The material structure described by VF5 is alpha U structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF file [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.711
_cell_length_b   5.237
_cell_length_c   8.901
_cell_angle_alpha   65.784
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   412.784
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.739  0.081  0.067  1.0
  V  V1  1  0.239  0.919  0.433  1.0
  V  V2  1  0.761  0.081  0.567  1.0
  V  V3  1  0.261  0.919  0.933  1.0
  F  F4  1  0.642  0.805  0.662  1.0
  F  F5  1  0.639  0.355  0.079  1.0
  F  F6  1  0.880  0.311  0.021  1.0
  F  F7  1  0.111  0.149  0.305  1.0
  F  F8  1  0.799  0.079  0.376  1.0
  F  F9  1  0.861  0.355  0.579  1.0
  F  F10  1  0.142  0.195  0.838  1.0
  F  F11  1  0.620  0.311  0.521  1.0
  F  F12  1  0.389  0.149  0.805  1.0
  F  F13  1  0.701  0.079  0.876  1.0
  F  F14  1  0.299  0.921  0.124  1.0
  F  F15  1  0.611  0.851  0.195  1.0
  F  F16  1  0.380  0.689  0.479  1.0
  F  F17  1  0.858  0.805  0.162  1.0
  F  F18  1  0.139  0.645  0.421  1.0
  F  F19  1  0.201  0.921  0.624  1.0
  F  F20  1  0.889  0.851  0.695  1.0
  F  F21  1  0.120  0.689  0.979  1.0
  F  F22  1  0.361  0.645  0.921  1.0
  F  F23  1  0.358  0.195  0.338  1.0
[/CIF]
.
The material structure described by VF5 is alpha U structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF file [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.711
_cell_length_b   5.237
_cell_length_c   8.901
_cell_angle_alpha   65.784
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   412.784
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.739  0.081  0.067  1.0
  V  V1  1  0.239  0.919  0.433  1.0
  V  V2  1  0.761  0.081  0.567  1.0
  V  V3  1  0.261  0.919  0.933  1.0
  F  F4  1  0.642  0.805  0.662  1.0
  F  F5  1  0.639  0.355  0.079  1.0
  F  F6  1  0.880  0.311  0.021  1.0
  F  F7  1  0.111  0.149  0.305  1.0
  F  F8  1  0.799  0.079  0.376  1.0
  F  F9  1  0.861  0.355  0.579  1.0
  F  F10  1  0.142  0.195  0.838  1.0
  F  F11  1  0.620  0.311  0.521  1.0
  F  F12  1  0.389  0.149  0.805  1.0
  F  F13  1  0.701  0.079  0.876  1.0
  F  F14  1  0.299  0.921  0.124  1.0
  F  F15  1  0.611  0.851  0.195  1.0
  F  F16  1  0.380  0.689  0.479  1.0
  F  F17  1  0.858  0.805  0.162  1.0
  F  F18  1  0.139  0.645  0.421  1.0
  F  F19  1  0.201  0.921  0.624  1.0
  F  F20  1  0.889  0.851  0.695  1.0
  F  F21  1  0.120  0.689  0.979  1.0
  F  F22  1  0.361  0.645  0.921  1.0
  F  F23  1  0.358  0.195  0.338  1.0
[/CIF]
.