The material structure described by CsNaMoO6 crystallizes in the orthorhombic P2_12_12_1 space group. Cs(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. Na(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Cs(1) and two equivalent Na(1) atoms. In the second O site, O(1) is bonded in a 4-coordinate geometry to one Cs(1), two equivalent Na(1), and one Mo(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cs(1) and one Mo(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1) and one Mo(1) atom. In the sixth O site, O(5) is bonded in a distorted T-shaped geometry to one Cs(1) and two equivalent Na(1) atoms. is represented by the CIF card [CIF]
data_CsNaMoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.015
_cell_length_b   7.861
_cell_length_c   12.978
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   715.644
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.044  0.844  0.352  1.0
  Cs  Cs1  1  0.456  0.156  0.852  1.0
  Cs  Cs2  1  0.544  0.656  0.648  1.0
  Cs  Cs3  1  0.956  0.344  0.148  1.0
  Na  Na4  1  0.628  0.719  0.012  1.0
  Na  Na5  1  0.872  0.281  0.512  1.0
  Na  Na6  1  0.128  0.781  0.988  1.0
  Na  Na7  1  0.372  0.219  0.488  1.0
  Mo  Mo8  1  0.551  0.586  0.353  1.0
  Mo  Mo9  1  0.949  0.414  0.853  1.0
  Mo  Mo10  1  0.051  0.914  0.647  1.0
  Mo  Mo11  1  0.449  0.086  0.147  1.0
  O  O12  1  0.604  0.424  0.447  1.0
  O  O13  1  0.896  0.576  0.947  1.0
  O  O14  1  0.104  0.076  0.553  1.0
  O  O15  1  0.396  0.924  0.053  1.0
  O  O16  1  0.748  0.604  0.266  1.0
  O  O17  1  0.752  0.396  0.766  1.0
  O  O18  1  0.248  0.896  0.734  1.0
  O  O19  1  0.252  0.104  0.234  1.0
  O  O20  1  0.526  0.781  0.422  1.0
  O  O21  1  0.974  0.219  0.922  1.0
  O  O22  1  0.026  0.719  0.578  1.0
  O  O23  1  0.474  0.281  0.078  1.0
  O  O24  1  0.326  0.544  0.286  1.0
  O  O25  1  0.174  0.456  0.786  1.0
  O  O26  1  0.826  0.956  0.714  1.0
  O  O27  1  0.674  0.044  0.214  1.0
  O  O28  1  0.861  0.937  0.906  1.0
  O  O29  1  0.639  0.063  0.406  1.0
  O  O30  1  0.361  0.563  0.094  1.0
  O  O31  1  0.139  0.437  0.594  1.0
  O  O32  1  0.837  0.816  0.145  1.0
  O  O33  1  0.663  0.184  0.645  1.0
  O  O34  1  0.337  0.684  0.855  1.0
  O  O35  1  0.163  0.316  0.355  1.0
[/CIF]
.
The material structure described by CsNaMoO6 crystallizes in the orthorhombic P2_12_12_1 space group. Cs(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. Na(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Cs(1) and two equivalent Na(1) atoms. In the second O site, O(1) is bonded in a 4-coordinate geometry to one Cs(1), two equivalent Na(1), and one Mo(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cs(1) and one Mo(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1) and one Mo(1) atom. In the sixth O site, O(5) is bonded in a distorted T-shaped geometry to one Cs(1) and two equivalent Na(1) atoms. is represented by the CIF card [CIF]
data_CsNaMoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.015
_cell_length_b   7.861
_cell_length_c   12.978
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   715.644
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.044  0.844  0.352  1.0
  Cs  Cs1  1  0.456  0.156  0.852  1.0
  Cs  Cs2  1  0.544  0.656  0.648  1.0
  Cs  Cs3  1  0.956  0.344  0.148  1.0
  Na  Na4  1  0.628  0.719  0.012  1.0
  Na  Na5  1  0.872  0.281  0.512  1.0
  Na  Na6  1  0.128  0.781  0.988  1.0
  Na  Na7  1  0.372  0.219  0.488  1.0
  Mo  Mo8  1  0.551  0.586  0.353  1.0
  Mo  Mo9  1  0.949  0.414  0.853  1.0
  Mo  Mo10  1  0.051  0.914  0.647  1.0
  Mo  Mo11  1  0.449  0.086  0.147  1.0
  O  O12  1  0.604  0.424  0.447  1.0
  O  O13  1  0.896  0.576  0.947  1.0
  O  O14  1  0.104  0.076  0.553  1.0
  O  O15  1  0.396  0.924  0.053  1.0
  O  O16  1  0.748  0.604  0.266  1.0
  O  O17  1  0.752  0.396  0.766  1.0
  O  O18  1  0.248  0.896  0.734  1.0
  O  O19  1  0.252  0.104  0.234  1.0
  O  O20  1  0.526  0.781  0.422  1.0
  O  O21  1  0.974  0.219  0.922  1.0
  O  O22  1  0.026  0.719  0.578  1.0
  O  O23  1  0.474  0.281  0.078  1.0
  O  O24  1  0.326  0.544  0.286  1.0
  O  O25  1  0.174  0.456  0.786  1.0
  O  O26  1  0.826  0.956  0.714  1.0
  O  O27  1  0.674  0.044  0.214  1.0
  O  O28  1  0.861  0.937  0.906  1.0
  O  O29  1  0.639  0.063  0.406  1.0
  O  O30  1  0.361  0.563  0.094  1.0
  O  O31  1  0.139  0.437  0.594  1.0
  O  O32  1  0.837  0.816  0.145  1.0
  O  O33  1  0.663  0.184  0.645  1.0
  O  O34  1  0.337  0.684  0.855  1.0
  O  O35  1  0.163  0.316  0.355  1.0
[/CIF]
.