The material described by Te7(OF5)6 is Protactinium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Te7(OF5)6 cluster. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 42°. In the second Te site, Te(2,3) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 42°. In the third Te site, Te(4) is bonded to one O(3), one F(11), one F(12), one F(13), one F(14), and one F(15) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 42°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2,3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2,3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(2,3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2,3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(2,3) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2,3) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(2,3) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2,3) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(2,3) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(2,3) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(2,3) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2,3) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Te(4) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Te(4) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one Te(4) atom. In the fourteenth F site, F(14) is bonded in a single-bond geometry to one Te(4) atom. In the fifteenth F site, F(15) is bonded in a single-bond geometry to one Te(4) atom. is represented by the CIF card [CIF]
data_Te7(OF5)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.103
_cell_length_b   9.313
_cell_length_c   9.351
_cell_angle_alpha   115.436
_cell_angle_beta   100.230
_cell_angle_gamma   99.904
_symmetry_Int_Tables_number   1
_cell_volume   676.472
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.000  1.0
  Te  Te1  1  0.249  0.394  0.084  1.0
  Te  Te2  1  0.751  0.606  0.916  1.0
  Te  Te3  1  0.774  0.242  0.239  1.0
  Te  Te4  1  0.226  0.758  0.761  1.0
  Te  Te5  1  0.242  0.075  0.393  1.0
  Te  Te6  1  0.758  0.925  0.607  1.0
  O  O7  1  0.059  0.220  0.017  1.0
  O  O8  1  0.941  0.780  0.983  1.0
  O  O9  1  0.884  0.075  0.162  1.0
  O  O10  1  0.116  0.925  0.838  1.0
  O  O11  1  0.188  0.054  0.173  1.0
  O  O12  1  0.812  0.946  0.827  1.0
  F  F13  1  0.131  0.545  0.140  1.0
  F  F14  1  0.869  0.455  0.860  1.0
  F  F15  1  0.297  0.427  0.301  1.0
  F  F16  1  0.703  0.573  0.699  1.0
  F  F17  1  0.370  0.246  0.029  1.0
  F  F18  1  0.630  0.754  0.971  1.0
  F  F19  1  0.205  0.370  0.871  1.0
  F  F20  1  0.795  0.630  0.129  1.0
  F  F21  1  0.425  0.568  0.147  1.0
  F  F22  1  0.575  0.432  0.853  1.0
  F  F23  1  0.820  0.244  0.443  1.0
  F  F24  1  0.180  0.756  0.557  1.0
  F  F25  1  0.954  0.415  0.314  1.0
  F  F26  1  0.046  0.585  0.686  1.0
  F  F27  1  0.725  0.244  0.037  1.0
  F  F28  1  0.275  0.756  0.963  1.0
  F  F29  1  0.591  0.075  0.170  1.0
  F  F30  1  0.409  0.925  0.830  1.0
  F  F31  1  0.666  0.399  0.320  1.0
  F  F32  1  0.334  0.601  0.680  1.0
  F  F33  1  0.429  0.227  0.439  1.0
  F  F34  1  0.571  0.773  0.561  1.0
  F  F35  1  0.150  0.248  0.476  1.0
  F  F36  1  0.850  0.752  0.524  1.0
  F  F37  1  0.056  0.921  0.350  1.0
  F  F38  1  0.944  0.079  0.650  1.0
  F  F39  1  0.337  0.905  0.319  1.0
  F  F40  1  0.663  0.095  0.681  1.0
  F  F41  1  0.304  0.099  0.605  1.0
  F  F42  1  0.696  0.901  0.395  1.0
[/CIF]
.
The material described by Te7(OF5)6 is Protactinium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Te7(OF5)6 cluster. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 42°. In the second Te site, Te(2,3) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 42°. In the third Te site, Te(4) is bonded to one O(3), one F(11), one F(12), one F(13), one F(14), and one F(15) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 42°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2,3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2,3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(2,3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2,3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(2,3) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2,3) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(2,3) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2,3) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(2,3) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(2,3) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(2,3) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2,3) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Te(4) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Te(4) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one Te(4) atom. In the fourteenth F site, F(14) is bonded in a single-bond geometry to one Te(4) atom. In the fifteenth F site, F(15) is bonded in a single-bond geometry to one Te(4) atom. is represented by the CIF card [CIF]
data_Te7(OF5)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.103
_cell_length_b   9.313
_cell_length_c   9.351
_cell_angle_alpha   115.436
_cell_angle_beta   100.230
_cell_angle_gamma   99.904
_symmetry_Int_Tables_number   1
_cell_volume   676.472
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.000  1.0
  Te  Te1  1  0.249  0.394  0.084  1.0
  Te  Te2  1  0.751  0.606  0.916  1.0
  Te  Te3  1  0.774  0.242  0.239  1.0
  Te  Te4  1  0.226  0.758  0.761  1.0
  Te  Te5  1  0.242  0.075  0.393  1.0
  Te  Te6  1  0.758  0.925  0.607  1.0
  O  O7  1  0.059  0.220  0.017  1.0
  O  O8  1  0.941  0.780  0.983  1.0
  O  O9  1  0.884  0.075  0.162  1.0
  O  O10  1  0.116  0.925  0.838  1.0
  O  O11  1  0.188  0.054  0.173  1.0
  O  O12  1  0.812  0.946  0.827  1.0
  F  F13  1  0.131  0.545  0.140  1.0
  F  F14  1  0.869  0.455  0.860  1.0
  F  F15  1  0.297  0.427  0.301  1.0
  F  F16  1  0.703  0.573  0.699  1.0
  F  F17  1  0.370  0.246  0.029  1.0
  F  F18  1  0.630  0.754  0.971  1.0
  F  F19  1  0.205  0.370  0.871  1.0
  F  F20  1  0.795  0.630  0.129  1.0
  F  F21  1  0.425  0.568  0.147  1.0
  F  F22  1  0.575  0.432  0.853  1.0
  F  F23  1  0.820  0.244  0.443  1.0
  F  F24  1  0.180  0.756  0.557  1.0
  F  F25  1  0.954  0.415  0.314  1.0
  F  F26  1  0.046  0.585  0.686  1.0
  F  F27  1  0.725  0.244  0.037  1.0
  F  F28  1  0.275  0.756  0.963  1.0
  F  F29  1  0.591  0.075  0.170  1.0
  F  F30  1  0.409  0.925  0.830  1.0
  F  F31  1  0.666  0.399  0.320  1.0
  F  F32  1  0.334  0.601  0.680  1.0
  F  F33  1  0.429  0.227  0.439  1.0
  F  F34  1  0.571  0.773  0.561  1.0
  F  F35  1  0.150  0.248  0.476  1.0
  F  F36  1  0.850  0.752  0.524  1.0
  F  F37  1  0.056  0.921  0.350  1.0
  F  F38  1  0.944  0.079  0.650  1.0
  F  F39  1  0.337  0.905  0.319  1.0
  F  F40  1  0.663  0.095  0.681  1.0
  F  F41  1  0.304  0.099  0.605  1.0
  F  F42  1  0.696  0.901  0.395  1.0
[/CIF]
.