The crystal structure described by Li4V5Co3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-65°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-66°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-68°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-66°. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 53-54°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the third V site, V(3) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form distorted VO6 octahedra that share corners with two equivalent V(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. In the fourth V site, V(4) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted VO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. In the fifth V site, V(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted VO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-53°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent V(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the second Co site, Co(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent V(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the third Co site, Co(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 44-48°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one V(2), and one Co(3) atom. In the second O site, O(2) is bonded to one Li(4), one V(2), one Co(1), and one Co(2) atom to form distorted corner-sharing OLiVCo2 tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(3), one Co(1), and one Co(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(3), one Co(1), and one Co(2) atom to form corner-sharing OLiVCo2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(1), one V(5), and one Co(3) atom to form OLiV2Co tetrahedra that share corners with two equivalent O(11)LiV2Co tetrahedra, corners with two equivalent O(12)LiV2Co tetrahedra, and corners with two equivalent O(15)LiV3 tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one V(5), and one Co(3) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Co(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Co(2) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(4), one Co(1), and one Co(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one V(2), and one V(5) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(1), one V(4), and one Co(3) atom to form distorted OLiV2Co tetrahedra that share  a cornercorner with one O(12)LiV2Co tetrahedra,  a cornercorner with one O(15)LiV3 tetrahedra, corners with two equivalent O(5)LiV2Co tetrahedra,  an edgeedge with one O(12)LiV2Co tetrahedra, and  an edgeedge with one O(15)LiV3 tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one V(4), one V(5), and one Co(3) atom to form distorted OLiV2Co tetrahedra that share  a cornercorner with one O(11)LiV2Co tetrahedra,  a cornercorner with one O(15)LiV3 tetrahedra, corners with two equivalent O(5)LiV2Co tetrahedra,  an edgeedge with one O(11)LiV2Co tetrahedra, and  an edgeedge with one O(15)LiV3 tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(1), one V(5), and one Co(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(3), one V(4), and one Co(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(1), one V(4), and one V(5) atom to form a mixture of distorted corner and edge-sharing OLiV3 tetrahedra. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(3), one V(4), and one Co(2) atom. is represented by the CIF card [CIF]
data_Li4V5Co3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.901
_cell_length_b   5.916
_cell_length_c   9.560
_cell_angle_alpha   90.724
_cell_angle_beta   89.779
_cell_angle_gamma   119.739
_symmetry_Int_Tables_number   1
_cell_volume   289.774
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.329  0.670  0.899  1.0
  Li  Li1  1  0.003  1.000  0.996  1.0
  Li  Li2  1  0.000  0.001  0.488  1.0
  Li  Li3  1  0.668  0.334  0.398  1.0
  V  V4  1  0.833  0.184  0.720  1.0
  V  V5  1  0.354  0.704  0.487  1.0
  V  V6  1  0.181  0.358  0.229  1.0
  V  V7  1  0.669  0.327  0.002  1.0
  V  V8  1  0.346  0.196  0.718  1.0
  Co  Co9  1  0.656  0.821  0.210  1.0
  Co  Co10  1  0.167  0.823  0.210  1.0
  Co  Co11  1  0.832  0.657  0.709  1.0
  O  O12  1  0.654  0.827  0.590  1.0
  O  O13  1  0.477  0.954  0.356  1.0
  O  O14  1  0.317  0.633  0.104  1.0
  O  O15  1  0.009  0.019  0.296  1.0
  O  O16  1  0.998  0.013  0.804  1.0
  O  O17  1  0.183  0.838  0.594  1.0
  O  O18  1  0.468  0.508  0.355  1.0
  O  O19  1  0.043  0.510  0.356  1.0
  O  O20  1  0.823  0.648  0.081  1.0
  O  O21  1  0.171  0.336  0.602  1.0
  O  O22  1  0.954  0.469  0.846  1.0
  O  O23  1  0.501  0.467  0.839  1.0
  O  O24  1  0.660  0.301  0.602  1.0
  O  O25  1  0.826  0.180  0.090  1.0
  O  O26  1  0.523  0.043  0.842  1.0
  O  O27  1  0.356  0.180  0.087  1.0
[/CIF]
.
