The material structure described by KZnB(H2Cl)2 crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 7-coordinate geometry to one H(1), one H(3), two equivalent Cl(1), and three equivalent Cl(2) atoms. Zn(1) is bonded to two equivalent H(2), one Cl(1), and one Cl(2) atom to form ZnH2Cl2 tetrahedra that share  an edgeedge with one B(1)H4 tetrahedra. B(1) is bonded to one H(1), one H(3), and two equivalent H(2) atoms to form BH4 tetrahedra that share  an edgeedge with one Zn(1)H2Cl2 tetrahedra. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one B(1) atom. In the second H site, H(2) is bonded in an L-shaped geometry to one Zn(1) and one B(1) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one K(1) and one B(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to two equivalent K(1) and one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Zn(1) atom. is represented by the CIF card [CIF]
data_KZnB(H2Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.185
_cell_length_b   6.880
_cell_length_c   8.046
_cell_angle_alpha   78.641
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   335.675
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.509  0.746  1.0
  K  K1  1  0.750  0.491  0.254  1.0
  Zn  Zn2  1  0.250  0.973  0.338  1.0
  Zn  Zn3  1  0.750  0.027  0.662  1.0
  B  B4  1  0.250  0.196  0.102  1.0
  B  B5  1  0.750  0.804  0.898  1.0
  H  H6  1  0.250  0.371  0.102  1.0
  H  H7  1  0.750  0.629  0.898  1.0
  H  H8  1  0.079  0.131  0.177  1.0
  H  H9  1  0.579  0.869  0.823  1.0
  H  H10  1  0.921  0.869  0.823  1.0
  H  H11  1  0.421  0.131  0.177  1.0
  H  H12  1  0.250  0.141  0.967  1.0
  H  H13  1  0.750  0.859  0.033  1.0
  Cl  Cl14  1  0.250  0.038  0.602  1.0
  Cl  Cl15  1  0.750  0.962  0.398  1.0
  Cl  Cl16  1  0.250  0.648  0.336  1.0
  Cl  Cl17  1  0.750  0.352  0.664  1.0
[/CIF]
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The material structure described by KZnB(H2Cl)2 crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 7-coordinate geometry to one H(1), one H(3), two equivalent Cl(1), and three equivalent Cl(2) atoms. Zn(1) is bonded to two equivalent H(2), one Cl(1), and one Cl(2) atom to form ZnH2Cl2 tetrahedra that share  an edgeedge with one B(1)H4 tetrahedra. B(1) is bonded to one H(1), one H(3), and two equivalent H(2) atoms to form BH4 tetrahedra that share  an edgeedge with one Zn(1)H2Cl2 tetrahedra. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one B(1) atom. In the second H site, H(2) is bonded in an L-shaped geometry to one Zn(1) and one B(1) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one K(1) and one B(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to two equivalent K(1) and one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Zn(1) atom. is represented by the CIF card [CIF]
data_KZnB(H2Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.185
_cell_length_b   6.880
_cell_length_c   8.046
_cell_angle_alpha   78.641
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   335.675
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.509  0.746  1.0
  K  K1  1  0.750  0.491  0.254  1.0
  Zn  Zn2  1  0.250  0.973  0.338  1.0
  Zn  Zn3  1  0.750  0.027  0.662  1.0
  B  B4  1  0.250  0.196  0.102  1.0
  B  B5  1  0.750  0.804  0.898  1.0
  H  H6  1  0.250  0.371  0.102  1.0
  H  H7  1  0.750  0.629  0.898  1.0
  H  H8  1  0.079  0.131  0.177  1.0
  H  H9  1  0.579  0.869  0.823  1.0
  H  H10  1  0.921  0.869  0.823  1.0
  H  H11  1  0.421  0.131  0.177  1.0
  H  H12  1  0.250  0.141  0.967  1.0
  H  H13  1  0.750  0.859  0.033  1.0
  Cl  Cl14  1  0.250  0.038  0.602  1.0
  Cl  Cl15  1  0.750  0.962  0.398  1.0
  Cl  Cl16  1  0.250  0.648  0.336  1.0
  Cl  Cl17  1  0.750  0.352  0.664  1.0
[/CIF]
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