The material structure described by Zn(AgO2)2 is Spinel-like structured and crystallizes in the monoclinic Cm space group. There are nine inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form AgO6 octahedra that share  a cornercorner with one Ag(2)O4 tetrahedra,  a cornercorner with one Ag(9)O4 tetrahedra, corners with two equivalent Ag(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Ag(1)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. In the second Ag site, Ag(2) is bonded to one O(2), one O(9), and two equivalent O(4) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Ag(1)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra, and corners with four equivalent Ag(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-64°. In the third Ag site, Ag(3) is bonded to one O(16), one O(3), two equivalent O(1), and two equivalent O(17) atoms to form AgO6 octahedra that share corners with three equivalent Ag(9)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(6)O6 octahedra, edges with two equivalent Ag(1)O6 octahedra, and edges with two equivalent Ag(6)O6 octahedra. In the fourth Ag site, Ag(4) is bonded to one O(11), one O(12), one O(14), one O(4), one O(6), and one O(9) atom to form AgO6 octahedra that share  a cornercorner with one Ag(5)O4 tetrahedra,  a cornercorner with one Ag(7)O4 tetrahedra, corners with two equivalent Ag(2)O4 tetrahedra, corners with two equivalent Ag(8)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Ag(4)O6 octahedra, and edges with two equivalent Zn(5)O6 octahedra. In the fifth Ag site, Ag(5) is bonded to one O(15), one O(6), and two equivalent O(10) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent Ag(4)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent Ag(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. In the sixth Ag site, Ag(6) is bonded to one O(10), one O(13), one O(15), one O(16), one O(17), and one O(18) atom to form AgO6 octahedra that share  a cornercorner with one Ag(8)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Ag(5)O4 tetrahedra, corners with two equivalent Ag(9)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Ag(6)O6 octahedra, and edges with two equivalent Zn(6)O6 octahedra. In the seventh Ag site, Ag(7) is bonded to one O(14), one O(5), and two equivalent O(7) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent Ag(4)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra, and corners with four equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-62°. In the eighth Ag site, Ag(8) is bonded to one O(11), one O(18), and two equivalent O(12) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent Ag(6)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent Ag(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. In the ninth Ag site, Ag(9) is bonded to one O(16), one O(8), and two equivalent O(17) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Ag(1)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, corners with three equivalent Ag(3)O6 octahedra, and corners with four equivalent Ag(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(13), one O(3), and two equivalent O(1) atoms to form ZnO4 tetrahedra that share  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent Ag(6)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Ag(3)O6 octahedra, and corners with four equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-61°. In the second Zn site, Zn(2) is bonded to one O(5), one O(9), two equivalent O(4), and two equivalent O(7) atoms to form ZnO6 octahedra that share corners with three equivalent Ag(2)O4 tetrahedra, corners with three equivalent