The material structure described by TmY15O24 is Spinel-like structured and crystallizes in the monoclinic C2 space group. Tm(1) is bonded to two equivalent O(12), two equivalent O(3), and two equivalent O(9) atoms to form distorted TmO6 octahedra that share corners with two equivalent Y(3)O6 octahedra, corners with two equivalent Y(4)O6 octahedra, corners with two equivalent Y(7)O6 octahedra, edges with two equivalent Y(1)O6 octahedra, edges with two equivalent Y(5)O6 octahedra, and edges with two equivalent Y(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are nine inequivalent Y sites. In the first Y site, Y(1) is bonded to one O(10), one O(12), one O(2), one O(3), one O(4), and one O(7) atom to form YO6 octahedra that share  a cornercorner with one Y(3)O6 octahedra,  a cornercorner with one Y(4)O6 octahedra,  a cornercorner with one Y(5)O6 octahedra,  a cornercorner with one Y(6)O6 octahedra,  a cornercorner with one Y(8)O6 octahedra,  a cornercorner with one Y(9)O6 octahedra,  an edgeedge with one Tm(1)O6 octahedra,  an edgeedge with one Y(2)O6 octahedra,  an edgeedge with one Y(3)O6 octahedra,  an edgeedge with one Y(4)O6 octahedra,  an edgeedge with one Y(5)O6 octahedra, and  an edgeedge with one Y(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the second Y site, Y(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form a mixture of distorted edge and corner-sharing YO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Y site, Y(3) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(9) atom to form distorted YO6 octahedra that share  a cornercorner with one Tm(1)O6 octahedra,  a cornercorner with one Y(1)O6 octahedra,  a cornercorner with one Y(7)O6 octahedra,  a cornercorner with one Y(8)O6 octahedra, corners with two equivalent Y(4)O6 octahedra,  an edgeedge with one Y(1)O6 octahedra,  an edgeedge with one Y(2)O6 octahedra,  an edgeedge with one Y(6)O6 octahedra,  an edgeedge with one Y(7)O6 octahedra, and edges with two equivalent Y(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the fourth Y site, Y(4) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(8) atom to form distorted YO6 octahedra that share  a cornercorner with one Tm(1)O6 octahedra,  a cornercorner with one Y(1)O6 octahedra,  a cornercorner with one Y(7)O6 octahedra,  a cornercorner with one Y(8)O6 octahedra, corners with two equivalent Y(3)O6 octahedra,  an edgeedge with one Y(1)O6 octahedra,  an edgeedge with one Y(2)O6 octahedra,  an edgeedge with one Y(6)O6 octahedra,  an edgeedge with one Y(7)O6 octahedra, and edges with two equivalent Y(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. In the fifth Y site, Y(5) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(9) atom to form distorted YO6 octahedra that share  a cornercorner with one Y(1)O6 octahedra,  a cornercorner with one Y(2)O6 octahedra,  a cornercorner with one Y(6)O6 octahedra,  a cornercorner with one Y(7)O6 octahedra, corners with two equivalent Y(9)O6 octahedra,  an edgeedge with one Tm(1)O6 octahedra,  an edgeedge with one Y(1)O6 octahedra,  an edgeedge with one Y(7)O6 octahedra,  an edgeedge with one Y(8)O6 octahedra, and edges with two equivalent Y(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the sixth Y site, Y(6) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(5) atoms to form a mixture of distorted edge and corner-sharing YO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the seventh Y site, Y(7) is bonded to one O(1), one O(11), one O(5), one O(6), one O(8), and one O(9) atom to