The material described by RbV3Cu4CdO13 crystallizes in the monoclinic P2_1/m space group. Rb(1) is bonded in a 10-coordinate geometry to one O(2), two equivalent O(3), three equivalent O(4), and four equivalent O(1) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(9), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-74°. In the second V site, V(2) is bonded to one O(4), one O(7), and two equivalent O(3) atoms to form VO4 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cu(3)O5 trigonal bipyramid, and corners with three equivalent Cu(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 50°. In the third V site, V(3) is bonded to one O(2), one O(5), and two equivalent O(6) atoms to form VO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra,  a cornercorner with one Cu(2)O5 trigonal bipyramid, and corners with three equivalent Cu(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 34°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 5-coordinate geometry to one O(10), one O(3), one O(6), one O(8), and one O(9) atom. In the second Cu site, Cu(2) is bonded to one O(2), one O(7), one O(8), and two equivalent O(3) atoms to form CuO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. In the third Cu site, Cu(3) is bonded to one O(5), one O(7), one O(8), and two equivalent O(6) atoms to form CuO5 trigonal bipyramids that share  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent V(3)O4 tetrahedra,  an edgeedge with one Cd(1)O6 octahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. Cd(1) is bonded to one O(4), one O(9), two equivalent O(1), and two equivalent O(6) atoms to form CdO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. There are ten inequivalent O sites. In the first O site, O(6) is bonded in a 4-coordinate geometry to one V(3), one Cu(1), one Cu(3), and one Cd(1) atom. In the second O site, O(7) is bonded in a distorted trigonal planar geometry to one V(2), one Cu(2), and one Cu(3) atom. In the third O site, O(8) is bonded to one Cu(2), one Cu(3), and two equivalent Cu(1) atoms to form distorted corner-sharing OCu4 trigonal pyramids. In the fourth O site, O(9) is bonded to one V(1), two equivalent Cu(1), and one Cd(1) atom to form distorted corner-sharing OVCdCu2 trigonal pyramids. In the fifth O site, O(10) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cu(1) atoms. In the sixth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one V(1), and one Cd(1) atom. In the seventh O site, O(2) is bonded in a distorted linear geometry to one Rb(1), one V(3), and one Cu(2) atom. In the eighth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one V(2), one Cu(1), and one Cu(2) atom. In the ninth O site, O(4) is bonded in a 2-coordinate geometry to three equivalent Rb(1), one V(2), and one Cd(1) atom. In the tenth O site, O(5) is bonded in a bent 120 degrees geometry to one V(3) and one Cu(3) atom. is represented by the CIF card [CIF]
data_RbV3CdCu4O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.284
_cell_length_b   8.504
_cell_length_c   11.018
_cell_angle_alpha   98.021
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   583.006
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.512  0.893  1.0
  Rb  Rb1  1  0.250  0.488  0.107  1.0
  V  V2  1  0.750  0.130  0.002  1.0
  V  V3  1  0.250  0.870  0.998  1.0
  V  V4  1  0.750  0.466  0.297  1.0
  V  V5  1  0.250  0.534  0.703  1.0
  V  V6  1  0.750  0.180  0.618  1.0
  V  V7  1  0.250  0.820  0.382  1.0
  Cd  Cd8  1  0.750  0.805  0.142  1.0
  Cd  Cd9  1  0.250  0.195  0.858  1.0
  Cu  Cu10  1  0.994  0.890  0.726  1.0
  Cu  Cu11  1  0.006  0.110  0.274  1.0
  Cu  Cu12  1  0.494  0.110  0.274  1.0
  Cu  Cu13  1  0.506  0.890  0.726  1.0
  Cu  Cu14  1  0.750  0.604  0.605  1.0
  Cu  Cu15  1  0.250  0.396  0.395  1.0
  Cu  Cu16  1  0.750  0.856  0.439  1.0
  Cu  Cu17  1  0.250  0.144  0.561  1.0
  O  O18  1  0.968  0.245  0.982  1.0
  O  O19  1  0.032  0.755  0.018  1.0
  O  O20  1  0.468  0.755  0.018  1.0
  O  O21  1  0.532  0.245  0.982  1.0
  O  O22  1  0.750  0.380  0.615  1.0
  O  O23  1  0.250  0.620  0.385  1.0
  O  O24  1  0.479  0.656  0.708  1.0
  O  O25  1  0.521  0.344  0.292  1.0
  O  O26  1  0.979  0.344  0.292  1.0
  O  O27  1  0.021  0.656  0.708  1.0
  O  O28  1  0.750  0.551  0.166  1.0
  O  O29  1  0.250  0.449  0.834  1.0
  O  O30  1  0.750  0.083  0.466  1.0
  O  O31  1  0.250  0.917  0.534  1.0
  O  O32  1  0.012  0.877  0.308  1.0
  O  O33  1  0.988  0.123  0.692  1.0
  O  O34  1  0.512  0.123  0.692  1.0
  O  O35  1  0.488  0.877  0.308  1.0
  O  O36  1  0.750  0.623  0.422  1.0
  O  O37  1  0.250  0.377  0.578  1.0
  O  O38  1  0.750  0.841  0.617  1.0
  O  O39  1  0.250  0.159  0.383  1.0
  O  O40  1  0.750  0.073  0.166  1.0
  O  O41  1  0.250  0.927  0.834  1.0
  O  O42  1  0.750  0.969  0.890  1.0
  O  O43  1  0.250  0.031  0.110  1.0
[/CIF]
.
