The structure described by Li5Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(14), one O(2), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-79°. In the third Li site, Li(3) is bonded to one O(10), one O(12), one O(13), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 66-81°. In the fourth Li site, Li(4) is bonded to one O(11), one O(12), one O(13), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Li(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 68-83°. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(11), and one O(13) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(11), one O(12), one O(14), one O(6), and one O(8) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  an edgeedge with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(4)O5 trigonal bipyramid. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  an edgeedge with one Li(2)O5 trigonal bipyramid. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(13), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(12), one O(14), and one O(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(4), one O(5), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid, and corners with two equivalent Li(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 39-57°. In the second P site, P(2) is bonded to one O(10), one O(11), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid, corners with two equivalent Li(3)O5 trigonal bipyramids, and corners with two equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 42-59°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(5), one Mn(2), and one C(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one Li(2), and one C(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(2), one Mn(2), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(2), and one P(1) atom. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Mn(2), and one P(1) atom to form distorted corner-sharing OLi2MnP trigonal pyramids. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Li(2), one Mn(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(2), one Mn(2), and one P(2) atom. In the eighth O site, O(8) is bonded to one Li(3), one Li(4), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(9)Li2MnP tetrahedra, corners with two equivalent O(13)Li3C tetrahedra,  a cornercorner with one O(12)Li2MnC trigonal pyramid,  a cornercorner with one O(5)Li2MnP trigonal pyramid,  an edgeedge with one O(12)Li2MnC trigonal pyramid,  an edgeedge with one O(10)Li2MnP trigonal pyramid, and  an edgeedge with one O(11)Li2MnP trigonal pyramid. In the ninth O site, O(9) is bonded to one Li(3), one Li(4), one Mn(2), and one P(2) atom to form distorted OLi2MnP tetrahedra that share  a cornercorner with one O(5)Li2MnP trigonal pyramid, corners with two equivalent O(12)Li2MnC trigonal pyramids, corners with two equivalent O(10)Li2MnP trigonal pyramids, corners with two equivalent O(11)Li2MnP trigonal pyramids, corners with two equivalent O(8)Li2MnP trigonal pyramids, and  an edgeedge with one O(13)Li3C tetrahedra. In the tenth O site, O(10) is bonded to one Li(3), one Li(5), one Mn(1), and one P(2) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(9)Li2MnP tetrahedra, corners with two equivalent O(13)Li3C tetrahedra,  a cornercorner with one O(11)Li2MnP trigonal pyramid, corners with two equivalent O(12)Li2MnC trigonal pyramids,  an edgeedge with one O(11)Li2MnP trigonal pyramid, and  an edgeedge with one O(8)Li2MnP trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(4), one Li(5), one Mn(1), and one P(2) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(9)Li2MnP tetrahedra, corners with two equivalent O(13)Li3C tetrahedra,  a cornercorner with one O(10)Li2MnP trigonal pyramid, corners with two equivalent O(12)Li2MnC trigonal pyramids,  an edgeedge with one O(10)Li2MnP trigonal pyramid, and  an edgeedge with one O(8)Li2MnP trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(3), one Li(4), one Mn(1), and one C(2) atom to form distorted OLi2MnC trigonal pyramids that share corners