form YO6 octahedra that share  a cornercorner with one Tm(1)O6 octahedra,  a cornercorner with one Y(2)O6 octahedra,  a cornercorner with one Y(3)O6 octahedra,  a cornercorner with one Y(4)O6 octahedra,  a cornercorner with one Y(5)O6 octahedra,  a cornercorner with one Y(9)O6 octahedra,  an edgeedge with one Y(3)O6 octahedra,  an edgeedge with one Y(4)O6 octahedra,  an edgeedge with one Y(5)O6 octahedra,  an edgeedge with one Y(6)O6 octahedra,  an edgeedge with one Y(8)O6 octahedra, and  an edgeedge with one Y(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-57°. In the eighth Y site, Y(8) is bonded to two equivalent O(11), two equivalent O(6), and two equivalent O(7) atoms to form a mixture of distorted edge and corner-sharing YO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the ninth Y site, Y(9) is bonded to one O(10), one O(11), one O(12), one O(3), one O(6), and one O(8) atom to form distorted YO6 octahedra that share  a cornercorner with one Y(1)O6 octahedra,  a cornercorner with one Y(2)O6 octahedra,  a cornercorner with one Y(6)O6 octahedra,  a cornercorner with one Y(7)O6 octahedra, corners with two equivalent Y(5)O6 octahedra,  an edgeedge with one Tm(1)O6 octahedra,  an edgeedge with one Y(1)O6 octahedra,  an edgeedge with one Y(7)O6 octahedra,  an edgeedge with one Y(8)O6 octahedra, and edges with two equivalent Y(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Y(3), one Y(5), one Y(6), and one Y(7) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(10)Y4 trigonal pyramids, corners with two equivalent O(2)Y4 trigonal pyramids, corners with two equivalent O(6)Y4 trigonal pyramids,  an edgeedge with one O(9)Y3Tm trigonal pyramid,  an edgeedge with one O(7)Y4 trigonal pyramid, and edges with two equivalent O(5)Y4 trigonal pyramids. In the second O site, O(2) is bonded to one Y(1), one Y(2), one Y(3), and one Y(5) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(3)Y3Tm trigonal pyramids, corners with two equivalent O(1)Y4 trigonal pyramids, corners with two equivalent O(8)Y4 trigonal pyramids,  an edgeedge with one O(9)Y3Tm trigonal pyramid,  an edgeedge with one O(7)Y4 trigonal pyramid, and edges with two equivalent O(4)Y4 trigonal pyramids. In the third O site, O(3) is bonded to one Tm(1), one Y(1), one Y(5), and one Y(9) atom to form OY3Tm trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(10)Y4 trigonal pyramids, corners with two equivalent O(2)Y4 trigonal pyramids, corners with two equivalent O(6)Y4 trigonal pyramids,  an edgeedge with one O(9)Y3Tm trigonal pyramid,  an edgeedge with one O(7)Y4 trigonal pyramid, and edges with two equivalent O(12)Y3Tm trigonal pyramids. In the fourth O site, O(4) is bonded to one Y(1), one Y(2), one Y(3), and one Y(4) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(12)Y3Tm trigonal pyramids, corners with two equivalent O(5)Y4 trigonal pyramids, corners with two equivalent O(7)Y4 trigonal pyramids,  an edgeedge with one O(10)Y4 trigonal pyramid,  an edgeedge with one O(8)Y4 trigonal pyramid, and edges with two equivalent O(2)Y4 trigonal pyramids. In the fifth O site, O(5) is bonded to one Y(3), one Y(4), one Y(6), and one Y(7) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(9)Y3Tm trigonal pyramids, corners with two equivalent O(11)Y4 trigonal pyramids, corners with two equivalent O(4)Y4 trigonal pyramids,  an edgeedge with one O(10)Y4 trigonal pyramid,  an edgeedge with one O(8)Y4 trigonal pyramid, and edges with two equivalent O(1)Y4 trigonal pyramids. In the sixth O site, O(6) is bonded