The structure described by LiLa2Co2Sb2(PbO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(7), and one O(9) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(6), one O(8), and one O(9) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 3-coordinate geometry to one Pb(2), one O(11), one O(2), and one O(5) atom. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(6), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-31°. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(4), and one O(9) atom. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to one Co(1), one O(10), one O(12), one O(2), one O(3), and one O(7) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form SbO6 octahedra that share corners with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-31°. In the second Sb site, Sb(2) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-30°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(2), one Co(2), one Pb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Co(1), one Pb(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one La(1), one Co(2), one Pb(2), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one La(2), one Pb(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one La(2), one Co(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one Co(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Li(1), one La(2), one Pb(2), and one Sb(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Co(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Pb(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(2), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one La(1), one Co(1), one Pb(1), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(2), one Co(2), one Pb(2), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LiLa2Co2Sb2(PbO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.777
_cell_length_b   6.089
_cell_length_c   8.133
_cell_angle_alpha   87.415
_cell_angle_beta   90.278
_cell_angle_gamma   91.845
_symmetry_Int_Tables_number   1
_cell_volume   285.666
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.024  0.381  0.457  1.0
  La  La1  1  0.498  0.428  0.757  1.0
  La  La2  1  0.013  0.028  0.234  1.0
  Co  Co3  1  0.973  0.703  0.590  1.0
  Co  Co4  1  0.507  0.964  0.994  1.0
  Sb  Sb5  1  0.993  0.500  0.997  1.0
  Sb  Sb6  1  0.506  0.978  0.489  1.0
  Pb  Pb7  1  0.503  0.521  0.254  1.0
  Pb  Pb8  1  0.011  0.035  0.778  1.0
  O  O9  1  0.597  0.951  0.244  1.0
  O  O10  1  0.085  0.487  0.754  1.0
  O  O11  1  0.451  0.025  0.736  1.0
  O  O12  1  0.926  0.444  0.233  1.0
  O  O13  1  0.217  0.799  0.434  1.0
  O  O14  1  0.716  0.682  0.942  1.0
  O  O15  1  0.810  0.137  0.507  1.0
  O  O16  1  0.251  0.277  0.025  1.0
  O  O17  1  0.320  0.245  0.447  1.0
  O  O18  1  0.764  0.232  0.956  1.0
  O  O19  1  0.644  0.680  0.540  1.0
  O  O20  1  0.190  0.775  0.033  1.0
[/CIF]
.
The structure described by LiLa2Co2Sb2(PbO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(7), and one O(9) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(6), one O(8), and one O(9) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 3-coordinate geometry to one Pb(2), one O(11), one O(2), and one O(5) atom. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(6), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-31°. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(4), and one O(9) atom. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to one Co(1), one O(10), one O(12), one O(2), one O(3), and one O(7) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form SbO6 octahedra that share corners with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-31°. In the second Sb site, Sb(2) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-30°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(2), one Co(2), one Pb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Co(1), one Pb(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one La(1), one Co(2), one Pb(2), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one La(2), one Pb(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one La(2), one Co(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one Co(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Li(1), one La(2), one Pb(2), and one Sb(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Co(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Pb(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(2), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one La(1), one Co(1), one Pb(1), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(2), one Co(2), one Pb(2), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LiLa2Co2Sb2(PbO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.777
_cell_length_b   6.089
_cell_length_c   8.133
_cell_angle_alpha   87.415
_cell_angle_beta   90.278
_cell_angle_gamma   91.845
_symmetry_Int_Tables_number   1
_cell_volume   285.666
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.024  0.381  0.457  1.0
  La  La1  1  0.498  0.428  0.757  1.0
  La  La2  1  0.013  0.028  0.234  1.0
  Co  Co3  1  0.973  0.703  0.590  1.0
  Co  Co4  1  0.507  0.964  0.994  1.0
  Sb  Sb5  1  0.993  0.500  0.997  1.0
  Sb  Sb6  1  0.506  0.978  0.489  1.0
  Pb  Pb7  1  0.503  0.521  0.254  1.0
  Pb  Pb8  1  0.011  0.035  0.778  1.0
  O  O9  1  0.597  0.951  0.244  1.0
  O  O10  1  0.085  0.487  0.754  1.0
  O  O11  1  0.451  0.025  0.736  1.0
  O  O12  1  0.926  0.444  0.233  1.0
  O  O13  1  0.217  0.799  0.434  1.0
  O  O14  1  0.716  0.682  0.942  1.0
  O  O15  1  0.810  0.137  0.507  1.0
  O  O16  1  0.251  0.277  0.025  1.0
  O  O17  1  0.320  0.245  0.447  1.0
  O  O18  1  0.764  0.232  0.956  1.0
  O  O19  1  0.644  0.680  0.540  1.0
  O  O20  1  0.190  0.775  0.033  1.0
[/CIF]
.