The material described by NiC2H4(NS2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NiC2H4(NS2)2 clusters. Ni(1) is bonded in a square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(4) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2), one S(2), and one S(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent S sites. In the first S site, S(2) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the second S site, S(3) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the third S site, S(4) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the fourth S site, S(1) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiH4C2(S2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.094
_cell_length_b   8.948
_cell_length_c   11.450
_cell_angle_alpha   51.064
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   804.378
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.107  0.219  0.327  1.0
  Ni  Ni1  1  0.607  0.781  0.173  1.0
  Ni  Ni2  1  0.893  0.781  0.673  1.0
  Ni  Ni3  1  0.393  0.219  0.827  1.0
  H  H4  1  0.243  0.727  0.322  1.0
  H  H5  1  0.743  0.273  0.178  1.0
  H  H6  1  0.757  0.273  0.678  1.0
  H  H7  1  0.257  0.727  0.822  1.0
  H  H8  1  0.308  0.649  0.494  1.0
  H  H9  1  0.808  0.351  0.006  1.0
  H  H10  1  0.692  0.351  0.506  1.0
  H  H11  1  0.192  0.649  0.994  1.0
  H  H12  1  0.966  0.714  0.326  1.0
  H  H13  1  0.466  0.286  0.174  1.0
  H  H14  1  0.034  0.286  0.674  1.0
  H  H15  1  0.534  0.714  0.826  1.0
  H  H16  1  0.898  0.787  0.157  1.0
  H  H17  1  0.398  0.213  0.343  1.0
  H  H18  1  0.102  0.213  0.843  1.0
  H  H19  1  0.602  0.787  0.657  1.0
  C  C20  1  0.207  0.904  0.375  1.0
  C  C21  1  0.707  0.096  0.125  1.0
  C  C22  1  0.793  0.096  0.625  1.0
  C  C23  1  0.293  0.904  0.875  1.0
  C  C24  1  0.008  0.538  0.273  1.0
  C  C25  1  0.508  0.462  0.227  1.0
  C  C26  1  0.992  0.462  0.727  1.0
  C  C27  1  0.492  0.538  0.773  1.0
  S  S28  1  0.119  0.083  0.220  1.0
  S  S29  1  0.619  0.917  0.280  1.0
  S  S30  1  0.881  0.917  0.780  1.0
  S  S31  1  0.381  0.083  0.720  1.0
  S  S32  1  0.103  0.366  0.425  1.0
  S  S33  1  0.603  0.634  0.075  1.0
  S  S34  1  0.897  0.634  0.575  1.0
  S  S35  1  0.397  0.366  0.925  1.0
  S  S36  1  0.993  0.480  0.157  1.0
  S  S37  1  0.493  0.520  0.343  1.0
  S  S38  1  0.007  0.520  0.843  1.0
  S  S39  1  0.507  0.480  0.657  1.0
  S  S40  1  0.223  0.957  0.495  1.0
  S  S41  1  0.723  0.043  0.005  1.0
  S  S42  1  0.777  0.043  0.505  1.0
  S  S43  1  0.277  0.957  0.995  1.0
  N  N44  1  0.253  0.748  0.400  1.0
  N  N45  1  0.753  0.252  0.100  1.0
  N  N46  1  0.747  0.252  0.600  1.0
  N  N47  1  0.247  0.748  0.900  1.0
  N  N48  1  0.956  0.691  0.249  1.0
  N  N49  1  0.456  0.309  0.251  1.0
  N  N50  1  0.044  0.309  0.751  1.0
  N  N51  1  0.544  0.691  0.749  1.0
[/CIF]
.
The material described by NiC2H4(NS2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NiC2H4(NS2)2 clusters. Ni(1) is bonded in a square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(4) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2), one S(2), and one S(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent S sites. In the first S site, S(2) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the second S site, S(3) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the third S site, S(4) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the fourth S site, S(1) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiH4C2(S2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.094
_cell_length_b   8.948
_cell_length_c   11.450
_cell_angle_alpha   51.064
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   804.378
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.107  0.219  0.327  1.0
  Ni  Ni1  1  0.607  0.781  0.173  1.0
  Ni  Ni2  1  0.893  0.781  0.673  1.0
  Ni  Ni3  1  0.393  0.219  0.827  1.0
  H  H4  1  0.243  0.727  0.322  1.0
  H  H5  1  0.743  0.273  0.178  1.0
  H  H6  1  0.757  0.273  0.678  1.0
  H  H7  1  0.257  0.727  0.822  1.0
  H  H8  1  0.308  0.649  0.494  1.0
  H  H9  1  0.808  0.351  0.006  1.0
  H  H10  1  0.692  0.351  0.506  1.0
  H  H11  1  0.192  0.649  0.994  1.0
  H  H12  1  0.966  0.714  0.326  1.0
  H  H13  1  0.466  0.286  0.174  1.0
  H  H14  1  0.034  0.286  0.674  1.0
  H  H15  1  0.534  0.714  0.826  1.0
  H  H16  1  0.898  0.787  0.157  1.0
  H  H17  1  0.398  0.213  0.343  1.0
  H  H18  1  0.102  0.213  0.843  1.0
  H  H19  1  0.602  0.787  0.657  1.0
  C  C20  1  0.207  0.904  0.375  1.0
  C  C21  1  0.707  0.096  0.125  1.0
  C  C22  1  0.793  0.096  0.625  1.0
  C  C23  1  0.293  0.904  0.875  1.0
  C  C24  1  0.008  0.538  0.273  1.0
  C  C25  1  0.508  0.462  0.227  1.0
  C  C26  1  0.992  0.462  0.727  1.0
  C  C27  1  0.492  0.538  0.773  1.0
  S  S28  1  0.119  0.083  0.220  1.0
  S  S29  1  0.619  0.917  0.280  1.0
  S  S30  1  0.881  0.917  0.780  1.0
  S  S31  1  0.381  0.083  0.720  1.0
  S  S32  1  0.103  0.366  0.425  1.0
  S  S33  1  0.603  0.634  0.075  1.0
  S  S34  1  0.897  0.634  0.575  1.0
  S  S35  1  0.397  0.366  0.925  1.0
  S  S36  1  0.993  0.480  0.157  1.0
  S  S37  1  0.493  0.520  0.343  1.0
  S  S38  1  0.007  0.520  0.843  1.0
  S  S39  1  0.507  0.480  0.657  1.0
  S  S40  1  0.223  0.957  0.495  1.0
  S  S41  1  0.723  0.043  0.005  1.0
  S  S42  1  0.777  0.043  0.505  1.0
  S  S43  1  0.277  0.957  0.995  1.0
  N  N44  1  0.253  0.748  0.400  1.0
  N  N45  1  0.753  0.252  0.100  1.0
  N  N46  1  0.747  0.252  0.600  1.0
  N  N47  1  0.247  0.748  0.900  1.0
  N  N48  1  0.956  0.691  0.249  1.0
  N  N49  1  0.456  0.309  0.251  1.0
  N  N50  1  0.044  0.309  0.751  1.0
  N  N51  1  0.544  0.691  0.749  1.0
[/CIF]
.