The material described by CuWO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted WO6 octahedra that share corners with eight equivalent Cu(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. Cu(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CuO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent W(1) and one Cu(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Cu(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.663
_cell_length_b   5.009
_cell_length_c   5.770
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   91.382
_symmetry_Int_Tables_number   1
_cell_volume   134.740
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.500  0.250  0.664  1.0
  Cu  Cu1  1  0.500  0.750  0.336  1.0
  W  W2  1  0.000  0.250  0.175  1.0
  W  W3  1  0.000  0.750  0.825  1.0
  O  O4  1  0.740  0.093  0.377  1.0
  O  O5  1  0.260  0.407  0.377  1.0
  O  O6  1  0.260  0.907  0.623  1.0
  O  O7  1  0.740  0.593  0.623  1.0
  O  O8  1  0.781  0.068  0.893  1.0
  O  O9  1  0.219  0.432  0.893  1.0
  O  O10  1  0.219  0.932  0.107  1.0
  O  O11  1  0.781  0.568  0.107  1.0
[/CIF]
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The material described by CuWO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted WO6 octahedra that share corners with eight equivalent Cu(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. Cu(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CuO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent W(1) and one Cu(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Cu(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.663
_cell_length_b   5.009
_cell_length_c   5.770
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   91.382
_symmetry_Int_Tables_number   1
_cell_volume   134.740
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.500  0.250  0.664  1.0
  Cu  Cu1  1  0.500  0.750  0.336  1.0
  W  W2  1  0.000  0.250  0.175  1.0
  W  W3  1  0.000  0.750  0.825  1.0
  O  O4  1  0.740  0.093  0.377  1.0
  O  O5  1  0.260  0.407  0.377  1.0
  O  O6  1  0.260  0.907  0.623  1.0
  O  O7  1  0.740  0.593  0.623  1.0
  O  O8  1  0.781  0.068  0.893  1.0
  O  O9  1  0.219  0.432  0.893  1.0
  O  O10  1  0.219  0.932  0.107  1.0
  O  O11  1  0.781  0.568  0.107  1.0
[/CIF]
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