to one Y(5), one Y(7), one Y(8), and one Y(9) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(3)Y3Tm trigonal pyramids, corners with two equivalent O(1)Y4 trigonal pyramids, corners with two equivalent O(8)Y4 trigonal pyramids,  an edgeedge with one O(9)Y3Tm trigonal pyramid,  an edgeedge with one O(7)Y4 trigonal pyramid, and edges with two equivalent O(11)Y4 trigonal pyramids. In the seventh O site, O(7) is bonded to one Y(1), one Y(3), one Y(5), and one Y(8) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(9)Y3Tm trigonal pyramids, corners with two equivalent O(11)Y4 trigonal pyramids, corners with two equivalent O(4)Y4 trigonal pyramids,  an edgeedge with one O(3)Y3Tm trigonal pyramid,  an edgeedge with one O(1)Y4 trigonal pyramid,  an edgeedge with one O(2)Y4 trigonal pyramid, and  an edgeedge with one O(6)Y4 trigonal pyramid. In the eighth O site, O(8) is bonded to one Y(2), one Y(4), one Y(7), and one Y(9) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(10)Y4 trigonal pyramids, corners with two equivalent O(2)Y4 trigonal pyramids, corners with two equivalent O(6)Y4 trigonal pyramids,  an edgeedge with one O(12)Y3Tm trigonal pyramid,  an edgeedge with one O(11)Y4 trigonal pyramid,  an edgeedge with one O(4)Y4 trigonal pyramid, and  an edgeedge with one O(5)Y4 trigonal pyramid. In the ninth O site, O(9) is bonded to one Tm(1), one Y(3), one Y(5), and one Y(7) atom to form OY3Tm trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(12)Y3Tm trigonal pyramids, corners with two equivalent O(5)Y4 trigonal pyramids, corners with two equivalent O(7)Y4 trigonal pyramids,  an edgeedge with one O(3)Y3Tm trigonal pyramid,  an edgeedge with one O(1)Y4 trigonal pyramid,  an edgeedge with one O(2)Y4 trigonal pyramid, and  an edgeedge with one O(6)Y4 trigonal pyramid. In the tenth O site, O(10) is bonded to one Y(1), one Y(4), one Y(6), and one Y(9) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(3)Y3Tm trigonal pyramids, corners with two equivalent O(1)Y4 trigonal pyramids, corners with two equivalent O(8)Y4 trigonal pyramids,  an edgeedge with one O(12)Y3Tm trigonal pyramid,  an edgeedge with one O(11)Y4 trigonal pyramid,  an edgeedge with one O(4)Y4 trigonal pyramid, and  an edgeedge with one O(5)Y4 trigonal pyramid. In the eleventh O site, O(11) is bonded to one Y(4), one Y(7), one Y(8), and one Y(9) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(12)Y3Tm trigonal pyramids, corners with two equivalent O(5)Y4 trigonal pyramids, corners with two equivalent O(7)Y4 trigonal pyramids,  an edgeedge with one O(10)Y4 trigonal pyramid,  an edgeedge with one O(8)Y4 trigonal pyramid, and edges with two equivalent O(6)Y4 trigonal pyramids. In the twelfth O site, O(12) is bonded to one Tm(1), one Y(1), one Y(4), and one Y(9) atom to form OY3Tm trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(9)Y3Tm trigonal pyramids, corners with two equivalent O(11)Y4 trigonal pyramids, corners with two equivalent O(4)Y4 trigonal pyramids,  an edgeedge with one O(10)Y4 trigonal pyramid,  an edgeedge with one O(8)Y4 trigonal pyramid, and edges with two equivalent O(3)Y3Tm trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Y15TmO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.176
_cell_length_b   9.176
_cell_length_c   10.592
_cell_angle_alpha   54.718
_cell_angle_beta   54.718
_cell_angle_gamma   70.506
_symmetry_Int_Tables_number   1
_cell_volume   594.335
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.000  1.000  0.749  1.0
  Y  Y1  1  0.783  0.217  0.000  1.0
