The compound described by KrBiF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrBiF7 clusters. Kr(1) is bonded in a linear geometry to one F(1) and one F(4) atom. Bi(1) is bonded in an octahedral geometry to one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Bi(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Kr(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Bi(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Kr(1) and one Bi(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Bi(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the CIF card [CIF]
data_BiKrF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.593
_cell_length_b   5.291
_cell_length_c   11.019
_cell_angle_alpha   84.476
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   614.746
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.991  0.602  0.734  1.0
  Bi  Bi1  1  0.491  0.398  0.766  1.0
  Bi  Bi2  1  0.009  0.398  0.266  1.0
  Bi  Bi3  1  0.509  0.602  0.234  1.0
  Kr  Kr4  1  0.236  0.987  0.525  1.0
  Kr  Kr5  1  0.736  0.013  0.975  1.0
  Kr  Kr6  1  0.764  0.013  0.475  1.0
  Kr  Kr7  1  0.264  0.987  0.025  1.0
  F  F8  1  0.384  0.149  0.481  1.0
  F  F9  1  0.884  0.851  0.019  1.0
  F  F10  1  0.616  0.851  0.519  1.0
  F  F11  1  0.116  0.149  0.981  1.0
  F  F12  1  0.637  0.498  0.114  1.0
  F  F13  1  0.137  0.502  0.386  1.0
  F  F14  1  0.363  0.502  0.886  1.0
  F  F15  1  0.863  0.498  0.614  1.0
  F  F16  1  0.613  0.916  0.247  1.0
  F  F17  1  0.113  0.084  0.253  1.0
  F  F18  1  0.387  0.084  0.753  1.0
  F  F19  1  0.887  0.916  0.747  1.0
  F  F20  1  0.435  0.812  0.070  1.0
  F  F21  1  0.935  0.188  0.430  1.0
  F  F22  1  0.565  0.188  0.930  1.0
  F  F23  1  0.065  0.812  0.570  1.0
  F  F24  1  0.587  0.413  0.381  1.0
  F  F25  1  0.087  0.587  0.119  1.0
  F  F26  1  0.413  0.587  0.619  1.0
  F  F27  1  0.913  0.413  0.881  1.0
  F  F28  1  0.394  0.320  0.194  1.0
  F  F29  1  0.894  0.680  0.306  1.0
  F  F30  1  0.606  0.680  0.806  1.0
  F  F31  1  0.106  0.320  0.694  1.0
  F  F32  1  0.134  0.757  0.819  1.0
  F  F33  1  0.634  0.243  0.681  1.0
  F  F34  1  0.866  0.243  0.181  1.0
  F  F35  1  0.366  0.757  0.319  1.0
[/CIF]
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The compound described by KrBiF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrBiF7 clusters. Kr(1) is bonded in a linear geometry to one F(1) and one F(4) atom. Bi(1) is bonded in an octahedral geometry to one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Bi(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Kr(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Bi(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Kr(1) and one Bi(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Bi(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the CIF card [CIF]
data_BiKrF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.593
_cell_length_b   5.291
_cell_length_c   11.019
_cell_angle_alpha   84.476
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   614.746
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.991  0.602  0.734  1.0
  Bi  Bi1  1  0.491  0.398  0.766  1.0
  Bi  Bi2  1  0.009  0.398  0.266  1.0
  Bi  Bi3  1  0.509  0.602  0.234  1.0
  Kr  Kr4  1  0.236  0.987  0.525  1.0
  Kr  Kr5  1  0.736  0.013  0.975  1.0
  Kr  Kr6  1  0.764  0.013  0.475  1.0
  Kr  Kr7  1  0.264  0.987  0.025  1.0
  F  F8  1  0.384  0.149  0.481  1.0
  F  F9  1  0.884  0.851  0.019  1.0
  F  F10  1  0.616  0.851  0.519  1.0
  F  F11  1  0.116  0.149  0.981  1.0
  F  F12  1  0.637  0.498  0.114  1.0
  F  F13  1  0.137  0.502  0.386  1.0
  F  F14  1  0.363  0.502  0.886  1.0
  F  F15  1  0.863  0.498  0.614  1.0
  F  F16  1  0.613  0.916  0.247  1.0
  F  F17  1  0.113  0.084  0.253  1.0
  F  F18  1  0.387  0.084  0.753  1.0
  F  F19  1  0.887  0.916  0.747  1.0
  F  F20  1  0.435  0.812  0.070  1.0
  F  F21  1  0.935  0.188  0.430  1.0
  F  F22  1  0.565  0.188  0.930  1.0
  F  F23  1  0.065  0.812  0.570  1.0
  F  F24  1  0.587  0.413  0.381  1.0
  F  F25  1  0.087  0.587  0.119  1.0
  F  F26  1  0.413  0.587  0.619  1.0
  F  F27  1  0.913  0.413  0.881  1.0
  F  F28  1  0.394  0.320  0.194  1.0
  F  F29  1  0.894  0.680  0.306  1.0
  F  F30  1  0.606  0.680  0.806  1.0
  F  F31  1  0.106  0.320  0.694  1.0
  F  F32  1  0.134  0.757  0.819  1.0
  F  F33  1  0.634  0.243  0.681  1.0
  F  F34  1  0.866  0.243  0.181  1.0
  F  F35  1  0.366  0.757  0.319  1.0
[/CIF]
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