The structure described by (CF2)2C2Te(BrF)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight difluoromethane molecules and two C2Te(BrF)2 clusters. In each C2Te(BrF)2 cluster, there are four inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one Te(2) and one F(10) atom. In the second C site, C(6) is bonded in a distorted single-bond geometry to one Te(1) and one F(5) atom. In the third C site, C(7) is bonded in a distorted single-bond geometry to one Te(2) and one F(8) atom. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one Te(1) and one F(1) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one C(6), one C(8), one Br(1), and one Br(3) atom. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one C(3), one C(7), one Br(1), one Br(2), and one Br(4) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted water-like geometry to one Te(1) and one Te(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(2) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Te(2) atom. There are four inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one C(6) atom. In the second F site, F(8) is bonded in a single-bond geometry to one C(7) atom. In the third F site, F(10) is bonded in a single-bond geometry to one C(3) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one C(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeC4(BrF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.364
_cell_length_b   11.060
_cell_length_c   11.321
_cell_angle_alpha   62.625
_cell_angle_beta   87.863
_cell_angle_gamma   88.650
_symmetry_Int_Tables_number   1
_cell_volume   1040.447
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.918  0.111  0.631  1.0
  Te  Te1  1  0.082  0.889  0.369  1.0
  Te  Te2  1  0.215  0.330  0.208  1.0
  Te  Te3  1  0.785  0.670  0.792  1.0
  C  C4  1  0.666  0.117  0.821  1.0
  C  C5  1  0.654  0.527  0.639  1.0
  C  C6  1  0.640  0.549  0.745  1.0
  C  C7  1  0.334  0.883  0.179  1.0
  C  C8  1  0.484  0.798  0.799  1.0
  C  C9  1  0.138  0.220  0.757  1.0
  C  C10  1  0.996  0.767  0.285  1.0
  C  C11  1  0.389  0.244  0.143  1.0
  C  C12  1  0.346  0.473  0.361  1.0
  C  C13  1  0.862  0.780  0.243  1.0
  C  C14  1  0.516  0.202  0.201  1.0
  C  C15  1  0.360  0.451  0.255  1.0
  C  C16  1  0.004  0.233  0.715  1.0
  C  C17  1  0.704  0.127  0.702  1.0
  C  C18  1  0.296  0.873  0.298  1.0
  C  C19  1  0.611  0.756  0.857  1.0
  Br  Br20  1  0.031  0.126  0.138  1.0
  Br  Br21  1  0.205  0.531  0.967  1.0
  Br  Br22  1  0.135  0.662  0.590  1.0
  Br  Br23  1  0.969  0.874  0.862  1.0
  Br  Br24  1  0.235  0.102  0.463  1.0
  Br  Br25  1  0.865  0.338  0.410  1.0
  Br  Br26  1  0.795  0.469  0.033  1.0
  Br  Br27  1  0.765  0.898  0.537  1.0
  F  F28  1  0.399  0.852  0.386  1.0
  F  F29  1  0.531  0.127  0.858  1.0
  F  F30  1  0.751  0.586  0.542  1.0
  F  F31  1  0.447  0.790  0.691  1.0
  F  F32  1  0.920  0.335  0.714  1.0
  F  F33  1  0.244  0.903  0.084  1.0
  F  F34  1  0.572  0.442  0.619  1.0
  F  F35  1  0.366  0.232  0.032  1.0
  F  F36  1  0.382  0.853  0.844  1.0
  F  F37  1  0.465  0.517  0.163  1.0
  F  F38  1  0.634  0.768  0.968  1.0
  F  F39  1  0.553  0.210  0.309  1.0
  F  F40  1  0.805  0.699  0.201  1.0
  F  F41  1  0.469  0.873  0.142  1.0
  F  F42  1  0.756  0.097  0.916  1.0
  F  F43  1  0.249  0.414  0.458  1.0
  F  F44  1  0.772  0.876  0.239  1.0
  F  F45  1  0.080  0.665  0.286  1.0
  F  F46  1  0.228  0.124  0.761  1.0
  F  F47  1  0.195  0.301  0.799  1.0
  F  F48  1  0.535  0.483  0.837  1.0
  F  F49  1  0.428  0.558  0.381  1.0
  F  F50  1  0.601  0.148  0.614  1.0
  F  F51  1  0.618  0.147  0.156  1.0
[/CIF]
.
