The material described by FeCl4FeO3Cl2O2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules, four tetrachloroferrat(iii) molecules, and four FeO3Cl2 clusters. In each FeO3Cl2 cluster, Fe(2) is bonded in a distorted trigonal bipyramidal geometry to one O(3), one O(4), one O(5), one Cl(5), and one Cl(6) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Fe(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Fe(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Fe(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Fe(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Fe(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Fe2Cl6O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.707
_cell_length_b   13.190
_cell_length_c   15.158
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1340.895
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.511  0.018  0.757  1.0
  Fe  Fe1  1  0.489  0.982  0.257  1.0
  Fe  Fe2  1  0.511  0.482  0.257  1.0
  Fe  Fe3  1  0.489  0.518  0.757  1.0
  Fe  Fe4  1  0.938  0.726  0.471  1.0
  Fe  Fe5  1  0.062  0.274  0.971  1.0
  Fe  Fe6  1  0.938  0.774  0.971  1.0
  Fe  Fe7  1  0.062  0.226  0.471  1.0
  Cl  Cl8  1  0.840  0.028  0.779  1.0
  Cl  Cl9  1  0.160  0.972  0.279  1.0
  Cl  Cl10  1  0.840  0.472  0.279  1.0
  Cl  Cl11  1  0.160  0.528  0.779  1.0
  Cl  Cl12  1  0.394  0.173  0.745  1.0
  Cl  Cl13  1  0.606  0.827  0.245  1.0
  Cl  Cl14  1  0.394  0.327  0.245  1.0
  Cl  Cl15  1  0.606  0.673  0.745  1.0
  Cl  Cl16  1  0.371  0.946  0.874  1.0
  Cl  Cl17  1  0.629  0.054  0.374  1.0
  Cl  Cl18  1  0.371  0.554  0.374  1.0
  Cl  Cl19  1  0.629  0.446  0.874  1.0
  Cl  Cl20  1  0.444  0.922  0.642  1.0
  Cl  Cl21  1  0.556  0.078  0.142  1.0
  Cl  Cl22  1  0.444  0.578  0.142  1.0
  Cl  Cl23  1  0.556  0.422  0.642  1.0
  Cl  Cl24  1  0.207  0.653  0.535  1.0
  Cl  Cl25  1  0.793  0.347  0.035  1.0
  Cl  Cl26  1  0.207  0.847  0.035  1.0
  Cl  Cl27  1  0.793  0.153  0.535  1.0
  Cl  Cl28  1  0.088  0.873  0.472  1.0
  Cl  Cl29  1  0.912  0.127  0.972  1.0
  Cl  Cl30  1  0.088  0.627  0.972  1.0
  Cl  Cl31  1  0.912  0.373  0.472  1.0
  O  O32  1  0.953  0.265  0.691  1.0
  O  O33  1  0.047  0.735  0.191  1.0
  O  O34  1  0.953  0.235  0.191  1.0
  O  O35  1  0.047  0.765  0.691  1.0
  O  O36  1  0.939  0.832  0.664  1.0
  O  O37  1  0.061  0.168  0.164  1.0
  O  O38  1  0.939  0.668  0.164  1.0
  O  O39  1  0.061  0.332  0.664  1.0
  O  O40  1  0.785  0.662  0.541  1.0
  O  O41  1  0.215  0.338  0.041  1.0
  O  O42  1  0.785  0.838  0.041  1.0
  O  O43  1  0.215  0.162  0.541  1.0
  O  O44  1  0.945  0.681  0.371  1.0
  O  O45  1  0.055  0.319  0.871  1.0
  O  O46  1  0.945  0.819  0.871  1.0
  O  O47  1  0.055  0.181  0.371  1.0
  O  O48  1  0.700  0.788  0.461  1.0
  O  O49  1  0.300  0.212  0.961  1.0
  O  O50  1  0.700  0.712  0.961  1.0
  O  O51  1  0.300  0.288  0.461  1.0
[/CIF]
.
