The material structure described by KUO3Cl crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 4-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent Cl(1) atoms. U(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), three equivalent O(1), and two equivalent Cl(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent U(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one U(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent K(1) and one U(1) atom. Cl(1) is bonded to three equivalent K(1) and two equivalent U(1) atoms to form distorted edge-sharing ClK3U2 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_KUClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.117
_cell_length_b   7.258
_cell_length_c   8.958
_cell_angle_alpha   75.206
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   258.790
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.859  0.755  1.0
  K  K1  1  0.750  0.141  0.245  1.0
  U  U2  1  0.250  0.613  0.327  1.0
  U  U3  1  0.750  0.387  0.673  1.0
  Cl  Cl4  1  0.250  0.230  0.910  1.0
  Cl  Cl5  1  0.750  0.770  0.090  1.0
  O  O6  1  0.250  0.452  0.583  1.0
  O  O7  1  0.750  0.548  0.417  1.0
  O  O8  1  0.250  0.848  0.372  1.0
  O  O9  1  0.750  0.152  0.628  1.0
  O  O10  1  0.250  0.389  0.264  1.0
  O  O11  1  0.750  0.611  0.736  1.0
[/CIF]
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The material structure described by KUO3Cl crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 4-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent Cl(1) atoms. U(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), three equivalent O(1), and two equivalent Cl(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent U(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one U(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent K(1) and one U(1) atom. Cl(1) is bonded to three equivalent K(1) and two equivalent U(1) atoms to form distorted edge-sharing ClK3U2 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_KUClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.117
_cell_length_b   7.258
_cell_length_c   8.958
_cell_angle_alpha   75.206
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   258.790
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.859  0.755  1.0
  K  K1  1  0.750  0.141  0.245  1.0
  U  U2  1  0.250  0.613  0.327  1.0
  U  U3  1  0.750  0.387  0.673  1.0
  Cl  Cl4  1  0.250  0.230  0.910  1.0
  Cl  Cl5  1  0.750  0.770  0.090  1.0
  O  O6  1  0.250  0.452  0.583  1.0
  O  O7  1  0.750  0.548  0.417  1.0
  O  O8  1  0.250  0.848  0.372  1.0
  O  O9  1  0.750  0.152  0.628  1.0
  O  O10  1  0.250  0.389  0.264  1.0
  O  O11  1  0.750  0.611  0.736  1.0
[/CIF]
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