The material described by V6F13 crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one F(1), one F(12), one F(13), one F(2), one F(6), and one F(8) atom to form a mixture of edge and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 38-51°. In the second V site, V(2) is bonded to one F(1), one F(13), one F(3), one F(4), and two equivalent F(7) atoms to form a mixture of edge and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the third V site, V(3) is bonded to one F(11), one F(2), one F(5), one F(8), and two equivalent F(9) atoms to form a mixture of edge, face, and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 38-46°. In the fourth V site, V(4) is bonded to one F(1), one F(10), one F(4), one F(6), and two equivalent F(3) atoms to form a mixture of edge and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. In the fifth V site, V(5) is bonded to one F(10), one F(11), one F(12), one F(5), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. In the sixth V site, V(6) is bonded to one F(10), one F(11), one F(13), one F(4), one F(8), and one F(9) atom to form a mixture of edge, face, and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 45-57°. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one V(3) atom. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(4) atoms. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(5) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one V(5) and two equivalent V(2) atoms. In the eighth F site, F(8) is bonded in a T-shaped geometry to one V(1), one V(3), and one V(6) atom. In the ninth F site, F(9) is bonded in a T-shaped geometry to one V(6) and two equivalent V(3) atoms. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one V(4), one V(5), and one V(6) atom. In the eleventh F site, F(11) is bonded in a T-shaped geometry to one V(3), one V(5), and one V(6) atom. In the twelfth F site, F(12) is bonded in a water-like geometry to one V(1) and one V(5) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(6) atom. is represented by the CIF file [CIF]
data_V6F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.128
_cell_length_b   8.175
_cell_length_c   10.584
_cell_angle_alpha   72.197
_cell_angle_beta   75.683
_cell_angle_gamma   61.911
_symmetry_Int_Tables_number   1
_cell_volume   586.206
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.955  0.926  0.754  1.0
  V  V1  1  0.866  0.720  0.498  1.0
  V  V2  1  0.781  0.575  0.978  1.0
  V  V3  1  0.420  0.845  0.498  1.0
  V  V4  1  0.678  0.368  0.751  1.0
  V  V5  1  0.759  0.503  0.272  1.0
  V  V6  1  0.241  0.497  0.728  1.0
  V  V7  1  0.322  0.632  0.249  1.0
  V  V8  1  0.580  0.155  0.502  1.0
  V  V9  1  0.219  0.425  0.022  1.0
  V  V10  1  0.134  0.280  0.502  1.0
  V  V11  1  0.045  0.074  0.246  1.0
  F  F12  1  0.837  0.995  0.386  1.0
  F  F13  1  0.765  0.831  0.870  1.0
  F  F14  1  0.603  0.877  0.598  1.0
  F  F15  1  0.686  0.705  0.387  1.0
  F  F16  1  0.632  0.544  0.864  1.0
  F  F17  1  0.259  0.838  0.362  1.0
  F  F18  1  0.885  0.445  0.614  1.0
  F  F19  1  0.170  0.687  0.856  1.0
  F  F20  1  0.948  0.578  0.115  1.0
  F  F21  1  0.466  0.572  0.624  1.0
  F  F22  1  0.554  0.682  0.139  1.0
  F  F23  1  0.121  0.861  0.150  1.0
  F  F24  1  0.022  0.731  0.629  1.0
  F  F25  1  0.978  0.269  0.371  1.0
  F  F26  1  0.879  0.139  0.850  1.0
  F  F27  1  0.446  0.318  0.861  1.0
  F  F28  1  0.534  0.428  0.376  1.0
  F  F29  1  0.052  0.422  0.885  1.0
  F  F30  1  0.830  0.313  0.144  1.0
  F  F31  1  0.115  0.555  0.386  1.0
  F  F32  1  0.741  0.162  0.638  1.0
  F  F33  1  0.368  0.456  0.136  1.0
  F  F34  1  0.314  0.295  0.613  1.0
  F  F35  1  0.397  0.123  0.402  1.0
  F  F36  1  0.235  0.169  0.130  1.0
  F  F37  1  0.163  0.005  0.614  1.0
[/CIF]
.
