The structure described by Cd(Pt3O4)3 crystallizes in the orthorhombic Pmmm space group. There are seven inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the second Pt site, Pt(2) is bonded in a square co-planar geometry to four equivalent O(2) atoms. In the third Pt site, Pt(3) is bonded in a square co-planar geometry to four equivalent O(3) atoms. In the fourth Pt site, Pt(4) is bonded in a rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. In the fifth Pt site, Pt(5) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the sixth Pt site, Pt(6) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. In the seventh Pt site, Pt(7) is bonded in a square co-planar geometry to four equivalent O(3) atoms. Cd(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Pt(1), one Pt(5), one Pt(6), and one Cd(1) atom to form a mixture of edge and corner-sharing OCdPt3 trigonal pyramids. In the second O site, O(2) is bonded to one Pt(2), one Pt(4), one Pt(6), and one Cd(1) atom to form a mixture of edge and corner-sharing OCdPt3 trigonal pyramids. In the third O site, O(3) is bonded in a trigonal planar geometry to one Pt(3), one Pt(4), and one Pt(7) atom. is represented by the CIF card [CIF]
data_Cd(Pt3O4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.736
_cell_length_b   5.753
_cell_length_c   17.159
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   566.215
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.332  1.0
  Cd  Cd1  1  0.500  0.500  0.668  1.0
  Pt  Pt2  1  0.500  0.000  0.419  1.0
  Pt  Pt3  1  0.500  0.000  0.754  1.0
  Pt  Pt4  1  0.500  0.000  0.083  1.0
  Pt  Pt5  1  0.752  0.500  0.162  1.0
  Pt  Pt6  1  0.758  0.500  0.500  1.0
  Pt  Pt7  1  0.752  0.500  0.838  1.0
  Pt  Pt8  1  0.000  0.757  0.331  1.0
  Pt  Pt9  1  0.000  0.757  0.669  1.0
  Pt  Pt10  1  0.000  0.754  0.000  1.0
  Pt  Pt11  1  0.500  0.000  0.246  1.0
  Pt  Pt12  1  0.500  0.000  0.581  1.0
  Pt  Pt13  1  0.500  0.000  0.917  1.0
  Pt  Pt14  1  0.248  0.500  0.162  1.0
  Pt  Pt15  1  0.242  0.500  0.500  1.0
  Pt  Pt16  1  0.248  0.500  0.838  1.0
  Pt  Pt17  1  0.000  0.243  0.331  1.0
  Pt  Pt18  1  0.000  0.243  0.669  1.0
  Pt  Pt19  1  0.000  0.246  0.000  1.0
  O  O20  1  0.742  0.741  0.413  1.0
  O  O21  1  0.740  0.740  0.749  1.0
  O  O22  1  0.750  0.753  0.082  1.0
  O  O23  1  0.260  0.260  0.251  1.0
  O  O24  1  0.258  0.259  0.587  1.0
  O  O25  1  0.250  0.247  0.918  1.0
  O  O26  1  0.260  0.740  0.251  1.0
  O  O27  1  0.258  0.741  0.587  1.0
  O  O28  1  0.250  0.753  0.918  1.0
  O  O29  1  0.742  0.259  0.413  1.0
  O  O30  1  0.740  0.260  0.749  1.0
  O  O31  1  0.750  0.247  0.082  1.0
  O  O32  1  0.258  0.259  0.413  1.0
  O  O33  1  0.260  0.260  0.749  1.0
  O  O34  1  0.250  0.247  0.082  1.0
  O  O35  1  0.740  0.740  0.251  1.0
  O  O36  1  0.742  0.741  0.587  1.0
  O  O37  1  0.750  0.753  0.918  1.0
  O  O38  1  0.740  0.260  0.251  1.0
  O  O39  1  0.742  0.259  0.587  1.0
  O  O40  1  0.750  0.247  0.918  1.0
  O  O41  1  0.258  0.741  0.413  1.0
  O  O42  1  0.260  0.740  0.749  1.0
  O  O43  1  0.250  0.753  0.082  1.0
[/CIF]
.
