The crystal structure described by XeWOF6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeWOF6 clusters. Xe(1) is bonded in a linear geometry to one F(1) and one F(2) atom. W(1) is bonded in a distorted octahedral geometry to one O(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. O(1) is bonded in a single-bond geometry to one W(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Xe(1) and one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF card [CIF]
data_WXeOF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.417
_cell_length_b   5.597
_cell_length_c   12.681
_cell_angle_alpha   87.990
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   738.832
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.007  0.392  0.771  1.0
  W  W1  1  0.993  0.608  0.229  1.0
  W  W2  1  0.507  0.608  0.729  1.0
  W  W3  1  0.493  0.392  0.271  1.0
  Xe  Xe4  1  0.752  0.017  0.979  1.0
  Xe  Xe5  1  0.252  0.983  0.521  1.0
  Xe  Xe6  1  0.248  0.983  0.021  1.0
  Xe  Xe7  1  0.748  0.017  0.479  1.0
  O  O8  1  0.918  0.475  0.337  1.0
  O  O9  1  0.082  0.525  0.663  1.0
  O  O10  1  0.582  0.475  0.837  1.0
  O  O11  1  0.418  0.525  0.163  1.0
  F  F12  1  0.395  0.178  0.960  1.0
  F  F13  1  0.415  0.781  0.584  1.0
  F  F14  1  0.381  0.490  0.380  1.0
  F  F15  1  0.906  0.907  0.226  1.0
  F  F16  1  0.607  0.643  0.306  1.0
  F  F17  1  0.633  0.239  0.203  1.0
  F  F18  1  0.881  0.510  0.120  1.0
  F  F19  1  0.915  0.219  0.916  1.0
  F  F20  1  0.585  0.219  0.416  1.0
  F  F21  1  0.367  0.761  0.797  1.0
  F  F22  1  0.605  0.822  0.040  1.0
  F  F23  1  0.094  0.093  0.774  1.0
  F  F24  1  0.085  0.781  0.084  1.0
  F  F25  1  0.133  0.761  0.297  1.0
  F  F26  1  0.867  0.239  0.703  1.0
  F  F27  1  0.119  0.490  0.880  1.0
  F  F28  1  0.105  0.178  0.460  1.0
  F  F29  1  0.107  0.357  0.194  1.0
  F  F30  1  0.619  0.510  0.620  1.0
  F  F31  1  0.594  0.907  0.726  1.0
  F  F32  1  0.893  0.643  0.806  1.0
  F  F33  1  0.393  0.357  0.694  1.0
  F  F34  1  0.406  0.093  0.274  1.0
  F  F35  1  0.895  0.822  0.540  1.0
[/CIF]
.
The crystal structure described by XeWOF6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeWOF6 clusters. Xe(1) is bonded in a linear geometry to one F(1) and one F(2) atom. W(1) is bonded in a distorted octahedral geometry to one O(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. O(1) is bonded in a single-bond geometry to one W(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Xe(1) and one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF card [CIF]
data_WXeOF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.417
_cell_length_b   5.597
_cell_length_c   12.681
_cell_angle_alpha   87.990
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   738.832
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.007  0.392  0.771  1.0
  W  W1  1  0.993  0.608  0.229  1.0
  W  W2  1  0.507  0.608  0.729  1.0
  W  W3  1  0.493  0.392  0.271  1.0
  Xe  Xe4  1  0.752  0.017  0.979  1.0
  Xe  Xe5  1  0.252  0.983  0.521  1.0
  Xe  Xe6  1  0.248  0.983  0.021  1.0
  Xe  Xe7  1  0.748  0.017  0.479  1.0
  O  O8  1  0.918  0.475  0.337  1.0
  O  O9  1  0.082  0.525  0.663  1.0
  O  O10  1  0.582  0.475  0.837  1.0
  O  O11  1  0.418  0.525  0.163  1.0
  F  F12  1  0.395  0.178  0.960  1.0
  F  F13  1  0.415  0.781  0.584  1.0
  F  F14  1  0.381  0.490  0.380  1.0
  F  F15  1  0.906  0.907  0.226  1.0
  F  F16  1  0.607  0.643  0.306  1.0
  F  F17  1  0.633  0.239  0.203  1.0
  F  F18  1  0.881  0.510  0.120  1.0
  F  F19  1  0.915  0.219  0.916  1.0
  F  F20  1  0.585  0.219  0.416  1.0
  F  F21  1  0.367  0.761  0.797  1.0
  F  F22  1  0.605  0.822  0.040  1.0
  F  F23  1  0.094  0.093  0.774  1.0
  F  F24  1  0.085  0.781  0.084  1.0
  F  F25  1  0.133  0.761  0.297  1.0
  F  F26  1  0.867  0.239  0.703  1.0
  F  F27  1  0.119  0.490  0.880  1.0
  F  F28  1  0.105  0.178  0.460  1.0
  F  F29  1  0.107  0.357  0.194  1.0
  F  F30  1  0.619  0.510  0.620  1.0
  F  F31  1  0.594  0.907  0.726  1.0
  F  F32  1  0.893  0.643  0.806  1.0
  F  F33  1  0.393  0.357  0.694  1.0
  F  F34  1  0.406  0.093  0.274  1.0
  F  F35  1  0.895  0.822  0.540  1.0
[/CIF]
.