The structure described by SO2ClF is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of eight sulfuryl chloride fluoride molecules. S(1) is bonded in a distorted tetrahedral geometry to one O(1,2); one O(3); one Cl(2); and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1,2) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Cl(2) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_SClO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.979
_cell_length_b   9.346
_cell_length_c   11.194
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   834.818
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.006  0.192  0.554  1.0
  S  S1  1  0.516  0.100  0.196  1.0
  S  S2  1  0.484  0.100  0.696  1.0
  S  S3  1  0.516  0.600  0.304  1.0
  S  S4  1  0.994  0.692  0.446  1.0
  S  S5  1  0.994  0.192  0.054  1.0
  S  S6  1  0.006  0.692  0.946  1.0
  S  S7  1  0.484  0.600  0.804  1.0
  Cl  Cl8  1  0.513  0.443  0.924  1.0
  Cl  Cl9  1  0.513  0.943  0.576  1.0
  Cl  Cl10  1  0.005  0.346  0.177  1.0
  Cl  Cl11  1  0.995  0.846  0.823  1.0
  Cl  Cl12  1  0.995  0.346  0.677  1.0
  Cl  Cl13  1  0.487  0.443  0.424  1.0
  Cl  Cl14  1  0.005  0.846  0.323  1.0
  Cl  Cl15  1  0.487  0.943  0.076  1.0
  O  O16  1  0.538  0.732  0.856  1.0
  O  O17  1  0.940  0.062  0.602  1.0
  O  O18  1  0.940  0.562  0.898  1.0
  O  O19  1  0.838  0.699  0.508  1.0
  O  O20  1  0.462  0.232  0.144  1.0
  O  O21  1  0.162  0.199  0.492  1.0
  O  O22  1  0.060  0.062  0.102  1.0
  O  O23  1  0.538  0.232  0.644  1.0
  O  O24  1  0.672  0.084  0.256  1.0
  O  O25  1  0.328  0.584  0.744  1.0
  O  O26  1  0.462  0.732  0.356  1.0
  O  O27  1  0.672  0.584  0.244  1.0
  O  O28  1  0.838  0.199  0.992  1.0
  O  O29  1  0.060  0.562  0.398  1.0
  O  O30  1  0.162  0.699  0.008  1.0
  O  O31  1  0.328  0.084  0.756  1.0
  F  F32  1  0.868  0.253  0.465  1.0
  F  F33  1  0.626  0.053  0.787  1.0
  F  F34  1  0.374  0.053  0.287  1.0
  F  F35  1  0.868  0.753  0.035  1.0
  F  F36  1  0.132  0.753  0.535  1.0
  F  F37  1  0.374  0.553  0.213  1.0
  F  F38  1  0.132  0.253  0.965  1.0
  F  F39  1  0.626  0.553  0.713  1.0
[/CIF]
.
The structure described by SO2ClF is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of eight sulfuryl chloride fluoride molecules. S(1) is bonded in a distorted tetrahedral geometry to one O(1,2); one O(3); one Cl(2); and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1,2) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Cl(2) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_SClO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.979
_cell_length_b   9.346
_cell_length_c   11.194
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   834.818
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.006  0.192  0.554  1.0
  S  S1  1  0.516  0.100  0.196  1.0
  S  S2  1  0.484  0.100  0.696  1.0
  S  S3  1  0.516  0.600  0.304  1.0
  S  S4  1  0.994  0.692  0.446  1.0
  S  S5  1  0.994  0.192  0.054  1.0
  S  S6  1  0.006  0.692  0.946  1.0
  S  S7  1  0.484  0.600  0.804  1.0
  Cl  Cl8  1  0.513  0.443  0.924  1.0
  Cl  Cl9  1  0.513  0.943  0.576  1.0
  Cl  Cl10  1  0.005  0.346  0.177  1.0
  Cl  Cl11  1  0.995  0.846  0.823  1.0
  Cl  Cl12  1  0.995  0.346  0.677  1.0
  Cl  Cl13  1  0.487  0.443  0.424  1.0
  Cl  Cl14  1  0.005  0.846  0.323  1.0
  Cl  Cl15  1  0.487  0.943  0.076  1.0
  O  O16  1  0.538  0.732  0.856  1.0
  O  O17  1  0.940  0.062  0.602  1.0
  O  O18  1  0.940  0.562  0.898  1.0
  O  O19  1  0.838  0.699  0.508  1.0
  O  O20  1  0.462  0.232  0.144  1.0
  O  O21  1  0.162  0.199  0.492  1.0
  O  O22  1  0.060  0.062  0.102  1.0
  O  O23  1  0.538  0.232  0.644  1.0
  O  O24  1  0.672  0.084  0.256  1.0
  O  O25  1  0.328  0.584  0.744  1.0
  O  O26  1  0.462  0.732  0.356  1.0
  O  O27  1  0.672  0.584  0.244  1.0
  O  O28  1  0.838  0.199  0.992  1.0
  O  O29  1  0.060  0.562  0.398  1.0
  O  O30  1  0.162  0.699  0.008  1.0
  O  O31  1  0.328  0.084  0.756  1.0
  F  F32  1  0.868  0.253  0.465  1.0
  F  F33  1  0.626  0.053  0.787  1.0
  F  F34  1  0.374  0.053  0.287  1.0
  F  F35  1  0.868  0.753  0.035  1.0
  F  F36  1  0.132  0.753  0.535  1.0
  F  F37  1  0.374  0.553  0.213  1.0
  F  F38  1  0.132  0.253  0.965  1.0
  F  F39  1  0.626  0.553  0.713  1.0
[/CIF]
.