The material described by Rb2Pd3S4 crystallizes in the orthorhombic Fddd space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pd(1), four equivalent Pd(2), and eight equivalent S(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Rb(1), one Pd(1), and two equivalent Pd(2) atoms. is represented by the CIF file [CIF]
data_Rb2Pd3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.163
_cell_length_b   6.225
_cell_length_c   13.810
_cell_angle_alpha   83.659
_cell_angle_beta   77.108
_cell_angle_gamma   60.330
_symmetry_Int_Tables_number   1
_cell_volume   448.718
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.546  0.250  0.908  1.0
  Rb  Rb1  1  0.704  0.250  0.592  1.0
  Rb  Rb2  1  0.454  0.750  0.092  1.0
  Rb  Rb3  1  0.296  0.750  0.408  1.0
  Pd  Pd4  1  0.125  0.250  0.750  1.0
  Pd  Pd5  1  0.875  0.750  0.250  1.0
  Pd  Pd6  1  0.875  0.250  0.249  1.0
  Pd  Pd7  1  0.375  0.250  0.251  1.0
  Pd  Pd8  1  0.125  0.750  0.751  1.0
  Pd  Pd9  1  0.625  0.750  0.749  1.0
  S  S10  1  0.344  0.918  0.636  1.0
  S  S11  1  0.237  0.918  0.864  1.0
  S  S12  1  0.020  0.582  0.636  1.0
  S  S13  1  0.899  0.582  0.864  1.0
  S  S14  1  0.656  0.082  0.364  1.0
  S  S15  1  0.763  0.082  0.136  1.0
  S  S16  1  0.980  0.418  0.364  1.0
  S  S17  1  0.101  0.418  0.136  1.0
[/CIF]
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The material described by Rb2Pd3S4 crystallizes in the orthorhombic Fddd space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pd(1), four equivalent Pd(2), and eight equivalent S(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Rb(1), one Pd(1), and two equivalent Pd(2) atoms. is represented by the CIF file [CIF]
data_Rb2Pd3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.163
_cell_length_b   6.225
_cell_length_c   13.810
_cell_angle_alpha   83.659
_cell_angle_beta   77.108
_cell_angle_gamma   60.330
_symmetry_Int_Tables_number   1
_cell_volume   448.718
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.546  0.250  0.908  1.0
  Rb  Rb1  1  0.704  0.250  0.592  1.0
  Rb  Rb2  1  0.454  0.750  0.092  1.0
  Rb  Rb3  1  0.296  0.750  0.408  1.0
  Pd  Pd4  1  0.125  0.250  0.750  1.0
  Pd  Pd5  1  0.875  0.750  0.250  1.0
  Pd  Pd6  1  0.875  0.250  0.249  1.0
  Pd  Pd7  1  0.375  0.250  0.251  1.0
  Pd  Pd8  1  0.125  0.750  0.751  1.0
  Pd  Pd9  1  0.625  0.750  0.749  1.0
  S  S10  1  0.344  0.918  0.636  1.0
  S  S11  1  0.237  0.918  0.864  1.0
  S  S12  1  0.020  0.582  0.636  1.0
  S  S13  1  0.899  0.582  0.864  1.0
  S  S14  1  0.656  0.082  0.364  1.0
  S  S15  1  0.763  0.082  0.136  1.0
  S  S16  1  0.980  0.418  0.364  1.0
  S  S17  1  0.101  0.418  0.136  1.0
[/CIF]
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