The crystal structure described by Li3Co13O5F19 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(1), one F(13), one F(14), one F(3), one F(6), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Co(5)OF5 pentagonal pyramid and  an edgeedge with one Co(6)OF5 pentagonal pyramid. In the second Li site, Li(2) is bonded to one F(12), one F(15), one F(2), one F(4), one F(7), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Co(11)F6 pentagonal pyramid,  a cornercorner with one Co(6)OF5 pentagonal pyramid,  an edgeedge with one Co(11)F6 pentagonal pyramid, and  an edgeedge with one Co(5)OF5 pentagonal pyramid. In the third Li site, Li(3) is bonded to one O(1), one O(3), one F(11), one F(16), one F(18), and one F(5) atom to form LiO2F4 octahedra that share  a cornercorner with one Co(11)F6 pentagonal pyramid,  a cornercorner with one Co(5)OF5 pentagonal pyramid,  an edgeedge with one Co(11)F6 pentagonal pyramid, and  an edgeedge with one Co(5)OF5 pentagonal pyramid. There are thirteen inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one F(12), one F(18), one F(2), and one F(4) atom. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one O(1), one O(4), one F(1), one F(13), one F(19), and one F(3) atom. In the third Co site, Co(3) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(11), one F(14), one F(5), and one F(6) atom. In the fourth Co site, Co(4) is bonded in a 6-coordinate geometry to one O(2), one O(5), one F(10), one F(15), one F(2), and one F(7) atom. In the fifth Co site, Co(5) is bonded to one O(3), one F(11), one F(16), one F(4), one F(6), and one F(9) atom to form distorted CoOF5 pentagonal pyramids that share  a cornercorner with one Li(1)F6 octahedra,  a cornercorner with one Li(3)O2F4 octahedra,  an edgeedge with one Li(2)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra, and  an edgeedge with one Co(11)F6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 45-47°. In the sixth Co site, Co(6) is bonded to one O(4), one F(10), one F(17), one F(3), one F(7), and one F(8) atom to form distorted CoOF5 pentagonal pyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one Co(7)O3F3 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Co(7)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 36-47°. In the seventh Co site, Co(7) is bonded to one O(2), one O(4), one O(5), one F(10), one F(17), and one F(19) atom to form a mixture of edge and corner-sharing CoO3F3 octahedra. In the eighth Co site, Co(8) is bonded in a 6-coordinate geometry to one O(3), one F(13), one F(16), one F(5), one F(6), and one F(9) atom. In the ninth Co site, Co(9) is bonded in a 6-coordinate geometry to one O(4), one O(5), one F(12), one F(17), one F(7), and one F(8) atom. In the tenth Co site, Co(10) is bonded in a 6-coordinate geometry to one O(5), one F(1), one F(10), one F(14), one F(19), and one F(8) atom. In the eleventh Co site, Co(11) is bonded to one F(11), one F(15), one F(18), one F(2), one F(5), and one F(9) atom to form distorted CoF6 pentagonal pyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one Li(3)O2F4 octahedra,  an edgeedge with one Li(2)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra, and  an edgeedge with one Co(5)OF5 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 37-39°. In the twelfth Co site, Co(12) is bonded in a 6-coordinate geometry to one O(1), one F(13), one F(14), one F(16), one F(19), and one F(3) atom. In the thirteenth Co site, Co(13) is bonded in a 6-coordinate geometry to one O(2), one F(12), one F(15), one F(17), one F(18), and one F(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a see-saw-like geometry to one Li(3), one Co(12), one Co(2), and one Co(3) atom. In the second O site, O(2) is bonded to one Co(1), one Co(13), one Co(4), and one Co(7) atom to form distorted OCo4 tetrahedra that share  a