Ag(7)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Ag(1)O6 octahedra, and edges with two equivalent Ag(4)O6 octahedra. In the third Zn site, Zn(3) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(7) atoms to form ZnO6 octahedra that share  a cornercorner with one Ag(2)O4 tetrahedra,  a cornercorner with one Ag(9)O4 tetrahedra, corners with two equivalent Ag(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, and edges with four equivalent Ag(1)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(11), one O(15), two equivalent O(10), and two equivalent O(12) atoms to form ZnO6 octahedra that share corners with three equivalent Ag(5)O4 tetrahedra, corners with three equivalent Ag(8)O4 tetrahedra,  an edgeedge with one Zn(5)O6 octahedra,  an edgeedge with one Zn(6)O6 octahedra, edges with two equivalent Ag(4)O6 octahedra, and edges with two equivalent Ag(6)O6 octahedra. In the fifth Zn site, Zn(5) is bonded to one O(14), one O(6), two equivalent O(12), and two equivalent O(4) atoms to form ZnO6 octahedra that share  a cornercorner with one Ag(5)O4 tetrahedra,  a cornercorner with one Ag(7)O4 tetrahedra, corners with two equivalent Ag(2)O4 tetrahedra, corners with two equivalent Ag(8)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent Ag(4)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(13), one O(18), two equivalent O(10), and two equivalent O(17) atoms to form ZnO6 octahedra that share  a cornercorner with one Ag(8)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Ag(5)O4 tetrahedra, corners with two equivalent Ag(9)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent Ag(6)O6 octahedra. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Ag(1), one Ag(3), one Zn(1), and one Zn(3) atom. In the second O site, O(2) is bonded to one Ag(2), two equivalent Ag(1), and one Zn(3) atom to form OZnAg3 tetrahedra that share corners with two equivalent O(4)Zn2Ag2 tetrahedra, corners with four equivalent O(7)Zn2Ag2 tetrahedra,  a cornercorner with one O(9)ZnAg3 trigonal pyramid, and corners with three equivalent O(8)ZnAg3 trigonal pyramids. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Ag(3), two equivalent Ag(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded to one Ag(2), one Ag(4), one Zn(2), and one Zn(5) atom to form distorted OZn2Ag2 tetrahedra that share  a cornercorner with one O(4)Zn2Ag2 tetrahedra,  a cornercorner with one O(2)ZnAg3 tetrahedra, corners with two equivalent O(7)Zn2Ag2 tetrahedra, corners with three equivalent O(12)Zn2Ag2 tetrahedra,  a cornercorner with one O(11)ZnAg3 trigonal pyramid,  a cornercorner with one O(9)ZnAg3 trigonal pyramid, corners with two equivalent O(14)ZnAg3 trigonal pyramids,  an edgeedge with one O(4)Zn2Ag2 tetrahedra,  an edgeedge with one O(6)ZnAg3 trigonal pyramid, and  an edgeedge with one O(9)ZnAg3 trigonal pyramid. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Ag(7), two equivalent Ag(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded to one Ag(5), two equivalent Ag(4), and one Zn(5) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with four equivalent O(12)Zn2Ag2 tetrahedra,  a cornercorner with one O(15)ZnAg3 trigonal pyramid, corners with two equivalent O(11)ZnAg3 trigonal pyramids, corners with three equivalent O(14)ZnAg3 trigonal pyramids, edges with two equivalent O(4)Zn2Ag2 tetrahedra, and  an edgeedge with one O(9)ZnAg3 trigonal pyramid. In the seventh O site, O(7) is bonded to one Ag(1), one Ag(7), one Zn(2), and one Zn(3) atom to form distorted OZn2Ag2 tetrahedra that share  a cornercorner with one O(7)Zn2Ag2 tetrahedra, corners with two equivalent O(4)Zn2Ag2 tetrahedra, corners with two equivalent