The compound described by Mn3Ga3N5 crystallizes in the triclinic P-1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form distorted MnN4 trigonal pyramids that share  a cornercorner with one Ga(3)N4 tetrahedra, corners with three equivalent Mn(3)N4 tetrahedra, and  an edgeedge with one Ga(3)N4 tetrahedra. In the second Mn site, Mn(2) is bonded in a 3-coordinate geometry to one Ga(2), one N(1), one N(3), and one N(5) atom. In the third Mn site, Mn(3) is bonded to one N(1), one N(2), one N(3), and one N(5) atom to form MnN4 tetrahedra that share corners with two equivalent Ga(3)N4 tetrahedra and corners with three equivalent Mn(1)N4 trigonal pyramids. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted water-like geometry to one N(3) and one N(5) atom. In the second Ga site, Ga(2) is bonded in a 4-coordinate geometry to one Mn(2), one N(2), and two equivalent N(4) atoms. In the third Ga site, Ga(3) is bonded to one N(1), one N(5), and two equivalent N(4) atoms to form distorted GaN4 tetrahedra that share corners with two equivalent Mn(3)N4 tetrahedra,  a cornercorner with one Mn(1)N4 trigonal pyramid,  an edgeedge with one Ga(3)N4 tetrahedra, and  an edgeedge with one Mn(1)N4 trigonal pyramid. There are five inequivalent N sites. In the first N site, N(1) is bonded to one Mn(1), one Mn(2), one Mn(3), and one Ga(3) atom to form NMn3Ga tetrahedra that share corners with three equivalent N(5)Mn2Ga2 tetrahedra,  a cornercorner with one N(4)MnGa4 trigonal bipyramid, corners with three equivalent N(3)Mn3Ga trigonal pyramids, and  an edgeedge with one N(4)MnGa4 trigonal bipyramid. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Ga(2) atom. In the third N site, N(3) is bonded to one Mn(1), one Mn(2), one Mn(3), and one Ga(1) atom to form distorted NMn3Ga trigonal pyramids that share  a cornercorner with one N(5)Mn2Ga2 tetrahedra, corners with three equivalent N(1)Mn3Ga tetrahedra,  a cornercorner with one N(4)MnGa4 trigonal bipyramid, and  an edgeedge with one N(5)Mn2Ga2 tetrahedra. In the fourth N site, N(4) is bonded to one Mn(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form NMnGa4 trigonal bipyramids that share  a cornercorner with one N(1)Mn3Ga tetrahedra, corners with two equivalent N(5)Mn2Ga2 tetrahedra,  a cornercorner with one N(3)Mn3Ga trigonal pyramid,  an edgeedge with one N(1)Mn3Ga tetrahedra, and edges with two equivalent N(4)MnGa4 trigonal bipyramids. In the fifth N site, N(5) is bonded to one Mn(2), one Mn(3), one Ga(1), and one Ga(3) atom to form NMn2Ga2 tetrahedra that share corners with three equivalent N(1)Mn3Ga tetrahedra, corners with two equivalent N(4)MnGa4 trigonal bipyramids,  a cornercorner with one N(3)Mn3Ga trigonal pyramid, and  an edgeedge with one N(3)Mn3Ga trigonal pyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3Ga3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.980
_cell_length_b   6.136
_cell_length_c   8.186
_cell_angle_alpha   100.096
_cell_angle_beta   116.781
_cell_angle_gamma   81.306
_symmetry_Int_Tables_number   1
_cell_volume   263.096
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.862  0.377  0.701  1.0
  Mn  Mn1  1  0.138  0.623  0.299  1.0
  Mn  Mn2  1  0.686  0.713  0.924  1.0
  Mn  Mn3  1  0.314  0.287  0.076  1.0
  Mn  Mn4  1  0.674  0.517  0.281  1.0
  Mn  Mn5  1  0.326  0.483  0.719  1.0
  Ga  Ga6  1  0.872  0.199  0.015  1.0
  Ga  Ga7  1  0.128  0.801  0.985  1.0
  Ga  Ga8  1  0.659  0.839  0.636  1.0
  Ga  Ga9  1  0.341  0.161  0.364  1.0
  Ga  Ga10  1  0.189  0.997  0.677  1.0
  Ga  Ga11  1  0.811  0.003  0.323  1.0
  N  N12  1  0.212  0.293  0.811  1.0
  N  N13  1  0.788  0.707  0.189  1.0
  N  N14  1  0.765  0.553  0.520  1.0
  N  N15  1  0.235  0.447  0.480  1.0
  N  N16  1  0.667  0.405  0.827  1.0
  N  N17  1  0.333  0.595  0.173  1.0
  N  N18  1  0.220  0.930  0.443  1.0
  N  N19  1  0.780  0.070  0.557  1.0
  N  N20  1  0.317  0.775  0.839  1.0
  N  N21  1  0.683  0.225  0.161  1.0
[/CIF]