cornercorner with one O(4)Co4 tetrahedra, corners with two equivalent O(5)Co4 tetrahedra,  a cornercorner with one O(3)LiCo3 trigonal pyramid, corners with two equivalent F(12)LiCo3 trigonal pyramids, corners with two equivalent F(15)LiCo3 trigonal pyramids, and  an edgeedge with one F(10)Co4 trigonal pyramid. In the third O site, O(3) is bonded to one Li(3), one Co(1), one Co(5), and one Co(8) atom to form distorted OLiCo3 trigonal pyramids that share  a cornercorner with one O(2)Co4 tetrahedra,  a cornercorner with one F(12)LiCo3 trigonal pyramid,  a cornercorner with one F(13)LiCo3 trigonal pyramid, and corners with two equivalent F(6)LiCo3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Co(2), one Co(6), one Co(7), and one Co(9) atom to form distorted OCo4 tetrahedra that share  a cornercorner with one O(2)Co4 tetrahedra,  a cornercorner with one F(12)LiCo3 trigonal pyramid,  a cornercorner with one F(13)LiCo3 trigonal pyramid, corners with two equivalent F(10)Co4 trigonal pyramids, corners with two equivalent F(8)LiCo3 trigonal pyramids, and  an edgeedge with one O(5)Co4 tetrahedra. In the fifth O site, O(5) is bonded to one Co(10), one Co(4), one Co(7), and one Co(9) atom to form OCo4 tetrahedra that share corners with two equivalent O(2)Co4 tetrahedra,  a cornercorner with one F(10)Co4 trigonal pyramid,  a cornercorner with one F(12)LiCo3 trigonal pyramid,  a cornercorner with one F(14)LiCo3 trigonal pyramid,  a cornercorner with one F(15)LiCo3 trigonal pyramid, corners with two equivalent F(8)LiCo3 trigonal pyramids,  an edgeedge with one O(4)Co4 tetrahedra, and  an edgeedge with one F(10)Co4 trigonal pyramid. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(10), one Co(2), and one Co(3) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Co(11), and one Co(4) atom. In the third F site, F(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(12), one Co(2), and one Co(6) atom. In the fourth F site, F(4) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Co(13), and one Co(5) atom. In the fifth F site, F(5) is bonded in a see-saw-like geometry to one Li(3), one Co(11), one Co(3), and one Co(8) atom. In the sixth F site, F(6) is bonded to one Li(1), one Co(3), one Co(5), and one Co(8) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one F(8)LiCo3 trigonal pyramid, corners with two equivalent O(3)LiCo3 trigonal pyramids, corners with two equivalent F(14)LiCo3 trigonal pyramids, and  an edgeedge with one F(13)LiCo3 trigonal pyramid. In the seventh F site, F(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(4), one Co(6), and one Co(9) atom. In the eighth F site, F(8) is bonded to one Li(1), one Co(10), one Co(6), and one Co(9) atom to form distorted FLiCo3 trigonal pyramids that share corners with two equivalent O(4)Co4 tetrahedra, corners with two equivalent O(5)Co4 tetrahedra,  a cornercorner with one F(12)LiCo3 trigonal pyramid,  a cornercorner with one F(13)LiCo3 trigonal pyramid,  a cornercorner with one F(6)LiCo3 trigonal pyramid,  an edgeedge with one F(10)Co4 trigonal pyramid, and  an edgeedge with one F(14)LiCo3 trigonal pyramid. In the ninth F site, F(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(11), one Co(5), and one Co(8) atom. In the tenth F site, F(10) is bonded to one Co(10), one Co(4), one Co(6), and one Co(7) atom to form distorted FCo4 trigonal pyramids that share  a cornercorner with one O(5)Co4 tetrahedra, corners with two equivalent O(4)Co4 tetrahedra,  a cornercorner with one F(14)LiCo3 trigonal pyramid,  a cornercorner with one F(15)LiCo3 trigonal pyramid,  an edgeedge with one O(2)Co4 tetrahedra,  an edgeedge with one O(5)Co4 tetrahedra, and  an edgeedge with one F(8)LiCo3 trigonal pyramid. In the eleventh F site, F(11) is bonded in a 4-coordinate geometry to one Li(3), one Co(11), one Co(3), and one