O(2)ZnAg3 tetrahedra,  a cornercorner with one O(14)ZnAg3 trigonal pyramid,  a cornercorner with one O(9)ZnAg3 trigonal pyramid,  an edgeedge with one O(7)Zn2Ag2 tetrahedra, and  an edgeedge with one O(8)ZnAg3 trigonal pyramid. In the eighth O site, O(8) is bonded to one Ag(9), two equivalent Ag(1), and one Zn(3) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(17)ZnAg3 tetrahedra, corners with three equivalent O(2)ZnAg3 tetrahedra,  a cornercorner with one O(16)Ag4 trigonal pyramid, and edges with two equivalent O(7)Zn2Ag2 tetrahedra. In the ninth O site, O(9) is bonded to one Ag(2), two equivalent Ag(4), and one Zn(2) atom to form distorted OZnAg3 trigonal pyramids that share  a cornercorner with one O(2)ZnAg3 tetrahedra, corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with two equivalent O(4)Zn2Ag2 tetrahedra, corners with two equivalent O(7)Zn2Ag2 tetrahedra, corners with two equivalent O(11)ZnAg3 trigonal pyramids, corners with two equivalent O(14)ZnAg3 trigonal pyramids, edges with two equivalent O(4)Zn2Ag2 tetrahedra, and  an edgeedge with one O(6)ZnAg3 trigonal pyramid. In the tenth O site, O(10) is bonded to one Ag(5), one Ag(6), one Zn(4), and one Zn(6) atom to form distorted OZn2Ag2 tetrahedra that share  a cornercorner with one O(10)Zn2Ag2 tetrahedra, corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with three equivalent O(17)ZnAg3 tetrahedra,  a cornercorner with one O(16)Ag4 trigonal pyramid,  a cornercorner with one O(11)ZnAg3 trigonal pyramid,  a cornercorner with one O(15)ZnAg3 trigonal pyramid,  a cornercorner with one O(6)ZnAg3 trigonal pyramid, corners with two equivalent O(18)ZnAg3 trigonal pyramids,  an edgeedge with one O(10)Zn2Ag2 tetrahedra, and  an edgeedge with one O(15)ZnAg3 trigonal pyramid. In the eleventh O site, O(11) is bonded to one Ag(8), two equivalent Ag(4), and one Zn(4) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with two equivalent O(4)Zn2Ag2 tetrahedra,  a cornercorner with one O(15)ZnAg3 trigonal pyramid,  a cornercorner with one O(18)ZnAg3 trigonal pyramid, corners with two equivalent O(6)ZnAg3 trigonal pyramids, corners with two equivalent O(9)ZnAg3 trigonal pyramids, edges with two equivalent O(12)Zn2Ag2 tetrahedra, and  an edgeedge with one O(14)ZnAg3 trigonal pyramid. In the twelfth O site, O(12) is bonded to one Ag(4), one Ag(8), one Zn(4), and one Zn(5) atom to form distorted OZn2Ag2 tetrahedra that share  a cornercorner with one O(12)Zn2Ag2 tetrahedra, corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with three equivalent O(4)Zn2Ag2 tetrahedra,  a cornercorner with one O(11)ZnAg3 trigonal pyramid,  a cornercorner with one O(15)ZnAg3 trigonal pyramid,  a cornercorner with one O(18)ZnAg3 trigonal pyramid,  a cornercorner with one O(9)ZnAg3 trigonal pyramid, corners with two equivalent O(6)ZnAg3 trigonal pyramids,  an edgeedge with one O(12)Zn2Ag2 tetrahedra,  an edgeedge with one O(11)ZnAg3 trigonal pyramid, and  an edgeedge with one O(14)ZnAg3 trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to two equivalent Ag(6), one Zn(1), and one Zn(6) atom. In the fourteenth O site, O(14) is bonded to one Ag(7), two equivalent Ag(4), and one Zn(5) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(7)Zn2Ag2 tetrahedra, corners with four equivalent O(4)Zn2Ag2 tetrahedra, corners with two equivalent O(9)ZnAg3 trigonal pyramids, corners with three equivalent O(6)ZnAg3 trigonal pyramids, edges with two equivalent O(12)Zn2Ag2 tetrahedra, and  an edgeedge with one O(11)ZnAg3 trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Ag(5), two equivalent Ag(6), and one Zn(4) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with