The material structure described by Co2P is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. In the second Co site, Co(2) is bonded to four equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing CoP4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to four equivalent Co(2) and five equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_Co2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.447
_cell_length_b   5.735
_cell_length_c   6.436
_cell_angle_alpha   90.001
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   127.227
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.750  0.037  0.332  1.0
  Co  Co1  1  0.250  0.963  0.668  1.0
  Co  Co2  1  0.750  0.537  0.168  1.0
  Co  Co3  1  0.250  0.463  0.832  1.0
  Co  Co4  1  0.250  0.359  0.435  1.0
  Co  Co5  1  0.750  0.641  0.565  1.0
  Co  Co6  1  0.250  0.859  0.065  1.0
  Co  Co7  1  0.750  0.141  0.935  1.0
  P  P8  1  0.250  0.740  0.378  1.0
  P  P9  1  0.750  0.260  0.622  1.0
  P  P10  1  0.250  0.240  0.122  1.0
  P  P11  1  0.750  0.760  0.878  1.0
[/CIF]
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The material structure described by Co2P is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. In the second Co site, Co(2) is bonded to four equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing CoP4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to four equivalent Co(2) and five equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_Co2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.447
_cell_length_b   5.735
_cell_length_c   6.436
_cell_angle_alpha   90.001
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   127.227
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.750  0.037  0.332  1.0
  Co  Co1  1  0.250  0.963  0.668  1.0
  Co  Co2  1  0.750  0.537  0.168  1.0
  Co  Co3  1  0.250  0.463  0.832  1.0
  Co  Co4  1  0.250  0.359  0.435  1.0
  Co  Co5  1  0.750  0.641  0.565  1.0
  Co  Co6  1  0.250  0.859  0.065  1.0
  Co  Co7  1  0.750  0.141  0.935  1.0
  P  P8  1  0.250  0.740  0.378  1.0
  P  P9  1  0.750  0.260  0.622  1.0
  P  P10  1  0.250  0.240  0.122  1.0
  P  P11  1  0.750  0.760  0.878  1.0
[/CIF]
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