The material described by RbMnO2Cl3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a distorted q6 geometry to one O(2), two equivalent Cl(3), three equivalent Cl(1), and three equivalent Cl(2) atoms. Mn(1) is bonded to one O(1), one O(2), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms to form distorted edge-sharing MnCl4O2 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Rb(1) and one Mn(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rb(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_RbMnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.833
_cell_length_b   6.952
_cell_length_c   9.121
_cell_angle_alpha   95.592
_cell_angle_beta   110.115
_cell_angle_gamma   110.486
_symmetry_Int_Tables_number   1
_cell_volume   369.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.729  0.073  0.808  1.0
  Rb  Rb1  1  0.271  0.927  0.192  1.0
  Mn  Mn2  1  0.994  0.664  0.674  1.0
  Mn  Mn3  1  0.006  0.336  0.326  1.0
  Cl  Cl4  1  0.784  0.593  0.827  1.0
  Cl  Cl5  1  0.216  0.407  0.173  1.0
  Cl  Cl6  1  0.214  0.015  0.810  1.0
  Cl  Cl7  1  0.786  0.985  0.190  1.0
  Cl  Cl8  1  0.785  0.299  0.503  1.0
  Cl  Cl9  1  0.215  0.701  0.497  1.0
  O  O10  1  0.189  0.592  0.805  1.0
  O  O11  1  0.811  0.408  0.195  1.0
  O  O12  1  0.200  0.259  0.456  1.0
  O  O13  1  0.800  0.741  0.544  1.0
[/CIF]
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The material described by RbMnO2Cl3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a distorted q6 geometry to one O(2), two equivalent Cl(3), three equivalent Cl(1), and three equivalent Cl(2) atoms. Mn(1) is bonded to one O(1), one O(2), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms to form distorted edge-sharing MnCl4O2 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Rb(1) and one Mn(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rb(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_RbMnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.833
_cell_length_b   6.952
_cell_length_c   9.121
_cell_angle_alpha   95.592
_cell_angle_beta   110.115
_cell_angle_gamma   110.486
_symmetry_Int_Tables_number   1
_cell_volume   369.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.729  0.073  0.808  1.0
  Rb  Rb1  1  0.271  0.927  0.192  1.0
  Mn  Mn2  1  0.994  0.664  0.674  1.0
  Mn  Mn3  1  0.006  0.336  0.326  1.0
  Cl  Cl4  1  0.784  0.593  0.827  1.0
  Cl  Cl5  1  0.216  0.407  0.173  1.0
  Cl  Cl6  1  0.214  0.015  0.810  1.0
  Cl  Cl7  1  0.786  0.985  0.190  1.0
  Cl  Cl8  1  0.785  0.299  0.503  1.0
  Cl  Cl9  1  0.215  0.701  0.497  1.0
  O  O10  1  0.189  0.592  0.805  1.0
  O  O11  1  0.811  0.408  0.195  1.0
  O  O12  1  0.200  0.259  0.456  1.0
  O  O13  1  0.800  0.741  0.544  1.0
[/CIF]
.