The material described by Pu3Zn22 crystallizes in the orthorhombic Imma space group. There are three inequivalent Pu sites. In the first Pu site, Pu(1) is bonded in a 20-coordinate geometry to two equivalent Zn(1), two equivalent Zn(10), two equivalent Zn(2), two equivalent Zn(3), two equivalent Zn(5), two equivalent Zn(6), four equivalent Zn(7), and four equivalent Zn(8) atoms. In the second Pu site, Pu(2) is bonded in a 16-coordinate geometry to two equivalent Zn(2), two equivalent Zn(3), two equivalent Zn(4), two equivalent Zn(9), and eight equivalent Zn(8) atoms. In the third Pu site, Pu(3) is bonded in a 16-coordinate geometry to two equivalent Zn(1), two equivalent Zn(4), two equivalent Zn(6), two equivalent Zn(9), and eight equivalent Zn(7) atoms. There are ten inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one Pu(1), one Pu(3), one Zn(1), one Zn(4), two equivalent Zn(10), two equivalent Zn(3), and four equivalent Zn(7) atoms to form distorted ZnPu2Zn10 cuboctahedra that share corners with two equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(5)Pu2Zn10 cuboctahedra, corners with three equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with two equivalent Zn(8)Pu3Zn9 cuboctahedra,  a faceface with one Zn(6)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(10)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(8)Pu3Zn9 cuboctahedra, faces with three equivalent Zn(1)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(3)Pu2Zn10 cuboctahedra, and faces with eight equivalent Zn(7)Pu3Zn9 cuboctahedra. In the second Zn site, Zn(2) is bonded to one Pu(1), one Pu(2), one Zn(2), one Zn(9), two equivalent Zn(5), two equivalent Zn(6), and four equivalent Zn(8) atoms to form distorted ZnPu2Zn10 cuboctahedra that share corners with two equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(10)Pu2Zn10 cuboctahedra, corners with three equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with two equivalent Zn(7)Pu3Zn9 cuboctahedra,  a faceface with one Zn(3)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(5)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(7)Pu3Zn9 cuboctahedra, faces with three equivalent Zn(2)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(6)Pu2Zn10 cuboctahedra, and faces with eight equivalent Zn(8)Pu3Zn9 cuboctahedra. In the third Zn site, Zn(3) is bonded to one Pu(1), one Pu(2), one Zn(10), one Zn(3), two equivalent Zn(1), two equivalent Zn(4), two equivalent Zn(7), and two equivalent Zn(8) atoms to form distorted ZnPu2Zn10 cuboctahedra that share  a cornercorner with one Zn(10)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with two equivalent Zn(5)Pu2Zn10 cuboctahedra, edges with two equivalent Zn(8)Pu3Zn9 cuboctahedra,  a faceface with one Zn(2)Pu2Zn10 cuboctahedra,  a faceface with one Zn(3)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(10)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(6)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(1)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(8)Pu3Zn9 cuboctahedra, and faces with six equivalent Zn(7)Pu3Zn9 cuboctahedra. In the fourth Zn site, Zn(4) is bonded in a 11-coordinate geometry to one Pu(2), one Pu(3), one Zn(1), two equivalent Zn(3), two equivalent Zn(7), two equivalent Zn(8), and two equivalent Zn(9) atoms. In the fifth Zn site, Zn(5) is bonded to two equivalent Pu(1), two equivalent Zn(6), four equivalent Zn(2), and four equivalent