The compound described by Tm5(PtIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 2-coordinate geometry to two equivalent Pt(1), two equivalent In(1), and four equivalent In(2) atoms. In the second Tm site, Tm(2) is bonded in a 4-coordinate geometry to four equivalent Pt(1), two equivalent In(2), and four equivalent In(1) atoms. In the third Tm site, Tm(3) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. Pt(1) is bonded in a 9-coordinate geometry to two equivalent Tm(1), four equivalent Tm(2), one In(2), and two equivalent In(1) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent Tm(1), two equivalent Tm(3), four equivalent Tm(2), and two equivalent Pt(1) atoms. In the second In site, In(2) is bonded in a 9-coordinate geometry to two equivalent Tm(2), two equivalent Tm(3), four equivalent Tm(1), and one Pt(1) atom. is represented by the CIF card [CIF]
data_Tm5(In2Pt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.567
_cell_length_b   7.991
_cell_length_c   17.981
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   512.441
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.000  0.116  0.416  1.0
  Tm  Tm1  1  0.000  0.884  0.584  1.0
  Tm  Tm2  1  0.000  0.384  0.916  1.0
  Tm  Tm3  1  0.000  0.616  0.084  1.0
  Tm  Tm4  1  0.000  0.244  0.220  1.0
  Tm  Tm5  1  0.000  0.756  0.780  1.0
  Tm  Tm6  1  0.000  0.256  0.720  1.0
  Tm  Tm7  1  0.000  0.744  0.280  1.0
  Tm  Tm8  1  0.000  0.000  0.000  1.0
  Tm  Tm9  1  0.000  0.500  0.500  1.0
  In  In10  1  0.500  0.424  0.352  1.0
  In  In11  1  0.500  0.576  0.648  1.0
  In  In12  1  0.500  0.076  0.852  1.0
  In  In13  1  0.500  0.924  0.148  1.0
  In  In14  1  0.500  0.290  0.067  1.0
  In  In15  1  0.500  0.710  0.933  1.0
  In  In16  1  0.500  0.210  0.567  1.0
  In  In17  1  0.500  0.790  0.433  1.0
  Pt  Pt18  1  0.500  0.028  0.304  1.0
  Pt  Pt19  1  0.500  0.972  0.696  1.0
  Pt  Pt20  1  0.500  0.472  0.804  1.0
  Pt  Pt21  1  0.500  0.528  0.196  1.0
[/CIF]
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The compound described by Tm5(PtIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 2-coordinate geometry to two equivalent Pt(1), two equivalent In(1), and four equivalent In(2) atoms. In the second Tm site, Tm(2) is bonded in a 4-coordinate geometry to four equivalent Pt(1), two equivalent In(2), and four equivalent In(1) atoms. In the third Tm site, Tm(3) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. Pt(1) is bonded in a 9-coordinate geometry to two equivalent Tm(1), four equivalent Tm(2), one In(2), and two equivalent In(1) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent Tm(1), two equivalent Tm(3), four equivalent Tm(2), and two equivalent Pt(1) atoms. In the second In site, In(2) is bonded in a 9-coordinate geometry to two equivalent Tm(2), two equivalent Tm(3), four equivalent Tm(1), and one Pt(1) atom. is represented by the CIF card [CIF]
data_Tm5(In2Pt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.567
_cell_length_b   7.991
_cell_length_c   17.981
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   512.441
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.000  0.116  0.416  1.0
  Tm  Tm1  1  0.000  0.884  0.584  1.0
  Tm  Tm2  1  0.000  0.384  0.916  1.0
  Tm  Tm3  1  0.000  0.616  0.084  1.0
  Tm  Tm4  1  0.000  0.244  0.220  1.0
  Tm  Tm5  1  0.000  0.756  0.780  1.0
  Tm  Tm6  1  0.000  0.256  0.720  1.0
  Tm  Tm7  1  0.000  0.744  0.280  1.0
  Tm  Tm8  1  0.000  0.000  0.000  1.0
  Tm  Tm9  1  0.000  0.500  0.500  1.0
  In  In10  1  0.500  0.424  0.352  1.0
  In  In11  1  0.500  0.576  0.648  1.0
  In  In12  1  0.500  0.076  0.852  1.0
  In  In13  1  0.500  0.924  0.148  1.0
  In  In14  1  0.500  0.290  0.067  1.0
  In  In15  1  0.500  0.710  0.933  1.0
  In  In16  1  0.500  0.210  0.567  1.0
  In  In17  1  0.500  0.790  0.433  1.0
  Pt  Pt18  1  0.500  0.028  0.304  1.0
  Pt  Pt19  1  0.500  0.972  0.696  1.0
  Pt  Pt20  1  0.500  0.472  0.804  1.0
  Pt  Pt21  1  0.500  0.528  0.196  1.0
[/CIF]
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