The material described by TiRhGe crystallizes in the orthorhombic Ima2 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 7-coordinate geometry to two equivalent Rh(2), two equivalent Ge(1), and four equivalent Ge(2) atoms. In the second Ti site, Ti(2) is bonded in a 9-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), one Ge(1), and four equivalent Ge(2) atoms. In the third Ti site, Ti(3) is bonded in a 11-coordinate geometry to two equivalent Rh(1), four equivalent Rh(2), one Ge(1), and four equivalent Ge(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to two equivalent Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to one Ti(1), one Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Ti(2), one Ti(3), two equivalent Ti(1), two equivalent Rh(1), and four equivalent Rh(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ti(3), one Rh(1), and two equivalent Rh(2) atoms. is represented by the CIF file [CIF]
data_TiGeRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.487
_cell_length_b   7.487
_cell_length_c   7.487
_cell_angle_alpha   127.508
_cell_angle_beta   123.064
_cell_angle_gamma   81.111
_symmetry_Int_Tables_number   1
_cell_volume   268.871
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.978  0.743  0.265  1.0
  Ti  Ti1  1  0.022  0.287  0.765  1.0
  Ti  Ti2  1  0.249  0.164  0.415  1.0
  Ti  Ti3  1  0.751  0.166  0.915  1.0
  Ti  Ti4  1  0.557  0.356  0.299  1.0
  Ti  Ti5  1  0.443  0.742  0.799  1.0
  Ge  Ge6  1  0.786  0.787  0.501  1.0
  Ge  Ge7  1  0.214  0.714  0.001  1.0
  Ge  Ge8  1  0.338  0.079  0.753  1.0
  Ge  Ge9  1  0.662  0.415  0.741  1.0
  Ge  Ge10  1  0.174  0.415  0.253  1.0
  Ge  Ge11  1  0.826  0.079  0.241  1.0
  Rh  Rh12  1  0.500  0.488  0.988  1.0
  Rh  Rh13  1  1.000  0.488  0.488  1.0
  Rh  Rh14  1  0.170  0.005  0.922  1.0
  Rh  Rh15  1  0.830  0.752  0.835  1.0
  Rh  Rh16  1  0.417  0.753  0.422  1.0
  Rh  Rh17  1  0.583  0.005  0.335  1.0
[/CIF]
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The material described by TiRhGe crystallizes in the orthorhombic Ima2 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 7-coordinate geometry to two equivalent Rh(2), two equivalent Ge(1), and four equivalent Ge(2) atoms. In the second Ti site, Ti(2) is bonded in a 9-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), one Ge(1), and four equivalent Ge(2) atoms. In the third Ti site, Ti(3) is bonded in a 11-coordinate geometry to two equivalent Rh(1), four equivalent Rh(2), one Ge(1), and four equivalent Ge(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to two equivalent Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to one Ti(1), one Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Ti(2), one Ti(3), two equivalent Ti(1), two equivalent Rh(1), and four equivalent Rh(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ti(3), one Rh(1), and two equivalent Rh(2) atoms. is represented by the CIF file [CIF]
data_TiGeRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.487
_cell_length_b   7.487
_cell_length_c   7.487
_cell_angle_alpha   127.508
_cell_angle_beta   123.064
_cell_angle_gamma   81.111
_symmetry_Int_Tables_number   1
_cell_volume   268.871
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.978  0.743  0.265  1.0
  Ti  Ti1  1  0.022  0.287  0.765  1.0
  Ti  Ti2  1  0.249  0.164  0.415  1.0
  Ti  Ti3  1  0.751  0.166  0.915  1.0
  Ti  Ti4  1  0.557  0.356  0.299  1.0
  Ti  Ti5  1  0.443  0.742  0.799  1.0
  Ge  Ge6  1  0.786  0.787  0.501  1.0
  Ge  Ge7  1  0.214  0.714  0.001  1.0
  Ge  Ge8  1  0.338  0.079  0.753  1.0
  Ge  Ge9  1  0.662  0.415  0.741  1.0
  Ge  Ge10  1  0.174  0.415  0.253  1.0
  Ge  Ge11  1  0.826  0.079  0.241  1.0
  Rh  Rh12  1  0.500  0.488  0.988  1.0
  Rh  Rh13  1  1.000  0.488  0.488  1.0
  Rh  Rh14  1  0.170  0.005  0.922  1.0
  Rh  Rh15  1  0.830  0.752  0.835  1.0
  Rh  Rh16  1  0.417  0.753  0.422  1.0
  Rh  Rh17  1  0.583  0.005  0.335  1.0
[/CIF]
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