The structure described by LiO3 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent O(2) atoms. In the second O site, O(2) is bonded to three equivalent Li(1) and one O(1) atom to form a mixture of distorted edge and corner-sharing OLi3O tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.011
_cell_length_b   4.011
_cell_length_c   4.011
_cell_angle_alpha   133.558
_cell_angle_beta   103.162
_cell_angle_gamma   94.772
_symmetry_Int_Tables_number   1
_cell_volume   42.828
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.483  0.483  0.000  1.0
  O  O1  1  0.985  0.985  0.000  1.0
  O  O2  1  0.352  0.126  0.226  1.0
  O  O3  1  0.899  0.126  0.774  1.0
[/CIF]
.
The structure described by LiO3 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent O(2) atoms. In the second O site, O(2) is bonded to three equivalent Li(1) and one O(1) atom to form a mixture of distorted edge and corner-sharing OLi3O tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.011
_cell_length_b   4.011
_cell_length_c   4.011
_cell_angle_alpha   133.558
_cell_angle_beta   103.162
_cell_angle_gamma   94.772
_symmetry_Int_Tables_number   1
_cell_volume   42.828
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.483  0.483  0.000  1.0
  O  O1  1  0.985  0.985  0.000  1.0
  O  O2  1  0.352  0.126  0.226  1.0
  O  O3  1  0.899  0.126  0.774  1.0
[/CIF]
.