The material structure described by Sr10Fe4Co(MoO6)5 crystallizes in the tetragonal I4/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(2), one O(5), one O(7), two equivalent O(3), two equivalent O(4), two equivalent O(6), and three equivalent O(1) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(2)O12 cuboctahedra, corners with nine equivalent Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with five equivalent Sr(1)O12 cuboctahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with three equivalent Mo(1)O6 octahedra, and faces with three equivalent Fe(1)O6 octahedra. In the second Sr site, Sr(2) is bonded to four equivalent O(1), four equivalent O(5), and four equivalent O(7) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Mo(1)O6 octahedra, and faces with four equivalent Fe(1)O6 octahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(2) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form MoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Fe(1)O6 octahedra, and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-18°. In the second Mo site, Mo(1) is bonded to one O(3), one O(5), one O(6), one O(7), and two equivalent O(1) atoms to form MoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with five equivalent Fe(1)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with six equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. Fe(1) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(1) atoms to form FeO6 octahedra that share  a cornercorner with one Mo(2)O6 octahedra, corners with five equivalent Mo(1)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with six equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-18°. Co(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form CoO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-16°. There are seven inequivalent O sites. In the first O site, O(1) is bonded to one Sr(2), three equivalent Sr(1), one Mo(1), and one Fe(1) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(2)Sr4CoMo octahedra, corners with five equivalent O(1)Sr4FeMo octahedra,  an edgeedge with one O(2)Sr4CoMo octahedra, and edges with three equivalent O(1)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second O site, O(2) is bonded to four equivalent Sr(1), one Mo(2), and one Co(1) atom to form distorted OSr4CoMo octahedra that share corners with two equivalent O(2)Sr4CoMo octahedra, corners with four equivalent O(1)Sr4FeMo octahedra, and edges with four equivalent O(1)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third O site, O(3) is bonded in a 4-coordinate geometry to four equivalent Sr(1), one Mo(1), and one Co(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to four equivalent Sr(1), one Mo(2), and one Fe(1) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Mo(1), and one Fe(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to four equivalent Sr(1), one Mo(1), and one Fe(1) atom. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Mo(1), and one Fe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr10Fe4Co(MoO6)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.749
_cell_length_b   9.749
_cell_length_c   9.749
_cell_angle_alpha   99.758
_cell_angle_beta   99.758
_cell_angle_gamma   131.378
_symmetry_Int_Tables_number   1
_cell_volume   633.674
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.348  0.051  0.900  1.0
  Sr  Sr1  1  0.750  0.250  0.500  1.0
  Sr  Sr2  1  0.552  0.652  0.703  1.0
  Sr  Sr3  1  0.949  0.850  0.297  1.0
  Sr  Sr4  1  0.150  0.448  0.100  1.0
  Sr  Sr5  1  0.250  0.750  0.500  1.0
  Sr  Sr6  1  0.652  0.949  0.100  1.0
  Sr  Sr7  1  0.448  0.348  0.297  1.0
  Sr  Sr8  1  0.850  0.552  0.900  1.0
  Sr  Sr9  1  0.051  0.150  0.703  1.0
  Fe  Fe10  1  0.799  0.402  0.201  1.0
  Fe  Fe11  1  0.598  0.799  0.396  1.0
  Fe  Fe12  1  0.402  0.201  0.604  1.0
  Fe  Fe13  1  0.201  0.598  0.799  1.0
  Co  Co14  1  0.000  0.000  0.000  1.0
  Mo  Mo15  1  0.900  0.702  0.602  1.0
  Mo  Mo16  1  0.298  0.900  0.198  1.0
  Mo  Mo17  1  0.100  0.298  0.398  1.0
  Mo  Mo18  1  0.500  0.500  0.000  1.0
  Mo  Mo19  1  0.702  0.100  0.802  1.0
  O  O20  1  0.448  0.849  0.801  1.0
  O  O21  1  0.849  0.048  0.401  1.0
  O  O22  1  0.647  0.448  0.599  1.0
  O  O23  1  0.048  0.647  0.199  1.0
  O  O24  1  0.253  0.253  0.000  1.0
  O  O25  1  0.151  0.952  0.599  1.0
  O  O26  1  0.552  0.151  0.199  1.0
  O  O27  1  0.353  0.552  0.401  1.0
  O  O28  1  0.747  0.747  0.000  1.0
  O  O29  1  0.952  0.353  0.801  1.0
  O  O30  1  0.847  0.028  0.875  1.0
  O  O31  1  0.642  0.427  0.069  1.0
  O  O32  1  0.442  0.831  0.273  1.0
  O  O33  1  0.239  0.231  0.469  1.0
  O  O34  1  0.039  0.633  0.673  1.0
  O  O35  1  0.358  0.573  0.931  1.0
  O  O36  1  0.153  0.972  0.125  1.0
  O  O37  1  0.961  0.367  0.327  1.0
  O  O38  1  0.761  0.769  0.531  1.0
  O  O39  1  0.558  0.169  0.727  1.0
  O  O40  1  0.769  0.239  0.008  1.0
  O  O41  1  0.573  0.642  0.215  1.0
  O  O42  1  0.367  0.039  0.406  1.0
  O  O43  1  0.169  0.442  0.612  1.0
  O  O44  1  0.972  0.847  0.820  1.0
  O  O45  1  0.633  0.961  0.594  1.0
  O  O46  1  0.427  0.358  0.785  1.0
  O  O47  1  0.231  0.761  0.992  1.0
  O  O48  1  0.028  0.153  0.180  1.0
  O  O49  1  0.831  0.558  0.388  1.0
[/CIF]
.
