The compound described by Na3VSO3 crystallizes in the trigonal R3c space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent O(1) atoms. V(1) is bonded in a distorted tetrahedral geometry to one S(1) and three equivalent O(1) atoms. S(1) is bonded in a 7-coordinate geometry to six equivalent Na(1) and one V(1) atom. O(1) is bonded to four equivalent Na(1) and one V(1) atom to form a mixture of distorted edge and corner-sharing ONa4V trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3VSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.484
_cell_length_b   6.484
_cell_length_c   6.484
_cell_angle_alpha   83.847
_cell_angle_beta   83.847
_cell_angle_gamma   83.847
_symmetry_Int_Tables_number   1
_cell_volume   268.240
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.094  0.707  0.397  1.0
  Na  Na1  1  0.207  0.594  0.897  1.0
  Na  Na2  1  0.897  0.207  0.594  1.0
  Na  Na3  1  0.707  0.397  0.094  1.0
  Na  Na4  1  0.397  0.094  0.707  1.0
  Na  Na5  1  0.594  0.897  0.207  1.0
  V  V6  1  0.682  0.682  0.682  1.0
  V  V7  1  0.182  0.182  0.182  1.0
  S  S8  1  0.500  0.500  0.500  1.0
  S  S9  1  1.000  1.000  1.000  1.0
  O  O10  1  0.916  0.537  0.722  1.0
  O  O11  1  0.537  0.722  0.916  1.0
  O  O12  1  0.722  0.916  0.537  1.0
  O  O13  1  0.416  0.222  0.037  1.0
  O  O14  1  0.037  0.416  0.222  1.0
  O  O15  1  0.222  0.037  0.416  1.0
[/CIF]
.
The compound described by Na3VSO3 crystallizes in the trigonal R3c space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent O(1) atoms. V(1) is bonded in a distorted tetrahedral geometry to one S(1) and three equivalent O(1) atoms. S(1) is bonded in a 7-coordinate geometry to six equivalent Na(1) and one V(1) atom. O(1) is bonded to four equivalent Na(1) and one V(1) atom to form a mixture of distorted edge and corner-sharing ONa4V trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3VSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.484
_cell_length_b   6.484
_cell_length_c   6.484
_cell_angle_alpha   83.847
_cell_angle_beta   83.847
_cell_angle_gamma   83.847
_symmetry_Int_Tables_number   1
_cell_volume   268.240
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.094  0.707  0.397  1.0
  Na  Na1  1  0.207  0.594  0.897  1.0
  Na  Na2  1  0.897  0.207  0.594  1.0
  Na  Na3  1  0.707  0.397  0.094  1.0
  Na  Na4  1  0.397  0.094  0.707  1.0
  Na  Na5  1  0.594  0.897  0.207  1.0
  V  V6  1  0.682  0.682  0.682  1.0
  V  V7  1  0.182  0.182  0.182  1.0
  S  S8  1  0.500  0.500  0.500  1.0
  S  S9  1  1.000  1.000  1.000  1.0
  O  O10  1  0.916  0.537  0.722  1.0
  O  O11  1  0.537  0.722  0.916  1.0
  O  O12  1  0.722  0.916  0.537  1.0
  O  O13  1  0.416  0.222  0.037  1.0
  O  O14  1  0.037  0.416  0.222  1.0
  O  O15  1  0.222  0.037  0.416  1.0
[/CIF]
.