The crystal structure described by Li3V(BO2)5 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), one O(7), and one O(9) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(4), one O(7), one O(8), and two equivalent O(2) atoms. V(1) is bonded to one O(1), one O(3), one O(4), one O(6), and two equivalent O(5) atoms to form distorted VO6 octahedra that share  an edgeedge with one V(1)O6 octahedra and  an edgeedge with one B(2)O4 tetrahedra. There are five inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(10), and one O(3) atom. In the second B site, B(2) is bonded to one O(2), one O(3), one O(6), and one O(8) atom to form BO4 tetrahedra that share  an edgeedge with one V(1)O6 octahedra. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(9) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(8) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Li(1), one Li(2), one V(1), and one B(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Li(3), one B(2), and one B(3) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one V(1), one B(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one V(1), and one B(3) atom. In the fifth O site, O(5) is bonded to one Li(1), two equivalent V(1), and one B(4) atom to form distorted OLiV2B tetrahedra that share corners with two equivalent O(6)LiVB2 tetrahedra and  an edgeedge with one O(5)LiV2B tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one V(1), one B(2), and one B(5) atom to form distorted corner-sharing OLiVB2 tetrahedra. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one Li(3), and one B(5) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one B(2), and one B(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Li(1), one B(3), and one B(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one B(1), and one B(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3V(BO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.961
_cell_length_b   7.197
_cell_length_c   9.401
_cell_angle_alpha   81.388
_cell_angle_beta   110.233
_cell_angle_gamma   118.042
_symmetry_Int_Tables_number   1
_cell_volume   389.930
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.229  0.496  0.757  1.0
  Li  Li1  1  0.811  0.995  0.840  1.0
  Li  Li2  1  0.023  0.815  0.538  1.0
  Li  Li3  1  0.977  0.185  0.462  1.0
  Li  Li4  1  0.189  0.005  0.160  1.0
  Li  Li5  1  0.771  0.504  0.243  1.0
  V  V6  1  0.224  0.494  0.124  1.0
  V  V7  1  0.776  0.506  0.876  1.0
  B  B8  1  0.300  0.191  0.926  1.0
  B  B9  1  0.407  0.138  0.707  1.0
  B  B10  1  0.365  0.248  0.433  1.0
  B  B11  1  0.223  0.835  0.868  1.0
  B  B12  1  0.743  0.282  0.601  1.0
  B  B13  1  0.257  0.718  0.399  1.0
  B  B14  1  0.777  0.165  0.132  1.0
  B  B15  1  0.635  0.752  0.567  1.0
  B  B16  1  0.593  0.862  0.293  1.0
  B  B17  1  0.700  0.809  0.074  1.0
  O  O18  1  0.250  0.295  0.001  1.0
  O  O19  1  0.272  0.155  0.551  1.0
  O  O20  1  0.403  0.276  0.812  1.0
  O  O21  1  0.223  0.259  0.297  1.0
  O  O22  1  0.142  0.629  0.900  1.0
  O  O23  1  0.654  0.216  0.725  1.0
  O  O24  1  0.050  0.698  0.381  1.0
  O  O25  1  0.697  0.086  0.255  1.0
  O  O26  1  0.600  0.316  0.461  1.0
  O  O27  1  0.766  0.024  0.038  1.0
  O  O28  1  0.234  0.976  0.962  1.0
  O  O29  1  0.400  0.684  0.539  1.0
  O  O30  1  0.303  0.914  0.745  1.0
  O  O31  1  0.950  0.302  0.619  1.0
  O  O32  1  0.346  0.784  0.275  1.0
  O  O33  1  0.858  0.371  0.100  1.0
  O  O34  1  0.777  0.741  0.703  1.0
  O  O35  1  0.597  0.724  0.188  1.0
  O  O36  1  0.728  0.845  0.449  1.0
  O  O37  1  0.750  0.705  0.999  1.0
[/CIF]
.
