The compound described by Ba3SrCo(CuO4)3 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms to form BaO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent Ba(2)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Cu(1)O6 octahedra, and faces with four equivalent Cu(2)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(1), one O(3), two equivalent O(2), four equivalent O(6), and four equivalent O(7) atoms to form BaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with four equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Cu(1)O6 octahedra, and faces with four equivalent Cu(2)O6 octahedra. Sr(1) is bonded to one O(1), one O(3), two equivalent O(2), four equivalent O(4), and four equivalent O(5) atoms to form SrO12 cuboctahedra that share corners with four equivalent Ba(2)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Cu(1)O6 octahedra, and faces with four equivalent Cu(2)O6 octahedra. Co(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Cu(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms to form CuO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra, corners with four equivalent Cu(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second Cu site, Cu(2) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(2) atoms to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. There are seven inequivalent O sites. In the first O site, O(1) is bonded to one Ba(2), two equivalent Ba(1), one Sr(1), and two equivalent Cu(1) atoms to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(1)Ba3SrCu2 octahedra, corners with eight equivalent O(7)Ba4CoCu octahedra, edges with four equivalent O(2)Ba3SrCu2 octahedra, faces with four equivalent O(4)Ba2Sr2Cu2 octahedra, and faces with four equivalent O(6)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 5-60°. In the second O site, O(2) is bonded to one Ba(2), two equivalent Ba(1), one Sr(1), and two equivalent Cu(2) atoms to form distorted OBa3SrCu2 octahedra that share corners with four equivalent O(4)Ba2Sr2Cu2 octahedra, corners with four equivalent O(7)Ba4CoCu octahedra, corners with four equivalent O(6)Ba4Cu2 octahedra, corners with six equivalent O(2)Ba3SrCu2 octahedra, edges with two equivalent O(1)Ba3SrCu2 octahedra, faces with two equivalent O(4)Ba2Sr2Cu2 octahedra, faces with two equivalent O(7)Ba4CoCu octahedra, and faces with two equivalent O(6)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the third O site, O(3) is bonded in a distorted linear geometry to one Ba(2), two equivalent Ba(1), one Sr(1), and two equivalent Co(1) atoms. In the fourth O site, O(4) is bonded to two equivalent Ba(1), two equivalent Sr(1), one Cu(1), and one Cu(2) atom to form distorted OBa2Sr2Cu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Cu2 octahedra, corners with two equivalent O(7)Ba4CoCu octahedra, corners with four equivalent O(2)Ba3SrCu2 octahedra, corners with four equivalent O(6)Ba4Cu2 octahedra, edges with two equivalent O(4)Ba2Sr2Cu2 octahedra,  a faceface with one O(4)Ba2Sr2Cu2 octahedra,  a faceface with one O(7)Ba4CoCu octahedra,  a faceface with one O(6)Ba4Cu2 octahedra, faces with two equivalent O(1)Ba3SrCu2 octahedra, and faces with two equivalent O(2)Ba3SrCu2 octahedra. The corner-sharing octahedral tilt angles range from 3-60°. In the fifth O site, O(5) is bonded in a distorted linear geometry to two equivalent Ba(1), two equivalent Sr(1), one Co(1), and one Cu(2) atom. In the sixth O site, O(6) is bonded to two equivalent Ba(1), two equivalent Ba(2), one Cu(1), and one Cu(2) atom to form distorted OBa4Cu2 octahedra that share corners with two equivalent O(6)Ba4Cu2 octahedra, corners with four equivalent O(4)Ba2Sr2Cu2 octahedra, corners with four equivalent O(2)Ba3SrCu2 octahedra, corners with six equivalent O(7)Ba4CoCu octahedra, edges with two equivalent O(7)Ba4CoCu octahedra, edges with two equivalent O(6)Ba4Cu2 octahedra,  a faceface with one O(4)Ba2Sr2Cu2 octahedra,  a faceface with one O(7)Ba4CoCu octahedra,  a faceface with one O(6)Ba4Cu2 