The compound described by Pb3Cd3(BO3)4 crystallizes in the hexagonal P6_3/m space group. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form edge-sharing CdO6 octahedra. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(3) atoms. In the second B site, B(2) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. Pb(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a 1-coordinate geometry to one Cd(1), one B(1), and two equivalent Pb(1) atoms. In the second O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Cd(1), one B(2), and one Pb(1) atom. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one B(1) atom. is represented by the CIF file [CIF]
data_Cd3B4(PbO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.147
_cell_length_b   10.147
_cell_length_c   7.120
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   634.870
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.000  0.000  1.0
  Cd  Cd1  1  0.500  0.500  0.000  1.0
  Cd  Cd2  1  0.000  0.500  0.000  1.0
  Cd  Cd3  1  0.500  0.000  0.500  1.0
  Cd  Cd4  1  0.500  0.500  0.500  1.0
  Cd  Cd5  1  0.000  0.500  0.500  1.0
  B  B6  1  0.608  0.809  0.750  1.0
  B  B7  1  0.201  0.392  0.750  1.0
  B  B8  1  0.191  0.799  0.750  1.0
  B  B9  1  0.392  0.191  0.250  1.0
  B  B10  1  0.799  0.608  0.250  1.0
  B  B11  1  0.809  0.201  0.250  1.0
  B  B12  1  0.667  0.333  0.750  1.0
  B  B13  1  0.333  0.667  0.250  1.0
  Pb  Pb14  1  0.847  0.133  0.750  1.0
  Pb  Pb15  1  0.286  0.153  0.750  1.0
  Pb  Pb16  1  0.867  0.714  0.750  1.0
  Pb  Pb17  1  0.153  0.867  0.250  1.0
  Pb  Pb18  1  0.714  0.847  0.250  1.0
  Pb  Pb19  1  0.133  0.286  0.250  1.0
  O  O20  1  0.651  0.188  0.750  1.0
  O  O21  1  0.537  0.349  0.750  1.0
  O  O22  1  0.812  0.463  0.750  1.0
  O  O23  1  0.349  0.812  0.250  1.0
  O  O24  1  0.463  0.651  0.250  1.0
  O  O25  1  0.188  0.537  0.250  1.0
  O  O26  1  0.346  0.894  0.750  1.0
  O  O27  1  0.548  0.654  0.750  1.0
  O  O28  1  0.106  0.452  0.750  1.0
  O  O29  1  0.654  0.106  0.250  1.0
  O  O30  1  0.452  0.346  0.250  1.0
  O  O31  1  0.894  0.548  0.250  1.0
  O  O32  1  0.648  0.894  0.917  1.0
  O  O33  1  0.246  0.352  0.917  1.0
  O  O34  1  0.106  0.754  0.917  1.0
  O  O35  1  0.352  0.106  0.417  1.0
  O  O36  1  0.754  0.648  0.417  1.0
  O  O37  1  0.894  0.246  0.417  1.0
  O  O38  1  0.352  0.106  0.083  1.0
  O  O39  1  0.754  0.648  0.083  1.0
  O  O40  1  0.894  0.246  0.083  1.0
  O  O41  1  0.648  0.894  0.583  1.0
  O  O42  1  0.246  0.352  0.583  1.0
  O  O43  1  0.106  0.754  0.583  1.0
[/CIF]
.
The compound described by Pb3Cd3(BO3)4 crystallizes in the hexagonal P6_3/m space group. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form edge-sharing CdO6 octahedra. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(3) atoms. In the second B site, B(2) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. Pb(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a 1-coordinate geometry to one Cd(1), one B(1), and two equivalent Pb(1) atoms. In the second O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Cd(1), one B(2), and one Pb(1) atom. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one B(1) atom. is represented by the CIF file [CIF]
data_Cd3B4(PbO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.147
_cell_length_b   10.147
_cell_length_c   7.120
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   634.870
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.000  0.000  1.0
  Cd  Cd1  1  0.500  0.500  0.000  1.0
  Cd  Cd2  1  0.000  0.500  0.000  1.0
  Cd  Cd3  1  0.500  0.000  0.500  1.0
  Cd  Cd4  1  0.500  0.500  0.500  1.0
  Cd  Cd5  1  0.000  0.500  0.500  1.0
  B  B6  1  0.608  0.809  0.750  1.0
  B  B7  1  0.201  0.392  0.750  1.0
  B  B8  1  0.191  0.799  0.750  1.0
  B  B9  1  0.392  0.191  0.250  1.0
  B  B10  1  0.799  0.608  0.250  1.0
  B  B11  1  0.809  0.201  0.250  1.0
  B  B12  1  0.667  0.333  0.750  1.0
  B  B13  1  0.333  0.667  0.250  1.0
  Pb  Pb14  1  0.847  0.133  0.750  1.0
  Pb  Pb15  1  0.286  0.153  0.750  1.0
  Pb  Pb16  1  0.867  0.714  0.750  1.0
  Pb  Pb17  1  0.153  0.867  0.250  1.0
  Pb  Pb18  1  0.714  0.847  0.250  1.0
  Pb  Pb19  1  0.133  0.286  0.250  1.0
  O  O20  1  0.651  0.188  0.750  1.0
  O  O21  1  0.537  0.349  0.750  1.0
  O  O22  1  0.812  0.463  0.750  1.0
  O  O23  1  0.349  0.812  0.250  1.0
  O  O24  1  0.463  0.651  0.250  1.0
  O  O25  1  0.188  0.537  0.250  1.0
  O  O26  1  0.346  0.894  0.750  1.0
  O  O27  1  0.548  0.654  0.750  1.0
  O  O28  1  0.106  0.452  0.750  1.0
  O  O29  1  0.654  0.106  0.250  1.0
  O  O30  1  0.452  0.346  0.250  1.0
  O  O31  1  0.894  0.548  0.250  1.0
  O  O32  1  0.648  0.894  0.917  1.0
  O  O33  1  0.246  0.352  0.917  1.0
  O  O34  1  0.106  0.754  0.917  1.0
  O  O35  1  0.352  0.106  0.417  1.0
  O  O36  1  0.754  0.648  0.417  1.0
  O  O37  1  0.894  0.246  0.417  1.0
  O  O38  1  0.352  0.106  0.083  1.0
  O  O39  1  0.754  0.648  0.083  1.0
  O  O40  1  0.894  0.246  0.083  1.0
  O  O41  1  0.648  0.894  0.583  1.0
  O  O42  1  0.246  0.352  0.583  1.0
  O  O43  1  0.106  0.754  0.583  1.0
[/CIF]
.