The material described by Mn3SbO8 is trigonal omega-derived structured and crystallizes in the tetragonal P4_32_12 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share edges with two equivalent Sb(1)O6 octahedra and edges with four equivalent Mn(2)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form SbO6 octahedra that share edges with two equivalent Mn(1)O6 octahedra and edges with four equivalent Mn(2)O6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(2), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Mn(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1) and two equivalent Mn(2) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Mn(2) and one Sb(1) atom. is represented by the CIF file [CIF]
data_Mn3SbO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.411
_cell_length_b   8.411
_cell_length_c   8.711
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   616.225
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.364  0.636  0.250  1.0
  Mn  Mn1  1  0.379  0.882  0.501  1.0
  Mn  Mn2  1  0.382  0.121  0.751  1.0
  Mn  Mn3  1  0.618  0.879  0.251  1.0
  Mn  Mn4  1  0.621  0.118  0.001  1.0
  Mn  Mn5  1  0.636  0.364  0.750  1.0
  Mn  Mn6  1  0.864  0.864  0.000  1.0
  Mn  Mn7  1  0.879  0.618  0.749  1.0
  Mn  Mn8  1  0.882  0.379  0.499  1.0
  Mn  Mn9  1  0.118  0.621  0.999  1.0
  Mn  Mn10  1  0.121  0.382  0.249  1.0
  Mn  Mn11  1  0.136  0.136  0.500  1.0
  Sb  Sb12  1  0.375  0.375  0.000  1.0
  Sb  Sb13  1  0.625  0.625  0.500  1.0
  Sb  Sb14  1  0.875  0.125  0.250  1.0
  Sb  Sb15  1  0.125  0.875  0.750  1.0
  O  O16  1  0.347  0.610  0.996  1.0
  O  O17  1  0.352  0.397  0.233  1.0
  O  O18  1  0.368  0.114  0.529  1.0
  O  O19  1  0.390  0.653  0.504  1.0
  O  O20  1  0.369  0.889  0.730  1.0
  O  O21  1  0.386  0.868  0.279  1.0
  O  O22  1  0.389  0.131  0.980  1.0
  O  O23  1  0.397  0.352  0.767  1.0
  O  O24  1  0.603  0.648  0.267  1.0
  O  O25  1  0.611  0.869  0.480  1.0
  O  O26  1  0.614  0.132  0.779  1.0
  O  O27  1  0.631  0.111  0.230  1.0
  O  O28  1  0.610  0.347  0.004  1.0
  O  O29  1  0.632  0.886  0.029  1.0
  O  O30  1  0.648  0.603  0.733  1.0
  O  O31  1  0.653  0.390  0.496  1.0
  O  O32  1  0.847  0.890  0.254  1.0
  O  O33  1  0.852  0.103  0.017  1.0
  O  O34  1  0.868  0.386  0.721  1.0
  O  O35  1  0.890  0.847  0.746  1.0
  O  O36  1  0.869  0.611  0.520  1.0
  O  O37  1  0.886  0.632  0.971  1.0
  O  O38  1  0.889  0.369  0.270  1.0
  O  O39  1  0.897  0.148  0.483  1.0
  O  O40  1  0.103  0.852  0.983  1.0
  O  O41  1  0.111  0.631  0.770  1.0
  O  O42  1  0.114  0.368  0.471  1.0
  O  O43  1  0.131  0.389  0.020  1.0
  O  O44  1  0.110  0.153  0.246  1.0
  O  O45  1  0.132  0.614  0.221  1.0
  O  O46  1  0.148  0.897  0.517  1.0
  O  O47  1  0.153  0.110  0.754  1.0
[/CIF]
.
The material described by Mn3SbO8 is trigonal omega-derived structured and crystallizes in the tetragonal P4_32_12 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share edges with two equivalent Sb(1)O6 octahedra and edges with four equivalent Mn(2)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form SbO6 octahedra that share edges with two equivalent Mn(1)O6 octahedra and edges with four equivalent Mn(2)O6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(2), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Mn(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1) and two equivalent Mn(2) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Mn(2) and one Sb(1) atom. is represented by the CIF file [CIF]
data_Mn3SbO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.411
_cell_length_b   8.411
_cell_length_c   8.711
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   616.225
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.364  0.636  0.250  1.0
  Mn  Mn1  1  0.379  0.882  0.501  1.0
  Mn  Mn2  1  0.382  0.121  0.751  1.0
  Mn  Mn3  1  0.618  0.879  0.251  1.0
  Mn  Mn4  1  0.621  0.118  0.001  1.0
  Mn  Mn5  1  0.636  0.364  0.750  1.0
  Mn  Mn6  1  0.864  0.864  0.000  1.0
  Mn  Mn7  1  0.879  0.618  0.749  1.0
  Mn  Mn8  1  0.882  0.379  0.499  1.0
  Mn  Mn9  1  0.118  0.621  0.999  1.0
  Mn  Mn10  1  0.121  0.382  0.249  1.0
  Mn  Mn11  1  0.136  0.136  0.500  1.0
  Sb  Sb12  1  0.375  0.375  0.000  1.0
  Sb  Sb13  1  0.625  0.625  0.500  1.0
  Sb  Sb14  1  0.875  0.125  0.250  1.0
  Sb  Sb15  1  0.125  0.875  0.750  1.0
  O  O16  1  0.347  0.610  0.996  1.0
  O  O17  1  0.352  0.397  0.233  1.0
  O  O18  1  0.368  0.114  0.529  1.0
  O  O19  1  0.390  0.653  0.504  1.0
  O  O20  1  0.369  0.889  0.730  1.0
  O  O21  1  0.386  0.868  0.279  1.0
  O  O22  1  0.389  0.131  0.980  1.0
  O  O23  1  0.397  0.352  0.767  1.0
  O  O24  1  0.603  0.648  0.267  1.0
  O  O25  1  0.611  0.869  0.480  1.0
  O  O26  1  0.614  0.132  0.779  1.0
  O  O27  1  0.631  0.111  0.230  1.0
  O  O28  1  0.610  0.347  0.004  1.0
  O  O29  1  0.632  0.886  0.029  1.0
  O  O30  1  0.648  0.603  0.733  1.0
  O  O31  1  0.653  0.390  0.496  1.0
  O  O32  1  0.847  0.890  0.254  1.0
  O  O33  1  0.852  0.103  0.017  1.0
  O  O34  1  0.868  0.386  0.721  1.0
  O  O35  1  0.890  0.847  0.746  1.0
  O  O36  1  0.869  0.611  0.520  1.0
  O  O37  1  0.886  0.632  0.971  1.0
  O  O38  1  0.889  0.369  0.270  1.0
  O  O39  1  0.897  0.148  0.483  1.0
  O  O40  1  0.103  0.852  0.983  1.0
  O  O41  1  0.111  0.631  0.770  1.0
  O  O42  1  0.114  0.368  0.471  1.0
  O  O43  1  0.131  0.389  0.020  1.0
  O  O44  1  0.110  0.153  0.246  1.0
  O  O45  1  0.132  0.614  0.221  1.0
  O  O46  1  0.148  0.897  0.517  1.0
  O  O47  1  0.153  0.110  0.754  1.0
[/CIF]
.