  Y  Y2  1  0.250  0.251  0.782  1.0
  Y  Y3  1  0.749  0.750  0.218  1.0
  Y  Y4  1  0.968  0.468  0.532  1.0
  Y  Y5  1  0.467  0.967  0.034  1.0
  Y  Y6  1  0.000  1.000  0.251  1.0
  Y  Y7  1  0.718  0.282  0.500  1.0
  Y  Y8  1  0.499  0.500  0.251  1.0
  Y  Y9  1  0.282  0.718  0.000  1.0
  Y  Y10  1  0.500  0.501  0.749  1.0
  Y  Y11  1  0.532  0.032  0.468  1.0
  Y  Y12  1  0.033  0.533  0.966  1.0
  Y  Y13  1  0.751  0.750  0.717  1.0
  Y  Y14  1  0.250  0.249  0.283  1.0
  Tm  Tm15  1  0.217  0.783  0.500  1.0
  O  O16  1  0.510  0.230  0.782  1.0
  O  O17  1  0.729  0.011  0.978  1.0
  O  O18  1  0.960  0.762  0.758  1.0
  O  O19  1  0.761  0.957  0.261  1.0
  O  O20  1  0.740  0.543  0.479  1.0
  O  O21  1  0.543  0.739  0.980  1.0
  O  O22  1  0.770  0.490  0.218  1.0
  O  O23  1  0.989  0.271  0.022  1.0
  O  O24  1  0.228  0.968  0.011  1.0
  O  O25  1  0.728  0.468  0.792  1.0
  O  O26  1  0.465  0.728  0.296  1.0
  O  O27  1  0.968  0.228  0.511  1.0
  O  O28  1  0.532  0.272  0.208  1.0
  O  O29  1  0.772  0.032  0.489  1.0
  O  O30  1  0.272  0.535  0.704  1.0
  O  O31  1  0.032  0.772  0.989  1.0
  O  O32  1  0.229  0.511  0.282  1.0
  O  O33  1  0.014  0.729  0.479  1.0
  O  O34  1  0.457  0.260  0.521  1.0
  O  O35  1  0.261  0.457  0.020  1.0
  O  O36  1  0.043  0.239  0.739  1.0
  O  O37  1  0.238  0.040  0.242  1.0
  O  O38  1  0.489  0.771  0.718  1.0
  O  O39  1  0.271  0.986  0.521  1.0
[/CIF]
.
The material structure described by TmY15O24 is Spinel-like structured and crystallizes in the monoclinic C2 space group. Tm(1) is bonded to two equivalent O(12), two equivalent O(3), and two equivalent O(9) atoms to form distorted TmO6 octahedra that share corners with two equivalent Y(3)O6 octahedra, corners with two equivalent Y(4)O6 octahedra, corners with two equivalent Y(7)O6 octahedra, edges with two equivalent Y(1)O6 octahedra, edges with two equivalent Y(5)O6 octahedra, and edges with two equivalent Y(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are nine inequivalent Y sites. In the first Y site, Y(1) is bonded to one O(10), one O(12), one O(2), one O(3), one O(4), and one O(7) atom to form YO6 octahedra that share  a cornercorner with one Y(3)O6 octahedra,  a cornercorner with one Y(4)O6 octahedra,  a cornercorner with one Y(5)O6 octahedra,  a cornercorner with one Y(6)O6 octahedra,  a cornercorner with one Y(8)O6 octahedra,  a cornercorner with one Y(9)O6 octahedra,  an edgeedge with one Tm(1)O6 octahedra,  an edgeedge with one Y(2)O6 octahedra,  an edgeedge with one Y(3)O6 octahedra,  an edgeedge with one Y(4)O6 octahedra,  an edgeedge with one Y(5)O6 octahedra, and  an edgeedge with one Y(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the second Y site, Y(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form a mixture of distorted edge and corner-sharing YO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Y site, Y(3) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(9) atom to form distorted YO6 octahedra that share  a cornercorner with one Tm(1)O6 octahedra,  a cornercorner with one Y(1)O6 octahedra,  a cornercorner with one Y(7)O6 octahedra,  a cornercorner with one Y(8)O6 octahedra, corners with two equivalent Y(4)O6 octahedra,  an edgeedge with one Y(1)O6 octahedra,  an edgeedge with one Y(2)O6 octahedra,  an edgeedge with one Y(6)O6 octahedra,  an edgeedge with one Y(7)O6 octahedra, and edges with two equivalent Y(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the fourth Y