The structure described by Ag2TeS3 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one S(2), one S(3), and two equivalent S(1) atoms. In the second Ag site, Ag(2) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form corner-sharing AgS4 tetrahedra. Te(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(2), two equivalent Ag(1), and one Te(1) atom to form corner-sharing SAg3Te tetrahedra. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the third S site, S(3) is bonded in a rectangular see-saw-like geometry to one Ag(1), two equivalent Ag(2), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag2TeS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.708
_cell_length_b   6.708
_cell_length_c   7.994
_cell_angle_alpha   102.832
_cell_angle_beta   102.832
_cell_angle_gamma   118.804
_symmetry_Int_Tables_number   1
_cell_volume   283.647
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.507  0.070  0.872  1.0
  Ag  Ag1  1  0.834  0.737  0.918  1.0
  Ag  Ag2  1  0.070  0.507  0.372  1.0
  Ag  Ag3  1  0.737  0.834  0.418  1.0
  Te  Te4  1  0.194  0.404  0.902  1.0
  Te  Te5  1  0.404  0.194  0.402  1.0
  S  S6  1  0.937  0.195  0.054  1.0
  S  S7  1  0.195  0.937  0.554  1.0
  S  S8  1  0.787  0.243  0.517  1.0
  S  S9  1  0.243  0.787  0.017  1.0
  S  S10  1  0.506  0.584  0.596  1.0
  S  S11  1  0.584  0.506  0.096  1.0
[/CIF]
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The structure described by Ag2TeS3 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one S(2), one S(3), and two equivalent S(1) atoms. In the second Ag site, Ag(2) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form corner-sharing AgS4 tetrahedra. Te(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(2), two equivalent Ag(1), and one Te(1) atom to form corner-sharing SAg3Te tetrahedra. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the third S site, S(3) is bonded in a rectangular see-saw-like geometry to one Ag(1), two equivalent Ag(2), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag2TeS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.708
_cell_length_b   6.708
_cell_length_c   7.994
_cell_angle_alpha   102.832
_cell_angle_beta   102.832
_cell_angle_gamma   118.804
_symmetry_Int_Tables_number   1
_cell_volume   283.647
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.507  0.070  0.872  1.0
  Ag  Ag1  1  0.834  0.737  0.918  1.0
  Ag  Ag2  1  0.070  0.507  0.372  1.0
  Ag  Ag3  1  0.737  0.834  0.418  1.0
  Te  Te4  1  0.194  0.404  0.902  1.0
  Te  Te5  1  0.404  0.194  0.402  1.0
  S  S6  1  0.937  0.195  0.054  1.0
  S  S7  1  0.195  0.937  0.554  1.0
  S  S8  1  0.787  0.243  0.517  1.0
  S  S9  1  0.243  0.787  0.017  1.0
  S  S10  1  0.506  0.584  0.596  1.0
  S  S11  1  0.584  0.506  0.096  1.0
[/CIF]
.