The compound described by Sr3RhF12 crystallizes in the monoclinic C2/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to two equivalent F(1) and six equivalent F(2) atoms. Rh(1) is bonded in a distorted body-centered cubic geometry to four equivalent F(1) and four equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Sr(1), one Sr(2), and one Rh(1) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to three equivalent Sr(2) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the CIF file [CIF]
data_Sr3RhF12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.266
_cell_length_b   8.121
_cell_length_c   8.281
_cell_angle_alpha   119.367
_cell_angle_beta   113.583
_cell_angle_gamma   35.333
_symmetry_Int_Tables_number   1
_cell_volume   246.285
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.000  0.000  1.0
  Sr  Sr1  1  0.000  0.500  0.500  1.0
  Sr  Sr2  1  0.000  0.000  0.500  1.0
  Rh  Rh3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.038  0.137  0.839  1.0
  F  F5  1  0.962  0.863  0.161  1.0
  F  F6  1  0.686  0.944  0.406  1.0
  F  F7  1  0.962  0.702  0.839  1.0
  F  F8  1  0.314  0.056  0.594  1.0
  F  F9  1  0.038  0.298  0.161  1.0
  F  F10  1  0.338  0.659  0.823  1.0
  F  F11  1  0.314  0.462  0.406  1.0
  F  F12  1  0.662  0.341  0.177  1.0
  F  F13  1  0.686  0.538  0.594  1.0
  F  F14  1  0.662  0.164  0.823  1.0
  F  F15  1  0.338  0.836  0.177  1.0
[/CIF]
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The compound described by Sr3RhF12 crystallizes in the monoclinic C2/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to two equivalent F(1) and six equivalent F(2) atoms. Rh(1) is bonded in a distorted body-centered cubic geometry to four equivalent F(1) and four equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Sr(1), one Sr(2), and one Rh(1) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to three equivalent Sr(2) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the CIF file [CIF]
data_Sr3RhF12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.266
_cell_length_b   8.121
_cell_length_c   8.281
_cell_angle_alpha   119.367
_cell_angle_beta   113.583
_cell_angle_gamma   35.333
_symmetry_Int_Tables_number   1
_cell_volume   246.285
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.000  0.000  1.0
  Sr  Sr1  1  0.000  0.500  0.500  1.0
  Sr  Sr2  1  0.000  0.000  0.500  1.0
  Rh  Rh3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.038  0.137  0.839  1.0
  F  F5  1  0.962  0.863  0.161  1.0
  F  F6  1  0.686  0.944  0.406  1.0
  F  F7  1  0.962  0.702  0.839  1.0
  F  F8  1  0.314  0.056  0.594  1.0
  F  F9  1  0.038  0.298  0.161  1.0
  F  F10  1  0.338  0.659  0.823  1.0
  F  F11  1  0.314  0.462  0.406  1.0
  F  F12  1  0.662  0.341  0.177  1.0
  F  F13  1  0.686  0.538  0.594  1.0
  F  F14  1  0.662  0.164  0.823  1.0
  F  F15  1  0.338  0.836  0.177  1.0
[/CIF]
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