The compound described by NiCl6 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and two NiCl4 clusters. In each NiCl4 cluster, Ni(1) is bonded in a square co-planar geometry to four equivalent Cl(2) atoms. Cl(2) is bonded in a single-bond geometry to one Ni(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.201
_cell_length_b   8.201
_cell_length_c   45.248
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   104.213
_symmetry_Int_Tables_number   1
_cell_volume   2949.916
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  Cl  Cl1  1  0.000  0.000  0.250  1.0
  Cl  Cl2  1  0.000  0.000  0.750  1.0
  Cl  Cl3  1  0.264  0.031  0.000  1.0
  Cl  Cl4  1  0.736  0.969  0.000  1.0
  Cl  Cl5  1  0.031  0.264  0.000  1.0
  Cl  Cl6  1  0.969  0.736  0.000  1.0
[/CIF]
.
The compound described by NiCl6 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and two NiCl4 clusters. In each NiCl4 cluster, Ni(1) is bonded in a square co-planar geometry to four equivalent Cl(2) atoms. Cl(2) is bonded in a single-bond geometry to one Ni(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.201
_cell_length_b   8.201
_cell_length_c   45.248
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   104.213
_symmetry_Int_Tables_number   1
_cell_volume   2949.916
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  Cl  Cl1  1  0.000  0.000  0.250  1.0
  Cl  Cl2  1  0.000  0.000  0.750  1.0
  Cl  Cl3  1  0.264  0.031  0.000  1.0
  Cl  Cl4  1  0.736  0.969  0.000  1.0
  Cl  Cl5  1  0.031  0.264  0.000  1.0
  Cl  Cl6  1  0.969  0.736  0.000  1.0
[/CIF]
.