The crystal structure described by AsF3 is Indium-like structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four arsenic trifluoride molecules. As(1) is bonded in a distorted T-shaped geometry to one F(1), one F(2), and one F(3) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF file [CIF]
data_AsF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.068
_cell_length_b   6.763
_cell_length_c   7.151
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   245.111
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.460  0.209  0.244  1.0
  As  As1  1  0.540  0.791  0.744  1.0
  As  As2  1  0.040  0.709  0.244  1.0
  As  As3  1  0.960  0.291  0.744  1.0
  F  F4  1  0.187  0.319  0.355  1.0
  F  F5  1  0.813  0.681  0.855  1.0
  F  F6  1  0.313  0.819  0.355  1.0
  F  F7  1  0.687  0.181  0.855  1.0
  F  F8  1  0.098  0.061  0.689  1.0
  F  F9  1  0.902  0.939  0.189  1.0
  F  F10  1  0.402  0.561  0.689  1.0
  F  F11  1  0.598  0.439  0.189  1.0
  F  F12  1  0.131  0.310  0.957  1.0
  F  F13  1  0.869  0.690  0.457  1.0
  F  F14  1  0.369  0.810  0.957  1.0
  F  F15  1  0.631  0.190  0.457  1.0
[/CIF]
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The crystal structure described by AsF3 is Indium-like structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four arsenic trifluoride molecules. As(1) is bonded in a distorted T-shaped geometry to one F(1), one F(2), and one F(3) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF file [CIF]
data_AsF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.068
_cell_length_b   6.763
_cell_length_c   7.151
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   245.111
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.460  0.209  0.244  1.0
  As  As1  1  0.540  0.791  0.744  1.0
  As  As2  1  0.040  0.709  0.244  1.0
  As  As3  1  0.960  0.291  0.744  1.0
  F  F4  1  0.187  0.319  0.355  1.0
  F  F5  1  0.813  0.681  0.855  1.0
  F  F6  1  0.313  0.819  0.355  1.0
  F  F7  1  0.687  0.181  0.855  1.0
  F  F8  1  0.098  0.061  0.689  1.0
  F  F9  1  0.902  0.939  0.189  1.0
  F  F10  1  0.402  0.561  0.689  1.0
  F  F11  1  0.598  0.439  0.189  1.0
  F  F12  1  0.131  0.310  0.957  1.0
  F  F13  1  0.869  0.690  0.457  1.0
  F  F14  1  0.369  0.810  0.957  1.0
  F  F15  1  0.631  0.190  0.457  1.0
[/CIF]
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