The structure described by NaMg14W crystallizes in the orthorhombic Amm2 space group. Na(1) is bonded to two equivalent Mg(6), four equivalent Mg(3), four equivalent Mg(5), and two equivalent W(1) atoms to form NaMg10W2 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra, corners with six equivalent Na(1)Mg10W2 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent W(1)Na2Mg10 cuboctahedra, edges with four equivalent Mg(6)NaMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(6)NaMg11 cuboctahedra, and faces with two equivalent W(1)Na2Mg10 cuboctahedra. There are seven inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2), two equivalent Mg(6), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent W(1)Na2Mg10 cuboctahedra, corners with six equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(6)NaMg11 cuboctahedra, faces with two equivalent Na(1)Mg10W2 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(6)NaMg11 cuboctahedra, and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1), two equivalent Mg(7), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Na(1)Mg10W2 cuboctahedra, corners with six equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent W(1)Na2Mg10 cuboctahedra, faces with four equivalent Mg(4)Mg12 cuboctahedra, and faces with six equivalent Mg(6)NaMg11 cuboctahedra. In the third Mg site, Mg(3) is bonded in a 12-coordinate geometry to two equivalent Na(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent W(1) atoms. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Na(1)Mg10W2 cuboctahedra, corners with four equivalent W(1)Na2Mg10 cuboctahedra, corners with six equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(6)NaMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, and faces with two equivalent Mg(6)NaMg11 cuboctahedra. In the fifth Mg site, Mg(5) is bonded in a 2-coordinate geometry to one Na(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(6), and one W(1) atom. In the sixth Mg site, Mg(6) is bonded to one Na(1), one Mg(1), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(7), and four equivalent Mg(5) atoms to form distorted MgNaMg11 cuboctahedra that share corners with six equivalent Mg(6)NaMg11 cuboctahedra, edges with two equivalent Na(1)Mg10W2 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra,  a faceface with one Na(1)Mg10W2 cuboctahedra,  a faceface with one Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Mg(6)NaMg11 cuboctahedra, faces with three equivalent Mg(2)Mg12 cuboctahedra, and faces with three equivalent W(1)Na2Mg10 cuboctahedra. In the seventh Mg site, Mg(7) is bonded in a distorted single-bond geometry to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), and one W(1) atom. W(1) is bonded to two equivalent Na(1), two equivalent Mg(7), four equivalent Mg(3), and four equivalent Mg(5) atoms to form WNa2Mg10 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra, corners with six equivalent W(1)Na2Mg10 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Na(1)Mg10W2 cuboctahedra, faces with two equivalent Na(1)Mg10W2 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, and faces with six equivalent Mg(6)NaMg11 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaMg14W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.311
_cell_length_b   6.487
_cell_length_c   10.058
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.929
_symmetry_Int_Tables_number   1
_cell_volume   353.271
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.168  0.334  0.125  1.0
  Mg  Mg1  1  0.170  0.335  0.625  1.0
  Mg  Mg2  1  0.168  0.834  0.625  1.0
  Mg  Mg3  1  0.667  0.334  0.125  1.0
  Mg  Mg4  1  0.667  0.336  0.625  1.0
  Mg  Mg5  1  0.667  0.833  0.125  1.0
  Mg  Mg6  1  0.667  0.831  0.625  1.0
  Mg  Mg7  1  0.325  0.150  0.367  1.0
  Mg  Mg8  1  0.325  0.150  0.883  1.0
  Mg  Mg9  1  0.325  0.675  0.367  1.0
  Mg  Mg10  1  0.325  0.675  0.883  1.0
  Mg  Mg11  1  0.828  0.164  0.379  1.0
  Mg  Mg12  1  0.828  0.164  0.871  1.0
  Mg  Mg13  1  0.845  0.673  0.364  1.0
  Mg  Mg14  1  0.845  0.673  0.886  1.0
  W  W15  1  0.180  0.840  0.125  1.0
[/CIF]
