The compound described by Ni2InSbO6 is Corundum-derived structured and crystallizes in the trigonal R3 space group. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form NiO6 octahedra that share corners with three equivalent In(1)O6 octahedra, corners with six equivalent Ni(2)O6 octahedra, edges with three equivalent Sb(1)O6 octahedra, and  a faceface with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. In the second Ni site, Ni(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted NiO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with six equivalent Ni(1)O6 octahedra, edges with three equivalent In(1)O6 octahedra, and  a faceface with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted InO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with six equivalent Sb(1)O6 octahedra, edges with three equivalent Ni(2)O6 octahedra, and  a faceface with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. Sb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SbO6 octahedra that share corners with three equivalent Ni(2)O6 octahedra, corners with six equivalent In(1)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and  a faceface with one Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ni(1), one Ni(2), one In(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OInNi2Sb trigonal pyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Ni(1), one Ni(2), one In(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_InNi2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.286
_cell_length_b   5.286
_cell_length_c   5.644
_cell_angle_alpha   62.062
_cell_angle_beta   62.053
_cell_angle_gamma   59.999
_symmetry_Int_Tables_number   1
_cell_volume   114.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.794  0.794  0.617  1.0
  Ni  Ni1  1  0.002  0.002  0.995  1.0
  Ni  Ni2  1  0.507  0.507  0.480  1.0
  Sb  Sb3  1  0.304  0.304  0.088  1.0
  O  O4  1  0.214  0.916  0.283  1.0
  O  O5  1  0.916  0.587  0.283  1.0
  O  O6  1  0.587  0.214  0.283  1.0
  O  O7  1  0.698  0.117  0.800  1.0
  O  O8  1  0.117  0.385  0.800  1.0
  O  O9  1  0.385  0.698  0.800  1.0
[/CIF]
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The compound described by Ni2InSbO6 is Corundum-derived structured and crystallizes in the trigonal R3 space group. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form NiO6 octahedra that share corners with three equivalent In(1)O6 octahedra, corners with six equivalent Ni(2)O6 octahedra, edges with three equivalent Sb(1)O6 octahedra, and  a faceface with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. In the second Ni site, Ni(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted NiO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with six equivalent Ni(1)O6 octahedra, edges with three equivalent In(1)O6 octahedra, and  a faceface with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted InO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with six equivalent Sb(1)O6 octahedra, edges with three equivalent Ni(2)O6 octahedra, and  a faceface with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. Sb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SbO6 octahedra that share corners with three equivalent Ni(2)O6 octahedra, corners with six equivalent In(1)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and  a faceface with one Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ni(1), one Ni(2), one In(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OInNi2Sb trigonal pyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Ni(1), one Ni(2), one In(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_InNi2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.286
_cell_length_b   5.286
_cell_length_c   5.644
_cell_angle_alpha   62.062
_cell_angle_beta   62.053
_cell_angle_gamma   59.999
_symmetry_Int_Tables_number   1
_cell_volume   114.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.794  0.794  0.617  1.0
  Ni  Ni1  1  0.002  0.002  0.995  1.0
  Ni  Ni2  1  0.507  0.507  0.480  1.0
  Sb  Sb3  1  0.304  0.304  0.088  1.0
  O  O4  1  0.214  0.916  0.283  1.0
  O  O5  1  0.916  0.587  0.283  1.0
  O  O6  1  0.587  0.214  0.283  1.0
  O  O7  1  0.698  0.117  0.800  1.0
  O  O8  1  0.117  0.385  0.800  1.0
  O  O9  1  0.385  0.698  0.800  1.0
[/CIF]
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