The compound described by Mn2Cd3O5 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cd(2)O6 octahedra,  a cornercorner with one Cd(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, edges with three equivalent Cd(1)O6 octahedra, edges with three equivalent Cd(2)O6 octahedra, and edges with three equivalent Cd(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cd(2)O6 octahedra,  a cornercorner with one Cd(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, edges with three equivalent Cd(1)O6 octahedra, edges with three equivalent Cd(2)O6 octahedra, and edges with three equivalent Cd(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form CdO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Cd(2)O6 octahedra,  a cornercorner with one Cd(3)O6 octahedra, corners with two equivalent Cd(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, edges with three equivalent Cd(2)O6 octahedra, and edges with three equivalent Cd(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the second Cd site, Cd(2) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form CdO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cd(3)O6 octahedra, corners with two equivalent Cd(2)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, edges with three equivalent Cd(1)O6 octahedra, and edges with three equivalent Cd(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the third Cd site, Cd(3) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form CdO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cd(2)O6 octahedra, corners with two equivalent Cd(3)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, edges with three equivalent Cd(1)O6 octahedra, and edges with three equivalent Cd(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(2), one Cd(2), one Cd(3), and two equivalent Cd(1) atoms to form OMn2Cd4 octahedra that share  a cornercorner with one O(2)Mn2Cd4 octahedra,  a cornercorner with one O(3)Mn2Cd4 octahedra,  a cornercorner with one O(4)Mn3Cd3 octahedra,  a cornercorner with one O(5)Mn3Cd3 octahedra, corners with two equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(3)Mn2Cd4 octahedra, edges with three equivalent O(4)Mn3Cd3 octahedra, and edges with three equivalent O(5)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second O site, O(2) is bonded to one Mn(1), one Mn(2), one Cd(1), one Cd(3), and two equivalent Cd(2) atoms to form OMn2Cd4 octahedra that share  a cornercorner with one O(1)Mn2Cd4 octahedra,  a cornercorner with one O(3)Mn2Cd4 octahedra,  a cornercorner with one O(4)Mn3Cd3 octahedra,  a cornercorner with one O(5)Mn3Cd3 octahedra, corners with two equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(3)Mn2Cd4 octahedra, edges with three equivalent O(4)Mn3Cd3 octahedra, and edges with three equivalent O(5)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(3) is bonded to one Mn(1), one Mn(2), one Cd(1), one Cd(2), and two equivalent Cd(3) atoms to form OMn2Cd4 octahedra that share  a cornercorner with one O(1)Mn2Cd4 octahedra,  a cornercorner with one O(2)Mn2Cd4 octahedra,  a cornercorner with one O(4)Mn3Cd3 octahedra,  a cornercorner with one O(5)Mn3Cd3 octahedra, corners with two equivalent O(3)Mn2Cd4 octahedra, edges with three equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(4)Mn3Cd3 octahedra, and edges with three equivalent O(5)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fourth O site, O(4) is bonded to one Mn(2), two equivalent Mn(1), one Cd(1), one Cd(2), and one Cd(3) atom to form OMn3Cd3 octahedra that share  a cornercorner with one O(1)Mn2Cd4 octahedra,  a cornercorner with one O(2)Mn2Cd4 octahedra,  a cornercorner with one O(3)Mn2Cd4 octahedra,  a cornercorner with one O(5)Mn3Cd3 octahedra, corners with two equivalent O(4)Mn3Cd3 octahedra, edges with three equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(3)Mn2Cd4 octahedra, and edges with three equivalent O(5)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fifth O site, O(5) is bonded to one Mn(1), two equivalent Mn(2), one Cd(1), one Cd(2), and one Cd(3) atom to form OMn3Cd3 octahedra that share  a cornercorner with one O(1)Mn2Cd4 octahedra,  a cornercorner with one O(2)Mn2Cd4 octahedra,  a cornercorner with one O(3)Mn2Cd4 octahedra,  a cornercorner with one O(4)Mn3Cd3 octahedra, corners with two equivalent O(5)Mn3Cd3 octahedra, edges with three equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(3)Mn2Cd4 octahedra, and edges with three equivalent O(4)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2Cd3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.683
_cell_length_b   5.721
_cell_length_c   5.740
_cell_angle_alpha   80.252
_cell_angle_beta   65.937
_cell_angle_gamma   65.864
_symmetry_Int_Tables_number   1
_cell_volume   128.143
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.600  0.202  0.598  1.0
  Cd  Cd1  1  0.796  0.607  0.800  1.0
  Cd  Cd2  1  0.405  0.795  0.396  1.0
  Mn  Mn3  1  0.998  0.004  1.000  1.0
  Mn  Mn4  1  0.201  0.398  0.198  1.0
  O  O5  1  0.101  0.203  0.596  1.0
  O  O6  1  0.281  0.619  0.820  1.0
  O  O7  1  0.921  0.785  0.376  1.0
  O  O8  1  0.490  0.021  0.003  1.0
  O  O9  1  0.716  0.381  0.192  1.0
[/CIF]
.
