The compound described by V(SbO3)4 crystallizes in the triclinic P1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(28), one O(29), one O(36), and one O(44) atom to form distorted VO6 octahedra that share  a cornercorner with one Sb(12)O6 octahedra,  a cornercorner with one Sb(13)O6 octahedra,  a cornercorner with one Sb(16)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(5)O6 octahedra,  an edgeedge with one Sb(6)O6 octahedra, and  a faceface with one Sb(12)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. In the second V site, V(2) is bonded to one O(15), one O(25), one O(3), one O(30), one O(33), and one O(41) atom to form distorted VO6 octahedra that share  a cornercorner with one Sb(13)O6 octahedra,  a cornercorner with one Sb(14)O6 octahedra,  a cornercorner with one Sb(9)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra,  an edgeedge with one Sb(6)O6 octahedra,  an edgeedge with one Sb(7)O6 octahedra, and  a faceface with one Sb(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-62°. In the third V site, V(3) is bonded to one O(1), one O(13), one O(27), one O(32), one O(35), and one O(43) atom to form distorted VO6 octahedra that share  a cornercorner with one Sb(11)O6 octahedra,  a cornercorner with one Sb(15)O6 octahedra,  a cornercorner with one Sb(16)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(5)O6 octahedra,  an edgeedge with one Sb(8)O6 octahedra, and  a faceface with one Sb(11)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. In the fourth V site, V(4) is bonded to one O(16), one O(26), one O(31), one O(34), one O(4), and one O(42) atom to form distorted VO6 octahedra that share  a cornercorner with one Sb(10)O6 octahedra,  a cornercorner with one Sb(14)O6 octahedra,  a cornercorner with one Sb(15)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(7)O6 octahedra,  an edgeedge with one Sb(8)O6 octahedra, and  a faceface with one Sb(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. There are sixteen inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(11), one O(18), one O(31), one O(38), one O(42), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Sb(10)O6 octahedra,  a cornercorner with one Sb(9)O6 octahedra, corners with two equivalent Sb(14)O6 octahedra, corners with two equivalent Sb(15)O6 octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-48°. In the second Sb site, Sb(2) is bonded to one O(12), one O(19), one O(32), one O(39), one O(43), and one O(8) atom to form SbO6 octahedra that share  a cornercorner with one Sb(10)O6 octahedra,  a cornercorner with one Sb(11)O6 octahedra, corners with two equivalent Sb(15)O6 octahedra, corners with two equivalent Sb(16)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-47°. In the third Sb site, Sb(3) is bonded to one O(20), one O(29), one O(40), one O(44), one O(5), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Sb(11)O6 octahedra,  a cornercorner with one Sb(12)O6 octahedra, corners with two equivalent Sb(13)O6 octahedra, corners with two equivalent Sb(16)O6 octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-47°. In the fourth Sb site, Sb(4) is bonded to one O(10), one O(17), one O(30), one O(37), one O(41), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one Sb(12)O6 octahedra,  a cornercorner with one Sb(9)O6 octahedra, corners with two equivalent Sb(13)O6 octahedra, corners with two equivalent Sb(14)O6 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-47°. In the fifth Sb site, Sb(5) is bonded to one O(1), one O(13), one O(21), one O(28), one O(36), and one O(48) atom to form SbO6 octahedra that share  a cornercorner with one Sb(13)O6 octahedra,  a cornercorner with one Sb(16)O6 octahedra, corners with two equivalent Sb(11)O6 octahedra, corners with two equivalent Sb(12)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. In the sixth Sb site, Sb(6) is bonded to one O(14), one O(2), one O(22), one O(25), one O(33), and one O(45) atom to form SbO6 octahedra that share  a cornercorner with one Sb(13)O6 octahedra,  a cornercorner with one Sb(14)O6 octahedra, corners with two equivalent Sb(12)O6 octahedra, corners with two equivalent Sb(9)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-54°. In the seventh Sb site, Sb(7) is bonded to one O(15), one O(23), one O(26), one O(3), one