The material described by CsCo(CO)4 crystallizes in the tetragonal I-4 space group. Cs(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Co(1) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. O(1) is bonded in a distorted single-bond geometry to one Cs(1) and one C(1) atom. is represented by the CIF card [CIF]
data_CsCo(CO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.694
_cell_length_b   6.694
_cell_length_c   6.694
_cell_angle_alpha   99.626
_cell_angle_beta   99.626
_cell_angle_gamma   131.727
_symmetry_Int_Tables_number   1
_cell_volume   204.267
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.250  0.750  0.500  1.0
  C  C2  1  0.210  0.609  0.703  1.0
  C  C3  1  0.493  0.790  0.399  1.0
  C  C4  1  0.906  0.507  0.297  1.0
  C  C5  1  0.391  0.094  0.601  1.0
  O  O6  1  0.660  0.821  0.331  1.0
  O  O7  1  0.179  0.510  0.838  1.0
  O  O8  1  0.671  0.340  0.162  1.0
  O  O9  1  0.490  0.329  0.669  1.0
[/CIF]
.
The material described by CsCo(CO)4 crystallizes in the tetragonal I-4 space group. Cs(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Co(1) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. O(1) is bonded in a distorted single-bond geometry to one Cs(1) and one C(1) atom. is represented by the CIF card [CIF]
data_CsCo(CO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.694
_cell_length_b   6.694
_cell_length_c   6.694
_cell_angle_alpha   99.626
_cell_angle_beta   99.626
_cell_angle_gamma   131.727
_symmetry_Int_Tables_number   1
_cell_volume   204.267
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.250  0.750  0.500  1.0
  C  C2  1  0.210  0.609  0.703  1.0
  C  C3  1  0.493  0.790  0.399  1.0
  C  C4  1  0.906  0.507  0.297  1.0
  C  C5  1  0.391  0.094  0.601  1.0
  O  O6  1  0.660  0.821  0.331  1.0
  O  O7  1  0.179  0.510  0.838  1.0
  O  O8  1  0.671  0.340  0.162  1.0
  O  O9  1  0.490  0.329  0.669  1.0
[/CIF]
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