The material structure described by Co3Ag2P3HO12 crystallizes in the monoclinic Cc space group. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(12), one O(4), one O(5), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-63°. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(2), one O(3), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 60-63°. In the third Co site, Co(3) is bonded to one O(1), one O(12), one O(3), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-63°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one O(11), one O(12), one O(7), and one O(8) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(11), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. In the second P site, P(2) is bonded to one O(10), one O(12), one O(2), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-53°. In the third P site, P(3) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. H(1) is bonded in a distorted single-bond geometry to one O(10) and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Co(3), one Ag(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Co(2), one Ag(1), and one P(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(3), and one P(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Co(1), one Ag(1), and one P(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Co(1), one Ag(1), and one P(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Co(2), one Co(3), one Ag(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Co(1), one Co(2), one Ag(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted tetrahedral geometry to one Co(1), one Co(3), one Ag(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Co(3), one P(1), and one H(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Co(2), one P(2), and one H(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Co(1), one Co(2), one Ag(2), and one P(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Co(1), one Co(3), one Ag(2), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3Ag2P3HO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.187
_cell_length_b   9.187
_cell_length_c   10.942
_cell_angle_alpha   53.510
_cell_angle_beta   53.510
_cell_angle_gamma   42.868
_symmetry_Int_Tables_number   1
_cell_volume   483.361
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.999  0.502  0.958  1.0
  Co  Co1  1  0.502  0.999  0.458  1.0
  Co  Co2  1  0.396  0.382  0.571  1.0
  Co  Co3  1  0.624  0.606  0.842  1.0
  Co  Co4  1  0.606  0.624  0.342  1.0
  Co  Co5  1  0.382  0.396  0.071  1.0
  Ag  Ag6  1  0.118  0.863  0.256  1.0
  Ag  Ag7  1  0.863  0.118  0.756  1.0
  Ag  Ag8  1  0.002  0.511  0.457  1.0
  Ag  Ag9  1  0.511  0.002  0.957  1.0
  P  P10  1  0.171  0.187  0.780  1.0
  P  P11  1  0.829  0.822  0.634  1.0
  P  P12  1  0.822  0.829  0.134  1.0
  P  P13  1  0.187  0.171  0.280  1.0
  P  P14  1  0.347  0.656  0.705  1.0
  P  P15  1  0.656  0.347  0.205  1.0
  H  H16  1  0.174  0.879  0.955  1.0
  H  H17  1  0.879  0.174  0.455  1.0
  O  O18  1  0.926  0.301  0.815  1.0
  O  O19  1  0.079  0.687  0.545  1.0
  O  O20  1  0.687  0.079  0.045  1.0
  O  O21  1  0.301  0.926  0.315  1.0
  O  O22  1  0.490  0.516  0.588  1.0
  O  O23  1  0.516  0.490  0.088  1.0
  O  O24  1  0.120  0.691  0.801  1.0
  O  O25  1  0.886  0.305  0.113  1.0
  O  O26  1  0.305  0.886  0.613  1.0
  O  O27  1  0.691  0.120  0.301  1.0
  O  O28  1  0.490  0.513  0.820  1.0
  O  O29  1  0.513  0.490  0.320  1.0
  O  O30  1  0.229  0.274  0.820  1.0
  O  O31  1  0.776  0.722  0.821  1.0
  O  O32  1  0.722  0.776  0.321  1.0
  O  O33  1  0.274  0.229  0.320  1.0
  O  O34  1  0.279  0.927  0.883  1.0
  O  O35  1  0.731  0.071  0.584  1.0
  O  O36  1  0.071  0.731  0.084  1.0
  O  O37  1  0.927  0.279  0.383  1.0
  O  O38  1  0.296  0.211  0.599  1.0
  O  O39  1  0.707  0.788  0.605  1.0
  O  O40  1  0.788  0.707  0.105  1.0
  O  O41  1  0.211  0.296  0.099  1.0
[/CIF]
.
