The structure described by K5Tl3O crystallizes in the orthorhombic Cmcm space group. There are five inequivalent K sites. In the first K site, K(1) is bonded in a single-bond geometry to four equivalent Tl(1) and one O(2) atom. In the second K site, K(2) is bonded in a single-bond geometry to two equivalent Tl(1), two equivalent Tl(3), and one O(2) atom. In the third K site, K(3) is bonded in a water-like geometry to two equivalent Tl(3) and two equivalent O(1) atoms. In the fourth K site, K(4) is bonded in a single-bond geometry to two equivalent Tl(1), two equivalent Tl(2), and one O(2) atom. In the fifth K site, K(5) is bonded in a single-bond geometry to four equivalent Tl(2) and one O(1) atom. There are three inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 12-coordinate geometry to two equivalent K(2), two equivalent K(4), four equivalent K(1), one Tl(1), one Tl(2), and two equivalent Tl(3) atoms. In the second Tl site, Tl(2) is bonded in a 8-coordinate geometry to two equivalent K(4), four equivalent K(5), one Tl(1), and two equivalent Tl(3) atoms. In the third Tl site, Tl(3) is bonded in a distorted body-centered cubic geometry to two equivalent K(2), two equivalent K(3), two equivalent Tl(1), and two equivalent Tl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent K(5) and four equivalent K(3) atoms to form edge-sharing OK6 octahedra. In the second O site, O(2) is bonded in an octahedral geometry to two equivalent K(1), two equivalent K(2), and two equivalent K(4) atoms. is represented by the CIF card [CIF]
data_K5Tl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.949
_cell_length_b   16.949
_cell_length_c   8.816
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   151.440
_symmetry_Int_Tables_number   1
_cell_volume   1210.826
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.511  0.045  0.750  1.0
  K  K1  1  0.680  0.320  0.466  1.0
  K  K2  1  0.450  0.550  0.534  1.0
  K  K3  1  0.045  0.511  0.250  1.0
  K  K4  1  0.375  0.120  0.750  1.0
  K  K5  1  0.207  0.193  0.750  1.0
  K  K6  1  0.450  0.550  0.966  1.0
  K  K7  1  0.793  0.807  0.250  1.0
  K  K8  1  0.550  0.450  0.466  1.0
  K  K9  1  0.320  0.680  0.534  1.0
  K  K10  1  0.489  0.955  0.250  1.0
  K  K11  1  0.955  0.489  0.750  1.0
  K  K12  1  0.320  0.680  0.966  1.0
  K  K13  1  0.880  0.625  0.750  1.0
  K  K14  1  0.550  0.450  0.034  1.0
  K  K15  1  0.120  0.375  0.250  1.0
  K  K16  1  0.625  0.880  0.250  1.0
  K  K17  1  0.680  0.320  0.034  1.0
  K  K18  1  0.807  0.793  0.750  1.0
  K  K19  1  0.193  0.207  0.250  1.0
  Tl  Tl20  1  0.816  0.184  0.943  1.0
  Tl  Tl21  1  0.077  0.923  0.039  1.0
  Tl  Tl22  1  0.086  0.338  0.750  1.0
  Tl  Tl23  1  0.914  0.662  0.250  1.0
  Tl  Tl24  1  0.662  0.914  0.750  1.0
  Tl  Tl25  1  0.923  0.077  0.961  1.0
  Tl  Tl26  1  0.077  0.923  0.461  1.0
  Tl  Tl27  1  0.184  0.816  0.443  1.0
  Tl  Tl28  1  0.338  0.086  0.250  1.0
  Tl  Tl29  1  0.184  0.816  0.057  1.0
  Tl  Tl30  1  0.816  0.184  0.557  1.0
  Tl  Tl31  1  0.923  0.077  0.539  1.0
  O  O32  1  0.511  0.489  0.750  1.0
  O  O33  1  0.489  0.511  0.250  1.0
  O  O34  1  0.675  0.325  0.750  1.0
  O  O35  1  0.325  0.675  0.250  1.0
[/CIF]
.
