The material structure described by Co3C10O9Cl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Co3C10O9Cl clusters. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one C(10), one C(3), one C(7), and one C(9) atom to form distorted corner-sharing CoC4 trigonal pyramids. In the second Co site, Co(2) is bonded to one C(4), one C(5), one C(6), and one C(9) atom to form distorted corner-sharing CoC4 trigonal pyramids. In the third Co site, Co(3) is bonded to one C(1), one C(2), one C(8), and one C(9) atom to form distorted corner-sharing CoC4 trigonal pyramids. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(3) and one O(4) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(3) and one O(3) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one O(2) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(2) and one O(8) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Co(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Co(2) and one O(7) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Co(3) and one O(6) atom. In the ninth C site, C(9) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(3), and one Cl(1) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Co(1) and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(10) atom. Cl(1) is bonded in a single-bond geometry to one C(9) atom. is represented by the CIF file [CIF]
data_Co3C10ClO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.143
_cell_length_b   8.995
_cell_length_c   12.550
_cell_angle_alpha   86.771
_cell_angle_beta   82.601
_cell_angle_gamma   67.992
_symmetry_Int_Tables_number   1
_cell_volume   845.044
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.139  0.373  0.751  1.0
  Co  Co1  1  0.333  0.086  0.731  1.0
  Co  Co2  1  0.566  0.731  0.180  1.0
  Co  Co3  1  0.861  0.627  0.249  1.0
  Co  Co4  1  0.434  0.269  0.820  1.0
  Co  Co5  1  0.667  0.914  0.269  1.0
  C  C6  1  0.464  0.452  0.825  1.0
  C  C7  1  0.663  0.151  0.801  1.0
  C  C8  1  0.999  0.636  0.126  1.0
  C  C9  1  0.773  0.956  0.371  1.0
  C  C10  1  0.536  0.548  0.175  1.0
  C  C11  1  0.458  0.067  0.305  1.0
  C  C12  1  0.247  0.002  0.849  1.0
  C  C13  1  0.001  0.364  0.874  1.0
  C  C14  1  0.337  0.849  0.199  1.0
  C  C15  1  0.000  0.383  0.652  1.0
  C  C16  1  0.636  0.767  0.042  1.0
  C  C17  1  0.370  0.272  0.680  1.0
  C  C18  1  0.753  0.998  0.151  1.0
  C  C19  1  0.630  0.728  0.320  1.0
  C  C20  1  0.117  0.575  0.740  1.0
  C  C21  1  0.227  0.044  0.629  1.0
  C  C22  1  0.883  0.425  0.260  1.0
  C  C23  1  1.000  0.617  0.348  1.0
  C  C24  1  0.364  0.233  0.958  1.0
  C  C25  1  0.542  0.933  0.695  1.0
  Cl  Cl26  1  0.467  0.317  0.559  1.0
  Cl  Cl27  1  0.533  0.683  0.441  1.0
  O  O28  1  0.094  0.604  0.412  1.0
  O  O29  1  0.908  0.363  0.952  1.0
  O  O30  1  0.815  0.080  0.788  1.0
  O  O31  1  0.509  0.431  0.171  1.0
  O  O32  1  0.906  0.396  0.588  1.0
  O  O33  1  0.185  0.920  0.212  1.0
  O  O34  1  0.676  0.830  0.669  1.0
  O  O35  1  0.323  0.210  0.047  1.0
  O  O36  1  0.677  0.790  0.953  1.0
  O  O37  1  0.197  0.944  0.925  1.0
  O  O38  1  0.162  0.013  0.561  1.0
  O  O39  1  0.898  0.292  0.270  1.0
  O  O40  1  0.803  0.056  0.075  1.0
  O  O41  1  0.838  0.987  0.439  1.0
  O  O42  1  0.092  0.637  0.048  1.0
  O  O43  1  0.491  0.569  0.829  1.0
  O  O44  1  0.102  0.708  0.730  1.0
  O  O45  1  0.324  0.170  0.331  1.0
[/CIF]
.
