The material structure described by Rb3Na(RuO4)2 crystallizes in the trigonal P-3m1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(2) and nine equivalent O(1) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Na(1) is bonded to six equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Ru(1)O4 tetrahedra. Ru(1) is bonded to one O(2) and three equivalent O(1) atoms to form RuO4 tetrahedra that share corners with three equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 16°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(2), three equivalent Rb(1), one Na(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Rb(1) and one Ru(1) atom. is represented by the CIF card [CIF]
data_Rb3Na(RuO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.208
_cell_length_b   6.208
_cell_length_c   8.065
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   269.121
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.667  0.333  0.341  1.0
  Rb  Rb1  1  0.000  0.000  0.000  1.0
  Rb  Rb2  1  0.333  0.667  0.659  1.0
  Na  Na3  1  0.000  0.000  0.500  1.0
  Ru  Ru4  1  0.667  0.333  0.779  1.0
  Ru  Ru5  1  0.333  0.667  0.221  1.0
  O  O6  1  0.178  0.356  0.308  1.0
  O  O7  1  0.644  0.822  0.308  1.0
  O  O8  1  0.178  0.822  0.308  1.0
  O  O9  1  0.822  0.644  0.692  1.0
  O  O10  1  0.822  0.178  0.692  1.0
  O  O11  1  0.356  0.178  0.692  1.0
  O  O12  1  0.667  0.333  0.998  1.0
  O  O13  1  0.333  0.667  0.002  1.0
[/CIF]
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The material structure described by Rb3Na(RuO4)2 crystallizes in the trigonal P-3m1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(2) and nine equivalent O(1) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Na(1) is bonded to six equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Ru(1)O4 tetrahedra. Ru(1) is bonded to one O(2) and three equivalent O(1) atoms to form RuO4 tetrahedra that share corners with three equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 16°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(2), three equivalent Rb(1), one Na(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Rb(1) and one Ru(1) atom. is represented by the CIF card [CIF]
data_Rb3Na(RuO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.208
_cell_length_b   6.208
_cell_length_c   8.065
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   269.121
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.667  0.333  0.341  1.0
  Rb  Rb1  1  0.000  0.000  0.000  1.0
  Rb  Rb2  1  0.333  0.667  0.659  1.0
  Na  Na3  1  0.000  0.000  0.500  1.0
  Ru  Ru4  1  0.667  0.333  0.779  1.0
  Ru  Ru5  1  0.333  0.667  0.221  1.0
  O  O6  1  0.178  0.356  0.308  1.0
  O  O7  1  0.644  0.822  0.308  1.0
  O  O8  1  0.178  0.822  0.308  1.0
  O  O9  1  0.822  0.644  0.692  1.0
  O  O10  1  0.822  0.178  0.692  1.0
  O  O11  1  0.356  0.178  0.692  1.0
  O  O12  1  0.667  0.333  0.998  1.0
  O  O13  1  0.333  0.667  0.002  1.0
[/CIF]
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