The structure described by Tb4RhInGe4 crystallizes in the monoclinic C2/m space group. There are four inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 6-coordinate geometry to two equivalent Rh(1), one Ge(4), two equivalent Ge(2), and three equivalent Ge(3) atoms. In the second Tb site, Tb(2) is bonded in a 11-coordinate geometry to three equivalent Rh(1), two equivalent In(2), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(4) atoms. In the third Tb site, Tb(3) is bonded in a 9-coordinate geometry to one Rh(1), two equivalent In(1), two equivalent Ge(1), two equivalent Ge(3), and two equivalent Ge(4) atoms. In the fourth Tb site, Tb(4) is bonded in a 10-coordinate geometry to two equivalent In(1), two equivalent In(2), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. Rh(1) is bonded in a 10-coordinate geometry to one Tb(3), two equivalent Tb(1), three equivalent Tb(2), one Ge(2), and three equivalent Ge(4) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded to four equivalent Tb(3), four equivalent Tb(4), two equivalent Ge(1), and two equivalent Ge(3) atoms to form a mixture of face and corner-sharing InTb8Ge4 cuboctahedra. In the second In site, In(2) is bonded to four equivalent Tb(2), four equivalent Tb(4), two equivalent Ge(1), and two equivalent Ge(2) atoms to form a mixture of face and corner-sharing InTb8Ge4 cuboctahedra. There are four inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Tb(2), two equivalent Tb(3), two equivalent Tb(4), one In(1), one In(2), and one Ge(4) atom. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Tb(1), two equivalent Tb(2), two equivalent Tb(4), one Rh(1), one In(2), and one Ge(3) atom. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Tb(3), two equivalent Tb(4), three equivalent Tb(1), one In(1), and one Ge(2) atom. In the fourth Ge site, Ge(4) is bonded in a 9-coordinate geometry to one Tb(1), two equivalent Tb(2), two equivalent Tb(3), three equivalent Rh(1), and one Ge(1) atom. is represented by the CIF file [CIF]
data_Tb4InGe4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.444
_cell_length_b   10.444
_cell_length_c   10.374
_cell_angle_alpha   75.300
_cell_angle_beta   75.300
_cell_angle_gamma   23.634
_symmetry_Int_Tables_number   1
_cell_volume   438.110
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.278  0.278  0.345  1.0
  Tb  Tb1  1  0.722  0.722  0.655  1.0
  Tb  Tb2  1  0.371  0.371  0.993  1.0
  Tb  Tb3  1  0.629  0.629  0.007  1.0
  Tb  Tb4  1  0.373  0.373  0.639  1.0
  Tb  Tb5  1  0.627  0.627  0.361  1.0
  Tb  Tb6  1  0.541  0.541  0.727  1.0
  Tb  Tb7  1  0.459  0.459  0.273  1.0
  In  In8  1  0.000  0.000  0.500  1.0
  In  In9  1  0.000  0.000  0.000  1.0
  Ge  Ge10  1  0.063  0.063  0.217  1.0
  Ge  Ge11  1  0.937  0.937  0.783  1.0
  Ge  Ge12  1  0.133  0.133  0.809  1.0
  Ge  Ge13  1  0.867  0.867  0.191  1.0
  Ge  Ge14  1  0.145  0.145  0.548  1.0
  Ge  Ge15  1  0.855  0.855  0.452  1.0
  Ge  Ge16  1  0.805  0.805  0.849  1.0
  Ge  Ge17  1  0.195  0.195  0.151  1.0
  Rh  Rh18  1  0.241  0.241  0.894  1.0
  Rh  Rh19  1  0.759  0.759  0.106  1.0
[/CIF]
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The structure described by Tb4RhInGe4 crystallizes in the monoclinic C2/m space group. There are four inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 6-coordinate geometry to two equivalent Rh(1), one Ge(4), two equivalent Ge(2), and three equivalent Ge(3) atoms. In the second Tb site, Tb(2) is bonded in a 11-coordinate geometry to three equivalent Rh(1), two equivalent In(2), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(4) atoms. In the third Tb site, Tb(3) is bonded in a 9-coordinate geometry to one Rh(1), two equivalent In(1), two equivalent Ge(1), two equivalent Ge(3), and two equivalent Ge(4) atoms. In the fourth Tb site, Tb(4) is bonded in a 10-coordinate geometry to two equivalent In(1), two equivalent In(2), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. Rh(1) is bonded in a 10-coordinate geometry to one Tb(3), two equivalent Tb(1), three equivalent Tb(2), one Ge(2), and three equivalent Ge(4) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded to four equivalent Tb(3), four equivalent Tb(4), two equivalent Ge(1), and two equivalent Ge(3) atoms to form a mixture of face and corner-sharing InTb8Ge4 cuboctahedra. In the second In site, In(2) is bonded to four equivalent Tb(2), four equivalent Tb(4), two equivalent Ge(1), and two equivalent Ge(2) atoms to form a mixture of face and corner-sharing InTb8Ge4 cuboctahedra. There are four inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Tb(2), two equivalent Tb(3), two equivalent Tb(4), one In(1), one In(2), and one Ge(4) atom. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Tb(1), two equivalent Tb(2), two equivalent Tb(4), one Rh(1), one In(2), and one Ge(3) atom. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Tb(3), two equivalent Tb(4), three equivalent Tb(1), one In(1), and one Ge(2) atom. In the fourth Ge site, Ge(4) is bonded in a 9-coordinate geometry to one Tb(1), two equivalent Tb(2), two equivalent Tb(3), three equivalent Rh(1), and one Ge(1) atom. is represented by the CIF file [CIF]
data_Tb4InGe4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.444
_cell_length_b   10.444
_cell_length_c   10.374
_cell_angle_alpha   75.300
_cell_angle_beta   75.300
_cell_angle_gamma   23.634
_symmetry_Int_Tables_number   1
_cell_volume   438.110
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.278  0.278  0.345  1.0
  Tb  Tb1  1  0.722  0.722  0.655  1.0
  Tb  Tb2  1  0.371  0.371  0.993  1.0
  Tb  Tb3  1  0.629  0.629  0.007  1.0
  Tb  Tb4  1  0.373  0.373  0.639  1.0
  Tb  Tb5  1  0.627  0.627  0.361  1.0
  Tb  Tb6  1  0.541  0.541  0.727  1.0
  Tb  Tb7  1  0.459  0.459  0.273  1.0
  In  In8  1  0.000  0.000  0.500  1.0
  In  In9  1  0.000  0.000  0.000  1.0
  Ge  Ge10  1  0.063  0.063  0.217  1.0
  Ge  Ge11  1  0.937  0.937  0.783  1.0
  Ge  Ge12  1  0.133  0.133  0.809  1.0
  Ge  Ge13  1  0.867  0.867  0.191  1.0
  Ge  Ge14  1  0.145  0.145  0.548  1.0
  Ge  Ge15  1  0.855  0.855  0.452  1.0
  Ge  Ge16  1  0.805  0.805  0.849  1.0
  Ge  Ge17  1  0.195  0.195  0.151  1.0
  Rh  Rh18  1  0.241  0.241  0.894  1.0
  Rh  Rh19  1  0.759  0.759  0.106  1.0
[/CIF]
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