The compound described by Ce(Pt2P)2 crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 15-coordinate geometry to one Pt(2), two equivalent Pt(3), two equivalent Pt(4), four equivalent Pt(1), two equivalent P(2), and four equivalent P(1) atoms. There are four inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 7-coordinate geometry to four equivalent Ce(1), two equivalent Pt(3), one P(2), and two equivalent P(1) atoms. In the second Pt site, Pt(2) is bonded in a 3-coordinate geometry to one Ce(1), one Pt(4), two equivalent Pt(3), and three equivalent P(2) atoms. In the third Pt site, Pt(3) is bonded in a 11-coordinate geometry to two equivalent Ce(1), two equivalent Pt(1), two equivalent Pt(2), two equivalent Pt(4), one P(2), and two equivalent P(1) atoms. In the fourth Pt site, Pt(4) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one Pt(2), two equivalent Pt(3), two equivalent Pt(4), one P(1), and one P(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Pt(4), two equivalent Pt(1), and two equivalent Pt(3) atoms. In the second P site, P(2) is bonded in a 8-coordinate geometry to two equivalent Ce(1), one Pt(1), one Pt(3), one Pt(4), and three equivalent Pt(2) atoms. is represented by the CIF card [CIF]
data_Ce(PPt2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.172
_cell_length_b   7.346
_cell_length_c   15.646
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   479.530
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.843  0.181  1.0
  Ce  Ce1  1  0.750  0.157  0.819  1.0
  Ce  Ce2  1  0.250  0.343  0.319  1.0
  Ce  Ce3  1  0.750  0.657  0.681  1.0
  P  P4  1  0.250  0.317  0.693  1.0
  P  P5  1  0.250  0.795  0.555  1.0
  P  P6  1  0.750  0.205  0.445  1.0
  P  P7  1  0.750  0.183  0.193  1.0
  P  P8  1  0.250  0.817  0.807  1.0
  P  P9  1  0.250  0.295  0.945  1.0
  P  P10  1  0.750  0.705  0.055  1.0
  P  P11  1  0.750  0.683  0.307  1.0
  Pt  Pt12  1  0.250  0.987  0.682  1.0
  Pt  Pt13  1  0.250  0.487  0.818  1.0
  Pt  Pt14  1  0.750  0.371  0.006  1.0
  Pt  Pt15  1  0.750  0.749  0.874  1.0
  Pt  Pt16  1  0.750  0.522  0.442  1.0
  Pt  Pt17  1  0.750  0.249  0.626  1.0
  Pt  Pt18  1  0.750  0.513  0.182  1.0
  Pt  Pt19  1  0.750  0.022  0.058  1.0
  Pt  Pt20  1  0.250  0.751  0.374  1.0
  Pt  Pt21  1  0.250  0.251  0.126  1.0
  Pt  Pt22  1  0.250  0.978  0.942  1.0
  Pt  Pt23  1  0.250  0.129  0.506  1.0
  Pt  Pt24  1  0.750  0.871  0.494  1.0
  Pt  Pt25  1  0.750  0.013  0.318  1.0
  Pt  Pt26  1  0.250  0.629  0.994  1.0
  Pt  Pt27  1  0.250  0.478  0.558  1.0
[/CIF]
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The compound described by Ce(Pt2P)2 crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 15-coordinate geometry to one Pt(2), two equivalent Pt(3), two equivalent Pt(4), four equivalent Pt(1), two equivalent P(2), and four equivalent P(1) atoms. There are four inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 7-coordinate geometry to four equivalent Ce(1), two equivalent Pt(3), one P(2), and two equivalent P(1) atoms. In the second Pt site, Pt(2) is bonded in a 3-coordinate geometry to one Ce(1), one Pt(4), two equivalent Pt(3), and three equivalent P(2) atoms. In the third Pt site, Pt(3) is bonded in a 11-coordinate geometry to two equivalent Ce(1), two equivalent Pt(1), two equivalent Pt(2), two equivalent Pt(4), one P(2), and two equivalent P(1) atoms. In the fourth Pt site, Pt(4) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one Pt(2), two equivalent Pt(3), two equivalent Pt(4), one P(1), and one P(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Pt(4), two equivalent Pt(1), and two equivalent Pt(3) atoms. In the second P site, P(2) is bonded in a 8-coordinate geometry to two equivalent Ce(1), one Pt(1), one Pt(3), one Pt(4), and three equivalent Pt(2) atoms. is represented by the CIF card [CIF]
data_Ce(PPt2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.172
_cell_length_b   7.346
_cell_length_c   15.646
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   479.530
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.843  0.181  1.0
  Ce  Ce1  1  0.750  0.157  0.819  1.0
  Ce  Ce2  1  0.250  0.343  0.319  1.0
  Ce  Ce3  1  0.750  0.657  0.681  1.0
  P  P4  1  0.250  0.317  0.693  1.0
  P  P5  1  0.250  0.795  0.555  1.0
  P  P6  1  0.750  0.205  0.445  1.0
  P  P7  1  0.750  0.183  0.193  1.0
  P  P8  1  0.250  0.817  0.807  1.0
  P  P9  1  0.250  0.295  0.945  1.0
  P  P10  1  0.750  0.705  0.055  1.0
  P  P11  1  0.750  0.683  0.307  1.0
  Pt  Pt12  1  0.250  0.987  0.682  1.0
  Pt  Pt13  1  0.250  0.487  0.818  1.0
  Pt  Pt14  1  0.750  0.371  0.006  1.0
  Pt  Pt15  1  0.750  0.749  0.874  1.0
  Pt  Pt16  1  0.750  0.522  0.442  1.0
  Pt  Pt17  1  0.750  0.249  0.626  1.0
  Pt  Pt18  1  0.750  0.513  0.182  1.0
  Pt  Pt19  1  0.750  0.022  0.058  1.0
  Pt  Pt20  1  0.250  0.751  0.374  1.0
  Pt  Pt21  1  0.250  0.251  0.126  1.0
  Pt  Pt22  1  0.250  0.978  0.942  1.0
  Pt  Pt23  1  0.250  0.129  0.506  1.0
  Pt  Pt24  1  0.750  0.871  0.494  1.0
  Pt  Pt25  1  0.750  0.013  0.318  1.0
  Pt  Pt26  1  0.250  0.629  0.994  1.0
  Pt  Pt27  1  0.250  0.478  0.558  1.0
[/CIF]
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