The structure described by Li5Co7O3F13 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(6) atom to form LiOF5 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(2)OF3 tetrahedra, corners with two equivalent Li(3)F4 tetrahedra, corners with two equivalent Co(1)O2F2 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Co(4)O2F4 octahedra, and edges with two equivalent Co(3)OF5 octahedra. In the second Li site, Li(2) is bonded to one O(3), one F(2), one F(7), and one F(9) atom to form LiOF3 tetrahedra that share  a cornercorner with one Li(1)OF5 octahedra,  a cornercorner with one Co(4)O2F4 octahedra,  a cornercorner with one Co(3)OF5 octahedra, corners with two equivalent Li(4)F6 octahedra, corners with two equivalent Co(6)OF5 octahedra, corners with two equivalent Co(7)OF5 octahedra, and corners with three equivalent Co(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 53-61°. In the third Li site, Li(3) is bonded to one F(11), one F(3), one F(5), and one F(6) atom to form LiF4 tetrahedra that share  a cornercorner with one Li(4)F6 octahedra,  a cornercorner with one Co(6)OF5 octahedra,  a cornercorner with one Co(7)OF5 octahedra, corners with two equivalent Li(1)OF5 octahedra, corners with two equivalent Co(4)O2F4 octahedra, corners with two equivalent Co(3)OF5 octahedra, and corners with three equivalent Co(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 55-61°. In the fourth Li site, Li(4) is bonded to one F(10), one F(11), one F(13), one F(7), one F(8), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(3)F4 tetrahedra,  a cornercorner with one Co(1)O2F2 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(2)OF3 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Co(6)OF5 octahedra, and edges with two equivalent Co(7)OF5 octahedra. In the fifth Li site, Li(5) is bonded to one F(10), one F(12), one F(13), and one F(4) atom to form LiF4 tetrahedra that share  a cornercorner with one Li(1)OF5 octahedra,  a cornercorner with one Co(4)O2F4 octahedra,  a cornercorner with one Co(3)OF5 octahedra, corners with two equivalent Li(4)F6 octahedra, corners with two equivalent Co(6)OF5 octahedra, corners with two equivalent Co(7)OF5 octahedra, and corners with three equivalent Co(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 55-61°. There are seven inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one F(1), and one F(8) atom to form CoO2F2 tetrahedra that share  a cornercorner with one Li(4)F6 octahedra,  a cornercorner with one Co(6)OF5 octahedra,  a cornercorner with one Co(7)OF5 octahedra, corners with two equivalent Li(1)OF5 octahedra, corners with two equivalent Co(4)O2F4 octahedra, corners with two equivalent Co(3)OF5 octahedra, and corners with three equivalent Co(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 50-63°. In the second Co site, Co(2) is bonded to one O(1), one O(2), one F(1), one F(10), one F(12), and one F(13) atom to form CoO2F4 octahedra that share corners with three equivalent Li(5)F4 tetrahedra, corners with three equivalent Co(1)O2F2 tetrahedra,  an edgeedge with one Li(4)F6 octahedra,  an edgeedge with one Li(1)OF5 octahedra,  an edgeedge with one Co(4)O2F4 octahedra,  an edgeedge with one Co(3)OF5 octahedra,  an edgeedge with one Co(6)OF5 octahedra, and  an edgeedge with one Co(7)OF5 octahedra. In the third Co site, Co(3) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form CoOF5 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(2)OF3 tetrahedra, corners with two equivalent Li(3)F4 tetrahedra, corners with two equivalent Co(1)O2F2 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Li(1)OF5 octahedra, and edges with two equivalent Co(4)O2F4 octahedra. