The crystal structure described by (CN3)2GeF6 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four guanidine molecules and two GeF6 clusters. In each GeF6 cluster, Ge(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ge(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF file [CIF]
data_GeC2(NF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.095
_cell_length_b   6.895
_cell_length_c   6.745
_cell_angle_alpha   120.739
_cell_angle_beta   110.592
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   222.303
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.719  0.373  0.745  1.0
  C  C1  1  0.454  0.649  0.298  1.0
  C  C2  1  0.991  0.100  0.200  1.0
  N  N3  1  0.446  0.420  0.181  1.0
  N  N4  1  0.446  0.760  0.181  1.0
  N  N5  1  0.992  0.984  0.969  1.0
  N  N6  1  0.992  0.327  0.314  1.0
  N  N7  1  0.992  0.987  0.314  1.0
  N  N8  1  0.466  0.767  0.534  1.0
  F  F9  1  0.902  0.543  0.086  1.0
  F  F10  1  0.534  0.202  0.404  1.0
  F  F11  1  0.524  0.581  0.783  1.0
  F  F12  1  0.524  0.203  0.783  1.0
  F  F13  1  0.915  0.541  0.706  1.0
  F  F14  1  0.915  0.165  0.706  1.0
[/CIF]
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The crystal structure described by (CN3)2GeF6 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four guanidine molecules and two GeF6 clusters. In each GeF6 cluster, Ge(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ge(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF file [CIF]
data_GeC2(NF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.095
_cell_length_b   6.895
_cell_length_c   6.745
_cell_angle_alpha   120.739
_cell_angle_beta   110.592
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   222.303
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.719  0.373  0.745  1.0
  C  C1  1  0.454  0.649  0.298  1.0
  C  C2  1  0.991  0.100  0.200  1.0
  N  N3  1  0.446  0.420  0.181  1.0
  N  N4  1  0.446  0.760  0.181  1.0
  N  N5  1  0.992  0.984  0.969  1.0
  N  N6  1  0.992  0.327  0.314  1.0
  N  N7  1  0.992  0.987  0.314  1.0
  N  N8  1  0.466  0.767  0.534  1.0
  F  F9  1  0.902  0.543  0.086  1.0
  F  F10  1  0.534  0.202  0.404  1.0
  F  F11  1  0.524  0.581  0.783  1.0
  F  F12  1  0.524  0.203  0.783  1.0
  F  F13  1  0.915  0.541  0.706  1.0
  F  F14  1  0.915  0.165  0.706  1.0
[/CIF]
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