The structure described by Li3Mn3TeO8 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-15°. In the third Li site, Li(3) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Mn(4)O6 octahedra, corners with four equivalent Mn(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-14°. In the fourth Li site, Li(4) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with four equivalent Mn(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fifth Li site, Li(5) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share corners with six equivalent Mn(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-15°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-15°. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-14°. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with four equivalent Li(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-15°. Te(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one Li(5), one Mn(2), one Mn(4), and one Mn(5) atom to form distorted OLi3Mn3 octahedra that share corners with two equivalent O(2)Li3Mn3 octahedra, corners with four equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(3)Li2Mn2Te square pyramids, edges with two equivalent O(4)Li2Mn2Te square pyramids, edges with two equivalent O(5)Li2Mn2Te square pyramids, edges with two equivalent O(6)Li2Mn2Te square pyramids, and edges with four equivalent O(7)Li2Mn2Te square pyramids. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Li(1), one Li(3), one Li(5), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted OLi3Mn3 octahedra that share corners with two equivalent O(1)Li3Mn3 octahedra, corners with four equivalent O(2)Li3Mn3 octahedra, edges with two equivalent O(3)Li2Mn2Te square pyramids, edges with two equivalent O(4)Li2Mn2Te square pyramids, edges with two equivalent O(5)Li2Mn2Te square pyramids, edges with two equivalent O(6)Li2Mn2Te square pyramids, and edges with four equivalent O(8)Li2Mn2Te square pyramids. The corner-sharing octahedral tilt angles range from 0-9°. In the third O site, O(3) is bonded to one Li(3), one Li(5), one Mn(4), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with two equivalent O(3)Li2Mn2Te square pyramids, corners with three equivalent O(4)Li2Mn2Te square pyramids, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and  an edgeedge with one O(8)Li2Mn2Te square pyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one Mn(3), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with two equivalent O(4)Li2Mn2Te square pyramids, corners with three equivalent O(3)Li2Mn2Te square pyramids, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and  an edgeedge with one O(8)Li2Mn2Te square pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Li(5), one Mn(1), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with three equivalent O(6)Li2Mn2Te square pyramids, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and  an edgeedge with one O(8)Li2Mn2Te square pyramid. In the sixth O site, O(6) is bonded to one Li(1), one Li(5), one Mn(2), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with three equivalent O(5)Li2Mn2Te square pyramids, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and  an edgeedge with one O(8)Li2Mn2Te square pyramid. In the seventh O site, O(7) is bonded to one Li(2), one Li(4), one Mn(2), one Mn(4), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with four equivalent O(7)Li2Mn2Te square pyramids, edges with four equivalent O(1)Li3Mn3 octahedra,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid, and  an edgeedge with one O(6)Li2Mn2Te square pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Mn(1), one Mn(3), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid, corners with four equivalent O(8)Li2Mn2Te square pyramids, edges with four equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid, and  an edgeedge with one O(6)Li2Mn2Te square pyramid. is represented by the CIF file [CIF]
data_Li3Mn3TeO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.160
_cell_length_b   6.327
_cell_length_c   8.684
_cell_angle_alpha   89.943
_cell_angle_beta   91.999
_cell_angle_gamma   90.033
_symmetry_Int_Tables_number   1
_cell_volume   338.269
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.250  0.750  1.0
  Li  Li1  1  0.250  0.750  0.250  1.0
  Li  Li2  1  0.750  0.750  0.750  1.0
  Li  Li3  1  0.250  0.250  0.250  1.0
  Li  Li4  1  1.000  0.508  0.500  1.0
  Li  Li5  1  0.500  0.992  0.000  1.0
  Mn  Mn6  1  0.250  0.750  0.750  1.0
  Mn  Mn7  1  0.750  0.250  0.250  1.0
  Mn  Mn8  1  0.250  0.250  0.750  1.0
  Mn  Mn9  1  0.750  0.750  0.250  1.0
  Mn  Mn10  1  0.003  0.500  1.000  1.0
  Mn  Mn11  1  0.497  0.000  0.500  1.0
  Te  Te12  1  0.500  0.498  0.500  1.0
  Te  Te13  1  0.000  0.002  0.000  1.0
  O  O14  1  0.537  0.974  0.255  1.0
  O  O15  1  0.037  0.526  0.754  1.0
  O  O16  1  0.463  0.974  0.746  1.0
  O  O17  1  0.963  0.526  0.245  1.0
  O  O18  1  0.775  0.781  0.008  1.0
  O  O19  1  0.275  0.280  0.494  1.0
  O  O20  1  0.274  0.718  0.508  1.0
  O  O21  1  0.777  0.220  0.994  1.0
  O  O22  1  0.488  0.500  0.275  1.0
  O  O23  1  0.989  0.999  0.775  1.0
  O  O24  1  0.225  0.220  0.006  1.0
  O  O25  1  0.725  0.719  0.492  1.0
  O  O26  1  0.724  0.280  0.506  1.0
  O  O27  1  0.226  0.782  0.992  1.0
  O  O28  1  0.510  0.501  0.725  1.0
  O  O29  1  0.012  0.999  0.225  1.0
[/CIF]
.
