The crystal structure described by Na3Cd4P5H9O22Cl3HPO2 crystallizes in the triclinic P1 space group. The structure consists of one phosphonous acid molecule inside a Na3Cd4P5H9O22Cl3 framework. In the Na3Cd4P5H9O22Cl3 framework, there are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 5-coordinate geometry to one O(1), one O(13), one O(18), one O(3), and one O(7) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(5), one Cl(1), and one Cl(3) atom. In the third Na site, Na(3) is bonded in a 5-coordinate geometry to one O(13), one O(2), one O(20), one O(8), and one Cl(3) atom. There are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one O(16), one O(23), one O(24), one O(6), one Cl(2), and one Cl(3) atom. In the second Cd site, Cd(2) is bonded in a distorted T-shaped geometry to one O(1), one O(12), and one O(20) atom. In the third Cd site, Cd(3) is bonded in a trigonal pyramidal geometry to one O(12), one O(15), one O(19), and one Cl(3) atom. In the fourth Cd site, Cd(4) is bonded in a 7-coordinate geometry to one O(10), one O(13), one O(21), one O(22), one O(6), one O(8), and one Cl(2) atom. There are five inequivalent P sites. In the first P site, P(1) is bonded in a trigonal planar geometry to one O(19), one O(24), and one O(4) atom. In the second P site, P(2) is bonded in a 2-coordinate geometry to one H(3), one O(3), and one O(5) atom. In the third P site, P(3) is bonded in a distorted trigonal bipyramidal geometry to one O(10), one O(11), one O(13), one O(18), and one O(9) atom. In the fourth P site, P(4) is bonded in a trigonal non-coplanar geometry to one O(15), one O(16), and one O(6) atom. In the fifth P site, P(6) is bonded in a tetrahedral geometry to one O(2), one O(21), one O(22), and one O(7) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(12) atom. In the second H site, H(2) is bonded in a linear geometry to one O(21) and one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(20) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(23) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(22) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one O(23) atom. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Cd(2), and one O(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Na(3) and one P(6) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(2), one P(1), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Na(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Cd(1), one Cd(4), and one P(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(1), one P(6), and one O(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Na(3), one Cd(4), and one Cl(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one P(3) and one H(7) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Cd(4), one P(3), and one H(5) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Na(2), one P(3), and one O(18) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Cd(2), one Cd(3), and one H(1) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Cd(4), and one P(3) atom. In the fourteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Cd(3) and one P(4) atom. In the fifteenth O site, O(16) is bonded in a 1-coordinate geometry to one Cd(1) and one P(4) atom. In the sixteenth O site, O(18) is bonded in a 3-coordinate geometry to one Na(1), one P(3), and one O(11) atom. In the seventeenth O site, O(19) is bonded in a bent 120 degrees geometry to one Cd(3) and one P(1) atom. In the eighteenth O site, O(20) is bonded in a distorted single-bond geometry to one Na(3), one Cd(2), and one H(4) atom. In the nineteenth O site, O(21) is bonded in a distorted water-like geometry to one Cd(4), one P(6), and one H(2) atom. In the twentieth O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Cd(4), one P(6), and one H(8) atom. In the twenty-first O site, O(23) is bonded in a distorted water-like geometry to one Cd(1), one H(10), and one H(6) atom. In the twenty-second O site, O(24) is bonded in a distorted linear geometry to one Cd(1) and one P(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Na(2) and one O(8) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Cd(1) and one Cd(4) atom. In the third Cl site, Cl(3) is bonded in a trigonal pyramidal geometry to one Na(2), one Na(3), one Cd(1), and one Cd(3) atom. is represented by the CIF file [CIF]
