The structure described by Zn6B3HO11 crystallizes in the trigonal R3c space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. In the second Zn site, Zn(2) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. B(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. H(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one B(1) atom. In the second O site, O(4) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one B(1) atom. In the third O site, O(5) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one B(1) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Zn(1) and one H(1) atom. In the fifth O site, O(2) is bonded in a trigonal pyramidal geometry to three equivalent Zn(2) and one H(1) atom. is represented by the CIF file [CIF]
data_Zn6B3HO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.297
_cell_length_b   10.022
_cell_length_c   8.297
_cell_angle_alpha   65.547
_cell_angle_beta   120.000
_cell_angle_gamma   114.453
_symmetry_Int_Tables_number   1
_cell_volume   524.780
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.138  0.914  0.809  1.0
  Zn  Zn1  1  0.585  0.914  0.862  1.0
  Zn  Zn2  1  0.191  0.914  0.415  1.0
  Zn  Zn3  1  0.856  0.087  0.195  1.0
  Zn  Zn4  1  0.426  0.087  0.144  1.0
  Zn  Zn5  1  0.805  0.087  0.574  1.0
  Zn  Zn6  1  0.085  0.414  0.309  1.0
  Zn  Zn7  1  0.691  0.414  0.362  1.0
  Zn  Zn8  1  0.638  0.414  0.915  1.0
  Zn  Zn9  1  0.926  0.587  0.695  1.0
  Zn  Zn10  1  0.305  0.587  0.644  1.0
  Zn  Zn11  1  0.356  0.587  0.074  1.0
  B  B12  1  0.228  0.250  0.729  1.0
  B  B13  1  0.751  0.250  0.772  1.0
  B  B14  1  0.271  0.250  0.249  1.0
  B  B15  1  0.771  0.750  0.272  1.0
  B  B16  1  0.251  0.750  0.229  1.0
  B  B17  1  0.728  0.750  0.749  1.0
  H  H18  1  0.259  0.776  0.741  1.0
  H  H19  1  0.759  0.276  0.241  1.0
  O  O20  1  0.299  0.898  0.701  1.0
  O  O21  1  0.705  0.115  0.295  1.0
  O  O22  1  0.799  0.398  0.201  1.0
  O  O23  1  0.205  0.615  0.795  1.0
  O  O24  1  0.895  0.750  0.750  1.0
  O  O25  1  0.605  0.750  0.105  1.0
  O  O26  1  0.250  0.750  0.395  1.0
  O  O27  1  0.105  0.250  0.250  1.0
  O  O28  1  0.395  0.250  0.895  1.0
  O  O29  1  0.750  0.250  0.605  1.0
  O  O30  1  0.089  0.115  0.699  1.0
  O  O31  1  0.725  0.115  0.911  1.0
  O  O32  1  0.301  0.115  0.275  1.0
  O  O33  1  0.909  0.886  0.300  1.0
  O  O34  1  0.277  0.886  0.091  1.0
  O  O35  1  0.700  0.886  0.723  1.0
  O  O36  1  0.225  0.615  0.199  1.0
  O  O37  1  0.801  0.615  0.411  1.0
  O  O38  1  0.589  0.615  0.775  1.0
  O  O39  1  0.777  0.386  0.800  1.0
  O  O40  1  0.200  0.386  0.591  1.0
  O  O41  1  0.409  0.386  0.223  1.0
[/CIF]
.
The structure described by Zn6B3HO11 crystallizes in the trigonal R3c space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. In the second Zn site, Zn(2) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. B(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. H(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one B(1) atom. In the second O site, O(4) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one B(1) atom. In the third O site, O(5) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one B(1) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Zn(1) and one H(1) atom. In the fifth O site, O(2) is bonded in a trigonal pyramidal geometry to three equivalent Zn(2) and one H(1) atom. is represented by the CIF file [CIF]
data_Zn6B3HO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.297
_cell_length_b   10.022
_cell_length_c   8.297
_cell_angle_alpha   65.547
_cell_angle_beta   120.000
_cell_angle_gamma   114.453
_symmetry_Int_Tables_number   1
_cell_volume   524.780
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.138  0.914  0.809  1.0
  Zn  Zn1  1  0.585  0.914  0.862  1.0
  Zn  Zn2  1  0.191  0.914  0.415  1.0
  Zn  Zn3  1  0.856  0.087  0.195  1.0
  Zn  Zn4  1  0.426  0.087  0.144  1.0
  Zn  Zn5  1  0.805  0.087  0.574  1.0
  Zn  Zn6  1  0.085  0.414  0.309  1.0
  Zn  Zn7  1  0.691  0.414  0.362  1.0
  Zn  Zn8  1  0.638  0.414  0.915  1.0
  Zn  Zn9  1  0.926  0.587  0.695  1.0
  Zn  Zn10  1  0.305  0.587  0.644  1.0
  Zn  Zn11  1  0.356  0.587  0.074  1.0
  B  B12  1  0.228  0.250  0.729  1.0
  B  B13  1  0.751  0.250  0.772  1.0
  B  B14  1  0.271  0.250  0.249  1.0
  B  B15  1  0.771  0.750  0.272  1.0
  B  B16  1  0.251  0.750  0.229  1.0
  B  B17  1  0.728  0.750  0.749  1.0
  H  H18  1  0.259  0.776  0.741  1.0
  H  H19  1  0.759  0.276  0.241  1.0
  O  O20  1  0.299  0.898  0.701  1.0
  O  O21  1  0.705  0.115  0.295  1.0
  O  O22  1  0.799  0.398  0.201  1.0
  O  O23  1  0.205  0.615  0.795  1.0
  O  O24  1  0.895  0.750  0.750  1.0
  O  O25  1  0.605  0.750  0.105  1.0
  O  O26  1  0.250  0.750  0.395  1.0
  O  O27  1  0.105  0.250  0.250  1.0
  O  O28  1  0.395  0.250  0.895  1.0
  O  O29  1  0.750  0.250  0.605  1.0
  O  O30  1  0.089  0.115  0.699  1.0
  O  O31  1  0.725  0.115  0.911  1.0
  O  O32  1  0.301  0.115  0.275  1.0
  O  O33  1  0.909  0.886  0.300  1.0
  O  O34  1  0.277  0.886  0.091  1.0
  O  O35  1  0.700  0.886  0.723  1.0
  O  O36  1  0.225  0.615  0.199  1.0
  O  O37  1  0.801  0.615  0.411  1.0
  O  O38  1  0.589  0.615  0.775  1.0
  O  O39  1  0.777  0.386  0.800  1.0
  O  O40  1  0.200  0.386  0.591  1.0
  O  O41  1  0.409  0.386  0.223  1.0
[/CIF]
.