The crystal structure described by Rb2U(OCl)4 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent Cl(1), and three equivalent Cl(2) atoms. U(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one U(1) atom. In the second O site, O(2) is bonded in a water-like geometry to two equivalent Rb(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one U(1) atom. In the second Cl site, Cl(2) is bonded to three equivalent Rb(1) and one U(1) atom to form a mixture of distorted edge and corner-sharing ClRb3U trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2U(ClO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.757
_cell_length_b   6.995
_cell_length_c   7.578
_cell_angle_alpha   78.588
_cell_angle_beta   76.589
_cell_angle_gamma   61.529
_symmetry_Int_Tables_number   1
_cell_volume   304.659
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.310  0.257  0.246  1.0
  Rb  Rb1  1  0.690  0.743  0.754  1.0
  U  U2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.983  0.215  0.663  1.0
  Cl  Cl4  1  0.017  0.785  0.337  1.0
  Cl  Cl5  1  0.782  0.379  0.144  1.0
  Cl  Cl6  1  0.218  0.621  0.856  1.0
  O  O7  1  0.272  0.992  0.002  1.0
  O  O8  1  0.728  0.008  0.998  1.0
  O  O9  1  0.515  0.232  0.583  1.0
  O  O10  1  0.485  0.768  0.417  1.0
[/CIF]
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The crystal structure described by Rb2U(OCl)4 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent Cl(1), and three equivalent Cl(2) atoms. U(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one U(1) atom. In the second O site, O(2) is bonded in a water-like geometry to two equivalent Rb(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one U(1) atom. In the second Cl site, Cl(2) is bonded to three equivalent Rb(1) and one U(1) atom to form a mixture of distorted edge and corner-sharing ClRb3U trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2U(ClO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.757
_cell_length_b   6.995
_cell_length_c   7.578
_cell_angle_alpha   78.588
_cell_angle_beta   76.589
_cell_angle_gamma   61.529
_symmetry_Int_Tables_number   1
_cell_volume   304.659
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.310  0.257  0.246  1.0
  Rb  Rb1  1  0.690  0.743  0.754  1.0
  U  U2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.983  0.215  0.663  1.0
  Cl  Cl4  1  0.017  0.785  0.337  1.0
  Cl  Cl5  1  0.782  0.379  0.144  1.0
  Cl  Cl6  1  0.218  0.621  0.856  1.0
  O  O7  1  0.272  0.992  0.002  1.0
  O  O8  1  0.728  0.008  0.998  1.0
  O  O9  1  0.515  0.232  0.583  1.0
  O  O10  1  0.485  0.768  0.417  1.0
[/CIF]
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