The crystal structure described by RbB5(HO3)4(H2)2 is Indium-derived structured and crystallizes in the orthorhombic Aea2 space group. The structure is zero-dimensional and consists of eight 1333-74-0 molecules and four RbB5(HO3)4 clusters. In each RbB5(HO3)4 cluster, Rb(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second B site, B(2) is bonded in a trigonal planar geometry to one H(4), one O(1), and one O(3) atom. In the third B site, B(3) is bonded in a bent 150 degrees geometry to one O(2) and one O(3) atom. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one B(2) atom. In the second H site, H(1) is bonded in a single-bond geometry to one O(4) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one B(2) and one B(3) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1) and one H(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Rb(1) and one O(6) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one O(5) atom. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one B(1), and one B(2) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbB5(H2O3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.624
_cell_length_b   8.624
_cell_length_c   13.972
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.639
_symmetry_Int_Tables_number   1
_cell_volume   1034.098
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.579  0.579  0.500  1.0
  Rb  Rb1  1  0.079  0.079  0.000  1.0
  B  B2  1  0.906  0.906  0.500  1.0
  B  B3  1  0.406  0.406  0.000  1.0
  B  B4  1  0.904  0.751  0.653  1.0
  B  B5  1  0.751  0.904  0.347  1.0
  B  B6  1  0.404  0.251  0.847  1.0
  B  B7  1  0.251  0.404  0.153  1.0
  B  B8  1  0.915  0.015  0.653  1.0
  B  B9  1  0.015  0.915  0.347  1.0
  B  B10  1  0.415  0.515  0.847  1.0
  B  B11  1  0.515  0.415  0.153  1.0
  H  H12  1  0.494  0.939  0.497  1.0
  H  H13  1  0.939  0.494  0.503  1.0
  H  H14  1  0.994  0.439  0.003  1.0
  H  H15  1  0.439  0.994  0.997  1.0
  H  H16  1  0.292  0.046  0.488  1.0
  H  H17  1  0.046  0.292  0.512  1.0
  H  H18  1  0.792  0.546  0.012  1.0
  H  H19  1  0.546  0.792  0.988  1.0
  H  H20  1  0.311  0.124  0.511  1.0
  H  H21  1  0.124  0.311  0.489  1.0
  H  H22  1  0.811  0.624  0.989  1.0
  H  H23  1  0.624  0.811  0.011  1.0
  H  H24  1  0.897  0.629  0.693  1.0
  H  H25  1  0.629  0.897  0.307  1.0
  H  H26  1  0.397  0.129  0.807  1.0
  H  H27  1  0.129  0.397  0.193  1.0
  O  O28  1  0.902  0.765  0.558  1.0
  O  O29  1  0.765  0.902  0.442  1.0
  O  O30  1  0.402  0.265  0.942  1.0
  O  O31  1  0.265  0.402  0.058  1.0
  O  O32  1  0.918  0.050  0.563  1.0
  O  O33  1  0.050  0.918  0.437  1.0
  O  O34  1  0.418  0.550  0.937  1.0
  O  O35  1  0.550  0.418  0.063  1.0
  O  O36  1  0.909  0.894  0.710  1.0
  O  O37  1  0.894  0.909  0.290  1.0
  O  O38  1  0.409  0.394  0.790  1.0
  O  O39  1  0.394  0.409  0.210  1.0
  O  O40  1  0.838  0.437  0.516  1.0
  O  O41  1  0.437  0.838  0.484  1.0
  O  O42  1  0.338  0.937  0.984  1.0
  O  O43  1  0.937  0.338  0.016  1.0
  O  O44  1  0.040  0.800  0.875  1.0
  O  O45  1  0.800  0.040  0.125  1.0
  O  O46  1  0.540  0.300  0.625  1.0
  O  O47  1  0.300  0.540  0.375  1.0
  O  O48  1  0.570  0.176  0.588  1.0
  O  O49  1  0.176  0.570  0.412  1.0
  O  O50  1  0.070  0.676  0.912  1.0
  O  O51  1  0.676  0.070  0.088  1.0
[/CIF]
.
