The compound described by Rb2PaF7 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent F(2), two equivalent F(4), three equivalent F(1), and three equivalent F(3) atoms. Pa(1) is bonded in a 9-coordinate geometry to one F(2), two equivalent F(1), two equivalent F(3), and four equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Pa(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to four equivalent Rb(1) and one Pa(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Pa(1) atom. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent Pa(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2PaF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.861
_cell_length_b   7.861
_cell_length_c   8.184
_cell_angle_alpha   59.220
_cell_angle_beta   59.220
_cell_angle_gamma   52.460
_symmetry_Int_Tables_number   1
_cell_volume   329.379
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.319  0.337  0.112  1.0
  Rb  Rb1  1  0.663  0.681  0.388  1.0
  Rb  Rb2  1  0.681  0.663  0.888  1.0
  Rb  Rb3  1  0.337  0.319  0.612  1.0
  Pa  Pa4  1  0.025  0.975  0.250  1.0
  Pa  Pa5  1  0.975  0.025  0.750  1.0
  F  F6  1  0.946  0.711  0.487  1.0
  F  F7  1  0.289  0.054  0.013  1.0
  F  F8  1  0.054  0.289  0.513  1.0
  F  F9  1  0.711  0.946  0.987  1.0
  F  F10  1  0.343  0.657  0.250  1.0
  F  F11  1  0.657  0.343  0.750  1.0
  F  F12  1  0.895  0.326  0.209  1.0
  F  F13  1  0.674  0.105  0.291  1.0
  F  F14  1  0.105  0.674  0.791  1.0
  F  F15  1  0.326  0.895  0.709  1.0
  F  F16  1  0.055  0.798  0.079  1.0
  F  F17  1  0.202  0.945  0.421  1.0
  F  F18  1  0.945  0.202  0.921  1.0
  F  F19  1  0.798  0.055  0.579  1.0
[/CIF]
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The compound described by Rb2PaF7 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent F(2), two equivalent F(4), three equivalent F(1), and three equivalent F(3) atoms. Pa(1) is bonded in a 9-coordinate geometry to one F(2), two equivalent F(1), two equivalent F(3), and four equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Pa(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to four equivalent Rb(1) and one Pa(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Pa(1) atom. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent Pa(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2PaF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.861
_cell_length_b   7.861
_cell_length_c   8.184
_cell_angle_alpha   59.220
_cell_angle_beta   59.220
_cell_angle_gamma   52.460
_symmetry_Int_Tables_number   1
_cell_volume   329.379
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.319  0.337  0.112  1.0
  Rb  Rb1  1  0.663  0.681  0.388  1.0
  Rb  Rb2  1  0.681  0.663  0.888  1.0
  Rb  Rb3  1  0.337  0.319  0.612  1.0
  Pa  Pa4  1  0.025  0.975  0.250  1.0
  Pa  Pa5  1  0.975  0.025  0.750  1.0
  F  F6  1  0.946  0.711  0.487  1.0
  F  F7  1  0.289  0.054  0.013  1.0
  F  F8  1  0.054  0.289  0.513  1.0
  F  F9  1  0.711  0.946  0.987  1.0
  F  F10  1  0.343  0.657  0.250  1.0
  F  F11  1  0.657  0.343  0.750  1.0
  F  F12  1  0.895  0.326  0.209  1.0
  F  F13  1  0.674  0.105  0.291  1.0
  F  F14  1  0.105  0.674  0.791  1.0
  F  F15  1  0.326  0.895  0.709  1.0
  F  F16  1  0.055  0.798  0.079  1.0
  F  F17  1  0.202  0.945  0.421  1.0
  F  F18  1  0.945  0.202  0.921  1.0
  F  F19  1  0.798  0.055  0.579  1.0
[/CIF]
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