The material described by SnBiO4 is beta Vanadium nitride-derived structured and crystallizes in the tetragonal I-4m2 space group. Sn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SnO6 octahedra that share corners with four equivalent Sn(1)O6 octahedra and edges with four equivalent Bi(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 23°. Bi(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted BiO6 pentagonal pyramids that share corners with four equivalent Bi(1)O6 pentagonal pyramids and edges with four equivalent Sn(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Sn(1) and one Bi(1) atom. is represented by the CIF file [CIF]
data_SnBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.228
_cell_length_b   6.228
_cell_length_c   6.228
_cell_angle_alpha   140.596
_cell_angle_beta   140.596
_cell_angle_gamma   56.949
_symmetry_Int_Tables_number   1
_cell_volume   96.560
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.750  0.250  0.500  1.0
  Bi  Bi1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.942  0.442  0.500  1.0
  O  O3  1  0.210  0.210  0.000  1.0
  O  O4  1  0.790  0.790  0.000  1.0
  O  O5  1  0.558  0.058  0.500  1.0
[/CIF]
.
The material described by SnBiO4 is beta Vanadium nitride-derived structured and crystallizes in the tetragonal I-4m2 space group. Sn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SnO6 octahedra that share corners with four equivalent Sn(1)O6 octahedra and edges with four equivalent Bi(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 23°. Bi(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted BiO6 pentagonal pyramids that share corners with four equivalent Bi(1)O6 pentagonal pyramids and edges with four equivalent Sn(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Sn(1) and one Bi(1) atom. is represented by the CIF file [CIF]
data_SnBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.228
_cell_length_b   6.228
_cell_length_c   6.228
_cell_angle_alpha   140.596
_cell_angle_beta   140.596
_cell_angle_gamma   56.949
_symmetry_Int_Tables_number   1
_cell_volume   96.560
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.750  0.250  0.500  1.0
  Bi  Bi1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.942  0.442  0.500  1.0
  O  O3  1  0.210  0.210  0.000  1.0
  O  O4  1  0.790  0.790  0.000  1.0
  O  O5  1  0.558  0.058  0.500  1.0
[/CIF]
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