The structure described by NH5OBr is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NH5OBr clusters. N(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. O(1) is bonded in a distorted water-like geometry to one H(4) and one H(5) atom. Br(1) is bonded in a 3-coordinate geometry to one H(2), one H(4), and one H(5) atom. is represented by the CIF card [CIF]
data_H5BrNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.770
_cell_length_b   7.068
_cell_length_c   8.336
_cell_angle_alpha   90.000
_cell_angle_beta   117.481
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   353.915
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.210  0.108  0.576  1.0
  H  H1  1  0.710  0.392  0.076  1.0
  H  H2  1  0.790  0.892  0.424  1.0
  H  H3  1  0.290  0.608  0.924  1.0
  H  H4  1  0.167  0.876  0.493  1.0
  H  H5  1  0.667  0.624  0.993  1.0
  H  H6  1  0.833  0.124  0.507  1.0
  H  H7  1  0.333  0.376  0.007  1.0
  H  H8  1  0.139  0.929  0.685  1.0
  H  H9  1  0.639  0.571  0.185  1.0
  H  H10  1  0.861  0.071  0.315  1.0
  H  H11  1  0.361  0.429  0.815  1.0
  H  H12  1  0.220  0.927  0.969  1.0
  H  H13  1  0.720  0.573  0.469  1.0
  H  H14  1  0.780  0.073  0.031  1.0
  H  H15  1  0.280  0.427  0.531  1.0
  H  H16  1  0.989  0.827  0.854  1.0
  H  H17  1  0.489  0.673  0.354  1.0
  H  H18  1  0.011  0.173  0.146  1.0
  H  H19  1  0.511  0.327  0.646  1.0
  Br  Br20  1  0.136  0.640  0.313  1.0
  Br  Br21  1  0.636  0.860  0.813  1.0
  Br  Br22  1  0.864  0.360  0.687  1.0
  Br  Br23  1  0.364  0.140  0.187  1.0
  N  N24  1  0.383  0.482  0.943  1.0
  N  N25  1  0.883  0.018  0.443  1.0
  N  N26  1  0.617  0.518  0.057  1.0
  N  N27  1  0.117  0.982  0.557  1.0
  O  O28  1  0.144  0.833  0.869  1.0
  O  O29  1  0.644  0.667  0.369  1.0
  O  O30  1  0.856  0.167  0.131  1.0
  O  O31  1  0.356  0.333  0.631  1.0
[/CIF]
.
The structure described by NH5OBr is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NH5OBr clusters. N(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. O(1) is bonded in a distorted water-like geometry to one H(4) and one H(5) atom. Br(1) is bonded in a 3-coordinate geometry to one H(2), one H(4), and one H(5) atom. is represented by the CIF card [CIF]
data_H5BrNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.770
_cell_length_b   7.068
_cell_length_c   8.336
_cell_angle_alpha   90.000
_cell_angle_beta   117.481
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   353.915
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.210  0.108  0.576  1.0
  H  H1  1  0.710  0.392  0.076  1.0
  H  H2  1  0.790  0.892  0.424  1.0
  H  H3  1  0.290  0.608  0.924  1.0
  H  H4  1  0.167  0.876  0.493  1.0
  H  H5  1  0.667  0.624  0.993  1.0
  H  H6  1  0.833  0.124  0.507  1.0
  H  H7  1  0.333  0.376  0.007  1.0
  H  H8  1  0.139  0.929  0.685  1.0
  H  H9  1  0.639  0.571  0.185  1.0
  H  H10  1  0.861  0.071  0.315  1.0
  H  H11  1  0.361  0.429  0.815  1.0
  H  H12  1  0.220  0.927  0.969  1.0
  H  H13  1  0.720  0.573  0.469  1.0
  H  H14  1  0.780  0.073  0.031  1.0
  H  H15  1  0.280  0.427  0.531  1.0
  H  H16  1  0.989  0.827  0.854  1.0
  H  H17  1  0.489  0.673  0.354  1.0
  H  H18  1  0.011  0.173  0.146  1.0
  H  H19  1  0.511  0.327  0.646  1.0
  Br  Br20  1  0.136  0.640  0.313  1.0
  Br  Br21  1  0.636  0.860  0.813  1.0
  Br  Br22  1  0.864  0.360  0.687  1.0
  Br  Br23  1  0.364  0.140  0.187  1.0
  N  N24  1  0.383  0.482  0.943  1.0
  N  N25  1  0.883  0.018  0.443  1.0
  N  N26  1  0.617  0.518  0.057  1.0
  N  N27  1  0.117  0.982  0.557  1.0
  O  O28  1  0.144  0.833  0.869  1.0
  O  O29  1  0.644  0.667  0.369  1.0
  O  O30  1  0.856  0.167  0.131  1.0
  O  O31  1  0.356  0.333  0.631  1.0
[/CIF]
.