The material structure described by NaBi3V2O10 crystallizes in the triclinic P1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(4), one O(5), one O(8), and one O(9) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(5), one O(7), and one O(9) atom to form VO4 tetrahedra that share corners with two equivalent Bi(2)O6 octahedra and corners with two equivalent Bi(3)O5 square pyramids. The corner-sharing octahedral tilt angles range from 59-70°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(6), and one O(8) atom to form VO4 tetrahedra that share corners with two equivalent Bi(2)O6 octahedra and  a cornercorner with one Bi(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 45-70°. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(6), and one O(7) atom. In the second Bi site, Bi(2) is bonded to one O(1), one O(10), one O(2), one O(4), one O(5), and one O(8) atom to form distorted BiO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, and  an edgeedge with one Bi(3)O5 square pyramid. In the third Bi site, Bi(3) is bonded to one O(10), one O(4), one O(6), one O(7), and one O(9) atom to form distorted BiO5 square pyramids that share  a cornercorner with one V(2)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, and  an edgeedge with one Bi(2)O6 octahedra. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(2), one Bi(1), and one Bi(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one Bi(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(2) and one Bi(1) atom. In the fourth O site, O(4) is bonded to one Na(1), one Bi(1), one Bi(2), and one Bi(3) atom to form edge-sharing ONaBi3 tetrahedra. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Na(1), one V(1), and one Bi(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(2), one Bi(1), and one Bi(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(1), one Bi(1), and one Bi(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one V(2), and one Bi(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Na(1), one V(1), and one Bi(3) atom. In the tenth O site, O(10) is bonded to one Na(1), one Bi(1), one Bi(2), and one Bi(3) atom to form edge-sharing ONaBi3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaV2Bi3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.667
_cell_length_b   7.115
_cell_length_c   7.223
_cell_angle_alpha   111.173
_cell_angle_beta   85.452
_cell_angle_gamma   111.340
_symmetry_Int_Tables_number   1
_cell_volume   252.498
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.089  0.956  0.476  1.0
  V  V1  1  0.742  0.316  0.382  1.0
  V  V2  1  0.326  0.605  0.072  1.0
  Bi  Bi3  1  0.976  0.970  0.976  1.0
  Bi  Bi4  1  0.435  0.662  0.595  1.0
  Bi  Bi5  1  0.611  0.235  0.843  1.0
  O  O6  1  0.588  0.668  0.925  1.0
  O  O7  1  0.775  0.581  0.418  1.0
  O  O8  1  0.085  0.645  0.986  1.0
  O  O9  1  0.277  0.936  0.754  1.0
  O  O10  1  0.015  0.301  0.451  1.0
  O  O11  1  0.253  0.325  0.015  1.0
  O  O12  1  0.668  0.153  0.125  1.0
  O  O13  1  0.391  0.748  0.328  1.0
  O  O14  1  0.502  0.238  0.538  1.0
  O  O15  1  0.782  0.971  0.723  1.0
[/CIF]
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The material structure described by NaBi3V2O10 crystallizes in the triclinic P1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(4), one O(5), one O(8), and one O(9) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(5), one O(7), and one O(9) atom to form VO4 tetrahedra that share corners with two equivalent Bi(2)O6 octahedra and corners with two equivalent Bi(3)O5 square pyramids. The corner-sharing octahedral tilt angles range from 59-70°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(6), and one O(8) atom to form VO4 tetrahedra that share corners with two equivalent Bi(2)O6 octahedra and  a cornercorner with one Bi(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 45-70°. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(6), and one O(7) atom. In the second Bi site, Bi(2) is bonded to one O(1), one O(10), one O(2), one O(4), one O(5), and one O(8) atom to form distorted BiO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, and  an edgeedge with one Bi(3)O5 square pyramid. In the third Bi site, Bi(3) is bonded to one O(10), one O(4), one O(6), one O(7), and one O(9) atom to form distorted BiO5 square pyramids that share  a cornercorner with one V(2)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, and  an edgeedge with one Bi(2)O6 octahedra. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(2), one Bi(1), and one Bi(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one Bi(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(2) and one Bi(1) atom. In the fourth O site, O(4) is bonded to one Na(1), one Bi(1), one Bi(2), and one Bi(3) atom to form edge-sharing ONaBi3 tetrahedra. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Na(1), one V(1), and one Bi(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(2), one Bi(1), and one Bi(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(1), one Bi(1), and one Bi(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one V(2), and one Bi(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Na(1), one V(1), and one Bi(3) atom. In the tenth O site, O(10) is bonded to one Na(1), one Bi(1), one Bi(2), and one Bi(3) atom to form edge-sharing ONaBi3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaV2Bi3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.667
_cell_length_b   7.115
_cell_length_c   7.223
_cell_angle_alpha   111.173
_cell_angle_beta   85.452
_cell_angle_gamma   111.340
_symmetry_Int_Tables_number   1
_cell_volume   252.498
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.089  0.956  0.476  1.0
  V  V1  1  0.742  0.316  0.382  1.0
  V  V2  1  0.326  0.605  0.072  1.0
  Bi  Bi3  1  0.976  0.970  0.976  1.0
  Bi  Bi4  1  0.435  0.662  0.595  1.0
  Bi  Bi5  1  0.611  0.235  0.843  1.0
  O  O6  1  0.588  0.668  0.925  1.0
  O  O7  1  0.775  0.581  0.418  1.0
  O  O8  1  0.085  0.645  0.986  1.0
  O  O9  1  0.277  0.936  0.754  1.0
  O  O10  1  0.015  0.301  0.451  1.0
  O  O11  1  0.253  0.325  0.015  1.0
  O  O12  1  0.668  0.153  0.125  1.0
  O  O13  1  0.391  0.748  0.328  1.0
  O  O14  1  0.502  0.238  0.538  1.0
  O  O15  1  0.782  0.971  0.723  1.0
[/CIF]
.