The compound described by Sm7Pd3 crystallizes in the orthorhombic Cmc2_1 space group. There are five inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pd(2) atoms. In the second Sm site, Sm(2) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pd(2) atoms. In the third Sm site, Sm(3) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pd(2) atoms. In the fourth Sm site, Sm(4) is bonded in a distorted water-like geometry to two equivalent Pd(2) atoms. In the fifth Sm site, Sm(5) is bonded in a distorted water-like geometry to one Pd(1) and one Pd(2) atom. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 6-coordinate geometry to one Sm(1), one Sm(2), two equivalent Sm(3), and two equivalent Sm(5) atoms. In the second Pd site, Pd(2) is bonded in a 6-coordinate geometry to one Sm(1), one Sm(2), one Sm(4), one Sm(5), and two equivalent Sm(3) atoms. is represented by the CIF card [CIF]
data_Sm7Pd3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.455
_cell_length_b   10.084
_cell_length_c   10.084
_cell_angle_alpha   119.782
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   569.658
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.449  0.333  0.667  1.0
  Sm  Sm1  1  0.949  0.667  0.333  1.0
  Sm  Sm2  1  0.246  0.127  0.873  1.0
  Sm  Sm3  1  0.246  0.747  0.874  1.0
  Sm  Sm4  1  0.246  0.126  0.253  1.0
  Sm  Sm5  1  0.746  0.873  0.127  1.0
  Sm  Sm6  1  0.746  0.253  0.126  1.0
  Sm  Sm7  1  0.746  0.874  0.747  1.0
  Sm  Sm8  1  0.446  0.538  0.462  1.0
  Sm  Sm9  1  0.445  0.925  0.462  1.0
  Sm  Sm10  1  0.445  0.538  0.075  1.0
  Sm  Sm11  1  0.946  0.462  0.538  1.0
  Sm  Sm12  1  0.945  0.075  0.538  1.0
  Sm  Sm13  1  0.945  0.462  0.925  1.0
  Pd  Pd14  1  0.190  0.811  0.189  1.0
  Pd  Pd15  1  0.190  0.378  0.189  1.0
  Pd  Pd16  1  0.190  0.811  0.622  1.0
  Pd  Pd17  1  0.690  0.189  0.811  1.0
  Pd  Pd18  1  0.690  0.622  0.811  1.0
  Pd  Pd19  1  0.690  0.189  0.378  1.0
[/CIF]
.
The compound described by Sm7Pd3 crystallizes in the orthorhombic Cmc2_1 space group. There are five inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pd(2) atoms. In the second Sm site, Sm(2) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pd(2) atoms. In the third Sm site, Sm(3) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pd(2) atoms. In the fourth Sm site, Sm(4) is bonded in a distorted water-like geometry to two equivalent Pd(2) atoms. In the fifth Sm site, Sm(5) is bonded in a distorted water-like geometry to one Pd(1) and one Pd(2) atom. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 6-coordinate geometry to one Sm(1), one Sm(2), two equivalent Sm(3), and two equivalent Sm(5) atoms. In the second Pd site, Pd(2) is bonded in a 6-coordinate geometry to one Sm(1), one Sm(2), one Sm(4), one Sm(5), and two equivalent Sm(3) atoms. is represented by the CIF card [CIF]
data_Sm7Pd3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.455
_cell_length_b   10.084
_cell_length_c   10.084
_cell_angle_alpha   119.782
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   569.658
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.449  0.333  0.667  1.0
  Sm  Sm1  1  0.949  0.667  0.333  1.0
  Sm  Sm2  1  0.246  0.127  0.873  1.0
  Sm  Sm3  1  0.246  0.747  0.874  1.0
  Sm  Sm4  1  0.246  0.126  0.253  1.0
  Sm  Sm5  1  0.746  0.873  0.127  1.0
  Sm  Sm6  1  0.746  0.253  0.126  1.0
  Sm  Sm7  1  0.746  0.874  0.747  1.0
  Sm  Sm8  1  0.446  0.538  0.462  1.0
  Sm  Sm9  1  0.445  0.925  0.462  1.0
  Sm  Sm10  1  0.445  0.538  0.075  1.0
  Sm  Sm11  1  0.946  0.462  0.538  1.0
  Sm  Sm12  1  0.945  0.075  0.538  1.0
  Sm  Sm13  1  0.945  0.462  0.925  1.0
  Pd  Pd14  1  0.190  0.811  0.189  1.0
  Pd  Pd15  1  0.190  0.378  0.189  1.0
  Pd  Pd16  1  0.190  0.811  0.622  1.0
  Pd  Pd17  1  0.690  0.189  0.811  1.0
  Pd  Pd18  1  0.690  0.622  0.811  1.0
  Pd  Pd19  1  0.690  0.189  0.378  1.0
[/CIF]
.