Co(5) atom. In the twelfth F site, F(12) is bonded to one Li(2), one Co(1), one Co(13), and one Co(9) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(5)Co4 tetrahedra, corners with two equivalent O(2)Co4 tetrahedra,  a cornercorner with one O(3)LiCo3 trigonal pyramid,  a cornercorner with one F(8)LiCo3 trigonal pyramid, and  an edgeedge with one F(15)LiCo3 trigonal pyramid. In the thirteenth F site, F(13) is bonded to one Li(1), one Co(12), one Co(2), and one Co(8) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(3)LiCo3 trigonal pyramid,  a cornercorner with one F(8)LiCo3 trigonal pyramid,  an edgeedge with one F(14)LiCo3 trigonal pyramid, and  an edgeedge with one F(6)LiCo3 trigonal pyramid. In the fourteenth F site, F(14) is bonded to one Li(1), one Co(10), one Co(12), and one Co(3) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one O(5)Co4 tetrahedra,  a cornercorner with one F(10)Co4 trigonal pyramid, corners with two equivalent F(6)LiCo3 trigonal pyramids,  an edgeedge with one F(13)LiCo3 trigonal pyramid, and  an edgeedge with one F(8)LiCo3 trigonal pyramid. In the fifteenth F site, F(15) is bonded to one Li(2), one Co(11), one Co(13), and one Co(4) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one O(5)Co4 tetrahedra, corners with two equivalent O(2)Co4 tetrahedra,  a cornercorner with one F(10)Co4 trigonal pyramid, and  an edgeedge with one F(12)LiCo3 trigonal pyramid. In the sixteenth F site, F(16) is bonded in a distorted see-saw-like geometry to one Li(3), one Co(12), one Co(5), and one Co(8) atom. In the seventeenth F site, F(17) is bonded in a distorted see-saw-like geometry to one Co(13), one Co(6), one Co(7), and one Co(9) atom. In the eighteenth F site, F(18) is bonded in a 4-coordinate geometry to one Li(3), one Co(1), one Co(11), and one Co(13) atom. In the nineteenth F site, F(19) is bonded in a distorted see-saw-like geometry to one Co(10), one Co(12), one Co(2), and one Co(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3Co13O5F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.126
_cell_length_b   6.158
_cell_length_c   12.249
_cell_angle_alpha   91.151
_cell_angle_beta   91.140
_cell_angle_gamma   91.135
_symmetry_Int_Tables_number   1
_cell_volume   461.766
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.508  0.491  0.254  1.0
  Li  Li1  1  0.504  0.491  0.753  1.0
  Li  Li2  1  0.010  0.986  0.499  1.0
  Co  Co3  1  0.255  0.942  0.713  1.0
  Co  Co4  1  0.263  0.939  0.220  1.0
  Co  Co5  1  0.061  0.599  0.369  1.0
  Co  Co6  1  0.071  0.581  0.871  1.0
  Co  Co7  1  0.546  0.755  0.536  1.0
  Co  Co8  1  0.545  0.754  0.039  1.0
  Co  Co9  1  0.026  0.010  0.988  1.0
  Co  Co10  1  0.404  0.223  0.475  1.0
  Co  Co11  1  0.398  0.243  0.976  1.0
  Co  Co12  1  0.942  0.423  0.112  1.0
  Co  Co13  1  0.929  0.423  0.620  1.0
  Co  Co14  1  0.780  0.055  0.297  1.0
  Co  Co15  1  0.770  0.053  0.791  1.0
  O  O16  1  0.051  0.900  0.333  1.0
  O  O17  1  0.043  0.889  0.831  1.0
  O  O18  1  0.319  0.963  0.557  1.0
  O  O19  1  0.319  0.965  0.061  1.0
  O  O20  1  0.091  0.338  0.973  1.0
  F  F21  1  0.193  0.562  0.201  1.0
  F  F22  1  0.193  0.556  0.700  1.0
  F  F23  1  0.587  0.810  0.222  1.0
  F  F24  1  0.587  0.807  0.716  1.0
  F  F25  1  0.084  0.330  0.473  1.0
  F  F26  1  0.408  0.578  0.405  1.0
  F  F27  1  0.430  0.587  0.903  1.0
  F  F28  1  0.588  0.429  0.093  1.0
  F  F29  1  0.580  0.421  0.589  1.0
  F  F30  1  0.878  0.712  0.030  1.0
  F  F31  1  0.883  0.688  0.525  1.0
  F  F32  1  0.429  0.188  0.798  1.0
  F  F33  1  0.439  0.190  0.303  1.0
  F  F34  1  0.824  0.407  0.288  1.0
  F  F35  1  0.815  0.404  0.783  1.0
  F  F36  1  0.694  0.045  0.456  1.0
  F  F37  1  0.684  0.054  0.952  1.0
  F  F38  1  0.935  0.104  0.647  1.0
  F  F39  1  0.934  0.104  0.148  1.0
[/CIF]
.
