The structure described by PN2H crystallizes in the orthorhombic P2_12_12_1 space group. P(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing PN4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to two equivalent P(1) and one H(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PHN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.674
_cell_length_b   4.690
_cell_length_c   7.025
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   153.989
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.979  0.761  0.385  1.0
  P  P1  1  0.521  0.239  0.885  1.0
  P  P2  1  0.479  0.739  0.615  1.0
  P  P3  1  0.021  0.261  0.115  1.0
  H  H4  1  0.646  0.548  0.192  1.0
  H  H5  1  0.854  0.452  0.692  1.0
  H  H6  1  0.146  0.952  0.808  1.0
  H  H7  1  0.354  0.048  0.308  1.0
  N  N8  1  0.853  0.518  0.234  1.0
  N  N9  1  0.647  0.482  0.734  1.0
  N  N10  1  0.353  0.982  0.766  1.0
  N  N11  1  0.147  0.018  0.266  1.0
  N  N12  1  0.709  0.898  0.488  1.0
  N  N13  1  0.791  0.102  0.988  1.0
  N  N14  1  0.209  0.602  0.512  1.0
  N  N15  1  0.291  0.398  0.012  1.0
[/CIF]
.
The structure described by PN2H crystallizes in the orthorhombic P2_12_12_1 space group. P(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing PN4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to two equivalent P(1) and one H(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PHN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.674
_cell_length_b   4.690
_cell_length_c   7.025
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   153.989
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.979  0.761  0.385  1.0
  P  P1  1  0.521  0.239  0.885  1.0
  P  P2  1  0.479  0.739  0.615  1.0
  P  P3  1  0.021  0.261  0.115  1.0
  H  H4  1  0.646  0.548  0.192  1.0
  H  H5  1  0.854  0.452  0.692  1.0
  H  H6  1  0.146  0.952  0.808  1.0
  H  H7  1  0.354  0.048  0.308  1.0
  N  N8  1  0.853  0.518  0.234  1.0
  N  N9  1  0.647  0.482  0.734  1.0
  N  N10  1  0.353  0.982  0.766  1.0
  N  N11  1  0.147  0.018  0.266  1.0
  N  N12  1  0.709  0.898  0.488  1.0
  N  N13  1  0.791  0.102  0.988  1.0
  N  N14  1  0.209  0.602  0.512  1.0
  N  N15  1  0.291  0.398  0.012  1.0
[/CIF]
.