The material described by La2CoZnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(13), one O(15), one O(17), one O(18), one O(2), one O(7), one O(9), and two equivalent O(21) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(10), one O(14), one O(16), one O(18), one O(19), one O(3), one O(8), and two equivalent O(22) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(15), one O(19), one O(20), one O(4), one O(5), and two equivalent O(23) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(14), one O(16), one O(17), one O(20), one O(6), and two equivalent O(24) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(16), one O(17), one O(23), one O(3), one O(9), and two equivalent O(5) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(18), one O(2), one O(24), one O(4), one O(9), and two equivalent O(6) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(14), one O(19), one O(21), one O(3), and two equivalent O(7) atoms. In the eighth La site, La(8) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(15), one O(2), one O(20), one O(22), one O(4), and two equivalent O(8) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(14), one O(17), one O(24), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Zn(3)O6 octahedra,  a cornercorner with one Zn(4)O6 octahedra, corners with two equivalent Zn(1)O6 octahedra, and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-24°. In the second Co site, Co(2) is bonded to one O(11), one O(15), one O(18), one O(2), one O(21), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(4)O6 octahedra, corners with two equivalent Zn(2)O6 octahedra, and corners with two equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-23°. In the third Co site, Co(3) is bonded to one O(12), one O(16), one O(19), one O(22), one O(3), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, and corners with two equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-24°. In the fourth Co site, Co(4) is bonded to one O(13), one O(20), one O(23), one O(4), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Zn(1)O6 octahedra, and corners with two equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-23°. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(13), one O(17), one O(21), one O(5), and one O(9) atom to form ZnO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-24°. In the second Zn site, Zn(2) is bonded to one O(10), one O(14), one O(18), one O(2), one O(22), and one O(6) atom to form ZnO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-23°. In the third Zn site, Zn(3) is bonded to one O(11), one O(15), one O(19), one O(23), one O(3), and one O(7) atom to form ZnO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-23°. In the fourth Zn site, Zn(4) is bonded to one O(12), one O(16), one O(20), one O(24), one O(4), and one O(8) atom to form ZnO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-24°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(4), one La(5), one La(7), one Co(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one La(1), one La(6), one La(8), one Co(2), and one Zn(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one La(2), one La(5), one La(7), one Co(3), and one Zn(3) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one La(3), one La(6), one La(8), one Co(4), and one Zn(4) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(3), two equivalent La(5), one Co(3), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(4), two equivalent La(6), one Co(4), and one Zn(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(1), two equivalent La(7), one Co(1), and one Zn(3) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(2), two equivalent La(8), one Co(2), and one Zn(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one La(1), one La(5), one La(6), one Co(4), and one Zn(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(2), one La(6), one La(7), one Co(1), and one Zn(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(3), one La(7), one La(8), one Co(2), and one Zn(3) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one La(4), one La(5), one La(8), one Co(3), and one Zn(4) atom. In the thirteenth O site, O(13) is bonded in a 5-coordinate geometry to one La(1), one La(3), one La(6), one Co(4), and one Zn(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one La(2), one La(4), one La(7), one Co(1), and one Zn(2) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one La(1), one La(3), one La(8), one Co(2), and one Zn(3) atom. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one La(2), one La(4), one La(5), one Co(3), and one Zn(4) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one La(1), one La(4), one La(5), one Co(1), and one Zn(1) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one La(1), one La(2), one La(6), one Co(2), and one Zn(2) atom. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one La(2), one La(3), one La(7), one Co(3), and one Zn(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one La(3), one La(4), one La(8), one Co(4), and one Zn(4) atom. In the twenty-first O site, O(21) is bonded in a 5-coordinate geometry to one La(7), two equivalent La(1), one Co(2), and one Zn(1) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one La(8), two equivalent La(2), one Co(3), and one Zn(2) atom. In the twenty-third O site, O(23) is bonded in a 5-coordinate geometry to one La(5), two equivalent La(3), one Co(4), and one Zn(3) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one La(6), two equivalent La(4), one Co(1), and one Zn(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2ZnCoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.463
_cell_length_b   5.469
_cell_length_c   5.473
_cell_angle_alpha   61.452
_cell_angle_beta   61.500
_cell_angle_gamma   61.616
_symmetry_Int_Tables_number   1
_cell_volume   119.571
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  1.000  1.000  1.0
  La  La1  1  0.249  0.249  0.248  1.0
  La  La2  1  0.751  0.751  0.752  1.0
  O  O3  1  0.829  0.234  0.693  1.0
  O  O4  1  0.691  0.829  0.234  1.0
  O  O5  1  0.234  0.692  0.829  1.0
  O  O6  1  0.171  0.766  0.307  1.0
  O  O7  1  0.765  0.308  0.171  1.0
  O  O8  1  0.308  0.171  0.766  1.0
  Zn  Zn9  1  0.500  0.500  0.500  1.0
[/CIF]
.