The structure described by Li3Mn3TeO8 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-15°. In the third Li site, Li(3) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Mn(4)O6 octahedra, corners with four equivalent Mn(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-14°. In the fourth Li site, Li(4) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with four equivalent Mn(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fifth Li site, Li(5) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share corners with six equivalent Mn(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-15°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-15°. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-14°. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with four equivalent Li(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-15°. Te(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one Li(5), one Mn(2), one Mn(4), and one Mn(5) atom to form distorted OLi3Mn3 octahedra that share corners with two equivalent O(2)Li3Mn3 octahedra, corners with four equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(3)Li2Mn2Te square pyramids, edges with two equivalent O(4)Li2Mn2Te square pyramids, edges with two equivalent O(5)Li2Mn2Te square pyramids, edges with two equivalent O(6)Li2Mn2Te square pyramids, and edges with four equivalent O(7)Li2Mn2Te square pyramids. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Li(1), one Li(3), one Li(5), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted OLi3Mn3 octahedra that share corners with two equivalent O(1)Li3Mn3 octahedra, corners with four equivalent O(2)Li3Mn3 octahedra, edges with two equivalent O(3)Li2Mn2Te square pyramids, edges with two equivalent O(4)Li2Mn2Te square pyramids, edges with two equivalent O(5)Li2Mn2Te square pyramids, edges with two equivalent O(6)Li2Mn2Te square pyramids, and edges with four equivalent O(8)Li2Mn2Te square pyramids. The corner-sharing octahedral tilt angles range from 0-9°. In the third O site, O(3) is bonded to one Li(3), one Li(5), one Mn(4), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with two equivalent O(3)Li2Mn2Te square pyramids, corners with three equivalent O(4)Li2Mn2Te square pyramids, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and  an edgeedge with one O(8)Li2Mn2Te square pyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one Mn(3), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with two equivalent O(4)Li2Mn2Te square pyramids, corners with three equivalent O(3)Li2Mn2Te square pyramids, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and  an edgeedge with one O(8)Li2Mn2Te square pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Li(5), one Mn(1), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with three equivalent O(6)Li2Mn2Te square pyramids, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and  an edgeedge with one O(8)Li2Mn2Te square pyramid. In the sixth O site, O(6) is bonded to one Li(1), one Li(5), one Mn(2), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with three equivalent O(5)Li2Mn2Te square pyramids, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and  an edgeedge with one O(8)Li2Mn2Te square pyramid. In the seventh O site, O(7) is bonded to one Li(2), one Li(4), one Mn(2), one Mn(4), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid, corners with four equivalent O(7)Li2Mn2Te square pyramids, edges with four equivalent O(1)Li3Mn3 octahedra,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid, and  an edgeedge with one O(6)Li2Mn2Te square pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Mn(1), one Mn(3), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid, corners with four equivalent O(8)Li2Mn2Te square pyramids, edges with four equivalent O(2)Li3Mn3 octahedra,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid, and  an edgeedge with one O(6)Li2Mn2Te square pyramid. is represented by the CIF file [CIF]
data_Li3Mn3TeO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.160
_cell_length_b   6.327
_cell_length_c   8.684
_cell_angle_alpha   89.943
_cell_angle_beta   91.999
_cell_angle_gamma   90.033
_symmetry_Int_Tables_number   1
_cell_volume   338.269
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.250  0.750  1.0
  Li  Li1  1  0.250  0.750  0.250  1.0
  Li  Li2  1  0.750  0.750  0.750  1.0
  Li  Li3  1  0.250  0.250  0.250  1.0
  Li  Li4  1  1.000  0.508  0.500  1.0
  Li  Li5  1  0.500  0.992  0.000  1.0
  Mn  Mn6  1  0.250  0.750  0.750  1.0
  Mn  Mn7  1  0.750  0.250  0.250  1.0
  Mn  Mn8  1  0.250  0.250  0.750  1.0
  Mn  Mn9  1  0.750  0.750  0.250  1.0
  Mn  Mn10  1  0.003  0.500  1.000  1.0
  Mn  Mn11  1  0.497  0.000  0.500  1.0
  Te  Te12  1  0.500  0.498  0.500  1.0
  Te  Te13  1  0.000  0.002  0.000  1.0
  O  O14  1  0.537  0.974  0.255  1.0
  O  O15  1  0.037  0.526  0.754  1.0
  O  O16  1  0.463  0.974  0.746  1.0
  O  O17  1  0.963  0.526  0.245  1.0
  O  O18  1  0.775  0.781  0.008  1.0
  O  O19  1  0.275  0.280  0.494  1.0
  O  O20  1  0.274  0.718  0.508  1.0
  O  O21  1  0.777  0.220  0.994  1.0
  O  O22  1  0.488  0.500  0.275  1.0
  O  O23  1  0.989  0.999  0.775  1.0
  O  O24  1  0.225  0.220  0.006  1.0
  O  O25  1  0.725  0.719  0.492  1.0
  O  O26  1  0.724  0.280  0.506  1.0
  O  O27  1  0.226  0.782  0.992  1.0
  O  O28  1  0.510  0.501  0.725  1.0
  O  O29  1  0.012  0.999  0.225  1.0
[/CIF]
.