The structure described by Li6V3WP6O24 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(11), one O(14), one O(18), one O(22), one O(3), and one O(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(14), one O(19), one O(3), one O(4), one O(8), and one O(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(16), one O(17), one O(20), one O(5), one O(8), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a distorted pentagonal planar geometry to one O(11), one O(16), one O(17), one O(21), and one O(6) atom. In the fifth Li site, Li(5) is bonded in a distorted pentagonal planar geometry to one O(13), one O(16), one O(20), one O(22), and one O(23) atom. In the sixth Li site, Li(6) is bonded in a distorted pentagonal planar geometry to one O(15), one O(17), one O(18), one O(20), and one O(24) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(12), one O(14), one O(19), one O(3), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third V site, V(3) is bonded to one O(16), one O(17), one O(20), one O(21), one O(23), and one O(24) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. W(1) is bonded to one O(11), one O(13), one O(15), one O(18), one O(22), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(24), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-45°. In the second P site, P(2) is bonded to one O(13), one O(21), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-44°. In the third P site, P(3) is bonded to one O(14), one O(15), one O(23), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-47°. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(16), and one O(2) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-46°. In the fifth P site, P(5) is bonded to one O(12), one O(17), one O(18), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-45°. In the sixth P site, P(6) is bonded to one O(1), one O(19), one O(20), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-43°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one V(2) and one P(6) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one P(4) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one V(2), and one P(5) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(3), one V(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(4), one W(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(2), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(4), one W(1), and one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(5) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(5), one W(1), and one P(2) atom. In the fourteenth O site, O(14) is bonded in a trigonal pyramidal geometry to one Li(1), one Li(2), one V(1), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(6), one W(1), and one P(3) atom. In the sixteenth O site, O(16) is bonded to one Li(3), one Li(4), one Li(5), one V(3), and one P(4) atom to form distorted face-sharing OLi3VP trigonal bipyramids. In the seventeenth O site, O(17) is bonded to one Li(3), one Li(4), one Li(6), one V(3), and one P(5) atom to form distorted face-sharing OLi3VP trigonal bipyramids. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one W(1), and one P(5) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(2), one V(1), and one P(6) atom. In the twentieth O site, O(20) is bonded in a 5-coordinate geometry to one Li(3), one Li(5), one Li(6), one V(3), and one P(6) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(4), one V(3), and one P(2) atom. In the twenty-second O site, O(22) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(5), one W(1), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(5), one V(3), and one P(3) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(6), one V(3), and one P(1) atom. is represented by the CIF file [CIF]
data_Li6V3P6WO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.646
_cell_length_b   8.649
_cell_length_c   8.662
_cell_angle_alpha   62.242
_cell_angle_beta   62.031
_cell_angle_gamma   61.973
_symmetry_Int_Tables_number   1
_cell_volume   479.338
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.027  0.006  1.000  1.0
  Li  Li1  1  0.754  0.148  0.345  1.0
  Li  Li2  1  0.474  0.505  0.493  1.0
  Li  Li3  1  0.271  0.837  0.647  1.0
  Li  Li4  1  0.650  0.271  0.834  1.0
  Li  Li5  1  0.832  0.650  0.274  1.0
  V  V6  1  0.141  0.146  0.138  1.0
  V  V7  1  0.357  0.360  0.354  1.0
  V  V8  1  0.644  0.650  0.648  1.0
  P  P9  1  0.052  0.751  0.442  1.0
  P  P10  1  0.445  0.056  0.750  1.0
  P  P11  1  0.750  0.446  0.051  1.0
  P  P12  1  0.258  0.537  0.956  1.0
  P  P13  1  0.539  0.961  0.258  1.0
  P  P14  1  0.954  0.256  0.533  1.0
  W  W15  1  0.857  0.854  0.855  1.0
  O  O16  1  0.124  0.298  0.488  1.0
  O  O17  1  0.316  0.500  0.113  1.0
  O  O18  1  0.049  0.918  0.263  1.0
  O  O19  1  0.527  0.117  0.307  1.0
  O  O20  1  0.238  0.592  0.419  1.0
  O  O21  1  0.033  0.805  0.599  1.0
  O  O22  1  0.258  0.070  0.908  1.0
  O  O23  1  0.438  0.236  0.583  1.0
  O  O24  1  0.597  0.421  0.243  1.0
  O  O25  1  0.193  0.386  0.988  1.0
  O  O26  1  0.109  0.735  0.925  1.0
  O  O27  1  0.374  0.008  0.205  1.0
  O  O28  1  0.601  0.031  0.808  1.0
  O  O29  1  0.904  0.253  0.072  1.0
  O  O30  1  0.810  0.599  0.028  1.0
  O  O31  1  0.421  0.555  0.766  1.0
  O  O32  1  0.549  0.774  0.421  1.0
  O  O33  1  0.732  0.922  0.107  1.0
  O  O34  1  0.968  0.198  0.382  1.0
  O  O35  1  0.768  0.423  0.553  1.0
  O  O36  1  0.484  0.891  0.693  1.0
  O  O37  1  0.924  0.107  0.729  1.0
  O  O38  1  0.694  0.483  0.889  1.0
  O  O39  1  0.885  0.696  0.484  1.0
[/CIF]
.
