The material described by CsTeF5 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent F(3), four equivalent F(1), and six equivalent F(2) atoms. Te(1) is bonded in a square pyramidal geometry to one F(3), two equivalent F(1), and two equivalent F(2) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Te(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to two equivalent Cs(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_CsTeF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.625
_cell_length_b   8.213
_cell_length_c   10.095
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   549.271
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.634  0.170  1.0
  Cs  Cs1  1  0.750  0.366  0.830  1.0
  Cs  Cs2  1  0.750  0.134  0.330  1.0
  Cs  Cs3  1  0.250  0.866  0.670  1.0
  Te  Te4  1  0.250  0.138  0.067  1.0
  Te  Te5  1  0.750  0.862  0.933  1.0
  Te  Te6  1  0.750  0.638  0.433  1.0
  Te  Te7  1  0.250  0.362  0.567  1.0
  F  F8  1  0.047  0.979  0.135  1.0
  F  F9  1  0.547  0.021  0.865  1.0
  F  F10  1  0.953  0.479  0.365  1.0
  F  F11  1  0.453  0.521  0.635  1.0
  F  F12  1  0.953  0.021  0.865  1.0
  F  F13  1  0.453  0.979  0.135  1.0
  F  F14  1  0.047  0.521  0.635  1.0
  F  F15  1  0.547  0.479  0.365  1.0
  F  F16  1  0.036  0.308  0.069  1.0
  F  F17  1  0.536  0.692  0.931  1.0
  F  F18  1  0.964  0.808  0.431  1.0
  F  F19  1  0.464  0.192  0.569  1.0
  F  F20  1  0.964  0.692  0.931  1.0
  F  F21  1  0.464  0.308  0.069  1.0
  F  F22  1  0.036  0.192  0.569  1.0
  F  F23  1  0.536  0.808  0.431  1.0
  F  F24  1  0.250  0.194  0.250  1.0
  F  F25  1  0.750  0.806  0.750  1.0
  F  F26  1  0.750  0.694  0.250  1.0
  F  F27  1  0.250  0.306  0.750  1.0
[/CIF]
.
The material described by CsTeF5 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent F(3), four equivalent F(1), and six equivalent F(2) atoms. Te(1) is bonded in a square pyramidal geometry to one F(3), two equivalent F(1), and two equivalent F(2) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Te(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to two equivalent Cs(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_CsTeF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.625
_cell_length_b   8.213
_cell_length_c   10.095
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   549.271
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.634  0.170  1.0
  Cs  Cs1  1  0.750  0.366  0.830  1.0
  Cs  Cs2  1  0.750  0.134  0.330  1.0
  Cs  Cs3  1  0.250  0.866  0.670  1.0
  Te  Te4  1  0.250  0.138  0.067  1.0
  Te  Te5  1  0.750  0.862  0.933  1.0
  Te  Te6  1  0.750  0.638  0.433  1.0
  Te  Te7  1  0.250  0.362  0.567  1.0
  F  F8  1  0.047  0.979  0.135  1.0
  F  F9  1  0.547  0.021  0.865  1.0
  F  F10  1  0.953  0.479  0.365  1.0
  F  F11  1  0.453  0.521  0.635  1.0
  F  F12  1  0.953  0.021  0.865  1.0
  F  F13  1  0.453  0.979  0.135  1.0
  F  F14  1  0.047  0.521  0.635  1.0
  F  F15  1  0.547  0.479  0.365  1.0
  F  F16  1  0.036  0.308  0.069  1.0
  F  F17  1  0.536  0.692  0.931  1.0
  F  F18  1  0.964  0.808  0.431  1.0
  F  F19  1  0.464  0.192  0.569  1.0
  F  F20  1  0.964  0.692  0.931  1.0
  F  F21  1  0.464  0.308  0.069  1.0
  F  F22  1  0.036  0.192  0.569  1.0
  F  F23  1  0.536  0.808  0.431  1.0
  F  F24  1  0.250  0.194  0.250  1.0
  F  F25  1  0.750  0.806  0.750  1.0
  F  F26  1  0.750  0.694  0.250  1.0
  F  F27  1  0.250  0.306  0.750  1.0
[/CIF]
.