The material structure described by Rb4P3(PdS4)3 crystallizes in the cubic Pm-3n space group. Rb(1) is bonded in a hexagonal planar geometry to six equivalent S(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent S(1) atoms. P(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded to two equivalent Rb(1), one Pd(1), and one P(1) atom to form a mixture of distorted edge and corner-sharing SRb2PPd trigonal pyramids. is represented by the CIF file [CIF]
data_Rb4P3(PdS4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.238
_cell_length_b   12.238
_cell_length_c   12.238
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1832.947
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.250  0.750  1.0
  Rb  Rb1  1  0.250  0.750  0.250  1.0
  Rb  Rb2  1  0.750  0.750  0.250  1.0
  Rb  Rb3  1  0.250  0.250  0.750  1.0
  Rb  Rb4  1  0.250  0.750  0.750  1.0
  Rb  Rb5  1  0.750  0.250  0.250  1.0
  Rb  Rb6  1  0.250  0.250  0.250  1.0
  Rb  Rb7  1  0.750  0.750  0.750  1.0
  P  P8  1  0.000  0.500  0.750  1.0
  P  P9  1  0.500  0.250  0.000  1.0
  P  P10  1  0.750  0.000  0.500  1.0
  P  P11  1  0.000  0.500  0.250  1.0
  P  P12  1  0.500  0.750  0.000  1.0
  P  P13  1  0.250  0.000  0.500  1.0
  Pd  Pd14  1  0.000  0.500  0.500  1.0
  Pd  Pd15  1  0.500  0.500  0.000  1.0
  Pd  Pd16  1  0.500  0.000  0.500  1.0
  Pd  Pd17  1  0.500  0.000  0.000  1.0
  Pd  Pd18  1  0.000  0.500  0.000  1.0
  Pd  Pd19  1  0.000  0.000  0.500  1.0
  S  S20  1  0.000  0.369  0.645  1.0
  S  S21  1  0.631  0.355  0.000  1.0
  S  S22  1  0.645  0.000  0.631  1.0
  S  S23  1  0.000  0.631  0.355  1.0
  S  S24  1  0.369  0.645  0.000  1.0
  S  S25  1  0.355  0.000  0.369  1.0
  S  S26  1  0.631  0.645  0.000  1.0
  S  S27  1  0.645  0.000  0.369  1.0
  S  S28  1  0.369  0.355  0.000  1.0
  S  S29  1  0.355  0.000  0.631  1.0
  S  S30  1  0.000  0.631  0.645  1.0
  S  S31  1  0.000  0.369  0.355  1.0
  S  S32  1  0.500  0.145  0.869  1.0
  S  S33  1  0.131  0.500  0.855  1.0
  S  S34  1  0.145  0.131  0.500  1.0
  S  S35  1  0.500  0.855  0.131  1.0
  S  S36  1  0.869  0.500  0.145  1.0
  S  S37  1  0.855  0.869  0.500  1.0
  S  S38  1  0.131  0.500  0.145  1.0
  S  S39  1  0.145  0.869  0.500  1.0
  S  S40  1  0.869  0.500  0.855  1.0
  S  S41  1  0.855  0.131  0.500  1.0
  S  S42  1  0.500  0.145  0.131  1.0
  S  S43  1  0.500  0.855  0.869  1.0
[/CIF]
.
The material structure described by Rb4P3(PdS4)3 crystallizes in the cubic Pm-3n space group. Rb(1) is bonded in a hexagonal planar geometry to six equivalent S(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent S(1) atoms. P(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded to two equivalent Rb(1), one Pd(1), and one P(1) atom to form a mixture of distorted edge and corner-sharing SRb2PPd trigonal pyramids. is represented by the CIF file [CIF]
data_Rb4P3(PdS4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.238
_cell_length_b   12.238
_cell_length_c   12.238
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1832.947
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.250  0.750  1.0
  Rb  Rb1  1  0.250  0.750  0.250  1.0
  Rb  Rb2  1  0.750  0.750  0.250  1.0
  Rb  Rb3  1  0.250  0.250  0.750  1.0
  Rb  Rb4  1  0.250  0.750  0.750  1.0
  Rb  Rb5  1  0.750  0.250  0.250  1.0
  Rb  Rb6  1  0.250  0.250  0.250  1.0
  Rb  Rb7  1  0.750  0.750  0.750  1.0
  P  P8  1  0.000  0.500  0.750  1.0
  P  P9  1  0.500  0.250  0.000  1.0
  P  P10  1  0.750  0.000  0.500  1.0
  P  P11  1  0.000  0.500  0.250  1.0
  P  P12  1  0.500  0.750  0.000  1.0
  P  P13  1  0.250  0.000  0.500  1.0
  Pd  Pd14  1  0.000  0.500  0.500  1.0
  Pd  Pd15  1  0.500  0.500  0.000  1.0
  Pd  Pd16  1  0.500  0.000  0.500  1.0
  Pd  Pd17  1  0.500  0.000  0.000  1.0
  Pd  Pd18  1  0.000  0.500  0.000  1.0
  Pd  Pd19  1  0.000  0.000  0.500  1.0
  S  S20  1  0.000  0.369  0.645  1.0
  S  S21  1  0.631  0.355  0.000  1.0
  S  S22  1  0.645  0.000  0.631  1.0
  S  S23  1  0.000  0.631  0.355  1.0
  S  S24  1  0.369  0.645  0.000  1.0
  S  S25  1  0.355  0.000  0.369  1.0
  S  S26  1  0.631  0.645  0.000  1.0
  S  S27  1  0.645  0.000  0.369  1.0
  S  S28  1  0.369  0.355  0.000  1.0
  S  S29  1  0.355  0.000  0.631  1.0
  S  S30  1  0.000  0.631  0.645  1.0
  S  S31  1  0.000  0.369  0.355  1.0
  S  S32  1  0.500  0.145  0.869  1.0
  S  S33  1  0.131  0.500  0.855  1.0
  S  S34  1  0.145  0.131  0.500  1.0
  S  S35  1  0.500  0.855  0.131  1.0
  S  S36  1  0.869  0.500  0.145  1.0
  S  S37  1  0.855  0.869  0.500  1.0
  S  S38  1  0.131  0.500  0.145  1.0
  S  S39  1  0.145  0.869  0.500  1.0
  S  S40  1  0.869  0.500  0.855  1.0
  S  S41  1  0.855  0.131  0.500  1.0
  S  S42  1  0.500  0.145  0.131  1.0
  S  S43  1  0.500  0.855  0.869  1.0
[/CIF]
.