The material described by Cs2SnF6 crystallizes in the trigonal P-3m1 space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form distorted CsF12 cuboctahedra that share corners with six equivalent Cs(1)F12 cuboctahedra, corners with three equivalent Sn(1)F6 octahedra, faces with eight equivalent Cs(1)F12 cuboctahedra, and faces with three equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 17°. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Cs(1)F12 cuboctahedra and faces with six equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2SnF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.304
_cell_length_b   6.304
_cell_length_c   5.004
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   172.241
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.667  0.333  0.697  1.0
  Cs  Cs1  1  0.333  0.667  0.303  1.0
  Sn  Sn2  1  0.000  0.000  0.000  1.0
  F  F3  1  0.848  0.152  0.219  1.0
  F  F4  1  0.848  0.697  0.219  1.0
  F  F5  1  0.303  0.152  0.219  1.0
  F  F6  1  0.152  0.848  0.781  1.0
  F  F7  1  0.152  0.303  0.781  1.0
  F  F8  1  0.697  0.848  0.781  1.0
[/CIF]
.
The material described by Cs2SnF6 crystallizes in the trigonal P-3m1 space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form distorted CsF12 cuboctahedra that share corners with six equivalent Cs(1)F12 cuboctahedra, corners with three equivalent Sn(1)F6 octahedra, faces with eight equivalent Cs(1)F12 cuboctahedra, and faces with three equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 17°. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Cs(1)F12 cuboctahedra and faces with six equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2SnF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.304
_cell_length_b   6.304
_cell_length_c   5.004
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   172.241
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.667  0.333  0.697  1.0
  Cs  Cs1  1  0.333  0.667  0.303  1.0
  Sn  Sn2  1  0.000  0.000  0.000  1.0
  F  F3  1  0.848  0.152  0.219  1.0
  F  F4  1  0.848  0.697  0.219  1.0
  F  F5  1  0.303  0.152  0.219  1.0
  F  F6  1  0.152  0.848  0.781  1.0
  F  F7  1  0.152  0.303  0.781  1.0
  F  F8  1  0.697  0.848  0.781  1.0
[/CIF]
.