The material described by Li11V6O5F19 crystallizes in the triclinic P1 space group. There are eleven inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(17), one F(3), one F(4), and one F(8) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one F(16), one F(2), one F(5), and one F(9) atom. In the third Li site, Li(3) is bonded to one F(15), one F(3), one F(5), and one F(9) atom to form distorted LiF4 trigonal pyramids that share  a cornercorner with one V(4)O2F4 octahedra, corners with two equivalent V(1)OF5 octahedra, and  an edgeedge with one V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 61-64°. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(1), one O(5), one F(13), one F(18), one F(6), and one F(7) atom. In the fifth Li site, Li(5) is bonded to one O(4), one F(14), one F(19), one F(6), and one F(7) atom to form distorted LiOF4 trigonal bipyramids that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(4)O2F4 octahedra,  a cornercorner with one V(5)O2F4 octahedra,  an edgeedge with one V(4)O2F4 octahedra, and  an edgeedge with one V(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 47-75°. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(1), one O(5), one F(10), one F(12), one F(4), and one F(8) atom. In the seventh Li site, Li(7) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(11), one F(12), one F(17), and one F(8) atom. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(3), one F(15), one F(16), one F(2), and one F(9) atom. In the ninth Li site, Li(9) is bonded in a 6-coordinate geometry to one O(3), one O(4), one F(13), one F(14), one F(19), and one F(7) atom. In the tenth Li site, Li(10) is bonded in a 5-coordinate geometry to one O(1), one F(13), one F(14), one F(18), and one F(6) atom. In the eleventh Li site, Li(11) is bonded to one O(5), one F(10), one F(12), one F(17), and one F(4) atom to form distorted LiOF4 trigonal bipyramids that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(3)OF5 octahedra,  an edgeedge with one V(2)O2F4 octahedra, and  an edgeedge with one V(6)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 47-74°. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one F(1), one F(11), one F(3), one F(5), and one F(8) atom to form VOF5 octahedra that share corners with four equivalent V(3)OF5 octahedra and corners with two equivalent Li(3)F4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 38-49°. In the second V site, V(2) is bonded to one O(1), one O(5), one F(10), one F(18), one F(4), and one F(6) atom to form VO2F4 octahedra that share corners with four equivalent V(6)O2F4 octahedra,  a cornercorner with one Li(11)OF4 trigonal bipyramid,  a cornercorner with one Li(5)OF4 trigonal bipyramid, and  an edgeedge with one Li(11)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-50°. In the third V site, V(3) is bonded to one O(2), one F(1), one F(11), one F(15), one F(17), and one F(3) atom to form VOF5 octahedra that share corners with four equivalent V(1)OF5 octahedra,  a cornercorner with one Li(11)OF4 trigonal bipyramid, and  an edgeedge with one Li(3)F4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 38-49°. In the fourth V site, V(4) is bonded to one O(3), one O(4), one F(14), one F(19), one F(2), and one F(9) atom to form VO2F4 octahedra that share corners with four equivalent V(5)O2F4 octahedra,  a cornercorner with one Li(5)OF4 trigonal bipyramid,  a cornercorner with one Li(3)F4 trigonal pyramid, and  an edgeedge with one Li(5)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-50°. In the fifth V site, V(5) is bonded to one O(3), one O(4), one F(16), one F(19), one F(2), and