The material structure described by NdOsGa4 crystallizes in the orthorhombic Pmma space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 16-coordinate geometry to four equivalent Os(1), two equivalent Ga(4), two equivalent Ga(6), four equivalent Ga(1), and four equivalent Ga(5) atoms. In the second Nd site, Nd(2) is bonded in a 10-coordinate geometry to one Ga(2), one Ga(4), two equivalent Ga(3), two equivalent Ga(5), two equivalent Ga(6), and four equivalent Ga(1) atoms. There are two inequivalent Os sites. In the first Os site, Os(2) is bonded in a 8-coordinate geometry to two equivalent Ga(2), two equivalent Ga(3), and four equivalent Ga(1) atoms. In the second Os site, Os(1) is bonded in a 8-coordinate geometry to two equivalent Nd(1), two equivalent Ga(1), two equivalent Ga(3), two equivalent Ga(4), and two equivalent Ga(5) atoms. There are six inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 9-coordinate geometry to one Nd(1), two equivalent Nd(2), one Os(1), one Os(2), one Ga(2), one Ga(3), one Ga(4), and one Ga(6) atom. In the second Ga site, Ga(2) is bonded in a 10-coordinate geometry to two equivalent Nd(2), two equivalent Os(2), two equivalent Ga(4), and four equivalent Ga(1) atoms. In the third Ga site, Ga(3) is bonded in a 10-coordinate geometry to two equivalent Nd(2), one Os(2), two equivalent Os(1), one Ga(3), two equivalent Ga(1), and two equivalent Ga(4) atoms. In the fourth Ga site, Ga(4) is bonded in a 10-coordinate geometry to one Nd(1), one Nd(2), two equivalent Os(1), one Ga(2), one Ga(4), two equivalent Ga(1), and two equivalent Ga(3) atoms. In the fifth Ga site, Ga(5) is bonded in a 5-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Os(1), and one Ga(6) atom. In the sixth Ga site, Ga(6) is bonded to two equivalent Nd(1), four equivalent Nd(2), two equivalent Ga(5), and four equivalent Ga(1) atoms to form face-sharing GaNd6Ga6 cuboctahedra. is represented by the CIF file [CIF]
data_NdGa4Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.633
_cell_length_b   8.738
_cell_length_c   9.681
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   645.779
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.320  0.500  0.750  1.0
  Nd  Nd1  1  0.680  0.500  0.250  1.0
  Nd  Nd2  1  0.839  0.249  0.750  1.0
  Nd  Nd3  1  0.161  0.751  0.250  1.0
  Nd  Nd4  1  0.839  0.751  0.750  1.0
  Nd  Nd5  1  0.161  0.249  0.250  1.0
  Ga  Ga6  1  0.179  0.236  0.575  1.0
  Ga  Ga7  1  0.821  0.764  0.425  1.0
  Ga  Ga8  1  0.179  0.764  0.925  1.0
  Ga  Ga9  1  0.821  0.236  0.425  1.0
  Ga  Ga10  1  0.821  0.236  0.075  1.0
  Ga  Ga11  1  0.179  0.764  0.575  1.0
  Ga  Ga12  1  0.821  0.764  0.075  1.0
  Ga  Ga13  1  0.179  0.236  0.925  1.0
  Ga  Ga14  1  0.131  0.000  0.750  1.0
  Ga  Ga15  1  0.869  0.000  0.250  1.0
  Ga  Ga16  1  0.339  0.000  0.062  1.0
  Ga  Ga17  1  0.661  0.000  0.938  1.0
  Ga  Ga18  1  0.339  0.000  0.438  1.0
  Ga  Ga19  1  0.661  0.000  0.562  1.0
  Ga  Ga20  1  0.452  0.156  0.750  1.0
  Ga  Ga21  1  0.548  0.844  0.250  1.0
  Ga  Ga22  1  0.452  0.844  0.750  1.0
  Ga  Ga23  1  0.548  0.156  0.250  1.0
  Ga  Ga24  1  0.658  0.500  0.584  1.0
  Ga  Ga25  1  0.342  0.500  0.416  1.0
  Ga  Ga26  1  0.658  0.500  0.916  1.0
  Ga  Ga27  1  0.342  0.500  0.084  1.0
  Ga  Ga28  1  0.000  0.500  0.500  1.0
  Ga  Ga29  1  0.000  0.500  0.000  1.0
  Os  Os30  1  0.500  0.259  0.500  1.0
  Os  Os31  1  0.500  0.741  0.500  1.0
  Os  Os32  1  0.500  0.741  0.000  1.0
  Os  Os33  1  0.500  0.259  0.000  1.0
  Os  Os34  1  0.000  0.000  0.500  1.0
  Os  Os35  1  0.000  0.000  0.000  1.0
[/CIF]
.
