The structure described by LiMn9CdO10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 2-coordinate geometry to one Cd(1), one O(10), one O(6), one O(7), and one O(8) atom. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(8)O6 octahedra, corners with two equivalent Mn(2)O5 trigonal bipyramids, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Mn(3)O5 trigonal bipyramid, edges with two equivalent Mn(4)O5 trigonal bipyramids, and edges with two equivalent Mn(7)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(5), one O(6), and one O(8) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O5 trigonal bipyramid, corners with four equivalent Mn(3)O5 trigonal bipyramids,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. In the third Mn site, Mn(3) is bonded to one O(1), one O(3), one O(5), one O(7), and one O(8) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(8)O6 octahedra,  a cornercorner with one Mn(7)O5 trigonal bipyramid, corners with four equivalent Mn(2)O5 trigonal bipyramids,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(2), one O(4), one O(6), and one O(9) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one Mn(2)O5 trigonal bipyramid, corners with four equivalent Mn(7)O5 trigonal bipyramids,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(6)O6 octahedra, corners with two equivalent Mn(7)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Mn(4)O5 trigonal bipyramid, edges with two equivalent Mn(2)O5 trigonal bipyramids, and edges with two equivalent Mn(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(5)O6 octahedra, corners with two equivalent Mn(4)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Mn(7)O5 trigonal bipyramid, edges with two equivalent Mn(2)O5 trigonal bipyramids, and edges with two equivalent Mn(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the seventh Mn site, Mn(7) is bonded to one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(5)O6 octahedra,  a cornercorner with one Mn(3)O5 trigonal bipyramid, corners with four equivalent Mn(4)O5 trigonal bipyramids,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Mn(2)O5 trigonal bipyramid, edges with two equivalent Mn(4)O5 trigonal bipyramids, and edges with two equivalent Mn(7)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the ninth Mn site, Mn(9) is bonded in a distorted square co-planar geometry to one Cd(1), one O(1), one O(4), one O(6), and one O(7) atom. Cd(1) is bonded in a 6-coordinate geometry to one Li(1), one Mn(9), one O(10), one O(6), one O(7), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(9) atom to form OMn5 trigonal bipyramids that share corners with two equivalent O(9)Mn6 octahedra, corners with four equivalent O(8)LiMn4Cd octahedra,  a cornercorner with one O(4)Mn5 trigonal bipyramid,  an edgeedge with one O(2)Mn6 octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, and  an edgeedge with one O(6)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-81°. In the second O site, O(2) is bonded to one Mn(1), one Mn(4), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(8)LiMn4Cd octahedra, corners with two equivalent O(9)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, edges with two equivalent O(10)LiMn4Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra,  an edgeedge with one O(1)Mn5 trigonal bipyramid, and edges with two equivalent O(4)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-7°. In the third O site, O(3) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(10)LiMn4Cd octahedra, corners with two equivalent O(5)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, edges with two equivalent O(8)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra,  an edgeedge with one O(4)Mn5 trigonal bipyramid, and edges with two equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth O site, O(4) is bonded to one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Mn(9) atom to form OMn5 trigonal bipyramids that share corners with two equivalent O(5)Mn6 octahedra, corners with four equivalent O(10)LiMn4Cd octahedra,  a cornercorner with one O(1)Mn5 trigonal bipyramid,  an edgeedge with one O(3)Mn6 octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra, and  an edgeedge with one O(6)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-81°. In the fifth O site, O(5) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(3)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, corners with two equivalent O(4)Mn5 trigonal bipyramids,  an edgeedge with one O(10)LiMn4Cd octahedra, edges with two equivalent O(8)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra, and edges with two equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-4°. In the sixth O site, O(6) is bonded to one Li(1), one Mn(2), one Mn(4), one Mn(9), and one Cd(1) atom to form distorted OLiMn3Cd trigonal bipyramids that share  a cornercorner with one O(10)LiMn4Cd octahedra,  a cornercorner with one O(8)LiMn4Cd octahedra,  a cornercorner with one O(2)Mn6 octahedra,  a cornercorner with one O(3)Mn6 octahedra,  a cornercorner with one O(5)Mn6 octahedra,  a cornercorner with one O(9)Mn6 octahedra,  an edgeedge with one O(10)LiMn4Cd octahedra,  an edgeedge with one O(8)LiMn4Cd octahedra,  an edgeedge with one O(1)Mn5 trigonal bipyramid, and  an edgeedge with one O(4)Mn5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 29-71°. