The crystal structure described by Mn(PO3)3 crystallizes in the triclinic P-1 space group. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(9) atom to form MnO5 trigonal bipyramids that share  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Mn(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(3), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Mn(1)O5 trigonal bipyramids. In the third P site, P(3) is bonded to one O(4), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the ninth O site, O(9) is bonded in a linear geometry to one Mn(1) and one P(2) atom. is represented by the CIF card [CIF]
data_Mn(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.811
_cell_length_b   7.253
_cell_length_c   7.300
_cell_angle_alpha   95.016
_cell_angle_beta   100.262
_cell_angle_gamma   93.142
_symmetry_Int_Tables_number   1
_cell_volume   352.555
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.087  0.182  0.841  1.0
  Mn  Mn1  1  0.913  0.818  0.159  1.0
  O  O2  1  0.857  0.042  0.680  1.0
  O  O3  1  0.143  0.958  0.320  1.0
  O  O4  1  0.238  0.143  0.641  1.0
  O  O5  1  0.762  0.857  0.359  1.0
  O  O6  1  0.927  0.195  0.037  1.0
  O  O7  1  0.073  0.805  0.963  1.0
  O  O8  1  0.332  0.188  0.023  1.0
  O  O9  1  0.668  0.812  0.977  1.0
  O  O10  1  0.014  0.281  0.385  1.0
  O  O11  1  0.986  0.719  0.615  1.0
  O  O12  1  0.383  0.245  0.377  1.0
  O  O13  1  0.617  0.755  0.623  1.0
  O  O14  1  0.589  0.475  0.811  1.0
  O  O15  1  0.411  0.525  0.189  1.0
  O  O16  1  0.666  0.270  0.224  1.0
  O  O17  1  0.334  0.730  0.776  1.0
  O  O18  1  0.084  0.464  0.818  1.0
  O  O19  1  0.916  0.536  0.182  1.0
  P  P20  1  0.193  0.147  0.431  1.0
  P  P21  1  0.807  0.853  0.569  1.0
  P  P22  1  0.882  0.334  0.191  1.0
  P  P23  1  0.118  0.666  0.809  1.0
  P  P24  1  0.437  0.326  0.186  1.0
  P  P25  1  0.563  0.674  0.814  1.0
[/CIF]
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The crystal structure described by Mn(PO3)3 crystallizes in the triclinic P-1 space group. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(9) atom to form MnO5 trigonal bipyramids that share  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Mn(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(3), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Mn(1)O5 trigonal bipyramids. In the third P site, P(3) is bonded to one O(4), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the ninth O site, O(9) is bonded in a linear geometry to one Mn(1) and one P(2) atom. is represented by the CIF card [CIF]
data_Mn(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.811
_cell_length_b   7.253
_cell_length_c   7.300
_cell_angle_alpha   95.016
_cell_angle_beta   100.262
_cell_angle_gamma   93.142
_symmetry_Int_Tables_number   1
_cell_volume   352.555
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.087  0.182  0.841  1.0
  Mn  Mn1  1  0.913  0.818  0.159  1.0
  O  O2  1  0.857  0.042  0.680  1.0
  O  O3  1  0.143  0.958  0.320  1.0
  O  O4  1  0.238  0.143  0.641  1.0
  O  O5  1  0.762  0.857  0.359  1.0
  O  O6  1  0.927  0.195  0.037  1.0
  O  O7  1  0.073  0.805  0.963  1.0
  O  O8  1  0.332  0.188  0.023  1.0
  O  O9  1  0.668  0.812  0.977  1.0
  O  O10  1  0.014  0.281  0.385  1.0
  O  O11  1  0.986  0.719  0.615  1.0
  O  O12  1  0.383  0.245  0.377  1.0
  O  O13  1  0.617  0.755  0.623  1.0
  O  O14  1  0.589  0.475  0.811  1.0
  O  O15  1  0.411  0.525  0.189  1.0
  O  O16  1  0.666  0.270  0.224  1.0
  O  O17  1  0.334  0.730  0.776  1.0
  O  O18  1  0.084  0.464  0.818  1.0
  O  O19  1  0.916  0.536  0.182  1.0
  P  P20  1  0.193  0.147  0.431  1.0
  P  P21  1  0.807  0.853  0.569  1.0
  P  P22  1  0.882  0.334  0.191  1.0
  P  P23  1  0.118  0.666  0.809  1.0
  P  P24  1  0.437  0.326  0.186  1.0
  P  P25  1  0.563  0.674  0.814  1.0
[/CIF]
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