The material structure described by Sc7V9O24 crystallizes in the triclinic P1 space group. There are seven inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 4-coordinate geometry to one O(21), one O(22), one O(5), and one O(6) atom. In the second Sc site, Sc(2) is bonded in a 4-coordinate geometry to one O(14), one O(15), one O(17), one O(2), and one O(6) atom. In the third Sc site, Sc(3) is bonded in a 4-coordinate geometry to one O(19), one O(20), one O(3), and one O(4) atom. In the fourth Sc site, Sc(4) is bonded in a 1-coordinate geometry to one O(13), one O(14), one O(24), one O(7), and one O(8) atom. In the fifth Sc site, Sc(5) is bonded in a distorted bent 150 degrees geometry to one O(14), one O(19), one O(5), and one O(9) atom. In the sixth Sc site, Sc(6) is bonded in a 1-coordinate geometry to one O(14), one O(17), and one O(4) atom. In the seventh Sc site, Sc(7) is bonded in a 5-coordinate geometry to one O(11), one O(22), one O(3), one O(4), and one O(9) atom. There are nine inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to one O(1), one O(17), one O(20), one O(22), one O(24), one O(4), one O(5), and one O(7) atom. In the second V site, V(2) is bonded in a 4-coordinate geometry to one O(13), one O(16), one O(21), and one O(22) atom. In the third V site, V(3) is bonded in a distorted bent 150 degrees geometry to one O(11), one O(16), one O(20), and one O(6) atom. In the fourth V site, V(4) is bonded in a distorted single-bond geometry to one O(12), one O(22), one O(3), and one O(7) atom. In the fifth V site, V(5) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(17), one O(18), and one O(9) atom. In the sixth V site, V(6) is bonded in a square co-planar geometry to one O(10), one O(11), one O(13), and one O(15) atom. In the seventh V site, V(7) is bonded in a distorted octahedral geometry to one O(19), one O(2), one O(21), one O(23), one O(3), and one O(6) atom. In the eighth V site, V(8) is bonded in a 4-coordinate geometry to one O(10), one O(12), one O(19), one O(23), and one O(7) atom. In the ninth V site, V(9) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(16), and one O(9) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1), one V(5), and one O(11) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Sc(2), one V(7), and one O(6) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sc(3), one Sc(7), one V(4), and one V(7) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sc(3), one Sc(6), one Sc(7), and one V(1) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Sc(1), one Sc(5), and one V(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Sc(1), one Sc(2), one V(3), one V(7), and one O(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sc(4), one V(1), one V(4), and one V(8) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Sc(4) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Sc(5), one Sc(7), one V(5), and one V(9) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one V(5), one V(6), and one V(8) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Sc(7), one V(3), one V(5), one V(6), and one O(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one V(4), one V(5), one V(8), and one V(9) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Sc(4), one V(2), one V(6), and one O(24) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Sc(2), one Sc(4), one Sc(5), one Sc(6), and one V(9) atom. In the fifteenth O site, O(15) is bonded in a 1-coordinate geometry to one Sc(2) and one V(6) atom. In the sixteenth O site, O(16) is bonded in a 1-coordinate geometry to one V(2), one V(3), and one V(9) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Sc(2), one Sc(6), one V(1), and one V(5) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one V(5) atom. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Sc(3), one Sc(5), one V(7), one V(8), and one O(23) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Sc(3), one V(1), and one V(3) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Sc(1), one V(2), and one V(7) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Sc(1), one Sc(7), one V(1), one V(2), and one V(4) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one V(7), one V(8), and one O(19) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one Sc(4), one V(1), and one O(13) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sc7V9O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.383