site, Y(4) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(8) atom to form distorted YO6 octahedra that share  a cornercorner with one Tm(1)O6 octahedra,  a cornercorner with one Y(1)O6 octahedra,  a cornercorner with one Y(7)O6 octahedra,  a cornercorner with one Y(8)O6 octahedra, corners with two equivalent Y(3)O6 octahedra,  an edgeedge with one Y(1)O6 octahedra,  an edgeedge with one Y(2)O6 octahedra,  an edgeedge with one Y(6)O6 octahedra,  an edgeedge with one Y(7)O6 octahedra, and edges with two equivalent Y(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. In the fifth Y site, Y(5) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(9) atom to form distorted YO6 octahedra that share  a cornercorner with one Y(1)O6 octahedra,  a cornercorner with one Y(2)O6 octahedra,  a cornercorner with one Y(6)O6 octahedra,  a cornercorner with one Y(7)O6 octahedra, corners with two equivalent Y(9)O6 octahedra,  an edgeedge with one Tm(1)O6 octahedra,  an edgeedge with one Y(1)O6 octahedra,  an edgeedge with one Y(7)O6 octahedra,  an edgeedge with one Y(8)O6 octahedra, and edges with two equivalent Y(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the sixth Y site, Y(6) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(5) atoms to form a mixture of distorted edge and corner-sharing YO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the seventh Y site, Y(7) is bonded to one O(1), one O(11), one O(5), one O(6), one O(8), and one O(9) atom to form YO6 octahedra that share  a cornercorner with one Tm(1)O6 octahedra,  a cornercorner with one Y(2)O6 octahedra,  a cornercorner with one Y(3)O6 octahedra,  a cornercorner with one Y(4)O6 octahedra,  a cornercorner with one Y(5)O6 octahedra,  a cornercorner with one Y(9)O6 octahedra,  an edgeedge with one Y(3)O6 octahedra,  an edgeedge with one Y(4)O6 octahedra,  an edgeedge with one Y(5)O6 octahedra,  an edgeedge with one Y(6)O6 octahedra,  an edgeedge with one Y(8)O6 octahedra, and  an edgeedge with one Y(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-57°. In the eighth Y site, Y(8) is bonded to two equivalent O(11), two equivalent O(6), and two equivalent O(7) atoms to form a mixture of distorted edge and corner-sharing YO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the ninth Y site, Y(9) is bonded to one O(10), one O(11), one O(12), one O(3), one O(6), and one O(8) atom to form distorted YO6 octahedra that share  a cornercorner with one Y(1)O6 octahedra,  a cornercorner with one Y(2)O6 octahedra,  a cornercorner with one Y(6)O6 octahedra,  a cornercorner with one Y(7)O6 octahedra, corners with two equivalent Y(5)O6 octahedra,  an edgeedge with one Tm(1)O6 octahedra,  an edgeedge with one Y(1)O6 octahedra,  an edgeedge with one Y(7)O6 octahedra,  an edgeedge with one Y(8)O6 octahedra, and edges with two equivalent Y(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Y(3), one Y(5), one Y(6), and one Y(7) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(10)Y4 trigonal pyramids, corners with two equivalent O(2)Y4 trigonal pyramids, corners with two equivalent O(6)Y4 trigonal pyramids,  an edgeedge with one O(9)Y3Tm trigonal pyramid,  an edgeedge with one O(7)Y4 trigonal pyramid, and edges with two equivalent O(5)Y4 trigonal pyramids. In the second O site, O(2) is bonded to one Y(1), one Y(2), one Y(3), and one Y(5) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(3)Y3Tm trigonal pyramids, corners with two equivalent O(1)Y4 trigonal pyramids, corners with two equivalent O(8)Y4 trigonal pyramids,  an edgeedge with one