The structure described by SbCl6SbSeCl9SeCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two SbCl6 clusters, two SbSeCl9 clusters, and two SeCl3 clusters. In each SbCl6 cluster, Sb(2) is bonded in an octahedral geometry to one Cl(2), one Cl(4), two equivalent Cl(3), and two equivalent Cl(5) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(2) atom. In each SbSeCl9 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(6), one Cl(8), two equivalent Cl(7), and two equivalent Cl(9) atoms. Se(1) is bonded in a 3-coordinate geometry to one Cl(10), one Cl(6), and two equivalent Cl(1) atoms. There are six inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(10) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the fourth Cl site, Cl(6) is bonded in a distorted L-shaped geometry to one Sb(1) and one Se(1) atom. In the fifth Cl site, Cl(7) is bonded in a distorted single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(1) atom. In each SeCl3 cluster, Se(2) is bonded in a 3-coordinate geometry to one Cl(11) and two equivalent Cl(12) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(12) is bonded in a single-bond geometry to one Se(2) atom. In the second Cl site, Cl(11) is bonded in a single-bond geometry to one Se(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbSeCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.946
_cell_length_b   9.492
_cell_length_c   12.726
_cell_angle_alpha   76.770
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1287.162
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.977  0.379  1.0
  Sb  Sb1  1  0.750  0.023  0.621  1.0
  Sb  Sb2  1  0.250  0.333  0.831  1.0
  Sb  Sb3  1  0.750  0.667  0.169  1.0
  Se  Se4  1  0.750  0.628  0.680  1.0
  Se  Se5  1  0.250  0.372  0.320  1.0
  Se  Se6  1  0.250  0.936  0.882  1.0
  Se  Se7  1  0.750  0.064  0.118  1.0
  Cl  Cl8  1  0.599  0.518  0.623  1.0
  Cl  Cl9  1  0.099  0.482  0.377  1.0
  Cl  Cl10  1  0.750  0.840  0.995  1.0
  Cl  Cl11  1  0.250  0.160  0.005  1.0
  Cl  Cl12  1  0.904  0.819  0.227  1.0
  Cl  Cl13  1  0.404  0.181  0.773  1.0
  Cl  Cl14  1  0.096  0.181  0.773  1.0
  Cl  Cl15  1  0.596  0.819  0.227  1.0
  Cl  Cl16  1  0.750  0.511  0.342  1.0
  Cl  Cl17  1  0.250  0.489  0.658  1.0
  Cl  Cl18  1  0.906  0.536  0.106  1.0
  Cl  Cl19  1  0.406  0.464  0.894  1.0
  Cl  Cl20  1  0.094  0.464  0.894  1.0
  Cl  Cl21  1  0.594  0.536  0.106  1.0
  Cl  Cl22  1  0.401  0.482  0.377  1.0
  Cl  Cl23  1  0.901  0.518  0.623  1.0
  Cl  Cl24  1  0.750  0.866  0.494  1.0
  Cl  Cl25  1  0.250  0.134  0.506  1.0
  Cl  Cl26  1  0.597  0.858  0.723  1.0
  Cl  Cl27  1  0.097  0.142  0.277  1.0
  Cl  Cl28  1  0.403  0.142  0.277  1.0
  Cl  Cl29  1  0.903  0.858  0.723  1.0
  Cl  Cl30  1  0.750  0.152  0.759  1.0
  Cl  Cl31  1  0.250  0.848  0.241  1.0
  Cl  Cl32  1  0.595  0.165  0.523  1.0
  Cl  Cl33  1  0.095  0.835  0.477  1.0
  Cl  Cl34  1  0.405  0.835  0.477  1.0
  Cl  Cl35  1  0.905  0.165  0.523  1.0
  Cl  Cl36  1  0.250  0.488  0.152  1.0
  Cl  Cl37  1  0.750  0.512  0.848  1.0
  Cl  Cl38  1  0.750  0.169  0.251  1.0
  Cl  Cl39  1  0.250  0.831  0.749  1.0
  Cl  Cl40  1  0.900  0.179  0.026  1.0
  Cl  Cl41  1  0.400  0.821  0.974  1.0
  Cl  Cl42  1  0.100  0.821  0.974  1.0
  Cl  Cl43  1  0.600  0.179  0.026  1.0
[/CIF]
.
