The material described by Mn(H2O)6(MnH4(OF2)2)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one manganese;hexahydrate molecule, two water molecules, and two MnH4(OF2)2 clusters. In each MnH4(OF2)2 cluster, Mn(2) is bonded in an octahedral geometry to one O(3), one O(5), one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Mn(2), one H(10), and one H(9) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(2), one H(5), and one H(6) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Mn(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Mn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Mn(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Mn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3H24(O3F2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.275
_cell_length_b   8.998
_cell_length_c   9.408
_cell_angle_alpha   110.612
_cell_angle_beta   103.362
_cell_angle_gamma   106.905
_symmetry_Int_Tables_number   1
_cell_volume   441.493
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.850  0.304  0.622  1.0
  Mn  Mn2  1  0.150  0.696  0.378  1.0
  H  H3  1  0.803  0.637  0.825  1.0
  H  H4  1  0.197  0.363  0.175  1.0
  H  H5  1  0.897  0.679  0.013  1.0
  H  H6  1  0.103  0.321  0.987  1.0
  H  H7  1  0.551  0.914  0.774  1.0
  H  H8  1  0.449  0.086  0.226  1.0
  H  H9  1  0.614  0.090  0.930  1.0
  H  H10  1  0.386  0.910  0.070  1.0
  H  H11  1  0.215  0.442  0.524  1.0
  H  H12  1  0.785  0.558  0.476  1.0
  H  H13  1  0.322  0.360  0.634  1.0
  H  H14  1  0.678  0.640  0.366  1.0
  H  H15  1  0.883  0.123  0.291  1.0
  H  H16  1  0.117  0.877  0.709  1.0
  H  H17  1  0.026  0.003  0.300  1.0
  H  H18  1  0.974  0.997  0.700  1.0
  H  H19  1  0.356  0.111  0.573  1.0
  H  H20  1  0.644  0.889  0.427  1.0
  H  H21  1  0.511  0.238  0.765  1.0
  H  H22  1  0.489  0.762  0.235  1.0
  H  H23  1  0.464  0.299  0.019  1.0
  H  H24  1  0.536  0.701  0.981  1.0
  H  H25  1  0.736  0.389  0.043  1.0
  H  H26  1  0.264  0.611  0.957  1.0
  O  O27  1  0.817  0.715  0.936  1.0
  O  O28  1  0.183  0.285  0.064  1.0
  O  O29  1  0.657  0.989  0.890  1.0
  O  O30  1  0.343  0.011  0.110  1.0
  O  O31  1  0.211  0.417  0.618  1.0
  O  O32  1  0.789  0.583  0.382  1.0
  O  O33  1  0.966  0.058  0.235  1.0
  O  O34  1  0.034  0.942  0.765  1.0
  O  O35  1  0.482  0.228  0.652  1.0
  O  O36  1  0.518  0.772  0.348  1.0
  O  O37  1  0.585  0.285  0.970  1.0
  O  O38  1  0.415  0.715  0.030  1.0
  F  F39  1  0.818  0.515  0.648  1.0
  F  F40  1  0.182  0.485  0.352  1.0
  F  F41  1  0.002  0.394  0.851  1.0
  F  F42  1  0.998  0.606  0.149  1.0
  F  F43  1  0.857  0.084  0.591  1.0
  F  F44  1  0.143  0.916  0.409  1.0
  F  F45  1  0.704  0.208  0.393  1.0
  F  F46  1  0.296  0.792  0.607  1.0
[/CIF]
.
The material described by Mn(H2O)6(MnH4(OF2)2)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one manganese;hexahydrate molecule, two water molecules, and two MnH4(OF2)2 clusters. In each MnH4(OF2)2 cluster, Mn(2) is bonded in an octahedral geometry to one O(3), one O(5), one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Mn(2), one H(10), and one H(9) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(2), one H(5), and one H(6) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Mn(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Mn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Mn(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Mn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3H24(O3F2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.275
_cell_length_b   8.998
_cell_length_c   9.408
_cell_angle_alpha   110.612
_cell_angle_beta   103.362
_cell_angle_gamma   106.905
_symmetry_Int_Tables_number   1
_cell_volume   441.493
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.850  0.304  0.622  1.0
  Mn  Mn2  1  0.150  0.696  0.378  1.0
  H  H3  1  0.803  0.637  0.825  1.0
  H  H4  1  0.197  0.363  0.175  1.0
  H  H5  1  0.897  0.679  0.013  1.0
  H  H6  1  0.103  0.321  0.987  1.0
  H  H7  1  0.551  0.914  0.774  1.0
  H  H8  1  0.449  0.086  0.226  1.0
  H  H9  1  0.614  0.090  0.930  1.0
  H  H10  1  0.386  0.910  0.070  1.0
  H  H11  1  0.215  0.442  0.524  1.0
  H  H12  1  0.785  0.558  0.476  1.0
  H  H13  1  0.322  0.360  0.634  1.0
  H  H14  1  0.678  0.640  0.366  1.0
  H  H15  1  0.883  0.123  0.291  1.0
  H  H16  1  0.117  0.877  0.709  1.0
  H  H17  1  0.026  0.003  0.300  1.0
  H  H18  1  0.974  0.997  0.700  1.0
  H  H19  1  0.356  0.111  0.573  1.0
  H  H20  1  0.644  0.889  0.427  1.0
  H  H21  1  0.511  0.238  0.765  1.0
  H  H22  1  0.489  0.762  0.235  1.0
  H  H23  1  0.464  0.299  0.019  1.0
  H  H24  1  0.536  0.701  0.981  1.0
  H  H25  1  0.736  0.389  0.043  1.0
  H  H26  1  0.264  0.611  0.957  1.0
  O  O27  1  0.817  0.715  0.936  1.0
  O  O28  1  0.183  0.285  0.064  1.0
  O  O29  1  0.657  0.989  0.890  1.0
  O  O30  1  0.343  0.011  0.110  1.0
  O  O31  1  0.211  0.417  0.618  1.0
  O  O32  1  0.789  0.583  0.382  1.0
  O  O33  1  0.966  0.058  0.235  1.0
  O  O34  1  0.034  0.942  0.765  1.0
  O  O35  1  0.482  0.228  0.652  1.0
  O  O36  1  0.518  0.772  0.348  1.0
  O  O37  1  0.585  0.285  0.970  1.0
  O  O38  1  0.415  0.715  0.030  1.0
  F  F39  1  0.818  0.515  0.648  1.0
  F  F40  1  0.182  0.485  0.352  1.0
  F  F41  1  0.002  0.394  0.851  1.0
  F  F42  1  0.998  0.606  0.149  1.0
  F  F43  1  0.857  0.084  0.591  1.0
  F  F44  1  0.143  0.916  0.409  1.0
  F  F45  1  0.704  0.208  0.393  1.0
  F  F46  1  0.296  0.792  0.607  1.0
[/CIF]
.