The crystal structure described by Li(Fe2O3)4 is Spinel-like structured and crystallizes in the monoclinic Cc space group. Li(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(7), and one O(9) atom to form LiO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, and edges with two equivalent Fe(8)O6 octahedra. There are eight inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(10), one O(3), one O(4), and one O(9) atom to form FeO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, and corners with two equivalent Fe(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-61°. In the second Fe site, Fe(2) is bonded to one O(1), one O(12), one O(2), one O(3), one O(4), and one O(5) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra,  an edgeedge with one Fe(8)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. In the third Fe site, Fe(3) is bonded to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra,  an edgeedge with one Fe(8)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. In the fourth Fe site, Fe(4) is bonded to one O(1), one O(2), one O(7), and one O(8) atom to form FeO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, and corners with two equivalent Fe(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-60°. In the fifth Fe site, Fe(5) is bonded to one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(8)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. In the sixth Fe site, Fe(6) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(8)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. In the seventh Fe site, Fe(7) is bonded to one O(11), one O(12), one O(5), and one O(6) atom to form FeO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, and corners with two equivalent Fe(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-60°. In the eighth Fe site, Fe(8) is bonded to one O(10), one O(11), one O(12), one O(2), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(2), one Fe(3), and one Fe(4) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Fe(2), one Fe(3), one Fe(4), and one Fe(8) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Fe(1), one Fe(2), one Fe(3), and one Fe(6) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Fe(1), one Fe(2), one Fe(3), and one Fe(5) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Fe(2), one Fe(5), one Fe(6), and one Fe(7) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Fe(3), one Fe(5), one Fe(6), and one Fe(7) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(4), one Fe(5), and one Fe(6) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Fe(4), one Fe(5), one Fe(6), and one Fe(8) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(1), one Fe(5), and one Fe(8) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(1), one Fe(6), and one Fe(8) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(3), one Fe(7), and one Fe(8) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(2), one Fe(7), and one Fe(8) atom. is represented by the CIF file [CIF]
data_Li(Fe2O3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.037
_cell_length_b   6.037
_cell_length_c   13.408
_cell_angle_alpha   77.146
_cell_angle_beta   77.146
_cell_angle_gamma   89.870
_symmetry_Int_Tables_number   1
_cell_volume   463.889
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.958  0.459  0.583  1.0
  Li  Li1  1  0.459  0.958  0.083  1.0
  Fe  Fe2  1  0.001  0.257  0.002  1.0
  Fe  Fe3  1  0.292  0.799  0.919  1.0
  Fe  Fe4  1  0.786  0.797  0.921  1.0
  Fe  Fe5  1  0.583  0.331  0.833  1.0
  Fe  Fe6  1  0.117  0.625  0.748  1.0
  Fe  Fe7  1  0.117  0.128  0.748  1.0
  Fe  Fe8  1  0.661  0.918  0.665  1.0
  Fe  Fe9  1  0.459  0.461  0.582  1.0
  Fe  Fe10  1  0.257  0.001  0.502  1.0
  Fe  Fe11  1  0.797  0.786  0.421  1.0
  Fe  Fe12  1  0.799  0.292  0.419  1.0
  Fe  Fe13  1  0.331  0.583  0.333  1.0
  Fe  Fe14  1  0.128  0.117  0.248  1.0
  Fe  Fe15  1  0.625  0.117  0.248  1.0
  Fe  Fe16  1  0.918  0.661  0.165  1.0
  Fe  Fe17  1  0.461  0.459  0.082  1.0
  O  O18  1  0.535  0.030  0.914  1.0
  O  O19  1  0.528  0.548  0.921  1.0
  O  O20  1  0.055  0.040  0.911  1.0
  O  O21  1  0.051  0.561  0.909  1.0
  O  O22  1  0.352  0.871  0.757  1.0
  O  O23  1  0.891  0.876  0.749  1.0
  O  O24  1  0.893  0.374  0.751  1.0
  O  O25  1  0.360  0.378  0.744  1.0
  O  O26  1  0.215  0.696  0.589  1.0
  O  O27  1  0.216  0.215  0.591  1.0
  O  O28  1  0.695  0.697  0.584  1.0
  O  O29  1  0.701  0.221  0.578  1.0
  O  O30  1  0.030  0.535  0.414  1.0
  O  O31  1  0.548  0.528  0.421  1.0
  O  O32  1  0.561  0.051  0.409  1.0
  O  O33  1  0.040  0.055  0.411  1.0
  O  O34  1  0.871  0.352  0.257  1.0
  O  O35  1  0.876  0.891  0.249  1.0
  O  O36  1  0.378  0.360  0.244  1.0
  O  O37  1  0.374  0.893  0.251  1.0
  O  O38  1  0.696  0.215  0.089  1.0
  O  O39  1  0.215  0.216  0.091  1.0
  O  O40  1  0.221  0.701  0.078  1.0
  O  O41  1  0.697  0.695  0.084  1.0
[/CIF]
.
