The compound described by PuTe2O6 crystallizes in the monoclinic P2_1/c space group. Pu(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a trigonal planar geometry to two equivalent Pu(1) and one Te(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Pu(1) and one Te(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to one Pu(1) and one Te(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Pu(1) and one Te(1) atom. In the fifth O site, O(4) is bonded in a 3-coordinate geometry to one Pu(1), one Te(1), and one Te(2) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Pu(1) and one Te(2) atom. is represented by the CIF card [CIF]
data_Pu(TeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.307
_cell_length_b   7.030
_cell_length_c   8.517
_cell_angle_alpha   56.048
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   561.618
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.410  0.267  0.492  1.0
  Pu  Pu1  1  0.910  0.733  0.008  1.0
  Pu  Pu2  1  0.590  0.733  0.508  1.0
  Pu  Pu3  1  0.090  0.267  0.992  1.0
  Te  Te4  1  0.582  0.735  0.039  1.0
  Te  Te5  1  0.082  0.265  0.461  1.0
  Te  Te6  1  0.418  0.265  0.961  1.0
  Te  Te7  1  0.918  0.735  0.539  1.0
  Te  Te8  1  0.224  0.809  0.929  1.0
  Te  Te9  1  0.724  0.191  0.571  1.0
  Te  Te10  1  0.776  0.191  0.071  1.0
  Te  Te11  1  0.276  0.809  0.429  1.0
  O  O12  1  0.725  0.561  0.123  1.0
  O  O13  1  0.225  0.439  0.377  1.0
  O  O14  1  0.275  0.439  0.877  1.0
  O  O15  1  0.775  0.561  0.623  1.0
  O  O16  1  0.599  0.866  0.184  1.0
  O  O17  1  0.099  0.134  0.316  1.0
  O  O18  1  0.401  0.134  0.816  1.0
  O  O19  1  0.901  0.866  0.684  1.0
  O  O20  1  0.480  0.474  0.204  1.0
  O  O21  1  0.980  0.526  0.296  1.0
  O  O22  1  0.520  0.526  0.796  1.0
  O  O23  1  0.020  0.474  0.704  1.0
  O  O24  1  0.259  0.977  0.161  1.0
  O  O25  1  0.759  0.023  0.339  1.0
  O  O26  1  0.741  0.023  0.839  1.0
  O  O27  1  0.241  0.977  0.661  1.0
  O  O28  1  0.403  0.999  0.416  1.0
  O  O29  1  0.903  0.001  0.084  1.0
  O  O30  1  0.597  0.001  0.584  1.0
  O  O31  1  0.097  0.999  0.916  1.0
  O  O32  1  0.405  0.610  0.459  1.0
  O  O33  1  0.905  0.390  0.041  1.0
  O  O34  1  0.595  0.390  0.541  1.0
  O  O35  1  0.095  0.610  0.959  1.0
[/CIF]
.
The compound described by PuTe2O6 crystallizes in the monoclinic P2_1/c space group. Pu(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a trigonal planar geometry to two equivalent Pu(1) and one Te(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Pu(1) and one Te(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to one Pu(1) and one Te(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Pu(1) and one Te(1) atom. In the fifth O site, O(4) is bonded in a 3-coordinate geometry to one Pu(1), one Te(1), and one Te(2) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Pu(1) and one Te(2) atom. is represented by the CIF card [CIF]
data_Pu(TeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.307
_cell_length_b   7.030
_cell_length_c   8.517
_cell_angle_alpha   56.048
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   561.618
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.410  0.267  0.492  1.0
  Pu  Pu1  1  0.910  0.733  0.008  1.0
  Pu  Pu2  1  0.590  0.733  0.508  1.0
  Pu  Pu3  1  0.090  0.267  0.992  1.0
  Te  Te4  1  0.582  0.735  0.039  1.0
  Te  Te5  1  0.082  0.265  0.461  1.0
  Te  Te6  1  0.418  0.265  0.961  1.0
  Te  Te7  1  0.918  0.735  0.539  1.0
  Te  Te8  1  0.224  0.809  0.929  1.0
  Te  Te9  1  0.724  0.191  0.571  1.0
  Te  Te10  1  0.776  0.191  0.071  1.0
  Te  Te11  1  0.276  0.809  0.429  1.0
  O  O12  1  0.725  0.561  0.123  1.0
  O  O13  1  0.225  0.439  0.377  1.0
  O  O14  1  0.275  0.439  0.877  1.0
  O  O15  1  0.775  0.561  0.623  1.0
  O  O16  1  0.599  0.866  0.184  1.0
  O  O17  1  0.099  0.134  0.316  1.0
  O  O18  1  0.401  0.134  0.816  1.0
  O  O19  1  0.901  0.866  0.684  1.0
  O  O20  1  0.480  0.474  0.204  1.0
  O  O21  1  0.980  0.526  0.296  1.0
  O  O22  1  0.520  0.526  0.796  1.0
  O  O23  1  0.020  0.474  0.704  1.0
  O  O24  1  0.259  0.977  0.161  1.0
  O  O25  1  0.759  0.023  0.339  1.0
  O  O26  1  0.741  0.023  0.839  1.0
  O  O27  1  0.241  0.977  0.661  1.0
  O  O28  1  0.403  0.999  0.416  1.0
  O  O29  1  0.903  0.001  0.084  1.0
  O  O30  1  0.597  0.001  0.584  1.0
  O  O31  1  0.097  0.999  0.916  1.0
  O  O32  1  0.405  0.610  0.459  1.0
  O  O33  1  0.905  0.390  0.041  1.0
  O  O34  1  0.595  0.390  0.541  1.0
  O  O35  1  0.095  0.610  0.959  1.0
[/CIF]
.