The structure described by LiV(OF)2 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent F(1), and two equivalent F(2) atoms. V(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiV(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.916
_cell_length_b   7.477
_cell_length_c   7.537
_cell_angle_alpha   76.208
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   269.057
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.255  0.626  0.637  1.0
  Li  Li1  1  0.245  0.626  0.137  1.0
  Li  Li2  1  0.755  0.374  0.863  1.0
  Li  Li3  1  0.745  0.374  0.363  1.0
  V  V4  1  0.767  0.839  0.837  1.0
  V  V5  1  0.733  0.839  0.337  1.0
  V  V6  1  0.267  0.161  0.663  1.0
  V  V7  1  0.233  0.161  0.163  1.0
  O  O8  1  0.061  0.963  0.700  1.0
  O  O9  1  0.439  0.963  0.200  1.0
  O  O10  1  0.616  0.816  0.547  1.0
  O  O11  1  0.884  0.816  0.047  1.0
  O  O12  1  0.116  0.184  0.953  1.0
  O  O13  1  0.384  0.184  0.453  1.0
  O  O14  1  0.561  0.037  0.800  1.0
  O  O15  1  0.939  0.037  0.300  1.0
  F  F16  1  0.456  0.683  0.893  1.0
  F  F17  1  0.936  0.613  0.798  1.0
  F  F18  1  0.044  0.683  0.393  1.0
  F  F19  1  0.564  0.613  0.298  1.0
  F  F20  1  0.436  0.387  0.702  1.0
  F  F21  1  0.956  0.317  0.607  1.0
  F  F22  1  0.064  0.387  0.202  1.0
  F  F23  1  0.544  0.317  0.107  1.0
[/CIF]
.
The structure described by LiV(OF)2 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent F(1), and two equivalent F(2) atoms. V(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiV(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.916
_cell_length_b   7.477
_cell_length_c   7.537
_cell_angle_alpha   76.208
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   269.057
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.255  0.626  0.637  1.0
  Li  Li1  1  0.245  0.626  0.137  1.0
  Li  Li2  1  0.755  0.374  0.863  1.0
  Li  Li3  1  0.745  0.374  0.363  1.0
  V  V4  1  0.767  0.839  0.837  1.0
  V  V5  1  0.733  0.839  0.337  1.0
  V  V6  1  0.267  0.161  0.663  1.0
  V  V7  1  0.233  0.161  0.163  1.0
  O  O8  1  0.061  0.963  0.700  1.0
  O  O9  1  0.439  0.963  0.200  1.0
  O  O10  1  0.616  0.816  0.547  1.0
  O  O11  1  0.884  0.816  0.047  1.0
  O  O12  1  0.116  0.184  0.953  1.0
  O  O13  1  0.384  0.184  0.453  1.0
  O  O14  1  0.561  0.037  0.800  1.0
  O  O15  1  0.939  0.037  0.300  1.0
  F  F16  1  0.456  0.683  0.893  1.0
  F  F17  1  0.936  0.613  0.798  1.0
  F  F18  1  0.044  0.683  0.393  1.0
  F  F19  1  0.564  0.613  0.298  1.0
  F  F20  1  0.436  0.387  0.702  1.0
  F  F21  1  0.956  0.317  0.607  1.0
  F  F22  1  0.064  0.387  0.202  1.0
  F  F23  1  0.544  0.317  0.107  1.0
[/CIF]
.