The compound described by (Nb2NBr10)2(N2)3 is Indium-derived structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of six ammonia atoms and two Nb2NBr10 clusters. In each Nb2NBr10 cluster, Nb(1) is bonded to one N(3), one Br(2), and four equivalent Br(1) atoms to form distorted corner-sharing NbBr5N octahedra. The corner-sharing octahedra are not tilted. N(3) is bonded in a linear geometry to two equivalent Nb(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Nb(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Nb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NbBr5N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.437
_cell_length_b   7.437
_cell_length_c   19.978
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1104.872
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.500  0.500  0.406  1.0
  Nb  Nb1  1  0.000  0.000  0.906  1.0
  Nb  Nb2  1  0.500  0.500  0.594  1.0
  Nb  Nb3  1  0.000  0.000  0.094  1.0
  Br  Br4  1  0.785  0.684  0.394  1.0
  Br  Br5  1  0.215  0.316  0.394  1.0
  Br  Br6  1  0.715  0.184  0.894  1.0
  Br  Br7  1  0.285  0.816  0.894  1.0
  Br  Br8  1  0.684  0.215  0.394  1.0
  Br  Br9  1  0.316  0.785  0.394  1.0
  Br  Br10  1  0.184  0.285  0.894  1.0
  Br  Br11  1  0.816  0.715  0.894  1.0
  Br  Br12  1  0.215  0.316  0.606  1.0
  Br  Br13  1  0.785  0.684  0.606  1.0
  Br  Br14  1  0.285  0.816  0.106  1.0
  Br  Br15  1  0.715  0.184  0.106  1.0
  Br  Br16  1  0.316  0.785  0.606  1.0
  Br  Br17  1  0.684  0.215  0.606  1.0
  Br  Br18  1  0.816  0.715  0.106  1.0
  Br  Br19  1  0.184  0.285  0.106  1.0
  Br  Br20  1  0.500  0.500  0.265  1.0
  Br  Br21  1  0.000  0.000  0.765  1.0
  Br  Br22  1  0.500  0.500  0.735  1.0
  Br  Br23  1  0.000  0.000  0.235  1.0
  N  N24  1  0.500  0.500  0.000  1.0
  N  N25  1  0.000  0.000  0.500  1.0
  N  N26  1  0.000  0.500  0.250  1.0
  N  N27  1  0.500  0.000  0.750  1.0
  N  N28  1  0.500  0.000  0.250  1.0
  N  N29  1  0.000  0.500  0.750  1.0
  N  N30  1  0.500  0.500  0.500  1.0
  N  N31  1  0.000  0.000  0.000  1.0
[/CIF]
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The compound described by (Nb2NBr10)2(N2)3 is Indium-derived structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of six ammonia atoms and two Nb2NBr10 clusters. In each Nb2NBr10 cluster, Nb(1) is bonded to one N(3), one Br(2), and four equivalent Br(1) atoms to form distorted corner-sharing NbBr5N octahedra. The corner-sharing octahedra are not tilted. N(3) is bonded in a linear geometry to two equivalent Nb(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Nb(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Nb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NbBr5N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.437
_cell_length_b   7.437
_cell_length_c   19.978
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1104.872
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.500  0.500  0.406  1.0
  Nb  Nb1  1  0.000  0.000  0.906  1.0
  Nb  Nb2  1  0.500  0.500  0.594  1.0
  Nb  Nb3  1  0.000  0.000  0.094  1.0
  Br  Br4  1  0.785  0.684  0.394  1.0
  Br  Br5  1  0.215  0.316  0.394  1.0
  Br  Br6  1  0.715  0.184  0.894  1.0
  Br  Br7  1  0.285  0.816  0.894  1.0
  Br  Br8  1  0.684  0.215  0.394  1.0
  Br  Br9  1  0.316  0.785  0.394  1.0
  Br  Br10  1  0.184  0.285  0.894  1.0
  Br  Br11  1  0.816  0.715  0.894  1.0
  Br  Br12  1  0.215  0.316  0.606  1.0
  Br  Br13  1  0.785  0.684  0.606  1.0
  Br  Br14  1  0.285  0.816  0.106  1.0
  Br  Br15  1  0.715  0.184  0.106  1.0
  Br  Br16  1  0.316  0.785  0.606  1.0
  Br  Br17  1  0.684  0.215  0.606  1.0
  Br  Br18  1  0.816  0.715  0.106  1.0
  Br  Br19  1  0.184  0.285  0.106  1.0
  Br  Br20  1  0.500  0.500  0.265  1.0
  Br  Br21  1  0.000  0.000  0.765  1.0
  Br  Br22  1  0.500  0.500  0.735  1.0
  Br  Br23  1  0.000  0.000  0.235  1.0
  N  N24  1  0.500  0.500  0.000  1.0
  N  N25  1  0.000  0.000  0.500  1.0
  N  N26  1  0.000  0.500  0.250  1.0
  N  N27  1  0.500  0.000  0.750  1.0
  N  N28  1  0.500  0.000  0.250  1.0
  N  N29  1  0.000  0.500  0.750  1.0
  N  N30  1  0.500  0.500  0.500  1.0
  N  N31  1  0.000  0.000  0.000  1.0
[/CIF]
.