The structure described by (Mo3Cl7)4(N2)2O2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia atoms, four water atoms, and four Mo3Cl7 clusters. In each Mo3Cl7 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(6) atom to form edge-sharing MoCl5 square pyramids. In the second Mo site, Mo(2) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(7) atom to form distorted edge-sharing MoCl5 square pyramids. In the third Mo site, Mo(3) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom to form distorted edge-sharing MoCl5 square pyramids. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the third Cl site, Cl(3) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(3) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo6N2Cl14O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.658
_cell_length_b   12.658
_cell_length_c   9.295
_cell_angle_alpha   71.628
_cell_angle_beta   71.628
_cell_angle_gamma   76.789
_symmetry_Int_Tables_number   1
_cell_volume   1327.561
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.519  0.069  0.145  1.0
  Mo  Mo1  1  0.931  0.481  0.355  1.0
  Mo  Mo2  1  0.481  0.931  0.855  1.0
  Mo  Mo3  1  0.069  0.519  0.645  1.0
  Mo  Mo4  1  0.678  0.939  0.943  1.0
  Mo  Mo5  1  0.061  0.322  0.557  1.0
  Mo  Mo6  1  0.322  0.061  0.057  1.0
  Mo  Mo7  1  0.939  0.678  0.443  1.0
  Mo  Mo8  1  0.470  0.843  0.185  1.0
  Mo  Mo9  1  0.157  0.530  0.315  1.0
  Mo  Mo10  1  0.530  0.157  0.815  1.0
  Mo  Mo11  1  0.843  0.470  0.685  1.0
  N  N12  1  0.000  0.000  0.000  1.0
  N  N13  1  0.000  0.000  0.500  1.0
  N  N14  1  0.826  0.174  0.250  1.0
  N  N15  1  0.174  0.826  0.750  1.0
  Cl  Cl16  1  0.346  0.983  0.337  1.0
  Cl  Cl17  1  0.017  0.654  0.163  1.0
  Cl  Cl18  1  0.654  0.017  0.663  1.0
  Cl  Cl19  1  0.983  0.346  0.837  1.0
  Cl  Cl20  1  0.393  0.244  0.028  1.0
  Cl  Cl21  1  0.756  0.607  0.472  1.0
  Cl  Cl22  1  0.607  0.756  0.972  1.0
  Cl  Cl23  1  0.244  0.393  0.528  1.0
  Cl  Cl24  1  0.638  0.884  0.243  1.0
  Cl  Cl25  1  0.116  0.362  0.257  1.0
  Cl  Cl26  1  0.362  0.116  0.757  1.0
  Cl  Cl27  1  0.884  0.638  0.743  1.0
  Cl  Cl28  1  0.692  0.139  0.935  1.0
  Cl  Cl29  1  0.861  0.308  0.565  1.0
  Cl  Cl30  1  0.308  0.861  0.065  1.0
  Cl  Cl31  1  0.139  0.692  0.435  1.0
  Cl  Cl32  1  0.441  0.672  0.385  1.0
  Cl  Cl33  1  0.328  0.559  0.115  1.0
  Cl  Cl34  1  0.559  0.328  0.615  1.0
  Cl  Cl35  1  0.672  0.441  0.885  1.0
  Cl  Cl36  1  0.541  0.160  0.318  1.0
  Cl  Cl37  1  0.840  0.459  0.182  1.0
  Cl  Cl38  1  0.459  0.840  0.682  1.0
  Cl  Cl39  1  0.160  0.541  0.818  1.0
  Cl  Cl40  1  0.876  0.872  0.876  1.0
  Cl  Cl41  1  0.128  0.124  0.624  1.0
  Cl  Cl42  1  0.124  0.128  0.124  1.0
  Cl  Cl43  1  0.872  0.876  0.376  1.0
  O  O44  1  0.450  0.550  0.750  1.0
  O  O45  1  0.550  0.450  0.250  1.0
[/CIF]
.
