The crystal structure described by Sr4La(CoO3)5 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic C2/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(4), one O(6), two equivalent O(2), two equivalent O(3), two equivalent O(5), and four equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with two equivalent La(1)O12 cuboctahedra, corners with five equivalent Sr(1)O12 cuboctahedra, corners with five equivalent Sr(2)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Co(2)O6 octahedra, faces with three equivalent Co(1)O6 octahedra, and faces with three equivalent Co(3)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(5), two equivalent O(1), two equivalent O(3), three equivalent O(4), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with three equivalent La(1)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with five equivalent Sr(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra,  a faceface with one Co(2)O6 octahedra, faces with three equivalent Co(1)O6 octahedra, and faces with four equivalent Co(3)O6 octahedra. La(1) is bonded to two equivalent O(5), two equivalent O(6), four equivalent O(1), and four equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with two equivalent La(1)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Co(2)O6 octahedra, faces with two equivalent Co(3)O6 octahedra, and faces with four equivalent Co(1)O6 octahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(4), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Co(3)O6 octahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the second Co site, Co(2) is bonded to two equivalent O(5) and four equivalent O(1) atoms to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the third Co site, Co(3) is bonded to one O(4), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-6°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Sr(2), two equivalent Sr(1), one La(1), one Co(1), and one Co(2) atom to form distorted OSr3LaCo2 octahedra that share corners with two equivalent O(6)Sr2La2Co2 octahedra, corners with three equivalent O(1)Sr3LaCo2 octahedra, corners with three equivalent O(5)Sr3LaCo2 octahedra, corners with three equivalent O(4)Sr4Co2 octahedra, corners with four equivalent O(3)Sr4Co2 octahedra, corners with seven equivalent O(2)Sr3LaCo2 octahedra,  an edgeedge with one O(1)Sr3LaCo2 octahedra,  an edgeedge with one O(3)Sr4Co2 octahedra, edges with two equivalent O(2)Sr3LaCo2 octahedra,  a faceface with one O(6)Sr2La2Co2 octahedra,  a faceface with one O(2)Sr3LaCo2 octahedra,  a faceface with one O(4)Sr4Co2 octahedra, faces with two equivalent O(5)Sr3LaCo2 octahedra, and faces with three equivalent O(1)Sr3LaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the second O site, O(2) is bonded to one Sr(1), two equivalent Sr(2), one La(1), one Co(1), and one Co(3) atom to form distorted OSr3LaCo2 octahedra that share  a cornercorner with one O(6)Sr2La2Co2 octahedra, corners with three equivalent O(3)Sr4Co2 octahedra, corners with three equivalent O(4)Sr4Co2 octahedra, corners with four equivalent O(2)Sr3LaCo2 octahedra, corners with four equivalent O(5)Sr3LaCo2 octahedra, corners with seven equivalent O(1)Sr3LaCo2 octahedra,  an edgeedge with one O(2)Sr3LaCo2 octahedra,  an edgeedge with one O(3)Sr4Co2 octahedra, edges with two equivalent O(1)Sr3LaCo2 octahedra,  a faceface with one O(6)Sr2La2Co2 octahedra,  a faceface with one O(1)Sr3LaCo2 octahedra,  a faceface with one O(5)Sr3LaCo2 octahedra,  a faceface with one O(3)Sr4Co2 octahedra, faces with two equivalent O(2)Sr3LaCo2 octahedra, and faces with two equivalent O(4)Sr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Co(3) atoms to form distorted OSr4Co2 octahedra that share corners with two equivalent O(6)Sr2La2Co2 octahedra, corners with two equivalent O(5)Sr3LaCo2 