one F(7) atom to form VO2F4 octahedra that share corners with four equivalent V(4)O2F4 octahedra,  a cornercorner with one Li(5)OF4 trigonal bipyramid, and  an edgeedge with one Li(5)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-50°. In the sixth V site, V(6) is bonded to one O(1), one O(5), one F(10), one F(12), one F(13), and one F(18) atom to form VO2F4 octahedra that share corners with four equivalent V(2)O2F4 octahedra,  a cornercorner with one Li(11)OF4 trigonal bipyramid, and  an edgeedge with one Li(11)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-50°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(10), one Li(4), one Li(6), one V(2), and one V(6) atom to form distorted OLi3V2 trigonal bipyramids that share  a cornercorner with one F(10)Li2V2 trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid,  an edgeedge with one F(10)Li2V2 trigonal pyramid,  an edgeedge with one F(4)Li3V trigonal pyramid,  an edgeedge with one F(6)Li3V trigonal pyramid, and edges with two equivalent F(18)Li2V2 trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one Li(7), one V(1), and one V(3) atom to form distorted OLi2V2 tetrahedra that share  a cornercorner with one F(4)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid, corners with three equivalent F(17)Li3V trigonal pyramids, and  an edgeedge with one F(8)Li3V trigonal pyramid. In the third O site, O(3) is bonded to one Li(2), one Li(8), one Li(9), one V(4), and one V(5) atom to form distorted OLi3V2 trigonal bipyramids that share  a cornercorner with one F(9)Li3V tetrahedra,  a cornercorner with one F(19)Li2V2 trigonal pyramid,  an edgeedge with one F(9)Li3V tetrahedra,  an edgeedge with one F(19)Li2V2 trigonal pyramid,  an edgeedge with one F(14)Li3V trigonal pyramid, and edges with two equivalent F(2)Li2V2 trigonal pyramids. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(2), one Li(5), one Li(9), one V(4), and one V(5) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(11), one Li(4), one Li(6), one V(2), and one V(6) atom. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Li(1), one Li(7), one V(1), and one V(3) atom. In the second F site, F(2) is bonded to one Li(2), one Li(8), one V(4), and one V(5) atom to form distorted FLi2V2 trigonal pyramids that share corners with three equivalent F(9)Li3V tetrahedra,  a cornercorner with one F(14)Li3V trigonal pyramid, corners with two equivalent F(19)Li2V2 trigonal pyramids, and edges with two equivalent O(3)Li3V2 trigonal bipyramids. In the third F site, F(3) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(3), one V(1), and one V(3) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(11), one Li(6), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(2)Li2V2 tetrahedra,  a cornercorner with one F(18)Li2V2 trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid, corners with two equivalent F(8)Li3V trigonal pyramids, corners with three equivalent F(10)Li2V2 trigonal pyramids,  an edgeedge with one O(1)Li3V2 trigonal bipyramid, and  an edgeedge with one F(17)Li3V trigonal pyramid. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Li(2), one Li(3), and one V(1) atom. In the sixth F site, F(6) is bonded to one Li(10), one Li(4), one Li(5), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(1)Li3V2 trigonal bipyramid,  a cornercorner with one F(10)Li2V2 trigonal pyramid,  a cornercorner with one F(19)Li2V2 trigonal pyramid,  a cornercorner with one F(4)Li3V trigonal pyramid, corners with three equivalent F(18)Li2V2 trigonal pyramids,  an edgeedge with one O(1)Li3V2 trigonal bipyramid, and  an edgeedge with one F(14)Li3V trigonal pyramid. In