The compound described by MgP2H4(NO2)2(NH4)4(NP(OH)2)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four ammonium molecules, two phosphoramidous acid molecules, and one MgP2H4(NO2)2 cluster. In the MgP2H4(NO2)2 cluster, Mg(1) is bonded in a distorted water-like geometry to one N(4) and one H(5) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(5) atom. In the second P site, P(4) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one O(4), and one O(8) atom. There are two inequivalent N sites. In the first N site, N(4) is bonded in a 4-coordinate geometry to one Mg(1), one P(4), one H(4), and one H(8) atom. In the second N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(1), and one H(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one Mg(1) and one N(1) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one P(4) atom. In the third O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgP4H24(NO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.073
_cell_length_b   8.544
_cell_length_c   7.212
_cell_angle_alpha   92.683
_cell_angle_beta   115.441
_cell_angle_gamma   90.110
_symmetry_Int_Tables_number   1
_cell_volume   448.602
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.616  0.187  0.067  1.0
  P  P1  1  0.873  0.486  0.837  1.0
  P  P2  1  0.142  0.959  0.658  1.0
  P  P3  1  0.126  0.535  0.129  1.0
  P  P4  1  0.880  0.003  0.391  1.0
  H  H5  1  0.959  0.223  0.830  1.0
  H  H6  1  0.081  0.697  0.674  1.0
  H  H7  1  0.060  0.795  0.179  1.0
  H  H8  1  0.955  0.268  0.372  1.0
  H  H9  1  0.755  0.243  0.845  1.0
  H  H10  1  0.199  0.726  0.535  1.0
  H  H11  1  0.189  0.779  0.050  1.0
  H  H12  1  0.833  0.248  0.511  1.0
  H  H13  1  0.289  0.444  0.823  1.0
  H  H14  1  0.699  0.892  0.646  1.0
  H  H15  1  0.696  0.581  0.144  1.0
  H  H16  1  0.272  0.086  0.371  1.0
  H  H17  1  0.237  0.449  0.561  1.0
  H  H18  1  0.753  0.915  0.905  1.0
  H  H19  1  0.745  0.569  0.401  1.0
  H  H20  1  0.230  0.067  0.108  1.0
  H  H21  1  0.461  0.456  0.751  1.0
  H  H22  1  0.533  0.913  0.728  1.0
  H  H23  1  0.521  0.561  0.213  1.0
  H  H24  1  0.444  0.078  0.298  1.0
  H  H25  1  0.335  0.290  0.703  1.0
  H  H26  1  0.660  0.744  0.778  1.0
  H  H27  1  0.653  0.732  0.281  1.0
  H  H28  1  0.313  0.237  0.240  1.0
  N  N29  1  0.844  0.290  0.790  1.0
  N  N30  1  0.179  0.767  0.659  1.0
  N  N31  1  0.160  0.730  0.160  1.0
  N  N32  1  0.857  0.202  0.390  1.0
  N  N33  1  0.328  0.411  0.707  1.0
  N  N34  1  0.661  0.865  0.762  1.0
  N  N35  1  0.653  0.610  0.258  1.0
  N  N36  1  0.313  0.117  0.255  1.0
  O  O37  1  0.906  0.555  0.664  1.0
  O  O38  1  0.117  0.011  0.849  1.0
  O  O39  1  0.092  0.476  0.306  1.0
  O  O40  1  0.894  0.955  0.192  1.0
  O  O41  1  0.704  0.546  0.863  1.0
  O  O42  1  0.286  0.041  0.608  1.0
  O  O43  1  0.287  0.464  0.096  1.0
  O  O44  1  0.711  0.939  0.412  1.0
[/CIF]
.
The compound described by MgP2H4(NO2)2(NH4)4(NP(OH)2)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four ammonium molecules, two phosphoramidous acid molecules, and one MgP2H4(NO2)2 cluster. In the MgP2H4(NO2)2 cluster, Mg(1) is bonded in a distorted water-like geometry to one N(4) and one H(5) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(5) atom. In the second P site, P(4) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one O(4), and one O(8) atom. There are two inequivalent N sites. In the first N site, N(4) is bonded in a 4-coordinate geometry to one Mg(1), one P(4), one H(4), and one H(8) atom. In the second N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(1), and one H(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one Mg(1) and one N(1) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one P(4) atom. In the third O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgP4H24(NO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.073
_cell_length_b   8.544
_cell_length_c   7.212
_cell_angle_alpha   92.683
_cell_angle_beta   115.441
_cell_angle_gamma   90.110
_symmetry_Int_Tables_number   1
_cell_volume   448.602
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.616  0.187  0.067  1.0
  P  P1  1  0.873  0.486  0.837  1.0
  P  P2  1  0.142  0.959  0.658  1.0
  P  P3  1  0.126  0.535  0.129  1.0
  P  P4  1  0.880  0.003  0.391  1.0
  H  H5  1  0.959  0.223  0.830  1.0
  H  H6  1  0.081  0.697  0.674  1.0
  H  H7  1  0.060  0.795  0.179  1.0
  H  H8  1  0.955  0.268  0.372  1.0
  H  H9  1  0.755  0.243  0.845  1.0
  H  H10  1  0.199  0.726  0.535  1.0
  H  H11  1  0.189  0.779  0.050  1.0
  H  H12  1  0.833  0.248  0.511  1.0
  H  H13  1  0.289  0.444  0.823  1.0
  H  H14  1  0.699  0.892  0.646  1.0
  H  H15  1  0.696  0.581  0.144  1.0
  H  H16  1  0.272  0.086  0.371  1.0
  H  H17  1  0.237  0.449  0.561  1.0
  H  H18  1  0.753  0.915  0.905  1.0
  H  H19  1  0.745  0.569  0.401  1.0
  H  H20  1  0.230  0.067  0.108  1.0
  H  H21  1  0.461  0.456  0.751  1.0
  H  H22  1  0.533  0.913  0.728  1.0
  H  H23  1  0.521  0.561  0.213  1.0
  H  H24  1  0.444  0.078  0.298  1.0
  H  H25  1  0.335  0.290  0.703  1.0
  H  H26  1  0.660  0.744  0.778  1.0
  H  H27  1  0.653  0.732  0.281  1.0
  H  H28  1  0.313  0.237  0.240  1.0
  N  N29  1  0.844  0.290  0.790  1.0
  N  N30  1  0.179  0.767  0.659  1.0
  N  N31  1  0.160  0.730  0.160  1.0
  N  N32  1  0.857  0.202  0.390  1.0
  N  N33  1  0.328  0.411  0.707  1.0
  N  N34  1  0.661  0.865  0.762  1.0
  N  N35  1  0.653  0.610  0.258  1.0
  N  N36  1  0.313  0.117  0.255  1.0
  O  O37  1  0.906  0.555  0.664  1.0
  O  O38  1  0.117  0.011  0.849  1.0
  O  O39  1  0.092  0.476  0.306  1.0
  O  O40  1  0.894  0.955  0.192  1.0
  O  O41  1  0.704  0.546  0.863  1.0
  O  O42  1  0.286  0.041  0.608  1.0
  O  O43  1  0.287  0.464  0.096  1.0
  O  O44  1  0.711  0.939  0.412  1.0
[/CIF]
.