The material described by Cs2Pu(OCl2)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 9-coordinate geometry to one O(1) and eight equivalent Cl(1) atoms. Pu(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one Cs(1) and one Pu(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Pu(1) atom. is represented by the CIF card [CIF]
data_Cs2Pu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.287
_cell_length_b   7.287
_cell_length_c   5.906
_cell_angle_alpha   84.759
_cell_angle_beta   84.759
_cell_angle_gamma   64.902
_symmetry_Int_Tables_number   1
_cell_volume   282.296
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.340  0.340  0.304  1.0
  Cs  Cs1  1  0.660  0.660  0.696  1.0
  Pu  Pu2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.348  0.855  0.209  1.0
  Cl  Cl4  1  0.652  0.145  0.791  1.0
  Cl  Cl5  1  0.145  0.652  0.791  1.0
  Cl  Cl6  1  0.855  0.348  0.209  1.0
  O  O7  1  0.888  0.888  0.218  1.0
  O  O8  1  0.112  0.112  0.782  1.0
[/CIF]
.
The material described by Cs2Pu(OCl2)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 9-coordinate geometry to one O(1) and eight equivalent Cl(1) atoms. Pu(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one Cs(1) and one Pu(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Pu(1) atom. is represented by the CIF card [CIF]
data_Cs2Pu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.287
_cell_length_b   7.287
_cell_length_c   5.906
_cell_angle_alpha   84.759
_cell_angle_beta   84.759
_cell_angle_gamma   64.902
_symmetry_Int_Tables_number   1
_cell_volume   282.296
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.340  0.340  0.304  1.0
  Cs  Cs1  1  0.660  0.660  0.696  1.0
  Pu  Pu2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.348  0.855  0.209  1.0
  Cl  Cl4  1  0.652  0.145  0.791  1.0
  Cl  Cl5  1  0.145  0.652  0.791  1.0
  Cl  Cl6  1  0.855  0.348  0.209  1.0
  O  O7  1  0.888  0.888  0.218  1.0
  O  O8  1  0.112  0.112  0.782  1.0
[/CIF]
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