O(34), and one O(46) atom to form distorted SbO6 octahedra that share  a cornercorner with one Sb(14)O6 octahedra,  a cornercorner with one Sb(15)O6 octahedra, corners with two equivalent Sb(10)O6 octahedra, corners with two equivalent Sb(9)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-54°. In the eighth Sb site, Sb(8) is bonded to one O(16), one O(24), one O(27), one O(35), one O(4), and one O(47) atom to form SbO6 octahedra that share  a cornercorner with one Sb(15)O6 octahedra,  a cornercorner with one Sb(16)O6 octahedra, corners with two equivalent Sb(10)O6 octahedra, corners with two equivalent Sb(11)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. In the ninth Sb site, Sb(9) is bonded to one O(15), one O(3), one O(33), one O(41), one O(45), and one O(7) atom to form distorted SbO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(6)O6 octahedra, corners with two equivalent Sb(7)O6 octahedra, and  a faceface with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-56°. In the tenth Sb site, Sb(10) is bonded to one O(16), one O(34), one O(4), one O(42), one O(46), and one O(8) atom to form distorted SbO6 octahedra that share  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(7)O6 octahedra, corners with two equivalent Sb(8)O6 octahedra, and  a faceface with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-56°. In the eleventh Sb site, Sb(11) is bonded to one O(1), one O(13), one O(35), one O(43), one O(47), and one O(5) atom to form distorted SbO6 octahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Sb(5)O6 octahedra, corners with two equivalent Sb(8)O6 octahedra, and  a faceface with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-56°. In the twelfth Sb site, Sb(12) is bonded to one O(14), one O(2), one O(36), one O(44), one O(48), and one O(6) atom to form distorted SbO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(5)O6 octahedra, corners with two equivalent Sb(6)O6 octahedra, and  a faceface with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-56°. In the thirteenth Sb site, Sb(13) is bonded to one O(17), one O(21), one O(25), one O(29), one O(37), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Sb(5)O6 octahedra,  a cornercorner with one Sb(6)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-62°. In the fourteenth Sb site, Sb(14) is bonded to one O(10), one O(18), one O(22), one O(26), one O(30), and one O(38) atom to form SbO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Sb(6)O6 octahedra,  a cornercorner with one Sb(7)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-63°. In the fifteenth Sb site, Sb(15) is bonded to one O(11), one O(19), one O(23), one O(27), one O(31), and one O(39) atom to form SbO6 octahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Sb(7)O6 octahedra,  a cornercorner with one Sb(8)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-63°. In the sixteenth Sb site, Sb(16) is bonded to one O(12), one O(20), one O(24), one O(28), one O(32), and one O(40) atom to form SbO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sb(5)O6 octahedra,  a cornercorner with one Sb(8)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and corners with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-63°. There are forty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3), one Sb(11), and one Sb(5) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(1), one Sb(12), and one Sb(6) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(2), one Sb(7), and one Sb(9) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(4), one Sb(10), and one Sb(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(11) and one Sb(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Sb(12) and one Sb(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(9) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Sb(10) and one Sb(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Sb(13) and one Sb(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Sb(14) and one Sb(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(15) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Sb(16) and one Sb(2) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one V(3), one Sb(11), and one Sb(5) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one V(1), one Sb(12), and one