The compound described by TeI4 is Indium-like structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is zero-dimensional and consists of two TeI4 clusters. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one I(3), one I(5), two equivalent I(1), and two equivalent I(8) atoms to form edge-sharing TeI6 octahedra. In the second Te site, Te(2) is bonded to one I(2), one I(3), one I(4), one I(6), one I(8), and one I(9) atom to form edge-sharing TeI6 octahedra. In the third Te site, Te(3) is bonded to one I(10), one I(2), two equivalent I(4), and two equivalent I(7) atoms to form edge-sharing TeI6 octahedra. There are ten inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Te(1) atom. In the second I site, I(2) is bonded in a distorted T-shaped geometry to one Te(3) and two equivalent Te(2) atoms. In the third I site, I(3) is bonded in a distorted T-shaped geometry to one Te(1) and two equivalent Te(2) atoms. In the fourth I site, I(4) is bonded in an L-shaped geometry to one Te(2) and one Te(3) atom. In the fifth I site, I(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth I site, I(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh I site, I(7) is bonded in a single-bond geometry to one Te(3) atom. In the eighth I site, I(8) is bonded in an L-shaped geometry to one Te(1) and one Te(2) atom. In the ninth I site, I(9) is bonded in a single-bond geometry to one Te(2) atom. In the tenth I site, I(10) is bonded in a single-bond geometry to one Te(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeI4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.177
_cell_length_b   14.862
_cell_length_c   17.088
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1822.562
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.277  0.395  0.000  1.0
  Te  Te1  1  0.735  0.163  0.359  1.0
  Te  Te2  1  0.265  0.663  0.859  1.0
  Te  Te3  1  0.260  0.932  0.000  1.0
  Te  Te4  1  0.735  0.163  0.641  1.0
  Te  Te5  1  0.723  0.895  0.500  1.0
  Te  Te6  1  0.740  0.432  0.500  1.0
  Te  Te7  1  0.265  0.663  0.141  1.0
  I  I8  1  0.507  0.826  0.621  1.0
  I  I9  1  0.985  0.251  0.500  1.0
  I  I10  1  0.487  0.080  0.500  1.0
  I  I11  1  0.510  0.825  0.129  1.0
  I  I12  1  0.986  0.757  0.500  1.0
  I  I13  1  0.036  0.742  0.747  1.0
  I  I14  1  0.510  0.825  0.871  1.0
  I  I15  1  0.048  0.004  0.122  1.0
  I  I16  1  0.952  0.504  0.378  1.0
  I  I17  1  0.021  0.501  0.870  1.0
  I  I18  1  0.493  0.326  0.121  1.0
  I  I19  1  0.495  0.084  0.748  1.0
  I  I20  1  0.964  0.242  0.247  1.0
  I  I21  1  0.979  0.001  0.370  1.0
  I  I22  1  0.505  0.584  0.248  1.0
  I  I23  1  0.505  0.584  0.752  1.0
  I  I24  1  0.979  0.001  0.630  1.0
  I  I25  1  0.952  0.504  0.622  1.0
  I  I26  1  0.507  0.826  0.379  1.0
  I  I27  1  0.015  0.751  0.000  1.0
  I  I28  1  0.493  0.326  0.879  1.0
  I  I29  1  0.472  0.567  0.500  1.0
  I  I30  1  0.490  0.325  0.371  1.0
  I  I31  1  0.048  0.004  0.878  1.0
  I  I32  1  0.021  0.501  0.130  1.0
  I  I33  1  0.964  0.242  0.753  1.0
  I  I34  1  0.513  0.580  0.000  1.0
  I  I35  1  0.014  0.257  0.000  1.0
  I  I36  1  0.490  0.325  0.629  1.0
  I  I37  1  0.495  0.084  0.252  1.0
  I  I38  1  0.528  0.067  0.000  1.0
  I  I39  1  0.036  0.742  0.253  1.0
[/CIF]
.
