The compound described by Cu(C2O4)2CuC4(NO4)2(NO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules; one schembl9516229 molecule; and one CuC4(NO4)2 cluster. In the CuC4(NO4)2 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(3) and two equivalent O(5) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one C(2), one O(1), and one O(3) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one O(4), and one O(5) atom. N(2) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(3) is bonded in a 2-coordinate geometry to one Cu(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. In the fourth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(2) atom. is represented by the CIF card [CIF]
data_CuC4(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.071
_cell_length_b   8.763
_cell_length_c   10.605
_cell_angle_alpha   113.845
_cell_angle_beta   101.891
_cell_angle_gamma   93.752
_symmetry_Int_Tables_number   1
_cell_volume   579.947
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.000  0.000  1.0
  Cu  Cu1  1  0.500  0.500  0.500  1.0
  C  C2  1  0.383  0.873  0.150  1.0
  C  C3  1  0.617  0.127  0.850  1.0
  C  C4  1  0.270  0.752  0.048  1.0
  C  C5  1  0.730  0.248  0.952  1.0
  C  C6  1  0.470  0.296  0.367  1.0
  C  C7  1  0.530  0.704  0.633  1.0
  C  C8  1  0.254  0.362  0.344  1.0
  C  C9  1  0.746  0.638  0.656  1.0
  N  N10  1  0.951  0.937  0.303  1.0
  N  N11  1  0.049  0.063  0.697  1.0
  N  N12  1  0.783  0.545  0.065  1.0
  N  N13  1  0.217  0.455  0.935  1.0
  O  O14  1  0.535  0.811  0.238  1.0
  O  O15  1  0.465  0.189  0.762  1.0
  O  O16  1  0.941  0.844  0.244  1.0
  O  O17  1  0.059  0.156  0.756  1.0
  O  O18  1  0.274  0.003  0.106  1.0
  O  O19  1  0.726  0.997  0.894  1.0
  O  O20  1  0.381  0.650  0.052  1.0
  O  O21  1  0.619  0.350  0.948  1.0
  O  O22  1  0.907  0.200  0.008  1.0
  O  O23  1  0.093  0.800  0.992  1.0
  O  O24  1  0.602  0.356  0.444  1.0
  O  O25  1  0.398  0.644  0.556  1.0
  O  O26  1  0.254  0.470  0.399  1.0
  O  O27  1  0.746  0.530  0.601  1.0
  O  O28  1  0.110  0.316  0.281  1.0
  O  O29  1  0.890  0.684  0.719  1.0
  O  O30  1  0.503  0.201  0.318  1.0
  O  O31  1  0.497  0.799  0.682  1.0
  O  O32  1  0.879  0.945  0.390  1.0
  O  O33  1  0.121  0.055  0.610  1.0
[/CIF]
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The compound described by Cu(C2O4)2CuC4(NO4)2(NO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules; one schembl9516229 molecule; and one CuC4(NO4)2 cluster. In the CuC4(NO4)2 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(3) and two equivalent O(5) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one C(2), one O(1), and one O(3) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one O(4), and one O(5) atom. N(2) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(3) is bonded in a 2-coordinate geometry to one Cu(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. In the fourth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(2) atom. is represented by the CIF card [CIF]
data_CuC4(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.071
_cell_length_b   8.763
_cell_length_c   10.605
_cell_angle_alpha   113.845
_cell_angle_beta   101.891
_cell_angle_gamma   93.752
_symmetry_Int_Tables_number   1
_cell_volume   579.947
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.000  0.000  1.0
  Cu  Cu1  1  0.500  0.500  0.500  1.0
  C  C2  1  0.383  0.873  0.150  1.0
  C  C3  1  0.617  0.127  0.850  1.0
  C  C4  1  0.270  0.752  0.048  1.0
  C  C5  1  0.730  0.248  0.952  1.0
  C  C6  1  0.470  0.296  0.367  1.0
  C  C7  1  0.530  0.704  0.633  1.0
  C  C8  1  0.254  0.362  0.344  1.0
  C  C9  1  0.746  0.638  0.656  1.0
  N  N10  1  0.951  0.937  0.303  1.0
  N  N11  1  0.049  0.063  0.697  1.0
  N  N12  1  0.783  0.545  0.065  1.0
  N  N13  1  0.217  0.455  0.935  1.0
  O  O14  1  0.535  0.811  0.238  1.0
  O  O15  1  0.465  0.189  0.762  1.0
  O  O16  1  0.941  0.844  0.244  1.0
  O  O17  1  0.059  0.156  0.756  1.0
  O  O18  1  0.274  0.003  0.106  1.0
  O  O19  1  0.726  0.997  0.894  1.0
  O  O20  1  0.381  0.650  0.052  1.0
  O  O21  1  0.619  0.350  0.948  1.0
  O  O22  1  0.907  0.200  0.008  1.0
  O  O23  1  0.093  0.800  0.992  1.0
  O  O24  1  0.602  0.356  0.444  1.0
  O  O25  1  0.398  0.644  0.556  1.0
  O  O26  1  0.254  0.470  0.399  1.0
  O  O27  1  0.746  0.530  0.601  1.0
  O  O28  1  0.110  0.316  0.281  1.0
  O  O29  1  0.890  0.684  0.719  1.0
  O  O30  1  0.503  0.201  0.318  1.0
  O  O31  1  0.497  0.799  0.682  1.0
  O  O32  1  0.879  0.945  0.390  1.0
  O  O33  1  0.121  0.055  0.610  1.0
[/CIF]
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