The material structure described by ReHOCl3CN2S is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four CN2S clusters and four ReHOCl3 clusters. In each CN2S cluster, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(2) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. S(1) is bonded in a distorted single-bond geometry to one C(1) atom. In each ReHOCl3 cluster, Re(1) is bonded in a 5-coordinate geometry to one H(1), one O(1), one Cl(1), one Cl(2), and one Cl(3) atom. H(1) is bonded in a single-bond geometry to one Re(1) atom. O(1) is bonded in a single-bond geometry to one Re(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ReHCSN2Cl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.844
_cell_length_b   11.364
_cell_length_c   11.738
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1046.315
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.302  0.154  0.656  1.0
  Re  Re1  1  0.698  0.846  0.156  1.0
  Re  Re2  1  0.698  0.654  0.656  1.0
  Re  Re3  1  0.302  0.346  0.156  1.0
  H  H4  1  0.266  0.219  0.527  1.0
  H  H5  1  0.734  0.781  0.027  1.0
  H  H6  1  0.734  0.719  0.527  1.0
  H  H7  1  0.266  0.281  0.027  1.0
  C  C8  1  0.156  0.530  0.933  1.0
  C  C9  1  0.844  0.470  0.433  1.0
  C  C10  1  0.844  0.030  0.933  1.0
  C  C11  1  0.156  0.970  0.433  1.0
  S  S12  1  0.075  0.080  0.498  1.0
  S  S13  1  0.925  0.920  0.998  1.0
  S  S14  1  0.925  0.580  0.498  1.0
  S  S15  1  0.075  0.420  0.998  1.0
  N  N16  1  0.187  0.593  0.833  1.0
  N  N17  1  0.813  0.407  0.333  1.0
  N  N18  1  0.813  0.093  0.833  1.0
  N  N19  1  0.187  0.907  0.333  1.0
  N  N20  1  0.263  0.628  0.925  1.0
  N  N21  1  0.737  0.372  0.425  1.0
  N  N22  1  0.737  0.128  0.925  1.0
  N  N23  1  0.263  0.872  0.425  1.0
  Cl  Cl24  1  0.521  0.076  0.549  1.0
  Cl  Cl25  1  0.479  0.924  0.049  1.0
  Cl  Cl26  1  0.479  0.576  0.549  1.0
  Cl  Cl27  1  0.521  0.424  0.049  1.0
  Cl  Cl28  1  0.484  0.283  0.739  1.0
  Cl  Cl29  1  0.516  0.717  0.239  1.0
  Cl  Cl30  1  0.516  0.783  0.739  1.0
  Cl  Cl31  1  0.484  0.217  0.239  1.0
  Cl  Cl32  1  0.076  0.276  0.702  1.0
  Cl  Cl33  1  0.924  0.724  0.202  1.0
  Cl  Cl34  1  0.924  0.776  0.702  1.0
  Cl  Cl35  1  0.076  0.224  0.202  1.0
  O  O36  1  0.246  0.029  0.731  1.0
  O  O37  1  0.754  0.971  0.231  1.0
  O  O38  1  0.754  0.529  0.731  1.0
  O  O39  1  0.246  0.471  0.231  1.0
[/CIF]
.
The material structure described by ReHOCl3CN2S is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four CN2S clusters and four ReHOCl3 clusters. In each CN2S cluster, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(2) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. S(1) is bonded in a distorted single-bond geometry to one C(1) atom. In each ReHOCl3 cluster, Re(1) is bonded in a 5-coordinate geometry to one H(1), one O(1), one Cl(1), one Cl(2), and one Cl(3) atom. H(1) is bonded in a single-bond geometry to one Re(1) atom. O(1) is bonded in a single-bond geometry to one Re(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ReHCSN2Cl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.844
_cell_length_b   11.364
_cell_length_c   11.738
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1046.315
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.302  0.154  0.656  1.0
  Re  Re1  1  0.698  0.846  0.156  1.0
  Re  Re2  1  0.698  0.654  0.656  1.0
  Re  Re3  1  0.302  0.346  0.156  1.0
  H  H4  1  0.266  0.219  0.527  1.0
  H  H5  1  0.734  0.781  0.027  1.0
  H  H6  1  0.734  0.719  0.527  1.0
  H  H7  1  0.266  0.281  0.027  1.0
  C  C8  1  0.156  0.530  0.933  1.0
  C  C9  1  0.844  0.470  0.433  1.0
  C  C10  1  0.844  0.030  0.933  1.0
  C  C11  1  0.156  0.970  0.433  1.0
  S  S12  1  0.075  0.080  0.498  1.0
  S  S13  1  0.925  0.920  0.998  1.0
  S  S14  1  0.925  0.580  0.498  1.0
  S  S15  1  0.075  0.420  0.998  1.0
  N  N16  1  0.187  0.593  0.833  1.0
  N  N17  1  0.813  0.407  0.333  1.0
  N  N18  1  0.813  0.093  0.833  1.0
  N  N19  1  0.187  0.907  0.333  1.0
  N  N20  1  0.263  0.628  0.925  1.0
  N  N21  1  0.737  0.372  0.425  1.0
  N  N22  1  0.737  0.128  0.925  1.0
  N  N23  1  0.263  0.872  0.425  1.0
  Cl  Cl24  1  0.521  0.076  0.549  1.0
  Cl  Cl25  1  0.479  0.924  0.049  1.0
  Cl  Cl26  1  0.479  0.576  0.549  1.0
  Cl  Cl27  1  0.521  0.424  0.049  1.0
  Cl  Cl28  1  0.484  0.283  0.739  1.0
  Cl  Cl29  1  0.516  0.717  0.239  1.0
  Cl  Cl30  1  0.516  0.783  0.739  1.0
  Cl  Cl31  1  0.484  0.217  0.239  1.0
  Cl  Cl32  1  0.076  0.276  0.702  1.0
  Cl  Cl33  1  0.924  0.724  0.202  1.0
  Cl  Cl34  1  0.924  0.776  0.702  1.0
  Cl  Cl35  1  0.076  0.224  0.202  1.0
  O  O36  1  0.246  0.029  0.731  1.0
  O  O37  1  0.754  0.971  0.231  1.0
  O  O38  1  0.754  0.529  0.731  1.0
  O  O39  1  0.246  0.471  0.231  1.0
[/CIF]
.