The material described by KAuC2N2OCl2 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to four equivalent N(1), two equivalent O(1), and two equivalent Cl(1) atoms. Au(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent Cl(1) atoms. C(1) is bonded in a distorted single-bond geometry to one Au(1) and one N(1) atom. N(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. O(1) is bonded in a linear geometry to two equivalent K(1) atoms. Cl(1) is bonded in a bent 120 degrees geometry to one K(1) and one Au(1) atom. is represented by the CIF file [CIF]
data_KAuC2N2Cl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.295
_cell_length_b   8.129
_cell_length_c   9.607
_cell_angle_alpha   115.030
_cell_angle_beta   102.605
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   432.342
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.324  0.000  1.0
  K  K1  1  0.750  0.676  0.000  1.0
  Au  Au2  1  0.000  0.500  0.500  1.0
  Au  Au3  1  0.500  0.000  0.500  1.0
  C  C4  1  0.809  0.479  0.296  1.0
  C  C5  1  0.691  0.183  0.704  1.0
  C  C6  1  0.191  0.521  0.704  1.0
  C  C7  1  0.309  0.817  0.296  1.0
  N  N8  1  0.694  0.469  0.179  1.0
  N  N9  1  0.806  0.291  0.821  1.0
  N  N10  1  0.306  0.531  0.821  1.0
  N  N11  1  0.194  0.709  0.179  1.0
  Cl  Cl12  1  0.240  0.327  0.358  1.0
  Cl  Cl13  1  0.260  0.968  0.642  1.0
  Cl  Cl14  1  0.760  0.673  0.642  1.0
  Cl  Cl15  1  0.740  0.032  0.358  1.0
  O  O16  1  0.500  0.000  0.000  1.0
  O  O17  1  0.000  0.000  0.000  1.0
[/CIF]
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The material described by KAuC2N2OCl2 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to four equivalent N(1), two equivalent O(1), and two equivalent Cl(1) atoms. Au(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent Cl(1) atoms. C(1) is bonded in a distorted single-bond geometry to one Au(1) and one N(1) atom. N(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. O(1) is bonded in a linear geometry to two equivalent K(1) atoms. Cl(1) is bonded in a bent 120 degrees geometry to one K(1) and one Au(1) atom. is represented by the CIF file [CIF]
data_KAuC2N2Cl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.295
_cell_length_b   8.129
_cell_length_c   9.607
_cell_angle_alpha   115.030
_cell_angle_beta   102.605
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   432.342
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.324  0.000  1.0
  K  K1  1  0.750  0.676  0.000  1.0
  Au  Au2  1  0.000  0.500  0.500  1.0
  Au  Au3  1  0.500  0.000  0.500  1.0
  C  C4  1  0.809  0.479  0.296  1.0
  C  C5  1  0.691  0.183  0.704  1.0
  C  C6  1  0.191  0.521  0.704  1.0
  C  C7  1  0.309  0.817  0.296  1.0
  N  N8  1  0.694  0.469  0.179  1.0
  N  N9  1  0.806  0.291  0.821  1.0
  N  N10  1  0.306  0.531  0.821  1.0
  N  N11  1  0.194  0.709  0.179  1.0
  Cl  Cl12  1  0.240  0.327  0.358  1.0
  Cl  Cl13  1  0.260  0.968  0.642  1.0
  Cl  Cl14  1  0.760  0.673  0.642  1.0
  Cl  Cl15  1  0.740  0.032  0.358  1.0
  O  O16  1  0.500  0.000  0.000  1.0
  O  O17  1  0.000  0.000  0.000  1.0
[/CIF]
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