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one Mn(3), one Mn(7), one Mn(9), and one Cd(1) atom. In the eighth O site, O(8) is bonded to one Li(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Cd(1) atom to form OLiMn4Cd octahedra that share corners with two equivalent O(2)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, corners with four equivalent O(1)Mn5 trigonal bipyramids,  an edgeedge with one O(10)LiMn4Cd octahedra,  an edgeedge with one O(9)Mn6 octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, and  an edgeedge with one O(6)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-7°. In the ninth O site, O(9) is bonded to one Mn(1), one Mn(4), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(2)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, corners with two equivalent O(1)Mn5 trigonal bipyramids,  an edgeedge with one O(8)LiMn4Cd octahedra, edges with two equivalent O(10)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, and edges with two equivalent O(4)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-4°. In the tenth O site, O(10) is bonded to one Li(1), one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Cd(1) atom to form OLiMn4Cd octahedra that share corners with two equivalent O(3)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, corners with four equivalent O(4)Mn5 trigonal bipyramids,  an edgeedge with one O(8)LiMn4Cd octahedra,  an edgeedge with one O(5)Mn6 octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra, and  an edgeedge with one O(6)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-7°. is represented by the CIF card [CIF]
data_LiMn9CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.700
_cell_length_b   8.995
_cell_length_c   5.580
_cell_angle_alpha   71.864
_cell_angle_beta   103.750
_cell_angle_gamma   94.206
_symmetry_Int_Tables_number   1
_cell_volume   264.099
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.275  0.798  0.611  1.0
  Mn  Mn1  1  0.537  0.407  0.328  1.0
  Mn  Mn2  1  0.032  0.027  0.014  1.0
  Mn  Mn3  1  0.545  0.046  0.514  1.0
  Mn  Mn4  1  0.036  0.572  0.245  1.0
  Mn  Mn5  1  0.040  0.202  0.432  1.0
  Mn  Mn6  1  0.533  0.193  0.932  1.0
  Mn  Mn7  1  0.550  0.553  0.764  1.0
  Mn  Mn8  1  0.043  0.397  0.837  1.0
  Mn  Mn9  1  0.821  0.800  0.448  1.0
  Cd  Cd10  1  0.446  0.801  0.074  1.0
  O  O11  1  0.791  0.048  0.267  1.0
  O  O12  1  0.795  0.403  0.095  1.0
  O  O13  1  0.791  0.197  0.694  1.0
  O  O14  1  0.794  0.552  0.518  1.0
  O  O15  1  0.288  0.203  0.172  1.0
  O  O16  1  0.108  0.800  0.276  1.0
  O  O17  1  0.614  0.800  0.701  1.0
  O  O18  1  0.274  0.027  0.748  1.0
  O  O19  1  0.291  0.396  0.579  1.0
  O  O20  1  0.277  0.573  0.977  1.0
[/CIF]
.
The structure described by LiMn9CdO10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 2-coordinate geometry to one Cd(1), one O(10), one O(6), one O(7), and one O(8) atom. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(8)O6 octahedra, corners with two equivalent Mn(2)O5 trigonal bipyramids, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Mn(3)O5 trigonal bipyramid, edges with two equivalent Mn(4)O5 trigonal bipyramids, and edges with two equivalent Mn(7)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(5), one O(6), and one O(8) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O5 trigonal bipyramid, corners with four equivalent Mn(3)O5 trigonal bipyramids,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. In the third Mn site, Mn(3) is bonded to one O(1), one O(3), one O(5), one O(7), and one O(8) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(8)O6 octahedra,  a cornercorner with one Mn(7)O5 trigonal bipyramid, corners with four equivalent Mn(2)O5 trigonal bipyramids,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(2), one O(4), one O(6), and one O(9) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one Mn(2)O5 trigonal bipyramid, corners with four equivalent Mn(7)O5 trigonal bipyramids,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(6)O6 octahedra, corners with two equivalent Mn(7)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Mn(4)O5 trigonal bipyramid, edges with two equivalent Mn(2)O5 trigonal bipyramids, and edges with two equivalent Mn(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(5)O6 octahedra, corners with two equivalent Mn(4)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Mn(7)O5 trigonal bipyramid, edges with two equivalent Mn(2)O5 trigonal bipyramids, and edges with two equivalent Mn(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the seventh Mn site, Mn(7) is bonded to one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(5)O6 octahedra,  a cornercorner with one Mn(3)O5 trigonal bipyramid, corners with four equivalent Mn(4)O5 trigonal bipyramids,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Mn(2)O5 trigonal bipyramid, edges with two equivalent Mn(4)O5 trigonal bipyramids, and edges with two equivalent Mn(7)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the ninth Mn site, Mn(9) is bonded in a distorted square co-planar geometry to one Cd(1), one O(1), one O(4), one O(6), and one O(7) atom. Cd(1) is bonded in a 6-coordinate geometry to one Li(1), one Mn(9), one O(10), one O(6), one O(7), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(9) atom to form OMn5 trigonal bipyramids that share corners with two equivalent O(9)Mn6 octahedra, corners with four equivalent O(8)LiMn4Cd octahedra,  a cornercorner with one O(4)Mn5 trigonal bipyramid,  