The material described by BP2N2Cl7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two BP2N2Cl7 clusters. B(1) is bonded to two equivalent N(1), one Cl(3), and one Cl(7) atom to form BN2Cl2 tetrahedra that share corners with two equivalent P(1)N2Cl2 tetrahedra and  an edgeedge with one B(1)N2Cl2 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one Cl(1), and one Cl(5) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(2)NCl3 tetrahedra and corners with two equivalent B(1)N2Cl2 tetrahedra. In the second P site, P(2) is bonded to one N(2), one Cl(2), one Cl(4), and one Cl(6) atom to form corner-sharing PNCl3 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted T-shaped geometry to two equivalent B(1) and one P(1) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one B(1) atom. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one P(1) atom. In the seventh Cl site, Cl(6) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF file [CIF]
data_BP2N2Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.652
_cell_length_b   9.980
_cell_length_c   15.826
_cell_angle_alpha   69.174
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1277.268
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.571  0.402  0.516  1.0
  B  B1  1  0.929  0.402  0.016  1.0
  B  B2  1  0.429  0.598  0.484  1.0
  B  B3  1  0.071  0.598  0.984  1.0
  P  P4  1  0.875  0.606  0.836  1.0
  P  P5  1  0.476  0.167  0.833  1.0
  P  P6  1  0.375  0.394  0.664  1.0
  P  P7  1  0.524  0.833  0.167  1.0
  P  P8  1  0.625  0.606  0.336  1.0
  P  P9  1  0.125  0.394  0.164  1.0
  P  P10  1  0.024  0.167  0.333  1.0
  P  P11  1  0.976  0.833  0.667  1.0
  N  N12  1  0.458  0.463  0.570  1.0
  N  N13  1  0.042  0.463  0.070  1.0
  N  N14  1  0.958  0.537  0.930  1.0
  N  N15  1  0.522  0.730  0.267  1.0
  N  N16  1  0.542  0.537  0.430  1.0
  N  N17  1  0.478  0.270  0.733  1.0
  N  N18  1  0.978  0.730  0.767  1.0
  N  N19  1  0.022  0.270  0.233  1.0
  Cl  Cl20  1  0.837  0.688  0.343  1.0
  Cl  Cl21  1  0.682  0.073  0.864  1.0
  Cl  Cl22  1  0.726  0.384  0.059  1.0
  Cl  Cl23  1  0.564  0.740  0.077  1.0
  Cl  Cl24  1  0.174  0.545  0.216  1.0
  Cl  Cl25  1  0.175  0.005  0.362  1.0
  Cl  Cl26  1  0.436  0.260  0.923  1.0
  Cl  Cl27  1  0.826  0.455  0.784  1.0
  Cl  Cl28  1  0.674  0.455  0.284  1.0
  Cl  Cl29  1  0.226  0.616  0.441  1.0
  Cl  Cl30  1  0.663  0.688  0.843  1.0
  Cl  Cl31  1  0.675  0.995  0.138  1.0
  Cl  Cl32  1  0.325  0.005  0.862  1.0
  Cl  Cl33  1  0.337  0.312  0.157  1.0
  Cl  Cl34  1  0.492  0.770  0.494  1.0
  Cl  Cl35  1  0.326  0.545  0.716  1.0
  Cl  Cl36  1  0.818  0.073  0.364  1.0
  Cl  Cl37  1  0.274  0.616  0.941  1.0
  Cl  Cl38  1  0.318  0.927  0.136  1.0
  Cl  Cl39  1  0.163  0.312  0.657  1.0
  Cl  Cl40  1  0.825  0.995  0.638  1.0
  Cl  Cl41  1  0.064  0.260  0.423  1.0
  Cl  Cl42  1  0.992  0.230  0.006  1.0
  Cl  Cl43  1  0.182  0.927  0.636  1.0
  Cl  Cl44  1  0.774  0.384  0.559  1.0
  Cl  Cl45  1  0.936  0.740  0.577  1.0
  Cl  Cl46  1  0.008  0.770  0.994  1.0
  Cl  Cl47  1  0.508  0.230  0.506  1.0
[/CIF]
.
