The crystal structure described by Mn2CuN2H6O5(NH2O)2H2O is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four hydroxylamine molecules, two water molecules, and two Mn2CuN2H6O5 clusters. In each Mn2CuN2H6O5 cluster, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 5-coordinate geometry to two equivalent N(1), two equivalent H(5), and one O(3) atom. In the second Mn site, Mn(2) is bonded in a distorted trigonal planar geometry to one O(5) and two equivalent O(4) atoms. Cu(1) is bonded in a linear geometry to one O(2) and one O(5) atom. N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(3), and one O(4) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(5) is bonded in a 2-coordinate geometry to one Mn(1) and one H(5) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one Cu(1) and two equivalent H(2) atoms. In the second O site, O(3) is bonded in a single-bond geometry to one Mn(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one N(1) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one Mn(2) and one Cu(1) atom. is represented by the CIF file [CIF]
data_Mn2CuH12(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.749
_cell_length_b   6.472
_cell_length_c   10.445
_cell_angle_alpha   87.617
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   793.493
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.250  0.302  0.671  1.0
  Mn  Mn1  1  0.750  0.698  0.329  1.0
  Mn  Mn2  1  0.250  0.392  0.026  1.0
  Mn  Mn3  1  0.750  0.608  0.974  1.0
  Cu  Cu4  1  0.250  0.250  0.299  1.0
  Cu  Cu5  1  0.750  0.750  0.701  1.0
  H  H6  1  0.922  0.346  0.306  1.0
  H  H7  1  0.422  0.654  0.694  1.0
  H  H8  1  0.078  0.654  0.694  1.0
  H  H9  1  0.578  0.346  0.306  1.0
  H  H10  1  0.683  0.056  0.555  1.0
  H  H11  1  0.183  0.944  0.445  1.0
  H  H12  1  0.317  0.944  0.445  1.0
  H  H13  1  0.817  0.056  0.555  1.0
  H  H14  1  0.052  0.256  0.753  1.0
  H  H15  1  0.552  0.744  0.247  1.0
  H  H16  1  0.948  0.744  0.247  1.0
  H  H17  1  0.448  0.256  0.753  1.0
  H  H18  1  0.184  0.786  0.922  1.0
  H  H19  1  0.684  0.214  0.078  1.0
  H  H20  1  0.816  0.214  0.078  1.0
  H  H21  1  0.316  0.786  0.922  1.0
  H  H22  1  0.284  0.028  0.648  1.0
  H  H23  1  0.784  0.972  0.352  1.0
  H  H24  1  0.716  0.972  0.352  1.0
  H  H25  1  0.216  0.028  0.648  1.0
  H  H26  1  0.050  0.200  0.299  1.0
  H  H27  1  0.550  0.800  0.701  1.0
  H  H28  1  0.950  0.800  0.701  1.0
  H  H29  1  0.450  0.200  0.299  1.0
  N  N30  1  0.870  0.694  0.215  1.0
  N  N31  1  0.370  0.306  0.785  1.0
  N  N32  1  0.130  0.306  0.785  1.0
  N  N33  1  0.630  0.694  0.215  1.0
  N  N34  1  0.536  0.209  0.322  1.0
  N  N35  1  0.036  0.791  0.678  1.0
  N  N36  1  0.464  0.791  0.678  1.0
  N  N37  1  0.964  0.209  0.322  1.0
  O  O38  1  0.076  0.925  0.594  1.0
  O  O39  1  0.576  0.075  0.406  1.0
  O  O40  1  0.924  0.075  0.406  1.0
  O  O41  1  0.424  0.925  0.594  1.0
  O  O42  1  0.750  0.011  0.607  1.0
  O  O43  1  0.250  0.989  0.393  1.0
  O  O44  1  0.750  0.542  0.455  1.0
  O  O45  1  0.250  0.458  0.545  1.0
  O  O46  1  0.882  0.614  0.101  1.0
  O  O47  1  0.382  0.386  0.899  1.0
  O  O48  1  0.118  0.386  0.899  1.0
  O  O49  1  0.618  0.614  0.101  1.0
  O  O50  1  0.250  0.472  0.196  1.0
  O  O51  1  0.750  0.528  0.804  1.0
  O  O52  1  0.250  0.851  0.881  1.0
  O  O53  1  0.750  0.149  0.119  1.0
[/CIF]
.
