The crystal structure described by Zn(WO2)2 is Spinel-like structured and crystallizes in the orthorhombic Pbcm space group. W(1) is bonded to one O(3), two equivalent O(2), and three equivalent O(1) atoms to form a mixture of corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-66°. Zn(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to three equivalent W(1) and one Zn(1) atom to form distorted OZnW3 tetrahedra that share corners with three equivalent O(1)ZnW3 tetrahedra, corners with five equivalent O(3)Zn2W2 tetrahedra, and edges with two equivalent O(1)ZnW3 tetrahedra. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to four equivalent W(1) atoms. In the third O site, O(3) is bonded to two equivalent W(1) and two equivalent Zn(1) atoms to form distorted OZn2W2 tetrahedra that share corners with two equivalent O(3)Zn2W2 tetrahedra and corners with ten equivalent O(1)ZnW3 tetrahedra. is represented by the CIF card [CIF]
data_Zn(WO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.203
_cell_length_b   10.347
_cell_length_c   10.482
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   347.384
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.034  0.355  0.750  1.0
  Zn  Zn1  1  0.034  0.145  0.250  1.0
  Zn  Zn2  1  0.966  0.855  0.750  1.0
  Zn  Zn3  1  0.966  0.645  0.250  1.0
  W  W4  1  0.698  0.119  0.926  1.0
  W  W5  1  0.698  0.381  0.426  1.0
  W  W6  1  0.302  0.881  0.426  1.0
  W  W7  1  0.698  0.381  0.074  1.0
  W  W8  1  0.302  0.881  0.074  1.0
  W  W9  1  0.698  0.119  0.574  1.0
  W  W10  1  0.302  0.619  0.574  1.0
  W  W11  1  0.302  0.619  0.926  1.0
  O  O12  1  0.198  0.982  0.611  1.0
  O  O13  1  0.802  0.018  0.389  1.0
  O  O14  1  0.193  0.250  0.500  1.0
  O  O15  1  0.802  0.482  0.611  1.0
  O  O16  1  0.802  0.482  0.889  1.0
  O  O17  1  0.563  0.273  0.250  1.0
  O  O18  1  0.198  0.518  0.389  1.0
  O  O19  1  0.437  0.773  0.250  1.0
  O  O20  1  0.193  0.250  0.000  1.0
  O  O21  1  0.807  0.750  0.500  1.0
  O  O22  1  0.198  0.982  0.889  1.0
  O  O23  1  0.437  0.727  0.750  1.0
  O  O24  1  0.563  0.227  0.750  1.0
  O  O25  1  0.807  0.750  0.000  1.0
  O  O26  1  0.198  0.518  0.111  1.0
  O  O27  1  0.802  0.018  0.111  1.0
[/CIF]
.
The crystal structure described by Zn(WO2)2 is Spinel-like structured and crystallizes in the orthorhombic Pbcm space group. W(1) is bonded to one O(3), two equivalent O(2), and three equivalent O(1) atoms to form a mixture of corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-66°. Zn(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to three equivalent W(1) and one Zn(1) atom to form distorted OZnW3 tetrahedra that share corners with three equivalent O(1)ZnW3 tetrahedra, corners with five equivalent O(3)Zn2W2 tetrahedra, and edges with two equivalent O(1)ZnW3 tetrahedra. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to four equivalent W(1) atoms. In the third O site, O(3) is bonded to two equivalent W(1) and two equivalent Zn(1) atoms to form distorted OZn2W2 tetrahedra that share corners with two equivalent O(3)Zn2W2 tetrahedra and corners with ten equivalent O(1)ZnW3 tetrahedra. is represented by the CIF card [CIF]
data_Zn(WO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.203
_cell_length_b   10.347
_cell_length_c   10.482
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   347.384
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.034  0.355  0.750  1.0
  Zn  Zn1  1  0.034  0.145  0.250  1.0
  Zn  Zn2  1  0.966  0.855  0.750  1.0
  Zn  Zn3  1  0.966  0.645  0.250  1.0
  W  W4  1  0.698  0.119  0.926  1.0
  W  W5  1  0.698  0.381  0.426  1.0
  W  W6  1  0.302  0.881  0.426  1.0
  W  W7  1  0.698  0.381  0.074  1.0
  W  W8  1  0.302  0.881  0.074  1.0
  W  W9  1  0.698  0.119  0.574  1.0
  W  W10  1  0.302  0.619  0.574  1.0
  W  W11  1  0.302  0.619  0.926  1.0
  O  O12  1  0.198  0.982  0.611  1.0
  O  O13  1  0.802  0.018  0.389  1.0
  O  O14  1  0.193  0.250  0.500  1.0
  O  O15  1  0.802  0.482  0.611  1.0
  O  O16  1  0.802  0.482  0.889  1.0
  O  O17  1  0.563  0.273  0.250  1.0
  O  O18  1  0.198  0.518  0.389  1.0
  O  O19  1  0.437  0.773  0.250  1.0
  O  O20  1  0.193  0.250  0.000  1.0
  O  O21  1  0.807  0.750  0.500  1.0
  O  O22  1  0.198  0.982  0.889  1.0
  O  O23  1  0.437  0.727  0.750  1.0
  O  O24  1  0.563  0.227  0.750  1.0
  O  O25  1  0.807  0.750  0.000  1.0
  O  O26  1  0.198  0.518  0.111  1.0
  O  O27  1  0.802  0.018  0.111  1.0
[/CIF]
.