The crystal structure described by TlTlF3 is alpha Rhenium trioxide-like structured and crystallizes in the cubic Pm-3m space group. The structure consists of one 7440-28-0 atom inside a TlF3 framework. In the TlF3 framework, Tl(2) is bonded to six equivalent F(1) atoms to form corner-sharing TlF6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to two equivalent Tl(2) atoms. is represented by the CIF file [CIF]
data_Tl2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.637
_cell_length_b   4.637
_cell_length_c   4.637
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   99.685
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.500  0.500  0.500  1.0
  Tl  Tl1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.500  0.000  0.000  1.0
  F  F3  1  0.000  0.500  0.000  1.0
  F  F4  1  0.000  0.000  0.500  1.0
[/CIF]
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The crystal structure described by TlTlF3 is alpha Rhenium trioxide-like structured and crystallizes in the cubic Pm-3m space group. The structure consists of one 7440-28-0 atom inside a TlF3 framework. In the TlF3 framework, Tl(2) is bonded to six equivalent F(1) atoms to form corner-sharing TlF6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to two equivalent Tl(2) atoms. is represented by the CIF file [CIF]
data_Tl2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.637
_cell_length_b   4.637
_cell_length_c   4.637
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   99.685
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.500  0.500  0.500  1.0
  Tl  Tl1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.500  0.000  0.000  1.0
  F  F3  1  0.000  0.500  0.000  1.0
  F  F4  1  0.000  0.000  0.500  1.0
[/CIF]
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