The material structure described by N4H3NH2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules and four N4H3 clusters. In each N4H3 cluster, there are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(5) atom. In the second N site, N(1) is bonded in a linear geometry to one N(2) and one N(3) atom. In the third N site, N(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. In the fourth N site, N(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) and one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF file [CIF]
data_HN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.499
_cell_length_b   5.790
_cell_length_c   12.659
_cell_angle_alpha   65.088
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   365.571
_cell_formula_units_Z   20
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.322  0.725  0.935  1.0
  H  H1  1  0.822  0.275  0.565  1.0
  H  H2  1  0.678  0.275  0.065  1.0
  H  H3  1  0.178  0.725  0.435  1.0
  H  H4  1  0.028  0.367  0.642  1.0
  H  H5  1  0.528  0.633  0.858  1.0
  H  H6  1  0.972  0.633  0.358  1.0
  H  H7  1  0.472  0.367  0.142  1.0
  H  H8  1  0.993  0.868  0.650  1.0
  H  H9  1  0.493  0.132  0.850  1.0
  H  H10  1  0.007  0.132  0.350  1.0
  H  H11  1  0.507  0.868  0.150  1.0
  H  H12  1  0.700  0.914  0.915  1.0
  H  H13  1  0.200  0.086  0.585  1.0
  H  H14  1  0.300  0.086  0.085  1.0
  H  H15  1  0.800  0.914  0.415  1.0
  H  H16  1  0.802  0.146  0.717  1.0
  H  H17  1  0.302  0.854  0.783  1.0
  H  H18  1  0.198  0.854  0.283  1.0
  H  H19  1  0.698  0.146  0.217  1.0
  N  N20  1  0.477  0.655  0.599  1.0
  N  N21  1  0.977  0.345  0.901  1.0
  N  N22  1  0.523  0.345  0.401  1.0
  N  N23  1  0.023  0.655  0.099  1.0
  N  N24  1  0.285  0.594  0.575  1.0
  N  N25  1  0.785  0.406  0.925  1.0
  N  N26  1  0.715  0.406  0.425  1.0
  N  N27  1  0.215  0.594  0.075  1.0
  N  N28  1  0.666  0.718  0.623  1.0
  N  N29  1  0.166  0.282  0.877  1.0
  N  N30  1  0.334  0.282  0.377  1.0
  N  N31  1  0.834  0.718  0.123  1.0
  N  N32  1  0.423  0.787  0.855  1.0
  N  N33  1  0.923  0.213  0.645  1.0
  N  N34  1  0.577  0.213  0.145  1.0
  N  N35  1  0.077  0.787  0.355  1.0
  N  N36  1  0.092  0.011  0.658  1.0
  N  N37  1  0.592  0.989  0.842  1.0
  N  N38  1  0.908  0.989  0.342  1.0
  N  N39  1  0.408  0.011  0.158  1.0
[/CIF]
.
The material structure described by N4H3NH2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules and four N4H3 clusters. In each N4H3 cluster, there are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(5) atom. In the second N site, N(1) is bonded in a linear geometry to one N(2) and one N(3) atom. In the third N site, N(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. In the fourth N site, N(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) and one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF file [CIF]
data_HN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.499
_cell_length_b   5.790
_cell_length_c   12.659
_cell_angle_alpha   65.088
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   365.571
_cell_formula_units_Z   20
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.322  0.725  0.935  1.0
  H  H1  1  0.822  0.275  0.565  1.0
  H  H2  1  0.678  0.275  0.065  1.0
  H  H3  1  0.178  0.725  0.435  1.0
  H  H4  1  0.028  0.367  0.642  1.0
  H  H5  1  0.528  0.633  0.858  1.0
  H  H6  1  0.972  0.633  0.358  1.0
  H  H7  1  0.472  0.367  0.142  1.0
  H  H8  1  0.993  0.868  0.650  1.0
  H  H9  1  0.493  0.132  0.850  1.0
  H  H10  1  0.007  0.132  0.350  1.0
  H  H11  1  0.507  0.868  0.150  1.0
  H  H12  1  0.700  0.914  0.915  1.0
  H  H13  1  0.200  0.086  0.585  1.0
  H  H14  1  0.300  0.086  0.085  1.0
  H  H15  1  0.800  0.914  0.415  1.0
  H  H16  1  0.802  0.146  0.717  1.0
  H  H17  1  0.302  0.854  0.783  1.0
  H  H18  1  0.198  0.854  0.283  1.0
  H  H19  1  0.698  0.146  0.217  1.0
  N  N20  1  0.477  0.655  0.599  1.0
  N  N21  1  0.977  0.345  0.901  1.0
  N  N22  1  0.523  0.345  0.401  1.0
  N  N23  1  0.023  0.655  0.099  1.0
  N  N24  1  0.285  0.594  0.575  1.0
  N  N25  1  0.785  0.406  0.925  1.0
  N  N26  1  0.715  0.406  0.425  1.0
  N  N27  1  0.215  0.594  0.075  1.0
  N  N28  1  0.666  0.718  0.623  1.0
  N  N29  1  0.166  0.282  0.877  1.0
  N  N30  1  0.334  0.282  0.377  1.0
  N  N31  1  0.834  0.718  0.123  1.0
  N  N32  1  0.423  0.787  0.855  1.0
  N  N33  1  0.923  0.213  0.645  1.0
  N  N34  1  0.577  0.213  0.145  1.0
  N  N35  1  0.077  0.787  0.355  1.0
  N  N36  1  0.092  0.011  0.658  1.0
  N  N37  1  0.592  0.989  0.842  1.0
  N  N38  1  0.908  0.989  0.342  1.0
  N  N39  1  0.408  0.011  0.158  1.0
[/CIF]
.