The crystal structure described by AuCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuCl4 clusters and four SCl3 clusters. In each AuCl4 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(6), and one Cl(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_AuSCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.338
_cell_length_b   8.746
_cell_length_c   11.779
_cell_angle_alpha   73.058
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1018.760
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.097  0.785  0.031  1.0
  Au  Au1  1  0.403  0.785  0.531  1.0
  Au  Au2  1  0.597  0.215  0.469  1.0
  Au  Au3  1  0.903  0.215  0.969  1.0
  S  S4  1  0.296  0.235  0.015  1.0
  S  S5  1  0.796  0.765  0.485  1.0
  S  S6  1  0.204  0.235  0.515  1.0
  S  S7  1  0.704  0.765  0.985  1.0
  Cl  Cl8  1  0.284  0.430  0.074  1.0
  Cl  Cl9  1  0.716  0.570  0.926  1.0
  Cl  Cl10  1  0.234  0.695  0.189  1.0
  Cl  Cl11  1  0.240  0.942  0.425  1.0
  Cl  Cl12  1  0.538  0.874  0.368  1.0
  Cl  Cl13  1  0.438  0.378  0.362  1.0
  Cl  Cl14  1  0.072  0.306  0.385  1.0
  Cl  Cl15  1  0.784  0.570  0.426  1.0
  Cl  Cl16  1  0.038  0.126  0.132  1.0
  Cl  Cl17  1  0.897  0.909  0.352  1.0
  Cl  Cl18  1  0.216  0.430  0.574  1.0
  Cl  Cl19  1  0.397  0.091  0.148  1.0
  Cl  Cl20  1  0.562  0.622  0.638  1.0
  Cl  Cl21  1  0.760  0.058  0.575  1.0
  Cl  Cl22  1  0.462  0.126  0.632  1.0
  Cl  Cl23  1  0.603  0.909  0.852  1.0
  Cl  Cl24  1  0.938  0.622  0.138  1.0
  Cl  Cl25  1  0.740  0.058  0.075  1.0
  Cl  Cl26  1  0.734  0.305  0.311  1.0
  Cl  Cl27  1  0.260  0.942  0.925  1.0
  Cl  Cl28  1  0.572  0.694  0.115  1.0
  Cl  Cl29  1  0.062  0.378  0.862  1.0
  Cl  Cl30  1  0.428  0.306  0.885  1.0
  Cl  Cl31  1  0.266  0.695  0.689  1.0
  Cl  Cl32  1  0.962  0.874  0.868  1.0
  Cl  Cl33  1  0.103  0.091  0.648  1.0
  Cl  Cl34  1  0.766  0.305  0.811  1.0
  Cl  Cl35  1  0.928  0.694  0.615  1.0
[/CIF]
.
The crystal structure described by AuCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuCl4 clusters and four SCl3 clusters. In each AuCl4 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(6), and one Cl(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_AuSCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.338
_cell_length_b   8.746
_cell_length_c   11.779
_cell_angle_alpha   73.058
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1018.760
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.097  0.785  0.031  1.0
  Au  Au1  1  0.403  0.785  0.531  1.0
  Au  Au2  1  0.597  0.215  0.469  1.0
  Au  Au3  1  0.903  0.215  0.969  1.0
  S  S4  1  0.296  0.235  0.015  1.0
  S  S5  1  0.796  0.765  0.485  1.0
  S  S6  1  0.204  0.235  0.515  1.0
  S  S7  1  0.704  0.765  0.985  1.0
  Cl  Cl8  1  0.284  0.430  0.074  1.0
  Cl  Cl9  1  0.716  0.570  0.926  1.0
  Cl  Cl10  1  0.234  0.695  0.189  1.0
  Cl  Cl11  1  0.240  0.942  0.425  1.0
  Cl  Cl12  1  0.538  0.874  0.368  1.0
  Cl  Cl13  1  0.438  0.378  0.362  1.0
  Cl  Cl14  1  0.072  0.306  0.385  1.0
  Cl  Cl15  1  0.784  0.570  0.426  1.0
  Cl  Cl16  1  0.038  0.126  0.132  1.0
  Cl  Cl17  1  0.897  0.909  0.352  1.0
  Cl  Cl18  1  0.216  0.430  0.574  1.0
  Cl  Cl19  1  0.397  0.091  0.148  1.0
  Cl  Cl20  1  0.562  0.622  0.638  1.0
  Cl  Cl21  1  0.760  0.058  0.575  1.0
  Cl  Cl22  1  0.462  0.126  0.632  1.0
  Cl  Cl23  1  0.603  0.909  0.852  1.0
  Cl  Cl24  1  0.938  0.622  0.138  1.0
  Cl  Cl25  1  0.740  0.058  0.075  1.0
  Cl  Cl26  1  0.734  0.305  0.311  1.0
  Cl  Cl27  1  0.260  0.942  0.925  1.0
  Cl  Cl28  1  0.572  0.694  0.115  1.0
  Cl  Cl29  1  0.062  0.378  0.862  1.0
  Cl  Cl30  1  0.428  0.306  0.885  1.0
  Cl  Cl31  1  0.266  0.695  0.689  1.0
  Cl  Cl32  1  0.962  0.874  0.868  1.0
  Cl  Cl33  1  0.103  0.091  0.648  1.0
  Cl  Cl34  1  0.766  0.305  0.811  1.0
  Cl  Cl35  1  0.928  0.694  0.615  1.0
[/CIF]
.