The crystal structure described by RbCe(OCl)4 crystallizes in the orthorhombic P2_12_12 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent Cl(2) atoms. Ce(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Rb(1), one Ce(1), and one O(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Rb(1), one Ce(1), and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to one Ce(1) and one O(2) atom. In the second Cl site, Cl(2) is bonded in a trigonal planar geometry to two equivalent Rb(1) and one Ce(1) atom. is represented by the CIF file [CIF]
data_RbCe(ClO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.414
_cell_length_b   7.428
_cell_length_c   8.886
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   489.325
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.086  0.000  1.0
  Rb  Rb1  1  0.500  0.914  0.500  1.0
  Ce  Ce2  1  0.000  0.464  0.500  1.0
  Ce  Ce3  1  0.500  0.536  0.000  1.0
  Cl  Cl4  1  0.174  0.601  0.183  1.0
  Cl  Cl5  1  0.826  0.601  0.817  1.0
  Cl  Cl6  1  0.326  0.399  0.683  1.0
  Cl  Cl7  1  0.674  0.399  0.317  1.0
  Cl  Cl8  1  0.128  0.177  0.343  1.0
  Cl  Cl9  1  0.872  0.177  0.657  1.0
  Cl  Cl10  1  0.372  0.823  0.843  1.0
  Cl  Cl11  1  0.628  0.823  0.157  1.0
  O  O12  1  0.442  0.224  0.056  1.0
  O  O13  1  0.558  0.224  0.944  1.0
  O  O14  1  0.058  0.776  0.556  1.0
  O  O15  1  0.942  0.776  0.444  1.0
  O  O16  1  0.244  0.576  0.359  1.0
  O  O17  1  0.756  0.576  0.641  1.0
  O  O18  1  0.256  0.424  0.859  1.0
  O  O19  1  0.744  0.424  0.141  1.0
[/CIF]
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The crystal structure described by RbCe(OCl)4 crystallizes in the orthorhombic P2_12_12 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent Cl(2) atoms. Ce(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Rb(1), one Ce(1), and one O(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Rb(1), one Ce(1), and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to one Ce(1) and one O(2) atom. In the second Cl site, Cl(2) is bonded in a trigonal planar geometry to two equivalent Rb(1) and one Ce(1) atom. is represented by the CIF file [CIF]
data_RbCe(ClO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.414
_cell_length_b   7.428
_cell_length_c   8.886
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   489.325
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.086  0.000  1.0
  Rb  Rb1  1  0.500  0.914  0.500  1.0
  Ce  Ce2  1  0.000  0.464  0.500  1.0
  Ce  Ce3  1  0.500  0.536  0.000  1.0
  Cl  Cl4  1  0.174  0.601  0.183  1.0
  Cl  Cl5  1  0.826  0.601  0.817  1.0
  Cl  Cl6  1  0.326  0.399  0.683  1.0
  Cl  Cl7  1  0.674  0.399  0.317  1.0
  Cl  Cl8  1  0.128  0.177  0.343  1.0
  Cl  Cl9  1  0.872  0.177  0.657  1.0
  Cl  Cl10  1  0.372  0.823  0.843  1.0
  Cl  Cl11  1  0.628  0.823  0.157  1.0
  O  O12  1  0.442  0.224  0.056  1.0
  O  O13  1  0.558  0.224  0.944  1.0
  O  O14  1  0.058  0.776  0.556  1.0
  O  O15  1  0.942  0.776  0.444  1.0
  O  O16  1  0.244  0.576  0.359  1.0
  O  O17  1  0.756  0.576  0.641  1.0
  O  O18  1  0.256  0.424  0.859  1.0
  O  O19  1  0.744  0.424  0.141  1.0
[/CIF]
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