The structure described by LiLa4Ga2(FeO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a trigonal planar geometry to one O(1), one O(12), and one O(6) atom. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(2), one O(5), one O(7), and one O(9) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(8) atom. In the third La site, La(3) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. In the fourth La site, La(4) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Ga(1)O6 octahedra and corners with four equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-35°. In the second Fe site, Fe(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(7) atom. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form GaO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 31°. In the second Ga site, Ga(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form GaO6 octahedra that share corners with four equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-35°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Fe(2), and one Ga(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Fe(1), and one Ga(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(2) atom. In the fourth O site, O(4) is bonded to one La(3), one La(4), one Fe(1), and one Ga(1) atom to form a mixture of distorted corner and edge-sharing OLa2GaFe tetrahedra. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Fe(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Li(1), one La(2), one La(4), one Fe(2), and one Ga(1) atom. In the seventh O site, O(7) is bonded to one La(1), one La(3), one La(4), one Fe(2), and one Ga(1) atom to form distorted OLa3GaFe trigonal bipyramids that share  a cornercorner with one O(9)La3GaFe square pyramid, corners with three equivalent O(4)La2GaFe tetrahedra, corners with two equivalent O(11)La3GaFe trigonal bipyramids,  an edgeedge with one O(9)La3GaFe square pyramid, and  an edgeedge with one O(11)La3GaFe trigonal bipyramid. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(2), one La(3), one La(4), one Fe(1), and one Ga(2) atom. In the ninth O site, O(9) is bonded to one La(1), one La(3), one La(4), one Fe(1), and one Ga(2) atom to form distorted OLa3GaFe square pyramids that share corners with three equivalent O(4)La2GaFe tetrahedra,  a cornercorner with one O(7)La3GaFe trigonal bipyramid, corners with two equivalent O(11)La3GaFe trigonal bipyramids, and  an edgeedge with one O(7)La3GaFe trigonal bipyramid. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(2), one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eleventh O site, O(11) is bonded to one La(1), one La(2), one La(3), one Fe(2), and one Ga(1) atom to form distorted OLa3GaFe trigonal bipyramids that share corners with two equivalent O(9)La3GaFe square pyramids, corners with two equivalent O(7)La3GaFe trigonal bipyramids,  an edgeedge with one O(4)La2GaFe tetrahedra, and  an edgeedge with one O(7)La3GaFe trigonal bipyramid. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(1), one La(2), one La(4), one Fe(1), and one Ga(2) atom. is represented by the CIF file [CIF]
data_LiLa4Ga2(FeO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.893
_cell_length_b   5.674
_cell_length_c   7.856
_cell_angle_alpha   89.705
_cell_angle_beta   89.884
_cell_angle_gamma   88.661
_symmetry_Int_Tables_number   1
_cell_volume   262.575
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.313  0.121  0.763  1.0
  La  La1  1  0.468  0.528  0.748  1.0
  La  La2  1  0.907  0.012  0.754  1.0
  La  La3  1  0.563  0.512  0.245  1.0
  La  La4  1  0.057  0.987  0.245  1.0
  Ga  Ga5  1  0.011  0.501  0.998  1.0
  Ga  Ga6  1  0.508  0.003  0.485  1.0
  Fe  Fe7  1  0.010  0.500  0.500  1.0
  Fe  Fe8  1  0.507  0.996  0.017  1.0
  O  O9  1  0.528  0.916  0.736  1.0
  O  O10  1  0.029  0.595  0.747  1.0
  O  O11  1  0.467  0.103  0.260  1.0
  O  O12  1  0.978  0.409  0.252  1.0
  O  O13  1  0.704  0.293  0.549  1.0
  O  O14  1  0.175  0.201  0.957  1.0
  O  O15  1  0.302  0.694  0.040  1.0
  O  O16  1  0.792  0.794  0.452  1.0
  O  O17  1  0.299  0.711  0.449  1.0
  O  O18  1  0.813  0.782  0.042  1.0
  O  O19  1  0.694  0.303  0.950  1.0
  O  O20  1  0.208  0.206  0.557  1.0
[/CIF]
.
