The compound described by PbBiF5 crystallizes in the triclinic P1 space group. Pb(1) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(5), and three equivalent F(3) atoms. Bi(1) is bonded in a distorted pentagonal planar geometry to one F(1), one F(2), one F(5), and two equivalent F(4) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Pb(1) and one Bi(1) atom. In the second F site, F(2) is bonded in a water-like geometry to one Pb(1) and one Bi(1) atom. In the third F site, F(3) is bonded in a distorted bent 120 degrees geometry to three equivalent Pb(1) atoms. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to two equivalent Bi(1) atoms. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Pb(1) and one Bi(1) atom. is represented by the CIF file [CIF]
data_BiPbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.248
_cell_length_b   4.341
_cell_length_c   7.255
_cell_angle_alpha   90.300
_cell_angle_beta   106.056
_cell_angle_gamma   118.475
_symmetry_Int_Tables_number   1
_cell_volume   111.522
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.881  0.904  0.960  1.0
  Pb  Pb1  1  0.965  0.530  0.445  1.0
  F  F2  1  0.792  0.870  0.632  1.0
  F  F3  1  0.582  0.740  0.181  1.0
  F  F4  1  0.301  0.145  0.373  1.0
  F  F5  1  0.703  0.316  0.975  1.0
  F  F6  1  0.272  0.620  0.809  1.0
[/CIF]
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The compound described by PbBiF5 crystallizes in the triclinic P1 space group. Pb(1) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(5), and three equivalent F(3) atoms. Bi(1) is bonded in a distorted pentagonal planar geometry to one F(1), one F(2), one F(5), and two equivalent F(4) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Pb(1) and one Bi(1) atom. In the second F site, F(2) is bonded in a water-like geometry to one Pb(1) and one Bi(1) atom. In the third F site, F(3) is bonded in a distorted bent 120 degrees geometry to three equivalent Pb(1) atoms. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to two equivalent Bi(1) atoms. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Pb(1) and one Bi(1) atom. is represented by the CIF file [CIF]
data_BiPbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.248
_cell_length_b   4.341
_cell_length_c   7.255
_cell_angle_alpha   90.300
_cell_angle_beta   106.056
_cell_angle_gamma   118.475
_symmetry_Int_Tables_number   1
_cell_volume   111.522
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.881  0.904  0.960  1.0
  Pb  Pb1  1  0.965  0.530  0.445  1.0
  F  F2  1  0.792  0.870  0.632  1.0
  F  F3  1  0.582  0.740  0.181  1.0
  F  F4  1  0.301  0.145  0.373  1.0
  F  F5  1  0.703  0.316  0.975  1.0
  F  F6  1  0.272  0.620  0.809  1.0
[/CIF]
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