The compound described by Na4Ga3Ge3O16 crystallizes in the cubic P-43n space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. Ga(1) is bonded to four equivalent O(2) atoms to form GaO4 tetrahedra that share corners with four equivalent Ge(1)O4 tetrahedra. Ge(1) is bonded to four equivalent O(2) atoms to form GeO4 tetrahedra that share corners with four equivalent Ga(1)O4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Na(1) and three equivalent O(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Na(1), one Ga(1), and one Ge(1) atom. is represented by the CIF card [CIF]
data_Na4Ga3Ge3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.257
_cell_length_b   9.257
_cell_length_c   9.257
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   793.245
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.829  0.829  0.171  1.0
  Na  Na1  1  0.171  0.829  0.829  1.0
  Na  Na2  1  0.171  0.171  0.171  1.0
  Na  Na3  1  0.829  0.171  0.829  1.0
  Na  Na4  1  0.329  0.671  0.329  1.0
  Na  Na5  1  0.671  0.329  0.329  1.0
  Na  Na6  1  0.671  0.671  0.671  1.0
  Na  Na7  1  0.329  0.329  0.671  1.0
  Ga  Ga8  1  0.500  0.000  0.250  1.0
  Ga  Ga9  1  0.000  0.750  0.500  1.0
  Ga  Ga10  1  0.250  0.500  0.000  1.0
  Ga  Ga11  1  0.000  0.250  0.500  1.0
  Ga  Ga12  1  0.750  0.500  0.000  1.0
  Ga  Ga13  1  0.500  0.000  0.750  1.0
  Ge  Ge14  1  0.250  0.000  0.500  1.0
  Ge  Ge15  1  0.000  0.500  0.250  1.0
  Ge  Ge16  1  0.500  0.750  0.000  1.0
  Ge  Ge17  1  0.750  0.000  0.500  1.0
  Ge  Ge18  1  0.500  0.250  0.000  1.0
  Ge  Ge19  1  0.000  0.500  0.750  1.0
  O  O20  1  0.075  0.925  0.075  1.0
  O  O21  1  0.925  0.075  0.075  1.0
  O  O22  1  0.075  0.075  0.925  1.0
  O  O23  1  0.925  0.925  0.925  1.0
  O  O24  1  0.575  0.575  0.425  1.0
  O  O25  1  0.425  0.575  0.575  1.0
  O  O26  1  0.575  0.425  0.575  1.0
  O  O27  1  0.425  0.425  0.425  1.0
  O  O28  1  0.146  0.861  0.580  1.0
  O  O29  1  0.139  0.420  0.146  1.0
  O  O30  1  0.580  0.854  0.139  1.0
  O  O31  1  0.854  0.139  0.580  1.0
  O  O32  1  0.861  0.580  0.146  1.0
  O  O33  1  0.420  0.146  0.139  1.0
  O  O34  1  0.146  0.139  0.420  1.0
  O  O35  1  0.139  0.580  0.854  1.0
  O  O36  1  0.580  0.146  0.861  1.0
  O  O37  1  0.854  0.861  0.420  1.0
  O  O38  1  0.861  0.420  0.854  1.0
  O  O39  1  0.420  0.854  0.861  1.0
  O  O40  1  0.646  0.080  0.361  1.0
  O  O41  1  0.639  0.646  0.920  1.0
  O  O42  1  0.080  0.639  0.354  1.0
  O  O43  1  0.354  0.080  0.639  1.0
  O  O44  1  0.361  0.646  0.080  1.0
  O  O45  1  0.920  0.639  0.646  1.0
  O  O46  1  0.646  0.920  0.639  1.0
  O  O47  1  0.639  0.354  0.080  1.0
  O  O48  1  0.080  0.361  0.646  1.0
  O  O49  1  0.354  0.920  0.361  1.0
  O  O50  1  0.361  0.354  0.920  1.0
  O  O51  1  0.920  0.361  0.354  1.0
[/CIF]
.
