The compound described by NbVO4 crystallizes in the monoclinic C2/c space group. Nb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. V(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Nb(1) and two equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing ONb2V2 trigonal pyramids. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Nb(1) and one V(1) atom. is represented by the CIF file [CIF]
data_NbVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.160
_cell_length_b   6.160
_cell_length_c   4.959
_cell_angle_alpha   68.924
_cell_angle_beta   68.924
_cell_angle_gamma   114.810
_symmetry_Int_Tables_number   1
_cell_volume   127.169
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.132  0.868  0.250  1.0
  Nb  Nb1  1  0.868  0.132  0.750  1.0
  V  V2  1  0.594  0.406  0.250  1.0
  V  V3  1  0.406  0.594  0.750  1.0
  O  O4  1  0.269  0.200  0.762  1.0
  O  O5  1  0.200  0.269  0.262  1.0
  O  O6  1  0.479  0.898  0.836  1.0
  O  O7  1  0.898  0.479  0.336  1.0
  O  O8  1  0.102  0.521  0.664  1.0
  O  O9  1  0.521  0.102  0.164  1.0
  O  O10  1  0.800  0.731  0.738  1.0
  O  O11  1  0.731  0.800  0.238  1.0
[/CIF]
.
The compound described by NbVO4 crystallizes in the monoclinic C2/c space group. Nb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. V(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Nb(1) and two equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing ONb2V2 trigonal pyramids. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Nb(1) and one V(1) atom. is represented by the CIF file [CIF]
data_NbVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.160
_cell_length_b   6.160
_cell_length_c   4.959
_cell_angle_alpha   68.924
_cell_angle_beta   68.924
_cell_angle_gamma   114.810
_symmetry_Int_Tables_number   1
_cell_volume   127.169
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.132  0.868  0.250  1.0
  Nb  Nb1  1  0.868  0.132  0.750  1.0
  V  V2  1  0.594  0.406  0.250  1.0
  V  V3  1  0.406  0.594  0.750  1.0
  O  O4  1  0.269  0.200  0.762  1.0
  O  O5  1  0.200  0.269  0.262  1.0
  O  O6  1  0.479  0.898  0.836  1.0
  O  O7  1  0.898  0.479  0.336  1.0
  O  O8  1  0.102  0.521  0.664  1.0
  O  O9  1  0.521  0.102  0.164  1.0
  O  O10  1  0.800  0.731  0.738  1.0
  O  O11  1  0.731  0.800  0.238  1.0
[/CIF]
.