The structure described by Cs4Mn3O6 crystallizes in the monoclinic P2 space group. There are eight inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(6), and one O(7) atom. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(4), one O(6), one O(8), and one O(9) atom. In the third Cs site, Cs(3) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(5), one O(7), one O(8), and one O(9) atom. In the fourth Cs site, Cs(4) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(8), and one O(9) atom. In the fifth Cs site, Cs(5) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(6), and one O(9) atom. In the sixth Cs site, Cs(6) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(7), and one O(8) atom. In the seventh Cs site, Cs(7) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(2), one O(4), and one O(5) atom. In the eighth Cs site, Cs(8) is bonded in a 4-coordinate geometry to one O(12), one O(3), one O(4), and one O(5) atom. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(6) atoms. In the second Mn site, Mn(2) is bonded in a 4-coordinate geometry to two equivalent O(5) and two equivalent O(7) atoms. In the third Mn site, Mn(3) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. In the fourth Mn site, Mn(4) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(5) atoms. In the fifth Mn site, Mn(5) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(10) and two equivalent O(12) atoms. In the sixth Mn site, Mn(6) is bonded in a 4-coordinate geometry to two equivalent O(11) and two equivalent O(12) atoms. In the seventh Mn site, Mn(7) is bonded in a 4-coordinate geometry to two equivalent O(8) and two equivalent O(9) atoms. In the eighth Mn site, Mn(8) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(8) atoms. In the ninth Mn site, Mn(9) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(9) atoms. In the tenth Mn site, Mn(10) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(10) and two equivalent O(11) atoms. In the eleventh Mn site, Mn(11) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(6) atoms. In the twelfth Mn site, Mn(12) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(3) and two equivalent O(7) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(5), one Cs(6), one Mn(8), and one Mn(9) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(5), one Cs(7), one Mn(11), and one Mn(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(6), one Cs(8), one Mn(12), and one Mn(4) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cs(2), one Cs(4), one Cs(7), one Cs(8), one Mn(1), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Cs(3), one Cs(4), one Cs(7), one Cs(8), one Mn(2), and one Mn(4) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Cs(1), one Cs(2), one Cs(5), one Mn(1), and one Mn(11) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Cs(1), one Cs(3), one Cs(6), one Mn(12), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Cs(2), one Cs(3), one Cs(4), one Cs(6), one Mn(7), and one Mn(8) atom. In the ninth O site, O(9) is bonded in a distorted L-shaped geometry to one Cs(2), one Cs(3), one Cs(4), one Cs(5), one Mn(7), and one Mn(9) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Cs(2), one Cs(3), one Cs(5), one Cs(7), one Mn(10), and one Mn(5) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Cs(2), one Cs(3), one Cs(6), one Mn(10), and one Mn(6) atom. In the twelfth O site, O(12) is bonded in a distorted L-shaped geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(8), one Mn(5), and one Mn(6) atom. is represented by the CIF file [CIF]
data_Cs4Mn3O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.392
_cell_length_b   12.202
_cell_length_c   12.327
_cell_angle_alpha   63.190
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1126.579
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.003  0.346  0.842  1.0
  Cs  Cs1  1  0.003  0.654  0.158  1.0
