The structure described by Rb4InSbCl12 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a 12-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), four equivalent Cl(3), and four equivalent Cl(4) atoms. In(1) is bonded in an octahedral geometry to two equivalent Cl(1) and four equivalent Cl(4) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(3) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one In(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to four equivalent Rb(1) and one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded to four equivalent Rb(1) and one In(1) atom to form a mixture of distorted face, corner, and edge-sharing ClRb4In square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb4InSbCl12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.427
_cell_length_b   7.427
_cell_length_c   10.306
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   568.432
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.000  0.781  1.0
  Rb  Rb1  1  0.000  0.500  0.219  1.0
  Rb  Rb2  1  0.500  0.000  0.219  1.0
  Rb  Rb3  1  0.000  0.500  0.781  1.0
  In  In4  1  0.000  0.000  0.000  1.0
  Sb  Sb5  1  0.500  0.500  0.500  1.0
  Cl  Cl6  1  0.000  0.000  0.751  1.0
  Cl  Cl7  1  0.500  0.500  0.266  1.0
  Cl  Cl8  1  0.730  0.730  0.500  1.0
  Cl  Cl9  1  0.243  0.243  0.000  1.0
  Cl  Cl10  1  0.730  0.270  0.500  1.0
  Cl  Cl11  1  0.243  0.757  0.000  1.0
  Cl  Cl12  1  0.000  0.000  0.249  1.0
  Cl  Cl13  1  0.500  0.500  0.734  1.0
  Cl  Cl14  1  0.270  0.270  0.500  1.0
  Cl  Cl15  1  0.757  0.757  0.000  1.0
  Cl  Cl16  1  0.270  0.730  0.500  1.0
  Cl  Cl17  1  0.757  0.243  0.000  1.0
[/CIF]
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The structure described by Rb4InSbCl12 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a 12-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), four equivalent Cl(3), and four equivalent Cl(4) atoms. In(1) is bonded in an octahedral geometry to two equivalent Cl(1) and four equivalent Cl(4) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(3) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one In(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to four equivalent Rb(1) and one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded to four equivalent Rb(1) and one In(1) atom to form a mixture of distorted face, corner, and edge-sharing ClRb4In square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb4InSbCl12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.427
_cell_length_b   7.427
_cell_length_c   10.306
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   568.432
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.000  0.781  1.0
  Rb  Rb1  1  0.000  0.500  0.219  1.0
  Rb  Rb2  1  0.500  0.000  0.219  1.0
  Rb  Rb3  1  0.000  0.500  0.781  1.0
  In  In4  1  0.000  0.000  0.000  1.0
  Sb  Sb5  1  0.500  0.500  0.500  1.0
  Cl  Cl6  1  0.000  0.000  0.751  1.0
  Cl  Cl7  1  0.500  0.500  0.266  1.0
  Cl  Cl8  1  0.730  0.730  0.500  1.0
  Cl  Cl9  1  0.243  0.243  0.000  1.0
  Cl  Cl10  1  0.730  0.270  0.500  1.0
  Cl  Cl11  1  0.243  0.757  0.000  1.0
  Cl  Cl12  1  0.000  0.000  0.249  1.0
  Cl  Cl13  1  0.500  0.500  0.734  1.0
  Cl  Cl14  1  0.270  0.270  0.500  1.0
  Cl  Cl15  1  0.757  0.757  0.000  1.0
  Cl  Cl16  1  0.270  0.730  0.500  1.0
  Cl  Cl17  1  0.757  0.243  0.000  1.0
[/CIF]
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