two equivalent O(17)ZnAg3 tetrahedra,  a cornercorner with one O(11)ZnAg3 trigonal pyramid,  a cornercorner with one O(6)ZnAg3 trigonal pyramid, corners with two equivalent O(16)Ag4 trigonal pyramids, corners with two equivalent O(18)ZnAg3 trigonal pyramids, and edges with two equivalent O(10)Zn2Ag2 tetrahedra. In the sixteenth O site, O(16) is bonded to one Ag(3), one Ag(9), and two equivalent Ag(6) atoms to form distorted OAg4 trigonal pyramids that share corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with two equivalent O(17)ZnAg3 tetrahedra,  a cornercorner with one O(8)ZnAg3 trigonal pyramid, corners with two equivalent O(15)ZnAg3 trigonal pyramids, edges with two equivalent O(17)ZnAg3 tetrahedra, and  an edgeedge with one O(18)ZnAg3 trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Ag(3), one Ag(6), one Ag(9), and one Zn(6) atom to form OZnAg3 tetrahedra that share  a cornercorner with one O(17)ZnAg3 tetrahedra, corners with three equivalent O(10)Zn2Ag2 tetrahedra,  a cornercorner with one O(16)Ag4 trigonal pyramid,  a cornercorner with one O(15)ZnAg3 trigonal pyramid,  a cornercorner with one O(8)ZnAg3 trigonal pyramid,  an edgeedge with one O(17)ZnAg3 tetrahedra,  an edgeedge with one O(16)Ag4 trigonal pyramid, and  an edgeedge with one O(18)ZnAg3 trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Ag(8), two equivalent Ag(6), and one Zn(6) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with four equivalent O(10)Zn2Ag2 tetrahedra,  a cornercorner with one O(11)ZnAg3 trigonal pyramid, corners with two equivalent O(15)ZnAg3 trigonal pyramids, edges with two equivalent O(17)ZnAg3 tetrahedra, and  an edgeedge with one O(16)Ag4 trigonal pyramid. is represented by the CIF card [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.341
_cell_length_b   6.341
_cell_length_c   15.503
_cell_angle_alpha   89.102
_cell_angle_beta   89.102
_cell_angle_gamma   61.619
_symmetry_Int_Tables_number   1
_cell_volume   548.309
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.155  0.155  0.958  1.0
  Zn  Zn1  1  0.834  0.834  0.666  1.0
  Zn  Zn2  1  0.667  0.667  0.831  1.0
  Zn  Zn3  1  0.166  0.166  0.334  1.0
  Zn  Zn4  1  0.000  0.000  0.500  1.0
  Zn  Zn5  1  0.333  0.333  0.169  1.0
  Ag  Ag6  1  0.163  0.668  0.833  1.0
  Ag  Ag7  1  0.490  0.490  0.622  1.0
  Ag  Ag8  1  0.500  0.500  0.999  1.0
  Ag  Ag9  1  0.668  0.163  0.833  1.0
  Ag  Ag10  1  0.500  1.000  0.500  1.0
  Ag  Ag11  1  0.823  0.823  0.290  1.0
  Ag  Ag12  1  1.000  0.500  0.500  1.0
  Ag  Ag13  1  0.840  0.330  0.167  1.0
  Ag  Ag14  1  0.176  0.176  0.711  1.0
  Ag  Ag15  1  0.330  0.840  0.167  1.0
  Ag  Ag16  1  0.510  0.510  0.378  1.0
  Ag  Ag17  1  0.839  0.839  0.044  1.0
  O  O18  1  0.342  0.807  0.913  1.0
  O  O19  1  0.496  0.496  0.768  1.0
  O  O20  1  0.807  0.342  0.913  1.0
  O  O21  1  0.329  0.329  0.915  1.0
  O  O22  1  0.689  0.118  0.577  1.0
  O  O23  1  0.990  0.990  0.751  1.0
  O  O24  1  0.830  0.830  0.429  1.0
  O  O25  1  0.548  0.982  0.755  1.0
  O  O26  1  0.118  0.689  0.577  1.0
  O  O27  1  0.836  0.836  0.901  1.0
  O  O28  1  0.681  0.681  0.577  1.0
  O  O29  1  0.982  0.548  0.755  1.0
  O  O30  1  0.023  0.450  0.243  1.0
  O  O31  1  0.319  0.319  0.423  1.0
  O  O32  1  0.882  0.312  0.424  1.0
  O  O33  1  0.450  0.023  0.243  1.0
  O  O34  1  0.167  0.167  0.087  1.0
  O  O35  1  0.171  0.171  0.571  1.0
  O  O36  1  0.013  0.013  0.245  1.0
  O  O37  1  0.312  0.882  0.424  1.0
  O  O38  1  0.655  0.655  0.091  1.0
  O  O39  1  0.216  0.648  0.089  1.0
  O  O40  1  0.505  0.505  0.237  1.0
  O  O41  1  0.648  0.216  0.089  1.0
[/CIF]
.