  Cs  Cs2  1  0.606  0.178  0.163  1.0
  Cs  Cs3  1  0.606  0.822  0.837  1.0
  Cs  Cs4  1  0.390  0.333  0.320  1.0
  Cs  Cs5  1  0.390  0.667  0.680  1.0
  Cs  Cs6  1  0.504  0.326  0.825  1.0
  Cs  Cs7  1  0.504  0.674  0.175  1.0
  Cs  Cs8  1  0.118  0.154  0.164  1.0
  Cs  Cs9  1  0.118  0.846  0.836  1.0
  Cs  Cs10  1  0.878  0.330  0.343  1.0
  Cs  Cs11  1  0.878  0.670  0.657  1.0
  Cs  Cs12  1  0.256  0.179  0.662  1.0
  Cs  Cs13  1  0.256  0.821  0.338  1.0
  Cs  Cs14  1  0.750  0.841  0.319  1.0
  Cs  Cs15  1  0.750  0.159  0.681  1.0
  Mn  Mn16  1  0.650  0.000  0.000  1.0
  Mn  Mn17  1  0.351  0.500  0.500  1.0
  Mn  Mn18  1  0.317  0.000  0.000  1.0
  Mn  Mn19  1  0.684  0.500  0.500  1.0
  Mn  Mn20  1  0.162  0.000  0.500  1.0
  Mn  Mn21  1  0.829  0.000  0.500  1.0
  Mn  Mn22  1  0.502  0.500  0.000  1.0
  Mn  Mn23  1  0.834  0.500  0.000  1.0
  Mn  Mn24  1  0.171  0.500  0.000  1.0
  Mn  Mn25  1  0.495  0.000  0.500  1.0
  Mn  Mn26  1  0.981  0.000  0.000  1.0
  Mn  Mn27  1  0.019  0.500  0.500  1.0
  O  O28  1  0.002  0.402  0.101  1.0
  O  O29  1  0.002  0.598  0.899  1.0
  O  O30  1  0.150  0.108  0.912  1.0
  O  O31  1  0.150  0.892  0.088  1.0
  O  O32  1  0.851  0.587  0.391  1.0
  O  O33  1  0.851  0.413  0.609  1.0
  O  O34  1  0.471  0.053  0.876  1.0
  O  O35  1  0.471  0.947  0.124  1.0
  O  O36  1  0.530  0.625  0.445  1.0
  O  O37  1  0.530  0.375  0.555  1.0
  O  O38  1  0.827  0.114  0.994  1.0
  O  O39  1  0.827  0.886  0.006  1.0
  O  O40  1  0.173  0.499  0.390  1.0
  O  O41  1  0.173  0.501  0.610  1.0
  O  O42  1  0.680  0.531  0.878  1.0
  O  O43  1  0.680  0.469  0.122  1.0
  O  O44  1  0.324  0.623  0.967  1.0
  O  O45  1  0.324  0.377  0.033  1.0
  O  O46  1  0.329  0.937  0.617  1.0
  O  O47  1  0.329  0.063  0.383  1.0
  O  O48  1  0.649  0.879  0.579  1.0
  O  O49  1  0.649  0.121  0.421  1.0
  O  O50  1  0.008  0.040  0.587  1.0
  O  O51  1  0.008  0.960  0.413  1.0
[/CIF]
.
The structure described by Cs4Mn3O6 crystallizes in the monoclinic P2 space group. There are eight inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(6), and one O(7) atom. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(4), one O(6), one O(8), and one O(9) atom. In the third Cs site, Cs(3) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(5), one O(7), one O(8), and one O(9) atom. In the fourth Cs site, Cs(4) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(8), and one O(9) atom. In the fifth Cs site, Cs(5) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(6), and one O(9) atom. In the sixth Cs site, Cs(6) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(7), and one O(8) atom. In the seventh Cs site, Cs(7) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(2), one O(4), and one O(5) atom. In the eighth Cs site, Cs(8) is bonded in a 4-coordinate geometry to one O(12), one O(3), one O(4), and one O(5) atom. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(6) atoms. In the second Mn site, Mn(2) is bonded in a 4-coordinate geometry to two equivalent O(5) and two equivalent O(7) atoms. In the third Mn site, Mn(3) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. In the fourth Mn site, Mn(4) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(5) atoms. In the fifth Mn site, Mn(5) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(10) and two equivalent O(12) atoms. In the sixth Mn site, Mn(6) is bonded in a 4-coordinate geometry to two equivalent O(11) and two equivalent O(12) atoms. In the seventh Mn site, Mn(7) is bonded in a 4-coordinate geometry to two equivalent O(8) and two equivalent O(9) atoms. In the eighth Mn site, Mn(8) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(8) atoms. In the ninth Mn site, Mn(9) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(9) atoms. In the tenth Mn site, Mn(10) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(10) and two