The structure described by Li6V3WP6O24 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(11), one O(14), one O(18), one O(22), one O(3), and one O(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(14), one O(19), one O(3), one O(4), one O(8), and one O(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(16), one O(17), one O(20), one O(5), one O(8), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a distorted pentagonal planar geometry to one O(11), one O(16), one O(17), one O(21), and one O(6) atom. In the fifth Li site, Li(5) is bonded in a distorted pentagonal planar geometry to one O(13), one O(16), one O(20), one O(22), and one O(23) atom. In the sixth Li site, Li(6) is bonded in a distorted pentagonal planar geometry to one O(15), one O(17), one O(18), one O(20), and one O(24) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(12), one O(14), one O(19), one O(3), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third V site, V(3) is bonded to one O(16), one O(17), one O(20), one O(21), one O(23), and one O(24) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. W(1) is bonded to one O(11), one O(13), one O(15), one O(18), one O(22), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(24), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-45°. In the second P site, P(2) is bonded to one O(13), one O(21), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-44°. In the third P site, P(3) is bonded to one O(14), one O(15), one O(23), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-47°. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(16), and one O(2) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-46°. In the fifth P site, P(5) is bonded to one O(12), one O(17), one O(18), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-45°. In the sixth P site, P(6) is bonded to one O(1), one O(19), one O(20), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-43°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one V(2) and one P(6) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one P(4) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one V(2), and one P(5) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(3), one V(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(4), one W(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(2), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(4), one W(1), and one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(5) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(5), one W(1), and one P(2) atom. In the fourteenth O site, O(14) is bonded in a trigonal pyramidal geometry to one Li(1), one Li(2), one V(1), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(6), one W(1), and one P(3) atom. In the sixteenth O site, O(16) is bonded to one Li(3), one Li(4), one Li(5), one V(3), and one P(4) atom to form distorted face-sharing OLi3VP trigonal bipyramids. In the seventeenth O site, O(17) is bonded to one Li(3), one Li(4), one Li(6), one V(3), and one P(5) atom to form distorted face-sharing OLi3VP trigonal bipyramids. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one W(1), and one P(5) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(2), one V(1), and one P(6) atom. In the twentieth O site, O(20) is bonded in a 5-coordinate geometry to one Li(3), one Li(5), one Li(6), one V(3), and one P(6) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(4), one V(3), and one P(2) atom. In the twenty-second O site, O(22) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(5), one W(1), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(5), one V(3), and one P(3) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(6), one V(3), and one P(1) atom. is represented by the CIF file [CIF]
data_Li6V3P6WO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.646
_cell_length_b   8.649
_cell_length_c   8.662
_cell_angle_alpha   62.242
_cell_angle_beta   62.031
_cell_angle_gamma   61.973
_symmetry_Int_Tables_number   1
_cell_volume   479.338
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.027  0.006  1.000  1.0
  Li  Li1  1  0.754  0.148  0.345  1.0
  Li  Li2  1  0.474  0.505  0.493  1.0
  Li  Li3  1  0.271  0.837  0.647  1.0
  Li  Li4  1  0.650  0.271  0.834  1.0
  Li  Li5  1  0.832  0.650  0.274  1.0
  V  V6  1  0.141  0.146  0.138  1.0
  V  V7  1  0.357  0.360  0.354  1.0
  V  V8  1  0.644  0.650  0.648  1.0
  P  P9  1  0.052  0.751  0.442  1.0
  P  P10  1  0.445  0.056  0.750  1.0
  P  P11  1  0.750  0.446  0.051  1.0
  P  P12  1  0.258  0.537  0.956  1.0
  P  P13  1  0.539  0.961  0.258  1.0
  P  P14  1  0.954  0.256  0.533  1.0
  W  W15  1  0.857  0.854  0.855  1.0
  O  O16  1  0.124  0.298  0.488  1.0
  O  O17  1  0.316  0.500  0.113  1.0
  O  O18  1  0.049  0.918  0.263  1.0
  O  O19  1  0.527  0.117  0.307  1.0
  O  O20  1  0.238  0.592  0.419  1.0
  O  O21  1  0.033  0.805  0.599  1.0
  O  O22  1  0.258  0.070  0.908  1.0
  O  O23  1  0.438  0.236  0.583  1.0
  O  O24  1  0.597  0.421  0.243  1.0
  O  O25  1  0.193  0.386  0.988  1.0
  O  O26  1  0.109  0.735  0.925  1.0
  O  O27  1  0.374  0.008  0.205  1.0
  O  O28  1  0.601  0.031  0.808  1.0
  O  O29  1  0.904  0.253  0.072  1.0
  O  O30  1  0.810  0.599  0.028  1.0
  O  O31  1  0.421  0.555  0.766  1.0
  O  O32  1  0.549  0.774  0.421  1.0
  O  O33  1  0.732  0.922  0.107  1.0
  O  O34  1  0.968  0.198  0.382  1.0
  O  O35  1  0.768  0.423  0.553  1.0
  O  O36  1  0.484  0.891  0.693  1.0
  O  O37  1  0.924  0.107  0.729  1.0
  O  O38  1  0.694  0.483  0.889  1.0
  O  O39  1  0.885  0.696  0.484  1.0
[/CIF]
.