The material described by Co(N3O)2CoI2(N3O)2(I)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7553-56-2 molecules, two Co(N3O)2 clusters, and four CoI2(N3O)2 clusters. In each Co(N3O)2 cluster, Co(2) is bonded in a 5-coordinate geometry to one N(6), two equivalent N(3), one O(1), and one O(2) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one N(3) atom. In the second N site, N(6) is bonded in a distorted linear geometry to one Co(2) and one N(6) atom. In the third N site, N(2) is bonded in a water-like geometry to one O(1) and one O(2) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Co(2) and one N(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Co(2) and one N(2) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Co(2) and one N(2) atom. In each CoI2(N3O)2 cluster, Co(1) is bonded in a distorted trigonal bipyramidal geometry to one N(8), two equivalent N(5), one O(3), and one O(4) atom. There are four inequivalent N sites. In the first N site, N(5) is bonded in a bent 120 degrees geometry to one Co(1) and one N(7) atom. In the second N site, N(7) is bonded in a single-bond geometry to one N(5) atom. In the third N site, N(8) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the fourth N site, N(1) is bonded in a water-like geometry to one O(3) and one O(4) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in an L-shaped geometry to one Co(1) and one N(1) atom. In the second O site, O(4) is bonded in an L-shaped geometry to one Co(1) and one N(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one N(8) and one I(3) atom. In the second I site, I(3) is bonded in a single-bond geometry to one I(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoI2(N3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.816
_cell_length_b   12.816
_cell_length_c   14.860
_cell_angle_alpha   54.593
_cell_angle_beta   54.593
_cell_angle_gamma   43.570
_symmetry_Int_Tables_number   1
_cell_volume   1314.626
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.270  0.270  0.235  1.0
  Co  Co1  1  0.730  0.730  0.765  1.0
  Co  Co2  1  0.001  0.001  0.163  1.0
  Co  Co3  1  0.999  0.999  0.837  1.0
  I  I4  1  0.436  0.436  0.963  1.0
  I  I5  1  0.564  0.564  0.037  1.0
  I  I6  1  0.176  0.176  0.771  1.0
  I  I7  1  0.824  0.824  0.229  1.0
  I  I8  1  0.389  0.389  0.826  1.0
  I  I9  1  0.611  0.611  0.174  1.0
  I  I10  1  0.693  0.693  0.434  1.0
  I  I11  1  0.307  0.307  0.566  1.0
  N  N12  1  0.827  0.827  0.551  1.0
  N  N13  1  0.173  0.173  0.449  1.0
  N  N14  1  0.091  0.091  0.200  1.0
  N  N15  1  0.909  0.909  0.800  1.0
  N  N16  1  0.704  0.186  0.277  1.0
  N  N17  1  0.186  0.704  0.277  1.0
  N  N18  1  0.296  0.814  0.723  1.0
  N  N19  1  0.814  0.296  0.723  1.0
  N  N20  1  0.639  0.132  0.342  1.0
  N  N21  1  0.132  0.639  0.342  1.0
  N  N22  1  0.361  0.868  0.658  1.0
  N  N23  1  0.868  0.361  0.658  1.0
  N  N24  1  0.052  0.427  0.161  1.0
  N  N25  1  0.427  0.052  0.161  1.0
  N  N26  1  0.948  0.573  0.839  1.0
  N  N27  1  0.573  0.948  0.839  1.0
  N  N28  1  0.997  0.997  0.041  1.0
  N  N29  1  0.003  0.003  0.959  1.0
  N  N30  1  0.925  0.480  0.210  1.0
  N  N31  1  0.480  0.925  0.210  1.0
  N  N32  1  0.075  0.520  0.790  1.0
  N  N33  1  0.520  0.075  0.790  1.0
  N  N34  1  0.365  0.365  0.129  1.0
  N  N35  1  0.635  0.635  0.871  1.0
  O  O36  1  0.107  0.107  0.100  1.0
  O  O37  1  0.893  0.893  0.900  1.0
  O  O38  1  0.023  0.023  0.280  1.0
  O  O39  1  0.977  0.977  0.720  1.0
  O  O40  1  0.761  0.761  0.598  1.0
  O  O41  1  0.239  0.239  0.402  1.0
  O  O42  1  0.837  0.837  0.626  1.0
  O  O43  1  0.163  0.163  0.374  1.0
[/CIF]
.
