The material described by ZnBr4(Br)2 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrogen bromide atoms and two ZnBr4 clusters. In each ZnBr4 cluster, Zn(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Br(2) atoms. Br(2) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the CIF card [CIF]
data_ZnBr6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.694
_cell_length_b   9.694
_cell_length_c   47.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   112.858
_symmetry_Int_Tables_number   1
_cell_volume   4105.600
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  Br  Br1  1  0.000  0.000  0.250  1.0
  Br  Br2  1  0.000  0.000  0.750  1.0
  Br  Br3  1  0.258  0.014  0.000  1.0
  Br  Br4  1  0.742  0.986  0.000  1.0
  Br  Br5  1  0.014  0.258  0.000  1.0
  Br  Br6  1  0.986  0.742  0.000  1.0
[/CIF]
.
The material described by ZnBr4(Br)2 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrogen bromide atoms and two ZnBr4 clusters. In each ZnBr4 cluster, Zn(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Br(2) atoms. Br(2) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the CIF card [CIF]
data_ZnBr6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.694
_cell_length_b   9.694
_cell_length_c   47.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   112.858
_symmetry_Int_Tables_number   1
_cell_volume   4105.600
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  Br  Br1  1  0.000  0.000  0.250  1.0
  Br  Br2  1  0.000  0.000  0.750  1.0
  Br  Br3  1  0.258  0.014  0.000  1.0
  Br  Br4  1  0.742  0.986  0.000  1.0
  Br  Br5  1  0.014  0.258  0.000  1.0
  Br  Br6  1  0.986  0.742  0.000  1.0
[/CIF]
.