The structure described by Li4Nb2V3Mn3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Nb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-62°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent Nb(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-67°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Nb(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-67°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. There are two inequivalent Nb sites. In the first Nb site, Nb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted NbO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the second Nb site, Nb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form NbO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Nb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Nb(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Nb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Nb(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Nb(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-48°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Nb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Nb(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Nb(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Nb(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Nb(1), one V(3), and one Mn(2) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Nb(1), one V(1), and one V(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(1) atom to form corner-sharing OLiMnV2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(2), and one Mn(3) atom to form corner-sharing OLiMn2V tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Nb(1), one V(3), and one Mn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Nb(1), one V(1), and one Mn(1) atom to form distorted OLiMnNbV tetrahedra that share  a cornercorner with one O(8)LiMnNbV tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra, and  an edgeedge with one O(8)LiMnNbV tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Nb(1), one V(2), and one Mn(1) atom to form distorted OLiMnNbV tetrahedra that share  a cornercorner with one O(7)LiMnNbV tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra, and  an edgeedge with one O(7)LiMnNbV tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Nb(2), one V(1), and one V(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Nb(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Nb(2), one V(3), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Nb(2), one V(3), and one Mn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Nb(2), one V(1), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Nb(2), one Mn(2), and one Mn(3) atom to form distorted corner-sharing OLiMn2Nb tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Nb(2), one V(2), and one Mn(1) atom. is represented by the CIF card [CIF]
data_Li4Mn3Nb2V3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.020
_cell_length_b   5.890
_cell_length_c   9.777
_cell_angle_alpha   89.946
_cell_angle_beta   91.488
_cell_angle_gamma   119.237
_symmetry_Int_Tables_number   1
_cell_volume   302.372
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.315  0.657  0.899  1.0
  Li  Li1  1  0.003  0.003  0.992  1.0
  Li  Li2  1  0.008  0.004  0.490  1.0
  Li  Li3  1  0.662  0.329  0.401  1.0
  Mn  Mn4  1  0.668  0.834  0.212  1.0
  Mn  Mn5  1  0.830  0.661  0.715  1.0
  Mn  Mn6  1  0.830  0.170  0.715  1.0
  Nb  Nb7  1  0.340  0.670  0.495  1.0
  Nb  Nb8  1  0.651  0.326  0.994  1.0
  V  V9  1  0.174  0.821  0.218  1.0
  V  V10  1  0.174  0.352  0.219  1.0
  V  V11  1  0.343  0.171  0.721  1.0
  O  O12  1  0.189  0.846  0.591  1.0
  O  O13  1  0.034  0.517  0.345  1.0
  O  O14  1  0.320  0.659  0.106  1.0
  O  O15  1  0.017  0.008  0.301  1.0
  O  O16  1  0.015  0.008  0.802  1.0
  O  O17  1  0.189  0.343  0.591  1.0
  O  O18  1  0.475  0.960  0.339  1.0
  O  O19  1  0.475  0.514  0.339  1.0
  O  O20  1  0.334  0.167  0.102  1.0
  O  O21  1  0.680  0.841  0.590  1.0
  O  O22  1  0.500  0.470  0.848  1.0
  O  O23  1  0.499  0.030  0.848  1.0
  O  O24  1  0.648  0.324  0.614  1.0
  O  O25  1  0.839  0.667  0.091  1.0
  O  O26  1  0.950  0.474  0.841  1.0
  O  O27  1  0.839  0.173  0.092  1.0
[/CIF]
.
The structure described by Li4Nb2V3Mn3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Nb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-62°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent Nb(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-67°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Nb(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-67°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. There are two inequivalent Nb sites. In the first Nb site, Nb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted NbO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the second Nb site, Nb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form NbO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Nb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Nb(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Nb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Nb(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Nb(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-48°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Nb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Nb(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Nb(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Nb(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Nb(1), one V(3), and one Mn(2) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Nb(1), one V(1), and one V(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(1) atom to form corner-sharing OLiMnV2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(2), and one Mn(3) atom to form corner-sharing OLiMn2V tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Nb(1), one V(3), and one Mn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Nb(1), one V(1), and one Mn(1) atom to form distorted OLiMnNbV tetrahedra that share  a cornercorner with one O(8)LiMnNbV tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra, and  an edgeedge with one O(8)LiMnNbV tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Nb(1), one V(2), and one Mn(1) atom to form distorted OLiMnNbV tetrahedra that share  a cornercorner with one O(7)LiMnNbV tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra, and  an edgeedge with one O(7)LiMnNbV tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Nb(2), one V(1), and one V(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Nb(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Nb(2), one V(3), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Nb(2), one V(3), and one Mn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Nb(2), one V(1), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Nb(2), one Mn(2), and one Mn(3) atom to form distorted corner-sharing OLiMn2Nb tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Nb(2), one V(2), and one Mn(1) atom. is represented by the CIF card [CIF]
data_Li4Mn3Nb2V3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.020
_cell_length_b   5.890
_cell_length_c   9.777
_cell_angle_alpha   89.946
_cell_angle_beta   91.488
_cell_angle_gamma   119.237
_symmetry_Int_Tables_number   1
_cell_volume   302.372
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.315  0.657  0.899  1.0
  Li  Li1  1  0.003  0.003  0.992  1.0
  Li  Li2  1  0.008  0.004  0.490  1.0
  Li  Li3  1  0.662  0.329  0.401  1.0
  Mn  Mn4  1  0.668  0.834  0.212  1.0
  Mn  Mn5  1  0.830  0.661  0.715  1.0
  Mn  Mn6  1  0.830  0.170  0.715  1.0
  Nb  Nb7  1  0.340  0.670  0.495  1.0
  Nb  Nb8  1  0.651  0.326  0.994  1.0
  V  V9  1  0.174  0.821  0.218  1.0
  V  V10  1  0.174  0.352  0.219  1.0
  V  V11  1  0.343  0.171  0.721  1.0
  O  O12  1  0.189  0.846  0.591  1.0
  O  O13  1  0.034  0.517  0.345  1.0
  O  O14  1  0.320  0.659  0.106  1.0
  O  O15  1  0.017  0.008  0.301  1.0
  O  O16  1  0.015  0.008  0.802  1.0
  O  O17  1  0.189  0.343  0.591  1.0
  O  O18  1  0.475  0.960  0.339  1.0
  O  O19  1  0.475  0.514  0.339  1.0
  O  O20  1  0.334  0.167  0.102  1.0
  O  O21  1  0.680  0.841  0.590  1.0
  O  O22  1  0.500  0.470  0.848  1.0
  O  O23  1  0.499  0.030  0.848  1.0
  O  O24  1  0.648  0.324  0.614  1.0
  O  O25  1  0.839  0.667  0.091  1.0
  O  O26  1  0.950  0.474  0.841  1.0
  O  O27  1  0.839  0.173  0.092  1.0
[/CIF]
.