The material described by Rh(CO)4Ga2Cl7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Ga2Cl7 clusters and two Rh(CO)4 clusters. In each Ga2Cl7 cluster, there are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom to form corner-sharing GaCl4 tetrahedra. In the second Ga site, Ga(2) is bonded to one Cl(1), one Cl(2), one Cl(3), and one Cl(5) atom to form corner-sharing GaCl4 tetrahedra. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. In the fifth Cl site, Cl(5) is bonded in a bent 120 degrees geometry to one Ga(1) and one Ga(2) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Ga(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Ga(1) atom. In one of the Rh(CO)4 clusters, Rh(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Rh(1) and one O(1,4) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Rh(1) and one O(1,4) atom. O(1,4) is bonded in a single-bond geometry to one C(1) atom. In one of the Rh(CO)4 clusters, Rh(2) is bonded in a square co-planar geometry to two equivalent C(3) and two equivalent C(4) atoms. There are two inequivalent C sites. In the first C site, C(3) is bonded in a distorted linear geometry to one Rh(2) and one O(2) atom. In the second C site, C(4) is bonded in a distorted linear geometry to one Rh(2) and one O(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(4) atom. is represented by the CIF card [CIF]
data_Ga2RhC4Cl7O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.035
_cell_length_b   10.046
_cell_length_c   10.610
_cell_angle_alpha   76.408
_cell_angle_beta   76.829
_cell_angle_gamma   65.692
_symmetry_Int_Tables_number   1
_cell_volume   937.073
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.805  0.167  0.176  1.0
  Ga  Ga1  1  0.567  0.704  0.578  1.0
  Ga  Ga2  1  0.195  0.833  0.824  1.0
  Ga  Ga3  1  0.433  0.296  0.422  1.0
  Rh  Rh4  1  0.000  0.500  0.500  1.0
  Rh  Rh5  1  0.500  0.000  0.000  1.0
  C  C6  1  0.008  0.695  0.488  1.0
  C  C7  1  0.971  0.472  0.692  1.0
  C  C8  1  0.361  0.207  0.981  1.0
  C  C9  1  0.644  0.060  0.866  1.0
  C  C10  1  0.029  0.528  0.308  1.0
  C  C11  1  0.992  0.305  0.512  1.0
  C  C12  1  0.356  0.940  0.134  1.0
  C  C13  1  0.639  0.793  0.019  1.0
  Cl  Cl14  1  0.656  0.809  0.679  1.0
  Cl  Cl15  1  0.344  0.191  0.321  1.0
  Cl  Cl16  1  0.382  0.528  0.344  1.0
  Cl  Cl17  1  0.635  0.743  0.367  1.0
  Cl  Cl18  1  0.885  0.936  0.156  1.0
  Cl  Cl19  1  0.365  0.257  0.633  1.0
  Cl  Cl20  1  0.312  0.830  0.602  1.0
  Cl  Cl21  1  0.688  0.170  0.398  1.0
  Cl  Cl22  1  0.024  0.754  0.824  1.0
  Cl  Cl23  1  0.115  0.064  0.844  1.0
  Cl  Cl24  1  0.360  0.687  0.947  1.0
  Cl  Cl25  1  0.640  0.313  0.053  1.0
  Cl  Cl26  1  0.976  0.246  0.176  1.0
  Cl  Cl27  1  0.618  0.472  0.656  1.0
  O  O28  1  0.987  0.192  0.522  1.0
  O  O29  1  0.281  0.327  0.968  1.0
  O  O30  1  0.726  0.096  0.786  1.0
  O  O31  1  0.274  0.904  0.214  1.0
  O  O32  1  0.013  0.808  0.478  1.0
  O  O33  1  0.719  0.673  0.032  1.0
  O  O34  1  0.954  0.452  0.804  1.0
  O  O35  1  0.046  0.548  0.196  1.0
[/CIF]
.
The material described by Rh(CO)4Ga2Cl7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Ga2Cl7 clusters and two Rh(CO)4 clusters. In each Ga2Cl7 cluster, there are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom to form corner-sharing GaCl4 tetrahedra. In the second Ga site, Ga(2) is bonded to one Cl(1), one Cl(2), one Cl(3), and one Cl(5) atom to form corner-sharing GaCl4 tetrahedra. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. In the fifth Cl site, Cl(5) is bonded in a bent 120 degrees geometry to one Ga(1) and one Ga(2) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Ga(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Ga(1) atom. In one of the Rh(CO)4 clusters, Rh(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Rh(1) and one O(1,4) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Rh(1) and one O(1,4) atom. O(1,4) is bonded in a single-bond geometry to one C(1) atom. In one of the Rh(CO)4 clusters, Rh(2) is bonded in a square co-planar geometry to two equivalent C(3) and two equivalent C(4) atoms. There are two inequivalent C sites. In the first C site, C(3) is bonded in a distorted linear geometry to one Rh(2) and one O(2) atom. In the second C site, C(4) is bonded in a distorted linear geometry to one Rh(2) and one O(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(4) atom. is represented by the CIF card [CIF]
data_Ga2RhC4Cl7O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.035
_cell_length_b   10.046
_cell_length_c   10.610
_cell_angle_alpha   76.408
_cell_angle_beta   76.829
_cell_angle_gamma   65.692
_symmetry_Int_Tables_number   1
_cell_volume   937.073
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.805  0.167  0.176  1.0
  Ga  Ga1  1  0.567  0.704  0.578  1.0
  Ga  Ga2  1  0.195  0.833  0.824  1.0
  Ga  Ga3  1  0.433  0.296  0.422  1.0
  Rh  Rh4  1  0.000  0.500  0.500  1.0
  Rh  Rh5  1  0.500  0.000  0.000  1.0
  C  C6  1  0.008  0.695  0.488  1.0
  C  C7  1  0.971  0.472  0.692  1.0
  C  C8  1  0.361  0.207  0.981  1.0
  C  C9  1  0.644  0.060  0.866  1.0
  C  C10  1  0.029  0.528  0.308  1.0
  C  C11  1  0.992  0.305  0.512  1.0
  C  C12  1  0.356  0.940  0.134  1.0
  C  C13  1  0.639  0.793  0.019  1.0
  Cl  Cl14  1  0.656  0.809  0.679  1.0
  Cl  Cl15  1  0.344  0.191  0.321  1.0
  Cl  Cl16  1  0.382  0.528  0.344  1.0
  Cl  Cl17  1  0.635  0.743  0.367  1.0
  Cl  Cl18  1  0.885  0.936  0.156  1.0
  Cl  Cl19  1  0.365  0.257  0.633  1.0
  Cl  Cl20  1  0.312  0.830  0.602  1.0
  Cl  Cl21  1  0.688  0.170  0.398  1.0
  Cl  Cl22  1  0.024  0.754  0.824  1.0
  Cl  Cl23  1  0.115  0.064  0.844  1.0
  Cl  Cl24  1  0.360  0.687  0.947  1.0
  Cl  Cl25  1  0.640  0.313  0.053  1.0
  Cl  Cl26  1  0.976  0.246  0.176  1.0
  Cl  Cl27  1  0.618  0.472  0.656  1.0
  O  O28  1  0.987  0.192  0.522  1.0
  O  O29  1  0.281  0.327  0.968  1.0
  O  O30  1  0.726  0.096  0.786  1.0
  O  O31  1  0.274  0.904  0.214  1.0
  O  O32  1  0.013  0.808  0.478  1.0
  O  O33  1  0.719  0.673  0.032  1.0
  O  O34  1  0.954  0.452  0.804  1.0
  O  O35  1  0.046  0.548  0.196  1.0
[/CIF]
.