The compound described by Zn(WO2)2 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form WO4 tetrahedra that share corners with six equivalent W(2)O6 octahedra and corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-67°. In the second W site, W(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent W(1)O4 tetrahedra, edges with two equivalent W(2)O6 octahedra, and edges with four equivalent Zn(1)O6 octahedra. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent W(1)O4 tetrahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent W(2)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one W(1), one W(2), and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one W(1), two equivalent W(2), and one Zn(1) atom. is represented by the CIF file [CIF]
data_Zn(WO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.355
_cell_length_b   6.355
_cell_length_c   6.355
_cell_angle_alpha   120.895
_cell_angle_beta   117.361
_cell_angle_gamma   91.543
_symmetry_Int_Tables_number   1
_cell_volume   183.608
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.500  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  W  W2  1  0.098  0.848  0.250  1.0
  W  W3  1  0.902  0.152  0.750  1.0
  W  W4  1  0.500  0.000  0.000  1.0
  W  W5  1  0.500  0.500  0.500  1.0
  O  O6  1  0.746  0.258  0.012  1.0
  O  O7  1  0.733  0.259  0.475  1.0
  O  O8  1  0.746  0.734  0.488  1.0
  O  O9  1  0.284  0.259  0.025  1.0
  O  O10  1  0.716  0.741  0.975  1.0
  O  O11  1  0.267  0.741  0.525  1.0
  O  O12  1  0.254  0.266  0.512  1.0
  O  O13  1  0.254  0.742  0.988  1.0
[/CIF]
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The compound described by Zn(WO2)2 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form WO4 tetrahedra that share corners with six equivalent W(2)O6 octahedra and corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-67°. In the second W site, W(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent W(1)O4 tetrahedra, edges with two equivalent W(2)O6 octahedra, and edges with four equivalent Zn(1)O6 octahedra. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent W(1)O4 tetrahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent W(2)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one W(1), one W(2), and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one W(1), two equivalent W(2), and one Zn(1) atom. is represented by the CIF file [CIF]
data_Zn(WO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.355
_cell_length_b   6.355
_cell_length_c   6.355
_cell_angle_alpha   120.895
_cell_angle_beta   117.361
_cell_angle_gamma   91.543
_symmetry_Int_Tables_number   1
_cell_volume   183.608
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.500  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  W  W2  1  0.098  0.848  0.250  1.0
  W  W3  1  0.902  0.152  0.750  1.0
  W  W4  1  0.500  0.000  0.000  1.0
  W  W5  1  0.500  0.500  0.500  1.0
  O  O6  1  0.746  0.258  0.012  1.0
  O  O7  1  0.733  0.259  0.475  1.0
  O  O8  1  0.746  0.734  0.488  1.0
  O  O9  1  0.284  0.259  0.025  1.0
  O  O10  1  0.716  0.741  0.975  1.0
  O  O11  1  0.267  0.741  0.525  1.0
  O  O12  1  0.254  0.266  0.512  1.0
  O  O13  1  0.254  0.742  0.988  1.0
[/CIF]
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