The material structure described by Mn3Rh2CoAs3 crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 11-coordinate geometry to four equivalent Rh(1), two equivalent Co(1), one As(2), and four equivalent As(1) atoms. In the second Mn site, Mn(2) is bonded in a 11-coordinate geometry to four equivalent Rh(1), two equivalent Co(1), one As(2), and four equivalent As(1) atoms. Rh(1) is bonded in a 11-coordinate geometry to two equivalent Mn(1), four equivalent Mn(2), one Co(1), two equivalent As(1), and two equivalent As(2) atoms. Co(1) is bonded in a 12-coordinate geometry to two equivalent Mn(1), four equivalent Mn(2), two equivalent Rh(1), two equivalent As(1), and two equivalent As(2) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 9-coordinate geometry to two equivalent Mn(1), four equivalent Mn(2), two equivalent Rh(1), and one Co(1) atom. In the second As site, As(2) is bonded in a 9-coordinate geometry to one Mn(1), two equivalent Mn(2), four equivalent Rh(1), and two equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_Mn3CoAs3Rh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.654
_cell_length_b   6.425
_cell_length_c   6.425
_cell_angle_alpha   58.927
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   129.189
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.587  0.413  1.0
  Mn  Mn1  1  0.500  0.406  0.998  1.0
  Mn  Mn2  1  0.500  0.002  0.594  1.0
  Co  Co3  1  0.000  0.260  0.740  1.0
  As  As4  1  0.000  0.329  0.348  1.0
  As  As5  1  0.000  0.652  0.671  1.0
  As  As6  1  0.500  0.019  0.981  1.0
  Rh  Rh7  1  0.000  0.741  0.997  1.0
  Rh  Rh8  1  0.000  0.003  0.259  1.0
[/CIF]
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The material structure described by Mn3Rh2CoAs3 crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 11-coordinate geometry to four equivalent Rh(1), two equivalent Co(1), one As(2), and four equivalent As(1) atoms. In the second Mn site, Mn(2) is bonded in a 11-coordinate geometry to four equivalent Rh(1), two equivalent Co(1), one As(2), and four equivalent As(1) atoms. Rh(1) is bonded in a 11-coordinate geometry to two equivalent Mn(1), four equivalent Mn(2), one Co(1), two equivalent As(1), and two equivalent As(2) atoms. Co(1) is bonded in a 12-coordinate geometry to two equivalent Mn(1), four equivalent Mn(2), two equivalent Rh(1), two equivalent As(1), and two equivalent As(2) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 9-coordinate geometry to two equivalent Mn(1), four equivalent Mn(2), two equivalent Rh(1), and one Co(1) atom. In the second As site, As(2) is bonded in a 9-coordinate geometry to one Mn(1), two equivalent Mn(2), four equivalent Rh(1), and two equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_Mn3CoAs3Rh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.654
_cell_length_b   6.425
_cell_length_c   6.425
_cell_angle_alpha   58.927
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   129.189
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.587  0.413  1.0
  Mn  Mn1  1  0.500  0.406  0.998  1.0
  Mn  Mn2  1  0.500  0.002  0.594  1.0
  Co  Co3  1  0.000  0.260  0.740  1.0
  As  As4  1  0.000  0.329  0.348  1.0
  As  As5  1  0.000  0.652  0.671  1.0
  As  As6  1  0.500  0.019  0.981  1.0
  Rh  Rh7  1  0.000  0.741  0.997  1.0
  Rh  Rh8  1  0.000  0.003  0.259  1.0
[/CIF]
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