The compound described by Mo3N2O9O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four water atoms and two Mo3N2O9 clusters. In each Mo3N2O9 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to one N(1), one O(1), one O(4), and one O(5) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to two equivalent N(1), one O(2), and one O(3) atom. N(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one O(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one O(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo3N2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.912
_cell_length_b   7.928
_cell_length_c   11.795
_cell_angle_alpha   107.791
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   971.551
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.495  0.991  0.213  1.0
  Mo  Mo1  1  0.995  0.009  0.787  1.0
  Mo  Mo2  1  0.505  0.009  0.787  1.0
  Mo  Mo3  1  0.005  0.991  0.213  1.0
  Mo  Mo4  1  0.250  0.307  0.149  1.0
  Mo  Mo5  1  0.750  0.693  0.851  1.0
  N  N6  1  0.604  0.837  0.859  1.0
  N  N7  1  0.104  0.163  0.141  1.0
  N  N8  1  0.396  0.163  0.141  1.0
  N  N9  1  0.896  0.837  0.859  1.0
  O  O10  1  0.510  0.160  0.107  1.0
  O  O11  1  0.010  0.840  0.893  1.0
  O  O12  1  0.490  0.840  0.893  1.0
  O  O13  1  0.990  0.160  0.107  1.0
  O  O14  1  0.250  0.424  0.325  1.0
  O  O15  1  0.750  0.576  0.675  1.0
  O  O16  1  0.250  0.438  0.059  1.0
  O  O17  1  0.750  0.562  0.941  1.0
  O  O18  1  0.488  0.764  0.146  1.0
  O  O19  1  0.988  0.236  0.854  1.0
  O  O20  1  0.512  0.236  0.854  1.0
  O  O21  1  0.012  0.764  0.146  1.0
  O  O22  1  0.534  0.071  0.363  1.0
  O  O23  1  0.034  0.929  0.637  1.0
  O  O24  1  0.466  0.929  0.637  1.0
  O  O25  1  0.966  0.071  0.363  1.0
  O  O26  1  0.495  0.752  0.433  1.0
  O  O27  1  0.995  0.248  0.567  1.0
  O  O28  1  0.505  0.248  0.567  1.0
  O  O29  1  0.005  0.752  0.433  1.0
  O  O30  1  0.250  0.567  0.410  1.0
  O  O31  1  0.750  0.433  0.590  1.0
[/CIF]
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The compound described by Mo3N2O9O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four water atoms and two Mo3N2O9 clusters. In each Mo3N2O9 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to one N(1), one O(1), one O(4), and one O(5) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to two equivalent N(1), one O(2), and one O(3) atom. N(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one O(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one O(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo3N2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.912
_cell_length_b   7.928
_cell_length_c   11.795
_cell_angle_alpha   107.791
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   971.551
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.495  0.991  0.213  1.0
  Mo  Mo1  1  0.995  0.009  0.787  1.0
  Mo  Mo2  1  0.505  0.009  0.787  1.0
  Mo  Mo3  1  0.005  0.991  0.213  1.0
  Mo  Mo4  1  0.250  0.307  0.149  1.0
  Mo  Mo5  1  0.750  0.693  0.851  1.0
  N  N6  1  0.604  0.837  0.859  1.0
  N  N7  1  0.104  0.163  0.141  1.0
  N  N8  1  0.396  0.163  0.141  1.0
  N  N9  1  0.896  0.837  0.859  1.0
  O  O10  1  0.510  0.160  0.107  1.0
  O  O11  1  0.010  0.840  0.893  1.0
  O  O12  1  0.490  0.840  0.893  1.0
  O  O13  1  0.990  0.160  0.107  1.0
  O  O14  1  0.250  0.424  0.325  1.0
  O  O15  1  0.750  0.576  0.675  1.0
  O  O16  1  0.250  0.438  0.059  1.0
  O  O17  1  0.750  0.562  0.941  1.0
  O  O18  1  0.488  0.764  0.146  1.0
  O  O19  1  0.988  0.236  0.854  1.0
  O  O20  1  0.512  0.236  0.854  1.0
  O  O21  1  0.012  0.764  0.146  1.0
  O  O22  1  0.534  0.071  0.363  1.0
  O  O23  1  0.034  0.929  0.637  1.0
  O  O24  1  0.466  0.929  0.637  1.0
  O  O25  1  0.966  0.071  0.363  1.0
  O  O26  1  0.495  0.752  0.433  1.0
  O  O27  1  0.995  0.248  0.567  1.0
  O  O28  1  0.505  0.248  0.567  1.0
  O  O29  1  0.005  0.752  0.433  1.0
  O  O30  1  0.250  0.567  0.410  1.0
  O  O31  1  0.750  0.433  0.590  1.0
[/CIF]
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