The crystal structure described by CoN6(OCl)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CoN6(OCl)2 clusters. Co(1) is bonded in a 5-coordinate geometry to one N(2), two equivalent N(4), and two equivalent Cl(1) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a distorted linear geometry to one Co(1) and one N(1) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one N(3) and two equivalent N(4) atoms. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one Co(1), one N(4), and two equivalent N(3) atoms. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF file [CIF]
data_CoN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.800
_cell_length_b   6.800
_cell_length_c   8.778
_cell_angle_alpha   88.202
_cell_angle_beta   88.202
_cell_angle_gamma   91.231
_symmetry_Int_Tables_number   1
_cell_volume   405.427
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.977  0.023  0.250  1.0
  Co  Co1  1  0.023  0.977  0.750  1.0
  N  N2  1  0.290  0.710  0.250  1.0
  N  N3  1  0.710  0.290  0.750  1.0
  N  N4  1  0.158  0.842  0.250  1.0
  N  N5  1  0.842  0.158  0.750  1.0
  N  N6  1  0.588  0.278  0.298  1.0
  N  N7  1  0.722  0.412  0.202  1.0
  N  N8  1  0.412  0.722  0.702  1.0
  N  N9  1  0.278  0.588  0.798  1.0
  N  N10  1  0.713  0.202  0.177  1.0
  N  N11  1  0.798  0.287  0.323  1.0
  N  N12  1  0.287  0.798  0.823  1.0
  N  N13  1  0.202  0.713  0.677  1.0
  Cl  Cl14  1  0.787  0.850  0.407  1.0
  Cl  Cl15  1  0.150  0.213  0.093  1.0
  Cl  Cl16  1  0.213  0.150  0.593  1.0
  Cl  Cl17  1  0.850  0.787  0.907  1.0
  O  O18  1  0.289  0.589  0.361  1.0
  O  O19  1  0.411  0.711  0.139  1.0
  O  O20  1  0.711  0.411  0.639  1.0
  O  O21  1  0.589  0.289  0.861  1.0
[/CIF]
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The crystal structure described by CoN6(OCl)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CoN6(OCl)2 clusters. Co(1) is bonded in a 5-coordinate geometry to one N(2), two equivalent N(4), and two equivalent Cl(1) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a distorted linear geometry to one Co(1) and one N(1) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one N(3) and two equivalent N(4) atoms. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one Co(1), one N(4), and two equivalent N(3) atoms. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF file [CIF]
data_CoN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.800
_cell_length_b   6.800
_cell_length_c   8.778
_cell_angle_alpha   88.202
_cell_angle_beta   88.202
_cell_angle_gamma   91.231
_symmetry_Int_Tables_number   1
_cell_volume   405.427
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.977  0.023  0.250  1.0
  Co  Co1  1  0.023  0.977  0.750  1.0
  N  N2  1  0.290  0.710  0.250  1.0
  N  N3  1  0.710  0.290  0.750  1.0
  N  N4  1  0.158  0.842  0.250  1.0
  N  N5  1  0.842  0.158  0.750  1.0
  N  N6  1  0.588  0.278  0.298  1.0
  N  N7  1  0.722  0.412  0.202  1.0
  N  N8  1  0.412  0.722  0.702  1.0
  N  N9  1  0.278  0.588  0.798  1.0
  N  N10  1  0.713  0.202  0.177  1.0
  N  N11  1  0.798  0.287  0.323  1.0
  N  N12  1  0.287  0.798  0.823  1.0
  N  N13  1  0.202  0.713  0.677  1.0
  Cl  Cl14  1  0.787  0.850  0.407  1.0
  Cl  Cl15  1  0.150  0.213  0.093  1.0
  Cl  Cl16  1  0.213  0.150  0.593  1.0
  Cl  Cl17  1  0.850  0.787  0.907  1.0
  O  O18  1  0.289  0.589  0.361  1.0
  O  O19  1  0.411  0.711  0.139  1.0
  O  O20  1  0.711  0.411  0.639  1.0
  O  O21  1  0.589  0.289  0.861  1.0
[/CIF]
.