The material described by SrLaVFeO6 is (Cubic) Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(11), two equivalent O(7), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra, faces with three equivalent V(2)O6 octahedra, and faces with three equivalent Fe(1)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(10), two equivalent O(12), and two equivalent O(8) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one Fe(1)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(1)O12 cuboctahedra, corners with six equivalent La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra, faces with three equivalent V(2)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. In the second La site, La(2) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(1)O12 cuboctahedra, corners with six equivalent La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one Fe(2)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent Fe(1)O6 octahedra. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Fe site, Fe(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form FeO6 octahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(2), and one Fe(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(1), and one Fe(1) atom. In the third O site, O(3) is bonded to one Sr(1), one Sr(2), two equivalent La(1), one V(2), and one Fe(2) atom to form a mixture of distorted edge and corner-sharing OSr2La2VFe octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(1), and one Fe(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(2), and one Fe(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(1), and one Fe(1) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(1), one La(1), one La(2), one V(2), and one Fe(1) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to two equivalent Sr(2), one La(1), one La(2), one V(1), and one Fe(2) atom. In the ninth O site, O(9) is bonded to two equivalent Sr(1), one La(1), one La(2), one V(2), and one Fe(1) atom to form a mixture of distorted edge and corner-sharing OSr2La2VFe octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the tenth O site, O(10) is bonded in a distorted linear geometry to two equivalent Sr(2), one La(1), one La(2), one V(1), and one Fe(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to two equivalent Sr(1), one La(1), one La(2), one V(2), and one Fe(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to two equivalent Sr(2), one La(1), one La(2), one V(1), and one Fe(2) atom. is represented by the CIF file [CIF]
data_SrLaVFeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.536
_cell_length_b   5.563
_cell_length_c   5.564
_cell_angle_alpha   60.043
_cell_angle_beta   60.327
_cell_angle_gamma   60.185
_symmetry_Int_Tables_number   1
_cell_volume   121.671
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  1.000  0.000  0.000  1.0
  La  La1  1  0.747  0.754  0.751  1.0
  O  O2  1  0.256  0.252  0.746  1.0
  O  O3  1  0.253  0.747  0.747  1.0
  O  O4  1  0.746  0.252  0.746  1.0
  O  O5  1  0.746  0.746  0.253  1.0
  O  O6  1  0.747  0.252  0.253  1.0
  O  O7  1  0.256  0.746  0.253  1.0
  Sr  Sr8  1  0.249  0.250  0.251  1.0
  V  V9  1  0.499  0.500  0.500  1.0
[/CIF]
.
The material described by SrLaVFeO6 is (Cubic) Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(11), two equivalent O(7), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra, faces with three equivalent V(2)O6 octahedra, and faces with three equivalent Fe(1)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(10), two equivalent O(12), and two equivalent O(8) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one Fe(1)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(1)O12 cuboctahedra, corners with six equivalent La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra, faces with three equivalent V(2)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. In the second La site, La(2) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(1)O12 cuboctahedra, corners with six equivalent La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one Fe(2)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent Fe(1)O6 octahedra. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Fe site, Fe(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form FeO6 octahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(2), and one Fe(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(1), and one Fe(1) atom. In the third O site, O(3) is bonded to one Sr(1), one Sr(2), two equivalent La(1), one V(2), and one Fe(2) atom to form a mixture of distorted edge and corner-sharing OSr2La2VFe octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(1), and one Fe(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(2), and one Fe(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(1), and one Fe(1) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(1), one La(1), one La(2), one V(2), and one Fe(1) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to two equivalent Sr(2), one La(1), one La(2), one V(1), and one Fe(2) atom. In the ninth O site, O(9) is bonded to two equivalent Sr(1), one La(1), one La(2), one V(2), and one Fe(1) atom to form a mixture of distorted edge and corner-sharing OSr2La2VFe octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the tenth O site, O(10) is bonded in a distorted linear geometry to two equivalent Sr(2), one La(1), one La(2), one V(1), and one Fe(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to two equivalent Sr(1), one La(1), one La(2), one V(2), and one Fe(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to two equivalent Sr(2), one La(1), one La(2), one V(1), and one Fe(2) atom. is represented by the CIF file [CIF]
data_SrLaVFeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.536
_cell_length_b   5.563
_cell_length_c   5.564
_cell_angle_alpha   60.043
_cell_angle_beta   60.327
_cell_angle_gamma   60.185
_symmetry_Int_Tables_number   1
_cell_volume   121.671
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  1.000  0.000  0.000  1.0
  La  La1  1  0.747  0.754  0.751  1.0
  O  O2  1  0.256  0.252  0.746  1.0
  O  O3  1  0.253  0.747  0.747  1.0
  O  O4  1  0.746  0.252  0.746  1.0
  O  O5  1  0.746  0.746  0.253  1.0
  O  O6  1  0.747  0.252  0.253  1.0
  O  O7  1  0.256  0.746  0.253  1.0
  Sr  Sr8  1  0.249  0.250  0.251  1.0
  V  V9  1  0.499  0.500  0.500  1.0
[/CIF]
.