The crystal structure described by WZnAsO5 crystallizes in the monoclinic P2_1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(2), one O(6), and one O(7) atom to form WO5 trigonal bipyramids that share  a cornercorner with one Zn(1)O5 trigonal bipyramid, corners with two equivalent W(2)O5 trigonal bipyramids, corners with two equivalent Zn(2)O5 trigonal bipyramids, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. In the second W site, W(2) is bonded to one O(1), one O(2), one O(5), one O(8), and one O(9) atom to form WO5 trigonal bipyramids that share  a cornercorner with one Zn(2)O5 trigonal bipyramid, corners with two equivalent W(1)O5 trigonal bipyramids, corners with two equivalent Zn(1)O5 trigonal bipyramids, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), one O(6), one O(7), and one O(9) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one W(1)O5 trigonal bipyramid, corners with two equivalent W(2)O5 trigonal bipyramids, and  an edgeedge with one W(1)O5 trigonal bipyramid. In the second Zn site, Zn(2) is bonded to one O(10), one O(2), one O(4), one O(5), and one O(8) atom to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one W(2)O5 trigonal bipyramid, corners with two equivalent W(1)O5 trigonal bipyramids, and  an edgeedge with one W(2)O5 trigonal bipyramid. There are two inequivalent As sites. In the first As site, As(1) is bonded in a distorted T-shaped geometry to one O(3), one O(5), and one O(7) atom. In the second As site, As(2) is bonded in a distorted T-shaped geometry to one O(4), one O(6), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one W(1), one W(2), and one Zn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Zn(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one As(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one As(2) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one W(2), one Zn(2), and one As(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one W(1), one Zn(1), and one As(2) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one W(1), one Zn(1), and one As(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one W(2), one Zn(2), and one As(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(2) and one Zn(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAsWO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.299
_cell_length_b   6.636
_cell_length_c   8.956
_cell_angle_alpha   89.431
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   493.139
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.084  0.631  0.574  1.0
  Zn  Zn1  1  0.584  0.369  0.426  1.0
  Zn  Zn2  1  0.918  0.879  0.080  1.0
  Zn  Zn3  1  0.418  0.121  0.920  1.0
  As  As4  1  0.932  0.210  0.390  1.0
  As  As5  1  0.432  0.790  0.610  1.0
  As  As6  1  0.069  0.295  0.888  1.0
  As  As7  1  0.569  0.705  0.112  1.0
  W  W8  1  0.722  0.436  0.765  1.0
  W  W9  1  0.222  0.564  0.235  1.0
  W  W10  1  0.278  0.064  0.264  1.0
  W  W11  1  0.778  0.936  0.736  1.0
  O  O12  1  0.712  0.195  0.629  1.0
  O  O13  1  0.212  0.805  0.371  1.0
  O  O14  1  0.288  0.310  0.130  1.0
  O  O15  1  0.788  0.690  0.870  1.0
  O  O16  1  0.774  0.332  0.303  1.0
  O  O17  1  0.274  0.668  0.697  1.0
  O  O18  1  0.226  0.173  0.801  1.0
  O  O19  1  0.726  0.827  0.199  1.0
  O  O20  1  0.037  0.093  0.226  1.0
  O  O21  1  0.537  0.907  0.774  1.0
  O  O22  1  0.963  0.411  0.723  1.0
  O  O23  1  0.463  0.589  0.277  1.0
  O  O24  1  0.090  0.440  0.394  1.0
  O  O25  1  0.590  0.560  0.606  1.0
  O  O26  1  0.908  0.062  0.894  1.0
  O  O27  1  0.408  0.938  0.106  1.0
  O  O28  1  0.908  0.833  0.593  1.0
  O  O29  1  0.408  0.167  0.407  1.0
  O  O30  1  0.093  0.676  0.093  1.0
  O  O31  1  0.593  0.324  0.907  1.0
[/CIF]
.