Zn(8) atoms to form distorted ZnPu2Zn10 cuboctahedra that share corners with two equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(10)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with four equivalent Zn(3)Pu2Zn10 cuboctahedra, edges with four equivalent Zn(8)Pu3Zn9 cuboctahedra, faces with two equivalent Zn(5)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(2)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(6)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(7)Pu3Zn9 cuboctahedra, and faces with four equivalent Zn(8)Pu3Zn9 cuboctahedra. In the sixth Zn site, Zn(6) is bonded to one Pu(1), one Pu(3), one Zn(5), one Zn(6), two equivalent Zn(2), two equivalent Zn(7), two equivalent Zn(8), and two equivalent Zn(9) atoms to form distorted ZnPu2Zn10 cuboctahedra that share  a cornercorner with one Zn(5)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with two equivalent Zn(10)Pu2Zn10 cuboctahedra, edges with two equivalent Zn(7)Pu3Zn9 cuboctahedra,  a faceface with one Zn(1)Pu2Zn10 cuboctahedra,  a faceface with one Zn(6)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(3)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(5)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(2)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(7)Pu3Zn9 cuboctahedra, and faces with six equivalent Zn(8)Pu3Zn9 cuboctahedra. In the seventh Zn site, Zn(10) is bonded to two equivalent Pu(1), two equivalent Zn(3), four equivalent Zn(1), and four equivalent Zn(7) atoms to form distorted ZnPu2Zn10 cuboctahedra that share corners with two equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(5)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with four equivalent Zn(6)Pu2Zn10 cuboctahedra, edges with four equivalent Zn(7)Pu3Zn9 cuboctahedra, faces with two equivalent Zn(10)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(1)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(3)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(7)Pu3Zn9 cuboctahedra, and faces with four equivalent Zn(8)Pu3Zn9 cuboctahedra. In the eighth Zn site, Zn(7) is bonded to one Pu(1), two equivalent Pu(3), one Zn(10), one Zn(3), one Zn(4), one Zn(6), one Zn(7), one Zn(8), one Zn(9), and two equivalent Zn(1) atoms to form distorted ZnPu3Zn9 cuboctahedra that share  a cornercorner with one Zn(10)Pu2Zn10 cuboctahedra,  a cornercorner with one Zn(5)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with five equivalent Zn(8)Pu3Zn9 cuboctahedra, corners with six equivalent Zn(7)Pu3Zn9 cuboctahedra,  an edgeedge with one Zn(10)Pu2Zn10 cuboctahedra,  an edgeedge with one Zn(2)Pu2Zn10 cuboctahedra,  an edgeedge with one Zn(6)Pu2Zn10 cuboctahedra, edges with two equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with three equivalent Zn(7)Pu3Zn9 cuboctahedra,  a faceface with one Zn(10)Pu2Zn10 cuboctahedra,  a faceface with one Zn(2)Pu2Zn10 cuboctahedra,  a faceface with one Zn(5)Pu2Zn10 cuboctahedra,  a faceface with one Zn(8)Pu3Zn9 cuboctahedra, faces with two equivalent Zn(6)Pu2Zn10 cuboctahedra, faces with three equivalent Zn(3)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(1)Pu2Zn10 cuboctahedra, and faces with five equivalent Zn(7)Pu3Zn9 cuboctahedra. In the ninth Zn site, Zn(8) is bonded to one Pu(1), two equivalent Pu(2), one Zn(3), one Zn(4), one Zn(5), one Zn(6), one Zn(7), one Zn(8), one Zn(9), and two equivalent Zn(2) atoms to form distorted ZnPu3Zn9 cuboctahedra