octahedra, corners with four equivalent O(4)Sr4Co2 octahedra, corners with six equivalent O(2)Sr3LaCo2 octahedra, corners with eight equivalent O(1)Sr3LaCo2 octahedra, edges with two equivalent O(1)Sr3LaCo2 octahedra, edges with two equivalent O(2)Sr3LaCo2 octahedra, faces with two equivalent O(2)Sr3LaCo2 octahedra, faces with two equivalent O(5)Sr3LaCo2 octahedra, faces with two equivalent O(3)Sr4Co2 octahedra, and faces with two equivalent O(4)Sr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the fourth O site, O(4) is bonded to one Sr(1), three equivalent Sr(2), one Co(1), and one Co(3) atom to form distorted OSr4Co2 octahedra that share corners with two equivalent O(6)Sr2La2Co2 octahedra, corners with two equivalent O(5)Sr3LaCo2 octahedra, corners with two equivalent O(4)Sr4Co2 octahedra, corners with four equivalent O(3)Sr4Co2 octahedra, corners with six equivalent O(1)Sr3LaCo2 octahedra, corners with six equivalent O(2)Sr3LaCo2 octahedra, edges with two equivalent O(5)Sr3LaCo2 octahedra, edges with two equivalent O(4)Sr4Co2 octahedra, faces with two equivalent O(1)Sr3LaCo2 octahedra, faces with two equivalent O(3)Sr4Co2 octahedra, and faces with four equivalent O(2)Sr3LaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(5) is bonded to one Sr(2), two equivalent Sr(1), one La(1), one Co(2), and one Co(3) atom to form distorted OSr3LaCo2 octahedra that share corners with two equivalent O(3)Sr4Co2 octahedra, corners with two equivalent O(4)Sr4Co2 octahedra, corners with four equivalent O(5)Sr3LaCo2 octahedra, corners with six equivalent O(1)Sr3LaCo2 octahedra, corners with eight equivalent O(2)Sr3LaCo2 octahedra, edges with two equivalent O(6)Sr2La2Co2 octahedra, edges with two equivalent O(4)Sr4Co2 octahedra, faces with two equivalent O(2)Sr3LaCo2 octahedra, faces with two equivalent O(3)Sr4Co2 octahedra, and faces with four equivalent O(1)Sr3LaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the sixth O site, O(6) is bonded to two equivalent Sr(1), two equivalent La(1), and two equivalent Co(1) atoms to form distorted OSr2La2Co2 octahedra that share corners with two equivalent O(6)Sr2La2Co2 octahedra, corners with four equivalent O(2)Sr3LaCo2 octahedra, corners with four equivalent O(3)Sr4Co2 octahedra, corners with four equivalent O(4)Sr4Co2 octahedra, corners with eight equivalent O(1)Sr3LaCo2 octahedra, edges with four equivalent O(5)Sr3LaCo2 octahedra, faces with four equivalent O(1)Sr3LaCo2 octahedra, and faces with four equivalent O(2)Sr3LaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4La(CoO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.697
_cell_length_b   8.697
_cell_length_c   6.709
_cell_angle_alpha   74.786
_cell_angle_beta   74.786
_cell_angle_gamma   36.578
_symmetry_Int_Tables_number   1
_cell_volume   290.614
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.100  0.100  0.100  1.0
  Sr  Sr1  1  0.700  0.700  0.698  1.0
  Sr  Sr2  1  0.300  0.300  0.302  1.0
  Sr  Sr3  1  0.900  0.900  0.900  1.0
  La  La4  1  0.500  0.500  0.500  1.0
  Co  Co5  1  0.899  0.899  0.400  1.0
  Co  Co6  1  0.500  0.500  0.000  1.0
  Co  Co7  1  0.101  0.101  0.600  1.0
  Co  Co8  1  0.702  0.702  0.200  1.0
  Co  Co9  1  0.298  0.298  0.800  1.0
  O  O10  1  0.698  0.201  0.213  1.0
  O  O11  1  0.302  0.799  0.787  1.0
  O  O12  1  0.891  0.400  0.398  1.0
  O  O13  1  0.500  0.000  0.000  1.0
  O  O14  1  0.109  0.600  0.602  1.0
  O  O15  1  0.800  0.800  0.306  1.0
  O  O16  1  0.406  0.406  0.901  1.0
  O  O17  1  0.000  0.000  0.500  1.0
  O  O18  1  0.594  0.594  0.099  1.0
  O  O19  1  0.200  0.200  0.694  1.0
  O  O20  1  0.600  0.109  0.602  1.0
  O  O21  1  0.201  0.698  0.213  1.0
  O  O22  1  0.799  0.302  0.787  1.0
  O  O23  1  0.400  0.891  0.398  1.0
  O  O24  1  0.000  0.500  0.000  1.0
[/CIF]
.