The material described by V6F13 crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one F(1), one F(12), one F(13), one F(2), one F(6), and one F(8) atom to form a mixture of edge and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 38-51°. In the second V site, V(2) is bonded to one F(1), one F(13), one F(3), one F(4), and two equivalent F(7) atoms to form a mixture of edge and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the third V site, V(3) is bonded to one F(11), one F(2), one F(5), one F(8), and two equivalent F(9) atoms to form a mixture of edge, face, and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 38-46°. In the fourth V site, V(4) is bonded to one F(1), one F(10), one F(4), one F(6), and two equivalent F(3) atoms to form a mixture of edge and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. In the fifth V site, V(5) is bonded to one F(10), one F(11), one F(12), one F(5), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. In the sixth V site, V(6) is bonded to one F(10), one F(11), one F(13), one F(4), one F(8), and one F(9) atom to form a mixture of edge, face, and corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 45-57°. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one V(3) atom. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(4) atoms. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(5) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one V(5) and two equivalent V(2) atoms. In the eighth F site, F(8) is bonded in a T-shaped geometry to one V(1), one V(3), and one V(6) atom. In the ninth F site, F(9) is bonded in a T-shaped geometry to one V(6) and two equivalent V(3) atoms. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one V(4), one V(5), and one V(6) atom. In the eleventh F site, F(11) is bonded in a T-shaped geometry to one V(3), one V(5), and one V(6) atom. In the twelfth F site, F(12) is bonded in a water-like geometry to one V(1) and one V(5) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(6) atom. is represented by the CIF file [CIF]
data_V6F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.128
_cell_length_b   8.175
_cell_length_c   10.584
_cell_angle_alpha   72.197
_cell_angle_beta   75.683
_cell_angle_gamma   61.911
_symmetry_Int_Tables_number   1
_cell_volume   586.206
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.955  0.926  0.754  1.0
  V  V1  1  0.866  0.720  0.498  1.0
  V  V2  1  0.781  0.575  0.978  1.0
  V  V3  1  0.420  0.845  0.498  1.0
  V  V4  1  0.678  0.368  0.751  1.0
  V  V5  1  0.759  0.503  0.272  1.0
  V  V6  1  0.241  0.497  0.728  1.0
  V  V7  1  0.322  0.632  0.249  1.0
  V  V8  1  0.580  0.155  0.502  1.0
  V  V9  1  0.219  0.425  0.022  1.0
  V  V10  1  0.134  0.280  0.502  1.0
  V  V11  1  0.045  0.074  0.246  1.0
  F  F12  1  0.837  0.995  0.386  1.0
  F  F13  1  0.765  0.831  0.870  1.0
  F  F14  1  0.603  0.877  0.598  1.0
  F  F15  1  0.686  0.705  0.387  1.0
  F  F16  1  0.632  0.544  0.864  1.0
  F  F17  1  0.259  0.838  0.362  1.0
  F  F18  1  0.885  0.445  0.614  1.0
  F  F19  1  0.170  0.687  0.856  1.0
  F  F20  1  0.948  0.578  0.115  1.0
  F  F21  1  0.466  0.572  0.624  1.0
  F  F22  1  0.554  0.682  0.139  1.0
  F  F23  1  0.121  0.861  0.150  1.0
  F  F24  1  0.022  0.731  0.629  1.0
  F  F25  1  0.978  0.269  0.371  1.0
  F  F26  1  0.879  0.139  0.850  1.0
  F  F27  1  0.446  0.318  0.861  1.0
  F  F28  1  0.534  0.428  0.376  1.0
  F  F29  1  0.052  0.422  0.885  1.0
  F  F30  1  0.830  0.313  0.144  1.0
  F  F31  1  0.115  0.555  0.386  1.0
  F  F32  1  0.741  0.162  0.638  1.0
  F  F33  1  0.368  0.456  0.136  1.0
  F  F34  1  0.314  0.295  0.613  1.0
  F  F35  1  0.397  0.123  0.402  1.0
  F  F36  1  0.235  0.169  0.130  1.0
  F  F37  1  0.163  0.005  0.614  1.0
[/CIF]
.