The compound described by TeI4 is Indium-like structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is zero-dimensional and consists of two TeI4 clusters. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one I(3), one I(5), two equivalent I(1), and two equivalent I(8) atoms to form edge-sharing TeI6 octahedra. In the second Te site, Te(2) is bonded to one I(2), one I(3), one I(4), one I(6), one I(8), and one I(9) atom to form edge-sharing TeI6 octahedra. In the third Te site, Te(3) is bonded to one I(10), one I(2), two equivalent I(4), and two equivalent I(7) atoms to form edge-sharing TeI6 octahedra. There are ten inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Te(1) atom. In the second I site, I(2) is bonded in a distorted T-shaped geometry to one Te(3) and two equivalent Te(2) atoms. In the third I site, I(3) is bonded in a distorted T-shaped geometry to one Te(1) and two equivalent Te(2) atoms. In the fourth I site, I(4) is bonded in an L-shaped geometry to one Te(2) and one Te(3) atom. In the fifth I site, I(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth I site, I(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh I site, I(7) is bonded in a single-bond geometry to one Te(3) atom. In the eighth I site, I(8) is bonded in an L-shaped geometry to one Te(1) and one Te(2) atom. In the ninth I site, I(9) is bonded in a single-bond geometry to one Te(2) atom. In the tenth I site, I(10) is bonded in a single-bond geometry to one Te(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeI4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.177
_cell_length_b   14.862
_cell_length_c   17.088
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1822.562
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.277  0.395  0.000  1.0
  Te  Te1  1  0.735  0.163  0.359  1.0
  Te  Te2  1  0.265  0.663  0.859  1.0
  Te  Te3  1  0.260  0.932  0.000  1.0
  Te  Te4  1  0.735  0.163  0.641  1.0
  Te  Te5  1  0.723  0.895  0.500  1.0
  Te  Te6  1  0.740  0.432  0.500  1.0
  Te  Te7  1  0.265  0.663  0.141  1.0
  I  I8  1  0.507  0.826  0.621  1.0
  I  I9  1  0.985  0.251  0.500  1.0
  I  I10  1  0.487  0.080  0.500  1.0
  I  I11  1  0.510  0.825  0.129  1.0
  I  I12  1  0.986  0.757  0.500  1.0
  I  I13  1  0.036  0.742  0.747  1.0
  I  I14  1  0.510  0.825  0.871  1.0
  I  I15  1  0.048  0.004  0.122  1.0
  I  I16  1  0.952  0.504  0.378  1.0
  I  I17  1  0.021  0.501  0.870  1.0
  I  I18  1  0.493  0.326  0.121  1.0
  I  I19  1  0.495  0.084  0.748  1.0
  I  I20  1  0.964  0.242  0.247  1.0
  I  I21  1  0.979  0.001  0.370  1.0
  I  I22  1  0.505  0.584  0.248  1.0
  I  I23  1  0.505  0.584  0.752  1.0
  I  I24  1  0.979  0.001  0.630  1.0
  I  I25  1  0.952  0.504  0.622  1.0
  I  I26  1  0.507  0.826  0.379  1.0
  I  I27  1  0.015  0.751  0.000  1.0
  I  I28  1  0.493  0.326  0.879  1.0
  I  I29  1  0.472  0.567  0.500  1.0
  I  I30  1  0.490  0.325  0.371  1.0
  I  I31  1  0.048  0.004  0.878  1.0
  I  I32  1  0.021  0.501  0.130  1.0
  I  I33  1  0.964  0.242  0.753  1.0
  I  I34  1  0.513  0.580  0.000  1.0
  I  I35  1  0.014  0.257  0.000  1.0
  I  I36  1  0.490  0.325  0.629  1.0
  I  I37  1  0.495  0.084  0.252  1.0
  I  I38  1  0.528  0.067  0.000  1.0
  I  I39  1  0.036  0.742  0.253  1.0
[/CIF]
.