The structure described by Na5MgSbO5 crystallizes in the triclinic P1 space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(4), and one O(5) atom. In the third Na site, Na(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the fourth Na site, Na(4) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the fifth Na site, Na(5) is bonded in a T-shaped geometry to one O(2), one O(3), and one O(4) atom. Mg(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. Sb(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Na(1), one Na(3), one Na(4), one Mg(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal bipyramidal geometry to one Na(2), one Na(3), one Na(4), one Na(5), and one Sb(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(3), one Na(5), and one Mg(1) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Na(1), one Na(2), one Na(4), one Na(5), one Mg(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(4), one Mg(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Na5MgSbO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.362
_cell_length_b   5.833
_cell_length_c   6.706
_cell_angle_alpha   79.581
_cell_angle_beta   86.925
_cell_angle_gamma   72.836
_symmetry_Int_Tables_number   1
_cell_volume   197.065
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.721  0.682  0.867  1.0
  Na  Na1  1  0.644  0.613  0.329  1.0
  Na  Na2  1  0.180  0.480  0.624  1.0
  Na  Na3  1  0.222  0.350  0.186  1.0
  Na  Na4  1  0.890  0.078  0.449  1.0
  Mg  Mg5  1  0.631  0.272  0.912  1.0
  Sb  Sb6  1  0.136  0.898  0.020  1.0
  O  O7  1  0.315  0.589  0.904  1.0
  O  O8  1  0.159  0.732  0.310  1.0
  O  O9  1  0.776  0.375  0.644  1.0
  O  O10  1  0.835  0.301  0.136  1.0
  O  O11  1  0.456  0.008  0.014  1.0
[/CIF]
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The structure described by Na5MgSbO5 crystallizes in the triclinic P1 space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(4), and one O(5) atom. In the third Na site, Na(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the fourth Na site, Na(4) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the fifth Na site, Na(5) is bonded in a T-shaped geometry to one O(2), one O(3), and one O(4) atom. Mg(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. Sb(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Na(1), one Na(3), one Na(4), one Mg(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal bipyramidal geometry to one Na(2), one Na(3), one Na(4), one Na(5), and one Sb(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(3), one Na(5), and one Mg(1) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Na(1), one Na(2), one Na(4), one Na(5), one Mg(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(4), one Mg(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Na5MgSbO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.362
_cell_length_b   5.833
_cell_length_c   6.706
_cell_angle_alpha   79.581
_cell_angle_beta   86.925
_cell_angle_gamma   72.836
_symmetry_Int_Tables_number   1
_cell_volume   197.065
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.721  0.682  0.867  1.0
  Na  Na1  1  0.644  0.613  0.329  1.0
  Na  Na2  1  0.180  0.480  0.624  1.0
  Na  Na3  1  0.222  0.350  0.186  1.0
  Na  Na4  1  0.890  0.078  0.449  1.0
  Mg  Mg5  1  0.631  0.272  0.912  1.0
  Sb  Sb6  1  0.136  0.898  0.020  1.0
  O  O7  1  0.315  0.589  0.904  1.0
  O  O8  1  0.159  0.732  0.310  1.0
  O  O9  1  0.776  0.375  0.644  1.0
  O  O10  1  0.835  0.301  0.136  1.0
  O  O11  1  0.456  0.008  0.014  1.0
[/CIF]
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