The material described by CrBiO4 is Zircon structured and crystallizes in the monoclinic C2/c space group. Cr(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cr(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cr(1) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.109
_cell_length_b   6.171
_cell_length_c   6.172
_cell_angle_alpha   63.094
_cell_angle_beta   73.956
_cell_angle_gamma   106.053
_symmetry_Int_Tables_number   1
_cell_volume   176.130
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.750  0.626  0.124  1.0
  Bi  Bi1  1  0.250  0.375  0.875  1.0
  Cr  Cr2  1  0.250  0.875  0.375  1.0
  Cr  Cr3  1  0.750  0.125  0.625  1.0
  O  O4  1  0.437  0.710  0.369  1.0
  O  O5  1  0.437  0.227  0.194  1.0
  O  O6  1  0.063  0.694  0.727  1.0
  O  O7  1  0.063  0.869  0.211  1.0
  O  O8  1  0.937  0.131  0.790  1.0
  O  O9  1  0.938  0.306  0.273  1.0
  O  O10  1  0.563  0.773  0.806  1.0
  O  O11  1  0.563  0.289  0.632  1.0
[/CIF]
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The material described by CrBiO4 is Zircon structured and crystallizes in the monoclinic C2/c space group. Cr(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cr(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cr(1) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.109
_cell_length_b   6.171
_cell_length_c   6.172
_cell_angle_alpha   63.094
_cell_angle_beta   73.956
_cell_angle_gamma   106.053
_symmetry_Int_Tables_number   1
_cell_volume   176.130
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.750  0.626  0.124  1.0
  Bi  Bi1  1  0.250  0.375  0.875  1.0
  Cr  Cr2  1  0.250  0.875  0.375  1.0
  Cr  Cr3  1  0.750  0.125  0.625  1.0
  O  O4  1  0.437  0.710  0.369  1.0
  O  O5  1  0.437  0.227  0.194  1.0
  O  O6  1  0.063  0.694  0.727  1.0
  O  O7  1  0.063  0.869  0.211  1.0
  O  O8  1  0.937  0.131  0.790  1.0
  O  O9  1  0.938  0.306  0.273  1.0
  O  O10  1  0.563  0.773  0.806  1.0
  O  O11  1  0.563  0.289  0.632  1.0
[/CIF]
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