The crystal structure described by LiAl2Pb2H4(O2F3)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a distorted linear geometry to two equivalent F(3) atoms. Al(1) is bonded to one O(2), two equivalent O(1), one F(1), one F(2), and one F(3) atom to form edge-sharing AlO3F3 octahedra. Pb(1) is bonded in a distorted pentagonal planar geometry to two equivalent O(2), one F(1), one F(2), and one F(3) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Al(1) and one H(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Al(1), two equivalent Pb(1), and one H(2) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Al(1) and one Pb(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Li(1), one Al(1), and one Pb(1) atom. is represented by the CIF card [CIF]
data_LiAl2H4Pb2(O2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.423
_cell_length_b   7.589
_cell_length_c   5.085
_cell_angle_alpha   94.949
_cell_angle_beta   103.181
_cell_angle_gamma   108.104
_symmetry_Int_Tables_number   1
_cell_volume   226.094
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Al  Al1  1  0.192  0.656  0.175  1.0
  Al  Al2  1  0.808  0.344  0.825  1.0
  H  H3  1  0.159  0.491  0.692  1.0
  H  H4  1  0.841  0.509  0.308  1.0
  H  H5  1  0.229  0.866  0.838  1.0
  H  H6  1  0.771  0.134  0.162  1.0
  Pb  Pb7  1  0.783  0.870  0.660  1.0
  Pb  Pb8  1  0.217  0.130  0.340  1.0
  O  O9  1  0.126  0.459  0.866  1.0
  O  O10  1  0.874  0.541  0.134  1.0
  O  O11  1  0.141  0.848  0.975  1.0
  O  O12  1  0.859  0.152  0.025  1.0
  F  F13  1  0.269  0.828  0.490  1.0
  F  F14  1  0.731  0.172  0.510  1.0
  F  F15  1  0.255  0.493  0.407  1.0
  F  F16  1  0.745  0.507  0.593  1.0
  F  F17  1  0.492  0.729  0.158  1.0
  F  F18  1  0.508  0.271  0.842  1.0
[/CIF]
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The crystal structure described by LiAl2Pb2H4(O2F3)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a distorted linear geometry to two equivalent F(3) atoms. Al(1) is bonded to one O(2), two equivalent O(1), one F(1), one F(2), and one F(3) atom to form edge-sharing AlO3F3 octahedra. Pb(1) is bonded in a distorted pentagonal planar geometry to two equivalent O(2), one F(1), one F(2), and one F(3) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Al(1) and one H(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Al(1), two equivalent Pb(1), and one H(2) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Al(1) and one Pb(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Li(1), one Al(1), and one Pb(1) atom. is represented by the CIF card [CIF]
data_LiAl2H4Pb2(O2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.423
_cell_length_b   7.589
_cell_length_c   5.085
_cell_angle_alpha   94.949
_cell_angle_beta   103.181
_cell_angle_gamma   108.104
_symmetry_Int_Tables_number   1
_cell_volume   226.094
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Al  Al1  1  0.192  0.656  0.175  1.0
  Al  Al2  1  0.808  0.344  0.825  1.0
  H  H3  1  0.159  0.491  0.692  1.0
  H  H4  1  0.841  0.509  0.308  1.0
  H  H5  1  0.229  0.866  0.838  1.0
  H  H6  1  0.771  0.134  0.162  1.0
  Pb  Pb7  1  0.783  0.870  0.660  1.0
  Pb  Pb8  1  0.217  0.130  0.340  1.0
  O  O9  1  0.126  0.459  0.866  1.0
  O  O10  1  0.874  0.541  0.134  1.0
  O  O11  1  0.141  0.848  0.975  1.0
  O  O12  1  0.859  0.152  0.025  1.0
  F  F13  1  0.269  0.828  0.490  1.0
  F  F14  1  0.731  0.172  0.510  1.0
  F  F15  1  0.255  0.493  0.407  1.0
  F  F16  1  0.745  0.507  0.593  1.0
  F  F17  1  0.492  0.729  0.158  1.0
  F  F18  1  0.508  0.271  0.842  1.0
[/CIF]
.