The material described by Re2O2F9Sb2F11 is Tetraauricupride structured and crystallizes in the monoclinic P2 space group. The structure is zero-dimensional and consists of one Re2O2F9 cluster and one Sb2F11 cluster. In the Re2O2F9 cluster, Re(1) is bonded to one O(1), one F(2), one F(3), one F(5), one F(6), and one F(8) atom to form distorted corner-sharing ReOF5 octahedra. The corner-sharing octahedral tilt angles are 8°. O(1) is bonded in a single-bond geometry to one Re(1) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Re(1) atom. In the second F site, F(3) is bonded in a linear geometry to two equivalent Re(1) atoms. In the third F site, F(5) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Re(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Re(1) atom. In the Sb2F11 cluster, Sb(1) is bonded to one F(1), one F(10), one F(11), one F(4), one F(7), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 2°. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(7) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the fourth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(10) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_ReSbOF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.698
_cell_length_b   8.203
_cell_length_c   8.220
_cell_angle_alpha   85.488
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.281
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.011  0.808  0.190  1.0
  Re  Re1  1  0.011  0.192  0.810  1.0
  Sb  Sb2  1  0.514  0.329  0.325  1.0
  Sb  Sb3  1  0.514  0.671  0.675  1.0
  O  O4  1  0.026  0.343  0.660  1.0
  O  O5  1  0.026  0.657  0.340  1.0
  F  F6  1  0.282  0.762  0.568  1.0
  F  F7  1  0.007  0.016  0.683  1.0
  F  F8  1  0.989  0.000  0.000  1.0
  F  F9  1  0.350  0.482  0.200  1.0
  F  F10  1  0.014  0.317  0.987  1.0
  F  F11  1  0.280  0.155  0.843  1.0
  F  F12  1  0.508  0.500  0.500  1.0
  F  F13  1  0.737  0.820  0.173  1.0
  F  F14  1  0.007  0.984  0.317  1.0
  F  F15  1  0.518  0.174  0.166  1.0
  F  F16  1  0.744  0.558  0.759  1.0
  F  F17  1  0.280  0.845  0.157  1.0
  F  F18  1  0.678  0.204  0.477  1.0
  F  F19  1  0.014  0.683  0.013  1.0
  F  F20  1  0.737  0.180  0.827  1.0
  F  F21  1  0.518  0.826  0.834  1.0
  F  F22  1  0.678  0.796  0.523  1.0
  F  F23  1  0.350  0.518  0.800  1.0
  F  F24  1  0.744  0.442  0.241  1.0
  F  F25  1  0.282  0.238  0.432  1.0
[/CIF]
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The material described by Re2O2F9Sb2F11 is Tetraauricupride structured and crystallizes in the monoclinic P2 space group. The structure is zero-dimensional and consists of one Re2O2F9 cluster and one Sb2F11 cluster. In the Re2O2F9 cluster, Re(1) is bonded to one O(1), one F(2), one F(3), one F(5), one F(6), and one F(8) atom to form distorted corner-sharing ReOF5 octahedra. The corner-sharing octahedral tilt angles are 8°. O(1) is bonded in a single-bond geometry to one Re(1) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Re(1) atom. In the second F site, F(3) is bonded in a linear geometry to two equivalent Re(1) atoms. In the third F site, F(5) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Re(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Re(1) atom. In the Sb2F11 cluster, Sb(1) is bonded to one F(1), one F(10), one F(11), one F(4), one F(7), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 2°. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(7) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the fourth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(10) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_ReSbOF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.698
_cell_length_b   8.203
_cell_length_c   8.220
_cell_angle_alpha   85.488
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.281
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.011  0.808  0.190  1.0
  Re  Re1  1  0.011  0.192  0.810  1.0
  Sb  Sb2  1  0.514  0.329  0.325  1.0
  Sb  Sb3  1  0.514  0.671  0.675  1.0
  O  O4  1  0.026  0.343  0.660  1.0
  O  O5  1  0.026  0.657  0.340  1.0
  F  F6  1  0.282  0.762  0.568  1.0
  F  F7  1  0.007  0.016  0.683  1.0
  F  F8  1  0.989  0.000  0.000  1.0
  F  F9  1  0.350  0.482  0.200  1.0
  F  F10  1  0.014  0.317  0.987  1.0
  F  F11  1  0.280  0.155  0.843  1.0
  F  F12  1  0.508  0.500  0.500  1.0
  F  F13  1  0.737  0.820  0.173  1.0
  F  F14  1  0.007  0.984  0.317  1.0
  F  F15  1  0.518  0.174  0.166  1.0
  F  F16  1  0.744  0.558  0.759  1.0
  F  F17  1  0.280  0.845  0.157  1.0
  F  F18  1  0.678  0.204  0.477  1.0
  F  F19  1  0.014  0.683  0.013  1.0
  F  F20  1  0.737  0.180  0.827  1.0
  F  F21  1  0.518  0.826  0.834  1.0
  F  F22  1  0.678  0.796  0.523  1.0
  F  F23  1  0.350  0.518  0.800  1.0
  F  F24  1  0.744  0.442  0.241  1.0
  F  F25  1  0.282  0.238  0.432  1.0
[/CIF]
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