The material structure described by Mg14VZn crystallizes in the orthorhombic Amm2 space group. There are nine inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2); two equivalent Mg(6); four Mg(4,4); and four Mg(5,5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent V(1)Mg10Zn2 cuboctahedra; corners with six equivalent Mg(1)Mg12 cuboctahedra; corners with eight equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with eight Mg(5,5)Mg10VZn cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Zn(1)Mg10V2 cuboctahedra; faces with four Mg(5,5)Mg10VZn cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with six equivalent Mg(7)Mg11V cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1); two equivalent Mg(7); four Mg(4,4); and four Mg(5,5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Zn(1)Mg10V2 cuboctahedra; corners with six equivalent Mg(2)Mg12 cuboctahedra; corners with eight equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with eight Mg(5,5)Mg10VZn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent V(1)Mg10Zn2 cuboctahedra; faces with four Mg(5,5)Mg10VZn cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with six equivalent Mg(6)Mg11Zn cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), two equivalent V(1), and two equivalent Zn(1) atoms to form distorted MgMg8V2Zn2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; faces with two equivalent V(1)Mg10Zn2 cuboctahedra; faces with two equivalent Zn(1)Mg10V2 cuboctahedra; and faces with eight Mg(5,5)Mg10VZn cuboctahedra. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; corners with four equivalent V(1)Mg10Zn2 cuboctahedra; corners with four equivalent Zn(1)Mg10V2 cuboctahedra; corners with six Mg(4,4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; and faces with eight Mg(5,5)Mg10VZn cuboctahedra. In the fifth Mg site, Mg(5) is bonded to one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), one V(1), and one Zn(1) atom to form distorted MgMg10VZn cuboctahedra that share corners with four equivalent Mg(7)Mg11V cuboctahedra; corners with four equivalent Mg(6)Mg11Zn cuboctahedra; corners with ten Mg(5,5)Mg10VZn cuboctahedra; edges with two equivalent Mg(5)Mg10VZn cuboctahedra; edges with two equivalent Mg(7)Mg11V cuboctahedra; edges with two equivalent Mg(6)Mg11Zn cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Mg10Zn2 cuboctahedra;  a faceface with one Zn(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with four equivalent Mg(5)Mg10VZn cuboctahedra; faces with four equivalent Mg(4)Mg12 cuboctahedra; and faces with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra. In the sixth Mg site, Mg(5) is bonded to one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), one V(1), and one Zn(1) atom to form distorted MgMg10VZn cuboctahedra that share corners with four equivalent Mg(7)Mg11V cuboctahedra; corners with four equivalent Mg(6)Mg11Zn cuboctahedra; corners with ten Mg(5,5)Mg10VZn cuboctahedra; edges with two equivalent Mg(5)Mg10VZn cuboctahedra; edges with two equivalent Mg(7)Mg11V cuboctahedra; edges with two equivalent Mg(6)Mg11Zn cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Mg10Zn2 cuboctahedra;  a faceface with one Zn(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with four equivalent Mg(5)Mg10VZn cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra. In the seventh Mg site, Mg(6) is bonded to one Mg(1), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(7), four equivalent Mg(5), and one Zn(1) atom to form distorted MgMg11Zn cuboctahedra that share corners with four equivalent Mg(7)Mg11V cuboctahedra; corners with six equivalent Mg(6)Mg11Zn cuboctahedra; corners with eight Mg(5,5)Mg10VZn cuboctahedra; edges with two equivalent Mg(7)Mg11V cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Zn(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; faces with three equivalent Mg(2)Mg12 cuboctahedra; faces with three equivalent V(1)Mg10Zn2 cuboctahedra; and faces with four equivalent Mg(5)Mg10VZn cuboctahedra. In the eighth Mg site, Mg(7) is bonded to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), four equivalent Mg(5), and one V(1) atom to form distorted MgMg11V cuboctahedra that share corners with four equivalent Mg(6)Mg11Zn cuboctahedra; corners with six equivalent Mg(7)Mg11V cuboctahedra; corners with eight Mg(5,5)Mg10VZn cuboctahedra; edges with two equivalent Mg(6)Mg11Zn cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Mg10Zn2 cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; faces with three equivalent Mg(1)Mg12 cuboctahedra; faces with three equivalent Zn(1)Mg10V2 cuboctahedra; and faces with four equivalent Mg(5)Mg10VZn cuboctahedra. In the ninth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; corners with four equivalent V(1)Mg10Zn2 cuboctahedra; corners with four equivalent Zn(1)Mg10V2 cuboctahedra; corners with six Mg(4,4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; and