The material described by RbV3Cu4CdO13 crystallizes in the monoclinic P2_1/m space group. Rb(1) is bonded in a 10-coordinate geometry to one O(2), two equivalent O(3), three equivalent O(4), and four equivalent O(1) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(9), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-74°. In the second V site, V(2) is bonded to one O(4), one O(7), and two equivalent O(3) atoms to form VO4 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cu(3)O5 trigonal bipyramid, and corners with three equivalent Cu(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 50°. In the third V site, V(3) is bonded to one O(2), one O(5), and two equivalent O(6) atoms to form VO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra,  a cornercorner with one Cu(2)O5 trigonal bipyramid, and corners with three equivalent Cu(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 34°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 5-coordinate geometry to one O(10), one O(3), one O(6), one O(8), and one O(9) atom. In the second Cu site, Cu(2) is bonded to one O(2), one O(7), one O(8), and two equivalent O(3) atoms to form CuO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. In the third Cu site, Cu(3) is bonded to one O(5), one O(7), one O(8), and two equivalent O(6) atoms to form CuO5 trigonal bipyramids that share  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent V(3)O4 tetrahedra,  an edgeedge with one Cd(1)O6 octahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. Cd(1) is bonded to one O(4), one O(9), two equivalent O(1), and two equivalent O(6) atoms to form CdO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. There are ten inequivalent O sites. In the first O site, O(6) is bonded in a 4-coordinate geometry to one V(3), one Cu(1), one Cu(3), and one Cd(1) atom. In the second O site, O(7) is bonded in a distorted trigonal planar geometry to one V(2), one Cu(2), and one Cu(3) atom. In the third O site, O(8) is bonded to one Cu(2), one Cu(3), and two equivalent Cu(1) atoms to form distorted corner-sharing OCu4 trigonal pyramids. In the fourth O site, O(9) is bonded to one V(1), two equivalent Cu(1), and one Cd(1) atom to form distorted corner-sharing OVCdCu2 trigonal pyramids. In the fifth O site, O(10) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cu(1) atoms. In the sixth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one V(1), and one Cd(1) atom. In the seventh O site, O(2) is bonded in a distorted linear geometry to one Rb(1), one V(3), and one Cu(2) atom. In the eighth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one V(2), one Cu(1), and one Cu(2) atom. In the ninth O site, O(4) is bonded in a 2-coordinate geometry to three equivalent Rb(1), one V(2), and one Cd(1) atom. In the tenth O site, O(5) is bonded in a bent 120 degrees geometry to one V(3) and one Cu(3) atom. is represented by the CIF card [CIF]
data_RbV3CdCu4O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.284
_cell_length_b   8.504
_cell_length_c   11.018
_cell_angle_alpha   98.021
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   583.006
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.512  0.893  1.0
  Rb  Rb1  1  0.250  0.488  0.107  1.0
  V  V2  1  0.750  0.130  0.002  1.0
  V  V3  1  0.250  0.870  0.998  1.0
  V  V4  1  0.750  0.466  0.297  1.0
  V  V5  1  0.250  0.534  0.703  1.0
  V  V6  1  0.750  0.180  0.618  1.0
  V  V7  1  0.250  0.820  0.382  1.0
  Cd  Cd8  1  0.750  0.805  0.142  1.0
  Cd  Cd9  1  0.250  0.195  0.858  1.0
  Cu  Cu10  1  0.994  0.890  0.726  1.0
  Cu  Cu11  1  0.006  0.110  0.274  1.0
  Cu  Cu12  1  0.494  0.110  0.274  1.0
  Cu  Cu13  1  0.506  0.890  0.726  1.0
  Cu  Cu14  1  0.750  0.604  0.605  1.0
  Cu  Cu15  1  0.250  0.396  0.395  1.0
  Cu  Cu16  1  0.750  0.856  0.439  1.0
  Cu  Cu17  1  0.250  0.144  0.561  1.0
  O  O18  1  0.968  0.245  0.982  1.0
  O  O19  1  0.032  0.755  0.018  1.0
  O  O20  1  0.468  0.755  0.018  1.0
  O  O21  1  0.532  0.245  0.982  1.0
  O  O22  1  0.750  0.380  0.615  1.0
  O  O23  1  0.250  0.620  0.385  1.0
  O  O24  1  0.479  0.656  0.708  1.0
  O  O25  1  0.521  0.344  0.292  1.0
  O  O26  1  0.979  0.344  0.292  1.0
  O  O27  1  0.021  0.656  0.708  1.0
  O  O28  1  0.750  0.551  0.166  1.0
  O  O29  1  0.250  0.449  0.834  1.0
  O  O30  1  0.750  0.083  0.466  1.0
  O  O31  1  0.250  0.917  0.534  1.0
  O  O32  1  0.012  0.877  0.308  1.0
  O  O33  1  0.988  0.123  0.692  1.0
  O  O34  1  0.512  0.123  0.692  1.0
  O  O35  1  0.488  0.877  0.308  1.0
  O  O36  1  0.750  0.623  0.422  1.0
  O  O37  1  0.250  0.377  0.578  1.0
  O  O38  1  0.750  0.841  0.617  1.0
  O  O39  1  0.250  0.159  0.383  1.0
  O  O40  1  0.750  0.073  0.166  1.0
  O  O41  1  0.250  0.927  0.834  1.0
  O  O42  1  0.750  0.969  0.890  1.0
  O  O43  1  0.250  0.031  0.110  1.0
[/CIF]
.