The compound described by V3S4 crystallizes in the monoclinic C2/m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 7-coordinate geometry to three equivalent S(1) and four equivalent S(2) atoms. In the second V site, V(2) is bonded in a 4-coordinate geometry to four equivalent S(1) and four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to two equivalent V(2) and three equivalent V(1) atoms. In the second S site, S(2) is bonded in a 6-coordinate geometry to two equivalent V(2) and four equivalent V(1) atoms. is represented by the CIF card [CIF]
data_V3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.300
_cell_length_b   6.300
_cell_length_c   7.025
_cell_angle_alpha   57.741
_cell_angle_beta   57.741
_cell_angle_gamma   28.062
_symmetry_Int_Tables_number   1
_cell_volume   109.519
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.910  0.910  0.460  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  V  V2  1  0.090  0.090  0.540  1.0
  S  S3  1  0.339  0.339  0.277  1.0
  S  S4  1  0.592  0.592  0.256  1.0
  S  S5  1  0.661  0.661  0.723  1.0
  S  S6  1  0.408  0.408  0.744  1.0
[/CIF]
.
The compound described by V3S4 crystallizes in the monoclinic C2/m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 7-coordinate geometry to three equivalent S(1) and four equivalent S(2) atoms. In the second V site, V(2) is bonded in a 4-coordinate geometry to four equivalent S(1) and four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to two equivalent V(2) and three equivalent V(1) atoms. In the second S site, S(2) is bonded in a 6-coordinate geometry to two equivalent V(2) and four equivalent V(1) atoms. is represented by the CIF card [CIF]
data_V3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.300
_cell_length_b   6.300
_cell_length_c   7.025
_cell_angle_alpha   57.741
_cell_angle_beta   57.741
_cell_angle_gamma   28.062
_symmetry_Int_Tables_number   1
_cell_volume   109.519
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.910  0.910  0.460  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  V  V2  1  0.090  0.090  0.540  1.0
  S  S3  1  0.339  0.339  0.277  1.0
  S  S4  1  0.592  0.592  0.256  1.0
  S  S5  1  0.661  0.661  0.723  1.0
  S  S6  1  0.408  0.408  0.744  1.0
[/CIF]
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