The compound described by Sr(ReO3)3 crystallizes in the orthorhombic Pnn2 space group. Sr(1) is bonded in a 9-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are four inequivalent Re sites. In the first Re site, Re(1) is bonded to two equivalent O(5), two equivalent O(8), and two equivalent O(9) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the second Re site, Re(2) is bonded to one O(2), one O(3), one O(6), one O(9), and two equivalent O(4) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 40-43°. In the third Re site, Re(3) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 40-43°. In the fourth Re site, Re(4) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 40-42°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to two equivalent Re(3) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sr(1), one Re(2), and one Re(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sr(1), one Re(2), and one Re(4) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Sr(1) and two equivalent Re(2) atoms. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Sr(1), one Re(1), and one Re(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Sr(1), one Re(2), and one Re(3) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Sr(1), one Re(3), and one Re(4) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Sr(1), one Re(1), and one Re(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Sr(1), one Re(1), and one Re(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to two equivalent Sr(1) and two equivalent Re(3) atoms. is represented by the CIF card [CIF]
data_Sr(ReO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.304
_cell_length_b   9.334
_cell_length_c   9.371
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.788
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.177  0.821  0.822  1.0
  Sr  Sr1  1  0.677  0.679  0.322  1.0
  Sr  Sr2  1  0.177  0.179  0.178  1.0
  Sr  Sr3  1  0.677  0.321  0.678  1.0
  Re  Re4  1  0.863  0.000  0.500  1.0
  Re  Re5  1  0.502  0.005  0.360  1.0
  Re  Re6  1  0.502  0.862  0.001  1.0
  Re  Re7  1  0.002  0.638  0.501  1.0
  Re  Re8  1  0.363  0.500  0.000  1.0
  Re  Re9  1  0.002  0.505  0.140  1.0
  Re  Re10  1  0.002  0.495  0.860  1.0
  Re  Re11  1  0.639  0.500  0.000  1.0
  Re  Re12  1  0.002  0.362  0.499  1.0
  Re  Re13  1  0.502  0.138  0.999  1.0
  Re  Re14  1  0.502  0.995  0.640  1.0
  Re  Re15  1  0.139  0.000  0.500  1.0
  O  O16  1  0.661  0.000  0.000  1.0
  O  O17  1  0.494  0.862  0.797  1.0
  O  O18  1  0.296  0.994  0.639  1.0
  O  O19  1  0.507  0.838  0.495  1.0
  O  O20  1  0.002  0.995  0.663  1.0
  O  O21  1  0.296  0.006  0.361  1.0
  O  O22  1  0.502  0.862  0.206  1.0
  O  O23  1  0.138  0.796  0.505  1.0
  O  O24  1  0.638  0.704  0.005  1.0
  O  O25  1  0.161  0.500  0.500  1.0
  O  O26  1  0.860  0.795  0.496  1.0
  O  O27  1  0.360  0.705  0.996  1.0
  O  O28  1  0.994  0.638  0.297  1.0
  O  O29  1  0.205  0.498  0.138  1.0
  O  O30  1  0.502  0.495  0.837  1.0
  O  O31  1  0.832  0.500  0.500  1.0
  O  O32  1  0.007  0.662  0.995  1.0
  O  O33  1  0.002  0.362  0.294  1.0
  O  O34  1  0.205  0.502  0.862  1.0
  O  O35  1  0.796  0.506  0.139  1.0
  O  O36  1  0.002  0.638  0.706  1.0
  O  O37  1  0.007  0.338  0.005  1.0
  O  O38  1  0.502  0.505  0.163  1.0
  O  O39  1  0.796  0.494  0.861  1.0
  O  O40  1  0.994  0.362  0.703  1.0
  O  O41  1  0.638  0.296  0.995  1.0
  O  O42  1  0.138  0.204  0.495  1.0
  O  O43  1  0.360  0.295  0.004  1.0
  O  O44  1  0.860  0.205  0.504  1.0
  O  O45  1  0.502  0.138  0.794  1.0
  O  O46  1  0.705  0.002  0.638  1.0
  O  O47  1  0.332  0.000  0.000  1.0
  O  O48  1  0.002  0.005  0.337  1.0
  O  O49  1  0.507  0.162  0.505  1.0
  O  O50  1  0.705  0.998  0.362  1.0
  O  O51  1  0.494  0.138  0.203  1.0
[/CIF]
.
