The crystal structure described by Pu3O2 is Corundum structured and crystallizes in the trigonal R-3c space group. Pu(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to six equivalent Pu(1) atoms to form a mixture of corner, edge, and face-sharing OPu6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pu3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.672
_cell_length_b   6.672
_cell_length_c   6.672
_cell_angle_alpha   55.152
_cell_angle_beta   55.152
_cell_angle_gamma   55.152
_symmetry_Int_Tables_number   1
_cell_volume   186.330
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.918  0.250  0.582  1.0
  Pu  Pu1  1  0.250  0.582  0.918  1.0
  Pu  Pu2  1  0.582  0.918  0.250  1.0
  Pu  Pu3  1  0.418  0.082  0.750  1.0
  Pu  Pu4  1  0.750  0.418  0.082  1.0
  Pu  Pu5  1  0.082  0.750  0.418  1.0
  O  O6  1  0.838  0.838  0.838  1.0
  O  O7  1  0.662  0.662  0.662  1.0
  O  O8  1  0.338  0.338  0.338  1.0
  O  O9  1  0.162  0.162  0.162  1.0
[/CIF]
.
The crystal structure described by Pu3O2 is Corundum structured and crystallizes in the trigonal R-3c space group. Pu(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to six equivalent Pu(1) atoms to form a mixture of corner, edge, and face-sharing OPu6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pu3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.672
_cell_length_b   6.672
_cell_length_c   6.672
_cell_angle_alpha   55.152
_cell_angle_beta   55.152
_cell_angle_gamma   55.152
_symmetry_Int_Tables_number   1
_cell_volume   186.330
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.918  0.250  0.582  1.0
  Pu  Pu1  1  0.250  0.582  0.918  1.0
  Pu  Pu2  1  0.582  0.918  0.250  1.0
  Pu  Pu3  1  0.418  0.082  0.750  1.0
  Pu  Pu4  1  0.750  0.418  0.082  1.0
  Pu  Pu5  1  0.082  0.750  0.418  1.0
  O  O6  1  0.838  0.838  0.838  1.0
  O  O7  1  0.662  0.662  0.662  1.0
  O  O8  1  0.338  0.338  0.338  1.0
  O  O9  1  0.162  0.162  0.162  1.0
[/CIF]
.