The compound described by C(NS)2AsF6SF5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2h-1,3,2,4-dithiadiazole molecules; two AsF6 clusters; and two SF5 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(11), one F(2), one F(3), one F(4), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In each SF5 cluster, S(1) is bonded in a square pyramidal geometry to one F(10), one F(5), one F(6), one F(8), and one F(9) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(8) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth F site, F(10) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_AsCS3N2F11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.319
_cell_length_b   7.221
_cell_length_c   13.374
_cell_angle_alpha   95.600
_cell_angle_beta   96.667
_cell_angle_gamma   104.087
_symmetry_Int_Tables_number   1
_cell_volume   582.890
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.483  0.757  0.830  1.0
  As  As1  1  0.517  0.243  0.170  1.0
  C  C2  1  0.072  0.759  0.271  1.0
  C  C3  1  0.928  0.241  0.729  1.0
  S  S4  1  0.187  0.749  0.403  1.0
  S  S5  1  0.813  0.251  0.597  1.0
  S  S6  1  0.874  0.854  0.126  1.0
  S  S7  1  0.881  0.390  0.831  1.0
  S  S8  1  0.126  0.146  0.874  1.0
  S  S9  1  0.119  0.610  0.169  1.0
  N  N10  1  0.984  0.691  0.083  1.0
  N  N11  1  0.048  0.125  0.753  1.0
  N  N12  1  0.016  0.309  0.917  1.0
  N  N13  1  0.952  0.875  0.247  1.0
  F  F14  1  0.255  0.209  0.094  1.0
  F  F15  1  0.359  0.760  0.942  1.0
  F  F16  1  0.528  0.012  0.837  1.0
  F  F17  1  0.222  0.725  0.757  1.0
  F  F18  1  0.171  0.524  0.373  1.0
  F  F19  1  0.941  0.695  0.433  1.0
  F  F20  1  0.745  0.791  0.906  1.0
  F  F21  1  0.472  0.988  0.163  1.0
  F  F22  1  0.389  0.247  0.279  1.0
  F  F23  1  0.794  0.026  0.567  1.0
  F  F24  1  0.778  0.275  0.243  1.0
  F  F25  1  0.568  0.198  0.628  1.0
  F  F26  1  0.829  0.476  0.627  1.0
  F  F27  1  0.287  0.737  0.516  1.0
  F  F28  1  0.641  0.240  0.058  1.0
  F  F29  1  0.432  0.802  0.372  1.0
  F  F30  1  0.560  0.498  0.176  1.0
  F  F31  1  0.611  0.753  0.721  1.0
  F  F32  1  0.206  0.974  0.433  1.0
  F  F33  1  0.713  0.263  0.484  1.0
  F  F34  1  0.440  0.502  0.824  1.0
  F  F35  1  0.059  0.305  0.567  1.0
[/CIF]
.
The compound described by C(NS)2AsF6SF5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2h-1,3,2,4-dithiadiazole molecules; two AsF6 clusters; and two SF5 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(11), one F(2), one F(3), one F(4), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In each SF5 cluster, S(1) is bonded in a square pyramidal geometry to one F(10), one F(5), one F(6), one F(8), and one F(9) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(8) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth F site, F(10) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_AsCS3N2F11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.319
_cell_length_b   7.221
_cell_length_c   13.374
_cell_angle_alpha   95.600
_cell_angle_beta   96.667
_cell_angle_gamma   104.087
_symmetry_Int_Tables_number   1
_cell_volume   582.890
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.483  0.757  0.830  1.0
  As  As1  1  0.517  0.243  0.170  1.0
  C  C2  1  0.072  0.759  0.271  1.0
  C  C3  1  0.928  0.241  0.729  1.0
  S  S4  1  0.187  0.749  0.403  1.0
  S  S5  1  0.813  0.251  0.597  1.0
  S  S6  1  0.874  0.854  0.126  1.0
  S  S7  1  0.881  0.390  0.831  1.0
  S  S8  1  0.126  0.146  0.874  1.0
  S  S9  1  0.119  0.610  0.169  1.0
  N  N10  1  0.984  0.691  0.083  1.0
  N  N11  1  0.048  0.125  0.753  1.0
  N  N12  1  0.016  0.309  0.917  1.0
  N  N13  1  0.952  0.875  0.247  1.0
  F  F14  1  0.255  0.209  0.094  1.0
  F  F15  1  0.359  0.760  0.942  1.0
  F  F16  1  0.528  0.012  0.837  1.0
  F  F17  1  0.222  0.725  0.757  1.0
  F  F18  1  0.171  0.524  0.373  1.0
  F  F19  1  0.941  0.695  0.433  1.0
  F  F20  1  0.745  0.791  0.906  1.0
  F  F21  1  0.472  0.988  0.163  1.0
  F  F22  1  0.389  0.247  0.279  1.0
  F  F23  1  0.794  0.026  0.567  1.0
  F  F24  1  0.778  0.275  0.243  1.0
  F  F25  1  0.568  0.198  0.628  1.0
  F  F26  1  0.829  0.476  0.627  1.0
  F  F27  1  0.287  0.737  0.516  1.0
  F  F28  1  0.641  0.240  0.058  1.0
  F  F29  1  0.432  0.802  0.372  1.0
  F  F30  1  0.560  0.498  0.176  1.0
  F  F31  1  0.611  0.753  0.721  1.0
  F  F32  1  0.206  0.974  0.433  1.0
  F  F33  1  0.713  0.263  0.484  1.0
  F  F34  1  0.440  0.502  0.824  1.0
  F  F35  1  0.059  0.305  0.567  1.0
[/CIF]
.