The crystal structure described by RbB2SbO6 crystallizes in the orthorhombic Pmn2_1 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(1) atoms. B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(4) atom. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 2°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one B(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1) and two equivalent B(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Rb(1), one B(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbB2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.892
_cell_length_b   7.477
_cell_length_c   9.765
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   284.194
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.556  0.000  0.612  1.0
  Rb  Rb1  1  0.444  0.500  0.112  1.0
  B  B2  1  0.991  0.669  0.790  1.0
  B  B3  1  0.009  0.831  0.290  1.0
  B  B4  1  0.009  0.169  0.290  1.0
  B  B5  1  0.991  0.331  0.790  1.0
  Sb  Sb6  1  0.934  0.000  0.009  1.0
  Sb  Sb7  1  0.066  0.500  0.509  1.0
  O  O8  1  0.933  0.807  0.153  1.0
  O  O9  1  0.067  0.693  0.653  1.0
  O  O10  1  0.067  0.307  0.653  1.0
  O  O11  1  0.933  0.193  0.153  1.0
  O  O12  1  0.026  0.000  0.353  1.0
  O  O13  1  0.974  0.500  0.853  1.0
  O  O14  1  0.433  0.000  0.006  1.0
  O  O15  1  0.567  0.500  0.506  1.0
  O  O16  1  0.916  0.818  0.863  1.0
  O  O17  1  0.084  0.682  0.363  1.0
  O  O18  1  0.084  0.318  0.363  1.0
  O  O19  1  0.916  0.182  0.863  1.0
[/CIF]
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The crystal structure described by RbB2SbO6 crystallizes in the orthorhombic Pmn2_1 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(1) atoms. B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(4) atom. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 2°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one B(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1) and two equivalent B(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Rb(1), one B(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbB2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.892
_cell_length_b   7.477
_cell_length_c   9.765
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   284.194
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.556  0.000  0.612  1.0
  Rb  Rb1  1  0.444  0.500  0.112  1.0
  B  B2  1  0.991  0.669  0.790  1.0
  B  B3  1  0.009  0.831  0.290  1.0
  B  B4  1  0.009  0.169  0.290  1.0
  B  B5  1  0.991  0.331  0.790  1.0
  Sb  Sb6  1  0.934  0.000  0.009  1.0
  Sb  Sb7  1  0.066  0.500  0.509  1.0
  O  O8  1  0.933  0.807  0.153  1.0
  O  O9  1  0.067  0.693  0.653  1.0
  O  O10  1  0.067  0.307  0.653  1.0
  O  O11  1  0.933  0.193  0.153  1.0
  O  O12  1  0.026  0.000  0.353  1.0
  O  O13  1  0.974  0.500  0.853  1.0
  O  O14  1  0.433  0.000  0.006  1.0
  O  O15  1  0.567  0.500  0.506  1.0
  O  O16  1  0.916  0.818  0.863  1.0
  O  O17  1  0.084  0.682  0.363  1.0
  O  O18  1  0.084  0.318  0.363  1.0
  O  O19  1  0.916  0.182  0.863  1.0
[/CIF]
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