The material described by Cr2CoP3 is Modderite-derived structured and crystallizes in the monoclinic Pm space group. There are eight inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 6-coordinate geometry to one P(3), one P(5), two equivalent P(11), and two equivalent P(8) atoms. In the second Cr site, Cr(2) is bonded in a 6-coordinate geometry to one P(1), one P(6), two equivalent P(12), and two equivalent P(9) atoms. In the third Cr site, Cr(3) is bonded in a 6-coordinate geometry to one P(10), one P(9), two equivalent P(1), and two equivalent P(4) atoms. In the fourth Cr site, Cr(4) is bonded in a 6-coordinate geometry to one P(11), one P(7), two equivalent P(2), and two equivalent P(5) atoms. In the fifth Cr site, Cr(5) is bonded in a 6-coordinate geometry to one P(12), one P(8), two equivalent P(3), and two equivalent P(6) atoms. In the sixth Cr site, Cr(6) is bonded in a 6-coordinate geometry to one P(10), one P(9), two equivalent P(1), and two equivalent P(4) atoms. In the seventh Cr site, Cr(7) is bonded in a 6-coordinate geometry to one P(11), one P(7), two equivalent P(2), and two equivalent P(5) atoms. In the eighth Cr site, Cr(8) is bonded in a 6-coordinate geometry to one P(12), one P(8), two equivalent P(3), and two equivalent P(6) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one P(2), one P(4), two equivalent P(10), and two equivalent P(7) atoms. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one P(3), one P(5), two equivalent P(11), and two equivalent P(8) atoms. In the third Co site, Co(3) is bonded in a 6-coordinate geometry to one P(1), one P(6), two equivalent P(12), and two equivalent P(9) atoms. In the fourth Co site, Co(4) is bonded in a 6-coordinate geometry to one P(2), one P(4), two equivalent P(10), and two equivalent P(7) atoms. There are twelve inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to one Cr(2), two equivalent Cr(3), two equivalent Cr(6), and one Co(3) atom. In the second P site, P(2) is bonded in a 6-coordinate geometry to two equivalent Cr(4), two equivalent Cr(7), one Co(1), and one Co(4) atom. In the third P site, P(3) is bonded in a 6-coordinate geometry to one Cr(1), two equivalent Cr(5), two equivalent Cr(8), and one Co(2) atom. In the fourth P site, P(4) is bonded in a 6-coordinate geometry to two equivalent Cr(3), two equivalent Cr(6), one Co(1), and one Co(4) atom. In the fifth P site, P(5) is bonded in a 6-coordinate geometry to one Cr(1), two equivalent Cr(4), two equivalent Cr(7), and one Co(2) atom. In the sixth P site, P(6) is bonded in a 6-coordinate geometry to one Cr(2), two equivalent Cr(5), two equivalent Cr(8), and one Co(3) atom. In the seventh P site, P(7) is bonded in a 6-coordinate geometry to one Cr(4), one Cr(7), two equivalent Co(1), and two equivalent Co(4) atoms. In the eighth P site, P(8) is bonded in a 6-coordinate geometry to one Cr(5), one Cr(8), two equivalent Cr(1), and two equivalent Co(2) atoms. In the ninth P site, P(9) is bonded in a 6-coordinate geometry to one Cr(3), one Cr(6), two equivalent Cr(2), and two equivalent Co(3) atoms. In the tenth P site, P(10) is bonded in a 6-coordinate geometry to one Cr(3), one Cr(6), two equivalent Co(1), and two equivalent Co(4) atoms. In the eleventh P site, P(11) is bonded in a 6-coordinate geometry to one Cr(4), one Cr(7), two equivalent Cr(1), and two equivalent Co(2) atoms. In the twelfth P site, P(12) is bonded in a 6-coordinate geometry to one Cr(5), one Cr(8), two equivalent Cr(2), and two equivalent Co(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr2CoP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.109
_cell_length_b   5.262
_cell_length_c   17.620
_cell_angle_alpha   89.991
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   288.264
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.009  0.603  1.0
  Cr  Cr1  1  0.000  0.008  0.938  1.0
  Cr  Cr2  1  0.500  0.497  0.101  1.0
  Cr  Cr3  1  0.500  0.494  0.432  1.0
  Cr  Cr4  1  0.500  0.493  0.766  1.0
  Cr  Cr5  1  0.500  0.997  0.067  1.0
  Cr  Cr6  1  0.500  0.996  0.398  1.0
  Cr  Cr7  1  0.500  0.995  0.732  1.0
  Co  Co8  1  0.000  0.501  0.233  1.0
  Co  Co9  1  0.000  0.506  0.566  1.0
  Co  Co10  1  0.000  0.505  0.899  1.0
  Co  Co11  1  0.000  0.001  0.266  1.0
  P  P12  1  0.000  0.686  0.022  1.0
  P  P13  1  0.000  0.690  0.353  1.0
  P  P14  1  0.000  0.688  0.688  1.0
  P  P15  1  0.000  0.190  0.147  1.0
  P  P16  1  0.000  0.183  0.479  1.0
  P  P17  1  0.000  0.183  0.813  1.0
  P  P18  1  0.500  0.312  0.307  1.0
  P  P19  1  0.500  0.317  0.642  1.0
  P  P20  1  0.500  0.318  0.976  1.0
  P  P21  1  0.500  0.812  0.191  1.0
  P  P22  1  0.500  0.809  0.524  1.0
  P  P23  1  0.500  0.809  0.857  1.0
[/CIF]
