The structure described by Li3B2SbO6 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(5), one O(6), and two equivalent O(3) atoms to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  a cornercorner with one Sb(1)O4 trigonal pyramid, and  an edgeedge with one Li(1)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with two equivalent Sb(1)O4 trigonal pyramids, and  an edgeedge with one Li(3)O4 tetrahedra. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra, corners with three equivalent Sb(1)O4 trigonal pyramids, and  an edgeedge with one Li(2)O4 tetrahedra. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(6) atom. Sb(1) is bonded to one O(1), one O(2), one O(4), and one O(6) atom to form distorted SbO4 trigonal pyramids that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, and corners with three equivalent Li(3)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), one B(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(3), one B(2), and one Sb(1) atom. In the third O site, O(3) is bonded to one Li(2), two equivalent Li(1), and one B(2) atom to form distorted OLi3B tetrahedra that share  a cornercorner with one O(4)Li2BSb tetrahedra, corners with three equivalent O(5)Li3B tetrahedra, and  an edgeedge with one O(3)Li3B tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one B(1), and one Sb(1) atom to form a mixture of distorted corner and edge-sharing OLi2BSb tetrahedra. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), and one B(1) atom to form OLi3B tetrahedra that share  a cornercorner with one O(4)Li2BSb tetrahedra, corners with three equivalent O(3)Li3B tetrahedra, and  an edgeedge with one O(4)Li2BSb tetrahedra. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Li(1), one B(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li3B2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.901
_cell_length_b   7.540
_cell_length_c   8.369
_cell_angle_alpha   64.925
_cell_angle_beta   85.739
_cell_angle_gamma   85.766
_symmetry_Int_Tables_number   1
_cell_volume   279.030
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.196  0.081  0.065  1.0
  Li  Li1  1  0.296  0.951  0.736  1.0
  Li  Li2  1  0.308  0.238  0.368  1.0
  Li  Li3  1  0.692  0.762  0.632  1.0
  Li  Li4  1  0.704  0.049  0.264  1.0
  Li  Li5  1  0.804  0.919  0.935  1.0
  B  B6  1  0.176  0.869  0.434  1.0
  B  B7  1  0.316  0.686  0.099  1.0
  B  B8  1  0.684  0.314  0.901  1.0
  B  B9  1  0.824  0.131  0.566  1.0
  Sb  Sb10  1  0.209  0.466  0.669  1.0
  Sb  Sb11  1  0.791  0.534  0.331  1.0
  O  O12  1  0.075  0.187  0.586  1.0
  O  O13  1  0.178  0.523  0.228  1.0
  O  O14  1  0.191  0.850  0.986  1.0
  O  O15  1  0.289  0.758  0.607  1.0
  O  O16  1  0.315  0.016  0.306  1.0
  O  O17  1  0.393  0.333  0.901  1.0
  O  O18  1  0.607  0.667  0.099  1.0
  O  O19  1  0.685  0.984  0.694  1.0
  O  O20  1  0.711  0.242  0.393  1.0
  O  O21  1  0.809  0.150  0.014  1.0
  O  O22  1  0.822  0.477  0.772  1.0
  O  O23  1  0.925  0.813  0.414  1.0
[/CIF]
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The structure described by Li3B2SbO6 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(5), one O(6), and two equivalent O(3) atoms to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  a cornercorner with one Sb(1)O4 trigonal pyramid, and  an edgeedge with one Li(1)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with two equivalent Sb(1)O4 trigonal pyramids, and  an edgeedge with one Li(3)O4 tetrahedra. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra, corners with three equivalent Sb(1)O4 trigonal pyramids, and  an edgeedge with one Li(2)O4 tetrahedra. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(6) atom. Sb(1) is bonded to one O(1), one O(2), one O(4), and one O(6) atom to form distorted SbO4 trigonal pyramids that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, and corners with three equivalent Li(3)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), one B(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(3), one B(2), and one Sb(1) atom. In the third O site, O(3) is bonded to one Li(2), two equivalent Li(1), and one B(2) atom to form distorted OLi3B tetrahedra that share  a cornercorner with one O(4)Li2BSb tetrahedra, corners with three equivalent O(5)Li3B tetrahedra, and  an edgeedge with one O(3)Li3B tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one B(1), and one Sb(1) atom to form a mixture of distorted corner and edge-sharing OLi2BSb tetrahedra. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), and one B(1) atom to form OLi3B tetrahedra that share  a cornercorner with one O(4)Li2BSb tetrahedra, corners with three equivalent O(3)Li3B tetrahedra, and  an edgeedge with one O(4)Li2BSb tetrahedra. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Li(1), one B(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li3B2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.901
_cell_length_b   7.540
_cell_length_c   8.369
_cell_angle_alpha   64.925
_cell_angle_beta   85.739
_cell_angle_gamma   85.766
_symmetry_Int_Tables_number   1
_cell_volume   279.030
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.196  0.081  0.065  1.0
  Li  Li1  1  0.296  0.951  0.736  1.0
  Li  Li2  1  0.308  0.238  0.368  1.0
  Li  Li3  1  0.692  0.762  0.632  1.0
  Li  Li4  1  0.704  0.049  0.264  1.0
  Li  Li5  1  0.804  0.919  0.935  1.0
  B  B6  1  0.176  0.869  0.434  1.0
  B  B7  1  0.316  0.686  0.099  1.0
  B  B8  1  0.684  0.314  0.901  1.0
  B  B9  1  0.824  0.131  0.566  1.0
  Sb  Sb10  1  0.209  0.466  0.669  1.0
  Sb  Sb11  1  0.791  0.534  0.331  1.0
  O  O12  1  0.075  0.187  0.586  1.0
  O  O13  1  0.178  0.523  0.228  1.0
  O  O14  1  0.191  0.850  0.986  1.0
  O  O15  1  0.289  0.758  0.607  1.0
  O  O16  1  0.315  0.016  0.306  1.0
  O  O17  1  0.393  0.333  0.901  1.0
  O  O18  1  0.607  0.667  0.099  1.0
  O  O19  1  0.685  0.984  0.694  1.0
  O  O20  1  0.711  0.242  0.393  1.0
  O  O21  1  0.809  0.150  0.014  1.0
  O  O22  1  0.822  0.477  0.772  1.0
  O  O23  1  0.925  0.813  0.414  1.0
[/CIF]
.