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one F(2), one F(4), one F(5), and one F(6) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(2)OF3 tetrahedra, corners with two equivalent Li(3)F4 tetrahedra, corners with two equivalent Co(1)O2F2 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Li(1)OF5 octahedra, and edges with two equivalent Co(3)OF5 octahedra. In the fifth Co site, Co(5) is bonded to one O(3), one F(3), one F(5), one F(6), one F(7), and one F(9) atom to form CoOF5 octahedra that share corners with three equivalent Li(3)F4 tetrahedra, corners with three equivalent Li(2)OF3 tetrahedra,  an edgeedge with one Li(4)F6 octahedra,  an edgeedge with one Li(1)OF5 octahedra,  an edgeedge with one Co(4)O2F4 octahedra,  an edgeedge with one Co(3)OF5 octahedra,  an edgeedge with one Co(6)OF5 octahedra, and  an edgeedge with one Co(7)OF5 octahedra. In the sixth Co site, Co(6) is bonded to one O(3), one F(10), one F(11), one F(12), one F(8), and one F(9) atom to form CoOF5 octahedra that share  a cornercorner with one Li(3)F4 tetrahedra,  a cornercorner with one Co(1)O2F2 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(2)OF3 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Li(4)F6 octahedra, and edges with two equivalent Co(7)OF5 octahedra. In the seventh Co site, Co(7) is bonded to one O(3), one F(11), one F(12), one F(13), one F(7), and one F(8) atom to form CoOF5 octahedra that share  a cornercorner with one Li(3)F4 tetrahedra,  a cornercorner with one Co(1)O2F2 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(2)OF3 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Li(4)F6 octahedra, and edges with two equivalent Co(6)OF5 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(3), and one Co(4) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), one Co(2), and one Co(4) atom. In the third O site, O(3) is bonded to one Li(2), one Co(5), one Co(6), and one Co(7) atom to form distorted OLiCo3 tetrahedra that share  a cornercorner with one F(13)Li2Co2 trigonal pyramid,  a cornercorner with one F(6)Li2Co2 trigonal pyramid, and corners with two equivalent F(12)LiCo3 trigonal pyramids. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), one Co(2), and one Co(3) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Co(3), and one Co(4) atom. In the third F site, F(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Co(3), and one Co(5) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(5), one Co(3), and one Co(4) atom to form distorted FLi2Co2 trigonal pyramids that share  a cornercorner with one F(13)Li2Co2 trigonal pyramid,  a cornercorner with one F(12)LiCo3 trigonal pyramid, and  an edgeedge with one F(6)Li2Co2 trigonal pyramid. In the fifth F site, F(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(3), one Co(4), and one Co(5) atom. In the sixth F site, F(6) is bonded to one Li(1), one Li(3), one Co(4), and one Co(5) atom to form distorted FLi2Co2 trigonal pyramids that share  a cornercorner with one O(3)LiCo3 tetrahedra and  an edgeedge with one F(4)Li2Co2 trigonal pyramid. In the seventh F site, F(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Co(5), and one Co(7) atom. In the eighth F site, F(8) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(1), one Co(6), and one Co(7) atom. In the ninth F site, F(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Co(5), and one Co(6) atom. In the tenth F site, F(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(5), one Co(2), and one Co(6) atom. In the eleventh F site, F(11) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one Co(6), and one Co(7) atom. In the twelfth F site, F(12) is bonded to one Li(5), one Co(2), one Co(6), and one Co(7) atom to form distorted FLiCo3 trigonal pyramids that share corners with two equivalent O(3)LiCo3 tetrahedra,  a cornercorner with one F(13)Li2Co2 trigonal pyramid,  a cornercorner with one F(4)Li2Co2 trigonal pyramid, and  an edgeedge with one F(13)Li2Co2 trigonal pyramid. In the thirteenth F site, F(13) is bonded to one Li(4), one Li(5), one Co(2), and one Co(7) atom to form distorted FLi2Co2 trigonal pyramids that share  a cornercorner with one O(3)LiCo3 tetrahedra,  a cornercorner with one F(4)Li2Co2 trigonal pyramid,  a cornercorner with one F(12)LiCo3 trigonal pyramid, and  an edgeedge with one F(12)LiCo3 trigonal pyramid. is represented by the CIF card [CIF]
