The crystal structure described by SO2F2 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of four sulfuryl fluoride molecules. S(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent F(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_S(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.117
_cell_length_b   5.117
_cell_length_c   11.304
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   295.991
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.920  0.920  0.500  1.0
  S  S1  1  0.580  0.420  0.750  1.0
  S  S2  1  0.420  0.580  0.250  1.0
  S  S3  1  0.080  0.080  0.000  1.0
  O  O4  1  0.990  0.670  0.461  1.0
  O  O5  1  0.010  0.330  0.961  1.0
  O  O6  1  0.670  0.990  0.539  1.0
  O  O7  1  0.170  0.510  0.211  1.0
  O  O8  1  0.490  0.830  0.289  1.0
  O  O9  1  0.330  0.010  0.039  1.0
  O  O10  1  0.830  0.490  0.711  1.0
  O  O11  1  0.510  0.170  0.789  1.0
  F  F12  1  0.618  0.493  0.155  1.0
  F  F13  1  0.118  0.007  0.595  1.0
  F  F14  1  0.993  0.882  0.905  1.0
  F  F15  1  0.007  0.118  0.405  1.0
  F  F16  1  0.507  0.382  0.345  1.0
  F  F17  1  0.882  0.993  0.095  1.0
  F  F18  1  0.382  0.507  0.655  1.0
  F  F19  1  0.493  0.618  0.845  1.0
[/CIF]
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The crystal structure described by SO2F2 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of four sulfuryl fluoride molecules. S(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent F(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_S(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.117
_cell_length_b   5.117
_cell_length_c   11.304
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   295.991
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.920  0.920  0.500  1.0
  S  S1  1  0.580  0.420  0.750  1.0
  S  S2  1  0.420  0.580  0.250  1.0
  S  S3  1  0.080  0.080  0.000  1.0
  O  O4  1  0.990  0.670  0.461  1.0
  O  O5  1  0.010  0.330  0.961  1.0
  O  O6  1  0.670  0.990  0.539  1.0
  O  O7  1  0.170  0.510  0.211  1.0
  O  O8  1  0.490  0.830  0.289  1.0
  O  O9  1  0.330  0.010  0.039  1.0
  O  O10  1  0.830  0.490  0.711  1.0
  O  O11  1  0.510  0.170  0.789  1.0
  F  F12  1  0.618  0.493  0.155  1.0
  F  F13  1  0.118  0.007  0.595  1.0
  F  F14  1  0.993  0.882  0.905  1.0
  F  F15  1  0.007  0.118  0.405  1.0
  F  F16  1  0.507  0.382  0.345  1.0
  F  F17  1  0.882  0.993  0.095  1.0
  F  F18  1  0.382  0.507  0.655  1.0
  F  F19  1  0.493  0.618  0.845  1.0
[/CIF]
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