The crystal structure described by KSbWO6 crystallizes in the orthorhombic Ima2 space group. K(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(4) atoms. W(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-42°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.366
_cell_length_b   7.366
_cell_length_c   7.366
_cell_angle_alpha   120.744
_cell_angle_beta   119.673
_cell_angle_gamma   89.642
_symmetry_Int_Tables_number   1
_cell_volume   281.662
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.595  0.903  0.192  1.0
  K  K1  1  0.289  0.097  0.692  1.0
  Sb  Sb2  1  0.999  0.500  0.499  1.0
  Sb  Sb3  1  0.999  0.000  0.999  1.0
  W  W4  1  0.996  0.499  0.997  1.0
  W  W5  1  0.498  0.501  0.497  1.0
  O  O6  1  0.079  0.826  0.753  1.0
  O  O7  1  0.691  0.441  0.750  1.0
  O  O8  1  0.680  0.812  0.748  1.0
  O  O9  1  0.067  0.434  0.754  1.0
  O  O10  1  0.067  0.813  0.133  1.0
  O  O11  1  0.680  0.432  0.367  1.0
  O  O12  1  0.927  0.174  0.253  1.0
  O  O13  1  0.309  0.559  0.250  1.0
  O  O14  1  0.320  0.187  0.254  1.0
  O  O15  1  0.936  0.568  0.248  1.0
  O  O16  1  0.936  0.188  0.867  1.0
  O  O17  1  0.320  0.566  0.633  1.0
[/CIF]
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The crystal structure described by KSbWO6 crystallizes in the orthorhombic Ima2 space group. K(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(4) atoms. W(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-42°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.366
_cell_length_b   7.366
_cell_length_c   7.366
_cell_angle_alpha   120.744
_cell_angle_beta   119.673
_cell_angle_gamma   89.642
_symmetry_Int_Tables_number   1
_cell_volume   281.662
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.595  0.903  0.192  1.0
  K  K1  1  0.289  0.097  0.692  1.0
  Sb  Sb2  1  0.999  0.500  0.499  1.0
  Sb  Sb3  1  0.999  0.000  0.999  1.0
  W  W4  1  0.996  0.499  0.997  1.0
  W  W5  1  0.498  0.501  0.497  1.0
  O  O6  1  0.079  0.826  0.753  1.0
  O  O7  1  0.691  0.441  0.750  1.0
  O  O8  1  0.680  0.812  0.748  1.0
  O  O9  1  0.067  0.434  0.754  1.0
  O  O10  1  0.067  0.813  0.133  1.0
  O  O11  1  0.680  0.432  0.367  1.0
  O  O12  1  0.927  0.174  0.253  1.0
  O  O13  1  0.309  0.559  0.250  1.0
  O  O14  1  0.320  0.187  0.254  1.0
  O  O15  1  0.936  0.568  0.248  1.0
  O  O16  1  0.936  0.188  0.867  1.0
  O  O17  1  0.320  0.566  0.633  1.0
[/CIF]
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