The structure described by K5AuP2 crystallizes in the hexagonal P6_3/mmc space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a distorted trigonal planar geometry to three equivalent P(1) atoms. In the second K site, K(2) is bonded in a trigonal planar geometry to three equivalent Au(1) atoms. In the third K site, K(3) is bonded to four equivalent P(1) atoms to form distorted KP4 tetrahedra that share corners with six equivalent K(3)P4 tetrahedra, corners with four equivalent Au(1)K3P2 trigonal bipyramids, and edges with three equivalent K(3)P4 tetrahedra. Au(1) is bonded to three equivalent K(2) and two equivalent P(1) atoms to form distorted AuK3P2 trigonal bipyramids that share corners with eight equivalent K(3)P4 tetrahedra and corners with six equivalent Au(1)K3P2 trigonal bipyramids. P(1) is bonded in a 8-coordinate geometry to three equivalent K(1), four equivalent K(3), and one Au(1) atom. is represented by the CIF card [CIF]
data_K5P2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.656
_cell_length_b   5.656
_cell_length_c   18.714
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   518.465
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.854  1.0
  K  K1  1  0.000  0.000  0.646  1.0
  K  K2  1  0.333  0.667  0.750  1.0
  K  K3  1  0.000  0.000  0.354  1.0
  K  K4  1  0.333  0.667  0.549  1.0
  K  K5  1  0.667  0.333  0.250  1.0
  K  K6  1  0.667  0.333  0.451  1.0
  K  K7  1  0.667  0.333  0.049  1.0
  K  K8  1  0.333  0.667  0.951  1.0
  K  K9  1  0.000  0.000  0.146  1.0
  P  P10  1  0.333  0.667  0.123  1.0
  P  P11  1  0.667  0.333  0.623  1.0
  P  P12  1  0.667  0.333  0.877  1.0
  P  P13  1  0.333  0.667  0.377  1.0
  Au  Au14  1  0.667  0.333  0.750  1.0
  Au  Au15  1  0.333  0.667  0.250  1.0
[/CIF]
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The structure described by K5AuP2 crystallizes in the hexagonal P6_3/mmc space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a distorted trigonal planar geometry to three equivalent P(1) atoms. In the second K site, K(2) is bonded in a trigonal planar geometry to three equivalent Au(1) atoms. In the third K site, K(3) is bonded to four equivalent P(1) atoms to form distorted KP4 tetrahedra that share corners with six equivalent K(3)P4 tetrahedra, corners with four equivalent Au(1)K3P2 trigonal bipyramids, and edges with three equivalent K(3)P4 tetrahedra. Au(1) is bonded to three equivalent K(2) and two equivalent P(1) atoms to form distorted AuK3P2 trigonal bipyramids that share corners with eight equivalent K(3)P4 tetrahedra and corners with six equivalent Au(1)K3P2 trigonal bipyramids. P(1) is bonded in a 8-coordinate geometry to three equivalent K(1), four equivalent K(3), and one Au(1) atom. is represented by the CIF card [CIF]
data_K5P2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.656
_cell_length_b   5.656
_cell_length_c   18.714
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   518.465
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.854  1.0
  K  K1  1  0.000  0.000  0.646  1.0
  K  K2  1  0.333  0.667  0.750  1.0
  K  K3  1  0.000  0.000  0.354  1.0
  K  K4  1  0.333  0.667  0.549  1.0
  K  K5  1  0.667  0.333  0.250  1.0
  K  K6  1  0.667  0.333  0.451  1.0
  K  K7  1  0.667  0.333  0.049  1.0
  K  K8  1  0.333  0.667  0.951  1.0
  K  K9  1  0.000  0.000  0.146  1.0
  P  P10  1  0.333  0.667  0.123  1.0
  P  P11  1  0.667  0.333  0.623  1.0
  P  P12  1  0.667  0.333  0.877  1.0
  P  P13  1  0.333  0.667  0.377  1.0
  Au  Au14  1  0.667  0.333  0.750  1.0
  Au  Au15  1  0.333  0.667  0.250  1.0
[/CIF]
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