octahedra, faces with two equivalent O(1)Ba3SrCu2 octahedra, and faces with two equivalent O(2)Ba3SrCu2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the seventh O site, O(7) is bonded to two equivalent Ba(1), two equivalent Ba(2), one Co(1), and one Cu(2) atom to form distorted OBa4CoCu octahedra that share corners with two equivalent O(4)Ba2Sr2Cu2 octahedra, corners with two equivalent O(7)Ba4CoCu octahedra, corners with four equivalent O(1)Ba3SrCu2 octahedra, corners with four equivalent O(2)Ba3SrCu2 octahedra, corners with six equivalent O(6)Ba4Cu2 octahedra, edges with two equivalent O(7)Ba4CoCu octahedra, edges with two equivalent O(6)Ba4Cu2 octahedra,  a faceface with one O(4)Ba2Sr2Cu2 octahedra,  a faceface with one O(7)Ba4CoCu octahedra,  a faceface with one O(6)Ba4Cu2 octahedra, and faces with two equivalent O(2)Ba3SrCu2 octahedra. The corner-sharing octahedral tilt angles range from 2-63°. is represented by the CIF card [CIF]
data_Ba3SrCo(CuO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.971
_cell_length_b   7.971
_cell_length_c   3.984
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.158
_symmetry_Int_Tables_number   1
_cell_volume   253.162
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.751  0.249  0.500  1.0
  Ba  Ba1  1  0.248  0.248  0.500  1.0
  Ba  Ba2  1  0.249  0.751  0.500  1.0
  Sr  Sr3  1  0.753  0.753  0.500  1.0
  Co  Co4  1  0.503  0.503  0.000  1.0
  Cu  Cu5  1  1.000  1.000  0.000  1.0
  Cu  Cu6  1  0.000  0.501  0.000  1.0
  Cu  Cu7  1  0.501  0.000  0.000  1.0
  O  O8  1  0.992  0.992  0.500  1.0
  O  O9  1  0.992  0.508  0.500  1.0
  O  O10  1  0.508  0.992  0.500  1.0
  O  O11  1  0.504  0.504  0.500  1.0
  O  O12  1  0.749  0.988  0.000  1.0
  O  O13  1  0.743  0.509  0.000  1.0
  O  O14  1  0.252  0.997  0.000  1.0
  O  O15  1  0.260  0.502  0.000  1.0
  O  O16  1  0.997  0.252  0.000  1.0
  O  O17  1  0.988  0.749  0.000  1.0
  O  O18  1  0.502  0.260  0.000  1.0
  O  O19  1  0.509  0.743  0.000  1.0
[/CIF]
.
The compound described by Ba3SrCo(CuO4)3 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms to form BaO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent Ba(2)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Cu(1)O6 octahedra, and faces with four equivalent Cu(2)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(1), one O(3), two equivalent O(2), four equivalent O(6), and four equivalent O(7) atoms to form BaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with four equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Cu(1)O6 octahedra, and faces with four equivalent Cu(2)O6 octahedra. Sr(1) is bonded to one O(1), one O(3), two equivalent O(2), four equivalent O(4), and four equivalent O(5) atoms to form SrO12 cuboctahedra that share corners with four equivalent Ba(2)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Cu(1)O6 octahedra, and faces with four equivalent Cu(2)O6 octahedra. Co(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Cu(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms to form CuO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra, corners with four equivalent Cu(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second Cu site, Cu(2) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(2) atoms to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. There are seven inequivalent O sites. In the first O site, O(1) is bonded to one Ba(2), two equivalent Ba(1), one Sr(1), and two equivalent Cu(1) atoms to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(1)Ba3SrCu2 octahedra, corners with eight equivalent O(7)Ba4CoCu octahedra, edges with four equivalent O(2)Ba3SrCu2 octahedra, faces with four equivalent O(4)Ba2Sr2Cu2 octahedra, and faces with four equivalent O(6)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 5-60°. In the second O site, O(2) is bonded to one Ba(2), two equivalent Ba(1), one Sr(1), and two equivalent Cu(2) atoms to form distorted OBa3SrCu2 octahedra that share corners with four equivalent