The crystal structure described by Mn2CuN2 crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to four equivalent N(1) atoms to form a mixture of corner and edge-sharing MnN4 trigonal pyramids. Cu(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to four equivalent Mn(1) and one Cu(1) atom to form a mixture of corner and edge-sharing NMn4Cu trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2CuN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.227
_cell_length_b   3.216
_cell_length_c   7.132
_cell_angle_alpha   90.000
_cell_angle_beta   116.855
_cell_angle_gamma   119.881
_symmetry_Int_Tables_number   1
_cell_volume   54.772
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.854  0.427  0.140  1.0
  Mn  Mn1  1  0.146  0.573  0.860  1.0
  Cu  Cu2  1  0.000  0.000  0.500  1.0
  N  N3  1  0.418  0.209  0.812  1.0
  N  N4  1  0.582  0.791  0.188  1.0
[/CIF]
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The crystal structure described by Mn2CuN2 crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to four equivalent N(1) atoms to form a mixture of corner and edge-sharing MnN4 trigonal pyramids. Cu(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to four equivalent Mn(1) and one Cu(1) atom to form a mixture of corner and edge-sharing NMn4Cu trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2CuN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.227
_cell_length_b   3.216
_cell_length_c   7.132
_cell_angle_alpha   90.000
_cell_angle_beta   116.855
_cell_angle_gamma   119.881
_symmetry_Int_Tables_number   1
_cell_volume   54.772
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.854  0.427  0.140  1.0
  Mn  Mn1  1  0.146  0.573  0.860  1.0
  Cu  Cu2  1  0.000  0.000  0.500  1.0
  N  N3  1  0.418  0.209  0.812  1.0
  N  N4  1  0.582  0.791  0.188  1.0
[/CIF]
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