The crystal structure described by Li3V(BO2)5 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), one O(7), and one O(9) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(4), one O(7), one O(8), and two equivalent O(2) atoms. V(1) is bonded to one O(1), one O(3), one O(4), one O(6), and two equivalent O(5) atoms to form distorted VO6 octahedra that share  an edgeedge with one V(1)O6 octahedra and  an edgeedge with one B(2)O4 tetrahedra. There are five inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(10), and one O(3) atom. In the second B site, B(2) is bonded to one O(2), one O(3), one O(6), and one O(8) atom to form BO4 tetrahedra that share  an edgeedge with one V(1)O6 octahedra. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(9) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(8) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Li(1), one Li(2), one V(1), and one B(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Li(3), one B(2), and one B(3) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one V(1), one B(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one V(1), and one B(3) atom. In the fifth O site, O(5) is bonded to one Li(1), two equivalent V(1), and one B(4) atom to form distorted OLiV2B tetrahedra that share corners with two equivalent O(6)LiVB2 tetrahedra and  an edgeedge with one O(5)LiV2B tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one V(1), one B(2), and one B(5) atom to form distorted corner-sharing OLiVB2 tetrahedra. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one Li(3), and one B(5) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one B(2), and one B(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Li(1), one B(3), and one B(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one B(1), and one B(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3V(BO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.961
_cell_length_b   7.197
_cell_length_c   9.401
_cell_angle_alpha   81.388
_cell_angle_beta   110.233
_cell_angle_gamma   118.042
_symmetry_Int_Tables_number   1
_cell_volume   389.930
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.229  0.496  0.757  1.0
  Li  Li1  1  0.811  0.995  0.840  1.0
  Li  Li2  1  0.023  0.815  0.538  1.0
  Li  Li3  1  0.977  0.185  0.462  1.0
  Li  Li4  1  0.189  0.005  0.160  1.0
  Li  Li5  1  0.771  0.504  0.243  1.0
  V  V6  1  0.224  0.494  0.124  1.0
  V  V7  1  0.776  0.506  0.876  1.0
  B  B8  1  0.300  0.191  0.926  1.0
  B  B9  1  0.407  0.138  0.707  1.0
  B  B10  1  0.365  0.248  0.433  1.0
  B  B11  1  0.223  0.835  0.868  1.0
  B  B12  1  0.743  0.282  0.601  1.0
  B  B13  1  0.257  0.718  0.399  1.0
  B  B14  1  0.777  0.165  0.132  1.0
  B  B15  1  0.635  0.752  0.567  1.0
  B  B16  1  0.593  0.862  0.293  1.0
  B  B17  1  0.700  0.809  0.074  1.0
  O  O18  1  0.250  0.295  0.001  1.0
  O  O19  1  0.272  0.155  0.551  1.0
  O  O20  1  0.403  0.276  0.812  1.0
  O  O21  1  0.223  0.259  0.297  1.0
  O  O22  1  0.142  0.629  0.900  1.0
  O  O23  1  0.654  0.216  0.725  1.0
  O  O24  1  0.050  0.698  0.381  1.0
  O  O25  1  0.697  0.086  0.255  1.0
  O  O26  1  0.600  0.316  0.461  1.0
  O  O27  1  0.766  0.024  0.038  1.0
  O  O28  1  0.234  0.976  0.962  1.0
  O  O29  1  0.400  0.684  0.539  1.0
  O  O30  1  0.303  0.914  0.745  1.0
  O  O31  1  0.950  0.302  0.619  1.0
  O  O32  1  0.346  0.784  0.275  1.0
  O  O33  1  0.858  0.371  0.100  1.0
  O  O34  1  0.777  0.741  0.703  1.0
  O  O35  1  0.597  0.724  0.188  1.0
  O  O36  1  0.728  0.845  0.449  1.0
  O  O37  1  0.750  0.705  0.999  1.0
[/CIF]
.