The material structure described by Ag2NO3Cl crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent O(2) and three equivalent Cl(1) atoms to form distorted AgCl3O4 pentagonal bipyramids that share corners with two equivalent Ag(1)Cl3O4 pentagonal bipyramids, corners with four equivalent Ag(2)Cl2O4 pentagonal pyramids, edges with four equivalent Ag(1)Cl3O4 pentagonal bipyramids, and edges with three equivalent Ag(2)Cl2O4 pentagonal pyramids. In the second Ag site, Ag(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms to form distorted AgCl2O4 pentagonal pyramids that share corners with four equivalent Ag(1)Cl3O4 pentagonal bipyramids, corners with four equivalent Ag(2)Cl2O4 pentagonal pyramids, and edges with three equivalent Ag(1)Cl3O4 pentagonal bipyramids. N(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one N(1) atom. Cl(1) is bonded to two equivalent Ag(2) and three equivalent Ag(1) atoms to form a mixture of corner and edge-sharing ClAg5 trigonal bipyramids. is represented by the CIF card [CIF]
data_Ag2NClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.151
_cell_length_b   6.664
_cell_length_c   12.955
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   444.642
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.250  0.763  0.532  1.0
  Ag  Ag1  1  0.750  0.237  0.468  1.0
  Ag  Ag2  1  0.250  0.354  0.248  1.0
  Ag  Ag3  1  0.750  0.737  0.032  1.0
  Ag  Ag4  1  0.750  0.146  0.748  1.0
  Ag  Ag5  1  0.250  0.854  0.252  1.0
  Ag  Ag6  1  0.250  0.263  0.968  1.0
  Ag  Ag7  1  0.750  0.646  0.752  1.0
  N  N8  1  0.750  0.142  0.147  1.0
  N  N9  1  0.250  0.858  0.853  1.0
  N  N10  1  0.750  0.642  0.353  1.0
  N  N11  1  0.250  0.358  0.647  1.0
  Cl  Cl12  1  0.750  0.396  0.909  1.0
  Cl  Cl13  1  0.750  0.896  0.591  1.0
  Cl  Cl14  1  0.250  0.104  0.409  1.0
  Cl  Cl15  1  0.250  0.604  0.091  1.0
  O  O16  1  0.750  0.791  0.292  1.0
  O  O17  1  0.463  0.934  0.884  1.0
  O  O18  1  0.037  0.434  0.616  1.0
  O  O19  1  0.250  0.709  0.792  1.0
  O  O20  1  0.537  0.566  0.384  1.0
  O  O21  1  0.963  0.066  0.116  1.0
  O  O22  1  0.037  0.934  0.884  1.0
  O  O23  1  0.250  0.209  0.708  1.0
  O  O24  1  0.537  0.066  0.116  1.0
  O  O25  1  0.463  0.434  0.616  1.0
  O  O26  1  0.750  0.291  0.208  1.0
  O  O27  1  0.963  0.566  0.384  1.0
[/CIF]
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The material structure described by Ag2NO3Cl crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent O(2) and three equivalent Cl(1) atoms to form distorted AgCl3O4 pentagonal bipyramids that share corners with two equivalent Ag(1)Cl3O4 pentagonal bipyramids, corners with four equivalent Ag(2)Cl2O4 pentagonal pyramids, edges with four equivalent Ag(1)Cl3O4 pentagonal bipyramids, and edges with three equivalent Ag(2)Cl2O4 pentagonal pyramids. In the second Ag site, Ag(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms to form distorted AgCl2O4 pentagonal pyramids that share corners with four equivalent Ag(1)Cl3O4 pentagonal bipyramids, corners with four equivalent Ag(2)Cl2O4 pentagonal pyramids, and edges with three equivalent Ag(1)Cl3O4 pentagonal bipyramids. N(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one N(1) atom. Cl(1) is bonded to two equivalent Ag(2) and three equivalent Ag(1) atoms to form a mixture of corner and edge-sharing ClAg5 trigonal bipyramids. is represented by the CIF card [CIF]
data_Ag2NClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.151
_cell_length_b   6.664
_cell_length_c   12.955
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   444.642
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.250  0.763  0.532  1.0
  Ag  Ag1  1  0.750  0.237  0.468  1.0
  Ag  Ag2  1  0.250  0.354  0.248  1.0
  Ag  Ag3  1  0.750  0.737  0.032  1.0
  Ag  Ag4  1  0.750  0.146  0.748  1.0
  Ag  Ag5  1  0.250  0.854  0.252  1.0
  Ag  Ag6  1  0.250  0.263  0.968  1.0
  Ag  Ag7  1  0.750  0.646  0.752  1.0
  N  N8  1  0.750  0.142  0.147  1.0
  N  N9  1  0.250  0.858  0.853  1.0
  N  N10  1  0.750  0.642  0.353  1.0
  N  N11  1  0.250  0.358  0.647  1.0
  Cl  Cl12  1  0.750  0.396  0.909  1.0
  Cl  Cl13  1  0.750  0.896  0.591  1.0
  Cl  Cl14  1  0.250  0.104  0.409  1.0
  Cl  Cl15  1  0.250  0.604  0.091  1.0
  O  O16  1  0.750  0.791  0.292  1.0
  O  O17  1  0.463  0.934  0.884  1.0
  O  O18  1  0.037  0.434  0.616  1.0
  O  O19  1  0.250  0.709  0.792  1.0
  O  O20  1  0.537  0.566  0.384  1.0
  O  O21  1  0.963  0.066  0.116  1.0
  O  O22  1  0.037  0.934  0.884  1.0
  O  O23  1  0.250  0.209  0.708  1.0
  O  O24  1  0.537  0.066  0.116  1.0
  O  O25  1  0.463  0.434  0.616  1.0
  O  O26  1  0.750  0.291  0.208  1.0
  O  O27  1  0.963  0.566  0.384  1.0
[/CIF]
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