The compound described by KZnO2Cl3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to one O(1), two equivalent Cl(1), two equivalent Cl(2), and three equivalent Cl(3) atoms. Zn(1) is bonded in a trigonal planar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one O(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Zn(1) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KZnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.632
_cell_length_b   6.442
_cell_length_c   12.353
_cell_angle_alpha   76.078
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   821.208
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.353  0.624  0.626  1.0
  K  K1  1  0.853  0.376  0.874  1.0
  K  K2  1  0.647  0.376  0.374  1.0
  K  K3  1  0.147  0.624  0.126  1.0
  Zn  Zn4  1  0.384  0.974  0.331  1.0
  Zn  Zn5  1  0.884  0.026  0.169  1.0
  Zn  Zn6  1  0.616  0.026  0.669  1.0
  Zn  Zn7  1  0.116  0.974  0.831  1.0
  Cl  Cl8  1  0.382  0.317  0.250  1.0
  Cl  Cl9  1  0.882  0.683  0.250  1.0
  Cl  Cl10  1  0.618  0.683  0.750  1.0
  Cl  Cl11  1  0.118  0.317  0.750  1.0
  Cl  Cl12  1  0.221  0.757  0.365  1.0
  Cl  Cl13  1  0.721  0.243  0.135  1.0
  Cl  Cl14  1  0.779  0.243  0.635  1.0
  Cl  Cl15  1  0.279  0.757  0.865  1.0
  Cl  Cl16  1  0.565  0.835  0.411  1.0
  Cl  Cl17  1  0.065  0.165  0.089  1.0
  Cl  Cl18  1  0.435  0.165  0.589  1.0
  Cl  Cl19  1  0.935  0.835  0.911  1.0
  O  O20  1  0.440  0.843  0.135  1.0
  O  O21  1  0.940  0.157  0.365  1.0
  O  O22  1  0.560  0.157  0.865  1.0
  O  O23  1  0.060  0.843  0.635  1.0
  O  O24  1  0.451  0.174  0.897  1.0
  O  O25  1  0.951  0.826  0.603  1.0
  O  O26  1  0.549  0.826  0.103  1.0
  O  O27  1  0.049  0.174  0.397  1.0
[/CIF]
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The compound described by KZnO2Cl3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to one O(1), two equivalent Cl(1), two equivalent Cl(2), and three equivalent Cl(3) atoms. Zn(1) is bonded in a trigonal planar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one O(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Zn(1) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KZnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.632
_cell_length_b   6.442
_cell_length_c   12.353
_cell_angle_alpha   76.078
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   821.208
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.353  0.624  0.626  1.0
  K  K1  1  0.853  0.376  0.874  1.0
  K  K2  1  0.647  0.376  0.374  1.0
  K  K3  1  0.147  0.624  0.126  1.0
  Zn  Zn4  1  0.384  0.974  0.331  1.0
  Zn  Zn5  1  0.884  0.026  0.169  1.0
  Zn  Zn6  1  0.616  0.026  0.669  1.0
  Zn  Zn7  1  0.116  0.974  0.831  1.0
  Cl  Cl8  1  0.382  0.317  0.250  1.0
  Cl  Cl9  1  0.882  0.683  0.250  1.0
  Cl  Cl10  1  0.618  0.683  0.750  1.0
  Cl  Cl11  1  0.118  0.317  0.750  1.0
  Cl  Cl12  1  0.221  0.757  0.365  1.0
  Cl  Cl13  1  0.721  0.243  0.135  1.0
  Cl  Cl14  1  0.779  0.243  0.635  1.0
  Cl  Cl15  1  0.279  0.757  0.865  1.0
  Cl  Cl16  1  0.565  0.835  0.411  1.0
  Cl  Cl17  1  0.065  0.165  0.089  1.0
  Cl  Cl18  1  0.435  0.165  0.589  1.0
  Cl  Cl19  1  0.935  0.835  0.911  1.0
  O  O20  1  0.440  0.843  0.135  1.0
  O  O21  1  0.940  0.157  0.365  1.0
  O  O22  1  0.560  0.157  0.865  1.0
  O  O23  1  0.060  0.843  0.635  1.0
  O  O24  1  0.451  0.174  0.897  1.0
  O  O25  1  0.951  0.826  0.603  1.0
  O  O26  1  0.549  0.826  0.103  1.0
  O  O27  1  0.049  0.174  0.397  1.0
[/CIF]
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