The material structure described by LiSb(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a water-like geometry to two equivalent O(1) atoms. Sb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1), one Sb(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sb(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sb(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSb(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.206
_cell_length_b   7.206
_cell_length_c   10.431
_cell_angle_alpha   78.123
_cell_angle_beta   78.123
_cell_angle_gamma   111.937
_symmetry_Int_Tables_number   1
_cell_volume   467.282
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.859  0.141  0.750  1.0
  Li  Li1  1  0.141  0.859  0.250  1.0
  Sb  Sb2  1  0.133  0.867  0.750  1.0
  Sb  Sb3  1  0.867  0.133  0.250  1.0
  P  P4  1  0.763  0.688  0.551  1.0
  P  P5  1  0.270  0.622  0.011  1.0
  P  P6  1  0.378  0.730  0.489  1.0
  P  P7  1  0.688  0.763  0.051  1.0
  P  P8  1  0.312  0.237  0.949  1.0
  P  P9  1  0.622  0.270  0.511  1.0
  P  P10  1  0.730  0.378  0.989  1.0
  P  P11  1  0.237  0.312  0.449  1.0
  O  O12  1  0.809  0.906  0.906  1.0
  O  O13  1  0.937  0.496  0.875  1.0
  O  O14  1  0.811  0.756  0.670  1.0
  O  O15  1  0.906  0.809  0.406  1.0
  O  O16  1  0.296  0.806  0.896  1.0
  O  O17  1  0.496  0.937  0.375  1.0
  O  O18  1  0.340  0.475  0.939  1.0
  O  O19  1  0.721  0.443  0.583  1.0
  O  O20  1  0.756  0.811  0.170  1.0
  O  O21  1  0.557  0.279  0.917  1.0
  O  O22  1  0.525  0.660  0.561  1.0
  O  O23  1  0.806  0.296  0.396  1.0
  O  O24  1  0.194  0.704  0.604  1.0
  O  O25  1  0.475  0.340  0.439  1.0
  O  O26  1  0.443  0.721  0.083  1.0
  O  O27  1  0.244  0.189  0.830  1.0
  O  O28  1  0.279  0.557  0.417  1.0
  O  O29  1  0.660  0.525  0.061  1.0
  O  O30  1  0.504  0.063  0.625  1.0
  O  O31  1  0.704  0.194  0.104  1.0
  O  O32  1  0.094  0.191  0.594  1.0
  O  O33  1  0.189  0.244  0.330  1.0
  O  O34  1  0.063  0.504  0.125  1.0
  O  O35  1  0.191  0.094  0.094  1.0
[/CIF]
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The material structure described by LiSb(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a water-like geometry to two equivalent O(1) atoms. Sb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1), one Sb(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sb(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sb(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSb(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.206
_cell_length_b   7.206
_cell_length_c   10.431
_cell_angle_alpha   78.123
_cell_angle_beta   78.123
_cell_angle_gamma   111.937
_symmetry_Int_Tables_number   1
_cell_volume   467.282
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.859  0.141  0.750  1.0
  Li  Li1  1  0.141  0.859  0.250  1.0
  Sb  Sb2  1  0.133  0.867  0.750  1.0
  Sb  Sb3  1  0.867  0.133  0.250  1.0
  P  P4  1  0.763  0.688  0.551  1.0
  P  P5  1  0.270  0.622  0.011  1.0
  P  P6  1  0.378  0.730  0.489  1.0
  P  P7  1  0.688  0.763  0.051  1.0
  P  P8  1  0.312  0.237  0.949  1.0
  P  P9  1  0.622  0.270  0.511  1.0
  P  P10  1  0.730  0.378  0.989  1.0
  P  P11  1  0.237  0.312  0.449  1.0
  O  O12  1  0.809  0.906  0.906  1.0
  O  O13  1  0.937  0.496  0.875  1.0
  O  O14  1  0.811  0.756  0.670  1.0
  O  O15  1  0.906  0.809  0.406  1.0
  O  O16  1  0.296  0.806  0.896  1.0
  O  O17  1  0.496  0.937  0.375  1.0
  O  O18  1  0.340  0.475  0.939  1.0
  O  O19  1  0.721  0.443  0.583  1.0
  O  O20  1  0.756  0.811  0.170  1.0
  O  O21  1  0.557  0.279  0.917  1.0
  O  O22  1  0.525  0.660  0.561  1.0
  O  O23  1  0.806  0.296  0.396  1.0
  O  O24  1  0.194  0.704  0.604  1.0
  O  O25  1  0.475  0.340  0.439  1.0
  O  O26  1  0.443  0.721  0.083  1.0
  O  O27  1  0.244  0.189  0.830  1.0
  O  O28  1  0.279  0.557  0.417  1.0
  O  O29  1  0.660  0.525  0.061  1.0
  O  O30  1  0.504  0.063  0.625  1.0
  O  O31  1  0.704  0.194  0.104  1.0
  O  O32  1  0.094  0.191  0.594  1.0
  O  O33  1  0.189  0.244  0.330  1.0
  O  O34  1  0.063  0.504  0.125  1.0
  O  O35  1  0.191  0.094  0.094  1.0
[/CIF]
.