data_Na3Cd4P6H10(ClO8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.322
_cell_length_b   9.412
_cell_length_c   10.455
_cell_angle_alpha   63.996
_cell_angle_beta   77.495
_cell_angle_gamma   64.133
_symmetry_Int_Tables_number   1
_cell_volume   741.498
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.980  0.791  0.795  1.0
  Na  Na1  1  0.950  0.799  0.406  1.0
  Na  Na2  1  0.960  0.222  0.504  1.0
  Cd  Cd3  1  0.251  0.002  0.100  1.0
  Cd  Cd4  1  0.768  0.510  0.741  1.0
  Cd  Cd5  1  0.751  0.286  0.153  1.0
  Cd  Cd6  1  0.301  0.980  0.758  1.0
  P  P7  1  0.623  0.007  0.177  1.0
  P  P8  1  0.820  0.747  0.142  1.0
  P  P9  1  0.293  0.748  0.622  1.0
  P  P10  1  0.404  0.631  0.166  1.0
  P  P11  1  0.272  0.486  0.147  1.0
  P  P12  1  0.628  0.052  0.591  1.0
  H  H13  1  0.795  0.564  0.960  1.0
  H  H14  1  0.568  0.982  0.443  1.0
  H  H15  1  0.755  0.630  0.246  1.0
  H  H16  1  0.662  0.485  0.551  1.0
  H  H17  1  0.377  0.624  0.843  1.0
  H  H18  1  0.156  0.335  0.880  1.0
  H  H19  1  0.385  0.717  0.421  1.0
  H  H20  1  0.453  0.263  0.654  1.0
  H  H21  1  0.387  0.313  0.205  1.0
  H  H22  1  0.283  0.341  0.951  1.0
  Cl  Cl23  1  0.139  0.420  0.591  1.0
  Cl  Cl24  1  0.057  0.062  0.914  1.0
  Cl  Cl25  1  0.021  0.109  0.271  1.0
  O  O26  1  0.820  0.752  0.646  1.0
  O  O27  1  0.729  0.141  0.488  1.0
  O  O28  1  0.826  0.744  1.000  1.0
  O  O29  1  0.672  0.949  0.327  1.0
  O  O30  1  0.943  0.767  0.196  1.0
  O  O31  1  0.405  0.771  0.015  1.0
  O  O32  1  0.722  0.874  0.718  1.0
  O  O33  1  0.167  0.240  0.585  1.0
  O  O34  1  0.426  0.717  0.502  1.0
  O  O35  1  0.422  0.680  0.747  1.0
  O  O36  1  0.152  0.723  0.556  1.0
  O  O37  1  0.822  0.456  0.950  1.0
  O  O38  1  0.189  0.929  0.619  1.0
  O  O39  1  0.263  0.536  0.987  1.0
  O  O40  1  0.565  0.484  0.222  1.0
  O  O41  1  0.317  0.719  0.272  1.0
  O  O42  1  0.127  0.483  0.244  1.0
  O  O43  1  0.213  0.606  0.710  1.0
  O  O44  1  0.660  0.159  0.066  1.0
  O  O45  1  0.766  0.415  0.595  1.0
  O  O46  1  0.513  0.018  0.529  1.0
  O  O47  1  0.508  0.138  0.696  1.0
  O  O48  1  0.257  0.262  0.928  1.0
  O  O49  1  0.477  0.987  0.162  1.0
[/CIF]
.
The crystal structure described by Na3Cd4P5H9O22Cl3HPO2 crystallizes in the triclinic P1 space group. The structure consists of one phosphonous acid molecule inside a Na3Cd4P5H9O22Cl3 framework. In the Na3Cd4P5H9O22Cl3 framework, there are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 5-coordinate geometry to one O(1), one O(13), one O(18), one O(3), and one O(7) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(5), one Cl(1), and one Cl(3) atom. In the third Na site, Na(3) is bonded in a 5-coordinate geometry to one O(13), one O(2), one O(20), one O(8), and one Cl(3) atom. There are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one O(16), one O(23), one O(24), one O(6), one Cl(2), and one Cl(3) atom. In the second Cd site, Cd(2) is bonded in a distorted T-shaped geometry to one O(1), one O(12), and one O(20) atom. In the third Cd site, Cd(3) is bonded in a trigonal pyramidal geometry to one O(12), one O(15), one O(19), and one Cl(3) atom. In the fourth Cd site, Cd(4) is bonded in a 7-coordinate geometry to one O(10), one O(13), one O(21), one O(22), one O(6), one O(8), and one Cl(2) atom. There are five inequivalent P sites. In the first P site, P(1) is bonded in a trigonal planar geometry to one O(19), one O(24), and one O(4) atom. In the second P site, P(2) is bonded in a 2-coordinate geometry to one H(3), one O(3), and one O(5) atom. In the third P site, P(3) is bonded in a distorted trigonal bipyramidal geometry to one O(10), one O(11), one O(13), one O(18), and one O(9) atom. In the fourth P site, P(4) is bonded in a trigonal non-coplanar geometry to one O(15), one O(16), and one O(6) atom. In the fifth P site, P(6) is bonded in a tetrahedral geometry to one O(2), one O(21), one O(22), and one O(7) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(12) atom. In the second H site, H(2) is bonded in a linear geometry to one O(21) and one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(20) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(23) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(22) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one O(23) atom. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Cd(2), and one O(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Na(3) and one P(6) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(2), one P(1), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Na(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Cd(1), one Cd(4), and one P(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(1), one P(6), and one O(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Na(3), one Cd(4), and one Cl(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one P(3) and one H(7) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Cd(4), one P(3), and one H(5) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Na(2), one P(3), and one O(18) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Cd(2), one Cd(3), and one H(1) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Cd(4), and one P(3) atom. In the fourteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Cd(3) and one P(4) atom. In the fifteenth O site, O(16) is bonded in a 1-coordinate geometry to one Cd(1) and one P(4) atom. In the sixteenth O site, O(18) is bonded in a 3-coordinate geometry to one Na(1), one P(3), and one O(11) atom. In the seventeenth O site, O(19) is bonded in a bent 120 degrees geometry to one Cd(3) and one P(1) atom. In the eighteenth O site, O(20) is bonded in a distorted single-bond geometry to one Na(3), one Cd(2), and one H(4) atom. In the nineteenth O site, O(21) is bonded in a distorted water-like geometry to one Cd(4), one P(6), and one H(2) atom. In the twentieth O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Cd(4), one P(6), and one H(8) atom. In the twenty-first O site, O(23) is bonded in a distorted water-like geometry to one Cd(1), one H(10), and one H(6) atom. In the twenty-second O site, O(24) is bonded in a distorted linear geometry to one Cd(1) and one P(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Na(2) and one O(8) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Cd(1) and one Cd(4) atom. In the third Cl site, Cl(3) is bonded in a trigonal pyramidal geometry to one Na(2), one Na(3), one Cd(1), and one Cd(3) atom. is represented by the CIF file [CIF]
data_Na3Cd4P6H10(ClO8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.322
_cell_length_b   9.412
_cell_length_c   10.455
_cell_angle_alpha   63.996
_cell_angle_beta   77.495
_cell_angle_gamma   64.133
_symmetry_Int_Tables_number   1
_cell_volume   741.498
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.980  0.791  0.795  1.0
  Na  Na1  1  0.950  0.799  0.406  1.0
  Na  Na2  1  0.960  0.222  0.504  1.0
  Cd  Cd3  1  0.251  0.002  0.100  1.0
  Cd  Cd4  1  0.768  0.510  0.741  1.0
  Cd  Cd5  1  0.751  0.286  0.153  1.0
  Cd  Cd6  1  0.301  0.980  0.758  1.0
  P  P7  1  0.623  0.007  0.177  1.0
  P  P8  1  0.820  0.747  0.142  1.0
  P  P9  1  0.293  0.748  0.622  1.0
  P  P10  1  0.404  0.631  0.166  1.0
  P  P11  1  0.272  0.486  0.147  1.0
  P  P12  1  0.628  0.052  0.591  1.0
  H  H13  1  0.795  0.564  0.960  1.0
  H  H14  1  0.568  0.982  0.443  1.0
  H  H15  1  0.755  0.630  0.246  1.0
  H  H16  1  0.662  0.485  0.551  1.0
  H  H17  1  0.377  0.624  0.843  1.0
  H  H18  1  0.156  0.335  0.880  1.0
  H  H19  1  0.385  0.717  0.421  1.0
  H  H20  1  0.453  0.263  0.654  1.0
  H  H21  1  0.387  0.313  0.205  1.0
  H  H22  1  0.283  0.341  0.951  1.0
  Cl  Cl23  1  0.139  0.420  0.591  1.0
  Cl  Cl24  1  0.057  0.062  0.914  1.0
  Cl  Cl25  1  0.021  0.109  0.271  1.0
  O  O26  1  0.820  0.752  0.646  1.0
  O  O27  1  0.729  0.141  0.488  1.0
  O  O28  1  0.826  0.744  1.000  1.0
  O  O29  1  0.672  0.949  0.327  1.0
  O  O30  1  0.943  0.767  0.196  1.0
  O  O31  1  0.405  0.771  0.015  1.0
  O  O32  1  0.722  0.874  0.718  1.0
  O  O33  1  0.167  0.240  0.585  1.0
  O  O34  1  0.426  0.717  0.502  1.0
  O  O35  1  0.422  0.680  0.747  1.0
  O  O36  1  0.152  0.723  0.556  1.0
  O  O37  1  0.822  0.456  0.950  1.0
  O  O38  1  0.189  0.929  0.619  1.0
  O  O39  1  0.263  0.536  0.987  1.0
  O  O40  1  0.565  0.484  0.222  1.0
  O  O41  1  0.317  0.719  0.272  1.0
  O  O42  1  0.127  0.483  0.244  1.0
  O  O43  1  0.213  0.606  0.710  1.0
  O  O44  1  0.660  0.159  0.066  1.0
  O  O45  1  0.766  0.415  0.595  1.0
  O  O46  1  0.513  0.018  0.529  1.0
  O  O47  1  0.508  0.138  0.696  1.0
  O  O48  1  0.257  0.262  0.928  1.0
  O  O49  1  0.477  0.987  0.162  1.0
[/CIF]
.