The material structure described by Zn(AgO2)2 is Spinel-like structured and crystallizes in the monoclinic Cm space group. There are nine inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form AgO6 octahedra that share  a cornercorner with one Ag(2)O4 tetrahedra,  a cornercorner with one Ag(9)O4 tetrahedra, corners with two equivalent Ag(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Ag(1)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. In the second Ag site, Ag(2) is bonded to one O(2), one O(9), and two equivalent O(4) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Ag(1)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra, and corners with four equivalent Ag(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-64°. In the third Ag site, Ag(3) is bonded to one O(16), one O(3), two equivalent O(1), and two equivalent O(17) atoms to form AgO6 octahedra that share corners with three equivalent Ag(9)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(6)O6 octahedra, edges with two equivalent Ag(1)O6 octahedra, and edges with two equivalent Ag(6)O6 octahedra. In the fourth Ag site, Ag(4) is bonded to one O(11), one O(12), one O(14), one O(4), one O(6), and one O(9) atom to form AgO6 octahedra that share  a cornercorner with one Ag(5)O4 tetrahedra,  a cornercorner with one Ag(7)O4 tetrahedra, corners with two equivalent Ag(2)O4 tetrahedra, corners with two equivalent Ag(8)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Ag(4)O6 octahedra, and edges with two equivalent Zn(5)O6 octahedra. In the fifth Ag site, Ag(5) is bonded to one O(15), one O(6), and two equivalent O(10) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent Ag(4)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent Ag(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. In the sixth Ag site, Ag(6) is bonded to one O(10), one O(13), one O(15), one O(16), one O(17), and one O(18) atom to form AgO6 octahedra that share  a cornercorner with one Ag(8)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Ag(5)O4 tetrahedra, corners with two equivalent Ag(9)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Ag(6)O6 octahedra, and edges with two equivalent Zn(6)O6 octahedra. In the seventh Ag site, Ag(7) is bonded to one O(14), one O(5), and two equivalent O(7) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent Ag(4)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra, and corners with four equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-62°. In the eighth Ag site, Ag(8) is bonded to one O(11), one O(18), and two equivalent O(12) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent Ag(6)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent Ag(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. In the ninth Ag site, Ag(9) is bonded to one O(16), one O(8), and two equivalent O(17) atoms to form AgO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Ag(1)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, corners with three equivalent Ag(3)O6 octahedra, and corners with four equivalent Ag(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(13), one O(3), and two equivalent O(1) atoms to form ZnO4 tetrahedra that share  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent Ag(6)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Ag(3)O6 octahedra, and corners with four equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-61°. In the second Zn site, Zn(2) is bonded to one O(5), one O(9), two equivalent O(4), and two equivalent O(7) atoms to form ZnO6 octahedra that share corners with three equivalent Ag(2)O4 tetrahedra, corners with three equivalent