_cell_length_b   8.408
_cell_length_c   8.468
_cell_angle_alpha   109.717
_cell_angle_beta   109.503
_cell_angle_gamma   108.839
_symmetry_Int_Tables_number   1
_cell_volume   461.398
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.035  0.784  0.751  1.0
  Sc  Sc1  1  0.286  0.826  0.461  1.0
  Sc  Sc2  1  0.963  0.212  0.250  1.0
  Sc  Sc3  1  0.463  0.713  0.251  1.0
  Sc  Sc4  1  0.326  0.538  0.714  1.0
  Sc  Sc5  1  0.675  0.964  0.786  1.0
  Sc  Sc6  1  0.791  0.825  0.963  1.0
  V  V7  1  0.488  0.992  0.005  1.0
  V  V8  1  0.212  0.174  0.037  1.0
  V  V9  1  0.687  0.470  0.282  1.0
  V  V10  1  0.312  0.027  0.219  1.0
  V  V11  1  0.536  0.286  0.751  1.0
  V  V12  1  0.998  0.500  0.000  1.0
  V  V13  1  0.005  0.003  0.498  1.0
  V  V14  1  0.717  0.184  0.534  1.0
  V  V15  1  0.507  0.502  0.498  1.0
  O  O16  1  0.571  0.304  0.960  1.0
  O  O17  1  0.179  0.951  0.544  1.0
  O  O18  1  0.998  0.957  0.274  1.0
  O  O19  1  0.804  0.086  0.963  1.0
  O  O20  1  0.219  0.681  0.777  1.0
  O  O21  1  0.027  0.813  0.458  1.0
  O  O22  1  0.542  0.998  0.233  1.0
  O  O23  1  0.708  0.748  0.264  1.0
  O  O24  1  0.492  0.487  0.777  1.0
  O  O25  1  0.807  0.309  0.729  1.0
  O  O26  1  0.739  0.509  0.018  1.0
  O  O27  1  0.562  0.284  0.485  1.0
  O  O28  1  0.244  0.470  0.990  1.0
  O  O29  1  0.443  0.714  0.511  1.0
  O  O30  1  0.173  0.688  0.278  1.0
  O  O31  1  0.522  0.505  0.225  1.0
  O  O32  1  0.464  0.015  0.759  1.0
  O  O33  1  0.311  0.260  0.731  1.0
  O  O34  1  0.972  0.193  0.537  1.0
  O  O35  1  0.786  0.325  0.222  1.0
  O  O36  1  0.016  0.052  0.720  1.0
  O  O37  1  0.183  0.904  0.043  1.0
  O  O38  1  0.822  0.059  0.455  1.0
  O  O39  1  0.418  0.685  0.045  1.0
[/CIF]
.
The material structure described by Sc7V9O24 crystallizes in the triclinic P1 space group. There are seven inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 4-coordinate geometry to one O(21), one O(22), one O(5), and one O(6) atom. In the second Sc site, Sc(2) is bonded in a 4-coordinate geometry to one O(14), one O(15), one O(17), one O(2), and one O(6) atom. In the third Sc site, Sc(3) is bonded in a 4-coordinate geometry to one O(19), one O(20), one O(3), and one O(4) atom. In the fourth Sc site, Sc(4) is bonded in a 1-coordinate geometry to one O(13), one O(14), one O(24), one O(7), and one O(8) atom. In the fifth Sc site, Sc(5) is bonded in a distorted bent 150 degrees geometry to one O(14), one O(19), one O(5), and one O(9) atom. In the sixth Sc site, Sc(6) is bonded in a 1-coordinate geometry to one O(14), one O(17), and one O(4) atom. In the seventh Sc site, Sc(7) is bonded in a 5-coordinate geometry to one O(11), one O(22), one O(3), one O(4), and one O(9) atom. There are nine inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to one O(1), one O(17), one O(20), one O(22), one O(24), one O(4), one O(5), and one O(7) atom. In the second V site, V(2) is bonded in a 4-coordinate geometry to one O(13), one O(16), one O(21), and one O(22) atom. In the third V site, V(3) is bonded in a distorted bent 150 degrees geometry to one O(11), one O(16), one O(20), and one O(6) atom. In the fourth V site, V(4) is bonded in a distorted single-bond geometry to one O(12), one O(22), one O(3), and one O(7) atom. In the fifth V site, V(5) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(17), one O(18), and one O(9) atom. In the sixth V site, V(6) is bonded in a square co-planar geometry to one O(10), one O(11), one O(13), and one O(15) atom. In the seventh V site, V(7) is bonded in a distorted octahedral geometry to one O(19), one O(2), one O(21), one O(23), one O(3), and one O(6) atom. In the eighth V site, V(8) is bonded in a 4-coordinate geometry to one O(10), one O(12), one O(19), one O(23), and one O(7) atom. In the