The material described by Mn8O13F3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(2), one O(7), one O(9), one F(1), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra,  an edgeedge with one Mn(2)O5F octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-59°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the third Mn site, Mn(3) is bonded to one O(11), one O(3), one O(5), one O(6), one O(8), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra,  an edgeedge with one Mn(2)O5F octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(13), one O(4), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(13), one O(2), one O(6), one O(8), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O5F octahedra, and  an edgeedge with one Mn(8)O5F octahedra. The corner-sharing octahedral tilt angles range from 51-56°. In the sixth Mn site, Mn(6) is bonded to one O(10), one O(13), one O(2), one O(4), one O(5), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(7)O4F2 octahedra, and  an edgeedge with one Mn(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the seventh Mn site, Mn(7) is bonded to one O(12), one O(3), one O(4), one O(9), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O5F octahedra, and  an edgeedge with one Mn(8)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(11), one O(12), one O(3), one O(7), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(7)O4F2 octahedra, and  an edgeedge with one Mn(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-55°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(8) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(7), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(7) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(8) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(8) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(2), one Mn(7), and one Mn(8) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(6) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(7) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn8O13F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.509
_cell_length_b   7.454
_cell_length_c   7.468
_cell_angle_alpha   83.953
_cell_angle_beta   88.182
_cell_angle_gamma   88.615
_symmetry_Int_Tables_number   1
_cell_volume   249.449
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.501  0.702  0.952  1.0
  Mn  Mn1  1  0.517  0.294  0.062  1.0
  Mn  Mn2  1  0.486  0.188  0.448  1.0
  Mn  Mn3  1  0.500  0.801  0.556  1.0
  Mn  Mn4  1  0.014  0.954  0.210  1.0
  Mn  Mn5  1  0.008  0.559  0.294  1.0
  Mn  Mn6  1  0.992  0.456  0.699  1.0
  Mn  Mn7  1  0.016  0.063  0.796  1.0
  O  O8  1  0.242  0.094  0.018  1.0
  O  O9  1  0.229  0.734  0.153  1.0
  O  O10  1  0.229  0.237  0.649  1.0
  O  O11  1  0.226  0.597  0.511  1.0
  O  O12  1  0.264  0.341  0.266  1.0
  O  O13  1  0.273  0.982  0.413  1.0
  O  O14  1  0.260  0.845  0.767  1.0
  O  O15  1  0.734  0.153  0.238  1.0
  O  O16  1  0.720  0.652  0.732  1.0
  O  O17  1  0.736  0.515  0.096  1.0
  O  O18  1  0.728  0.016  0.594  1.0
  O  O19  1  0.766  0.267  0.846  1.0
  O  O20  1  0.764  0.769  0.341  1.0
  F  F21  1  0.269  0.465  0.915  1.0
  F  F22  1  0.749  0.401  0.467  1.0
  F  F23  1  0.778  0.915  0.977  1.0
[/CIF]
.
The material described by Mn8O13F3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(2), one O(7), one O(9), one F(1), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra,  an edgeedge with one Mn(2)O5F octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-59°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the third Mn site, Mn(3) is bonded to one O(11), one O(3), one O(5), one O(6), one O(8), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra,  an edgeedge with one Mn(2)O5F octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(13), one O(4), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(13), one O(2), one O(6), one O(8), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O5F octahedra, and  an edgeedge with one Mn(8)O5F octahedra. The corner-sharing octahedral tilt angles range from 51-56°. In the sixth Mn site, Mn(6) is bonded to one O(10), one O(13), one O(2), one O(4), one O(5), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(7)O4F2 octahedra, and  an edgeedge with one Mn(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the seventh Mn site, Mn(7) is bonded to one O(12), one O(3), one O(4), one O(9), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O5F octahedra, and  an edgeedge with one Mn(8)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(11), one O(12), one O(3), one O(7), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(7)O4F2 octahedra, and  an edgeedge with one Mn(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-55°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(8) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(7), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(7) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(8) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(8) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(2), one Mn(7), and one Mn(8) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(6) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(7) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn8O13F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.509
_cell_length_b   7.454
_cell_length_c   7.468
_cell_angle_alpha   83.953
_cell_angle_beta   88.182
_cell_angle_gamma   88.615
_symmetry_Int_Tables_number   1
_cell_volume   249.449
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.501  0.702  0.952  1.0
  Mn  Mn1  1  0.517  0.294  0.062  1.0
  Mn  Mn2  1  0.486  0.188  0.448  1.0
  Mn  Mn3  1  0.500  0.801  0.556  1.0
  Mn  Mn4  1  0.014  0.954  0.210  1.0
  Mn  Mn5  1  0.008  0.559  0.294  1.0
  Mn  Mn6  1  0.992  0.456  0.699  1.0
  Mn  Mn7  1  0.016  0.063  0.796  1.0
  O  O8  1  0.242  0.094  0.018  1.0
  O  O9  1  0.229  0.734  0.153  1.0
  O  O10  1  0.229  0.237  0.649  1.0
  O  O11  1  0.226  0.597  0.511  1.0
  O  O12  1  0.264  0.341  0.266  1.0
  O  O13  1  0.273  0.982  0.413  1.0
  O  O14  1  0.260  0.845  0.767  1.0
  O  O15  1  0.734  0.153  0.238  1.0
  O  O16  1  0.720  0.652  0.732  1.0
  O  O17  1  0.736  0.515  0.096  1.0
  O  O18  1  0.728  0.016  0.594  1.0
  O  O19  1  0.766  0.267  0.846  1.0
  O  O20  1  0.764  0.769  0.341  1.0
  F  F21  1  0.269  0.465  0.915  1.0
  F  F22  1  0.749  0.401  0.467  1.0
  F  F23  1  0.778  0.915  0.977  1.0
[/CIF]
.