The material structure described by (Fe2P2H5(CO6)2)2H2O2 crystallizes in the monoclinic P2_1 space group. The structure consists of two water molecules inside a Fe2P2H5(CO6)2 framework. In the Fe2P2H5(CO6)2 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a square pyramidal geometry to one O(1), one O(11), one O(5), one O(7), and one O(9) atom. In the second Fe site, Fe(2) is bonded in a 5-coordinate geometry to one P(2), one O(10), one O(2), one O(6), and one O(8) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(8) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal planar geometry to one O(11), one O(2), and one O(9) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one Fe(2), one O(1), one O(10), and one O(12) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted bent 150 degrees geometry to one O(12) and one O(3) atom. In the fourth H site, H(5) is bonded in a distorted single-bond geometry to one O(4) and one O(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Fe(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Fe(2) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one H(2), one H(3), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one H(5) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Fe(1) and one C(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Fe(1), one C(1), and one H(5) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Fe(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Fe(2), one P(2), and one H(1) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Fe(1) and one P(1) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one P(2) and one H(3) atom. is represented by the CIF card [CIF]
data_Fe2P2H6C2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   18.146
_cell_length_b   5.002
_cell_length_c   7.584
_cell_angle_alpha   73.563
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   660.304
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.640  0.880  0.257  1.0
  Fe  Fe1  1  0.140  0.120  0.743  1.0
  Fe  Fe2  1  0.344  0.100  0.208  1.0
  Fe  Fe3  1  0.844  0.900  0.792  1.0
  P  P4  1  0.704  0.242  0.486  1.0
  P  P5  1  0.204  0.758  0.514  1.0
  P  P6  1  0.295  0.827  0.995  1.0
  P  P7  1  0.795  0.173  0.005  1.0
  H  H8  1  0.728  0.548  0.882  1.0
  H  H9  1  0.228  0.452  0.118  1.0
  H  H10  1  0.313  0.380  0.652  1.0
  H  H11  1  0.813  0.620  0.348  1.0
  H  H12  1  0.376  0.021  0.802  1.0
  H  H13  1  0.876  0.979  0.198  1.0
  H  H14  1  0.591  0.895  0.708  1.0
  H  H15  1  0.091  0.105  0.292  1.0
  H  H16  1  0.606  0.412  0.925  1.0
  H  H17  1  0.106  0.588  0.075  1.0
  H  H18  1  0.388  0.516  0.683  1.0
  H  H19  1  0.888  0.484  0.317  1.0
  C  C20  1  0.500  0.134  0.158  1.0
  C  C21  1  1.000  0.866  0.842  1.0
  C  C22  1  0.487  0.854  0.307  1.0
  C  C23  1  0.987  0.146  0.693  1.0
  O  O24  1  0.726  0.098  0.131  1.0
  O  O25  1  0.226  0.902  0.869  1.0
  O  O26  1  0.266  0.922  0.414  1.0
  O  O27  1  0.766  0.078  0.586  1.0
  O  O28  1  0.864  0.663  0.309  1.0
  O  O29  1  0.364  0.337  0.691  1.0
  O  O30  1  0.137  0.448  0.167  1.0
  O  O31  1  0.637  0.552  0.833  1.0
  O  O32  1  0.542  0.695  0.362  1.0
  O  O33  1  0.042  0.305  0.638  1.0
  O  O34  1  0.444  0.288  0.104  1.0
  O  O35  1  0.944  0.712  0.896  1.0
  O  O36  1  0.566  0.185  0.101  1.0
  O  O37  1  0.066  0.815  0.899  1.0
  O  O38  1  0.421  0.806  0.362  1.0
  O  O39  1  0.921  0.194  0.638  1.0
  O  O40  1  0.711  0.551  0.408  1.0
  O  O41  1  0.211  0.449  0.592  1.0
  O  O42  1  0.283  0.482  0.095  1.0
  O  O43  1  0.783  0.518  0.905  1.0
  O  O44  1  0.632  0.105  0.469  1.0
  O  O45  1  0.132  0.895  0.531  1.0
  O  O46  1  0.365  0.817  0.869  1.0
  O  O47  1  0.865  0.183  0.131  1.0
  O  O48  1  0.600  0.809  0.840  1.0
  O  O49  1  0.100  0.191  0.160  1.0
[/CIF]
.
