The structure described by WP2 crystallizes in the monoclinic C2/m space group. W(1) is bonded in a 8-coordinate geometry to three equivalent P(1) and five equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent W(1) and three equivalent P(1) atoms. In the second P site, P(2) is bonded in a 5-coordinate geometry to five equivalent W(1) atoms. is represented by the CIF file [CIF]
data_P2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.191
_cell_length_b   4.530
_cell_length_c   6.740
_cell_angle_alpha   80.601
_cell_angle_beta   76.296
_cell_angle_gamma   69.361
_symmetry_Int_Tables_number   1
_cell_volume   88.218
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.138  0.749  0.975  1.0
  P  P1  1  0.862  0.251  0.025  1.0
  P  P2  1  0.400  0.799  0.400  1.0
  P  P3  1  0.600  0.201  0.600  1.0
  W  W4  1  0.842  0.609  0.707  1.0
  W  W5  1  0.158  0.391  0.293  1.0
[/CIF]
.
The structure described by WP2 crystallizes in the monoclinic C2/m space group. W(1) is bonded in a 8-coordinate geometry to three equivalent P(1) and five equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent W(1) and three equivalent P(1) atoms. In the second P site, P(2) is bonded in a 5-coordinate geometry to five equivalent W(1) atoms. is represented by the CIF file [CIF]
data_P2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.191
_cell_length_b   4.530
_cell_length_c   6.740
_cell_angle_alpha   80.601
_cell_angle_beta   76.296
_cell_angle_gamma   69.361
_symmetry_Int_Tables_number   1
_cell_volume   88.218
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.138  0.749  0.975  1.0
  P  P1  1  0.862  0.251  0.025  1.0
  P  P2  1  0.400  0.799  0.400  1.0
  P  P3  1  0.600  0.201  0.600  1.0
  W  W4  1  0.842  0.609  0.707  1.0
  W  W5  1  0.158  0.391  0.293  1.0
[/CIF]
.