The structure described by Re2CdC2S2(NO2)4(CN2S)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four n-cyanosulfimide molecules and two Re2CdC2S2(NO2)4 clusters. In each Re2CdC2S2(NO2)4 cluster, Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Cd(1) is bonded in a distorted linear geometry to two equivalent S(2) and two equivalent O(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(2) atom. S(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Re(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_CdRe2C4S4(NO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.006
_cell_length_b   7.141
_cell_length_c   13.065
_cell_angle_alpha   67.892
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1210.488
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.000  0.500  1.0
  Cd  Cd1  1  0.000  0.000  0.000  1.0
  Re  Re2  1  0.475  0.596  0.788  1.0
  Re  Re3  1  0.525  0.404  0.212  1.0
  Re  Re4  1  0.975  0.404  0.712  1.0
  Re  Re5  1  0.025  0.596  0.288  1.0
  C  C6  1  0.261  0.882  0.037  1.0
  C  C7  1  0.739  0.118  0.963  1.0
  C  C8  1  0.761  0.118  0.463  1.0
  C  C9  1  0.239  0.882  0.537  1.0
  C  C10  1  0.367  0.440  0.509  1.0
  C  C11  1  0.633  0.560  0.491  1.0
  C  C12  1  0.867  0.560  0.991  1.0
  C  C13  1  0.133  0.440  0.009  1.0
  S  S14  1  0.900  0.847  0.788  1.0
  S  S15  1  0.100  0.153  0.212  1.0
  S  S16  1  0.400  0.153  0.712  1.0
  S  S17  1  0.600  0.847  0.288  1.0
  S  S18  1  0.661  0.009  0.636  1.0
  S  S19  1  0.339  0.991  0.364  1.0
  S  S20  1  0.161  0.991  0.864  1.0
  S  S21  1  0.839  0.009  0.136  1.0
  N  N22  1  0.232  0.803  0.634  1.0
  N  N23  1  0.768  0.197  0.366  1.0
  N  N24  1  0.732  0.197  0.866  1.0
  N  N25  1  0.268  0.803  0.134  1.0
  N  N26  1  0.259  0.963  0.929  1.0
  N  N27  1  0.741  0.037  0.071  1.0
  N  N28  1  0.759  0.037  0.571  1.0
  N  N29  1  0.241  0.963  0.429  1.0
  N  N30  1  0.150  0.589  0.931  1.0
  N  N31  1  0.850  0.411  0.069  1.0
  N  N32  1  0.650  0.411  0.569  1.0
  N  N33  1  0.350  0.589  0.431  1.0
  N  N34  1  0.385  0.268  0.585  1.0
  N  N35  1  0.615  0.732  0.415  1.0
  N  N36  1  0.885  0.732  0.915  1.0
  N  N37  1  0.115  0.268  0.085  1.0
  O  O38  1  0.360  0.527  0.839  1.0
  O  O39  1  0.640  0.473  0.161  1.0
  O  O40  1  0.860  0.473  0.661  1.0
  O  O41  1  0.140  0.527  0.339  1.0
  O  O42  1  0.473  0.726  0.639  1.0
  O  O43  1  0.527  0.274  0.361  1.0
  O  O44  1  0.973  0.274  0.861  1.0
  O  O45  1  0.027  0.726  0.139  1.0
  O  O46  1  0.043  0.622  0.679  1.0
  O  O47  1  0.957  0.378  0.321  1.0
  O  O48  1  0.543  0.378  0.821  1.0
  O  O49  1  0.457  0.622  0.179  1.0
  O  O50  1  0.024  0.247  0.651  1.0
  O  O51  1  0.976  0.753  0.349  1.0
  O  O52  1  0.524  0.753  0.849  1.0
  O  O53  1  0.476  0.247  0.151  1.0
[/CIF]
.
The structure described by Re2CdC2S2(NO2)4(CN2S)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four n-cyanosulfimide molecules and two Re2CdC2S2(NO2)4 clusters. In each Re2CdC2S2(NO2)4 cluster, Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Cd(1) is bonded in a distorted linear geometry to two equivalent S(2) and two equivalent O(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(2) atom. S(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Re(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_CdRe2C4S4(NO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.006
_cell_length_b   7.141
_cell_length_c   13.065
_cell_angle_alpha   67.892
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1210.488
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.000  0.500  1.0
  Cd  Cd1  1  0.000  0.000  0.000  1.0
  Re  Re2  1  0.475  0.596  0.788  1.0
  Re  Re3  1  0.525  0.404  0.212  1.0
  Re  Re4  1  0.975  0.404  0.712  1.0
  Re  Re5  1  0.025  0.596  0.288  1.0
  C  C6  1  0.261  0.882  0.037  1.0
  C  C7  1  0.739  0.118  0.963  1.0
  C  C8  1  0.761  0.118  0.463  1.0
  C  C9  1  0.239  0.882  0.537  1.0
  C  C10  1  0.367  0.440  0.509  1.0
  C  C11  1  0.633  0.560  0.491  1.0
  C  C12  1  0.867  0.560  0.991  1.0
  C  C13  1  0.133  0.440  0.009  1.0
  S  S14  1  0.900  0.847  0.788  1.0
  S  S15  1  0.100  0.153  0.212  1.0
  S  S16  1  0.400  0.153  0.712  1.0
  S  S17  1  0.600  0.847  0.288  1.0
  S  S18  1  0.661  0.009  0.636  1.0
  S  S19  1  0.339  0.991  0.364  1.0
  S  S20  1  0.161  0.991  0.864  1.0
  S  S21  1  0.839  0.009  0.136  1.0
  N  N22  1  0.232  0.803  0.634  1.0
  N  N23  1  0.768  0.197  0.366  1.0
  N  N24  1  0.732  0.197  0.866  1.0
  N  N25  1  0.268  0.803  0.134  1.0
  N  N26  1  0.259  0.963  0.929  1.0
  N  N27  1  0.741  0.037  0.071  1.0
  N  N28  1  0.759  0.037  0.571  1.0
  N  N29  1  0.241  0.963  0.429  1.0
  N  N30  1  0.150  0.589  0.931  1.0
  N  N31  1  0.850  0.411  0.069  1.0
  N  N32  1  0.650  0.411  0.569  1.0
  N  N33  1  0.350  0.589  0.431  1.0
  N  N34  1  0.385  0.268  0.585  1.0
  N  N35  1  0.615  0.732  0.415  1.0
  N  N36  1  0.885  0.732  0.915  1.0
  N  N37  1  0.115  0.268  0.085  1.0
  O  O38  1  0.360  0.527  0.839  1.0
  O  O39  1  0.640  0.473  0.161  1.0
  O  O40  1  0.860  0.473  0.661  1.0
  O  O41  1  0.140  0.527  0.339  1.0
  O  O42  1  0.473  0.726  0.639  1.0
  O  O43  1  0.527  0.274  0.361  1.0
  O  O44  1  0.973  0.274  0.861  1.0
  O  O45  1  0.027  0.726  0.139  1.0
  O  O46  1  0.043  0.622  0.679  1.0
  O  O47  1  0.957  0.378  0.321  1.0
  O  O48  1  0.543  0.378  0.821  1.0
  O  O49  1  0.457  0.622  0.179  1.0
  O  O50  1  0.024  0.247  0.651  1.0
  O  O51  1  0.976  0.753  0.349  1.0
  O  O52  1  0.524  0.753  0.849  1.0
  O  O53  1  0.476  0.247  0.151  1.0
[/CIF]
.