The material structure described by ZnH3(CO2)3N(CH3)2 crystallizes in the monoclinic Cc space group. The structure consists of four dimethylamine molecules inside a ZnH3(CO2)3 framework. In the ZnH3(CO2)3 framework, Zn(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are three inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one H(7), one O(1), and one O(5) atom. In the second C site, C(4) is bonded in a trigonal planar geometry to one H(8), one O(2), and one O(4) atom. In the third C site, C(5) is bonded in a trigonal planar geometry to one H(9), one O(3), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. is represented by the CIF file [CIF]
data_ZnH9C5NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.213
_cell_length_b   8.213
_cell_length_c   8.765
_cell_angle_alpha   62.257
_cell_angle_beta   62.257
_cell_angle_gamma   59.845
_symmetry_Int_Tables_number   1
_cell_volume   431.165
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.504  0.999  0.500  1.0
  Zn  Zn1  1  0.999  0.504  0.000  1.0
  H  H2  1  0.409  0.897  0.977  1.0
  H  H3  1  0.159  0.887  0.096  1.0
  H  H4  1  0.365  0.675  0.055  1.0
  H  H5  1  0.897  0.409  0.477  1.0
  H  H6  1  0.675  0.365  0.555  1.0
  H  H7  1  0.887  0.159  0.596  1.0
  H  H8  1  0.614  0.142  0.903  1.0
  H  H9  1  0.825  0.094  0.945  1.0
  H  H10  1  0.603  0.282  0.024  1.0
  H  H11  1  0.142  0.614  0.403  1.0
  H  H12  1  0.282  0.603  0.524  1.0
  H  H13  1  0.094  0.825  0.445  1.0
  H  H14  1  0.250  0.333  0.251  1.0
  H  H15  1  0.661  0.752  0.249  1.0
  H  H16  1  0.835  0.166  0.251  1.0
  H  H17  1  0.333  0.250  0.751  1.0
  H  H18  1  0.166  0.835  0.751  1.0
  H  H19  1  0.752  0.661  0.749  1.0
  C  C20  1  0.318  0.812  0.086  1.0
  C  C21  1  0.812  0.318  0.586  1.0
  C  C22  1  0.688  0.216  0.914  1.0
  C  C23  1  0.216  0.688  0.414  1.0
  C  C24  1  0.248  0.200  0.249  1.0
  C  C25  1  0.796  0.754  0.247  1.0
  C  C26  1  0.698  0.301  0.253  1.0
  C  C27  1  0.200  0.248  0.749  1.0
  C  C28  1  0.301  0.698  0.753  1.0
  C  C29  1  0.754  0.796  0.747  1.0
  N  N30  1  0.354  0.750  0.251  1.0
  N  N31  1  0.750  0.354  0.751  1.0
  O  O32  1  0.347  0.033  0.338  1.0
  O  O33  1  0.776  0.854  0.334  1.0
  O  O34  1  0.533  0.279  0.340  1.0
  O  O35  1  0.033  0.347  0.838  1.0
  O  O36  1  0.279  0.533  0.840  1.0
  O  O37  1  0.854  0.776  0.834  1.0
  O  O38  1  0.655  0.964  0.660  1.0
  O  O39  1  0.224  0.148  0.661  1.0
  O  O40  1  0.467  0.718  0.667  1.0
  O  O41  1  0.964  0.655  0.160  1.0
  O  O42  1  0.718  0.467  0.167  1.0
  O  O43  1  0.148  0.224  0.161  1.0
[/CIF]
.
The material structure described by ZnH3(CO2)3N(CH3)2 crystallizes in the monoclinic Cc space group. The structure consists of four dimethylamine molecules inside a ZnH3(CO2)3 framework. In the ZnH3(CO2)3 framework, Zn(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are three inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one H(7), one O(1), and one O(5) atom. In the second C site, C(4) is bonded in a trigonal planar geometry to one H(8), one O(2), and one O(4) atom. In the third C site, C(5) is bonded in a trigonal planar geometry to one H(9), one O(3), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. is represented by the CIF file [CIF]
data_ZnH9C5NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.213
_cell_length_b   8.213
_cell_length_c   8.765
_cell_angle_alpha   62.257
_cell_angle_beta   62.257
_cell_angle_gamma   59.845
_symmetry_Int_Tables_number   1
_cell_volume   431.165
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.504  0.999  0.500  1.0
  Zn  Zn1  1  0.999  0.504  0.000  1.0
  H  H2  1  0.409  0.897  0.977  1.0
  H  H3  1  0.159  0.887  0.096  1.0
  H  H4  1  0.365  0.675  0.055  1.0
  H  H5  1  0.897  0.409  0.477  1.0
  H  H6  1  0.675  0.365  0.555  1.0
  H  H7  1  0.887  0.159  0.596  1.0
  H  H8  1  0.614  0.142  0.903  1.0
  H  H9  1  0.825  0.094  0.945  1.0
  H  H10  1  0.603  0.282  0.024  1.0
  H  H11  1  0.142  0.614  0.403  1.0
  H  H12  1  0.282  0.603  0.524  1.0
  H  H13  1  0.094  0.825  0.445  1.0
  H  H14  1  0.250  0.333  0.251  1.0
  H  H15  1  0.661  0.752  0.249  1.0
  H  H16  1  0.835  0.166  0.251  1.0
  H  H17  1  0.333  0.250  0.751  1.0
  H  H18  1  0.166  0.835  0.751  1.0
  H  H19  1  0.752  0.661  0.749  1.0
  C  C20  1  0.318  0.812  0.086  1.0
  C  C21  1  0.812  0.318  0.586  1.0
  C  C22  1  0.688  0.216  0.914  1.0
  C  C23  1  0.216  0.688  0.414  1.0
  C  C24  1  0.248  0.200  0.249  1.0
  C  C25  1  0.796  0.754  0.247  1.0
  C  C26  1  0.698  0.301  0.253  1.0
  C  C27  1  0.200  0.248  0.749  1.0
  C  C28  1  0.301  0.698  0.753  1.0
  C  C29  1  0.754  0.796  0.747  1.0
  N  N30  1  0.354  0.750  0.251  1.0
  N  N31  1  0.750  0.354  0.751  1.0
  O  O32  1  0.347  0.033  0.338  1.0
  O  O33  1  0.776  0.854  0.334  1.0
  O  O34  1  0.533  0.279  0.340  1.0
  O  O35  1  0.033  0.347  0.838  1.0
  O  O36  1  0.279  0.533  0.840  1.0
  O  O37  1  0.854  0.776  0.834  1.0
  O  O38  1  0.655  0.964  0.660  1.0
  O  O39  1  0.224  0.148  0.661  1.0
  O  O40  1  0.467  0.718  0.667  1.0
  O  O41  1  0.964  0.655  0.160  1.0
  O  O42  1  0.718  0.467  0.167  1.0
  O  O43  1  0.148  0.224  0.161  1.0
[/CIF]
.