The compound described by Dy2Rh3Sn5 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to two equivalent Rh(3), two equivalent Sn(2), two equivalent Sn(3), and two equivalent Sn(5) atoms. In the second Dy site, Dy(2) is bonded in a 13-coordinate geometry to one Rh(3), four equivalent Rh(1), two equivalent Sn(1), two equivalent Sn(3), and four equivalent Sn(4) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 9-coordinate geometry to one Dy(2), two equivalent Dy(1), one Sn(2), one Sn(3), two equivalent Sn(1), and two equivalent Sn(4) atoms. In the second Rh site, Rh(1) is bonded in a 9-coordinate geometry to four equivalent Dy(2), one Sn(1), two equivalent Sn(3), and two equivalent Sn(4) atoms. In the third Rh site, Rh(2) is bonded in a 7-coordinate geometry to one Sn(1), three equivalent Sn(2), and three equivalent Sn(5) atoms. There are five inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to two equivalent Dy(2), one Rh(1), one Rh(2), and two equivalent Rh(3) atoms. In the second Sn site, Sn(2) is bonded in a 6-coordinate geometry to two equivalent Dy(1), one Rh(3), and three equivalent Rh(2) atoms. In the third Sn site, Sn(3) is bonded in a 3-coordinate geometry to two equivalent Dy(1), two equivalent Dy(2), one Rh(3), and two equivalent Rh(1) atoms. In the fourth Sn site, Sn(4) is bonded in a 6-coordinate geometry to four equivalent Dy(2), two equivalent Rh(1), and two equivalent Rh(3) atoms. In the fifth Sn site, Sn(5) is bonded in a 5-coordinate geometry to two equivalent Dy(1) and three equivalent Rh(2) atoms. is represented by the CIF card [CIF]
data_Dy2Sn5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.456
_cell_length_b   13.456
_cell_length_c   7.335
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   161.189
_symmetry_Int_Tables_number   1
_cell_volume   428.217
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.173  0.827  0.755  1.0
  Dy  Dy1  1  0.827  0.173  0.255  1.0
  Dy  Dy2  1  0.476  0.524  0.737  1.0
  Dy  Dy3  1  0.524  0.476  0.237  1.0
  Sn  Sn4  1  0.881  0.119  0.731  1.0
  Sn  Sn5  1  0.119  0.881  0.231  1.0
  Sn  Sn6  1  0.705  0.295  0.050  1.0
  Sn  Sn7  1  0.295  0.705  0.550  1.0
  Sn  Sn8  1  0.596  0.404  0.615  1.0
  Sn  Sn9  1  0.404  0.596  0.115  1.0
  Sn  Sn10  1  0.952  0.048  0.397  1.0
  Sn  Sn11  1  0.048  0.952  0.897  1.0
  Sn  Sn12  1  0.291  0.709  0.977  1.0
  Sn  Sn13  1  0.709  0.291  0.477  1.0
  Rh  Rh14  1  0.050  0.950  0.519  1.0
  Rh  Rh15  1  0.950  0.050  0.019  1.0
  Rh  Rh16  1  0.777  0.223  0.765  1.0
  Rh  Rh17  1  0.223  0.777  0.265  1.0
  Rh  Rh18  1  0.394  0.606  0.482  1.0
  Rh  Rh19  1  0.606  0.394  0.982  1.0
[/CIF]
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The compound described by Dy2Rh3Sn5 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to two equivalent Rh(3), two equivalent Sn(2), two equivalent Sn(3), and two equivalent Sn(5) atoms. In the second Dy site, Dy(2) is bonded in a 13-coordinate geometry to one Rh(3), four equivalent Rh(1), two equivalent Sn(1), two equivalent Sn(3), and four equivalent Sn(4) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 9-coordinate geometry to one Dy(2), two equivalent Dy(1), one Sn(2), one Sn(3), two equivalent Sn(1), and two equivalent Sn(4) atoms. In the second Rh site, Rh(1) is bonded in a 9-coordinate geometry to four equivalent Dy(2), one Sn(1), two equivalent Sn(3), and two equivalent Sn(4) atoms. In the third Rh site, Rh(2) is bonded in a 7-coordinate geometry to one Sn(1), three equivalent Sn(2), and three equivalent Sn(5) atoms. There are five inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to two equivalent Dy(2), one Rh(1), one Rh(2), and two equivalent Rh(3) atoms. In the second Sn site, Sn(2) is bonded in a 6-coordinate geometry to two equivalent Dy(1), one Rh(3), and three equivalent Rh(2) atoms. In the third Sn site, Sn(3) is bonded in a 3-coordinate geometry to two equivalent Dy(1), two equivalent Dy(2), one Rh(3), and two equivalent Rh(1) atoms. In the fourth Sn site, Sn(4) is bonded in a 6-coordinate geometry to four equivalent Dy(2), two equivalent Rh(1), and two equivalent Rh(3) atoms. In the fifth Sn site, Sn(5) is bonded in a 5-coordinate geometry to two equivalent Dy(1) and three equivalent Rh(2) atoms. is represented by the CIF card [CIF]
data_Dy2Sn5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.456
_cell_length_b   13.456
_cell_length_c   7.335
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   161.189
_symmetry_Int_Tables_number   1
_cell_volume   428.217
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.173  0.827  0.755  1.0
  Dy  Dy1  1  0.827  0.173  0.255  1.0
  Dy  Dy2  1  0.476  0.524  0.737  1.0
  Dy  Dy3  1  0.524  0.476  0.237  1.0
  Sn  Sn4  1  0.881  0.119  0.731  1.0
  Sn  Sn5  1  0.119  0.881  0.231  1.0
  Sn  Sn6  1  0.705  0.295  0.050  1.0
  Sn  Sn7  1  0.295  0.705  0.550  1.0
  Sn  Sn8  1  0.596  0.404  0.615  1.0
  Sn  Sn9  1  0.404  0.596  0.115  1.0
  Sn  Sn10  1  0.952  0.048  0.397  1.0
  Sn  Sn11  1  0.048  0.952  0.897  1.0
  Sn  Sn12  1  0.291  0.709  0.977  1.0
  Sn  Sn13  1  0.709  0.291  0.477  1.0
  Rh  Rh14  1  0.050  0.950  0.519  1.0
  Rh  Rh15  1  0.950  0.050  0.019  1.0
  Rh  Rh16  1  0.777  0.223  0.765  1.0
  Rh  Rh17  1  0.223  0.777  0.265  1.0
  Rh  Rh18  1  0.394  0.606  0.482  1.0
  Rh  Rh19  1  0.606  0.394  0.982  1.0
[/CIF]
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