The material structure described by (CN3H6)2SbF5 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight guanidinium molecules and four SbF5 clusters. In each SbF5 cluster, Sb(1) is bonded in a square pyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbH12C2N6F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.063
_cell_length_b   9.063
_cell_length_c   9.776
_cell_angle_alpha   62.772
_cell_angle_beta   62.772
_cell_angle_gamma   56.014
_symmetry_Int_Tables_number   1
_cell_volume   569.481
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.654  0.654  0.862  1.0
  Sb  Sb1  1  0.346  0.346  0.138  1.0
  H  H2  1  0.004  0.214  0.770  1.0
  H  H3  1  0.214  0.004  0.770  1.0
  H  H4  1  0.996  0.786  0.230  1.0
  H  H5  1  0.786  0.996  0.230  1.0
  H  H6  1  0.011  0.733  0.830  1.0
  H  H7  1  0.733  0.011  0.830  1.0
  H  H8  1  0.989  0.267  0.170  1.0
  H  H9  1  0.267  0.989  0.170  1.0
  H  H10  1  0.214  0.738  0.806  1.0
  H  H11  1  0.738  0.214  0.806  1.0
  H  H12  1  0.786  0.262  0.194  1.0
  H  H13  1  0.262  0.786  0.194  1.0
  H  H14  1  0.626  0.835  0.137  1.0
  H  H15  1  0.835  0.626  0.137  1.0
  H  H16  1  0.374  0.165  0.863  1.0
  H  H17  1  0.165  0.374  0.863  1.0
  H  H18  1  0.786  0.509  0.548  1.0
  H  H19  1  0.509  0.786  0.548  1.0
  H  H20  1  0.214  0.491  0.452  1.0
  H  H21  1  0.491  0.214  0.452  1.0
  H  H22  1  0.922  0.444  0.370  1.0
  H  H23  1  0.444  0.922  0.370  1.0
  H  H24  1  0.078  0.556  0.630  1.0
  H  H25  1  0.556  0.078  0.630  1.0
  C  C26  1  0.986  0.986  0.802  1.0
  C  C27  1  0.014  0.014  0.198  1.0
  C  C28  1  0.680  0.680  0.354  1.0
  C  C29  1  0.320  0.320  0.646  1.0
  N  N30  1  0.075  0.075  0.780  1.0
  N  N31  1  0.925  0.925  0.220  1.0
  N  N32  1  0.077  0.805  0.813  1.0
  N  N33  1  0.805  0.077  0.813  1.0
  N  N34  1  0.923  0.195  0.187  1.0
  N  N35  1  0.195  0.923  0.187  1.0
  N  N36  1  0.716  0.716  0.196  1.0
  N  N37  1  0.284  0.284  0.804  1.0
  N  N38  1  0.799  0.526  0.433  1.0
  N  N39  1  0.526  0.799  0.433  1.0
  N  N40  1  0.201  0.474  0.567  1.0
  N  N41  1  0.474  0.201  0.567  1.0
  F  F42  1  0.759  0.759  0.637  1.0
  F  F43  1  0.241  0.241  0.363  1.0
  F  F44  1  0.430  0.772  0.769  1.0
  F  F45  1  0.772  0.430  0.769  1.0
  F  F46  1  0.570  0.228  0.231  1.0
  F  F47  1  0.228  0.570  0.231  1.0
  F  F48  1  0.920  0.580  0.867  1.0
  F  F49  1  0.580  0.920  0.867  1.0
  F  F50  1  0.080  0.420  0.133  1.0
  F  F51  1  0.420  0.080  0.133  1.0
[/CIF]
.
The material structure described by (CN3H6)2SbF5 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight guanidinium molecules and four SbF5 clusters. In each SbF5 cluster, Sb(1) is bonded in a square pyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbH12C2N6F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.063
_cell_length_b   9.063
_cell_length_c   9.776
_cell_angle_alpha   62.772
_cell_angle_beta   62.772
_cell_angle_gamma   56.014
_symmetry_Int_Tables_number   1
_cell_volume   569.481
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.654  0.654  0.862  1.0
  Sb  Sb1  1  0.346  0.346  0.138  1.0
  H  H2  1  0.004  0.214  0.770  1.0
  H  H3  1  0.214  0.004  0.770  1.0
  H  H4  1  0.996  0.786  0.230  1.0
  H  H5  1  0.786  0.996  0.230  1.0
  H  H6  1  0.011  0.733  0.830  1.0
  H  H7  1  0.733  0.011  0.830  1.0
  H  H8  1  0.989  0.267  0.170  1.0
  H  H9  1  0.267  0.989  0.170  1.0
  H  H10  1  0.214  0.738  0.806  1.0
  H  H11  1  0.738  0.214  0.806  1.0
  H  H12  1  0.786  0.262  0.194  1.0
  H  H13  1  0.262  0.786  0.194  1.0
  H  H14  1  0.626  0.835  0.137  1.0
  H  H15  1  0.835  0.626  0.137  1.0
  H  H16  1  0.374  0.165  0.863  1.0
  H  H17  1  0.165  0.374  0.863  1.0
  H  H18  1  0.786  0.509  0.548  1.0
  H  H19  1  0.509  0.786  0.548  1.0
  H  H20  1  0.214  0.491  0.452  1.0
  H  H21  1  0.491  0.214  0.452  1.0
  H  H22  1  0.922  0.444  0.370  1.0
  H  H23  1  0.444  0.922  0.370  1.0
  H  H24  1  0.078  0.556  0.630  1.0
  H  H25  1  0.556  0.078  0.630  1.0
  C  C26  1  0.986  0.986  0.802  1.0
  C  C27  1  0.014  0.014  0.198  1.0
  C  C28  1  0.680  0.680  0.354  1.0
  C  C29  1  0.320  0.320  0.646  1.0
  N  N30  1  0.075  0.075  0.780  1.0
  N  N31  1  0.925  0.925  0.220  1.0
  N  N32  1  0.077  0.805  0.813  1.0
  N  N33  1  0.805  0.077  0.813  1.0
  N  N34  1  0.923  0.195  0.187  1.0
  N  N35  1  0.195  0.923  0.187  1.0
  N  N36  1  0.716  0.716  0.196  1.0
  N  N37  1  0.284  0.284  0.804  1.0
  N  N38  1  0.799  0.526  0.433  1.0
  N  N39  1  0.526  0.799  0.433  1.0
  N  N40  1  0.201  0.474  0.567  1.0
  N  N41  1  0.474  0.201  0.567  1.0
  F  F42  1  0.759  0.759  0.637  1.0
  F  F43  1  0.241  0.241  0.363  1.0
  F  F44  1  0.430  0.772  0.769  1.0
  F  F45  1  0.772  0.430  0.769  1.0
  F  F46  1  0.570  0.228  0.231  1.0
  F  F47  1  0.228  0.570  0.231  1.0
  F  F48  1  0.920  0.580  0.867  1.0
  F  F49  1  0.580  0.920  0.867  1.0
  F  F50  1  0.080  0.420  0.133  1.0
  F  F51  1  0.420  0.080  0.133  1.0
[/CIF]
.