The material described by Ba10CuZn4(WO6)5 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic C2/m space group. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(2), one O(4), two equivalent O(1), two equivalent O(10), two equivalent O(9), and four equivalent O(6) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(1)O12 cuboctahedra, corners with two equivalent Ba(2)O12 cuboctahedra, corners with two equivalent Ba(5)O12 cuboctahedra, corners with three equivalent Ba(3)O12 cuboctahedra, corners with three equivalent Ba(4)O12 cuboctahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(5)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(4)O12 cuboctahedra,  a faceface with one W(2)O6 octahedra,  a faceface with one W(3)O6 octahedra, faces with two equivalent W(1)O6 octahedra, faces with two equivalent Zn(1)O6 octahedra, and faces with two equivalent Zn(2)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(1), one O(3), two equivalent O(10), two equivalent O(2), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(1)O12 cuboctahedra, corners with two equivalent Ba(2)O12 cuboctahedra, corners with two equivalent Ba(3)O12 cuboctahedra, corners with three equivalent Ba(4)O12 cuboctahedra, corners with three equivalent Ba(5)O12 cuboctahedra,  a faceface with one Ba(4)O12 cuboctahedra,  a faceface with one Ba(5)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra,  a faceface with one W(1)O6 octahedra,  a faceface with one W(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Zn(2)O6 octahedra, faces with two equivalent W(2)O6 octahedra, and faces with two equivalent Zn(1)O6 octahedra. In the third Ba site, Ba(3) is bonded to one O(2), one O(5), two equivalent O(3), two equivalent O(8), two equivalent O(9), and four equivalent O(7) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(2)O12 cuboctahedra, corners with two equivalent Ba(3)O12 cuboctahedra, corners with two equivalent Ba(4)O12 cuboctahedra, corners with three equivalent Ba(1)O12 cuboctahedra, corners with three equivalent Ba(5)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Ba(4)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(5)O12 cuboctahedra,  a faceface with one Zn(1)O6 octahedra,  a faceface with one Zn(2)O6 octahedra, faces with two equivalent W(2)O6 octahedra, faces with two equivalent W(3)O6 octahedra, and faces with two equivalent Cu(1)O6 octahedra. In the fourth Ba site, Ba(4) is bonded to one O(1), two equivalent O(6), two equivalent O(9), three equivalent O(4), and four equivalent O(8) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(3)O12 cuboctahedra, corners with two equivalent Ba(4)O12 cuboctahedra, corners with two equivalent Ba(5)O12 cuboctahedra, corners with three equivalent Ba(1)O12 cuboctahedra, corners with three equivalent Ba(2)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(4)O12 cuboctahedra,  a faceface with one W(1)O6 octahedra,  a faceface with one Zn(2)O6 octahedra, faces with three equivalent W(3)O6 octahedra, and faces with three equivalent Zn(1)O6 octahedra. In the fifth Ba site, Ba(5) is bonded to one O(3), two equivalent O(7), two equivalent O(9), three equivalent O(5), and four equivalent O(10) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(1)O12 cuboctahedra, corners with two equivalent Ba(4)O12 cuboctahedra, corners with two equivalent Ba(5)O12 cuboctahedra, corners with three equivalent Ba(2)O12 cuboctahedra, corners with three equivalent Ba(3)O12 cuboctahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with two equivalent Ba(5)O12 cuboctahedra,  a faceface with one W(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra, faces with three equivalent W(2)O6 octahedra, and faces with three equivalent Zn(2)O6 octahedra. There are three inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1) and four equivalent O(6) atoms to form WO6 octahedra that share corners with two equivalent Zn(2)O6 octahedra, corners with four equivalent Zn(1)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(4)O12 cuboctahedra, and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second W site, W(2) is bonded to one O(2), one O(5), two equivalent O(10), and two equivalent O(7) atoms