The structure described by Li2V3O8 crystallizes in the cubic P4_332 space group. Li(1) is bonded to one O(2) and three equivalent O(1) atoms to form LiO4 tetrahedra that share corners with nine equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-59°. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra and edges with four equivalent V(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded to one Li(1) and three equivalent V(1) atoms to form distorted corner-sharing OLiV3 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.289
_cell_length_b   8.289
_cell_length_c   8.289
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   569.604
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.995  0.995  0.995  1.0
  Li  Li1  1  0.005  0.495  0.505  1.0
  Li  Li2  1  0.255  0.255  0.255  1.0
  Li  Li3  1  0.245  0.745  0.755  1.0
  Li  Li4  1  0.505  0.005  0.495  1.0
  Li  Li5  1  0.495  0.505  0.005  1.0
  Li  Li6  1  0.755  0.245  0.745  1.0
  Li  Li7  1  0.745  0.755  0.245  1.0
  V  V8  1  0.133  0.117  0.625  1.0
  V  V9  1  0.117  0.625  0.133  1.0
  V  V10  1  0.125  0.367  0.883  1.0
  V  V11  1  0.383  0.375  0.633  1.0
  V  V12  1  0.375  0.633  0.383  1.0
  V  V13  1  0.367  0.883  0.125  1.0
  V  V14  1  0.625  0.133  0.117  1.0
  V  V15  1  0.633  0.383  0.375  1.0
  V  V16  1  0.617  0.875  0.867  1.0
  V  V17  1  0.883  0.125  0.367  1.0
  V  V18  1  0.867  0.617  0.875  1.0
  V  V19  1  0.875  0.867  0.617  1.0
  O  O20  1  0.141  0.394  0.096  1.0
  O  O21  1  0.096  0.141  0.394  1.0
  O  O22  1  0.139  0.361  0.639  1.0
  O  O23  1  0.154  0.856  0.109  1.0
  O  O24  1  0.109  0.154  0.856  1.0
  O  O25  1  0.144  0.609  0.346  1.0
  O  O26  1  0.106  0.904  0.641  1.0
  O  O27  1  0.111  0.611  0.889  1.0
  O  O28  1  0.394  0.096  0.141  1.0
  O  O29  1  0.389  0.389  0.389  1.0
  O  O30  1  0.346  0.144  0.609  1.0
  O  O31  1  0.356  0.391  0.846  1.0
  O  O32  1  0.361  0.639  0.139  1.0
  O  O33  1  0.391  0.846  0.356  1.0
  O  O34  1  0.359  0.606  0.596  1.0
  O  O35  1  0.404  0.859  0.894  1.0
  O  O36  1  0.639  0.139  0.361  1.0
  O  O37  1  0.609  0.346  0.144  1.0
  O  O38  1  0.596  0.359  0.606  1.0
  O  O39  1  0.606  0.596  0.359  1.0
  O  O40  1  0.641  0.106  0.904  1.0
  O  O41  1  0.654  0.644  0.891  1.0
  O  O42  1  0.611  0.889  0.111  1.0
  O  O43  1  0.644  0.891  0.654  1.0
  O  O44  1  0.856  0.109  0.154  1.0
  O  O45  1  0.889  0.111  0.611  1.0
  O  O46  1  0.846  0.356  0.391  1.0
  O  O47  1  0.904  0.641  0.106  1.0
  O  O48  1  0.891  0.654  0.644  1.0
  O  O49  1  0.894  0.404  0.859  1.0
  O  O50  1  0.859  0.894  0.404  1.0
  O  O51  1  0.861  0.861  0.861  1.0
[/CIF]
.
The structure described by Li2V3O8 crystallizes in the cubic P4_332 space group. Li(1) is bonded to one O(2) and three equivalent O(1) atoms to form LiO4 tetrahedra that share corners with nine equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-59°. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra and edges with four equivalent V(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded to one Li(1) and three equivalent V(1) atoms to form distorted corner-sharing OLiV3 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.289
_cell_length_b   8.289
_cell_length_c   8.289
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   569.604
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.995  0.995  0.995  1.0
  Li  Li1  1  0.005  0.495  0.505  1.0
  Li  Li2  1  0.255  0.255  0.255  1.0
  Li  Li3  1  0.245  0.745  0.755  1.0
  Li  Li4  1  0.505  0.005  0.495  1.0
  Li  Li5  1  0.495  0.505  0.005  1.0
  Li  Li6  1  0.755  0.245  0.745  1.0
  Li  Li7  1  0.745  0.755  0.245  1.0
  V  V8  1  0.133  0.117  0.625  1.0
  V  V9  1  0.117  0.625  0.133  1.0
  V  V10  1  0.125  0.367  0.883  1.0
  V  V11  1  0.383  0.375  0.633  1.0
  V  V12  1  0.375  0.633  0.383  1.0
  V  V13  1  0.367  0.883  0.125  1.0
  V  V14  1  0.625  0.133  0.117  1.0
  V  V15  1  0.633  0.383  0.375  1.0
  V  V16  1  0.617  0.875  0.867  1.0
  V  V17  1  0.883  0.125  0.367  1.0
  V  V18  1  0.867  0.617  0.875  1.0
  V  V19  1  0.875  0.867  0.617  1.0
  O  O20  1  0.141  0.394  0.096  1.0
  O  O21  1  0.096  0.141  0.394  1.0
  O  O22  1  0.139  0.361  0.639  1.0
  O  O23  1  0.154  0.856  0.109  1.0
  O  O24  1  0.109  0.154  0.856  1.0
  O  O25  1  0.144  0.609  0.346  1.0
  O  O26  1  0.106  0.904  0.641  1.0
  O  O27  1  0.111  0.611  0.889  1.0
  O  O28  1  0.394  0.096  0.141  1.0
  O  O29  1  0.389  0.389  0.389  1.0
  O  O30  1  0.346  0.144  0.609  1.0
  O  O31  1  0.356  0.391  0.846  1.0
  O  O32  1  0.361  0.639  0.139  1.0
  O  O33  1  0.391  0.846  0.356  1.0
  O  O34  1  0.359  0.606  0.596  1.0
  O  O35  1  0.404  0.859  0.894  1.0
  O  O36  1  0.639  0.139  0.361  1.0
  O  O37  1  0.609  0.346  0.144  1.0
  O  O38  1  0.596  0.359  0.606  1.0
  O  O39  1  0.606  0.596  0.359  1.0
  O  O40  1  0.641  0.106  0.904  1.0
  O  O41  1  0.654  0.644  0.891  1.0
  O  O42  1  0.611  0.889  0.111  1.0
  O  O43  1  0.644  0.891  0.654  1.0
  O  O44  1  0.856  0.109  0.154  1.0
  O  O45  1  0.889  0.111  0.611  1.0
  O  O46  1  0.846  0.356  0.391  1.0
  O  O47  1  0.904  0.641  0.106  1.0
  O  O48  1  0.891  0.654  0.644  1.0
  O  O49  1  0.894  0.404  0.859  1.0
  O  O50  1  0.859  0.894  0.404  1.0
  O  O51  1  0.861  0.861  0.861  1.0
[/CIF]
.