The material described by PbCl4 is Silicon tetrafluoride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two lead tetrachloride molecules. Pb(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pb(1) atom. is represented by the CIF card [CIF]
data_PbCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.486
_cell_length_b   6.709
_cell_length_c   10.110
_cell_angle_alpha   76.588
_cell_angle_beta   74.261
_cell_angle_gamma   65.918
_symmetry_Int_Tables_number   1
_cell_volume   323.840
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.258  0.750  0.250  1.0
  Pb  Pb1  1  0.742  0.250  0.750  1.0
  Cl  Cl2  1  0.137  0.431  0.312  1.0
  Cl  Cl3  1  0.863  0.569  0.688  1.0
  Cl  Cl4  1  0.619  0.187  0.557  1.0
  Cl  Cl5  1  0.364  0.313  0.943  1.0
  Cl  Cl6  1  0.879  0.070  0.188  1.0
  Cl  Cl7  1  0.121  0.930  0.812  1.0
  Cl  Cl8  1  0.381  0.813  0.443  1.0
  Cl  Cl9  1  0.636  0.687  0.057  1.0
[/CIF]
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The material described by PbCl4 is Silicon tetrafluoride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two lead tetrachloride molecules. Pb(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pb(1) atom. is represented by the CIF card [CIF]
data_PbCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.486
_cell_length_b   6.709
_cell_length_c   10.110
_cell_angle_alpha   76.588
_cell_angle_beta   74.261
_cell_angle_gamma   65.918
_symmetry_Int_Tables_number   1
_cell_volume   323.840
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.258  0.750  0.250  1.0
  Pb  Pb1  1  0.742  0.250  0.750  1.0
  Cl  Cl2  1  0.137  0.431  0.312  1.0
  Cl  Cl3  1  0.863  0.569  0.688  1.0
  Cl  Cl4  1  0.619  0.187  0.557  1.0
  Cl  Cl5  1  0.364  0.313  0.943  1.0
  Cl  Cl6  1  0.879  0.070  0.188  1.0
  Cl  Cl7  1  0.121  0.930  0.812  1.0
  Cl  Cl8  1  0.381  0.813  0.443  1.0
  Cl  Cl9  1  0.636  0.687  0.057  1.0
[/CIF]
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