The material structure described by NdOsGa4 crystallizes in the orthorhombic Pmma space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 16-coordinate geometry to four equivalent Os(1), two equivalent Ga(4), two equivalent Ga(6), four equivalent Ga(1), and four equivalent Ga(5) atoms. In the second Nd site, Nd(2) is bonded in a 10-coordinate geometry to one Ga(2), one Ga(4), two equivalent Ga(3), two equivalent Ga(5), two equivalent Ga(6), and four equivalent Ga(1) atoms. There are two inequivalent Os sites. In the first Os site, Os(2) is bonded in a 8-coordinate geometry to two equivalent Ga(2), two equivalent Ga(3), and four equivalent Ga(1) atoms. In the second Os site, Os(1) is bonded in a 8-coordinate geometry to two equivalent Nd(1), two equivalent Ga(1), two equivalent Ga(3), two equivalent Ga(4), and two equivalent Ga(5) atoms. There are six inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 9-coordinate geometry to one Nd(1), two equivalent Nd(2), one Os(1), one Os(2), one Ga(2), one Ga(3), one Ga(4), and one Ga(6) atom. In the second Ga site, Ga(2) is bonded in a 10-coordinate geometry to two equivalent Nd(2), two equivalent Os(2), two equivalent Ga(4), and four equivalent Ga(1) atoms. In the third Ga site, Ga(3) is bonded in a 10-coordinate geometry to two equivalent Nd(2), one Os(2), two equivalent Os(1), one Ga(3), two equivalent Ga(1), and two equivalent Ga(4) atoms. In the fourth Ga site, Ga(4) is bonded in a 10-coordinate geometry to one Nd(1), one Nd(2), two equivalent Os(1), one Ga(2), one Ga(4), two equivalent Ga(1), and two equivalent Ga(3) atoms. In the fifth Ga site, Ga(5) is bonded in a 5-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Os(1), and one Ga(6) atom. In the sixth Ga site, Ga(6) is bonded to two equivalent Nd(1), four equivalent Nd(2), two equivalent Ga(5), and four equivalent Ga(1) atoms to form face-sharing GaNd6Ga6 cuboctahedra. is represented by the CIF file [CIF]
data_NdGa4Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.633
_cell_length_b   8.738
_cell_length_c   9.681
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   645.779
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.320  0.500  0.750  1.0
  Nd  Nd1  1  0.680  0.500  0.250  1.0
  Nd  Nd2  1  0.839  0.249  0.750  1.0
  Nd  Nd3  1  0.161  0.751  0.250  1.0
  Nd  Nd4  1  0.839  0.751  0.750  1.0
  Nd  Nd5  1  0.161  0.249  0.250  1.0
  Ga  Ga6  1  0.179  0.236  0.575  1.0
  Ga  Ga7  1  0.821  0.764  0.425  1.0
  Ga  Ga8  1  0.179  0.764  0.925  1.0
  Ga  Ga9  1  0.821  0.236  0.425  1.0
  Ga  Ga10  1  0.821  0.236  0.075  1.0
  Ga  Ga11  1  0.179  0.764  0.575  1.0
  Ga  Ga12  1  0.821  0.764  0.075  1.0
  Ga  Ga13  1  0.179  0.236  0.925  1.0
  Ga  Ga14  1  0.131  0.000  0.750  1.0
  Ga  Ga15  1  0.869  0.000  0.250  1.0
  Ga  Ga16  1  0.339  0.000  0.062  1.0
  Ga  Ga17  1  0.661  0.000  0.938  1.0
  Ga  Ga18  1  0.339  0.000  0.438  1.0
  Ga  Ga19  1  0.661  0.000  0.562  1.0
  Ga  Ga20  1  0.452  0.156  0.750  1.0
  Ga  Ga21  1  0.548  0.844  0.250  1.0
  Ga  Ga22  1  0.452  0.844  0.750  1.0
  Ga  Ga23  1  0.548  0.156  0.250  1.0
  Ga  Ga24  1  0.658  0.500  0.584  1.0
  Ga  Ga25  1  0.342  0.500  0.416  1.0
  Ga  Ga26  1  0.658  0.500  0.916  1.0
  Ga  Ga27  1  0.342  0.500  0.084  1.0
  Ga  Ga28  1  0.000  0.500  0.500  1.0
  Ga  Ga29  1  0.000  0.500  0.000  1.0
  Os  Os30  1  0.500  0.259  0.500  1.0
  Os  Os31  1  0.500  0.741  0.500  1.0
  Os  Os32  1  0.500  0.741  0.000  1.0
  Os  Os33  1  0.500  0.259  0.000  1.0
  Os  Os34  1  0.000  0.000  0.500  1.0
  Os  Os35  1  0.000  0.000  0.000  1.0
[/CIF]
.