Ag(7)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Ag(1)O6 octahedra, and edges with two equivalent Ag(4)O6 octahedra. In the third Zn site, Zn(3) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(7) atoms to form ZnO6 octahedra that share  a cornercorner with one Ag(2)O4 tetrahedra,  a cornercorner with one Ag(9)O4 tetrahedra, corners with two equivalent Ag(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, and edges with four equivalent Ag(1)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(11), one O(15), two equivalent O(10), and two equivalent O(12) atoms to form ZnO6 octahedra that share corners with three equivalent Ag(5)O4 tetrahedra, corners with three equivalent Ag(8)O4 tetrahedra,  an edgeedge with one Zn(5)O6 octahedra,  an edgeedge with one Zn(6)O6 octahedra, edges with two equivalent Ag(4)O6 octahedra, and edges with two equivalent Ag(6)O6 octahedra. In the fifth Zn site, Zn(5) is bonded to one O(14), one O(6), two equivalent O(12), and two equivalent O(4) atoms to form ZnO6 octahedra that share  a cornercorner with one Ag(5)O4 tetrahedra,  a cornercorner with one Ag(7)O4 tetrahedra, corners with two equivalent Ag(2)O4 tetrahedra, corners with two equivalent Ag(8)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent Ag(4)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(13), one O(18), two equivalent O(10), and two equivalent O(17) atoms to form ZnO6 octahedra that share  a cornercorner with one Ag(8)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Ag(5)O4 tetrahedra, corners with two equivalent Ag(9)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent Ag(6)O6 octahedra. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Ag(1), one Ag(3), one Zn(1), and one Zn(3) atom. In the second O site, O(2) is bonded to one Ag(2), two equivalent Ag(1), and one Zn(3) atom to form OZnAg3 tetrahedra that share corners with two equivalent O(4)Zn2Ag2 tetrahedra, corners with four equivalent O(7)Zn2Ag2 tetrahedra,  a cornercorner with one O(9)ZnAg3 trigonal pyramid, and corners with three equivalent O(8)ZnAg3 trigonal pyramids. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Ag(3), two equivalent Ag(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded to one Ag(2), one Ag(4), one Zn(2), and one Zn(5) atom to form distorted OZn2Ag2 tetrahedra that share  a cornercorner with one O(4)Zn2Ag2 tetrahedra,  a cornercorner with one O(2)ZnAg3 tetrahedra, corners with two equivalent O(7)Zn2Ag2 tetrahedra, corners with three equivalent O(12)Zn2Ag2 tetrahedra,  a cornercorner with one O(11)ZnAg3 trigonal pyramid,  a cornercorner with one O(9)ZnAg3 trigonal pyramid, corners with two equivalent O(14)ZnAg3 trigonal pyramids,  an edgeedge with one O(4)Zn2Ag2 tetrahedra,  an edgeedge with one O(6)ZnAg3 trigonal pyramid, and  an edgeedge with one O(9)ZnAg3 trigonal pyramid. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Ag(7), two equivalent Ag(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded to one Ag(5), two equivalent Ag(4), and one Zn(5) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with four equivalent O(12)Zn2Ag2 tetrahedra,  a cornercorner with one O(15)ZnAg3 trigonal pyramid, corners with two equivalent O(11)ZnAg3 trigonal pyramids, corners with three equivalent O(14)ZnAg3 trigonal pyramids, edges with two equivalent O(4)Zn2Ag2 tetrahedra, and  an edgeedge with one O(9)ZnAg3 trigonal pyramid. In the seventh O site, O(7) is bonded to one Ag(1), one Ag(7), one Zn(2), and one Zn(3) atom to form distorted OZn2Ag2 tetrahedra that share  a cornercorner with one O(7)Zn2Ag2 tetrahedra, corners with two equivalent O(4)Zn2Ag2 tetrahedra, corners with two equivalent O(2)ZnAg3 