The material structure described by Li4V2Co3Sb3O16 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent V(2)O6 octahedra, and corners with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-66°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(5), one O(7), and two equivalent O(11) atoms. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-65°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms. In the second V site, V(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, and edges with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form distorted CoO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form SbO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the second Sb site, Sb(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form SbO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with four equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one Co(2), and one Sb(2) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), and two equivalent Sb(1) atoms to form distorted OLiVSb2 trigonal pyramids that share corners with two equivalent O(4)LiCoSb2 tetrahedra, corners with two equivalent O(6)LiVCoSb tetrahedra, corners with two equivalent O(11)LiVCoSb trigonal pyramids, and edges with two equivalent O(6)LiVCoSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded to one Li(3), one Co(1), and two equivalent Sb(1) atoms to form distorted OLiCoSb2 tetrahedra that share corners with four equivalent O(6)LiVCoSb tetrahedra, corners with two equivalent O(2)LiVSb2 trigonal pyramids, and edges with two equivalent O(11)LiVCoSb trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Co(2), and one Sb(2) atom to form corner-sharing OLiCo2Sb tetrahedra. In the sixth O site, O(6) is bonded to one Li(4), one V(1), one Co(1), and one Sb(1) atom to form distorted OLiVCoSb tetrahedra that share  a cornercorner with one O(6)LiVCoSb tetrahedra, corners with two equivalent O(4)LiCoSb2 tetrahedra,  a cornercorner with one O(2)LiVSb2 trigonal pyramid, corners with three equivalent O(11)LiVCoSb trigonal pyramids,  an edgeedge with one O(6)LiVCoSb tetrahedra, and  an edgeedge with one O(2)LiVSb2 trigonal pyramid. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), and two equivalent Sb(1) atoms. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(3), one V(1), and two equivalent Co(2) atoms. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one Co(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent Co(2), and one Sb(2) atom. In the eleventh O site, O(11) is bonded to one Li(2), one V(2), one Co(1), and one Sb(1) atom to form distorted OLiVCoSb trigonal pyramids that share  a cornercorner with one O(5)LiCo2Sb tetrahedra, corners with three equivalent O(6)LiVCoSb tetrahedra,  a cornercorner with one O(11)LiVCoSb trigonal pyramid,  a cornercorner with one O(2)LiVSb2 trigonal pyramid,  an edgeedge with one O(4)LiCoSb2 tetrahedra, and  an edgeedge with one O(11)LiVCoSb trigonal pyramid. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), and two equivalent Co(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4V2Co3Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.137
_cell_length_b   6.098
_cell_length_c   9.740
_cell_angle_alpha   89.981
_cell_angle_beta   90.799
_cell_angle_gamma   119.778
_symmetry_Int_Tables_number   1
_cell_volume   316.348
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.339  0.670  0.887  1.0
  Li  Li1  1  0.956  0.978  0.981  1.0
  Li  Li2  1  0.988  0.994  0.508  1.0
  Li  Li3  1  0.649  0.324  0.403  1.0
  V  V4  1  0.357  0.678  0.500  1.0
  V  V5  1  0.694  0.347  0.976  1.0
  Co  Co6  1  0.658  0.829  0.215  1.0
  Co  Co7  1  0.851  0.658  0.717  1.0
  Co  Co8  1  0.851  0.193  0.717  1.0
  Sb  Sb9  1  0.163  0.829  0.215  1.0
  Sb  Sb10  1  0.163  0.334  0.215  1.0
  Sb  Sb11  1  0.353  0.176  0.713  1.0
  O  O12  1  0.185  0.845  0.593  1.0
  O  O13  1  0.027  0.514  0.339  1.0
  O  O14  1  0.313  0.656  0.103  1.0
  O  O15  1  0.007  0.004  0.320  1.0
  O  O16  1  0.016  0.008  0.798  1.0
  O  O17  1  0.185  0.340  0.593  1.0
  O  O18  1  0.461  0.955  0.340  1.0
  O  O19  1  0.461  0.506  0.340  1.0
  O  O20  1  0.313  0.157  0.103  1.0
  O  O21  1  0.646  0.823  0.581  1.0
  O  O22  1  0.517  0.476  0.845  1.0
  O  O23  1  0.517  0.040  0.844  1.0
  O  O24  1  0.665  0.332  0.603  1.0
  O  O25  1  0.847  0.680  0.104  1.0
  O  O26  1  0.973  0.487  0.853  1.0
  O  O27  1  0.846  0.167  0.104  1.0
[/CIF]
.