The material structure described by Sr10Fe4Co(MoO6)5 crystallizes in the tetragonal I4/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(2), one O(5), one O(7), two equivalent O(3), two equivalent O(4), two equivalent O(6), and three equivalent O(1) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(2)O12 cuboctahedra, corners with nine equivalent Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with five equivalent Sr(1)O12 cuboctahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with three equivalent Mo(1)O6 octahedra, and faces with three equivalent Fe(1)O6 octahedra. In the second Sr site, Sr(2) is bonded to four equivalent O(1), four equivalent O(5), and four equivalent O(7) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Mo(1)O6 octahedra, and faces with four equivalent Fe(1)O6 octahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(2) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form MoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Fe(1)O6 octahedra, and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-18°. In the second Mo site, Mo(1) is bonded to one O(3), one O(5), one O(6), one O(7), and two equivalent O(1) atoms to form MoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with five equivalent Fe(1)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with six equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. Fe(1) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(1) atoms to form FeO6 octahedra that share  a cornercorner with one Mo(2)O6 octahedra, corners with five equivalent Mo(1)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with six equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-18°. Co(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form CoO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-16°. There are seven inequivalent O sites. In the first O site, O(1) is bonded to one Sr(2), three equivalent Sr(1), one Mo(1), and one Fe(1) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(2)Sr4CoMo octahedra, corners with five equivalent O(1)Sr4FeMo octahedra,  an edgeedge with one O(2)Sr4CoMo octahedra, and edges with three equivalent O(1)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second O site, O(2) is bonded to four equivalent Sr(1), one Mo(2), and one Co(1) atom to form distorted OSr4CoMo octahedra that share corners with two equivalent O(2)Sr4CoMo octahedra, corners with four equivalent O(1)Sr4FeMo octahedra, and edges with four equivalent O(1)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third O site, O(3) is bonded in a 4-coordinate geometry to four equivalent Sr(1), one Mo(1), and one Co(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to four equivalent Sr(1), one Mo(2), and one Fe(1) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Mo(1), and one Fe(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to four equivalent Sr(1), one Mo(1), and one Fe(1) atom. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Mo(1), and one Fe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr10Fe4Co(MoO6)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.749
_cell_length_b   9.749
_cell_length_c   9.749
_cell_angle_alpha   99.758
_cell_angle_beta   99.758
_cell_angle_gamma   131.378
_symmetry_Int_Tables_number   1
_cell_volume   633.674
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.348  0.051  0.900  1.0
  Sr  Sr1  1  0.750  0.250  0.500  1.0
  Sr  Sr2  1  0.552  0.652  0.703  1.0
  Sr  Sr3  1  0.949  0.850  0.297  1.0
  Sr  Sr4  1  0.150  0.448  0.100  1.0
  Sr  Sr5  1  0.250  0.750  0.500  1.0
  Sr  Sr6  1  0.652  0.949  0.100  1.0
  Sr  Sr7  1  0.448  0.348  0.297  1.0
  Sr  Sr8  1  0.850  0.552  0.900  1.0
  Sr  Sr9  1  0.051  0.150  0.703  1.0
  Fe  Fe10  1  0.799  0.402  0.201  1.0
  Fe  Fe11  1  0.598  0.799  0.396  1.0
  Fe  Fe12  1  0.402  0.201  0.604  1.0
  Fe  Fe13  1  0.201  0.598  0.799  1.0
  Co  Co14  1  0.000  0.000  0.000  1.0
  Mo  Mo15  1  0.900  0.702  0.602  1.0
  Mo  Mo16  1  0.298  0.900  0.198  1.0
  Mo  Mo17  1  0.100  0.298  0.398  1.0
  Mo  Mo18  1  0.500  0.500  0.000  1.0
  Mo  Mo19  1  0.702  0.100  0.802  1.0
  O  O20  1  0.448  0.849  0.801  1.0
  O  O21  1  0.849  0.048  0.401  1.0
  O  O22  1  0.647  0.448  0.599  1.0
  O  O23  1  0.048  0.647  0.199  1.0
  O  O24  1  0.253  0.253  0.000  1.0
  O  O25  1  0.151  0.952  0.599  1.0
  O  O26  1  0.552  0.151  0.199  1.0
  O  O27  1  0.353  0.552  0.401  1.0
  O  O28  1  0.747  0.747  0.000  1.0
  O  O29  1  0.952  0.353  0.801  1.0
  O  O30  1  0.847  0.028  0.875  1.0
  O  O31  1  0.642  0.427  0.069  1.0
  O  O32  1  0.442  0.831  0.273  1.0
  O  O33  1  0.239  0.231  0.469  1.0
  O  O34  1  0.039  0.633  0.673  1.0
  O  O35  1  0.358  0.573  0.931  1.0
  O  O36  1  0.153  0.972  0.125  1.0
  O  O37  1  0.961  0.367  0.327  1.0
  O  O38  1  0.761  0.769  0.531  1.0
  O  O39  1  0.558  0.169  0.727  1.0
  O  O40  1  0.769  0.239  0.008  1.0
  O  O41  1  0.573  0.642  0.215  1.0
  O  O42  1  0.367  0.039  0.406  1.0
  O  O43  1  0.169  0.442  0.612  1.0
  O  O44  1  0.972  0.847  0.820  1.0
  O  O45  1  0.633  0.961  0.594  1.0
  O  O46  1  0.427  0.358  0.785  1.0
  O  O47  1  0.231  0.761  0.992  1.0
  O  O48  1  0.028  0.153  0.180  1.0
  O  O49  1  0.831  0.558  0.388  1.0
[/CIF]
.