The structure described by Li2PbGeS4 crystallizes in the tetragonal I-42m space group. Li(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. Pb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Ge(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 3-coordinate geometry to two equivalent Li(1), two equivalent Pb(1), and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2GePbS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.101
_cell_length_b   6.101
_cell_length_c   6.101
_cell_angle_alpha   114.840
_cell_angle_beta   114.840
_cell_angle_gamma   99.197
_symmetry_Int_Tables_number   1
_cell_volume   170.712
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.250  0.500  1.0
  Li  Li1  1  0.250  0.750  0.500  1.0
  Ge  Ge2  1  0.500  0.500  0.000  1.0
  Pb  Pb3  1  0.000  0.000  0.000  1.0
  S  S4  1  0.466  0.860  0.000  1.0
  S  S5  1  0.140  0.140  0.606  1.0
  S  S6  1  0.534  0.534  0.394  1.0
  S  S7  1  0.860  0.466  0.000  1.0
[/CIF]
.
The structure described by Li2PbGeS4 crystallizes in the tetragonal I-42m space group. Li(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. Pb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Ge(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 3-coordinate geometry to two equivalent Li(1), two equivalent Pb(1), and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2GePbS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.101
_cell_length_b   6.101
_cell_length_c   6.101
_cell_angle_alpha   114.840
_cell_angle_beta   114.840
_cell_angle_gamma   99.197
_symmetry_Int_Tables_number   1
_cell_volume   170.712
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.250  0.500  1.0
  Li  Li1  1  0.250  0.750  0.500  1.0
  Ge  Ge2  1  0.500  0.500  0.000  1.0
  Pb  Pb3  1  0.000  0.000  0.000  1.0
  S  S4  1  0.466  0.860  0.000  1.0
  S  S5  1  0.140  0.140  0.606  1.0
  S  S6  1  0.534  0.534  0.394  1.0
  S  S7  1  0.860  0.466  0.000  1.0
[/CIF]
.