The structure described by K5Tl3O crystallizes in the orthorhombic Cmcm space group. There are five inequivalent K sites. In the first K site, K(1) is bonded in a single-bond geometry to four equivalent Tl(1) and one O(2) atom. In the second K site, K(2) is bonded in a single-bond geometry to two equivalent Tl(1), two equivalent Tl(3), and one O(2) atom. In the third K site, K(3) is bonded in a water-like geometry to two equivalent Tl(3) and two equivalent O(1) atoms. In the fourth K site, K(4) is bonded in a single-bond geometry to two equivalent Tl(1), two equivalent Tl(2), and one O(2) atom. In the fifth K site, K(5) is bonded in a single-bond geometry to four equivalent Tl(2) and one O(1) atom. There are three inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 12-coordinate geometry to two equivalent K(2), two equivalent K(4), four equivalent K(1), one Tl(1), one Tl(2), and two equivalent Tl(3) atoms. In the second Tl site, Tl(2) is bonded in a 8-coordinate geometry to two equivalent K(4), four equivalent K(5), one Tl(1), and two equivalent Tl(3) atoms. In the third Tl site, Tl(3) is bonded in a distorted body-centered cubic geometry to two equivalent K(2), two equivalent K(3), two equivalent Tl(1), and two equivalent Tl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent K(5) and four equivalent K(3) atoms to form edge-sharing OK6 octahedra. In the second O site, O(2) is bonded in an octahedral geometry to two equivalent K(1), two equivalent K(2), and two equivalent K(4) atoms. is represented by the CIF card [CIF]
data_K5Tl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.949
_cell_length_b   16.949
_cell_length_c   8.816
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   151.440
_symmetry_Int_Tables_number   1
_cell_volume   1210.826
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.511  0.045  0.750  1.0
  K  K1  1  0.680  0.320  0.466  1.0
  K  K2  1  0.450  0.550  0.534  1.0
  K  K3  1  0.045  0.511  0.250  1.0
  K  K4  1  0.375  0.120  0.750  1.0
  K  K5  1  0.207  0.193  0.750  1.0
  K  K6  1  0.450  0.550  0.966  1.0
  K  K7  1  0.793  0.807  0.250  1.0
  K  K8  1  0.550  0.450  0.466  1.0
  K  K9  1  0.320  0.680  0.534  1.0
  K  K10  1  0.489  0.955  0.250  1.0
  K  K11  1  0.955  0.489  0.750  1.0
  K  K12  1  0.320  0.680  0.966  1.0
  K  K13  1  0.880  0.625  0.750  1.0
  K  K14  1  0.550  0.450  0.034  1.0
  K  K15  1  0.120  0.375  0.250  1.0
  K  K16  1  0.625  0.880  0.250  1.0
  K  K17  1  0.680  0.320  0.034  1.0
  K  K18  1  0.807  0.793  0.750  1.0
  K  K19  1  0.193  0.207  0.250  1.0
  Tl  Tl20  1  0.816  0.184  0.943  1.0
  Tl  Tl21  1  0.077  0.923  0.039  1.0
  Tl  Tl22  1  0.086  0.338  0.750  1.0
  Tl  Tl23  1  0.914  0.662  0.250  1.0
  Tl  Tl24  1  0.662  0.914  0.750  1.0
  Tl  Tl25  1  0.923  0.077  0.961  1.0
  Tl  Tl26  1  0.077  0.923  0.461  1.0
  Tl  Tl27  1  0.184  0.816  0.443  1.0
  Tl  Tl28  1  0.338  0.086  0.250  1.0
  Tl  Tl29  1  0.184  0.816  0.057  1.0
  Tl  Tl30  1  0.816  0.184  0.557  1.0
  Tl  Tl31  1  0.923  0.077  0.539  1.0
  O  O32  1  0.511  0.489  0.750  1.0
  O  O33  1  0.489  0.511  0.250  1.0
  O  O34  1  0.675  0.325  0.750  1.0
  O  O35  1  0.325  0.675  0.250  1.0
[/CIF]
.