The compound described by H2SO4 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four tetrahydroxy-lambda4-sulfane molecules. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one H(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H2SO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.748
_cell_length_b   4.748
_cell_length_c   9.084
_cell_angle_alpha   72.306
_cell_angle_beta   72.306
_cell_angle_gamma   60.975
_symmetry_Int_Tables_number   1
_cell_volume   167.520
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.466  0.699  0.390  1.0
  H  H1  1  0.699  0.466  0.890  1.0
  H  H2  1  0.272  0.247  0.168  1.0
  H  H3  1  0.247  0.272  0.668  1.0
  S  S4  1  0.093  0.872  0.255  1.0
  S  S5  1  0.872  0.093  0.755  1.0
  O  O6  1  0.317  0.683  0.137  1.0
  O  O7  1  0.237  0.728  0.412  1.0
  O  O8  1  0.728  0.237  0.912  1.0
  O  O9  1  0.683  0.317  0.637  1.0
  O  O10  1  0.060  0.232  0.205  1.0
  O  O11  1  0.760  0.911  0.303  1.0
  O  O12  1  0.911  0.760  0.803  1.0
  O  O13  1  0.232  0.060  0.705  1.0
[/CIF]
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The compound described by H2SO4 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four tetrahydroxy-lambda4-sulfane molecules. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one H(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H2SO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.748
_cell_length_b   4.748
_cell_length_c   9.084
_cell_angle_alpha   72.306
_cell_angle_beta   72.306
_cell_angle_gamma   60.975
_symmetry_Int_Tables_number   1
_cell_volume   167.520
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.466  0.699  0.390  1.0
  H  H1  1  0.699  0.466  0.890  1.0
  H  H2  1  0.272  0.247  0.168  1.0
  H  H3  1  0.247  0.272  0.668  1.0
  S  S4  1  0.093  0.872  0.255  1.0
  S  S5  1  0.872  0.093  0.755  1.0
  O  O6  1  0.317  0.683  0.137  1.0
  O  O7  1  0.237  0.728  0.412  1.0
  O  O8  1  0.728  0.237  0.912  1.0
  O  O9  1  0.683  0.317  0.637  1.0
  O  O10  1  0.060  0.232  0.205  1.0
  O  O11  1  0.760  0.911  0.303  1.0
  O  O12  1  0.911  0.760  0.803  1.0
  O  O13  1  0.232  0.060  0.705  1.0
[/CIF]
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