The crystal structure described by Tc2C4NO8C4N is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two C4N clusters and two Tc2C4NO8 clusters. In each C4N cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(2), and one N(1) atom. In the second C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. N(1) is bonded in a 4-coordinate geometry to two equivalent C(1) and two equivalent C(2) atoms. In each Tc2C4NO8 cluster, Tc(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are two inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one O(4) atom. In the second C site, C(4) is bonded in a distorted linear geometry to one C(3) and one N(2) atom. N(2) is bonded in a bent 120 degrees geometry to two equivalent C(4) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Tc(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(3) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Tc(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TcC4NO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.085
_cell_length_b   11.411
_cell_length_c   14.370
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   833.822
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.441  0.254  0.733  1.0
  Tc  Tc1  1  0.441  0.746  0.267  1.0
  Tc  Tc2  1  0.559  0.754  0.767  1.0
  Tc  Tc3  1  0.559  0.246  0.233  1.0
  C  C4  1  0.054  0.909  0.560  1.0
  C  C5  1  0.054  0.091  0.440  1.0
  C  C6  1  0.946  0.409  0.940  1.0
  C  C7  1  0.946  0.591  0.060  1.0
  C  C8  1  0.814  0.061  0.491  1.0
  C  C9  1  0.814  0.939  0.509  1.0
  C  C10  1  0.186  0.561  0.009  1.0
  C  C11  1  0.186  0.439  0.991  1.0
  C  C12  1  0.866  0.607  0.622  1.0
  C  C13  1  0.866  0.393  0.378  1.0
  C  C14  1  0.134  0.107  0.878  1.0
  C  C15  1  0.134  0.893  0.122  1.0
  C  C16  1  0.001  0.556  0.564  1.0
  C  C17  1  0.001  0.444  0.436  1.0
  C  C18  1  0.999  0.056  0.936  1.0
  C  C19  1  0.999  0.944  0.064  1.0
  N  N20  1  0.118  0.000  0.500  1.0
  N  N21  1  0.882  0.500  0.000  1.0
  N  N22  1  0.132  0.500  0.500  1.0
  N  N23  1  0.868  0.000  0.000  1.0
  O  O24  1  0.774  0.228  0.732  1.0
  O  O25  1  0.774  0.772  0.268  1.0
  O  O26  1  0.226  0.728  0.768  1.0
  O  O27  1  0.226  0.272  0.232  1.0
  O  O28  1  0.319  0.228  0.624  1.0
  O  O29  1  0.319  0.772  0.376  1.0
  O  O30  1  0.681  0.728  0.876  1.0
  O  O31  1  0.681  0.272  0.124  1.0
  O  O32  1  0.386  0.398  0.763  1.0
  O  O33  1  0.386  0.602  0.237  1.0
  O  O34  1  0.614  0.898  0.737  1.0
  O  O35  1  0.614  0.102  0.263  1.0
  O  O36  1  0.307  0.150  0.825  1.0
  O  O37  1  0.307  0.850  0.175  1.0
  O  O38  1  0.693  0.650  0.675  1.0
  O  O39  1  0.693  0.350  0.325  1.0
[/CIF]
.
The crystal structure described by Tc2C4NO8C4N is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two C4N clusters and two Tc2C4NO8 clusters. In each C4N cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(2), and one N(1) atom. In the second C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. N(1) is bonded in a 4-coordinate geometry to two equivalent C(1) and two equivalent C(2) atoms. In each Tc2C4NO8 cluster, Tc(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are two inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one O(4) atom. In the second C site, C(4) is bonded in a distorted linear geometry to one C(3) and one N(2) atom. N(2) is bonded in a bent 120 degrees geometry to two equivalent C(4) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Tc(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(3) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Tc(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TcC4NO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.085
_cell_length_b   11.411
_cell_length_c   14.370
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   833.822
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.441  0.254  0.733  1.0
  Tc  Tc1  1  0.441  0.746  0.267  1.0
  Tc  Tc2  1  0.559  0.754  0.767  1.0
  Tc  Tc3  1  0.559  0.246  0.233  1.0
  C  C4  1  0.054  0.909  0.560  1.0
  C  C5  1  0.054  0.091  0.440  1.0
  C  C6  1  0.946  0.409  0.940  1.0
  C  C7  1  0.946  0.591  0.060  1.0
  C  C8  1  0.814  0.061  0.491  1.0
  C  C9  1  0.814  0.939  0.509  1.0
  C  C10  1  0.186  0.561  0.009  1.0
  C  C11  1  0.186  0.439  0.991  1.0
  C  C12  1  0.866  0.607  0.622  1.0
  C  C13  1  0.866  0.393  0.378  1.0
  C  C14  1  0.134  0.107  0.878  1.0
  C  C15  1  0.134  0.893  0.122  1.0
  C  C16  1  0.001  0.556  0.564  1.0
  C  C17  1  0.001  0.444  0.436  1.0
  C  C18  1  0.999  0.056  0.936  1.0
  C  C19  1  0.999  0.944  0.064  1.0
  N  N20  1  0.118  0.000  0.500  1.0
  N  N21  1  0.882  0.500  0.000  1.0
  N  N22  1  0.132  0.500  0.500  1.0
  N  N23  1  0.868  0.000  0.000  1.0
  O  O24  1  0.774  0.228  0.732  1.0
  O  O25  1  0.774  0.772  0.268  1.0
  O  O26  1  0.226  0.728  0.768  1.0
  O  O27  1  0.226  0.272  0.232  1.0
  O  O28  1  0.319  0.228  0.624  1.0
  O  O29  1  0.319  0.772  0.376  1.0
  O  O30  1  0.681  0.728  0.876  1.0
  O  O31  1  0.681  0.272  0.124  1.0
  O  O32  1  0.386  0.398  0.763  1.0
  O  O33  1  0.386  0.602  0.237  1.0
  O  O34  1  0.614  0.898  0.737  1.0
  O  O35  1  0.614  0.102  0.263  1.0
  O  O36  1  0.307  0.150  0.825  1.0
  O  O37  1  0.307  0.850  0.175  1.0
  O  O38  1  0.693  0.650  0.675  1.0
  O  O39  1  0.693  0.350  0.325  1.0
[/CIF]
.