The crystal structure described by Yb2WO6 crystallizes in the monoclinic P2/c space group. There are three inequivalent Yb sites. In the first Yb site, Yb(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. In the second Yb site, Yb(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. In the third Yb site, Yb(3) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms. W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Yb(1), one Yb(3), and one W(1) atom. In the second O site, O(1) is bonded to one Yb(1), one Yb(2), one Yb(3), and one W(1) atom to form corner-sharing OYb3W tetrahedra. In the third O site, O(2) is bonded to one Yb(3), two equivalent Yb(1), and one W(1) atom to form a mixture of edge and corner-sharing OYb3W tetrahedra. In the fourth O site, O(3) is bonded in a 4-coordinate geometry to one Yb(1), one Yb(2), one Yb(3), and one W(1) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to one Yb(1), one Yb(2), and one W(1) atom. In the sixth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Yb(1), one Yb(2), and one W(1) atom. is represented by the CIF card [CIF]
data_Yb2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.546
_cell_length_b   7.491
_cell_length_c   10.945
_cell_angle_alpha   79.880
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   447.643
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.191  0.195  0.416  1.0
  Yb  Yb1  1  0.191  0.805  0.084  1.0
  Yb  Yb2  1  0.809  0.805  0.584  1.0
  Yb  Yb3  1  0.809  0.195  0.916  1.0
  Yb  Yb4  1  0.670  0.500  0.250  1.0
  Yb  Yb5  1  0.330  0.500  0.750  1.0
  Yb  Yb6  1  0.737  0.000  0.250  1.0
  Yb  Yb7  1  0.263  0.000  0.750  1.0
  W  W8  1  0.250  0.294  0.098  1.0
  W  W9  1  0.250  0.706  0.402  1.0
  W  W10  1  0.750  0.706  0.902  1.0
  W  W11  1  0.750  0.294  0.598  1.0
  O  O12  1  0.459  0.217  0.252  1.0
  O  O13  1  0.459  0.783  0.248  1.0
  O  O14  1  0.541  0.783  0.748  1.0
  O  O15  1  0.541  0.217  0.752  1.0
  O  O16  1  0.025  0.076  0.103  1.0
  O  O17  1  0.025  0.924  0.397  1.0
  O  O18  1  0.975  0.924  0.897  1.0
  O  O19  1  0.975  0.076  0.603  1.0
  O  O20  1  0.984  0.288  0.212  1.0
  O  O21  1  0.984  0.712  0.288  1.0
  O  O22  1  0.016  0.712  0.788  1.0
  O  O23  1  0.016  0.288  0.712  1.0
  O  O24  1  0.837  0.348  0.435  1.0
  O  O25  1  0.837  0.652  0.065  1.0
  O  O26  1  0.163  0.652  0.565  1.0
  O  O27  1  0.163  0.348  0.935  1.0
  O  O28  1  0.659  0.522  0.610  1.0
  O  O29  1  0.659  0.478  0.890  1.0
  O  O30  1  0.341  0.478  0.390  1.0
  O  O31  1  0.341  0.522  0.110  1.0
  O  O32  1  0.486  0.144  0.569  1.0
  O  O33  1  0.486  0.856  0.931  1.0
  O  O34  1  0.514  0.856  0.431  1.0
  O  O35  1  0.514  0.144  0.069  1.0
[/CIF]
.
The crystal structure described by Yb2WO6 crystallizes in the monoclinic P2/c space group. There are three inequivalent Yb sites. In the first Yb site, Yb(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. In the second Yb site, Yb(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. In the third Yb site, Yb(3) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms. W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Yb(1), one Yb(3), and one W(1) atom. In the second O site, O(1) is bonded to one Yb(1), one Yb(2), one Yb(3), and one W(1) atom to form corner-sharing OYb3W tetrahedra. In the third O site, O(2) is bonded to one Yb(3), two equivalent Yb(1), and one W(1) atom to form a mixture of edge and corner-sharing OYb3W tetrahedra. In the fourth O site, O(3) is bonded in a 4-coordinate geometry to one Yb(1), one Yb(2), one Yb(3), and one W(1) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to one Yb(1), one Yb(2), and one W(1) atom. In the sixth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Yb(1), one Yb(2), and one W(1) atom. is represented by the CIF card [CIF]
data_Yb2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.546
_cell_length_b   7.491
_cell_length_c   10.945
_cell_angle_alpha   79.880
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   447.643
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.191  0.195  0.416  1.0
  Yb  Yb1  1  0.191  0.805  0.084  1.0
  Yb  Yb2  1  0.809  0.805  0.584  1.0
  Yb  Yb3  1  0.809  0.195  0.916  1.0
  Yb  Yb4  1  0.670  0.500  0.250  1.0
  Yb  Yb5  1  0.330  0.500  0.750  1.0
  Yb  Yb6  1  0.737  0.000  0.250  1.0
  Yb  Yb7  1  0.263  0.000  0.750  1.0
  W  W8  1  0.250  0.294  0.098  1.0
  W  W9  1  0.250  0.706  0.402  1.0
  W  W10  1  0.750  0.706  0.902  1.0
  W  W11  1  0.750  0.294  0.598  1.0
  O  O12  1  0.459  0.217  0.252  1.0
  O  O13  1  0.459  0.783  0.248  1.0
  O  O14  1  0.541  0.783  0.748  1.0
  O  O15  1  0.541  0.217  0.752  1.0
  O  O16  1  0.025  0.076  0.103  1.0
  O  O17  1  0.025  0.924  0.397  1.0
  O  O18  1  0.975  0.924  0.897  1.0
  O  O19  1  0.975  0.076  0.603  1.0
  O  O20  1  0.984  0.288  0.212  1.0
  O  O21  1  0.984  0.712  0.288  1.0
  O  O22  1  0.016  0.712  0.788  1.0
  O  O23  1  0.016  0.288  0.712  1.0
  O  O24  1  0.837  0.348  0.435  1.0
  O  O25  1  0.837  0.652  0.065  1.0
  O  O26  1  0.163  0.652  0.565  1.0
  O  O27  1  0.163  0.348  0.935  1.0
  O  O28  1  0.659  0.522  0.610  1.0
  O  O29  1  0.659  0.478  0.890  1.0
  O  O30  1  0.341  0.478  0.390  1.0
  O  O31  1  0.341  0.522  0.110  1.0
  O  O32  1  0.486  0.144  0.569  1.0
  O  O33  1  0.486  0.856  0.931  1.0
  O  O34  1  0.514  0.856  0.431  1.0
  O  O35  1  0.514  0.144  0.069  1.0
[/CIF]
.