an edgeedge with one O(2)Mn6 octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, and  an edgeedge with one O(6)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-81°. In the second O site, O(2) is bonded to one Mn(1), one Mn(4), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(8)LiMn4Cd octahedra, corners with two equivalent O(9)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, edges with two equivalent O(10)LiMn4Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra,  an edgeedge with one O(1)Mn5 trigonal bipyramid, and edges with two equivalent O(4)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-7°. In the third O site, O(3) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(10)LiMn4Cd octahedra, corners with two equivalent O(5)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, edges with two equivalent O(8)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra,  an edgeedge with one O(4)Mn5 trigonal bipyramid, and edges with two equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth O site, O(4) is bonded to one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Mn(9) atom to form OMn5 trigonal bipyramids that share corners with two equivalent O(5)Mn6 octahedra, corners with four equivalent O(10)LiMn4Cd octahedra,  a cornercorner with one O(1)Mn5 trigonal bipyramid,  an edgeedge with one O(3)Mn6 octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra, and  an edgeedge with one O(6)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-81°. In the fifth O site, O(5) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(3)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, corners with two equivalent O(4)Mn5 trigonal bipyramids,  an edgeedge with one O(10)LiMn4Cd octahedra, edges with two equivalent O(8)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra, and edges with two equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-4°. In the sixth O site, O(6) is bonded to one Li(1), one Mn(2), one Mn(4), one Mn(9), and one Cd(1) atom to form distorted OLiMn3Cd trigonal bipyramids that share  a cornercorner with one O(10)LiMn4Cd octahedra,  a cornercorner with one O(8)LiMn4Cd octahedra,  a cornercorner with one O(2)Mn6 octahedra,  a cornercorner with one O(3)Mn6 octahedra,  a cornercorner with one O(5)Mn6 octahedra,  a cornercorner with one O(9)Mn6 octahedra,  an edgeedge with one O(10)LiMn4Cd octahedra,  an edgeedge with one O(8)LiMn4Cd octahedra,  an edgeedge with one O(1)Mn5 trigonal bipyramid, and  an edgeedge with one O(4)Mn5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 29-71°. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one Mn(3), one Mn(7), one Mn(9), and one Cd(1) atom. In the eighth O site, O(8) is bonded to one Li(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Cd(1) atom to form OLiMn4Cd octahedra that share corners with two equivalent O(2)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, corners with four equivalent O(1)Mn5 trigonal bipyramids,  an edgeedge with one O(10)LiMn4Cd octahedra,  an edgeedge with one O(9)Mn6 octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, and  an edgeedge with one O(6)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-7°. In the ninth O site, O(9) is bonded to one Mn(1), one Mn(4), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(2)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, corners with two equivalent O(1)Mn5 trigonal bipyramids,  an edgeedge with one O(8)LiMn4Cd octahedra, edges with two equivalent O(10)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(5)Mn6 octahedra, and edges with two equivalent O(4)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-4°. In the tenth O site, O(10) is bonded to one Li(1), one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Cd(1) atom to form OLiMn4Cd octahedra that share corners with two equivalent O(3)Mn6 octahedra,  a cornercorner with one O(6)LiMn3Cd trigonal bipyramid, corners with four equivalent O(4)Mn5 trigonal bipyramids,  an edgeedge with one O(8)LiMn4Cd octahedra,  an edgeedge with one O(5)Mn6 octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with two equivalent O(9)Mn6 octahedra, and  an edgeedge with one O(6)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-7°. is represented by the CIF card [CIF]
data_LiMn9CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.700
_cell_length_b   8.995
_cell_length_c   5.580
_cell_angle_alpha   71.864
_cell_angle_beta   103.750
_cell_angle_gamma   94.206
_symmetry_Int_Tables_number   1
_cell_volume   264.099
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.275  0.798  0.611  1.0
  Mn  Mn1  1  0.537  0.407  0.328  1.0
  Mn  Mn2  1  0.032  0.027  0.014  1.0
  Mn  Mn3  1  0.545  0.046  0.514  1.0
  Mn  Mn4  1  0.036  0.572  0.245  1.0
  Mn  Mn5  1  0.040  0.202  0.432  1.0
  Mn  Mn6  1  0.533  0.193  0.932  1.0
  Mn  Mn7  1  0.550  0.553  0.764  1.0
  Mn  Mn8  1  0.043  0.397  0.837  1.0
  Mn  Mn9  1  0.821  0.800  0.448  1.0
  Cd  Cd10  1  0.446  0.801  0.074  1.0
  O  O11  1  0.791  0.048  0.267  1.0
  O  O12  1  0.795  0.403  0.095  1.0
  O  O13  1  0.791  0.197  0.694  1.0
  O  O14  1  0.794  0.552  0.518  1.0
  O  O15  1  0.288  0.203  0.172  1.0
  O  O16  1  0.108  0.800  0.276  1.0
  O  O17  1  0.614  0.800  0.701  1.0
  O  O18  1  0.274  0.027  0.748  1.0
  O  O19  1  0.291  0.396  0.579  1.0
  O  O20  1  0.277  0.573  0.977  1.0
[/CIF]
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