The material structure described by (Fe2P2H5(CO6)2)2H2O2 crystallizes in the monoclinic P2_1 space group. The structure consists of two water molecules inside a Fe2P2H5(CO6)2 framework. In the Fe2P2H5(CO6)2 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a square pyramidal geometry to one O(1), one O(11), one O(5), one O(7), and one O(9) atom. In the second Fe site, Fe(2) is bonded in a 5-coordinate geometry to one P(2), one O(10), one O(2), one O(6), and one O(8) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(8) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal planar geometry to one O(11), one O(2), and one O(9) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one Fe(2), one O(1), one O(10), and one O(12) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted bent 150 degrees geometry to one O(12) and one O(3) atom. In the fourth H site, H(5) is bonded in a distorted single-bond geometry to one O(4) and one O(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Fe(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Fe(2) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one H(2), one H(3), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one H(5) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Fe(1) and one C(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Fe(1), one C(1), and one H(5) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Fe(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Fe(2), one P(2), and one H(1) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Fe(1) and one P(1) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one P(2) and one H(3) atom. is represented by the CIF card [CIF]
data_Fe2P2H6C2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   18.146
_cell_length_b   5.002
_cell_length_c   7.584
_cell_angle_alpha   73.563
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   660.304
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.640  0.880  0.257  1.0
  Fe  Fe1  1  0.140  0.120  0.743  1.0
  Fe  Fe2  1  0.344  0.100  0.208  1.0
  Fe  Fe3  1  0.844  0.900  0.792  1.0
  P  P4  1  0.704  0.242  0.486  1.0
  P  P5  1  0.204  0.758  0.514  1.0
  P  P6  1  0.295  0.827  0.995  1.0
  P  P7  1  0.795  0.173  0.005  1.0
  H  H8  1  0.728  0.548  0.882  1.0
  H  H9  1  0.228  0.452  0.118  1.0
  H  H10  1  0.313  0.380  0.652  1.0
  H  H11  1  0.813  0.620  0.348  1.0
  H  H12  1  0.376  0.021  0.802  1.0
  H  H13  1  0.876  0.979  0.198  1.0
  H  H14  1  0.591  0.895  0.708  1.0
  H  H15  1  0.091  0.105  0.292  1.0
  H  H16  1  0.606  0.412  0.925  1.0
  H  H17  1  0.106  0.588  0.075  1.0
  H  H18  1  0.388  0.516  0.683  1.0
  H  H19  1  0.888  0.484  0.317  1.0
  C  C20  1  0.500  0.134  0.158  1.0
  C  C21  1  1.000  0.866  0.842  1.0
  C  C22  1  0.487  0.854  0.307  1.0
  C  C23  1  0.987  0.146  0.693  1.0
  O  O24  1  0.726  0.098  0.131  1.0
  O  O25  1  0.226  0.902  0.869  1.0
  O  O26  1  0.266  0.922  0.414  1.0
  O  O27  1  0.766  0.078  0.586  1.0
  O  O28  1  0.864  0.663  0.309  1.0
  O  O29  1  0.364  0.337  0.691  1.0
  O  O30  1  0.137  0.448  0.167  1.0
  O  O31  1  0.637  0.552  0.833  1.0
  O  O32  1  0.542  0.695  0.362  1.0
  O  O33  1  0.042  0.305  0.638  1.0
  O  O34  1  0.444  0.288  0.104  1.0
  O  O35  1  0.944  0.712  0.896  1.0
  O  O36  1  0.566  0.185  0.101  1.0
  O  O37  1  0.066  0.815  0.899  1.0
  O  O38  1  0.421  0.806  0.362  1.0
  O  O39  1  0.921  0.194  0.638  1.0
  O  O40  1  0.711  0.551  0.408  1.0
  O  O41  1  0.211  0.449  0.592  1.0
  O  O42  1  0.283  0.482  0.095  1.0
  O  O43  1  0.783  0.518  0.905  1.0
  O  O44  1  0.632  0.105  0.469  1.0
  O  O45  1  0.132  0.895  0.531  1.0
  O  O46  1  0.365  0.817  0.869  1.0
  O  O47  1  0.865  0.183  0.131  1.0
  O  O48  1  0.600  0.809  0.840  1.0
  O  O49  1  0.100  0.191  0.160  1.0
[/CIF]
.