to form WO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, and faces with three equivalent Ba(5)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third W site, W(3) is bonded to one O(3), one O(4), two equivalent O(8), and two equivalent O(9) atoms to form WO6 octahedra that share  a cornercorner with one Cu(1)O6 octahedra, corners with two equivalent Zn(2)O6 octahedra, corners with three equivalent Zn(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(5)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, and faces with three equivalent Ba(4)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Cu(1) is bonded to two equivalent O(3) and four equivalent O(7) atoms to form CuO6 octahedra that share corners with two equivalent W(3)O6 octahedra, corners with four equivalent W(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(5)O12 cuboctahedra, and faces with four equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), two equivalent O(6), and two equivalent O(8) atoms to form ZnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with three equivalent W(3)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, and faces with three equivalent Ba(4)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Zn site, Zn(2) is bonded to one O(1), one O(5), two equivalent O(10), and two equivalent O(9) atoms to form ZnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(3)O6 octahedra, corners with three equivalent W(2)O6 octahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Ba(4)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(5)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Ba(2), one Ba(4), two equivalent Ba(1), one W(1), and one Zn(2) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(4)Ba4ZnW octahedra,  a cornercorner with one O(5)Ba4ZnW octahedra, corners with two equivalent O(7)Ba4CuW octahedra, corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(9)Ba4ZnW octahedra, corners with three equivalent O(1)Ba4ZnW octahedra, corners with four equivalent O(6)Ba4ZnW octahedra, corners with six equivalent O(8)Ba4ZnW octahedra, edges with two equivalent O(2)Ba4ZnW octahedra, edges with two equivalent O(4)Ba4ZnW octahedra, faces with two equivalent O(10)Ba4ZnW octahedra, faces with two equivalent O(9)Ba4ZnW octahedra, and faces with four equivalent O(6)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the second O site, O(2) is bonded to one Ba(1), one Ba(3), two equivalent Ba(2), one W(2), and one Zn(1) atom to form distorted OBa4ZnW octahedra that share corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(4)Ba4ZnW octahedra, corners with two equivalent O(5)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(7)Ba4CuW octahedra, corners with four equivalent O(6)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra, edges with two equivalent O(3)Ba4CuW octahedra, edges with two equivalent O(1)Ba4ZnW octahedra, faces with two equivalent O(7)Ba4CuW octahedra, faces with two equivalent O(10)Ba4ZnW octahedra, faces with two equivalent O(6)Ba4ZnW octahedra, and faces with two equivalent O(8)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the third O site, O(3) is bonded to one Ba(2), one Ba(5), two equivalent Ba(3), one W(3), and one Cu(1) atom to form distorted OBa4CuW octahedra that share  a cornercorner with one O(1)Ba4ZnW octahedra,  a cornercorner with one O(4)Ba4ZnW octahedra,  a cornercorner with one O(5)Ba4ZnW octahedra, corners with two equivalent O(6)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with two equivalent O(9)Ba4ZnW octahedra, corners with three equivalent O(3)Ba4CuW octahedra, corners with four equivalent O(7)Ba4CuW octahedra, corners with six equivalent O(10)Ba4ZnW octahedra, edges with two equivalent O(2)Ba4ZnW octahedra, edges with two equivalent O(5)Ba4ZnW octahedra, faces with two equivalent O(8)Ba4ZnW octahedra, faces with two equivalent O(9)Ba4ZnW octahedra, and faces with four equivalent O(7)Ba4CuW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the fourth O site, O(4) is bonded to one Ba(1), three equivalent Ba(4), one W(3), and one Zn(1) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(1)Ba4ZnW octahedra, corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(4)Ba4ZnW