The compound described by CoN3ClN5Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CoN3Cl clusters and four N5Cl clusters. In each CoN3Cl cluster, Co(1) is bonded in a trigonal planar geometry to one N(4), one N(6), and one N(7) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one Co(1) atom. In the second N site, N(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one Cl(2) atom. In the third N site, N(7) is bonded in a single-bond geometry to one Co(1) atom. Cl(2) is bonded in a single-bond geometry to one N(6) atom. In each N5Cl cluster, there are five inequivalent N sites. In the first N site, N(8) is bonded in a water-like geometry to one N(5) and one Cl(1) atom. In the second N site, N(1) is bonded in a water-like geometry to one N(2) and one N(5) atom. In the third N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the fourth N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fifth N site, N(5) is bonded in a water-like geometry to one N(1) and one N(8) atom. Cl(1) is bonded in a single-bond geometry to one N(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(N4Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.842
_cell_length_b   8.610
_cell_length_c   11.765
_cell_angle_alpha   66.749
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1009.016
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.900  0.594  0.216  1.0
  Co  Co1  1  0.600  0.594  0.716  1.0
  Co  Co2  1  0.100  0.406  0.784  1.0
  Co  Co3  1  0.400  0.406  0.284  1.0
  N  N4  1  0.986  0.111  0.359  1.0
  N  N5  1  0.514  0.111  0.859  1.0
  N  N6  1  0.014  0.889  0.641  1.0
  N  N7  1  0.486  0.889  0.141  1.0
  N  N8  1  0.021  0.107  0.258  1.0
  N  N9  1  0.479  0.107  0.758  1.0
  N  N10  1  0.979  0.893  0.742  1.0
  N  N11  1  0.521  0.893  0.242  1.0
  N  N12  1  0.071  0.098  0.176  1.0
  N  N13  1  0.429  0.098  0.676  1.0
  N  N14  1  0.929  0.902  0.824  1.0
  N  N15  1  0.571  0.902  0.324  1.0
  N  N16  1  0.754  0.626  0.224  1.0
  N  N17  1  0.746  0.626  0.724  1.0
  N  N18  1  0.246  0.374  0.776  1.0
  N  N19  1  0.254  0.374  0.276  1.0
  N  N20  1  0.860  0.144  0.356  1.0
  N  N21  1  0.640  0.144  0.856  1.0
  N  N22  1  0.140  0.856  0.644  1.0
  N  N23  1  0.360  0.856  0.144  1.0
  N  N24  1  0.989  0.557  0.344  1.0
  N  N25  1  0.511  0.557  0.844  1.0
  N  N26  1  0.011  0.443  0.656  1.0
  N  N27  1  0.489  0.443  0.156  1.0
  N  N28  1  0.952  0.560  0.103  1.0
  N  N29  1  0.548  0.560  0.603  1.0
  N  N30  1  0.048  0.440  0.897  1.0
  N  N31  1  0.452  0.440  0.397  1.0
  N  N32  1  0.832  0.158  0.455  1.0
  N  N33  1  0.668  0.158  0.955  1.0
  N  N34  1  0.168  0.842  0.545  1.0
  N  N35  1  0.332  0.842  0.045  1.0
  Cl  Cl36  1  0.676  0.204  0.456  1.0
  Cl  Cl37  1  0.824  0.204  0.956  1.0
  Cl  Cl38  1  0.324  0.796  0.544  1.0
  Cl  Cl39  1  0.176  0.796  0.044  1.0
  Cl  Cl40  1  0.614  0.532  0.098  1.0
  Cl  Cl41  1  0.886  0.532  0.598  1.0
  Cl  Cl42  1  0.386  0.468  0.902  1.0
  Cl  Cl43  1  0.114  0.468  0.402  1.0
[/CIF]
.
The compound described by CoN3ClN5Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CoN3Cl clusters and four N5Cl clusters. In each CoN3Cl cluster, Co(1) is bonded in a trigonal planar geometry to one N(4), one N(6), and one N(7) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one Co(1) atom. In the second N site, N(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one Cl(2) atom. In the third N site, N(7) is bonded in a single-bond geometry to one Co(1) atom. Cl(2) is bonded in a single-bond geometry to one N(6) atom. In each N5Cl cluster, there are five inequivalent N sites. In the first N site, N(8) is bonded in a water-like geometry to one N(5) and one Cl(1) atom. In the second N site, N(1) is bonded in a water-like geometry to one N(2) and one N(5) atom. In the third N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the fourth N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fifth N site, N(5) is bonded in a water-like geometry to one N(1) and one N(8) atom. Cl(1) is bonded in a single-bond geometry to one N(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(N4Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.842
_cell_length_b   8.610
_cell_length_c   11.765
_cell_angle_alpha   66.749
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1009.016
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.900  0.594  0.216  1.0
  Co  Co1  1  0.600  0.594  0.716  1.0
  Co  Co2  1  0.100  0.406  0.784  1.0
  Co  Co3  1  0.400  0.406  0.284  1.0
  N  N4  1  0.986  0.111  0.359  1.0
  N  N5  1  0.514  0.111  0.859  1.0
  N  N6  1  0.014  0.889  0.641  1.0
  N  N7  1  0.486  0.889  0.141  1.0
  N  N8  1  0.021  0.107  0.258  1.0
  N  N9  1  0.479  0.107  0.758  1.0
  N  N10  1  0.979  0.893  0.742  1.0
  N  N11  1  0.521  0.893  0.242  1.0
  N  N12  1  0.071  0.098  0.176  1.0
  N  N13  1  0.429  0.098  0.676  1.0
  N  N14  1  0.929  0.902  0.824  1.0
  N  N15  1  0.571  0.902  0.324  1.0
  N  N16  1  0.754  0.626  0.224  1.0
  N  N17  1  0.746  0.626  0.724  1.0
  N  N18  1  0.246  0.374  0.776  1.0
  N  N19  1  0.254  0.374  0.276  1.0
  N  N20  1  0.860  0.144  0.356  1.0
  N  N21  1  0.640  0.144  0.856  1.0
  N  N22  1  0.140  0.856  0.644  1.0
  N  N23  1  0.360  0.856  0.144  1.0
  N  N24  1  0.989  0.557  0.344  1.0
  N  N25  1  0.511  0.557  0.844  1.0
  N  N26  1  0.011  0.443  0.656  1.0
  N  N27  1  0.489  0.443  0.156  1.0
  N  N28  1  0.952  0.560  0.103  1.0
  N  N29  1  0.548  0.560  0.603  1.0
  N  N30  1  0.048  0.440  0.897  1.0
  N  N31  1  0.452  0.440  0.397  1.0
  N  N32  1  0.832  0.158  0.455  1.0
  N  N33  1  0.668  0.158  0.955  1.0
  N  N34  1  0.168  0.842  0.545  1.0
  N  N35  1  0.332  0.842  0.045  1.0
  Cl  Cl36  1  0.676  0.204  0.456  1.0
  Cl  Cl37  1  0.824  0.204  0.956  1.0
  Cl  Cl38  1  0.324  0.796  0.544  1.0
  Cl  Cl39  1  0.176  0.796  0.044  1.0
  Cl  Cl40  1  0.614  0.532  0.098  1.0
  Cl  Cl41  1  0.886  0.532  0.598  1.0
  Cl  Cl42  1  0.386  0.468  0.902  1.0
  Cl  Cl43  1  0.114  0.468  0.402  1.0
[/CIF]
.