tetrahedra,  a cornercorner with one O(14)ZnAg3 trigonal pyramid,  a cornercorner with one O(9)ZnAg3 trigonal pyramid,  an edgeedge with one O(7)Zn2Ag2 tetrahedra, and  an edgeedge with one O(8)ZnAg3 trigonal pyramid. In the eighth O site, O(8) is bonded to one Ag(9), two equivalent Ag(1), and one Zn(3) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(17)ZnAg3 tetrahedra, corners with three equivalent O(2)ZnAg3 tetrahedra,  a cornercorner with one O(16)Ag4 trigonal pyramid, and edges with two equivalent O(7)Zn2Ag2 tetrahedra. In the ninth O site, O(9) is bonded to one Ag(2), two equivalent Ag(4), and one Zn(2) atom to form distorted OZnAg3 trigonal pyramids that share  a cornercorner with one O(2)ZnAg3 tetrahedra, corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with two equivalent O(4)Zn2Ag2 tetrahedra, corners with two equivalent O(7)Zn2Ag2 tetrahedra, corners with two equivalent O(11)ZnAg3 trigonal pyramids, corners with two equivalent O(14)ZnAg3 trigonal pyramids, edges with two equivalent O(4)Zn2Ag2 tetrahedra, and  an edgeedge with one O(6)ZnAg3 trigonal pyramid. In the tenth O site, O(10) is bonded to one Ag(5), one Ag(6), one Zn(4), and one Zn(6) atom to form distorted OZn2Ag2 tetrahedra that share  a cornercorner with one O(10)Zn2Ag2 tetrahedra, corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with three equivalent O(17)ZnAg3 tetrahedra,  a cornercorner with one O(16)Ag4 trigonal pyramid,  a cornercorner with one O(11)ZnAg3 trigonal pyramid,  a cornercorner with one O(15)ZnAg3 trigonal pyramid,  a cornercorner with one O(6)ZnAg3 trigonal pyramid, corners with two equivalent O(18)ZnAg3 trigonal pyramids,  an edgeedge with one O(10)Zn2Ag2 tetrahedra, and  an edgeedge with one O(15)ZnAg3 trigonal pyramid. In the eleventh O site, O(11) is bonded to one Ag(8), two equivalent Ag(4), and one Zn(4) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with two equivalent O(4)Zn2Ag2 tetrahedra,  a cornercorner with one O(15)ZnAg3 trigonal pyramid,  a cornercorner with one O(18)ZnAg3 trigonal pyramid, corners with two equivalent O(6)ZnAg3 trigonal pyramids, corners with two equivalent O(9)ZnAg3 trigonal pyramids, edges with two equivalent O(12)Zn2Ag2 tetrahedra, and  an edgeedge with one O(14)ZnAg3 trigonal pyramid. In the twelfth O site, O(12) is bonded to one Ag(4), one Ag(8), one Zn(4), and one Zn(5) atom to form distorted OZn2Ag2 tetrahedra that share  a cornercorner with one O(12)Zn2Ag2 tetrahedra, corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with three equivalent O(4)Zn2Ag2 tetrahedra,  a cornercorner with one O(11)ZnAg3 trigonal pyramid,  a cornercorner with one O(15)ZnAg3 trigonal pyramid,  a cornercorner with one O(18)ZnAg3 trigonal pyramid,  a cornercorner with one O(9)ZnAg3 trigonal pyramid, corners with two equivalent O(6)ZnAg3 trigonal pyramids,  an edgeedge with one O(12)Zn2Ag2 tetrahedra,  an edgeedge with one O(11)ZnAg3 trigonal pyramid, and  an edgeedge with one O(14)ZnAg3 trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to two equivalent Ag(6), one Zn(1), and one Zn(6) atom. In the fourteenth O site, O(14) is bonded to one Ag(7), two equivalent Ag(4), and one Zn(5) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(7)Zn2Ag2 tetrahedra, corners with four equivalent O(4)Zn2Ag2 tetrahedra, corners with two equivalent O(9)ZnAg3 trigonal pyramids, corners with three equivalent O(6)ZnAg3 trigonal pyramids, edges with two equivalent O(12)Zn2Ag2 tetrahedra, and  an edgeedge with one O(11)ZnAg3 trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Ag(5), two equivalent Ag(6), and one Zn(4) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with two equivalent