The crystal structure described by Na(Cu3O4)2 crystallizes in the cubic Fm-3m space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to one Na(1) and three equivalent Cu(1) atoms to form a mixture of distorted corner and edge-sharing ONaCu3 tetrahedra. is represented by the CIF file [CIF]
data_Na(Cu3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.388
_cell_length_b   6.388
_cell_length_c   6.388
_cell_angle_alpha   60.002
_cell_angle_beta   60.002
_cell_angle_gamma   60.002
_symmetry_Int_Tables_number   1
_cell_volume   184.349
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  1.000  0.000  1.0
  Cu  Cu1  1  0.500  0.500  1.000  1.0
  Cu  Cu2  1  0.500  1.000  1.000  1.0
  Cu  Cu3  1  1.000  0.500  0.000  1.0
  Cu  Cu4  1  1.000  0.000  0.500  1.0
  Cu  Cu5  1  0.500  0.000  0.500  1.0
  Cu  Cu6  1  0.000  0.500  0.500  1.0
  O  O7  1  0.855  0.855  0.435  1.0
  O  O8  1  0.145  0.145  0.145  1.0
  O  O9  1  0.565  0.145  0.145  1.0
  O  O10  1  0.855  0.435  0.855  1.0
  O  O11  1  0.435  0.855  0.855  1.0
  O  O12  1  0.145  0.565  0.145  1.0
  O  O13  1  0.855  0.855  0.855  1.0
  O  O14  1  0.145  0.145  0.565  1.0
[/CIF]
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The crystal structure described by Na(Cu3O4)2 crystallizes in the cubic Fm-3m space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to one Na(1) and three equivalent Cu(1) atoms to form a mixture of distorted corner and edge-sharing ONaCu3 tetrahedra. is represented by the CIF file [CIF]
data_Na(Cu3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.388
_cell_length_b   6.388
_cell_length_c   6.388
_cell_angle_alpha   60.002
_cell_angle_beta   60.002
_cell_angle_gamma   60.002
_symmetry_Int_Tables_number   1
_cell_volume   184.349
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  1.000  0.000  1.0
  Cu  Cu1  1  0.500  0.500  1.000  1.0
  Cu  Cu2  1  0.500  1.000  1.000  1.0
  Cu  Cu3  1  1.000  0.500  0.000  1.0
  Cu  Cu4  1  1.000  0.000  0.500  1.0
  Cu  Cu5  1  0.500  0.000  0.500  1.0
  Cu  Cu6  1  0.000  0.500  0.500  1.0
  O  O7  1  0.855  0.855  0.435  1.0
  O  O8  1  0.145  0.145  0.145  1.0
  O  O9  1  0.565  0.145  0.145  1.0
  O  O10  1  0.855  0.435  0.855  1.0
  O  O11  1  0.435  0.855  0.855  1.0
  O  O12  1  0.145  0.565  0.145  1.0
  O  O13  1  0.855  0.855  0.855  1.0
  O  O14  1  0.145  0.145  0.565  1.0
[/CIF]
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