with two equivalent O(9)Li2MnP tetrahedra, corners with two equivalent O(13)Li3C tetrahedra,  a cornercorner with one O(8)Li2MnP trigonal pyramid, corners with two equivalent O(10)Li2MnP trigonal pyramids, corners with two equivalent O(11)Li2MnP trigonal pyramids, and  an edgeedge with one O(8)Li2MnP trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(3), one Li(4), one Li(5), and one C(1) atom to form OLi3C tetrahedra that share corners with two equivalent O(12)Li2MnC trigonal pyramids, corners with two equivalent O(10)Li2MnP trigonal pyramids, corners with two equivalent O(11)Li2MnP trigonal pyramids, corners with two equivalent O(8)Li2MnP trigonal pyramids, and  an edgeedge with one O(9)Li2MnP tetrahedra. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Mn(1), and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.070
_cell_length_b   8.560
_cell_length_c   6.469
_cell_angle_alpha   88.871
_cell_angle_beta   90.056
_cell_angle_gamma   84.917
_symmetry_Int_Tables_number   1
_cell_volume   279.557
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.797  0.110  0.240  1.0
  Li  Li1  1  0.272  0.268  0.471  1.0
  Li  Li2  1  0.724  0.736  0.512  1.0
  Li  Li3  1  0.728  0.729  0.970  1.0
  Li  Li4  1  0.223  0.899  0.752  1.0
  Mn  Mn5  1  0.203  0.663  0.248  1.0
  Mn  Mn6  1  0.799  0.332  0.755  1.0
  P  P7  1  0.725  0.415  0.258  1.0
  P  P8  1  0.263  0.588  0.744  1.0
  C  C9  1  0.697  0.038  0.740  1.0
  C  C10  1  0.321  0.958  0.262  1.0
  O  O11  1  0.945  0.060  0.754  1.0
  O  O12  1  0.416  0.088  0.292  1.0
  O  O13  1  0.527  0.161  0.726  1.0
  O  O14  1  0.792  0.315  0.066  1.0
  O  O15  1  0.857  0.310  0.437  1.0
  O  O16  1  0.424  0.443  0.297  1.0
  O  O17  1  0.158  0.426  0.739  1.0
  O  O18  1  0.835  0.579  0.244  1.0
  O  O19  1  0.572  0.571  0.745  1.0
  O  O20  1  0.155  0.698  0.561  1.0
  O  O21  1  0.160  0.688  0.933  1.0
  O  O22  1  0.486  0.827  0.245  1.0
  O  O23  1  0.615  0.898  0.742  1.0
  O  O24  1  0.071  0.939  0.248  1.0
[/CIF]
.
The structure described by Li5Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(14), one O(2), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-79°. In the third Li site, Li(3) is bonded to one O(10), one O(12), one O(13), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 66-81°. In the fourth Li site, Li(4) is bonded to one O(11), one O(12), one O(13), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Li(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 68-83°. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(11), and one O(13) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(11), one O(12), one O(14), one O(6), and one O(8) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  an edgeedge with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(4)O5 trigonal bipyramid. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  an edgeedge with one Li(2)O5 trigonal bipyramid. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(13), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(12), one O(14), and one O(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(4), one O(5), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid, and corners with two equivalent Li(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 39-57°. In the second P site, P(2) is bonded to one O(10), one O(11), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid, corners with two equivalent Li(3)O5 trigonal bipyramids, and corners with two equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 42-59°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(5), one Mn(2), and one C(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one Li(2), and one C(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(2), one Mn(2), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(2), and one P(1) atom. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Mn(2), and one P(1) atom to form distorted corner-sharing OLi2MnP trigonal pyramids. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Li(2), one Mn(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(2), one Mn(2), and one P(2) atom. In the eighth O site, O(8) is bonded to one Li(3), one Li(4), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(9)Li2MnP tetrahedra, corners with two equivalent O(13)Li3C tetrahedra,  a cornercorner with one O(12)Li2MnC trigonal pyramid,  a cornercorner with one O(5)Li2MnP trigonal pyramid,  an edgeedge with one O(12)Li2MnC trigonal pyramid,  an edgeedge with one O(10)Li2MnP trigonal pyramid, and  an edgeedge with one O(11)Li2MnP trigonal pyramid. In the ninth O site, O(9) is bonded to one Li(3), one Li(4), one Mn(2), and one P(2) atom to form distorted OLi2MnP tetrahedra that share  a cornercorner with one O(5)Li2MnP trigonal pyramid, corners with two equivalent O(12)Li2MnC trigonal pyramids, corners with two equivalent O(10)Li2MnP trigonal pyramids, corners with two equivalent O(11)Li2MnP trigonal pyramids, corners with two equivalent O(8)Li2MnP trigonal pyramids, and  an edgeedge with one O(13)Li3C tetrahedra. In the tenth O site, O(10) is bonded to one Li(3), one Li(5), one Mn(1), and one P(2) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(9)Li2MnP tetrahedra, corners with two equivalent O(13)Li3C tetrahedra,  a cornercorner with one O(11)Li2MnP trigonal pyramid, corners with two equivalent O(12)Li2MnC trigonal pyramids,  an edgeedge with one O(11)Li2MnP trigonal pyramid, and  an edgeedge with one O(8)Li2MnP trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(4), one Li(5), one Mn(1), and one P(2) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(9)Li2MnP tetrahedra, corners with two equivalent O(13)Li3C tetrahedra,  a cornercorner with one O(10)Li2MnP trigonal pyramid, corners with two equivalent O(12)Li2MnC trigonal pyramids,  an edgeedge with one O(10)Li2MnP trigonal pyramid, and  an edgeedge with one O(8)Li2MnP trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(3), one Li(4), one Mn(1), and one C(2) atom to form distorted OLi2MnC trigonal pyramids that share corners with two equivalent O(9)Li2MnP tetrahedra, corners with two equivalent O(13)Li3C tetrahedra,  a cornercorner with one O(8)Li2MnP trigonal pyramid, corners with two equivalent O(10)Li2MnP trigonal pyramids, corners with two equivalent O(11)Li2MnP trigonal pyramids, and  an edgeedge with one O(8)Li2MnP trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(3), one Li(4), one Li(5), and one C(1) atom to form OLi3C tetrahedra that share corners with two equivalent O(12)Li2MnC trigonal pyramids, corners with two equivalent O(10)Li2MnP trigonal pyramids, corners with two equivalent O(11)Li2MnP trigonal pyramids, corners with two equivalent O(8)Li2MnP trigonal pyramids, and  an edgeedge with one O(9)Li2MnP tetrahedra. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Mn(1), and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.070
_cell_length_b   8.560
_cell_length_c   6.469
_cell_angle_alpha   88.871
_cell_angle_beta   90.056
_cell_angle_gamma   84.917
_symmetry_Int_Tables_number   1
_cell_volume   279.557
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.797  0.110  0.240  1.0
  Li  Li1  1  0.272  0.268  0.471  1.0
  Li  Li2  1  0.724  0.736  0.512  1.0
  Li  Li3  1  0.728  0.729  0.970  1.0
  Li  Li4  1  0.223  0.899  0.752  1.0
  Mn  Mn5  1  0.203  0.663  0.248  1.0
  Mn  Mn6  1  0.799  0.332  0.755  1.0
  P  P7  1  0.725  0.415  0.258  1.0
  P  P8  1  0.263  0.588  0.744  1.0
  C  C9  1  0.697  0.038  0.740  1.0
  C  C10  1  0.321  0.958  0.262  1.0
  O  O11  1  0.945  0.060  0.754  1.0
  O  O12  1  0.416  0.088  0.292  1.0
  O  O13  1  0.527  0.161  0.726  1.0
  O  O14  1  0.792  0.315  0.066  1.0
  O  O15  1  0.857  0.310  0.437  1.0
  O  O16  1  0.424  0.443  0.297  1.0
  O  O17  1  0.158  0.426  0.739  1.0
  O  O18  1  0.835  0.579  0.244  1.0
  O  O19  1  0.572  0.571  0.745  1.0
  O  O20  1  0.155  0.698  0.561  1.0
  O  O21  1  0.160  0.688  0.933  1.0
  O  O22  1  0.486  0.827  0.245  1.0
  O  O23  1  0.615  0.898  0.742  1.0
  O  O24  1  0.071  0.939  0.248  1.0
[/CIF]
.