The material described by BP2N2Cl7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two BP2N2Cl7 clusters. B(1) is bonded to two equivalent N(1), one Cl(3), and one Cl(7) atom to form BN2Cl2 tetrahedra that share corners with two equivalent P(1)N2Cl2 tetrahedra and  an edgeedge with one B(1)N2Cl2 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one Cl(1), and one Cl(5) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(2)NCl3 tetrahedra and corners with two equivalent B(1)N2Cl2 tetrahedra. In the second P site, P(2) is bonded to one N(2), one Cl(2), one Cl(4), and one Cl(6) atom to form corner-sharing PNCl3 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted T-shaped geometry to two equivalent B(1) and one P(1) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one B(1) atom. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one P(1) atom. In the seventh Cl site, Cl(6) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF file [CIF]
data_BP2N2Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.652
_cell_length_b   9.980
_cell_length_c   15.826
_cell_angle_alpha   69.174
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1277.268
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.571  0.402  0.516  1.0
  B  B1  1  0.929  0.402  0.016  1.0
  B  B2  1  0.429  0.598  0.484  1.0
  B  B3  1  0.071  0.598  0.984  1.0
  P  P4  1  0.875  0.606  0.836  1.0
  P  P5  1  0.476  0.167  0.833  1.0
  P  P6  1  0.375  0.394  0.664  1.0
  P  P7  1  0.524  0.833  0.167  1.0
  P  P8  1  0.625  0.606  0.336  1.0
  P  P9  1  0.125  0.394  0.164  1.0
  P  P10  1  0.024  0.167  0.333  1.0
  P  P11  1  0.976  0.833  0.667  1.0
  N  N12  1  0.458  0.463  0.570  1.0
  N  N13  1  0.042  0.463  0.070  1.0
  N  N14  1  0.958  0.537  0.930  1.0
  N  N15  1  0.522  0.730  0.267  1.0
  N  N16  1  0.542  0.537  0.430  1.0
  N  N17  1  0.478  0.270  0.733  1.0
  N  N18  1  0.978  0.730  0.767  1.0
  N  N19  1  0.022  0.270  0.233  1.0
  Cl  Cl20  1  0.837  0.688  0.343  1.0
  Cl  Cl21  1  0.682  0.073  0.864  1.0
  Cl  Cl22  1  0.726  0.384  0.059  1.0
  Cl  Cl23  1  0.564  0.740  0.077  1.0
  Cl  Cl24  1  0.174  0.545  0.216  1.0
  Cl  Cl25  1  0.175  0.005  0.362  1.0
  Cl  Cl26  1  0.436  0.260  0.923  1.0
  Cl  Cl27  1  0.826  0.455  0.784  1.0
  Cl  Cl28  1  0.674  0.455  0.284  1.0
  Cl  Cl29  1  0.226  0.616  0.441  1.0
  Cl  Cl30  1  0.663  0.688  0.843  1.0
  Cl  Cl31  1  0.675  0.995  0.138  1.0
  Cl  Cl32  1  0.325  0.005  0.862  1.0
  Cl  Cl33  1  0.337  0.312  0.157  1.0
  Cl  Cl34  1  0.492  0.770  0.494  1.0
  Cl  Cl35  1  0.326  0.545  0.716  1.0
  Cl  Cl36  1  0.818  0.073  0.364  1.0
  Cl  Cl37  1  0.274  0.616  0.941  1.0
  Cl  Cl38  1  0.318  0.927  0.136  1.0
  Cl  Cl39  1  0.163  0.312  0.657  1.0
  Cl  Cl40  1  0.825  0.995  0.638  1.0
  Cl  Cl41  1  0.064  0.260  0.423  1.0
  Cl  Cl42  1  0.992  0.230  0.006  1.0
  Cl  Cl43  1  0.182  0.927  0.636  1.0
  Cl  Cl44  1  0.774  0.384  0.559  1.0
  Cl  Cl45  1  0.936  0.740  0.577  1.0
  Cl  Cl46  1  0.008  0.770  0.994  1.0
  Cl  Cl47  1  0.508  0.230  0.506  1.0
[/CIF]
.