The compound described by Rb5In(MoO4)4 crystallizes in the monoclinic P2/c space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(7), two equivalent O(1), and two equivalent O(6) atoms. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to one O(1), one O(4), one O(5), two equivalent O(7), two equivalent O(8), and three equivalent O(3) atoms. In the third Rb site, Rb(3) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(7), and two equivalent O(8) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(2), one O(4), one O(7), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 44°. In the second Mo site, Mo(2) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-44°. In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form InO6 octahedra that share corners with two equivalent Mo(1)O4 tetrahedra and corners with four equivalent Mo(2)O4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Mo(1) atom. In the second O site, O(5) is bonded in a 2-coordinate geometry to one Rb(1), one Rb(2), one Mo(2), and one In(1) atom. In the third O site, O(6) is bonded in a 1-coordinate geometry to two equivalent Rb(1) and one Mo(2) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), two equivalent Rb(2), and one Mo(1) atom. In the fifth O site, O(8) is bonded in a 4-coordinate geometry to one Rb(3), two equivalent Rb(2), and one Mo(1) atom. In the sixth O site, O(1) is bonded in a 2-coordinate geometry to one Rb(2), two equivalent Rb(1), one Mo(2), and one In(1) atom. In the seventh O site, O(2) is bonded in a 2-coordinate geometry to one Rb(1), one Mo(1), and one In(1) atom. In the eighth O site, O(3) is bonded in a distorted single-bond geometry to one Rb(3), three equivalent Rb(2), and one Mo(2) atom. is represented by the CIF card [CIF]
data_Rb5In(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.998
_cell_length_b   11.075
_cell_length_c   11.414
_cell_angle_alpha   66.226
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   925.164
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.345  0.845  0.104  1.0
  Rb  Rb1  1  0.655  0.155  0.896  1.0
  Rb  Rb2  1  0.345  0.655  0.896  1.0
  Rb  Rb3  1  0.655  0.345  0.104  1.0
  Rb  Rb4  1  0.869  0.356  0.591  1.0
  Rb  Rb5  1  0.131  0.644  0.409  1.0
  Rb  Rb6  1  0.869  0.144  0.409  1.0
  Rb  Rb7  1  0.131  0.856  0.591  1.0
  Rb  Rb8  1  0.611  0.750  0.500  1.0
  Rb  Rb9  1  0.389  0.250  0.500  1.0
  In  In10  1  0.915  0.750  0.000  1.0
  In  In11  1  0.085  0.250  0.000  1.0
  Mo  Mo12  1  0.659  0.558  0.283  1.0
  Mo  Mo13  1  0.341  0.442  0.717  1.0
  Mo  Mo14  1  0.659  0.942  0.717  1.0
  Mo  Mo15  1  0.341  0.058  0.283  1.0
  Mo  Mo16  1  0.852  0.943  0.196  1.0
  Mo  Mo17  1  0.148  0.057  0.804  1.0
  Mo  Mo18  1  0.852  0.557  0.804  1.0
  Mo  Mo19  1  0.148  0.443  0.196  1.0
  O  O20  1  0.889  0.118  0.114  1.0
  O  O21  1  0.111  0.882  0.886  1.0
  O  O22  1  0.889  0.382  0.886  1.0
  O  O23  1  0.111  0.618  0.114  1.0
  O  O24  1  0.722  0.623  0.114  1.0
  O  O25  1  0.278  0.377  0.886  1.0
  O  O26  1  0.722  0.877  0.886  1.0
  O  O27  1  0.278  0.123  0.114  1.0
  O  O28  1  0.908  0.894  0.356  1.0
  O  O29  1  0.092  0.106  0.644  1.0
  O  O30  1  0.908  0.606  0.644  1.0
  O  O31  1  0.092  0.394  0.356  1.0
  O  O32  1  0.456  0.605  0.303  1.0
  O  O33  1  0.544  0.395  0.697  1.0
  O  O34  1  0.456  0.895  0.697  1.0
  O  O35  1  0.544  0.105  0.303  1.0
  O  O36  1  0.970  0.852  0.125  1.0
  O  O37  1  0.030  0.148  0.875  1.0
  O  O38  1  0.970  0.648  0.875  1.0
  O  O39  1  0.030  0.352  0.125  1.0
  O  O40  1  0.642  0.917  0.180  1.0
  O  O41  1  0.358  0.083  0.820  1.0
  O  O42  1  0.642  0.583  0.820  1.0
  O  O43  1  0.358  0.417  0.180  1.0
  O  O44  1  0.324  0.885  0.348  1.0
  O  O45  1  0.676  0.115  0.652  1.0
  O  O46  1  0.324  0.615  0.652  1.0
  O  O47  1  0.676  0.385  0.348  1.0
  O  O48  1  0.793  0.614  0.370  1.0
  O  O49  1  0.207  0.386  0.630  1.0
  O  O50  1  0.793  0.886  0.630  1.0
  O  O51  1  0.207  0.114  0.370  1.0
[/CIF]
.
