The material described by Li2VMn(PO4)3 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted trigonal planar geometry to one O(13), one O(3), and one O(8) atom. In the second Li site, Li(2) is bonded to one O(15), one O(20), one O(23), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 62-64°. In the third Li site, Li(3) is bonded to one O(1), one O(17), one O(19), and one O(22) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-67°. In the fourth Li site, Li(4) is bonded to one O(14), one O(21), one O(24), and one O(5) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-70°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(12), one O(14), one O(17), one O(23), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. In the second V site, V(2) is bonded to one O(11), one O(13), one O(16), one O(18), one O(2), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(19), one O(20), one O(24), one O(3), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. In the second Mn site, Mn(2) is bonded to one O(1), one O(15), one O(21), one O(22), one O(5), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(2)O4 tetrahedra,  an edgeedge with one Li(3)O4 trigonal pyramid, and  an edgeedge with one Li(4)O4 trigonal pyramid. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 26-45°. In the second P site, P(2) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Li(4)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 19-49°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 24-47°. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(15), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 32-46°. In the fifth P site, P(5) is bonded to one O(16), one O(17), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 22-52°. In the sixth P site, P(6) is bonded to one O(18), one O(22), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 25-48°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(3), one Mn(2), and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(4), one Mn(2), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(2), one Mn(2), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(2) and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one V(1) and one P(3) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(1), one V(2), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(4), one V(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(2), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one V(2) and one P(5) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Li(3), one V(1), and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one V(2) and one P(6) atom. In the nineteenth O site, O(19) is bonded in a trigonal planar geometry to one Li(3), one Mn(1), and one P(4) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(1), and one P(5) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(2), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Li(3), one Mn(2), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal planar geometry to one Li(4), one Mn(1), and one P(6) atom. is represented by the CIF file [CIF]
data_Li2MnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.002
_cell_length_b   8.554
_cell_length_c   8.331
_cell_angle_alpha   59.410
_cell_angle_beta   63.771
_cell_angle_gamma   92.560
_symmetry_Int_Tables_number   1
_cell_volume   464.188
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.371  0.210  0.370  1.0
  Li  Li1  1  0.870  0.692  0.040  1.0
  Li  Li2  1  0.869  0.926  0.400  1.0
  Li  Li3  1  0.866  0.259  0.814  1.0
  Mn  Mn4  1  0.052  0.357  0.299  1.0
  Mn  Mn5  1  0.958  0.644  0.696  1.0
  V  V6  1  0.559  0.847  0.296  1.0
  V  V7  1  0.434  0.140  0.718  1.0
  P  P8  1  0.255  0.034  0.212  1.0
  P  P9  1  0.246  0.452  0.506  1.0
  P  P10  1  0.251  0.749  0.786  1.0
  P  P11  1  0.754  0.247  0.215  1.0
  P  P12  1  0.754  0.542  0.492  1.0
  P  P13  1  0.749  0.969  0.782  1.0
  O  O14  1  0.089  0.843  0.380  1.0
  O  O15  1  0.275  0.110  0.989  1.0
  O  O16  1  0.224  0.176  0.271  1.0
  O  O17  1  0.214  0.487  0.325  1.0
  O  O18  1  0.092  0.440  0.696  1.0
  O  O19  1  0.096  0.777  0.748  1.0
  O  O20  1  0.427  0.999  0.198  1.0
  O  O21  1  0.294  0.268  0.589  1.0
  O  O22  1  0.417  0.625  0.385  1.0
  O  O23  1  0.204  0.543  0.978  1.0
  O  O24  1  0.284  0.902  0.826  1.0
  O  O25  1  0.422  0.802  0.577  1.0
  O  O26  1  0.574  0.196  0.412  1.0
  O  O27  1  0.734  0.111  0.147  1.0
  O  O28  1  0.806  0.461  0.023  1.0
  O  O29  1  0.579  0.375  0.616  1.0
  O  O30  1  0.721  0.738  0.402  1.0
  O  O31  1  0.575  0.000  0.809  1.0
  O  O32  1  0.895  0.209  0.275  1.0
  O  O33  1  0.894  0.548  0.295  1.0
  O  O34  1  0.802  0.500  0.664  1.0
  O  O35  1  0.795  0.839  0.707  1.0
  O  O36  1  0.730  0.877  0.012  1.0
  O  O37  1  0.899  0.172  0.625  1.0
[/CIF]
.
