The material structure described by NaZn2(MoO5)2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form NaO6 octahedra that share corners with four equivalent Zn(1)O6 octahedra and corners with six equivalent Mo(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 63°. Mo(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form MoO4 tetrahedra that share corners with three equivalent Na(1)O6 octahedra and corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-69°. Zn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form ZnO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with four equivalent Mo(1)O4 tetrahedra, and edges with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 63°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Na(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Na(1), one Mo(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mo(1) and two equivalent Zn(1) atoms. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent Zn(1) atoms. is represented by the CIF card [CIF]
data_NaZn2(MoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.692
_cell_length_b   5.692
_cell_length_c   7.795
_cell_angle_alpha   68.582
_cell_angle_beta   68.582
_cell_angle_gamma   69.075
_symmetry_Int_Tables_number   1
_cell_volume   211.453
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Zn  Zn1  1  0.000  0.500  0.000  1.0
  Zn  Zn2  1  0.500  0.000  0.000  1.0
  Mo  Mo3  1  0.077  0.077  0.717  1.0
  Mo  Mo4  1  0.923  0.923  0.283  1.0
  O  O5  1  0.233  0.233  0.488  1.0
  O  O6  1  0.767  0.767  0.512  1.0
  O  O7  1  0.182  0.729  0.742  1.0
  O  O8  1  0.729  0.182  0.742  1.0
  O  O9  1  0.818  0.271  0.258  1.0
  O  O10  1  0.271  0.818  0.258  1.0
  O  O11  1  0.167  0.167  0.888  1.0
  O  O12  1  0.833  0.833  0.112  1.0
  O  O13  1  0.636  0.636  0.947  1.0
  O  O14  1  0.364  0.364  0.053  1.0
[/CIF]
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The material structure described by NaZn2(MoO5)2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form NaO6 octahedra that share corners with four equivalent Zn(1)O6 octahedra and corners with six equivalent Mo(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 63°. Mo(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form MoO4 tetrahedra that share corners with three equivalent Na(1)O6 octahedra and corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-69°. Zn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form ZnO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with four equivalent Mo(1)O4 tetrahedra, and edges with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 63°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Na(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Na(1), one Mo(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mo(1) and two equivalent Zn(1) atoms. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent Zn(1) atoms. is represented by the CIF card [CIF]
data_NaZn2(MoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.692
_cell_length_b   5.692
_cell_length_c   7.795
_cell_angle_alpha   68.582
_cell_angle_beta   68.582
_cell_angle_gamma   69.075
_symmetry_Int_Tables_number   1
_cell_volume   211.453
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Zn  Zn1  1  0.000  0.500  0.000  1.0
  Zn  Zn2  1  0.500  0.000  0.000  1.0
  Mo  Mo3  1  0.077  0.077  0.717  1.0
  Mo  Mo4  1  0.923  0.923  0.283  1.0
  O  O5  1  0.233  0.233  0.488  1.0
  O  O6  1  0.767  0.767  0.512  1.0
  O  O7  1  0.182  0.729  0.742  1.0
  O  O8  1  0.729  0.182  0.742  1.0
  O  O9  1  0.818  0.271  0.258  1.0
  O  O10  1  0.271  0.818  0.258  1.0
  O  O11  1  0.167  0.167  0.888  1.0
  O  O12  1  0.833  0.833  0.112  1.0
  O  O13  1  0.636  0.636  0.947  1.0
  O  O14  1  0.364  0.364  0.053  1.0
[/CIF]
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