The material described by MoN is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3mc space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent N(2) and four equivalent N(1) atoms to form a mixture of edge, corner, and face-sharing MoN6 octahedra. The corner-sharing octahedral tilt angles range from 42-48°. In the second Mo site, Mo(2) is bonded to six equivalent N(1) atoms to form a mixture of edge, corner, and face-sharing MoN6 octahedra. The corner-sharing octahedral tilt angles range from 42-48°. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Mo(2) and four equivalent Mo(1) atoms to form a mixture of distorted edge and corner-sharing NMo6 pentagonal pyramids. In the second N site, N(2) is bonded to six equivalent Mo(1) atoms to form a mixture of distorted edge and corner-sharing NMo6 pentagonal pyramids. is represented by the CIF card [CIF]
data_MoN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.872
_cell_length_b   2.872
_cell_length_c   5.644
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   40.300
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.000  0.000  0.509  1.0
  Mo  Mo1  1  1.000  1.000  0.009  1.0
  N  N2  1  0.333  0.667  0.259  1.0
  N  N3  1  0.667  0.333  0.759  1.0
[/CIF]
.
The material described by MoN is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3mc space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent N(2) and four equivalent N(1) atoms to form a mixture of edge, corner, and face-sharing MoN6 octahedra. The corner-sharing octahedral tilt angles range from 42-48°. In the second Mo site, Mo(2) is bonded to six equivalent N(1) atoms to form a mixture of edge, corner, and face-sharing MoN6 octahedra. The corner-sharing octahedral tilt angles range from 42-48°. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Mo(2) and four equivalent Mo(1) atoms to form a mixture of distorted edge and corner-sharing NMo6 pentagonal pyramids. In the second N site, N(2) is bonded to six equivalent Mo(1) atoms to form a mixture of distorted edge and corner-sharing NMo6 pentagonal pyramids. is represented by the CIF card [CIF]
data_MoN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.872
_cell_length_b   2.872
_cell_length_c   5.644
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   40.300
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.000  0.000  0.509  1.0
  Mo  Mo1  1  1.000  1.000  0.009  1.0
  N  N2  1  0.333  0.667  0.259  1.0
  N  N3  1  0.667  0.333  0.759  1.0
[/CIF]
.