The compound described by GdOF crystallizes in the orthorhombic Fddd space group. Gd(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing GdO4F2 pentagonal pyramids. O(1) is bonded to four equivalent Gd(1) atoms to form a mixture of corner and edge-sharing OGd4 tetrahedra. F(1) is bonded in a linear geometry to two equivalent Gd(1) atoms. is represented by the CIF file [CIF]
data_GdOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.087
_cell_length_b   6.663
_cell_length_c   5.863
_cell_angle_alpha   68.575
_cell_angle_beta   61.064
_cell_angle_gamma   50.361
_symmetry_Int_Tables_number   1
_cell_volume   185.938
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.199  0.801  0.199  1.0
  Gd  Gd1  1  0.449  0.051  0.449  1.0
  Gd  Gd2  1  0.801  0.199  0.801  1.0
  Gd  Gd3  1  0.051  0.449  0.051  1.0
  O  O4  1  0.132  0.132  0.868  1.0
  O  O5  1  0.868  0.868  0.132  1.0
  O  O6  1  0.382  0.382  0.118  1.0
  O  O7  1  0.118  0.118  0.382  1.0
  F  F8  1  0.625  0.625  0.125  1.0
  F  F9  1  0.625  0.625  0.625  1.0
  F  F10  1  0.625  0.125  0.625  1.0
  F  F11  1  0.125  0.625  0.625  1.0
[/CIF]
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The compound described by GdOF crystallizes in the orthorhombic Fddd space group. Gd(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing GdO4F2 pentagonal pyramids. O(1) is bonded to four equivalent Gd(1) atoms to form a mixture of corner and edge-sharing OGd4 tetrahedra. F(1) is bonded in a linear geometry to two equivalent Gd(1) atoms. is represented by the CIF file [CIF]
data_GdOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.087
_cell_length_b   6.663
_cell_length_c   5.863
_cell_angle_alpha   68.575
_cell_angle_beta   61.064
_cell_angle_gamma   50.361
_symmetry_Int_Tables_number   1
_cell_volume   185.938
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.199  0.801  0.199  1.0
  Gd  Gd1  1  0.449  0.051  0.449  1.0
  Gd  Gd2  1  0.801  0.199  0.801  1.0
  Gd  Gd3  1  0.051  0.449  0.051  1.0
  O  O4  1  0.132  0.132  0.868  1.0
  O  O5  1  0.868  0.868  0.132  1.0
  O  O6  1  0.382  0.382  0.118  1.0
  O  O7  1  0.118  0.118  0.382  1.0
  F  F8  1  0.625  0.625  0.125  1.0
  F  F9  1  0.625  0.625  0.625  1.0
  F  F10  1  0.625  0.125  0.625  1.0
  F  F11  1  0.125  0.625  0.625  1.0
[/CIF]
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