that share  a cornercorner with one Zn(10)Pu2Zn10 cuboctahedra,  a cornercorner with one Zn(5)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with five equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with six equivalent Zn(8)Pu3Zn9 cuboctahedra,  an edgeedge with one Zn(1)Pu2Zn10 cuboctahedra,  an edgeedge with one Zn(3)Pu2Zn10 cuboctahedra,  an edgeedge with one Zn(5)Pu2Zn10 cuboctahedra, edges with two equivalent Zn(7)Pu3Zn9 cuboctahedra, edges with three equivalent Zn(8)Pu3Zn9 cuboctahedra,  a faceface with one Zn(1)Pu2Zn10 cuboctahedra,  a faceface with one Zn(10)Pu2Zn10 cuboctahedra,  a faceface with one Zn(5)Pu2Zn10 cuboctahedra,  a faceface with one Zn(7)Pu3Zn9 cuboctahedra, faces with two equivalent Zn(3)Pu2Zn10 cuboctahedra, faces with three equivalent Zn(6)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(2)Pu2Zn10 cuboctahedra, and faces with five equivalent Zn(8)Pu3Zn9 cuboctahedra. In the tenth Zn site, Zn(9) is bonded in a 11-coordinate geometry to one Pu(2), one Pu(3), one Zn(2), two equivalent Zn(4), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(8) atoms. is represented by the CIF file [CIF]
data_Pu3Zn22
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.871
_cell_length_b   8.865
_cell_length_c   12.318
_cell_angle_alpha   111.077
_cell_angle_beta   111.111
_cell_angle_gamma   89.975
_symmetry_Int_Tables_number   1
_cell_volume   833.892
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.125  0.876  0.251  1.0
  Pu  Pu1  1  0.253  0.503  0.506  1.0
  Pu  Pu2  1  0.502  0.252  0.005  1.0
  Pu  Pu3  1  0.747  0.497  0.494  1.0
  Pu  Pu4  1  0.498  0.748  0.995  1.0
  Pu  Pu5  1  0.875  0.124  0.749  1.0
  Zn  Zn6  1  0.165  0.261  0.022  1.0
  Zn  Zn7  1  0.857  0.261  0.022  1.0
  Zn  Zn8  1  0.261  0.857  0.522  1.0
  Zn  Zn9  1  0.118  0.219  0.237  1.0
  Zn  Zn10  1  0.844  0.376  0.251  1.0
  Zn  Zn11  1  0.000  0.000  0.500  1.0
  Zn  Zn12  1  0.219  0.118  0.737  1.0
  Zn  Zn13  1  0.835  0.739  0.978  1.0
  Zn  Zn14  1  0.320  0.042  0.122  1.0
  Zn  Zn15  1  0.042  0.801  0.622  1.0
  Zn  Zn16  1  0.198  0.420  0.878  1.0
  Zn  Zn17  1  0.042  0.321  0.622  1.0
  Zn  Zn18  1  0.680  0.958  0.878  1.0
  Zn  Zn19  1  0.420  0.199  0.378  1.0
  Zn  Zn20  1  0.882  0.781  0.763  1.0
  Zn  Zn21  1  0.593  0.624  0.749  1.0
  Zn  Zn22  1  0.624  0.156  0.248  1.0
  Zn  Zn23  1  0.882  0.483  0.763  1.0
  Zn  Zn24  1  0.958  0.199  0.378  1.0
  Zn  Zn25  1  0.482  0.882  0.263  1.0
  Zn  Zn26  1  0.518  0.118  0.737  1.0
  Zn  Zn27  1  0.118  0.517  0.237  1.0
  Zn  Zn28  1  0.376  0.408  0.752  1.0
  Zn  Zn29  1  0.802  0.580  0.122  1.0
  Zn  Zn30  1  0.320  0.580  0.122  1.0
  Zn  Zn31  1  0.680  0.420  0.878  1.0
  Zn  Zn32  1  0.156  0.624  0.749  1.0
  Zn  Zn33  1  0.781  0.882  0.263  1.0
  Zn  Zn34  1  0.407  0.376  0.251  1.0
  Zn  Zn35  1  0.802  0.042  0.122  1.0
  Zn  Zn36  1  0.624  0.592  0.248  1.0
  Zn  Zn37  1  0.958  0.679  0.378  1.0
  Zn  Zn38  1  0.580  0.321  0.622  1.0
  Zn  Zn39  1  0.739  0.834  0.478  1.0
  Zn  Zn40  1  0.376  0.844  0.752  1.0
  Zn  Zn41  1  0.420  0.679  0.378  1.0
  Zn  Zn42  1  0.000  0.000  0.000  1.0
  Zn  Zn43  1  0.261  0.166  0.522  1.0
  Zn  Zn44  1  0.739  0.143  0.478  1.0
  Zn  Zn45  1  0.580  0.801  0.622  1.0
  Zn  Zn46  1  0.198  0.958  0.878  1.0
  Zn  Zn47  1  0.000  0.500  0.000  1.0
  Zn  Zn48  1  0.500  0.000  0.500  1.0
  Zn  Zn49  1  0.143  0.739  0.978  1.0
[/CIF]
.
