The structure described by LiTm4Ge4 is delta Molybdenum Boride-derived structured and crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 3-coordinate geometry to one Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. There are two inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 6-coordinate geometry to one Ge(2), two equivalent Ge(1), and three equivalent Ge(3) atoms. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to one Ge(1), two equivalent Ge(2), and four equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to one Li(1), two equivalent Tm(2), four equivalent Tm(1), and one Ge(2) atom. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Li(1), two equivalent Tm(1), four equivalent Tm(2), and one Ge(1) atom. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to one Li(1), three equivalent Tm(1), four equivalent Tm(2), and one Ge(3) atom. is represented by the CIF card [CIF]
data_Li(TmGe)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.023
_cell_length_b   7.575
_cell_length_c   14.433
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   767.828
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.162  0.523  0.750  1.0
  Li  Li1  1  0.838  0.477  0.250  1.0
  Li  Li2  1  0.338  0.023  0.250  1.0
  Li  Li3  1  0.662  0.977  0.750  1.0
  Tm  Tm4  1  0.329  0.176  0.628  1.0
  Tm  Tm5  1  0.671  0.824  0.372  1.0
  Tm  Tm6  1  0.171  0.676  0.372  1.0
  Tm  Tm7  1  0.671  0.824  0.128  1.0
  Tm  Tm8  1  0.829  0.324  0.628  1.0
  Tm  Tm9  1  0.329  0.176  0.872  1.0
  Tm  Tm10  1  0.829  0.324  0.872  1.0
  Tm  Tm11  1  0.171  0.676  0.128  1.0
  Tm  Tm12  1  0.016  0.187  0.098  1.0
  Tm  Tm13  1  0.984  0.813  0.902  1.0
  Tm  Tm14  1  0.484  0.687  0.902  1.0
  Tm  Tm15  1  0.984  0.813  0.598  1.0
  Tm  Tm16  1  0.516  0.313  0.098  1.0
  Tm  Tm17  1  0.016  0.187  0.402  1.0
  Tm  Tm18  1  0.516  0.313  0.402  1.0
  Tm  Tm19  1  0.484  0.687  0.598  1.0
  Ge  Ge20  1  0.018  0.088  0.750  1.0
  Ge  Ge21  1  0.982  0.912  0.250  1.0
  Ge  Ge22  1  0.482  0.588  0.250  1.0
  Ge  Ge23  1  0.518  0.412  0.750  1.0
  Ge  Ge24  1  0.284  0.863  0.750  1.0
  Ge  Ge25  1  0.716  0.137  0.250  1.0
  Ge  Ge26  1  0.216  0.363  0.250  1.0
  Ge  Ge27  1  0.784  0.637  0.750  1.0
  Ge  Ge28  1  0.168  0.466  0.536  1.0
  Ge  Ge29  1  0.832  0.534  0.464  1.0
  Ge  Ge30  1  0.332  0.966  0.464  1.0
  Ge  Ge31  1  0.832  0.534  0.036  1.0
  Ge  Ge32  1  0.668  0.034  0.536  1.0
  Ge  Ge33  1  0.168  0.466  0.964  1.0
  Ge  Ge34  1  0.668  0.034  0.964  1.0
  Ge  Ge35  1  0.332  0.966  0.036  1.0
[/CIF]
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The structure described by LiTm4Ge4 is delta Molybdenum Boride-derived structured and crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 3-coordinate geometry to one Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. There are two inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 6-coordinate geometry to one Ge(2), two equivalent Ge(1), and three equivalent Ge(3) atoms. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to one Ge(1), two equivalent Ge(2), and four equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to one Li(1), two equivalent Tm(2), four equivalent Tm(1), and one Ge(2) atom. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Li(1), two equivalent Tm(1), four equivalent Tm(2), and one Ge(1) atom. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to one Li(1), three equivalent Tm(1), four equivalent Tm(2), and one Ge(3) atom. is represented by the CIF card [CIF]
data_Li(TmGe)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.023
_cell_length_b   7.575
_cell_length_c   14.433
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   767.828
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.162  0.523  0.750  1.0
  Li  Li1  1  0.838  0.477  0.250  1.0
  Li  Li2  1  0.338  0.023  0.250  1.0
  Li  Li3  1  0.662  0.977  0.750  1.0
  Tm  Tm4  1  0.329  0.176  0.628  1.0
  Tm  Tm5  1  0.671  0.824  0.372  1.0
  Tm  Tm6  1  0.171  0.676  0.372  1.0
  Tm  Tm7  1  0.671  0.824  0.128  1.0
  Tm  Tm8  1  0.829  0.324  0.628  1.0
  Tm  Tm9  1  0.329  0.176  0.872  1.0
  Tm  Tm10  1  0.829  0.324  0.872  1.0
  Tm  Tm11  1  0.171  0.676  0.128  1.0
  Tm  Tm12  1  0.016  0.187  0.098  1.0
  Tm  Tm13  1  0.984  0.813  0.902  1.0
  Tm  Tm14  1  0.484  0.687  0.902  1.0
  Tm  Tm15  1  0.984  0.813  0.598  1.0
  Tm  Tm16  1  0.516  0.313  0.098  1.0
  Tm  Tm17  1  0.016  0.187  0.402  1.0
  Tm  Tm18  1  0.516  0.313  0.402  1.0
  Tm  Tm19  1  0.484  0.687  0.598  1.0
  Ge  Ge20  1  0.018  0.088  0.750  1.0
  Ge  Ge21  1  0.982  0.912  0.250  1.0
  Ge  Ge22  1  0.482  0.588  0.250  1.0
  Ge  Ge23  1  0.518  0.412  0.750  1.0
  Ge  Ge24  1  0.284  0.863  0.750  1.0
  Ge  Ge25  1  0.716  0.137  0.250  1.0
  Ge  Ge26  1  0.216  0.363  0.250  1.0
  Ge  Ge27  1  0.784  0.637  0.750  1.0
  Ge  Ge28  1  0.168  0.466  0.536  1.0
  Ge  Ge29  1  0.832  0.534  0.464  1.0
  Ge  Ge30  1  0.332  0.966  0.464  1.0
  Ge  Ge31  1  0.832  0.534  0.036  1.0
  Ge  Ge32  1  0.668  0.034  0.536  1.0
  Ge  Ge33  1  0.168  0.466  0.964  1.0
  Ge  Ge34  1  0.668  0.034  0.964  1.0
  Ge  Ge35  1  0.332  0.966  0.036  1.0
[/CIF]
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