octahedra, corners with four equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra, corners with six equivalent O(6)Ba4ZnW octahedra, edges with two equivalent O(1)Ba4ZnW octahedra, edges with two equivalent O(4)Ba4ZnW octahedra, faces with two equivalent O(6)Ba4ZnW octahedra, faces with two equivalent O(9)Ba4ZnW octahedra, and faces with four equivalent O(8)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the fifth O site, O(5) is bonded to one Ba(3), three equivalent Ba(5), one W(2), and one Zn(2) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(1)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(5)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(10)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra, corners with six equivalent O(7)Ba4CuW octahedra, edges with two equivalent O(3)Ba4CuW octahedra, edges with two equivalent O(5)Ba4ZnW octahedra, faces with two equivalent O(7)Ba4CuW octahedra, faces with two equivalent O(9)Ba4ZnW octahedra, and faces with four equivalent O(10)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the sixth O site, O(6) is bonded to one Ba(2), one Ba(4), two equivalent Ba(1), one W(1), and one Zn(1) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(6)Ba4ZnW octahedra, corners with two equivalent O(7)Ba4CuW octahedra, corners with two equivalent O(1)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with three equivalent O(4)Ba4ZnW octahedra, corners with three equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(10)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra,  an edgeedge with one O(10)Ba4ZnW octahedra,  an edgeedge with one O(6)Ba4ZnW octahedra,  an edgeedge with one O(8)Ba4ZnW octahedra,  an edgeedge with one O(9)Ba4ZnW octahedra,  a faceface with one O(2)Ba4ZnW octahedra,  a faceface with one O(4)Ba4ZnW octahedra,  a faceface with one O(8)Ba4ZnW octahedra, faces with two equivalent O(1)Ba4ZnW octahedra, and faces with three equivalent O(6)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the seventh O site, O(7) is bonded to one Ba(2), one Ba(5), two equivalent Ba(3), one W(2), and one Cu(1) atom to form distorted OBa4CuW octahedra that share  a cornercorner with one O(7)Ba4CuW octahedra,  a cornercorner with one O(1)Ba4ZnW octahedra, corners with two equivalent O(3)Ba4CuW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(6)Ba4ZnW octahedra, corners with three equivalent O(10)Ba4ZnW octahedra, corners with three equivalent O(5)Ba4ZnW octahedra, corners with four equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra,  an edgeedge with one O(7)Ba4CuW octahedra,  an edgeedge with one O(10)Ba4ZnW octahedra,  an edgeedge with one O(8)Ba4ZnW octahedra,  an edgeedge with one O(9)Ba4ZnW octahedra,  a faceface with one O(10)Ba4ZnW octahedra,  a faceface with one O(2)Ba4ZnW octahedra,  a faceface with one O(5)Ba4ZnW octahedra, faces with two equivalent O(3)Ba4CuW octahedra, and faces with three equivalent O(7)Ba4CuW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the eighth O site, O(8) is bonded to one Ba(2), one Ba(3), two equivalent Ba(4), one W(3), and one Zn(1) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(2)Ba4ZnW octahedra,  a cornercorner with one O(5)Ba4ZnW octahedra, corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(4)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with three equivalent O(1)Ba4ZnW octahedra, corners with three equivalent O(6)Ba4ZnW octahedra, corners with three equivalent O(9)Ba4ZnW octahedra, corners with four equivalent O(7)Ba4CuW octahedra,  an edgeedge with one O(7)Ba4CuW octahedra,  an edgeedge with one O(6)Ba4ZnW octahedra,  an edgeedge with one O(8)Ba4ZnW octahedra,  an edgeedge with one O(9)Ba4ZnW octahedra,  a faceface with one O(3)Ba4CuW octahedra,  a faceface with one O(2)Ba4ZnW octahedra,  a faceface with one O(6)Ba4ZnW octahedra,  a faceface with one O(9)Ba4ZnW octahedra, faces with two equivalent O(4)Ba4ZnW octahedra, and faces with two equivalent O(8)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the ninth O site, O(9) is bonded to one Ba(1), one Ba(3), one Ba(4), one Ba(5), one W(3), and one