The compound described by Rb5In(MoO4)4 crystallizes in the monoclinic P2/c space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(7), two equivalent O(1), and two equivalent O(6) atoms. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to one O(1), one O(4), one O(5), two equivalent O(7), two equivalent O(8), and three equivalent O(3) atoms. In the third Rb site, Rb(3) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(7), and two equivalent O(8) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(2), one O(4), one O(7), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 44°. In the second Mo site, Mo(2) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-44°. In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form InO6 octahedra that share corners with two equivalent Mo(1)O4 tetrahedra and corners with four equivalent Mo(2)O4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Mo(1) atom. In the second O site, O(5) is bonded in a 2-coordinate geometry to one Rb(1), one Rb(2), one Mo(2), and one In(1) atom. In the third O site, O(6) is bonded in a 1-coordinate geometry to two equivalent Rb(1) and one Mo(2) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), two equivalent Rb(2), and one Mo(1) atom. In the fifth O site, O(8) is bonded in a 4-coordinate geometry to one Rb(3), two equivalent Rb(2), and one Mo(1) atom. In the sixth O site, O(1) is bonded in a 2-coordinate geometry to one Rb(2), two equivalent Rb(1), one Mo(2), and one In(1) atom. In the seventh O site, O(2) is bonded in a 2-coordinate geometry to one Rb(1), one Mo(1), and one In(1) atom. In the eighth O site, O(3) is bonded in a distorted single-bond geometry to one Rb(3), three equivalent Rb(2), and one Mo(2) atom. is represented by the CIF card [CIF]
data_Rb5In(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.998
_cell_length_b   11.075
_cell_length_c   11.414
_cell_angle_alpha   66.226
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   925.164
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.345  0.845  0.104  1.0
  Rb  Rb1  1  0.655  0.155  0.896  1.0
  Rb  Rb2  1  0.345  0.655  0.896  1.0
  Rb  Rb3  1  0.655  0.345  0.104  1.0
  Rb  Rb4  1  0.869  0.356  0.591  1.0
  Rb  Rb5  1  0.131  0.644  0.409  1.0
  Rb  Rb6  1  0.869  0.144  0.409  1.0
  Rb  Rb7  1  0.131  0.856  0.591  1.0
  Rb  Rb8  1  0.611  0.750  0.500  1.0
  Rb  Rb9  1  0.389  0.250  0.500  1.0
  In  In10  1  0.915  0.750  0.000  1.0
  In  In11  1  0.085  0.250  0.000  1.0
  Mo  Mo12  1  0.659  0.558  0.283  1.0
  Mo  Mo13  1  0.341  0.442  0.717  1.0
  Mo  Mo14  1  0.659  0.942  0.717  1.0
  Mo  Mo15  1  0.341  0.058  0.283  1.0
  Mo  Mo16  1  0.852  0.943  0.196  1.0
  Mo  Mo17  1  0.148  0.057  0.804  1.0
  Mo  Mo18  1  0.852  0.557  0.804  1.0
  Mo  Mo19  1  0.148  0.443  0.196  1.0
  O  O20  1  0.889  0.118  0.114  1.0
  O  O21  1  0.111  0.882  0.886  1.0
  O  O22  1  0.889  0.382  0.886  1.0
  O  O23  1  0.111  0.618  0.114  1.0
  O  O24  1  0.722  0.623  0.114  1.0
  O  O25  1  0.278  0.377  0.886  1.0
  O  O26  1  0.722  0.877  0.886  1.0
  O  O27  1  0.278  0.123  0.114  1.0
  O  O28  1  0.908  0.894  0.356  1.0
  O  O29  1  0.092  0.106  0.644  1.0
  O  O30  1  0.908  0.606  0.644  1.0
  O  O31  1  0.092  0.394  0.356  1.0
  O  O32  1  0.456  0.605  0.303  1.0
  O  O33  1  0.544  0.395  0.697  1.0
  O  O34  1  0.456  0.895  0.697  1.0
  O  O35  1  0.544  0.105  0.303  1.0
  O  O36  1  0.970  0.852  0.125  1.0
  O  O37  1  0.030  0.148  0.875  1.0
  O  O38  1  0.970  0.648  0.875  1.0
  O  O39  1  0.030  0.352  0.125  1.0
  O  O40  1  0.642  0.917  0.180  1.0
  O  O41  1  0.358  0.083  0.820  1.0
  O  O42  1  0.642  0.583  0.820  1.0
  O  O43  1  0.358  0.417  0.180  1.0
  O  O44  1  0.324  0.885  0.348  1.0
  O  O45  1  0.676  0.115  0.652  1.0
  O  O46  1  0.324  0.615  0.652  1.0
  O  O47  1  0.676  0.385  0.348  1.0
  O  O48  1  0.793  0.614  0.370  1.0
  O  O49  1  0.207  0.386  0.630  1.0
  O  O50  1  0.793  0.886  0.630  1.0
  O  O51  1  0.207  0.114  0.370  1.0
[/CIF]
.