The structure described by SbCl6N2Se3Cl is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two N2Se3Cl clusters and two SbCl6 clusters. In each N2Se3Cl cluster, there are two inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(6) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(3) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one N(2) and one N(3) atom. In the second Se site, Se(3) is bonded in a single-bond geometry to one N(3) atom. In the third Se site, Se(6) is bonded in a distorted water-like geometry to one N(2) and one Cl(13) atom. Cl(13) is bonded in a single-bond geometry to one Se(6) atom. In one of the SbCl6 clusters, Sb(1) is bonded in an octahedral geometry to one Cl(10), one Cl(12), one Cl(2), one Cl(5), one Cl(6), and one Cl(9) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(10) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(12) is bonded in a single-bond geometry to one Sb(1) atom. In one of the SbCl6 clusters, Sb(2) is bonded in an octahedral geometry to one Cl(1), one Cl(11), one Cl(14), one Cl(3), one Cl(4), and one Cl(7) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth Cl site, Cl(11) is bonded in a single-bond geometry to one Sb(2) atom. In the sixth Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbSe3N2Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.335
_cell_length_b   7.371
_cell_length_c   15.770
_cell_angle_alpha   89.841
_cell_angle_beta   94.275
_cell_angle_gamma   112.051
_symmetry_Int_Tables_number   1
_cell_volume   787.760
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.011  0.877  0.501  1.0
  Sb  Sb1  1  0.999  0.997  0.000  1.0
  Se  Se2  1  0.671  0.195  0.665  1.0
  Se  Se3  1  0.608  0.645  0.260  1.0
  Se  Se4  1  0.901  0.498  0.806  1.0
  Se  Se5  1  0.181  0.563  0.191  1.0
  Se  Se6  1  0.358  0.477  0.362  1.0
  Se  Se7  1  0.541  0.327  0.828  1.0
  N  N8  1  0.442  0.690  0.187  1.0
  N  N9  1  0.497  0.159  0.744  1.0
  N  N10  1  0.886  0.378  0.710  1.0
  N  N11  1  0.157  0.460  0.292  1.0
  Cl  Cl12  1  0.737  0.676  0.994  1.0
  Cl  Cl13  1  0.822  0.544  0.445  1.0
  Cl  Cl14  1  0.969  0.011  0.847  1.0
  Cl  Cl15  1  0.262  0.316  0.007  1.0
  Cl  Cl16  1  0.249  0.765  0.572  1.0
  Cl  Cl17  1  0.191  0.206  0.554  1.0
  Cl  Cl18  1  0.033  0.980  0.154  1.0
  Cl  Cl19  1  0.652  0.371  0.212  1.0
  Cl  Cl20  1  0.196  0.943  0.376  1.0
  Cl  Cl21  1  0.770  0.985  0.428  1.0
  Cl  Cl22  1  0.233  0.842  0.989  1.0
  Cl  Cl23  1  0.818  0.804  0.623  1.0
  Cl  Cl24  1  0.430  0.563  0.779  1.0
  Cl  Cl25  1  0.766  0.151  0.012  1.0
[/CIF]
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The structure described by SbCl6N2Se3Cl is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two N2Se3Cl clusters and two SbCl6 clusters. In each N2Se3Cl cluster, there are two inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(6) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(3) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one N(2) and one N(3) atom. In the second Se site, Se(3) is bonded in a single-bond geometry to one N(3) atom. In the third Se site, Se(6) is bonded in a distorted water-like geometry to one N(2) and one Cl(13) atom. Cl(13) is bonded in a single-bond geometry to one Se(6) atom. In one of the SbCl6 clusters, Sb(1) is bonded in an octahedral geometry to one Cl(10), one Cl(12), one Cl(2), one Cl(5), one Cl(6), and one Cl(9) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(10) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(12) is bonded in a single-bond geometry to one Sb(1) atom. In one of the SbCl6 clusters, Sb(2) is bonded in an octahedral geometry to one Cl(1), one Cl(11), one Cl(14), one Cl(3), one Cl(4), and one Cl(7) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth Cl site, Cl(11) is bonded in a single-bond geometry to one Sb(2) atom. In the sixth Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbSe3N2Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.335
_cell_length_b   7.371
_cell_length_c   15.770
_cell_angle_alpha   89.841
_cell_angle_beta   94.275
_cell_angle_gamma   112.051
_symmetry_Int_Tables_number   1
_cell_volume   787.760
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.011  0.877  0.501  1.0
  Sb  Sb1  1  0.999  0.997  0.000  1.0
  Se  Se2  1  0.671  0.195  0.665  1.0
  Se  Se3  1  0.608  0.645  0.260  1.0
  Se  Se4  1  0.901  0.498  0.806  1.0
  Se  Se5  1  0.181  0.563  0.191  1.0
  Se  Se6  1  0.358  0.477  0.362  1.0
  Se  Se7  1  0.541  0.327  0.828  1.0
  N  N8  1  0.442  0.690  0.187  1.0
  N  N9  1  0.497  0.159  0.744  1.0
  N  N10  1  0.886  0.378  0.710  1.0
  N  N11  1  0.157  0.460  0.292  1.0
  Cl  Cl12  1  0.737  0.676  0.994  1.0
  Cl  Cl13  1  0.822  0.544  0.445  1.0
  Cl  Cl14  1  0.969  0.011  0.847  1.0
  Cl  Cl15  1  0.262  0.316  0.007  1.0
  Cl  Cl16  1  0.249  0.765  0.572  1.0
  Cl  Cl17  1  0.191  0.206  0.554  1.0
  Cl  Cl18  1  0.033  0.980  0.154  1.0
  Cl  Cl19  1  0.652  0.371  0.212  1.0
  Cl  Cl20  1  0.196  0.943  0.376  1.0
  Cl  Cl21  1  0.770  0.985  0.428  1.0
  Cl  Cl22  1  0.233  0.842  0.989  1.0
  Cl  Cl23  1  0.818  0.804  0.623  1.0
  Cl  Cl24  1  0.430  0.563  0.779  1.0
  Cl  Cl25  1  0.766  0.151  0.012  1.0
[/CIF]
.