The structure described by Pt(NH3)4CuC4O9(H2O)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four water molecules, two CuC4O9 clusters, and two Pt(NH3)4 clusters. In each CuC4O9 cluster, Cu(1) is bonded in a square pyramidal geometry to one O(6), two equivalent O(1), and two equivalent O(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(2) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one Cu(1) atom. In each Pt(NH3)4 cluster, Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(3), and one H(7) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(2), one H(4), and one H(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuH16PtC4N4O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.206
_cell_length_b   9.206
_cell_length_c   7.462
_cell_angle_alpha   66.133
_cell_angle_beta   66.133
_cell_angle_gamma   44.530
_symmetry_Int_Tables_number   1
_cell_volume   398.826
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.532  0.468  0.500  1.0
  H  H1  1  0.823  0.377  0.015  1.0
  H  H2  1  0.379  0.823  0.784  1.0
  H  H3  1  0.623  0.177  0.985  1.0
  H  H4  1  0.177  0.621  0.216  1.0
  H  H5  1  0.778  0.390  0.812  1.0
  H  H6  1  0.391  0.778  0.019  1.0
  H  H7  1  0.610  0.222  0.188  1.0
  H  H8  1  0.222  0.609  0.981  1.0
  H  H9  1  0.783  0.821  0.799  1.0
  H  H10  1  0.819  0.784  0.595  1.0
  H  H11  1  0.179  0.217  0.201  1.0
  H  H12  1  0.216  0.181  0.405  1.0
  H  H13  1  0.008  0.305  0.811  1.0
  H  H14  1  0.304  0.008  0.877  1.0
  H  H15  1  0.695  0.992  0.189  1.0
  H  H16  1  0.992  0.696  0.123  1.0
  Pt  Pt17  1  0.001  0.999  0.000  1.0
  C  C18  1  0.330  0.329  0.567  1.0
  C  C19  1  0.326  0.333  0.774  1.0
  C  C20  1  0.671  0.670  0.433  1.0
  C  C21  1  0.667  0.674  0.226  1.0
  N  N22  1  0.889  0.302  0.899  1.0
  N  N23  1  0.303  0.889  0.909  1.0
  N  N24  1  0.698  0.111  0.101  1.0
  N  N25  1  0.111  0.697  0.091  1.0
  O  O26  1  0.403  0.408  0.415  1.0
  O  O27  1  0.406  0.404  0.775  1.0
  O  O28  1  0.592  0.597  0.585  1.0
  O  O29  1  0.596  0.594  0.225  1.0
  O  O30  1  0.854  0.826  0.661  1.0
  O  O31  1  0.174  0.146  0.339  1.0
  O  O32  1  0.262  0.255  0.559  1.0
  O  O33  1  0.246  0.270  0.924  1.0
  O  O34  1  0.745  0.738  0.441  1.0
  O  O35  1  0.730  0.754  0.076  1.0
  O  O36  1  0.800  0.200  0.500  1.0
[/CIF]
.
The structure described by Pt(NH3)4CuC4O9(H2O)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four water molecules, two CuC4O9 clusters, and two Pt(NH3)4 clusters. In each CuC4O9 cluster, Cu(1) is bonded in a square pyramidal geometry to one O(6), two equivalent O(1), and two equivalent O(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(2) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one Cu(1) atom. In each Pt(NH3)4 cluster, Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(3), and one H(7) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(2), one H(4), and one H(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuH16PtC4N4O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.206
_cell_length_b   9.206
_cell_length_c   7.462
_cell_angle_alpha   66.133
_cell_angle_beta   66.133
_cell_angle_gamma   44.530
_symmetry_Int_Tables_number   1
_cell_volume   398.826
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.532  0.468  0.500  1.0
  H  H1  1  0.823  0.377  0.015  1.0
  H  H2  1  0.379  0.823  0.784  1.0
  H  H3  1  0.623  0.177  0.985  1.0
  H  H4  1  0.177  0.621  0.216  1.0
  H  H5  1  0.778  0.390  0.812  1.0
  H  H6  1  0.391  0.778  0.019  1.0
  H  H7  1  0.610  0.222  0.188  1.0
  H  H8  1  0.222  0.609  0.981  1.0
  H  H9  1  0.783  0.821  0.799  1.0
  H  H10  1  0.819  0.784  0.595  1.0
  H  H11  1  0.179  0.217  0.201  1.0
  H  H12  1  0.216  0.181  0.405  1.0
  H  H13  1  0.008  0.305  0.811  1.0
  H  H14  1  0.304  0.008  0.877  1.0
  H  H15  1  0.695  0.992  0.189  1.0
  H  H16  1  0.992  0.696  0.123  1.0
  Pt  Pt17  1  0.001  0.999  0.000  1.0
  C  C18  1  0.330  0.329  0.567  1.0
  C  C19  1  0.326  0.333  0.774  1.0
  C  C20  1  0.671  0.670  0.433  1.0
  C  C21  1  0.667  0.674  0.226  1.0
  N  N22  1  0.889  0.302  0.899  1.0
  N  N23  1  0.303  0.889  0.909  1.0
  N  N24  1  0.698  0.111  0.101  1.0
  N  N25  1  0.111  0.697  0.091  1.0
  O  O26  1  0.403  0.408  0.415  1.0
  O  O27  1  0.406  0.404  0.775  1.0
  O  O28  1  0.592  0.597  0.585  1.0
  O  O29  1  0.596  0.594  0.225  1.0
  O  O30  1  0.854  0.826  0.661  1.0
  O  O31  1  0.174  0.146  0.339  1.0
  O  O32  1  0.262  0.255  0.559  1.0
  O  O33  1  0.246  0.270  0.924  1.0
  O  O34  1  0.745  0.738  0.441  1.0
  O  O35  1  0.730  0.754  0.076  1.0
  O  O36  1  0.800  0.200  0.500  1.0
[/CIF]
.