Zn(2) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(1)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(4)Ba4ZnW octahedra, corners with two equivalent O(5)Ba4ZnW octahedra, corners with three equivalent O(10)Ba4ZnW octahedra, corners with three equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(7)Ba4CuW octahedra, corners with four equivalent O(6)Ba4ZnW octahedra,  an edgeedge with one O(7)Ba4CuW octahedra,  an edgeedge with one O(10)Ba4ZnW octahedra,  an edgeedge with one O(6)Ba4ZnW octahedra,  an edgeedge with one O(8)Ba4ZnW octahedra,  a faceface with one O(3)Ba4CuW octahedra,  a faceface with one O(1)Ba4ZnW octahedra,  a faceface with one O(10)Ba4ZnW octahedra,  a faceface with one O(4)Ba4ZnW octahedra,  a faceface with one O(5)Ba4ZnW octahedra,  a faceface with one O(8)Ba4ZnW octahedra, and faces with two equivalent O(9)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the tenth O site, O(10) is bonded to one Ba(1), one Ba(2), two equivalent Ba(5), one W(2), and one Zn(2) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(1)Ba4ZnW octahedra,  a cornercorner with one O(2)Ba4ZnW octahedra,  a cornercorner with one O(4)Ba4ZnW octahedra, corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(5)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with three equivalent O(3)Ba4CuW octahedra, corners with three equivalent O(7)Ba4CuW octahedra, corners with three equivalent O(9)Ba4ZnW octahedra, corners with four equivalent O(6)Ba4ZnW octahedra,  an edgeedge with one O(7)Ba4CuW octahedra,  an edgeedge with one O(10)Ba4ZnW octahedra,  an edgeedge with one O(6)Ba4ZnW octahedra,  an edgeedge with one O(9)Ba4ZnW octahedra,  a faceface with one O(7)Ba4CuW octahedra,  a faceface with one O(1)Ba4ZnW octahedra,  a faceface with one O(2)Ba4ZnW octahedra,  a faceface with one O(9)Ba4ZnW octahedra, faces with two equivalent O(10)Ba4ZnW octahedra, and faces with two equivalent O(5)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF file [CIF]
data_Ba10Zn4Cu(WO6)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.104
_cell_length_b   10.104
_cell_length_c   14.290
_cell_angle_alpha   61.890
_cell_angle_beta   61.890
_cell_angle_gamma   33.554
_symmetry_Int_Tables_number   1
_cell_volume   701.907
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.400  0.400  0.650  1.0
  Ba  Ba1  1  1.000  1.000  0.250  1.0
  Ba  Ba2  1  0.600  0.600  0.850  1.0
  Ba  Ba3  1  0.200  0.200  0.450  1.0
  Ba  Ba4  1  0.800  0.800  0.050  1.0
  Ba  Ba5  1  0.600  0.600  0.350  1.0
  Ba  Ba6  1  0.200  0.200  0.950  1.0
  Ba  Ba7  1  0.800  0.800  0.550  1.0
  Ba  Ba8  1  0.400  0.400  0.150  1.0
  Ba  Ba9  1  0.000  0.000  0.750  1.0
  Zn  Zn10  1  0.600  0.600  0.600  1.0
  Zn  Zn11  1  0.200  0.200  0.200  1.0
  Zn  Zn12  1  0.800  0.800  0.800  1.0
  Zn  Zn13  1  0.400  0.400  0.400  1.0
  Cu  Cu14  1  0.000  0.000  0.000  1.0
  W  W15  1  0.000  0.000  0.500  1.0
  W  W16  1  0.600  0.600  0.100  1.0
  W  W17  1  0.200  0.200  0.700  1.0
  W  W18  1  0.800  0.800  0.300  1.0
  W  W19  1  0.400  0.400  0.900  1.0
  O  O20  1  0.905  0.905  0.643  1.0
  O  O21  1  0.505  0.505  0.243  1.0
  O  O22  1  0.105  0.105  0.843  1.0
  O  O23  1  0.705  0.705  0.443  1.0
  O  O24  1  0.305  0.305  0.043  1.0
  O  O25  1  0.190  0.714  0.452  1.0
  O  O26  1  0.790  0.314  0.052  1.0
  O  O27  1  0.390  0.914  0.652  1.0
  O  O28  1  0.990  0.514  0.252  1.0
  O  O29  1  0.590  0.114  0.852  1.0
  O  O30  1  0.286  0.810  0.548  1.0
  O  O31  1  0.886  0.410  0.148  1.0
  O  O32  1  0.486  0.010  0.748  1.0
  O  O33  1  0.086  0.610  0.348  1.0
  O  O34  1  0.686  0.210  0.948  1.0
  O  O35  1  0.095  0.095  0.357  1.0
  O  O36  1  0.695  0.695  0.957  1.0
  O  O37  1  0.295  0.295  0.557  1.0
  O  O38  1  0.895  0.895  0.157  1.0
  O  O39  1  0.495  0.495  0.757  1.0
  O  O40  1  0.810  0.286  0.548  1.0
  O  O41  1  0.410  0.886  0.148  1.0
  O  O42  1  0.010  0.486  0.748  1.0
  O  O43  1  0.610  0.086  0.348  1.0
  O  O44  1  0.210  0.686  0.948  1.0
  O  O45  1  0.714  0.190  0.452  1.0
  O  O46  1  0.314  0.790  0.052  1.0
  O  O47  1  0.914  0.390  0.652  1.0
  O  O48  1  0.514  0.990  0.252  1.0
  O  O49  1  0.114  0.590  0.852  1.0
[/CIF]
.
