The material structure described by MgWCoZn2O6 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted MgO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-48°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-45°. Co(1) is bonded in a distorted trigonal planar geometry to one O(2), one O(3), and one O(4) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  a faceface with one Mg(1)O6 octahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-48°. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom to form distorted OMgZn2W tetrahedra that share  a cornercorner with one O(3)MgZnCoW tetrahedra, corners with two equivalent O(5)MgZn2W tetrahedra, corners with two equivalent O(6)MgZn2W tetrahedra, corners with three equivalent O(2)MgZnCoW tetrahedra, corners with three equivalent O(4)MgZnCoW tetrahedra,  an edgeedge with one O(5)MgZn2W tetrahedra,  an edgeedge with one O(6)MgZn2W tetrahedra, and  an edgeedge with one O(3)MgZnCoW tetrahedra. In the second O site, O(2) is bonded to one Mg(1), one W(1), one Co(1), and one Zn(1) atom to form distorted OMgZnCoW tetrahedra that share  a cornercorner with one O(5)MgZn2W tetrahedra, corners with two equivalent O(3)MgZnCoW tetrahedra, corners with two equivalent O(4)MgZnCoW tetrahedra, corners with three equivalent O(1)MgZn2W tetrahedra, corners with three equivalent O(6)MgZn2W tetrahedra,  an edgeedge with one O(5)MgZn2W tetrahedra,  an edgeedge with one O(3)MgZnCoW tetrahedra, and  an edgeedge with one O(4)MgZnCoW tetrahedra. In the third O site, O(3) is bonded to one Mg(1), one W(1), one Co(1), and one Zn(1) atom to form distorted OMgZnCoW tetrahedra that share  a cornercorner with one O(1)MgZn2W tetrahedra, corners with two equivalent O(2)MgZnCoW tetrahedra, corners with two equivalent O(4)MgZnCoW tetrahedra, corners with three equivalent O(5)MgZn2W tetrahedra, corners with three equivalent O(6)MgZn2W tetrahedra,  an edgeedge with one O(1)MgZn2W tetrahedra,  an edgeedge with one O(2)MgZnCoW tetrahedra, and  an edgeedge with one O(4)MgZnCoW tetrahedra. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Co(1), and one Zn(1) atom to form OMgZnCoW tetrahedra that share  a cornercorner with one O(6)MgZn2W tetrahedra, corners with two equivalent O(2)MgZnCoW tetrahedra, corners with two equivalent O(3)MgZnCoW tetrahedra, corners with three equivalent O(1)MgZn2W tetrahedra, corners with three equivalent O(5)MgZn2W tetrahedra,  an edgeedge with one O(6)MgZn2W tetrahedra,  an edgeedge with one O(2)MgZnCoW tetrahedra, and  an edgeedge with one O(3)MgZnCoW tetrahedra. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom to form OMgZn2W tetrahedra that share  a cornercorner with one O(2)MgZnCoW tetrahedra, corners with two equivalent O(1)MgZn2W tetrahedra, corners with two equivalent O(6)MgZn2W tetrahedra, corners with three equivalent O(3)MgZnCoW tetrahedra, corners with three equivalent O(4)MgZnCoW tetrahedra,  an edgeedge with one O(1)MgZn2W tetrahedra,  an edgeedge with one O(6)MgZn2W tetrahedra, and  an edgeedge with one O(2)MgZnCoW tetrahedra. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom to form OMgZn2W tetrahedra that share  a cornercorner with one O(4)MgZnCoW tetrahedra, corners with two equivalent O(1)MgZn2W tetrahedra, corners with two equivalent O(5)MgZn2W tetrahedra, corners with three equivalent O(2)MgZnCoW tetrahedra, corners with three equivalent O(3)MgZnCoW tetrahedra,  an edgeedge with one O(1)MgZn2W tetrahedra,  an edgeedge with one O(5)MgZn2W tetrahedra, and  an edgeedge with one O(4)MgZnCoW tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgZn2CoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.416
_cell_length_b   6.017
_cell_length_c   8.125
_cell_angle_alpha   99.164
_cell_angle_beta   131.833
_cell_angle_gamma   116.383
_symmetry_Int_Tables_number   1
_cell_volume   129.145
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.997  0.272  0.360  1.0
  Zn  Zn1  1  0.998  0.639  0.182  1.0
  Zn  Zn2  1  0.003  0.502  0.747  1.0
  Co  Co3  1  0.002  0.831  0.570  1.0
  W  W4  1  0.016  0.014  0.001  1.0
  O  O5  1  0.725  0.838  0.093  1.0
  O  O6  1  0.380  0.161  0.965  1.0
  O  O7  1  0.249  0.424  0.217  1.0
  O  O8  1  0.358  0.784  0.584  1.0
  O  O9  1  0.589  0.111  0.369  1.0
  O  O10  1  0.695  0.535  0.784  1.0
[/CIF]
.
