The structure described by BiVO4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.468
_cell_length_b   6.468
_cell_length_c   6.149
_cell_angle_alpha   77.664
_cell_angle_beta   77.664
_cell_angle_gamma   121.669
_symmetry_Int_Tables_number   1
_cell_volume   196.762
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.399  0.601  0.750  1.0
  V  V1  1  0.601  0.399  0.250  1.0
  Bi  Bi2  1  0.106  0.894  0.750  1.0
  Bi  Bi3  1  0.894  0.106  0.250  1.0
  O  O4  1  0.796  0.753  0.148  1.0
  O  O5  1  0.247  0.204  0.352  1.0
  O  O6  1  0.204  0.247  0.852  1.0
  O  O7  1  0.753  0.796  0.648  1.0
  O  O8  1  0.740  0.357  0.012  1.0
  O  O9  1  0.643  0.260  0.488  1.0
  O  O10  1  0.260  0.643  0.988  1.0
  O  O11  1  0.357  0.740  0.512  1.0
[/CIF]
.
The structure described by BiVO4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.468
_cell_length_b   6.468
_cell_length_c   6.149
_cell_angle_alpha   77.664
_cell_angle_beta   77.664
_cell_angle_gamma   121.669
_symmetry_Int_Tables_number   1
_cell_volume   196.762
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.399  0.601  0.750  1.0
  V  V1  1  0.601  0.399  0.250  1.0
  Bi  Bi2  1  0.106  0.894  0.750  1.0
  Bi  Bi3  1  0.894  0.106  0.250  1.0
  O  O4  1  0.796  0.753  0.148  1.0
  O  O5  1  0.247  0.204  0.352  1.0
  O  O6  1  0.204  0.247  0.852  1.0
  O  O7  1  0.753  0.796  0.648  1.0
  O  O8  1  0.740  0.357  0.012  1.0
  O  O9  1  0.643  0.260  0.488  1.0
  O  O10  1  0.260  0.643  0.988  1.0
  O  O11  1  0.357  0.740  0.512  1.0
[/CIF]
.