The material structure described by Na3SbO3 crystallizes in the cubic I-43m space group. Na(1) is bonded to five equivalent O(1) atoms to form a mixture of edge and corner-sharing NaO5 square pyramids. Sb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. O(1) is bonded to five equivalent Na(1) and one Sb(1) atom to form a mixture of edge and corner-sharing ONa5Sb octahedra. The corner-sharing octahedral tilt angles are 19°. is represented by the CIF file [CIF]
data_Na3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.177
_cell_length_b   8.177
_cell_length_c   8.177
_cell_angle_alpha   109.473
_cell_angle_beta   109.473
_cell_angle_gamma   109.473
_symmetry_Int_Tables_number   1
_cell_volume   420.860
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.243  0.723  0.723  1.0
  Na  Na1  1  0.723  0.723  0.243  1.0
  Na  Na2  1  0.723  0.243  0.723  1.0
  Na  Na3  1  1.000  0.520  0.277  1.0
  Na  Na4  1  1.000  0.277  0.520  1.0
  Na  Na5  1  0.757  0.480  0.480  1.0
  Na  Na6  1  0.480  0.480  0.757  1.0
  Na  Na7  1  0.520  0.277  1.000  1.0
  Na  Na8  1  0.277  1.000  0.520  1.0
  Na  Na9  1  0.520  1.000  0.277  1.0
  Na  Na10  1  0.480  0.757  0.480  1.0
  Na  Na11  1  0.277  0.520  1.000  1.0
  Sb  Sb12  1  0.000  0.710  0.000  1.0
  Sb  Sb13  1  0.000  0.000  0.710  1.0
  Sb  Sb14  1  0.290  0.290  0.290  1.0
  Sb  Sb15  1  0.710  0.000  0.000  1.0
  O  O16  1  0.482  0.260  0.482  1.0
  O  O17  1  0.260  0.482  0.482  1.0
  O  O18  1  0.482  0.482  0.260  1.0
  O  O19  1  0.518  0.778  0.000  1.0
  O  O20  1  0.778  0.000  0.518  1.0
  O  O21  1  0.518  0.000  0.778  1.0
  O  O22  1  0.222  0.740  0.222  1.0
  O  O23  1  0.778  0.518  0.000  1.0
  O  O24  1  0.000  0.518  0.778  1.0
  O  O25  1  0.222  0.222  0.740  1.0
  O  O26  1  0.740  0.222  0.222  1.0
  O  O27  1  0.000  0.778  0.518  1.0
[/CIF]
.
The material structure described by Na3SbO3 crystallizes in the cubic I-43m space group. Na(1) is bonded to five equivalent O(1) atoms to form a mixture of edge and corner-sharing NaO5 square pyramids. Sb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. O(1) is bonded to five equivalent Na(1) and one Sb(1) atom to form a mixture of edge and corner-sharing ONa5Sb octahedra. The corner-sharing octahedral tilt angles are 19°. is represented by the CIF file [CIF]
data_Na3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.177
_cell_length_b   8.177
_cell_length_c   8.177
_cell_angle_alpha   109.473
_cell_angle_beta   109.473
_cell_angle_gamma   109.473
_symmetry_Int_Tables_number   1
_cell_volume   420.860
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.243  0.723  0.723  1.0
  Na  Na1  1  0.723  0.723  0.243  1.0
  Na  Na2  1  0.723  0.243  0.723  1.0
  Na  Na3  1  1.000  0.520  0.277  1.0
  Na  Na4  1  1.000  0.277  0.520  1.0
  Na  Na5  1  0.757  0.480  0.480  1.0
  Na  Na6  1  0.480  0.480  0.757  1.0
  Na  Na7  1  0.520  0.277  1.000  1.0
  Na  Na8  1  0.277  1.000  0.520  1.0
  Na  Na9  1  0.520  1.000  0.277  1.0
  Na  Na10  1  0.480  0.757  0.480  1.0
  Na  Na11  1  0.277  0.520  1.000  1.0
  Sb  Sb12  1  0.000  0.710  0.000  1.0
  Sb  Sb13  1  0.000  0.000  0.710  1.0
  Sb  Sb14  1  0.290  0.290  0.290  1.0
  Sb  Sb15  1  0.710  0.000  0.000  1.0
  O  O16  1  0.482  0.260  0.482  1.0
  O  O17  1  0.260  0.482  0.482  1.0
  O  O18  1  0.482  0.482  0.260  1.0
  O  O19  1  0.518  0.778  0.000  1.0
  O  O20  1  0.778  0.000  0.518  1.0
  O  O21  1  0.518  0.000  0.778  1.0
  O  O22  1  0.222  0.740  0.222  1.0
  O  O23  1  0.778  0.518  0.000  1.0
  O  O24  1  0.000  0.518  0.778  1.0
  O  O25  1  0.222  0.222  0.740  1.0
  O  O26  1  0.740  0.222  0.222  1.0
  O  O27  1  0.000  0.778  0.518  1.0
[/CIF]
.