The crystal structure described by ReO2 is beta Vanadium nitride-like structured and crystallizes in the orthorhombic Pbcn space group. Re(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 43-44°. O(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. is represented by the CIF file [CIF]
data_ReO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.585
_cell_length_b   4.854
_cell_length_c   5.661
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   125.985
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.250  0.500  0.607  1.0
  Re  Re1  1  0.750  0.000  0.893  1.0
  Re  Re2  1  0.750  0.500  0.393  1.0
  Re  Re3  1  0.250  0.000  0.107  1.0
  O  O4  1  0.591  0.241  0.640  1.0
  O  O5  1  0.091  0.259  0.860  1.0
  O  O6  1  0.409  0.741  0.860  1.0
  O  O7  1  0.909  0.759  0.640  1.0
  O  O8  1  0.091  0.241  0.360  1.0
  O  O9  1  0.591  0.259  0.140  1.0
  O  O10  1  0.909  0.741  0.140  1.0
  O  O11  1  0.409  0.759  0.360  1.0
[/CIF]
.
The crystal structure described by ReO2 is beta Vanadium nitride-like structured and crystallizes in the orthorhombic Pbcn space group. Re(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 43-44°. O(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. is represented by the CIF file [CIF]
data_ReO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.585
_cell_length_b   4.854
_cell_length_c   5.661
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   125.985
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.250  0.500  0.607  1.0
  Re  Re1  1  0.750  0.000  0.893  1.0
  Re  Re2  1  0.750  0.500  0.393  1.0
  Re  Re3  1  0.250  0.000  0.107  1.0
  O  O4  1  0.591  0.241  0.640  1.0
  O  O5  1  0.091  0.259  0.860  1.0
  O  O6  1  0.409  0.741  0.860  1.0
  O  O7  1  0.909  0.759  0.640  1.0
  O  O8  1  0.091  0.241  0.360  1.0
  O  O9  1  0.591  0.259  0.140  1.0
  O  O10  1  0.909  0.741  0.140  1.0
  O  O11  1  0.409  0.759  0.360  1.0
[/CIF]
.