faces with eight Mg(5,5)Mg10VZn cuboctahedra. V(1) is bonded to two equivalent Mg(7); four equivalent Mg(3); four Mg(5,5); and two equivalent Zn(1) atoms to form VMg10Zn2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with six equivalent V(1)Mg10Zn2 cuboctahedra; corners with eight Mg(4,4)Mg12 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with eight Mg(5,5)Mg10VZn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Zn(1)Mg10V2 cuboctahedra; faces with four Mg(5,5)Mg10VZn cuboctahedra; faces with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; and faces with six equivalent Mg(6)Mg11Zn cuboctahedra. Zn(1) is bonded to two equivalent Mg(6); four equivalent Mg(3); four Mg(5,5); and two equivalent V(1) atoms to form ZnMg10V2 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with six equivalent Zn(1)Mg10V2 cuboctahedra; corners with eight Mg(4,4)Mg12 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; edges with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with eight Mg(5,5)Mg10VZn cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent V(1)Mg10Zn2 cuboctahedra; faces with four Mg(5,5)Mg10VZn cuboctahedra; faces with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; and faces with six equivalent Mg(7)Mg11V cuboctahedra. is represented by the CIF card [CIF]
data_Mg14VZn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.274
_cell_length_b   6.271
_cell_length_c   10.171
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.985
_symmetry_Int_Tables_number   1
_cell_volume   346.563
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.168  0.334  0.625  1.0
  Mg  Mg1  1  0.168  0.834  0.625  1.0
  Mg  Mg2  1  0.668  0.337  0.125  1.0
  Mg  Mg3  1  0.666  0.333  0.625  1.0
  Mg  Mg4  1  0.668  0.831  0.125  1.0
  Mg  Mg5  1  0.666  0.833  0.625  1.0
  Mg  Mg6  1  0.328  0.163  0.365  1.0
  Mg  Mg7  1  0.328  0.163  0.885  1.0
  Mg  Mg8  1  0.328  0.665  0.365  1.0
  Mg  Mg9  1  0.328  0.665  0.885  1.0
  Mg  Mg10  1  0.836  0.168  0.372  1.0
  Mg  Mg11  1  0.836  0.168  0.878  1.0
  Mg  Mg12  1  0.838  0.669  0.372  1.0
  Mg  Mg13  1  0.838  0.669  0.878  1.0
  V  V14  1  0.166  0.833  0.125  1.0
  Zn  Zn15  1  0.170  0.335  0.125  1.0
[/CIF]
.
The material structure described by Mg14VZn crystallizes in the orthorhombic Amm2 space group. There are nine inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2); two equivalent Mg(6); four Mg(4,4); and four Mg(5,5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent V(1)Mg10Zn2 cuboctahedra; corners with six equivalent Mg(1)Mg12 cuboctahedra; corners with eight equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with eight Mg(5,5)Mg10VZn cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Zn(1)Mg10V2 cuboctahedra; faces with four Mg(5,5)Mg10VZn cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with six equivalent Mg(7)Mg11V cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1); two equivalent Mg(7); four Mg(4,4); and four Mg(5,5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Zn(1)Mg10V2 cuboctahedra; corners with six equivalent Mg(2)Mg12 cuboctahedra; corners with eight equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with eight Mg(5,5)Mg10VZn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent V(1)Mg10Zn2 cuboctahedra; faces with four Mg(5,5)Mg10VZn cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with six equivalent Mg(6)Mg11Zn cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), two equivalent V(1), and two equivalent Zn(1) atoms to form distorted MgMg8V2Zn2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; faces with two equivalent V(1)Mg10Zn2 cuboctahedra; faces with two equivalent Zn(1)Mg10V2 cuboctahedra; and faces with eight Mg(5,5)Mg10VZn cuboctahedra. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; corners with four equivalent V(1)Mg10Zn2 cuboctahedra; corners with four equivalent Zn(1)Mg10V2 cuboctahedra; corners with six Mg(4,4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; and faces with eight Mg(5,5)Mg10VZn cuboctahedra. In the fifth Mg site, Mg(5) is bonded to one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), one V(1), and one Zn(1) atom to form distorted MgMg10VZn cuboctahedra that share corners with four equivalent Mg(7)Mg11V cuboctahedra; corners with four equivalent Mg(6)Mg11Zn cuboctahedra; corners with ten Mg(5,5)Mg10VZn cuboctahedra; edges with two equivalent Mg(5)Mg10VZn cuboctahedra; edges with two equivalent Mg(7)Mg11V cuboctahedra; edges with two equivalent Mg(6)Mg11Zn cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Mg10Zn2 cuboctahedra;  a faceface with one Zn(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with four equivalent Mg(5)Mg10VZn cuboctahedra; faces with four equivalent Mg(4)Mg12 cuboctahedra; and faces with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra. In the sixth Mg site, Mg(5) is bonded to