The material described by WO2 is Hydrophilite-like structured and crystallizes in the tetragonal I4/m space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent W(1) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to three equivalent W(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_WO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.709
_cell_length_b   7.709
_cell_length_c   7.709
_cell_angle_alpha   92.630
_cell_angle_beta   92.630
_cell_angle_gamma   155.264
_symmetry_Int_Tables_number   1
_cell_volume   187.220
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.653  0.838  0.492  1.0
  W  W1  1  0.162  0.653  0.815  1.0
  W  W2  1  0.838  0.347  0.185  1.0
  W  W3  1  0.347  0.162  0.508  1.0
  O  O4  1  0.837  0.537  0.374  1.0
  O  O5  1  0.463  0.837  0.299  1.0
  O  O6  1  0.537  0.163  0.701  1.0
  O  O7  1  0.163  0.463  0.626  1.0
  O  O8  1  0.159  0.213  0.371  1.0
  O  O9  1  0.787  0.159  0.946  1.0
  O  O10  1  0.841  0.787  0.629  1.0
  O  O11  1  0.213  0.841  0.054  1.0
[/CIF]
.
The material described by WO2 is Hydrophilite-like structured and crystallizes in the tetragonal I4/m space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent W(1) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to three equivalent W(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_WO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.709
_cell_length_b   7.709
_cell_length_c   7.709
_cell_angle_alpha   92.630
_cell_angle_beta   92.630
_cell_angle_gamma   155.264
_symmetry_Int_Tables_number   1
_cell_volume   187.220
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.653  0.838  0.492  1.0
  W  W1  1  0.162  0.653  0.815  1.0
  W  W2  1  0.838  0.347  0.185  1.0
  W  W3  1  0.347  0.162  0.508  1.0
  O  O4  1  0.837  0.537  0.374  1.0
  O  O5  1  0.463  0.837  0.299  1.0
  O  O6  1  0.537  0.163  0.701  1.0
  O  O7  1  0.163  0.463  0.626  1.0
  O  O8  1  0.159  0.213  0.371  1.0
  O  O9  1  0.787  0.159  0.946  1.0
  O  O10  1  0.841  0.787  0.629  1.0
  O  O11  1  0.213  0.841  0.054  1.0
[/CIF]
.