The crystal structure described by AuSCl5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuSCl5 clusters. Au(1) is bonded in a rectangular see-saw-like geometry to one S(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Au(1), one Cl(1), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_AuSCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.285
_cell_length_b   8.115
_cell_length_c   13.144
_cell_angle_alpha   64.564
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   798.076
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.669  0.911  0.655  1.0
  Au  Au1  1  0.169  0.089  0.845  1.0
  Au  Au2  1  0.331  0.089  0.345  1.0
  Au  Au3  1  0.831  0.911  0.155  1.0
  S  S4  1  0.777  0.765  0.037  1.0
  S  S5  1  0.723  0.765  0.537  1.0
  S  S6  1  0.223  0.235  0.963  1.0
  S  S7  1  0.277  0.235  0.463  1.0
  Cl  Cl8  1  0.665  0.502  0.617  1.0
  Cl  Cl9  1  0.835  0.502  0.117  1.0
  Cl  Cl10  1  0.335  0.498  0.383  1.0
  Cl  Cl11  1  0.165  0.498  0.883  1.0
  Cl  Cl12  1  0.841  0.171  0.985  1.0
  Cl  Cl13  1  0.341  0.829  0.515  1.0
  Cl  Cl14  1  0.159  0.829  0.015  1.0
  Cl  Cl15  1  0.659  0.171  0.485  1.0
  Cl  Cl16  1  0.886  0.078  0.254  1.0
  Cl  Cl17  1  0.386  0.922  0.246  1.0
  Cl  Cl18  1  0.114  0.922  0.746  1.0
  Cl  Cl19  1  0.614  0.078  0.754  1.0
  Cl  Cl20  1  0.809  0.651  0.318  1.0
  Cl  Cl21  1  0.309  0.349  0.182  1.0
  Cl  Cl22  1  0.191  0.349  0.682  1.0
  Cl  Cl23  1  0.691  0.651  0.818  1.0
  Cl  Cl24  1  0.535  0.760  0.045  1.0
  Cl  Cl25  1  0.035  0.240  0.455  1.0
  Cl  Cl26  1  0.465  0.240  0.955  1.0
  Cl  Cl27  1  0.965  0.760  0.545  1.0
[/CIF]
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The crystal structure described by AuSCl5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuSCl5 clusters. Au(1) is bonded in a rectangular see-saw-like geometry to one S(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Au(1), one Cl(1), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_AuSCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.285
_cell_length_b   8.115
_cell_length_c   13.144
_cell_angle_alpha   64.564
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   798.076
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.669  0.911  0.655  1.0
  Au  Au1  1  0.169  0.089  0.845  1.0
  Au  Au2  1  0.331  0.089  0.345  1.0
  Au  Au3  1  0.831  0.911  0.155  1.0
  S  S4  1  0.777  0.765  0.037  1.0
  S  S5  1  0.723  0.765  0.537  1.0
  S  S6  1  0.223  0.235  0.963  1.0
  S  S7  1  0.277  0.235  0.463  1.0
  Cl  Cl8  1  0.665  0.502  0.617  1.0
  Cl  Cl9  1  0.835  0.502  0.117  1.0
  Cl  Cl10  1  0.335  0.498  0.383  1.0
  Cl  Cl11  1  0.165  0.498  0.883  1.0
  Cl  Cl12  1  0.841  0.171  0.985  1.0
  Cl  Cl13  1  0.341  0.829  0.515  1.0
  Cl  Cl14  1  0.159  0.829  0.015  1.0
  Cl  Cl15  1  0.659  0.171  0.485  1.0
  Cl  Cl16  1  0.886  0.078  0.254  1.0
  Cl  Cl17  1  0.386  0.922  0.246  1.0
  Cl  Cl18  1  0.114  0.922  0.746  1.0
  Cl  Cl19  1  0.614  0.078  0.754  1.0
  Cl  Cl20  1  0.809  0.651  0.318  1.0
  Cl  Cl21  1  0.309  0.349  0.182  1.0
  Cl  Cl22  1  0.191  0.349  0.682  1.0
  Cl  Cl23  1  0.691  0.651  0.818  1.0
  Cl  Cl24  1  0.535  0.760  0.045  1.0
  Cl  Cl25  1  0.035  0.240  0.455  1.0
  Cl  Cl26  1  0.465  0.240  0.955  1.0
  Cl  Cl27  1  0.965  0.760  0.545  1.0
[/CIF]
.