one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), one V(1), and one Zn(1) atom to form distorted MgMg10VZn cuboctahedra that share corners with four equivalent Mg(7)Mg11V cuboctahedra; corners with four equivalent Mg(6)Mg11Zn cuboctahedra; corners with ten Mg(5,5)Mg10VZn cuboctahedra; edges with two equivalent Mg(5)Mg10VZn cuboctahedra; edges with two equivalent Mg(7)Mg11V cuboctahedra; edges with two equivalent Mg(6)Mg11Zn cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Mg10Zn2 cuboctahedra;  a faceface with one Zn(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with four equivalent Mg(5)Mg10VZn cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra. In the seventh Mg site, Mg(6) is bonded to one Mg(1), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(7), four equivalent Mg(5), and one Zn(1) atom to form distorted MgMg11Zn cuboctahedra that share corners with four equivalent Mg(7)Mg11V cuboctahedra; corners with six equivalent Mg(6)Mg11Zn cuboctahedra; corners with eight Mg(5,5)Mg10VZn cuboctahedra; edges with two equivalent Mg(7)Mg11V cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Zn(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; faces with three equivalent Mg(2)Mg12 cuboctahedra; faces with three equivalent V(1)Mg10Zn2 cuboctahedra; and faces with four equivalent Mg(5)Mg10VZn cuboctahedra. In the eighth Mg site, Mg(7) is bonded to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), four equivalent Mg(5), and one V(1) atom to form distorted MgMg11V cuboctahedra that share corners with four equivalent Mg(6)Mg11Zn cuboctahedra; corners with six equivalent Mg(7)Mg11V cuboctahedra; corners with eight Mg(5,5)Mg10VZn cuboctahedra; edges with two equivalent Mg(6)Mg11Zn cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Mg10Zn2 cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; faces with three equivalent Mg(1)Mg12 cuboctahedra; faces with three equivalent Zn(1)Mg10V2 cuboctahedra; and faces with four equivalent Mg(5)Mg10VZn cuboctahedra. In the ninth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; corners with four equivalent V(1)Mg10Zn2 cuboctahedra; corners with four equivalent Zn(1)Mg10V2 cuboctahedra; corners with six Mg(4,4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(5)Mg10VZn cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(3)Mg8V2Zn2 cuboctahedra; and faces with eight Mg(5,5)Mg10VZn cuboctahedra. V(1) is bonded to two equivalent Mg(7); four equivalent Mg(3); four Mg(5,5); and two equivalent Zn(1) atoms to form VMg10Zn2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with six equivalent V(1)Mg10Zn2 cuboctahedra; corners with eight Mg(4,4)Mg12 cuboctahedra; edges with two equivalent Zn(1)Mg10V2 cuboctahedra; edges with four equivalent Mg(7)Mg11V cuboctahedra; edges with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with eight Mg(5,5)Mg10VZn cuboctahedra; faces with two equivalent Mg(7)Mg11V cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Zn(1)Mg10V2 cuboctahedra; faces with four Mg(5,5)Mg10VZn cuboctahedra; faces with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; and faces with six equivalent Mg(6)Mg11Zn cuboctahedra. Zn(1) is bonded to two equivalent Mg(6); four equivalent Mg(3); four Mg(5,5); and two equivalent V(1) atoms to form ZnMg10V2 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with six equivalent Zn(1)Mg10V2 cuboctahedra; corners with eight Mg(4,4)Mg12 cuboctahedra; edges with two equivalent V(1)Mg10Zn2 cuboctahedra; edges with four equivalent Mg(6)Mg11Zn cuboctahedra; edges with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; edges with eight Mg(5,5)Mg10VZn cuboctahedra; faces with two equivalent Mg(6)Mg11Zn cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent V(1)Mg10Zn2 cuboctahedra; faces with four Mg(5,5)Mg10VZn cuboctahedra; faces with four equivalent Mg(3)Mg8V2Zn2 cuboctahedra; and faces with six equivalent Mg(7)Mg11V cuboctahedra. is represented by the CIF card [CIF]
data_Mg14VZn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.274
_cell_length_b   6.271
_cell_length_c   10.171
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.985
_symmetry_Int_Tables_number   1
_cell_volume   346.563
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.168  0.334  0.625  1.0
  Mg  Mg1  1  0.168  0.834  0.625  1.0
  Mg  Mg2  1  0.668  0.337  0.125  1.0
  Mg  Mg3  1  0.666  0.333  0.625  1.0
  Mg  Mg4  1  0.668  0.831  0.125  1.0
  Mg  Mg5  1  0.666  0.833  0.625  1.0
  Mg  Mg6  1  0.328  0.163  0.365  1.0
  Mg  Mg7  1  0.328  0.163  0.885  1.0
  Mg  Mg8  1  0.328  0.665  0.365  1.0
  Mg  Mg9  1  0.328  0.665  0.885  1.0
  Mg  Mg10  1  0.836  0.168  0.372  1.0
  Mg  Mg11  1  0.836  0.168  0.878  1.0
  Mg  Mg12  1  0.838  0.669  0.372  1.0
  Mg  Mg13  1  0.838  0.669  0.878  1.0
  V  V14  1  0.166  0.833  0.125  1.0
  Zn  Zn15  1  0.170  0.335  0.125  1.0
[/CIF]
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