The structure described by LiLa4Ga2(FeO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a trigonal planar geometry to one O(1), one O(12), and one O(6) atom. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(2), one O(5), one O(7), and one O(9) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(8) atom. In the third La site, La(3) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. In the fourth La site, La(4) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Ga(1)O6 octahedra and corners with four equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-35°. In the second Fe site, Fe(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(7) atom. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form GaO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 31°. In the second Ga site, Ga(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form GaO6 octahedra that share corners with four equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-35°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Fe(2), and one Ga(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Fe(1), and one Ga(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(2) atom. In the fourth O site, O(4) is bonded to one La(3), one La(4), one Fe(1), and one Ga(1) atom to form a mixture of distorted corner and edge-sharing OLa2GaFe tetrahedra. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Fe(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Li(1), one La(2), one La(4), one Fe(2), and one Ga(1) atom. In the seventh O site, O(7) is bonded to one La(1), one La(3), one La(4), one Fe(2), and one Ga(1) atom to form distorted OLa3GaFe trigonal bipyramids that share  a cornercorner with one O(9)La3GaFe square pyramid, corners with three equivalent O(4)La2GaFe tetrahedra, corners with two equivalent O(11)La3GaFe trigonal bipyramids,  an edgeedge with one O(9)La3GaFe square pyramid, and  an edgeedge with one O(11)La3GaFe trigonal bipyramid. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(2), one La(3), one La(4), one Fe(1), and one Ga(2) atom. In the ninth O site, O(9) is bonded to one La(1), one La(3), one La(4), one Fe(1), and one Ga(2) atom to form distorted OLa3GaFe square pyramids that share corners with three equivalent O(4)La2GaFe tetrahedra,  a cornercorner with one O(7)La3GaFe trigonal bipyramid, corners with two equivalent O(11)La3GaFe trigonal bipyramids, and  an edgeedge with one O(7)La3GaFe trigonal bipyramid. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(2), one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eleventh O site, O(11) is bonded to one La(1), one La(2), one La(3), one Fe(2), and one Ga(1) atom to form distorted OLa3GaFe trigonal bipyramids that share corners with two equivalent O(9)La3GaFe square pyramids, corners with two equivalent O(7)La3GaFe trigonal bipyramids,  an edgeedge with one O(4)La2GaFe tetrahedra, and  an edgeedge with one O(7)La3GaFe trigonal bipyramid. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(1), one La(2), one La(4), one Fe(1), and one Ga(2) atom. is represented by the CIF file [CIF]
data_LiLa4Ga2(FeO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.893
_cell_length_b   5.674
_cell_length_c   7.856
_cell_angle_alpha   89.705
_cell_angle_beta   89.884
_cell_angle_gamma   88.661
_symmetry_Int_Tables_number   1
_cell_volume   262.575
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.313  0.121  0.763  1.0
  La  La1  1  0.468  0.528  0.748  1.0
  La  La2  1  0.907  0.012  0.754  1.0
  La  La3  1  0.563  0.512  0.245  1.0
  La  La4  1  0.057  0.987  0.245  1.0
  Ga  Ga5  1  0.011  0.501  0.998  1.0
  Ga  Ga6  1  0.508  0.003  0.485  1.0
  Fe  Fe7  1  0.010  0.500  0.500  1.0
  Fe  Fe8  1  0.507  0.996  0.017  1.0
  O  O9  1  0.528  0.916  0.736  1.0
  O  O10  1  0.029  0.595  0.747  1.0
  O  O11  1  0.467  0.103  0.260  1.0
  O  O12  1  0.978  0.409  0.252  1.0
  O  O13  1  0.704  0.293  0.549  1.0
  O  O14  1  0.175  0.201  0.957  1.0
  O  O15  1  0.302  0.694  0.040  1.0
  O  O16  1  0.792  0.794  0.452  1.0
  O  O17  1  0.299  0.711  0.449  1.0
  O  O18  1  0.813  0.782  0.042  1.0
  O  O19  1  0.694  0.303  0.950  1.0
  O  O20  1  0.208  0.206  0.557  1.0
[/CIF]
.