The compound described by Cs2TaAgS4 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Ta(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Ta(1), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Cs2TaAgS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.568
_cell_length_b   12.975
_cell_length_c   7.879
_cell_angle_alpha   84.894
_cell_angle_beta   62.512
_cell_angle_gamma   32.594
_symmetry_Int_Tables_number   1
_cell_volume   554.107
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.678  0.678  0.322  1.0
  Cs  Cs1  1  0.322  0.322  0.678  1.0
  Cs  Cs2  1  0.572  0.572  0.928  1.0
  Cs  Cs3  1  0.928  0.928  0.572  1.0
  Ta  Ta4  1  0.500  0.500  0.500  1.0
  Ta  Ta5  1  0.750  0.750  0.750  1.0
  Ag  Ag6  1  0.000  0.000  0.000  1.0
  Ag  Ag7  1  0.250  0.250  0.250  1.0
  S  S8  1  0.246  0.860  0.567  1.0
  S  S9  1  0.327  0.567  0.860  1.0
  S  S10  1  0.567  0.327  0.246  1.0
  S  S11  1  0.860  0.246  0.327  1.0
  S  S12  1  0.390  0.004  0.923  1.0
  S  S13  1  0.923  0.683  0.390  1.0
  S  S14  1  0.683  0.923  0.004  1.0
  S  S15  1  0.004  0.390  0.683  1.0
[/CIF]
.
The compound described by Cs2TaAgS4 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Ta(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Ta(1), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Cs2TaAgS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.568
_cell_length_b   12.975
_cell_length_c   7.879
_cell_angle_alpha   84.894
_cell_angle_beta   62.512
_cell_angle_gamma   32.594
_symmetry_Int_Tables_number   1
_cell_volume   554.107
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.678  0.678  0.322  1.0
  Cs  Cs1  1  0.322  0.322  0.678  1.0
  Cs  Cs2  1  0.572  0.572  0.928  1.0
  Cs  Cs3  1  0.928  0.928  0.572  1.0
  Ta  Ta4  1  0.500  0.500  0.500  1.0
  Ta  Ta5  1  0.750  0.750  0.750  1.0
  Ag  Ag6  1  0.000  0.000  0.000  1.0
  Ag  Ag7  1  0.250  0.250  0.250  1.0
  S  S8  1  0.246  0.860  0.567  1.0
  S  S9  1  0.327  0.567  0.860  1.0
  S  S10  1  0.567  0.327  0.246  1.0
  S  S11  1  0.860  0.246  0.327  1.0
  S  S12  1  0.390  0.004  0.923  1.0
  S  S13  1  0.923  0.683  0.390  1.0
  S  S14  1  0.683  0.923  0.004  1.0
  S  S15  1  0.004  0.390  0.683  1.0
[/CIF]
.