The structure described by Re3S4O2F(O2)3 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, four trioxidane molecules, four water atoms, and two Re3S4O2F clusters. In each Re3S4O2F cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), two equivalent S(4), and one F(1) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one S(1), one S(2), two equivalent S(3), and one O(7) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(8) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the third S site, S(3) is bonded in a distorted T-shaped geometry to one Re(3) and two equivalent Re(2) atoms. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Re(3) and two equivalent Re(1) atoms. There are two inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Re(2) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Re(3) atom. F(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3S4O8F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.155
_cell_length_b   9.155
_cell_length_c   9.176
_cell_angle_alpha   75.821
_cell_angle_beta   75.821
_cell_angle_gamma   106.296
_symmetry_Int_Tables_number   1
_cell_volume   673.867
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.207  0.052  0.958  1.0
  Re  Re1  1  0.065  0.278  0.931  1.0
  Re  Re2  1  0.056  0.062  0.741  1.0
  Re  Re3  1  0.722  0.935  0.069  1.0
  Re  Re4  1  0.948  0.793  0.042  1.0
  Re  Re5  1  0.938  0.944  0.259  1.0
  S  S6  1  0.286  0.284  0.723  1.0
  S  S7  1  0.716  0.714  0.277  1.0
  S  S8  1  0.173  0.197  0.136  1.0
  S  S9  1  0.863  0.182  0.823  1.0
  S  S10  1  0.180  0.868  0.807  1.0
  S  S11  1  0.803  0.827  0.864  1.0
  S  S12  1  0.132  0.820  0.193  1.0
  S  S13  1  0.818  0.137  0.177  1.0
  O  O14  1  0.608  0.452  0.927  1.0
  O  O15  1  0.117  0.557  0.519  1.0
  O  O16  1  0.465  0.127  0.396  1.0
  O  O17  1  0.081  0.462  0.434  1.0
  O  O18  1  0.605  0.075  0.540  1.0
  O  O19  1  0.461  0.600  0.926  1.0
  O  O20  1  0.400  0.539  0.074  1.0
  O  O21  1  0.925  0.395  0.460  1.0
  O  O22  1  0.538  0.919  0.566  1.0
  O  O23  1  0.873  0.535  0.604  1.0
  O  O24  1  0.443  0.883  0.481  1.0
  O  O25  1  0.548  0.392  0.073  1.0
  O  O26  1  0.139  0.484  0.880  1.0
  O  O27  1  0.127  0.102  0.536  1.0
  O  O28  1  0.516  0.861  0.120  1.0
  O  O29  1  0.898  0.873  0.464  1.0
  F  F30  1  0.440  0.091  0.908  1.0
  F  F31  1  0.909  0.560  0.092  1.0
[/CIF]
.
The structure described by Re3S4O2F(O2)3 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, four trioxidane molecules, four water atoms, and two Re3S4O2F clusters. In each Re3S4O2F cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), two equivalent S(4), and one F(1) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one S(1), one S(2), two equivalent S(3), and one O(7) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(8) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the third S site, S(3) is bonded in a distorted T-shaped geometry to one Re(3) and two equivalent Re(2) atoms. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Re(3) and two equivalent Re(1) atoms. There are two inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Re(2) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Re(3) atom. F(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3S4O8F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.155
_cell_length_b   9.155
_cell_length_c   9.176
_cell_angle_alpha   75.821
_cell_angle_beta   75.821
_cell_angle_gamma   106.296
_symmetry_Int_Tables_number   1
_cell_volume   673.867
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.207  0.052  0.958  1.0
  Re  Re1  1  0.065  0.278  0.931  1.0
  Re  Re2  1  0.056  0.062  0.741  1.0
  Re  Re3  1  0.722  0.935  0.069  1.0
  Re  Re4  1  0.948  0.793  0.042  1.0
  Re  Re5  1  0.938  0.944  0.259  1.0
  S  S6  1  0.286  0.284  0.723  1.0
  S  S7  1  0.716  0.714  0.277  1.0
  S  S8  1  0.173  0.197  0.136  1.0
  S  S9  1  0.863  0.182  0.823  1.0
  S  S10  1  0.180  0.868  0.807  1.0
  S  S11  1  0.803  0.827  0.864  1.0
  S  S12  1  0.132  0.820  0.193  1.0
  S  S13  1  0.818  0.137  0.177  1.0
  O  O14  1  0.608  0.452  0.927  1.0
  O  O15  1  0.117  0.557  0.519  1.0
  O  O16  1  0.465  0.127  0.396  1.0
  O  O17  1  0.081  0.462  0.434  1.0
  O  O18  1  0.605  0.075  0.540  1.0
  O  O19  1  0.461  0.600  0.926  1.0
  O  O20  1  0.400  0.539  0.074  1.0
  O  O21  1  0.925  0.395  0.460  1.0
  O  O22  1  0.538  0.919  0.566  1.0
  O  O23  1  0.873  0.535  0.604  1.0
  O  O24  1  0.443  0.883  0.481  1.0
  O  O25  1  0.548  0.392  0.073  1.0
  O  O26  1  0.139  0.484  0.880  1.0
  O  O27  1  0.127  0.102  0.536  1.0
  O  O28  1  0.516  0.861  0.120  1.0
  O  O29  1  0.898  0.873  0.464  1.0
  F  F30  1  0.440  0.091  0.908  1.0
  F  F31  1  0.909  0.560  0.092  1.0
[/CIF]
.