The material structure described by CN2H2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight cyanamide molecules. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H2CN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.754
_cell_length_b   6.957
_cell_length_c   9.186
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   431.660
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.901  0.293  0.483  1.0
  H  H1  1  0.599  0.793  0.517  1.0
  H  H2  1  0.401  0.707  0.017  1.0
  H  H3  1  0.099  0.207  0.983  1.0
  H  H4  1  0.099  0.707  0.517  1.0
  H  H5  1  0.401  0.207  0.483  1.0
  H  H6  1  0.599  0.293  0.983  1.0
  H  H7  1  0.901  0.793  0.017  1.0
  H  H8  1  0.719  0.452  0.412  1.0
  H  H9  1  0.781  0.952  0.588  1.0
  H  H10  1  0.219  0.548  0.088  1.0
  H  H11  1  0.281  0.048  0.912  1.0
  H  H12  1  0.281  0.548  0.588  1.0
  H  H13  1  0.219  0.048  0.412  1.0
  H  H14  1  0.781  0.452  0.912  1.0
  H  H15  1  0.719  0.952  0.088  1.0
  C  C16  1  0.919  0.357  0.269  1.0
  C  C17  1  0.581  0.857  0.731  1.0
  C  C18  1  0.419  0.643  0.231  1.0
  C  C19  1  0.081  0.143  0.769  1.0
  C  C20  1  0.081  0.643  0.731  1.0
  C  C21  1  0.419  0.143  0.269  1.0
  C  C22  1  0.581  0.357  0.769  1.0
  C  C23  1  0.919  0.857  0.231  1.0
  N  N24  1  0.830  0.354  0.395  1.0
  N  N25  1  0.670  0.854  0.605  1.0
  N  N26  1  0.330  0.646  0.105  1.0
  N  N27  1  0.170  0.146  0.895  1.0
  N  N28  1  0.170  0.646  0.605  1.0
  N  N29  1  0.330  0.146  0.395  1.0
  N  N30  1  0.670  0.354  0.895  1.0
  N  N31  1  0.830  0.854  0.105  1.0
  N  N32  1  0.991  0.359  0.152  1.0
  N  N33  1  0.509  0.859  0.848  1.0
  N  N34  1  0.491  0.641  0.348  1.0
  N  N35  1  0.009  0.141  0.652  1.0
  N  N36  1  0.009  0.641  0.848  1.0
  N  N37  1  0.491  0.141  0.152  1.0
  N  N38  1  0.509  0.359  0.652  1.0
  N  N39  1  0.991  0.859  0.348  1.0
[/CIF]
.
The material structure described by CN2H2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight cyanamide molecules. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H2CN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.754
_cell_length_b   6.957
_cell_length_c   9.186
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   431.660
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.901  0.293  0.483  1.0
  H  H1  1  0.599  0.793  0.517  1.0
  H  H2  1  0.401  0.707  0.017  1.0
  H  H3  1  0.099  0.207  0.983  1.0
  H  H4  1  0.099  0.707  0.517  1.0
  H  H5  1  0.401  0.207  0.483  1.0
  H  H6  1  0.599  0.293  0.983  1.0
  H  H7  1  0.901  0.793  0.017  1.0
  H  H8  1  0.719  0.452  0.412  1.0
  H  H9  1  0.781  0.952  0.588  1.0
  H  H10  1  0.219  0.548  0.088  1.0
  H  H11  1  0.281  0.048  0.912  1.0
  H  H12  1  0.281  0.548  0.588  1.0
  H  H13  1  0.219  0.048  0.412  1.0
  H  H14  1  0.781  0.452  0.912  1.0
  H  H15  1  0.719  0.952  0.088  1.0
  C  C16  1  0.919  0.357  0.269  1.0
  C  C17  1  0.581  0.857  0.731  1.0
  C  C18  1  0.419  0.643  0.231  1.0
  C  C19  1  0.081  0.143  0.769  1.0
  C  C20  1  0.081  0.643  0.731  1.0
  C  C21  1  0.419  0.143  0.269  1.0
  C  C22  1  0.581  0.357  0.769  1.0
  C  C23  1  0.919  0.857  0.231  1.0
  N  N24  1  0.830  0.354  0.395  1.0
  N  N25  1  0.670  0.854  0.605  1.0
  N  N26  1  0.330  0.646  0.105  1.0
  N  N27  1  0.170  0.146  0.895  1.0
  N  N28  1  0.170  0.646  0.605  1.0
  N  N29  1  0.330  0.146  0.395  1.0
  N  N30  1  0.670  0.354  0.895  1.0
  N  N31  1  0.830  0.854  0.105  1.0
  N  N32  1  0.991  0.359  0.152  1.0
  N  N33  1  0.509  0.859  0.848  1.0
  N  N34  1  0.491  0.641  0.348  1.0
  N  N35  1  0.009  0.141  0.652  1.0
  N  N36  1  0.009  0.641  0.848  1.0
  N  N37  1  0.491  0.141  0.152  1.0
  N  N38  1  0.509  0.359  0.652  1.0
  N  N39  1  0.991  0.859  0.348  1.0
[/CIF]
.