The material described by KCo(CO)4 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. Co(1) is bonded in a tetrahedral geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one O(4) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(1) and one O(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one C(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one K(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one K(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KCo(CO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.558
_cell_length_b   11.558
_cell_length_c   14.641
_cell_angle_alpha   54.786
_cell_angle_beta   54.786
_cell_angle_gamma   29.015
_symmetry_Int_Tables_number   1
_cell_volume   761.991
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.124  0.222  0.942  1.0
  K  K1  1  0.778  0.876  0.558  1.0
  K  K2  1  0.876  0.778  0.058  1.0
  K  K3  1  0.222  0.124  0.442  1.0
  Co  Co4  1  0.823  0.422  0.744  1.0
  Co  Co5  1  0.422  0.823  0.244  1.0
  Co  Co6  1  0.578  0.177  0.756  1.0
  Co  Co7  1  0.177  0.578  0.256  1.0
  C  C8  1  0.352  0.360  0.189  1.0
  C  C9  1  0.803  0.121  0.655  1.0
  C  C10  1  0.633  0.580  0.664  1.0
  C  C11  1  0.879  0.197  0.845  1.0
  C  C12  1  0.899  0.726  0.339  1.0
  C  C13  1  0.420  0.367  0.836  1.0
  C  C14  1  0.121  0.803  0.155  1.0
  C  C15  1  0.580  0.633  0.164  1.0
  C  C16  1  0.648  0.640  0.811  1.0
  C  C17  1  0.726  0.899  0.839  1.0
  C  C18  1  0.367  0.420  0.336  1.0
  C  C19  1  0.101  0.274  0.661  1.0
  C  C20  1  0.197  0.879  0.345  1.0
  C  C21  1  0.640  0.648  0.311  1.0
  C  C22  1  0.360  0.352  0.689  1.0
  C  C23  1  0.274  0.101  0.161  1.0
  O  O24  1  0.708  0.834  0.397  1.0
  O  O25  1  0.951  0.088  0.590  1.0
  O  O26  1  0.049  0.912  0.410  1.0
  O  O27  1  0.481  0.204  0.147  1.0
  O  O28  1  0.796  0.519  0.353  1.0
  O  O29  1  0.691  0.500  0.111  1.0
  O  O30  1  0.519  0.796  0.853  1.0
  O  O31  1  0.500  0.691  0.611  1.0
  O  O32  1  0.500  0.309  0.389  1.0
  O  O33  1  0.834  0.708  0.897  1.0
  O  O34  1  0.912  0.049  0.910  1.0
  O  O35  1  0.088  0.951  0.090  1.0
  O  O36  1  0.204  0.481  0.647  1.0
  O  O37  1  0.166  0.292  0.103  1.0
  O  O38  1  0.292  0.166  0.603  1.0
  O  O39  1  0.309  0.500  0.889  1.0
[/CIF]
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The material described by KCo(CO)4 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. Co(1) is bonded in a tetrahedral geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one O(4) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(1) and one O(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one C(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one K(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one K(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KCo(CO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.558
_cell_length_b   11.558
_cell_length_c   14.641
_cell_angle_alpha   54.786
_cell_angle_beta   54.786
_cell_angle_gamma   29.015
_symmetry_Int_Tables_number   1
_cell_volume   761.991
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.124  0.222  0.942  1.0
  K  K1  1  0.778  0.876  0.558  1.0
  K  K2  1  0.876  0.778  0.058  1.0
  K  K3  1  0.222  0.124  0.442  1.0
  Co  Co4  1  0.823  0.422  0.744  1.0
  Co  Co5  1  0.422  0.823  0.244  1.0
  Co  Co6  1  0.578  0.177  0.756  1.0
  Co  Co7  1  0.177  0.578  0.256  1.0
  C  C8  1  0.352  0.360  0.189  1.0
  C  C9  1  0.803  0.121  0.655  1.0
  C  C10  1  0.633  0.580  0.664  1.0
  C  C11  1  0.879  0.197  0.845  1.0
  C  C12  1  0.899  0.726  0.339  1.0
  C  C13  1  0.420  0.367  0.836  1.0
  C  C14  1  0.121  0.803  0.155  1.0
  C  C15  1  0.580  0.633  0.164  1.0
  C  C16  1  0.648  0.640  0.811  1.0
  C  C17  1  0.726  0.899  0.839  1.0
  C  C18  1  0.367  0.420  0.336  1.0
  C  C19  1  0.101  0.274  0.661  1.0
  C  C20  1  0.197  0.879  0.345  1.0
  C  C21  1  0.640  0.648  0.311  1.0
  C  C22  1  0.360  0.352  0.689  1.0
  C  C23  1  0.274  0.101  0.161  1.0
  O  O24  1  0.708  0.834  0.397  1.0
  O  O25  1  0.951  0.088  0.590  1.0
  O  O26  1  0.049  0.912  0.410  1.0
  O  O27  1  0.481  0.204  0.147  1.0
  O  O28  1  0.796  0.519  0.353  1.0
  O  O29  1  0.691  0.500  0.111  1.0
  O  O30  1  0.519  0.796  0.853  1.0
  O  O31  1  0.500  0.691  0.611  1.0
  O  O32  1  0.500  0.309  0.389  1.0
  O  O33  1  0.834  0.708  0.897  1.0
  O  O34  1  0.912  0.049  0.910  1.0
  O  O35  1  0.088  0.951  0.090  1.0
  O  O36  1  0.204  0.481  0.647  1.0
  O  O37  1  0.166  0.292  0.103  1.0
  O  O38  1  0.292  0.166  0.603  1.0
  O  O39  1  0.309  0.500  0.889  1.0
[/CIF]
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