The structure described by FeN6AgSbS4 crystallizes in the tetragonal P-4n2 space group. The structure consists of two FeN6 clusters inside a AgSbS4 framework. In each FeN6 cluster, Fe(1) is bonded in a distorted octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted L-shaped geometry to one Fe(1) and one N(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Fe(1) atom. In the AgSbS4 framework, Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. Sb(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a trigonal planar geometry to one Ag(1), one Sb(1), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_FeAgSb(S2N3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.629
_cell_length_b   7.297
_cell_length_c   7.297
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   459.407
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.250  0.000  0.500  1.0
  Fe  Fe1  1  0.750  0.500  0.000  1.0
  Ag  Ag2  1  0.000  0.500  0.500  1.0
  Ag  Ag3  1  0.500  0.000  0.000  1.0
  Sb  Sb4  1  0.500  0.500  0.500  1.0
  Sb  Sb5  1  0.000  0.000  0.000  1.0
  S  S6  1  0.246  0.405  0.707  1.0
  S  S7  1  0.746  0.095  0.207  1.0
  S  S8  1  0.754  0.293  0.405  1.0
  S  S9  1  0.254  0.207  0.905  1.0
  S  S10  1  0.246  0.595  0.293  1.0
  S  S11  1  0.746  0.905  0.793  1.0
  S  S12  1  0.754  0.707  0.595  1.0
  S  S13  1  0.254  0.793  0.095  1.0
  N  N14  1  0.009  0.946  0.444  1.0
  N  N15  1  0.509  0.554  0.944  1.0
  N  N16  1  0.991  0.556  0.946  1.0
  N  N17  1  0.491  0.944  0.446  1.0
  N  N18  1  0.009  0.054  0.556  1.0
  N  N19  1  0.509  0.446  0.056  1.0
  N  N20  1  0.991  0.444  0.054  1.0
  N  N21  1  0.491  0.056  0.554  1.0
  N  N22  1  0.250  0.838  0.662  1.0
  N  N23  1  0.750  0.662  0.162  1.0
  N  N24  1  0.750  0.338  0.838  1.0
  N  N25  1  0.250  0.162  0.338  1.0
[/CIF]
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The structure described by FeN6AgSbS4 crystallizes in the tetragonal P-4n2 space group. The structure consists of two FeN6 clusters inside a AgSbS4 framework. In each FeN6 cluster, Fe(1) is bonded in a distorted octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted L-shaped geometry to one Fe(1) and one N(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Fe(1) atom. In the AgSbS4 framework, Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. Sb(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a trigonal planar geometry to one Ag(1), one Sb(1), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_FeAgSb(S2N3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.629
_cell_length_b   7.297
_cell_length_c   7.297
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   459.407
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.250  0.000  0.500  1.0
  Fe  Fe1  1  0.750  0.500  0.000  1.0
  Ag  Ag2  1  0.000  0.500  0.500  1.0
  Ag  Ag3  1  0.500  0.000  0.000  1.0
  Sb  Sb4  1  0.500  0.500  0.500  1.0
  Sb  Sb5  1  0.000  0.000  0.000  1.0
  S  S6  1  0.246  0.405  0.707  1.0
  S  S7  1  0.746  0.095  0.207  1.0
  S  S8  1  0.754  0.293  0.405  1.0
  S  S9  1  0.254  0.207  0.905  1.0
  S  S10  1  0.246  0.595  0.293  1.0
  S  S11  1  0.746  0.905  0.793  1.0
  S  S12  1  0.754  0.707  0.595  1.0
  S  S13  1  0.254  0.793  0.095  1.0
  N  N14  1  0.009  0.946  0.444  1.0
  N  N15  1  0.509  0.554  0.944  1.0
  N  N16  1  0.991  0.556  0.946  1.0
  N  N17  1  0.491  0.944  0.446  1.0
  N  N18  1  0.009  0.054  0.556  1.0
  N  N19  1  0.509  0.446  0.056  1.0
  N  N20  1  0.991  0.444  0.054  1.0
  N  N21  1  0.491  0.056  0.554  1.0
  N  N22  1  0.250  0.838  0.662  1.0
  N  N23  1  0.750  0.662  0.162  1.0
  N  N24  1  0.750  0.338  0.838  1.0
  N  N25  1  0.250  0.162  0.338  1.0
[/CIF]
.