The compound described by AgB3O5 crystallizes in the orthorhombic Pna2_1 space group. Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are three inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second B site, B(2) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form corner-sharing BO4 tetrahedra. In the third B site, B(3) is bonded to one O(1), one O(4), and two equivalent O(5) atoms to form corner-sharing BO4 tetrahedra. There are five inequivalent O sites. In the first O site, O(5) is bonded in a trigonal planar geometry to one B(2) and two equivalent B(3) atoms. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one B(1), and one B(3) atom. In the third O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ag(1), one B(1), and one B(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one B(1), and one B(2) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one B(2), and one B(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgB3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.874
_cell_length_b   8.325
_cell_length_c   10.335
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   333.285
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.746  0.411  0.578  1.0
  Ag  Ag1  1  0.246  0.589  0.422  1.0
  Ag  Ag2  1  0.246  0.911  0.922  1.0
  Ag  Ag3  1  0.746  0.089  0.078  1.0
  B  B4  1  0.089  0.246  0.337  1.0
  B  B5  1  0.589  0.754  0.663  1.0
  B  B6  1  0.589  0.746  0.163  1.0
  B  B7  1  0.089  0.254  0.837  1.0
  B  B8  1  0.280  0.960  0.313  1.0
  B  B9  1  0.780  0.040  0.687  1.0
  B  B10  1  0.780  0.460  0.187  1.0
  B  B11  1  0.280  0.540  0.813  1.0
  B  B12  1  0.821  0.898  0.471  1.0
  B  B13  1  0.321  0.102  0.529  1.0
  B  B14  1  0.321  0.398  0.029  1.0
  B  B15  1  0.821  0.602  0.971  1.0
  O  O16  1  0.183  0.245  0.466  1.0
  O  O17  1  0.683  0.755  0.534  1.0
  O  O18  1  0.683  0.745  0.034  1.0
  O  O19  1  0.183  0.255  0.966  1.0
  O  O20  1  0.960  0.390  0.295  1.0
  O  O21  1  0.460  0.610  0.705  1.0
  O  O22  1  0.460  0.890  0.205  1.0
  O  O23  1  0.960  0.110  0.795  1.0
  O  O24  1  0.128  0.111  0.265  1.0
  O  O25  1  0.628  0.889  0.735  1.0
  O  O26  1  0.628  0.611  0.235  1.0
  O  O27  1  0.128  0.389  0.765  1.0
  O  O28  1  0.030  0.853  0.366  1.0
  O  O29  1  0.530  0.147  0.634  1.0
  O  O30  1  0.530  0.353  0.134  1.0
  O  O31  1  0.030  0.647  0.866  1.0
  O  O32  1  0.523  0.008  0.427  1.0
  O  O33  1  0.023  0.992  0.573  1.0
  O  O34  1  0.023  0.508  0.073  1.0
  O  O35  1  0.523  0.492  0.927  1.0
[/CIF]
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The compound described by AgB3O5 crystallizes in the orthorhombic Pna2_1 space group. Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are three inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second B site, B(2) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form corner-sharing BO4 tetrahedra. In the third B site, B(3) is bonded to one O(1), one O(4), and two equivalent O(5) atoms to form corner-sharing BO4 tetrahedra. There are five inequivalent O sites. In the first O site, O(5) is bonded in a trigonal planar geometry to one B(2) and two equivalent B(3) atoms. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one B(1), and one B(3) atom. In the third O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ag(1), one B(1), and one B(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one B(1), and one B(2) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one B(2), and one B(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgB3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.874
_cell_length_b   8.325
_cell_length_c   10.335
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   333.285
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.746  0.411  0.578  1.0
  Ag  Ag1  1  0.246  0.589  0.422  1.0
  Ag  Ag2  1  0.246  0.911  0.922  1.0
  Ag  Ag3  1  0.746  0.089  0.078  1.0
  B  B4  1  0.089  0.246  0.337  1.0
  B  B5  1  0.589  0.754  0.663  1.0
  B  B6  1  0.589  0.746  0.163  1.0
  B  B7  1  0.089  0.254  0.837  1.0
  B  B8  1  0.280  0.960  0.313  1.0
  B  B9  1  0.780  0.040  0.687  1.0
  B  B10  1  0.780  0.460  0.187  1.0
  B  B11  1  0.280  0.540  0.813  1.0
  B  B12  1  0.821  0.898  0.471  1.0
  B  B13  1  0.321  0.102  0.529  1.0
  B  B14  1  0.321  0.398  0.029  1.0
  B  B15  1  0.821  0.602  0.971  1.0
  O  O16  1  0.183  0.245  0.466  1.0
  O  O17  1  0.683  0.755  0.534  1.0
  O  O18  1  0.683  0.745  0.034  1.0
  O  O19  1  0.183  0.255  0.966  1.0
  O  O20  1  0.960  0.390  0.295  1.0
  O  O21  1  0.460  0.610  0.705  1.0
  O  O22  1  0.460  0.890  0.205  1.0
  O  O23  1  0.960  0.110  0.795  1.0
  O  O24  1  0.128  0.111  0.265  1.0
  O  O25  1  0.628  0.889  0.735  1.0
  O  O26  1  0.628  0.611  0.235  1.0
  O  O27  1  0.128  0.389  0.765  1.0
  O  O28  1  0.030  0.853  0.366  1.0
  O  O29  1  0.530  0.147  0.634  1.0
  O  O30  1  0.530  0.353  0.134  1.0
  O  O31  1  0.030  0.647  0.866  1.0
  O  O32  1  0.523  0.008  0.427  1.0
  O  O33  1  0.023  0.992  0.573  1.0
  O  O34  1  0.023  0.508  0.073  1.0
  O  O35  1  0.523  0.492  0.927  1.0
[/CIF]
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