The crystal structure described by Sr4La(CoO3)5 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic C2/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(4), one O(6), two equivalent O(2), two equivalent O(3), two equivalent O(5), and four equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with two equivalent La(1)O12 cuboctahedra, corners with five equivalent Sr(1)O12 cuboctahedra, corners with five equivalent Sr(2)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Co(2)O6 octahedra, faces with three equivalent Co(1)O6 octahedra, and faces with three equivalent Co(3)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(5), two equivalent O(1), two equivalent O(3), three equivalent O(4), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with three equivalent La(1)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with five equivalent Sr(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra,  a faceface with one Co(2)O6 octahedra, faces with three equivalent Co(1)O6 octahedra, and faces with four equivalent Co(3)O6 octahedra. La(1) is bonded to two equivalent O(5), two equivalent O(6), four equivalent O(1), and four equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with two equivalent La(1)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Co(2)O6 octahedra, faces with two equivalent Co(3)O6 octahedra, and faces with four equivalent Co(1)O6 octahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(4), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Co(3)O6 octahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the second Co site, Co(2) is bonded to two equivalent O(5) and four equivalent O(1) atoms to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the third Co site, Co(3) is bonded to one O(4), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-6°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Sr(2), two equivalent Sr(1), one La(1), one Co(1), and one Co(2) atom to form distorted OSr3LaCo2 octahedra that share corners with two equivalent O(6)Sr2La2Co2 octahedra, corners with three equivalent O(1)Sr3LaCo2 octahedra, corners with three equivalent O(5)Sr3LaCo2 octahedra, corners with three equivalent O(4)Sr4Co2 octahedra, corners with four equivalent O(3)Sr4Co2 octahedra, corners with seven equivalent O(2)Sr3LaCo2 octahedra,  an edgeedge with one O(1)Sr3LaCo2 octahedra,  an edgeedge with one O(3)Sr4Co2 octahedra, edges with two equivalent O(2)Sr3LaCo2 octahedra,  a faceface with one O(6)Sr2La2Co2 octahedra,  a faceface with one O(2)Sr3LaCo2 octahedra,  a faceface with one O(4)Sr4Co2 octahedra, faces with two equivalent O(5)Sr3LaCo2 octahedra, and faces with three equivalent O(1)Sr3LaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the second O site, O(2) is bonded to one Sr(1), two equivalent Sr(2), one La(1), one Co(1), and one Co(3) atom to form distorted OSr3LaCo2 octahedra that share  a cornercorner with one O(6)Sr2La2Co2 octahedra, corners with three equivalent O(3)Sr4Co2 octahedra, corners with three equivalent O(4)Sr4Co2 octahedra, corners with four equivalent O(2)Sr3LaCo2 octahedra, corners with four equivalent O(5)Sr3LaCo2 octahedra, corners with seven equivalent O(1)Sr3LaCo2 octahedra,  an edgeedge with one O(2)Sr3LaCo2 octahedra,  an edgeedge with one O(3)Sr4Co2 octahedra, edges with two equivalent O(1)Sr3LaCo2 octahedra,  a faceface with one O(6)Sr2La2Co2 octahedra,  a faceface with one O(1)Sr3LaCo2 octahedra,  a faceface with one O(5)Sr3LaCo2 octahedra,  a faceface with one O(3)Sr4Co2 octahedra, faces with two equivalent O(2)Sr3LaCo2 octahedra, and faces with two equivalent O(4)Sr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Co(3) atoms to form distorted OSr4Co2 octahedra that share corners with two equivalent O(6)Sr2La2Co2 octahedra, corners with two equivalent O(5)Sr3LaCo2 