the seventh F site, F(7) is bonded in a 4-coordinate geometry to one Li(4), one Li(5), one Li(9), and one V(5) atom. In the eighth F site, F(8) is bonded to one Li(1), one Li(6), one Li(7), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(2)Li2V2 tetrahedra,  a cornercorner with one O(1)Li3V2 trigonal bipyramid,  a cornercorner with one F(10)Li2V2 trigonal pyramid, corners with two equivalent F(17)Li3V trigonal pyramids, corners with two equivalent F(4)Li3V trigonal pyramids, and  an edgeedge with one O(2)Li2V2 tetrahedra. In the ninth F site, F(9) is bonded to one Li(2), one Li(3), one Li(8), and one V(4) atom to form FLi3V tetrahedra that share  a cornercorner with one O(3)Li3V2 trigonal bipyramid,  a cornercorner with one F(19)Li2V2 trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid, corners with three equivalent F(2)Li2V2 trigonal pyramids, and  an edgeedge with one O(3)Li3V2 trigonal bipyramid. In the tenth F site, F(10) is bonded to one Li(11), one Li(6), one V(2), and one V(6) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one O(1)Li3V2 trigonal bipyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid, corners with two equivalent F(18)Li2V2 trigonal pyramids, corners with three equivalent F(4)Li3V trigonal pyramids, and  an edgeedge with one O(1)Li3V2 trigonal bipyramid. In the eleventh F site, F(11) is bonded in a 2-coordinate geometry to one Li(7), one V(1), and one V(3) atom. In the twelfth F site, F(12) is bonded in a 4-coordinate geometry to one Li(11), one Li(6), one Li(7), and one V(6) atom. In the thirteenth F site, F(13) is bonded in a 4-coordinate geometry to one Li(10), one Li(4), one Li(9), and one V(6) atom. In the fourteenth F site, F(14) is bonded to one Li(10), one Li(5), one Li(9), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(9)Li3V tetrahedra,  a cornercorner with one O(1)Li3V2 trigonal bipyramid,  a cornercorner with one F(18)Li2V2 trigonal pyramid,  a cornercorner with one F(2)Li2V2 trigonal pyramid, corners with three equivalent F(19)Li2V2 trigonal pyramids,  an edgeedge with one O(3)Li3V2 trigonal bipyramid, and  an edgeedge with one F(6)Li3V trigonal pyramid. In the fifteenth F site, F(15) is bonded in a distorted T-shaped geometry to one Li(3), one Li(8), and one V(3) atom. In the sixteenth F site, F(16) is bonded in a 3-coordinate geometry to one Li(2), one Li(8), and one V(5) atom. In the seventeenth F site, F(17) is bonded to one Li(1), one Li(11), one Li(7), and one V(3) atom to form distorted FLi3V trigonal pyramids that share corners with three equivalent O(2)Li2V2 tetrahedra,  a cornercorner with one F(10)Li2V2 trigonal pyramid, corners with two equivalent F(8)Li3V trigonal pyramids, and  an edgeedge with one F(4)Li3V trigonal pyramid. In the eighteenth F site, F(18) is bonded to one Li(10), one Li(4), one V(2), and one V(6) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(4)Li3V trigonal pyramid, corners with two equivalent F(10)Li2V2 trigonal pyramids, corners with three equivalent F(6)Li3V trigonal pyramids, and edges with two equivalent O(1)Li3V2 trigonal bipyramids. In the nineteenth F site, F(19) is bonded to one Li(5), one Li(9), one V(4), and one V(5) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one F(9)Li3V tetrahedra,  a cornercorner with one O(3)Li3V2 trigonal bipyramid,  a cornercorner with one F(6)Li3V trigonal pyramid, corners with two equivalent F(2)Li2V2 trigonal pyramids, corners with three equivalent F(14)Li3V trigonal pyramids, and  an edgeedge with one O(3)Li3V2 trigonal bipyramid. is represented by the CIF file [CIF]
data_Li11V6O5F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.131
