The structure described by SbOPO4 crystallizes in the orthorhombic Fdd2 space group. Sb(1) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. P(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(1) and one P(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_SbPO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.253
_cell_length_b   9.082
_cell_length_c   6.947
_cell_angle_alpha   78.287
_cell_angle_beta   60.149
_cell_angle_gamma   41.563
_symmetry_Int_Tables_number   1
_cell_volume   355.766
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.873  0.379  0.381  1.0
  Sb  Sb1  1  0.367  0.381  0.379  1.0
  Sb  Sb2  1  0.871  0.377  0.883  1.0
  Sb  Sb3  1  0.869  0.883  0.377  1.0
  P  P4  1  0.029  0.541  0.970  1.0
  P  P5  1  0.709  0.221  0.790  1.0
  P  P6  1  0.460  0.970  0.541  1.0
  P  P7  1  0.280  0.790  0.221  1.0
  O  O8  1  0.594  0.728  0.434  1.0
  O  O9  1  0.666  0.182  0.328  1.0
  O  O10  1  0.311  0.647  0.399  1.0
  O  O11  1  0.816  0.006  0.656  1.0
  O  O12  1  0.221  0.098  0.759  1.0
  O  O13  1  0.421  0.115  0.364  1.0
  O  O14  1  0.068  0.584  0.426  1.0
  O  O15  1  0.824  0.328  0.182  1.0
  O  O16  1  0.922  0.426  0.584  1.0
  O  O17  1  0.152  0.029  0.328  1.0
  O  O18  1  0.244  0.434  0.728  1.0
  O  O19  1  0.491  0.328  0.029  1.0
  O  O20  1  0.922  0.759  0.098  1.0
  O  O21  1  0.135  0.829  0.151  1.0
  O  O22  1  0.099  0.364  0.115  1.0
  O  O23  1  0.886  0.151  0.829  1.0
  O  O24  1  0.851  0.607  0.939  1.0
  O  O25  1  0.643  0.399  0.647  1.0
  O  O26  1  0.522  0.656  0.006  1.0
  O  O27  1  0.603  0.939  0.607  1.0
[/CIF]
.
The structure described by SbOPO4 crystallizes in the orthorhombic Fdd2 space group. Sb(1) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. P(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(1) and one P(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_SbPO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.253
_cell_length_b   9.082
_cell_length_c   6.947
_cell_angle_alpha   78.287
_cell_angle_beta   60.149
_cell_angle_gamma   41.563
_symmetry_Int_Tables_number   1
_cell_volume   355.766
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.873  0.379  0.381  1.0
  Sb  Sb1  1  0.367  0.381  0.379  1.0
  Sb  Sb2  1  0.871  0.377  0.883  1.0
  Sb  Sb3  1  0.869  0.883  0.377  1.0
  P  P4  1  0.029  0.541  0.970  1.0
  P  P5  1  0.709  0.221  0.790  1.0
  P  P6  1  0.460  0.970  0.541  1.0
  P  P7  1  0.280  0.790  0.221  1.0
  O  O8  1  0.594  0.728  0.434  1.0
  O  O9  1  0.666  0.182  0.328  1.0
  O  O10  1  0.311  0.647  0.399  1.0
  O  O11  1  0.816  0.006  0.656  1.0
  O  O12  1  0.221  0.098  0.759  1.0
  O  O13  1  0.421  0.115  0.364  1.0
  O  O14  1  0.068  0.584  0.426  1.0
  O  O15  1  0.824  0.328  0.182  1.0
  O  O16  1  0.922  0.426  0.584  1.0
  O  O17  1  0.152  0.029  0.328  1.0
  O  O18  1  0.244  0.434  0.728  1.0
  O  O19  1  0.491  0.328  0.029  1.0
  O  O20  1  0.922  0.759  0.098  1.0
  O  O21  1  0.135  0.829  0.151  1.0
  O  O22  1  0.099  0.364  0.115  1.0
  O  O23  1  0.886  0.151  0.829  1.0
  O  O24  1  0.851  0.607  0.939  1.0
  O  O25  1  0.643  0.399  0.647  1.0
  O  O26  1  0.522  0.656  0.006  1.0
  O  O27  1  0.603  0.939  0.607  1.0
[/CIF]
.