The structure described by WFe2C10TeSeO10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WFe2C10TeSeO10 clusters. W(1) is bonded in a 8-coordinate geometry to one Fe(1), one Fe(2), one C(1), one C(3), one C(5), one C(9), one Te(1), and one Se(1) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 3-coordinate geometry to one W(1), one C(10), one C(2), one C(8), one Te(1), and one Se(1) atom. In the second Fe site, Fe(2) is bonded in a 3-coordinate geometry to one W(1), one C(4), one C(6), one C(7), one Te(1), and one Se(1) atom. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one O(5) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one W(1) and one O(9) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(2) and one O(8) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one W(1) and one O(6) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Fe(2) and one O(4) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Fe(2) and one O(1) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Fe(1) and one O(7) atom. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one W(1) and one O(2) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Fe(1) and one O(10) atom. Te(1) is bonded in a 3-coordinate geometry to one W(1), one Fe(1), and one Fe(2) atom. Se(1) is bonded in a 3-coordinate geometry to one W(1), one Fe(1), and one Fe(2) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(3) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Fe2TeWC10SeO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.956
_cell_length_b   9.569
_cell_length_c   13.835
_cell_angle_alpha   81.564
_cell_angle_beta   82.139
_cell_angle_gamma   85.340
_symmetry_Int_Tables_number   1
_cell_volume   900.703
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.281  1.000  0.271  1.0
  Fe  Fe1  1  0.647  0.669  0.634  1.0
  Fe  Fe2  1  0.353  0.331  0.366  1.0
  Fe  Fe3  1  0.719  0.000  0.729  1.0
  Te  Te4  1  0.431  0.886  0.681  1.0
  Te  Te5  1  0.569  0.114  0.319  1.0
  W  W6  1  0.394  0.272  0.165  1.0
  W  W7  1  0.606  0.728  0.835  1.0
  C  C8  1  0.214  0.246  0.063  1.0
  C  C9  1  0.446  0.865  0.221  1.0
  C  C10  1  0.725  0.524  0.865  1.0
  C  C11  1  0.299  0.259  0.491  1.0
  C  C12  1  0.636  0.389  0.136  1.0
  C  C13  1  0.364  0.611  0.864  1.0
  C  C14  1  0.792  0.504  0.637  1.0
  C  C15  1  0.570  0.416  0.375  1.0
  C  C16  1  0.786  0.754  0.937  1.0
  C  C17  1  0.554  0.135  0.779  1.0
  C  C18  1  0.208  0.496  0.363  1.0
  C  C19  1  0.086  0.952  0.210  1.0
  C  C20  1  0.426  0.844  0.929  1.0
  C  C21  1  0.574  0.156  0.071  1.0
  C  C22  1  0.275  0.476  0.135  1.0
  C  C23  1  0.701  0.741  0.509  1.0
  C  C24  1  0.221  0.910  0.391  1.0
  C  C25  1  0.914  0.048  0.790  1.0
  C  C26  1  0.430  0.584  0.625  1.0
  C  C27  1  0.779  0.090  0.609  1.0
  Se  Se28  1  0.103  0.220  0.302  1.0
  Se  Se29  1  0.897  0.780  0.698  1.0
  O  O30  1  0.707  0.471  0.385  1.0
  O  O31  1  0.325  0.907  0.983  1.0
  O  O32  1  0.675  0.093  0.017  1.0
  O  O33  1  0.112  0.231  0.006  1.0
  O  O34  1  0.117  0.603  0.363  1.0
  O  O35  1  0.548  0.775  0.192  1.0
  O  O36  1  0.228  0.545  0.880  1.0
  O  O37  1  0.961  0.919  0.173  1.0
  O  O38  1  0.293  0.529  0.615  1.0
  O  O39  1  0.734  0.790  0.427  1.0
  O  O40  1  0.211  0.591  0.116  1.0
  O  O41  1  0.888  0.769  0.994  1.0
  O  O42  1  0.039  0.081  0.827  1.0
  O  O43  1  0.772  0.455  0.120  1.0
  O  O44  1  0.816  0.149  0.530  1.0
  O  O45  1  0.184  0.851  0.470  1.0
  O  O46  1  0.452  0.225  0.808  1.0
  O  O47  1  0.266  0.210  0.573  1.0
  O  O48  1  0.789  0.409  0.884  1.0
  O  O49  1  0.883  0.397  0.637  1.0
[/CIF]
.