The material described by Li2VMn(PO4)3 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted trigonal planar geometry to one O(13), one O(3), and one O(8) atom. In the second Li site, Li(2) is bonded to one O(15), one O(20), one O(23), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 62-64°. In the third Li site, Li(3) is bonded to one O(1), one O(17), one O(19), and one O(22) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-67°. In the fourth Li site, Li(4) is bonded to one O(14), one O(21), one O(24), and one O(5) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-70°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(12), one O(14), one O(17), one O(23), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. In the second V site, V(2) is bonded to one O(11), one O(13), one O(16), one O(18), one O(2), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(19), one O(20), one O(24), one O(3), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. In the second Mn site, Mn(2) is bonded to one O(1), one O(15), one O(21), one O(22), one O(5), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(2)O4 tetrahedra,  an edgeedge with one Li(3)O4 trigonal pyramid, and  an edgeedge with one Li(4)O4 trigonal pyramid. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 26-45°. In the second P site, P(2) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Li(4)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 19-49°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 24-47°. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(15), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 32-46°. In the fifth P site, P(5) is bonded to one O(16), one O(17), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 22-52°. In the sixth P site, P(6) is bonded to one O(18), one O(22), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid, and  a cornercorner with one Li(4)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 25-48°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(3), one Mn(2), and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(4), one Mn(2), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(2), one Mn(2), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(2) and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one V(1) and one P(3) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(1), one V(2), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(4), one V(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(2), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one V(2) and one P(5) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Li(3), one V(1), and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one V(2) and one P(6) atom. In the nineteenth O site, O(19) is bonded in a trigonal planar geometry to one Li(3), one Mn(1), and one P(4) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(1), and one P(5) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(2), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Li(3), one Mn(2), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal planar geometry to one Li(4), one Mn(1), and one P(6) atom. is represented by the CIF file [CIF]
data_Li2MnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.002
_cell_length_b   8.554
_cell_length_c   8.331
_cell_angle_alpha   59.410
_cell_angle_beta   63.771
_cell_angle_gamma   92.560
_symmetry_Int_Tables_number   1
_cell_volume   464.188
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.371  0.210  0.370  1.0
  Li  Li1  1  0.870  0.692  0.040  1.0
  Li  Li2  1  0.869  0.926  0.400  1.0
  Li  Li3  1  0.866  0.259  0.814  1.0
  Mn  Mn4  1  0.052  0.357  0.299  1.0
  Mn  Mn5  1  0.958  0.644  0.696  1.0
  V  V6  1  0.559  0.847  0.296  1.0
  V  V7  1  0.434  0.140  0.718  1.0
  P  P8  1  0.255  0.034  0.212  1.0
  P  P9  1  0.246  0.452  0.506  1.0
  P  P10  1  0.251  0.749  0.786  1.0
  P  P11  1  0.754  0.247  0.215  1.0
  P  P12  1  0.754  0.542  0.492  1.0
  P  P13  1  0.749  0.969  0.782  1.0
  O  O14  1  0.089  0.843  0.380  1.0
  O  O15  1  0.275  0.110  0.989  1.0
  O  O16  1  0.224  0.176  0.271  1.0
  O  O17  1  0.214  0.487  0.325  1.0
  O  O18  1  0.092  0.440  0.696  1.0
  O  O19  1  0.096  0.777  0.748  1.0
  O  O20  1  0.427  0.999  0.198  1.0
  O  O21  1  0.294  0.268  0.589  1.0
  O  O22  1  0.417  0.625  0.385  1.0
  O  O23  1  0.204  0.543  0.978  1.0
  O  O24  1  0.284  0.902  0.826  1.0
  O  O25  1  0.422  0.802  0.577  1.0
  O  O26  1  0.574  0.196  0.412  1.0
  O  O27  1  0.734  0.111  0.147  1.0
  O  O28  1  0.806  0.461  0.023  1.0
  O  O29  1  0.579  0.375  0.616  1.0
  O  O30  1  0.721  0.738  0.402  1.0
  O  O31  1  0.575  0.000  0.809  1.0
  O  O32  1  0.895  0.209  0.275  1.0
  O  O33  1  0.894  0.548  0.295  1.0
  O  O34  1  0.802  0.500  0.664  1.0
  O  O35  1  0.795  0.839  0.707  1.0
  O  O36  1  0.730  0.877  0.012  1.0
  O  O37  1  0.899  0.172  0.625  1.0
[/CIF]
.