The structure described by Rb5NO5 crystallizes in the monoclinic Pm space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted trigonal planar geometry to one Rb(2) and three equivalent O(4) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to two equivalent Rb(1) and six equivalent Rb(2) atoms. In the third Rb site, Rb(3) is bonded in a 4-coordinate geometry to one N(1), one O(3), one O(4), and two equivalent O(2) atoms. N(1) is bonded in a distorted tetrahedral geometry to two equivalent Rb(3), one O(1), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one N(1) and one O(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to four equivalent Rb(3) and one O(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(3) and one N(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Rb(3) and three equivalent Rb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb5NO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.995
_cell_length_b   4.534
_cell_length_c   19.208
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   115.266
_symmetry_Int_Tables_number   1
_cell_volume   393.336
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.225  0.195  0.956  1.0
  Rb  Rb1  1  0.966  0.938  0.200  1.0
  Rb  Rb2  1  0.225  0.195  0.444  1.0
  Rb  Rb3  1  0.719  0.788  0.811  1.0
  Rb  Rb4  1  0.719  0.788  0.589  1.0
  N  N5  1  0.176  0.893  0.700  1.0
  O  O6  1  0.411  0.213  0.700  1.0
  O  O7  1  0.693  0.230  0.700  1.0
  O  O8  1  0.264  0.679  0.700  1.0
  O  O9  1  0.851  0.488  0.481  1.0
  O  O10  1  0.851  0.488  0.919  1.0
[/CIF]
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The structure described by Rb5NO5 crystallizes in the monoclinic Pm space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted trigonal planar geometry to one Rb(2) and three equivalent O(4) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to two equivalent Rb(1) and six equivalent Rb(2) atoms. In the third Rb site, Rb(3) is bonded in a 4-coordinate geometry to one N(1), one O(3), one O(4), and two equivalent O(2) atoms. N(1) is bonded in a distorted tetrahedral geometry to two equivalent Rb(3), one O(1), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one N(1) and one O(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to four equivalent Rb(3) and one O(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(3) and one N(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Rb(3) and three equivalent Rb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb5NO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.995
_cell_length_b   4.534
_cell_length_c   19.208
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   115.266
_symmetry_Int_Tables_number   1
_cell_volume   393.336
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.225  0.195  0.956  1.0
  Rb  Rb1  1  0.966  0.938  0.200  1.0
  Rb  Rb2  1  0.225  0.195  0.444  1.0
  Rb  Rb3  1  0.719  0.788  0.811  1.0
  Rb  Rb4  1  0.719  0.788  0.589  1.0
  N  N5  1  0.176  0.893  0.700  1.0
  O  O6  1  0.411  0.213  0.700  1.0
  O  O7  1  0.693  0.230  0.700  1.0
  O  O8  1  0.264  0.679  0.700  1.0
  O  O9  1  0.851  0.488  0.481  1.0
  O  O10  1  0.851  0.488  0.919  1.0
[/CIF]
.