The material described by FeCl4FeO3Cl2O2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules, four tetrachloroferrat(iii) molecules, and four FeO3Cl2 clusters. In each FeO3Cl2 cluster, Fe(2) is bonded in a distorted trigonal bipyramidal geometry to one O(3), one O(4), one O(5), one Cl(5), and one Cl(6) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Fe(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Fe(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Fe(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Fe(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Fe(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Fe2Cl6O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.707
_cell_length_b   13.190
_cell_length_c   15.158
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1340.895
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.511  0.018  0.757  1.0
  Fe  Fe1  1  0.489  0.982  0.257  1.0
  Fe  Fe2  1  0.511  0.482  0.257  1.0
  Fe  Fe3  1  0.489  0.518  0.757  1.0
  Fe  Fe4  1  0.938  0.726  0.471  1.0
  Fe  Fe5  1  0.062  0.274  0.971  1.0
  Fe  Fe6  1  0.938  0.774  0.971  1.0
  Fe  Fe7  1  0.062  0.226  0.471  1.0
  Cl  Cl8  1  0.840  0.028  0.779  1.0
  Cl  Cl9  1  0.160  0.972  0.279  1.0
  Cl  Cl10  1  0.840  0.472  0.279  1.0
  Cl  Cl11  1  0.160  0.528  0.779  1.0
  Cl  Cl12  1  0.394  0.173  0.745  1.0
  Cl  Cl13  1  0.606  0.827  0.245  1.0
  Cl  Cl14  1  0.394  0.327  0.245  1.0
  Cl  Cl15  1  0.606  0.673  0.745  1.0
  Cl  Cl16  1  0.371  0.946  0.874  1.0
  Cl  Cl17  1  0.629  0.054  0.374  1.0
  Cl  Cl18  1  0.371  0.554  0.374  1.0
  Cl  Cl19  1  0.629  0.446  0.874  1.0
  Cl  Cl20  1  0.444  0.922  0.642  1.0
  Cl  Cl21  1  0.556  0.078  0.142  1.0
  Cl  Cl22  1  0.444  0.578  0.142  1.0
  Cl  Cl23  1  0.556  0.422  0.642  1.0
  Cl  Cl24  1  0.207  0.653  0.535  1.0
  Cl  Cl25  1  0.793  0.347  0.035  1.0
  Cl  Cl26  1  0.207  0.847  0.035  1.0
  Cl  Cl27  1  0.793  0.153  0.535  1.0
  Cl  Cl28  1  0.088  0.873  0.472  1.0
  Cl  Cl29  1  0.912  0.127  0.972  1.0
  Cl  Cl30  1  0.088  0.627  0.972  1.0
  Cl  Cl31  1  0.912  0.373  0.472  1.0
  O  O32  1  0.953  0.265  0.691  1.0
  O  O33  1  0.047  0.735  0.191  1.0
  O  O34  1  0.953  0.235  0.191  1.0
  O  O35  1  0.047  0.765  0.691  1.0
  O  O36  1  0.939  0.832  0.664  1.0
  O  O37  1  0.061  0.168  0.164  1.0
  O  O38  1  0.939  0.668  0.164  1.0
  O  O39  1  0.061  0.332  0.664  1.0
  O  O40  1  0.785  0.662  0.541  1.0
  O  O41  1  0.215  0.338  0.041  1.0
  O  O42  1  0.785  0.838  0.041  1.0
  O  O43  1  0.215  0.162  0.541  1.0
  O  O44  1  0.945  0.681  0.371  1.0
  O  O45  1  0.055  0.319  0.871  1.0
  O  O46  1  0.945  0.819  0.871  1.0
  O  O47  1  0.055  0.181  0.371  1.0
  O  O48  1  0.700  0.788  0.461  1.0
  O  O49  1  0.300  0.212  0.961  1.0
  O  O50  1  0.700  0.712  0.961  1.0
  O  O51  1  0.300  0.288  0.461  1.0
[/CIF]
.