The compound described by CoV2O6 crystallizes in the monoclinic C2 space group. V(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), and three equivalent O(1) atoms. Co(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form edge-sharing CoO6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and one Co(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2CoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.029
_cell_length_b   5.029
_cell_length_c   6.732
_cell_angle_alpha   70.138
_cell_angle_beta   70.138
_cell_angle_gamma   41.223
_symmetry_Int_Tables_number   1
_cell_volume   104.536
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.793  0.820  0.656  1.0
  V  V1  1  0.180  0.207  0.344  1.0
  Co  Co2  1  0.999  0.001  0.000  1.0
  O  O3  1  0.680  0.706  0.435  1.0
  O  O4  1  0.022  0.049  0.275  1.0
  O  O5  1  0.951  0.978  0.725  1.0
  O  O6  1  0.294  0.320  0.565  1.0
  O  O7  1  0.330  0.364  0.111  1.0
  O  O8  1  0.636  0.670  0.889  1.0
[/CIF]
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The compound described by CoV2O6 crystallizes in the monoclinic C2 space group. V(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), and three equivalent O(1) atoms. Co(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form edge-sharing CoO6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and one Co(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2CoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.029
_cell_length_b   5.029
_cell_length_c   6.732
_cell_angle_alpha   70.138
_cell_angle_beta   70.138
_cell_angle_gamma   41.223
_symmetry_Int_Tables_number   1
_cell_volume   104.536
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.793  0.820  0.656  1.0
  V  V1  1  0.180  0.207  0.344  1.0
  Co  Co2  1  0.999  0.001  0.000  1.0
  O  O3  1  0.680  0.706  0.435  1.0
  O  O4  1  0.022  0.049  0.275  1.0
  O  O5  1  0.951  0.978  0.725  1.0
  O  O6  1  0.294  0.320  0.565  1.0
  O  O7  1  0.330  0.364  0.111  1.0
  O  O8  1  0.636  0.670  0.889  1.0
[/CIF]
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