The material structure described by Co3C10O9Cl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Co3C10O9Cl clusters. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one C(10), one C(3), one C(7), and one C(9) atom to form distorted corner-sharing CoC4 trigonal pyramids. In the second Co site, Co(2) is bonded to one C(4), one C(5), one C(6), and one C(9) atom to form distorted corner-sharing CoC4 trigonal pyramids. In the third Co site, Co(3) is bonded to one C(1), one C(2), one C(8), and one C(9) atom to form distorted corner-sharing CoC4 trigonal pyramids. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(3) and one O(4) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(3) and one O(3) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one O(2) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(2) and one O(8) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Co(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Co(2) and one O(7) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Co(3) and one O(6) atom. In the ninth C site, C(9) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(3), and one Cl(1) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Co(1) and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(10) atom. Cl(1) is bonded in a single-bond geometry to one C(9) atom. is represented by the CIF file [CIF]
data_Co3C10ClO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.143
_cell_length_b   8.995
_cell_length_c   12.550
_cell_angle_alpha   86.771
_cell_angle_beta   82.601
_cell_angle_gamma   67.992
_symmetry_Int_Tables_number   1
_cell_volume   845.044
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.139  0.373  0.751  1.0
  Co  Co1  1  0.333  0.086  0.731  1.0
  Co  Co2  1  0.566  0.731  0.180  1.0
  Co  Co3  1  0.861  0.627  0.249  1.0
  Co  Co4  1  0.434  0.269  0.820  1.0
  Co  Co5  1  0.667  0.914  0.269  1.0
  C  C6  1  0.464  0.452  0.825  1.0
  C  C7  1  0.663  0.151  0.801  1.0
  C  C8  1  0.999  0.636  0.126  1.0
  C  C9  1  0.773  0.956  0.371  1.0
  C  C10  1  0.536  0.548  0.175  1.0
  C  C11  1  0.458  0.067  0.305  1.0
  C  C12  1  0.247  0.002  0.849  1.0
  C  C13  1  0.001  0.364  0.874  1.0
  C  C14  1  0.337  0.849  0.199  1.0
  C  C15  1  0.000  0.383  0.652  1.0
  C  C16  1  0.636  0.767  0.042  1.0
  C  C17  1  0.370  0.272  0.680  1.0
  C  C18  1  0.753  0.998  0.151  1.0
  C  C19  1  0.630  0.728  0.320  1.0
  C  C20  1  0.117  0.575  0.740  1.0
  C  C21  1  0.227  0.044  0.629  1.0
  C  C22  1  0.883  0.425  0.260  1.0
  C  C23  1  1.000  0.617  0.348  1.0
  C  C24  1  0.364  0.233  0.958  1.0
  C  C25  1  0.542  0.933  0.695  1.0
  Cl  Cl26  1  0.467  0.317  0.559  1.0
  Cl  Cl27  1  0.533  0.683  0.441  1.0
  O  O28  1  0.094  0.604  0.412  1.0
  O  O29  1  0.908  0.363  0.952  1.0
  O  O30  1  0.815  0.080  0.788  1.0
  O  O31  1  0.509  0.431  0.171  1.0
  O  O32  1  0.906  0.396  0.588  1.0
  O  O33  1  0.185  0.920  0.212  1.0
  O  O34  1  0.676  0.830  0.669  1.0
  O  O35  1  0.323  0.210  0.047  1.0
  O  O36  1  0.677  0.790  0.953  1.0
  O  O37  1  0.197  0.944  0.925  1.0
  O  O38  1  0.162  0.013  0.561  1.0
  O  O39  1  0.898  0.292  0.270  1.0
  O  O40  1  0.803  0.056  0.075  1.0
  O  O41  1  0.838  0.987  0.439  1.0
  O  O42  1  0.092  0.637  0.048  1.0
  O  O43  1  0.491  0.569  0.829  1.0
  O  O44  1  0.102  0.708  0.730  1.0
  O  O45  1  0.324  0.170  0.331  1.0
[/CIF]
.