The compound described by P2S5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two P2S5 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form corner-sharing PS4 tetrahedra. In the second P site, P(2) is bonded to one S(2), one S(5), one S(6), and one S(7) atom to form corner-sharing PS4 tetrahedra. In the third P site, P(3) is bonded to one S(3), one S(6), one S(8), and one S(9) atom to form corner-sharing PS4 tetrahedra. In the fourth P site, P(4) is bonded to one S(10), one S(4), one S(7), and one S(9) atom to form corner-sharing PS4 tetrahedra. There are ten inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one P(1) and one P(3) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one P(1) and one P(4) atom. In the fifth S site, S(5) is bonded in a single-bond geometry to one P(2) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one P(2) and one P(3) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one P(2) and one P(4) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one P(3) atom. In the ninth S site, S(9) is bonded in a water-like geometry to one P(3) and one P(4) atom. In the tenth S site, S(10) is bonded in a single-bond geometry to one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2S5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.321
_cell_length_b   9.462
_cell_length_c   9.461
_cell_angle_alpha   92.585
_cell_angle_beta   109.131
_cell_angle_gamma   101.081
_symmetry_Int_Tables_number   1
_cell_volume   768.366
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.742  0.186  0.910  1.0
  P  P1  1  0.258  0.814  0.090  1.0
  P  P2  1  0.084  0.282  0.837  1.0
  P  P3  1  0.916  0.718  0.163  1.0
  P  P4  1  0.736  0.296  0.567  1.0
  P  P5  1  0.264  0.704  0.433  1.0
  P  P6  1  0.820  0.966  0.658  1.0
  P  P7  1  0.180  0.034  0.342  1.0
  S  S8  1  0.652  0.191  0.064  1.0
  S  S9  1  0.348  0.809  0.936  1.0
  S  S10  1  0.979  0.284  0.003  1.0
  S  S11  1  0.021  0.716  0.997  1.0
  S  S12  1  0.632  0.299  0.733  1.0
  S  S13  1  0.368  0.701  0.267  1.0
  S  S14  1  0.715  0.970  0.823  1.0
  S  S15  1  0.285  0.030  0.177  1.0
  S  S16  1  0.300  0.370  0.924  1.0
  S  S17  1  0.700  0.630  0.076  1.0
  S  S18  1  0.974  0.396  0.662  1.0
  S  S19  1  0.026  0.604  0.338  1.0
  S  S20  1  0.058  0.066  0.752  1.0
  S  S21  1  0.942  0.934  0.248  1.0
  S  S22  1  0.638  0.397  0.406  1.0
  S  S23  1  0.362  0.603  0.594  1.0
  S  S24  1  0.713  0.080  0.482  1.0
  S  S25  1  0.287  0.920  0.518  1.0
  S  S26  1  0.797  0.770  0.581  1.0
  S  S27  1  0.203  0.230  0.419  1.0
[/CIF]
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The compound described by P2S5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two P2S5 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form corner-sharing PS4 tetrahedra. In the second P site, P(2) is bonded to one S(2), one S(5), one S(6), and one S(7) atom to form corner-sharing PS4 tetrahedra. In the third P site, P(3) is bonded to one S(3), one S(6), one S(8), and one S(9) atom to form corner-sharing PS4 tetrahedra. In the fourth P site, P(4) is bonded to one S(10), one S(4), one S(7), and one S(9) atom to form corner-sharing PS4 tetrahedra. There are ten inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one P(1) and one P(3) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one P(1) and one P(4) atom. In the fifth S site, S(5) is bonded in a single-bond geometry to one P(2) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one P(2) and one P(3) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one P(2) and one P(4) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one P(3) atom. In the ninth S site, S(9) is bonded in a water-like geometry to one P(3) and one P(4) atom. In the tenth S site, S(10) is bonded in a single-bond geometry to one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2S5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.321
_cell_length_b   9.462
_cell_length_c   9.461
_cell_angle_alpha   92.585
_cell_angle_beta   109.131
_cell_angle_gamma   101.081
_symmetry_Int_Tables_number   1
_cell_volume   768.366
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.742  0.186  0.910  1.0
  P  P1  1  0.258  0.814  0.090  1.0
  P  P2  1  0.084  0.282  0.837  1.0
  P  P3  1  0.916  0.718  0.163  1.0
  P  P4  1  0.736  0.296  0.567  1.0
  P  P5  1  0.264  0.704  0.433  1.0
  P  P6  1  0.820  0.966  0.658  1.0
  P  P7  1  0.180  0.034  0.342  1.0
  S  S8  1  0.652  0.191  0.064  1.0
  S  S9  1  0.348  0.809  0.936  1.0
  S  S10  1  0.979  0.284  0.003  1.0
  S  S11  1  0.021  0.716  0.997  1.0
  S  S12  1  0.632  0.299  0.733  1.0
  S  S13  1  0.368  0.701  0.267  1.0
  S  S14  1  0.715  0.970  0.823  1.0
  S  S15  1  0.285  0.030  0.177  1.0
  S  S16  1  0.300  0.370  0.924  1.0
  S  S17  1  0.700  0.630  0.076  1.0
  S  S18  1  0.974  0.396  0.662  1.0
  S  S19  1  0.026  0.604  0.338  1.0
  S  S20  1  0.058  0.066  0.752  1.0
  S  S21  1  0.942  0.934  0.248  1.0
  S  S22  1  0.638  0.397  0.406  1.0
  S  S23  1  0.362  0.603  0.594  1.0
  S  S24  1  0.713  0.080  0.482  1.0
  S  S25  1  0.287  0.920  0.518  1.0
  S  S26  1  0.797  0.770  0.581  1.0
  S  S27  1  0.203  0.230  0.419  1.0
[/CIF]
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