Sb(6) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one V(2), one Sb(7), and one Sb(9) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one V(4), one Sb(10), and one Sb(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Sb(13) and one Sb(4) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(14) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Sb(15) and one Sb(2) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Sb(16) and one Sb(3) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Sb(13) and one Sb(5) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Sb(14) and one Sb(6) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Sb(15) and one Sb(7) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Sb(16) and one Sb(8) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one V(2), one Sb(13), and one Sb(6) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal planar geometry to one V(4), one Sb(14), and one Sb(7) atom. In the twenty-seventh O site, O(27) is bonded in a distorted trigonal planar geometry to one V(3), one Sb(15), and one Sb(8) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one V(1), one Sb(16), and one Sb(5) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one V(1), one Sb(13), and one Sb(3) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one V(2), one Sb(14), and one Sb(4) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal planar geometry to one V(4), one Sb(1), and one Sb(15) atom. In the thirty-second O site, O(32) is bonded in a distorted trigonal planar geometry to one V(3), one Sb(16), and one Sb(2) atom. In the thirty-third O site, O(33) is bonded in a T-shaped geometry to one V(2), one Sb(6), and one Sb(9) atom. In the thirty-fourth O site, O(34) is bonded in a T-shaped geometry to one V(4), one Sb(10), and one Sb(7) atom. In the thirty-fifth O site, O(35) is bonded in a T-shaped geometry to one V(3), one Sb(11), and one Sb(8) atom. In the thirty-sixth O site, O(36) is bonded in a T-shaped geometry to one V(1), one Sb(12), and one Sb(5) atom. In the thirty-seventh O site, O(37) is bonded in a bent 150 degrees geometry to one Sb(13) and one Sb(4) atom. In the thirty-eighth O site, O(38) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(14) atom. In the thirty-ninth O site, O(39) is bonded in a bent 150 degrees geometry to one Sb(15) and one Sb(2) atom. In the fortieth O site, O(40) is bonded in a bent 150 degrees geometry to one Sb(16) and one Sb(3) atom. In the forty-first O site, O(41) is bonded in a T-shaped geometry to one V(2), one Sb(4), and one Sb(9) atom. In the forty-second O site, O(42) is bonded in a T-shaped geometry to one V(4), one Sb(1), and one Sb(10) atom. In the forty-third O site, O(43) is bonded in a T-shaped geometry to one V(3), one Sb(11), and one Sb(2) atom. In the forty-fourth O site, O(44) is bonded in a T-shaped geometry to one V(1), one Sb(12), and one Sb(3) atom. In the forty-fifth O site, O(45) is bonded in a bent 150 degrees geometry to one Sb(6) and one Sb(9) atom. In the forty-sixth O site, O(46) is bonded in a bent 150 degrees geometry to one Sb(10) and one Sb(7) atom. In the forty-seventh O site, O(47) is bonded in a bent 150 degrees geometry to one Sb(11) and one Sb(8) atom. In the forty-eighth O site, O(48) is bonded in a bent 150 degrees geometry to one Sb(12) and one Sb(5) atom. is represented by the CIF card [CIF]
data_V(SbO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.092
_cell_length_b   5.500
_cell_length_c   7.657
_cell_angle_alpha   94.700
_cell_angle_beta   90.278
_cell_angle_gamma   91.026
_symmetry_Int_Tables_number   1
_cell_volume   213.673
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.275  0.752  0.587  1.0
  O  O1  1  0.149  0.983  0.270  1.0
  O  O2  1  0.319  0.162  0.943  1.0
  O  O3  1  0.177  0.298  0.597  1.0
  O  O4  1  0.828  0.301  0.080  1.0
  O  O5  1  0.351  0.488  0.258  1.0
  O  O6  1  0.661  0.463  0.751  1.0
  O  O7  1  0.186  0.655  0.936  1.0
  O  O8  1  0.826  0.648  0.476  1.0
  O  O9  1  0.690  0.787  0.072  1.0
  O  O10  1  0.899  0.933  0.760  1.0
  O  O11  1  0.655  0.141  0.447  1.0
  Sb  Sb12  1  0.005  0.993  0.030  1.0
  Sb  Sb13  1  0.491  0.461  0.488  1.0
  Sb  Sb14  1  0.988  0.991  0.498  1.0
  Sb  Sb15  1  0.508  0.467  0.024  1.0
  V  V16  1  0.992  0.597  0.722  1.0
[/CIF]
.
