The crystal structure described by LiSr4Mn2Ga2O11 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a rectangular see-saw-like geometry to one O(11), one O(3), one O(4), and one O(7) atom. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the third Sr site, Sr(3) is bonded in a 4-coordinate geometry to one O(10), one O(3), one O(5), one O(6), and one O(8) atom. In the fourth Sr site, Sr(4) is bonded in a 4-coordinate geometry to one O(10), one O(4), one O(5), one O(6), one O(8), and two equivalent O(3) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with four equivalent Mn(2)O6 octahedra,  a cornercorner with one Ga(1)O5 trigonal bipyramid, and  a cornercorner with one Ga(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-17°. In the second Mn site, Mn(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra,  a cornercorner with one Ga(1)O5 trigonal bipyramid, and  a cornercorner with one Ga(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-17°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(2), one O(3), and one O(9) atom to form GaO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with three equivalent Ga(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 27-33°. In the second Ga site, Ga(2) is bonded to one O(1), one O(10), one O(11), one O(4), and one O(9) atom to form GaO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with three equivalent Ga(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 28-32°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Mn(1), and one Ga(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Mn(2), and one Ga(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Li(1), one Sr(3), two equivalent Sr(4), one Mn(1), and one Ga(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Sr(4), one Mn(2), and one Ga(2) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Li(1), one Sr(1), one Sr(2), one Mn(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a distorted octahedral geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ga(1), and one Ga(2) atom. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ga(1), and one Ga(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Li(1), one Sr(1), one Sr(2), one Ga(1), and one Ga(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4LiMn2Ga2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.752
_cell_length_b   5.813
_cell_length_c   8.528
_cell_angle_alpha   71.371
_cell_angle_beta   71.615
_cell_angle_gamma   93.632
_symmetry_Int_Tables_number   1
_cell_volume   252.088
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.138  0.633  0.739  1.0
  Sr  Sr1  1  0.620  0.129  0.740  1.0
  Sr  Sr2  1  0.408  0.821  0.265  1.0
  Sr  Sr3  1  0.826  0.414  0.267  1.0
  Li  Li4  1  0.129  0.130  0.238  1.0
  Mn  Mn5  1  0.241  0.241  0.507  1.0
  Mn  Mn6  1  0.750  0.752  0.507  1.0
  Ga  Ga7  1  0.531  0.475  0.993  1.0
  Ga  Ga8  1  0.976  0.030  0.994  1.0
  O  O9  1  0.162  0.063  0.756  1.0
  O  O10  1  0.579  0.682  0.757  1.0
  O  O11  1  0.323  0.403  0.245  1.0
  O  O12  1  0.936  0.849  0.242  1.0
  O  O13  1  0.530  0.005  0.465  1.0
  O  O14  1  0.968  0.494  0.537  1.0
  O  O15  1  0.004  0.003  0.491  1.0
  O  O16  1  0.498  0.499  0.502  1.0
  O  O17  1  0.753  0.252  0.997  1.0
  O  O18  1  0.741  0.741  0.017  1.0
  O  O19  1  0.257  0.253  0.990  1.0
[/CIF]
.
The crystal structure described by LiSr4Mn2Ga2O11 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a rectangular see-saw-like geometry to one O(11), one O(3), one O(4), and one O(7) atom. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the third Sr site, Sr(3) is bonded in a 4-coordinate geometry to one O(10), one O(3), one O(5), one O(6), and one O(8) atom. In the fourth Sr site, Sr(4) is bonded in a 4-coordinate geometry to one O(10), one O(4), one O(5), one O(6), one O(8), and two equivalent O(3) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with four equivalent Mn(2)O6 octahedra,  a cornercorner with one Ga(1)O5 trigonal bipyramid, and  a cornercorner with one Ga(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-17°. In the second Mn site, Mn(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra,  a cornercorner with one Ga(1)O5 trigonal bipyramid, and  a cornercorner with one Ga(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-17°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(2), one O(3), and one O(9) atom to form GaO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with three equivalent Ga(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 27-33°. In the second Ga site, Ga(2) is bonded to one O(1), one O(10), one O(11), one O(4), and one O(9) atom to form GaO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with three equivalent Ga(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 28-32°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Mn(1), and one Ga(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Mn(2), and one Ga(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Li(1), one Sr(3), two equivalent Sr(4), one Mn(1), and one Ga(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Sr(4), one Mn(2), and one Ga(2) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Li(1), one Sr(1), one Sr(2), one Mn(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a distorted octahedral geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ga(1), and one Ga(2) atom. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ga(1), and one Ga(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Li(1), one Sr(1), one Sr(2), one Ga(1), and one Ga(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4LiMn2Ga2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.752
_cell_length_b   5.813
_cell_length_c   8.528
_cell_angle_alpha   71.371
_cell_angle_beta   71.615
_cell_angle_gamma   93.632
_symmetry_Int_Tables_number   1
_cell_volume   252.088
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.138  0.633  0.739  1.0
  Sr  Sr1  1  0.620  0.129  0.740  1.0
  Sr  Sr2  1  0.408  0.821  0.265  1.0
  Sr  Sr3  1  0.826  0.414  0.267  1.0
  Li  Li4  1  0.129  0.130  0.238  1.0
  Mn  Mn5  1  0.241  0.241  0.507  1.0
  Mn  Mn6  1  0.750  0.752  0.507  1.0
  Ga  Ga7  1  0.531  0.475  0.993  1.0
  Ga  Ga8  1  0.976  0.030  0.994  1.0
  O  O9  1  0.162  0.063  0.756  1.0
  O  O10  1  0.579  0.682  0.757  1.0
  O  O11  1  0.323  0.403  0.245  1.0
  O  O12  1  0.936  0.849  0.242  1.0
  O  O13  1  0.530  0.005  0.465  1.0
  O  O14  1  0.968  0.494  0.537  1.0
  O  O15  1  0.004  0.003  0.491  1.0
  O  O16  1  0.498  0.499  0.502  1.0
  O  O17  1  0.753  0.252  0.997  1.0
  O  O18  1  0.741  0.741  0.017  1.0
  O  O19  1  0.257  0.253  0.990  1.0
[/CIF]
.