The material described by EuAu5Cd crystallizes in the monoclinic C2 space group. Eu(1) is bonded to three equivalent Au(1), three equivalent Au(2), and six equivalent Au(3) atoms to form a mixture of distorted face and edge-sharing EuAu12 cuboctahedra. There are four inequivalent Au sites. In the first Au site, Au(1) is bonded in a 11-coordinate geometry to three equivalent Eu(1), two equivalent Au(2), two equivalent Au(3), two equivalent Au(4), and two equivalent Cd(1) atoms. In the second Au site, Au(2) is bonded in a 11-coordinate geometry to three equivalent Eu(1), two equivalent Au(1), two equivalent Au(3), two equivalent Au(4), and two equivalent Cd(1) atoms. In the third Au site, Au(3) is bonded in a 11-coordinate geometry to three equivalent Eu(1), one Au(1), one Au(2), two equivalent Au(3), two equivalent Au(4), and two equivalent Cd(1) atoms. In the fourth Au site, Au(4) is bonded in a linear geometry to two equivalent Au(1), two equivalent Au(2), four equivalent Au(3), and two equivalent Cd(1) atoms. Cd(1) is bonded in a 10-coordinate geometry to two equivalent Au(1), two equivalent Au(2), two equivalent Au(4), and four equivalent Au(3) atoms. is represented by the CIF card [CIF]
data_EuCdAu5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.797
_cell_length_b   5.797
_cell_length_c   5.812
_cell_angle_alpha   102.963
_cell_angle_beta   102.963
_cell_angle_gamma   123.704
_symmetry_Int_Tables_number   1
_cell_volume   142.936
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.000  1.000  0.000  1.0
  Cd  Cd1  1  0.750  0.250  0.500  1.0
  Au  Au2  1  0.695  0.305  0.000  1.0
  Au  Au3  1  0.305  0.695  0.000  1.0
  Au  Au4  1  0.305  0.305  0.610  1.0
  Au  Au5  1  0.695  0.695  0.390  1.0
  Au  Au6  1  0.250  0.750  0.500  1.0
[/CIF]
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The material described by EuAu5Cd crystallizes in the monoclinic C2 space group. Eu(1) is bonded to three equivalent Au(1), three equivalent Au(2), and six equivalent Au(3) atoms to form a mixture of distorted face and edge-sharing EuAu12 cuboctahedra. There are four inequivalent Au sites. In the first Au site, Au(1) is bonded in a 11-coordinate geometry to three equivalent Eu(1), two equivalent Au(2), two equivalent Au(3), two equivalent Au(4), and two equivalent Cd(1) atoms. In the second Au site, Au(2) is bonded in a 11-coordinate geometry to three equivalent Eu(1), two equivalent Au(1), two equivalent Au(3), two equivalent Au(4), and two equivalent Cd(1) atoms. In the third Au site, Au(3) is bonded in a 11-coordinate geometry to three equivalent Eu(1), one Au(1), one Au(2), two equivalent Au(3), two equivalent Au(4), and two equivalent Cd(1) atoms. In the fourth Au site, Au(4) is bonded in a linear geometry to two equivalent Au(1), two equivalent Au(2), four equivalent Au(3), and two equivalent Cd(1) atoms. Cd(1) is bonded in a 10-coordinate geometry to two equivalent Au(1), two equivalent Au(2), two equivalent Au(4), and four equivalent Au(3) atoms. is represented by the CIF card [CIF]
data_EuCdAu5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.797
_cell_length_b   5.797
_cell_length_c   5.812
_cell_angle_alpha   102.963
_cell_angle_beta   102.963
_cell_angle_gamma   123.704
_symmetry_Int_Tables_number   1
_cell_volume   142.936
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.000  1.000  0.000  1.0
  Cd  Cd1  1  0.750  0.250  0.500  1.0
  Au  Au2  1  0.695  0.305  0.000  1.0
  Au  Au3  1  0.305  0.695  0.000  1.0
  Au  Au4  1  0.305  0.305  0.610  1.0
  Au  Au5  1  0.695  0.695  0.390  1.0
  Au  Au6  1  0.250  0.750  0.500  1.0
[/CIF]
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