The compound described by Cd(NO3)2(CN2S)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfanylcyanamide molecules and two Cd(NO3)2 clusters. In each Cd(NO3)2 cluster, Cd(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Cd(1) and one N(3) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Cd(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_CdC2S2(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.565
_cell_length_b   4.780
_cell_length_c   12.599
_cell_angle_alpha   80.145
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   745.558
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.000  0.000  1.0
  Cd  Cd1  1  0.500  0.000  0.500  1.0
  C  C2  1  0.882  0.503  0.302  1.0
  C  C3  1  0.118  0.497  0.698  1.0
  C  C4  1  0.382  0.497  0.198  1.0
  C  C5  1  0.618  0.503  0.802  1.0
  S  S6  1  0.584  0.361  0.279  1.0
  S  S7  1  0.416  0.639  0.721  1.0
  S  S8  1  0.084  0.639  0.221  1.0
  S  S9  1  0.916  0.361  0.779  1.0
  N  N10  1  0.971  0.611  0.273  1.0
  N  N11  1  0.029  0.389  0.727  1.0
  N  N12  1  0.471  0.389  0.227  1.0
  N  N13  1  0.529  0.611  0.773  1.0
  N  N14  1  0.797  0.413  0.332  1.0
  N  N15  1  0.203  0.587  0.668  1.0
  N  N16  1  0.297  0.587  0.168  1.0
  N  N17  1  0.703  0.413  0.832  1.0
  N  N18  1  0.788  0.949  0.034  1.0
  N  N19  1  0.212  0.051  0.966  1.0
  N  N20  1  0.288  0.051  0.466  1.0
  N  N21  1  0.712  0.949  0.534  1.0
  O  O22  1  0.664  0.811  0.468  1.0
  O  O23  1  0.336  0.189  0.532  1.0
  O  O24  1  0.164  0.189  0.032  1.0
  O  O25  1  0.836  0.811  0.968  1.0
  O  O26  1  0.350  0.898  0.414  1.0
  O  O27  1  0.650  0.102  0.586  1.0
  O  O28  1  0.850  0.102  0.086  1.0
  O  O29  1  0.150  0.898  0.914  1.0
  O  O30  1  0.692  0.938  0.049  1.0
  O  O31  1  0.308  0.062  0.951  1.0
  O  O32  1  0.192  0.062  0.451  1.0
  O  O33  1  0.808  0.938  0.549  1.0
[/CIF]
.
The compound described by Cd(NO3)2(CN2S)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfanylcyanamide molecules and two Cd(NO3)2 clusters. In each Cd(NO3)2 cluster, Cd(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Cd(1) and one N(3) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Cd(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_CdC2S2(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.565
_cell_length_b   4.780
_cell_length_c   12.599
_cell_angle_alpha   80.145
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   745.558
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.000  0.000  1.0
  Cd  Cd1  1  0.500  0.000  0.500  1.0
  C  C2  1  0.882  0.503  0.302  1.0
  C  C3  1  0.118  0.497  0.698  1.0
  C  C4  1  0.382  0.497  0.198  1.0
  C  C5  1  0.618  0.503  0.802  1.0
  S  S6  1  0.584  0.361  0.279  1.0
  S  S7  1  0.416  0.639  0.721  1.0
  S  S8  1  0.084  0.639  0.221  1.0
  S  S9  1  0.916  0.361  0.779  1.0
  N  N10  1  0.971  0.611  0.273  1.0
  N  N11  1  0.029  0.389  0.727  1.0
  N  N12  1  0.471  0.389  0.227  1.0
  N  N13  1  0.529  0.611  0.773  1.0
  N  N14  1  0.797  0.413  0.332  1.0
  N  N15  1  0.203  0.587  0.668  1.0
  N  N16  1  0.297  0.587  0.168  1.0
  N  N17  1  0.703  0.413  0.832  1.0
  N  N18  1  0.788  0.949  0.034  1.0
  N  N19  1  0.212  0.051  0.966  1.0
  N  N20  1  0.288  0.051  0.466  1.0
  N  N21  1  0.712  0.949  0.534  1.0
  O  O22  1  0.664  0.811  0.468  1.0
  O  O23  1  0.336  0.189  0.532  1.0
  O  O24  1  0.164  0.189  0.032  1.0
  O  O25  1  0.836  0.811  0.968  1.0
  O  O26  1  0.350  0.898  0.414  1.0
  O  O27  1  0.650  0.102  0.586  1.0
  O  O28  1  0.850  0.102  0.086  1.0
  O  O29  1  0.150  0.898  0.914  1.0
  O  O30  1  0.692  0.938  0.049  1.0
  O  O31  1  0.308  0.062  0.951  1.0
  O  O32  1  0.192  0.062  0.451  1.0
  O  O33  1  0.808  0.938  0.549  1.0
[/CIF]
.