The material described by NaCdN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent N(1) atoms. Cd(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing CdN4 tetrahedra. N(1) is bonded to three equivalent Na(1) and four equivalent Cd(1) atoms to form a mixture of distorted edge and corner-sharing NNa3Cd4 hexagonal pyramids. is represented by the CIF file [CIF]
data_NaCdN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.884
_cell_length_b   3.939
_cell_length_c   6.065
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   188.331
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.608  0.250  0.860  1.0
  Na  Na1  1  0.108  0.250  0.640  1.0
  Na  Na2  1  0.392  0.750  0.140  1.0
  Na  Na3  1  0.892  0.750  0.360  1.0
  Cd  Cd4  1  0.634  0.250  0.394  1.0
  Cd  Cd5  1  0.134  0.250  0.106  1.0
  Cd  Cd6  1  0.366  0.750  0.606  1.0
  Cd  Cd7  1  0.866  0.750  0.894  1.0
  N  N8  1  0.839  0.250  0.125  1.0
  N  N9  1  0.339  0.250  0.375  1.0
  N  N10  1  0.161  0.750  0.875  1.0
  N  N11  1  0.661  0.750  0.625  1.0
[/CIF]
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The material described by NaCdN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent N(1) atoms. Cd(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing CdN4 tetrahedra. N(1) is bonded to three equivalent Na(1) and four equivalent Cd(1) atoms to form a mixture of distorted edge and corner-sharing NNa3Cd4 hexagonal pyramids. is represented by the CIF file [CIF]
data_NaCdN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.884
_cell_length_b   3.939
_cell_length_c   6.065
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   188.331
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.608  0.250  0.860  1.0
  Na  Na1  1  0.108  0.250  0.640  1.0
  Na  Na2  1  0.392  0.750  0.140  1.0
  Na  Na3  1  0.892  0.750  0.360  1.0
  Cd  Cd4  1  0.634  0.250  0.394  1.0
  Cd  Cd5  1  0.134  0.250  0.106  1.0
  Cd  Cd6  1  0.366  0.750  0.606  1.0
  Cd  Cd7  1  0.866  0.750  0.894  1.0
  N  N8  1  0.839  0.250  0.125  1.0
  N  N9  1  0.339  0.250  0.375  1.0
  N  N10  1  0.161  0.750  0.875  1.0
  N  N11  1  0.661  0.750  0.625  1.0
[/CIF]
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