The crystal structure described by (LiSO4)2N2 crystallizes in the monoclinic P2_1 space group. The structure consists of four ammonia atoms inside a LiSO4 framework. In the LiSO4 framework, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(5), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra and corners with three equivalent S(2)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one S(2)O4 tetrahedra and corners with three equivalent S(1)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra and corners with three equivalent Li(2)O4 tetrahedra. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra and corners with three equivalent Li(1)O4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(2) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Li(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one S(1) atom. In the fifth O site, O(5) is bonded in a linear geometry to one Li(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Li(2) and one S(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Li(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Li(1) and one S(2) atom. is represented by the CIF file [CIF]
data_LiSNO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.444
_cell_length_b   8.847
_cell_length_c   9.231
_cell_angle_alpha   89.745
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   444.587
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.221  0.681  0.416  1.0
  Li  Li1  1  0.721  0.319  0.584  1.0
  Li  Li2  1  0.257  0.178  0.088  1.0
  Li  Li3  1  0.757  0.822  0.912  1.0
  S  S4  1  0.252  0.798  0.090  1.0
  S  S5  1  0.752  0.202  0.910  1.0
  S  S6  1  0.228  0.298  0.424  1.0
  S  S7  1  0.728  0.702  0.576  1.0
  N  N8  1  0.720  0.496  0.217  1.0
  N  N9  1  0.220  0.504  0.783  1.0
  N  N10  1  0.760  0.004  0.296  1.0
  N  N11  1  0.260  0.996  0.704  1.0
  O  O12  1  0.235  0.961  0.130  1.0
  O  O13  1  0.735  0.039  0.870  1.0
  O  O14  1  0.163  0.702  0.209  1.0
  O  O15  1  0.663  0.298  0.791  1.0
  O  O16  1  0.100  0.776  0.958  1.0
  O  O17  1  0.600  0.224  0.042  1.0
  O  O18  1  0.514  0.763  0.060  1.0
  O  O19  1  0.014  0.237  0.940  1.0
  O  O20  1  0.239  0.463  0.443  1.0
  O  O21  1  0.739  0.537  0.557  1.0
  O  O22  1  0.156  0.268  0.271  1.0
  O  O23  1  0.656  0.732  0.729  1.0
  O  O24  1  0.031  0.229  0.515  1.0
  O  O25  1  0.531  0.771  0.485  1.0
  O  O26  1  0.467  0.228  0.460  1.0
  O  O27  1  0.967  0.772  0.540  1.0
[/CIF]
.
The crystal structure described by (LiSO4)2N2 crystallizes in the monoclinic P2_1 space group. The structure consists of four ammonia atoms inside a LiSO4 framework. In the LiSO4 framework, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(5), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra and corners with three equivalent S(2)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one S(2)O4 tetrahedra and corners with three equivalent S(1)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra and corners with three equivalent Li(2)O4 tetrahedra. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra and corners with three equivalent Li(1)O4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(2) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Li(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one S(1) atom. In the fifth O site, O(5) is bonded in a linear geometry to one Li(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Li(2) and one S(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Li(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Li(1) and one S(2) atom. is represented by the CIF file [CIF]
data_LiSNO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.444
_cell_length_b   8.847
_cell_length_c   9.231
_cell_angle_alpha   89.745
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   444.587
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.221  0.681  0.416  1.0
  Li  Li1  1  0.721  0.319  0.584  1.0
  Li  Li2  1  0.257  0.178  0.088  1.0
  Li  Li3  1  0.757  0.822  0.912  1.0
  S  S4  1  0.252  0.798  0.090  1.0
  S  S5  1  0.752  0.202  0.910  1.0
  S  S6  1  0.228  0.298  0.424  1.0
  S  S7  1  0.728  0.702  0.576  1.0
  N  N8  1  0.720  0.496  0.217  1.0
  N  N9  1  0.220  0.504  0.783  1.0
  N  N10  1  0.760  0.004  0.296  1.0
  N  N11  1  0.260  0.996  0.704  1.0
  O  O12  1  0.235  0.961  0.130  1.0
  O  O13  1  0.735  0.039  0.870  1.0
  O  O14  1  0.163  0.702  0.209  1.0
  O  O15  1  0.663  0.298  0.791  1.0
  O  O16  1  0.100  0.776  0.958  1.0
  O  O17  1  0.600  0.224  0.042  1.0
  O  O18  1  0.514  0.763  0.060  1.0
  O  O19  1  0.014  0.237  0.940  1.0
  O  O20  1  0.239  0.463  0.443  1.0
  O  O21  1  0.739  0.537  0.557  1.0
  O  O22  1  0.156  0.268  0.271  1.0
  O  O23  1  0.656  0.732  0.729  1.0
  O  O24  1  0.031  0.229  0.515  1.0
  O  O25  1  0.531  0.771  0.485  1.0
  O  O26  1  0.467  0.228  0.460  1.0
  O  O27  1  0.967  0.772  0.540  1.0
[/CIF]
.