The structure described by Ge2P2SO12 crystallizes in the monoclinic Cc space group. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form GeO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. In the second Ge site, Ge(2) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom to form GeO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Ge(1)O6 octahedra and corners with two equivalent Ge(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-35°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Ge(1)O6 octahedra and corners with two equivalent Ge(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-31°. S(1) is bonded to one O(11), one O(2), one O(6), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent Ge(1)O6 octahedra and corners with two equivalent Ge(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-33°. There are twelve inequivalent O sites. In the first O site, O(7) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(2) atom. In the third O site, O(9) is bonded in a bent 150 degrees geometry to one Ge(1) and one S(1) atom. In the fourth O site, O(10) is bonded in a bent 150 degrees geometry to one Ge(2) and one P(1) atom. In the fifth O site, O(11) is bonded in a bent 150 degrees geometry to one Ge(2) and one S(1) atom. In the sixth O site, O(12) is bonded in a bent 150 degrees geometry to one Ge(2) and one P(2) atom. In the seventh O site, O(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(1) atom. In the eighth O site, O(2) is bonded in a bent 150 degrees geometry to one Ge(1) and one S(1) atom. In the ninth O site, O(3) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(2) atom. In the tenth O site, O(4) is bonded in a bent 150 degrees geometry to one Ge(2) and one P(1) atom. In the eleventh O site, O(5) is bonded in a bent 150 degrees geometry to one Ge(2) and one P(2) atom. In the twelfth O site, O(6) is bonded in a bent 150 degrees geometry to one Ge(2) and one S(1) atom. is represented by the CIF card [CIF]
data_Ge2P2SO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.305
_cell_length_b   8.321
_cell_length_c   8.637
_cell_angle_alpha   118.636
_cell_angle_beta   90.000
_cell_angle_gamma   119.935
_symmetry_Int_Tables_number   1
_cell_volume   430.938
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.354  0.710  0.063  1.0
  Ge  Ge1  1  0.857  0.710  0.563  1.0
  Ge  Ge2  1  0.636  0.296  0.936  1.0
  Ge  Ge3  1  0.160  0.296  0.436  1.0
  O  O4  1  0.513  0.656  0.924  1.0
  O  O5  1  0.132  0.399  0.917  1.0
  O  O6  1  0.268  0.781  0.924  1.0
  O  O7  1  0.013  0.781  0.424  1.0
  O  O8  1  0.767  0.399  0.417  1.0
  O  O9  1  0.643  0.656  0.424  1.0
  O  O10  1  0.484  0.344  0.078  1.0
  O  O11  1  0.859  0.587  0.076  1.0
  O  O12  1  0.733  0.215  0.082  1.0
  O  O13  1  0.982  0.215  0.582  1.0
  O  O14  1  0.228  0.587  0.576  1.0
  O  O15  1  0.359  0.344  0.578  1.0
  O  O16  1  0.433  0.655  0.222  1.0
  O  O17  1  0.221  0.790  0.223  1.0
  O  O18  1  0.577  0.014  0.229  1.0
  O  O19  1  0.936  0.014  0.729  1.0
  O  O20  1  0.069  0.790  0.723  1.0
  O  O21  1  0.722  0.655  0.722  1.0
  O  O22  1  0.568  0.346  0.773  1.0
  O  O23  1  0.783  0.207  0.774  1.0
  O  O24  1  0.434  0.997  0.778  1.0
  O  O25  1  0.063  0.997  0.278  1.0
  O  O26  1  0.924  0.207  0.274  1.0
  O  O27  1  0.278  0.346  0.273  1.0
  P  P28  1  0.541  0.504  0.751  1.0
  P  P29  1  0.251  0.789  0.750  1.0
  P  P30  1  0.038  0.789  0.250  1.0
  P  P31  1  0.463  0.504  0.251  1.0
  S  S32  1  0.959  0.210  0.749  1.0
  S  S33  1  0.751  0.210  0.249  1.0
[/CIF]
.
