The crystal structure described by Ca5Mn8O13 is Caswellsilverite-like structured and crystallizes in the trigonal R3m space group. There are five inequivalent Ca sites. In the first Ca site, Ca(1) is bonded to three equivalent O(5) and three equivalent O(6) atoms to form CaO6 octahedra that share corners with three equivalent Mn(5)O6 octahedra, corners with three equivalent Mn(6)O6 octahedra, edges with three equivalent Mn(5)O6 octahedra, edges with three equivalent Mn(6)O6 octahedra, and edges with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. In the second Ca site, Ca(2) is bonded to three equivalent O(7) and three equivalent O(9) atoms to form CaO6 octahedra that share corners with three equivalent Mn(7)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra, edges with three equivalent Mn(7)O6 octahedra, edges with three equivalent Mn(8)O6 octahedra, and edges with six equivalent Ca(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-3°. In the third Ca site, Ca(3) is bonded to three equivalent O(10) and three equivalent O(11) atoms to form CaO6 octahedra that share corners with three equivalent Ca(5)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra, edges with three equivalent Ca(5)O6 octahedra, edges with three equivalent Mn(8)O6 octahedra, and edges with six equivalent Ca(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth Ca site, Ca(4) is bonded to three equivalent O(12) and three equivalent O(13) atoms to form CaO6 octahedra that share corners with three equivalent Ca(5)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra, edges with three equivalent Ca(5)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and edges with six equivalent Ca(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fifth Ca site, Ca(5) is bonded to three equivalent O(11) and three equivalent O(12) atoms to form a mixture of corner and edge-sharing CaO6 octahedra. The corner-sharing octahedra are not tilted. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to three equivalent O(1) and three equivalent O(13) atoms to form MnO6 octahedra that share corners with three equivalent Ca(4)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra, edges with three equivalent Ca(4)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, and edges with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second Mn site, Mn(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the third Mn site, Mn(3) is bonded to three equivalent O(2) and three equivalent O(3) atoms to form a mixture of corner and edge-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the fourth Mn site, Mn(4) is bonded to three equivalent O(3) and three equivalent O(4) atoms to form a mixture of corner and edge-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the fifth Mn site, Mn(5) is bonded to three equivalent O(4) and three equivalent O(5) atoms to form MnO6 octahedra that share corners with three equivalent Ca(1)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra, edges with three equivalent Ca(1)O6 octahedra, edges with three equivalent Mn(4)O6 octahedra, and edges with six equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the sixth Mn site, Mn(6) is bonded to three equivalent O(6) and three equivalent O(8) atoms to form MnO6 octahedra that share corners with three equivalent Ca(1)O6 octahedra, corners with three equivalent Mn(7)O6 octahedra, edges with three equivalent Ca(1)O6 octahedra, edges with three equivalent Mn(7)O6 octahedra, and edges with six equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the seventh Mn site, Mn(7) is bonded to three equivalent O(7) and three equivalent O(8) atoms to form MnO6 octahedra that share corners with three equivalent Ca(2)O6 octahedra, corners with three equivalent Mn(6)O6 octahedra, edges with three equivalent Ca(2)O6 octahedra, edges with three equivalent Mn(6)O6 octahedra, and edges with six equivalent Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the eighth Mn site, Mn(8) is bonded to three equivalent O(10) and three equivalent O(9) atoms to form MnO6 octahedra that share corners with three