equivalent O(11) atoms. In the eleventh Mn site, Mn(11) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(6) atoms. In the twelfth Mn site, Mn(12) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(3) and two equivalent O(7) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(5), one Cs(6), one Mn(8), and one Mn(9) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(5), one Cs(7), one Mn(11), and one Mn(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(6), one Cs(8), one Mn(12), and one Mn(4) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cs(2), one Cs(4), one Cs(7), one Cs(8), one Mn(1), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Cs(3), one Cs(4), one Cs(7), one Cs(8), one Mn(2), and one Mn(4) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Cs(1), one Cs(2), one Cs(5), one Mn(1), and one Mn(11) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Cs(1), one Cs(3), one Cs(6), one Mn(12), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Cs(2), one Cs(3), one Cs(4), one Cs(6), one Mn(7), and one Mn(8) atom. In the ninth O site, O(9) is bonded in a distorted L-shaped geometry to one Cs(2), one Cs(3), one Cs(4), one Cs(5), one Mn(7), and one Mn(9) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Cs(2), one Cs(3), one Cs(5), one Cs(7), one Mn(10), and one Mn(5) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Cs(2), one Cs(3), one Cs(6), one Mn(10), and one Mn(6) atom. In the twelfth O site, O(12) is bonded in a distorted L-shaped geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(8), one Mn(5), and one Mn(6) atom. is represented by the CIF file [CIF]
data_Cs4Mn3O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.392
_cell_length_b   12.202
_cell_length_c   12.327
_cell_angle_alpha   63.190
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1126.579
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.003  0.346  0.842  1.0
  Cs  Cs1  1  0.003  0.654  0.158  1.0
  Cs  Cs2  1  0.606  0.178  0.163  1.0
  Cs  Cs3  1  0.606  0.822  0.837  1.0
  Cs  Cs4  1  0.390  0.333  0.320  1.0
  Cs  Cs5  1  0.390  0.667  0.680  1.0
  Cs  Cs6  1  0.504  0.326  0.825  1.0
  Cs  Cs7  1  0.504  0.674  0.175  1.0
  Cs  Cs8  1  0.118  0.154  0.164  1.0
  Cs  Cs9  1  0.118  0.846  0.836  1.0
  Cs  Cs10  1  0.878  0.330  0.343  1.0
  Cs  Cs11  1  0.878  0.670  0.657  1.0
  Cs  Cs12  1  0.256  0.179  0.662  1.0
  Cs  Cs13  1  0.256  0.821  0.338  1.0
  Cs  Cs14  1  0.750  0.841  0.319  1.0
  Cs  Cs15  1  0.750  0.159  0.681  1.0
  Mn  Mn16  1  0.650  0.000  0.000  1.0
  Mn  Mn17  1  0.351  0.500  0.500  1.0
  Mn  Mn18  1  0.317  0.000  0.000  1.0
  Mn  Mn19  1  0.684  0.500  0.500  1.0
  Mn  Mn20  1  0.162  0.000  0.500  1.0
  Mn  Mn21  1  0.829  0.000  0.500  1.0
  Mn  Mn22  1  0.502  0.500  0.000  1.0
  Mn  Mn23  1  0.834  0.500  0.000  1.0
  Mn  Mn24  1  0.171  0.500  0.000  1.0
  Mn  Mn25  1  0.495  0.000  0.500  1.0
  Mn  Mn26  1  0.981  0.000  0.000  1.0
  Mn  Mn27  1  0.019  0.500  0.500  1.0
  O  O28  1  0.002  0.402  0.101  1.0
  O  O29  1  0.002  0.598  0.899  1.0
  O  O30  1  0.150  0.108  0.912  1.0
  O  O31  1  0.150  0.892  0.088  1.0
  O  O32  1  0.851  0.587  0.391  1.0
  O  O33  1  0.851  0.413  0.609  1.0
  O  O34  1  0.471  0.053  0.876  1.0
  O  O35  1  0.471  0.947  0.124  1.0
  O  O36  1  0.530  0.625  0.445  1.0
  O  O37  1  0.530  0.375  0.555  1.0
  O  O38  1  0.827  0.114  0.994  1.0
  O  O39  1  0.827  0.886  0.006  1.0
  O  O40  1  0.173  0.499  0.390  1.0
  O  O41  1  0.173  0.501  0.610  1.0
  O  O42  1  0.680  0.531  0.878  1.0
  O  O43  1  0.680  0.469  0.122  1.0
  O  O44  1  0.324  0.623  0.967  1.0
  O  O45  1  0.324  0.377  0.033  1.0
  O  O46  1  0.329  0.937  0.617  1.0
  O  O47  1  0.329  0.063  0.383  1.0
  O  O48  1  0.649  0.879  0.579  1.0
  O  O49  1  0.649  0.121  0.421  1.0
  O  O50  1  0.008  0.040  0.587  1.0
  O  O51  1  0.008  0.960  0.413  1.0
[/CIF]
.