The material structure described by MgWCoZn2O6 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted MgO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-48°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-45°. Co(1) is bonded in a distorted trigonal planar geometry to one O(2), one O(3), and one O(4) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  a faceface with one Mg(1)O6 octahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-48°. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom to form distorted OMgZn2W tetrahedra that share  a cornercorner with one O(3)MgZnCoW tetrahedra, corners with two equivalent O(5)MgZn2W tetrahedra, corners with two equivalent O(6)MgZn2W tetrahedra, corners with three equivalent O(2)MgZnCoW tetrahedra, corners with three equivalent O(4)MgZnCoW tetrahedra,  an edgeedge with one O(5)MgZn2W tetrahedra,  an edgeedge with one O(6)MgZn2W tetrahedra, and  an edgeedge with one O(3)MgZnCoW tetrahedra. In the second O site, O(2) is bonded to one Mg(1), one W(1), one Co(1), and one Zn(1) atom to form distorted OMgZnCoW tetrahedra that share  a cornercorner with one O(5)MgZn2W tetrahedra, corners with two equivalent O(3)MgZnCoW tetrahedra, corners with two equivalent O(4)MgZnCoW tetrahedra, corners with three equivalent O(1)MgZn2W tetrahedra, corners with three equivalent O(6)MgZn2W tetrahedra,  an edgeedge with one O(5)MgZn2W tetrahedra,  an edgeedge with one O(3)MgZnCoW tetrahedra, and  an edgeedge with one O(4)MgZnCoW tetrahedra. In the third O site, O(3) is bonded to one Mg(1), one W(1), one Co(1), and one Zn(1) atom to form distorted OMgZnCoW tetrahedra that share  a cornercorner with one O(1)MgZn2W tetrahedra, corners with two equivalent O(2)MgZnCoW tetrahedra, corners with two equivalent O(4)MgZnCoW tetrahedra, corners with three equivalent O(5)MgZn2W tetrahedra, corners with three equivalent O(6)MgZn2W tetrahedra,  an edgeedge with one O(1)MgZn2W tetrahedra,  an edgeedge with one O(2)MgZnCoW tetrahedra, and  an edgeedge with one O(4)MgZnCoW tetrahedra. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Co(1), and one Zn(1) atom to form OMgZnCoW tetrahedra that share  a cornercorner with one O(6)MgZn2W tetrahedra, corners with two equivalent O(2)MgZnCoW tetrahedra, corners with two equivalent O(3)MgZnCoW tetrahedra, corners with three equivalent O(1)MgZn2W tetrahedra, corners with three equivalent O(5)MgZn2W tetrahedra,  an edgeedge with one O(6)MgZn2W tetrahedra,  an edgeedge with one O(2)MgZnCoW tetrahedra, and  an edgeedge with one O(3)MgZnCoW tetrahedra. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom to form OMgZn2W tetrahedra that share  a cornercorner with one O(2)MgZnCoW tetrahedra, corners with two equivalent O(1)MgZn2W tetrahedra, corners with two equivalent O(6)MgZn2W tetrahedra, corners with three equivalent O(3)MgZnCoW tetrahedra, corners with three equivalent O(4)MgZnCoW tetrahedra,  an edgeedge with one O(1)MgZn2W tetrahedra,  an edgeedge with one O(6)MgZn2W tetrahedra, and  an edgeedge with one O(2)MgZnCoW tetrahedra. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom to form OMgZn2W tetrahedra that share  a cornercorner with one O(4)MgZnCoW tetrahedra, corners with two equivalent O(1)MgZn2W tetrahedra, corners with two equivalent O(5)MgZn2W tetrahedra, corners with three equivalent O(2)MgZnCoW tetrahedra, corners with three equivalent O(3)MgZnCoW tetrahedra,  an edgeedge with one O(1)MgZn2W tetrahedra,  an edgeedge with one O(5)MgZn2W tetrahedra, and  an edgeedge with one O(4)MgZnCoW tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgZn2CoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.416
_cell_length_b   6.017
_cell_length_c   8.125
_cell_angle_alpha   99.164
_cell_angle_beta   131.833
_cell_angle_gamma   116.383
_symmetry_Int_Tables_number   1
_cell_volume   129.145
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.997  0.272  0.360  1.0
  Zn  Zn1  1  0.998  0.639  0.182  1.0
  Zn  Zn2  1  0.003  0.502  0.747  1.0
  Co  Co3  1  0.002  0.831  0.570  1.0
  W  W4  1  0.016  0.014  0.001  1.0
  O  O5  1  0.725  0.838  0.093  1.0
  O  O6  1  0.380  0.161  0.965  1.0
  O  O7  1  0.249  0.424  0.217  1.0
  O  O8  1  0.358  0.784  0.584  1.0
  O  O9  1  0.589  0.111  0.369  1.0
  O  O10  1  0.695  0.535  0.784  1.0
[/CIF]
.