The material described by Co(N3O)2CoI2(N3O)2(I)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7553-56-2 molecules, two Co(N3O)2 clusters, and four CoI2(N3O)2 clusters. In each Co(N3O)2 cluster, Co(2) is bonded in a 5-coordinate geometry to one N(6), two equivalent N(3), one O(1), and one O(2) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one N(3) atom. In the second N site, N(6) is bonded in a distorted linear geometry to one Co(2) and one N(6) atom. In the third N site, N(2) is bonded in a water-like geometry to one O(1) and one O(2) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Co(2) and one N(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Co(2) and one N(2) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Co(2) and one N(2) atom. In each CoI2(N3O)2 cluster, Co(1) is bonded in a distorted trigonal bipyramidal geometry to one N(8), two equivalent N(5), one O(3), and one O(4) atom. There are four inequivalent N sites. In the first N site, N(5) is bonded in a bent 120 degrees geometry to one Co(1) and one N(7) atom. In the second N site, N(7) is bonded in a single-bond geometry to one N(5) atom. In the third N site, N(8) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the fourth N site, N(1) is bonded in a water-like geometry to one O(3) and one O(4) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in an L-shaped geometry to one Co(1) and one N(1) atom. In the second O site, O(4) is bonded in an L-shaped geometry to one Co(1) and one N(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one N(8) and one I(3) atom. In the second I site, I(3) is bonded in a single-bond geometry to one I(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoI2(N3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.816
_cell_length_b   12.816
_cell_length_c   14.860
_cell_angle_alpha   54.593
_cell_angle_beta   54.593
_cell_angle_gamma   43.570
_symmetry_Int_Tables_number   1
_cell_volume   1314.626
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.270  0.270  0.235  1.0
  Co  Co1  1  0.730  0.730  0.765  1.0
  Co  Co2  1  0.001  0.001  0.163  1.0
  Co  Co3  1  0.999  0.999  0.837  1.0
  I  I4  1  0.436  0.436  0.963  1.0
  I  I5  1  0.564  0.564  0.037  1.0
  I  I6  1  0.176  0.176  0.771  1.0
  I  I7  1  0.824  0.824  0.229  1.0
  I  I8  1  0.389  0.389  0.826  1.0
  I  I9  1  0.611  0.611  0.174  1.0
  I  I10  1  0.693  0.693  0.434  1.0
  I  I11  1  0.307  0.307  0.566  1.0
  N  N12  1  0.827  0.827  0.551  1.0
  N  N13  1  0.173  0.173  0.449  1.0
  N  N14  1  0.091  0.091  0.200  1.0
  N  N15  1  0.909  0.909  0.800  1.0
  N  N16  1  0.704  0.186  0.277  1.0
  N  N17  1  0.186  0.704  0.277  1.0
  N  N18  1  0.296  0.814  0.723  1.0
  N  N19  1  0.814  0.296  0.723  1.0
  N  N20  1  0.639  0.132  0.342  1.0
  N  N21  1  0.132  0.639  0.342  1.0
  N  N22  1  0.361  0.868  0.658  1.0
  N  N23  1  0.868  0.361  0.658  1.0
  N  N24  1  0.052  0.427  0.161  1.0
  N  N25  1  0.427  0.052  0.161  1.0
  N  N26  1  0.948  0.573  0.839  1.0
  N  N27  1  0.573  0.948  0.839  1.0
  N  N28  1  0.997  0.997  0.041  1.0
  N  N29  1  0.003  0.003  0.959  1.0
  N  N30  1  0.925  0.480  0.210  1.0
  N  N31  1  0.480  0.925  0.210  1.0
  N  N32  1  0.075  0.520  0.790  1.0
  N  N33  1  0.520  0.075  0.790  1.0
  N  N34  1  0.365  0.365  0.129  1.0
  N  N35  1  0.635  0.635  0.871  1.0
  O  O36  1  0.107  0.107  0.100  1.0
  O  O37  1  0.893  0.893  0.900  1.0
  O  O38  1  0.023  0.023  0.280  1.0
  O  O39  1  0.977  0.977  0.720  1.0
  O  O40  1  0.761  0.761  0.598  1.0
  O  O41  1  0.239  0.239  0.402  1.0
  O  O42  1  0.837  0.837  0.626  1.0
  O  O43  1  0.163  0.163  0.374  1.0
[/CIF]
.