
_cell_length_c   9.326
_cell_angle_alpha   54.859
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   221.939
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.000  0.500  0.000  1.0
  Mo  Mo1  1  0.500  0.500  0.500  1.0
  W  W2  1  0.000  0.000  0.500  1.0
  W  W3  1  0.500  0.000  0.000  1.0
  O  O4  1  0.277  0.750  0.528  1.0
  O  O5  1  0.777  0.250  0.972  1.0
  O  O6  1  0.723  0.250  0.472  1.0
  O  O7  1  0.223  0.750  0.028  1.0
  O  O8  1  0.224  0.306  0.472  1.0
  O  O9  1  0.724  0.694  0.028  1.0
  O  O10  1  0.776  0.694  0.528  1.0
  O  O11  1  0.276  0.306  0.972  1.0
  O  O12  1  0.494  0.195  0.749  1.0
  O  O13  1  0.994  0.805  0.751  1.0
  O  O14  1  0.006  0.195  0.249  1.0
  O  O15  1  0.506  0.805  0.251  1.0
[/CIF]
.