The material described by AgCN2H3 crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four AgCN2H3 clusters. Ag(1) is bonded in a linear geometry to one C(1) and one N(2) atom. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(2), and two equivalent H(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_AgH3CN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.330
_cell_length_b   5.854
_cell_length_c   15.632
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.241
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.751  0.250  0.524  1.0
  Ag  Ag1  1  0.249  0.750  0.476  1.0
  Ag  Ag2  1  0.751  0.750  0.976  1.0
  Ag  Ag3  1  0.249  0.250  0.024  1.0
  H  H4  1  0.525  0.390  0.673  1.0
  H  H5  1  0.475  0.890  0.327  1.0
  H  H6  1  0.525  0.610  0.827  1.0
  H  H7  1  0.475  0.110  0.173  1.0
  H  H8  1  0.475  0.610  0.327  1.0
  H  H9  1  0.525  0.110  0.673  1.0
  H  H10  1  0.475  0.390  0.173  1.0
  H  H11  1  0.525  0.890  0.827  1.0
  H  H12  1  0.842  0.250  0.699  1.0
  H  H13  1  0.158  0.750  0.301  1.0
  H  H14  1  0.842  0.750  0.801  1.0
  H  H15  1  0.158  0.250  0.199  1.0
  C  C16  1  0.827  0.250  0.396  1.0
  C  C17  1  0.173  0.750  0.604  1.0
  C  C18  1  0.827  0.750  0.104  1.0
  C  C19  1  0.173  0.250  0.896  1.0
  N  N20  1  0.872  0.250  0.322  1.0
  N  N21  1  0.128  0.750  0.678  1.0
  N  N22  1  0.872  0.750  0.178  1.0
  N  N23  1  0.128  0.250  0.822  1.0
  N  N24  1  0.655  0.250  0.659  1.0
  N  N25  1  0.345  0.750  0.341  1.0
  N  N26  1  0.655  0.750  0.841  1.0
  N  N27  1  0.345  0.250  0.159  1.0
[/CIF]
.
The material described by AgCN2H3 crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four AgCN2H3 clusters. Ag(1) is bonded in a linear geometry to one C(1) and one N(2) atom. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(2), and two equivalent H(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_AgH3CN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.330
_cell_length_b   5.854
_cell_length_c   15.632
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.241
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.751  0.250  0.524  1.0
  Ag  Ag1  1  0.249  0.750  0.476  1.0
  Ag  Ag2  1  0.751  0.750  0.976  1.0
  Ag  Ag3  1  0.249  0.250  0.024  1.0
  H  H4  1  0.525  0.390  0.673  1.0
  H  H5  1  0.475  0.890  0.327  1.0
  H  H6  1  0.525  0.610  0.827  1.0
  H  H7  1  0.475  0.110  0.173  1.0
  H  H8  1  0.475  0.610  0.327  1.0
  H  H9  1  0.525  0.110  0.673  1.0
  H  H10  1  0.475  0.390  0.173  1.0
  H  H11  1  0.525  0.890  0.827  1.0
  H  H12  1  0.842  0.250  0.699  1.0
  H  H13  1  0.158  0.750  0.301  1.0
  H  H14  1  0.842  0.750  0.801  1.0
  H  H15  1  0.158  0.250  0.199  1.0
  C  C16  1  0.827  0.250  0.396  1.0
  C  C17  1  0.173  0.750  0.604  1.0
  C  C18  1  0.827  0.750  0.104  1.0
  C  C19  1  0.173  0.250  0.896  1.0
  N  N20  1  0.872  0.250  0.322  1.0
  N  N21  1  0.128  0.750  0.678  1.0
  N  N22  1  0.872  0.750  0.178  1.0
  N  N23  1  0.128  0.250  0.822  1.0
  N  N24  1  0.655  0.250  0.659  1.0
  N  N25  1  0.345  0.750  0.341  1.0
  N  N26  1  0.655  0.750  0.841  1.0
  N  N27  1  0.345  0.250  0.159  1.0
[/CIF]
.