ninth V site, V(9) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(16), and one O(9) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1), one V(5), and one O(11) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Sc(2), one V(7), and one O(6) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sc(3), one Sc(7), one V(4), and one V(7) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sc(3), one Sc(6), one Sc(7), and one V(1) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Sc(1), one Sc(5), and one V(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Sc(1), one Sc(2), one V(3), one V(7), and one O(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sc(4), one V(1), one V(4), and one V(8) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Sc(4) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Sc(5), one Sc(7), one V(5), and one V(9) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one V(5), one V(6), and one V(8) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Sc(7), one V(3), one V(5), one V(6), and one O(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one V(4), one V(5), one V(8), and one V(9) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Sc(4), one V(2), one V(6), and one O(24) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Sc(2), one Sc(4), one Sc(5), one Sc(6), and one V(9) atom. In the fifteenth O site, O(15) is bonded in a 1-coordinate geometry to one Sc(2) and one V(6) atom. In the sixteenth O site, O(16) is bonded in a 1-coordinate geometry to one V(2), one V(3), and one V(9) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Sc(2), one Sc(6), one V(1), and one V(5) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one V(5) atom. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Sc(3), one Sc(5), one V(7), one V(8), and one O(23) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Sc(3), one V(1), and one V(3) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Sc(1), one V(2), and one V(7) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Sc(1), one Sc(7), one V(1), one V(2), and one V(4) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one V(7), one V(8), and one O(19) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one Sc(4), one V(1), and one O(13) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sc7V9O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.383
_cell_length_b   8.408
_cell_length_c   8.468
_cell_angle_alpha   109.717
_cell_angle_beta   109.503
_cell_angle_gamma   108.839
_symmetry_Int_Tables_number   1
_cell_volume   461.398
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.035  0.784  0.751  1.0
  Sc  Sc1  1  0.286  0.826  0.461  1.0
  Sc  Sc2  1  0.963  0.212  0.250  1.0
  Sc  Sc3  1  0.463  0.713  0.251  1.0
  Sc  Sc4  1  0.326  0.538  0.714  1.0
  Sc  Sc5  1  0.675  0.964  0.786  1.0
  Sc  Sc6  1  0.791  0.825  0.963  1.0
  V  V7  1  0.488  0.992  0.005  1.0
  V  V8  1  0.212  0.174  0.037  1.0
  V  V9  1  0.687  0.470  0.282  1.0
  V  V10  1  0.312  0.027  0.219  1.0
  V  V11  1  0.536  0.286  0.751  1.0
  V  V12  1  0.998  0.500  0.000  1.0
  V  V13  1  0.005  0.003  0.498  1.0
  V  V14  1  0.717  0.184  0.534  1.0
  V  V15  1  0.507  0.502  0.498  1.0
  O  O16  1  0.571  0.304  0.960  1.0
  O  O17  1  0.179  0.951  0.544  1.0
  O  O18  1  0.998  0.957  0.274  1.0
  O  O19  1  0.804  0.086  0.963  1.0
  O  O20  1  0.219  0.681  0.777  1.0
  O  O21  1  0.027  0.813  0.458  1.0
  O  O22  1  0.542  0.998  0.233  1.0
  O  O23  1  0.708  0.748  0.264  1.0
  O  O24  1  0.492  0.487  0.777  1.0
  O  O25  1  0.807  0.309  0.729  1.0
  O  O26  1  0.739  0.509  0.018  1.0
  O  O27  1  0.562  0.284  0.485  1.0
  O  O28  1  0.244  0.470  0.990  1.0
  O  O29  1  0.443  0.714  0.511  1.0
  O  O30  1  0.173  0.688  0.278  1.0
  O  O31  1  0.522  0.505  0.225  1.0
  O  O32  1  0.464  0.015  0.759  1.0
  O  O33  1  0.311  0.260  0.731  1.0
  O  O34  1  0.972  0.193  0.537  1.0
  O  O35  1  0.786  0.325  0.222  1.0
  O  O36  1  0.016  0.052  0.720  1.0
  O  O37  1  0.183  0.904  0.043  1.0
  O  O38  1  0.822  0.059  0.455  1.0
  O  O39  1  0.418  0.685  0.045  1.0
[/CIF]
.