The material described by Zn(AuF4)2 crystallizes in the monoclinic P2_1/c space group. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. Zn(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Au(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Au(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Au(1) atom. is represented by the CIF card [CIF]
data_Zn(AuF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.416
_cell_length_b   5.519
_cell_length_c   10.877
_cell_angle_alpha   70.293
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   306.094
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.000  1.0
  Zn  Zn1  1  0.000  0.500  0.500  1.0
  Au  Au2  1  0.712  0.862  0.666  1.0
  Au  Au3  1  0.212  0.138  0.834  1.0
  Au  Au4  1  0.288  0.138  0.334  1.0
  Au  Au5  1  0.788  0.862  0.166  1.0
  F  F6  1  0.615  0.560  0.813  1.0
  F  F7  1  0.115  0.440  0.687  1.0
  F  F8  1  0.385  0.440  0.187  1.0
  F  F9  1  0.885  0.560  0.313  1.0
  F  F10  1  0.689  0.167  0.022  1.0
  F  F11  1  0.189  0.833  0.478  1.0
  F  F12  1  0.799  0.659  0.048  1.0
  F  F13  1  0.299  0.341  0.452  1.0
  F  F14  1  0.201  0.341  0.952  1.0
  F  F15  1  0.701  0.659  0.548  1.0
  F  F16  1  0.784  0.060  0.281  1.0
  F  F17  1  0.284  0.940  0.219  1.0
  F  F18  1  0.216  0.940  0.719  1.0
  F  F19  1  0.716  0.060  0.781  1.0
  F  F20  1  0.811  0.167  0.522  1.0
  F  F21  1  0.311  0.833  0.978  1.0
[/CIF]
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The material described by Zn(AuF4)2 crystallizes in the monoclinic P2_1/c space group. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. Zn(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Au(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Au(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Au(1) atom. is represented by the CIF card [CIF]
data_Zn(AuF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.416
_cell_length_b   5.519
_cell_length_c   10.877
_cell_angle_alpha   70.293
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   306.094
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.000  1.0
  Zn  Zn1  1  0.000  0.500  0.500  1.0
  Au  Au2  1  0.712  0.862  0.666  1.0
  Au  Au3  1  0.212  0.138  0.834  1.0
  Au  Au4  1  0.288  0.138  0.334  1.0
  Au  Au5  1  0.788  0.862  0.166  1.0
  F  F6  1  0.615  0.560  0.813  1.0
  F  F7  1  0.115  0.440  0.687  1.0
  F  F8  1  0.385  0.440  0.187  1.0
  F  F9  1  0.885  0.560  0.313  1.0
  F  F10  1  0.689  0.167  0.022  1.0
  F  F11  1  0.189  0.833  0.478  1.0
  F  F12  1  0.799  0.659  0.048  1.0
  F  F13  1  0.299  0.341  0.452  1.0
  F  F14  1  0.201  0.341  0.952  1.0
  F  F15  1  0.701  0.659  0.548  1.0
  F  F16  1  0.784  0.060  0.281  1.0
  F  F17  1  0.284  0.940  0.219  1.0
  F  F18  1  0.216  0.940  0.719  1.0
  F  F19  1  0.716  0.060  0.781  1.0
  F  F20  1  0.811  0.167  0.522  1.0
  F  F21  1  0.311  0.833  0.978  1.0
[/CIF]
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