The compound described by Rb2PSO8 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(2) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(7) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Rb(1), one Rb(2), and one S(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one S(1) atom. is represented by the CIF card [CIF]
data_Rb2PSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.562
_cell_length_b   7.643
_cell_length_c   8.036
_cell_angle_alpha   89.938
_cell_angle_beta   90.482
_cell_angle_gamma   99.396
_symmetry_Int_Tables_number   1
_cell_volume   458.178
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.599  0.233  0.684  1.0
  Rb  Rb1  1  0.899  0.265  0.181  1.0
  Rb  Rb2  1  0.401  0.767  0.316  1.0
  Rb  Rb3  1  0.101  0.735  0.819  1.0
  P  P4  1  0.103  0.253  0.687  1.0
  P  P5  1  0.897  0.747  0.313  1.0
  S  S6  1  0.395  0.244  0.184  1.0
  S  S7  1  0.605  0.756  0.816  1.0
  O  O8  1  0.994  0.329  0.821  1.0
  O  O9  1  0.502  0.172  0.316  1.0
  O  O10  1  0.006  0.671  0.179  1.0
  O  O11  1  0.498  0.828  0.684  1.0
  O  O12  1  0.977  0.175  0.544  1.0
  O  O13  1  0.518  0.326  0.050  1.0
  O  O14  1  0.023  0.825  0.456  1.0
  O  O15  1  0.482  0.674  0.950  1.0
  O  O16  1  0.239  0.402  0.605  1.0
  O  O17  1  0.263  0.097  0.114  1.0
  O  O18  1  0.761  0.598  0.395  1.0
  O  O19  1  0.737  0.903  0.886  1.0
  O  O20  1  0.206  0.114  0.763  1.0
  O  O21  1  0.303  0.386  0.252  1.0
  O  O22  1  0.794  0.886  0.237  1.0
  O  O23  1  0.697  0.614  0.748  1.0
[/CIF]
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The compound described by Rb2PSO8 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(2) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(7) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Rb(1), one Rb(2), and one S(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one S(1) atom. is represented by the CIF card [CIF]
data_Rb2PSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.562
_cell_length_b   7.643
_cell_length_c   8.036
_cell_angle_alpha   89.938
_cell_angle_beta   90.482
_cell_angle_gamma   99.396
_symmetry_Int_Tables_number   1
_cell_volume   458.178
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.599  0.233  0.684  1.0
  Rb  Rb1  1  0.899  0.265  0.181  1.0
  Rb  Rb2  1  0.401  0.767  0.316  1.0
  Rb  Rb3  1  0.101  0.735  0.819  1.0
  P  P4  1  0.103  0.253  0.687  1.0
  P  P5  1  0.897  0.747  0.313  1.0
  S  S6  1  0.395  0.244  0.184  1.0
  S  S7  1  0.605  0.756  0.816  1.0
  O  O8  1  0.994  0.329  0.821  1.0
  O  O9  1  0.502  0.172  0.316  1.0
  O  O10  1  0.006  0.671  0.179  1.0
  O  O11  1  0.498  0.828  0.684  1.0
  O  O12  1  0.977  0.175  0.544  1.0
  O  O13  1  0.518  0.326  0.050  1.0
  O  O14  1  0.023  0.825  0.456  1.0
  O  O15  1  0.482  0.674  0.950  1.0
  O  O16  1  0.239  0.402  0.605  1.0
  O  O17  1  0.263  0.097  0.114  1.0
  O  O18  1  0.761  0.598  0.395  1.0
  O  O19  1  0.737  0.903  0.886  1.0
  O  O20  1  0.206  0.114  0.763  1.0
  O  O21  1  0.303  0.386  0.252  1.0
  O  O22  1  0.794  0.886  0.237  1.0
  O  O23  1  0.697  0.614  0.748  1.0
[/CIF]
.