The crystal structure described by LiTiTe2 is Caswellsilverite-like structured and crystallizes in the trigonal P-3m1 space group. Li(1) is bonded to six equivalent Te(1) atoms to form LiTe6 octahedra that share corners with twelve equivalent Ti(1)Te6 octahedra, edges with six equivalent Li(1)Te6 octahedra, and faces with two equivalent Ti(1)Te6 octahedra. The corner-sharing octahedral tilt angles are 47°. Ti(1) is bonded to six equivalent Te(1) atoms to form TiTe6 octahedra that share corners with twelve equivalent Li(1)Te6 octahedra, edges with six equivalent Ti(1)Te6 octahedra, and faces with two equivalent Li(1)Te6 octahedra. The corner-sharing octahedral tilt angles are 47°. Te(1) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of distorted edge and corner-sharing TeLi3Ti3 pentagonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiTiTe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.002
_cell_length_b   4.002
_cell_length_c   6.879
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   95.414
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.500  1.0
  Ti  Ti1  1  0.000  0.000  0.000  1.0
  Te  Te2  1  0.333  0.667  0.239  1.0
  Te  Te3  1  0.667  0.333  0.761  1.0
[/CIF]
.
The crystal structure described by LiTiTe2 is Caswellsilverite-like structured and crystallizes in the trigonal P-3m1 space group. Li(1) is bonded to six equivalent Te(1) atoms to form LiTe6 octahedra that share corners with twelve equivalent Ti(1)Te6 octahedra, edges with six equivalent Li(1)Te6 octahedra, and faces with two equivalent Ti(1)Te6 octahedra. The corner-sharing octahedral tilt angles are 47°. Ti(1) is bonded to six equivalent Te(1) atoms to form TiTe6 octahedra that share corners with twelve equivalent Li(1)Te6 octahedra, edges with six equivalent Ti(1)Te6 octahedra, and faces with two equivalent Li(1)Te6 octahedra. The corner-sharing octahedral tilt angles are 47°. Te(1) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of distorted edge and corner-sharing TeLi3Ti3 pentagonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiTiTe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.002
_cell_length_b   4.002
_cell_length_c   6.879
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   95.414
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.500  1.0
  Ti  Ti1  1  0.000  0.000  0.000  1.0
  Te  Te2  1  0.333  0.667  0.239  1.0
  Te  Te3  1  0.667  0.333  0.761  1.0
[/CIF]
.