The material described by RhSbO4 is Hydrophilite-derived structured and crystallizes in the tetragonal I4_1md space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with four equivalent Rh(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with four equivalent Rh(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_SbRhO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.587
_cell_length_b   5.587
_cell_length_c   5.587
_cell_angle_alpha   71.766
_cell_angle_beta   108.234
_cell_angle_gamma   68.024
_symmetry_Int_Tables_number   1
_cell_volume   134.064
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.253  0.247  0.500  1.0
  Sb  Sb1  1  0.003  0.997  0.000  1.0
  Rh  Rh2  1  0.746  0.754  0.500  1.0
  Rh  Rh3  1  0.496  0.504  0.000  1.0
  O  O4  1  0.563  0.245  0.808  1.0
  O  O5  1  0.052  0.755  0.807  1.0
  O  O6  1  0.495  0.813  0.693  1.0
  O  O7  1  0.005  0.303  0.692  1.0
  O  O8  1  0.495  0.198  0.307  1.0
  O  O9  1  0.005  0.687  0.308  1.0
  O  O10  1  0.437  0.755  0.193  1.0
  O  O11  1  0.947  0.245  0.192  1.0
[/CIF]
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The material described by RhSbO4 is Hydrophilite-derived structured and crystallizes in the tetragonal I4_1md space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with four equivalent Rh(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with four equivalent Rh(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_SbRhO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.587
_cell_length_b   5.587
_cell_length_c   5.587
_cell_angle_alpha   71.766
_cell_angle_beta   108.234
_cell_angle_gamma   68.024
_symmetry_Int_Tables_number   1
_cell_volume   134.064
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.253  0.247  0.500  1.0
  Sb  Sb1  1  0.003  0.997  0.000  1.0
  Rh  Rh2  1  0.746  0.754  0.500  1.0
  Rh  Rh3  1  0.496  0.504  0.000  1.0
  O  O4  1  0.563  0.245  0.808  1.0
  O  O5  1  0.052  0.755  0.807  1.0
  O  O6  1  0.495  0.813  0.693  1.0
  O  O7  1  0.005  0.303  0.692  1.0
  O  O8  1  0.495  0.198  0.307  1.0
  O  O9  1  0.005  0.687  0.308  1.0
  O  O10  1  0.437  0.755  0.193  1.0
  O  O11  1  0.947  0.245  0.192  1.0
[/CIF]
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