The material described by Li2AgF5 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a 6-coordinate geometry to one F(3), two equivalent F(2), and three equivalent F(1) atoms. Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 72°. There are three inequivalent F sites. In the first F site, F(1) is bonded to three equivalent Li(1) and one Ag(1) atom to form a mixture of distorted edge and corner-sharing FLi3Ag trigonal pyramids. In the second F site, F(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_Li2AgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.781
_cell_length_b   5.781
_cell_length_c   8.024
_cell_angle_alpha   69.539
_cell_angle_beta   69.539
_cell_angle_gamma   54.469
_symmetry_Int_Tables_number   1
_cell_volume   200.677
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.378  0.356  0.737  1.0
  Li  Li1  1  0.356  0.378  0.237  1.0
  Li  Li2  1  0.644  0.622  0.763  1.0
  Li  Li3  1  0.622  0.644  0.263  1.0
  Ag  Ag4  1  0.000  0.000  0.000  1.0
  Ag  Ag5  1  0.000  0.000  0.500  1.0
  F  F6  1  0.599  0.221  0.958  1.0
  F  F7  1  0.346  0.023  0.343  1.0
  F  F8  1  0.023  0.346  0.843  1.0
  F  F9  1  0.221  0.599  0.458  1.0
  F  F10  1  0.274  0.726  0.750  1.0
  F  F11  1  0.726  0.274  0.250  1.0
  F  F12  1  0.779  0.401  0.542  1.0
  F  F13  1  0.977  0.654  0.157  1.0
  F  F14  1  0.654  0.977  0.657  1.0
  F  F15  1  0.401  0.779  0.042  1.0
[/CIF]
.
The material described by Li2AgF5 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a 6-coordinate geometry to one F(3), two equivalent F(2), and three equivalent F(1) atoms. Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 72°. There are three inequivalent F sites. In the first F site, F(1) is bonded to three equivalent Li(1) and one Ag(1) atom to form a mixture of distorted edge and corner-sharing FLi3Ag trigonal pyramids. In the second F site, F(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_Li2AgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.781
_cell_length_b   5.781
_cell_length_c   8.024
_cell_angle_alpha   69.539
_cell_angle_beta   69.539
_cell_angle_gamma   54.469
_symmetry_Int_Tables_number   1
_cell_volume   200.677
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.378  0.356  0.737  1.0
  Li  Li1  1  0.356  0.378  0.237  1.0
  Li  Li2  1  0.644  0.622  0.763  1.0
  Li  Li3  1  0.622  0.644  0.263  1.0
  Ag  Ag4  1  0.000  0.000  0.000  1.0
  Ag  Ag5  1  0.000  0.000  0.500  1.0
  F  F6  1  0.599  0.221  0.958  1.0
  F  F7  1  0.346  0.023  0.343  1.0
  F  F8  1  0.023  0.346  0.843  1.0
  F  F9  1  0.221  0.599  0.458  1.0
  F  F10  1  0.274  0.726  0.750  1.0
  F  F11  1  0.726  0.274  0.250  1.0
  F  F12  1  0.779  0.401  0.542  1.0
  F  F13  1  0.977  0.654  0.157  1.0
  F  F14  1  0.654  0.977  0.657  1.0
  F  F15  1  0.401  0.779  0.042  1.0
[/CIF]
.