The structure described by CsNiPdF5 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded in a 11-coordinate geometry to three equivalent F(2) and eight equivalent F(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. Ni(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing NiF6 octahedra. The corner-sharing octahedral tilt angles are 43°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Pd(1), and one Ni(1) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to three equivalent Cs(1) and two equivalent Ni(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsNiPdF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.364
_cell_length_b   7.364
_cell_length_c   7.364
_cell_angle_alpha   126.288
_cell_angle_beta   117.975
_cell_angle_gamma   86.507
_symmetry_Int_Tables_number   1
_cell_volume   270.823
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.869  0.619  0.250  1.0
  Cs  Cs1  1  0.131  0.381  0.750  1.0
  Ni  Ni2  1  0.000  0.000  0.000  1.0
  Ni  Ni3  1  0.500  0.000  0.500  1.0
  Pd  Pd4  1  0.500  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.500  0.500  1.0
  F  F6  1  0.442  0.654  0.336  1.0
  F  F7  1  0.558  0.894  0.211  1.0
  F  F8  1  0.182  0.346  0.289  1.0
  F  F9  1  0.818  0.106  0.164  1.0
  F  F10  1  0.558  0.346  0.664  1.0
  F  F11  1  0.442  0.106  0.789  1.0
  F  F12  1  0.820  0.070  0.750  1.0
  F  F13  1  0.180  0.930  0.250  1.0
  F  F14  1  0.182  0.894  0.836  1.0
  F  F15  1  0.818  0.654  0.711  1.0
[/CIF]
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The structure described by CsNiPdF5 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded in a 11-coordinate geometry to three equivalent F(2) and eight equivalent F(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. Ni(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing NiF6 octahedra. The corner-sharing octahedral tilt angles are 43°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Pd(1), and one Ni(1) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to three equivalent Cs(1) and two equivalent Ni(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsNiPdF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.364
_cell_length_b   7.364
_cell_length_c   7.364
_cell_angle_alpha   126.288
_cell_angle_beta   117.975
_cell_angle_gamma   86.507
_symmetry_Int_Tables_number   1
_cell_volume   270.823
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.869  0.619  0.250  1.0
  Cs  Cs1  1  0.131  0.381  0.750  1.0
  Ni  Ni2  1  0.000  0.000  0.000  1.0
  Ni  Ni3  1  0.500  0.000  0.500  1.0
  Pd  Pd4  1  0.500  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.500  0.500  1.0
  F  F6  1  0.442  0.654  0.336  1.0
  F  F7  1  0.558  0.894  0.211  1.0
  F  F8  1  0.182  0.346  0.289  1.0
  F  F9  1  0.818  0.106  0.164  1.0
  F  F10  1  0.558  0.346  0.664  1.0
  F  F11  1  0.442  0.106  0.789  1.0
  F  F12  1  0.820  0.070  0.750  1.0
  F  F13  1  0.180  0.930  0.250  1.0
  F  F14  1  0.182  0.894  0.836  1.0
  F  F15  1  0.818  0.654  0.711  1.0
[/CIF]
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