The structure described by AsCl3 is Ammonia-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four arsenic trichloride molecules. As(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one As(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one As(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_AsCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.298
_cell_length_b   9.652
_cell_length_c   11.657
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   483.543
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.013  0.698  0.786  1.0
  As  As1  1  0.513  0.802  0.214  1.0
  As  As2  1  0.987  0.198  0.714  1.0
  As  As3  1  0.487  0.302  0.286  1.0
  Cl  Cl4  1  0.249  0.522  0.865  1.0
  Cl  Cl5  1  0.749  0.978  0.135  1.0
  Cl  Cl6  1  0.751  0.022  0.635  1.0
  Cl  Cl7  1  0.251  0.478  0.365  1.0
  Cl  Cl8  1  0.229  0.297  0.124  1.0
  Cl  Cl9  1  0.729  0.203  0.876  1.0
  Cl  Cl10  1  0.771  0.797  0.376  1.0
  Cl  Cl11  1  0.271  0.703  0.624  1.0
  Cl  Cl12  1  0.237  0.137  0.378  1.0
  Cl  Cl13  1  0.737  0.363  0.622  1.0
  Cl  Cl14  1  0.763  0.637  0.122  1.0
  Cl  Cl15  1  0.263  0.863  0.878  1.0
[/CIF]
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The structure described by AsCl3 is Ammonia-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four arsenic trichloride molecules. As(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one As(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one As(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_AsCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.298
_cell_length_b   9.652
_cell_length_c   11.657
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   483.543
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.013  0.698  0.786  1.0
  As  As1  1  0.513  0.802  0.214  1.0
  As  As2  1  0.987  0.198  0.714  1.0
  As  As3  1  0.487  0.302  0.286  1.0
  Cl  Cl4  1  0.249  0.522  0.865  1.0
  Cl  Cl5  1  0.749  0.978  0.135  1.0
  Cl  Cl6  1  0.751  0.022  0.635  1.0
  Cl  Cl7  1  0.251  0.478  0.365  1.0
  Cl  Cl8  1  0.229  0.297  0.124  1.0
  Cl  Cl9  1  0.729  0.203  0.876  1.0
  Cl  Cl10  1  0.771  0.797  0.376  1.0
  Cl  Cl11  1  0.271  0.703  0.624  1.0
  Cl  Cl12  1  0.237  0.137  0.378  1.0
  Cl  Cl13  1  0.737  0.363  0.622  1.0
  Cl  Cl14  1  0.763  0.637  0.122  1.0
  Cl  Cl15  1  0.263  0.863  0.878  1.0
[/CIF]
.