octahedra, corners with four equivalent O(4)Sr4Co2 octahedra, corners with six equivalent O(2)Sr3LaCo2 octahedra, corners with eight equivalent O(1)Sr3LaCo2 octahedra, edges with two equivalent O(1)Sr3LaCo2 octahedra, edges with two equivalent O(2)Sr3LaCo2 octahedra, faces with two equivalent O(2)Sr3LaCo2 octahedra, faces with two equivalent O(5)Sr3LaCo2 octahedra, faces with two equivalent O(3)Sr4Co2 octahedra, and faces with two equivalent O(4)Sr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the fourth O site, O(4) is bonded to one Sr(1), three equivalent Sr(2), one Co(1), and one Co(3) atom to form distorted OSr4Co2 octahedra that share corners with two equivalent O(6)Sr2La2Co2 octahedra, corners with two equivalent O(5)Sr3LaCo2 octahedra, corners with two equivalent O(4)Sr4Co2 octahedra, corners with four equivalent O(3)Sr4Co2 octahedra, corners with six equivalent O(1)Sr3LaCo2 octahedra, corners with six equivalent O(2)Sr3LaCo2 octahedra, edges with two equivalent O(5)Sr3LaCo2 octahedra, edges with two equivalent O(4)Sr4Co2 octahedra, faces with two equivalent O(1)Sr3LaCo2 octahedra, faces with two equivalent O(3)Sr4Co2 octahedra, and faces with four equivalent O(2)Sr3LaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(5) is bonded to one Sr(2), two equivalent Sr(1), one La(1), one Co(2), and one Co(3) atom to form distorted OSr3LaCo2 octahedra that share corners with two equivalent O(3)Sr4Co2 octahedra, corners with two equivalent O(4)Sr4Co2 octahedra, corners with four equivalent O(5)Sr3LaCo2 octahedra, corners with six equivalent O(1)Sr3LaCo2 octahedra, corners with eight equivalent O(2)Sr3LaCo2 octahedra, edges with two equivalent O(6)Sr2La2Co2 octahedra, edges with two equivalent O(4)Sr4Co2 octahedra, faces with two equivalent O(2)Sr3LaCo2 octahedra, faces with two equivalent O(3)Sr4Co2 octahedra, and faces with four equivalent O(1)Sr3LaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the sixth O site, O(6) is bonded to two equivalent Sr(1), two equivalent La(1), and two equivalent Co(1) atoms to form distorted OSr2La2Co2 octahedra that share corners with two equivalent O(6)Sr2La2Co2 octahedra, corners with four equivalent O(2)Sr3LaCo2 octahedra, corners with four equivalent O(3)Sr4Co2 octahedra, corners with four equivalent O(4)Sr4Co2 octahedra, corners with eight equivalent O(1)Sr3LaCo2 octahedra, edges with four equivalent O(5)Sr3LaCo2 octahedra, faces with four equivalent O(1)Sr3LaCo2 octahedra, and faces with four equivalent O(2)Sr3LaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4La(CoO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.697
_cell_length_b   8.697
_cell_length_c   6.709
_cell_angle_alpha   74.786
_cell_angle_beta   74.786
_cell_angle_gamma   36.578
_symmetry_Int_Tables_number   1
_cell_volume   290.614
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.100  0.100  0.100  1.0
  Sr  Sr1  1  0.700  0.700  0.698  1.0
  Sr  Sr2  1  0.300  0.300  0.302  1.0
  Sr  Sr3  1  0.900  0.900  0.900  1.0
  La  La4  1  0.500  0.500  0.500  1.0
  Co  Co5  1  0.899  0.899  0.400  1.0
  Co  Co6  1  0.500  0.500  0.000  1.0
  Co  Co7  1  0.101  0.101  0.600  1.0
  Co  Co8  1  0.702  0.702  0.200  1.0
  Co  Co9  1  0.298  0.298  0.800  1.0
  O  O10  1  0.698  0.201  0.213  1.0
  O  O11  1  0.302  0.799  0.787  1.0
  O  O12  1  0.891  0.400  0.398  1.0
  O  O13  1  0.500  0.000  0.000  1.0
  O  O14  1  0.109  0.600  0.602  1.0
  O  O15  1  0.800  0.800  0.306  1.0
  O  O16  1  0.406  0.406  0.901  1.0
  O  O17  1  0.000  0.000  0.500  1.0
  O  O18  1  0.594  0.594  0.099  1.0
  O  O19  1  0.200  0.200  0.694  1.0
  O  O20  1  0.600  0.109  0.602  1.0
  O  O21  1  0.201  0.698  0.213  1.0
  O  O22  1  0.799  0.302  0.787  1.0
  O  O23  1  0.400  0.891  0.398  1.0
  O  O24  1  0.000  0.500  0.000  1.0
[/CIF]
.