The material described by (WO3Cl2)4O2 is Indium-derived structured and crystallizes in the orthorhombic Ccce space group. The structure is zero-dimensional and consists of eight water atoms and four WO3Cl2 clusters. In each WO3Cl2 cluster, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one Cl(1), and one Cl(2) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(4) is bonded in a linear geometry to two equivalent W(1) atoms. In the third O site, O(1) is bonded in a single-bond geometry to one W(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one W(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_W2Cl4O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.252
_cell_length_b   13.252
_cell_length_c   12.163
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   129.395
_symmetry_Int_Tables_number   1
_cell_volume   1650.611
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.565  0.406  0.658  1.0
  W  W1  1  0.094  0.935  0.158  1.0
  W  W2  1  0.906  0.065  0.158  1.0
  W  W3  1  0.435  0.594  0.658  1.0
  W  W4  1  0.935  0.094  0.842  1.0
  W  W5  1  0.406  0.565  0.342  1.0
  W  W6  1  0.594  0.435  0.342  1.0
  W  W7  1  0.065  0.906  0.842  1.0
  Cl  Cl8  1  0.722  0.369  0.653  1.0
  Cl  Cl9  1  0.131  0.778  0.153  1.0
  Cl  Cl10  1  0.869  0.222  0.153  1.0
  Cl  Cl11  1  0.278  0.631  0.653  1.0
  Cl  Cl12  1  0.778  0.131  0.847  1.0
  Cl  Cl13  1  0.369  0.722  0.347  1.0
  Cl  Cl14  1  0.631  0.278  0.347  1.0
  Cl  Cl15  1  0.222  0.869  0.847  1.0
  Cl  Cl16  1  0.617  0.455  0.847  1.0
  Cl  Cl17  1  0.045  0.883  0.347  1.0
  Cl  Cl18  1  0.955  0.117  0.347  1.0
  Cl  Cl19  1  0.383  0.545  0.847  1.0
  Cl  Cl20  1  0.883  0.045  0.653  1.0
  Cl  Cl21  1  0.455  0.617  0.153  1.0
  Cl  Cl22  1  0.545  0.383  0.153  1.0
  Cl  Cl23  1  0.117  0.955  0.653  1.0
  O  O24  1  0.428  0.243  0.670  1.0
  O  O25  1  0.257  0.072  0.170  1.0
  O  O26  1  0.743  0.928  0.170  1.0
  O  O27  1  0.572  0.757  0.670  1.0
  O  O28  1  0.072  0.257  0.830  1.0
  O  O29  1  0.243  0.428  0.330  1.0
  O  O30  1  0.757  0.572  0.330  1.0
  O  O31  1  0.928  0.743  0.830  1.0
  O  O32  1  0.768  0.576  0.661  1.0
  O  O33  1  0.924  0.732  0.161  1.0
  O  O34  1  0.076  0.268  0.161  1.0
  O  O35  1  0.232  0.424  0.661  1.0
  O  O36  1  0.732  0.924  0.839  1.0
  O  O37  1  0.576  0.768  0.339  1.0
  O  O38  1  0.424  0.232  0.339  1.0
  O  O39  1  0.268  0.076  0.839  1.0
  O  O40  1  0.500  0.500  0.660  1.0
  O  O41  1  0.000  0.000  0.160  1.0
  O  O42  1  0.000  0.000  0.840  1.0
  O  O43  1  0.500  0.500  0.340  1.0
  O  O44  1  0.578  0.422  0.500  1.0
  O  O45  1  0.078  0.922  0.000  1.0
  O  O46  1  0.922  0.078  0.000  1.0
  O  O47  1  0.422  0.578  0.500  1.0
  O  O48  1  0.215  0.215  0.500  1.0
  O  O49  1  0.285  0.285  0.000  1.0
  O  O50  1  0.715  0.715  0.000  1.0
  O  O51  1  0.785  0.785  0.500  1.0
[/CIF]
.