The crystal structure described by Li(Fe2O3)4 is Spinel-like structured and crystallizes in the monoclinic Cc space group. Li(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(7), and one O(9) atom to form LiO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, and edges with two equivalent Fe(8)O6 octahedra. There are eight inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(10), one O(3), one O(4), and one O(9) atom to form FeO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, and corners with two equivalent Fe(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-61°. In the second Fe site, Fe(2) is bonded to one O(1), one O(12), one O(2), one O(3), one O(4), and one O(5) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra,  an edgeedge with one Fe(8)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. In the third Fe site, Fe(3) is bonded to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra,  an edgeedge with one Fe(8)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. In the fourth Fe site, Fe(4) is bonded to one O(1), one O(2), one O(7), and one O(8) atom to form FeO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, and corners with two equivalent Fe(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-60°. In the fifth Fe site, Fe(5) is bonded to one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(8)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. In the sixth Fe site, Fe(6) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(8)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. In the seventh Fe site, Fe(7) is bonded to one O(11), one O(12), one O(5), and one O(6) atom to form FeO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, and corners with two equivalent Fe(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-60°. In the eighth Fe site, Fe(8) is bonded to one O(10), one O(11), one O(12), one O(2), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Fe(1)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(2), one Fe(3), and one Fe(4) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Fe(2), one Fe(3), one Fe(4), and one Fe(8) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Fe(1), one Fe(2), one Fe(3), and one Fe(6) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Fe(1), one Fe(2), one Fe(3), and one Fe(5) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Fe(2), one Fe(5), one Fe(6), and one Fe(7) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Fe(3), one Fe(5), one Fe(6), and one Fe(7) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(4), one Fe(5), and one Fe(6) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Fe(4), one Fe(5), one Fe(6), and one Fe(8) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(1), one Fe(5), and one Fe(8) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(1), one Fe(6), and one Fe(8) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(3), one Fe(7), and one Fe(8) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(2), one Fe(7), and one Fe(8) atom. is represented by the CIF file [CIF]
data_Li(Fe2O3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.037
_cell_length_b   6.037
_cell_length_c   13.408
_cell_angle_alpha   77.146
_cell_angle_beta   77.146
_cell_angle_gamma   89.870
_symmetry_Int_Tables_number   1
_cell_volume   463.889
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.958  0.459  0.583  1.0
  Li  Li1  1  0.459  0.958  0.083  1.0
  Fe  Fe2  1  0.001  0.257  0.002  1.0
  Fe  Fe3  1  0.292  0.799  0.919  1.0
  Fe  Fe4  1  0.786  0.797  0.921  1.0
  Fe  Fe5  1  0.583  0.331  0.833  1.0
  Fe  Fe6  1  0.117  0.625  0.748  1.0
  Fe  Fe7  1  0.117  0.128  0.748  1.0
  Fe  Fe8  1  0.661  0.918  0.665  1.0
  Fe  Fe9  1  0.459  0.461  0.582  1.0
  Fe  Fe10  1  0.257  0.001  0.502  1.0
  Fe  Fe11  1  0.797  0.786  0.421  1.0
  Fe  Fe12  1  0.799  0.292  0.419  1.0
  Fe  Fe13  1  0.331  0.583  0.333  1.0
  Fe  Fe14  1  0.128  0.117  0.248  1.0
  Fe  Fe15  1  0.625  0.117  0.248  1.0
  Fe  Fe16  1  0.918  0.661  0.165  1.0
  Fe  Fe17  1  0.461  0.459  0.082  1.0
  O  O18  1  0.535  0.030  0.914  1.0
  O  O19  1  0.528  0.548  0.921  1.0
  O  O20  1  0.055  0.040  0.911  1.0
  O  O21  1  0.051  0.561  0.909  1.0
  O  O22  1  0.352  0.871  0.757  1.0
  O  O23  1  0.891  0.876  0.749  1.0
  O  O24  1  0.893  0.374  0.751  1.0
  O  O25  1  0.360  0.378  0.744  1.0
  O  O26  1  0.215  0.696  0.589  1.0
  O  O27  1  0.216  0.215  0.591  1.0
  O  O28  1  0.695  0.697  0.584  1.0
  O  O29  1  0.701  0.221  0.578  1.0
  O  O30  1  0.030  0.535  0.414  1.0
  O  O31  1  0.548  0.528  0.421  1.0
  O  O32  1  0.561  0.051  0.409  1.0
  O  O33  1  0.040  0.055  0.411  1.0
  O  O34  1  0.871  0.352  0.257  1.0
  O  O35  1  0.876  0.891  0.249  1.0
  O  O36  1  0.378  0.360  0.244  1.0
  O  O37  1  0.374  0.893  0.251  1.0
  O  O38  1  0.696  0.215  0.089  1.0
  O  O39  1  0.215  0.216  0.091  1.0
  O  O40  1  0.221  0.701  0.078  1.0
  O  O41  1  0.697  0.695  0.084  1.0
[/CIF]
.