The structure described by Ho7In(CoGe3)4 crystallizes in the tetragonal P4/m space group. There are three inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 11-coordinate geometry to two equivalent Co(1), two equivalent In(1), one Ge(2), two equivalent Ge(3), and four equivalent Ge(1) atoms. In the second Ho site, Ho(2) is bonded in a 16-coordinate geometry to four equivalent Co(1), four equivalent Ge(3), and eight equivalent Ge(2) atoms. In the third Ho site, Ho(3) is bonded in a 14-coordinate geometry to four equivalent Co(1), two equivalent Ge(2), four equivalent Ge(1), and four equivalent Ge(3) atoms. Co(1) is bonded in a 5-coordinate geometry to one Ho(2), two equivalent Ho(1), two equivalent Ho(3), one Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. In(1) is bonded to eight equivalent Ho(1) and four equivalent Ge(1) atoms to form face-sharing InHo8Ge4 cuboctahedra. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Ho(3), four equivalent Ho(1), one Co(1), one In(1), and one Ge(3) atom. In the second Ge site, Ge(2) is bonded in a 6-coordinate geometry to one Ho(1), one Ho(3), two equivalent Ho(2), two equivalent Co(1), and two equivalent Ge(3) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Ho(2), two equivalent Ho(1), two equivalent Ho(3), two equivalent Co(1), one Ge(1), and two equivalent Ge(2) atoms. is represented by the CIF card [CIF]
data_Ho7In(CoGe3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.381
_cell_length_b   10.381
_cell_length_c   4.177
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.062
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.675  0.678  0.500  1.0
  Ho  Ho1  1  0.322  0.675  0.500  1.0
  Ho  Ho2  1  0.000  0.000  0.000  1.0
  Ho  Ho3  1  0.325  0.322  0.500  1.0
  Ho  Ho4  1  0.000  0.500  0.500  1.0
  Ho  Ho5  1  0.678  0.325  0.500  1.0
  Ho  Ho6  1  0.500  0.000  0.500  1.0
  In  In7  1  0.500  0.500  0.000  1.0
  Co  Co8  1  0.118  0.279  0.000  1.0
  Co  Co9  1  0.721  0.118  0.000  1.0
  Co  Co10  1  0.882  0.721  0.000  1.0
  Co  Co11  1  0.279  0.882  0.000  1.0
  Ge  Ge12  1  0.486  0.788  0.000  1.0
  Ge  Ge13  1  0.788  0.514  0.000  1.0
  Ge  Ge14  1  0.514  0.212  0.000  1.0
  Ge  Ge15  1  0.065  0.194  0.500  1.0
  Ge  Ge16  1  0.887  0.285  0.000  1.0
  Ge  Ge17  1  0.715  0.887  0.000  1.0
  Ge  Ge18  1  0.935  0.806  0.500  1.0
  Ge  Ge19  1  0.806  0.065  0.500  1.0
  Ge  Ge20  1  0.113  0.715  0.000  1.0
  Ge  Ge21  1  0.194  0.935  0.500  1.0
  Ge  Ge22  1  0.285  0.113  0.000  1.0
  Ge  Ge23  1  0.212  0.486  0.000  1.0
[/CIF]
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The structure described by Ho7In(CoGe3)4 crystallizes in the tetragonal P4/m space group. There are three inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 11-coordinate geometry to two equivalent Co(1), two equivalent In(1), one Ge(2), two equivalent Ge(3), and four equivalent Ge(1) atoms. In the second Ho site, Ho(2) is bonded in a 16-coordinate geometry to four equivalent Co(1), four equivalent Ge(3), and eight equivalent Ge(2) atoms. In the third Ho site, Ho(3) is bonded in a 14-coordinate geometry to four equivalent Co(1), two equivalent Ge(2), four equivalent Ge(1), and four equivalent Ge(3) atoms. Co(1) is bonded in a 5-coordinate geometry to one Ho(2), two equivalent Ho(1), two equivalent Ho(3), one Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. In(1) is bonded to eight equivalent Ho(1) and four equivalent Ge(1) atoms to form face-sharing InHo8Ge4 cuboctahedra. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Ho(3), four equivalent Ho(1), one Co(1), one In(1), and one Ge(3) atom. In the second Ge site, Ge(2) is bonded in a 6-coordinate geometry to one Ho(1), one Ho(3), two equivalent Ho(2), two equivalent Co(1), and two equivalent Ge(3) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Ho(2), two equivalent Ho(1), two equivalent Ho(3), two equivalent Co(1), one Ge(1), and two equivalent Ge(2) atoms. is represented by the CIF card [CIF]
data_Ho7In(CoGe3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.381
_cell_length_b   10.381
_cell_length_c   4.177
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.062
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.675  0.678  0.500  1.0
  Ho  Ho1  1  0.322  0.675  0.500  1.0
  Ho  Ho2  1  0.000  0.000  0.000  1.0
  Ho  Ho3  1  0.325  0.322  0.500  1.0
  Ho  Ho4  1  0.000  0.500  0.500  1.0
  Ho  Ho5  1  0.678  0.325  0.500  1.0
  Ho  Ho6  1  0.500  0.000  0.500  1.0
  In  In7  1  0.500  0.500  0.000  1.0
  Co  Co8  1  0.118  0.279  0.000  1.0
  Co  Co9  1  0.721  0.118  0.000  1.0
  Co  Co10  1  0.882  0.721  0.000  1.0
  Co  Co11  1  0.279  0.882  0.000  1.0
  Ge  Ge12  1  0.486  0.788  0.000  1.0
  Ge  Ge13  1  0.788  0.514  0.000  1.0
  Ge  Ge14  1  0.514  0.212  0.000  1.0
  Ge  Ge15  1  0.065  0.194  0.500  1.0
  Ge  Ge16  1  0.887  0.285  0.000  1.0
  Ge  Ge17  1  0.715  0.887  0.000  1.0
  Ge  Ge18  1  0.935  0.806  0.500  1.0
  Ge  Ge19  1  0.806  0.065  0.500  1.0
  Ge  Ge20  1  0.113  0.715  0.000  1.0
  Ge  Ge21  1  0.194  0.935  0.500  1.0
  Ge  Ge22  1  0.285  0.113  0.000  1.0
  Ge  Ge23  1  0.212  0.486  0.000  1.0
[/CIF]
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