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The structure described by NaMg14W crystallizes in the orthorhombic Amm2 space group. Na(1) is bonded to two equivalent Mg(6), four equivalent Mg(3), four equivalent Mg(5), and two equivalent W(1) atoms to form NaMg10W2 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra, corners with six equivalent Na(1)Mg10W2 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent W(1)Na2Mg10 cuboctahedra, edges with four equivalent Mg(6)NaMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(6)NaMg11 cuboctahedra, and faces with two equivalent W(1)Na2Mg10 cuboctahedra. There are seven inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2), two equivalent Mg(6), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent W(1)Na2Mg10 cuboctahedra, corners with six equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(6)NaMg11 cuboctahedra, faces with two equivalent Na(1)Mg10W2 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(6)NaMg11 cuboctahedra, and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1), two equivalent Mg(7), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Na(1)Mg10W2 cuboctahedra, corners with six equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent W(1)Na2Mg10 cuboctahedra, faces with four equivalent Mg(4)Mg12 cuboctahedra, and faces with six equivalent Mg(6)NaMg11 cuboctahedra. In the third Mg site, Mg(3) is bonded in a 12-coordinate geometry to two equivalent Na(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent W(1) atoms. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Na(1)Mg10W2 cuboctahedra, corners with four equivalent W(1)Na2Mg10 cuboctahedra, corners with six equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(6)NaMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, and faces with two equivalent Mg(6)NaMg11 cuboctahedra. In the fifth Mg site, Mg(5) is bonded in a 2-coordinate geometry to one Na(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(6), and one W(1) atom. In the sixth Mg site, Mg(6) is bonded to one Na(1), one Mg(1), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(7), and four equivalent Mg(5) atoms to form distorted MgNaMg11 cuboctahedra that share corners with six equivalent Mg(6)NaMg11 cuboctahedra, edges with two equivalent Na(1)Mg10W2 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra,  a faceface with one Na(1)Mg10W2 cuboctahedra,  a faceface with one Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Mg(6)NaMg11 cuboctahedra, faces with three equivalent Mg(2)Mg12 cuboctahedra, and faces with three equivalent W(1)Na2Mg10 cuboctahedra. In the seventh Mg site, Mg(7) is bonded in a distorted single-bond geometry to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), and one W(1) atom. W(1) is bonded to two equivalent Na(1), two equivalent Mg(7), four equivalent Mg(3), and four equivalent Mg(5) atoms to form WNa2Mg10 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra, corners with six equivalent W(1)Na2Mg10 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Na(1)Mg10W2 cuboctahedra, faces with two equivalent Na(1)Mg10W2 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, and faces with six equivalent Mg(6)NaMg11 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaMg14W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.311
_cell_length_b   6.487
_cell_length_c   10.058
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.929
_symmetry_Int_Tables_number   1
_cell_volume   353.271
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.168  0.334  0.125  1.0
  Mg  Mg1  1  0.170  0.335  0.625  1.0
  Mg  Mg2  1  0.168  0.834  0.625  1.0
  Mg  Mg3  1  0.667  0.334  0.125  1.0
  Mg  Mg4  1  0.667  0.336  0.625  1.0
  Mg  Mg5  1  0.667  0.833  0.125  1.0
  Mg  Mg6  1  0.667  0.831  0.625  1.0
  Mg  Mg7  1  0.325  0.150  0.367  1.0
  Mg  Mg8  1  0.325  0.150  0.883  1.0
  Mg  Mg9  1  0.325  0.675  0.367  1.0
  Mg  Mg10  1  0.325  0.675  0.883  1.0
  Mg  Mg11  1  0.828  0.164  0.379  1.0
  Mg  Mg12  1  0.828  0.164  0.871  1.0
  Mg  Mg13  1  0.845  0.673  0.364  1.0
  Mg  Mg14  1  0.845  0.673  0.886  1.0
  W  W15  1  0.180  0.840  0.125  1.0
[/CIF]
.