The structure described by K3SO4F crystallizes in the cubic P-43m space group. K(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form distorted KO4F2 pentagonal pyramids that share corners with two equivalent K(1)O4F2 pentagonal pyramids, corners with four equivalent S(1)O4 tetrahedra, and edges with eight equivalent K(1)O4F2 pentagonal pyramids. S(1) is bonded to four equivalent O(1) atoms to form SO4 tetrahedra that share corners with twelve equivalent K(1)O4F2 pentagonal pyramids. O(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent K(1) and one S(1) atom. F(1) is bonded to six equivalent K(1) atoms to form corner-sharing FK6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_K3SO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.467
_cell_length_b   5.467
_cell_length_c   5.467
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   163.407
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.000  0.000  1.0
  K  K1  1  0.000  0.000  0.500  1.0
  K  K2  1  0.000  0.500  0.000  1.0
  S  S3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.342  0.342  0.658  1.0
  O  O5  1  0.342  0.658  0.342  1.0
  O  O6  1  0.658  0.342  0.342  1.0
  O  O7  1  0.658  0.658  0.658  1.0
  F  F8  1  0.000  0.000  0.000  1.0
[/CIF]
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The structure described by K3SO4F crystallizes in the cubic P-43m space group. K(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form distorted KO4F2 pentagonal pyramids that share corners with two equivalent K(1)O4F2 pentagonal pyramids, corners with four equivalent S(1)O4 tetrahedra, and edges with eight equivalent K(1)O4F2 pentagonal pyramids. S(1) is bonded to four equivalent O(1) atoms to form SO4 tetrahedra that share corners with twelve equivalent K(1)O4F2 pentagonal pyramids. O(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent K(1) and one S(1) atom. F(1) is bonded to six equivalent K(1) atoms to form corner-sharing FK6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_K3SO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.467
_cell_length_b   5.467
_cell_length_c   5.467
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   163.407
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.000  0.000  1.0
  K  K1  1  0.000  0.000  0.500  1.0
  K  K2  1  0.000  0.500  0.000  1.0
  S  S3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.342  0.342  0.658  1.0
  O  O5  1  0.342  0.658  0.342  1.0
  O  O6  1  0.658  0.342  0.342  1.0
  O  O7  1  0.658  0.658  0.658  1.0
  F  F8  1  0.000  0.000  0.000  1.0
[/CIF]
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