The structure described by PHOF2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight difluoro(oxo)phosphanium molecules. P(1) is bonded in a distorted tetrahedral geometry to one H(1), one O(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. O(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PHOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.007
_cell_length_b   6.494
_cell_length_c   14.867
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   579.970
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.547  0.311  0.645  1.0
  P  P1  1  0.953  0.689  0.145  1.0
  P  P2  1  0.047  0.189  0.355  1.0
  P  P3  1  0.453  0.811  0.855  1.0
  P  P4  1  0.453  0.689  0.355  1.0
  P  P5  1  0.047  0.311  0.855  1.0
  P  P6  1  0.953  0.811  0.645  1.0
  P  P7  1  0.547  0.189  0.145  1.0
  H  H8  1  0.415  0.149  0.676  1.0
  H  H9  1  0.085  0.851  0.176  1.0
  H  H10  1  0.915  0.351  0.324  1.0
  H  H11  1  0.585  0.649  0.824  1.0
  H  H12  1  0.585  0.851  0.324  1.0
  H  H13  1  0.915  0.149  0.824  1.0
  H  H14  1  0.085  0.649  0.676  1.0
  H  H15  1  0.415  0.351  0.176  1.0
  O  O16  1  0.708  0.408  0.706  1.0
  O  O17  1  0.792  0.592  0.206  1.0
  O  O18  1  0.208  0.092  0.294  1.0
  O  O19  1  0.292  0.908  0.794  1.0
  O  O20  1  0.292  0.592  0.294  1.0
  O  O21  1  0.208  0.408  0.794  1.0
  O  O22  1  0.792  0.908  0.706  1.0
  O  O23  1  0.708  0.092  0.206  1.0
  F  F24  1  0.378  0.466  0.601  1.0
  F  F25  1  0.122  0.534  0.101  1.0
  F  F26  1  0.878  0.034  0.399  1.0
  F  F27  1  0.622  0.966  0.899  1.0
  F  F28  1  0.622  0.534  0.399  1.0
  F  F29  1  0.878  0.466  0.899  1.0
  F  F30  1  0.122  0.966  0.601  1.0
  F  F31  1  0.378  0.034  0.101  1.0
  F  F32  1  0.654  0.224  0.556  1.0
  F  F33  1  0.846  0.776  0.056  1.0
  F  F34  1  0.154  0.276  0.444  1.0
  F  F35  1  0.346  0.724  0.944  1.0
  F  F36  1  0.346  0.776  0.444  1.0
  F  F37  1  0.154  0.224  0.944  1.0
  F  F38  1  0.846  0.724  0.556  1.0
  F  F39  1  0.654  0.276  0.056  1.0
[/CIF]
.
The structure described by PHOF2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight difluoro(oxo)phosphanium molecules. P(1) is bonded in a distorted tetrahedral geometry to one H(1), one O(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. O(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PHOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.007
_cell_length_b   6.494
_cell_length_c   14.867
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   579.970
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.547  0.311  0.645  1.0
  P  P1  1  0.953  0.689  0.145  1.0
  P  P2  1  0.047  0.189  0.355  1.0
  P  P3  1  0.453  0.811  0.855  1.0
  P  P4  1  0.453  0.689  0.355  1.0
  P  P5  1  0.047  0.311  0.855  1.0
  P  P6  1  0.953  0.811  0.645  1.0
  P  P7  1  0.547  0.189  0.145  1.0
  H  H8  1  0.415  0.149  0.676  1.0
  H  H9  1  0.085  0.851  0.176  1.0
  H  H10  1  0.915  0.351  0.324  1.0
  H  H11  1  0.585  0.649  0.824  1.0
  H  H12  1  0.585  0.851  0.324  1.0
  H  H13  1  0.915  0.149  0.824  1.0
  H  H14  1  0.085  0.649  0.676  1.0
  H  H15  1  0.415  0.351  0.176  1.0
  O  O16  1  0.708  0.408  0.706  1.0
  O  O17  1  0.792  0.592  0.206  1.0
  O  O18  1  0.208  0.092  0.294  1.0
  O  O19  1  0.292  0.908  0.794  1.0
  O  O20  1  0.292  0.592  0.294  1.0
  O  O21  1  0.208  0.408  0.794  1.0
  O  O22  1  0.792  0.908  0.706  1.0
  O  O23  1  0.708  0.092  0.206  1.0
  F  F24  1  0.378  0.466  0.601  1.0
  F  F25  1  0.122  0.534  0.101  1.0
  F  F26  1  0.878  0.034  0.399  1.0
  F  F27  1  0.622  0.966  0.899  1.0
  F  F28  1  0.622  0.534  0.399  1.0
  F  F29  1  0.878  0.466  0.899  1.0
  F  F30  1  0.122  0.966  0.601  1.0
  F  F31  1  0.378  0.034  0.101  1.0
  F  F32  1  0.654  0.224  0.556  1.0
  F  F33  1  0.846  0.776  0.056  1.0
  F  F34  1  0.154  0.276  0.444  1.0
  F  F35  1  0.346  0.724  0.944  1.0
  F  F36  1  0.346  0.776  0.444  1.0
  F  F37  1  0.154  0.224  0.944  1.0
  F  F38  1  0.846  0.724  0.556  1.0
  F  F39  1  0.654  0.276  0.056  1.0
[/CIF]
.