The structure described by Sr3(Rh4B3)2 crystallizes in the orthorhombic Fmmm space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 16-coordinate geometry to one Sr(2), two equivalent Rh(2), four equivalent Rh(1), four equivalent Rh(3), and six equivalent B(1) atoms. In the second Sr site, Sr(2) is bonded in a 20-coordinate geometry to two equivalent Sr(1), four equivalent Rh(2), eight equivalent Rh(1), and six equivalent B(2) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted square co-planar geometry to two equivalent Sr(1), two equivalent Sr(2), two equivalent B(1), and two equivalent B(2) atoms. In the second Rh site, Rh(2) is bonded in a distorted square co-planar geometry to two equivalent Sr(1); two equivalent Sr(2); two equivalent B(1); and two B(2,2) atoms. In the third Rh site, Rh(3) is bonded in a 4-coordinate geometry to four equivalent Sr(1) and four equivalent B(1) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a 5-coordinate geometry to three equivalent Sr(1), one Rh(2), two equivalent Rh(1), and two equivalent Rh(3) atoms. In the second B site, B(2) is bonded in a 6-coordinate geometry to three equivalent Sr(2), two equivalent Rh(2), and four equivalent Rh(1) atoms. In the third B site, B(2) is bonded in a 6-coordinate geometry to three equivalent Sr(2), two equivalent Rh(2), and four equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_Sr3(B3Rh4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.578
_cell_length_b   5.718
_cell_length_c   8.996
_cell_angle_alpha   81.301
_cell_angle_beta   71.937
_cell_angle_gamma   60.804
_symmetry_Int_Tables_number   1
_cell_volume   238.141
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.317  0.000  0.366  1.0
  Sr  Sr1  1  0.500  0.000  0.000  1.0
  Sr  Sr2  1  0.683  0.000  0.634  1.0
  B  B3  1  0.996  0.670  0.338  1.0
  B  B4  1  0.004  0.330  0.662  1.0
  B  B5  1  0.164  0.671  0.000  1.0
  B  B6  1  0.666  0.330  0.338  1.0
  B  B7  1  0.334  0.670  0.662  1.0
  B  B8  1  0.836  0.329  0.000  1.0
  Rh  Rh9  1  0.416  0.500  0.169  1.0
  Rh  Rh10  1  0.913  0.000  0.173  1.0
  Rh  Rh11  1  0.916  0.500  0.169  1.0
  Rh  Rh12  1  0.750  0.500  0.500  1.0
  Rh  Rh13  1  0.084  0.500  0.831  1.0
  Rh  Rh14  1  0.584  0.500  0.831  1.0
  Rh  Rh15  1  0.250  0.500  0.500  1.0
  Rh  Rh16  1  0.087  0.000  0.827  1.0
[/CIF]
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The structure described by Sr3(Rh4B3)2 crystallizes in the orthorhombic Fmmm space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 16-coordinate geometry to one Sr(2), two equivalent Rh(2), four equivalent Rh(1), four equivalent Rh(3), and six equivalent B(1) atoms. In the second Sr site, Sr(2) is bonded in a 20-coordinate geometry to two equivalent Sr(1), four equivalent Rh(2), eight equivalent Rh(1), and six equivalent B(2) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted square co-planar geometry to two equivalent Sr(1), two equivalent Sr(2), two equivalent B(1), and two equivalent B(2) atoms. In the second Rh site, Rh(2) is bonded in a distorted square co-planar geometry to two equivalent Sr(1); two equivalent Sr(2); two equivalent B(1); and two B(2,2) atoms. In the third Rh site, Rh(3) is bonded in a 4-coordinate geometry to four equivalent Sr(1) and four equivalent B(1) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a 5-coordinate geometry to three equivalent Sr(1), one Rh(2), two equivalent Rh(1), and two equivalent Rh(3) atoms. In the second B site, B(2) is bonded in a 6-coordinate geometry to three equivalent Sr(2), two equivalent Rh(2), and four equivalent Rh(1) atoms. In the third B site, B(2) is bonded in a 6-coordinate geometry to three equivalent Sr(2), two equivalent Rh(2), and four equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_Sr3(B3Rh4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.578
_cell_length_b   5.718
_cell_length_c   8.996
_cell_angle_alpha   81.301
_cell_angle_beta   71.937
_cell_angle_gamma   60.804
_symmetry_Int_Tables_number   1
_cell_volume   238.141
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.317  0.000  0.366  1.0
  Sr  Sr1  1  0.500  0.000  0.000  1.0
  Sr  Sr2  1  0.683  0.000  0.634  1.0
  B  B3  1  0.996  0.670  0.338  1.0
  B  B4  1  0.004  0.330  0.662  1.0
  B  B5  1  0.164  0.671  0.000  1.0
  B  B6  1  0.666  0.330  0.338  1.0
  B  B7  1  0.334  0.670  0.662  1.0
  B  B8  1  0.836  0.329  0.000  1.0
  Rh  Rh9  1  0.416  0.500  0.169  1.0
  Rh  Rh10  1  0.913  0.000  0.173  1.0
  Rh  Rh11  1  0.916  0.500  0.169  1.0
  Rh  Rh12  1  0.750  0.500  0.500  1.0
  Rh  Rh13  1  0.084  0.500  0.831  1.0
  Rh  Rh14  1  0.584  0.500  0.831  1.0
  Rh  Rh15  1  0.250  0.500  0.500  1.0
  Rh  Rh16  1  0.087  0.000  0.827  1.0
[/CIF]
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