The material described by Ba10CuZn4(WO6)5 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic C2/m space group. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(2), one O(4), two equivalent O(1), two equivalent O(10), two equivalent O(9), and four equivalent O(6) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(1)O12 cuboctahedra, corners with two equivalent Ba(2)O12 cuboctahedra, corners with two equivalent Ba(5)O12 cuboctahedra, corners with three equivalent Ba(3)O12 cuboctahedra, corners with three equivalent Ba(4)O12 cuboctahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(5)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(4)O12 cuboctahedra,  a faceface with one W(2)O6 octahedra,  a faceface with one W(3)O6 octahedra, faces with two equivalent W(1)O6 octahedra, faces with two equivalent Zn(1)O6 octahedra, and faces with two equivalent Zn(2)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(1), one O(3), two equivalent O(10), two equivalent O(2), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(1)O12 cuboctahedra, corners with two equivalent Ba(2)O12 cuboctahedra, corners with two equivalent Ba(3)O12 cuboctahedra, corners with three equivalent Ba(4)O12 cuboctahedra, corners with three equivalent Ba(5)O12 cuboctahedra,  a faceface with one Ba(4)O12 cuboctahedra,  a faceface with one Ba(5)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra,  a faceface with one W(1)O6 octahedra,  a faceface with one W(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Zn(2)O6 octahedra, faces with two equivalent W(2)O6 octahedra, and faces with two equivalent Zn(1)O6 octahedra. In the third Ba site, Ba(3) is bonded to one O(2), one O(5), two equivalent O(3), two equivalent O(8), two equivalent O(9), and four equivalent O(7) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(2)O12 cuboctahedra, corners with two equivalent Ba(3)O12 cuboctahedra, corners with two equivalent Ba(4)O12 cuboctahedra, corners with three equivalent Ba(1)O12 cuboctahedra, corners with three equivalent Ba(5)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Ba(4)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(5)O12 cuboctahedra,  a faceface with one Zn(1)O6 octahedra,  a faceface with one Zn(2)O6 octahedra, faces with two equivalent W(2)O6 octahedra, faces with two equivalent W(3)O6 octahedra, and faces with two equivalent Cu(1)O6 octahedra. In the fourth Ba site, Ba(4) is bonded to one O(1), two equivalent O(6), two equivalent O(9), three equivalent O(4), and four equivalent O(8) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(3)O12 cuboctahedra, corners with two equivalent Ba(4)O12 cuboctahedra, corners with two equivalent Ba(5)O12 cuboctahedra, corners with three equivalent Ba(1)O12 cuboctahedra, corners with three equivalent Ba(2)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(4)O12 cuboctahedra,  a faceface with one W(1)O6 octahedra,  a faceface with one Zn(2)O6 octahedra, faces with three equivalent W(3)O6 octahedra, and faces with three equivalent Zn(1)O6 octahedra. In the fifth Ba site, Ba(5) is bonded to one O(3), two equivalent O(7), two equivalent O(9), three equivalent O(5), and four equivalent O(10) atoms to form BaO12 cuboctahedra that share corners with two equivalent Ba(1)O12 cuboctahedra, corners with two equivalent Ba(4)O12 cuboctahedra, corners with two equivalent Ba(5)O12 cuboctahedra, corners with three equivalent Ba(2)O12 cuboctahedra, corners with three equivalent Ba(3)O12 cuboctahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with two equivalent Ba(5)O12 cuboctahedra,  a faceface with one W(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra, faces with three equivalent W(2)O6 octahedra, and faces with three equivalent Zn(2)O6 octahedra. There are three inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1) and four equivalent O(6) atoms to form WO6 octahedra that share corners with two equivalent Zn(2)O6 octahedra, corners with four equivalent Zn(1)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(4)O12 cuboctahedra, and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second W site, W(2) is bonded to one O(2), one O(5), two equivalent O(10), and two equivalent O(7) atoms to form