The structure described by Li3WP3O11 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(7), and two equivalent O(2) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(10), one O(7), one O(9), and two equivalent O(1) atoms. In the third Li site, Li(3) is bonded in a distorted trigonal planar geometry to one O(11), one O(8), and one O(9) atom. W(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one O(11), one O(2), one O(4), and one O(6) atom. In the third P site, P(3) is bonded in a distorted tetrahedral geometry to one O(10), one O(7), one O(8), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Li(2), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one W(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one W(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), one W(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Li(3), one W(1), and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one P(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one W(1), and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Li(3), one W(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3P3WO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.155
_cell_length_b   8.227
_cell_length_c   6.413
_cell_angle_alpha   96.165
_cell_angle_beta   99.474
_cell_angle_gamma   109.123
_symmetry_Int_Tables_number   1
_cell_volume   394.906
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.824  0.616  0.991  1.0
  Li  Li1  1  0.574  0.410  0.179  1.0
  Li  Li2  1  0.962  0.712  0.474  1.0
  Li  Li3  1  0.038  0.288  0.526  1.0
  Li  Li4  1  0.426  0.590  0.821  1.0
  Li  Li5  1  0.176  0.384  0.009  1.0
  P  P6  1  0.619  0.882  0.229  1.0
  P  P7  1  0.860  0.140  0.114  1.0
  P  P8  1  0.288  0.621  0.414  1.0
  P  P9  1  0.712  0.379  0.586  1.0
  P  P10  1  0.140  0.860  0.886  1.0
  P  P11  1  0.381  0.118  0.771  1.0
  W  W12  1  0.725  0.906  0.681  1.0
  W  W13  1  0.275  0.094  0.319  1.0
  O  O14  1  0.617  0.686  0.093  1.0
  O  O15  1  0.873  0.360  0.077  1.0
  O  O16  1  0.438  0.915  0.220  1.0
  O  O17  1  0.690  0.099  0.173  1.0
  O  O18  1  0.745  0.878  0.415  1.0
  O  O19  1  0.168  0.055  0.038  1.0
  O  O20  1  0.294  0.426  0.271  1.0
  O  O21  1  0.174  0.773  0.316  1.0
  O  O22  1  0.795  0.457  0.458  1.0
  O  O23  1  0.475  0.747  0.516  1.0
  O  O24  1  0.989  0.884  0.719  1.0
  O  O25  1  0.011  0.116  0.281  1.0
  O  O26  1  0.525  0.253  0.484  1.0
  O  O27  1  0.205  0.543  0.542  1.0
  O  O28  1  0.826  0.227  0.684  1.0
  O  O29  1  0.706  0.574  0.729  1.0
  O  O30  1  0.832  0.945  0.962  1.0
  O  O31  1  0.255  0.122  0.585  1.0
  O  O32  1  0.310  0.901  0.827  1.0
  O  O33  1  0.562  0.085  0.780  1.0
  O  O34  1  0.127  0.640  0.923  1.0
  O  O35  1  0.383  0.314  0.907  1.0
[/CIF]
.
The structure described by Li3WP3O11 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(7), and two equivalent O(2) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(10), one O(7), one O(9), and two equivalent O(1) atoms. In the third Li site, Li(3) is bonded in a distorted trigonal planar geometry to one O(11), one O(8), and one O(9) atom. W(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one O(11), one O(2), one O(4), and one O(6) atom. In the third P site, P(3) is bonded in a distorted tetrahedral geometry to one O(10), one O(7), one O(8), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Li(2), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one W(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one W(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), one W(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Li(3), one W(1), and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one P(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one W(1), and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Li(3), one W(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3P3WO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.155
_cell_length_b   8.227
_cell_length_c   6.413
_cell_angle_alpha   96.165
_cell_angle_beta   99.474
_cell_angle_gamma   109.123
_symmetry_Int_Tables_number   1
_cell_volume   394.906
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.824  0.616  0.991  1.0
  Li  Li1  1  0.574  0.410  0.179  1.0
  Li  Li2  1  0.962  0.712  0.474  1.0
  Li  Li3  1  0.038  0.288  0.526  1.0
  Li  Li4  1  0.426  0.590  0.821  1.0
  Li  Li5  1  0.176  0.384  0.009  1.0
  P  P6  1  0.619  0.882  0.229  1.0
  P  P7  1  0.860  0.140  0.114  1.0
  P  P8  1  0.288  0.621  0.414  1.0
  P  P9  1  0.712  0.379  0.586  1.0
  P  P10  1  0.140  0.860  0.886  1.0
  P  P11  1  0.381  0.118  0.771  1.0
  W  W12  1  0.725  0.906  0.681  1.0
  W  W13  1  0.275  0.094  0.319  1.0
  O  O14  1  0.617  0.686  0.093  1.0
  O  O15  1  0.873  0.360  0.077  1.0
  O  O16  1  0.438  0.915  0.220  1.0
  O  O17  1  0.690  0.099  0.173  1.0
  O  O18  1  0.745  0.878  0.415  1.0
  O  O19  1  0.168  0.055  0.038  1.0
  O  O20  1  0.294  0.426  0.271  1.0
  O  O21  1  0.174  0.773  0.316  1.0
  O  O22  1  0.795  0.457  0.458  1.0
  O  O23  1  0.475  0.747  0.516  1.0
  O  O24  1  0.989  0.884  0.719  1.0
  O  O25  1  0.011  0.116  0.281  1.0
  O  O26  1  0.525  0.253  0.484  1.0
  O  O27  1  0.205  0.543  0.542  1.0
  O  O28  1  0.826  0.227  0.684  1.0
  O  O29  1  0.706  0.574  0.729  1.0
  O  O30  1  0.832  0.945  0.962  1.0
  O  O31  1  0.255  0.122  0.585  1.0
  O  O32  1  0.310  0.901  0.827  1.0
  O  O33  1  0.562  0.085  0.780  1.0
  O  O34  1  0.127  0.640  0.923  1.0
  O  O35  1  0.383  0.314  0.907  1.0
[/CIF]
.