The material structure described by N2GeF5 crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of four ammonia atoms and two GeF5 clusters. In each GeF5 cluster, Ge(1) is bonded in a distorted square pyramidal geometry to one F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF file [CIF]
data_GeN2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.071
_cell_length_b   6.071
_cell_length_c   7.698
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   283.719
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.500  0.000  0.232  1.0
  Ge  Ge1  1  0.000  0.500  0.768  1.0
  N  N2  1  0.500  0.000  0.580  1.0
  N  N3  1  0.000  0.500  0.420  1.0
  N  N4  1  0.500  0.500  0.000  1.0
  N  N5  1  0.000  0.000  0.000  1.0
  F  F6  1  0.500  0.000  0.004  1.0
  F  F7  1  0.000  0.500  0.996  1.0
  F  F8  1  0.697  0.211  0.281  1.0
  F  F9  1  0.303  0.789  0.281  1.0
  F  F10  1  0.711  0.803  0.281  1.0
  F  F11  1  0.289  0.197  0.281  1.0
  F  F12  1  0.803  0.289  0.719  1.0
  F  F13  1  0.197  0.711  0.719  1.0
  F  F14  1  0.789  0.697  0.719  1.0
  F  F15  1  0.211  0.303  0.719  1.0
[/CIF]
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The material structure described by N2GeF5 crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of four ammonia atoms and two GeF5 clusters. In each GeF5 cluster, Ge(1) is bonded in a distorted square pyramidal geometry to one F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF file [CIF]
data_GeN2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.071
_cell_length_b   6.071
_cell_length_c   7.698
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   283.719
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.500  0.000  0.232  1.0
  Ge  Ge1  1  0.000  0.500  0.768  1.0
  N  N2  1  0.500  0.000  0.580  1.0
  N  N3  1  0.000  0.500  0.420  1.0
  N  N4  1  0.500  0.500  0.000  1.0
  N  N5  1  0.000  0.000  0.000  1.0
  F  F6  1  0.500  0.000  0.004  1.0
  F  F7  1  0.000  0.500  0.996  1.0
  F  F8  1  0.697  0.211  0.281  1.0
  F  F9  1  0.303  0.789  0.281  1.0
  F  F10  1  0.711  0.803  0.281  1.0
  F  F11  1  0.289  0.197  0.281  1.0
  F  F12  1  0.803  0.289  0.719  1.0
  F  F13  1  0.197  0.711  0.719  1.0
  F  F14  1  0.789  0.697  0.719  1.0
  F  F15  1  0.211  0.303  0.719  1.0
[/CIF]
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