The material described by LiSiBiO4 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form LiO4 tetrahedra that share corners with four equivalent Si(1)O4 tetrahedra and corners with four equivalent Bi(1)O4 tetrahedra. Si(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Bi(1)O4 tetrahedra. Bi(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form BiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Si(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Si(1), and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Si(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Si(1), and one Bi(1) atom. is represented by the CIF file [CIF]
data_LiSiBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.505
_cell_length_b   7.254
_cell_length_c   10.471
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   418.132
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.249  0.492  0.157  1.0
  Li  Li1  1  0.749  0.992  0.343  1.0
  Li  Li2  1  0.249  0.008  0.657  1.0
  Li  Li3  1  0.749  0.508  0.843  1.0
  Si  Si4  1  0.751  0.739  0.090  1.0
  Si  Si5  1  0.251  0.239  0.410  1.0
  Si  Si6  1  0.751  0.761  0.590  1.0
  Si  Si7  1  0.251  0.261  0.910  1.0
  Bi  Bi8  1  0.250  0.981  0.158  1.0
  Bi  Bi9  1  0.750  0.481  0.342  1.0
  Bi  Bi10  1  0.250  0.519  0.658  1.0
  Bi  Bi11  1  0.750  0.019  0.842  1.0
  O  O12  1  0.193  0.257  0.064  1.0
  O  O13  1  0.038  0.706  0.125  1.0
  O  O14  1  0.591  0.573  0.159  1.0
  O  O15  1  0.673  0.942  0.151  1.0
  O  O16  1  0.173  0.442  0.349  1.0
  O  O17  1  0.091  0.073  0.341  1.0
  O  O18  1  0.538  0.206  0.375  1.0
  O  O19  1  0.693  0.757  0.436  1.0
  O  O20  1  0.193  0.243  0.564  1.0
  O  O21  1  0.038  0.794  0.625  1.0
  O  O22  1  0.591  0.927  0.659  1.0
  O  O23  1  0.673  0.558  0.651  1.0
  O  O24  1  0.173  0.058  0.849  1.0
  O  O25  1  0.091  0.427  0.841  1.0
  O  O26  1  0.538  0.294  0.875  1.0
  O  O27  1  0.693  0.743  0.936  1.0
[/CIF]
.
The material described by LiSiBiO4 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form LiO4 tetrahedra that share corners with four equivalent Si(1)O4 tetrahedra and corners with four equivalent Bi(1)O4 tetrahedra. Si(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Bi(1)O4 tetrahedra. Bi(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form BiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Si(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Si(1), and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Si(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Si(1), and one Bi(1) atom. is represented by the CIF file [CIF]
data_LiSiBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.505
_cell_length_b   7.254
_cell_length_c   10.471
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   418.132
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.249  0.492  0.157  1.0
  Li  Li1  1  0.749  0.992  0.343  1.0
  Li  Li2  1  0.249  0.008  0.657  1.0
  Li  Li3  1  0.749  0.508  0.843  1.0
  Si  Si4  1  0.751  0.739  0.090  1.0
  Si  Si5  1  0.251  0.239  0.410  1.0
  Si  Si6  1  0.751  0.761  0.590  1.0
  Si  Si7  1  0.251  0.261  0.910  1.0
  Bi  Bi8  1  0.250  0.981  0.158  1.0
  Bi  Bi9  1  0.750  0.481  0.342  1.0
  Bi  Bi10  1  0.250  0.519  0.658  1.0
  Bi  Bi11  1  0.750  0.019  0.842  1.0
  O  O12  1  0.193  0.257  0.064  1.0
  O  O13  1  0.038  0.706  0.125  1.0
  O  O14  1  0.591  0.573  0.159  1.0
  O  O15  1  0.673  0.942  0.151  1.0
  O  O16  1  0.173  0.442  0.349  1.0
  O  O17  1  0.091  0.073  0.341  1.0
  O  O18  1  0.538  0.206  0.375  1.0
  O  O19  1  0.693  0.757  0.436  1.0
  O  O20  1  0.193  0.243  0.564  1.0
  O  O21  1  0.038  0.794  0.625  1.0
  O  O22  1  0.591  0.927  0.659  1.0
  O  O23  1  0.673  0.558  0.651  1.0
  O  O24  1  0.173  0.058  0.849  1.0
  O  O25  1  0.091  0.427  0.841  1.0
  O  O26  1  0.538  0.294  0.875  1.0
  O  O27  1  0.693  0.743  0.936  1.0
[/CIF]
.