The crystal structure described by Mn3Pd20P6 crystallizes in the cubic Fm-3m space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to four equivalent Pd(1) and twelve equivalent Pd(2) atoms to form distorted MnPd16 tetrahedra that share edges with six equivalent Mn(1)Pd16 tetrahedra, edges with twelve equivalent Pd(1)MnP3Pd6 tetrahedra, faces with four equivalent Mn(2)Pd12 cuboctahedra, and faces with four equivalent Pd(1)MnP3Pd6 tetrahedra. In the second Mn site, Mn(2) is bonded to twelve equivalent Pd(2) atoms to form MnPd12 cuboctahedra that share edges with twenty-four equivalent Pd(1)MnP3Pd6 tetrahedra and faces with eight equivalent Mn(1)Pd16 tetrahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to one Mn(1), six equivalent Pd(2), and three equivalent P(1) atoms to form distorted PdMnP3Pd6 tetrahedra that share corners with three equivalent Pd(1)MnP3Pd6 tetrahedra, edges with three equivalent Mn(2)Pd12 cuboctahedra, edges with three equivalent Mn(1)Pd16 tetrahedra, edges with three equivalent Pd(1)MnP3Pd6 tetrahedra,  a faceface with one Mn(1)Pd16 tetrahedra, and faces with six equivalent Pd(1)MnP3Pd6 tetrahedra. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to one Mn(2), two equivalent Mn(1), four equivalent Pd(1), five equivalent Pd(2), and two equivalent P(1) atoms. P(1) is bonded in a 8-coordinate geometry to four equivalent Pd(1) and four equivalent Pd(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3(P3Pd10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.556
_cell_length_b   8.556
_cell_length_c   8.556
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   442.828
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.250  0.250  0.250  1.0
  Mn  Mn1  1  0.750  0.750  0.750  1.0
  Mn  Mn2  1  0.000  0.000  0.000  1.0
  P  P3  1  0.734  0.734  0.266  1.0
  P  P4  1  0.266  0.266  0.734  1.0
  P  P5  1  0.266  0.734  0.734  1.0
  P  P6  1  0.734  0.266  0.734  1.0
  P  P7  1  0.266  0.734  0.266  1.0
  P  P8  1  0.734  0.266  0.266  1.0
  Pd  Pd9  1  0.619  0.619  0.619  1.0
  Pd  Pd10  1  0.381  0.856  0.381  1.0
  Pd  Pd11  1  0.658  0.342  0.000  1.0
  Pd  Pd12  1  0.000  0.342  0.658  1.0
  Pd  Pd13  1  0.658  0.000  0.000  1.0
  Pd  Pd14  1  0.619  0.619  0.144  1.0
  Pd  Pd15  1  0.000  0.000  0.658  1.0
  Pd  Pd16  1  0.000  0.342  0.000  1.0
  Pd  Pd17  1  0.658  0.000  0.342  1.0
  Pd  Pd18  1  0.342  0.000  0.000  1.0
  Pd  Pd19  1  0.000  0.658  0.000  1.0
  Pd  Pd20  1  0.342  0.000  0.658  1.0
  Pd  Pd21  1  0.000  0.658  0.342  1.0
  Pd  Pd22  1  0.342  0.658  0.000  1.0
  Pd  Pd23  1  0.144  0.619  0.619  1.0
  Pd  Pd24  1  0.381  0.381  0.381  1.0
  Pd  Pd25  1  0.856  0.381  0.381  1.0
  Pd  Pd26  1  0.381  0.381  0.856  1.0
  Pd  Pd27  1  0.619  0.144  0.619  1.0
  Pd  Pd28  1  0.000  0.000  0.342  1.0
[/CIF]
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The crystal structure described by Mn3Pd20P6 crystallizes in the cubic Fm-3m space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to four equivalent Pd(1) and twelve equivalent Pd(2) atoms to form distorted MnPd16 tetrahedra that share edges with six equivalent Mn(1)Pd16 tetrahedra, edges with twelve equivalent Pd(1)MnP3Pd6 tetrahedra, faces with four equivalent Mn(2)Pd12 cuboctahedra, and faces with four equivalent Pd(1)MnP3Pd6 tetrahedra. In the second Mn site, Mn(2) is bonded to twelve equivalent Pd(2) atoms to form MnPd12 cuboctahedra that share edges with twenty-four equivalent Pd(1)MnP3Pd6 tetrahedra and faces with eight equivalent Mn(1)Pd16 tetrahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to one Mn(1), six equivalent Pd(2), and three equivalent P(1) atoms to form distorted PdMnP3Pd6 tetrahedra that share corners with three equivalent Pd(1)MnP3Pd6 tetrahedra, edges with three equivalent Mn(2)Pd12 cuboctahedra, edges with three equivalent Mn(1)Pd16 tetrahedra, edges with three equivalent Pd(1)MnP3Pd6 tetrahedra,  a faceface with one Mn(1)Pd16 tetrahedra, and faces with six equivalent Pd(1)MnP3Pd6 tetrahedra. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to one Mn(2), two equivalent Mn(1), four equivalent Pd(1), five equivalent Pd(2), and two equivalent P(1) atoms. P(1) is bonded in a 8-coordinate geometry to four equivalent Pd(1) and four equivalent Pd(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3(P3Pd10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.556
_cell_length_b   8.556
_cell_length_c   8.556
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   442.828
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.250  0.250  0.250  1.0
  Mn  Mn1  1  0.750  0.750  0.750  1.0
  Mn  Mn2  1  0.000  0.000  0.000  1.0
  P  P3  1  0.734  0.734  0.266  1.0
  P  P4  1  0.266  0.266  0.734  1.0
  P  P5  1  0.266  0.734  0.734  1.0
  P  P6  1  0.734  0.266  0.734  1.0
  P  P7  1  0.266  0.734  0.266  1.0
  P  P8  1  0.734  0.266  0.266  1.0
  Pd  Pd9  1  0.619  0.619  0.619  1.0
  Pd  Pd10  1  0.381  0.856  0.381  1.0
  Pd  Pd11  1  0.658  0.342  0.000  1.0
  Pd  Pd12  1  0.000  0.342  0.658  1.0
  Pd  Pd13  1  0.658  0.000  0.000  1.0
  Pd  Pd14  1  0.619  0.619  0.144  1.0
  Pd  Pd15  1  0.000  0.000  0.658  1.0
  Pd  Pd16  1  0.000  0.342  0.000  1.0
  Pd  Pd17  1  0.658  0.000  0.342  1.0
  Pd  Pd18  1  0.342  0.000  0.000  1.0
  Pd  Pd19  1  0.000  0.658  0.000  1.0
  Pd  Pd20  1  0.342  0.000  0.658  1.0
  Pd  Pd21  1  0.000  0.658  0.342  1.0
  Pd  Pd22  1  0.342  0.658  0.000  1.0
  Pd  Pd23  1  0.144  0.619  0.619  1.0
  Pd  Pd24  1  0.381  0.381  0.381  1.0
  Pd  Pd25  1  0.856  0.381  0.381  1.0
  Pd  Pd26  1  0.381  0.381  0.856  1.0
  Pd  Pd27  1  0.619  0.144  0.619  1.0
  Pd  Pd28  1  0.000  0.000  0.342  1.0
[/CIF]
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