_cell_length_b   5.460
_cell_length_c   16.205
_cell_angle_alpha   98.981
_cell_angle_beta   90.070
_cell_angle_gamma   91.473
_symmetry_Int_Tables_number   1
_cell_volume   448.253
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.491  0.240  0.559  1.0
  Li  Li1  1  0.002  0.398  0.899  1.0
  Li  Li2  1  0.514  0.280  0.795  1.0
  Li  Li3  1  0.988  0.091  0.229  1.0
  Li  Li4  1  0.490  0.118  0.110  1.0
  Li  Li5  1  0.001  0.249  0.431  1.0
  Li  Li6  1  0.002  0.716  0.556  1.0
  Li  Li7  1  0.502  0.857  0.886  1.0
  Li  Li8  1  0.011  0.580  0.101  1.0
  Li  Li9  1  0.501  0.549  0.222  1.0
  Li  Li10  1  0.492  0.796  0.442  1.0
  V  V11  1  0.987  0.351  0.666  1.0
  V  V12  1  0.499  0.168  0.335  1.0
  V  V13  1  0.518  0.817  0.664  1.0
  V  V14  1  0.504  0.491  0.002  1.0
  V  V15  1  0.005  0.992  0.001  1.0
  V  V16  1  0.000  0.667  0.333  1.0
  O  O17  1  0.806  0.353  0.307  1.0
  O  O18  1  0.694  0.517  0.630  1.0
  O  O19  1  0.809  0.678  0.972  1.0
  O  O20  1  0.203  0.305  0.035  1.0
  O  O21  1  0.200  0.977  0.366  1.0
  F  F22  1  0.825  0.009  0.622  1.0
  F  F23  1  0.689  0.165  0.954  1.0
  F  F24  1  0.327  0.176  0.689  1.0
  F  F25  1  0.644  0.151  0.451  1.0
  F  F26  1  0.872  0.359  0.782  1.0
  F  F27  1  0.352  0.190  0.220  1.0
  F  F28  1  0.852  0.005  0.118  1.0
  F  F29  1  0.137  0.347  0.549  1.0
  F  F30  1  0.365  0.501  0.884  1.0
  F  F31  1  0.311  0.493  0.383  1.0
  F  F32  1  0.182  0.671  0.698  1.0
  F  F33  1  0.850  0.683  0.449  1.0
  F  F34  1  0.143  0.656  0.217  1.0
  F  F35  1  0.655  0.474  0.117  1.0
  F  F36  1  0.603  0.919  0.780  1.0
  F  F37  1  0.159  0.994  0.891  1.0
  F  F38  1  0.360  0.848  0.553  1.0
  F  F39  1  0.683  0.839  0.288  1.0
  F  F40  1  0.315  0.816  0.050  1.0
[/CIF]
.
The material described by Li11V6O5F19 crystallizes in the triclinic P1 space group. There are eleven inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(17), one F(3), one F(4), and one F(8) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one F(16), one F(2), one F(5), and one F(9) atom. In the third Li site, Li(3) is bonded to one F(15), one F(3), one F(5), and one F(9) atom to form distorted LiF4 trigonal pyramids that share  a cornercorner with one V(4)O2F4 octahedra, corners with two equivalent V(1)OF5 octahedra, and  an edgeedge with one V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 61-64°. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(1), one O(5), one F(13), one F(18), one F(6), and one F(7) atom. In the fifth Li site, Li(5) is bonded to one O(4), one F(14), one F(19), one F(6), and one F(7) atom to form distorted LiOF4 trigonal bipyramids that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(4)O2F4 octahedra,  a cornercorner with one V(5)O2F4 octahedra,  an edgeedge with one V(4)O2F4 octahedra, and  an edgeedge with one V(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 47-75°. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(1), one O(5), one F(10), one F(12), one F(4), and one F(8) atom. In the seventh Li site, Li(7) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(11), one F(12), one F(17), and one F(8) atom. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(3), one F(15), one F(16), one F(2), and one F(9) atom. In the ninth Li site, Li(9) is bonded in a 6-coordinate geometry to one O(3), one O(4), one F(13), one F(14), one F(19), and one F(7) atom. In the tenth Li site, Li(10) is bonded in a 5-coordinate geometry to one O(1), one F(13), one F(14), one F(18), and one F(6) atom. In the eleventh Li site, Li(11) is bonded to one O(5), one F(10), one F(12), one F(17), and one F(4) atom to form distorted LiOF4 trigonal bipyramids that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(3)OF5 octahedra,  an edgeedge with one V(2)O2F4 octahedra, and  an edgeedge with one V(6)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 47-74°. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one F(1), one F(11), one F(3), one F(5), and one F(8) atom to form VOF5 octahedra that share corners with four equivalent V(3)OF5 octahedra and corners with two equivalent Li(3)F4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 38-49°. In the second V site, V(2) is bonded to one O(1), one O(5), one F(10), one F(18), one F(4), and one F(6) atom to form VO2F4 octahedra that share corners with four equivalent V(6)O2F4 octahedra,  a cornercorner with one Li(11)OF4 trigonal bipyramid,  a cornercorner with one Li(5)OF4 trigonal bipyramid, and  an edgeedge with one Li(11)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-50°. In the third V site, V(3) is bonded to one O(2), one F(1), one F(11), one F(15), one F(17), and one F(3) atom to form VOF5 octahedra that share corners with four equivalent V(1)OF5 octahedra,  a cornercorner with one Li(11)OF4 trigonal bipyramid, and  an edgeedge with one Li(3)F4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 38-49°. In the fourth V site, V(4) is bonded to one O(3), one O(4), one F(14), one F(19), one F(2), and one F(9) atom to form VO2F4 octahedra that share corners with four equivalent V(5)O2F4 octahedra,  a cornercorner with one Li(5)OF4 trigonal bipyramid,  a cornercorner with one Li(3)F4 trigonal pyramid, and  an edgeedge with one Li(5)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-50°. In the fifth V site, V(5) is bonded to one O(3), one O(4), one F(16), one F(19), one F(2), and one F(7) atom to form VO2F4 octahedra that share corners with four equivalent V(4)O2F4 octahedra,  a cornercorner with one Li(5)OF4 trigonal bipyramid, and  an edgeedge with one Li(5)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-50°. In the sixth V site, V(6) is bonded to one O(1), one O(5), one F(10), one F(12), one F(13), and one F(18) atom to form VO2F4 octahedra that share corners with four equivalent V(2)O2F4 octahedra,  a cornercorner with one Li(11)OF4 trigonal bipyramid, and  an edgeedge with one Li(11)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-50°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(10), one Li(4), one Li(6), one V(2), and one V(6) atom to form distorted OLi3V2 trigonal bipyramids that share  a cornercorner with one F(10)Li2V2 trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid,  an edgeedge with one F(10)Li2V2 trigonal pyramid,  an edgeedge with one F(4)Li3V trigonal pyramid,  an edgeedge with one F(6)Li3V trigonal pyramid, and edges with two equivalent F(18)Li2V2 trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one Li(7), one V(1), and one V(3) atom to form distorted OLi2V2 tetrahedra that share  a cornercorner with one F(4)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid, corners with three equivalent F(17)Li3V trigonal pyramids, and  an edgeedge with one F(8)Li3V trigonal pyramid. In the third O site, O(3) is bonded to one Li(2), one Li(8), one Li(9), one V(4), and one V(5) atom to form distorted OLi3V2 trigonal bipyramids that share  a cornercorner with one F(9)Li3V tetrahedra,  a cornercorner with one F(19)Li2V2 trigonal pyramid,  an edgeedge with one F(9)Li3V tetrahedra,  an edgeedge with one F(19)Li2V2 trigonal pyramid,  an edgeedge with one F(14)Li3V trigonal pyramid, and edges with two equivalent F(2)Li2V2 trigonal pyramids. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(2), one Li(5), one Li(9), one V(4), and one V(5) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(11), one Li(4), one Li(6), one V(2), and one V(6) atom. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Li(1), one Li(7), one V(1), and one V(3) atom. In the second F site, F(2) is bonded to one Li(2), one Li(8), one V(4), and one V(5) atom to form distorted FLi2V2 trigonal pyramids that share corners with three equivalent F(9)Li3V tetrahedra,  a cornercorner with one F(14)Li3V trigonal pyramid, corners with two equivalent F(19)Li2V2 trigonal pyramids, and edges with two equivalent O(3)Li3V2 trigonal bipyramids. In the third F site, F(3) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(3), one V(1), and one V(3) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(11), one Li(6), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(2)Li2V2 tetrahedra,  a cornercorner with one F(18)Li2V2 trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid, corners with two equivalent F(8)Li3V trigonal pyramids, corners with three equivalent F(10)Li2V2 trigonal pyramids,  an edgeedge with one O(1)Li3V2 trigonal bipyramid, and  an edgeedge with one F(17)Li3V trigonal pyramid. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Li(2), one Li(3), and one V(1) atom. In the sixth F site, F(6) is bonded to one Li(10), one Li(4), one Li(5), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(1)Li3V2 trigonal bipyramid,  a cornercorner with one F(10)Li2V2 trigonal pyramid,  a cornercorner with one F(19)Li2V2 trigonal pyramid,  a cornercorner with one F(4)Li3V trigonal pyramid, corners with three equivalent F(18)Li2V2 trigonal pyramids,  an edgeedge with one O(1)Li3V2 trigonal bipyramid, and  an edgeedge with one F(14)Li3V trigonal pyramid. In the seventh F site, F(7) is bonded in a 4-coordinate geometry to one Li(4), one Li(5), one Li(9), and one V(5) atom. In the eighth F site, F(8) is bonded to one Li(1), one Li(6), one Li(7), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(2)Li2V2 tetrahedra,  a cornercorner with one O(1)Li3V2 trigonal bipyramid,  a cornercorner with one F(10)Li2V2 trigonal pyramid, corners with two equivalent F(17)Li3V trigonal pyramids, corners with two equivalent F(4)Li3V trigonal pyramids, and  an edgeedge with one O(2)Li2V2 tetrahedra. In the ninth F site, F(9) is bonded to one Li(2), one Li(3), one Li(8), and one V(4) atom to form FLi3V tetrahedra that share  a cornercorner with one O(3)Li3V2 trigonal bipyramid,  a cornercorner with one F(19)Li2V2 trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid, corners with three equivalent F(2)Li2V2 trigonal pyramids, and  an edgeedge with one O(3)Li3V2 trigonal bipyramid. In the tenth F site, F(10) is bonded to one Li(11), one Li(6), one V(2), and one V(6) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one O(1)Li3V2 trigonal bipyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid, corners with two equivalent F(18)Li2V2 trigonal pyramids, corners with three equivalent F(4)Li3V trigonal pyramids, and  an edgeedge with one O(1)Li3V2 trigonal bipyramid. In the eleventh F site, F(11) is bonded in a 2-coordinate geometry to one Li(7), one V(1), and one V(3) atom. In the twelfth F site, F(12) is bonded in a 4-coordinate geometry to one Li(11), one Li(6), one Li(7), and one V(6) atom. In the thirteenth F site, F(13) is bonded in a 4-coordinate geometry to one Li(10), one Li(4), one Li(9), and one V(6) atom. In the fourteenth F site, F(14) is bonded to one Li(10), one Li(5), one Li(9), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(9)Li3V