The material described by (WO3Cl2)4O2 is Indium-derived structured and crystallizes in the orthorhombic Ccce space group. The structure is zero-dimensional and consists of eight water atoms and four WO3Cl2 clusters. In each WO3Cl2 cluster, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one Cl(1), and one Cl(2) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(4) is bonded in a linear geometry to two equivalent W(1) atoms. In the third O site, O(1) is bonded in a single-bond geometry to one W(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one W(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_W2Cl4O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.252
_cell_length_b   13.252
_cell_length_c   12.163
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   129.395
_symmetry_Int_Tables_number   1
_cell_volume   1650.611
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.565  0.406  0.658  1.0
  W  W1  1  0.094  0.935  0.158  1.0
  W  W2  1  0.906  0.065  0.158  1.0
  W  W3  1  0.435  0.594  0.658  1.0
  W  W4  1  0.935  0.094  0.842  1.0
  W  W5  1  0.406  0.565  0.342  1.0
  W  W6  1  0.594  0.435  0.342  1.0
  W  W7  1  0.065  0.906  0.842  1.0
  Cl  Cl8  1  0.722  0.369  0.653  1.0
  Cl  Cl9  1  0.131  0.778  0.153  1.0
  Cl  Cl10  1  0.869  0.222  0.153  1.0
  Cl  Cl11  1  0.278  0.631  0.653  1.0
  Cl  Cl12  1  0.778  0.131  0.847  1.0
  Cl  Cl13  1  0.369  0.722  0.347  1.0
  Cl  Cl14  1  0.631  0.278  0.347  1.0
  Cl  Cl15  1  0.222  0.869  0.847  1.0
  Cl  Cl16  1  0.617  0.455  0.847  1.0
  Cl  Cl17  1  0.045  0.883  0.347  1.0
  Cl  Cl18  1  0.955  0.117  0.347  1.0
  Cl  Cl19  1  0.383  0.545  0.847  1.0
  Cl  Cl20  1  0.883  0.045  0.653  1.0
  Cl  Cl21  1  0.455  0.617  0.153  1.0
  Cl  Cl22  1  0.545  0.383  0.153  1.0
  Cl  Cl23  1  0.117  0.955  0.653  1.0
  O  O24  1  0.428  0.243  0.670  1.0
  O  O25  1  0.257  0.072  0.170  1.0
  O  O26  1  0.743  0.928  0.170  1.0
  O  O27  1  0.572  0.757  0.670  1.0
  O  O28  1  0.072  0.257  0.830  1.0
  O  O29  1  0.243  0.428  0.330  1.0
  O  O30  1  0.757  0.572  0.330  1.0
  O  O31  1  0.928  0.743  0.830  1.0
  O  O32  1  0.768  0.576  0.661  1.0
  O  O33  1  0.924  0.732  0.161  1.0
  O  O34  1  0.076  0.268  0.161  1.0
  O  O35  1  0.232  0.424  0.661  1.0
  O  O36  1  0.732  0.924  0.839  1.0
  O  O37  1  0.576  0.768  0.339  1.0
  O  O38  1  0.424  0.232  0.339  1.0
  O  O39  1  0.268  0.076  0.839  1.0
  O  O40  1  0.500  0.500  0.660  1.0
  O  O41  1  0.000  0.000  0.160  1.0
  O  O42  1  0.000  0.000  0.840  1.0
  O  O43  1  0.500  0.500  0.340  1.0
  O  O44  1  0.578  0.422  0.500  1.0
  O  O45  1  0.078  0.922  0.000  1.0
  O  O46  1  0.922  0.078  0.000  1.0
  O  O47  1  0.422  0.578  0.500  1.0
  O  O48  1  0.215  0.215  0.500  1.0
  O  O49  1  0.285  0.285  0.000  1.0
  O  O50  1  0.715  0.715  0.000  1.0
  O  O51  1  0.785  0.785  0.500  1.0
[/CIF]
.