The compound described by MnOF crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 18-29°. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a 3-coordinate geometry to three equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.807
_cell_length_b   4.393
_cell_length_c   5.533
_cell_angle_alpha   112.776
_cell_angle_beta   110.108
_cell_angle_gamma   90.175
_symmetry_Int_Tables_number   1
_cell_volume   79.118
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.574  0.822  0.648  1.0
  F  F1  1  0.426  0.178  0.352  1.0
  Mn  Mn2  1  0.634  0.384  0.768  1.0
  Mn  Mn3  1  0.366  0.616  0.232  1.0
  O  O4  1  0.165  0.403  0.831  1.0
  O  O5  1  0.835  0.597  0.169  1.0
[/CIF]
.
The compound described by MnOF crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 18-29°. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a 3-coordinate geometry to three equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.807
_cell_length_b   4.393
_cell_length_c   5.533
_cell_angle_alpha   112.776
_cell_angle_beta   110.108
_cell_angle_gamma   90.175
_symmetry_Int_Tables_number   1
_cell_volume   79.118
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.574  0.822  0.648  1.0
  F  F1  1  0.426  0.178  0.352  1.0
  Mn  Mn2  1  0.634  0.384  0.768  1.0
  Mn  Mn3  1  0.366  0.616  0.232  1.0
  O  O4  1  0.165  0.403  0.831  1.0
  O  O5  1  0.835  0.597  0.169  1.0
[/CIF]
.