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The compound described by Mn3Ga3N5 crystallizes in the triclinic P-1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form distorted MnN4 trigonal pyramids that share  a cornercorner with one Ga(3)N4 tetrahedra, corners with three equivalent Mn(3)N4 tetrahedra, and  an edgeedge with one Ga(3)N4 tetrahedra. In the second Mn site, Mn(2) is bonded in a 3-coordinate geometry to one Ga(2), one N(1), one N(3), and one N(5) atom. In the third Mn site, Mn(3) is bonded to one N(1), one N(2), one N(3), and one N(5) atom to form MnN4 tetrahedra that share corners with two equivalent Ga(3)N4 tetrahedra and corners with three equivalent Mn(1)N4 trigonal pyramids. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted water-like geometry to one N(3) and one N(5) atom. In the second Ga site, Ga(2) is bonded in a 4-coordinate geometry to one Mn(2), one N(2), and two equivalent N(4) atoms. In the third Ga site, Ga(3) is bonded to one N(1), one N(5), and two equivalent N(4) atoms to form distorted GaN4 tetrahedra that share corners with two equivalent Mn(3)N4 tetrahedra,  a cornercorner with one Mn(1)N4 trigonal pyramid,  an edgeedge with one Ga(3)N4 tetrahedra, and  an edgeedge with one Mn(1)N4 trigonal pyramid. There are five inequivalent N sites. In the first N site, N(1) is bonded to one Mn(1), one Mn(2), one Mn(3), and one Ga(3) atom to form NMn3Ga tetrahedra that share corners with three equivalent N(5)Mn2Ga2 tetrahedra,  a cornercorner with one N(4)MnGa4 trigonal bipyramid, corners with three equivalent N(3)Mn3Ga trigonal pyramids, and  an edgeedge with one N(4)MnGa4 trigonal bipyramid. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Ga(2) atom. In the third N site, N(3) is bonded to one Mn(1), one Mn(2), one Mn(3), and one Ga(1) atom to form distorted NMn3Ga trigonal pyramids that share  a cornercorner with one N(5)Mn2Ga2 tetrahedra, corners with three equivalent N(1)Mn3Ga tetrahedra,  a cornercorner with one N(4)MnGa4 trigonal bipyramid, and  an edgeedge with one N(5)Mn2Ga2 tetrahedra. In the fourth N site, N(4) is bonded to one Mn(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form NMnGa4 trigonal bipyramids that share  a cornercorner with one N(1)Mn3Ga tetrahedra, corners with two equivalent N(5)Mn2Ga2 tetrahedra,  a cornercorner with one N(3)Mn3Ga trigonal pyramid,  an edgeedge with one N(1)Mn3Ga tetrahedra, and edges with two equivalent N(4)MnGa4 trigonal bipyramids. In the fifth N site, N(5) is bonded to one Mn(2), one Mn(3), one Ga(1), and one Ga(3) atom to form NMn2Ga2 tetrahedra that share corners with three equivalent N(1)Mn3Ga tetrahedra, corners with two equivalent N(4)MnGa4 trigonal bipyramids,  a cornercorner with one N(3)Mn3Ga trigonal pyramid, and  an edgeedge with one N(3)Mn3Ga trigonal pyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3Ga3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.980
_cell_length_b   6.136
_cell_length_c   8.186
_cell_angle_alpha   100.096
_cell_angle_beta   116.781
_cell_angle_gamma   81.306
_symmetry_Int_Tables_number   1
_cell_volume   263.096
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.862  0.377  0.701  1.0
  Mn  Mn1  1  0.138  0.623  0.299  1.0
  Mn  Mn2  1  0.686  0.713  0.924  1.0
  Mn  Mn3  1  0.314  0.287  0.076  1.0
  Mn  Mn4  1  0.674  0.517  0.281  1.0
  Mn  Mn5  1  0.326  0.483  0.719  1.0
  Ga  Ga6  1  0.872  0.199  0.015  1.0
  Ga  Ga7  1  0.128  0.801  0.985  1.0
  Ga  Ga8  1  0.659  0.839  0.636  1.0
  Ga  Ga9  1  0.341  0.161  0.364  1.0
  Ga  Ga10  1  0.189  0.997  0.677  1.0
  Ga  Ga11  1  0.811  0.003  0.323  1.0
  N  N12  1  0.212  0.293  0.811  1.0
  N  N13  1  0.788  0.707  0.189  1.0
  N  N14  1  0.765  0.553  0.520  1.0
  N  N15  1  0.235  0.447  0.480  1.0
  N  N16  1  0.667  0.405  0.827  1.0
  N  N17  1  0.333  0.595  0.173  1.0
  N  N18  1  0.220  0.930  0.443  1.0
  N  N19  1  0.780  0.070  0.557  1.0
  N  N20  1  0.317  0.775  0.839  1.0
  N  N21  1  0.683  0.225  0.161  1.0
[/CIF]
.