The compound described by CoC2H14(N5O3)2(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and one CoC2H14(N5O3)2 cluster. In the CoC2H14(N5O3)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one N(4) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Co(1), one N(2), one H(6), and one H(7) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(5) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one N(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one N(4), one O(1), and one O(2) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(1), one H(1), and one H(2) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(5) atom. In the third O site, O(2) is bonded in a single-bond geometry to one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoH14C2(NO)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.365
_cell_length_b   7.498
_cell_length_c   9.350
_cell_angle_alpha   97.662
_cell_angle_beta   96.400
_cell_angle_gamma   119.033
_symmetry_Int_Tables_number   1
_cell_volume   438.064
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.000  1.0
  H  H1  1  0.258  0.928  0.043  1.0
  H  H2  1  0.742  0.072  0.957  1.0
  H  H3  1  0.280  0.833  0.884  1.0
  H  H4  1  0.720  0.167  0.116  1.0
  H  H5  1  0.334  0.616  0.401  1.0
  H  H6  1  0.666  0.384  0.599  1.0
  H  H7  1  0.001  0.813  0.473  1.0
  H  H8  1  0.999  0.187  0.527  1.0
  H  H9  1  0.218  0.790  0.553  1.0
  H  H10  1  0.782  0.210  0.447  1.0
  H  H11  1  0.393  0.629  0.148  1.0
  H  H12  1  0.607  0.371  0.852  1.0
  H  H13  1  0.233  0.385  0.161  1.0
  H  H14  1  0.767  0.615  0.839  1.0
  C  C15  1  0.097  0.673  0.328  1.0
  C  C16  1  0.903  0.327  0.672  1.0
  N  N17  1  0.246  0.528  0.168  1.0
  N  N18  1  0.754  0.472  0.832  1.0
  N  N19  1  0.230  0.601  0.310  1.0
  N  N20  1  0.770  0.399  0.690  1.0
  N  N21  1  0.103  0.760  0.463  1.0
  N  N22  1  0.897  0.240  0.537  1.0
  N  N23  1  0.964  0.644  0.201  1.0
  N  N24  1  0.036  0.356  0.799  1.0
  N  N25  1  0.829  0.719  0.206  1.0
  N  N26  1  0.171  0.281  0.794  1.0
  N  N27  1  0.537  0.803  0.709  1.0
  N  N28  1  0.463  0.197  0.291  1.0
  O  O29  1  0.714  0.685  0.085  1.0
  O  O30  1  0.286  0.315  0.915  1.0
  O  O31  1  0.818  0.814  0.323  1.0
  O  O32  1  0.182  0.186  0.677  1.0
  O  O33  1  0.205  0.798  0.967  1.0
  O  O34  1  0.795  0.202  0.033  1.0
  O  O35  1  0.693  0.867  0.814  1.0
  O  O36  1  0.307  0.133  0.186  1.0
  O  O37  1  0.405  0.867  0.722  1.0
  O  O38  1  0.595  0.133  0.278  1.0
  O  O39  1  0.512  0.679  0.594  1.0
  O  O40  1  0.488  0.321  0.406  1.0
[/CIF]
.
The compound described by CoC2H14(N5O3)2(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and one CoC2H14(N5O3)2 cluster. In the CoC2H14(N5O3)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one N(4) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Co(1), one N(2), one H(6), and one H(7) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(5) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one N(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one N(4), one O(1), and one O(2) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(1), one H(1), and one H(2) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(5) atom. In the third O site, O(2) is bonded in a single-bond geometry to one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoH14C2(NO)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.365
_cell_length_b   7.498
_cell_length_c   9.350
_cell_angle_alpha   97.662
_cell_angle_beta   96.400
_cell_angle_gamma   119.033
_symmetry_Int_Tables_number   1
_cell_volume   438.064
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.000  1.0
  H  H1  1  0.258  0.928  0.043  1.0
  H  H2  1  0.742  0.072  0.957  1.0
  H  H3  1  0.280  0.833  0.884  1.0
  H  H4  1  0.720  0.167  0.116  1.0
  H  H5  1  0.334  0.616  0.401  1.0
  H  H6  1  0.666  0.384  0.599  1.0
  H  H7  1  0.001  0.813  0.473  1.0
  H  H8  1  0.999  0.187  0.527  1.0
  H  H9  1  0.218  0.790  0.553  1.0
  H  H10  1  0.782  0.210  0.447  1.0
  H  H11  1  0.393  0.629  0.148  1.0
  H  H12  1  0.607  0.371  0.852  1.0
  H  H13  1  0.233  0.385  0.161  1.0
  H  H14  1  0.767  0.615  0.839  1.0
  C  C15  1  0.097  0.673  0.328  1.0
  C  C16  1  0.903  0.327  0.672  1.0
  N  N17  1  0.246  0.528  0.168  1.0
  N  N18  1  0.754  0.472  0.832  1.0
  N  N19  1  0.230  0.601  0.310  1.0
  N  N20  1  0.770  0.399  0.690  1.0
  N  N21  1  0.103  0.760  0.463  1.0
  N  N22  1  0.897  0.240  0.537  1.0
  N  N23  1  0.964  0.644  0.201  1.0
  N  N24  1  0.036  0.356  0.799  1.0
  N  N25  1  0.829  0.719  0.206  1.0
  N  N26  1  0.171  0.281  0.794  1.0
  N  N27  1  0.537  0.803  0.709  1.0
  N  N28  1  0.463  0.197  0.291  1.0
  O  O29  1  0.714  0.685  0.085  1.0
  O  O30  1  0.286  0.315  0.915  1.0
  O  O31  1  0.818  0.814  0.323  1.0
  O  O32  1  0.182  0.186  0.677  1.0
  O  O33  1  0.205  0.798  0.967  1.0
  O  O34  1  0.795  0.202  0.033  1.0
  O  O35  1  0.693  0.867  0.814  1.0
  O  O36  1  0.307  0.133  0.186  1.0
  O  O37  1  0.405  0.867  0.722  1.0
  O  O38  1  0.595  0.133  0.278  1.0
  O  O39  1  0.512  0.679  0.594  1.0
  O  O40  1  0.488  0.321  0.406  1.0
[/CIF]
.