The material structure described by SmLa7Ti2V6O24 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Amm2 space group. Sm(1) is bonded to one O(4), one O(6), two equivalent O(5), four equivalent O(7), and four equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(5)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent La(4)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(3), two equivalent O(2), four equivalent O(7), and four equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(3)O12 cuboctahedra, corners with eight equivalent La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. In the second La site, La(2) is bonded to one O(1), one O(3), two equivalent O(10), two equivalent O(2), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(3), two equivalent O(2), four equivalent O(10), and four equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent La(4)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. In the fourth La site, La(4) is bonded to one O(4), one O(6), two equivalent O(10), two equivalent O(5), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. In the fifth La site, La(5) is bonded to one O(4), one O(6), two equivalent O(5), four equivalent O(10), and four equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra, faces with four equivalent La(4)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. Ti(1) is bonded to one O(1), one O(4), two equivalent O(7), and two equivalent O(9) atoms to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(3), one O(6), two equivalent O(10), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with four equivalent V(1)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), and two equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), and two equivalent V(1) atoms. In the third O site, O(3) is bonded to one La(1), one La(3), two equivalent La(2), and two equivalent V(2) atoms to form distorted corner-sharing OLa4V2 octahedra. The corner-sharing octahedral tilt angles are 1°. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sm(1), one La(5), two equivalent La(4), and two equivalent Ti(1) atoms. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(5), two equivalent La(4), and two equivalent V(1) atoms. In the sixth O site, O(6) is bonded to one Sm(1), one La(5), two equivalent La(4), and two equivalent V(2) atoms to form distorted corner-sharing OLa3SmV2 octahedra. The corner-sharing octahedral tilt angles are 1°. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(4), one Ti(1), and one V(1) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(4), one V(1), and one V(2) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one La(2), one La(3), one La(4), one La(5), one Ti(1), and one V(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one La(2), one La(3), one La(4), one La(5), one V(1), and one V(2) atom. is represented by the CIF file [CIF]
data_La7SmTi2V6O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.937
_cell_length_b   7.937
_cell_length_c   7.894
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.110
_symmetry_Int_Tables_number   1
_cell_volume   497.246
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.254  0.254  0.000  1.0
  La  La1  1  0.747  0.253  0.000  1.0
  La  La2  1  0.253  0.747  0.000  1.0
  La  La3  1  0.746  0.746  0.000  1.0
  La  La4  1  0.747  0.253  0.500  1.0
  La  La5  1  0.253  0.747  0.500  1.0
  La  La6  1  0.746  0.746  0.500  1.0
  Sm  Sm7  1  0.255  0.255  0.500  1.0
  Ti  Ti8  1  0.001  0.001  0.749  1.0
  Ti  Ti9  1  0.001  0.001  0.251  1.0
  V  V10  1  0.500  0.000  0.750  1.0
  V  V11  1  0.000  0.500  0.750  1.0
  V  V12  1  0.500  0.500  0.750  1.0
  V  V13  1  0.500  0.000  0.250  1.0
  V  V14  1  0.000  0.500  0.250  1.0
  V  V15  1  0.500  0.500  0.250  1.0
  O  O16  1  0.000  0.000  0.000  1.0
  O  O17  1  0.500  0.000  0.000  1.0
  O  O18  1  0.000  0.500  0.000  1.0
  O  O19  1  0.500  0.500  0.000  1.0
  O  O20  1  0.001  0.001  0.500  1.0
  O  O21  1  0.498  0.002  0.500  1.0
  O  O22  1  0.002  0.498  0.500  1.0
  O  O23  1  0.497  0.497  0.500  1.0
  O  O24  1  0.002  0.245  0.748  1.0
  O  O25  1  0.499  0.248  0.748  1.0
  O  O26  1  1.000  0.755  0.750  1.0
  O  O27  1  0.499  0.752  0.750  1.0
  O  O28  1  0.002  0.245  0.252  1.0
  O  O29  1  0.499  0.248  0.252  1.0
  O  O30  1  1.000  0.755  0.250  1.0
  O  O31  1  0.499  0.752  0.250  1.0
  O  O32  1  0.245  0.002  0.748  1.0
  O  O33  1  0.755  1.000  0.750  1.0
  O  O34  1  0.248  0.499  0.748  1.0
  O  O35  1  0.752  0.499  0.750  1.0
  O  O36  1  0.245  0.002  0.252  1.0
  O  O37  1  0.755  1.000  0.250  1.0
  O  O38  1  0.248  0.499  0.252  1.0
  O  O39  1  0.752  0.499  0.250  1.0
[/CIF]
.
