The compound described by RbY(SeO3)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. Y(1) is bonded in an octahedral geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one O(2) and two equivalent O(1) atoms. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one Se(2) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Rb(1), one Y(1), and one Se(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Y(1), and one Se(1) atom. In the fourth O site, O(3) is bonded to two equivalent Rb(1), one Y(1), and one Se(2) atom to form a mixture of distorted corner and edge-sharing ORb2YSe tetrahedra. is represented by the CIF file [CIF]
data_RbY(SeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.862
_cell_length_b   8.950
_cell_length_c   14.028
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   735.955
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.992  0.627  1.0
  Rb  Rb1  1  0.250  0.508  0.127  1.0
  Rb  Rb2  1  0.750  0.008  0.373  1.0
  Rb  Rb3  1  0.750  0.492  0.873  1.0
  Y  Y4  1  0.250  0.811  0.899  1.0
  Y  Y5  1  0.250  0.689  0.399  1.0
  Y  Y6  1  0.750  0.189  0.101  1.0
  Y  Y7  1  0.750  0.311  0.601  1.0
  Se  Se8  1  0.750  0.018  0.797  1.0
  Se  Se9  1  0.750  0.482  0.297  1.0
  Se  Se10  1  0.250  0.982  0.203  1.0
  Se  Se11  1  0.250  0.518  0.703  1.0
  Se  Se12  1  0.750  0.715  0.562  1.0
  Se  Se13  1  0.750  0.785  0.062  1.0
  Se  Se14  1  0.250  0.285  0.438  1.0
  Se  Se15  1  0.250  0.215  0.938  1.0
  O  O16  1  0.979  0.897  0.795  1.0
  O  O17  1  0.521  0.603  0.295  1.0
  O  O18  1  0.479  0.103  0.205  1.0
  O  O19  1  0.021  0.397  0.705  1.0
  O  O20  1  0.021  0.103  0.205  1.0
  O  O21  1  0.479  0.397  0.705  1.0
  O  O22  1  0.521  0.897  0.795  1.0
  O  O23  1  0.979  0.603  0.295  1.0
  O  O24  1  0.750  0.085  0.681  1.0
  O  O25  1  0.750  0.415  0.181  1.0
  O  O26  1  0.250  0.915  0.319  1.0
  O  O27  1  0.250  0.585  0.819  1.0
  O  O28  1  0.980  0.788  0.500  1.0
  O  O29  1  0.520  0.712  1.000  1.0
  O  O30  1  0.480  0.212  0.500  1.0
  O  O31  1  0.020  0.288  0.000  1.0
  O  O32  1  0.020  0.212  0.500  1.0
  O  O33  1  0.480  0.288  0.000  1.0
  O  O34  1  0.520  0.788  0.500  1.0
  O  O35  1  0.980  0.712  1.000  1.0
  O  O36  1  0.750  0.532  0.526  1.0
  O  O37  1  0.750  0.968  0.026  1.0
  O  O38  1  0.250  0.468  0.474  1.0
  O  O39  1  0.250  0.032  0.974  1.0
[/CIF]
.
The compound described by RbY(SeO3)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. Y(1) is bonded in an octahedral geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one O(2) and two equivalent O(1) atoms. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one Se(2) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Rb(1), one Y(1), and one Se(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Y(1), and one Se(1) atom. In the fourth O site, O(3) is bonded to two equivalent Rb(1), one Y(1), and one Se(2) atom to form a mixture of distorted corner and edge-sharing ORb2YSe tetrahedra. is represented by the CIF file [CIF]
data_RbY(SeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.862
_cell_length_b   8.950
_cell_length_c   14.028
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   735.955
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.992  0.627  1.0
  Rb  Rb1  1  0.250  0.508  0.127  1.0
  Rb  Rb2  1  0.750  0.008  0.373  1.0
  Rb  Rb3  1  0.750  0.492  0.873  1.0
  Y  Y4  1  0.250  0.811  0.899  1.0
  Y  Y5  1  0.250  0.689  0.399  1.0
  Y  Y6  1  0.750  0.189  0.101  1.0
  Y  Y7  1  0.750  0.311  0.601  1.0
  Se  Se8  1  0.750  0.018  0.797  1.0
  Se  Se9  1  0.750  0.482  0.297  1.0
  Se  Se10  1  0.250  0.982  0.203  1.0
  Se  Se11  1  0.250  0.518  0.703  1.0
  Se  Se12  1  0.750  0.715  0.562  1.0
  Se  Se13  1  0.750  0.785  0.062  1.0
  Se  Se14  1  0.250  0.285  0.438  1.0
  Se  Se15  1  0.250  0.215  0.938  1.0
  O  O16  1  0.979  0.897  0.795  1.0
  O  O17  1  0.521  0.603  0.295  1.0
  O  O18  1  0.479  0.103  0.205  1.0
  O  O19  1  0.021  0.397  0.705  1.0
  O  O20  1  0.021  0.103  0.205  1.0
  O  O21  1  0.479  0.397  0.705  1.0
  O  O22  1  0.521  0.897  0.795  1.0
  O  O23  1  0.979  0.603  0.295  1.0
  O  O24  1  0.750  0.085  0.681  1.0
  O  O25  1  0.750  0.415  0.181  1.0
  O  O26  1  0.250  0.915  0.319  1.0
  O  O27  1  0.250  0.585  0.819  1.0
  O  O28  1  0.980  0.788  0.500  1.0
  O  O29  1  0.520  0.712  1.000  1.0
  O  O30  1  0.480  0.212  0.500  1.0
  O  O31  1  0.020  0.288  0.000  1.0
  O  O32  1  0.020  0.212  0.500  1.0
  O  O33  1  0.480  0.288  0.000  1.0
  O  O34  1  0.520  0.788  0.500  1.0
  O  O35  1  0.980  0.712  1.000  1.0
  O  O36  1  0.750  0.532  0.526  1.0
  O  O37  1  0.750  0.968  0.026  1.0
  O  O38  1  0.250  0.468  0.474  1.0
  O  O39  1  0.250  0.032  0.974  1.0
[/CIF]
.