The structure described by PbCsF3 is Orthorhombic Perovskite-like structured and crystallizes in the trigonal R3c space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent F(1) atoms. Pb(1) is bonded to six equivalent F(1) atoms to form corner-sharing PbF6 octahedra. The corner-sharing octahedral tilt angles are 22°. F(1) is bonded in a 5-coordinate geometry to three equivalent Cs(1) and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_CsPbF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.665
_cell_length_b   6.665
_cell_length_c   6.665
_cell_angle_alpha   62.289
_cell_angle_beta   62.289
_cell_angle_gamma   62.289
_symmetry_Int_Tables_number   1
_cell_volume   220.028
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.242  0.242  0.242  1.0
  Cs  Cs1  1  0.742  0.742  0.742  1.0
  Pb  Pb2  1  0.992  0.992  0.992  1.0
  Pb  Pb3  1  0.492  0.492  0.492  1.0
  F  F4  1  0.290  0.786  0.176  1.0
  F  F5  1  0.786  0.176  0.290  1.0
  F  F6  1  0.176  0.290  0.786  1.0
  F  F7  1  0.676  0.286  0.790  1.0
  F  F8  1  0.790  0.676  0.286  1.0
  F  F9  1  0.286  0.790  0.676  1.0
[/CIF]
.
The structure described by PbCsF3 is Orthorhombic Perovskite-like structured and crystallizes in the trigonal R3c space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent F(1) atoms. Pb(1) is bonded to six equivalent F(1) atoms to form corner-sharing PbF6 octahedra. The corner-sharing octahedral tilt angles are 22°. F(1) is bonded in a 5-coordinate geometry to three equivalent Cs(1) and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_CsPbF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.665
_cell_length_b   6.665
_cell_length_c   6.665
_cell_angle_alpha   62.289
_cell_angle_beta   62.289
_cell_angle_gamma   62.289
_symmetry_Int_Tables_number   1
_cell_volume   220.028
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.242  0.242  0.242  1.0
  Cs  Cs1  1  0.742  0.742  0.742  1.0
  Pb  Pb2  1  0.992  0.992  0.992  1.0
  Pb  Pb3  1  0.492  0.492  0.492  1.0
  F  F4  1  0.290  0.786  0.176  1.0
  F  F5  1  0.786  0.176  0.290  1.0
  F  F6  1  0.176  0.290  0.786  1.0
  F  F7  1  0.676  0.286  0.790  1.0
  F  F8  1  0.790  0.676  0.286  1.0
  F  F9  1  0.286  0.790  0.676  1.0
[/CIF]
.