The structure described by Ge2P2SO12 crystallizes in the monoclinic Cc space group. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form GeO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. In the second Ge site, Ge(2) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom to form GeO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Ge(1)O6 octahedra and corners with two equivalent Ge(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-35°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Ge(1)O6 octahedra and corners with two equivalent Ge(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-31°. S(1) is bonded to one O(11), one O(2), one O(6), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent Ge(1)O6 octahedra and corners with two equivalent Ge(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-33°. There are twelve inequivalent O sites. In the first O site, O(7) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(2) atom. In the third O site, O(9) is bonded in a bent 150 degrees geometry to one Ge(1) and one S(1) atom. In the fourth O site, O(10) is bonded in a bent 150 degrees geometry to one Ge(2) and one P(1) atom. In the fifth O site, O(11) is bonded in a bent 150 degrees geometry to one Ge(2) and one S(1) atom. In the sixth O site, O(12) is bonded in a bent 150 degrees geometry to one Ge(2) and one P(2) atom. In the seventh O site, O(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(1) atom. In the eighth O site, O(2) is bonded in a bent 150 degrees geometry to one Ge(1) and one S(1) atom. In the ninth O site, O(3) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(2) atom. In the tenth O site, O(4) is bonded in a bent 150 degrees geometry to one Ge(2) and one P(1) atom. In the eleventh O site, O(5) is bonded in a bent 150 degrees geometry to one Ge(2) and one P(2) atom. In the twelfth O site, O(6) is bonded in a bent 150 degrees geometry to one Ge(2) and one S(1) atom. is represented by the CIF card [CIF]
data_Ge2P2SO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.305
_cell_length_b   8.321
_cell_length_c   8.637
_cell_angle_alpha   118.636
_cell_angle_beta   90.000
_cell_angle_gamma   119.935
_symmetry_Int_Tables_number   1
_cell_volume   430.938
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.354  0.710  0.063  1.0
  Ge  Ge1  1  0.857  0.710  0.563  1.0
  Ge  Ge2  1  0.636  0.296  0.936  1.0
  Ge  Ge3  1  0.160  0.296  0.436  1.0
  O  O4  1  0.513  0.656  0.924  1.0
  O  O5  1  0.132  0.399  0.917  1.0
  O  O6  1  0.268  0.781  0.924  1.0
  O  O7  1  0.013  0.781  0.424  1.0
  O  O8  1  0.767  0.399  0.417  1.0
  O  O9  1  0.643  0.656  0.424  1.0
  O  O10  1  0.484  0.344  0.078  1.0
  O  O11  1  0.859  0.587  0.076  1.0
  O  O12  1  0.733  0.215  0.082  1.0
  O  O13  1  0.982  0.215  0.582  1.0
  O  O14  1  0.228  0.587  0.576  1.0
  O  O15  1  0.359  0.344  0.578  1.0
  O  O16  1  0.433  0.655  0.222  1.0
  O  O17  1  0.221  0.790  0.223  1.0
  O  O18  1  0.577  0.014  0.229  1.0
  O  O19  1  0.936  0.014  0.729  1.0
  O  O20  1  0.069  0.790  0.723  1.0
  O  O21  1  0.722  0.655  0.722  1.0
  O  O22  1  0.568  0.346  0.773  1.0
  O  O23  1  0.783  0.207  0.774  1.0
  O  O24  1  0.434  0.997  0.778  1.0
  O  O25  1  0.063  0.997  0.278  1.0
  O  O26  1  0.924  0.207  0.274  1.0
  O  O27  1  0.278  0.346  0.273  1.0
  P  P28  1  0.541  0.504  0.751  1.0
  P  P29  1  0.251  0.789  0.750  1.0
  P  P30  1  0.038  0.789  0.250  1.0
  P  P31  1  0.463  0.504  0.251  1.0
  S  S32  1  0.959  0.210  0.749  1.0
  S  S33  1  0.751  0.210  0.249  1.0
[/CIF]
.