The material structure described by CuN4SO5 is gamma nitrogen structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CuN4SO5 clusters. Cu(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1), one O(2), and one O(4) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cu(1) and one N(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Cu(1) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuSN4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.647
_cell_length_b   10.026
_cell_length_c   10.598
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   812.569
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.750  0.449  0.411  1.0
  Cu  Cu1  1  0.750  0.949  0.089  1.0
  Cu  Cu2  1  0.250  0.551  0.589  1.0
  Cu  Cu3  1  0.250  0.051  0.911  1.0
  S  S4  1  0.250  0.284  0.425  1.0
  S  S5  1  0.250  0.784  0.075  1.0
  S  S6  1  0.750  0.716  0.575  1.0
  S  S7  1  0.750  0.216  0.925  1.0
  N  N8  1  0.949  0.021  0.223  1.0
  N  N9  1  0.551  0.521  0.277  1.0
  N  N10  1  0.449  0.979  0.777  1.0
  N  N11  1  0.051  0.479  0.723  1.0
  N  N12  1  0.051  0.979  0.777  1.0
  N  N13  1  0.449  0.479  0.723  1.0
  N  N14  1  0.551  0.021  0.223  1.0
  N  N15  1  0.949  0.521  0.277  1.0
  N  N16  1  0.471  0.498  0.192  1.0
  N  N17  1  0.029  0.998  0.308  1.0
  N  N18  1  0.971  0.502  0.808  1.0
  N  N19  1  0.529  0.002  0.692  1.0
  N  N20  1  0.529  0.502  0.808  1.0
  N  N21  1  0.971  0.002  0.692  1.0
  N  N22  1  0.029  0.498  0.192  1.0
  N  N23  1  0.471  0.998  0.308  1.0
  O  O24  1  0.409  0.225  0.481  1.0
  O  O25  1  0.091  0.725  0.019  1.0
  O  O26  1  0.909  0.775  0.519  1.0
  O  O27  1  0.591  0.275  0.981  1.0
  O  O28  1  0.591  0.775  0.519  1.0
  O  O29  1  0.909  0.275  0.981  1.0
  O  O30  1  0.091  0.225  0.481  1.0
  O  O31  1  0.409  0.725  0.019  1.0
  O  O32  1  0.250  0.435  0.453  1.0
  O  O33  1  0.250  0.935  0.047  1.0
  O  O34  1  0.750  0.565  0.547  1.0
  O  O35  1  0.750  0.065  0.953  1.0
  O  O36  1  0.250  0.272  0.287  1.0
  O  O37  1  0.250  0.772  0.213  1.0
  O  O38  1  0.750  0.728  0.713  1.0
  O  O39  1  0.750  0.228  0.787  1.0
  O  O40  1  0.750  0.286  0.354  1.0
  O  O41  1  0.750  0.786  0.146  1.0
  O  O42  1  0.250  0.714  0.646  1.0
  O  O43  1  0.250  0.214  0.854  1.0
[/CIF]
.
The material structure described by CuN4SO5 is gamma nitrogen structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CuN4SO5 clusters. Cu(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1), one O(2), and one O(4) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cu(1) and one N(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Cu(1) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuSN4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.647
_cell_length_b   10.026
_cell_length_c   10.598
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   812.569
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.750  0.449  0.411  1.0
  Cu  Cu1  1  0.750  0.949  0.089  1.0
  Cu  Cu2  1  0.250  0.551  0.589  1.0
  Cu  Cu3  1  0.250  0.051  0.911  1.0
  S  S4  1  0.250  0.284  0.425  1.0
  S  S5  1  0.250  0.784  0.075  1.0
  S  S6  1  0.750  0.716  0.575  1.0
  S  S7  1  0.750  0.216  0.925  1.0
  N  N8  1  0.949  0.021  0.223  1.0
  N  N9  1  0.551  0.521  0.277  1.0
  N  N10  1  0.449  0.979  0.777  1.0
  N  N11  1  0.051  0.479  0.723  1.0
  N  N12  1  0.051  0.979  0.777  1.0
  N  N13  1  0.449  0.479  0.723  1.0
  N  N14  1  0.551  0.021  0.223  1.0
  N  N15  1  0.949  0.521  0.277  1.0
  N  N16  1  0.471  0.498  0.192  1.0
  N  N17  1  0.029  0.998  0.308  1.0
  N  N18  1  0.971  0.502  0.808  1.0
  N  N19  1  0.529  0.002  0.692  1.0
  N  N20  1  0.529  0.502  0.808  1.0
  N  N21  1  0.971  0.002  0.692  1.0
  N  N22  1  0.029  0.498  0.192  1.0
  N  N23  1  0.471  0.998  0.308  1.0
  O  O24  1  0.409  0.225  0.481  1.0
  O  O25  1  0.091  0.725  0.019  1.0
  O  O26  1  0.909  0.775  0.519  1.0
  O  O27  1  0.591  0.275  0.981  1.0
  O  O28  1  0.591  0.775  0.519  1.0
  O  O29  1  0.909  0.275  0.981  1.0
  O  O30  1  0.091  0.225  0.481  1.0
  O  O31  1  0.409  0.725  0.019  1.0
  O  O32  1  0.250  0.435  0.453  1.0
  O  O33  1  0.250  0.935  0.047  1.0
  O  O34  1  0.750  0.565  0.547  1.0
  O  O35  1  0.750  0.065  0.953  1.0
  O  O36  1  0.250  0.272  0.287  1.0
  O  O37  1  0.250  0.772  0.213  1.0
  O  O38  1  0.750  0.728  0.713  1.0
  O  O39  1  0.750  0.228  0.787  1.0
  O  O40  1  0.750  0.286  0.354  1.0
  O  O41  1  0.750  0.786  0.146  1.0
  O  O42  1  0.250  0.714  0.646  1.0
  O  O43  1  0.250  0.214  0.854  1.0
[/CIF]
.