The structure described by Ga3Pb5F19 crystallizes in the tetragonal I4cm space group. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to two equivalent F(6) and four equivalent F(7) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedra are not tilted. In the second Ga site, Ga(2) is bonded in an octahedral geometry to one F(2), one F(3), two equivalent F(4), and two equivalent F(5) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(4), one F(5), and two equivalent F(7) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(3) atoms. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Pb(2) and two equivalent Pb(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Ga(2) and two equivalent Pb(1) atoms. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Ga(2) and two equivalent Pb(2) atoms. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Ga(2) and one Pb(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ga(2) and one Pb(1) atom. In the sixth F site, F(6) is bonded in a linear geometry to two equivalent Ga(1) atoms. In the seventh F site, F(7) is bonded in a single-bond geometry to one Ga(1) and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Ga3Pb5F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.013
_cell_length_b   11.013
_cell_length_c   11.013
_cell_angle_alpha   97.268
_cell_angle_beta   97.268
_cell_angle_gamma   138.330
_symmetry_Int_Tables_number   1
_cell_volume   829.877
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.670  0.670  0.000  1.0
  Ga  Ga1  1  0.812  0.633  0.500  1.0
  Ga  Ga2  1  0.170  0.170  0.000  1.0
  Ga  Ga3  1  0.133  0.312  0.500  1.0
  Ga  Ga4  1  0.312  0.812  0.179  1.0
  Ga  Ga5  1  0.633  0.133  0.821  1.0
  Pb  Pb6  1  0.297  0.595  0.845  1.0
  Pb  Pb7  1  0.751  0.453  0.155  1.0
  Pb  Pb8  1  0.797  0.953  0.702  1.0
  Pb  Pb9  1  0.631  0.131  0.500  1.0
  Pb  Pb10  1  0.595  0.751  0.298  1.0
  Pb  Pb11  1  0.953  0.251  0.155  1.0
  Pb  Pb12  1  0.095  0.797  0.845  1.0
  Pb  Pb13  1  0.251  0.095  0.298  1.0
  Pb  Pb14  1  0.131  0.631  0.500  1.0
  Pb  Pb15  1  0.453  0.297  0.702  1.0
  F  F16  1  0.633  0.901  0.500  1.0
  F  F17  1  0.293  0.297  0.500  1.0
  F  F18  1  0.310  0.810  0.353  1.0
  F  F19  1  0.457  0.957  0.647  1.0
  F  F20  1  0.569  0.428  0.355  1.0
  F  F21  1  0.071  0.829  0.628  1.0
  F  F22  1  0.957  0.310  0.500  1.0
  F  F23  1  0.201  0.443  0.372  1.0
  F  F24  1  0.915  0.915  0.000  1.0
  F  F25  1  0.777  0.716  0.174  1.0
  F  F26  1  0.714  0.573  0.645  1.0
  F  F27  1  0.401  0.133  0.500  1.0
  F  F28  1  0.943  0.701  0.372  1.0
  F  F29  1  0.214  0.569  0.142  1.0
  F  F30  1  0.542  0.602  0.826  1.0
  F  F31  1  0.573  0.928  0.858  1.0
  F  F32  1  0.102  0.042  0.826  1.0
  F  F33  1  0.069  0.714  0.142  1.0
  F  F34  1  0.443  0.071  0.242  1.0
  F  F35  1  0.602  0.777  0.060  1.0
  F  F36  1  0.297  0.797  0.004  1.0
  F  F37  1  0.797  0.793  0.500  1.0
  F  F38  1  0.716  0.542  0.940  1.0
  F  F39  1  0.329  0.571  0.628  1.0
  F  F40  1  0.073  0.214  0.645  1.0
  F  F41  1  0.415  0.415  0.000  1.0
  F  F42  1  0.810  0.457  0.500  1.0
  F  F43  1  0.793  0.293  0.996  1.0
  F  F44  1  0.901  0.401  0.268  1.0
  F  F45  1  0.428  0.073  0.858  1.0
  F  F46  1  0.277  0.102  0.060  1.0
  F  F47  1  0.216  0.277  0.174  1.0
  F  F48  1  0.042  0.216  0.940  1.0
  F  F49  1  0.829  0.201  0.758  1.0
  F  F50  1  0.133  0.633  0.732  1.0
  F  F51  1  0.701  0.329  0.758  1.0
  F  F52  1  0.928  0.069  0.355  1.0
  F  F53  1  0.571  0.943  0.242  1.0
[/CIF]
.