The structure described by Cd(Pt3O4)3 crystallizes in the orthorhombic Pmmm space group. There are seven inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the second Pt site, Pt(2) is bonded in a square co-planar geometry to four equivalent O(2) atoms. In the third Pt site, Pt(3) is bonded in a square co-planar geometry to four equivalent O(3) atoms. In the fourth Pt site, Pt(4) is bonded in a rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. In the fifth Pt site, Pt(5) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the sixth Pt site, Pt(6) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. In the seventh Pt site, Pt(7) is bonded in a square co-planar geometry to four equivalent O(3) atoms. Cd(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Pt(1), one Pt(5), one Pt(6), and one Cd(1) atom to form a mixture of edge and corner-sharing OCdPt3 trigonal pyramids. In the second O site, O(2) is bonded to one Pt(2), one Pt(4), one Pt(6), and one Cd(1) atom to form a mixture of edge and corner-sharing OCdPt3 trigonal pyramids. In the third O site, O(3) is bonded in a trigonal planar geometry to one Pt(3), one Pt(4), and one Pt(7) atom. is represented by the CIF card [CIF]
data_Cd(Pt3O4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.736
_cell_length_b   5.753
_cell_length_c   17.159
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   566.215
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.332  1.0
  Cd  Cd1  1  0.500  0.500  0.668  1.0
  Pt  Pt2  1  0.500  0.000  0.419  1.0
  Pt  Pt3  1  0.500  0.000  0.754  1.0
  Pt  Pt4  1  0.500  0.000  0.083  1.0
  Pt  Pt5  1  0.752  0.500  0.162  1.0
  Pt  Pt6  1  0.758  0.500  0.500  1.0
  Pt  Pt7  1  0.752  0.500  0.838  1.0
  Pt  Pt8  1  0.000  0.757  0.331  1.0
  Pt  Pt9  1  0.000  0.757  0.669  1.0
  Pt  Pt10  1  0.000  0.754  0.000  1.0
  Pt  Pt11  1  0.500  0.000  0.246  1.0
  Pt  Pt12  1  0.500  0.000  0.581  1.0
  Pt  Pt13  1  0.500  0.000  0.917  1.0
  Pt  Pt14  1  0.248  0.500  0.162  1.0
  Pt  Pt15  1  0.242  0.500  0.500  1.0
  Pt  Pt16  1  0.248  0.500  0.838  1.0
  Pt  Pt17  1  0.000  0.243  0.331  1.0
  Pt  Pt18  1  0.000  0.243  0.669  1.0
  Pt  Pt19  1  0.000  0.246  0.000  1.0
  O  O20  1  0.742  0.741  0.413  1.0
  O  O21  1  0.740  0.740  0.749  1.0
  O  O22  1  0.750  0.753  0.082  1.0
  O  O23  1  0.260  0.260  0.251  1.0
  O  O24  1  0.258  0.259  0.587  1.0
  O  O25  1  0.250  0.247  0.918  1.0
  O  O26  1  0.260  0.740  0.251  1.0
  O  O27  1  0.258  0.741  0.587  1.0
  O  O28  1  0.250  0.753  0.918  1.0
  O  O29  1  0.742  0.259  0.413  1.0
  O  O30  1  0.740  0.260  0.749  1.0
  O  O31  1  0.750  0.247  0.082  1.0
  O  O32  1  0.258  0.259  0.413  1.0
  O  O33  1  0.260  0.260  0.749  1.0
  O  O34  1  0.250  0.247  0.082  1.0
  O  O35  1  0.740  0.740  0.251  1.0
  O  O36  1  0.742  0.741  0.587  1.0
  O  O37  1  0.750  0.753  0.918  1.0
  O  O38  1  0.740  0.260  0.251  1.0
  O  O39  1  0.742  0.259  0.587  1.0
  O  O40  1  0.750  0.247  0.918  1.0
  O  O41  1  0.258  0.741  0.413  1.0
  O  O42  1  0.260  0.740  0.749  1.0
  O  O43  1  0.250  0.753  0.082  1.0
[/CIF]
.