The material structure described by Li4V2Co3Sb3O16 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent V(2)O6 octahedra, and corners with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-66°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(5), one O(7), and two equivalent O(11) atoms. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-65°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms. In the second V site, V(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, and edges with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form distorted CoO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form SbO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the second Sb site, Sb(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form SbO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with four equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one Co(2), and one Sb(2) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), and two equivalent Sb(1) atoms to form distorted OLiVSb2 trigonal pyramids that share corners with two equivalent O(4)LiCoSb2 tetrahedra, corners with two equivalent O(6)LiVCoSb tetrahedra, corners with two equivalent O(11)LiVCoSb trigonal pyramids, and edges with two equivalent O(6)LiVCoSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded to one Li(3), one Co(1), and two equivalent Sb(1) atoms to form distorted OLiCoSb2 tetrahedra that share corners with four equivalent O(6)LiVCoSb tetrahedra, corners with two equivalent O(2)LiVSb2 trigonal pyramids, and edges with two equivalent O(11)LiVCoSb trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Co(2), and one Sb(2) atom to form corner-sharing OLiCo2Sb tetrahedra. In the sixth O site, O(6) is bonded to one Li(4), one V(1), one Co(1), and one Sb(1) atom to form distorted OLiVCoSb tetrahedra that share  a cornercorner with one O(6)LiVCoSb tetrahedra, corners with two equivalent O(4)LiCoSb2 tetrahedra,  a cornercorner with one O(2)LiVSb2 trigonal pyramid, corners with three equivalent O(11)LiVCoSb trigonal pyramids,  an edgeedge with one O(6)LiVCoSb tetrahedra, and  an edgeedge with one O(2)LiVSb2 trigonal pyramid. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), and two equivalent Sb(1) atoms. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(3), one V(1), and two equivalent Co(2) atoms. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one Co(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent Co(2), and one Sb(2) atom. In the eleventh O site, O(11) is bonded to one Li(2), one V(2), one Co(1), and one Sb(1) atom to form distorted OLiVCoSb trigonal pyramids that share  a cornercorner with one O(5)LiCo2Sb tetrahedra, corners with three equivalent O(6)LiVCoSb tetrahedra,  a cornercorner with one O(11)LiVCoSb trigonal pyramid,  a cornercorner with one O(2)LiVSb2 trigonal pyramid,  an edgeedge with one O(4)LiCoSb2 tetrahedra, and  an edgeedge with one O(11)LiVCoSb trigonal pyramid. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), and two equivalent Co(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4V2Co3Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.137
_cell_length_b   6.098
_cell_length_c   9.740
_cell_angle_alpha   89.981
_cell_angle_beta   90.799
_cell_angle_gamma   119.778
_symmetry_Int_Tables_number   1
_cell_volume   316.348
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.339  0.670  0.887  1.0
  Li  Li1  1  0.956  0.978  0.981  1.0
  Li  Li2  1  0.988  0.994  0.508  1.0
  Li  Li3  1  0.649  0.324  0.403  1.0
  V  V4  1  0.357  0.678  0.500  1.0
  V  V5  1  0.694  0.347  0.976  1.0
  Co  Co6  1  0.658  0.829  0.215  1.0
  Co  Co7  1  0.851  0.658  0.717  1.0
  Co  Co8  1  0.851  0.193  0.717  1.0
  Sb  Sb9  1  0.163  0.829  0.215  1.0
  Sb  Sb10  1  0.163  0.334  0.215  1.0
  Sb  Sb11  1  0.353  0.176  0.713  1.0
  O  O12  1  0.185  0.845  0.593  1.0
  O  O13  1  0.027  0.514  0.339  1.0
  O  O14  1  0.313  0.656  0.103  1.0
  O  O15  1  0.007  0.004  0.320  1.0
  O  O16  1  0.016  0.008  0.798  1.0
  O  O17  1  0.185  0.340  0.593  1.0
  O  O18  1  0.461  0.955  0.340  1.0
  O  O19  1  0.461  0.506  0.340  1.0
  O  O20  1  0.313  0.157  0.103  1.0
  O  O21  1  0.646  0.823  0.581  1.0
  O  O22  1  0.517  0.476  0.845  1.0
  O  O23  1  0.517  0.040  0.844  1.0
  O  O24  1  0.665  0.332  0.603  1.0
  O  O25  1  0.847  0.680  0.104  1.0
  O  O26  1  0.973  0.487  0.853  1.0
  O  O27  1  0.846  0.167  0.104  1.0
[/CIF]
.