The material structure described by LiVMnP2(HO5)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(4), one O(5), one O(6), and one O(7) atom. V(1) is bonded in a 2-coordinate geometry to one O(1) and one O(10) atom. Mn(1) is bonded in a distorted hexagonal bipyramidal geometry to one O(1), one O(10), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted L-shaped geometry to one O(2), one O(4), one O(5), and one O(8) atom. In the second P site, P(2) is bonded in a distorted L-shaped geometry to one O(3), one O(6), one O(7), and one O(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one V(1), one Mn(1), one H(2), and one O(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Mn(1), one P(1), and one O(10) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Li(1), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Li(1), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Mn(1), one P(2), and one O(1) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Mn(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one P(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one V(1), one Mn(1), one H(1), and one O(4) atom. is represented by the CIF file [CIF]
data_LiMnVP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.224
_cell_length_b   5.345
_cell_length_c   7.351
_cell_angle_alpha   110.796
_cell_angle_beta   103.583
_cell_angle_gamma   100.149
_symmetry_Int_Tables_number   1
_cell_volume   178.762
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.775  0.409  0.152  1.0
  Mn  Mn1  1  0.001  0.005  0.997  1.0
  V  V2  1  0.998  0.997  0.505  1.0
  P  P3  1  0.319  0.642  0.231  1.0
  P  P4  1  0.674  0.357  0.773  1.0
  H  H5  1  0.644  0.939  0.343  1.0
  H  H6  1  0.353  0.037  0.662  1.0
  O  O7  1  0.142  0.976  0.719  1.0
  O  O8  1  0.283  0.811  0.381  1.0
  O  O9  1  0.722  0.658  0.647  1.0
  O  O10  1  0.633  0.747  0.071  1.0
  O  O11  1  0.105  0.652  0.135  1.0
  O  O12  1  0.869  0.345  0.886  1.0
  O  O13  1  0.363  0.243  0.931  1.0
  O  O14  1  0.292  0.342  0.346  1.0
  O  O15  1  0.727  0.196  0.618  1.0
  O  O16  1  0.849  0.046  0.278  1.0
[/CIF]
.
The material structure described by LiVMnP2(HO5)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(4), one O(5), one O(6), and one O(7) atom. V(1) is bonded in a 2-coordinate geometry to one O(1) and one O(10) atom. Mn(1) is bonded in a distorted hexagonal bipyramidal geometry to one O(1), one O(10), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted L-shaped geometry to one O(2), one O(4), one O(5), and one O(8) atom. In the second P site, P(2) is bonded in a distorted L-shaped geometry to one O(3), one O(6), one O(7), and one O(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one V(1), one Mn(1), one H(2), and one O(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Mn(1), one P(1), and one O(10) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Li(1), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Li(1), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Mn(1), one P(2), and one O(1) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Mn(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one P(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one V(1), one Mn(1), one H(1), and one O(4) atom. is represented by the CIF file [CIF]
data_LiMnVP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.224
_cell_length_b   5.345
_cell_length_c   7.351
_cell_angle_alpha   110.796
_cell_angle_beta   103.583
_cell_angle_gamma   100.149
_symmetry_Int_Tables_number   1
_cell_volume   178.762
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.775  0.409  0.152  1.0
  Mn  Mn1  1  0.001  0.005  0.997  1.0
  V  V2  1  0.998  0.997  0.505  1.0
  P  P3  1  0.319  0.642  0.231  1.0
  P  P4  1  0.674  0.357  0.773  1.0
  H  H5  1  0.644  0.939  0.343  1.0
  H  H6  1  0.353  0.037  0.662  1.0
  O  O7  1  0.142  0.976  0.719  1.0
  O  O8  1  0.283  0.811  0.381  1.0
  O  O9  1  0.722  0.658  0.647  1.0
  O  O10  1  0.633  0.747  0.071  1.0
  O  O11  1  0.105  0.652  0.135  1.0
  O  O12  1  0.869  0.345  0.886  1.0
  O  O13  1  0.363  0.243  0.931  1.0
  O  O14  1  0.292  0.342  0.346  1.0
  O  O15  1  0.727  0.196  0.618  1.0
  O  O16  1  0.849  0.046  0.278  1.0
[/CIF]
.