The compound described by Hg4SbHO6 crystallizes in the triclinic P1 space group. There are four inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 2-coordinate geometry to one O(1) and one O(4) atom. In the second Hg site, Hg(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the third Hg site, Hg(3) is bonded to one H(1), one O(1), one O(2), one O(4), and one O(6) atom to form HgHO4 square pyramids that share corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. In the fourth Hg site, Hg(4) is bonded in a 3-coordinate geometry to one H(1), one O(3), and one O(5) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with four equivalent Hg(3)HO4 square pyramids. H(1) is bonded in a bent 120 degrees geometry to one Hg(3) and one Hg(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Hg(1), one Hg(3), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Hg(2), one Hg(3), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Hg(2), one Hg(4), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Hg(1), one Hg(3), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Hg(2), one Hg(4), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Hg(2), one Hg(3), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Hg4SbHO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.988
_cell_length_b   4.992
_cell_length_c   8.739
_cell_angle_alpha   104.730
_cell_angle_beta   105.566
_cell_angle_gamma   92.966
_symmetry_Int_Tables_number   1
_cell_volume   201.042
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.970  0.908  0.988  1.0
  Hg  Hg1  1  0.177  0.105  0.340  1.0
  Hg  Hg2  1  0.335  0.301  0.741  1.0
  Hg  Hg3  1  0.684  0.496  0.145  1.0
  Sb  Sb4  1  0.756  0.703  0.559  1.0
  H  H5  1  0.547  0.257  0.962  1.0
  O  O6  1  0.675  0.594  0.754  1.0
  O  O7  1  0.053  0.460  0.545  1.0
  O  O8  1  0.494  0.404  0.347  1.0
  O  O9  1  0.033  0.003  0.758  1.0
  O  O10  1  0.837  0.840  0.355  1.0
  O  O11  1  0.471  0.957  0.547  1.0
[/CIF]
.
The compound described by Hg4SbHO6 crystallizes in the triclinic P1 space group. There are four inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 2-coordinate geometry to one O(1) and one O(4) atom. In the second Hg site, Hg(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the third Hg site, Hg(3) is bonded to one H(1), one O(1), one O(2), one O(4), and one O(6) atom to form HgHO4 square pyramids that share corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. In the fourth Hg site, Hg(4) is bonded in a 3-coordinate geometry to one H(1), one O(3), and one O(5) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with four equivalent Hg(3)HO4 square pyramids. H(1) is bonded in a bent 120 degrees geometry to one Hg(3) and one Hg(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Hg(1), one Hg(3), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Hg(2), one Hg(3), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Hg(2), one Hg(4), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Hg(1), one Hg(3), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Hg(2), one Hg(4), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Hg(2), one Hg(3), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Hg4SbHO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.988
_cell_length_b   4.992
_cell_length_c   8.739
_cell_angle_alpha   104.730
_cell_angle_beta   105.566
_cell_angle_gamma   92.966
_symmetry_Int_Tables_number   1
_cell_volume   201.042
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.970  0.908  0.988  1.0
  Hg  Hg1  1  0.177  0.105  0.340  1.0
  Hg  Hg2  1  0.335  0.301  0.741  1.0
  Hg  Hg3  1  0.684  0.496  0.145  1.0
  Sb  Sb4  1  0.756  0.703  0.559  1.0
  H  H5  1  0.547  0.257  0.962  1.0
  O  O6  1  0.675  0.594  0.754  1.0
  O  O7  1  0.053  0.460  0.545  1.0
  O  O8  1  0.494  0.404  0.347  1.0
  O  O9  1  0.033  0.003  0.758  1.0
  O  O10  1  0.837  0.840  0.355  1.0
  O  O11  1  0.471  0.957  0.547  1.0
[/CIF]
.