The material described by SnCl4(H2O)2 is Indium-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of four SnCl4(H2O)2 clusters. Sn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to one Sn(1), one H(1), and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_SnH4(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.716
_cell_length_b   7.819
_cell_length_c   11.571
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   878.987
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.926  0.750  1.0
  Sn  Sn1  1  0.500  0.574  0.250  1.0
  Sn  Sn2  1  0.000  0.074  0.250  1.0
  Sn  Sn3  1  0.500  0.426  0.750  1.0
  H  H4  1  0.979  0.183  0.572  1.0
  H  H5  1  0.521  0.317  0.072  1.0
  H  H6  1  0.479  0.317  0.428  1.0
  H  H7  1  0.021  0.183  0.928  1.0
  H  H8  1  0.021  0.817  0.428  1.0
  H  H9  1  0.479  0.683  0.928  1.0
  H  H10  1  0.521  0.683  0.572  1.0
  H  H11  1  0.979  0.817  0.072  1.0
  H  H12  1  0.831  0.172  0.635  1.0
  H  H13  1  0.669  0.328  0.135  1.0
  H  H14  1  0.331  0.328  0.365  1.0
  H  H15  1  0.169  0.172  0.865  1.0
  H  H16  1  0.169  0.828  0.365  1.0
  H  H17  1  0.331  0.672  0.865  1.0
  H  H18  1  0.669  0.672  0.635  1.0
  H  H19  1  0.831  0.828  0.135  1.0
  Cl  Cl20  1  0.085  0.724  0.895  1.0
  Cl  Cl21  1  0.415  0.776  0.395  1.0
  Cl  Cl22  1  0.585  0.776  0.105  1.0
  Cl  Cl23  1  0.915  0.724  0.605  1.0
  Cl  Cl24  1  0.915  0.276  0.105  1.0
  Cl  Cl25  1  0.585  0.224  0.605  1.0
  Cl  Cl26  1  0.415  0.224  0.895  1.0
  Cl  Cl27  1  0.085  0.276  0.395  1.0
  Cl  Cl28  1  0.215  0.967  0.658  1.0
  Cl  Cl29  1  0.285  0.533  0.158  1.0
  Cl  Cl30  1  0.715  0.533  0.342  1.0
  Cl  Cl31  1  0.785  0.967  0.842  1.0
  Cl  Cl32  1  0.785  0.033  0.342  1.0
  Cl  Cl33  1  0.715  0.467  0.842  1.0
  Cl  Cl34  1  0.285  0.467  0.658  1.0
  Cl  Cl35  1  0.215  0.033  0.158  1.0
  O  O36  1  0.930  0.149  0.642  1.0
  O  O37  1  0.570  0.351  0.142  1.0
  O  O38  1  0.430  0.351  0.358  1.0
  O  O39  1  0.070  0.149  0.858  1.0
  O  O40  1  0.070  0.851  0.358  1.0
  O  O41  1  0.430  0.649  0.858  1.0
  O  O42  1  0.570  0.649  0.642  1.0
  O  O43  1  0.930  0.851  0.142  1.0
[/CIF]
.
The material described by SnCl4(H2O)2 is Indium-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of four SnCl4(H2O)2 clusters. Sn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to one Sn(1), one H(1), and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_SnH4(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.716
_cell_length_b   7.819
_cell_length_c   11.571
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   878.987
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.926  0.750  1.0
  Sn  Sn1  1  0.500  0.574  0.250  1.0
  Sn  Sn2  1  0.000  0.074  0.250  1.0
  Sn  Sn3  1  0.500  0.426  0.750  1.0
  H  H4  1  0.979  0.183  0.572  1.0
  H  H5  1  0.521  0.317  0.072  1.0
  H  H6  1  0.479  0.317  0.428  1.0
  H  H7  1  0.021  0.183  0.928  1.0
  H  H8  1  0.021  0.817  0.428  1.0
  H  H9  1  0.479  0.683  0.928  1.0
  H  H10  1  0.521  0.683  0.572  1.0
  H  H11  1  0.979  0.817  0.072  1.0
  H  H12  1  0.831  0.172  0.635  1.0
  H  H13  1  0.669  0.328  0.135  1.0
  H  H14  1  0.331  0.328  0.365  1.0
  H  H15  1  0.169  0.172  0.865  1.0
  H  H16  1  0.169  0.828  0.365  1.0
  H  H17  1  0.331  0.672  0.865  1.0
  H  H18  1  0.669  0.672  0.635  1.0
  H  H19  1  0.831  0.828  0.135  1.0
  Cl  Cl20  1  0.085  0.724  0.895  1.0
  Cl  Cl21  1  0.415  0.776  0.395  1.0
  Cl  Cl22  1  0.585  0.776  0.105  1.0
  Cl  Cl23  1  0.915  0.724  0.605  1.0
  Cl  Cl24  1  0.915  0.276  0.105  1.0
  Cl  Cl25  1  0.585  0.224  0.605  1.0
  Cl  Cl26  1  0.415  0.224  0.895  1.0
  Cl  Cl27  1  0.085  0.276  0.395  1.0
  Cl  Cl28  1  0.215  0.967  0.658  1.0
  Cl  Cl29  1  0.285  0.533  0.158  1.0
  Cl  Cl30  1  0.715  0.533  0.342  1.0
  Cl  Cl31  1  0.785  0.967  0.842  1.0
  Cl  Cl32  1  0.785  0.033  0.342  1.0
  Cl  Cl33  1  0.715  0.467  0.842  1.0
  Cl  Cl34  1  0.285  0.467  0.658  1.0
  Cl  Cl35  1  0.215  0.033  0.158  1.0
  O  O36  1  0.930  0.149  0.642  1.0
  O  O37  1  0.570  0.351  0.142  1.0
  O  O38  1  0.430  0.351  0.358  1.0
  O  O39  1  0.070  0.149  0.858  1.0
  O  O40  1  0.070  0.851  0.358  1.0
  O  O41  1  0.430  0.649  0.858  1.0
  O  O42  1  0.570  0.649  0.642  1.0
  O  O43  1  0.930  0.851  0.142  1.0
[/CIF]
.