The material described by Au2PbP2 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to four equivalent Pb(1) and two equivalent P(1) atoms. In the second Au site, Au(2) is bonded in a 2-coordinate geometry to three equivalent Pb(1) and two equivalent P(1) atoms. Pb(1) is bonded in a 9-coordinate geometry to three equivalent Au(2), four equivalent Au(1), and two equivalent Pb(1) atoms. P(1) is bonded to one Au(1), one Au(2), and two equivalent P(1) atoms to form corner-sharing PP2Au2 tetrahedra. is represented by the CIF card [CIF]
data_P2PbAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.291
_cell_length_b   5.954
_cell_length_c   11.225
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.045
_symmetry_Int_Tables_number   1
_cell_volume   211.399
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.201  0.403  0.543  1.0
  P  P1  1  0.799  0.597  0.043  1.0
  P  P2  1  0.799  0.597  0.457  1.0
  P  P3  1  0.201  0.403  0.957  1.0
  Pb  Pb4  1  0.476  0.951  0.750  1.0
  Pb  Pb5  1  0.524  0.049  0.250  1.0
  Au  Au6  1  0.000  0.000  0.000  1.0
  Au  Au7  1  0.223  0.447  0.750  1.0
  Au  Au8  1  0.000  0.000  0.500  1.0
  Au  Au9  1  0.777  0.553  0.250  1.0
[/CIF]
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The material described by Au2PbP2 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to four equivalent Pb(1) and two equivalent P(1) atoms. In the second Au site, Au(2) is bonded in a 2-coordinate geometry to three equivalent Pb(1) and two equivalent P(1) atoms. Pb(1) is bonded in a 9-coordinate geometry to three equivalent Au(2), four equivalent Au(1), and two equivalent Pb(1) atoms. P(1) is bonded to one Au(1), one Au(2), and two equivalent P(1) atoms to form corner-sharing PP2Au2 tetrahedra. is represented by the CIF card [CIF]
data_P2PbAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.291
_cell_length_b   5.954
_cell_length_c   11.225
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.045
_symmetry_Int_Tables_number   1
_cell_volume   211.399
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.201  0.403  0.543  1.0
  P  P1  1  0.799  0.597  0.043  1.0
  P  P2  1  0.799  0.597  0.457  1.0
  P  P3  1  0.201  0.403  0.957  1.0
  Pb  Pb4  1  0.476  0.951  0.750  1.0
  Pb  Pb5  1  0.524  0.049  0.250  1.0
  Au  Au6  1  0.000  0.000  0.000  1.0
  Au  Au7  1  0.223  0.447  0.750  1.0
  Au  Au8  1  0.000  0.000  0.500  1.0
  Au  Au9  1  0.777  0.553  0.250  1.0
[/CIF]
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