The crystal structure described by TlTeF5 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four TeF5 clusters. In each TeF5 cluster, Te(1) is bonded in a distorted square pyramidal geometry to one F(2), two equivalent F(1), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_TlTeF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.686
_cell_length_b   6.133
_cell_length_c   16.732
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   480.843
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.311  0.750  0.561  1.0
  Tl  Tl1  1  0.811  0.250  0.939  1.0
  Tl  Tl2  1  0.689  0.250  0.439  1.0
  Tl  Tl3  1  0.189  0.750  0.061  1.0
  Te  Te4  1  0.051  0.750  0.335  1.0
  Te  Te5  1  0.551  0.250  0.165  1.0
  Te  Te6  1  0.949  0.250  0.665  1.0
  Te  Te7  1  0.449  0.750  0.835  1.0
  F  F8  1  0.230  0.471  0.699  1.0
  F  F9  1  0.730  0.529  0.801  1.0
  F  F10  1  0.770  0.971  0.301  1.0
  F  F11  1  0.270  0.029  0.199  1.0
  F  F12  1  0.770  0.529  0.301  1.0
  F  F13  1  0.270  0.471  0.199  1.0
  F  F14  1  0.230  0.029  0.699  1.0
  F  F15  1  0.730  0.971  0.801  1.0
  F  F16  1  0.700  0.750  0.925  1.0
  F  F17  1  0.200  0.250  0.575  1.0
  F  F18  1  0.300  0.250  0.075  1.0
  F  F19  1  0.800  0.750  0.425  1.0
  F  F20  1  0.279  0.982  0.905  1.0
  F  F21  1  0.779  0.018  0.595  1.0
  F  F22  1  0.721  0.482  0.095  1.0
  F  F23  1  0.221  0.518  0.405  1.0
  F  F24  1  0.721  0.018  0.095  1.0
  F  F25  1  0.221  0.982  0.405  1.0
  F  F26  1  0.279  0.518  0.905  1.0
  F  F27  1  0.779  0.482  0.595  1.0
[/CIF]
.
The crystal structure described by TlTeF5 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four TeF5 clusters. In each TeF5 cluster, Te(1) is bonded in a distorted square pyramidal geometry to one F(2), two equivalent F(1), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_TlTeF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.686
_cell_length_b   6.133
_cell_length_c   16.732
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   480.843
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.311  0.750  0.561  1.0
  Tl  Tl1  1  0.811  0.250  0.939  1.0
  Tl  Tl2  1  0.689  0.250  0.439  1.0
  Tl  Tl3  1  0.189  0.750  0.061  1.0
  Te  Te4  1  0.051  0.750  0.335  1.0
  Te  Te5  1  0.551  0.250  0.165  1.0
  Te  Te6  1  0.949  0.250  0.665  1.0
  Te  Te7  1  0.449  0.750  0.835  1.0
  F  F8  1  0.230  0.471  0.699  1.0
  F  F9  1  0.730  0.529  0.801  1.0
  F  F10  1  0.770  0.971  0.301  1.0
  F  F11  1  0.270  0.029  0.199  1.0
  F  F12  1  0.770  0.529  0.301  1.0
  F  F13  1  0.270  0.471  0.199  1.0
  F  F14  1  0.230  0.029  0.699  1.0
  F  F15  1  0.730  0.971  0.801  1.0
  F  F16  1  0.700  0.750  0.925  1.0
  F  F17  1  0.200  0.250  0.575  1.0
  F  F18  1  0.300  0.250  0.075  1.0
  F  F19  1  0.800  0.750  0.425  1.0
  F  F20  1  0.279  0.982  0.905  1.0
  F  F21  1  0.779  0.018  0.595  1.0
  F  F22  1  0.721  0.482  0.095  1.0
  F  F23  1  0.221  0.518  0.405  1.0
  F  F24  1  0.721  0.018  0.095  1.0
  F  F25  1  0.221  0.982  0.405  1.0
  F  F26  1  0.279  0.518  0.905  1.0
  F  F27  1  0.779  0.482  0.595  1.0
[/CIF]
.