The compound described by Na4Ga3Ge3O16 crystallizes in the cubic P-43n space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. Ga(1) is bonded to four equivalent O(2) atoms to form GaO4 tetrahedra that share corners with four equivalent Ge(1)O4 tetrahedra. Ge(1) is bonded to four equivalent O(2) atoms to form GeO4 tetrahedra that share corners with four equivalent Ga(1)O4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Na(1) and three equivalent O(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Na(1), one Ga(1), and one Ge(1) atom. is represented by the CIF card [CIF]
data_Na4Ga3Ge3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.257
_cell_length_b   9.257
_cell_length_c   9.257
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   793.245
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.829  0.829  0.171  1.0
  Na  Na1  1  0.171  0.829  0.829  1.0
  Na  Na2  1  0.171  0.171  0.171  1.0
  Na  Na3  1  0.829  0.171  0.829  1.0
  Na  Na4  1  0.329  0.671  0.329  1.0
  Na  Na5  1  0.671  0.329  0.329  1.0
  Na  Na6  1  0.671  0.671  0.671  1.0
  Na  Na7  1  0.329  0.329  0.671  1.0
  Ga  Ga8  1  0.500  0.000  0.250  1.0
  Ga  Ga9  1  0.000  0.750  0.500  1.0
  Ga  Ga10  1  0.250  0.500  0.000  1.0
  Ga  Ga11  1  0.000  0.250  0.500  1.0
  Ga  Ga12  1  0.750  0.500  0.000  1.0
  Ga  Ga13  1  0.500  0.000  0.750  1.0
  Ge  Ge14  1  0.250  0.000  0.500  1.0
  Ge  Ge15  1  0.000  0.500  0.250  1.0
  Ge  Ge16  1  0.500  0.750  0.000  1.0
  Ge  Ge17  1  0.750  0.000  0.500  1.0
  Ge  Ge18  1  0.500  0.250  0.000  1.0
  Ge  Ge19  1  0.000  0.500  0.750  1.0
  O  O20  1  0.075  0.925  0.075  1.0
  O  O21  1  0.925  0.075  0.075  1.0
  O  O22  1  0.075  0.075  0.925  1.0
  O  O23  1  0.925  0.925  0.925  1.0
  O  O24  1  0.575  0.575  0.425  1.0
  O  O25  1  0.425  0.575  0.575  1.0
  O  O26  1  0.575  0.425  0.575  1.0
  O  O27  1  0.425  0.425  0.425  1.0
  O  O28  1  0.146  0.861  0.580  1.0
  O  O29  1  0.139  0.420  0.146  1.0
  O  O30  1  0.580  0.854  0.139  1.0
  O  O31  1  0.854  0.139  0.580  1.0
  O  O32  1  0.861  0.580  0.146  1.0
  O  O33  1  0.420  0.146  0.139  1.0
  O  O34  1  0.146  0.139  0.420  1.0
  O  O35  1  0.139  0.580  0.854  1.0
  O  O36  1  0.580  0.146  0.861  1.0
  O  O37  1  0.854  0.861  0.420  1.0
  O  O38  1  0.861  0.420  0.854  1.0
  O  O39  1  0.420  0.854  0.861  1.0
  O  O40  1  0.646  0.080  0.361  1.0
  O  O41  1  0.639  0.646  0.920  1.0
  O  O42  1  0.080  0.639  0.354  1.0
  O  O43  1  0.354  0.080  0.639  1.0
  O  O44  1  0.361  0.646  0.080  1.0
  O  O45  1  0.920  0.639  0.646  1.0
  O  O46  1  0.646  0.920  0.639  1.0
  O  O47  1  0.639  0.354  0.080  1.0
  O  O48  1  0.080  0.361  0.646  1.0
  O  O49  1  0.354  0.920  0.361  1.0
  O  O50  1  0.361  0.354  0.920  1.0
  O  O51  1  0.920  0.361  0.354  1.0
[/CIF]
.