The crystal structure described by KC2H3S2O crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one S(2), one S(3), one S(5), three equivalent S(1), and two equivalent O(2) atoms. In the second K site, K(2) is bonded in a 1-coordinate geometry to one S(2), one S(3), one S(6), three equivalent S(4), and one O(3) atom. In the third K site, K(3) is bonded in a 7-coordinate geometry to one S(4), one S(6), two equivalent S(2), two equivalent S(5), and one O(1) atom. There are six inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one H(2), one H(5), one H(6), and one O(1) atom. In the second C site, C(2) is bonded in a tetrahedral geometry to one H(1), one H(4), one H(7), and one O(2) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one S(1), one S(5), and one O(2) atom. In the fourth C site, C(4) is bonded in a tetrahedral geometry to one H(3), one H(8), one H(9), and one O(3) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one S(2), one S(6), and one O(1) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one S(3), one S(4), and one O(3) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one C(3) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to one K(1), one K(2), two equivalent K(3), and one C(5) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one K(1), one K(2), and one C(6) atom. In the fourth S site, S(4) is bonded in a 5-coordinate geometry to one K(3), three equivalent K(2), and one C(6) atom. In the fifth S site, S(5) is bonded in a distorted rectangular see-saw-like geometry to one K(1), two equivalent K(3), and one C(3) atom. In the sixth S site, S(6) is bonded in a 3-coordinate geometry to one K(2), one K(3), and one C(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(3), one C(1), and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one C(2), and one C(3) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(2), one C(4), and one C(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KH3C2S2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.647
_cell_length_b   10.715
_cell_length_c   13.977
_cell_angle_alpha   71.624
_cell_angle_beta   82.035
_cell_angle_gamma   84.192
_symmetry_Int_Tables_number   1
_cell_volume   933.874
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.837  0.434  0.403  1.0
  K  K1  1  0.237  0.449  0.130  1.0
  K  K2  1  0.763  0.551  0.870  1.0
  K  K3  1  0.424  0.860  0.676  1.0
  K  K4  1  0.163  0.566  0.597  1.0
  K  K5  1  0.576  0.140  0.324  1.0
  H  H6  1  0.159  0.167  0.684  1.0
  H  H7  1  0.760  0.055  0.102  1.0
  H  H8  1  0.509  0.229  0.776  1.0
  H  H9  1  0.094  0.795  0.354  1.0
  H  H10  1  0.020  0.988  0.097  1.0
  H  H11  1  0.980  0.012  0.903  1.0
  H  H12  1  0.035  0.839  0.963  1.0
  H  H13  1  0.240  0.945  0.898  1.0
  H  H14  1  0.916  0.900  0.408  1.0
  H  H15  1  0.708  0.214  0.856  1.0
  H  H16  1  0.906  0.205  0.646  1.0
  H  H17  1  0.538  0.847  0.089  1.0
  H  H18  1  0.965  0.161  0.037  1.0
  H  H19  1  0.084  0.100  0.592  1.0
  H  H20  1  0.841  0.833  0.316  1.0
  H  H21  1  0.292  0.786  0.144  1.0
  H  H22  1  0.462  0.153  0.911  1.0
  H  H23  1  0.491  0.771  0.224  1.0
  C  C24  1  0.919  0.075  0.101  1.0
  C  C25  1  0.933  0.815  0.378  1.0
  C  C26  1  0.679  0.687  0.505  1.0
  C  C27  1  0.081  0.925  0.899  1.0
  C  C28  1  0.067  0.185  0.622  1.0
  C  C29  1  0.321  0.313  0.495  1.0
  C  C30  1  0.544  0.229  0.851  1.0
  C  C31  1  0.896  0.869  0.781  1.0
  C  C32  1  0.296  0.412  0.854  1.0
  C  C33  1  0.104  0.131  0.219  1.0
  C  C34  1  0.456  0.771  0.149  1.0
  C  C35  1  0.704  0.588  0.146  1.0
  S  S36  1  0.349  0.451  0.394  1.0
  S  S37  1  0.079  0.167  0.331  1.0
  S  S38  1  0.881  0.666  0.177  1.0
  S  S39  1  0.739  0.438  0.126  1.0
  S  S40  1  0.506  0.197  0.541  1.0
  S  S41  1  0.680  0.868  0.860  1.0
  S  S42  1  0.921  0.833  0.669  1.0
  S  S43  1  0.651  0.549  0.606  1.0
  S  S44  1  0.494  0.803  0.459  1.0
  S  S45  1  0.119  0.334  0.823  1.0
  S  S46  1  0.261  0.562  0.874  1.0
  S  S47  1  0.320  0.132  0.140  1.0
  O  O48  1  0.925  0.100  0.196  1.0
  O  O49  1  0.876  0.697  0.459  1.0
  O  O50  1  0.511  0.643  0.135  1.0
  O  O51  1  0.489  0.357  0.865  1.0
  O  O52  1  0.124  0.303  0.541  1.0
  O  O53  1  0.075  0.900  0.804  1.0
[/CIF]
.
