The compound described by LiV4O10 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a square co-planar geometry to two equivalent O(3) and two equivalent O(4) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(4), one O(5), and two equivalent O(2) atoms to form distorted VO5 trigonal bipyramids that share corners with four equivalent V(1)O4 tetrahedra and  an edgeedge with one V(2)O5 trigonal bipyramid. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(2) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one V(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(1) and one V(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiV4O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.652
_cell_length_b   6.536
_cell_length_c   5.766
_cell_angle_alpha   91.411
_cell_angle_beta   97.884
_cell_angle_gamma   77.284
_symmetry_Int_Tables_number   1
_cell_volume   242.203
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  V  V1  1  0.202  0.709  0.562  1.0
  V  V2  1  0.798  0.291  0.438  1.0
  V  V3  1  0.657  0.810  0.406  1.0
  V  V4  1  0.343  0.190  0.594  1.0
  O  O5  1  0.943  0.802  0.435  1.0
  O  O6  1  0.057  0.198  0.565  1.0
  O  O7  1  0.381  0.885  0.521  1.0
  O  O8  1  0.619  0.115  0.479  1.0
  O  O9  1  0.217  0.677  0.846  1.0
  O  O10  1  0.783  0.323  0.154  1.0
  O  O11  1  0.592  0.768  0.129  1.0
  O  O12  1  0.408  0.232  0.871  1.0
  O  O13  1  0.294  0.457  0.449  1.0
  O  O14  1  0.706  0.543  0.551  1.0
[/CIF]
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The compound described by LiV4O10 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a square co-planar geometry to two equivalent O(3) and two equivalent O(4) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(4), one O(5), and two equivalent O(2) atoms to form distorted VO5 trigonal bipyramids that share corners with four equivalent V(1)O4 tetrahedra and  an edgeedge with one V(2)O5 trigonal bipyramid. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(2) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one V(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(1) and one V(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiV4O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.652
_cell_length_b   6.536
_cell_length_c   5.766
_cell_angle_alpha   91.411
_cell_angle_beta   97.884
_cell_angle_gamma   77.284
_symmetry_Int_Tables_number   1
_cell_volume   242.203
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  V  V1  1  0.202  0.709  0.562  1.0
  V  V2  1  0.798  0.291  0.438  1.0
  V  V3  1  0.657  0.810  0.406  1.0
  V  V4  1  0.343  0.190  0.594  1.0
  O  O5  1  0.943  0.802  0.435  1.0
  O  O6  1  0.057  0.198  0.565  1.0
  O  O7  1  0.381  0.885  0.521  1.0
  O  O8  1  0.619  0.115  0.479  1.0
  O  O9  1  0.217  0.677  0.846  1.0
  O  O10  1  0.783  0.323  0.154  1.0
  O  O11  1  0.592  0.768  0.129  1.0
  O  O12  1  0.408  0.232  0.871  1.0
  O  O13  1  0.294  0.457  0.449  1.0
  O  O14  1  0.706  0.543  0.551  1.0
[/CIF]
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