The material structure described by AsF6(SeBr)3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three AsF6 clusters and three SeBr clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(15), one F(16), one F(5), one F(6), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(15) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(16) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In one of the SeBr clusters, there are three inequivalent Se sites. In the first Se site, Se(5) is bonded in a water-like geometry to one Se(9) and one Br(1) atom. In the second Se site, Se(6) is bonded in a distorted water-like geometry to one Se(9), one Br(2), and one Br(9) atom. In the third Se site, Se(9) is bonded in a water-like geometry to one Se(5) and one Se(6) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Se(5) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Se(6) atom. In the third Br site, Br(9) is bonded in a single-bond geometry to one Se(6) atom. In two of the SeBr clusters, there are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one Se(3) and one Se(7) atom. In the second Se site, Se(3) is bonded in a distorted water-like geometry to one Se(1), one Br(3), and one Br(7) atom. In the third Se site, Se(7) is bonded in a water-like geometry to one Se(1) and one Br(5) atom. There are three inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Se(3) atom. In the second Br site, Br(5) is bonded in a single-bond geometry to one Se(7) atom. In the third Br site, Br(7) is bonded in a single-bond geometry to one Se(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsSe3(BrF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.314
_cell_length_b   10.386
_cell_length_c   11.990
_cell_angle_alpha   79.450
_cell_angle_beta   87.317
_cell_angle_gamma   76.454
_symmetry_Int_Tables_number   1
_cell_volume   989.498
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.500  0.000  0.000  1.0
  As  As1  1  0.304  0.572  0.688  1.0
  As  As2  1  0.698  0.427  0.311  1.0
  Se  Se3  1  0.200  0.645  0.308  1.0
  Se  Se4  1  0.799  0.356  0.692  1.0
  Se  Se5  1  0.274  0.670  0.086  1.0
  Se  Se6  1  0.725  0.331  0.912  1.0
  Se  Se7  1  0.533  0.911  0.665  1.0
  Se  Se8  1  0.476  0.104  0.362  1.0
  Se  Se9  1  0.935  0.747  0.311  1.0
  Se  Se10  1  0.064  0.252  0.689  1.0
  Se  Se11  1  0.539  0.116  0.575  1.0
  Br  Br12  1  0.802  0.777  0.652  1.0
  Br  Br13  1  0.201  0.220  0.347  1.0
  Br  Br14  1  0.020  0.794  0.021  1.0
  Br  Br15  1  0.980  0.207  0.979  1.0
  Br  Br16  1  0.916  0.976  0.323  1.0
  Br  Br17  1  0.076  0.023  0.678  1.0
  Br  Br18  1  0.274  0.455  0.059  1.0
  Br  Br19  1  0.727  0.545  0.940  1.0
  Br  Br20  1  0.455  0.883  0.397  1.0
  F  F21  1  0.484  0.618  0.626  1.0
  F  F22  1  0.517  0.377  0.374  1.0
  F  F23  1  0.433  0.434  0.780  1.0
  F  F24  1  0.567  0.565  0.221  1.0
  F  F25  1  0.636  0.075  0.903  1.0
  F  F26  1  0.363  0.926  0.097  1.0
  F  F27  1  0.586  0.842  0.960  1.0
  F  F28  1  0.414  0.158  0.041  1.0
  F  F29  1  0.307  0.465  0.588  1.0
  F  F30  1  0.692  0.533  0.412  1.0
  F  F31  1  0.126  0.523  0.752  1.0
  F  F32  1  0.876  0.477  0.247  1.0
  F  F33  1  0.302  0.676  0.790  1.0
  F  F34  1  0.699  0.323  0.210  1.0
  F  F35  1  0.349  0.037  0.893  1.0
  F  F36  1  0.650  0.964  0.109  1.0
  F  F37  1  0.178  0.708  0.596  1.0
  F  F38  1  0.824  0.291  0.403  1.0
[/CIF]
.