The structure described by WFe2C10TeSeO10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WFe2C10TeSeO10 clusters. W(1) is bonded in a 8-coordinate geometry to one Fe(1), one Fe(2), one C(1), one C(3), one C(5), one C(9), one Te(1), and one Se(1) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 3-coordinate geometry to one W(1), one C(10), one C(2), one C(8), one Te(1), and one Se(1) atom. In the second Fe site, Fe(2) is bonded in a 3-coordinate geometry to one W(1), one C(4), one C(6), one C(7), one Te(1), and one Se(1) atom. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one O(5) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one W(1) and one O(9) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(2) and one O(8) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one W(1) and one O(6) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Fe(2) and one O(4) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Fe(2) and one O(1) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Fe(1) and one O(7) atom. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one W(1) and one O(2) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Fe(1) and one O(10) atom. Te(1) is bonded in a 3-coordinate geometry to one W(1), one Fe(1), and one Fe(2) atom. Se(1) is bonded in a 3-coordinate geometry to one W(1), one Fe(1), and one Fe(2) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(3) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Fe2TeWC10SeO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.956
_cell_length_b   9.569
_cell_length_c   13.835
_cell_angle_alpha   81.564
_cell_angle_beta   82.139
_cell_angle_gamma   85.340
_symmetry_Int_Tables_number   1
_cell_volume   900.703
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.281  1.000  0.271  1.0
  Fe  Fe1  1  0.647  0.669  0.634  1.0
  Fe  Fe2  1  0.353  0.331  0.366  1.0
  Fe  Fe3  1  0.719  0.000  0.729  1.0
  Te  Te4  1  0.431  0.886  0.681  1.0
  Te  Te5  1  0.569  0.114  0.319  1.0
  W  W6  1  0.394  0.272  0.165  1.0
  W  W7  1  0.606  0.728  0.835  1.0
  C  C8  1  0.214  0.246  0.063  1.0
  C  C9  1  0.446  0.865  0.221  1.0
  C  C10  1  0.725  0.524  0.865  1.0
  C  C11  1  0.299  0.259  0.491  1.0
  C  C12  1  0.636  0.389  0.136  1.0
  C  C13  1  0.364  0.611  0.864  1.0
  C  C14  1  0.792  0.504  0.637  1.0
  C  C15  1  0.570  0.416  0.375  1.0
  C  C16  1  0.786  0.754  0.937  1.0
  C  C17  1  0.554  0.135  0.779  1.0
  C  C18  1  0.208  0.496  0.363  1.0
  C  C19  1  0.086  0.952  0.210  1.0
  C  C20  1  0.426  0.844  0.929  1.0
  C  C21  1  0.574  0.156  0.071  1.0
  C  C22  1  0.275  0.476  0.135  1.0
  C  C23  1  0.701  0.741  0.509  1.0
  C  C24  1  0.221  0.910  0.391  1.0
  C  C25  1  0.914  0.048  0.790  1.0
  C  C26  1  0.430  0.584  0.625  1.0
  C  C27  1  0.779  0.090  0.609  1.0
  Se  Se28  1  0.103  0.220  0.302  1.0
  Se  Se29  1  0.897  0.780  0.698  1.0
  O  O30  1  0.707  0.471  0.385  1.0
  O  O31  1  0.325  0.907  0.983  1.0
  O  O32  1  0.675  0.093  0.017  1.0
  O  O33  1  0.112  0.231  0.006  1.0
  O  O34  1  0.117  0.603  0.363  1.0
  O  O35  1  0.548  0.775  0.192  1.0
  O  O36  1  0.228  0.545  0.880  1.0
  O  O37  1  0.961  0.919  0.173  1.0
  O  O38  1  0.293  0.529  0.615  1.0
  O  O39  1  0.734  0.790  0.427  1.0
  O  O40  1  0.211  0.591  0.116  1.0
  O  O41  1  0.888  0.769  0.994  1.0
  O  O42  1  0.039  0.081  0.827  1.0
  O  O43  1  0.772  0.455  0.120  1.0
  O  O44  1  0.816  0.149  0.530  1.0
  O  O45  1  0.184  0.851  0.470  1.0
  O  O46  1  0.452  0.225  0.808  1.0
  O  O47  1  0.266  0.210  0.573  1.0
  O  O48  1  0.789  0.409  0.884  1.0
  O  O49  1  0.883  0.397  0.637  1.0
[/CIF]
.