The compound described by Mn2Cd3O5 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cd(2)O6 octahedra,  a cornercorner with one Cd(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, edges with three equivalent Cd(1)O6 octahedra, edges with three equivalent Cd(2)O6 octahedra, and edges with three equivalent Cd(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cd(2)O6 octahedra,  a cornercorner with one Cd(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, edges with three equivalent Cd(1)O6 octahedra, edges with three equivalent Cd(2)O6 octahedra, and edges with three equivalent Cd(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form CdO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Cd(2)O6 octahedra,  a cornercorner with one Cd(3)O6 octahedra, corners with two equivalent Cd(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, edges with three equivalent Cd(2)O6 octahedra, and edges with three equivalent Cd(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the second Cd site, Cd(2) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form CdO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cd(3)O6 octahedra, corners with two equivalent Cd(2)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, edges with three equivalent Cd(1)O6 octahedra, and edges with three equivalent Cd(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the third Cd site, Cd(3) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form CdO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cd(2)O6 octahedra, corners with two equivalent Cd(3)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, edges with three equivalent Cd(1)O6 octahedra, and edges with three equivalent Cd(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(2), one Cd(2), one Cd(3), and two equivalent Cd(1) atoms to form OMn2Cd4 octahedra that share  a cornercorner with one O(2)Mn2Cd4 octahedra,  a cornercorner with one O(3)Mn2Cd4 octahedra,  a cornercorner with one O(4)Mn3Cd3 octahedra,  a cornercorner with one O(5)Mn3Cd3 octahedra, corners with two equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(3)Mn2Cd4 octahedra, edges with three equivalent O(4)Mn3Cd3 octahedra, and edges with three equivalent O(5)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second O site, O(2) is bonded to one Mn(1), one Mn(2), one Cd(1), one Cd(3), and two equivalent Cd(2) atoms to form OMn2Cd4 octahedra that share  a cornercorner with one O(1)Mn2Cd4 octahedra,  a cornercorner with one O(3)Mn2Cd4 octahedra,  a cornercorner with one O(4)Mn3Cd3 octahedra,  a cornercorner with one O(5)Mn3Cd3 octahedra, corners with two equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(3)Mn2Cd4 octahedra, edges with three equivalent O(4)Mn3Cd3 octahedra, and edges with three equivalent O(5)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(3) is bonded to one Mn(1), one Mn(2), one Cd(1), one Cd(2), and two equivalent Cd(3) atoms to form OMn2Cd4 octahedra that share  a cornercorner with one O(1)Mn2Cd4 octahedra,  a cornercorner with one O(2)Mn2Cd4 octahedra,  a cornercorner with one O(4)Mn3Cd3 octahedra,  a cornercorner with one O(5)Mn3Cd3 octahedra, corners with two equivalent O(3)Mn2Cd4 octahedra, edges with three equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(4)Mn3Cd3 octahedra, and edges with three equivalent O(5)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fourth O site, O(4) is bonded to one Mn(2), two equivalent Mn(1), one Cd(1), one Cd(2), and one Cd(3) atom to form OMn3Cd3 octahedra that share  a cornercorner with one O(1)Mn2Cd4 octahedra,  a cornercorner with one O(2)Mn2Cd4 octahedra,  a cornercorner with one O(3)Mn2Cd4 octahedra,  a cornercorner with one O(5)Mn3Cd3 octahedra, corners with two equivalent O(4)Mn3Cd3 octahedra, edges with three equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(3)Mn2Cd4 octahedra, and edges with three equivalent O(5)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fifth O site, O(5) is bonded to one Mn(1), two equivalent Mn(2), one Cd(1), one Cd(2), and one Cd(3) atom to form OMn3Cd3 octahedra that share  a cornercorner with one O(1)Mn2Cd4 octahedra,  a cornercorner with one O(2)Mn2Cd4 octahedra,  a cornercorner with one O(3)Mn2Cd4 octahedra,  a cornercorner with one O(4)Mn3Cd3 octahedra, corners with two equivalent O(5)Mn3Cd3 octahedra, edges with three equivalent O(1)Mn2Cd4 octahedra, edges with three equivalent O(2)Mn2Cd4 octahedra, edges with three equivalent O(3)Mn2Cd4 octahedra, and edges with three equivalent O(4)Mn3Cd3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2Cd3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.683
_cell_length_b   5.721
_cell_length_c   5.740
_cell_angle_alpha   80.252
_cell_angle_beta   65.937
_cell_angle_gamma   65.864
_symmetry_Int_Tables_number   1
_cell_volume   128.143
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.600  0.202  0.598  1.0
  Cd  Cd1  1  0.796  0.607  0.800  1.0
  Cd  Cd2  1  0.405  0.795  0.396  1.0
  Mn  Mn3  1  0.998  0.004  1.000  1.0
  Mn  Mn4  1  0.201  0.398  0.198  1.0
  O  O5  1  0.101  0.203  0.596  1.0
  O  O6  1  0.281  0.619  0.820  1.0
  O  O7  1  0.921  0.785  0.376  1.0
  O  O8  1  0.490  0.021  0.003  1.0
  O  O9  1  0.716  0.381  0.192  1.0
[/CIF]
.