The structure described by Ga3Pb5F19 crystallizes in the tetragonal I4cm space group. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to two equivalent F(6) and four equivalent F(7) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedra are not tilted. In the second Ga site, Ga(2) is bonded in an octahedral geometry to one F(2), one F(3), two equivalent F(4), and two equivalent F(5) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(4), one F(5), and two equivalent F(7) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(3) atoms. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Pb(2) and two equivalent Pb(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Ga(2) and two equivalent Pb(1) atoms. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Ga(2) and two equivalent Pb(2) atoms. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Ga(2) and one Pb(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ga(2) and one Pb(1) atom. In the sixth F site, F(6) is bonded in a linear geometry to two equivalent Ga(1) atoms. In the seventh F site, F(7) is bonded in a single-bond geometry to one Ga(1) and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Ga3Pb5F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.013
_cell_length_b   11.013
_cell_length_c   11.013
_cell_angle_alpha   97.268
_cell_angle_beta   97.268
_cell_angle_gamma   138.330
_symmetry_Int_Tables_number   1
_cell_volume   829.877
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.670  0.670  0.000  1.0
  Ga  Ga1  1  0.812  0.633  0.500  1.0
  Ga  Ga2  1  0.170  0.170  0.000  1.0
  Ga  Ga3  1  0.133  0.312  0.500  1.0
  Ga  Ga4  1  0.312  0.812  0.179  1.0
  Ga  Ga5  1  0.633  0.133  0.821  1.0
  Pb  Pb6  1  0.297  0.595  0.845  1.0
  Pb  Pb7  1  0.751  0.453  0.155  1.0
  Pb  Pb8  1  0.797  0.953  0.702  1.0
  Pb  Pb9  1  0.631  0.131  0.500  1.0
  Pb  Pb10  1  0.595  0.751  0.298  1.0
  Pb  Pb11  1  0.953  0.251  0.155  1.0
  Pb  Pb12  1  0.095  0.797  0.845  1.0
  Pb  Pb13  1  0.251  0.095  0.298  1.0
  Pb  Pb14  1  0.131  0.631  0.500  1.0
  Pb  Pb15  1  0.453  0.297  0.702  1.0
  F  F16  1  0.633  0.901  0.500  1.0
  F  F17  1  0.293  0.297  0.500  1.0
  F  F18  1  0.310  0.810  0.353  1.0
  F  F19  1  0.457  0.957  0.647  1.0
  F  F20  1  0.569  0.428  0.355  1.0
  F  F21  1  0.071  0.829  0.628  1.0
  F  F22  1  0.957  0.310  0.500  1.0
  F  F23  1  0.201  0.443  0.372  1.0
  F  F24  1  0.915  0.915  0.000  1.0
  F  F25  1  0.777  0.716  0.174  1.0
  F  F26  1  0.714  0.573  0.645  1.0
  F  F27  1  0.401  0.133  0.500  1.0
  F  F28  1  0.943  0.701  0.372  1.0
  F  F29  1  0.214  0.569  0.142  1.0
  F  F30  1  0.542  0.602  0.826  1.0
  F  F31  1  0.573  0.928  0.858  1.0
  F  F32  1  0.102  0.042  0.826  1.0
  F  F33  1  0.069  0.714  0.142  1.0
  F  F34  1  0.443  0.071  0.242  1.0
  F  F35  1  0.602  0.777  0.060  1.0
  F  F36  1  0.297  0.797  0.004  1.0
  F  F37  1  0.797  0.793  0.500  1.0
  F  F38  1  0.716  0.542  0.940  1.0
  F  F39  1  0.329  0.571  0.628  1.0
  F  F40  1  0.073  0.214  0.645  1.0
  F  F41  1  0.415  0.415  0.000  1.0
  F  F42  1  0.810  0.457  0.500  1.0
  F  F43  1  0.793  0.293  0.996  1.0
  F  F44  1  0.901  0.401  0.268  1.0
  F  F45  1  0.428  0.073  0.858  1.0
  F  F46  1  0.277  0.102  0.060  1.0
  F  F47  1  0.216  0.277  0.174  1.0
  F  F48  1  0.042  0.216  0.940  1.0
  F  F49  1  0.829  0.201  0.758  1.0
  F  F50  1  0.133  0.633  0.732  1.0
  F  F51  1  0.701  0.329  0.758  1.0
  F  F52  1  0.928  0.069  0.355  1.0
  F  F53  1  0.571  0.943  0.242  1.0
[/CIF]
.