equivalent Ca(2)O6 octahedra, corners with three equivalent Ca(3)O6 octahedra, edges with three equivalent Ca(2)O6 octahedra, edges with three equivalent Ca(3)O6 octahedra, and edges with six equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Mn(1) and three equivalent Mn(2) atoms to form OMn6 octahedra that share corners with three equivalent O(13)Ca3Mn3 octahedra, corners with three equivalent O(2)Mn6 octahedra, edges with three equivalent O(13)Ca3Mn3 octahedra, edges with three equivalent O(2)Mn6 octahedra, and edges with six equivalent O(1)Mn6 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded to three equivalent Mn(2) and three equivalent Mn(3) atoms to form a mixture of corner and edge-sharing OMn6 octahedra. The corner-sharing octahedra are not tilted. In the third O site, O(3) is bonded to three equivalent Mn(3) and three equivalent Mn(4) atoms to form a mixture of corner and edge-sharing OMn6 octahedra. The corner-sharing octahedra are not tilted. In the fourth O site, O(4) is bonded to three equivalent Mn(4) and three equivalent Mn(5) atoms to form OMn6 octahedra that share corners with three equivalent O(5)Ca3Mn3 octahedra, corners with three equivalent O(3)Mn6 octahedra, edges with three equivalent O(5)Ca3Mn3 octahedra, edges with three equivalent O(3)Mn6 octahedra, and edges with six equivalent O(4)Mn6 octahedra. The corner-sharing octahedra are not tilted. In the fifth O site, O(5) is bonded to three equivalent Ca(1) and three equivalent Mn(5) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(6)Ca3Mn3 octahedra, corners with three equivalent O(4)Mn6 octahedra, edges with three equivalent O(6)Ca3Mn3 octahedra, edges with three equivalent O(4)Mn6 octahedra, and edges with six equivalent O(5)Ca3Mn3 octahedra. The corner-sharing octahedra are not tilted. In the sixth O site, O(6) is bonded to three equivalent Ca(1) and three equivalent Mn(6) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(5)Ca3Mn3 octahedra, corners with three equivalent O(8)Mn6 octahedra, edges with three equivalent O(5)Ca3Mn3 octahedra, edges with three equivalent O(8)Mn6 octahedra, and edges with six equivalent O(6)Ca3Mn3 octahedra. The corner-sharing octahedra are not tilted. In the seventh O site, O(7) is bonded to three equivalent Ca(2) and three equivalent Mn(7) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(9)Ca3Mn3 octahedra, corners with three equivalent O(8)Mn6 octahedra, edges with three equivalent O(9)Ca3Mn3 octahedra, edges with three equivalent O(8)Mn6 octahedra, and edges with six equivalent O(7)Ca3Mn3 octahedra. The corner-sharing octahedra are not tilted. In the eighth O site, O(8) is bonded to three equivalent Mn(6) and three equivalent Mn(7) atoms to form OMn6 octahedra that share corners with three equivalent O(6)Ca3Mn3 octahedra, corners with three equivalent O(7)Ca3Mn3 octahedra, edges with three equivalent O(6)Ca3Mn3 octahedra, edges with three equivalent O(7)Ca3Mn3 octahedra, and edges with six equivalent O(8)Mn6 octahedra. The corner-sharing octahedra are not tilted. In the ninth O site, O(9) is bonded to three equivalent Ca(2) and three equivalent Mn(8) atoms to form a mixture of corner and edge-sharing OCa3Mn3 octahedra. The corner-sharing octahedra are not tilted. In the tenth O site, O(10) is bonded to three equivalent Ca(3) and three equivalent Mn(8) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(9)Ca3Mn3 octahedra, corners with three equivalent O(11)Ca6 octahedra, edges with three equivalent O(9)Ca3Mn3 octahedra, edges with three equivalent O(11)Ca6 octahedra, and edges with six equivalent O(10)Ca3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the eleventh O site, O(11) is bonded to three equivalent Ca(3) and three equivalent Ca(5) atoms to form OCa6 octahedra that share corners with three equivalent O(10)Ca3Mn3 octahedra, corners with three equivalent O(12)Ca6 octahedra, edges with three equivalent O(10)Ca3Mn3 octahedra, edges with three equivalent O(12)Ca6 octahedra, and edges with six equivalent O(11)Ca6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the twelfth O site, O(12) is