The structure described by V2O2F3 crystallizes in the orthorhombic Cmcm space group. V(1) is bonded to three equivalent O(1), one F(1), and two equivalent F(2) atoms to form a mixture of edge and corner-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 22-37°. O(1) is bonded in a distorted T-shaped geometry to three equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_V2O2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.729
_cell_length_b   5.370
_cell_length_c   9.921
_cell_angle_alpha   90.028
_cell_angle_beta   89.998
_cell_angle_gamma   69.686
_symmetry_Int_Tables_number   1
_cell_volume   186.316
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.144  0.711  0.441  1.0
  V  V1  1  0.856  0.289  0.559  1.0
  V  V2  1  0.144  0.711  0.059  1.0
  V  V3  1  0.856  0.289  0.941  1.0
  O  O4  1  0.328  0.344  0.536  1.0
  O  O5  1  0.328  0.345  0.964  1.0
  O  O6  1  0.672  0.655  0.036  1.0
  O  O7  1  0.672  0.656  0.464  1.0
  F  F8  1  0.207  0.586  0.250  1.0
  F  F9  1  0.793  0.414  0.750  1.0
  F  F10  1  0.039  0.923  0.882  1.0
  F  F11  1  0.039  0.923  0.618  1.0
  F  F12  1  0.961  0.077  0.118  1.0
  F  F13  1  0.961  0.077  0.382  1.0
[/CIF]
.
The structure described by V2O2F3 crystallizes in the orthorhombic Cmcm space group. V(1) is bonded to three equivalent O(1), one F(1), and two equivalent F(2) atoms to form a mixture of edge and corner-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 22-37°. O(1) is bonded in a distorted T-shaped geometry to three equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_V2O2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.729
_cell_length_b   5.370
_cell_length_c   9.921
_cell_angle_alpha   90.028
_cell_angle_beta   89.998
_cell_angle_gamma   69.686
_symmetry_Int_Tables_number   1
_cell_volume   186.316
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.144  0.711  0.441  1.0
  V  V1  1  0.856  0.289  0.559  1.0
  V  V2  1  0.144  0.711  0.059  1.0
  V  V3  1  0.856  0.289  0.941  1.0
  O  O4  1  0.328  0.344  0.536  1.0
  O  O5  1  0.328  0.345  0.964  1.0
  O  O6  1  0.672  0.655  0.036  1.0
  O  O7  1  0.672  0.656  0.464  1.0
  F  F8  1  0.207  0.586  0.250  1.0
  F  F9  1  0.793  0.414  0.750  1.0
  F  F10  1  0.039  0.923  0.882  1.0
  F  F11  1  0.039  0.923  0.618  1.0
  F  F12  1  0.961  0.077  0.118  1.0
  F  F13  1  0.961  0.077  0.382  1.0
[/CIF]
.