The structure described by BaSrEuVO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. Sr(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Eu sites. In the first Eu site, Eu(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form EuO6 octahedra that share corners with two equivalent V(2)O6 octahedra and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-21°. In the second Eu site, Eu(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form EuO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Eu(2)O6 octahedra and corners with four equivalent Eu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-22°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Eu(1)O6 octahedra and corners with four equivalent Eu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Sr(1), one Eu(1), and one V(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Eu(2), and one V(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Eu(1), and one V(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Sr(1), one Eu(2), and one V(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Ba(1), one Sr(1), one Eu(2), and one V(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ba(1), one Sr(1), one Eu(1), and one V(2) atom. is represented by the CIF card [CIF]
data_BaSrEuVO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.894
_cell_length_b   5.908
_cell_length_c   8.328
_cell_angle_alpha   90.436
_cell_angle_beta   90.411
_cell_angle_gamma   90.355
_symmetry_Int_Tables_number   1
_cell_volume   289.978
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.506  0.525  0.249  1.0
  Ba  Ba1  1  0.494  0.475  0.751  1.0
  Sr  Sr2  1  0.994  0.032  0.251  1.0
  Sr  Sr3  1  0.006  0.968  0.749  1.0
  Eu  Eu4  1  0.000  0.500  0.000  1.0
  Eu  Eu5  1  0.500  0.000  0.500  1.0
  V  V6  1  0.500  0.000  0.000  1.0
  V  V7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.242  0.193  0.966  1.0
  O  O9  1  0.251  0.700  0.530  1.0
  O  O10  1  0.758  0.807  0.034  1.0
  O  O11  1  0.749  0.300  0.470  1.0
  O  O12  1  0.302  0.748  0.967  1.0
  O  O13  1  0.191  0.237  0.533  1.0
  O  O14  1  0.698  0.252  0.033  1.0
  O  O15  1  0.809  0.763  0.467  1.0
  O  O16  1  0.432  0.994  0.226  1.0
  O  O17  1  0.055  0.484  0.274  1.0
  O  O18  1  0.568  0.006  0.774  1.0
  O  O19  1  0.945  0.516  0.726  1.0
[/CIF]
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The structure described by BaSrEuVO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. Sr(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Eu sites. In the first Eu site, Eu(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form EuO6 octahedra that share corners with two equivalent V(2)O6 octahedra and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-21°. In the second Eu site, Eu(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form EuO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Eu(2)O6 octahedra and corners with four equivalent Eu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-22°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Eu(1)O6 octahedra and corners with four equivalent Eu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Sr(1), one Eu(1), and one V(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Eu(2), and one V(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Eu(1), and one V(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Sr(1), one Eu(2), and one V(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Ba(1), one Sr(1), one Eu(2), and one V(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ba(1), one Sr(1), one Eu(1), and one V(2) atom. is represented by the CIF card [CIF]
data_BaSrEuVO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.894
_cell_length_b   5.908
_cell_length_c   8.328
_cell_angle_alpha   90.436
_cell_angle_beta   90.411
_cell_angle_gamma   90.355
_symmetry_Int_Tables_number   1
_cell_volume   289.978
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.506  0.525  0.249  1.0
  Ba  Ba1  1  0.494  0.475  0.751  1.0
  Sr  Sr2  1  0.994  0.032  0.251  1.0
  Sr  Sr3  1  0.006  0.968  0.749  1.0
  Eu  Eu4  1  0.000  0.500  0.000  1.0
  Eu  Eu5  1  0.500  0.000  0.500  1.0
  V  V6  1  0.500  0.000  0.000  1.0
  V  V7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.242  0.193  0.966  1.0
  O  O9  1  0.251  0.700  0.530  1.0
  O  O10  1  0.758  0.807  0.034  1.0
  O  O11  1  0.749  0.300  0.470  1.0
  O  O12  1  0.302  0.748  0.967  1.0
  O  O13  1  0.191  0.237  0.533  1.0
  O  O14  1  0.698  0.252  0.033  1.0
  O  O15  1  0.809  0.763  0.467  1.0
  O  O16  1  0.432  0.994  0.226  1.0
  O  O17  1  0.055  0.484  0.274  1.0
  O  O18  1  0.568  0.006  0.774  1.0
  O  O19  1  0.945  0.516  0.726  1.0
[/CIF]
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