The structure described by Na3V2O2(PO4)2F crystallizes in the triclinic P1 space group. There are six inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(18), one O(2), one O(6), one O(7), and one F(1) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(16), one O(17), one O(4), one O(8), and one F(2) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(14), one O(15), one O(18), one O(2), and one F(1) atom. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(14), one O(15), one O(19), one O(3), and one F(1) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(13), one O(17), one O(20), one O(4), one O(5), one O(9), and one F(2) atom. In the sixth Na site, Na(6) is bonded in a 7-coordinate geometry to one O(12), one O(17), one O(20), one O(4), one O(5), one O(8), and one F(2) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(15), one O(2), one O(3), one O(4), one O(7), and one F(1) atom to form distorted VO5F octahedra that share  a cornercorner with one V(4)O5F octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 6°. In the second V site, V(2) is bonded to one O(10), one O(16), one O(20), one O(8), one O(9), and one F(2) atom to form distorted VO5F octahedra that share  a cornercorner with one V(3)O5F octahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 7°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one F(2) atom to form distorted VO5F octahedra that share  a cornercorner with one V(2)O5F octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 7°. In the fourth V site, V(4) is bonded to one O(14), one O(17), one O(18), one O(19), one O(6), and one F(1) atom to form distorted VO5F octahedra that share  a cornercorner with one V(1)O5F octahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 6°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O5F octahedra and corners with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the second P site, P(2) is bonded to one O(14), one O(6), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(2)O5F octahedra and corners with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the third P site, P(3) is bonded to one O(12), one O(13), one O(15), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O5F octahedra and corners with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the fourth P site, P(4) is bonded to one O(16), one O(18), one O(19), and one O(20) atom to form PO4 tetrahedra that share corners with two equivalent V(2)O5F octahedra and corners with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-50°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one V(3), and one P(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(3), one V(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(4), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Na(2), one Na(5), one Na(6), and one V(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Na(5), one Na(6), one V(3), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one V(4), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(6), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(5), one V(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Na(1), one Na(3), one Na(4), and one V(2) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Na(1), one Na(3), one Na(4), and one V(3) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(6), one V(3), and one P(3) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(5), one V(3), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(4), one V(4), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(4), one V(1), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Na(2), one V(2), and one P(4) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Na(2), one Na(5), one Na(6), and one V(4) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(3), one V(4), and one P(4) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Na(4), one V(4), and one P(4) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Na(5), one Na(6), one V(2), and one P(4) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a square pyramidal geometry to one Na(1), one Na(3), one Na(4), one V(1), and one V(4) atom. In the second F site, F(2) is bonded in a square pyramidal geometry to one Na(2), one Na(5), one Na(6), one V(2), and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3V2P2O10F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.480
_cell_length_b   6.482
_cell_length_c   6.997
_cell_angle_alpha   62.600
_cell_angle_beta   62.639
_cell_angle_gamma   89.927
_symmetry_Int_Tables_number   1
_cell_volume   223.333
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.008  0.993  0.000  1.0
  Na  Na1  1  0.314  0.249  0.003  1.0
  Na  Na2  1  0.262  0.735  0.000  1.0
  Na  Na3  1  0.747  0.708  0.996  1.0
  O  O4  1  0.844  0.148  0.321  1.0
  O  O5  1  0.473  0.161  0.674  1.0
  O  O6  1  0.853  0.159  0.677  1.0
  O  O7  1  0.345  0.363  0.288  1.0
  O  O8  1  0.838  0.528  0.325  1.0
  O  O9  1  0.168  0.470  0.680  1.0
  O  O10  1  0.638  0.655  0.713  1.0
  O  O11  1  0.146  0.832  0.327  1.0
  O  O12  1  0.530  0.834  0.321  1.0
  O  O13  1  0.166  0.854  0.674  1.0
  P  P14  1  0.753  0.249  0.499  1.0
  P  P15  1  0.253  0.747  0.501  1.0
  V  V16  1  0.195  0.205  0.603  1.0
  V  V17  1  0.797  0.806  0.398  1.0
[/CIF]
.
