The material described by V2F9 is Indium-like structured and crystallizes in the hexagonal P6_3/mcm space group. The structure is zero-dimensional and consists of two V2F9 clusters. V(1) is bonded to three equivalent F(1) and three equivalent F(2) atoms to form distorted face-sharing VF6 octahedra. There are two inequivalent F sites. In the first F site, F(2) is bonded in an L-shaped geometry to two equivalent V(1) atoms. In the second F site, F(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2F9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.204
_cell_length_b   5.204
_cell_length_c   14.470
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   339.302
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.351  1.0
  V  V1  1  0.000  0.000  0.149  1.0
  V  V2  1  0.000  0.000  0.649  1.0
  V  V3  1  0.000  0.000  0.851  1.0
  F  F4  1  0.000  0.703  0.593  1.0
  F  F5  1  0.297  0.000  0.093  1.0
  F  F6  1  0.000  0.297  0.093  1.0
  F  F7  1  0.297  0.297  0.593  1.0
  F  F8  1  0.264  0.264  0.250  1.0
  F  F9  1  0.703  0.000  0.593  1.0
  F  F10  1  0.297  0.297  0.907  1.0
  F  F11  1  0.703  0.703  0.093  1.0
  F  F12  1  0.264  0.000  0.750  1.0
  F  F13  1  0.297  0.000  0.407  1.0
  F  F14  1  0.736  0.736  0.750  1.0
  F  F15  1  0.703  0.703  0.407  1.0
  F  F16  1  0.000  0.703  0.907  1.0
  F  F17  1  0.000  0.736  0.250  1.0
  F  F18  1  0.703  0.000  0.907  1.0
  F  F19  1  0.736  0.000  0.250  1.0
  F  F20  1  0.000  0.297  0.407  1.0
  F  F21  1  0.000  0.264  0.750  1.0
[/CIF]
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The material described by V2F9 is Indium-like structured and crystallizes in the hexagonal P6_3/mcm space group. The structure is zero-dimensional and consists of two V2F9 clusters. V(1) is bonded to three equivalent F(1) and three equivalent F(2) atoms to form distorted face-sharing VF6 octahedra. There are two inequivalent F sites. In the first F site, F(2) is bonded in an L-shaped geometry to two equivalent V(1) atoms. In the second F site, F(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2F9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.204
_cell_length_b   5.204
_cell_length_c   14.470
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   339.302
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.351  1.0
  V  V1  1  0.000  0.000  0.149  1.0
  V  V2  1  0.000  0.000  0.649  1.0
  V  V3  1  0.000  0.000  0.851  1.0
  F  F4  1  0.000  0.703  0.593  1.0
  F  F5  1  0.297  0.000  0.093  1.0
  F  F6  1  0.000  0.297  0.093  1.0
  F  F7  1  0.297  0.297  0.593  1.0
  F  F8  1  0.264  0.264  0.250  1.0
  F  F9  1  0.703  0.000  0.593  1.0
  F  F10  1  0.297  0.297  0.907  1.0
  F  F11  1  0.703  0.703  0.093  1.0
  F  F12  1  0.264  0.000  0.750  1.0
  F  F13  1  0.297  0.000  0.407  1.0
  F  F14  1  0.736  0.736  0.750  1.0
  F  F15  1  0.703  0.703  0.407  1.0
  F  F16  1  0.000  0.703  0.907  1.0
  F  F17  1  0.000  0.736  0.250  1.0
  F  F18  1  0.703  0.000  0.907  1.0
  F  F19  1  0.736  0.000  0.250  1.0
  F  F20  1  0.000  0.297  0.407  1.0
  F  F21  1  0.000  0.264  0.750  1.0
[/CIF]
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