The crystal structure described by Li3Co13O5F19 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(1), one F(13), one F(14), one F(3), one F(6), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Co(5)OF5 pentagonal pyramid and  an edgeedge with one Co(6)OF5 pentagonal pyramid. In the second Li site, Li(2) is bonded to one F(12), one F(15), one F(2), one F(4), one F(7), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Co(11)F6 pentagonal pyramid,  a cornercorner with one Co(6)OF5 pentagonal pyramid,  an edgeedge with one Co(11)F6 pentagonal pyramid, and  an edgeedge with one Co(5)OF5 pentagonal pyramid. In the third Li site, Li(3) is bonded to one O(1), one O(3), one F(11), one F(16), one F(18), and one F(5) atom to form LiO2F4 octahedra that share  a cornercorner with one Co(11)F6 pentagonal pyramid,  a cornercorner with one Co(5)OF5 pentagonal pyramid,  an edgeedge with one Co(11)F6 pentagonal pyramid, and  an edgeedge with one Co(5)OF5 pentagonal pyramid. There are thirteen inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one F(12), one F(18), one F(2), and one F(4) atom. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one O(1), one O(4), one F(1), one F(13), one F(19), and one F(3) atom. In the third Co site, Co(3) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(11), one F(14), one F(5), and one F(6) atom. In the fourth Co site, Co(4) is bonded in a 6-coordinate geometry to one O(2), one O(5), one F(10), one F(15), one F(2), and one F(7) atom. In the fifth Co site, Co(5) is bonded to one O(3), one F(11), one F(16), one F(4), one F(6), and one F(9) atom to form distorted CoOF5 pentagonal pyramids that share  a cornercorner with one Li(1)F6 octahedra,  a cornercorner with one Li(3)O2F4 octahedra,  an edgeedge with one Li(2)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra, and  an edgeedge with one Co(11)F6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 45-47°. In the sixth Co site, Co(6) is bonded to one O(4), one F(10), one F(17), one F(3), one F(7), and one F(8) atom to form distorted CoOF5 pentagonal pyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one Co(7)O3F3 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Co(7)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 36-47°. In the seventh Co site, Co(7) is bonded to one O(2), one O(4), one O(5), one F(10), one F(17), and one F(19) atom to form a mixture of edge and corner-sharing CoO3F3 octahedra. In the eighth Co site, Co(8) is bonded in a 6-coordinate geometry to one O(3), one F(13), one F(16), one F(5), one F(6), and one F(9) atom. In the ninth Co site, Co(9) is bonded in a 6-coordinate geometry to one O(4), one O(5), one F(12), one F(17), one F(7), and one F(8) atom. In the tenth Co site, Co(10) is bonded in a 6-coordinate geometry to one O(5), one F(1), one F(10), one F(14), one F(19), and one F(8) atom. In the eleventh Co site, Co(11) is bonded to one F(11), one F(15), one F(18), one F(2), one F(5), and one F(9) atom to form distorted CoF6 pentagonal pyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one Li(3)O2F4 octahedra,  an edgeedge with one Li(2)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra, and  an edgeedge with one Co(5)OF5 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 37-39°. In the twelfth Co site, Co(12) is bonded in a 6-coordinate geometry to one O(1), one F(13), one F(14), one F(16), one F(19), and one F(3) atom. In the thirteenth Co site, Co(13) is bonded in a 6-coordinate geometry to one O(2), one F(12), one F(15), one F(17), one F(18), and one F(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a see-saw-like geometry to one Li(3), one Co(12), one Co(2), and one Co(3) atom. In the second O site, O(2) is bonded to one Co(1), one Co(13), one Co(4), and one Co(7) atom to form distorted OCo4 tetrahedra that share  a cornercorner with one O(4)Co4 