The structure described by KMnO2Cl3 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), two equivalent Cl(1), two equivalent Cl(2), and three equivalent Cl(3) atoms. Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one K(1) and one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one K(1) and one Mn(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to two equivalent K(1) and two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted see-saw-like geometry to three equivalent K(1) and one Mn(1) atom. is represented by the CIF file [CIF]
data_KMnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.476
_cell_length_b   6.772
_cell_length_c   8.996
_cell_angle_alpha   107.746
_cell_angle_beta   90.547
_cell_angle_gamma   112.197
_symmetry_Int_Tables_number   1
_cell_volume   344.396
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.935  0.635  0.789  1.0
  K  K1  1  0.065  0.365  0.211  1.0
  Mn  Mn2  1  0.623  0.969  0.683  1.0
  Mn  Mn3  1  0.377  0.031  0.317  1.0
  Cl  Cl4  1  0.738  0.189  0.481  1.0
  Cl  Cl5  1  0.262  0.811  0.519  1.0
  Cl  Cl6  1  0.486  0.745  0.832  1.0
  Cl  Cl7  1  0.514  0.255  0.168  1.0
  Cl  Cl8  1  0.988  0.165  0.818  1.0
  Cl  Cl9  1  0.012  0.835  0.182  1.0
  O  O10  1  0.288  0.228  0.437  1.0
  O  O11  1  0.712  0.772  0.563  1.0
  O  O12  1  0.567  0.192  0.797  1.0
  O  O13  1  0.433  0.808  0.203  1.0
[/CIF]
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The structure described by KMnO2Cl3 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), two equivalent Cl(1), two equivalent Cl(2), and three equivalent Cl(3) atoms. Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one K(1) and one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one K(1) and one Mn(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to two equivalent K(1) and two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted see-saw-like geometry to three equivalent K(1) and one Mn(1) atom. is represented by the CIF file [CIF]
data_KMnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.476
_cell_length_b   6.772
_cell_length_c   8.996
_cell_angle_alpha   107.746
_cell_angle_beta   90.547
_cell_angle_gamma   112.197
_symmetry_Int_Tables_number   1
_cell_volume   344.396
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.935  0.635  0.789  1.0
  K  K1  1  0.065  0.365  0.211  1.0
  Mn  Mn2  1  0.623  0.969  0.683  1.0
  Mn  Mn3  1  0.377  0.031  0.317  1.0
  Cl  Cl4  1  0.738  0.189  0.481  1.0
  Cl  Cl5  1  0.262  0.811  0.519  1.0
  Cl  Cl6  1  0.486  0.745  0.832  1.0
  Cl  Cl7  1  0.514  0.255  0.168  1.0
  Cl  Cl8  1  0.988  0.165  0.818  1.0
  Cl  Cl9  1  0.012  0.835  0.182  1.0
  O  O10  1  0.288  0.228  0.437  1.0
  O  O11  1  0.712  0.772  0.563  1.0
  O  O12  1  0.567  0.192  0.797  1.0
  O  O13  1  0.433  0.808  0.203  1.0
[/CIF]
.