The structure described by AgMo6S8 crystallizes in the trigonal R-3 space group. Mo(1) is bonded to one S(2) and four equivalent S(1) atoms to form a mixture of distorted edge and corner-sharing MoS5 square pyramids. Ag(1) is bonded in a linear geometry to two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 4-coordinate geometry to three equivalent Mo(1) and one Ag(1) atom. In the second S site, S(1) is bonded in a 4-coordinate geometry to four equivalent Mo(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag(Mo3S4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.537
_cell_length_b   6.537
_cell_length_c   6.537
_cell_angle_alpha   92.072
_cell_angle_beta   92.072
_cell_angle_gamma   92.072
_symmetry_Int_Tables_number   1
_cell_volume   278.718
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Mo  Mo1  1  0.216  0.553  0.407  1.0
  Mo  Mo2  1  0.553  0.407  0.216  1.0
  Mo  Mo3  1  0.407  0.216  0.553  1.0
  Mo  Mo4  1  0.593  0.784  0.447  1.0
  Mo  Mo5  1  0.447  0.593  0.784  1.0
  Mo  Mo6  1  0.784  0.447  0.593  1.0
  S  S7  1  0.383  0.729  0.133  1.0
  S  S8  1  0.133  0.383  0.729  1.0
  S  S9  1  0.729  0.133  0.383  1.0
  S  S10  1  0.271  0.867  0.617  1.0
  S  S11  1  0.776  0.776  0.776  1.0
  S  S12  1  0.867  0.617  0.271  1.0
  S  S13  1  0.617  0.271  0.867  1.0
  S  S14  1  0.224  0.224  0.224  1.0
[/CIF]
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The structure described by AgMo6S8 crystallizes in the trigonal R-3 space group. Mo(1) is bonded to one S(2) and four equivalent S(1) atoms to form a mixture of distorted edge and corner-sharing MoS5 square pyramids. Ag(1) is bonded in a linear geometry to two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 4-coordinate geometry to three equivalent Mo(1) and one Ag(1) atom. In the second S site, S(1) is bonded in a 4-coordinate geometry to four equivalent Mo(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag(Mo3S4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.537
_cell_length_b   6.537
_cell_length_c   6.537
_cell_angle_alpha   92.072
_cell_angle_beta   92.072
_cell_angle_gamma   92.072
_symmetry_Int_Tables_number   1
_cell_volume   278.718
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Mo  Mo1  1  0.216  0.553  0.407  1.0
  Mo  Mo2  1  0.553  0.407  0.216  1.0
  Mo  Mo3  1  0.407  0.216  0.553  1.0
  Mo  Mo4  1  0.593  0.784  0.447  1.0
  Mo  Mo5  1  0.447  0.593  0.784  1.0
  Mo  Mo6  1  0.784  0.447  0.593  1.0
  S  S7  1  0.383  0.729  0.133  1.0
  S  S8  1  0.133  0.383  0.729  1.0
  S  S9  1  0.729  0.133  0.383  1.0
  S  S10  1  0.271  0.867  0.617  1.0
  S  S11  1  0.776  0.776  0.776  1.0
  S  S12  1  0.867  0.617  0.271  1.0
  S  S13  1  0.617  0.271  0.867  1.0
  S  S14  1  0.224  0.224  0.224  1.0
[/CIF]
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