The structure described by SnPHO5 crystallizes in the triclinic P-1 space group. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent H(1), two equivalent O(1), and two equivalent O(2) atoms to form distorted corner-sharing SnH2O4 octahedra. In the second Sn site, Sn(2) is bonded to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form corner-sharing SnO8 hexagonal bipyramids. The corner-sharing octahedral tilt angles are 52°. P(1) is bonded in a distorted L-shaped geometry to one O(2), one O(3), one O(4), and one O(5) atom. H(1) is bonded in a single-bond geometry to one Sn(1) and one O(1) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Sn(1), one Sn(2), one H(1), and one O(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Sn(1) and one P(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Sn(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sn(2), one P(1), and one O(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sn(2) and one P(1) atom. is represented by the CIF card [CIF]
data_SnPHO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.305
_cell_length_b   5.358
_cell_length_c   7.554
_cell_angle_alpha   109.524
_cell_angle_beta   105.660
_cell_angle_gamma   96.940
_symmetry_Int_Tables_number   1
_cell_volume   189.530
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.500  1.0
  Sn  Sn1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.332  0.646  0.227  1.0
  P  P3  1  0.668  0.354  0.773  1.0
  H  H4  1  0.640  0.966  0.337  1.0
  H  H5  1  0.360  0.034  0.663  1.0
  O  O6  1  0.157  0.955  0.721  1.0
  O  O7  1  0.295  0.805  0.375  1.0
  O  O8  1  0.697  0.653  0.660  1.0
  O  O9  1  0.627  0.759  0.064  1.0
  O  O10  1  0.115  0.668  0.135  1.0
  O  O11  1  0.885  0.332  0.865  1.0
  O  O12  1  0.373  0.241  0.936  1.0
  O  O13  1  0.303  0.347  0.340  1.0
  O  O14  1  0.705  0.195  0.625  1.0
  O  O15  1  0.843  0.045  0.279  1.0
[/CIF]
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The structure described by SnPHO5 crystallizes in the triclinic P-1 space group. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent H(1), two equivalent O(1), and two equivalent O(2) atoms to form distorted corner-sharing SnH2O4 octahedra. In the second Sn site, Sn(2) is bonded to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form corner-sharing SnO8 hexagonal bipyramids. The corner-sharing octahedral tilt angles are 52°. P(1) is bonded in a distorted L-shaped geometry to one O(2), one O(3), one O(4), and one O(5) atom. H(1) is bonded in a single-bond geometry to one Sn(1) and one O(1) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Sn(1), one Sn(2), one H(1), and one O(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Sn(1) and one P(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Sn(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sn(2), one P(1), and one O(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sn(2) and one P(1) atom. is represented by the CIF card [CIF]
data_SnPHO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.305
_cell_length_b   5.358
_cell_length_c   7.554
_cell_angle_alpha   109.524
_cell_angle_beta   105.660
_cell_angle_gamma   96.940
_symmetry_Int_Tables_number   1
_cell_volume   189.530
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.500  1.0
  Sn  Sn1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.332  0.646  0.227  1.0
  P  P3  1  0.668  0.354  0.773  1.0
  H  H4  1  0.640  0.966  0.337  1.0
  H  H5  1  0.360  0.034  0.663  1.0
  O  O6  1  0.157  0.955  0.721  1.0
  O  O7  1  0.295  0.805  0.375  1.0
  O  O8  1  0.697  0.653  0.660  1.0
  O  O9  1  0.627  0.759  0.064  1.0
  O  O10  1  0.115  0.668  0.135  1.0
  O  O11  1  0.885  0.332  0.865  1.0
  O  O12  1  0.373  0.241  0.936  1.0
  O  O13  1  0.303  0.347  0.340  1.0
  O  O14  1  0.705  0.195  0.625  1.0
  O  O15  1  0.843  0.045  0.279  1.0
[/CIF]
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