O(4)Ba2Sr2Cu2 octahedra, corners with four equivalent O(7)Ba4CoCu octahedra, corners with four equivalent O(6)Ba4Cu2 octahedra, corners with six equivalent O(2)Ba3SrCu2 octahedra, edges with two equivalent O(1)Ba3SrCu2 octahedra, faces with two equivalent O(4)Ba2Sr2Cu2 octahedra, faces with two equivalent O(7)Ba4CoCu octahedra, and faces with two equivalent O(6)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the third O site, O(3) is bonded in a distorted linear geometry to one Ba(2), two equivalent Ba(1), one Sr(1), and two equivalent Co(1) atoms. In the fourth O site, O(4) is bonded to two equivalent Ba(1), two equivalent Sr(1), one Cu(1), and one Cu(2) atom to form distorted OBa2Sr2Cu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Cu2 octahedra, corners with two equivalent O(7)Ba4CoCu octahedra, corners with four equivalent O(2)Ba3SrCu2 octahedra, corners with four equivalent O(6)Ba4Cu2 octahedra, edges with two equivalent O(4)Ba2Sr2Cu2 octahedra,  a faceface with one O(4)Ba2Sr2Cu2 octahedra,  a faceface with one O(7)Ba4CoCu octahedra,  a faceface with one O(6)Ba4Cu2 octahedra, faces with two equivalent O(1)Ba3SrCu2 octahedra, and faces with two equivalent O(2)Ba3SrCu2 octahedra. The corner-sharing octahedral tilt angles range from 3-60°. In the fifth O site, O(5) is bonded in a distorted linear geometry to two equivalent Ba(1), two equivalent Sr(1), one Co(1), and one Cu(2) atom. In the sixth O site, O(6) is bonded to two equivalent Ba(1), two equivalent Ba(2), one Cu(1), and one Cu(2) atom to form distorted OBa4Cu2 octahedra that share corners with two equivalent O(6)Ba4Cu2 octahedra, corners with four equivalent O(4)Ba2Sr2Cu2 octahedra, corners with four equivalent O(2)Ba3SrCu2 octahedra, corners with six equivalent O(7)Ba4CoCu octahedra, edges with two equivalent O(7)Ba4CoCu octahedra, edges with two equivalent O(6)Ba4Cu2 octahedra,  a faceface with one O(4)Ba2Sr2Cu2 octahedra,  a faceface with one O(7)Ba4CoCu octahedra,  a faceface with one O(6)Ba4Cu2 octahedra, faces with two equivalent O(1)Ba3SrCu2 octahedra, and faces with two equivalent O(2)Ba3SrCu2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the seventh O site, O(7) is bonded to two equivalent Ba(1), two equivalent Ba(2), one Co(1), and one Cu(2) atom to form distorted OBa4CoCu octahedra that share corners with two equivalent O(4)Ba2Sr2Cu2 octahedra, corners with two equivalent O(7)Ba4CoCu octahedra, corners with four equivalent O(1)Ba3SrCu2 octahedra, corners with four equivalent O(2)Ba3SrCu2 octahedra, corners with six equivalent O(6)Ba4Cu2 octahedra, edges with two equivalent O(7)Ba4CoCu octahedra, edges with two equivalent O(6)Ba4Cu2 octahedra,  a faceface with one O(4)Ba2Sr2Cu2 octahedra,  a faceface with one O(7)Ba4CoCu octahedra,  a faceface with one O(6)Ba4Cu2 octahedra, and faces with two equivalent O(2)Ba3SrCu2 octahedra. The corner-sharing octahedral tilt angles range from 2-63°. is represented by the CIF card [CIF]
data_Ba3SrCo(CuO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.971
_cell_length_b   7.971
_cell_length_c   3.984
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.158
_symmetry_Int_Tables_number   1
_cell_volume   253.162
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.751  0.249  0.500  1.0
  Ba  Ba1  1  0.248  0.248  0.500  1.0
  Ba  Ba2  1  0.249  0.751  0.500  1.0
  Sr  Sr3  1  0.753  0.753  0.500  1.0
  Co  Co4  1  0.503  0.503  0.000  1.0
  Cu  Cu5  1  1.000  1.000  0.000  1.0
  Cu  Cu6  1  0.000  0.501  0.000  1.0
  Cu  Cu7  1  0.501  0.000  0.000  1.0
  O  O8  1  0.992  0.992  0.500  1.0
  O  O9  1  0.992  0.508  0.500  1.0
  O  O10  1  0.508  0.992  0.500  1.0
  O  O11  1  0.504  0.504  0.500  1.0
  O  O12  1  0.749  0.988  0.000  1.0
  O  O13  1  0.743  0.509  0.000  1.0
  O  O14  1  0.252  0.997  0.000  1.0
  O  O15  1  0.260  0.502  0.000  1.0
  O  O16  1  0.997  0.252  0.000  1.0
  O  O17  1  0.988  0.749  0.000  1.0
  O  O18  1  0.502  0.260  0.000  1.0
  O  O19  1  0.509  0.743  0.000  1.0
[/CIF]
.