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The material described by Cr2CoP3 is Modderite-derived structured and crystallizes in the monoclinic Pm space group. There are eight inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 6-coordinate geometry to one P(3), one P(5), two equivalent P(11), and two equivalent P(8) atoms. In the second Cr site, Cr(2) is bonded in a 6-coordinate geometry to one P(1), one P(6), two equivalent P(12), and two equivalent P(9) atoms. In the third Cr site, Cr(3) is bonded in a 6-coordinate geometry to one P(10), one P(9), two equivalent P(1), and two equivalent P(4) atoms. In the fourth Cr site, Cr(4) is bonded in a 6-coordinate geometry to one P(11), one P(7), two equivalent P(2), and two equivalent P(5) atoms. In the fifth Cr site, Cr(5) is bonded in a 6-coordinate geometry to one P(12), one P(8), two equivalent P(3), and two equivalent P(6) atoms. In the sixth Cr site, Cr(6) is bonded in a 6-coordinate geometry to one P(10), one P(9), two equivalent P(1), and two equivalent P(4) atoms. In the seventh Cr site, Cr(7) is bonded in a 6-coordinate geometry to one P(11), one P(7), two equivalent P(2), and two equivalent P(5) atoms. In the eighth Cr site, Cr(8) is bonded in a 6-coordinate geometry to one P(12), one P(8), two equivalent P(3), and two equivalent P(6) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one P(2), one P(4), two equivalent P(10), and two equivalent P(7) atoms. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one P(3), one P(5), two equivalent P(11), and two equivalent P(8) atoms. In the third Co site, Co(3) is bonded in a 6-coordinate geometry to one P(1), one P(6), two equivalent P(12), and two equivalent P(9) atoms. In the fourth Co site, Co(4) is bonded in a 6-coordinate geometry to one P(2), one P(4), two equivalent P(10), and two equivalent P(7) atoms. There are twelve inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to one Cr(2), two equivalent Cr(3), two equivalent Cr(6), and one Co(3) atom. In the second P site, P(2) is bonded in a 6-coordinate geometry to two equivalent Cr(4), two equivalent Cr(7), one Co(1), and one Co(4) atom. In the third P site, P(3) is bonded in a 6-coordinate geometry to one Cr(1), two equivalent Cr(5), two equivalent Cr(8), and one Co(2) atom. In the fourth P site, P(4) is bonded in a 6-coordinate geometry to two equivalent Cr(3), two equivalent Cr(6), one Co(1), and one Co(4) atom. In the fifth P site, P(5) is bonded in a 6-coordinate geometry to one Cr(1), two equivalent Cr(4), two equivalent Cr(7), and one Co(2) atom. In the sixth P site, P(6) is bonded in a 6-coordinate geometry to one Cr(2), two equivalent Cr(5), two equivalent Cr(8), and one Co(3) atom. In the seventh P site, P(7) is bonded in a 6-coordinate geometry to one Cr(4), one Cr(7), two equivalent Co(1), and two equivalent Co(4) atoms. In the eighth P site, P(8) is bonded in a 6-coordinate geometry to one Cr(5), one Cr(8), two equivalent Cr(1), and two equivalent Co(2) atoms. In the ninth P site, P(9) is bonded in a 6-coordinate geometry to one Cr(3), one Cr(6), two equivalent Cr(2), and two equivalent Co(3) atoms. In the tenth P site, P(10) is bonded in a 6-coordinate geometry to one Cr(3), one Cr(6), two equivalent Co(1), and two equivalent Co(4) atoms. In the eleventh P site, P(11) is bonded in a 6-coordinate geometry to one Cr(4), one Cr(7), two equivalent Cr(1), and two equivalent Co(2) atoms. In the twelfth P site, P(12) is bonded in a 6-coordinate geometry to one Cr(5), one Cr(8), two equivalent Cr(2), and two equivalent Co(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr2CoP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.109
_cell_length_b   5.262
_cell_length_c   17.620
_cell_angle_alpha   89.991
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   288.264
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.009  0.603  1.0
  Cr  Cr1  1  0.000  0.008  0.938  1.0
  Cr  Cr2  1  0.500  0.497  0.101  1.0
  Cr  Cr3  1  0.500  0.494  0.432  1.0
  Cr  Cr4  1  0.500  0.493  0.766  1.0
  Cr  Cr5  1  0.500  0.997  0.067  1.0
  Cr  Cr6  1  0.500  0.996  0.398  1.0
  Cr  Cr7  1  0.500  0.995  0.732  1.0
  Co  Co8  1  0.000  0.501  0.233  1.0
  Co  Co9  1  0.000  0.506  0.566  1.0
  Co  Co10  1  0.000  0.505  0.899  1.0
  Co  Co11  1  0.000  0.001  0.266  1.0
  P  P12  1  0.000  0.686  0.022  1.0
  P  P13  1  0.000  0.690  0.353  1.0
  P  P14  1  0.000  0.688  0.688  1.0
  P  P15  1  0.000  0.190  0.147  1.0
  P  P16  1  0.000  0.183  0.479  1.0
  P  P17  1  0.000  0.183  0.813  1.0
  P  P18  1  0.500  0.312  0.307  1.0
  P  P19  1  0.500  0.317  0.642  1.0
  P  P20  1  0.500  0.318  0.976  1.0
  P  P21  1  0.500  0.812  0.191  1.0
  P  P22  1  0.500  0.809  0.524  1.0
  P  P23  1  0.500  0.809  0.857  1.0
[/CIF]
.