The crystal structure described by Sm(PdP)2 crystallizes in the tetragonal I4/mmm space group. Sm(1) is bonded in a 16-coordinate geometry to eight equivalent Pd(1) and eight equivalent P(1) atoms. Pd(1) is bonded to four equivalent Sm(1) and four equivalent P(1) atoms to form a mixture of distorted edge, face, and corner-sharing PdSm4P4 cuboctahedra. P(1) is bonded in a 9-coordinate geometry to four equivalent Sm(1), four equivalent Pd(1), and one P(1) atom. is represented by the CIF file [CIF]
data_Sm(PPd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.741
_cell_length_b   5.741
_cell_length_c   5.741
_cell_angle_alpha   137.888
_cell_angle_beta   137.888
_cell_angle_gamma   61.074
_symmetry_Int_Tables_number   1
_cell_volume   84.128
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.388  0.388  0.000  1.0
  P  P2  1  0.612  0.612  0.000  1.0
  Pd  Pd3  1  0.750  0.250  0.500  1.0
  Pd  Pd4  1  0.250  0.750  0.500  1.0
[/CIF]
.
The crystal structure described by Sm(PdP)2 crystallizes in the tetragonal I4/mmm space group. Sm(1) is bonded in a 16-coordinate geometry to eight equivalent Pd(1) and eight equivalent P(1) atoms. Pd(1) is bonded to four equivalent Sm(1) and four equivalent P(1) atoms to form a mixture of distorted edge, face, and corner-sharing PdSm4P4 cuboctahedra. P(1) is bonded in a 9-coordinate geometry to four equivalent Sm(1), four equivalent Pd(1), and one P(1) atom. is represented by the CIF file [CIF]
data_Sm(PPd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.741
_cell_length_b   5.741
_cell_length_c   5.741
_cell_angle_alpha   137.888
_cell_angle_beta   137.888
_cell_angle_gamma   61.074
_symmetry_Int_Tables_number   1
_cell_volume   84.128
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.388  0.388  0.000  1.0
  P  P2  1  0.612  0.612  0.000  1.0
  Pd  Pd3  1  0.750  0.250  0.500  1.0
  Pd  Pd4  1  0.250  0.750  0.500  1.0
[/CIF]
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