The crystal structure described by (N2)2P2N2S is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 7727-37-9 molecules and four P2N2S clusters. In each P2N2S cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a linear geometry to one N(3) and one N(6) atom. In the second P site, P(2) is bonded in a bent 120 degrees geometry to one N(3) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one P(1) atom. In the second N site, N(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. S(1) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF file [CIF]
data_P2SN6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.516
_cell_length_b   12.077
_cell_length_c   12.826
_cell_angle_alpha   78.459
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1292.412
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.554  0.907  0.276  1.0
  P  P1  1  0.446  0.093  0.724  1.0
  P  P2  1  0.054  0.593  0.724  1.0
  P  P3  1  0.946  0.407  0.276  1.0
  P  P4  1  0.480  0.683  0.214  1.0
  P  P5  1  0.520  0.317  0.786  1.0
  P  P6  1  0.980  0.817  0.786  1.0
  P  P7  1  0.020  0.183  0.214  1.0
  S  S8  1  0.818  0.860  0.681  1.0
  S  S9  1  0.182  0.140  0.319  1.0
  S  S10  1  0.318  0.640  0.319  1.0
  S  S11  1  0.682  0.360  0.681  1.0
  N  N12  1  0.831  0.723  0.427  1.0
  N  N13  1  0.169  0.277  0.573  1.0
  N  N14  1  0.331  0.777  0.573  1.0
  N  N15  1  0.669  0.223  0.427  1.0
  N  N16  1  0.932  0.761  0.378  1.0
  N  N17  1  0.068  0.239  0.622  1.0
  N  N18  1  0.432  0.739  0.622  1.0
  N  N19  1  0.568  0.261  0.378  1.0
  N  N20  1  0.571  0.805  0.217  1.0
  N  N21  1  0.429  0.195  0.783  1.0
  N  N22  1  0.071  0.695  0.783  1.0
  N  N23  1  0.929  0.305  0.217  1.0
  N  N24  1  0.318  0.906  0.979  1.0
  N  N25  1  0.682  0.094  0.021  1.0
  N  N26  1  0.818  0.594  0.021  1.0
  N  N27  1  0.182  0.406  0.979  1.0
  N  N28  1  0.840  0.681  0.035  1.0
  N  N29  1  0.160  0.319  0.965  1.0
  N  N30  1  0.340  0.819  0.965  1.0
  N  N31  1  0.660  0.181  0.035  1.0
  N  N32  1  0.563  0.022  0.304  1.0
  N  N33  1  0.437  0.978  0.696  1.0
  N  N34  1  0.063  0.478  0.696  1.0
  N  N35  1  0.937  0.522  0.304  1.0
[/CIF]
.
The crystal structure described by (N2)2P2N2S is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 7727-37-9 molecules and four P2N2S clusters. In each P2N2S cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a linear geometry to one N(3) and one N(6) atom. In the second P site, P(2) is bonded in a bent 120 degrees geometry to one N(3) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one P(1) atom. In the second N site, N(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. S(1) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF file [CIF]
data_P2SN6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.516
_cell_length_b   12.077
_cell_length_c   12.826
_cell_angle_alpha   78.459
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1292.412
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.554  0.907  0.276  1.0
  P  P1  1  0.446  0.093  0.724  1.0
  P  P2  1  0.054  0.593  0.724  1.0
  P  P3  1  0.946  0.407  0.276  1.0
  P  P4  1  0.480  0.683  0.214  1.0
  P  P5  1  0.520  0.317  0.786  1.0
  P  P6  1  0.980  0.817  0.786  1.0
  P  P7  1  0.020  0.183  0.214  1.0
  S  S8  1  0.818  0.860  0.681  1.0
  S  S9  1  0.182  0.140  0.319  1.0
  S  S10  1  0.318  0.640  0.319  1.0
  S  S11  1  0.682  0.360  0.681  1.0
  N  N12  1  0.831  0.723  0.427  1.0
  N  N13  1  0.169  0.277  0.573  1.0
  N  N14  1  0.331  0.777  0.573  1.0
  N  N15  1  0.669  0.223  0.427  1.0
  N  N16  1  0.932  0.761  0.378  1.0
  N  N17  1  0.068  0.239  0.622  1.0
  N  N18  1  0.432  0.739  0.622  1.0
  N  N19  1  0.568  0.261  0.378  1.0
  N  N20  1  0.571  0.805  0.217  1.0
  N  N21  1  0.429  0.195  0.783  1.0
  N  N22  1  0.071  0.695  0.783  1.0
  N  N23  1  0.929  0.305  0.217  1.0
  N  N24  1  0.318  0.906  0.979  1.0
  N  N25  1  0.682  0.094  0.021  1.0
  N  N26  1  0.818  0.594  0.021  1.0
  N  N27  1  0.182  0.406  0.979  1.0
  N  N28  1  0.840  0.681  0.035  1.0
  N  N29  1  0.160  0.319  0.965  1.0
  N  N30  1  0.340  0.819  0.965  1.0
  N  N31  1  0.660  0.181  0.035  1.0
  N  N32  1  0.563  0.022  0.304  1.0
  N  N33  1  0.437  0.978  0.696  1.0
  N  N34  1  0.063  0.478  0.696  1.0
  N  N35  1  0.937  0.522  0.304  1.0
[/CIF]
.