O(9)Y3Tm trigonal pyramid,  an edgeedge with one O(7)Y4 trigonal pyramid, and edges with two equivalent O(4)Y4 trigonal pyramids. In the third O site, O(3) is bonded to one Tm(1), one Y(1), one Y(5), and one Y(9) atom to form OY3Tm trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(10)Y4 trigonal pyramids, corners with two equivalent O(2)Y4 trigonal pyramids, corners with two equivalent O(6)Y4 trigonal pyramids,  an edgeedge with one O(9)Y3Tm trigonal pyramid,  an edgeedge with one O(7)Y4 trigonal pyramid, and edges with two equivalent O(12)Y3Tm trigonal pyramids. In the fourth O site, O(4) is bonded to one Y(1), one Y(2), one Y(3), and one Y(4) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(12)Y3Tm trigonal pyramids, corners with two equivalent O(5)Y4 trigonal pyramids, corners with two equivalent O(7)Y4 trigonal pyramids,  an edgeedge with one O(10)Y4 trigonal pyramid,  an edgeedge with one O(8)Y4 trigonal pyramid, and edges with two equivalent O(2)Y4 trigonal pyramids. In the fifth O site, O(5) is bonded to one Y(3), one Y(4), one Y(6), and one Y(7) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(9)Y3Tm trigonal pyramids, corners with two equivalent O(11)Y4 trigonal pyramids, corners with two equivalent O(4)Y4 trigonal pyramids,  an edgeedge with one O(10)Y4 trigonal pyramid,  an edgeedge with one O(8)Y4 trigonal pyramid, and edges with two equivalent O(1)Y4 trigonal pyramids. In the sixth O site, O(6) is bonded to one Y(5), one Y(7), one Y(8), and one Y(9) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(3)Y3Tm trigonal pyramids, corners with two equivalent O(1)Y4 trigonal pyramids, corners with two equivalent O(8)Y4 trigonal pyramids,  an edgeedge with one O(9)Y3Tm trigonal pyramid,  an edgeedge with one O(7)Y4 trigonal pyramid, and edges with two equivalent O(11)Y4 trigonal pyramids. In the seventh O site, O(7) is bonded to one Y(1), one Y(3), one Y(5), and one Y(8) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(9)Y3Tm trigonal pyramids, corners with two equivalent O(11)Y4 trigonal pyramids, corners with two equivalent O(4)Y4 trigonal pyramids,  an edgeedge with one O(3)Y3Tm trigonal pyramid,  an edgeedge with one O(1)Y4 trigonal pyramid,  an edgeedge with one O(2)Y4 trigonal pyramid, and  an edgeedge with one O(6)Y4 trigonal pyramid. In the eighth O site, O(8) is bonded to one Y(2), one Y(4), one Y(7), and one Y(9) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(10)Y4 trigonal pyramids, corners with two equivalent O(2)Y4 trigonal pyramids, corners with two equivalent O(6)Y4 trigonal pyramids,  an edgeedge with one O(12)Y3Tm trigonal pyramid,  an edgeedge with one O(11)Y4 trigonal pyramid,  an edgeedge with one O(4)Y4 trigonal pyramid, and  an edgeedge with one O(5)Y4 trigonal pyramid. In the ninth O site, O(9) is bonded to one Tm(1), one Y(3), one Y(5), and one Y(7) atom to form OY3Tm trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(12)Y3Tm trigonal pyramids, corners with two equivalent O(5)Y4 trigonal pyramids, corners with two equivalent O(7)Y4 trigonal pyramids,  an edgeedge with one O(3)Y3Tm trigonal pyramid,  an edgeedge with one O(1)Y4 trigonal pyramid,  an edgeedge with one O(2)Y4 trigonal pyramid, and  an edgeedge with one O(6)Y4 trigonal pyramid. In the tenth O site, O(10) is bonded to one Y(1), one Y(4), one Y(6), and one Y(9) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(3)Y3Tm trigonal pyramids, corners with two equivalent O(1)Y4 trigonal pyramids, corners with two equivalent O(8)Y4 trigonal pyramids,  an edgeedge