The structure described by V4AgO10 crystallizes in the monoclinic Cm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(10), one O(3), one O(5), one O(9), and two equivalent O(1) atoms. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(10), one O(4), one O(6), one O(9), and two equivalent O(2) atoms. In the third V site, V(3) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(7), one O(9), and two equivalent O(3) atoms. In the fourth V site, V(4) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(3), one O(8), and two equivalent O(4) atoms. Ag(1) is bonded to one O(8), two equivalent O(6), and two equivalent O(7) atoms to form edge-sharing AgO5 square pyramids. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(4) and two equivalent V(2) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one V(1), one V(4), and two equivalent V(3) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(2), one V(3), and two equivalent V(4) atoms. In the fifth O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one V(2) and two equivalent Ag(1) atoms. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(3) and two equivalent Ag(1) atoms. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one V(4) and one Ag(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one V(1), one V(2), and one V(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one V(1), one V(2), and one V(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V4AgO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.689
_cell_length_b   6.191
_cell_length_c   9.179
_cell_angle_alpha   91.343
_cell_angle_beta   90.000
_cell_angle_gamma   72.669
_symmetry_Int_Tables_number   1
_cell_volume   200.064
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.065  0.869  0.334  1.0
  V  V1  1  0.932  0.136  0.665  1.0
  V  V2  1  0.771  0.457  0.335  1.0
  V  V3  1  0.228  0.543  0.663  1.0
  Ag  Ag4  1  0.380  0.240  0.016  1.0
  O  O5  1  0.603  0.793  0.364  1.0
  O  O6  1  0.399  0.203  0.635  1.0
  O  O7  1  0.240  0.519  0.382  1.0
  O  O8  1  0.760  0.481  0.616  1.0
  O  O9  1  0.050  0.900  0.159  1.0
  O  O10  1  0.935  0.129  0.846  1.0
  O  O11  1  0.800  0.399  0.157  1.0
  O  O12  1  0.216  0.569  0.840  1.0
  O  O13  1  0.923  0.153  0.405  1.0
  O  O14  1  0.079  0.842  0.607  1.0
[/CIF]
.
The structure described by V4AgO10 crystallizes in the monoclinic Cm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(10), one O(3), one O(5), one O(9), and two equivalent O(1) atoms. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(10), one O(4), one O(6), one O(9), and two equivalent O(2) atoms. In the third V site, V(3) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(7), one O(9), and two equivalent O(3) atoms. In the fourth V site, V(4) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(3), one O(8), and two equivalent O(4) atoms. Ag(1) is bonded to one O(8), two equivalent O(6), and two equivalent O(7) atoms to form edge-sharing AgO5 square pyramids. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(4) and two equivalent V(2) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one V(1), one V(4), and two equivalent V(3) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(2), one V(3), and two equivalent V(4) atoms. In the fifth O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one V(2) and two equivalent Ag(1) atoms. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(3) and two equivalent Ag(1) atoms. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one V(4) and one Ag(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one V(1), one V(2), and one V(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one V(1), one V(2), and one V(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V4AgO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.689
_cell_length_b   6.191
_cell_length_c   9.179
_cell_angle_alpha   91.343
_cell_angle_beta   90.000
_cell_angle_gamma   72.669
_symmetry_Int_Tables_number   1
_cell_volume   200.064
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.065  0.869  0.334  1.0
  V  V1  1  0.932  0.136  0.665  1.0
  V  V2  1  0.771  0.457  0.335  1.0
  V  V3  1  0.228  0.543  0.663  1.0
  Ag  Ag4  1  0.380  0.240  0.016  1.0
  O  O5  1  0.603  0.793  0.364  1.0
  O  O6  1  0.399  0.203  0.635  1.0
  O  O7  1  0.240  0.519  0.382  1.0
  O  O8  1  0.760  0.481  0.616  1.0
  O  O9  1  0.050  0.900  0.159  1.0
  O  O10  1  0.935  0.129  0.846  1.0
  O  O11  1  0.800  0.399  0.157  1.0
  O  O12  1  0.216  0.569  0.840  1.0
  O  O13  1  0.923  0.153  0.405  1.0
  O  O14  1  0.079  0.842  0.607  1.0
[/CIF]
.