data_Li5Co7O3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.038
_cell_length_b   6.091
_cell_length_c   10.582
_cell_angle_alpha   73.373
_cell_angle_beta   73.478
_cell_angle_gamma   60.480
_symmetry_Int_Tables_number   1
_cell_volume   319.700
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.754  0.735  0.750  1.0
  Li  Li1  1  0.195  0.698  0.435  1.0
  Li  Li2  1  0.805  0.306  0.564  1.0
  Li  Li3  1  0.755  0.250  0.253  1.0
  Li  Li4  1  0.316  0.805  0.065  1.0
  Co  Co5  1  0.680  0.222  0.926  1.0
  Co  Co6  1  0.003  0.484  0.992  1.0
  Co  Co7  1  0.259  0.734  0.752  1.0
  Co  Co8  1  0.238  0.258  0.760  1.0
  Co  Co9  1  0.500  0.995  0.495  1.0
  Co  Co10  1  0.253  0.232  0.258  1.0
  Co  Co11  1  0.736  0.750  0.258  1.0
  O  O12  1  0.349  0.399  0.870  1.0
  O  O13  1  0.891  0.390  0.868  1.0
  O  O14  1  0.397  0.895  0.369  1.0
  F  F15  1  0.878  0.870  0.869  1.0
  F  F16  1  0.117  0.634  0.632  1.0
  F  F17  1  0.620  0.640  0.625  1.0
  F  F18  1  0.380  0.875  0.864  1.0
  F  F19  1  0.138  0.106  0.632  1.0
  F  F20  1  0.598  0.118  0.626  1.0
  F  F21  1  0.865  0.891  0.368  1.0
  F  F22  1  0.628  0.127  0.132  1.0
  F  F23  1  0.390  0.362  0.370  1.0
  F  F24  1  0.119  0.134  0.132  1.0
  F  F25  1  0.880  0.377  0.370  1.0
  F  F26  1  0.107  0.605  0.135  1.0
  F  F27  1  0.648  0.610  0.129  1.0
[/CIF]
.
The structure described by Li5Co7O3F13 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(6) atom to form LiOF5 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(2)OF3 tetrahedra, corners with two equivalent Li(3)F4 tetrahedra, corners with two equivalent Co(1)O2F2 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Co(4)O2F4 octahedra, and edges with two equivalent Co(3)OF5 octahedra. In the second Li site, Li(2) is bonded to one O(3), one F(2), one F(7), and one F(9) atom to form LiOF3 tetrahedra that share  a cornercorner with one Li(1)OF5 octahedra,  a cornercorner with one Co(4)O2F4 octahedra,  a cornercorner with one Co(3)OF5 octahedra, corners with two equivalent Li(4)F6 octahedra, corners with two equivalent Co(6)OF5 octahedra, corners with two equivalent Co(7)OF5 octahedra, and corners with three equivalent Co(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 53-61°. In the third Li site, Li(3) is bonded to one F(11), one F(3), one F(5), and one F(6) atom to form LiF4 tetrahedra that share  a cornercorner with one Li(4)F6 octahedra,  a cornercorner with one Co(6)OF5 octahedra,  a cornercorner with one Co(7)OF5 octahedra, corners with two equivalent Li(1)OF5 octahedra, corners with two equivalent Co(4)O2F4 octahedra, corners with two equivalent Co(3)OF5 octahedra, and corners with three equivalent Co(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 55-61°. In the fourth Li site, Li(4) is bonded to one F(10), one F(11), one F(13), one F(7), one F(8), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(3)F4 tetrahedra,  a cornercorner with one Co(1)O2F2 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(2)OF3 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Co(6)OF5 octahedra, and edges with two equivalent Co(7)OF5 octahedra. In the fifth Li site, Li(5) is bonded to one F(10), one F(12), one F(13), and one F(4) atom to form LiF4 tetrahedra that share  a