The structure described by PbCu2(TeO3)2Cl2 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(4), and one O(6) atom. In the second Cu site, Cu(2) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(5), one Cl(2), and two equivalent Cl(1) atoms. Pb(1) is bonded in a 8-coordinate geometry to one O(5), one O(6), two equivalent O(2), two equivalent O(4), and two equivalent Cl(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted T-shaped geometry to one O(2), one O(3), and one O(5) atom. In the second Te site, Te(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1), two equivalent Pb(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cu(2), one Te(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cu(1), two equivalent Pb(1), and one Te(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2), one Pb(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Cu(1), one Pb(1), and one Te(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent Cu(2) atoms. In the second Cl site, Cl(2) is bonded in a T-shaped geometry to one Cu(2) and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Cu2Te2Pb(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.330
_cell_length_b   7.342
_cell_length_c   8.405
_cell_angle_alpha   90.000
_cell_angle_beta   96.328
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   449.540
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.638  0.091  0.912  1.0
  Cu  Cu1  1  0.362  0.591  0.088  1.0
  Cu  Cu2  1  0.681  0.608  0.412  1.0
  Cu  Cu3  1  0.319  0.108  0.588  1.0
  Te  Te4  1  0.128  0.458  0.388  1.0
  Te  Te5  1  0.872  0.958  0.612  1.0
  Te  Te6  1  0.647  0.229  0.233  1.0
  Te  Te7  1  0.353  0.729  0.767  1.0
  Pb  Pb8  1  0.874  0.600  0.939  1.0
  Pb  Pb9  1  0.126  0.100  0.061  1.0
  Cl  Cl10  1  0.449  0.824  0.379  1.0
  Cl  Cl11  1  0.551  0.324  0.621  1.0
  Cl  Cl12  1  0.892  0.842  0.228  1.0
  Cl  Cl13  1  0.108  0.342  0.772  1.0
  O  O14  1  0.540  0.471  0.242  1.0
  O  O15  1  0.460  0.971  0.758  1.0
  O  O16  1  0.146  0.475  0.163  1.0
  O  O17  1  0.854  0.975  0.837  1.0
  O  O18  1  0.868  0.418  0.376  1.0
  O  O19  1  0.132  0.918  0.624  1.0
  O  O20  1  0.796  0.255  0.058  1.0
  O  O21  1  0.204  0.755  0.942  1.0
  O  O22  1  0.191  0.209  0.392  1.0
  O  O23  1  0.809  0.709  0.608  1.0
  O  O24  1  0.463  0.151  0.063  1.0
  O  O25  1  0.537  0.651  0.937  1.0
[/CIF]
.
The structure described by PbCu2(TeO3)2Cl2 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(4), and one O(6) atom. In the second Cu site, Cu(2) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(5), one Cl(2), and two equivalent Cl(1) atoms. Pb(1) is bonded in a 8-coordinate geometry to one O(5), one O(6), two equivalent O(2), two equivalent O(4), and two equivalent Cl(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted T-shaped geometry to one O(2), one O(3), and one O(5) atom. In the second Te site, Te(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1), two equivalent Pb(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cu(2), one Te(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cu(1), two equivalent Pb(1), and one Te(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2), one Pb(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Cu(1), one Pb(1), and one Te(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent Cu(2) atoms. In the second Cl site, Cl(2) is bonded in a T-shaped geometry to one Cu(2) and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Cu2Te2Pb(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.330
_cell_length_b   7.342
_cell_length_c   8.405
_cell_angle_alpha   90.000
_cell_angle_beta   96.328
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   449.540
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.638  0.091  0.912  1.0
  Cu  Cu1  1  0.362  0.591  0.088  1.0
  Cu  Cu2  1  0.681  0.608  0.412  1.0
  Cu  Cu3  1  0.319  0.108  0.588  1.0
  Te  Te4  1  0.128  0.458  0.388  1.0
  Te  Te5  1  0.872  0.958  0.612  1.0
  Te  Te6  1  0.647  0.229  0.233  1.0
  Te  Te7  1  0.353  0.729  0.767  1.0
  Pb  Pb8  1  0.874  0.600  0.939  1.0
  Pb  Pb9  1  0.126  0.100  0.061  1.0
  Cl  Cl10  1  0.449  0.824  0.379  1.0
  Cl  Cl11  1  0.551  0.324  0.621  1.0
  Cl  Cl12  1  0.892  0.842  0.228  1.0
  Cl  Cl13  1  0.108  0.342  0.772  1.0
  O  O14  1  0.540  0.471  0.242  1.0
  O  O15  1  0.460  0.971  0.758  1.0
  O  O16  1  0.146  0.475  0.163  1.0
  O  O17  1  0.854  0.975  0.837  1.0
  O  O18  1  0.868  0.418  0.376  1.0
  O  O19  1  0.132  0.918  0.624  1.0
  O  O20  1  0.796  0.255  0.058  1.0
  O  O21  1  0.204  0.755  0.942  1.0
  O  O22  1  0.191  0.209  0.392  1.0
  O  O23  1  0.809  0.709  0.608  1.0
  O  O24  1  0.463  0.151  0.063  1.0
  O  O25  1  0.537  0.651  0.937  1.0
[/CIF]
.