The crystal structure described by LiSm(MoO4)2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Sm(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Sm(1) and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(1) and two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Sm(1), and one Mo(1) atom. is represented by the CIF file [CIF]
data_LiSm(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.952
_cell_length_b   5.093
_cell_length_c   11.098
_cell_angle_alpha   67.314
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   310.356
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.716  0.000  0.750  1.0
  Li  Li1  1  0.284  0.000  0.250  1.0
  Sm  Sm2  1  0.287  0.500  0.750  1.0
  Sm  Sm3  1  0.713  0.500  0.250  1.0
  Mo  Mo4  1  0.817  0.735  0.522  1.0
  Mo  Mo5  1  0.183  0.265  0.478  1.0
  Mo  Mo6  1  0.817  0.265  0.978  1.0
  Mo  Mo7  1  0.183  0.735  0.022  1.0
  O  O8  1  0.896  0.858  0.093  1.0
  O  O9  1  0.104  0.142  0.907  1.0
  O  O10  1  0.896  0.142  0.407  1.0
  O  O11  1  0.104  0.858  0.593  1.0
  O  O12  1  0.365  0.719  0.895  1.0
  O  O13  1  0.635  0.281  0.105  1.0
  O  O14  1  0.365  0.281  0.605  1.0
  O  O15  1  0.635  0.719  0.395  1.0
  O  O16  1  0.911  0.636  0.885  1.0
  O  O17  1  0.089  0.364  0.115  1.0
  O  O18  1  0.911  0.364  0.615  1.0
  O  O19  1  0.089  0.636  0.385  1.0
  O  O20  1  0.625  0.777  0.637  1.0
  O  O21  1  0.375  0.223  0.363  1.0
  O  O22  1  0.625  0.223  0.863  1.0
  O  O23  1  0.375  0.777  0.137  1.0
[/CIF]
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The crystal structure described by LiSm(MoO4)2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Sm(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Sm(1) and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(1) and two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Sm(1), and one Mo(1) atom. is represented by the CIF file [CIF]
data_LiSm(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.952
_cell_length_b   5.093
_cell_length_c   11.098
_cell_angle_alpha   67.314
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   310.356
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.716  0.000  0.750  1.0
  Li  Li1  1  0.284  0.000  0.250  1.0
  Sm  Sm2  1  0.287  0.500  0.750  1.0
  Sm  Sm3  1  0.713  0.500  0.250  1.0
  Mo  Mo4  1  0.817  0.735  0.522  1.0
  Mo  Mo5  1  0.183  0.265  0.478  1.0
  Mo  Mo6  1  0.817  0.265  0.978  1.0
  Mo  Mo7  1  0.183  0.735  0.022  1.0
  O  O8  1  0.896  0.858  0.093  1.0
  O  O9  1  0.104  0.142  0.907  1.0
  O  O10  1  0.896  0.142  0.407  1.0
  O  O11  1  0.104  0.858  0.593  1.0
  O  O12  1  0.365  0.719  0.895  1.0
  O  O13  1  0.635  0.281  0.105  1.0
  O  O14  1  0.365  0.281  0.605  1.0
  O  O15  1  0.635  0.719  0.395  1.0
  O  O16  1  0.911  0.636  0.885  1.0
  O  O17  1  0.089  0.364  0.115  1.0
  O  O18  1  0.911  0.364  0.615  1.0
  O  O19  1  0.089  0.636  0.385  1.0
  O  O20  1  0.625  0.777  0.637  1.0
  O  O21  1  0.375  0.223  0.363  1.0
  O  O22  1  0.625  0.223  0.863  1.0
  O  O23  1  0.375  0.777  0.137  1.0
[/CIF]
.