The crystal structure described by Mn2CuN2H6O5(NH2O)2H2O is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four hydroxylamine molecules, two water molecules, and two Mn2CuN2H6O5 clusters. In each Mn2CuN2H6O5 cluster, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 5-coordinate geometry to two equivalent N(1), two equivalent H(5), and one O(3) atom. In the second Mn site, Mn(2) is bonded in a distorted trigonal planar geometry to one O(5) and two equivalent O(4) atoms. Cu(1) is bonded in a linear geometry to one O(2) and one O(5) atom. N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(3), and one O(4) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(5) is bonded in a 2-coordinate geometry to one Mn(1) and one H(5) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one Cu(1) and two equivalent H(2) atoms. In the second O site, O(3) is bonded in a single-bond geometry to one Mn(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one N(1) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one Mn(2) and one Cu(1) atom. is represented by the CIF file [CIF]
data_Mn2CuH12(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.749
_cell_length_b   6.472
_cell_length_c   10.445
_cell_angle_alpha   87.617
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   793.493
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.250  0.302  0.671  1.0
  Mn  Mn1  1  0.750  0.698  0.329  1.0
  Mn  Mn2  1  0.250  0.392  0.026  1.0
  Mn  Mn3  1  0.750  0.608  0.974  1.0
  Cu  Cu4  1  0.250  0.250  0.299  1.0
  Cu  Cu5  1  0.750  0.750  0.701  1.0
  H  H6  1  0.922  0.346  0.306  1.0
  H  H7  1  0.422  0.654  0.694  1.0
  H  H8  1  0.078  0.654  0.694  1.0
  H  H9  1  0.578  0.346  0.306  1.0
  H  H10  1  0.683  0.056  0.555  1.0
  H  H11  1  0.183  0.944  0.445  1.0
  H  H12  1  0.317  0.944  0.445  1.0
  H  H13  1  0.817  0.056  0.555  1.0
  H  H14  1  0.052  0.256  0.753  1.0
  H  H15  1  0.552  0.744  0.247  1.0
  H  H16  1  0.948  0.744  0.247  1.0
  H  H17  1  0.448  0.256  0.753  1.0
  H  H18  1  0.184  0.786  0.922  1.0
  H  H19  1  0.684  0.214  0.078  1.0
  H  H20  1  0.816  0.214  0.078  1.0
  H  H21  1  0.316  0.786  0.922  1.0
  H  H22  1  0.284  0.028  0.648  1.0
  H  H23  1  0.784  0.972  0.352  1.0
  H  H24  1  0.716  0.972  0.352  1.0
  H  H25  1  0.216  0.028  0.648  1.0
  H  H26  1  0.050  0.200  0.299  1.0
  H  H27  1  0.550  0.800  0.701  1.0
  H  H28  1  0.950  0.800  0.701  1.0
  H  H29  1  0.450  0.200  0.299  1.0
  N  N30  1  0.870  0.694  0.215  1.0
  N  N31  1  0.370  0.306  0.785  1.0
  N  N32  1  0.130  0.306  0.785  1.0
  N  N33  1  0.630  0.694  0.215  1.0
  N  N34  1  0.536  0.209  0.322  1.0
  N  N35  1  0.036  0.791  0.678  1.0
  N  N36  1  0.464  0.791  0.678  1.0
  N  N37  1  0.964  0.209  0.322  1.0
  O  O38  1  0.076  0.925  0.594  1.0
  O  O39  1  0.576  0.075  0.406  1.0
  O  O40  1  0.924  0.075  0.406  1.0
  O  O41  1  0.424  0.925  0.594  1.0
  O  O42  1  0.750  0.011  0.607  1.0
  O  O43  1  0.250  0.989  0.393  1.0
  O  O44  1  0.750  0.542  0.455  1.0
  O  O45  1  0.250  0.458  0.545  1.0
  O  O46  1  0.882  0.614  0.101  1.0
  O  O47  1  0.382  0.386  0.899  1.0
  O  O48  1  0.118  0.386  0.899  1.0
  O  O49  1  0.618  0.614  0.101  1.0
  O  O50  1  0.250  0.472  0.196  1.0
  O  O51  1  0.750  0.528  0.804  1.0
  O  O52  1  0.250  0.851  0.881  1.0
  O  O53  1  0.750  0.149  0.119  1.0
[/CIF]
.