The material described by Rh2Zn11 crystallizes in the cubic I-43m space group. Rh(1) is bonded in a distorted q6 geometry to three equivalent Zn(1), three equivalent Zn(3), and six equivalent Zn(2) atoms. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 12-coordinate geometry to three equivalent Rh(1), three equivalent Zn(1), three equivalent Zn(2), and three equivalent Zn(3) atoms. In the second Zn site, Zn(3) is bonded in a 13-coordinate geometry to two equivalent Rh(1), one Zn(3), two equivalent Zn(1), and eight equivalent Zn(2) atoms. In the third Zn site, Zn(2) is bonded in a 2-coordinate geometry to two equivalent Rh(1), one Zn(1), and four equivalent Zn(3) atoms. is represented by the CIF file [CIF]
data_Zn11Rh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.794
_cell_length_b   7.794
_cell_length_c   7.794
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   364.422
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.787  1.0
  Zn  Zn1  1  0.000  0.787  1.000  1.0
  Zn  Zn2  1  0.787  0.000  1.000  1.0
  Zn  Zn3  1  0.213  0.213  0.213  1.0
  Zn  Zn4  1  0.351  0.351  0.619  1.0
  Zn  Zn5  1  0.649  0.268  1.000  1.0
  Zn  Zn6  1  0.268  0.649  1.000  1.0
  Zn  Zn7  1  0.000  0.268  0.649  1.0
  Zn  Zn8  1  0.381  0.732  0.732  1.0
  Zn  Zn9  1  0.732  0.381  0.732  1.0
  Zn  Zn10  1  0.268  0.000  0.649  1.0
  Zn  Zn11  1  0.649  0.000  0.268  1.0
  Zn  Zn12  1  0.000  0.649  0.268  1.0
  Zn  Zn13  1  0.619  0.351  0.351  1.0
  Zn  Zn14  1  0.351  0.619  0.351  1.0
  Zn  Zn15  1  0.732  0.732  0.381  1.0
  Zn  Zn16  1  0.000  0.356  0.356  1.0
  Zn  Zn17  1  0.644  0.000  0.644  1.0
  Zn  Zn18  1  0.356  0.000  0.356  1.0
  Zn  Zn19  1  0.356  0.356  0.000  1.0
  Zn  Zn20  1  0.644  0.644  1.000  1.0
  Zn  Zn21  1  0.000  0.644  0.644  1.0
  Rh  Rh22  1  0.000  0.000  0.345  1.0
  Rh  Rh23  1  0.000  0.345  1.000  1.0
  Rh  Rh24  1  0.345  0.000  1.000  1.0
  Rh  Rh25  1  0.655  0.655  0.655  1.0
[/CIF]
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The material described by Rh2Zn11 crystallizes in the cubic I-43m space group. Rh(1) is bonded in a distorted q6 geometry to three equivalent Zn(1), three equivalent Zn(3), and six equivalent Zn(2) atoms. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 12-coordinate geometry to three equivalent Rh(1), three equivalent Zn(1), three equivalent Zn(2), and three equivalent Zn(3) atoms. In the second Zn site, Zn(3) is bonded in a 13-coordinate geometry to two equivalent Rh(1), one Zn(3), two equivalent Zn(1), and eight equivalent Zn(2) atoms. In the third Zn site, Zn(2) is bonded in a 2-coordinate geometry to two equivalent Rh(1), one Zn(1), and four equivalent Zn(3) atoms. is represented by the CIF file [CIF]
data_Zn11Rh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.794
_cell_length_b   7.794
_cell_length_c   7.794
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   364.422
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.787  1.0
  Zn  Zn1  1  0.000  0.787  1.000  1.0
  Zn  Zn2  1  0.787  0.000  1.000  1.0
  Zn  Zn3  1  0.213  0.213  0.213  1.0
  Zn  Zn4  1  0.351  0.351  0.619  1.0
  Zn  Zn5  1  0.649  0.268  1.000  1.0
  Zn  Zn6  1  0.268  0.649  1.000  1.0
  Zn  Zn7  1  0.000  0.268  0.649  1.0
  Zn  Zn8  1  0.381  0.732  0.732  1.0
  Zn  Zn9  1  0.732  0.381  0.732  1.0
  Zn  Zn10  1  0.268  0.000  0.649  1.0
  Zn  Zn11  1  0.649  0.000  0.268  1.0
  Zn  Zn12  1  0.000  0.649  0.268  1.0
  Zn  Zn13  1  0.619  0.351  0.351  1.0
  Zn  Zn14  1  0.351  0.619  0.351  1.0
  Zn  Zn15  1  0.732  0.732  0.381  1.0
  Zn  Zn16  1  0.000  0.356  0.356  1.0
  Zn  Zn17  1  0.644  0.000  0.644  1.0
  Zn  Zn18  1  0.356  0.000  0.356  1.0
  Zn  Zn19  1  0.356  0.356  0.000  1.0
  Zn  Zn20  1  0.644  0.644  1.000  1.0
  Zn  Zn21  1  0.000  0.644  0.644  1.0
  Rh  Rh22  1  0.000  0.000  0.345  1.0
  Rh  Rh23  1  0.000  0.345  1.000  1.0
  Rh  Rh24  1  0.345  0.000  1.000  1.0
  Rh  Rh25  1  0.655  0.655  0.655  1.0
[/CIF]
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