The crystal structure described by ZnC(NCl)3CN3Cl is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two chlorguanidin molecules and one ZnC(NCl)3 cluster. In the ZnC(NCl)3 cluster, Zn(1) is bonded to two equivalent N(5), one Cl(1), and one Cl(3) atom to form distorted edge-sharing ZnN2Cl2 trigonal pyramids. C(2) is bonded in a trigonal planar geometry to one N(4), one N(5), and one N(6) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one C(2) atom. In the second N site, N(5) is bonded in a distorted trigonal planar geometry to two equivalent Zn(1) and one C(2) atom. In the third N site, N(6) is bonded in a bent 120 degrees geometry to one C(2) and one Cl(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one N(6) atom. is represented by the CIF file [CIF]
data_ZnC2(N3Cl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.561
_cell_length_b   7.456
_cell_length_c   11.991
_cell_angle_alpha   88.050
_cell_angle_beta   78.365
_cell_angle_gamma   88.324
_symmetry_Int_Tables_number   1
_cell_volume   661.517
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.959  0.557  0.881  1.0
  Zn  Zn1  1  0.041  0.443  0.119  1.0
  C  C2  1  0.654  0.281  0.602  1.0
  C  C3  1  0.346  0.719  0.398  1.0
  C  C4  1  0.787  0.216  0.997  1.0
  C  C5  1  0.213  0.784  0.003  1.0
  N  N6  1  0.815  0.242  0.539  1.0
  N  N7  1  0.185  0.758  0.461  1.0
  N  N8  1  0.598  0.464  0.625  1.0
  N  N9  1  0.402  0.536  0.375  1.0
  N  N10  1  0.531  0.160  0.648  1.0
  N  N11  1  0.469  0.840  0.352  1.0
  N  N12  1  0.729  0.188  0.900  1.0
  N  N13  1  0.271  0.812  0.100  1.0
  N  N14  1  0.884  0.354  0.007  1.0
  N  N15  1  0.116  0.646  0.993  1.0
  N  N16  1  0.735  0.081  0.084  1.0
  N  N17  1  0.265  0.919  0.916  1.0
  Cl  Cl18  1  0.737  0.753  0.890  1.0
  Cl  Cl19  1  0.263  0.247  0.110  1.0
  Cl  Cl20  1  0.750  0.618  0.569  1.0
  Cl  Cl21  1  0.250  0.382  0.431  1.0
  Cl  Cl22  1  0.104  0.391  0.745  1.0
  Cl  Cl23  1  0.896  0.609  0.255  1.0
  Cl  Cl24  1  0.202  0.901  0.794  1.0
  Cl  Cl25  1  0.798  0.099  0.206  1.0
[/CIF]
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The crystal structure described by ZnC(NCl)3CN3Cl is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two chlorguanidin molecules and one ZnC(NCl)3 cluster. In the ZnC(NCl)3 cluster, Zn(1) is bonded to two equivalent N(5), one Cl(1), and one Cl(3) atom to form distorted edge-sharing ZnN2Cl2 trigonal pyramids. C(2) is bonded in a trigonal planar geometry to one N(4), one N(5), and one N(6) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one C(2) atom. In the second N site, N(5) is bonded in a distorted trigonal planar geometry to two equivalent Zn(1) and one C(2) atom. In the third N site, N(6) is bonded in a bent 120 degrees geometry to one C(2) and one Cl(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one N(6) atom. is represented by the CIF file [CIF]
data_ZnC2(N3Cl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.561
_cell_length_b   7.456
_cell_length_c   11.991
_cell_angle_alpha   88.050
_cell_angle_beta   78.365
_cell_angle_gamma   88.324
_symmetry_Int_Tables_number   1
_cell_volume   661.517
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.959  0.557  0.881  1.0
  Zn  Zn1  1  0.041  0.443  0.119  1.0
  C  C2  1  0.654  0.281  0.602  1.0
  C  C3  1  0.346  0.719  0.398  1.0
  C  C4  1  0.787  0.216  0.997  1.0
  C  C5  1  0.213  0.784  0.003  1.0
  N  N6  1  0.815  0.242  0.539  1.0
  N  N7  1  0.185  0.758  0.461  1.0
  N  N8  1  0.598  0.464  0.625  1.0
  N  N9  1  0.402  0.536  0.375  1.0
  N  N10  1  0.531  0.160  0.648  1.0
  N  N11  1  0.469  0.840  0.352  1.0
  N  N12  1  0.729  0.188  0.900  1.0
  N  N13  1  0.271  0.812  0.100  1.0
  N  N14  1  0.884  0.354  0.007  1.0
  N  N15  1  0.116  0.646  0.993  1.0
  N  N16  1  0.735  0.081  0.084  1.0
  N  N17  1  0.265  0.919  0.916  1.0
  Cl  Cl18  1  0.737  0.753  0.890  1.0
  Cl  Cl19  1  0.263  0.247  0.110  1.0
  Cl  Cl20  1  0.750  0.618  0.569  1.0
  Cl  Cl21  1  0.250  0.382  0.431  1.0
  Cl  Cl22  1  0.104  0.391  0.745  1.0
  Cl  Cl23  1  0.896  0.609  0.255  1.0
  Cl  Cl24  1  0.202  0.901  0.794  1.0
  Cl  Cl25  1  0.798  0.099  0.206  1.0
[/CIF]
.