cornercorner with one Li(1)OF5 octahedra,  a cornercorner with one Co(4)O2F4 octahedra,  a cornercorner with one Co(3)OF5 octahedra, corners with two equivalent Li(4)F6 octahedra, corners with two equivalent Co(6)OF5 octahedra, corners with two equivalent Co(7)OF5 octahedra, and corners with three equivalent Co(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 55-61°. There are seven inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one F(1), and one F(8) atom to form CoO2F2 tetrahedra that share  a cornercorner with one Li(4)F6 octahedra,  a cornercorner with one Co(6)OF5 octahedra,  a cornercorner with one Co(7)OF5 octahedra, corners with two equivalent Li(1)OF5 octahedra, corners with two equivalent Co(4)O2F4 octahedra, corners with two equivalent Co(3)OF5 octahedra, and corners with three equivalent Co(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 50-63°. In the second Co site, Co(2) is bonded to one O(1), one O(2), one F(1), one F(10), one F(12), and one F(13) atom to form CoO2F4 octahedra that share corners with three equivalent Li(5)F4 tetrahedra, corners with three equivalent Co(1)O2F2 tetrahedra,  an edgeedge with one Li(4)F6 octahedra,  an edgeedge with one Li(1)OF5 octahedra,  an edgeedge with one Co(4)O2F4 octahedra,  an edgeedge with one Co(3)OF5 octahedra,  an edgeedge with one Co(6)OF5 octahedra, and  an edgeedge with one Co(7)OF5 octahedra. In the third Co site, Co(3) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form CoOF5 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(2)OF3 tetrahedra, corners with two equivalent Li(3)F4 tetrahedra, corners with two equivalent Co(1)O2F2 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Li(1)OF5 octahedra, and edges with two equivalent Co(4)O2F4 octahedra. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one F(2), one F(4), one F(5), and one F(6) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(2)OF3 tetrahedra, corners with two equivalent Li(3)F4 tetrahedra, corners with two equivalent Co(1)O2F2 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Li(1)OF5 octahedra, and edges with two equivalent Co(3)OF5 octahedra. In the fifth Co site, Co(5) is bonded to one O(3), one F(3), one F(5), one F(6), one F(7), and one F(9) atom to form CoOF5 octahedra that share corners with three equivalent Li(3)F4 tetrahedra, corners with three equivalent Li(2)OF3 tetrahedra,  an edgeedge with one Li(4)F6 octahedra,  an edgeedge with one Li(1)OF5 octahedra,  an edgeedge with one Co(4)O2F4 octahedra,  an edgeedge with one Co(3)OF5 octahedra,  an edgeedge with one Co(6)OF5 octahedra, and  an edgeedge with one Co(7)OF5 octahedra. In the sixth Co site, Co(6) is bonded to one O(3), one F(10), one F(11), one F(12), one F(8), and one F(9) atom to form CoOF5 octahedra that share  a cornercorner with one Li(3)F4 tetrahedra,  a cornercorner with one Co(1)O2F2 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(2)OF3 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Li(4)F6 octahedra, and edges with two equivalent Co(7)OF5 octahedra. In the seventh Co site, Co(7) is bonded to one O(3), one F(11), one F(12), one F(13), one F(7), and one F(8) atom to form CoOF5 octahedra that share  a cornercorner with one Li(3)F4 tetrahedra,  a cornercorner with one Co(1)O2F2 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(2)OF3 tetrahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(5)OF5 octahedra, edges with two equivalent Li(4)F6 octahedra, and edges with two equivalent Co(6)OF5 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(3), and one Co(4) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), one Co(2), and one Co(4) atom. In the third O site, O(3) is bonded to one Li(2), one Co(5), one Co(6), and one Co(7) atom to form distorted OLiCo3 tetrahedra that share  a cornercorner with one F(13)Li2Co2 trigonal pyramid,  a cornercorner with one F(6)Li2Co2 trigonal pyramid, and corners with two equivalent F(12)LiCo3 trigonal pyramids. