The material structure described by Re3Se4O3(O2)3 crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of eighteen hydrogen peroxide molecules and three Re3Se4O3 clusters. In each Re3Se4O3 cluster, Re(1) is bonded in a distorted single-bond geometry to one Se(2), three equivalent Se(1), and one O(1) atom. There are two inequivalent Se sites. In the first Se site, Se(2) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. In the second Se site, Se(1) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. O(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3Se4O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.877
_cell_length_b   9.877
_cell_length_c   9.877
_cell_angle_alpha   108.698
_cell_angle_beta   108.698
_cell_angle_gamma   108.698
_symmetry_Int_Tables_number   1
_cell_volume   762.272
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.926  0.926  0.695  1.0
  Re  Re1  1  0.695  0.926  0.926  1.0
  Re  Re2  1  0.926  0.695  0.926  1.0
  Re  Re3  1  0.074  0.074  0.305  1.0
  Re  Re4  1  0.305  0.074  0.074  1.0
  Re  Re5  1  0.074  0.305  0.074  1.0
  Se  Se6  1  0.813  0.102  0.813  1.0
  Se  Se7  1  0.813  0.813  0.102  1.0
  Se  Se8  1  0.102  0.813  0.813  1.0
  Se  Se9  1  0.187  0.898  0.187  1.0
  Se  Se10  1  0.187  0.187  0.898  1.0
  Se  Se11  1  0.898  0.187  0.187  1.0
  Se  Se12  1  0.718  0.718  0.718  1.0
  Se  Se13  1  0.282  0.282  0.282  1.0
  O  O14  1  0.872  0.872  0.497  1.0
  O  O15  1  0.497  0.872  0.872  1.0
  O  O16  1  0.872  0.497  0.872  1.0
  O  O17  1  0.128  0.128  0.503  1.0
  O  O18  1  0.503  0.128  0.128  1.0
  O  O19  1  0.128  0.503  0.128  1.0
  O  O20  1  0.926  0.536  0.412  1.0
  O  O21  1  0.412  0.926  0.536  1.0
  O  O22  1  0.536  0.412  0.926  1.0
  O  O23  1  0.412  0.536  0.926  1.0
  O  O24  1  0.926  0.412  0.536  1.0
  O  O25  1  0.536  0.926  0.412  1.0
  O  O26  1  0.074  0.464  0.588  1.0
  O  O27  1  0.588  0.074  0.464  1.0
  O  O28  1  0.464  0.588  0.074  1.0
  O  O29  1  0.588  0.464  0.074  1.0
  O  O30  1  0.074  0.588  0.464  1.0
  O  O31  1  0.464  0.074  0.588  1.0
[/CIF]
.
The material structure described by Re3Se4O3(O2)3 crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of eighteen hydrogen peroxide molecules and three Re3Se4O3 clusters. In each Re3Se4O3 cluster, Re(1) is bonded in a distorted single-bond geometry to one Se(2), three equivalent Se(1), and one O(1) atom. There are two inequivalent Se sites. In the first Se site, Se(2) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. In the second Se site, Se(1) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. O(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3Se4O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.877
_cell_length_b   9.877
_cell_length_c   9.877
_cell_angle_alpha   108.698
_cell_angle_beta   108.698
_cell_angle_gamma   108.698
_symmetry_Int_Tables_number   1
_cell_volume   762.272
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.926  0.926  0.695  1.0
  Re  Re1  1  0.695  0.926  0.926  1.0
  Re  Re2  1  0.926  0.695  0.926  1.0
  Re  Re3  1  0.074  0.074  0.305  1.0
  Re  Re4  1  0.305  0.074  0.074  1.0
  Re  Re5  1  0.074  0.305  0.074  1.0
  Se  Se6  1  0.813  0.102  0.813  1.0
  Se  Se7  1  0.813  0.813  0.102  1.0
  Se  Se8  1  0.102  0.813  0.813  1.0
  Se  Se9  1  0.187  0.898  0.187  1.0
  Se  Se10  1  0.187  0.187  0.898  1.0
  Se  Se11  1  0.898  0.187  0.187  1.0
  Se  Se12  1  0.718  0.718  0.718  1.0
  Se  Se13  1  0.282  0.282  0.282  1.0
  O  O14  1  0.872  0.872  0.497  1.0
  O  O15  1  0.497  0.872  0.872  1.0
  O  O16  1  0.872  0.497  0.872  1.0
  O  O17  1  0.128  0.128  0.503  1.0
  O  O18  1  0.503  0.128  0.128  1.0
  O  O19  1  0.128  0.503  0.128  1.0
  O  O20  1  0.926  0.536  0.412  1.0
  O  O21  1  0.412  0.926  0.536  1.0
  O  O22  1  0.536  0.412  0.926  1.0
  O  O23  1  0.412  0.536  0.926  1.0
  O  O24  1  0.926  0.412  0.536  1.0
  O  O25  1  0.536  0.926  0.412  1.0
  O  O26  1  0.074  0.464  0.588  1.0
  O  O27  1  0.588  0.074  0.464  1.0
  O  O28  1  0.464  0.588  0.074  1.0
  O  O29  1  0.588  0.464  0.074  1.0
  O  O30  1  0.074  0.588  0.464  1.0
  O  O31  1  0.464  0.074  0.588  1.0
[/CIF]
.