The material described by VOF is Baddeleyite-derived structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing VO4F3 hexagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of edge and corner-sharing OV4 tetrahedra. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.312
_cell_length_b   3.773
_cell_length_c   10.046
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   125.566
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.249  0.014  0.399  1.0
  V  V1  1  0.749  0.486  0.601  1.0
  V  V2  1  0.751  0.514  0.101  1.0
  V  V3  1  0.251  0.986  0.899  1.0
  O  O4  1  0.749  0.993  0.521  1.0
  O  O5  1  0.249  0.507  0.479  1.0
  O  O6  1  0.251  0.493  0.979  1.0
  O  O7  1  0.751  0.007  0.021  1.0
  F  F8  1  0.750  0.181  0.277  1.0
  F  F9  1  0.250  0.319  0.723  1.0
  F  F10  1  0.250  0.681  0.223  1.0
  F  F11  1  0.750  0.819  0.777  1.0
[/CIF]
.
The material described by VOF is Baddeleyite-derived structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing VO4F3 hexagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of edge and corner-sharing OV4 tetrahedra. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.312
_cell_length_b   3.773
_cell_length_c   10.046
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   125.566
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.249  0.014  0.399  1.0
  V  V1  1  0.749  0.486  0.601  1.0
  V  V2  1  0.751  0.514  0.101  1.0
  V  V3  1  0.251  0.986  0.899  1.0
  O  O4  1  0.749  0.993  0.521  1.0
  O  O5  1  0.249  0.507  0.479  1.0
  O  O6  1  0.251  0.493  0.979  1.0
  O  O7  1  0.751  0.007  0.021  1.0
  F  F8  1  0.750  0.181  0.277  1.0
  F  F9  1  0.250  0.319  0.723  1.0
  F  F10  1  0.250  0.681  0.223  1.0
  F  F11  1  0.750  0.819  0.777  1.0
[/CIF]
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