The material structure described by NH2(NH)2P2NH6O6 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia molecules, two ammonia molecules, and one P2NH6O6 cluster. In the P2NH6O6 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. N(4) is bonded in a trigonal non-coplanar geometry to one H(10), one H(6), and one H(7) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(6) is bonded in a distorted linear geometry to one N(4) and one O(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(10) is bonded in a distorted single-bond geometry to one N(4) and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(6) atom. In the third O site, O(3) is bonded in a water-like geometry to one P(1) and one H(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one P(2) and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one H(2) atom. is represented by the CIF card [CIF]
data_PH5N2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.283
_cell_length_b   8.313
_cell_length_c   8.618
_cell_angle_alpha   107.625
_cell_angle_beta   118.656
_cell_angle_gamma   85.380
_symmetry_Int_Tables_number   1
_cell_volume   494.759
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.336  0.245  0.710  1.0
  P  P1  1  0.664  0.755  0.290  1.0
  P  P2  1  0.270  0.253  0.027  1.0
  P  P3  1  0.730  0.747  0.973  1.0
  H  H4  1  0.000  0.207  0.003  1.0
  H  H5  1  1.000  0.793  0.997  1.0
  H  H6  1  0.687  0.010  0.943  1.0
  H  H7  1  0.313  0.990  0.057  1.0
  H  H8  1  0.256  0.517  0.771  1.0
  H  H9  1  0.744  0.483  0.229  1.0
  H  H10  1  0.255  0.562  0.395  1.0
  H  H11  1  0.745  0.438  0.605  1.0
  H  H12  1  0.915  0.854  0.708  1.0
  H  H13  1  0.085  0.146  0.292  1.0
  H  H14  1  0.692  0.076  0.509  1.0
  H  H15  1  0.308  0.924  0.491  1.0
  H  H16  1  0.532  0.191  0.392  1.0
  H  H17  1  0.468  0.809  0.608  1.0
  H  H18  1  0.905  0.263  0.383  1.0
  H  H19  1  0.095  0.737  0.617  1.0
  H  H20  1  0.103  0.695  0.314  1.0
  H  H21  1  0.897  0.305  0.686  1.0
  H  H22  1  0.406  0.769  0.376  1.0
  H  H23  1  0.594  0.231  0.624  1.0
  N  N24  1  0.873  0.272  0.252  1.0
  N  N25  1  0.127  0.728  0.748  1.0
  N  N26  1  0.214  0.681  0.432  1.0
  N  N27  1  0.786  0.319  0.568  1.0
  N  N28  1  0.981  0.200  0.195  1.0
  N  N29  1  0.019  0.800  0.805  1.0
  N  N30  1  0.641  0.199  0.523  1.0
  N  N31  1  0.359  0.801  0.477  1.0
  O  O32  1  0.207  0.399  0.694  1.0
  O  O33  1  0.793  0.601  0.306  1.0
  O  O34  1  0.757  0.889  0.478  1.0
  O  O35  1  0.243  0.111  0.522  1.0
  O  O36  1  0.464  0.703  0.211  1.0
  O  O37  1  0.536  0.297  0.789  1.0
  O  O38  1  0.688  0.833  0.149  1.0
  O  O39  1  0.312  0.167  0.851  1.0
  O  O40  1  0.047  0.199  0.911  1.0
  O  O41  1  0.953  0.801  0.089  1.0
  O  O42  1  0.647  0.892  0.865  1.0
  O  O43  1  0.353  0.108  0.135  1.0
[/CIF]
.
The material structure described by NH2(NH)2P2NH6O6 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia molecules, two ammonia molecules, and one P2NH6O6 cluster. In the P2NH6O6 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. N(4) is bonded in a trigonal non-coplanar geometry to one H(10), one H(6), and one H(7) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(6) is bonded in a distorted linear geometry to one N(4) and one O(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(10) is bonded in a distorted single-bond geometry to one N(4) and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(6) atom. In the third O site, O(3) is bonded in a water-like geometry to one P(1) and one H(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one P(2) and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one H(2) atom. is represented by the CIF card [CIF]
data_PH5N2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.283
_cell_length_b   8.313
_cell_length_c   8.618
_cell_angle_alpha   107.625
_cell_angle_beta   118.656
_cell_angle_gamma   85.380
_symmetry_Int_Tables_number   1
_cell_volume   494.759
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.336  0.245  0.710  1.0
  P  P1  1  0.664  0.755  0.290  1.0
  P  P2  1  0.270  0.253  0.027  1.0
  P  P3  1  0.730  0.747  0.973  1.0
  H  H4  1  0.000  0.207  0.003  1.0
  H  H5  1  1.000  0.793  0.997  1.0
  H  H6  1  0.687  0.010  0.943  1.0
  H  H7  1  0.313  0.990  0.057  1.0
  H  H8  1  0.256  0.517  0.771  1.0
  H  H9  1  0.744  0.483  0.229  1.0
  H  H10  1  0.255  0.562  0.395  1.0
  H  H11  1  0.745  0.438  0.605  1.0
  H  H12  1  0.915  0.854  0.708  1.0
  H  H13  1  0.085  0.146  0.292  1.0
  H  H14  1  0.692  0.076  0.509  1.0
  H  H15  1  0.308  0.924  0.491  1.0
  H  H16  1  0.532  0.191  0.392  1.0
  H  H17  1  0.468  0.809  0.608  1.0
  H  H18  1  0.905  0.263  0.383  1.0
  H  H19  1  0.095  0.737  0.617  1.0
  H  H20  1  0.103  0.695  0.314  1.0
  H  H21  1  0.897  0.305  0.686  1.0
  H  H22  1  0.406  0.769  0.376  1.0
  H  H23  1  0.594  0.231  0.624  1.0
  N  N24  1  0.873  0.272  0.252  1.0
  N  N25  1  0.127  0.728  0.748  1.0
  N  N26  1  0.214  0.681  0.432  1.0
  N  N27  1  0.786  0.319  0.568  1.0
  N  N28  1  0.981  0.200  0.195  1.0
  N  N29  1  0.019  0.800  0.805  1.0
  N  N30  1  0.641  0.199  0.523  1.0
  N  N31  1  0.359  0.801  0.477  1.0
  O  O32  1  0.207  0.399  0.694  1.0
  O  O33  1  0.793  0.601  0.306  1.0
  O  O34  1  0.757  0.889  0.478  1.0
  O  O35  1  0.243  0.111  0.522  1.0
  O  O36  1  0.464  0.703  0.211  1.0
  O  O37  1  0.536  0.297  0.789  1.0
  O  O38  1  0.688  0.833  0.149  1.0
  O  O39  1  0.312  0.167  0.851  1.0
  O  O40  1  0.047  0.199  0.911  1.0
  O  O41  1  0.953  0.801  0.089  1.0
  O  O42  1  0.647  0.892  0.865  1.0
  O  O43  1  0.353  0.108  0.135  1.0
[/CIF]
.