The material structure described by Co3Ag2P3HO12 crystallizes in the monoclinic Cc space group. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(12), one O(4), one O(5), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-63°. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(2), one O(3), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 60-63°. In the third Co site, Co(3) is bonded to one O(1), one O(12), one O(3), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-63°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one O(11), one O(12), one O(7), and one O(8) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(11), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. In the second P site, P(2) is bonded to one O(10), one O(12), one O(2), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-53°. In the third P site, P(3) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. H(1) is bonded in a distorted single-bond geometry to one O(10) and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Co(3), one Ag(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Co(2), one Ag(1), and one P(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(3), and one P(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Co(1), one Ag(1), and one P(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Co(1), one Ag(1), and one P(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Co(2), one Co(3), one Ag(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Co(1), one Co(2), one Ag(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted tetrahedral geometry to one Co(1), one Co(3), one Ag(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Co(3), one P(1), and one H(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Co(2), one P(2), and one H(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Co(1), one Co(2), one Ag(2), and one P(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Co(1), one Co(3), one Ag(2), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3Ag2P3HO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.187
_cell_length_b   9.187
_cell_length_c   10.942
_cell_angle_alpha   53.510
_cell_angle_beta   53.510
_cell_angle_gamma   42.868
_symmetry_Int_Tables_number   1
_cell_volume   483.361
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.999  0.502  0.958  1.0
  Co  Co1  1  0.502  0.999  0.458  1.0
  Co  Co2  1  0.396  0.382  0.571  1.0
  Co  Co3  1  0.624  0.606  0.842  1.0
  Co  Co4  1  0.606  0.624  0.342  1.0
  Co  Co5  1  0.382  0.396  0.071  1.0
  Ag  Ag6  1  0.118  0.863  0.256  1.0
  Ag  Ag7  1  0.863  0.118  0.756  1.0
  Ag  Ag8  1  0.002  0.511  0.457  1.0
  Ag  Ag9  1  0.511  0.002  0.957  1.0
  P  P10  1  0.171  0.187  0.780  1.0
  P  P11  1  0.829  0.822  0.634  1.0
  P  P12  1  0.822  0.829  0.134  1.0
  P  P13  1  0.187  0.171  0.280  1.0
  P  P14  1  0.347  0.656  0.705  1.0
  P  P15  1  0.656  0.347  0.205  1.0
  H  H16  1  0.174  0.879  0.955  1.0
  H  H17  1  0.879  0.174  0.455  1.0
  O  O18  1  0.926  0.301  0.815  1.0
  O  O19  1  0.079  0.687  0.545  1.0
  O  O20  1  0.687  0.079  0.045  1.0
  O  O21  1  0.301  0.926  0.315  1.0
  O  O22  1  0.490  0.516  0.588  1.0
  O  O23  1  0.516  0.490  0.088  1.0
  O  O24  1  0.120  0.691  0.801  1.0
  O  O25  1  0.886  0.305  0.113  1.0
  O  O26  1  0.305  0.886  0.613  1.0
  O  O27  1  0.691  0.120  0.301  1.0
  O  O28  1  0.490  0.513  0.820  1.0
  O  O29  1  0.513  0.490  0.320  1.0
  O  O30  1  0.229  0.274  0.820  1.0
  O  O31  1  0.776  0.722  0.821  1.0
  O  O32  1  0.722  0.776  0.321  1.0
  O  O33  1  0.274  0.229  0.320  1.0
  O  O34  1  0.279  0.927  0.883  1.0
  O  O35  1  0.731  0.071  0.584  1.0
  O  O36  1  0.071  0.731  0.084  1.0
  O  O37  1  0.927  0.279  0.383  1.0
  O  O38  1  0.296  0.211  0.599  1.0
  O  O39  1  0.707  0.788  0.605  1.0
  O  O40  1  0.788  0.707  0.105  1.0
  O  O41  1  0.211  0.296  0.099  1.0
[/CIF]
.