The structure described by MgMo10Ag6O33 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 5-coordinate geometry to one O(13), one O(17), one O(25), one O(29), one O(5), and one O(9) atom. There are ten inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(18), one O(24), one O(25), one O(29), one O(30), and one O(33) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(19), one O(24), one O(25), one O(28), one O(31), and one O(32) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(20), one O(22), one O(23), one O(27), one O(30), and one O(33) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(21), one O(22), one O(23), one O(26), one O(31), and one O(32) atom. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(16), one O(2), one O(4), and one O(8) atom. In the sixth Mo site, Mo(6) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(3), one O(5), and one O(9) atom. In the seventh Mo site, Mo(7) is bonded in a tetrahedral geometry to one O(13), one O(3), one O(4), and one O(6) atom. In the eighth Mo site, Mo(8) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(15), one O(2), one O(5), and one O(7) atom. In the ninth Mo site, Mo(9) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(22), one O(24), one O(30), and one O(32) atom. In the tenth Mo site, Mo(10) is bonded in a 6-coordinate geometry to one O(15), one O(17), one O(23), one O(25), one O(31), and one O(33) atom. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one O(10), one O(12), one O(22), and one O(24) atom. In the second Ag site, Ag(2) is bonded in a distorted T-shaped geometry to one O(11), one O(23), and one O(25) atom. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one O(10), one O(18), one O(2), one O(20), and one O(6) atom. In the fourth Ag site, Ag(4) is bonded in a 5-coordinate geometry to one O(17), one O(21), one O(27), one O(3), and one O(9) atom. In the fifth Ag site, Ag(5) is bonded in a distorted trigonal pyramidal geometry to one O(12), one O(18), one O(28), and one O(8) atom. In the sixth Ag site, Ag(6) is bonded in a 4-coordinate geometry to one O(15), one O(19), one O(7), and one O(9) atom. There are thirty-three inequivalent O sites. In the first O site, O(1) is bonded in a T-shaped geometry to one Mo(5), one Mo(6), and one Mo(8) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mo(5), one Mo(8), and one Ag(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(6), one Mo(7), and one Ag(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mo(5) and one Mo(7) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Mg(1), one Mo(6), and one Mo(8) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Mo(7) and one Ag(3) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Mo(8) and one Ag(6) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mo(5) and one Ag(5) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), one Mo(6), one Ag(4), and one Ag(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(6), one Ag(1), and one Ag(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(5) and one Ag(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Mo(8), one Ag(1), and one Ag(5) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Mo(7) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(9) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mo(10), one Mo(8), and one Ag(6) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Mo(5) and one Mo(9) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Mg(1), one Mo(10), and one Ag(4) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(3), and one Ag(5) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Mo(2) and one Ag(6) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Mo(3) and one Ag(3) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Mo(4) and one Ag(4) atom. In the twenty-second O site, O(22) is bonded to one Mo(3), one Mo(4), one Mo(9), and one Ag(1) atom to form a mixture of distorted corner and edge-sharing OAgMo3 tetrahedra. In the twenty-third O site, O(23) is bonded to one Mo(10), one Mo(3), one Mo(4), and one Ag(2) atom to form edge-sharing OAgMo3 tetrahedra. In the twenty-fourth O site, O(24) is bonded to one Mo(1), one Mo(2), one Mo(9), and one Ag(1) atom to form corner-sharing OAgMo3 tetrahedra. In the twenty-fifth O site, O(25) is bonded in a 5-coordinate geometry to one Mg(1), one Mo(1), one Mo(10), one Mo(2), and one Ag(2) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one Mo(4) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 120 degrees geometry to one Mo(3) and one Ag(4) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one Mo(2) and one Ag(5) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the thirtieth O site, O(30) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(3), and one Mo(9) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal non-coplanar geometry to one Mo(10), one Mo(2), and one Mo(4) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(4), and one Mo(9) atom. In the thirty-third O site, O(33) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(10), and one Mo(3) atom. is represented by the CIF file [CIF]