The structure described by SbCl6SbSeCl9SeCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two SbCl6 clusters, two SbSeCl9 clusters, and two SeCl3 clusters. In each SbCl6 cluster, Sb(2) is bonded in an octahedral geometry to one Cl(2), one Cl(4), two equivalent Cl(3), and two equivalent Cl(5) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(2) atom. In each SbSeCl9 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(6), one Cl(8), two equivalent Cl(7), and two equivalent Cl(9) atoms. Se(1) is bonded in a 3-coordinate geometry to one Cl(10), one Cl(6), and two equivalent Cl(1) atoms. There are six inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(10) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the fourth Cl site, Cl(6) is bonded in a distorted L-shaped geometry to one Sb(1) and one Se(1) atom. In the fifth Cl site, Cl(7) is bonded in a distorted single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(1) atom. In each SeCl3 cluster, Se(2) is bonded in a 3-coordinate geometry to one Cl(11) and two equivalent Cl(12) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(12) is bonded in a single-bond geometry to one Se(2) atom. In the second Cl site, Cl(11) is bonded in a single-bond geometry to one Se(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbSeCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.946
_cell_length_b   9.492
_cell_length_c   12.726
_cell_angle_alpha   76.770
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1287.162
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.977  0.379  1.0
  Sb  Sb1  1  0.750  0.023  0.621  1.0
  Sb  Sb2  1  0.250  0.333  0.831  1.0
  Sb  Sb3  1  0.750  0.667  0.169  1.0
  Se  Se4  1  0.750  0.628  0.680  1.0
  Se  Se5  1  0.250  0.372  0.320  1.0
  Se  Se6  1  0.250  0.936  0.882  1.0
  Se  Se7  1  0.750  0.064  0.118  1.0
  Cl  Cl8  1  0.599  0.518  0.623  1.0
  Cl  Cl9  1  0.099  0.482  0.377  1.0
  Cl  Cl10  1  0.750  0.840  0.995  1.0
  Cl  Cl11  1  0.250  0.160  0.005  1.0
  Cl  Cl12  1  0.904  0.819  0.227  1.0
  Cl  Cl13  1  0.404  0.181  0.773  1.0
  Cl  Cl14  1  0.096  0.181  0.773  1.0
  Cl  Cl15  1  0.596  0.819  0.227  1.0
  Cl  Cl16  1  0.750  0.511  0.342  1.0
  Cl  Cl17  1  0.250  0.489  0.658  1.0
  Cl  Cl18  1  0.906  0.536  0.106  1.0
  Cl  Cl19  1  0.406  0.464  0.894  1.0
  Cl  Cl20  1  0.094  0.464  0.894  1.0
  Cl  Cl21  1  0.594  0.536  0.106  1.0
  Cl  Cl22  1  0.401  0.482  0.377  1.0
  Cl  Cl23  1  0.901  0.518  0.623  1.0
  Cl  Cl24  1  0.750  0.866  0.494  1.0
  Cl  Cl25  1  0.250  0.134  0.506  1.0
  Cl  Cl26  1  0.597  0.858  0.723  1.0
  Cl  Cl27  1  0.097  0.142  0.277  1.0
  Cl  Cl28  1  0.403  0.142  0.277  1.0
  Cl  Cl29  1  0.903  0.858  0.723  1.0
  Cl  Cl30  1  0.750  0.152  0.759  1.0
  Cl  Cl31  1  0.250  0.848  0.241  1.0
  Cl  Cl32  1  0.595  0.165  0.523  1.0
  Cl  Cl33  1  0.095  0.835  0.477  1.0
  Cl  Cl34  1  0.405  0.835  0.477  1.0
  Cl  Cl35  1  0.905  0.165  0.523  1.0
  Cl  Cl36  1  0.250  0.488  0.152  1.0
  Cl  Cl37  1  0.750  0.512  0.848  1.0
  Cl  Cl38  1  0.750  0.169  0.251  1.0
  Cl  Cl39  1  0.250  0.831  0.749  1.0
  Cl  Cl40  1  0.900  0.179  0.026  1.0
  Cl  Cl41  1  0.400  0.821  0.974  1.0
  Cl  Cl42  1  0.100  0.821  0.974  1.0
  Cl  Cl43  1  0.600  0.179  0.026  1.0
[/CIF]
.