The crystal structure described by RbB5(HO3)4(H2)2 is Indium-derived structured and crystallizes in the orthorhombic Aea2 space group. The structure is zero-dimensional and consists of eight 1333-74-0 molecules and four RbB5(HO3)4 clusters. In each RbB5(HO3)4 cluster, Rb(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second B site, B(2) is bonded in a trigonal planar geometry to one H(4), one O(1), and one O(3) atom. In the third B site, B(3) is bonded in a bent 150 degrees geometry to one O(2) and one O(3) atom. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one B(2) atom. In the second H site, H(1) is bonded in a single-bond geometry to one O(4) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one B(2) and one B(3) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1) and one H(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Rb(1) and one O(6) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one O(5) atom. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one B(1), and one B(2) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbB5(H2O3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.624
_cell_length_b   8.624
_cell_length_c   13.972
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.639
_symmetry_Int_Tables_number   1
_cell_volume   1034.098
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.579  0.579  0.500  1.0
  Rb  Rb1  1  0.079  0.079  0.000  1.0
  B  B2  1  0.906  0.906  0.500  1.0
  B  B3  1  0.406  0.406  0.000  1.0
  B  B4  1  0.904  0.751  0.653  1.0
  B  B5  1  0.751  0.904  0.347  1.0
  B  B6  1  0.404  0.251  0.847  1.0
  B  B7  1  0.251  0.404  0.153  1.0
  B  B8  1  0.915  0.015  0.653  1.0
  B  B9  1  0.015  0.915  0.347  1.0
  B  B10  1  0.415  0.515  0.847  1.0
  B  B11  1  0.515  0.415  0.153  1.0
  H  H12  1  0.494  0.939  0.497  1.0
  H  H13  1  0.939  0.494  0.503  1.0
  H  H14  1  0.994  0.439  0.003  1.0
  H  H15  1  0.439  0.994  0.997  1.0
  H  H16  1  0.292  0.046  0.488  1.0
  H  H17  1  0.046  0.292  0.512  1.0
  H  H18  1  0.792  0.546  0.012  1.0
  H  H19  1  0.546  0.792  0.988  1.0
  H  H20  1  0.311  0.124  0.511  1.0
  H  H21  1  0.124  0.311  0.489  1.0
  H  H22  1  0.811  0.624  0.989  1.0
  H  H23  1  0.624  0.811  0.011  1.0
  H  H24  1  0.897  0.629  0.693  1.0
  H  H25  1  0.629  0.897  0.307  1.0
  H  H26  1  0.397  0.129  0.807  1.0
  H  H27  1  0.129  0.397  0.193  1.0
  O  O28  1  0.902  0.765  0.558  1.0
  O  O29  1  0.765  0.902  0.442  1.0
  O  O30  1  0.402  0.265  0.942  1.0
  O  O31  1  0.265  0.402  0.058  1.0
  O  O32  1  0.918  0.050  0.563  1.0
  O  O33  1  0.050  0.918  0.437  1.0
  O  O34  1  0.418  0.550  0.937  1.0
  O  O35  1  0.550  0.418  0.063  1.0
  O  O36  1  0.909  0.894  0.710  1.0
  O  O37  1  0.894  0.909  0.290  1.0
  O  O38  1  0.409  0.394  0.790  1.0
  O  O39  1  0.394  0.409  0.210  1.0
  O  O40  1  0.838  0.437  0.516  1.0
  O  O41  1  0.437  0.838  0.484  1.0
  O  O42  1  0.338  0.937  0.984  1.0
  O  O43  1  0.937  0.338  0.016  1.0
  O  O44  1  0.040  0.800  0.875  1.0
  O  O45  1  0.800  0.040  0.125  1.0
  O  O46  1  0.540  0.300  0.625  1.0
  O  O47  1  0.300  0.540  0.375  1.0
  O  O48  1  0.570  0.176  0.588  1.0
  O  O49  1  0.176  0.570  0.412  1.0
  O  O50  1  0.070  0.676  0.912  1.0
  O  O51  1  0.676  0.070  0.088  1.0
[/CIF]
.