bonded to three equivalent Ca(4) and three equivalent Ca(5) atoms to form OCa6 octahedra that share corners with three equivalent O(13)Ca3Mn3 octahedra, corners with three equivalent O(11)Ca6 octahedra, edges with three equivalent O(13)Ca3Mn3 octahedra, edges with three equivalent O(11)Ca6 octahedra, and edges with six equivalent O(12)Ca6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the thirteenth O site, O(13) is bonded to three equivalent Ca(4) and three equivalent Mn(1) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(12)Ca6 octahedra, corners with three equivalent O(1)Mn6 octahedra, edges with three equivalent O(12)Ca6 octahedra, edges with three equivalent O(1)Mn6 octahedra, and edges with six equivalent O(13)Ca3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ca5Mn8O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.291
_cell_length_b   3.291
_cell_length_c   34.552
_cell_angle_alpha   92.729
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   323.551
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.461  0.922  0.383  1.0
  Ca  Ca1  1  0.537  0.075  0.612  1.0
  Ca  Ca2  1  0.922  0.844  0.765  1.0
  Ca  Ca3  1  0.310  0.620  0.930  1.0
  Ca  Ca4  1  0.616  0.232  0.848  1.0
  Mn  Mn5  1  0.002  0.005  0.007  1.0
  Mn  Mn6  1  0.694  0.387  0.081  1.0
  Mn  Mn7  1  0.385  0.770  0.155  1.0
  Mn  Mn8  1  0.077  0.153  0.230  1.0
  Mn  Mn9  1  0.768  0.536  0.304  1.0
  Mn  Mn10  1  0.154  0.307  0.461  1.0
  Mn  Mn11  1  0.845  0.690  0.535  1.0
  Mn  Mn12  1  0.230  0.459  0.689  1.0
  O  O13  1  0.348  0.696  0.044  1.0
  O  O14  1  0.039  0.079  0.118  1.0
  O  O15  1  0.731  0.461  0.192  1.0
  O  O16  1  0.422  0.845  0.267  1.0
  O  O17  1  0.114  0.228  0.342  1.0
  O  O18  1  0.808  0.616  0.424  1.0
  O  O19  1  0.191  0.381  0.572  1.0
  O  O20  1  0.499  0.999  0.498  1.0
  O  O21  1  0.884  0.768  0.652  1.0
  O  O22  1  0.575  0.150  0.725  1.0
  O  O23  1  0.269  0.538  0.807  1.0
  O  O24  1  0.963  0.926  0.889  1.0
  O  O25  1  0.657  0.314  0.970  1.0
[/CIF]
.
The crystal structure described by Ca5Mn8O13 is Caswellsilverite-like structured and crystallizes in the trigonal R3m space group. There are five inequivalent Ca sites. In the first Ca site, Ca(1) is bonded to three equivalent O(5) and three equivalent O(6) atoms to form CaO6 octahedra that share corners with three equivalent Mn(5)O6 octahedra, corners with three equivalent Mn(6)O6 octahedra, edges with three equivalent Mn(5)O6 octahedra, edges with three equivalent Mn(6)O6 octahedra, and edges with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. In the second Ca site, Ca(2) is bonded to three equivalent O(7) and three equivalent O(9) atoms to form CaO6 octahedra that share corners with three equivalent Mn(7)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra, edges with three equivalent Mn(7)O6 octahedra, edges with three equivalent Mn(8)O6 octahedra, and edges with six equivalent Ca(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-3°. In the third Ca site, Ca(3) is bonded to three equivalent O(10) and three equivalent O(11) atoms to form CaO6 octahedra that share corners with three equivalent Ca(5)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra, edges with three equivalent Ca(5)O6 octahedra, edges with three equivalent Mn(8)O6 octahedra, and edges with six equivalent Ca(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth Ca site, Ca(4) is bonded to three equivalent O(12) and three equivalent O(13) atoms to form CaO6 octahedra that share corners with three equivalent Ca(5)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra, edges with three equivalent Ca(5)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and edges with six equivalent Ca(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fifth Ca site, Ca(5) is bonded to three equivalent O(11) and three equivalent O(12) atoms to form a mixture of corner and edge-sharing CaO6 octahedra. The corner-sharing octahedra are not tilted. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to three equivalent O(1) and three equivalent O(13) atoms to form MnO6 octahedra that share corners with three equivalent Ca(4)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra, edges with three equivalent Ca(4)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, and edges with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second Mn site, Mn(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the third Mn site, Mn(3) is bonded to three equivalent O(2) and three equivalent O(3) atoms to form a mixture of corner and edge-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the fourth Mn site, Mn(4) is bonded to three equivalent O(3) and three equivalent O(4) atoms to form a mixture of corner and edge-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the fifth Mn site, Mn(5) is bonded to three equivalent O(4) and three equivalent O(5) atoms to form MnO6 octahedra that share corners with three equivalent Ca(1)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra, edges with three equivalent Ca(1)O6 octahedra, edges with three equivalent Mn(4)O6 octahedra, and edges with six equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the sixth Mn site, Mn(6) is bonded to three equivalent O(6) and three equivalent O(8) atoms to form MnO6 octahedra that share corners with three equivalent Ca(1)O6 octahedra, corners with three equivalent Mn(7)O6 octahedra, edges with three equivalent Ca(1)O6 octahedra, edges with three equivalent Mn(7)O6 octahedra, and edges with six equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the seventh Mn site, Mn(7) is bonded to three equivalent O(7) and three equivalent O(8) atoms to form MnO6 octahedra that share corners with three equivalent Ca(2)O6 octahedra, corners with three equivalent Mn(6)O6 octahedra, edges with three equivalent Ca(2)O6 octahedra, edges with three equivalent Mn(6)O6 octahedra, and edges with six equivalent Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the eighth Mn site, Mn(8) is bonded to three equivalent O(10) and three equivalent O(9) atoms to form MnO6 octahedra that share corners with three equivalent Ca(2)O6 octahedra, corners with three equivalent Ca(3)O6 octahedra, edges with three equivalent Ca(2)O6 octahedra, edges with three equivalent Ca(3)O6 octahedra, and edges with six equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Mn(1) and three equivalent Mn(2) atoms to form OMn6 octahedra that share corners with three equivalent O(13)Ca3Mn3 octahedra, corners with three equivalent O(2)Mn6 octahedra, edges with three equivalent O(13)Ca3Mn3 octahedra, edges with three equivalent O(2)Mn6 octahedra, and edges with six equivalent O(1)Mn6 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded to three equivalent Mn(2) and three equivalent Mn(3) atoms to form a mixture of corner and edge-sharing OMn6 octahedra. The corner-sharing octahedra are not tilted. In the third O site, O(3) is bonded to three equivalent Mn(3) and three equivalent Mn(4) atoms to form a mixture of corner and edge-sharing OMn6 octahedra. The corner-sharing octahedra are not tilted. In the fourth O site, O(4) is bonded to three equivalent Mn(4) and three equivalent Mn(5) atoms to form OMn6 octahedra that share corners with three equivalent O(5)Ca3Mn3 octahedra, corners with three equivalent O(3)Mn6 octahedra, edges with three equivalent O(5)Ca3Mn3 octahedra, edges with three equivalent O(3)Mn6 octahedra, and edges with six equivalent O(4)Mn6 octahedra. The corner-sharing octahedra are not tilted. In the fifth O site, O(5) is bonded to three equivalent Ca(1) and three equivalent Mn(5) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(6)Ca3Mn3 octahedra, corners with three equivalent O(4)Mn6 octahedra, edges with three equivalent O(6)Ca3Mn3 octahedra, edges with three equivalent O(4)Mn6 octahedra, and edges with six equivalent O(5)Ca3Mn3 octahedra. The corner-sharing octahedra are not tilted. In the sixth O site, O(6) is bonded to three equivalent Ca(1) and three equivalent Mn(6) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(5)Ca3Mn3 octahedra, corners with three equivalent O(8)Mn6 octahedra, edges with three equivalent O(5)Ca3Mn3 