The material described by CdC2O4 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing CdO6 octahedra. The corner-sharing octahedral tilt angles are 56°. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(1) atom. is represented by the CIF file [CIF]
data_Cd(CO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.412
_cell_length_b   5.906
_cell_length_c   6.579
_cell_angle_alpha   57.149
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   176.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.000  0.000  1.0
  Cd  Cd1  1  0.500  0.000  0.500  1.0
  C  C2  1  0.882  0.456  0.082  1.0
  C  C3  1  0.118  0.544  0.918  1.0
  C  C4  1  0.618  0.456  0.582  1.0
  C  C5  1  0.382  0.544  0.418  1.0
  O  O6  1  0.279  0.374  0.386  1.0
  O  O7  1  0.693  0.214  0.675  1.0
  O  O8  1  0.307  0.786  0.325  1.0
  O  O9  1  0.807  0.214  0.175  1.0
  O  O10  1  0.721  0.626  0.614  1.0
  O  O11  1  0.779  0.626  0.114  1.0
  O  O12  1  0.193  0.786  0.825  1.0
  O  O13  1  0.221  0.374  0.886  1.0
[/CIF]
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The material described by CdC2O4 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing CdO6 octahedra. The corner-sharing octahedral tilt angles are 56°. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(1) atom. is represented by the CIF file [CIF]
data_Cd(CO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.412
_cell_length_b   5.906
_cell_length_c   6.579
_cell_angle_alpha   57.149
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   176.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.000  0.000  1.0
  Cd  Cd1  1  0.500  0.000  0.500  1.0
  C  C2  1  0.882  0.456  0.082  1.0
  C  C3  1  0.118  0.544  0.918  1.0
  C  C4  1  0.618  0.456  0.582  1.0
  C  C5  1  0.382  0.544  0.418  1.0
  O  O6  1  0.279  0.374  0.386  1.0
  O  O7  1  0.693  0.214  0.675  1.0
  O  O8  1  0.307  0.786  0.325  1.0
  O  O9  1  0.807  0.214  0.175  1.0
  O  O10  1  0.721  0.626  0.614  1.0
  O  O11  1  0.779  0.626  0.114  1.0
  O  O12  1  0.193  0.786  0.825  1.0
  O  O13  1  0.221  0.374  0.886  1.0
[/CIF]
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