The material described by CeVO4 crystallizes in the monoclinic P2_1/c space group. Ce(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and three equivalent O(2) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ce(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ce(1) and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Ce(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Ce(1) and one V(1) atom. is represented by the CIF card [CIF]
data_CeVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.257
_cell_length_b   6.733
_cell_length_c   8.348
_cell_angle_alpha   54.962
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   333.965
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.347  0.814  0.783  1.0
  Ce  Ce1  1  0.153  0.814  0.283  1.0
  Ce  Ce2  1  0.653  0.186  0.217  1.0
  Ce  Ce3  1  0.847  0.186  0.717  1.0
  V  V4  1  0.337  0.310  0.801  1.0
  V  V5  1  0.163  0.310  0.301  1.0
  V  V6  1  0.663  0.690  0.199  1.0
  V  V7  1  0.837  0.690  0.699  1.0
  O  O8  1  0.508  0.171  0.746  1.0
  O  O9  1  0.992  0.171  0.246  1.0
  O  O10  1  0.492  0.829  0.254  1.0
  O  O11  1  0.008  0.829  0.754  1.0
  O  O12  1  0.154  0.104  0.889  1.0
  O  O13  1  0.346  0.104  0.389  1.0
  O  O14  1  0.846  0.896  0.111  1.0
  O  O15  1  0.654  0.896  0.611  1.0
  O  O16  1  0.396  0.347  0.984  1.0
  O  O17  1  0.104  0.347  0.484  1.0
  O  O18  1  0.604  0.653  0.016  1.0
  O  O19  1  0.896  0.653  0.516  1.0
  O  O20  1  0.280  0.612  0.618  1.0
  O  O21  1  0.220  0.612  0.118  1.0
  O  O22  1  0.720  0.388  0.382  1.0
  O  O23  1  0.780  0.388  0.882  1.0
[/CIF]
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The material described by CeVO4 crystallizes in the monoclinic P2_1/c space group. Ce(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and three equivalent O(2) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ce(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ce(1) and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Ce(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Ce(1) and one V(1) atom. is represented by the CIF card [CIF]
data_CeVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.257
_cell_length_b   6.733
_cell_length_c   8.348
_cell_angle_alpha   54.962
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   333.965
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.347  0.814  0.783  1.0
  Ce  Ce1  1  0.153  0.814  0.283  1.0
  Ce  Ce2  1  0.653  0.186  0.217  1.0
  Ce  Ce3  1  0.847  0.186  0.717  1.0
  V  V4  1  0.337  0.310  0.801  1.0
  V  V5  1  0.163  0.310  0.301  1.0
  V  V6  1  0.663  0.690  0.199  1.0
  V  V7  1  0.837  0.690  0.699  1.0
  O  O8  1  0.508  0.171  0.746  1.0
  O  O9  1  0.992  0.171  0.246  1.0
  O  O10  1  0.492  0.829  0.254  1.0
  O  O11  1  0.008  0.829  0.754  1.0
  O  O12  1  0.154  0.104  0.889  1.0
  O  O13  1  0.346  0.104  0.389  1.0
  O  O14  1  0.846  0.896  0.111  1.0
  O  O15  1  0.654  0.896  0.611  1.0
  O  O16  1  0.396  0.347  0.984  1.0
  O  O17  1  0.104  0.347  0.484  1.0
  O  O18  1  0.604  0.653  0.016  1.0
  O  O19  1  0.896  0.653  0.516  1.0
  O  O20  1  0.280  0.612  0.618  1.0
  O  O21  1  0.220  0.612  0.118  1.0
  O  O22  1  0.720  0.388  0.382  1.0
  O  O23  1  0.780  0.388  0.882  1.0
[/CIF]
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