The material structure described by AsF6(SeBr)3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three AsF6 clusters and three SeBr clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(15), one F(16), one F(5), one F(6), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(15) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(16) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In one of the SeBr clusters, there are three inequivalent Se sites. In the first Se site, Se(5) is bonded in a water-like geometry to one Se(9) and one Br(1) atom. In the second Se site, Se(6) is bonded in a distorted water-like geometry to one Se(9), one Br(2), and one Br(9) atom. In the third Se site, Se(9) is bonded in a water-like geometry to one Se(5) and one Se(6) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Se(5) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Se(6) atom. In the third Br site, Br(9) is bonded in a single-bond geometry to one Se(6) atom. In two of the SeBr clusters, there are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one Se(3) and one Se(7) atom. In the second Se site, Se(3) is bonded in a distorted water-like geometry to one Se(1), one Br(3), and one Br(7) atom. In the third Se site, Se(7) is bonded in a water-like geometry to one Se(1) and one Br(5) atom. There are three inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Se(3) atom. In the second Br site, Br(5) is bonded in a single-bond geometry to one Se(7) atom. In the third Br site, Br(7) is bonded in a single-bond geometry to one Se(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsSe3(BrF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.314
_cell_length_b   10.386
_cell_length_c   11.990
_cell_angle_alpha   79.450
_cell_angle_beta   87.317
_cell_angle_gamma   76.454
_symmetry_Int_Tables_number   1
_cell_volume   989.498
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.500  0.000  0.000  1.0
  As  As1  1  0.304  0.572  0.688  1.0
  As  As2  1  0.698  0.427  0.311  1.0
  Se  Se3  1  0.200  0.645  0.308  1.0
  Se  Se4  1  0.799  0.356  0.692  1.0
  Se  Se5  1  0.274  0.670  0.086  1.0
  Se  Se6  1  0.725  0.331  0.912  1.0
  Se  Se7  1  0.533  0.911  0.665  1.0
  Se  Se8  1  0.476  0.104  0.362  1.0
  Se  Se9  1  0.935  0.747  0.311  1.0
  Se  Se10  1  0.064  0.252  0.689  1.0
  Se  Se11  1  0.539  0.116  0.575  1.0
  Br  Br12  1  0.802  0.777  0.652  1.0
  Br  Br13  1  0.201  0.220  0.347  1.0
  Br  Br14  1  0.020  0.794  0.021  1.0
  Br  Br15  1  0.980  0.207  0.979  1.0
  Br  Br16  1  0.916  0.976  0.323  1.0
  Br  Br17  1  0.076  0.023  0.678  1.0
  Br  Br18  1  0.274  0.455  0.059  1.0
  Br  Br19  1  0.727  0.545  0.940  1.0
  Br  Br20  1  0.455  0.883  0.397  1.0
  F  F21  1  0.484  0.618  0.626  1.0
  F  F22  1  0.517  0.377  0.374  1.0
  F  F23  1  0.433  0.434  0.780  1.0
  F  F24  1  0.567  0.565  0.221  1.0
  F  F25  1  0.636  0.075  0.903  1.0
  F  F26  1  0.363  0.926  0.097  1.0
  F  F27  1  0.586  0.842  0.960  1.0
  F  F28  1  0.414  0.158  0.041  1.0
  F  F29  1  0.307  0.465  0.588  1.0
  F  F30  1  0.692  0.533  0.412  1.0
  F  F31  1  0.126  0.523  0.752  1.0
  F  F32  1  0.876  0.477  0.247  1.0
  F  F33  1  0.302  0.676  0.790  1.0
  F  F34  1  0.699  0.323  0.210  1.0
  F  F35  1  0.349  0.037  0.893  1.0
  F  F36  1  0.650  0.964  0.109  1.0
  F  F37  1  0.178  0.708  0.596  1.0
  F  F38  1  0.824  0.291  0.403  1.0
[/CIF]
.