The compound described by Li2AgF4 crystallizes in the monoclinic C2/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form edge-sharing LiF6 octahedra. In the second Li site, Li(2) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form edge-sharing LiF6 octahedra. Ag(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Li(1), and one Ag(1) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent Li(2), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Li2AgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.399
_cell_length_b   6.399
_cell_length_c   5.137
_cell_angle_alpha   75.530
_cell_angle_beta   75.530
_cell_angle_gamma   55.877
_symmetry_Int_Tables_number   1
_cell_volume   166.998
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.873  0.127  0.250  1.0
  Li  Li1  1  0.382  0.618  0.250  1.0
  Li  Li2  1  0.618  0.382  0.750  1.0
  Li  Li3  1  0.127  0.873  0.750  1.0
  Ag  Ag4  1  0.000  0.500  0.500  1.0
  Ag  Ag5  1  0.500  0.000  0.000  1.0
  F  F6  1  0.232  0.983  0.332  1.0
  F  F7  1  0.730  0.475  0.361  1.0
  F  F8  1  0.270  0.525  0.639  1.0
  F  F9  1  0.983  0.232  0.832  1.0
  F  F10  1  0.768  0.017  0.668  1.0
  F  F11  1  0.475  0.730  0.861  1.0
  F  F12  1  0.525  0.270  0.139  1.0
  F  F13  1  0.017  0.768  0.168  1.0
[/CIF]
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The compound described by Li2AgF4 crystallizes in the monoclinic C2/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form edge-sharing LiF6 octahedra. In the second Li site, Li(2) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form edge-sharing LiF6 octahedra. Ag(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Li(1), and one Ag(1) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent Li(2), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Li2AgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.399
_cell_length_b   6.399
_cell_length_c   5.137
_cell_angle_alpha   75.530
_cell_angle_beta   75.530
_cell_angle_gamma   55.877
_symmetry_Int_Tables_number   1
_cell_volume   166.998
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.873  0.127  0.250  1.0
  Li  Li1  1  0.382  0.618  0.250  1.0
  Li  Li2  1  0.618  0.382  0.750  1.0
  Li  Li3  1  0.127  0.873  0.750  1.0
  Ag  Ag4  1  0.000  0.500  0.500  1.0
  Ag  Ag5  1  0.500  0.000  0.000  1.0
  F  F6  1  0.232  0.983  0.332  1.0
  F  F7  1  0.730  0.475  0.361  1.0
  F  F8  1  0.270  0.525  0.639  1.0
  F  F9  1  0.983  0.232  0.832  1.0
  F  F10  1  0.768  0.017  0.668  1.0
  F  F11  1  0.475  0.730  0.861  1.0
  F  F12  1  0.525  0.270  0.139  1.0
  F  F13  1  0.017  0.768  0.168  1.0
[/CIF]
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