The crystal structure described by TiZn(BiO3)2 crystallizes in the tetragonal P4/mmm space group. Ti(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form TiO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with four equivalent Ti(1)O6 octahedra. The corner-sharing octahedra are not tilted. Zn(1) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra and corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Zn(1) and four equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent Ti(1) atoms. In the third O site, O(3) is bonded in a linear geometry to one Ti(1), one Zn(1), and four equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_TiZn(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.919
_cell_length_b   3.919
_cell_length_c   8.058
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   123.735
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.500  0.500  0.500  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  Bi  Bi2  1  0.000  0.000  0.778  1.0
  Bi  Bi3  1  0.000  0.000  0.222  1.0
  O  O4  1  0.500  0.000  0.000  1.0
  O  O5  1  0.000  0.500  0.000  1.0
  O  O6  1  0.500  0.000  0.500  1.0
  O  O7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.500  0.500  0.742  1.0
  O  O9  1  0.500  0.500  0.258  1.0
[/CIF]
.
The crystal structure described by TiZn(BiO3)2 crystallizes in the tetragonal P4/mmm space group. Ti(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form TiO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with four equivalent Ti(1)O6 octahedra. The corner-sharing octahedra are not tilted. Zn(1) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra and corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Zn(1) and four equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent Ti(1) atoms. In the third O site, O(3) is bonded in a linear geometry to one Ti(1), one Zn(1), and four equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_TiZn(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.919
_cell_length_b   3.919
_cell_length_c   8.058
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   123.735
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.500  0.500  0.500  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  Bi  Bi2  1  0.000  0.000  0.778  1.0
  Bi  Bi3  1  0.000  0.000  0.222  1.0
  O  O4  1  0.500  0.000  0.000  1.0
  O  O5  1  0.000  0.500  0.000  1.0
  O  O6  1  0.500  0.000  0.500  1.0
  O  O7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.500  0.500  0.742  1.0
  O  O9  1  0.500  0.500  0.258  1.0
[/CIF]
.