The material structure described by (CoSiN2ClF6)2(N2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two triazane molecules and two CoSiN2ClF6 clusters. In each CoSiN2ClF6 cluster, Co(1) is bonded in a 3-coordinate geometry to two equivalent N(3), one Cl(1), and two equivalent F(3) atoms. Si(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. N(3) is bonded in a distorted L-shaped geometry to one Co(1) and one N(3) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Co(1) and one Si(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Si(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoSiN5ClF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.772
_cell_length_b   7.381
_cell_length_c   10.693
_cell_angle_alpha   80.166
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.694
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.750  0.852  0.926  1.0
  Co  Co1  1  0.250  0.148  0.074  1.0
  Si  Si2  1  0.750  0.664  0.705  1.0
  Si  Si3  1  0.250  0.336  0.295  1.0
  N  N4  1  0.750  0.740  0.380  1.0
  N  N5  1  0.250  0.260  0.620  1.0
  N  N6  1  0.926  0.742  0.379  1.0
  N  N7  1  0.426  0.258  0.621  1.0
  N  N8  1  0.074  0.258  0.621  1.0
  N  N9  1  0.574  0.742  0.379  1.0
  N  N10  1  0.833  0.573  0.107  1.0
  N  N11  1  0.333  0.427  0.893  1.0
  N  N12  1  0.167  0.427  0.893  1.0
  N  N13  1  0.667  0.573  0.107  1.0
  Cl  Cl14  1  0.750  0.084  0.022  1.0
  Cl  Cl15  1  0.250  0.916  0.978  1.0
  F  F16  1  0.750  0.473  0.810  1.0
  F  F17  1  0.250  0.527  0.190  1.0
  F  F18  1  0.750  0.877  0.624  1.0
  F  F19  1  0.250  0.123  0.376  1.0
  F  F20  1  0.929  0.756  0.816  1.0
  F  F21  1  0.429  0.244  0.184  1.0
  F  F22  1  0.071  0.244  0.184  1.0
  F  F23  1  0.571  0.756  0.816  1.0
  F  F24  1  0.938  0.598  0.622  1.0
  F  F25  1  0.438  0.402  0.378  1.0
  F  F26  1  0.062  0.402  0.378  1.0
  F  F27  1  0.562  0.598  0.622  1.0
[/CIF]
.
The material structure described by (CoSiN2ClF6)2(N2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two triazane molecules and two CoSiN2ClF6 clusters. In each CoSiN2ClF6 cluster, Co(1) is bonded in a 3-coordinate geometry to two equivalent N(3), one Cl(1), and two equivalent F(3) atoms. Si(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. N(3) is bonded in a distorted L-shaped geometry to one Co(1) and one N(3) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Co(1) and one Si(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Si(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoSiN5ClF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.772
_cell_length_b   7.381
_cell_length_c   10.693
_cell_angle_alpha   80.166
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.694
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.750  0.852  0.926  1.0
  Co  Co1  1  0.250  0.148  0.074  1.0
  Si  Si2  1  0.750  0.664  0.705  1.0
  Si  Si3  1  0.250  0.336  0.295  1.0
  N  N4  1  0.750  0.740  0.380  1.0
  N  N5  1  0.250  0.260  0.620  1.0
  N  N6  1  0.926  0.742  0.379  1.0
  N  N7  1  0.426  0.258  0.621  1.0
  N  N8  1  0.074  0.258  0.621  1.0
  N  N9  1  0.574  0.742  0.379  1.0
  N  N10  1  0.833  0.573  0.107  1.0
  N  N11  1  0.333  0.427  0.893  1.0
  N  N12  1  0.167  0.427  0.893  1.0
  N  N13  1  0.667  0.573  0.107  1.0
  Cl  Cl14  1  0.750  0.084  0.022  1.0
  Cl  Cl15  1  0.250  0.916  0.978  1.0
  F  F16  1  0.750  0.473  0.810  1.0
  F  F17  1  0.250  0.527  0.190  1.0
  F  F18  1  0.750  0.877  0.624  1.0
  F  F19  1  0.250  0.123  0.376  1.0
  F  F20  1  0.929  0.756  0.816  1.0
  F  F21  1  0.429  0.244  0.184  1.0
  F  F22  1  0.071  0.244  0.184  1.0
  F  F23  1  0.571  0.756  0.816  1.0
  F  F24  1  0.938  0.598  0.622  1.0
  F  F25  1  0.438  0.402  0.378  1.0
  F  F26  1  0.062  0.402  0.378  1.0
  F  F27  1  0.562  0.598  0.622  1.0
[/CIF]
.