The compound described by Sr(ReO3)3 crystallizes in the orthorhombic Pnn2 space group. Sr(1) is bonded in a 9-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are four inequivalent Re sites. In the first Re site, Re(1) is bonded to two equivalent O(5), two equivalent O(8), and two equivalent O(9) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the second Re site, Re(2) is bonded to one O(2), one O(3), one O(6), one O(9), and two equivalent O(4) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 40-43°. In the third Re site, Re(3) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 40-43°. In the fourth Re site, Re(4) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 40-42°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to two equivalent Re(3) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sr(1), one Re(2), and one Re(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sr(1), one Re(2), and one Re(4) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Sr(1) and two equivalent Re(2) atoms. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Sr(1), one Re(1), and one Re(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Sr(1), one Re(2), and one Re(3) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Sr(1), one Re(3), and one Re(4) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Sr(1), one Re(1), and one Re(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Sr(1), one Re(1), and one Re(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to two equivalent Sr(1) and two equivalent Re(3) atoms. is represented by the CIF card [CIF]
data_Sr(ReO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.304
_cell_length_b   9.334
_cell_length_c   9.371
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.788
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.177  0.821  0.822  1.0
  Sr  Sr1  1  0.677  0.679  0.322  1.0
  Sr  Sr2  1  0.177  0.179  0.178  1.0
  Sr  Sr3  1  0.677  0.321  0.678  1.0
  Re  Re4  1  0.863  0.000  0.500  1.0
  Re  Re5  1  0.502  0.005  0.360  1.0
  Re  Re6  1  0.502  0.862  0.001  1.0
  Re  Re7  1  0.002  0.638  0.501  1.0
  Re  Re8  1  0.363  0.500  0.000  1.0
  Re  Re9  1  0.002  0.505  0.140  1.0
  Re  Re10  1  0.002  0.495  0.860  1.0
  Re  Re11  1  0.639  0.500  0.000  1.0
  Re  Re12  1  0.002  0.362  0.499  1.0
  Re  Re13  1  0.502  0.138  0.999  1.0
  Re  Re14  1  0.502  0.995  0.640  1.0
  Re  Re15  1  0.139  0.000  0.500  1.0
  O  O16  1  0.661  0.000  0.000  1.0
  O  O17  1  0.494  0.862  0.797  1.0
  O  O18  1  0.296  0.994  0.639  1.0
  O  O19  1  0.507  0.838  0.495  1.0
  O  O20  1  0.002  0.995  0.663  1.0
  O  O21  1  0.296  0.006  0.361  1.0
  O  O22  1  0.502  0.862  0.206  1.0
  O  O23  1  0.138  0.796  0.505  1.0
  O  O24  1  0.638  0.704  0.005  1.0
  O  O25  1  0.161  0.500  0.500  1.0
  O  O26  1  0.860  0.795  0.496  1.0
  O  O27  1  0.360  0.705  0.996  1.0
  O  O28  1  0.994  0.638  0.297  1.0
  O  O29  1  0.205  0.498  0.138  1.0
  O  O30  1  0.502  0.495  0.837  1.0
  O  O31  1  0.832  0.500  0.500  1.0
  O  O32  1  0.007  0.662  0.995  1.0
  O  O33  1  0.002  0.362  0.294  1.0
  O  O34  1  0.205  0.502  0.862  1.0
  O  O35  1  0.796  0.506  0.139  1.0
  O  O36  1  0.002  0.638  0.706  1.0
  O  O37  1  0.007  0.338  0.005  1.0
  O  O38  1  0.502  0.505  0.163  1.0
  O  O39  1  0.796  0.494  0.861  1.0
  O  O40  1  0.994  0.362  0.703  1.0
  O  O41  1  0.638  0.296  0.995  1.0
  O  O42  1  0.138  0.204  0.495  1.0
  O  O43  1  0.360  0.295  0.004  1.0
  O  O44  1  0.860  0.205  0.504  1.0
  O  O45  1  0.502  0.138  0.794  1.0
  O  O46  1  0.705  0.002  0.638  1.0
  O  O47  1  0.332  0.000  0.000  1.0
  O  O48  1  0.002  0.005  0.337  1.0
  O  O49  1  0.507  0.162  0.505  1.0
  O  O50  1  0.705  0.998  0.362  1.0
  O  O51  1  0.494  0.138  0.203  1.0
[/CIF]
.