The compound described by Cr4Te3S is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the orthorhombic Imm2 space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to two equivalent Te(1), three equivalent Te(2), and one S(1) atom to form distorted CrTe5S octahedra that share corners with six equivalent Cr(2)Te4S2 octahedra, corners with six equivalent Cr(1)Te5S octahedra, edges with two equivalent Cr(1)Te5S octahedra, edges with four equivalent Cr(2)Te4S2 octahedra,  a faceface with one Cr(2)Te4S2 octahedra, and  a faceface with one Cr(1)Te5S octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the second Cr site, Cr(2) is bonded to one Te(1), three equivalent Te(2), and two equivalent S(1) atoms to form distorted CrTe4S2 octahedra that share corners with six equivalent Cr(2)Te4S2 octahedra, corners with six equivalent Cr(1)Te5S octahedra, edges with two equivalent Cr(2)Te4S2 octahedra, edges with four equivalent Cr(1)Te5S octahedra,  a faceface with one Cr(2)Te4S2 octahedra, and  a faceface with one Cr(1)Te5S octahedra. The corner-sharing octahedral tilt angles range from 44-51°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 6-coordinate geometry to two equivalent Cr(2) and four equivalent Cr(1) atoms. In the second Te site, Te(2) is bonded to three equivalent Cr(1) and three equivalent Cr(2) atoms to form distorted edge-sharing TeCr6 pentagonal pyramids. S(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent Cr(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr4Te3S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.480
_cell_length_b   7.480
_cell_length_c   7.480
_cell_angle_alpha   148.961
_cell_angle_beta   125.392
_cell_angle_gamma   64.152
_symmetry_Int_Tables_number   1
_cell_volume   174.102
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.096  0.122  0.974  1.0
  Cr  Cr1  1  0.644  0.616  0.027  1.0
  Cr  Cr2  1  0.411  0.384  0.027  1.0
  Cr  Cr3  1  0.851  0.878  0.974  1.0
  Te  Te4  1  0.162  0.500  0.662  1.0
  Te  Te5  1  0.095  0.761  0.334  1.0
  Te  Te6  1  0.573  0.239  0.334  1.0
  S  S7  1  0.674  0.000  0.674  1.0
[/CIF]
.
The compound described by Cr4Te3S is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the orthorhombic Imm2 space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to two equivalent Te(1), three equivalent Te(2), and one S(1) atom to form distorted CrTe5S octahedra that share corners with six equivalent Cr(2)Te4S2 octahedra, corners with six equivalent Cr(1)Te5S octahedra, edges with two equivalent Cr(1)Te5S octahedra, edges with four equivalent Cr(2)Te4S2 octahedra,  a faceface with one Cr(2)Te4S2 octahedra, and  a faceface with one Cr(1)Te5S octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the second Cr site, Cr(2) is bonded to one Te(1), three equivalent Te(2), and two equivalent S(1) atoms to form distorted CrTe4S2 octahedra that share corners with six equivalent Cr(2)Te4S2 octahedra, corners with six equivalent Cr(1)Te5S octahedra, edges with two equivalent Cr(2)Te4S2 octahedra, edges with four equivalent Cr(1)Te5S octahedra,  a faceface with one Cr(2)Te4S2 octahedra, and  a faceface with one Cr(1)Te5S octahedra. The corner-sharing octahedral tilt angles range from 44-51°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 6-coordinate geometry to two equivalent Cr(2) and four equivalent Cr(1) atoms. In the second Te site, Te(2) is bonded to three equivalent Cr(1) and three equivalent Cr(2) atoms to form distorted edge-sharing TeCr6 pentagonal pyramids. S(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent Cr(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr4Te3S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.480
_cell_length_b   7.480
_cell_length_c   7.480
_cell_angle_alpha   148.961
_cell_angle_beta   125.392
_cell_angle_gamma   64.152
_symmetry_Int_Tables_number   1
_cell_volume   174.102
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.096  0.122  0.974  1.0
  Cr  Cr1  1  0.644  0.616  0.027  1.0
  Cr  Cr2  1  0.411  0.384  0.027  1.0
  Cr  Cr3  1  0.851  0.878  0.974  1.0
  Te  Te4  1  0.162  0.500  0.662  1.0
  Te  Te5  1  0.095  0.761  0.334  1.0
  Te  Te6  1  0.573  0.239  0.334  1.0
  S  S7  1  0.674  0.000  0.674  1.0
[/CIF]
.