The crystal structure described by Zn(N5H4)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Zn(N5H4)2 cluster. Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent N(5) atoms. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one Zn(1), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF card [CIF]
data_Zn(H4N5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.247
_cell_length_b   6.581
_cell_length_c   7.259
_cell_angle_alpha   69.391
_cell_angle_beta   88.863
_cell_angle_gamma   89.029
_symmetry_Int_Tables_number   1
_cell_volume   189.880
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  H  H1  1  0.942  0.177  0.588  1.0
  H  H2  1  0.058  0.823  0.412  1.0
  H  H3  1  0.757  0.156  0.798  1.0
  H  H4  1  0.243  0.844  0.202  1.0
  H  H5  1  0.953  0.522  0.226  1.0
  H  H6  1  0.047  0.478  0.774  1.0
  H  H7  1  0.763  0.759  0.152  1.0
  H  H8  1  0.237  0.241  0.848  1.0
  N  N9  1  0.358  0.277  0.361  1.0
  N  N10  1  0.642  0.723  0.639  1.0
  N  N11  1  0.493  0.225  0.238  1.0
  N  N12  1  0.507  0.775  0.762  1.0
  N  N13  1  0.619  0.170  0.117  1.0
  N  N14  1  0.381  0.830  0.883  1.0
  N  N15  1  0.860  0.264  0.673  1.0
  N  N16  1  0.140  0.737  0.327  1.0
  N  N17  1  0.868  0.644  0.271  1.0
  N  N18  1  0.132  0.356  0.729  1.0
[/CIF]
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The crystal structure described by Zn(N5H4)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Zn(N5H4)2 cluster. Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent N(5) atoms. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one Zn(1), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF card [CIF]
data_Zn(H4N5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.247
_cell_length_b   6.581
_cell_length_c   7.259
_cell_angle_alpha   69.391
_cell_angle_beta   88.863
_cell_angle_gamma   89.029
_symmetry_Int_Tables_number   1
_cell_volume   189.880
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  H  H1  1  0.942  0.177  0.588  1.0
  H  H2  1  0.058  0.823  0.412  1.0
  H  H3  1  0.757  0.156  0.798  1.0
  H  H4  1  0.243  0.844  0.202  1.0
  H  H5  1  0.953  0.522  0.226  1.0
  H  H6  1  0.047  0.478  0.774  1.0
  H  H7  1  0.763  0.759  0.152  1.0
  H  H8  1  0.237  0.241  0.848  1.0
  N  N9  1  0.358  0.277  0.361  1.0
  N  N10  1  0.642  0.723  0.639  1.0
  N  N11  1  0.493  0.225  0.238  1.0
  N  N12  1  0.507  0.775  0.762  1.0
  N  N13  1  0.619  0.170  0.117  1.0
  N  N14  1  0.381  0.830  0.883  1.0
  N  N15  1  0.860  0.264  0.673  1.0
  N  N16  1  0.140  0.737  0.327  1.0
  N  N17  1  0.868  0.644  0.271  1.0
  N  N18  1  0.132  0.356  0.729  1.0
[/CIF]
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