The compound described by V(SbO3)4 crystallizes in the triclinic P1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(28), one O(29), one O(36), and one O(44) atom to form distorted VO6 octahedra that share  a cornercorner with one Sb(12)O6 octahedra,  a cornercorner with one Sb(13)O6 octahedra,  a cornercorner with one Sb(16)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(5)O6 octahedra,  an edgeedge with one Sb(6)O6 octahedra, and  a faceface with one Sb(12)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. In the second V site, V(2) is bonded to one O(15), one O(25), one O(3), one O(30), one O(33), and one O(41) atom to form distorted VO6 octahedra that share  a cornercorner with one Sb(13)O6 octahedra,  a cornercorner with one Sb(14)O6 octahedra,  a cornercorner with one Sb(9)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra,  an edgeedge with one Sb(6)O6 octahedra,  an edgeedge with one Sb(7)O6 octahedra, and  a faceface with one Sb(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-62°. In the third V site, V(3) is bonded to one O(1), one O(13), one O(27), one O(32), one O(35), and one O(43) atom to form distorted VO6 octahedra that share  a cornercorner with one Sb(11)O6 octahedra,  a cornercorner with one Sb(15)O6 octahedra,  a cornercorner with one Sb(16)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(5)O6 octahedra,  an edgeedge with one Sb(8)O6 octahedra, and  a faceface with one Sb(11)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. In the fourth V site, V(4) is bonded to one O(16), one O(26), one O(31), one O(34), one O(4), and one O(42) atom to form distorted VO6 octahedra that share  a cornercorner with one Sb(10)O6 octahedra,  a cornercorner with one Sb(14)O6 octahedra,  a cornercorner with one Sb(15)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(7)O6 octahedra,  an edgeedge with one Sb(8)O6 octahedra, and  a faceface with one Sb(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. There are sixteen inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(11), one O(18), one O(31), one O(38), one O(42), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Sb(10)O6 octahedra,  a cornercorner with one Sb(9)O6 octahedra, corners with two equivalent Sb(14)O6 octahedra, corners with two equivalent Sb(15)O6 octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-48°. In the second Sb site, Sb(2) is bonded to one O(12), one O(19), one O(32), one O(39), one O(43), and one O(8) atom to form SbO6 octahedra that share  a cornercorner with one Sb(10)O6 octahedra,  a cornercorner with one Sb(11)O6 octahedra, corners with two equivalent Sb(15)O6 octahedra, corners with two equivalent Sb(16)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-47°. In the third Sb site, Sb(3) is bonded to one O(20), one O(29), one O(40), one O(44), one O(5), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Sb(11)O6 octahedra,  a cornercorner with one Sb(12)O6 octahedra, corners with two equivalent Sb(13)O6 octahedra, corners with two equivalent Sb(16)O6 octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-47°. In the fourth Sb site, Sb(4) is bonded to one O(10), one O(17), one O(30), one O(37), one O(41), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one Sb(12)O6 octahedra,  a cornercorner with one Sb(9)O6 octahedra, corners with two equivalent Sb(13)O6 octahedra, corners with two equivalent Sb(14)O6 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-47°. In the fifth Sb site, Sb(5) is bonded to one O(1), one O(13), one O(21), one O(28), one O(36), and one O(48) atom to form SbO6 octahedra that share  a cornercorner with one Sb(13)O6 octahedra,  a cornercorner with one Sb(16)O6 octahedra, corners with two equivalent Sb(11)O6 octahedra, corners with two equivalent Sb(12)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. In the sixth Sb site, Sb(6) is bonded to one O(14), one O(2), one O(22), one O(25), one O(33), and one O(45) atom to form SbO6 octahedra that share  a cornercorner with one Sb(13)O6 octahedra,  a cornercorner with one Sb(14)O6 octahedra, corners with two equivalent Sb(12)O6 octahedra, corners with two equivalent Sb(9)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-54°. In the seventh Sb site, Sb(7) is bonded to one O(15), one O(23), one O(26), one O(3), one