The structure described by LiSr4Y2(RuO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(6), and one O(9) atom. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. In the third Sr site, Sr(3) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(2), one O(6), one O(7), one O(8), one O(9), and two equivalent O(1) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(5), and one O(7) atom to form YO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with four equivalent Ru(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-33°. In the second Y site, Y(2) is bonded to one O(1), one O(11), one O(3), one O(6), one O(8), and one O(9) atom to form distorted YO6 octahedra that share corners with two equivalent Ru(2)O6 octahedra and corners with four equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-37°. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(11), one O(2), one O(4), one O(6), one O(8), and one O(9) atom to form RuO6 octahedra that share corners with two equivalent Y(1)O6 octahedra and corners with four equivalent Y(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-37°. In the second Ru site, Ru(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(7) atom to form RuO6 octahedra that share corners with two equivalent Y(2)O6 octahedra and corners with four equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-29°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), one Sr(3), two equivalent Sr(4), one Y(2), and one Ru(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), one Sr(3), one Sr(4), one Y(1), and one Ru(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Y(2), and one Ru(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Y(1), and one Ru(1) atom. In the fifth O site, O(5) is bonded in a distorted square pyramidal geometry to one Sr(1), one Sr(2), one Sr(3), one Y(1), and one Ru(2) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Li(1), one Sr(1), one Sr(2), one Sr(4), one Y(2), and one Ru(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), one Y(1), and one Ru(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one Y(2), and one Ru(1) atom. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to one Li(1), one Sr(2), one Sr(3), one Sr(4), one Y(2), and one Ru(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one Y(1), and one Ru(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Y(2), and one Ru(1) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), one Y(1), and one Ru(2) atom. is represented by the CIF file [CIF]
data_Sr4LiY2(RuO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.741
_cell_length_b   6.048
_cell_length_c   8.305
_cell_angle_alpha   88.427
_cell_angle_beta   91.300
_cell_angle_gamma   90.880
_symmetry_Int_Tables_number   1
_cell_volume   288.169
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.517  0.553  0.257  1.0
  Sr  Sr1  1  0.989  0.059  0.247  1.0
  Sr  Sr2  1  0.037  0.904  0.718  1.0
  Sr  Sr3  1  0.457  0.448  0.752  1.0
  Li  Li4  1  0.851  0.212  0.856  1.0
  Y  Y5  1  0.510  0.999  0.498  1.0
  Y  Y6  1  0.998  0.537  0.016  1.0
  Ru  Ru7  1  0.488  0.009  0.000  1.0
  Ru  Ru8  1  0.002  0.488  0.500  1.0
  O  O9  1  0.921  0.497  0.741  1.0
  O  O10  1  0.599  0.041  0.766  1.0
  O  O11  1  0.084  0.483  0.268  1.0
  O  O12  1  0.418  0.979  0.232  1.0
  O  O13  1  0.810  0.766  0.460  1.0
  O  O14  1  0.686  0.291  0.040  1.0
  O  O15  1  0.199  0.217  0.539  1.0
  O  O16  1  0.307  0.734  0.950  1.0
  O  O17  1  0.195  0.193  0.952  1.0
  O  O18  1  0.284  0.692  0.540  1.0
  O  O19  1  0.771  0.820  0.044  1.0
  O  O20  1  0.731  0.296  0.452  1.0
[/CIF]
.
The structure described by LiSr4Y2(RuO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(6), and one O(9) atom. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. In the third Sr site, Sr(3) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(2), one O(6), one O(7), one O(8), one O(9), and two equivalent O(1) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(5), and one O(7) atom to form YO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with four equivalent Ru(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-33°. In the second Y site, Y(2) is bonded to one O(1), one O(11), one O(3), one O(6), one O(8), and one O(9) atom to form distorted YO6 octahedra that share corners with two equivalent Ru(2)O6 octahedra and corners with four equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-37°. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(11), one O(2), one O(4), one O(6), one O(8), and one O(9) atom to form RuO6 octahedra that share corners with two equivalent Y(1)O6 octahedra and corners with four equivalent Y(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-37°. In the second Ru site, Ru(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(7) atom to form RuO6 octahedra that share corners with two equivalent Y(2)O6 octahedra and corners with four equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-29°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), one Sr(3), two equivalent Sr(4), one Y(2), and one Ru(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), one Sr(3), one Sr(4), one Y(1), and one Ru(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Y(2), and one Ru(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Y(1), and one Ru(1) atom. In the fifth O site, O(5) is bonded in a distorted square pyramidal geometry to one Sr(1), one Sr(2), one Sr(3), one Y(1), and one Ru(2) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Li(1), one Sr(1), one Sr(2), one Sr(4), one Y(2), and one Ru(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), one Y(1), and one Ru(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one Y(2), and one Ru(1) atom. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to one Li(1), one Sr(2), one Sr(3), one Sr(4), one Y(2), and one Ru(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one Y(1), and one Ru(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Y(2), and one Ru(1) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), one Y(1), and one Ru(2) atom. is represented by the CIF file [CIF]
data_Sr4LiY2(RuO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.741
_cell_length_b   6.048
_cell_length_c   8.305
_cell_angle_alpha   88.427
_cell_angle_beta   91.300
_cell_angle_gamma   90.880
_symmetry_Int_Tables_number   1
_cell_volume   288.169
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.517  0.553  0.257  1.0
  Sr  Sr1  1  0.989  0.059  0.247  1.0
  Sr  Sr2  1  0.037  0.904  0.718  1.0
  Sr  Sr3  1  0.457  0.448  0.752  1.0
  Li  Li4  1  0.851  0.212  0.856  1.0
  Y  Y5  1  0.510  0.999  0.498  1.0
  Y  Y6  1  0.998  0.537  0.016  1.0
  Ru  Ru7  1  0.488  0.009  0.000  1.0
  Ru  Ru8  1  0.002  0.488  0.500  1.0
  O  O9  1  0.921  0.497  0.741  1.0
  O  O10  1  0.599  0.041  0.766  1.0
  O  O11  1  0.084  0.483  0.268  1.0
  O  O12  1  0.418  0.979  0.232  1.0
  O  O13  1  0.810  0.766  0.460  1.0
  O  O14  1  0.686  0.291  0.040  1.0
  O  O15  1  0.199  0.217  0.539  1.0
  O  O16  1  0.307  0.734  0.950  1.0
  O  O17  1  0.195  0.193  0.952  1.0
  O  O18  1  0.284  0.692  0.540  1.0
  O  O19  1  0.771  0.820  0.044  1.0
  O  O20  1  0.731  0.296  0.452  1.0
[/CIF]
.