The material structure described by V2ON is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent N(1) and four equivalent O(1) atoms to form VN2O4 octahedra that share corners with six equivalent V(1)N2O4 octahedra, edges with four equivalent V(1)N2O4 octahedra, and edges with eight equivalent V(2)N4O2 octahedra. The corner-sharing octahedra are not tilted. In the second V site, V(2) is bonded to four equivalent N(1) and two equivalent O(1) atoms to form VN4O2 octahedra that share corners with six equivalent V(2)N4O2 octahedra, edges with four equivalent V(2)N4O2 octahedra, and edges with eight equivalent V(1)N2O4 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded to two equivalent V(1) and four equivalent V(2) atoms to form NV6 octahedra that share corners with six equivalent N(1)V6 octahedra, edges with four equivalent N(1)V6 octahedra, and edges with eight equivalent O(1)V6 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent V(2) and four equivalent V(1) atoms to form OV6 octahedra that share corners with six equivalent O(1)V6 octahedra, edges with four equivalent O(1)V6 octahedra, and edges with eight equivalent N(1)V6 octahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2NO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.080
_cell_length_b   3.080
_cell_length_c   4.419
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   41.917
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  N  N2  1  0.000  0.000  0.500  1.0
  O  O3  1  0.500  0.500  0.000  1.0
[/CIF]
.
The material structure described by V2ON is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent N(1) and four equivalent O(1) atoms to form VN2O4 octahedra that share corners with six equivalent V(1)N2O4 octahedra, edges with four equivalent V(1)N2O4 octahedra, and edges with eight equivalent V(2)N4O2 octahedra. The corner-sharing octahedra are not tilted. In the second V site, V(2) is bonded to four equivalent N(1) and two equivalent O(1) atoms to form VN4O2 octahedra that share corners with six equivalent V(2)N4O2 octahedra, edges with four equivalent V(2)N4O2 octahedra, and edges with eight equivalent V(1)N2O4 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded to two equivalent V(1) and four equivalent V(2) atoms to form NV6 octahedra that share corners with six equivalent N(1)V6 octahedra, edges with four equivalent N(1)V6 octahedra, and edges with eight equivalent O(1)V6 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent V(2) and four equivalent V(1) atoms to form OV6 octahedra that share corners with six equivalent O(1)V6 octahedra, edges with four equivalent O(1)V6 octahedra, and edges with eight equivalent N(1)V6 octahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2NO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.080
_cell_length_b   3.080
_cell_length_c   4.419
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   41.917
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  N  N2  1  0.000  0.000  0.500  1.0
  O  O3  1  0.500  0.500  0.000  1.0
[/CIF]
.