The material described by P4SeO6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P4SeO6 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(4) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(6) atom. In the fourth P site, P(4) is bonded in a distorted tetrahedral geometry to one Se(1), one O(4), one O(5), and one O(6) atom. Se(1) is bonded in a single-bond geometry to one P(4) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P4SeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.756
_cell_length_b   10.987
_cell_length_c   12.378
_cell_angle_alpha   70.156
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   864.291
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.464  0.665  0.211  1.0
  P  P1  1  0.964  0.335  0.289  1.0
  P  P2  1  0.536  0.335  0.789  1.0
  P  P3  1  0.036  0.665  0.711  1.0
  P  P4  1  0.244  0.570  0.048  1.0
  P  P5  1  0.744  0.430  0.452  1.0
  P  P6  1  0.756  0.430  0.952  1.0
  P  P7  1  0.256  0.570  0.548  1.0
  P  P8  1  0.136  0.822  0.071  1.0
  P  P9  1  0.636  0.178  0.429  1.0
  P  P10  1  0.864  0.178  0.929  1.0
  P  P11  1  0.364  0.822  0.571  1.0
  P  P12  1  0.510  0.793  0.963  1.0
  P  P13  1  0.010  0.207  0.537  1.0
  P  P14  1  0.490  0.207  0.037  1.0
  P  P15  1  0.990  0.793  0.463  1.0
  Se  Se16  1  0.706  0.887  0.835  1.0
  Se  Se17  1  0.206  0.113  0.665  1.0
  Se  Se18  1  0.294  0.113  0.165  1.0
  Se  Se19  1  0.794  0.887  0.335  1.0
  O  O20  1  0.085  0.684  0.050  1.0
  O  O21  1  0.585  0.316  0.450  1.0
  O  O22  1  0.915  0.316  0.950  1.0
  O  O23  1  0.415  0.684  0.550  1.0
  O  O24  1  0.274  0.766  0.189  1.0
  O  O25  1  0.774  0.234  0.311  1.0
  O  O26  1  0.726  0.234  0.811  1.0
  O  O27  1  0.226  0.766  0.689  1.0
  O  O28  1  0.367  0.549  0.169  1.0
  O  O29  1  0.867  0.451  0.331  1.0
  O  O30  1  0.633  0.451  0.831  1.0
  O  O31  1  0.133  0.549  0.669  1.0
  O  O32  1  0.412  0.662  0.953  1.0
  O  O33  1  0.912  0.338  0.547  1.0
  O  O34  1  0.588  0.338  0.047  1.0
  O  O35  1  0.088  0.662  0.453  1.0
  O  O36  1  0.599  0.743  0.092  1.0
  O  O37  1  0.099  0.257  0.408  1.0
  O  O38  1  0.401  0.257  0.908  1.0
  O  O39  1  0.901  0.743  0.592  1.0
  O  O40  1  0.181  0.877  0.473  1.0
  O  O41  1  0.681  0.123  0.027  1.0
  O  O42  1  0.819  0.123  0.527  1.0
  O  O43  1  0.319  0.877  0.973  1.0
[/CIF]
.
The material described by P4SeO6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P4SeO6 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(4) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(6) atom. In the fourth P site, P(4) is bonded in a distorted tetrahedral geometry to one Se(1), one O(4), one O(5), and one O(6) atom. Se(1) is bonded in a single-bond geometry to one P(4) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P4SeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.756
_cell_length_b   10.987
_cell_length_c   12.378
_cell_angle_alpha   70.156
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   864.291
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.464  0.665  0.211  1.0
  P  P1  1  0.964  0.335  0.289  1.0
  P  P2  1  0.536  0.335  0.789  1.0
  P  P3  1  0.036  0.665  0.711  1.0
  P  P4  1  0.244  0.570  0.048  1.0
  P  P5  1  0.744  0.430  0.452  1.0
  P  P6  1  0.756  0.430  0.952  1.0
  P  P7  1  0.256  0.570  0.548  1.0
  P  P8  1  0.136  0.822  0.071  1.0
  P  P9  1  0.636  0.178  0.429  1.0
  P  P10  1  0.864  0.178  0.929  1.0
  P  P11  1  0.364  0.822  0.571  1.0
  P  P12  1  0.510  0.793  0.963  1.0
  P  P13  1  0.010  0.207  0.537  1.0
  P  P14  1  0.490  0.207  0.037  1.0
  P  P15  1  0.990  0.793  0.463  1.0
  Se  Se16  1  0.706  0.887  0.835  1.0
  Se  Se17  1  0.206  0.113  0.665  1.0
  Se  Se18  1  0.294  0.113  0.165  1.0
  Se  Se19  1  0.794  0.887  0.335  1.0
  O  O20  1  0.085  0.684  0.050  1.0
  O  O21  1  0.585  0.316  0.450  1.0
  O  O22  1  0.915  0.316  0.950  1.0
  O  O23  1  0.415  0.684  0.550  1.0
  O  O24  1  0.274  0.766  0.189  1.0
  O  O25  1  0.774  0.234  0.311  1.0
  O  O26  1  0.726  0.234  0.811  1.0
  O  O27  1  0.226  0.766  0.689  1.0
  O  O28  1  0.367  0.549  0.169  1.0
  O  O29  1  0.867  0.451  0.331  1.0
  O  O30  1  0.633  0.451  0.831  1.0
  O  O31  1  0.133  0.549  0.669  1.0
  O  O32  1  0.412  0.662  0.953  1.0
  O  O33  1  0.912  0.338  0.547  1.0
  O  O34  1  0.588  0.338  0.047  1.0
  O  O35  1  0.088  0.662  0.453  1.0
  O  O36  1  0.599  0.743  0.092  1.0
  O  O37  1  0.099  0.257  0.408  1.0
  O  O38  1  0.401  0.257  0.908  1.0
  O  O39  1  0.901  0.743  0.592  1.0
  O  O40  1  0.181  0.877  0.473  1.0
  O  O41  1  0.681  0.123  0.027  1.0
  O  O42  1  0.819  0.123  0.527  1.0
  O  O43  1  0.319  0.877  0.973  1.0
[/CIF]
.