with one O(12)Y3Tm trigonal pyramid,  an edgeedge with one O(11)Y4 trigonal pyramid,  an edgeedge with one O(4)Y4 trigonal pyramid, and  an edgeedge with one O(5)Y4 trigonal pyramid. In the eleventh O site, O(11) is bonded to one Y(4), one Y(7), one Y(8), and one Y(9) atom to form OY4 trigonal pyramids that share  a cornercorner with one O(3)Y3Tm trigonal pyramid,  a cornercorner with one O(9)Y3Tm trigonal pyramid,  a cornercorner with one O(1)Y4 trigonal pyramid,  a cornercorner with one O(11)Y4 trigonal pyramid,  a cornercorner with one O(4)Y4 trigonal pyramid,  a cornercorner with one O(8)Y4 trigonal pyramid, corners with two equivalent O(12)Y3Tm trigonal pyramids, corners with two equivalent O(5)Y4 trigonal pyramids, corners with two equivalent O(7)Y4 trigonal pyramids,  an edgeedge with one O(10)Y4 trigonal pyramid,  an edgeedge with one O(8)Y4 trigonal pyramid, and edges with two equivalent O(6)Y4 trigonal pyramids. In the twelfth O site, O(12) is bonded to one Tm(1), one Y(1), one Y(4), and one Y(9) atom to form OY3Tm trigonal pyramids that share  a cornercorner with one O(12)Y3Tm trigonal pyramid,  a cornercorner with one O(10)Y4 trigonal pyramid,  a cornercorner with one O(2)Y4 trigonal pyramid,  a cornercorner with one O(5)Y4 trigonal pyramid,  a cornercorner with one O(6)Y4 trigonal pyramid,  a cornercorner with one O(7)Y4 trigonal pyramid, corners with two equivalent O(9)Y3Tm trigonal pyramids, corners with two equivalent O(11)Y4 trigonal pyramids, corners with two equivalent O(4)Y4 trigonal pyramids,  an edgeedge with one O(10)Y4 trigonal pyramid,  an edgeedge with one O(8)Y4 trigonal pyramid, and edges with two equivalent O(3)Y3Tm trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Y15TmO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.176
_cell_length_b   9.176
_cell_length_c   10.592
_cell_angle_alpha   54.718
_cell_angle_beta   54.718
_cell_angle_gamma   70.506
_symmetry_Int_Tables_number   1
_cell_volume   594.335
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.000  1.000  0.749  1.0
  Y  Y1  1  0.783  0.217  0.000  1.0
  Y  Y2  1  0.250  0.251  0.782  1.0
  Y  Y3  1  0.749  0.750  0.218  1.0
  Y  Y4  1  0.968  0.468  0.532  1.0
  Y  Y5  1  0.467  0.967  0.034  1.0
  Y  Y6  1  0.000  1.000  0.251  1.0
  Y  Y7  1  0.718  0.282  0.500  1.0
  Y  Y8  1  0.499  0.500  0.251  1.0
  Y  Y9  1  0.282  0.718  0.000  1.0
  Y  Y10  1  0.500  0.501  0.749  1.0
  Y  Y11  1  0.532  0.032  0.468  1.0
  Y  Y12  1  0.033  0.533  0.966  1.0
  Y  Y13  1  0.751  0.750  0.717  1.0
  Y  Y14  1  0.250  0.249  0.283  1.0
  Tm  Tm15  1  0.217  0.783  0.500  1.0
  O  O16  1  0.510  0.230  0.782  1.0
  O  O17  1  0.729  0.011  0.978  1.0
  O  O18  1  0.960  0.762  0.758  1.0
  O  O19  1  0.761  0.957  0.261  1.0
  O  O20  1  0.740  0.543  0.479  1.0
  O  O21  1  0.543  0.739  0.980  1.0
  O  O22  1  0.770  0.490  0.218  1.0
  O  O23  1  0.989  0.271  0.022  1.0
  O  O24  1  0.228  0.968  0.011  1.0
  O  O25  1  0.728  0.468  0.792  1.0
  O  O26  1  0.465  0.728  0.296  1.0
  O  O27  1  0.968  0.228  0.511  1.0
  O  O28  1  0.532  0.272  0.208  1.0
  O  O29  1  0.772  0.032  0.489  1.0
  O  O30  1  0.272  0.535  0.704  1.0
  O  O31  1  0.032  0.772  0.989  1.0
  O  O32  1  0.229  0.511  0.282  1.0
  O  O33  1  0.014  0.729  0.479  1.0
  O  O34  1  0.457  0.260  0.521  1.0
  O  O35  1  0.261  0.457  0.020  1.0
  O  O36  1  0.043  0.239  0.739  1.0
  O  O37  1  0.238  0.040  0.242  1.0
  O  O38  1  0.489  0.771  0.718  1.0
  O  O39  1  0.271  0.986  0.521  1.0
[/CIF]
.