octahedra, edges with three equivalent O(8)Mn6 octahedra, and edges with six equivalent O(6)Ca3Mn3 octahedra. The corner-sharing octahedra are not tilted. In the seventh O site, O(7) is bonded to three equivalent Ca(2) and three equivalent Mn(7) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(9)Ca3Mn3 octahedra, corners with three equivalent O(8)Mn6 octahedra, edges with three equivalent O(9)Ca3Mn3 octahedra, edges with three equivalent O(8)Mn6 octahedra, and edges with six equivalent O(7)Ca3Mn3 octahedra. The corner-sharing octahedra are not tilted. In the eighth O site, O(8) is bonded to three equivalent Mn(6) and three equivalent Mn(7) atoms to form OMn6 octahedra that share corners with three equivalent O(6)Ca3Mn3 octahedra, corners with three equivalent O(7)Ca3Mn3 octahedra, edges with three equivalent O(6)Ca3Mn3 octahedra, edges with three equivalent O(7)Ca3Mn3 octahedra, and edges with six equivalent O(8)Mn6 octahedra. The corner-sharing octahedra are not tilted. In the ninth O site, O(9) is bonded to three equivalent Ca(2) and three equivalent Mn(8) atoms to form a mixture of corner and edge-sharing OCa3Mn3 octahedra. The corner-sharing octahedra are not tilted. In the tenth O site, O(10) is bonded to three equivalent Ca(3) and three equivalent Mn(8) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(9)Ca3Mn3 octahedra, corners with three equivalent O(11)Ca6 octahedra, edges with three equivalent O(9)Ca3Mn3 octahedra, edges with three equivalent O(11)Ca6 octahedra, and edges with six equivalent O(10)Ca3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the eleventh O site, O(11) is bonded to three equivalent Ca(3) and three equivalent Ca(5) atoms to form OCa6 octahedra that share corners with three equivalent O(10)Ca3Mn3 octahedra, corners with three equivalent O(12)Ca6 octahedra, edges with three equivalent O(10)Ca3Mn3 octahedra, edges with three equivalent O(12)Ca6 octahedra, and edges with six equivalent O(11)Ca6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the twelfth O site, O(12) is bonded to three equivalent Ca(4) and three equivalent Ca(5) atoms to form OCa6 octahedra that share corners with three equivalent O(13)Ca3Mn3 octahedra, corners with three equivalent O(11)Ca6 octahedra, edges with three equivalent O(13)Ca3Mn3 octahedra, edges with three equivalent O(11)Ca6 octahedra, and edges with six equivalent O(12)Ca6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the thirteenth O site, O(13) is bonded to three equivalent Ca(4) and three equivalent Mn(1) atoms to form OCa3Mn3 octahedra that share corners with three equivalent O(12)Ca6 octahedra, corners with three equivalent O(1)Mn6 octahedra, edges with three equivalent O(12)Ca6 octahedra, edges with three equivalent O(1)Mn6 octahedra, and edges with six equivalent O(13)Ca3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ca5Mn8O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.291
_cell_length_b   3.291
_cell_length_c   34.552
_cell_angle_alpha   92.729
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   323.551
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.461  0.922  0.383  1.0
  Ca  Ca1  1  0.537  0.075  0.612  1.0
  Ca  Ca2  1  0.922  0.844  0.765  1.0
  Ca  Ca3  1  0.310  0.620  0.930  1.0
  Ca  Ca4  1  0.616  0.232  0.848  1.0
  Mn  Mn5  1  0.002  0.005  0.007  1.0
  Mn  Mn6  1  0.694  0.387  0.081  1.0
  Mn  Mn7  1  0.385  0.770  0.155  1.0
  Mn  Mn8  1  0.077  0.153  0.230  1.0
  Mn  Mn9  1  0.768  0.536  0.304  1.0
  Mn  Mn10  1  0.154  0.307  0.461  1.0
  Mn  Mn11  1  0.845  0.690  0.535  1.0
  Mn  Mn12  1  0.230  0.459  0.689  1.0
  O  O13  1  0.348  0.696  0.044  1.0
  O  O14  1  0.039  0.079  0.118  1.0
  O  O15  1  0.731  0.461  0.192  1.0
  O  O16  1  0.422  0.845  0.267  1.0
  O  O17  1  0.114  0.228  0.342  1.0
  O  O18  1  0.808  0.616  0.424  1.0
  O  O19  1  0.191  0.381  0.572  1.0
  O  O20  1  0.499  0.999  0.498  1.0
  O  O21  1  0.884  0.768  0.652  1.0
  O  O22  1  0.575  0.150  0.725  1.0
  O  O23  1  0.269  0.538  0.807  1.0
  O  O24  1  0.963  0.926  0.889  1.0
  O  O25  1  0.657  0.314  0.970  1.0
[/CIF]
.