The crystal structure described by NH4PHO3F is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonium molecules and one PHO3F cluster. In the PHO3F cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one F(1) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(6), and one F(2) atom. There are two inequivalent H sites. In the first H site, H(9) is bonded in a linear geometry to one O(3) and one O(6) atom. In the second H site, H(10) is bonded in a linear geometry to one O(1) and one O(4) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one H(10) atom. In the second O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(6) is bonded in a bent 150 degrees geometry to one P(2) and one H(9) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one H(10) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one P(2) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one H(9) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF card [CIF]
data_PH5NO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.323
_cell_length_b   7.396
_cell_length_c   7.653
_cell_angle_alpha   84.185
_cell_angle_beta   84.805
_cell_angle_gamma   68.155
_symmetry_Int_Tables_number   1
_cell_volume   382.129
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.742  0.738  0.598  1.0
  P  P1  1  0.258  0.262  0.402  1.0
  P  P2  1  0.714  0.233  0.942  1.0
  P  P3  1  0.286  0.767  0.058  1.0
  H  H4  1  0.197  0.749  0.728  1.0
  H  H5  1  0.803  0.251  0.272  1.0
  H  H6  1  0.118  0.770  0.524  1.0
  H  H7  1  0.882  0.230  0.476  1.0
  H  H8  1  0.192  0.943  0.587  1.0
  H  H9  1  0.808  0.057  0.413  1.0
  H  H10  1  0.360  0.719  0.554  1.0
  H  H11  1  0.640  0.281  0.446  1.0
  H  H12  1  0.774  0.588  0.094  1.0
  H  H13  1  0.226  0.412  0.906  1.0
  H  H14  1  0.942  0.694  0.045  1.0
  H  H15  1  0.058  0.306  0.955  1.0
  H  H16  1  0.702  0.834  0.061  1.0
  H  H17  1  0.298  0.166  0.939  1.0
  H  H18  1  0.819  0.723  0.241  1.0
  H  H19  1  0.181  0.277  0.759  1.0
  H  H20  1  0.514  0.901  0.791  1.0
  H  H21  1  0.486  0.099  0.209  1.0
  H  H22  1  0.616  0.458  0.714  1.0
  H  H23  1  0.384  0.542  0.286  1.0
  N  N24  1  0.192  0.292  0.890  1.0
  N  N25  1  0.808  0.708  0.110  1.0
  N  N26  1  0.783  0.205  0.403  1.0
  N  N27  1  0.217  0.795  0.597  1.0
  O  O28  1  0.576  0.363  0.801  1.0
  O  O29  1  0.187  0.666  0.962  1.0
  O  O30  1  0.602  0.923  0.686  1.0
  O  O31  1  0.398  0.077  0.314  1.0
  O  O32  1  0.645  0.599  0.568  1.0
  O  O33  1  0.355  0.401  0.432  1.0
  O  O34  1  0.859  0.796  0.449  1.0
  O  O35  1  0.141  0.204  0.551  1.0
  O  O36  1  0.813  0.334  0.038  1.0
  O  O37  1  0.388  0.883  0.949  1.0
  O  O38  1  0.424  0.637  0.199  1.0
  O  O39  1  0.612  0.117  0.051  1.0
  F  F40  1  0.894  0.629  0.744  1.0
  F  F41  1  0.114  0.917  0.170  1.0
  F  F42  1  0.886  0.083  0.830  1.0
  F  F43  1  0.106  0.371  0.256  1.0
[/CIF]
.
The crystal structure described by NH4PHO3F is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonium molecules and one PHO3F cluster. In the PHO3F cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one F(1) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(6), and one F(2) atom. There are two inequivalent H sites. In the first H site, H(9) is bonded in a linear geometry to one O(3) and one O(6) atom. In the second H site, H(10) is bonded in a linear geometry to one O(1) and one O(4) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one H(10) atom. In the second O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(6) is bonded in a bent 150 degrees geometry to one P(2) and one H(9) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one H(10) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one P(2) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one H(9) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF card [CIF]
data_PH5NO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.323
_cell_length_b   7.396
_cell_length_c   7.653
_cell_angle_alpha   84.185
_cell_angle_beta   84.805
_cell_angle_gamma   68.155
_symmetry_Int_Tables_number   1
_cell_volume   382.129
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.742  0.738  0.598  1.0
  P  P1  1  0.258  0.262  0.402  1.0
  P  P2  1  0.714  0.233  0.942  1.0
  P  P3  1  0.286  0.767  0.058  1.0
  H  H4  1  0.197  0.749  0.728  1.0
  H  H5  1  0.803  0.251  0.272  1.0
  H  H6  1  0.118  0.770  0.524  1.0
  H  H7  1  0.882  0.230  0.476  1.0
  H  H8  1  0.192  0.943  0.587  1.0
  H  H9  1  0.808  0.057  0.413  1.0
  H  H10  1  0.360  0.719  0.554  1.0
  H  H11  1  0.640  0.281  0.446  1.0
  H  H12  1  0.774  0.588  0.094  1.0
  H  H13  1  0.226  0.412  0.906  1.0
  H  H14  1  0.942  0.694  0.045  1.0
  H  H15  1  0.058  0.306  0.955  1.0
  H  H16  1  0.702  0.834  0.061  1.0
  H  H17  1  0.298  0.166  0.939  1.0
  H  H18  1  0.819  0.723  0.241  1.0
  H  H19  1  0.181  0.277  0.759  1.0
  H  H20  1  0.514  0.901  0.791  1.0
  H  H21  1  0.486  0.099  0.209  1.0
  H  H22  1  0.616  0.458  0.714  1.0
  H  H23  1  0.384  0.542  0.286  1.0
  N  N24  1  0.192  0.292  0.890  1.0
  N  N25  1  0.808  0.708  0.110  1.0
  N  N26  1  0.783  0.205  0.403  1.0
  N  N27  1  0.217  0.795  0.597  1.0
  O  O28  1  0.576  0.363  0.801  1.0
  O  O29  1  0.187  0.666  0.962  1.0
  O  O30  1  0.602  0.923  0.686  1.0
  O  O31  1  0.398  0.077  0.314  1.0
  O  O32  1  0.645  0.599  0.568  1.0
  O  O33  1  0.355  0.401  0.432  1.0
  O  O34  1  0.859  0.796  0.449  1.0
  O  O35  1  0.141  0.204  0.551  1.0
  O  O36  1  0.813  0.334  0.038  1.0
  O  O37  1  0.388  0.883  0.949  1.0
  O  O38  1  0.424  0.637  0.199  1.0
  O  O39  1  0.612  0.117  0.051  1.0
  F  F40  1  0.894  0.629  0.744  1.0
  F  F41  1  0.114  0.917  0.170  1.0
  F  F42  1  0.886  0.083  0.830  1.0
  F  F43  1  0.106  0.371  0.256  1.0
[/CIF]
.