The crystal structure described by Zn(CoZn(CN)6)2 is alpha Rhenium trioxide-derived structured and crystallizes in the tetragonal P-4m2 space group. The structure consists of one 7440-66-6 atom inside a CoZn(CN)6 framework. In the CoZn(CN)6 framework, Co(1) is bonded in an octahedral geometry to one C(1), one C(2), and four equivalent C(3) atoms. Zn(1) is bonded in an octahedral geometry to one N(1), one N(2), and four equivalent N(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Zn(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Zn(1) and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn3Co2(CN)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.270
_cell_length_b   7.270
_cell_length_c   10.243
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   541.446
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.000  0.247  1.0
  Zn  Zn1  1  0.000  0.500  0.753  1.0
  Zn  Zn2  1  0.500  0.500  0.000  1.0
  Co  Co3  1  0.500  0.000  0.745  1.0
  Co  Co4  1  0.000  0.500  0.255  1.0
  C  C5  1  0.500  0.000  0.926  1.0
  C  C6  1  0.000  0.500  0.438  1.0
  C  C7  1  0.183  0.320  0.249  1.0
  C  C8  1  0.680  0.817  0.751  1.0
  C  C9  1  0.817  0.320  0.249  1.0
  C  C10  1  0.320  0.817  0.751  1.0
  C  C11  1  0.500  0.000  0.562  1.0
  C  C12  1  0.000  0.500  0.074  1.0
  C  C13  1  0.817  0.680  0.249  1.0
  C  C14  1  0.320  0.183  0.751  1.0
  C  C15  1  0.183  0.680  0.249  1.0
  C  C16  1  0.680  0.183  0.751  1.0
  N  N17  1  0.500  0.000  0.039  1.0
  N  N18  1  0.000  0.500  0.551  1.0
  N  N19  1  0.300  0.212  0.237  1.0
  N  N20  1  0.788  0.700  0.763  1.0
  N  N21  1  0.700  0.212  0.237  1.0
  N  N22  1  0.212  0.700  0.763  1.0
  N  N23  1  0.500  0.000  0.449  1.0
  N  N24  1  0.000  0.500  0.961  1.0
  N  N25  1  0.700  0.788  0.237  1.0
  N  N26  1  0.212  0.300  0.763  1.0
  N  N27  1  0.300  0.788  0.237  1.0
  N  N28  1  0.788  0.300  0.763  1.0
[/CIF]
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The crystal structure described by Zn(CoZn(CN)6)2 is alpha Rhenium trioxide-derived structured and crystallizes in the tetragonal P-4m2 space group. The structure consists of one 7440-66-6 atom inside a CoZn(CN)6 framework. In the CoZn(CN)6 framework, Co(1) is bonded in an octahedral geometry to one C(1), one C(2), and four equivalent C(3) atoms. Zn(1) is bonded in an octahedral geometry to one N(1), one N(2), and four equivalent N(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Zn(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Zn(1) and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn3Co2(CN)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.270
_cell_length_b   7.270
_cell_length_c   10.243
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   541.446
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.000  0.247  1.0
  Zn  Zn1  1  0.000  0.500  0.753  1.0
  Zn  Zn2  1  0.500  0.500  0.000  1.0
  Co  Co3  1  0.500  0.000  0.745  1.0
  Co  Co4  1  0.000  0.500  0.255  1.0
  C  C5  1  0.500  0.000  0.926  1.0
  C  C6  1  0.000  0.500  0.438  1.0
  C  C7  1  0.183  0.320  0.249  1.0
  C  C8  1  0.680  0.817  0.751  1.0
  C  C9  1  0.817  0.320  0.249  1.0
  C  C10  1  0.320  0.817  0.751  1.0
  C  C11  1  0.500  0.000  0.562  1.0
  C  C12  1  0.000  0.500  0.074  1.0
  C  C13  1  0.817  0.680  0.249  1.0
  C  C14  1  0.320  0.183  0.751  1.0
  C  C15  1  0.183  0.680  0.249  1.0
  C  C16  1  0.680  0.183  0.751  1.0
  N  N17  1  0.500  0.000  0.039  1.0
  N  N18  1  0.000  0.500  0.551  1.0
  N  N19  1  0.300  0.212  0.237  1.0
  N  N20  1  0.788  0.700  0.763  1.0
  N  N21  1  0.700  0.212  0.237  1.0
  N  N22  1  0.212  0.700  0.763  1.0
  N  N23  1  0.500  0.000  0.449  1.0
  N  N24  1  0.000  0.500  0.961  1.0
  N  N25  1  0.700  0.788  0.237  1.0
  N  N26  1  0.212  0.300  0.763  1.0
  N  N27  1  0.300  0.788  0.237  1.0
  N  N28  1  0.788  0.300  0.763  1.0
[/CIF]
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