The structure described by (CF2)2C2Te(BrF)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight difluoromethane molecules and two C2Te(BrF)2 clusters. In each C2Te(BrF)2 cluster, there are four inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one Te(2) and one F(10) atom. In the second C site, C(6) is bonded in a distorted single-bond geometry to one Te(1) and one F(5) atom. In the third C site, C(7) is bonded in a distorted single-bond geometry to one Te(2) and one F(8) atom. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one Te(1) and one F(1) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one C(6), one C(8), one Br(1), and one Br(3) atom. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one C(3), one C(7), one Br(1), one Br(2), and one Br(4) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted water-like geometry to one Te(1) and one Te(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(2) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Te(2) atom. There are four inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one C(6) atom. In the second F site, F(8) is bonded in a single-bond geometry to one C(7) atom. In the third F site, F(10) is bonded in a single-bond geometry to one C(3) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one C(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeC4(BrF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.364
_cell_length_b   11.060
_cell_length_c   11.321
_cell_angle_alpha   62.625
_cell_angle_beta   87.863
_cell_angle_gamma   88.650
_symmetry_Int_Tables_number   1
_cell_volume   1040.447
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.918  0.111  0.631  1.0
  Te  Te1  1  0.082  0.889  0.369  1.0
  Te  Te2  1  0.215  0.330  0.208  1.0
  Te  Te3  1  0.785  0.670  0.792  1.0
  C  C4  1  0.666  0.117  0.821  1.0
  C  C5  1  0.654  0.527  0.639  1.0
  C  C6  1  0.640  0.549  0.745  1.0
  C  C7  1  0.334  0.883  0.179  1.0
  C  C8  1  0.484  0.798  0.799  1.0
  C  C9  1  0.138  0.220  0.757  1.0
  C  C10  1  0.996  0.767  0.285  1.0
  C  C11  1  0.389  0.244  0.143  1.0
  C  C12  1  0.346  0.473  0.361  1.0
  C  C13  1  0.862  0.780  0.243  1.0
  C  C14  1  0.516  0.202  0.201  1.0
  C  C15  1  0.360  0.451  0.255  1.0
  C  C16  1  0.004  0.233  0.715  1.0
  C  C17  1  0.704  0.127  0.702  1.0
  C  C18  1  0.296  0.873  0.298  1.0
  C  C19  1  0.611  0.756  0.857  1.0
  Br  Br20  1  0.031  0.126  0.138  1.0
  Br  Br21  1  0.205  0.531  0.967  1.0
  Br  Br22  1  0.135  0.662  0.590  1.0
  Br  Br23  1  0.969  0.874  0.862  1.0
  Br  Br24  1  0.235  0.102  0.463  1.0
  Br  Br25  1  0.865  0.338  0.410  1.0
  Br  Br26  1  0.795  0.469  0.033  1.0
  Br  Br27  1  0.765  0.898  0.537  1.0
  F  F28  1  0.399  0.852  0.386  1.0
  F  F29  1  0.531  0.127  0.858  1.0
  F  F30  1  0.751  0.586  0.542  1.0
  F  F31  1  0.447  0.790  0.691  1.0
  F  F32  1  0.920  0.335  0.714  1.0
  F  F33  1  0.244  0.903  0.084  1.0
  F  F34  1  0.572  0.442  0.619  1.0
  F  F35  1  0.366  0.232  0.032  1.0
  F  F36  1  0.382  0.853  0.844  1.0
  F  F37  1  0.465  0.517  0.163  1.0
  F  F38  1  0.634  0.768  0.968  1.0
  F  F39  1  0.553  0.210  0.309  1.0
  F  F40  1  0.805  0.699  0.201  1.0
  F  F41  1  0.469  0.873  0.142  1.0
  F  F42  1  0.756  0.097  0.916  1.0
  F  F43  1  0.249  0.414  0.458  1.0
  F  F44  1  0.772  0.876  0.239  1.0
  F  F45  1  0.080  0.665  0.286  1.0
  F  F46  1  0.228  0.124  0.761  1.0
  F  F47  1  0.195  0.301  0.799  1.0
  F  F48  1  0.535  0.483  0.837  1.0
  F  F49  1  0.428  0.558  0.381  1.0
  F  F50  1  0.601  0.148  0.614  1.0
  F  F51  1  0.618  0.147  0.156  1.0
[/CIF]
.