The compound described by LiNd2(HO)6 crystallizes in the triclinic P-1 space group. Li(1) is bonded in an octahedral geometry to two equivalent H(1), two equivalent H(2), and two equivalent H(3) atoms. Nd(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one Li(1) and one O(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one Li(1) and one O(2) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one Li(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Nd(1) and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Nd(1) and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Nd(1) and one H(3) atom. is represented by the CIF file [CIF]
data_LiNd2(HO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.574
_cell_length_b   6.621
_cell_length_c   3.811
_cell_angle_alpha   89.843
_cell_angle_beta   90.015
_cell_angle_gamma   120.766
_symmetry_Int_Tables_number   1
_cell_volume   142.503
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.500  1.0
  Nd  Nd1  1  0.335  0.668  0.260  1.0
  Nd  Nd2  1  0.665  0.332  0.740  1.0
  H  H3  1  0.893  0.723  0.162  1.0
  H  H4  1  0.835  0.115  0.158  1.0
  H  H5  1  0.266  0.168  0.149  1.0
  H  H6  1  0.107  0.277  0.838  1.0
  H  H7  1  0.165  0.885  0.842  1.0
  H  H8  1  0.734  0.832  0.851  1.0
  O  O9  1  0.918  0.598  0.253  1.0
  O  O10  1  0.682  0.084  0.256  1.0
  O  O11  1  0.392  0.315  0.259  1.0
  O  O12  1  0.082  0.402  0.747  1.0
  O  O13  1  0.318  0.916  0.744  1.0
  O  O14  1  0.608  0.685  0.741  1.0
[/CIF]
.
The compound described by LiNd2(HO)6 crystallizes in the triclinic P-1 space group. Li(1) is bonded in an octahedral geometry to two equivalent H(1), two equivalent H(2), and two equivalent H(3) atoms. Nd(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one Li(1) and one O(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one Li(1) and one O(2) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one Li(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Nd(1) and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Nd(1) and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Nd(1) and one H(3) atom. is represented by the CIF file [CIF]
data_LiNd2(HO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.574
_cell_length_b   6.621
_cell_length_c   3.811
_cell_angle_alpha   89.843
_cell_angle_beta   90.015
_cell_angle_gamma   120.766
_symmetry_Int_Tables_number   1
_cell_volume   142.503
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.500  1.0
  Nd  Nd1  1  0.335  0.668  0.260  1.0
  Nd  Nd2  1  0.665  0.332  0.740  1.0
  H  H3  1  0.893  0.723  0.162  1.0
  H  H4  1  0.835  0.115  0.158  1.0
  H  H5  1  0.266  0.168  0.149  1.0
  H  H6  1  0.107  0.277  0.838  1.0
  H  H7  1  0.165  0.885  0.842  1.0
  H  H8  1  0.734  0.832  0.851  1.0
  O  O9  1  0.918  0.598  0.253  1.0
  O  O10  1  0.682  0.084  0.256  1.0
  O  O11  1  0.392  0.315  0.259  1.0
  O  O12  1  0.082  0.402  0.747  1.0
  O  O13  1  0.318  0.916  0.744  1.0
  O  O14  1  0.608  0.685  0.741  1.0
[/CIF]
.