The material structure described by SmLa7Ti2V6O24 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Amm2 space group. Sm(1) is bonded to one O(4), one O(6), two equivalent O(5), four equivalent O(7), and four equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(5)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent La(4)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(3), two equivalent O(2), four equivalent O(7), and four equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(3)O12 cuboctahedra, corners with eight equivalent La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. In the second La site, La(2) is bonded to one O(1), one O(3), two equivalent O(10), two equivalent O(2), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(3), two equivalent O(2), four equivalent O(10), and four equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent La(4)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. In the fourth La site, La(4) is bonded to one O(4), one O(6), two equivalent O(10), two equivalent O(5), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. In the fifth La site, La(5) is bonded to one O(4), one O(6), two equivalent O(5), four equivalent O(10), and four equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra, faces with four equivalent La(4)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent V(2)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. Ti(1) is bonded to one O(1), one O(4), two equivalent O(7), and two equivalent O(9) atoms to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(3), one O(6), two equivalent O(10), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with four equivalent V(1)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), and two equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), and two equivalent V(1) atoms. In the third O site, O(3) is bonded to one La(1), one La(3), two equivalent La(2), and two equivalent V(2) atoms to form distorted corner-sharing OLa4V2 octahedra. The corner-sharing octahedral tilt angles are 1°. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sm(1), one La(5), two equivalent La(4), and two equivalent Ti(1) atoms. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(5), two equivalent La(4), and two equivalent V(1) atoms. In the sixth O site, O(6) is bonded to one Sm(1), one La(5), two equivalent La(4), and two equivalent V(2) atoms to form distorted corner-sharing OLa3SmV2 octahedra. The corner-sharing octahedral tilt angles are 1°. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(4), one Ti(1), and one V(1) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(4), one V(1), and one V(2) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one La(2), one La(3), one La(4), one La(5), one Ti(1), and one V(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one La(2), one La(3), one La(4), one La(5), one V(1), and one V(2) atom. is represented by the CIF file [CIF]
data_La7SmTi2V6O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.937
_cell_length_b   7.937
_cell_length_c   7.894
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.110
_symmetry_Int_Tables_number   1
_cell_volume   497.246
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.254  0.254  0.000  1.0
  La  La1  1  0.747  0.253  0.000  1.0
  La  La2  1  0.253  0.747  0.000  1.0
  La  La3  1  0.746  0.746  0.000  1.0
  La  La4  1  0.747  0.253  0.500  1.0
  La  La5  1  0.253  0.747  0.500  1.0
  La  La6  1  0.746  0.746  0.500  1.0
  Sm  Sm7  1  0.255  0.255  0.500  1.0
  Ti  Ti8  1  0.001  0.001  0.749  1.0
  Ti  Ti9  1  0.001  0.001  0.251  1.0
  V  V10  1  0.500  0.000  0.750  1.0
  V  V11  1  0.000  0.500  0.750  1.0
  V  V12  1  0.500  0.500  0.750  1.0
  V  V13  1  0.500  0.000  0.250  1.0
  V  V14  1  0.000  0.500  0.250  1.0
  V  V15  1  0.500  0.500  0.250  1.0
  O  O16  1  0.000  0.000  0.000  1.0
  O  O17  1  0.500  0.000  0.000  1.0
  O  O18  1  0.000  0.500  0.000  1.0
  O  O19  1  0.500  0.500  0.000  1.0
  O  O20  1  0.001  0.001  0.500  1.0
  O  O21  1  0.498  0.002  0.500  1.0
  O  O22  1  0.002  0.498  0.500  1.0
  O  O23  1  0.497  0.497  0.500  1.0
  O  O24  1  0.002  0.245  0.748  1.0
  O  O25  1  0.499  0.248  0.748  1.0
  O  O26  1  1.000  0.755  0.750  1.0
  O  O27  1  0.499  0.752  0.750  1.0
  O  O28  1  0.002  0.245  0.252  1.0
  O  O29  1  0.499  0.248  0.252  1.0
  O  O30  1  1.000  0.755  0.250  1.0
  O  O31  1  0.499  0.752  0.250  1.0
  O  O32  1  0.245  0.002  0.748  1.0
  O  O33  1  0.755  1.000  0.750  1.0
  O  O34  1  0.248  0.499  0.748  1.0
  O  O35  1  0.752  0.499  0.750  1.0
  O  O36  1  0.245  0.002  0.252  1.0
  O  O37  1  0.755  1.000  0.250  1.0
  O  O38  1  0.248  0.499  0.252  1.0
  O  O39  1  0.752  0.499  0.250  1.0
[/CIF]
.