The material described by MoV crystallizes in the hexagonal P-6m2 space group. V(1) is bonded to six equivalent V(1) and six equivalent Mo(1) atoms to form VV6Mo6 cuboctahedra that share corners with eighteen equivalent V(1)V6Mo6 cuboctahedra, edges with six equivalent V(1)V6Mo6 cuboctahedra, edges with twelve equivalent Mo(1)V6Mo6 cuboctahedra, faces with eight equivalent V(1)V6Mo6 cuboctahedra, and faces with twelve equivalent Mo(1)V6Mo6 cuboctahedra. Mo(1) is bonded to six equivalent V(1) and six equivalent Mo(1) atoms to form MoV6Mo6 cuboctahedra that share corners with eighteen equivalent Mo(1)V6Mo6 cuboctahedra, edges with six equivalent Mo(1)V6Mo6 cuboctahedra, edges with twelve equivalent V(1)V6Mo6 cuboctahedra, faces with eight equivalent Mo(1)V6Mo6 cuboctahedra, and faces with twelve equivalent V(1)V6Mo6 cuboctahedra. is represented by the CIF file [CIF]
data_VMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.699
_cell_length_b   2.699
_cell_length_c   4.800
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   30.279
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Mo  Mo1  1  0.333  0.667  0.500  1.0
[/CIF]
.
The material described by MoV crystallizes in the hexagonal P-6m2 space group. V(1) is bonded to six equivalent V(1) and six equivalent Mo(1) atoms to form VV6Mo6 cuboctahedra that share corners with eighteen equivalent V(1)V6Mo6 cuboctahedra, edges with six equivalent V(1)V6Mo6 cuboctahedra, edges with twelve equivalent Mo(1)V6Mo6 cuboctahedra, faces with eight equivalent V(1)V6Mo6 cuboctahedra, and faces with twelve equivalent Mo(1)V6Mo6 cuboctahedra. Mo(1) is bonded to six equivalent V(1) and six equivalent Mo(1) atoms to form MoV6Mo6 cuboctahedra that share corners with eighteen equivalent Mo(1)V6Mo6 cuboctahedra, edges with six equivalent Mo(1)V6Mo6 cuboctahedra, edges with twelve equivalent V(1)V6Mo6 cuboctahedra, faces with eight equivalent Mo(1)V6Mo6 cuboctahedra, and faces with twelve equivalent V(1)V6Mo6 cuboctahedra. is represented by the CIF file [CIF]
data_VMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.699
_cell_length_b   2.699
_cell_length_c   4.800
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   30.279
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Mo  Mo1  1  0.333  0.667  0.500  1.0
[/CIF]
.