The crystal structure described by WZnAsO5 crystallizes in the monoclinic P2_1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(2), one O(6), and one O(7) atom to form WO5 trigonal bipyramids that share  a cornercorner with one Zn(1)O5 trigonal bipyramid, corners with two equivalent W(2)O5 trigonal bipyramids, corners with two equivalent Zn(2)O5 trigonal bipyramids, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. In the second W site, W(2) is bonded to one O(1), one O(2), one O(5), one O(8), and one O(9) atom to form WO5 trigonal bipyramids that share  a cornercorner with one Zn(2)O5 trigonal bipyramid, corners with two equivalent W(1)O5 trigonal bipyramids, corners with two equivalent Zn(1)O5 trigonal bipyramids, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), one O(6), one O(7), and one O(9) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one W(1)O5 trigonal bipyramid, corners with two equivalent W(2)O5 trigonal bipyramids, and  an edgeedge with one W(1)O5 trigonal bipyramid. In the second Zn site, Zn(2) is bonded to one O(10), one O(2), one O(4), one O(5), and one O(8) atom to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one W(2)O5 trigonal bipyramid, corners with two equivalent W(1)O5 trigonal bipyramids, and  an edgeedge with one W(2)O5 trigonal bipyramid. There are two inequivalent As sites. In the first As site, As(1) is bonded in a distorted T-shaped geometry to one O(3), one O(5), and one O(7) atom. In the second As site, As(2) is bonded in a distorted T-shaped geometry to one O(4), one O(6), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one W(1), one W(2), and one Zn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Zn(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one As(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one As(2) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one W(2), one Zn(2), and one As(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one W(1), one Zn(1), and one As(2) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one W(1), one Zn(1), and one As(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one W(2), one Zn(2), and one As(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(2) and one Zn(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAsWO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.299
_cell_length_b   6.636
_cell_length_c   8.956
_cell_angle_alpha   89.431
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   493.139
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.084  0.631  0.574  1.0
  Zn  Zn1  1  0.584  0.369  0.426  1.0
  Zn  Zn2  1  0.918  0.879  0.080  1.0
  Zn  Zn3  1  0.418  0.121  0.920  1.0
  As  As4  1  0.932  0.210  0.390  1.0
  As  As5  1  0.432  0.790  0.610  1.0
  As  As6  1  0.069  0.295  0.888  1.0
  As  As7  1  0.569  0.705  0.112  1.0
  W  W8  1  0.722  0.436  0.765  1.0
  W  W9  1  0.222  0.564  0.235  1.0
  W  W10  1  0.278  0.064  0.264  1.0
  W  W11  1  0.778  0.936  0.736  1.0
  O  O12  1  0.712  0.195  0.629  1.0
  O  O13  1  0.212  0.805  0.371  1.0
  O  O14  1  0.288  0.310  0.130  1.0
  O  O15  1  0.788  0.690  0.870  1.0
  O  O16  1  0.774  0.332  0.303  1.0
  O  O17  1  0.274  0.668  0.697  1.0
  O  O18  1  0.226  0.173  0.801  1.0
  O  O19  1  0.726  0.827  0.199  1.0
  O  O20  1  0.037  0.093  0.226  1.0
  O  O21  1  0.537  0.907  0.774  1.0
  O  O22  1  0.963  0.411  0.723  1.0
  O  O23  1  0.463  0.589  0.277  1.0
  O  O24  1  0.090  0.440  0.394  1.0
  O  O25  1  0.590  0.560  0.606  1.0
  O  O26  1  0.908  0.062  0.894  1.0
  O  O27  1  0.408  0.938  0.106  1.0
  O  O28  1  0.908  0.833  0.593  1.0
  O  O29  1  0.408  0.167  0.407  1.0
  O  O30  1  0.093  0.676  0.093  1.0
  O  O31  1  0.593  0.324  0.907  1.0
[/CIF]
.