WO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, and faces with three equivalent Ba(5)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third W site, W(3) is bonded to one O(3), one O(4), two equivalent O(8), and two equivalent O(9) atoms to form WO6 octahedra that share  a cornercorner with one Cu(1)O6 octahedra, corners with two equivalent Zn(2)O6 octahedra, corners with three equivalent Zn(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(5)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, and faces with three equivalent Ba(4)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Cu(1) is bonded to two equivalent O(3) and four equivalent O(7) atoms to form CuO6 octahedra that share corners with two equivalent W(3)O6 octahedra, corners with four equivalent W(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Ba(5)O12 cuboctahedra, and faces with four equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), two equivalent O(6), and two equivalent O(8) atoms to form ZnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with three equivalent W(3)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, and faces with three equivalent Ba(4)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Zn site, Zn(2) is bonded to one O(1), one O(5), two equivalent O(10), and two equivalent O(9) atoms to form ZnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(3)O6 octahedra, corners with three equivalent W(2)O6 octahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Ba(4)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(5)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Ba(2), one Ba(4), two equivalent Ba(1), one W(1), and one Zn(2) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(4)Ba4ZnW octahedra,  a cornercorner with one O(5)Ba4ZnW octahedra, corners with two equivalent O(7)Ba4CuW octahedra, corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(9)Ba4ZnW octahedra, corners with three equivalent O(1)Ba4ZnW octahedra, corners with four equivalent O(6)Ba4ZnW octahedra, corners with six equivalent O(8)Ba4ZnW octahedra, edges with two equivalent O(2)Ba4ZnW octahedra, edges with two equivalent O(4)Ba4ZnW octahedra, faces with two equivalent O(10)Ba4ZnW octahedra, faces with two equivalent O(9)Ba4ZnW octahedra, and faces with four equivalent O(6)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the second O site, O(2) is bonded to one Ba(1), one Ba(3), two equivalent Ba(2), one W(2), and one Zn(1) atom to form distorted OBa4ZnW octahedra that share corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(4)Ba4ZnW octahedra, corners with two equivalent O(5)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(7)Ba4CuW octahedra, corners with four equivalent O(6)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra, edges with two equivalent O(3)Ba4CuW octahedra, edges with two equivalent O(1)Ba4ZnW octahedra, faces with two equivalent O(7)Ba4CuW octahedra, faces with two equivalent O(10)Ba4ZnW octahedra, faces with two equivalent O(6)Ba4ZnW octahedra, and faces with two equivalent O(8)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the third O site, O(3) is bonded to one Ba(2), one Ba(5), two equivalent Ba(3), one W(3), and one Cu(1) atom to form distorted OBa4CuW octahedra that share  a cornercorner with one O(1)Ba4ZnW octahedra,  a cornercorner with one O(4)Ba4ZnW octahedra,  a cornercorner with one O(5)Ba4ZnW octahedra, corners with two equivalent O(6)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with two equivalent O(9)Ba4ZnW octahedra, corners with three equivalent O(3)Ba4CuW octahedra, corners with four equivalent O(7)Ba4CuW octahedra, corners with six equivalent O(10)Ba4ZnW octahedra, edges with two equivalent O(2)Ba4ZnW octahedra, edges with two equivalent O(5)Ba4ZnW octahedra, faces with two equivalent O(8)Ba4ZnW octahedra, faces with two equivalent O(9)Ba4ZnW octahedra, and faces with four equivalent O(7)Ba4CuW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the fourth O site, O(4) is bonded to one Ba(1), three equivalent Ba(4), one W(3), and one Zn(1) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(1)Ba4ZnW octahedra, corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(4)Ba4ZnW octahedra, corners with four equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra, corners with six equivalent O(6)Ba4ZnW octahedra, edges with two equivalent O(1)Ba4ZnW octahedra, edges with two equivalent O(4)Ba4ZnW octahedra, faces with two equivalent O(6)Ba4ZnW octahedra, faces with two equivalent O(9)Ba4ZnW octahedra, and faces with four equivalent O(8)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the fifth O site, O(5) is bonded to one Ba(3), three equivalent Ba(5), one W(2), and one Zn(2) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(1)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(5)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(10)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra, corners with six equivalent O(7)Ba4CuW octahedra, edges with two equivalent O(3)Ba4CuW octahedra, edges with two equivalent O(5)Ba4ZnW octahedra, faces with two equivalent O(7)Ba4CuW octahedra, faces with two equivalent O(9)Ba4ZnW octahedra, and faces with four equivalent O(10)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the sixth O site, O(6) is bonded to one Ba(2), one Ba(4), two equivalent Ba(1), one W(1), and one Zn(1) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(6)Ba4ZnW octahedra, corners with two equivalent O(7)Ba4CuW octahedra, corners with two equivalent O(1)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with three equivalent O(4)Ba4ZnW octahedra, corners with three equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(10)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra,  an edgeedge with one O(10)Ba4ZnW octahedra,  an edgeedge with one O(6)Ba4ZnW octahedra,  an edgeedge with one O(8)Ba4ZnW octahedra,  an edgeedge with one O(9)Ba4ZnW octahedra,  a faceface with one O(2)Ba4ZnW octahedra,  a faceface with one O(4)Ba4ZnW octahedra,  a faceface with one O(8)Ba4ZnW octahedra, faces with two equivalent O(1)Ba4ZnW octahedra, and faces with three equivalent O(6)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the seventh O site, O(7) is bonded to one Ba(2), one Ba(5), two equivalent Ba(3), one W(2), and one Cu(1) atom to form distorted OBa4CuW octahedra that share  a cornercorner with one O(7)Ba4CuW octahedra,  a cornercorner with one O(1)Ba4ZnW octahedra, corners with two equivalent O(3)Ba4CuW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(6)Ba4ZnW octahedra, corners with three equivalent O(10)Ba4ZnW octahedra, corners with three equivalent O(5)Ba4ZnW octahedra, corners with four equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(9)Ba4ZnW octahedra,  an edgeedge with one O(7)Ba4CuW octahedra,  an edgeedge with one O(10)Ba4ZnW octahedra,  an edgeedge with one O(8)Ba4ZnW octahedra,  an edgeedge with one O(9)Ba4ZnW octahedra,  a faceface with one O(10)Ba4ZnW octahedra,  a faceface with one O(2)Ba4ZnW octahedra,  a faceface with one O(5)Ba4ZnW octahedra, faces with two equivalent O(3)Ba4CuW octahedra, and faces with three equivalent O(7)Ba4CuW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the eighth O site, O(8) is bonded to one Ba(2), one Ba(3), two equivalent Ba(4), one W(3), and one Zn(1) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(2)Ba4ZnW octahedra,  a cornercorner with one O(5)Ba4ZnW octahedra, corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(4)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with three equivalent O(1)Ba4ZnW octahedra, corners with three equivalent O(6)Ba4ZnW octahedra, corners with three equivalent O(9)Ba4ZnW octahedra, corners with four equivalent O(7)Ba4CuW octahedra,  an edgeedge with one O(7)Ba4CuW octahedra,  an edgeedge with one O(6)Ba4ZnW octahedra,  an edgeedge with one O(8)Ba4ZnW octahedra,  an edgeedge with one O(9)Ba4ZnW octahedra,  a faceface with one O(3)Ba4CuW octahedra,  a faceface with one O(2)Ba4ZnW octahedra,  a faceface with one O(6)Ba4ZnW octahedra,  a faceface with one O(9)Ba4ZnW octahedra, faces with two equivalent O(4)Ba4ZnW octahedra, and faces with two equivalent O(8)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the ninth O site, O(9) is bonded to one Ba(1), one Ba(3), one Ba(4), one Ba(5), one W(3), and one Zn(2) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(3)Ba4CuW octahedra,  a cornercorner with one O(1)Ba4ZnW octahedra, corners with two equivalent