The structure described by Na3V2O2(PO4)2F crystallizes in the triclinic P1 space group. There are six inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(18), one O(2), one O(6), one O(7), and one F(1) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(16), one O(17), one O(4), one O(8), and one F(2) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(14), one O(15), one O(18), one O(2), and one F(1) atom. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(14), one O(15), one O(19), one O(3), and one F(1) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(13), one O(17), one O(20), one O(4), one O(5), one O(9), and one F(2) atom. In the sixth Na site, Na(6) is bonded in a 7-coordinate geometry to one O(12), one O(17), one O(20), one O(4), one O(5), one O(8), and one F(2) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(15), one O(2), one O(3), one O(4), one O(7), and one F(1) atom to form distorted VO5F octahedra that share  a cornercorner with one V(4)O5F octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 6°. In the second V site, V(2) is bonded to one O(10), one O(16), one O(20), one O(8), one O(9), and one F(2) atom to form distorted VO5F octahedra that share  a cornercorner with one V(3)O5F octahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 7°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one F(2) atom to form distorted VO5F octahedra that share  a cornercorner with one V(2)O5F octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 7°. In the fourth V site, V(4) is bonded to one O(14), one O(17), one O(18), one O(19), one O(6), and one F(1) atom to form distorted VO5F octahedra that share  a cornercorner with one V(1)O5F octahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 6°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O5F octahedra and corners with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the second P site, P(2) is bonded to one O(14), one O(6), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(2)O5F octahedra and corners with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the third P site, P(3) is bonded to one O(12), one O(13), one O(15), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O5F octahedra and corners with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the fourth P site, P(4) is bonded to one O(16), one O(18), one O(19), and one O(20) atom to form PO4 tetrahedra that share corners with two equivalent V(2)O5F octahedra and corners with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-50°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one V(3), and one P(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(3), one V(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(4), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Na(2), one Na(5), one Na(6), and one V(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Na(5), one Na(6), one V(3), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one V(4), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(6), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(5), one V(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Na(1), one Na(3), one Na(4), and one V(2) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Na(1), one Na(3), one Na(4), and one V(3) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(6), one V(3), and one P(3) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(5), one V(3), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(4), one V(4), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(4), one V(1), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Na(2), one V(2), and one P(4) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Na(2), one Na(5), one Na(6), and one V(4) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(3), one V(4), and one P(4) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Na(4), one V(4), and one P(4) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Na(5), one Na(6), one V(2), and one P(4) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a square pyramidal geometry to one Na(1), one Na(3), one Na(4), one V(1), and one V(4) atom. In the second F site, F(2) is bonded in a square pyramidal geometry to one Na(2), one Na(5), one Na(6), one V(2), and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3V2P2O10F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.480
_cell_length_b   6.482
_cell_length_c   6.997
_cell_angle_alpha   62.600
_cell_angle_beta   62.639
_cell_angle_gamma   89.927
_symmetry_Int_Tables_number   1
_cell_volume   223.333
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.008  0.993  0.000  1.0
  Na  Na1  1  0.314  0.249  0.003  1.0
  Na  Na2  1  0.262  0.735  0.000  1.0
  Na  Na3  1  0.747  0.708  0.996  1.0
  O  O4  1  0.844  0.148  0.321  1.0
  O  O5  1  0.473  0.161  0.674  1.0
  O  O6  1  0.853  0.159  0.677  1.0
  O  O7  1  0.345  0.363  0.288  1.0
  O  O8  1  0.838  0.528  0.325  1.0
  O  O9  1  0.168  0.470  0.680  1.0
  O  O10  1  0.638  0.655  0.713  1.0
  O  O11  1  0.146  0.832  0.327  1.0
  O  O12  1  0.530  0.834  0.321  1.0
  O  O13  1  0.166  0.854  0.674  1.0
  P  P14  1  0.753  0.249  0.499  1.0
  P  P15  1  0.253  0.747  0.501  1.0
  V  V16  1  0.195  0.205  0.603  1.0
  V  V17  1  0.797  0.806  0.398  1.0
[/CIF]
.