The material described by Co(NO5)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Co(NO5)2 cluster. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Co(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Co(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.532
_cell_length_b   5.916
_cell_length_c   7.475
_cell_angle_alpha   109.596
_cell_angle_beta   86.373
_cell_angle_gamma   113.655
_symmetry_Int_Tables_number   1
_cell_volume   210.376
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.753  0.191  0.381  1.0
  N  N2  1  0.247  0.809  0.619  1.0
  O  O3  1  0.735  0.699  0.892  1.0
  O  O4  1  0.265  0.301  0.108  1.0
  O  O5  1  0.042  0.803  0.116  1.0
  O  O6  1  0.958  0.197  0.884  1.0
  O  O7  1  0.716  0.105  0.199  1.0
  O  O8  1  0.284  0.895  0.801  1.0
  O  O9  1  0.949  0.208  0.464  1.0
  O  O10  1  0.051  0.792  0.536  1.0
  O  O11  1  0.581  0.259  0.470  1.0
  O  O12  1  0.419  0.741  0.530  1.0
[/CIF]
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The material described by Co(NO5)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Co(NO5)2 cluster. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Co(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Co(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.532
_cell_length_b   5.916
_cell_length_c   7.475
_cell_angle_alpha   109.596
_cell_angle_beta   86.373
_cell_angle_gamma   113.655
_symmetry_Int_Tables_number   1
_cell_volume   210.376
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.753  0.191  0.381  1.0
  N  N2  1  0.247  0.809  0.619  1.0
  O  O3  1  0.735  0.699  0.892  1.0
  O  O4  1  0.265  0.301  0.108  1.0
  O  O5  1  0.042  0.803  0.116  1.0
  O  O6  1  0.958  0.197  0.884  1.0
  O  O7  1  0.716  0.105  0.199  1.0
  O  O8  1  0.284  0.895  0.801  1.0
  O  O9  1  0.949  0.208  0.464  1.0
  O  O10  1  0.051  0.792  0.536  1.0
  O  O11  1  0.581  0.259  0.470  1.0
  O  O12  1  0.419  0.741  0.530  1.0
[/CIF]
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