The structure described by CeCl3(H2O)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and one CeH14O7Cl2 cluster. In the CeH14O7Cl2 cluster, Ce(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and two equivalent Cl(1) atoms. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(7) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ce(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ce(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Ce(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Ce(1), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Ce(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Ce(1), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Ce(1), one H(13), and one H(14) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to two equivalent Ce(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one H(2) atom. is represented by the CIF card [CIF]
data_CeH14Cl3O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.955
_cell_length_b   8.262
_cell_length_c   9.362
_cell_angle_alpha   69.736
_cell_angle_beta   73.528
_cell_angle_gamma   81.443
_symmetry_Int_Tables_number   1
_cell_volume   552.635
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.217  0.183  0.824  1.0
  Ce  Ce1  1  0.783  0.817  0.176  1.0
  H  H2  1  0.996  0.150  0.592  1.0
  H  H3  1  0.004  0.850  0.408  1.0
  H  H4  1  0.122  0.980  0.626  1.0
  H  H5  1  0.878  0.020  0.374  1.0
  H  H6  1  0.914  0.464  0.728  1.0
  H  H7  1  0.086  0.536  0.272  1.0
  H  H8  1  0.092  0.531  0.610  1.0
  H  H9  1  0.908  0.469  0.390  1.0
  H  H10  1  0.264  0.175  0.152  1.0
  H  H11  1  0.736  0.825  0.848  1.0
  H  H12  1  0.123  0.039  0.190  1.0
  H  H13  1  0.877  0.961  0.810  1.0
  H  H14  1  0.614  0.130  0.850  1.0
  H  H15  1  0.386  0.870  0.150  1.0
  H  H16  1  0.563  0.325  0.847  1.0
  H  H17  1  0.437  0.675  0.153  1.0
  H  H18  1  0.479  0.865  0.739  1.0
  H  H19  1  0.521  0.135  0.261  1.0
  H  H20  1  0.554  0.042  0.619  1.0
  H  H21  1  0.446  0.958  0.381  1.0
  H  H22  1  0.354  0.362  0.449  1.0
  H  H23  1  0.646  0.638  0.551  1.0
  H  H24  1  0.513  0.341  0.524  1.0
  H  H25  1  0.487  0.659  0.476  1.0
  H  H26  1  0.203  0.572  0.815  1.0
  H  H27  1  0.797  0.428  0.185  1.0
  H  H28  1  0.257  0.470  0.974  1.0
  H  H29  1  0.743  0.530  0.026  1.0
  Cl  Cl30  1  0.143  0.821  0.987  1.0
  Cl  Cl31  1  0.857  0.179  0.013  1.0
  Cl  Cl32  1  0.788  0.223  0.461  1.0
  Cl  Cl33  1  0.212  0.777  0.539  1.0
  Cl  Cl34  1  0.337  0.385  0.212  1.0
  Cl  Cl35  1  0.663  0.615  0.788  1.0
  O  O36  1  0.061  0.074  0.669  1.0
  O  O37  1  0.939  0.926  0.331  1.0
  O  O38  1  0.032  0.424  0.676  1.0
  O  O39  1  0.968  0.576  0.324  1.0
  O  O40  1  0.235  0.086  0.116  1.0
  O  O41  1  0.765  0.914  0.884  1.0
  O  O42  1  0.522  0.224  0.837  1.0
  O  O43  1  0.478  0.776  0.163  1.0
  O  O44  1  0.448  0.989  0.697  1.0
  O  O45  1  0.552  0.011  0.303  1.0
  O  O46  1  0.383  0.352  0.548  1.0
  O  O47  1  0.617  0.648  0.452  1.0
  O  O48  1  0.220  0.456  0.887  1.0
  O  O49  1  0.780  0.544  0.113  1.0
[/CIF]
.
The structure described by CeCl3(H2O)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and one CeH14O7Cl2 cluster. In the CeH14O7Cl2 cluster, Ce(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and two equivalent Cl(1) atoms. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(7) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ce(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ce(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Ce(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Ce(1), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Ce(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Ce(1), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Ce(1), one H(13), and one H(14) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to two equivalent Ce(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one H(2) atom. is represented by the CIF card [CIF]
data_CeH14Cl3O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.955
_cell_length_b   8.262
_cell_length_c   9.362
_cell_angle_alpha   69.736
_cell_angle_beta   73.528
_cell_angle_gamma   81.443
_symmetry_Int_Tables_number   1
_cell_volume   552.635
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.217  0.183  0.824  1.0
  Ce  Ce1  1  0.783  0.817  0.176  1.0
  H  H2  1  0.996  0.150  0.592  1.0
  H  H3  1  0.004  0.850  0.408  1.0
  H  H4  1  0.122  0.980  0.626  1.0
  H  H5  1  0.878  0.020  0.374  1.0
  H  H6  1  0.914  0.464  0.728  1.0
  H  H7  1  0.086  0.536  0.272  1.0
  H  H8  1  0.092  0.531  0.610  1.0
  H  H9  1  0.908  0.469  0.390  1.0
  H  H10  1  0.264  0.175  0.152  1.0
  H  H11  1  0.736  0.825  0.848  1.0
  H  H12  1  0.123  0.039  0.190  1.0
  H  H13  1  0.877  0.961  0.810  1.0
  H  H14  1  0.614  0.130  0.850  1.0
  H  H15  1  0.386  0.870  0.150  1.0
  H  H16  1  0.563  0.325  0.847  1.0
  H  H17  1  0.437  0.675  0.153  1.0
  H  H18  1  0.479  0.865  0.739  1.0
  H  H19  1  0.521  0.135  0.261  1.0
  H  H20  1  0.554  0.042  0.619  1.0
  H  H21  1  0.446  0.958  0.381  1.0
  H  H22  1  0.354  0.362  0.449  1.0
  H  H23  1  0.646  0.638  0.551  1.0
  H  H24  1  0.513  0.341  0.524  1.0
  H  H25  1  0.487  0.659  0.476  1.0
  H  H26  1  0.203  0.572  0.815  1.0
  H  H27  1  0.797  0.428  0.185  1.0
  H  H28  1  0.257  0.470  0.974  1.0
  H  H29  1  0.743  0.530  0.026  1.0
  Cl  Cl30  1  0.143  0.821  0.987  1.0
  Cl  Cl31  1  0.857  0.179  0.013  1.0
  Cl  Cl32  1  0.788  0.223  0.461  1.0
  Cl  Cl33  1  0.212  0.777  0.539  1.0
  Cl  Cl34  1  0.337  0.385  0.212  1.0
  Cl  Cl35  1  0.663  0.615  0.788  1.0
  O  O36  1  0.061  0.074  0.669  1.0
  O  O37  1  0.939  0.926  0.331  1.0
  O  O38  1  0.032  0.424  0.676  1.0
  O  O39  1  0.968  0.576  0.324  1.0
  O  O40  1  0.235  0.086  0.116  1.0
  O  O41  1  0.765  0.914  0.884  1.0
  O  O42  1  0.522  0.224  0.837  1.0
  O  O43  1  0.478  0.776  0.163  1.0
  O  O44  1  0.448  0.989  0.697  1.0
  O  O45  1  0.552  0.011  0.303  1.0
  O  O46  1  0.383  0.352  0.548  1.0
  O  O47  1  0.617  0.648  0.452  1.0
  O  O48  1  0.220  0.456  0.887  1.0
  O  O49  1  0.780  0.544  0.113  1.0
[/CIF]
.