data_MgAg6Mo10O33
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.737
_cell_length_b   8.854
_cell_length_c   11.644
_cell_angle_alpha   77.177
_cell_angle_beta   79.270
_cell_angle_gamma   75.994
_symmetry_Int_Tables_number   1
_cell_volume   747.139
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.383  0.211  0.768  1.0
  Ag  Ag1  1  0.326  0.024  0.258  1.0
  Ag  Ag2  1  0.705  0.909  0.742  1.0
  Ag  Ag3  1  0.205  0.437  0.193  1.0
  Ag  Ag4  1  0.967  0.411  0.727  1.0
  Ag  Ag5  1  0.518  0.579  0.254  1.0
  Ag  Ag6  1  0.351  0.553  0.831  1.0
  Mo  Mo7  1  0.448  0.212  0.477  1.0
  Mo  Mo8  1  0.563  0.776  0.525  1.0
  Mo  Mo9  1  0.946  0.215  0.478  1.0
  Mo  Mo10  1  0.061  0.784  0.515  1.0
  Mo  Mo11  1  0.870  0.803  0.047  1.0
  Mo  Mo12  1  0.115  0.187  0.978  1.0
  Mo  Mo13  1  0.654  0.213  0.981  1.0
  Mo  Mo14  1  0.294  0.825  0.007  1.0
  Mo  Mo15  1  0.800  0.012  0.315  1.0
  Mo  Mo16  1  0.206  0.975  0.677  1.0
  O  O17  1  0.037  0.976  0.006  1.0
  O  O18  1  0.116  0.681  0.058  1.0
  O  O19  1  0.857  0.299  0.952  1.0
  O  O20  1  0.674  0.004  0.056  1.0
  O  O21  1  0.348  0.031  0.929  1.0
  O  O22  1  0.474  0.333  0.054  1.0
  O  O23  1  0.474  0.692  0.943  1.0
  O  O24  1  0.753  0.659  0.128  1.0
  O  O25  1  0.207  0.357  0.866  1.0
  O  O26  1  0.149  0.207  0.117  1.0
  O  O27  1  0.845  0.807  0.899  1.0
  O  O28  1  0.347  0.820  0.150  1.0
  O  O29  1  0.605  0.219  0.835  1.0
  O  O30  1  0.767  0.179  0.205  1.0
  O  O31  1  0.215  0.828  0.809  1.0
  O  O32  1  0.864  0.856  0.234  1.0
  O  O33  1  0.147  0.153  0.753  1.0
  O  O34  1  0.417  0.358  0.347  1.0
  O  O35  1  0.584  0.648  0.662  1.0
  O  O36  1  0.995  0.346  0.345  1.0
  O  O37  1  0.027  0.650  0.648  1.0
  O  O38  1  0.023  0.006  0.372  1.0
  O  O39  1  0.978  0.995  0.607  1.0
  O  O40  1  0.540  0.008  0.382  1.0
  O  O41  1  0.473  0.993  0.624  1.0
  O  O42  1  0.163  0.669  0.409  1.0
  O  O43  1  0.856  0.338  0.582  1.0
  O  O44  1  0.587  0.655  0.422  1.0
  O  O45  1  0.422  0.319  0.593  1.0
  O  O46  1  0.717  0.172  0.454  1.0
  O  O47  1  0.293  0.830  0.541  1.0
  O  O48  1  0.803  0.829  0.490  1.0
  O  O49  1  0.212  0.162  0.503  1.0
[/CIF]
.
The structure described by MgMo10Ag6O33 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 5-coordinate geometry to one O(13), one O(17), one O(25), one O(29), one O(5), and one O(9) atom. There are ten inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(18), one O(24), one O(25), one O(29), one O(30), and one O(33) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(19), one O(24), one O(25), one O(28), one O(31), and one O(32) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(20), one O(22), one O(23), one O(27), one O(30), and one O(33) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(21), one O(22), one O(23), one O(26), one O(31), and one O(32) atom. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(16), one O(2), one O(4), and one O(8) atom. In the sixth Mo site, Mo(6) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(3), one O(5), and one O(9) atom. In the seventh Mo site, Mo(7) is bonded in a tetrahedral geometry to one O(13), one O(3), one O(4), and one O(6) atom. In the eighth Mo site, Mo(8) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(15), one O(2), one O(5), and one O(7) atom. In the ninth Mo site, Mo(9) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(22), one O(24), one O(30), and one O(32) atom. In the tenth Mo site, Mo(10) is bonded in a 6-coordinate geometry to one O(15), one O(17), one O(23), one O(25), one O(31), and one O(33) atom. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one O(10), one O(12), one O(22), and one O(24) atom. In the second Ag site, Ag(2) is bonded in a distorted T-shaped geometry to one O(11), one O(23), and one O(25) atom. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one O(10), one O(18), one O(2), one O(20), and one O(6) atom. In the fourth Ag site, Ag(4) is bonded in a 5-coordinate geometry to one O(17), one O(21), one O(27), one O(3), and one O(9) atom. In the fifth Ag site, Ag(5) is bonded in a distorted trigonal pyramidal geometry to one O(12), one O(18), one O(28), and one O(8) atom. In the sixth Ag site, Ag(6) is bonded in a 4-coordinate geometry to one O(15), one O(19), one O(7), and one O(9) atom. There are thirty-three inequivalent O sites. In the first O site, O(1) is bonded in a T-shaped geometry to one Mo(5), one Mo(6), and one Mo(8) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mo(5), one Mo(8), and one Ag(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(6), one Mo(7), and one