The crystal structure described by KIn(MoO4)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 11-coordinate geometry to one O(5), two equivalent O(1), two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(5), and two equivalent O(4) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-36°. In the second Mo site, Mo(2) is bonded to one O(2), one O(6), and two equivalent O(3) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-47°. In(1) is bonded to one O(1), one O(6), two equivalent O(3), and two equivalent O(4) atoms to form InO6 octahedra that share corners with three equivalent Mo(1)O4 tetrahedra and corners with three equivalent Mo(2)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1), one Mo(1), and one In(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to two equivalent K(1) and one Mo(2) atom. In the fourth O site, O(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mo(2), and one In(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one K(1), one Mo(1), and one In(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one K(1) and one Mo(1) atom. is represented by the CIF file [CIF]
data_KIn(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.987
_cell_length_b   8.888
_cell_length_c   15.067
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   801.677
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.547  0.376  1.0
  K  K1  1  0.250  0.953  0.876  1.0
  K  K2  1  0.750  0.453  0.624  1.0
  K  K3  1  0.750  0.047  0.124  1.0
  In  In4  1  0.250  0.695  0.106  1.0
  In  In5  1  0.750  0.195  0.394  1.0
  In  In6  1  0.250  0.805  0.606  1.0
  In  In7  1  0.750  0.305  0.894  1.0
  Mo  Mo8  1  0.250  0.997  0.284  1.0
  Mo  Mo9  1  0.750  0.003  0.716  1.0
  Mo  Mo10  1  0.750  0.497  0.216  1.0
  Mo  Mo11  1  0.250  0.217  0.538  1.0
  Mo  Mo12  1  0.750  0.717  0.962  1.0
  Mo  Mo13  1  0.250  0.283  0.038  1.0
  Mo  Mo14  1  0.750  0.783  0.462  1.0
  Mo  Mo15  1  0.250  0.503  0.784  1.0
  O  O16  1  0.750  0.091  0.826  1.0
  O  O17  1  0.250  0.591  0.674  1.0
  O  O18  1  0.250  0.282  0.648  1.0
  O  O19  1  0.506  0.795  0.019  1.0
  O  O20  1  0.750  0.409  0.326  1.0
  O  O21  1  0.502  0.105  0.304  1.0
  O  O22  1  0.494  0.295  0.481  1.0
  O  O23  1  0.250  0.650  0.860  1.0
  O  O24  1  0.506  0.705  0.519  1.0
  O  O25  1  0.494  0.205  0.981  1.0
  O  O26  1  0.750  0.718  0.352  1.0
  O  O27  1  0.250  0.909  0.174  1.0
  O  O28  1  0.002  0.895  0.696  1.0
  O  O29  1  0.006  0.205  0.981  1.0
  O  O30  1  0.750  0.150  0.640  1.0
  O  O31  1  0.998  0.105  0.304  1.0
  O  O32  1  0.994  0.795  0.019  1.0
  O  O33  1  0.750  0.516  0.966  1.0
  O  O34  1  0.250  0.850  0.360  1.0
  O  O35  1  0.750  0.984  0.466  1.0
  O  O36  1  0.502  0.395  0.804  1.0
  O  O37  1  0.498  0.895  0.696  1.0
  O  O38  1  0.250  0.484  0.034  1.0
  O  O39  1  0.002  0.605  0.196  1.0
  O  O40  1  0.750  0.782  0.852  1.0
  O  O41  1  0.250  0.016  0.534  1.0
  O  O42  1  0.006  0.295  0.481  1.0
  O  O43  1  0.498  0.605  0.196  1.0
  O  O44  1  0.250  0.218  0.148  1.0
  O  O45  1  0.994  0.705  0.519  1.0
  O  O46  1  0.998  0.395  0.804  1.0
  O  O47  1  0.750  0.350  0.140  1.0
[/CIF]
.
The crystal structure described by KIn(MoO4)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 11-coordinate geometry to one O(5), two equivalent O(1), two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(5), and two equivalent O(4) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-36°. In the second Mo site, Mo(2) is bonded to one O(2), one O(6), and two equivalent O(3) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-47°. In(1) is bonded to one O(1), one O(6), two equivalent O(3), and two equivalent O(4) atoms to form InO6 octahedra that share corners with three equivalent Mo(1)O4 tetrahedra and corners with three equivalent Mo(2)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1), one Mo(1), and one In(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to two equivalent K(1) and one Mo(2) atom. In the fourth O site, O(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mo(2), and one In(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one K(1), one Mo(1), and one In(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one K(1) and one Mo(1) atom. is represented by the CIF file [CIF]
data_KIn(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.987
_cell_length_b   8.888
_cell_length_c   15.067
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   801.677
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.547  0.376  1.0
  K  K1  1  0.250  0.953  0.876  1.0
  K  K2  1  0.750  0.453  0.624  1.0
  K  K3  1  0.750  0.047  0.124  1.0
  In  In4  1  0.250  0.695  0.106  1.0
  In  In5  1  0.750  0.195  0.394  1.0
  In  In6  1  0.250  0.805  0.606  1.0
  In  In7  1  0.750  0.305  0.894  1.0
  Mo  Mo8  1  0.250  0.997  0.284  1.0
  Mo  Mo9  1  0.750  0.003  0.716  1.0
  Mo  Mo10  1  0.750  0.497  0.216  1.0
  Mo  Mo11  1  0.250  0.217  0.538  1.0
  Mo  Mo12  1  0.750  0.717  0.962  1.0
  Mo  Mo13  1  0.250  0.283  0.038  1.0
  Mo  Mo14  1  0.750  0.783  0.462  1.0
  Mo  Mo15  1  0.250  0.503  0.784  1.0
  O  O16  1  0.750  0.091  0.826  1.0
  O  O17  1  0.250  0.591  0.674  1.0
  O  O18  1  0.250  0.282  0.648  1.0
  O  O19  1  0.506  0.795  0.019  1.0
  O  O20  1  0.750  0.409  0.326  1.0
  O  O21  1  0.502  0.105  0.304  1.0
  O  O22  1  0.494  0.295  0.481  1.0
  O  O23  1  0.250  0.650  0.860  1.0
  O  O24  1  0.506  0.705  0.519  1.0
  O  O25  1  0.494  0.205  0.981  1.0
  O  O26  1  0.750  0.718  0.352  1.0
  O  O27  1  0.250  0.909  0.174  1.0
  O  O28  1  0.002  0.895  0.696  1.0
  O  O29  1  0.006  0.205  0.981  1.0
  O  O30  1  0.750  0.150  0.640  1.0
  O  O31  1  0.998  0.105  0.304  1.0
  O  O32  1  0.994  0.795  0.019  1.0
  O  O33  1  0.750  0.516  0.966  1.0
  O  O34  1  0.250  0.850  0.360  1.0
  O  O35  1  0.750  0.984  0.466  1.0
  O  O36  1  0.502  0.395  0.804  1.0
  O  O37  1  0.498  0.895  0.696  1.0
  O  O38  1  0.250  0.484  0.034  1.0
  O  O39  1  0.002  0.605  0.196  1.0
  O  O40  1  0.750  0.782  0.852  1.0
  O  O41  1  0.250  0.016  0.534  1.0
  O  O42  1  0.006  0.295  0.481  1.0
  O  O43  1  0.498  0.605  0.196  1.0
  O  O44  1  0.250  0.218  0.148  1.0
  O  O45  1  0.994  0.705  0.519  1.0
  O  O46  1  0.998  0.395  0.804  1.0
  O  O47  1  0.750  0.350  0.140  1.0
[/CIF]
.