The material described by La2CoZnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(13), one O(15), one O(17), one O(18), one O(2), one O(7), one O(9), and two equivalent O(21) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(10), one O(14), one O(16), one O(18), one O(19), one O(3), one O(8), and two equivalent O(22) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(15), one O(19), one O(20), one O(4), one O(5), and two equivalent O(23) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(14), one O(16), one O(17), one O(20), one O(6), and two equivalent O(24) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(16), one O(17), one O(23), one O(3), one O(9), and two equivalent O(5) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(18), one O(2), one O(24), one O(4), one O(9), and two equivalent O(6) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(14), one O(19), one O(21), one O(3), and two equivalent O(7) atoms. In the eighth La site, La(8) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(15), one O(2), one O(20), one O(22), one O(4), and two equivalent O(8) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(14), one O(17), one O(24), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Zn(3)O6 octahedra,  a cornercorner with one Zn(4)O6 octahedra, corners with two equivalent Zn(1)O6 octahedra, and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-24°. In the second Co site, Co(2) is bonded to one O(11), one O(15), one O(18), one O(2), one O(21), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(4)O6 octahedra, corners with two equivalent Zn(2)O6 octahedra, and corners with two equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-23°. In the third Co site, Co(3) is bonded to one O(12), one O(16), one O(19), one O(22), one O(3), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, and corners with two equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-24°. In the fourth Co site, Co(4) is bonded to one O(13), one O(20), one O(23), one O(4), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Zn(1)O6 octahedra, and corners with two equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-23°. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(13), one O(17), one O(21), one O(5), and one O(9) atom to form ZnO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-24°. In the second Zn site, Zn(2) is bonded to one O(10), one O(14), one O(18), one O(2), one O(22), and one O(6) atom to form ZnO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-23°. In the third Zn site, Zn(3) is bonded to one O(11), one O(15), one O(19), one O(23), one O(3), and one O(7) atom to form ZnO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-23°. In the fourth Zn site, Zn(4) is bonded to one O(12), one O(16), one O(20), one O(24), one O(4), and one O(8) atom to form ZnO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-24°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(4), one La(5), one La(7), one Co(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one La(1), one La(6), one La(8), one Co(2), and one Zn(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one La(2), one La(5), one La(7), one Co(3), and one Zn(3) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one La(3), one La(6), one La(8), one Co(4), and one Zn(4) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(3), two equivalent La(5), one Co(3), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(4), two equivalent La(6), one Co(4), and one Zn(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(1), two equivalent La(7), one Co(1), and one Zn(3) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(2), two equivalent La(8), one Co(2), and one Zn(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one La(1), one La(5), one La(6), one Co(4), and one Zn(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(2), one La(6), one La(7), one Co(1), and one Zn(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(3), one La(7), one La(8), one Co(2), and one Zn(3) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one La(4), one La(5), one La(8), one Co(3), and one Zn(4) atom. In the thirteenth O site, O(13) is bonded in a 5-coordinate geometry to one La(1), one La(3), one La(6), one Co(4), and one Zn(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one La(2), one La(4), one La(7), one Co(1), and one Zn(2) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one La(1), one La(3), one La(8), one Co(2), and one Zn(3) atom. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one La(2), one La(4), one La(5), one Co(3), and one Zn(4) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one La(1), one La(4), one La(5), one Co(1), and one Zn(1) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one La(1), one La(2), one La(6), one Co(2), and one Zn(2) atom. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one La(2), one La(3), one La(7), one Co(3), and one Zn(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one La(3), one La(4), one La(8), one Co(4), and one Zn(4) atom. In the twenty-first O site, O(21) is bonded in a 5-coordinate geometry to one La(7), two equivalent La(1), one Co(2), and one Zn(1) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one La(8), two equivalent La(2), one Co(3), and one Zn(2) atom. In the twenty-third O site, O(23) is bonded in a 5-coordinate geometry to one La(5), two equivalent La(3), one Co(4), and one Zn(3) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one La(6), two equivalent La(4), one Co(1), and one Zn(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2ZnCoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.463
_cell_length_b   5.469
_cell_length_c   5.473
_cell_angle_alpha   61.452
_cell_angle_beta   61.500
_cell_angle_gamma   61.616
_symmetry_Int_Tables_number   1
_cell_volume   119.571
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  1.000  1.000  1.0
  La  La1  1  0.249  0.249  0.248  1.0
  La  La2  1  0.751  0.751  0.752  1.0
  O  O3  1  0.829  0.234  0.693  1.0
  O  O4  1  0.691  0.829  0.234  1.0
  O  O5  1  0.234  0.692  0.829  1.0
  O  O6  1  0.171  0.766  0.307  1.0
  O  O7  1  0.765  0.308  0.171  1.0
  O  O8  1  0.308  0.171  0.766  1.0
  Zn  Zn9  1  0.500  0.500  0.500  1.0
[/CIF]
.