O(2)Ba4ZnW octahedra, corners with two equivalent O(4)Ba4ZnW octahedra, corners with two equivalent O(5)Ba4ZnW octahedra, corners with three equivalent O(10)Ba4ZnW octahedra, corners with three equivalent O(8)Ba4ZnW octahedra, corners with four equivalent O(7)Ba4CuW octahedra, corners with four equivalent O(6)Ba4ZnW octahedra,  an edgeedge with one O(7)Ba4CuW octahedra,  an edgeedge with one O(10)Ba4ZnW octahedra,  an edgeedge with one O(6)Ba4ZnW octahedra,  an edgeedge with one O(8)Ba4ZnW octahedra,  a faceface with one O(3)Ba4CuW octahedra,  a faceface with one O(1)Ba4ZnW octahedra,  a faceface with one O(10)Ba4ZnW octahedra,  a faceface with one O(4)Ba4ZnW octahedra,  a faceface with one O(5)Ba4ZnW octahedra,  a faceface with one O(8)Ba4ZnW octahedra, and faces with two equivalent O(9)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the tenth O site, O(10) is bonded to one Ba(1), one Ba(2), two equivalent Ba(5), one W(2), and one Zn(2) atom to form distorted OBa4ZnW octahedra that share  a cornercorner with one O(1)Ba4ZnW octahedra,  a cornercorner with one O(2)Ba4ZnW octahedra,  a cornercorner with one O(4)Ba4ZnW octahedra, corners with two equivalent O(10)Ba4ZnW octahedra, corners with two equivalent O(5)Ba4ZnW octahedra, corners with two equivalent O(8)Ba4ZnW octahedra, corners with three equivalent O(3)Ba4CuW octahedra, corners with three equivalent O(7)Ba4CuW octahedra, corners with three equivalent O(9)Ba4ZnW octahedra, corners with four equivalent O(6)Ba4ZnW octahedra,  an edgeedge with one O(7)Ba4CuW octahedra,  an edgeedge with one O(10)Ba4ZnW octahedra,  an edgeedge with one O(6)Ba4ZnW octahedra,  an edgeedge with one O(9)Ba4ZnW octahedra,  a faceface with one O(7)Ba4CuW octahedra,  a faceface with one O(1)Ba4ZnW octahedra,  a faceface with one O(2)Ba4ZnW octahedra,  a faceface with one O(9)Ba4ZnW octahedra, faces with two equivalent O(10)Ba4ZnW octahedra, and faces with two equivalent O(5)Ba4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF file [CIF]
data_Ba10Zn4Cu(WO6)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.104
_cell_length_b   10.104
_cell_length_c   14.290
_cell_angle_alpha   61.890
_cell_angle_beta   61.890
_cell_angle_gamma   33.554
_symmetry_Int_Tables_number   1
_cell_volume   701.907
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.400  0.400  0.650  1.0
  Ba  Ba1  1  1.000  1.000  0.250  1.0
  Ba  Ba2  1  0.600  0.600  0.850  1.0
  Ba  Ba3  1  0.200  0.200  0.450  1.0
  Ba  Ba4  1  0.800  0.800  0.050  1.0
  Ba  Ba5  1  0.600  0.600  0.350  1.0
  Ba  Ba6  1  0.200  0.200  0.950  1.0
  Ba  Ba7  1  0.800  0.800  0.550  1.0
  Ba  Ba8  1  0.400  0.400  0.150  1.0
  Ba  Ba9  1  0.000  0.000  0.750  1.0
  Zn  Zn10  1  0.600  0.600  0.600  1.0
  Zn  Zn11  1  0.200  0.200  0.200  1.0
  Zn  Zn12  1  0.800  0.800  0.800  1.0
  Zn  Zn13  1  0.400  0.400  0.400  1.0
  Cu  Cu14  1  0.000  0.000  0.000  1.0
  W  W15  1  0.000  0.000  0.500  1.0
  W  W16  1  0.600  0.600  0.100  1.0
  W  W17  1  0.200  0.200  0.700  1.0
  W  W18  1  0.800  0.800  0.300  1.0
  W  W19  1  0.400  0.400  0.900  1.0
  O  O20  1  0.905  0.905  0.643  1.0
  O  O21  1  0.505  0.505  0.243  1.0
  O  O22  1  0.105  0.105  0.843  1.0
  O  O23  1  0.705  0.705  0.443  1.0
  O  O24  1  0.305  0.305  0.043  1.0
  O  O25  1  0.190  0.714  0.452  1.0
  O  O26  1  0.790  0.314  0.052  1.0
  O  O27  1  0.390  0.914  0.652  1.0
  O  O28  1  0.990  0.514  0.252  1.0
  O  O29  1  0.590  0.114  0.852  1.0
  O  O30  1  0.286  0.810  0.548  1.0
  O  O31  1  0.886  0.410  0.148  1.0
  O  O32  1  0.486  0.010  0.748  1.0
  O  O33  1  0.086  0.610  0.348  1.0
  O  O34  1  0.686  0.210  0.948  1.0
  O  O35  1  0.095  0.095  0.357  1.0
  O  O36  1  0.695  0.695  0.957  1.0
  O  O37  1  0.295  0.295  0.557  1.0
  O  O38  1  0.895  0.895  0.157  1.0
  O  O39  1  0.495  0.495  0.757  1.0
  O  O40  1  0.810  0.286  0.548  1.0
  O  O41  1  0.410  0.886  0.148  1.0
  O  O42  1  0.010  0.486  0.748  1.0
  O  O43  1  0.610  0.086  0.348  1.0
  O  O44  1  0.210  0.686  0.948  1.0
  O  O45  1  0.714  0.190  0.452  1.0
  O  O46  1  0.314  0.790  0.052  1.0
  O  O47  1  0.914  0.390  0.652  1.0
  O  O48  1  0.514  0.990  0.252  1.0
  O  O49  1  0.114  0.590  0.852  1.0
[/CIF]
.