The structure described by (Mo3Cl7)4(N2)2O2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia atoms, four water atoms, and four Mo3Cl7 clusters. In each Mo3Cl7 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(6) atom to form edge-sharing MoCl5 square pyramids. In the second Mo site, Mo(2) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(7) atom to form distorted edge-sharing MoCl5 square pyramids. In the third Mo site, Mo(3) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom to form distorted edge-sharing MoCl5 square pyramids. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the third Cl site, Cl(3) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(3) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo6N2Cl14O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.658
_cell_length_b   12.658
_cell_length_c   9.295
_cell_angle_alpha   71.628
_cell_angle_beta   71.628
_cell_angle_gamma   76.789
_symmetry_Int_Tables_number   1
_cell_volume   1327.561
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.519  0.069  0.145  1.0
  Mo  Mo1  1  0.931  0.481  0.355  1.0
  Mo  Mo2  1  0.481  0.931  0.855  1.0
  Mo  Mo3  1  0.069  0.519  0.645  1.0
  Mo  Mo4  1  0.678  0.939  0.943  1.0
  Mo  Mo5  1  0.061  0.322  0.557  1.0
  Mo  Mo6  1  0.322  0.061  0.057  1.0
  Mo  Mo7  1  0.939  0.678  0.443  1.0
  Mo  Mo8  1  0.470  0.843  0.185  1.0
  Mo  Mo9  1  0.157  0.530  0.315  1.0
  Mo  Mo10  1  0.530  0.157  0.815  1.0
  Mo  Mo11  1  0.843  0.470  0.685  1.0
  N  N12  1  0.000  0.000  0.000  1.0
  N  N13  1  0.000  0.000  0.500  1.0
  N  N14  1  0.826  0.174  0.250  1.0
  N  N15  1  0.174  0.826  0.750  1.0
  Cl  Cl16  1  0.346  0.983  0.337  1.0
  Cl  Cl17  1  0.017  0.654  0.163  1.0
  Cl  Cl18  1  0.654  0.017  0.663  1.0
  Cl  Cl19  1  0.983  0.346  0.837  1.0
  Cl  Cl20  1  0.393  0.244  0.028  1.0
  Cl  Cl21  1  0.756  0.607  0.472  1.0
  Cl  Cl22  1  0.607  0.756  0.972  1.0
  Cl  Cl23  1  0.244  0.393  0.528  1.0
  Cl  Cl24  1  0.638  0.884  0.243  1.0
  Cl  Cl25  1  0.116  0.362  0.257  1.0
  Cl  Cl26  1  0.362  0.116  0.757  1.0
  Cl  Cl27  1  0.884  0.638  0.743  1.0
  Cl  Cl28  1  0.692  0.139  0.935  1.0
  Cl  Cl29  1  0.861  0.308  0.565  1.0
  Cl  Cl30  1  0.308  0.861  0.065  1.0
  Cl  Cl31  1  0.139  0.692  0.435  1.0
  Cl  Cl32  1  0.441  0.672  0.385  1.0
  Cl  Cl33  1  0.328  0.559  0.115  1.0
  Cl  Cl34  1  0.559  0.328  0.615  1.0
  Cl  Cl35  1  0.672  0.441  0.885  1.0
  Cl  Cl36  1  0.541  0.160  0.318  1.0
  Cl  Cl37  1  0.840  0.459  0.182  1.0
  Cl  Cl38  1  0.459  0.840  0.682  1.0
  Cl  Cl39  1  0.160  0.541  0.818  1.0
  Cl  Cl40  1  0.876  0.872  0.876  1.0
  Cl  Cl41  1  0.128  0.124  0.624  1.0
  Cl  Cl42  1  0.124  0.128  0.124  1.0
  Cl  Cl43  1  0.872  0.876  0.376  1.0
  O  O44  1  0.450  0.550  0.750  1.0
  O  O45  1  0.550  0.450  0.250  1.0
[/CIF]
.