The compound described by KAuC4N4H2O crystallizes in the orthorhombic P2_12_12_1 space group. K(1) is bonded in a 7-coordinate geometry to one N(4), two equivalent N(1), two equivalent N(3), and two equivalent O(1) atoms. Au(1) is bonded in a square co-planar geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one Au(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Au(1) and one N(2) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one Au(1) and one N(3) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one Au(1) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one K(1) and one C(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to two equivalent K(1), one H(1), and one H(2) atom. is represented by the CIF card [CIF]
data_KH2AuC4N4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.823
_cell_length_b   7.506
_cell_length_c   17.511
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   896.856
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.740  0.468  0.983  1.0
  K  K1  1  0.760  0.532  0.483  1.0
  K  K2  1  0.240  0.032  0.017  1.0
  K  K3  1  0.260  0.968  0.517  1.0
  H  H4  1  0.315  0.688  0.930  1.0
  H  H5  1  0.185  0.312  0.430  1.0
  H  H6  1  0.815  0.812  0.070  1.0
  H  H7  1  0.685  0.188  0.570  1.0
  H  H8  1  0.277  0.593  0.008  1.0
  H  H9  1  0.223  0.407  0.508  1.0
  H  H10  1  0.777  0.907  0.992  1.0
  H  H11  1  0.723  0.093  0.492  1.0
  Au  Au12  1  0.242  0.428  0.739  1.0
  Au  Au13  1  0.258  0.572  0.239  1.0
  Au  Au14  1  0.742  0.072  0.261  1.0
  Au  Au15  1  0.758  0.928  0.761  1.0
  C  C16  1  0.349  0.524  0.640  1.0
  C  C17  1  0.151  0.476  0.140  1.0
  C  C18  1  0.849  0.976  0.360  1.0
  C  C19  1  0.651  0.024  0.860  1.0
  C  C20  1  0.998  0.353  0.684  1.0
  C  C21  1  0.502  0.647  0.184  1.0
  C  C22  1  0.498  0.147  0.316  1.0
  C  C23  1  0.002  0.853  0.816  1.0
  C  C24  1  0.135  0.336  0.839  1.0
  C  C25  1  0.365  0.664  0.339  1.0
  C  C26  1  0.635  0.164  0.161  1.0
  C  C27  1  0.865  0.836  0.661  1.0
  C  C28  1  0.489  0.500  0.794  1.0
  C  C29  1  0.011  0.500  0.294  1.0
  C  C30  1  0.989  1.000  0.206  1.0
  C  C31  1  0.511  0.000  0.706  1.0
  N  N32  1  0.412  0.578  0.583  1.0
  N  N33  1  0.088  0.422  0.083  1.0
  N  N34  1  0.912  0.922  0.417  1.0
  N  N35  1  0.588  0.078  0.917  1.0
  N  N36  1  0.860  0.305  0.650  1.0
  N  N37  1  0.640  0.695  0.150  1.0
  N  N38  1  0.360  0.195  0.350  1.0
  N  N39  1  0.140  0.805  0.850  1.0
  N  N40  1  0.080  0.287  0.898  1.0
  N  N41  1  0.420  0.713  0.398  1.0
  N  N42  1  0.580  0.213  0.102  1.0
  N  N43  1  0.920  0.787  0.602  1.0
  N  N44  1  0.629  0.542  0.827  1.0
  N  N45  1  0.871  0.458  0.327  1.0
  N  N46  1  0.129  0.958  0.173  1.0
  N  N47  1  0.371  0.042  0.673  1.0
  O  O48  1  0.374  0.664  0.981  1.0
  O  O49  1  0.126  0.336  0.481  1.0
  O  O50  1  0.874  0.836  0.019  1.0
  O  O51  1  0.626  0.164  0.519  1.0
[/CIF]
.
The compound described by KAuC4N4H2O crystallizes in the orthorhombic P2_12_12_1 space group. K(1) is bonded in a 7-coordinate geometry to one N(4), two equivalent N(1), two equivalent N(3), and two equivalent O(1) atoms. Au(1) is bonded in a square co-planar geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one Au(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Au(1) and one N(2) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one Au(1) and one N(3) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one Au(1) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one K(1) and one C(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to two equivalent K(1), one H(1), and one H(2) atom. is represented by the CIF card [CIF]
data_KH2AuC4N4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.823
_cell_length_b   7.506
_cell_length_c   17.511
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   896.856
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.740  0.468  0.983  1.0
  K  K1  1  0.760  0.532  0.483  1.0
  K  K2  1  0.240  0.032  0.017  1.0
  K  K3  1  0.260  0.968  0.517  1.0
  H  H4  1  0.315  0.688  0.930  1.0
  H  H5  1  0.185  0.312  0.430  1.0
  H  H6  1  0.815  0.812  0.070  1.0
  H  H7  1  0.685  0.188  0.570  1.0
  H  H8  1  0.277  0.593  0.008  1.0
  H  H9  1  0.223  0.407  0.508  1.0
  H  H10  1  0.777  0.907  0.992  1.0
  H  H11  1  0.723  0.093  0.492  1.0
  Au  Au12  1  0.242  0.428  0.739  1.0
  Au  Au13  1  0.258  0.572  0.239  1.0
  Au  Au14  1  0.742  0.072  0.261  1.0
  Au  Au15  1  0.758  0.928  0.761  1.0
  C  C16  1  0.349  0.524  0.640  1.0
  C  C17  1  0.151  0.476  0.140  1.0
  C  C18  1  0.849  0.976  0.360  1.0
  C  C19  1  0.651  0.024  0.860  1.0
  C  C20  1  0.998  0.353  0.684  1.0
  C  C21  1  0.502  0.647  0.184  1.0
  C  C22  1  0.498  0.147  0.316  1.0
  C  C23  1  0.002  0.853  0.816  1.0
  C  C24  1  0.135  0.336  0.839  1.0
  C  C25  1  0.365  0.664  0.339  1.0
  C  C26  1  0.635  0.164  0.161  1.0
  C  C27  1  0.865  0.836  0.661  1.0
  C  C28  1  0.489  0.500  0.794  1.0
  C  C29  1  0.011  0.500  0.294  1.0
  C  C30  1  0.989  1.000  0.206  1.0
  C  C31  1  0.511  0.000  0.706  1.0
  N  N32  1  0.412  0.578  0.583  1.0
  N  N33  1  0.088  0.422  0.083  1.0
  N  N34  1  0.912  0.922  0.417  1.0
  N  N35  1  0.588  0.078  0.917  1.0
  N  N36  1  0.860  0.305  0.650  1.0
  N  N37  1  0.640  0.695  0.150  1.0
  N  N38  1  0.360  0.195  0.350  1.0
  N  N39  1  0.140  0.805  0.850  1.0
  N  N40  1  0.080  0.287  0.898  1.0
  N  N41  1  0.420  0.713  0.398  1.0
  N  N42  1  0.580  0.213  0.102  1.0
  N  N43  1  0.920  0.787  0.602  1.0
  N  N44  1  0.629  0.542  0.827  1.0
  N  N45  1  0.871  0.458  0.327  1.0
  N  N46  1  0.129  0.958  0.173  1.0
  N  N47  1  0.371  0.042  0.673  1.0
  O  O48  1  0.374  0.664  0.981  1.0
  O  O49  1  0.126  0.336  0.481  1.0
  O  O50  1  0.874  0.836  0.019  1.0
  O  O51  1  0.626  0.164  0.519  1.0
[/CIF]
.