The material structure described by WZnO2 crystallizes in the triclinic P-1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(4) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), and two equivalent O(3) atoms. In the second Zn site, Zn(2) is bonded in a distorted T-shaped geometry to one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one W(2), two equivalent W(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one W(1), two equivalent W(2), and one Zn(2) atom. In the third O site, O(3) is bonded to one W(1), one Zn(2), and two equivalent Zn(1) atoms to form distorted corner-sharing OZn3W tetrahedra. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent W(2), one Zn(1), and one Zn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnWO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.996
_cell_length_b   8.159
_cell_length_c   8.672
_cell_angle_alpha   95.155
_cell_angle_beta   90.608
_cell_angle_gamma   98.624
_symmetry_Int_Tables_number   1
_cell_volume   208.703
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.785  0.934  0.291  1.0
  Zn  Zn1  1  0.215  0.066  0.709  1.0
  Zn  Zn2  1  0.326  0.131  0.047  1.0
  Zn  Zn3  1  0.674  0.869  0.953  1.0
  W  W4  1  0.564  0.681  0.583  1.0
  W  W5  1  0.030  0.569  0.267  1.0
  W  W6  1  0.970  0.431  0.733  1.0
  W  W7  1  0.436  0.319  0.417  1.0
  O  O8  1  0.903  0.223  0.565  1.0
  O  O9  1  0.546  0.610  0.813  1.0
  O  O10  1  0.454  0.390  0.187  1.0
  O  O11  1  0.097  0.777  0.435  1.0
  O  O12  1  0.652  0.913  0.713  1.0
  O  O13  1  0.591  0.715  0.166  1.0
  O  O14  1  0.348  0.087  0.287  1.0
  O  O15  1  0.409  0.285  0.834  1.0
[/CIF]
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The material structure described by WZnO2 crystallizes in the triclinic P-1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(4) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), and two equivalent O(3) atoms. In the second Zn site, Zn(2) is bonded in a distorted T-shaped geometry to one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one W(2), two equivalent W(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one W(1), two equivalent W(2), and one Zn(2) atom. In the third O site, O(3) is bonded to one W(1), one Zn(2), and two equivalent Zn(1) atoms to form distorted corner-sharing OZn3W tetrahedra. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent W(2), one Zn(1), and one Zn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnWO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.996
_cell_length_b   8.159
_cell_length_c   8.672
_cell_angle_alpha   95.155
_cell_angle_beta   90.608
_cell_angle_gamma   98.624
_symmetry_Int_Tables_number   1
_cell_volume   208.703
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.785  0.934  0.291  1.0
  Zn  Zn1  1  0.215  0.066  0.709  1.0
  Zn  Zn2  1  0.326  0.131  0.047  1.0
  Zn  Zn3  1  0.674  0.869  0.953  1.0
  W  W4  1  0.564  0.681  0.583  1.0
  W  W5  1  0.030  0.569  0.267  1.0
  W  W6  1  0.970  0.431  0.733  1.0
  W  W7  1  0.436  0.319  0.417  1.0
  O  O8  1  0.903  0.223  0.565  1.0
  O  O9  1  0.546  0.610  0.813  1.0
  O  O10  1  0.454  0.390  0.187  1.0
  O  O11  1  0.097  0.777  0.435  1.0
  O  O12  1  0.652  0.913  0.713  1.0
  O  O13  1  0.591  0.715  0.166  1.0
  O  O14  1  0.348  0.087  0.287  1.0
  O  O15  1  0.409  0.285  0.834  1.0
[/CIF]
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