The crystal structure described by ZnC2N2(OCl)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules and two ZnC2N2(OCl)2 clusters. In each ZnC2N2(OCl)2 cluster, Zn(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent Cl(1) atoms. C(1) is bonded in a linear geometry to one N(3) and one O(1) atom. N(3) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnC2N6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.468
_cell_length_b   6.167
_cell_length_c   12.632
_cell_angle_alpha   71.876
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   626.959
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  Zn  Zn1  1  0.500  0.000  0.500  1.0
  C  C2  1  0.695  0.093  0.163  1.0
  C  C3  1  0.195  0.907  0.337  1.0
  C  C4  1  0.305  0.907  0.837  1.0
  C  C5  1  0.805  0.093  0.663  1.0
  N  N6  1  0.610  0.649  0.056  1.0
  N  N7  1  0.110  0.351  0.444  1.0
  N  N8  1  0.390  0.351  0.944  1.0
  N  N9  1  0.890  0.649  0.556  1.0
  N  N10  1  0.734  0.695  0.030  1.0
  N  N11  1  0.234  0.305  0.470  1.0
  N  N12  1  0.266  0.305  0.970  1.0
  N  N13  1  0.766  0.695  0.530  1.0
  N  N14  1  0.562  0.060  0.203  1.0
  N  N15  1  0.062  0.940  0.297  1.0
  N  N16  1  0.438  0.940  0.797  1.0
  N  N17  1  0.938  0.060  0.703  1.0
  Cl  Cl18  1  0.123  0.764  0.138  1.0
  Cl  Cl19  1  0.623  0.236  0.362  1.0
  Cl  Cl20  1  0.877  0.236  0.862  1.0
  Cl  Cl21  1  0.377  0.764  0.638  1.0
  O  O22  1  0.823  0.128  0.119  1.0
  O  O23  1  0.323  0.872  0.381  1.0
  O  O24  1  0.177  0.872  0.881  1.0
  O  O25  1  0.677  0.128  0.619  1.0
[/CIF]
.
The crystal structure described by ZnC2N2(OCl)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules and two ZnC2N2(OCl)2 clusters. In each ZnC2N2(OCl)2 cluster, Zn(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent Cl(1) atoms. C(1) is bonded in a linear geometry to one N(3) and one O(1) atom. N(3) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnC2N6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.468
_cell_length_b   6.167
_cell_length_c   12.632
_cell_angle_alpha   71.876
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   626.959
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  Zn  Zn1  1  0.500  0.000  0.500  1.0
  C  C2  1  0.695  0.093  0.163  1.0
  C  C3  1  0.195  0.907  0.337  1.0
  C  C4  1  0.305  0.907  0.837  1.0
  C  C5  1  0.805  0.093  0.663  1.0
  N  N6  1  0.610  0.649  0.056  1.0
  N  N7  1  0.110  0.351  0.444  1.0
  N  N8  1  0.390  0.351  0.944  1.0
  N  N9  1  0.890  0.649  0.556  1.0
  N  N10  1  0.734  0.695  0.030  1.0
  N  N11  1  0.234  0.305  0.470  1.0
  N  N12  1  0.266  0.305  0.970  1.0
  N  N13  1  0.766  0.695  0.530  1.0
  N  N14  1  0.562  0.060  0.203  1.0
  N  N15  1  0.062  0.940  0.297  1.0
  N  N16  1  0.438  0.940  0.797  1.0
  N  N17  1  0.938  0.060  0.703  1.0
  Cl  Cl18  1  0.123  0.764  0.138  1.0
  Cl  Cl19  1  0.623  0.236  0.362  1.0
  Cl  Cl20  1  0.877  0.236  0.862  1.0
  Cl  Cl21  1  0.377  0.764  0.638  1.0
  O  O22  1  0.823  0.128  0.119  1.0
  O  O23  1  0.323  0.872  0.381  1.0
  O  O24  1  0.177  0.872  0.881  1.0
  O  O25  1  0.677  0.128  0.619  1.0
[/CIF]
.