tetrahedra, corners with two equivalent O(5)Co4 tetrahedra,  a cornercorner with one O(3)LiCo3 trigonal pyramid, corners with two equivalent F(12)LiCo3 trigonal pyramids, corners with two equivalent F(15)LiCo3 trigonal pyramids, and  an edgeedge with one F(10)Co4 trigonal pyramid. In the third O site, O(3) is bonded to one Li(3), one Co(1), one Co(5), and one Co(8) atom to form distorted OLiCo3 trigonal pyramids that share  a cornercorner with one O(2)Co4 tetrahedra,  a cornercorner with one F(12)LiCo3 trigonal pyramid,  a cornercorner with one F(13)LiCo3 trigonal pyramid, and corners with two equivalent F(6)LiCo3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Co(2), one Co(6), one Co(7), and one Co(9) atom to form distorted OCo4 tetrahedra that share  a cornercorner with one O(2)Co4 tetrahedra,  a cornercorner with one F(12)LiCo3 trigonal pyramid,  a cornercorner with one F(13)LiCo3 trigonal pyramid, corners with two equivalent F(10)Co4 trigonal pyramids, corners with two equivalent F(8)LiCo3 trigonal pyramids, and  an edgeedge with one O(5)Co4 tetrahedra. In the fifth O site, O(5) is bonded to one Co(10), one Co(4), one Co(7), and one Co(9) atom to form OCo4 tetrahedra that share corners with two equivalent O(2)Co4 tetrahedra,  a cornercorner with one F(10)Co4 trigonal pyramid,  a cornercorner with one F(12)LiCo3 trigonal pyramid,  a cornercorner with one F(14)LiCo3 trigonal pyramid,  a cornercorner with one F(15)LiCo3 trigonal pyramid, corners with two equivalent F(8)LiCo3 trigonal pyramids,  an edgeedge with one O(4)Co4 tetrahedra, and  an edgeedge with one F(10)Co4 trigonal pyramid. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(10), one Co(2), and one Co(3) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Co(11), and one Co(4) atom. In the third F site, F(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(12), one Co(2), and one Co(6) atom. In the fourth F site, F(4) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Co(13), and one Co(5) atom. In the fifth F site, F(5) is bonded in a see-saw-like geometry to one Li(3), one Co(11), one Co(3), and one Co(8) atom. In the sixth F site, F(6) is bonded to one Li(1), one Co(3), one Co(5), and one Co(8) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one F(8)LiCo3 trigonal pyramid, corners with two equivalent O(3)LiCo3 trigonal pyramids, corners with two equivalent F(14)LiCo3 trigonal pyramids, and  an edgeedge with one F(13)LiCo3 trigonal pyramid. In the seventh F site, F(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(4), one Co(6), and one Co(9) atom. In the eighth F site, F(8) is bonded to one Li(1), one Co(10), one Co(6), and one Co(9) atom to form distorted FLiCo3 trigonal pyramids that share corners with two equivalent O(4)Co4 tetrahedra, corners with two equivalent O(5)Co4 tetrahedra,  a cornercorner with one F(12)LiCo3 trigonal pyramid,  a cornercorner with one F(13)LiCo3 trigonal pyramid,  a cornercorner with one F(6)LiCo3 trigonal pyramid,  an edgeedge with one F(10)Co4 trigonal pyramid, and  an edgeedge with one F(14)LiCo3 trigonal pyramid. In the ninth F site, F(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(11), one Co(5), and one Co(8) atom. In the tenth F site, F(10) is bonded to one Co(10), one Co(4), one Co(6), and one Co(7) atom to form distorted FCo4 trigonal pyramids that share  a cornercorner with one O(5)Co4 tetrahedra, corners with two equivalent O(4)Co4 tetrahedra,  a cornercorner with one F(14)LiCo3 trigonal pyramid,  a cornercorner with one F(15)LiCo3 trigonal pyramid,  an edgeedge with one O(2)Co4 tetrahedra,  an edgeedge with one O(5)Co4 tetrahedra, and  an edgeedge with one F(8)LiCo3 trigonal pyramid. In the eleventh F site, F(11) is bonded in a 4-coordinate geometry to one Li(3), one Co(11), one Co(3), and one Co(5) atom. In the twelfth F site, F(12) is bonded to one