The material described by NaSbF6 crystallizes in the cubic Pa-3 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent F(1) atoms. Sb(1) is bonded in an octahedral geometry to six equivalent F(1) atoms. F(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Sb(1) atom. is represented by the CIF file [CIF]
data_NaSbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.355
_cell_length_b   8.355
_cell_length_c   8.355
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   583.242
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.500  1.0
  Na  Na1  1  0.000  0.500  0.000  1.0
  Na  Na2  1  0.500  0.000  0.000  1.0
  Na  Na3  1  0.500  0.500  0.500  1.0
  Sb  Sb4  1  0.500  0.500  0.000  1.0
  Sb  Sb5  1  0.500  0.000  0.500  1.0
  Sb  Sb6  1  0.000  0.500  0.500  1.0
  Sb  Sb7  1  0.000  0.000  0.000  1.0
  F  F8  1  0.278  0.462  0.047  1.0
  F  F9  1  0.722  0.962  0.453  1.0
  F  F10  1  0.222  0.538  0.547  1.0
  F  F11  1  0.778  0.038  0.953  1.0
  F  F12  1  0.047  0.278  0.462  1.0
  F  F13  1  0.453  0.722  0.962  1.0
  F  F14  1  0.547  0.222  0.538  1.0
  F  F15  1  0.953  0.778  0.038  1.0
  F  F16  1  0.462  0.047  0.278  1.0
  F  F17  1  0.962  0.453  0.722  1.0
  F  F18  1  0.538  0.547  0.222  1.0
  F  F19  1  0.038  0.953  0.778  1.0
  F  F20  1  0.722  0.538  0.953  1.0
  F  F21  1  0.278  0.038  0.547  1.0
  F  F22  1  0.778  0.462  0.453  1.0
  F  F23  1  0.222  0.962  0.047  1.0
  F  F24  1  0.953  0.722  0.538  1.0
  F  F25  1  0.547  0.278  0.038  1.0
  F  F26  1  0.453  0.778  0.462  1.0
  F  F27  1  0.047  0.222  0.962  1.0
  F  F28  1  0.538  0.953  0.722  1.0
  F  F29  1  0.038  0.547  0.278  1.0
  F  F30  1  0.462  0.453  0.778  1.0
  F  F31  1  0.962  0.047  0.222  1.0
[/CIF]
.
The material described by NaSbF6 crystallizes in the cubic Pa-3 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent F(1) atoms. Sb(1) is bonded in an octahedral geometry to six equivalent F(1) atoms. F(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Sb(1) atom. is represented by the CIF file [CIF]
data_NaSbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.355
_cell_length_b   8.355
_cell_length_c   8.355
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   583.242
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.500  1.0
  Na  Na1  1  0.000  0.500  0.000  1.0
  Na  Na2  1  0.500  0.000  0.000  1.0
  Na  Na3  1  0.500  0.500  0.500  1.0
  Sb  Sb4  1  0.500  0.500  0.000  1.0
  Sb  Sb5  1  0.500  0.000  0.500  1.0
  Sb  Sb6  1  0.000  0.500  0.500  1.0
  Sb  Sb7  1  0.000  0.000  0.000  1.0
  F  F8  1  0.278  0.462  0.047  1.0
  F  F9  1  0.722  0.962  0.453  1.0
  F  F10  1  0.222  0.538  0.547  1.0
  F  F11  1  0.778  0.038  0.953  1.0
  F  F12  1  0.047  0.278  0.462  1.0
  F  F13  1  0.453  0.722  0.962  1.0
  F  F14  1  0.547  0.222  0.538  1.0
  F  F15  1  0.953  0.778  0.038  1.0
  F  F16  1  0.462  0.047  0.278  1.0
  F  F17  1  0.962  0.453  0.722  1.0
  F  F18  1  0.538  0.547  0.222  1.0
  F  F19  1  0.038  0.953  0.778  1.0
  F  F20  1  0.722  0.538  0.953  1.0
  F  F21  1  0.278  0.038  0.547  1.0
  F  F22  1  0.778  0.462  0.453  1.0
  F  F23  1  0.222  0.962  0.047  1.0
  F  F24  1  0.953  0.722  0.538  1.0
  F  F25  1  0.547  0.278  0.038  1.0
  F  F26  1  0.453  0.778  0.462  1.0
  F  F27  1  0.047  0.222  0.962  1.0
  F  F28  1  0.538  0.953  0.722  1.0
  F  F29  1  0.038  0.547  0.278  1.0
  F  F30  1  0.462  0.453  0.778  1.0
  F  F31  1  0.962  0.047  0.222  1.0
[/CIF]
.