The crystal structure described by N3S4O2F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N3S4O2F clusters. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one N(3), one O(1), one O(2), and one F(1) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. F(1) is bonded in a single-bond geometry to one S(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S4N3O2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.740
_cell_length_b   8.303
_cell_length_c   17.178
_cell_angle_alpha   66.805
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   752.547
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.293  0.793  0.235  1.0
  S  S1  1  0.446  0.347  0.614  1.0
  S  S2  1  0.258  0.834  0.953  1.0
  S  S3  1  0.269  0.474  0.369  1.0
  S  S4  1  0.793  0.207  0.265  1.0
  S  S5  1  0.742  0.166  0.047  1.0
  S  S6  1  0.946  0.653  0.886  1.0
  S  S7  1  0.554  0.653  0.386  1.0
  S  S8  1  0.231  0.474  0.869  1.0
  S  S9  1  0.207  0.793  0.735  1.0
  S  S10  1  0.769  0.526  0.131  1.0
  S  S11  1  0.707  0.207  0.765  1.0
  S  S12  1  0.758  0.166  0.547  1.0
  S  S13  1  0.731  0.526  0.631  1.0
  S  S14  1  0.242  0.834  0.453  1.0
  S  S15  1  0.054  0.347  0.114  1.0
  N  N16  1  0.665  0.386  0.218  1.0
  N  N17  1  0.165  0.614  0.282  1.0
  N  N18  1  0.980  0.795  0.788  1.0
  N  N19  1  0.026  0.722  0.956  1.0
  N  N20  1  0.835  0.386  0.718  1.0
  N  N21  1  0.335  0.614  0.782  1.0
  N  N22  1  0.474  0.722  0.456  1.0
  N  N23  1  0.526  0.278  0.544  1.0
  N  N24  1  0.974  0.278  0.044  1.0
  N  N25  1  0.480  0.205  0.712  1.0
  N  N26  1  0.520  0.795  0.288  1.0
  N  N27  1  0.020  0.205  0.212  1.0
  O  O28  1  0.568  0.172  0.106  1.0
  O  O29  1  0.679  0.191  0.962  1.0
  O  O30  1  0.068  0.828  0.394  1.0
  O  O31  1  0.821  0.191  0.462  1.0
  O  O32  1  0.932  0.172  0.606  1.0
  O  O33  1  0.179  0.809  0.538  1.0
  O  O34  1  0.432  0.828  0.894  1.0
  O  O35  1  0.321  0.809  0.038  1.0
  F  F36  1  0.156  0.031  0.912  1.0
  F  F37  1  0.344  0.031  0.412  1.0
  F  F38  1  0.844  0.969  0.088  1.0
  F  F39  1  0.656  0.969  0.588  1.0
[/CIF]
.
The crystal structure described by N3S4O2F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N3S4O2F clusters. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one N(3), one O(1), one O(2), and one F(1) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. F(1) is bonded in a single-bond geometry to one S(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S4N3O2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.740
_cell_length_b   8.303
_cell_length_c   17.178
_cell_angle_alpha   66.805
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   752.547
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.293  0.793  0.235  1.0
  S  S1  1  0.446  0.347  0.614  1.0
  S  S2  1  0.258  0.834  0.953  1.0
  S  S3  1  0.269  0.474  0.369  1.0
  S  S4  1  0.793  0.207  0.265  1.0
  S  S5  1  0.742  0.166  0.047  1.0
  S  S6  1  0.946  0.653  0.886  1.0
  S  S7  1  0.554  0.653  0.386  1.0
  S  S8  1  0.231  0.474  0.869  1.0
  S  S9  1  0.207  0.793  0.735  1.0
  S  S10  1  0.769  0.526  0.131  1.0
  S  S11  1  0.707  0.207  0.765  1.0
  S  S12  1  0.758  0.166  0.547  1.0
  S  S13  1  0.731  0.526  0.631  1.0
  S  S14  1  0.242  0.834  0.453  1.0
  S  S15  1  0.054  0.347  0.114  1.0
  N  N16  1  0.665  0.386  0.218  1.0
  N  N17  1  0.165  0.614  0.282  1.0
  N  N18  1  0.980  0.795  0.788  1.0
  N  N19  1  0.026  0.722  0.956  1.0
  N  N20  1  0.835  0.386  0.718  1.0
  N  N21  1  0.335  0.614  0.782  1.0
  N  N22  1  0.474  0.722  0.456  1.0
  N  N23  1  0.526  0.278  0.544  1.0
  N  N24  1  0.974  0.278  0.044  1.0
  N  N25  1  0.480  0.205  0.712  1.0
  N  N26  1  0.520  0.795  0.288  1.0
  N  N27  1  0.020  0.205  0.212  1.0
  O  O28  1  0.568  0.172  0.106  1.0
  O  O29  1  0.679  0.191  0.962  1.0
  O  O30  1  0.068  0.828  0.394  1.0
  O  O31  1  0.821  0.191  0.462  1.0
  O  O32  1  0.932  0.172  0.606  1.0
  O  O33  1  0.179  0.809  0.538  1.0
  O  O34  1  0.432  0.828  0.894  1.0
  O  O35  1  0.321  0.809  0.038  1.0
  F  F36  1  0.156  0.031  0.912  1.0
  F  F37  1  0.344  0.031  0.412  1.0
  F  F38  1  0.844  0.969  0.088  1.0
  F  F39  1  0.656  0.969  0.588  1.0
[/CIF]
.