The material described by Pu3Zn22 crystallizes in the orthorhombic Imma space group. There are three inequivalent Pu sites. In the first Pu site, Pu(1) is bonded in a 20-coordinate geometry to two equivalent Zn(1), two equivalent Zn(10), two equivalent Zn(2), two equivalent Zn(3), two equivalent Zn(5), two equivalent Zn(6), four equivalent Zn(7), and four equivalent Zn(8) atoms. In the second Pu site, Pu(2) is bonded in a 16-coordinate geometry to two equivalent Zn(2), two equivalent Zn(3), two equivalent Zn(4), two equivalent Zn(9), and eight equivalent Zn(8) atoms. In the third Pu site, Pu(3) is bonded in a 16-coordinate geometry to two equivalent Zn(1), two equivalent Zn(4), two equivalent Zn(6), two equivalent Zn(9), and eight equivalent Zn(7) atoms. There are ten inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one Pu(1), one Pu(3), one Zn(1), one Zn(4), two equivalent Zn(10), two equivalent Zn(3), and four equivalent Zn(7) atoms to form distorted ZnPu2Zn10 cuboctahedra that share corners with two equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(5)Pu2Zn10 cuboctahedra, corners with three equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with two equivalent Zn(8)Pu3Zn9 cuboctahedra,  a faceface with one Zn(6)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(10)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(8)Pu3Zn9 cuboctahedra, faces with three equivalent Zn(1)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(3)Pu2Zn10 cuboctahedra, and faces with eight equivalent Zn(7)Pu3Zn9 cuboctahedra. In the second Zn site, Zn(2) is bonded to one Pu(1), one Pu(2), one Zn(2), one Zn(9), two equivalent Zn(5), two equivalent Zn(6), and four equivalent Zn(8) atoms to form distorted ZnPu2Zn10 cuboctahedra that share corners with two equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(10)Pu2Zn10 cuboctahedra, corners with three equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with two equivalent Zn(7)Pu3Zn9 cuboctahedra,  a faceface with one Zn(3)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(5)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(7)Pu3Zn9 cuboctahedra, faces with three equivalent Zn(2)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(6)Pu2Zn10 cuboctahedra, and faces with eight equivalent Zn(8)Pu3Zn9 cuboctahedra. In the third Zn site, Zn(3) is bonded to one Pu(1), one Pu(2), one Zn(10), one Zn(3), two equivalent Zn(1), two equivalent Zn(4), two equivalent Zn(7), and two equivalent Zn(8) atoms to form distorted ZnPu2Zn10 cuboctahedra that share  a cornercorner with one Zn(10)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with two equivalent Zn(5)Pu2Zn10 cuboctahedra, edges with two equivalent Zn(8)Pu3Zn9 cuboctahedra,  a faceface with one Zn(2)Pu2Zn10 cuboctahedra,  a faceface with one Zn(3)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(10)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(6)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(1)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(8)Pu3Zn9 cuboctahedra, and faces with six equivalent Zn(7)Pu3Zn9 cuboctahedra. In the fourth Zn site, Zn(4) is bonded in a 11-coordinate geometry to one Pu(2), one Pu(3), one Zn(1), two equivalent Zn(3), two equivalent Zn(7), two equivalent Zn(8), and two equivalent Zn(9) atoms. In the fifth Zn site, Zn(5) is bonded to two equivalent Pu(1), two equivalent Zn(6), four equivalent Zn(2), and four equivalent Zn(8) atoms to form distorted ZnPu2Zn10 cuboctahedra that share corners with two equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(10)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with four equivalent Zn(3)Pu2Zn10 cuboctahedra, edges with four equivalent Zn(8)Pu3Zn9 cuboctahedra, faces with two equivalent Zn(5)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(2)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(6)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(7)Pu3Zn9 cuboctahedra, and faces with four equivalent Zn(8)Pu3Zn9 cuboctahedra. In the sixth Zn site, Zn(6) is bonded to one Pu(1), one Pu(3), one Zn(5), one Zn(6), two equivalent Zn(2), two equivalent Zn(7), two equivalent Zn(8), and two equivalent Zn(9) atoms to form distorted ZnPu2Zn10 cuboctahedra that share  a cornercorner with one Zn(5)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with two equivalent Zn(10)Pu2Zn10 cuboctahedra, edges with two equivalent Zn(7)Pu3Zn9 cuboctahedra,  a faceface with one Zn(1)Pu2Zn10 cuboctahedra,  a faceface with one Zn(6)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(3)Pu2Zn10 cuboctahedra, faces with two equivalent Zn(5)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(2)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(7)Pu3Zn9 cuboctahedra, and faces with six equivalent Zn(8)Pu3Zn9 cuboctahedra. In the seventh Zn site, Zn(10) is bonded to two equivalent Pu(1), two equivalent Zn(3), four equivalent Zn(1), and four equivalent Zn(7) atoms to form distorted ZnPu2Zn10 cuboctahedra that share corners with two equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(5)Pu2Zn10 cuboctahedra, corners with four equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with four equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with four equivalent Zn(6)Pu2Zn10 cuboctahedra, edges with four equivalent Zn(7)Pu3Zn9 cuboctahedra, faces with two equivalent Zn(10)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(1)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(3)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(7)Pu3Zn9 cuboctahedra, and faces with four equivalent Zn(8)Pu3Zn9 cuboctahedra. In the eighth Zn site, Zn(7) is bonded to one Pu(1), two equivalent Pu(3), one Zn(10), one Zn(3), one Zn(4), one Zn(6), one Zn(7), one Zn(8), one Zn(9), and two equivalent Zn(1) atoms to form distorted ZnPu3Zn9 cuboctahedra that share  a cornercorner with one Zn(10)Pu2Zn10 cuboctahedra,  a cornercorner with one Zn(5)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with five equivalent Zn(8)Pu3Zn9 cuboctahedra, corners with six equivalent Zn(7)Pu3Zn9 cuboctahedra,  an edgeedge with one Zn(10)Pu2Zn10 cuboctahedra,  an edgeedge with one Zn(2)Pu2Zn10 cuboctahedra,  an edgeedge with one Zn(6)Pu2Zn10 cuboctahedra, edges with two equivalent Zn(8)Pu3Zn9 cuboctahedra, edges with three equivalent Zn(7)Pu3Zn9 cuboctahedra,  a faceface with one Zn(10)Pu2Zn10 cuboctahedra,  a faceface with one Zn(2)Pu2Zn10 cuboctahedra,  a faceface with one Zn(5)Pu2Zn10 cuboctahedra,  a faceface with one Zn(8)Pu3Zn9 cuboctahedra, faces with two equivalent Zn(6)Pu2Zn10 cuboctahedra, faces with three equivalent Zn(3)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(1)Pu2Zn10 cuboctahedra, and faces with five equivalent Zn(7)Pu3Zn9 cuboctahedra. In the ninth Zn site, Zn(8) is bonded to one Pu(1), two equivalent Pu(2), one Zn(3), one Zn(4), one Zn(5), one Zn(6), one Zn(7), one Zn(8), one Zn(9), and two equivalent Zn(2) atoms to form distorted ZnPu3Zn9 cuboctahedra that share  a cornercorner with one Zn(10)Pu2Zn10 cuboctahedra,  a cornercorner with one