The compound described by VF4 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(7) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 32-43°. In the second V site, V(2) is bonded to one F(2), one F(4), one F(5), one F(6), one F(7), and one F(8) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 32-43°. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one V(2) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one V(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.612
_cell_length_b   9.060
_cell_length_c   10.889
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   553.693
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.792  0.100  0.049  1.0
  V  V1  1  0.313  0.312  0.202  1.0
  V  V2  1  0.813  0.812  0.298  1.0
  V  V3  1  0.292  0.600  0.451  1.0
  V  V4  1  0.708  0.100  0.549  1.0
  V  V5  1  0.187  0.312  0.702  1.0
  V  V6  1  0.687  0.812  0.798  1.0
  V  V7  1  0.208  0.600  0.951  1.0
  F  F8  1  0.939  0.506  0.970  1.0
  F  F9  1  0.343  0.440  0.049  1.0
  F  F10  1  0.253  0.725  0.071  1.0
  F  F11  1  0.457  0.163  0.098  1.0
  F  F12  1  0.986  0.250  0.137  1.0
  F  F13  1  0.751  0.691  0.176  1.0
  F  F14  1  0.709  0.984  0.205  1.0
  F  F15  1  0.103  0.873  0.264  1.0
  F  F16  1  0.603  0.373  0.236  1.0
  F  F17  1  0.209  0.484  0.295  1.0
  F  F18  1  0.251  0.191  0.324  1.0
  F  F19  1  0.486  0.750  0.363  1.0
  F  F20  1  0.957  0.663  0.402  1.0
  F  F21  1  0.753  0.225  0.429  1.0
  F  F22  1  0.843  0.940  0.451  1.0
  F  F23  1  0.439  0.006  0.530  1.0
  F  F24  1  0.561  0.506  0.470  1.0
  F  F25  1  0.157  0.440  0.549  1.0
  F  F26  1  0.247  0.725  0.571  1.0
  F  F27  1  0.043  0.163  0.598  1.0
  F  F28  1  0.514  0.250  0.637  1.0
  F  F29  1  0.749  0.691  0.676  1.0
  F  F30  1  0.791  0.984  0.705  1.0
  F  F31  1  0.397  0.873  0.764  1.0
  F  F32  1  0.897  0.373  0.736  1.0
  F  F33  1  0.291  0.484  0.795  1.0
  F  F34  1  0.249  0.191  0.824  1.0
  F  F35  1  0.014  0.750  0.863  1.0
  F  F36  1  0.543  0.663  0.902  1.0
  F  F37  1  0.747  0.225  0.929  1.0
  F  F38  1  0.657  0.940  0.951  1.0
  F  F39  1  0.061  0.006  0.030  1.0
[/CIF]
.
The compound described by VF4 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(7) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 32-43°. In the second V site, V(2) is bonded to one F(2), one F(4), one F(5), one F(6), one F(7), and one F(8) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 32-43°. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one V(2) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one V(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.612
_cell_length_b   9.060
_cell_length_c   10.889
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   553.693
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.792  0.100  0.049  1.0
  V  V1  1  0.313  0.312  0.202  1.0
  V  V2  1  0.813  0.812  0.298  1.0
  V  V3  1  0.292  0.600  0.451  1.0
  V  V4  1  0.708  0.100  0.549  1.0
  V  V5  1  0.187  0.312  0.702  1.0
  V  V6  1  0.687  0.812  0.798  1.0
  V  V7  1  0.208  0.600  0.951  1.0
  F  F8  1  0.939  0.506  0.970  1.0
  F  F9  1  0.343  0.440  0.049  1.0
  F  F10  1  0.253  0.725  0.071  1.0
  F  F11  1  0.457  0.163  0.098  1.0
  F  F12  1  0.986  0.250  0.137  1.0
  F  F13  1  0.751  0.691  0.176  1.0
  F  F14  1  0.709  0.984  0.205  1.0
  F  F15  1  0.103  0.873  0.264  1.0
  F  F16  1  0.603  0.373  0.236  1.0
  F  F17  1  0.209  0.484  0.295  1.0
  F  F18  1  0.251  0.191  0.324  1.0
  F  F19  1  0.486  0.750  0.363  1.0
  F  F20  1  0.957  0.663  0.402  1.0
  F  F21  1  0.753  0.225  0.429  1.0
  F  F22  1  0.843  0.940  0.451  1.0
  F  F23  1  0.439  0.006  0.530  1.0
  F  F24  1  0.561  0.506  0.470  1.0
  F  F25  1  0.157  0.440  0.549  1.0
  F  F26  1  0.247  0.725  0.571  1.0
  F  F27  1  0.043  0.163  0.598  1.0
  F  F28  1  0.514  0.250  0.637  1.0
  F  F29  1  0.749  0.691  0.676  1.0
  F  F30  1  0.791  0.984  0.705  1.0
  F  F31  1  0.397  0.873  0.764  1.0
  F  F32  1  0.897  0.373  0.736  1.0
  F  F33  1  0.291  0.484  0.795  1.0
  F  F34  1  0.249  0.191  0.824  1.0
  F  F35  1  0.014  0.750  0.863  1.0
  F  F36  1  0.543  0.663  0.902  1.0
  F  F37  1  0.747  0.225  0.929  1.0
  F  F38  1  0.657  0.940  0.951  1.0
  F  F39  1  0.061  0.006  0.030  1.0
[/CIF]
.