The material structure described by RhO2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Rh(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a trigonal planar geometry to three equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.090
_cell_length_b   4.487
_cell_length_c   4.487
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   62.220
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.000  0.307  0.307  1.0
  O  O3  1  0.500  0.193  0.807  1.0
  O  O4  1  0.500  0.807  0.193  1.0
  O  O5  1  0.000  0.693  0.693  1.0
[/CIF]
.
The material structure described by RhO2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Rh(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a trigonal planar geometry to three equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.090
_cell_length_b   4.487
_cell_length_c   4.487
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   62.220
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.000  0.307  0.307  1.0
  O  O3  1  0.500  0.193  0.807  1.0
  O  O4  1  0.500  0.807  0.193  1.0
  O  O5  1  0.000  0.693  0.693  1.0
[/CIF]
.