Li(2), one Co(1), one Co(13), and one Co(9) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(5)Co4 tetrahedra, corners with two equivalent O(2)Co4 tetrahedra,  a cornercorner with one O(3)LiCo3 trigonal pyramid,  a cornercorner with one F(8)LiCo3 trigonal pyramid, and  an edgeedge with one F(15)LiCo3 trigonal pyramid. In the thirteenth F site, F(13) is bonded to one Li(1), one Co(12), one Co(2), and one Co(8) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(3)LiCo3 trigonal pyramid,  a cornercorner with one F(8)LiCo3 trigonal pyramid,  an edgeedge with one F(14)LiCo3 trigonal pyramid, and  an edgeedge with one F(6)LiCo3 trigonal pyramid. In the fourteenth F site, F(14) is bonded to one Li(1), one Co(10), one Co(12), and one Co(3) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one O(5)Co4 tetrahedra,  a cornercorner with one F(10)Co4 trigonal pyramid, corners with two equivalent F(6)LiCo3 trigonal pyramids,  an edgeedge with one F(13)LiCo3 trigonal pyramid, and  an edgeedge with one F(8)LiCo3 trigonal pyramid. In the fifteenth F site, F(15) is bonded to one Li(2), one Co(11), one Co(13), and one Co(4) atom to form distorted FLiCo3 trigonal pyramids that share  a cornercorner with one O(5)Co4 tetrahedra, corners with two equivalent O(2)Co4 tetrahedra,  a cornercorner with one F(10)Co4 trigonal pyramid, and  an edgeedge with one F(12)LiCo3 trigonal pyramid. In the sixteenth F site, F(16) is bonded in a distorted see-saw-like geometry to one Li(3), one Co(12), one Co(5), and one Co(8) atom. In the seventeenth F site, F(17) is bonded in a distorted see-saw-like geometry to one Co(13), one Co(6), one Co(7), and one Co(9) atom. In the eighteenth F site, F(18) is bonded in a 4-coordinate geometry to one Li(3), one Co(1), one Co(11), and one Co(13) atom. In the nineteenth F site, F(19) is bonded in a distorted see-saw-like geometry to one Co(10), one Co(12), one Co(2), and one Co(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3Co13O5F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.126
_cell_length_b   6.158
_cell_length_c   12.249
_cell_angle_alpha   91.151
_cell_angle_beta   91.140
_cell_angle_gamma   91.135
_symmetry_Int_Tables_number   1
_cell_volume   461.766
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.508  0.491  0.254  1.0
  Li  Li1  1  0.504  0.491  0.753  1.0
  Li  Li2  1  0.010  0.986  0.499  1.0
  Co  Co3  1  0.255  0.942  0.713  1.0
  Co  Co4  1  0.263  0.939  0.220  1.0
  Co  Co5  1  0.061  0.599  0.369  1.0
  Co  Co6  1  0.071  0.581  0.871  1.0
  Co  Co7  1  0.546  0.755  0.536  1.0
  Co  Co8  1  0.545  0.754  0.039  1.0
  Co  Co9  1  0.026  0.010  0.988  1.0
  Co  Co10  1  0.404  0.223  0.475  1.0
  Co  Co11  1  0.398  0.243  0.976  1.0
  Co  Co12  1  0.942  0.423  0.112  1.0
  Co  Co13  1  0.929  0.423  0.620  1.0
  Co  Co14  1  0.780  0.055  0.297  1.0
  Co  Co15  1  0.770  0.053  0.791  1.0
  O  O16  1  0.051  0.900  0.333  1.0
  O  O17  1  0.043  0.889  0.831  1.0
  O  O18  1  0.319  0.963  0.557  1.0
  O  O19  1  0.319  0.965  0.061  1.0
  O  O20  1  0.091  0.338  0.973  1.0
  F  F21  1  0.193  0.562  0.201  1.0
  F  F22  1  0.193  0.556  0.700  1.0
  F  F23  1  0.587  0.810  0.222  1.0
  F  F24  1  0.587  0.807  0.716  1.0
  F  F25  1  0.084  0.330  0.473  1.0
  F  F26  1  0.408  0.578  0.405  1.0
  F  F27  1  0.430  0.587  0.903  1.0
  F  F28  1  0.588  0.429  0.093  1.0
  F  F29  1  0.580  0.421  0.589  1.0
  F  F30  1  0.878  0.712  0.030  1.0
  F  F31  1  0.883  0.688  0.525  1.0
  F  F32  1  0.429  0.188  0.798  1.0
  F  F33  1  0.439  0.190  0.303  1.0
  F  F34  1  0.824  0.407  0.288  1.0
  F  F35  1  0.815  0.404  0.783  1.0
  F  F36  1  0.694  0.045  0.456  1.0
  F  F37  1  0.684  0.054  0.952  1.0
  F  F38  1  0.935  0.104  0.647  1.0
  F  F39  1  0.934  0.104  0.148  1.0
[/CIF]
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