The compound described by LiZn(SbO2)4 crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted trigonal planar geometry to one O(3), one O(6), and one O(7) atom. Zn(1) is bonded to one O(4), one O(7), one O(8), and two equivalent O(6) atoms to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one Sb(1)O5 square pyramid, corners with two equivalent Zn(1)O5 trigonal bipyramids, edges with two equivalent Sb(3)O6 octahedra, and  an edgeedge with one Sb(1)O5 square pyramid. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(7), two equivalent O(4), and two equivalent O(5) atoms to form distorted SbO5 square pyramids that share  a cornercorner with one Zn(1)O5 trigonal bipyramid, edges with two equivalent Sb(1)O5 square pyramids, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to one O(4), one O(8), and two equivalent O(3) atoms. In the third Sb site, Sb(3) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(8) atoms to form SbO6 octahedra that share edges with two equivalent Sb(3)O6 octahedra and edges with two equivalent Zn(1)O5 trigonal bipyramids. In the fourth Sb site, Sb(4) is bonded in a 4-coordinate geometry to one O(2), one O(5), and two equivalent O(1) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Sb(3) and two equivalent Sb(4) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Sb(4) and two equivalent Sb(3) atoms. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Li(1) and two equivalent Sb(2) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Zn(1), one Sb(2), and two equivalent Sb(1) atoms. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Sb(4) and two equivalent Sb(1) atoms. In the sixth O site, O(6) is bonded in a see-saw-like geometry to one Li(1), two equivalent Zn(1), and one Sb(3) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Li(1), one Zn(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Zn(1), one Sb(2), and two equivalent Sb(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiZn(SbO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.442
_cell_length_b   8.971
_cell_length_c   11.720
_cell_angle_alpha   55.283
_cell_angle_beta   62.014
_cell_angle_gamma   60.492
_symmetry_Int_Tables_number   1
_cell_volume   249.697
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.008  0.912  0.262  1.0
  Zn  Zn1  1  0.229  0.208  0.181  1.0
  Sb  Sb2  1  0.545  0.182  0.476  1.0
  Sb  Sb3  1  0.035  0.625  0.156  1.0
  Sb  Sb4  1  0.889  0.410  0.906  1.0
  Sb  Sb5  1  0.447  0.736  0.600  1.0
  O  O6  1  0.791  0.710  0.720  1.0
  O  O7  1  0.572  0.405  0.788  1.0
  O  O8  1  0.341  0.675  0.253  1.0
  O  O9  1  0.175  0.347  0.296  1.0
  O  O10  1  0.126  0.006  0.588  1.0
  O  O11  1  0.923  0.151  0.088  1.0
  O  O12  1  0.980  0.016  0.374  1.0
  O  O13  1  0.087  0.482  0.015  1.0
[/CIF]
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The compound described by LiZn(SbO2)4 crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted trigonal planar geometry to one O(3), one O(6), and one O(7) atom. Zn(1) is bonded to one O(4), one O(7), one O(8), and two equivalent O(6) atoms to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one Sb(1)O5 square pyramid, corners with two equivalent Zn(1)O5 trigonal bipyramids, edges with two equivalent Sb(3)O6 octahedra, and  an edgeedge with one Sb(1)O5 square pyramid. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(7), two equivalent O(4), and two equivalent O(5) atoms to form distorted SbO5 square pyramids that share  a cornercorner with one Zn(1)O5 trigonal bipyramid, edges with two equivalent Sb(1)O5 square pyramids, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to one O(4), one O(8), and two equivalent O(3) atoms. In the third Sb site, Sb(3) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(8) atoms to form SbO6 octahedra that share edges with two equivalent Sb(3)O6 octahedra and edges with two equivalent Zn(1)O5 trigonal bipyramids. In the fourth Sb site, Sb(4) is bonded in a 4-coordinate geometry to one O(2), one O(5), and two equivalent O(1) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Sb(3) and two equivalent Sb(4) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Sb(4) and two equivalent Sb(3) atoms. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Li(1) and two equivalent Sb(2) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Zn(1), one Sb(2), and two equivalent Sb(1) atoms. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Sb(4) and two equivalent Sb(1) atoms. In the sixth O site, O(6) is bonded in a see-saw-like geometry to one Li(1), two equivalent Zn(1), and one Sb(3) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Li(1), one Zn(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Zn(1), one Sb(2), and two equivalent Sb(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiZn(SbO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.442
_cell_length_b   8.971
_cell_length_c   11.720
_cell_angle_alpha   55.283
_cell_angle_beta   62.014
_cell_angle_gamma   60.492
_symmetry_Int_Tables_number   1
_cell_volume   249.697
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.008  0.912  0.262  1.0
  Zn  Zn1  1  0.229  0.208  0.181  1.0
  Sb  Sb2  1  0.545  0.182  0.476  1.0
  Sb  Sb3  1  0.035  0.625  0.156  1.0
  Sb  Sb4  1  0.889  0.410  0.906  1.0
  Sb  Sb5  1  0.447  0.736  0.600  1.0
  O  O6  1  0.791  0.710  0.720  1.0
  O  O7  1  0.572  0.405  0.788  1.0
  O  O8  1  0.341  0.675  0.253  1.0
  O  O9  1  0.175  0.347  0.296  1.0
  O  O10  1  0.126  0.006  0.588  1.0
  O  O11  1  0.923  0.151  0.088  1.0
  O  O12  1  0.980  0.016  0.374  1.0
  O  O13  1  0.087  0.482  0.015  1.0
[/CIF]
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