The material structure described by H2NCNHSO2H is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two carbamothioyl(diaminomethylidene)ammonium molecules and one HSO4 cluster. In the HSO4 cluster, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. S(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one H(1) and one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one H(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF file [CIF]
data_H4CS(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.951
_cell_length_b   8.123
_cell_length_c   8.395
_cell_angle_alpha   118.036
_cell_angle_beta   114.025
_cell_angle_gamma   87.788
_symmetry_Int_Tables_number   1
_cell_volume   429.209
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.540  0.845  0.370  1.0
  H  H1  1  0.460  0.155  0.630  1.0
  H  H2  1  0.037  0.807  0.772  1.0
  H  H3  1  0.963  0.193  0.228  1.0
  H  H4  1  0.222  0.960  0.745  1.0
  H  H5  1  0.778  0.040  0.255  1.0
  H  H6  1  0.446  0.907  0.771  1.0
  H  H7  1  0.554  0.093  0.229  1.0
  H  H8  1  0.777  0.453  0.743  1.0
  H  H9  1  0.223  0.547  0.257  1.0
  H  H10  1  0.787  0.675  0.754  1.0
  H  H11  1  0.213  0.325  0.246  1.0
  H  H12  1  0.240  0.418  0.783  1.0
  H  H13  1  0.760  0.582  0.217  1.0
  H  H14  1  0.040  0.296  0.760  1.0
  H  H15  1  0.960  0.704  0.240  1.0
  C  C16  1  0.290  0.731  0.790  1.0
  C  C17  1  0.710  0.269  0.210  1.0
  C  C18  1  0.022  0.554  0.768  1.0
  C  C19  1  0.978  0.446  0.232  1.0
  S  S20  1  0.455  0.603  0.833  1.0
  S  S21  1  0.545  0.397  0.167  1.0
  S  S22  1  0.766  0.014  0.669  1.0
  S  S23  1  0.234  0.986  0.331  1.0
  N  N24  1  0.112  0.702  0.777  1.0
  N  N25  1  0.888  0.298  0.223  1.0
  N  N26  1  0.321  0.879  0.768  1.0
  N  N27  1  0.679  0.121  0.232  1.0
  N  N28  1  0.850  0.563  0.755  1.0
  N  N29  1  0.150  0.437  0.245  1.0
  N  N30  1  0.104  0.410  0.769  1.0
  N  N31  1  0.896  0.590  0.231  1.0
  O  O32  1  0.689  0.191  0.709  1.0
  O  O33  1  0.311  0.809  0.291  1.0
  O  O34  1  0.968  0.048  0.733  1.0
  O  O35  1  0.032  0.952  0.267  1.0
  O  O36  1  0.682  0.884  0.430  1.0
  O  O37  1  0.318  0.116  0.570  1.0
  O  O38  1  0.709  0.909  0.746  1.0
  O  O39  1  0.291  0.091  0.254  1.0
[/CIF]
.
The material structure described by H2NCNHSO2H is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two carbamothioyl(diaminomethylidene)ammonium molecules and one HSO4 cluster. In the HSO4 cluster, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. S(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one H(1) and one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one H(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF file [CIF]
data_H4CS(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.951
_cell_length_b   8.123
_cell_length_c   8.395
_cell_angle_alpha   118.036
_cell_angle_beta   114.025
_cell_angle_gamma   87.788
_symmetry_Int_Tables_number   1
_cell_volume   429.209
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.540  0.845  0.370  1.0
  H  H1  1  0.460  0.155  0.630  1.0
  H  H2  1  0.037  0.807  0.772  1.0
  H  H3  1  0.963  0.193  0.228  1.0
  H  H4  1  0.222  0.960  0.745  1.0
  H  H5  1  0.778  0.040  0.255  1.0
  H  H6  1  0.446  0.907  0.771  1.0
  H  H7  1  0.554  0.093  0.229  1.0
  H  H8  1  0.777  0.453  0.743  1.0
  H  H9  1  0.223  0.547  0.257  1.0
  H  H10  1  0.787  0.675  0.754  1.0
  H  H11  1  0.213  0.325  0.246  1.0
  H  H12  1  0.240  0.418  0.783  1.0
  H  H13  1  0.760  0.582  0.217  1.0
  H  H14  1  0.040  0.296  0.760  1.0
  H  H15  1  0.960  0.704  0.240  1.0
  C  C16  1  0.290  0.731  0.790  1.0
  C  C17  1  0.710  0.269  0.210  1.0
  C  C18  1  0.022  0.554  0.768  1.0
  C  C19  1  0.978  0.446  0.232  1.0
  S  S20  1  0.455  0.603  0.833  1.0
  S  S21  1  0.545  0.397  0.167  1.0
  S  S22  1  0.766  0.014  0.669  1.0
  S  S23  1  0.234  0.986  0.331  1.0
  N  N24  1  0.112  0.702  0.777  1.0
  N  N25  1  0.888  0.298  0.223  1.0
  N  N26  1  0.321  0.879  0.768  1.0
  N  N27  1  0.679  0.121  0.232  1.0
  N  N28  1  0.850  0.563  0.755  1.0
  N  N29  1  0.150  0.437  0.245  1.0
  N  N30  1  0.104  0.410  0.769  1.0
  N  N31  1  0.896  0.590  0.231  1.0
  O  O32  1  0.689  0.191  0.709  1.0
  O  O33  1  0.311  0.809  0.291  1.0
  O  O34  1  0.968  0.048  0.733  1.0
  O  O35  1  0.032  0.952  0.267  1.0
  O  O36  1  0.682  0.884  0.430  1.0
  O  O37  1  0.318  0.116  0.570  1.0
  O  O38  1  0.709  0.909  0.746  1.0
  O  O39  1  0.291  0.091  0.254  1.0
[/CIF]
.