The crystal structure described by Gd2(MoO4)3 crystallizes in the monoclinic C2/c space group. Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(5), one O(6), two equivalent O(2), and two equivalent O(4) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(6), and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(2) atom. In the second O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Gd(1) and two equivalent Mo(2) atoms. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one Mo(2) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the sixth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one Mo(2) atom. is represented by the CIF card [CIF]
data_Gd2(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.942
_cell_length_b   6.942
_cell_length_c   11.603
_cell_angle_alpha   79.526
_cell_angle_beta   79.526
_cell_angle_gamma   112.739
_symmetry_Int_Tables_number   1
_cell_volume   487.138
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.197  0.452  0.092  1.0
  Gd  Gd1  1  0.548  0.803  0.408  1.0
  Gd  Gd2  1  0.803  0.548  0.908  1.0
  Gd  Gd3  1  0.452  0.197  0.592  1.0
  Mo  Mo4  1  0.622  0.378  0.250  1.0
  Mo  Mo5  1  0.378  0.622  0.750  1.0
  Mo  Mo6  1  0.020  0.301  0.442  1.0
  Mo  Mo7  1  0.699  0.980  0.058  1.0
  Mo  Mo8  1  0.980  0.699  0.558  1.0
  Mo  Mo9  1  0.301  0.020  0.942  1.0
  O  O10  1  0.512  0.091  0.281  1.0
  O  O11  1  0.909  0.488  0.219  1.0
  O  O12  1  0.488  0.909  0.719  1.0
  O  O13  1  0.091  0.512  0.781  1.0
  O  O14  1  0.553  0.469  0.111  1.0
  O  O15  1  0.531  0.447  0.389  1.0
  O  O16  1  0.447  0.531  0.889  1.0
  O  O17  1  0.469  0.553  0.611  1.0
  O  O18  1  0.147  0.278  0.299  1.0
  O  O19  1  0.722  0.853  0.201  1.0
  O  O20  1  0.853  0.722  0.701  1.0
  O  O21  1  0.278  0.147  0.799  1.0
  O  O22  1  0.725  0.133  0.459  1.0
  O  O23  1  0.867  0.275  0.041  1.0
  O  O24  1  0.275  0.867  0.541  1.0
  O  O25  1  0.133  0.725  0.959  1.0
  O  O26  1  0.400  0.827  0.086  1.0
  O  O27  1  0.173  0.600  0.414  1.0
  O  O28  1  0.600  0.173  0.914  1.0
  O  O29  1  0.827  0.400  0.586  1.0
  O  O30  1  0.885  0.821  0.448  1.0
  O  O31  1  0.179  0.115  0.052  1.0
  O  O32  1  0.115  0.179  0.552  1.0
  O  O33  1  0.821  0.885  0.948  1.0
[/CIF]
.
The crystal structure described by Gd2(MoO4)3 crystallizes in the monoclinic C2/c space group. Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(5), one O(6), two equivalent O(2), and two equivalent O(4) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(6), and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(2) atom. In the second O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Gd(1) and two equivalent Mo(2) atoms. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one Mo(2) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the sixth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one Mo(2) atom. is represented by the CIF card [CIF]
data_Gd2(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.942
_cell_length_b   6.942
_cell_length_c   11.603
_cell_angle_alpha   79.526
_cell_angle_beta   79.526
_cell_angle_gamma   112.739
_symmetry_Int_Tables_number   1
_cell_volume   487.138
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.197  0.452  0.092  1.0
  Gd  Gd1  1  0.548  0.803  0.408  1.0
  Gd  Gd2  1  0.803  0.548  0.908  1.0
  Gd  Gd3  1  0.452  0.197  0.592  1.0
  Mo  Mo4  1  0.622  0.378  0.250  1.0
  Mo  Mo5  1  0.378  0.622  0.750  1.0
  Mo  Mo6  1  0.020  0.301  0.442  1.0
  Mo  Mo7  1  0.699  0.980  0.058  1.0
  Mo  Mo8  1  0.980  0.699  0.558  1.0
  Mo  Mo9  1  0.301  0.020  0.942  1.0
  O  O10  1  0.512  0.091  0.281  1.0
  O  O11  1  0.909  0.488  0.219  1.0
  O  O12  1  0.488  0.909  0.719  1.0
  O  O13  1  0.091  0.512  0.781  1.0
  O  O14  1  0.553  0.469  0.111  1.0
  O  O15  1  0.531  0.447  0.389  1.0
  O  O16  1  0.447  0.531  0.889  1.0
  O  O17  1  0.469  0.553  0.611  1.0
  O  O18  1  0.147  0.278  0.299  1.0
  O  O19  1  0.722  0.853  0.201  1.0
  O  O20  1  0.853  0.722  0.701  1.0
  O  O21  1  0.278  0.147  0.799  1.0
  O  O22  1  0.725  0.133  0.459  1.0
  O  O23  1  0.867  0.275  0.041  1.0
  O  O24  1  0.275  0.867  0.541  1.0
  O  O25  1  0.133  0.725  0.959  1.0
  O  O26  1  0.400  0.827  0.086  1.0
  O  O27  1  0.173  0.600  0.414  1.0
  O  O28  1  0.600  0.173  0.914  1.0
  O  O29  1  0.827  0.400  0.586  1.0
  O  O30  1  0.885  0.821  0.448  1.0
  O  O31  1  0.179  0.115  0.052  1.0
  O  O32  1  0.115  0.179  0.552  1.0
  O  O33  1  0.821  0.885  0.948  1.0
[/CIF]
.