The crystal structure described by Li4V3Mn3(TeO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with three equivalent Te(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-68°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(5), one O(7), and two equivalent O(11) atoms. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(4), one O(8), and two equivalent O(1) atoms. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Te(1)O6 octahedra, and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-74°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. In the second V site, V(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form distorted TeO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form distorted TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one Mn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent V(1), and one Te(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent V(1), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), two equivalent V(1), and one Mn(1) atom to form edge-sharing OLiMnV2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(2), and two equivalent Mn(2) atoms to form OLiMn2V tetrahedra that share  a cornercorner with one O(7)LiV2Te tetrahedra and corners with two equivalent O(12)LiMn2Te tetrahedra. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(4), one V(1), one Mn(1), and one Te(1) atom. In the seventh O site, O(7) is bonded to one Li(2), two equivalent V(1), and one Te(2) atom to form distorted OLiV2Te tetrahedra that share  a cornercorner with one O(12)LiMn2Te tetrahedra,  a cornercorner with one O(5)LiMn2V tetrahedra, and  an edgeedge with one O(4)LiMnV2 tetrahedra. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Mn(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one Mn(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), and two equivalent Mn(2) atoms. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Mn(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded to one Li(1), two equivalent Mn(2), and one Te(2) atom to form OLiMn2Te tetrahedra that share  a cornercorner with one O(7)LiV2Te tetrahedra and corners with two equivalent O(5)LiMn2V tetrahedra. is represented by the CIF card [CIF]
data_Li4Mn3V3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.067
_cell_length_b   6.067
_cell_length_c   10.224
_cell_angle_alpha   89.401
_cell_angle_beta   89.401
_cell_angle_gamma   57.698
_symmetry_Int_Tables_number   1
_cell_volume   318.054
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.342  0.342  0.905  1.0
  Li  Li1  1  0.994  0.994  0.989  1.0
  Li  Li2  1  0.995  0.995  0.491  1.0
  Li  Li3  1  0.667  0.667  0.401  1.0
  Mn  Mn4  1  0.165  0.165  0.215  1.0
  Mn  Mn5  1  0.831  0.337  0.713  1.0
  Mn  Mn6  1  0.337  0.831  0.713  1.0
  V  V7  1  0.648  0.167  0.219  1.0
  V  V8  1  0.167  0.648  0.219  1.0
  V  V9  1  0.825  0.825  0.731  1.0
  Te  Te10  1  0.331  0.331  0.503  1.0
  Te  Te11  1  0.656  0.656  0.996  1.0
  O  O12  1  0.667  0.161  0.599  1.0
  O  O13  1  0.484  0.484  0.331  1.0
  O  O14  1  0.340  0.340  0.107  1.0
  O  O15  1  0.995  0.995  0.306  1.0
  O  O16  1  0.991  0.991  0.801  1.0
  O  O17  1  0.161  0.667  0.599  1.0
  O  O18  1  0.501  0.025  0.320  1.0
  O  O19  1  0.025  0.501  0.320  1.0
  O  O20  1  0.854  0.854  0.113  1.0
  O  O21  1  0.157  0.157  0.597  1.0
  O  O22  1  0.984  0.532  0.831  1.0
  O  O23  1  0.532  0.984  0.831  1.0
  O  O24  1  0.678  0.678  0.616  1.0
  O  O25  1  0.827  0.321  0.095  1.0
  O  O26  1  0.525  0.525  0.852  1.0
  O  O27  1  0.321  0.827  0.095  1.0
[/CIF]
.
The crystal structure described by Li4V3Mn3(TeO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with three equivalent Te(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-68°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(5), one O(7), and two equivalent O(11) atoms. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(4), one O(8), and two equivalent O(1) atoms. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Te(1)O6 octahedra, and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-74°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. In the second V site, V(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form distorted TeO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form distorted TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one Mn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent V(1), and one Te(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent V(1), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), two equivalent V(1), and one Mn(1) atom to form edge-sharing OLiMnV2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(2), and two equivalent Mn(2) atoms to form OLiMn2V tetrahedra that share  a cornercorner with one O(7)LiV2Te tetrahedra and corners with two equivalent O(12)LiMn2Te tetrahedra. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(4), one V(1), one Mn(1), and one Te(1) atom. In the seventh O site, O(7) is bonded to one Li(2), two equivalent V(1), and one Te(2) atom to form distorted OLiV2Te tetrahedra that share  a cornercorner with one O(12)LiMn2Te tetrahedra,  a cornercorner with one O(5)LiMn2V tetrahedra, and  an edgeedge with one O(4)LiMnV2 tetrahedra. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Mn(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one Mn(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), and two equivalent Mn(2) atoms. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Mn(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded to one Li(1), two equivalent Mn(2), and one Te(2) atom to form OLiMn2Te tetrahedra that share  a cornercorner with one O(7)LiV2Te tetrahedra and corners with two equivalent O(5)LiMn2V tetrahedra. is represented by the CIF card [CIF]
data_Li4Mn3V3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.067
_cell_length_b   6.067
_cell_length_c   10.224
_cell_angle_alpha   89.401
_cell_angle_beta   89.401
_cell_angle_gamma   57.698
_symmetry_Int_Tables_number   1
_cell_volume   318.054
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.342  0.342  0.905  1.0
  Li  Li1  1  0.994  0.994  0.989  1.0
  Li  Li2  1  0.995  0.995  0.491  1.0
  Li  Li3  1  0.667  0.667  0.401  1.0
  Mn  Mn4  1  0.165  0.165  0.215  1.0
  Mn  Mn5  1  0.831  0.337  0.713  1.0
  Mn  Mn6  1  0.337  0.831  0.713  1.0
  V  V7  1  0.648  0.167  0.219  1.0
  V  V8  1  0.167  0.648  0.219  1.0
  V  V9  1  0.825  0.825  0.731  1.0
  Te  Te10  1  0.331  0.331  0.503  1.0
  Te  Te11  1  0.656  0.656  0.996  1.0
  O  O12  1  0.667  0.161  0.599  1.0
  O  O13  1  0.484  0.484  0.331  1.0
  O  O14  1  0.340  0.340  0.107  1.0
  O  O15  1  0.995  0.995  0.306  1.0
  O  O16  1  0.991  0.991  0.801  1.0
  O  O17  1  0.161  0.667  0.599  1.0
  O  O18  1  0.501  0.025  0.320  1.0
  O  O19  1  0.025  0.501  0.320  1.0
  O  O20  1  0.854  0.854  0.113  1.0
  O  O21  1  0.157  0.157  0.597  1.0
  O  O22  1  0.984  0.532  0.831  1.0
  O  O23  1  0.532  0.984  0.831  1.0
  O  O24  1  0.678  0.678  0.616  1.0
  O  O25  1  0.827  0.321  0.095  1.0
  O  O26  1  0.525  0.525  0.852  1.0
  O  O27  1  0.321  0.827  0.095  1.0
[/CIF]
.