O(34), and one O(46) atom to form distorted SbO6 octahedra that share  a cornercorner with one Sb(14)O6 octahedra,  a cornercorner with one Sb(15)O6 octahedra, corners with two equivalent Sb(10)O6 octahedra, corners with two equivalent Sb(9)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-54°. In the eighth Sb site, Sb(8) is bonded to one O(16), one O(24), one O(27), one O(35), one O(4), and one O(47) atom to form SbO6 octahedra that share  a cornercorner with one Sb(15)O6 octahedra,  a cornercorner with one Sb(16)O6 octahedra, corners with two equivalent Sb(10)O6 octahedra, corners with two equivalent Sb(11)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. In the ninth Sb site, Sb(9) is bonded to one O(15), one O(3), one O(33), one O(41), one O(45), and one O(7) atom to form distorted SbO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(6)O6 octahedra, corners with two equivalent Sb(7)O6 octahedra, and  a faceface with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-56°. In the tenth Sb site, Sb(10) is bonded to one O(16), one O(34), one O(4), one O(42), one O(46), and one O(8) atom to form distorted SbO6 octahedra that share  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(7)O6 octahedra, corners with two equivalent Sb(8)O6 octahedra, and  a faceface with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-56°. In the eleventh Sb site, Sb(11) is bonded to one O(1), one O(13), one O(35), one O(43), one O(47), and one O(5) atom to form distorted SbO6 octahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Sb(5)O6 octahedra, corners with two equivalent Sb(8)O6 octahedra, and  a faceface with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-56°. In the twelfth Sb site, Sb(12) is bonded to one O(14), one O(2), one O(36), one O(44), one O(48), and one O(6) atom to form distorted SbO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(5)O6 octahedra, corners with two equivalent Sb(6)O6 octahedra, and  a faceface with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-56°. In the thirteenth Sb site, Sb(13) is bonded to one O(17), one O(21), one O(25), one O(29), one O(37), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Sb(5)O6 octahedra,  a cornercorner with one Sb(6)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-62°. In the fourteenth Sb site, Sb(14) is bonded to one O(10), one O(18), one O(22), one O(26), one O(30), and one O(38) atom to form SbO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Sb(6)O6 octahedra,  a cornercorner with one Sb(7)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-63°. In the fifteenth Sb site, Sb(15) is bonded to one O(11), one O(19), one O(23), one O(27), one O(31), and one O(39) atom to form SbO6 octahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Sb(7)O6 octahedra,  a cornercorner with one Sb(8)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-63°. In the sixteenth Sb site, Sb(16) is bonded to one O(12), one O(20), one O(24), one O(28), one O(32), and one O(40) atom to form SbO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sb(5)O6 octahedra,  a cornercorner with one Sb(8)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and corners with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-63°. There are forty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3), one Sb(11), and one Sb(5) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(1), one Sb(12), and one Sb(6) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(2), one Sb(7), and one Sb(9) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(4), one Sb(10), and one Sb(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(11) and one Sb(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Sb(12) and one Sb(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(9) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Sb(10) and one Sb(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Sb(13) and one Sb(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Sb(14) and one Sb(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(15) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Sb(16) and one Sb(2) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one V(3), one Sb(11), and one Sb(5) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one V(1), one Sb(12), and one