The structure described by K2Mo3O10 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(4), two equivalent O(5), and three equivalent O(1) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mo(1), and one Mo(2) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mo(2) atom. In the third O site, O(1) is bonded to three equivalent K(1) and one Mo(1) atom to form a mixture of distorted corner and edge-sharing OK3Mo tetrahedra. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2) and two equivalent Mo(1) atoms. In the fifth O site, O(3) is bonded in a distorted linear geometry to one K(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_K2Mo3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.011
_cell_length_b   8.011
_cell_length_c   8.905
_cell_angle_alpha   82.146
_cell_angle_beta   82.146
_cell_angle_gamma   59.099
_symmetry_Int_Tables_number   1
_cell_volume   484.291
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.593  0.777  0.843  1.0
  K  K1  1  0.223  0.407  0.657  1.0
  K  K2  1  0.407  0.223  0.157  1.0
  K  K3  1  0.777  0.593  0.343  1.0
  Mo  Mo4  1  0.813  0.968  0.519  1.0
  Mo  Mo5  1  0.032  0.187  0.981  1.0
  Mo  Mo6  1  0.187  0.032  0.481  1.0
  Mo  Mo7  1  0.968  0.813  0.019  1.0
  Mo  Mo8  1  0.305  0.695  0.250  1.0
  Mo  Mo9  1  0.695  0.305  0.750  1.0
  O  O10  1  0.741  0.845  0.081  1.0
  O  O11  1  0.155  0.259  0.419  1.0
  O  O12  1  0.259  0.155  0.919  1.0
  O  O13  1  0.845  0.741  0.581  1.0
  O  O14  1  0.883  0.066  0.911  1.0
  O  O15  1  0.934  0.117  0.589  1.0
  O  O16  1  0.117  0.934  0.089  1.0
  O  O17  1  0.066  0.883  0.411  1.0
  O  O18  1  0.671  0.054  0.369  1.0
  O  O19  1  0.946  0.329  0.131  1.0
  O  O20  1  0.329  0.946  0.631  1.0
  O  O21  1  0.054  0.671  0.869  1.0
  O  O22  1  0.364  0.880  0.322  1.0
  O  O23  1  0.120  0.636  0.178  1.0
  O  O24  1  0.636  0.120  0.678  1.0
  O  O25  1  0.880  0.364  0.822  1.0
  O  O26  1  0.494  0.616  0.113  1.0
  O  O27  1  0.384  0.506  0.387  1.0
  O  O28  1  0.506  0.384  0.887  1.0
  O  O29  1  0.616  0.494  0.613  1.0
[/CIF]
.
The structure described by K2Mo3O10 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(4), two equivalent O(5), and three equivalent O(1) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mo(1), and one Mo(2) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mo(2) atom. In the third O site, O(1) is bonded to three equivalent K(1) and one Mo(1) atom to form a mixture of distorted corner and edge-sharing OK3Mo tetrahedra. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2) and two equivalent Mo(1) atoms. In the fifth O site, O(3) is bonded in a distorted linear geometry to one K(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_K2Mo3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.011
_cell_length_b   8.011
_cell_length_c   8.905
_cell_angle_alpha   82.146
_cell_angle_beta   82.146
_cell_angle_gamma   59.099
_symmetry_Int_Tables_number   1
_cell_volume   484.291
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.593  0.777  0.843  1.0
  K  K1  1  0.223  0.407  0.657  1.0
  K  K2  1  0.407  0.223  0.157  1.0
  K  K3  1  0.777  0.593  0.343  1.0
  Mo  Mo4  1  0.813  0.968  0.519  1.0
  Mo  Mo5  1  0.032  0.187  0.981  1.0
  Mo  Mo6  1  0.187  0.032  0.481  1.0
  Mo  Mo7  1  0.968  0.813  0.019  1.0
  Mo  Mo8  1  0.305  0.695  0.250  1.0
  Mo  Mo9  1  0.695  0.305  0.750  1.0
  O  O10  1  0.741  0.845  0.081  1.0
  O  O11  1  0.155  0.259  0.419  1.0
  O  O12  1  0.259  0.155  0.919  1.0
  O  O13  1  0.845  0.741  0.581  1.0
  O  O14  1  0.883  0.066  0.911  1.0
  O  O15  1  0.934  0.117  0.589  1.0
  O  O16  1  0.117  0.934  0.089  1.0
  O  O17  1  0.066  0.883  0.411  1.0
  O  O18  1  0.671  0.054  0.369  1.0
  O  O19  1  0.946  0.329  0.131  1.0
  O  O20  1  0.329  0.946  0.631  1.0
  O  O21  1  0.054  0.671  0.869  1.0
  O  O22  1  0.364  0.880  0.322  1.0
  O  O23  1  0.120  0.636  0.178  1.0
  O  O24  1  0.636  0.120  0.678  1.0
  O  O25  1  0.880  0.364  0.822  1.0
  O  O26  1  0.494  0.616  0.113  1.0
  O  O27  1  0.384  0.506  0.387  1.0
  O  O28  1  0.506  0.384  0.887  1.0
  O  O29  1  0.616  0.494  0.613  1.0
[/CIF]
.