The compound described by VOF2 crystallizes in the monoclinic C2/c space group. V(1) is bonded to two equivalent O(1) and four equivalent F(1) atoms to form corner-sharing VO2F4 octahedra. The corner-sharing octahedral tilt angles range from 17-27°. O(1) is bonded in a linear geometry to two equivalent V(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.200
_cell_length_b   5.328
_cell_length_c   5.201
_cell_angle_alpha   86.273
_cell_angle_beta   117.076
_cell_angle_gamma   62.178
_symmetry_Int_Tables_number   1
_cell_volume   106.190
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.500  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.049  0.250  0.799  1.0
  O  O3  1  0.951  0.750  0.201  1.0
  F  F4  1  0.501  0.226  0.667  1.0
  F  F5  1  0.893  0.274  0.227  1.0
  F  F6  1  0.107  0.726  0.773  1.0
  F  F7  1  0.499  0.774  0.333  1.0
[/CIF]
.
The compound described by VOF2 crystallizes in the monoclinic C2/c space group. V(1) is bonded to two equivalent O(1) and four equivalent F(1) atoms to form corner-sharing VO2F4 octahedra. The corner-sharing octahedral tilt angles range from 17-27°. O(1) is bonded in a linear geometry to two equivalent V(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.200
_cell_length_b   5.328
_cell_length_c   5.201
_cell_angle_alpha   86.273
_cell_angle_beta   117.076
_cell_angle_gamma   62.178
_symmetry_Int_Tables_number   1
_cell_volume   106.190
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.500  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.049  0.250  0.799  1.0
  O  O3  1  0.951  0.750  0.201  1.0
  F  F4  1  0.501  0.226  0.667  1.0
  F  F5  1  0.893  0.274  0.227  1.0
  F  F6  1  0.107  0.726  0.773  1.0
  F  F7  1  0.499  0.774  0.333  1.0
[/CIF]
.