O(17)ZnAg3 tetrahedra,  a cornercorner with one O(11)ZnAg3 trigonal pyramid,  a cornercorner with one O(6)ZnAg3 trigonal pyramid, corners with two equivalent O(16)Ag4 trigonal pyramids, corners with two equivalent O(18)ZnAg3 trigonal pyramids, and edges with two equivalent O(10)Zn2Ag2 tetrahedra. In the sixteenth O site, O(16) is bonded to one Ag(3), one Ag(9), and two equivalent Ag(6) atoms to form distorted OAg4 trigonal pyramids that share corners with two equivalent O(10)Zn2Ag2 tetrahedra, corners with two equivalent O(17)ZnAg3 tetrahedra,  a cornercorner with one O(8)ZnAg3 trigonal pyramid, corners with two equivalent O(15)ZnAg3 trigonal pyramids, edges with two equivalent O(17)ZnAg3 tetrahedra, and  an edgeedge with one O(18)ZnAg3 trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Ag(3), one Ag(6), one Ag(9), and one Zn(6) atom to form OZnAg3 tetrahedra that share  a cornercorner with one O(17)ZnAg3 tetrahedra, corners with three equivalent O(10)Zn2Ag2 tetrahedra,  a cornercorner with one O(16)Ag4 trigonal pyramid,  a cornercorner with one O(15)ZnAg3 trigonal pyramid,  a cornercorner with one O(8)ZnAg3 trigonal pyramid,  an edgeedge with one O(17)ZnAg3 tetrahedra,  an edgeedge with one O(16)Ag4 trigonal pyramid, and  an edgeedge with one O(18)ZnAg3 trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Ag(8), two equivalent Ag(6), and one Zn(6) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(12)Zn2Ag2 tetrahedra, corners with four equivalent O(10)Zn2Ag2 tetrahedra,  a cornercorner with one O(11)ZnAg3 trigonal pyramid, corners with two equivalent O(15)ZnAg3 trigonal pyramids, edges with two equivalent O(17)ZnAg3 tetrahedra, and  an edgeedge with one O(16)Ag4 trigonal pyramid. is represented by the CIF card [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.341
_cell_length_b   6.341
_cell_length_c   15.503
_cell_angle_alpha   89.102
_cell_angle_beta   89.102
_cell_angle_gamma   61.619
_symmetry_Int_Tables_number   1
_cell_volume   548.309
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.155  0.155  0.958  1.0
  Zn  Zn1  1  0.834  0.834  0.666  1.0
  Zn  Zn2  1  0.667  0.667  0.831  1.0
  Zn  Zn3  1  0.166  0.166  0.334  1.0
  Zn  Zn4  1  0.000  0.000  0.500  1.0
  Zn  Zn5  1  0.333  0.333  0.169  1.0
  Ag  Ag6  1  0.163  0.668  0.833  1.0
  Ag  Ag7  1  0.490  0.490  0.622  1.0
  Ag  Ag8  1  0.500  0.500  0.999  1.0
  Ag  Ag9  1  0.668  0.163  0.833  1.0
  Ag  Ag10  1  0.500  1.000  0.500  1.0
  Ag  Ag11  1  0.823  0.823  0.290  1.0
  Ag  Ag12  1  1.000  0.500  0.500  1.0
  Ag  Ag13  1  0.840  0.330  0.167  1.0
  Ag  Ag14  1  0.176  0.176  0.711  1.0
  Ag  Ag15  1  0.330  0.840  0.167  1.0
  Ag  Ag16  1  0.510  0.510  0.378  1.0
  Ag  Ag17  1  0.839  0.839  0.044  1.0
  O  O18  1  0.342  0.807  0.913  1.0
  O  O19  1  0.496  0.496  0.768  1.0
  O  O20  1  0.807  0.342  0.913  1.0
  O  O21  1  0.329  0.329  0.915  1.0
  O  O22  1  0.689  0.118  0.577  1.0
  O  O23  1  0.990  0.990  0.751  1.0
  O  O24  1  0.830  0.830  0.429  1.0
  O  O25  1  0.548  0.982  0.755  1.0
  O  O26  1  0.118  0.689  0.577  1.0
  O  O27  1  0.836  0.836  0.901  1.0
  O  O28  1  0.681  0.681  0.577  1.0
  O  O29  1  0.982  0.548  0.755  1.0
  O  O30  1  0.023  0.450  0.243  1.0
  O  O31  1  0.319  0.319  0.423  1.0
  O  O32  1  0.882  0.312  0.424  1.0
  O  O33  1  0.450  0.023  0.243  1.0
  O  O34  1  0.167  0.167  0.087  1.0
  O  O35  1  0.171  0.171  0.571  1.0
  O  O36  1  0.013  0.013  0.245  1.0
  O  O37  1  0.312  0.882  0.424  1.0
  O  O38  1  0.655  0.655  0.091  1.0
  O  O39  1  0.216  0.648  0.089  1.0
  O  O40  1  0.505  0.505  0.237  1.0
  O  O41  1  0.648  0.216  0.089  1.0
[/CIF]
.