Sb(6) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one V(2), one Sb(7), and one Sb(9) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one V(4), one Sb(10), and one Sb(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Sb(13) and one Sb(4) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(14) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Sb(15) and one Sb(2) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Sb(16) and one Sb(3) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Sb(13) and one Sb(5) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Sb(14) and one Sb(6) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Sb(15) and one Sb(7) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Sb(16) and one Sb(8) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one V(2), one Sb(13), and one Sb(6) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal planar geometry to one V(4), one Sb(14), and one Sb(7) atom. In the twenty-seventh O site, O(27) is bonded in a distorted trigonal planar geometry to one V(3), one Sb(15), and one Sb(8) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one V(1), one Sb(16), and one Sb(5) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one V(1), one Sb(13), and one Sb(3) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one V(2), one Sb(14), and one Sb(4) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal planar geometry to one V(4), one Sb(1), and one Sb(15) atom. In the thirty-second O site, O(32) is bonded in a distorted trigonal planar geometry to one V(3), one Sb(16), and one Sb(2) atom. In the thirty-third O site, O(33) is bonded in a T-shaped geometry to one V(2), one Sb(6), and one Sb(9) atom. In the thirty-fourth O site, O(34) is bonded in a T-shaped geometry to one V(4), one Sb(10), and one Sb(7) atom. In the thirty-fifth O site, O(35) is bonded in a T-shaped geometry to one V(3), one Sb(11), and one Sb(8) atom. In the thirty-sixth O site, O(36) is bonded in a T-shaped geometry to one V(1), one Sb(12), and one Sb(5) atom. In the thirty-seventh O site, O(37) is bonded in a bent 150 degrees geometry to one Sb(13) and one Sb(4) atom. In the thirty-eighth O site, O(38) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(14) atom. In the thirty-ninth O site, O(39) is bonded in a bent 150 degrees geometry to one Sb(15) and one Sb(2) atom. In the fortieth O site, O(40) is bonded in a bent 150 degrees geometry to one Sb(16) and one Sb(3) atom. In the forty-first O site, O(41) is bonded in a T-shaped geometry to one V(2), one Sb(4), and one Sb(9) atom. In the forty-second O site, O(42) is bonded in a T-shaped geometry to one V(4), one Sb(1), and one Sb(10) atom. In the forty-third O site, O(43) is bonded in a T-shaped geometry to one V(3), one Sb(11), and one Sb(2) atom. In the forty-fourth O site, O(44) is bonded in a T-shaped geometry to one V(1), one Sb(12), and one Sb(3) atom. In the forty-fifth O site, O(45) is bonded in a bent 150 degrees geometry to one Sb(6) and one Sb(9) atom. In the forty-sixth O site, O(46) is bonded in a bent 150 degrees geometry to one Sb(10) and one Sb(7) atom. In the forty-seventh O site, O(47) is bonded in a bent 150 degrees geometry to one Sb(11) and one Sb(8) atom. In the forty-eighth O site, O(48) is bonded in a bent 150 degrees geometry to one Sb(12) and one Sb(5) atom. is represented by the CIF card [CIF]
data_V(SbO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.092
_cell_length_b   5.500
_cell_length_c   7.657
_cell_angle_alpha   94.700
_cell_angle_beta   90.278
_cell_angle_gamma   91.026
_symmetry_Int_Tables_number   1
_cell_volume   213.673
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.275  0.752  0.587  1.0
  O  O1  1  0.149  0.983  0.270  1.0
  O  O2  1  0.319  0.162  0.943  1.0
  O  O3  1  0.177  0.298  0.597  1.0
  O  O4  1  0.828  0.301  0.080  1.0
  O  O5  1  0.351  0.488  0.258  1.0
  O  O6  1  0.661  0.463  0.751  1.0
  O  O7  1  0.186  0.655  0.936  1.0
  O  O8  1  0.826  0.648  0.476  1.0
  O  O9  1  0.690  0.787  0.072  1.0
  O  O10  1  0.899  0.933  0.760  1.0
  O  O11  1  0.655  0.141  0.447  1.0
  Sb  Sb12  1  0.005  0.993  0.030  1.0
  Sb  Sb13  1  0.491  0.461  0.488  1.0
  Sb  Sb14  1  0.988  0.991  0.498  1.0
  Sb  Sb15  1  0.508  0.467  0.024  1.0
  V  V16  1  0.992  0.597  0.722  1.0
[/CIF]
.