The crystal structure described by (CrCdN2)2Cd crystallizes in the monoclinic C2/c space group. The structure consists of four 7440-43-9 atoms inside a CrCdN2 framework. In the CrCdN2 framework, Cr(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form a mixture of edge and corner-sharing CrN4 tetrahedra. Cd(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent Cr(1) and two equivalent Cd(1) atoms. In the second N site, N(2) is bonded in a linear geometry to two equivalent Cr(1) atoms. is represented by the CIF card [CIF]
data_Cr2Cd3N4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.094
_cell_length_b   8.730
_cell_length_c   5.847
_cell_angle_alpha   90.000
_cell_angle_beta   112.266
_cell_angle_gamma   122.636
_symmetry_Int_Tables_number   1
_cell_volume   310.709
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.513  0.148  0.522  1.0
  Cr  Cr1  1  0.487  0.635  0.978  1.0
  Cr  Cr2  1  0.487  0.852  0.478  1.0
  Cr  Cr3  1  0.513  0.365  0.022  1.0
  Cd  Cd4  1  0.987  0.824  0.978  1.0
  Cd  Cd5  1  0.013  0.837  0.522  1.0
  Cd  Cd6  1  0.013  0.176  0.022  1.0
  Cd  Cd7  1  0.987  0.163  0.478  1.0
  Cd  Cd8  1  0.000  0.514  0.750  1.0
  Cd  Cd9  1  0.000  0.486  0.250  1.0
  N  N10  1  0.278  0.900  0.386  1.0
  N  N11  1  0.722  0.621  0.114  1.0
  N  N12  1  0.722  0.100  0.614  1.0
  N  N13  1  0.278  0.379  0.886  1.0
  N  N14  1  0.523  0.252  0.789  1.0
  N  N15  1  0.477  0.728  0.711  1.0
  N  N16  1  0.477  0.748  0.211  1.0
  N  N17  1  0.523  0.272  0.289  1.0
[/CIF]
.
The crystal structure described by (CrCdN2)2Cd crystallizes in the monoclinic C2/c space group. The structure consists of four 7440-43-9 atoms inside a CrCdN2 framework. In the CrCdN2 framework, Cr(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form a mixture of edge and corner-sharing CrN4 tetrahedra. Cd(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent Cr(1) and two equivalent Cd(1) atoms. In the second N site, N(2) is bonded in a linear geometry to two equivalent Cr(1) atoms. is represented by the CIF card [CIF]
data_Cr2Cd3N4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.094
_cell_length_b   8.730
_cell_length_c   5.847
_cell_angle_alpha   90.000
_cell_angle_beta   112.266
_cell_angle_gamma   122.636
_symmetry_Int_Tables_number   1
_cell_volume   310.709
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.513  0.148  0.522  1.0
  Cr  Cr1  1  0.487  0.635  0.978  1.0
  Cr  Cr2  1  0.487  0.852  0.478  1.0
  Cr  Cr3  1  0.513  0.365  0.022  1.0
  Cd  Cd4  1  0.987  0.824  0.978  1.0
  Cd  Cd5  1  0.013  0.837  0.522  1.0
  Cd  Cd6  1  0.013  0.176  0.022  1.0
  Cd  Cd7  1  0.987  0.163  0.478  1.0
  Cd  Cd8  1  0.000  0.514  0.750  1.0
  Cd  Cd9  1  0.000  0.486  0.250  1.0
  N  N10  1  0.278  0.900  0.386  1.0
  N  N11  1  0.722  0.621  0.114  1.0
  N  N12  1  0.722  0.100  0.614  1.0
  N  N13  1  0.278  0.379  0.886  1.0
  N  N14  1  0.523  0.252  0.789  1.0
  N  N15  1  0.477  0.728  0.711  1.0
  N  N16  1  0.477  0.748  0.211  1.0
  N  N17  1  0.523  0.272  0.289  1.0
[/CIF]
.