The crystal structure described by LiAg2F4 crystallizes in the orthorhombic Cmce space group. Li(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form a mixture of corner and edge-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 13-14°. There are two inequivalent F sites. In the first F site, F(1) is bonded to one Li(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing FLiAg4 square pyramids. In the second F site, F(2) is bonded in a T-shaped geometry to one Li(1) and two equivalent Ag(1) atoms. is represented by the CIF file [CIF]
data_LiAg2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.539
_cell_length_b   5.539
_cell_length_c   6.848
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   103.663
_symmetry_Int_Tables_number   1
_cell_volume   204.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.500  0.500  0.500  1.0
  Ag  Ag2  1  0.505  0.005  0.250  1.0
  Ag  Ag3  1  0.995  0.495  0.750  1.0
  Ag  Ag4  1  0.005  0.505  0.250  1.0
  Ag  Ag5  1  0.495  0.995  0.750  1.0
  F  F6  1  0.783  0.217  0.000  1.0
  F  F7  1  0.717  0.283  0.500  1.0
  F  F8  1  0.232  0.232  0.783  1.0
  F  F9  1  0.268  0.268  0.283  1.0
  F  F10  1  0.732  0.732  0.717  1.0
  F  F11  1  0.768  0.768  0.217  1.0
  F  F12  1  0.283  0.717  0.500  1.0
  F  F13  1  0.217  0.783  0.000  1.0
[/CIF]
.
The crystal structure described by LiAg2F4 crystallizes in the orthorhombic Cmce space group. Li(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form a mixture of corner and edge-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 13-14°. There are two inequivalent F sites. In the first F site, F(1) is bonded to one Li(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing FLiAg4 square pyramids. In the second F site, F(2) is bonded in a T-shaped geometry to one Li(1) and two equivalent Ag(1) atoms. is represented by the CIF file [CIF]
data_LiAg2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.539
_cell_length_b   5.539
_cell_length_c   6.848
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   103.663
_symmetry_Int_Tables_number   1
_cell_volume   204.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.500  0.500  0.500  1.0
  Ag  Ag2  1  0.505  0.005  0.250  1.0
  Ag  Ag3  1  0.995  0.495  0.750  1.0
  Ag  Ag4  1  0.005  0.505  0.250  1.0
  Ag  Ag5  1  0.495  0.995  0.750  1.0
  F  F6  1  0.783  0.217  0.000  1.0
  F  F7  1  0.717  0.283  0.500  1.0
  F  F8  1  0.232  0.232  0.783  1.0
  F  F9  1  0.268  0.268  0.283  1.0
  F  F10  1  0.732  0.732  0.717  1.0
  F  F11  1  0.768  0.768  0.217  1.0
  F  F12  1  0.283  0.717  0.500  1.0
  F  F13  1  0.217  0.783  0.000  1.0
[/CIF]
.