The structure described by (Mo4NH2O13)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one Mo4NH2O13 cluster. In the Mo4NH2O13 cluster, there are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(7), and one O(9) atom. In the second Mo site, Mo(2) is bonded to one O(2), one O(5), one O(7), one O(8), and two equivalent O(10) atoms to form distorted edge-sharing MoO6 octahedra. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(2), one O(5), and one O(6) atom. N(1) is bonded in a single-bond geometry to one O(6) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(12) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(8) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one Mo(3), and one Mo(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(3) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Mo(2), one Mo(3), and one Mo(4) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mo(4) and one N(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mo(2) and one H(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Mo(1), one Mo(3), one Mo(4), and two equivalent Mo(2) atoms. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Mo(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mo(1) and one H(1) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo4H2N2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.195
_cell_length_b   9.794
_cell_length_c   9.844
_cell_angle_alpha   65.564
_cell_angle_beta   71.152
_cell_angle_gamma   78.028
_symmetry_Int_Tables_number   1
_cell_volume   678.227
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.774  0.718  0.393  1.0
  Mo  Mo1  1  0.226  0.282  0.607  1.0
  Mo  Mo2  1  0.844  0.912  0.993  1.0
  Mo  Mo3  1  0.156  0.088  0.007  1.0
  Mo  Mo4  1  0.184  0.707  0.155  1.0
  Mo  Mo5  1  0.816  0.293  0.845  1.0
  Mo  Mo6  1  0.251  0.888  0.780  1.0
  Mo  Mo7  1  0.749  0.112  0.220  1.0
  H  H8  1  0.057  0.401  0.403  1.0
  H  H9  1  0.943  0.599  0.597  1.0
  H  H10  1  0.747  0.811  0.836  1.0
  H  H11  1  0.253  0.189  0.164  1.0
  N  N12  1  0.180  0.892  0.469  1.0
  N  N13  1  0.820  0.108  0.531  1.0
  N  N14  1  0.636  0.532  0.168  1.0
  N  N15  1  0.364  0.468  0.832  1.0
  O  O16  1  0.381  0.404  0.504  1.0
  O  O17  1  0.619  0.596  0.496  1.0
  O  O18  1  0.051  0.777  0.935  1.0
  O  O19  1  0.949  0.223  0.065  1.0
  O  O20  1  0.279  0.712  0.285  1.0
  O  O21  1  0.721  0.288  0.715  1.0
  O  O22  1  0.297  0.563  0.098  1.0
  O  O23  1  0.703  0.437  0.902  1.0
  O  O24  1  0.296  0.892  0.969  1.0
  O  O25  1  0.704  0.108  0.031  1.0
  O  O26  1  0.115  0.894  0.594  1.0
  O  O27  1  0.885  0.106  0.406  1.0
  O  O28  1  0.722  0.787  0.176  1.0
  O  O29  1  0.278  0.213  0.824  1.0
  O  O30  1  0.730  0.905  0.852  1.0
  O  O31  1  0.270  0.095  0.148  1.0
  O  O32  1  0.972  0.611  0.295  1.0
  O  O33  1  0.028  0.389  0.705  1.0
  O  O34  1  0.013  0.076  0.851  1.0
  O  O35  1  0.987  0.924  0.149  1.0
  O  O36  1  0.422  0.773  0.725  1.0
  O  O37  1  0.578  0.227  0.275  1.0
  O  O38  1  0.109  0.302  0.459  1.0
  O  O39  1  0.891  0.698  0.541  1.0
  O  O40  1  0.675  0.912  0.378  1.0
  O  O41  1  0.325  0.088  0.622  1.0
[/CIF]
.
The structure described by (Mo4NH2O13)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one Mo4NH2O13 cluster. In the Mo4NH2O13 cluster, there are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(7), and one O(9) atom. In the second Mo site, Mo(2) is bonded to one O(2), one O(5), one O(7), one O(8), and two equivalent O(10) atoms to form distorted edge-sharing MoO6 octahedra. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(2), one O(5), and one O(6) atom. N(1) is bonded in a single-bond geometry to one O(6) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(12) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(8) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one Mo(3), and one Mo(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(3) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Mo(2), one Mo(3), and one Mo(4) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mo(4) and one N(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mo(2) and one H(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Mo(1), one Mo(3), one Mo(4), and two equivalent Mo(2) atoms. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Mo(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mo(1) and one H(1) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo4H2N2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.195
_cell_length_b   9.794
_cell_length_c   9.844
_cell_angle_alpha   65.564
_cell_angle_beta   71.152
_cell_angle_gamma   78.028
_symmetry_Int_Tables_number   1
_cell_volume   678.227
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.774  0.718  0.393  1.0
  Mo  Mo1  1  0.226  0.282  0.607  1.0
  Mo  Mo2  1  0.844  0.912  0.993  1.0
  Mo  Mo3  1  0.156  0.088  0.007  1.0
  Mo  Mo4  1  0.184  0.707  0.155  1.0
  Mo  Mo5  1  0.816  0.293  0.845  1.0
  Mo  Mo6  1  0.251  0.888  0.780  1.0
  Mo  Mo7  1  0.749  0.112  0.220  1.0
  H  H8  1  0.057  0.401  0.403  1.0
  H  H9  1  0.943  0.599  0.597  1.0
  H  H10  1  0.747  0.811  0.836  1.0
  H  H11  1  0.253  0.189  0.164  1.0
  N  N12  1  0.180  0.892  0.469  1.0
  N  N13  1  0.820  0.108  0.531  1.0
  N  N14  1  0.636  0.532  0.168  1.0
  N  N15  1  0.364  0.468  0.832  1.0
  O  O16  1  0.381  0.404  0.504  1.0
  O  O17  1  0.619  0.596  0.496  1.0
  O  O18  1  0.051  0.777  0.935  1.0
  O  O19  1  0.949  0.223  0.065  1.0
  O  O20  1  0.279  0.712  0.285  1.0
  O  O21  1  0.721  0.288  0.715  1.0
  O  O22  1  0.297  0.563  0.098  1.0
  O  O23  1  0.703  0.437  0.902  1.0
  O  O24  1  0.296  0.892  0.969  1.0
  O  O25  1  0.704  0.108  0.031  1.0
  O  O26  1  0.115  0.894  0.594  1.0
  O  O27  1  0.885  0.106  0.406  1.0
  O  O28  1  0.722  0.787  0.176  1.0
  O  O29  1  0.278  0.213  0.824  1.0
  O  O30  1  0.730  0.905  0.852  1.0
  O  O31  1  0.270  0.095  0.148  1.0
  O  O32  1  0.972  0.611  0.295  1.0
  O  O33  1  0.028  0.389  0.705  1.0
  O  O34  1  0.013  0.076  0.851  1.0
  O  O35  1  0.987  0.924  0.149  1.0
  O  O36  1  0.422  0.773  0.725  1.0
  O  O37  1  0.578  0.227  0.275  1.0
  O  O38  1  0.109  0.302  0.459  1.0
  O  O39  1  0.891  0.698  0.541  1.0
  O  O40  1  0.675  0.912  0.378  1.0
  O  O41  1  0.325  0.088  0.622  1.0
[/CIF]
.