Ag(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mo(5) and one Mo(7) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Mg(1), one Mo(6), and one Mo(8) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Mo(7) and one Ag(3) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Mo(8) and one Ag(6) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mo(5) and one Ag(5) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), one Mo(6), one Ag(4), and one Ag(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(6), one Ag(1), and one Ag(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(5) and one Ag(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Mo(8), one Ag(1), and one Ag(5) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Mo(7) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(9) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mo(10), one Mo(8), and one Ag(6) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Mo(5) and one Mo(9) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Mg(1), one Mo(10), and one Ag(4) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(3), and one Ag(5) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Mo(2) and one Ag(6) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Mo(3) and one Ag(3) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Mo(4) and one Ag(4) atom. In the twenty-second O site, O(22) is bonded to one Mo(3), one Mo(4), one Mo(9), and one Ag(1) atom to form a mixture of distorted corner and edge-sharing OAgMo3 tetrahedra. In the twenty-third O site, O(23) is bonded to one Mo(10), one Mo(3), one Mo(4), and one Ag(2) atom to form edge-sharing OAgMo3 tetrahedra. In the twenty-fourth O site, O(24) is bonded to one Mo(1), one Mo(2), one Mo(9), and one Ag(1) atom to form corner-sharing OAgMo3 tetrahedra. In the twenty-fifth O site, O(25) is bonded in a 5-coordinate geometry to one Mg(1), one Mo(1), one Mo(10), one Mo(2), and one Ag(2) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one Mo(4) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 120 degrees geometry to one Mo(3) and one Ag(4) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one Mo(2) and one Ag(5) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the thirtieth O site, O(30) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(3), and one Mo(9) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal non-coplanar geometry to one Mo(10), one Mo(2), and one Mo(4) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(4), and one Mo(9) atom. In the thirty-third O site, O(33) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(10), and one Mo(3) atom. is represented by the CIF file [CIF]
data_MgAg6Mo10O33
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.737
_cell_length_b   8.854
_cell_length_c   11.644
_cell_angle_alpha   77.177
_cell_angle_beta   79.270
_cell_angle_gamma   75.994
_symmetry_Int_Tables_number   1
_cell_volume   747.139
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.383  0.211  0.768  1.0
  Ag  Ag1  1  0.326  0.024  0.258  1.0
  Ag  Ag2  1  0.705  0.909  0.742  1.0
  Ag  Ag3  1  0.205  0.437  0.193  1.0
  Ag  Ag4  1  0.967  0.411  0.727  1.0
  Ag  Ag5  1  0.518  0.579  0.254  1.0
  Ag  Ag6  1  0.351  0.553  0.831  1.0
  Mo  Mo7  1  0.448  0.212  0.477  1.0
  Mo  Mo8  1  0.563  0.776  0.525  1.0
  Mo  Mo9  1  0.946  0.215  0.478  1.0
  Mo  Mo10  1  0.061  0.784  0.515  1.0
  Mo  Mo11  1  0.870  0.803  0.047  1.0
  Mo  Mo12  1  0.115  0.187  0.978  1.0
  Mo  Mo13  1  0.654  0.213  0.981  1.0
  Mo  Mo14  1  0.294  0.825  0.007  1.0
  Mo  Mo15  1  0.800  0.012  0.315  1.0
  Mo  Mo16  1  0.206  0.975  0.677  1.0
  O  O17  1  0.037  0.976  0.006  1.0
  O  O18  1  0.116  0.681  0.058  1.0
  O  O19  1  0.857  0.299  0.952  1.0
  O  O20  1  0.674  0.004  0.056  1.0
  O  O21  1  0.348  0.031  0.929  1.0
  O  O22  1  0.474  0.333  0.054  1.0
  O  O23  1  0.474  0.692  0.943  1.0
  O  O24  1  0.753  0.659  0.128  1.0
  O  O25  1  0.207  0.357  0.866  1.0
  O  O26  1  0.149  0.207  0.117  1.0
  O  O27  1  0.845  0.807  0.899  1.0
  O  O28  1  0.347  0.820  0.150  1.0
  O  O29  1  0.605  0.219  0.835  1.0
  O  O30  1  0.767  0.179  0.205  1.0
  O  O31  1  0.215  0.828  0.809  1.0
  O  O32  1  0.864  0.856  0.234  1.0
  O  O33  1  0.147  0.153  0.753  1.0
  O  O34  1  0.417  0.358  0.347  1.0
  O  O35  1  0.584  0.648  0.662  1.0
  O  O36  1  0.995  0.346  0.345  1.0
  O  O37  1  0.027  0.650  0.648  1.0
  O  O38  1  0.023  0.006  0.372  1.0
  O  O39  1  0.978  0.995  0.607  1.0
  O  O40  1  0.540  0.008  0.382  1.0
  O  O41  1  0.473  0.993  0.624  1.0
  O  O42  1  0.163  0.669  0.409  1.0
  O  O43  1  0.856  0.338  0.582  1.0
  O  O44  1  0.587  0.655  0.422  1.0
  O  O45  1  0.422  0.319  0.593  1.0
  O  O46  1  0.717  0.172  0.454  1.0
  O  O47  1  0.293  0.830  0.541  1.0
  O  O48  1  0.803  0.829  0.490  1.0
  O  O49  1  0.212  0.162  0.503  1.0
[/CIF]
.