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), one Co(2), and one Co(3) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Co(3), and one Co(4) atom. In the third F site, F(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Co(3), and one Co(5) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(5), one Co(3), and one Co(4) atom to form distorted FLi2Co2 trigonal pyramids that share  a cornercorner with one F(13)Li2Co2 trigonal pyramid,  a cornercorner with one F(12)LiCo3 trigonal pyramid, and  an edgeedge with one F(6)Li2Co2 trigonal pyramid. In the fifth F site, F(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(3), one Co(4), and one Co(5) atom. In the sixth F site, F(6) is bonded to one Li(1), one Li(3), one Co(4), and one Co(5) atom to form distorted FLi2Co2 trigonal pyramids that share  a cornercorner with one O(3)LiCo3 tetrahedra and  an edgeedge with one F(4)Li2Co2 trigonal pyramid. In the seventh F site, F(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Co(5), and one Co(7) atom. In the eighth F site, F(8) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(1), one Co(6), and one Co(7) atom. In the ninth F site, F(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Co(5), and one Co(6) atom. In the tenth F site, F(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(5), one Co(2), and one Co(6) atom. In the eleventh F site, F(11) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one Co(6), and one Co(7) atom. In the twelfth F site, F(12) is bonded to one Li(5), one Co(2), one Co(6), and one Co(7) atom to form distorted FLiCo3 trigonal pyramids that share corners with two equivalent O(3)LiCo3 tetrahedra,  a cornercorner with one F(13)Li2Co2 trigonal pyramid,  a cornercorner with one F(4)Li2Co2 trigonal pyramid, and  an edgeedge with one F(13)Li2Co2 trigonal pyramid. In the thirteenth F site, F(13) is bonded to one Li(4), one Li(5), one Co(2), and one Co(7) atom to form distorted FLi2Co2 trigonal pyramids that share  a cornercorner with one O(3)LiCo3 tetrahedra,  a cornercorner with one F(4)Li2Co2 trigonal pyramid,  a cornercorner with one F(12)LiCo3 trigonal pyramid, and  an edgeedge with one F(12)LiCo3 trigonal pyramid. is represented by the CIF card [CIF]
data_Li5Co7O3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.038
_cell_length_b   6.091
_cell_length_c   10.582
_cell_angle_alpha   73.373
_cell_angle_beta   73.478
_cell_angle_gamma   60.480
_symmetry_Int_Tables_number   1
_cell_volume   319.700
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.754  0.735  0.750  1.0
  Li  Li1  1  0.195  0.698  0.435  1.0
  Li  Li2  1  0.805  0.306  0.564  1.0
  Li  Li3  1  0.755  0.250  0.253  1.0
  Li  Li4  1  0.316  0.805  0.065  1.0
  Co  Co5  1  0.680  0.222  0.926  1.0
  Co  Co6  1  0.003  0.484  0.992  1.0
  Co  Co7  1  0.259  0.734  0.752  1.0
  Co  Co8  1  0.238  0.258  0.760  1.0
  Co  Co9  1  0.500  0.995  0.495  1.0
  Co  Co10  1  0.253  0.232  0.258  1.0
  Co  Co11  1  0.736  0.750  0.258  1.0
  O  O12  1  0.349  0.399  0.870  1.0
  O  O13  1  0.891  0.390  0.868  1.0
  O  O14  1  0.397  0.895  0.369  1.0
  F  F15  1  0.878  0.870  0.869  1.0
  F  F16  1  0.117  0.634  0.632  1.0
  F  F17  1  0.620  0.640  0.625  1.0
  F  F18  1  0.380  0.875  0.864  1.0
  F  F19  1  0.138  0.106  0.632  1.0
  F  F20  1  0.598  0.118  0.626  1.0
  F  F21  1  0.865  0.891  0.368  1.0
  F  F22  1  0.628  0.127  0.132  1.0
  F  F23  1  0.390  0.362  0.370  1.0
  F  F24  1  0.119  0.134  0.132  1.0
  F  F25  1  0.880  0.377  0.370  1.0
  F  F26  1  0.107  0.605  0.135  1.0
  F  F27  1  0.648  0.610  0.129  1.0
[/CIF]
.