The structure described by NO9I3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one NO9I3 cluster. N(1) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one I(2) and one I(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one N(1) and one I(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one I(1) and one I(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one I(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one I(1) and one I(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one I(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one I(3) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(6), and one O(7) atom. In the second I site, I(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(7), and one O(8) atom. In the third I site, I(3) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(9) atom. is represented by the CIF file [CIF]
data_I3NO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.254
_cell_length_b   8.417
_cell_length_c   8.595
_cell_angle_alpha   79.317
_cell_angle_beta   61.360
_cell_angle_gamma   68.122
_symmetry_Int_Tables_number   1
_cell_volume   486.303
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  I  I0  1  0.204  0.297  0.202  1.0
  I  I1  1  0.796  0.703  0.798  1.0
  I  I2  1  0.779  0.196  0.756  1.0
  I  I3  1  0.221  0.804  0.244  1.0
  I  I4  1  0.232  0.274  0.768  1.0
  I  I5  1  0.768  0.726  0.232  1.0
  N  N6  1  0.730  0.138  0.188  1.0
  N  N7  1  0.270  0.862  0.812  1.0
  O  O8  1  0.986  0.866  0.237  1.0
  O  O9  1  0.014  0.134  0.763  1.0
  O  O10  1  0.392  0.052  0.714  1.0
  O  O11  1  0.608  0.948  0.286  1.0
  O  O12  1  0.634  0.245  0.288  1.0
  O  O13  1  0.366  0.755  0.712  1.0
  O  O14  1  0.115  0.265  0.030  1.0
  O  O15  1  0.885  0.735  0.970  1.0
  O  O16  1  0.230  0.505  0.123  1.0
  O  O17  1  0.770  0.495  0.877  1.0
  O  O18  1  0.041  0.633  0.619  1.0
  O  O19  1  0.959  0.367  0.381  1.0
  O  O20  1  0.194  0.004  0.319  1.0
  O  O21  1  0.806  0.996  0.681  1.0
  O  O22  1  0.391  0.815  0.007  1.0
  O  O23  1  0.609  0.185  0.993  1.0
  O  O24  1  0.578  0.637  0.290  1.0
  O  O25  1  0.422  0.363  0.710  1.0
[/CIF]
.
The structure described by NO9I3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one NO9I3 cluster. N(1) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one I(2) and one I(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one N(1) and one I(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one I(1) and one I(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one I(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one I(1) and one I(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one I(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one I(3) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(6), and one O(7) atom. In the second I site, I(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(7), and one O(8) atom. In the third I site, I(3) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(9) atom. is represented by the CIF file [CIF]
data_I3NO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.254
_cell_length_b   8.417
_cell_length_c   8.595
_cell_angle_alpha   79.317
_cell_angle_beta   61.360
_cell_angle_gamma   68.122
_symmetry_Int_Tables_number   1
_cell_volume   486.303
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  I  I0  1  0.204  0.297  0.202  1.0
  I  I1  1  0.796  0.703  0.798  1.0
  I  I2  1  0.779  0.196  0.756  1.0
  I  I3  1  0.221  0.804  0.244  1.0
  I  I4  1  0.232  0.274  0.768  1.0
  I  I5  1  0.768  0.726  0.232  1.0
  N  N6  1  0.730  0.138  0.188  1.0
  N  N7  1  0.270  0.862  0.812  1.0
  O  O8  1  0.986  0.866  0.237  1.0
  O  O9  1  0.014  0.134  0.763  1.0
  O  O10  1  0.392  0.052  0.714  1.0
  O  O11  1  0.608  0.948  0.286  1.0
  O  O12  1  0.634  0.245  0.288  1.0
  O  O13  1  0.366  0.755  0.712  1.0
  O  O14  1  0.115  0.265  0.030  1.0
  O  O15  1  0.885  0.735  0.970  1.0
  O  O16  1  0.230  0.505  0.123  1.0
  O  O17  1  0.770  0.495  0.877  1.0
  O  O18  1  0.041  0.633  0.619  1.0
  O  O19  1  0.959  0.367  0.381  1.0
  O  O20  1  0.194  0.004  0.319  1.0
  O  O21  1  0.806  0.996  0.681  1.0
  O  O22  1  0.391  0.815  0.007  1.0
  O  O23  1  0.609  0.185  0.993  1.0
  O  O24  1  0.578  0.637  0.290  1.0
  O  O25  1  0.422  0.363  0.710  1.0
[/CIF]
.