tetrahedra,  a cornercorner with one O(1)Li3V2 trigonal bipyramid,  a cornercorner with one F(18)Li2V2 trigonal pyramid,  a cornercorner with one F(2)Li2V2 trigonal pyramid, corners with three equivalent F(19)Li2V2 trigonal pyramids,  an edgeedge with one O(3)Li3V2 trigonal bipyramid, and  an edgeedge with one F(6)Li3V trigonal pyramid. In the fifteenth F site, F(15) is bonded in a distorted T-shaped geometry to one Li(3), one Li(8), and one V(3) atom. In the sixteenth F site, F(16) is bonded in a 3-coordinate geometry to one Li(2), one Li(8), and one V(5) atom. In the seventeenth F site, F(17) is bonded to one Li(1), one Li(11), one Li(7), and one V(3) atom to form distorted FLi3V trigonal pyramids that share corners with three equivalent O(2)Li2V2 tetrahedra,  a cornercorner with one F(10)Li2V2 trigonal pyramid, corners with two equivalent F(8)Li3V trigonal pyramids, and  an edgeedge with one F(4)Li3V trigonal pyramid. In the eighteenth F site, F(18) is bonded to one Li(10), one Li(4), one V(2), and one V(6) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(4)Li3V trigonal pyramid, corners with two equivalent F(10)Li2V2 trigonal pyramids, corners with three equivalent F(6)Li3V trigonal pyramids, and edges with two equivalent O(1)Li3V2 trigonal bipyramids. In the nineteenth F site, F(19) is bonded to one Li(5), one Li(9), one V(4), and one V(5) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one F(9)Li3V tetrahedra,  a cornercorner with one O(3)Li3V2 trigonal bipyramid,  a cornercorner with one F(6)Li3V trigonal pyramid, corners with two equivalent F(2)Li2V2 trigonal pyramids, corners with three equivalent F(14)Li3V trigonal pyramids, and  an edgeedge with one O(3)Li3V2 trigonal bipyramid. is represented by the CIF file [CIF]
data_Li11V6O5F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.131
_cell_length_b   5.460
_cell_length_c   16.205
_cell_angle_alpha   98.981
_cell_angle_beta   90.070
_cell_angle_gamma   91.473
_symmetry_Int_Tables_number   1
_cell_volume   448.253
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.491  0.240  0.559  1.0
  Li  Li1  1  0.002  0.398  0.899  1.0
  Li  Li2  1  0.514  0.280  0.795  1.0
  Li  Li3  1  0.988  0.091  0.229  1.0
  Li  Li4  1  0.490  0.118  0.110  1.0
  Li  Li5  1  0.001  0.249  0.431  1.0
  Li  Li6  1  0.002  0.716  0.556  1.0
  Li  Li7  1  0.502  0.857  0.886  1.0
  Li  Li8  1  0.011  0.580  0.101  1.0
  Li  Li9  1  0.501  0.549  0.222  1.0
  Li  Li10  1  0.492  0.796  0.442  1.0
  V  V11  1  0.987  0.351  0.666  1.0
  V  V12  1  0.499  0.168  0.335  1.0
  V  V13  1  0.518  0.817  0.664  1.0
  V  V14  1  0.504  0.491  0.002  1.0
  V  V15  1  0.005  0.992  0.001  1.0
  V  V16  1  0.000  0.667  0.333  1.0
  O  O17  1  0.806  0.353  0.307  1.0
  O  O18  1  0.694  0.517  0.630  1.0
  O  O19  1  0.809  0.678  0.972  1.0
  O  O20  1  0.203  0.305  0.035  1.0
  O  O21  1  0.200  0.977  0.366  1.0
  F  F22  1  0.825  0.009  0.622  1.0
  F  F23  1  0.689  0.165  0.954  1.0
  F  F24  1  0.327  0.176  0.689  1.0
  F  F25  1  0.644  0.151  0.451  1.0
  F  F26  1  0.872  0.359  0.782  1.0
  F  F27  1  0.352  0.190  0.220  1.0
  F  F28  1  0.852  0.005  0.118  1.0
  F  F29  1  0.137  0.347  0.549  1.0
  F  F30  1  0.365  0.501  0.884  1.0
  F  F31  1  0.311  0.493  0.383  1.0
  F  F32  1  0.182  0.671  0.698  1.0
  F  F33  1  0.850  0.683  0.449  1.0
  F  F34  1  0.143  0.656  0.217  1.0
  F  F35  1  0.655  0.474  0.117  1.0
  F  F36  1  0.603  0.919  0.780  1.0
  F  F37  1  0.159  0.994  0.891  1.0
  F  F38  1  0.360  0.848  0.553  1.0
  F  F39  1  0.683  0.839  0.288  1.0
  F  F40  1  0.315  0.816  0.050  1.0
[/CIF]
.