The crystal structure described by Li4V5Co3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-65°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-66°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-68°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-66°. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 53-54°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the third V site, V(3) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form distorted VO6 octahedra that share corners with two equivalent V(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. In the fourth V site, V(4) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted VO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. In the fifth V site, V(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted VO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-53°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent V(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the second Co site, Co(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent V(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the third Co site, Co(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 44-48°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one V(2), and one Co(3) atom. In the second O site, O(2) is bonded to one Li(4), one V(2), one Co(1), and one Co(2) atom to form distorted corner-sharing OLiVCo2 tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(3), one Co(1), and one Co(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(3), one Co(1), and one Co(2) atom to form corner-sharing OLiVCo2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(1), one V(5), and one Co(3) atom to form OLiV2Co tetrahedra that share corners with two equivalent O(11)LiV2Co tetrahedra, corners with two equivalent O(12)LiV2Co tetrahedra, and corners with two equivalent O(15)LiV3 tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one V(5), and one Co(3) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Co(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Co(2) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(4), one Co(1), and one Co(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one V(2), and one V(5) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(1), one V(4), and one Co(3) atom to form distorted OLiV2Co tetrahedra that share  a cornercorner with one O(12)LiV2Co tetrahedra,  a cornercorner with one O(15)LiV3 tetrahedra, corners with two equivalent O(5)LiV2Co tetrahedra,  an edgeedge with one O(12)LiV2Co tetrahedra, and  an edgeedge with one O(15)LiV3 tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one V(4), one V(5), and one Co(3) atom to form distorted OLiV2Co tetrahedra that share  a cornercorner with one O(11)LiV2Co tetrahedra,  a cornercorner with one O(15)LiV3 tetrahedra, corners with two equivalent O(5)LiV2Co tetrahedra,  an edgeedge with one O(11)LiV2Co tetrahedra, and  an edgeedge with one O(15)LiV3 tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(1), one V(5), and one Co(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(3), one V(4), and one Co(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(1), one V(4), and one V(5) atom to form a mixture of distorted corner and edge-sharing OLiV3 tetrahedra. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(3), one V(4), and one Co(2) atom. is represented by the CIF card [CIF]
data_Li4V5Co3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.901
_cell_length_b   5.916
_cell_length_c   9.560
_cell_angle_alpha   90.724
_cell_angle_beta   89.779
_cell_angle_gamma   119.739
_symmetry_Int_Tables_number   1
_cell_volume   289.774
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.329  0.670  0.899  1.0
  Li  Li1  1  0.003  1.000  0.996  1.0
  Li  Li2  1  0.000  0.001  0.488  1.0
  Li  Li3  1  0.668  0.334  0.398  1.0
  V  V4  1  0.833  0.184  0.720  1.0
  V  V5  1  0.354  0.704  0.487  1.0
  V  V6  1  0.181  0.358  0.229  1.0
  V  V7  1  0.669  0.327  0.002  1.0
  V  V8  1  0.346  0.196  0.718  1.0
  Co  Co9  1  0.656  0.821  0.210  1.0
  Co  Co10  1  0.167  0.823  0.210  1.0
  Co  Co11  1  0.832  0.657  0.709  1.0
  O  O12  1  0.654  0.827  0.590  1.0
  O  O13  1  0.477  0.954  0.356  1.0
  O  O14  1  0.317  0.633  0.104  1.0
  O  O15  1  0.009  0.019  0.296  1.0
  O  O16  1  0.998  0.013  0.804  1.0
  O  O17  1  0.183  0.838  0.594  1.0
  O  O18  1  0.468  0.508  0.355  1.0
  O  O19  1  0.043  0.510  0.356  1.0
  O  O20  1  0.823  0.648  0.081  1.0
  O  O21  1  0.171  0.336  0.602  1.0
  O  O22  1  0.954  0.469  0.846  1.0
  O  O23  1  0.501  0.467  0.839  1.0
  O  O24  1  0.660  0.301  0.602  1.0
  O  O25  1  0.826  0.180  0.090  1.0
  O  O26  1  0.523  0.043  0.842  1.0
  O  O27  1  0.356  0.180  0.087  1.0
[/CIF]
.