The material described by KOsN(OCl2)2 crystallizes in the orthorhombic Cmc2_1 space group. K(1) is bonded in a 8-coordinate geometry to one N(1), one O(1), two equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. Os(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. N(1) is bonded in a distorted single-bond geometry to one K(1) and one Os(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one K(1) and one Os(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to one K(1) and one Os(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one K(1) and one Os(1) atom. is represented by the CIF file [CIF]
data_KOsN(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.935
_cell_length_b   7.935
_cell_length_c   7.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.921
_symmetry_Int_Tables_number   1
_cell_volume   446.394
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.650  0.350  0.000  1.0
  K  K1  1  0.350  0.650  0.500  1.0
  Os  Os2  1  0.161  0.839  0.996  1.0
  Os  Os3  1  0.839  0.161  0.496  1.0
  N  N4  1  0.168  0.832  0.768  1.0
  N  N5  1  0.832  0.168  0.268  1.0
  Cl  Cl6  1  0.214  0.139  0.037  1.0
  Cl  Cl7  1  0.861  0.786  0.037  1.0
  Cl  Cl8  1  0.786  0.861  0.537  1.0
  Cl  Cl9  1  0.139  0.214  0.537  1.0
  Cl  Cl10  1  0.469  0.869  0.010  1.0
  Cl  Cl11  1  0.131  0.531  0.010  1.0
  Cl  Cl12  1  0.531  0.131  0.510  1.0
  Cl  Cl13  1  0.869  0.469  0.510  1.0
  O  O14  1  0.183  0.817  0.265  1.0
  O  O15  1  0.817  0.183  0.765  1.0
  O  O16  1  0.579  0.421  0.372  1.0
  O  O17  1  0.421  0.579  0.872  1.0
[/CIF]
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The material described by KOsN(OCl2)2 crystallizes in the orthorhombic Cmc2_1 space group. K(1) is bonded in a 8-coordinate geometry to one N(1), one O(1), two equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. Os(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. N(1) is bonded in a distorted single-bond geometry to one K(1) and one Os(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one K(1) and one Os(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to one K(1) and one Os(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one K(1) and one Os(1) atom. is represented by the CIF file [CIF]
data_KOsN(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.935
_cell_length_b   7.935
_cell_length_c   7.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.921
_symmetry_Int_Tables_number   1
_cell_volume   446.394
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.650  0.350  0.000  1.0
  K  K1  1  0.350  0.650  0.500  1.0
  Os  Os2  1  0.161  0.839  0.996  1.0
  Os  Os3  1  0.839  0.161  0.496  1.0
  N  N4  1  0.168  0.832  0.768  1.0
  N  N5  1  0.832  0.168  0.268  1.0
  Cl  Cl6  1  0.214  0.139  0.037  1.0
  Cl  Cl7  1  0.861  0.786  0.037  1.0
  Cl  Cl8  1  0.786  0.861  0.537  1.0
  Cl  Cl9  1  0.139  0.214  0.537  1.0
  Cl  Cl10  1  0.469  0.869  0.010  1.0
  Cl  Cl11  1  0.131  0.531  0.010  1.0
  Cl  Cl12  1  0.531  0.131  0.510  1.0
  Cl  Cl13  1  0.869  0.469  0.510  1.0
  O  O14  1  0.183  0.817  0.265  1.0
  O  O15  1  0.817  0.183  0.765  1.0
  O  O16  1  0.579  0.421  0.372  1.0
  O  O17  1  0.421  0.579  0.872  1.0
[/CIF]
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