The structure described by BiVO4 crystallizes in the triclinic P1 space group. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Bi(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one V(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one V(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Bi(1) atom. is represented by the CIF file [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.339
_cell_length_b   4.801
_cell_length_c   4.790
_cell_angle_alpha   76.081
_cell_angle_beta   65.112
_cell_angle_gamma   65.074
_symmetry_Int_Tables_number   1
_cell_volume   100.697
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.354  0.647  1.0
  Bi  Bi1  1  0.000  0.951  0.050  1.0
  O  O2  1  0.840  0.072  0.670  1.0
  O  O3  1  0.462  0.721  0.677  1.0
  O  O4  1  0.538  0.323  0.278  1.0
  O  O5  1  0.160  0.330  0.928  1.0
[/CIF]
.
The structure described by BiVO4 crystallizes in the triclinic P1 space group. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Bi(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one V(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one V(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Bi(1) atom. is represented by the CIF file [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.339
_cell_length_b   4.801
_cell_length_c   4.790
_cell_angle_alpha   76.081
_cell_angle_beta   65.112
_cell_angle_gamma   65.074
_symmetry_Int_Tables_number   1
_cell_volume   100.697
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.354  0.647  1.0
  Bi  Bi1  1  0.000  0.951  0.050  1.0
  O  O2  1  0.840  0.072  0.670  1.0
  O  O3  1  0.462  0.721  0.677  1.0
  O  O4  1  0.538  0.323  0.278  1.0
  O  O5  1  0.160  0.330  0.928  1.0
[/CIF]
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