The structure described by ZnCl3NNCl is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four chloramine molecules and four ZnCl3N clusters. In each ZnCl3N cluster, Zn(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent Cl(3) atoms. N(2) is bonded in a linear geometry to one Zn(1) and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one N(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the CIF card [CIF]
data_Zn(NCl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.452
_cell_length_b   8.800
_cell_length_c   13.886
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1032.860
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.618  0.250  0.124  1.0
  Zn  Zn1  1  0.118  0.250  0.376  1.0
  Zn  Zn2  1  0.382  0.750  0.876  1.0
  Zn  Zn3  1  0.882  0.750  0.624  1.0
  N  N4  1  0.046  0.750  0.135  1.0
  N  N5  1  0.546  0.750  0.365  1.0
  N  N6  1  0.954  0.250  0.865  1.0
  N  N7  1  0.454  0.250  0.635  1.0
  N  N8  1  0.634  0.750  0.898  1.0
  N  N9  1  0.134  0.750  0.602  1.0
  N  N10  1  0.366  0.250  0.102  1.0
  N  N11  1  0.866  0.250  0.398  1.0
  Cl  Cl12  1  0.185  0.250  0.074  1.0
  Cl  Cl13  1  0.685  0.250  0.426  1.0
  Cl  Cl14  1  0.815  0.750  0.926  1.0
  Cl  Cl15  1  0.315  0.750  0.574  1.0
  Cl  Cl16  1  0.767  0.250  0.889  1.0
  Cl  Cl17  1  0.267  0.250  0.611  1.0
  Cl  Cl18  1  0.233  0.750  0.111  1.0
  Cl  Cl19  1  0.733  0.750  0.389  1.0
  Cl  Cl20  1  0.683  0.017  0.129  1.0
  Cl  Cl21  1  0.183  0.483  0.371  1.0
  Cl  Cl22  1  0.317  0.517  0.871  1.0
  Cl  Cl23  1  0.817  0.983  0.629  1.0
  Cl  Cl24  1  0.317  0.983  0.871  1.0
  Cl  Cl25  1  0.817  0.517  0.629  1.0
  Cl  Cl26  1  0.683  0.483  0.129  1.0
  Cl  Cl27  1  0.183  0.017  0.371  1.0
[/CIF]
.
The structure described by ZnCl3NNCl is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four chloramine molecules and four ZnCl3N clusters. In each ZnCl3N cluster, Zn(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent Cl(3) atoms. N(2) is bonded in a linear geometry to one Zn(1) and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one N(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the CIF card [CIF]
data_Zn(NCl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.452
_cell_length_b   8.800
_cell_length_c   13.886
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1032.860
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.618  0.250  0.124  1.0
  Zn  Zn1  1  0.118  0.250  0.376  1.0
  Zn  Zn2  1  0.382  0.750  0.876  1.0
  Zn  Zn3  1  0.882  0.750  0.624  1.0
  N  N4  1  0.046  0.750  0.135  1.0
  N  N5  1  0.546  0.750  0.365  1.0
  N  N6  1  0.954  0.250  0.865  1.0
  N  N7  1  0.454  0.250  0.635  1.0
  N  N8  1  0.634  0.750  0.898  1.0
  N  N9  1  0.134  0.750  0.602  1.0
  N  N10  1  0.366  0.250  0.102  1.0
  N  N11  1  0.866  0.250  0.398  1.0
  Cl  Cl12  1  0.185  0.250  0.074  1.0
  Cl  Cl13  1  0.685  0.250  0.426  1.0
  Cl  Cl14  1  0.815  0.750  0.926  1.0
  Cl  Cl15  1  0.315  0.750  0.574  1.0
  Cl  Cl16  1  0.767  0.250  0.889  1.0
  Cl  Cl17  1  0.267  0.250  0.611  1.0
  Cl  Cl18  1  0.233  0.750  0.111  1.0
  Cl  Cl19  1  0.733  0.750  0.389  1.0
  Cl  Cl20  1  0.683  0.017  0.129  1.0
  Cl  Cl21  1  0.183  0.483  0.371  1.0
  Cl  Cl22  1  0.317  0.517  0.871  1.0
  Cl  Cl23  1  0.817  0.983  0.629  1.0
  Cl  Cl24  1  0.317  0.983  0.871  1.0
  Cl  Cl25  1  0.817  0.517  0.629  1.0
  Cl  Cl26  1  0.683  0.483  0.129  1.0
  Cl  Cl27  1  0.183  0.017  0.371  1.0
[/CIF]
.