The material described by CoN5Br3 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CoN5Br3 clusters. Co(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), and two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a T-shaped geometry to one Co(1) and two equivalent N(4) atoms. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Co(1) and one Br(1) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Co(1) and two equivalent Br(2) atoms. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one Co(1) and one N(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one N(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoBr3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.491
_cell_length_b   10.480
_cell_length_c   16.574
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1127.463
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.231  0.750  0.348  1.0
  Co  Co1  1  0.269  0.750  0.848  1.0
  Co  Co2  1  0.769  0.250  0.652  1.0
  Co  Co3  1  0.731  0.250  0.152  1.0
  Br  Br4  1  0.083  0.750  0.658  1.0
  Br  Br5  1  0.417  0.750  0.158  1.0
  Br  Br6  1  0.917  0.250  0.342  1.0
  Br  Br7  1  0.583  0.250  0.842  1.0
  Br  Br8  1  0.683  0.900  0.812  1.0
  Br  Br9  1  0.817  0.600  0.312  1.0
  Br  Br10  1  0.317  0.400  0.188  1.0
  Br  Br11  1  0.183  0.100  0.688  1.0
  Br  Br12  1  0.317  0.100  0.188  1.0
  Br  Br13  1  0.183  0.400  0.688  1.0
  Br  Br14  1  0.683  0.600  0.812  1.0
  Br  Br15  1  0.817  0.900  0.312  1.0
  N  N16  1  0.265  0.750  0.468  1.0
  N  N17  1  0.235  0.750  0.968  1.0
  N  N18  1  0.735  0.250  0.532  1.0
  N  N19  1  0.765  0.250  0.032  1.0
  N  N20  1  0.353  0.750  0.264  1.0
  N  N21  1  0.147  0.750  0.764  1.0
  N  N22  1  0.647  0.250  0.736  1.0
  N  N23  1  0.853  0.250  0.236  1.0
  N  N24  1  0.955  0.750  0.345  1.0
  N  N25  1  0.545  0.750  0.845  1.0
  N  N26  1  0.045  0.250  0.655  1.0
  N  N27  1  0.455  0.250  0.155  1.0
  N  N28  1  0.259  0.636  0.461  1.0
  N  N29  1  0.241  0.864  0.961  1.0
  N  N30  1  0.741  0.136  0.539  1.0
  N  N31  1  0.759  0.364  0.039  1.0
  N  N32  1  0.741  0.364  0.539  1.0
  N  N33  1  0.759  0.136  0.039  1.0
  N  N34  1  0.259  0.864  0.461  1.0
  N  N35  1  0.241  0.636  0.961  1.0
[/CIF]
.
The material described by CoN5Br3 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CoN5Br3 clusters. Co(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), and two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a T-shaped geometry to one Co(1) and two equivalent N(4) atoms. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Co(1) and one Br(1) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Co(1) and two equivalent Br(2) atoms. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one Co(1) and one N(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one N(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoBr3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.491
_cell_length_b   10.480
_cell_length_c   16.574
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1127.463
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.231  0.750  0.348  1.0
  Co  Co1  1  0.269  0.750  0.848  1.0
  Co  Co2  1  0.769  0.250  0.652  1.0
  Co  Co3  1  0.731  0.250  0.152  1.0
  Br  Br4  1  0.083  0.750  0.658  1.0
  Br  Br5  1  0.417  0.750  0.158  1.0
  Br  Br6  1  0.917  0.250  0.342  1.0
  Br  Br7  1  0.583  0.250  0.842  1.0
  Br  Br8  1  0.683  0.900  0.812  1.0
  Br  Br9  1  0.817  0.600  0.312  1.0
  Br  Br10  1  0.317  0.400  0.188  1.0
  Br  Br11  1  0.183  0.100  0.688  1.0
  Br  Br12  1  0.317  0.100  0.188  1.0
  Br  Br13  1  0.183  0.400  0.688  1.0
  Br  Br14  1  0.683  0.600  0.812  1.0
  Br  Br15  1  0.817  0.900  0.312  1.0
  N  N16  1  0.265  0.750  0.468  1.0
  N  N17  1  0.235  0.750  0.968  1.0
  N  N18  1  0.735  0.250  0.532  1.0
  N  N19  1  0.765  0.250  0.032  1.0
  N  N20  1  0.353  0.750  0.264  1.0
  N  N21  1  0.147  0.750  0.764  1.0
  N  N22  1  0.647  0.250  0.736  1.0
  N  N23  1  0.853  0.250  0.236  1.0
  N  N24  1  0.955  0.750  0.345  1.0
  N  N25  1  0.545  0.750  0.845  1.0
  N  N26  1  0.045  0.250  0.655  1.0
  N  N27  1  0.455  0.250  0.155  1.0
  N  N28  1  0.259  0.636  0.461  1.0
  N  N29  1  0.241  0.864  0.961  1.0
  N  N30  1  0.741  0.136  0.539  1.0
  N  N31  1  0.759  0.364  0.039  1.0
  N  N32  1  0.741  0.364  0.539  1.0
  N  N33  1  0.759  0.136  0.039  1.0
  N  N34  1  0.259  0.864  0.461  1.0
  N  N35  1  0.241  0.636  0.961  1.0
[/CIF]
.