The crystal structure described by UO7(SO4)2O2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, four sulfuric acid molecules, and two UO7 clusters. In each UO7 cluster, U(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(5), two equivalent O(1), and two equivalent O(10) atoms. There are five inequivalent O sites. In the first O site, O(10) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one U(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one U(1) atom. is represented by the CIF file [CIF]
data_US2O17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.501
_cell_length_b   7.278
_cell_length_c   7.615
_cell_angle_alpha   83.556
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   688.423
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.750  0.323  0.693  1.0
  U  U1  1  0.250  0.677  0.307  1.0
  S  S2  1  0.519  0.885  0.769  1.0
  S  S3  1  0.019  0.115  0.231  1.0
  S  S4  1  0.481  0.115  0.231  1.0
  S  S5  1  0.981  0.885  0.769  1.0
  O  O6  1  0.661  0.385  0.884  1.0
  O  O7  1  0.161  0.615  0.116  1.0
  O  O8  1  0.339  0.615  0.116  1.0
  O  O9  1  0.839  0.385  0.884  1.0
  O  O10  1  0.750  0.629  0.645  1.0
  O  O11  1  0.250  0.371  0.355  1.0
  O  O12  1  0.750  0.109  0.952  1.0
  O  O13  1  0.250  0.891  0.048  1.0
  O  O14  1  0.202  0.380  0.722  1.0
  O  O15  1  0.702  0.620  0.278  1.0
  O  O16  1  0.798  0.620  0.278  1.0
  O  O17  1  0.298  0.380  0.722  1.0
  O  O18  1  0.750  0.143  0.545  1.0
  O  O19  1  0.250  0.857  0.455  1.0
  O  O20  1  0.579  0.061  0.778  1.0
  O  O21  1  0.079  0.939  0.222  1.0
  O  O22  1  0.421  0.939  0.222  1.0
  O  O23  1  0.921  0.061  0.778  1.0
  O  O24  1  0.549  0.801  0.606  1.0
  O  O25  1  0.049  0.199  0.394  1.0
  O  O26  1  0.451  0.199  0.394  1.0
  O  O27  1  0.951  0.801  0.606  1.0
  O  O28  1  0.541  0.755  0.927  1.0
  O  O29  1  0.041  0.245  0.073  1.0
  O  O30  1  0.459  0.245  0.073  1.0
  O  O31  1  0.959  0.755  0.927  1.0
  O  O32  1  0.403  0.928  0.752  1.0
  O  O33  1  0.903  0.072  0.248  1.0
  O  O34  1  0.597  0.072  0.248  1.0
  O  O35  1  0.097  0.928  0.752  1.0
  O  O36  1  0.647  0.441  0.505  1.0
  O  O37  1  0.147  0.559  0.495  1.0
  O  O38  1  0.353  0.559  0.495  1.0
  O  O39  1  0.853  0.441  0.505  1.0
[/CIF]
.
The crystal structure described by UO7(SO4)2O2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, four sulfuric acid molecules, and two UO7 clusters. In each UO7 cluster, U(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(5), two equivalent O(1), and two equivalent O(10) atoms. There are five inequivalent O sites. In the first O site, O(10) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one U(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one U(1) atom. is represented by the CIF file [CIF]
data_US2O17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.501
_cell_length_b   7.278
_cell_length_c   7.615
_cell_angle_alpha   83.556
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   688.423
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.750  0.323  0.693  1.0
  U  U1  1  0.250  0.677  0.307  1.0
  S  S2  1  0.519  0.885  0.769  1.0
  S  S3  1  0.019  0.115  0.231  1.0
  S  S4  1  0.481  0.115  0.231  1.0
  S  S5  1  0.981  0.885  0.769  1.0
  O  O6  1  0.661  0.385  0.884  1.0
  O  O7  1  0.161  0.615  0.116  1.0
  O  O8  1  0.339  0.615  0.116  1.0
  O  O9  1  0.839  0.385  0.884  1.0
  O  O10  1  0.750  0.629  0.645  1.0
  O  O11  1  0.250  0.371  0.355  1.0
  O  O12  1  0.750  0.109  0.952  1.0
  O  O13  1  0.250  0.891  0.048  1.0
  O  O14  1  0.202  0.380  0.722  1.0
  O  O15  1  0.702  0.620  0.278  1.0
  O  O16  1  0.798  0.620  0.278  1.0
  O  O17  1  0.298  0.380  0.722  1.0
  O  O18  1  0.750  0.143  0.545  1.0
  O  O19  1  0.250  0.857  0.455  1.0
  O  O20  1  0.579  0.061  0.778  1.0
  O  O21  1  0.079  0.939  0.222  1.0
  O  O22  1  0.421  0.939  0.222  1.0
  O  O23  1  0.921  0.061  0.778  1.0
  O  O24  1  0.549  0.801  0.606  1.0
  O  O25  1  0.049  0.199  0.394  1.0
  O  O26  1  0.451  0.199  0.394  1.0
  O  O27  1  0.951  0.801  0.606  1.0
  O  O28  1  0.541  0.755  0.927  1.0
  O  O29  1  0.041  0.245  0.073  1.0
  O  O30  1  0.459  0.245  0.073  1.0
  O  O31  1  0.959  0.755  0.927  1.0
  O  O32  1  0.403  0.928  0.752  1.0
  O  O33  1  0.903  0.072  0.248  1.0
  O  O34  1  0.597  0.072  0.248  1.0
  O  O35  1  0.097  0.928  0.752  1.0
  O  O36  1  0.647  0.441  0.505  1.0
  O  O37  1  0.147  0.559  0.495  1.0
  O  O38  1  0.353  0.559  0.495  1.0
  O  O39  1  0.853  0.441  0.505  1.0
[/CIF]
.