The crystal structure described by KC2H3S2O crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one S(2), one S(3), one S(5), three equivalent S(1), and two equivalent O(2) atoms. In the second K site, K(2) is bonded in a 1-coordinate geometry to one S(2), one S(3), one S(6), three equivalent S(4), and one O(3) atom. In the third K site, K(3) is bonded in a 7-coordinate geometry to one S(4), one S(6), two equivalent S(2), two equivalent S(5), and one O(1) atom. There are six inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one H(2), one H(5), one H(6), and one O(1) atom. In the second C site, C(2) is bonded in a tetrahedral geometry to one H(1), one H(4), one H(7), and one O(2) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one S(1), one S(5), and one O(2) atom. In the fourth C site, C(4) is bonded in a tetrahedral geometry to one H(3), one H(8), one H(9), and one O(3) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one S(2), one S(6), and one O(1) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one S(3), one S(4), and one O(3) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one C(3) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to one K(1), one K(2), two equivalent K(3), and one C(5) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one K(1), one K(2), and one C(6) atom. In the fourth S site, S(4) is bonded in a 5-coordinate geometry to one K(3), three equivalent K(2), and one C(6) atom. In the fifth S site, S(5) is bonded in a distorted rectangular see-saw-like geometry to one K(1), two equivalent K(3), and one C(3) atom. In the sixth S site, S(6) is bonded in a 3-coordinate geometry to one K(2), one K(3), and one C(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(3), one C(1), and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one C(2), and one C(3) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(2), one C(4), and one C(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KH3C2S2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.647
_cell_length_b   10.715
_cell_length_c   13.977
_cell_angle_alpha   71.624
_cell_angle_beta   82.035
_cell_angle_gamma   84.192
_symmetry_Int_Tables_number   1
_cell_volume   933.874
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.837  0.434  0.403  1.0
  K  K1  1  0.237  0.449  0.130  1.0
  K  K2  1  0.763  0.551  0.870  1.0
  K  K3  1  0.424  0.860  0.676  1.0
  K  K4  1  0.163  0.566  0.597  1.0
  K  K5  1  0.576  0.140  0.324  1.0
  H  H6  1  0.159  0.167  0.684  1.0
  H  H7  1  0.760  0.055  0.102  1.0
  H  H8  1  0.509  0.229  0.776  1.0
  H  H9  1  0.094  0.795  0.354  1.0
  H  H10  1  0.020  0.988  0.097  1.0
  H  H11  1  0.980  0.012  0.903  1.0
  H  H12  1  0.035  0.839  0.963  1.0
  H  H13  1  0.240  0.945  0.898  1.0
  H  H14  1  0.916  0.900  0.408  1.0
  H  H15  1  0.708  0.214  0.856  1.0
  H  H16  1  0.906  0.205  0.646  1.0
  H  H17  1  0.538  0.847  0.089  1.0
  H  H18  1  0.965  0.161  0.037  1.0
  H  H19  1  0.084  0.100  0.592  1.0
  H  H20  1  0.841  0.833  0.316  1.0
  H  H21  1  0.292  0.786  0.144  1.0
  H  H22  1  0.462  0.153  0.911  1.0
  H  H23  1  0.491  0.771  0.224  1.0
  C  C24  1  0.919  0.075  0.101  1.0
  C  C25  1  0.933  0.815  0.378  1.0
  C  C26  1  0.679  0.687  0.505  1.0
  C  C27  1  0.081  0.925  0.899  1.0
  C  C28  1  0.067  0.185  0.622  1.0
  C  C29  1  0.321  0.313  0.495  1.0
  C  C30  1  0.544  0.229  0.851  1.0
  C  C31  1  0.896  0.869  0.781  1.0
  C  C32  1  0.296  0.412  0.854  1.0
  C  C33  1  0.104  0.131  0.219  1.0
  C  C34  1  0.456  0.771  0.149  1.0
  C  C35  1  0.704  0.588  0.146  1.0
  S  S36  1  0.349  0.451  0.394  1.0
  S  S37  1  0.079  0.167  0.331  1.0
  S  S38  1  0.881  0.666  0.177  1.0
  S  S39  1  0.739  0.438  0.126  1.0
  S  S40  1  0.506  0.197  0.541  1.0
  S  S41  1  0.680  0.868  0.860  1.0
  S  S42  1  0.921  0.833  0.669  1.0
  S  S43  1  0.651  0.549  0.606  1.0
  S  S44  1  0.494  0.803  0.459  1.0
  S  S45  1  0.119  0.334  0.823  1.0
  S  S46  1  0.261  0.562  0.874  1.0
  S  S47  1  0.320  0.132  0.140  1.0
  O  O48  1  0.925  0.100  0.196  1.0
  O  O49  1  0.876  0.697  0.459  1.0
  O  O50  1  0.511  0.643  0.135  1.0
  O  O51  1  0.489  0.357  0.865  1.0
  O  O52  1  0.124  0.303  0.541  1.0
  O  O53  1  0.075  0.900  0.804  1.0
[/CIF]
.