The compound described by B2N2Cl3BNCl3(Cl2)3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three 7782-50-5 molecules, one B2N2Cl3 cluster, and one BNCl3 cluster. In the B2N2Cl3 cluster, there are two inequivalent B sites. In the first B site, B(1) is bonded in a linear geometry to one N(2) and one Cl(2) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(4) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to one B(1) and one B(2) atom. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one B(2) and one Cl(11) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one B(2) atom. In the third Cl site, Cl(11) is bonded in a single-bond geometry to one N(3) atom. In the BNCl3 cluster, B(3) is bonded in a trigonal planar geometry to one N(1), one Cl(6), and one Cl(7) atom. N(1) is bonded in a distorted single-bond geometry to one B(3) and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one B(3) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one B(3) atom. is represented by the CIF file [CIF]
data_BNCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.734
_cell_length_b   11.345
_cell_length_c   10.226
_cell_angle_alpha   72.140
_cell_angle_beta   43.465
_cell_angle_gamma   49.907
_symmetry_Int_Tables_number   1
_cell_volume   914.722
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.312  0.129  0.233  1.0
  B  B1  1  0.521  0.007  0.844  1.0
  B  B2  1  0.941  0.065  0.126  1.0
  N  N3  1  0.996  0.066  0.191  1.0
  N  N4  1  0.405  0.084  0.047  1.0
  N  N5  1  0.688  0.929  0.718  1.0
  Cl  Cl6  1  0.183  0.632  0.950  1.0
  Cl  Cl7  1  0.189  0.188  0.478  1.0
  Cl  Cl8  1  0.174  0.911  0.100  1.0
  Cl  Cl9  1  0.467  0.016  0.736  1.0
  Cl  Cl10  1  0.659  0.548  0.020  1.0
  Cl  Cl11  1  0.070  0.979  0.874  1.0
  Cl  Cl12  1  0.734  0.173  0.304  1.0
  Cl  Cl13  1  0.256  0.424  0.019  1.0
  Cl  Cl14  1  0.686  0.949  0.055  1.0
  Cl  Cl15  1  0.856  0.948  0.946  1.0
  Cl  Cl16  1  0.834  0.751  0.552  1.0
  Cl  Cl17  1  0.834  0.454  0.989  1.0
[/CIF]
.
The compound described by B2N2Cl3BNCl3(Cl2)3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three 7782-50-5 molecules, one B2N2Cl3 cluster, and one BNCl3 cluster. In the B2N2Cl3 cluster, there are two inequivalent B sites. In the first B site, B(1) is bonded in a linear geometry to one N(2) and one Cl(2) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(4) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to one B(1) and one B(2) atom. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one B(2) and one Cl(11) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one B(2) atom. In the third Cl site, Cl(11) is bonded in a single-bond geometry to one N(3) atom. In the BNCl3 cluster, B(3) is bonded in a trigonal planar geometry to one N(1), one Cl(6), and one Cl(7) atom. N(1) is bonded in a distorted single-bond geometry to one B(3) and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one B(3) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one B(3) atom. is represented by the CIF file [CIF]
data_BNCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.734
_cell_length_b   11.345
_cell_length_c   10.226
_cell_angle_alpha   72.140
_cell_angle_beta   43.465
_cell_angle_gamma   49.907
_symmetry_Int_Tables_number   1
_cell_volume   914.722
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.312  0.129  0.233  1.0
  B  B1  1  0.521  0.007  0.844  1.0
  B  B2  1  0.941  0.065  0.126  1.0
  N  N3  1  0.996  0.066  0.191  1.0
  N  N4  1  0.405  0.084  0.047  1.0
  N  N5  1  0.688  0.929  0.718  1.0
  Cl  Cl6  1  0.183  0.632  0.950  1.0
  Cl  Cl7  1  0.189  0.188  0.478  1.0
  Cl  Cl8  1  0.174  0.911  0.100  1.0
  Cl  Cl9  1  0.467  0.016  0.736  1.0
  Cl  Cl10  1  0.659  0.548  0.020  1.0
  Cl  Cl11  1  0.070  0.979  0.874  1.0
  Cl  Cl12  1  0.734  0.173  0.304  1.0
  Cl  Cl13  1  0.256  0.424  0.019  1.0
  Cl  Cl14  1  0.686  0.949  0.055  1.0
  Cl  Cl15  1  0.856  0.948  0.946  1.0
  Cl  Cl16  1  0.834  0.751  0.552  1.0
  Cl  Cl17  1  0.834  0.454  0.989  1.0
[/CIF]
.