Zn(5)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(1)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(2)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(3)Pu2Zn10 cuboctahedra, corners with two equivalent Zn(6)Pu2Zn10 cuboctahedra, corners with five equivalent Zn(7)Pu3Zn9 cuboctahedra, corners with six equivalent Zn(8)Pu3Zn9 cuboctahedra,  an edgeedge with one Zn(1)Pu2Zn10 cuboctahedra,  an edgeedge with one Zn(3)Pu2Zn10 cuboctahedra,  an edgeedge with one Zn(5)Pu2Zn10 cuboctahedra, edges with two equivalent Zn(7)Pu3Zn9 cuboctahedra, edges with three equivalent Zn(8)Pu3Zn9 cuboctahedra,  a faceface with one Zn(1)Pu2Zn10 cuboctahedra,  a faceface with one Zn(10)Pu2Zn10 cuboctahedra,  a faceface with one Zn(5)Pu2Zn10 cuboctahedra,  a faceface with one Zn(7)Pu3Zn9 cuboctahedra, faces with two equivalent Zn(3)Pu2Zn10 cuboctahedra, faces with three equivalent Zn(6)Pu2Zn10 cuboctahedra, faces with four equivalent Zn(2)Pu2Zn10 cuboctahedra, and faces with five equivalent Zn(8)Pu3Zn9 cuboctahedra. In the tenth Zn site, Zn(9) is bonded in a 11-coordinate geometry to one Pu(2), one Pu(3), one Zn(2), two equivalent Zn(4), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(8) atoms. is represented by the CIF file [CIF]
data_Pu3Zn22
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.871
_cell_length_b   8.865
_cell_length_c   12.318
_cell_angle_alpha   111.077
_cell_angle_beta   111.111
_cell_angle_gamma   89.975
_symmetry_Int_Tables_number   1
_cell_volume   833.892
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.125  0.876  0.251  1.0
  Pu  Pu1  1  0.253  0.503  0.506  1.0
  Pu  Pu2  1  0.502  0.252  0.005  1.0
  Pu  Pu3  1  0.747  0.497  0.494  1.0
  Pu  Pu4  1  0.498  0.748  0.995  1.0
  Pu  Pu5  1  0.875  0.124  0.749  1.0
  Zn  Zn6  1  0.165  0.261  0.022  1.0
  Zn  Zn7  1  0.857  0.261  0.022  1.0
  Zn  Zn8  1  0.261  0.857  0.522  1.0
  Zn  Zn9  1  0.118  0.219  0.237  1.0
  Zn  Zn10  1  0.844  0.376  0.251  1.0
  Zn  Zn11  1  0.000  0.000  0.500  1.0
  Zn  Zn12  1  0.219  0.118  0.737  1.0
  Zn  Zn13  1  0.835  0.739  0.978  1.0
  Zn  Zn14  1  0.320  0.042  0.122  1.0
  Zn  Zn15  1  0.042  0.801  0.622  1.0
  Zn  Zn16  1  0.198  0.420  0.878  1.0
  Zn  Zn17  1  0.042  0.321  0.622  1.0
  Zn  Zn18  1  0.680  0.958  0.878  1.0
  Zn  Zn19  1  0.420  0.199  0.378  1.0
  Zn  Zn20  1  0.882  0.781  0.763  1.0
  Zn  Zn21  1  0.593  0.624  0.749  1.0
  Zn  Zn22  1  0.624  0.156  0.248  1.0
  Zn  Zn23  1  0.882  0.483  0.763  1.0
  Zn  Zn24  1  0.958  0.199  0.378  1.0
  Zn  Zn25  1  0.482  0.882  0.263  1.0
  Zn  Zn26  1  0.518  0.118  0.737  1.0
  Zn  Zn27  1  0.118  0.517  0.237  1.0
  Zn  Zn28  1  0.376  0.408  0.752  1.0
  Zn  Zn29  1  0.802  0.580  0.122  1.0
  Zn  Zn30  1  0.320  0.580  0.122  1.0
  Zn  Zn31  1  0.680  0.420  0.878  1.0
  Zn  Zn32  1  0.156  0.624  0.749  1.0
  Zn  Zn33  1  0.781  0.882  0.263  1.0
  Zn  Zn34  1  0.407  0.376  0.251  1.0
  Zn  Zn35  1  0.802  0.042  0.122  1.0
  Zn  Zn36  1  0.624  0.592  0.248  1.0
  Zn  Zn37  1  0.958  0.679  0.378  1.0
  Zn  Zn38  1  0.580  0.321  0.622  1.0
  Zn  Zn39  1  0.739  0.834  0.478  1.0
  Zn  Zn40  1  0.376  0.844  0.752  1.0
  Zn  Zn41  1  0.420  0.679  0.378  1.0
  Zn  Zn42  1  0.000  0.000  0.000  1.0
  Zn  Zn43  1  0.261  0.166  0.522  1.0
  Zn  Zn44  1  0.739  0.143  0.478  1.0
  Zn  Zn45  1  0.580  0.801  0.622  1.0
  Zn  Zn46  1  0.198  0.958  0.878  1.0
  Zn  Zn47  1  0.000  0.500  0.000  1.0
  Zn  Zn48  1  0.500  0.000  0.500  1.0
  Zn  Zn49  1  0.143  0.739  0.978  1.0
[/CIF]
.