The compound described by AuCl4PCl4 is Indium-derived structured and crystallizes in the orthorhombic Imma space group. The structure is zero-dimensional and consists of eight [pcl4]+1 molecules and eight AuCl4 clusters. In each AuCl4 cluster, Au(1) is bonded in a square co-planar geometry to one Cl(6), one Cl(7), and two equivalent Cl(5) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PAuCl8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.672
_cell_length_b   11.673
_cell_length_c   11.672
_cell_angle_alpha   120.177
_cell_angle_beta   114.410
_cell_angle_gamma   94.823
_symmetry_Int_Tables_number   1
_cell_volume   1162.707
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.253  0.253  0.500  1.0
  P  P1  1  0.247  0.747  1.000  1.0
  P  P2  1  0.747  0.747  0.500  1.0
  P  P3  1  0.753  0.253  1.000  1.0
  Au  Au4  1  0.750  0.828  0.078  1.0
  Au  Au5  1  0.250  0.172  0.922  1.0
  Au  Au6  1  0.750  0.312  0.562  1.0
  Au  Au7  1  0.250  0.688  0.438  1.0
  Cl  Cl8  1  0.923  0.241  0.014  1.0
  Cl  Cl9  1  0.577  0.591  0.318  1.0
  Cl  Cl10  1  0.773  0.759  0.681  1.0
  Cl  Cl11  1  0.727  0.409  0.986  1.0
  Cl  Cl12  1  0.077  0.759  0.986  1.0
  Cl  Cl13  1  0.423  0.409  0.681  1.0
  Cl  Cl14  1  0.227  0.241  0.318  1.0
  Cl  Cl15  1  0.273  0.591  0.014  1.0
  Cl  Cl16  1  0.605  0.074  0.816  1.0
  Cl  Cl17  1  0.895  0.711  0.469  1.0
  Cl  Cl18  1  0.742  0.926  0.531  1.0
  Cl  Cl19  1  0.758  0.289  0.184  1.0
  Cl  Cl20  1  0.395  0.926  0.184  1.0
  Cl  Cl21  1  0.105  0.289  0.531  1.0
  Cl  Cl22  1  0.258  0.074  0.469  1.0
  Cl  Cl23  1  0.242  0.711  0.816  1.0
  Cl  Cl24  1  0.395  0.832  0.437  1.0
  Cl  Cl25  1  0.105  0.542  0.437  1.0
  Cl  Cl26  1  0.605  0.168  0.563  1.0
  Cl  Cl27  1  0.895  0.458  0.563  1.0
  Cl  Cl28  1  0.068  0.690  0.258  1.0
  Cl  Cl29  1  0.432  0.690  0.622  1.0
  Cl  Cl30  1  0.568  0.310  0.378  1.0
  Cl  Cl31  1  0.932  0.310  0.742  1.0
  Cl  Cl32  1  0.395  0.317  0.922  1.0
  Cl  Cl33  1  0.105  0.026  0.922  1.0
  Cl  Cl34  1  0.605  0.683  0.078  1.0
  Cl  Cl35  1  0.895  0.974  0.078  1.0
  Cl  Cl36  1  0.250  0.370  0.120  1.0
  Cl  Cl37  1  0.750  0.630  0.880  1.0
  Cl  Cl38  1  0.250  0.975  0.725  1.0
  Cl  Cl39  1  0.750  0.025  0.275  1.0
[/CIF]
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The compound described by AuCl4PCl4 is Indium-derived structured and crystallizes in the orthorhombic Imma space group. The structure is zero-dimensional and consists of eight [pcl4]+1 molecules and eight AuCl4 clusters. In each AuCl4 cluster, Au(1) is bonded in a square co-planar geometry to one Cl(6), one Cl(7), and two equivalent Cl(5) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PAuCl8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.672
_cell_length_b   11.673
_cell_length_c   11.672
_cell_angle_alpha   120.177
_cell_angle_beta   114.410
_cell_angle_gamma   94.823
_symmetry_Int_Tables_number   1
_cell_volume   1162.707
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.253  0.253  0.500  1.0
  P  P1  1  0.247  0.747  1.000  1.0
  P  P2  1  0.747  0.747  0.500  1.0
  P  P3  1  0.753  0.253  1.000  1.0
  Au  Au4  1  0.750  0.828  0.078  1.0
  Au  Au5  1  0.250  0.172  0.922  1.0
  Au  Au6  1  0.750  0.312  0.562  1.0
  Au  Au7  1  0.250  0.688  0.438  1.0
  Cl  Cl8  1  0.923  0.241  0.014  1.0
  Cl  Cl9  1  0.577  0.591  0.318  1.0
  Cl  Cl10  1  0.773  0.759  0.681  1.0
  Cl  Cl11  1  0.727  0.409  0.986  1.0
  Cl  Cl12  1  0.077  0.759  0.986  1.0
  Cl  Cl13  1  0.423  0.409  0.681  1.0
  Cl  Cl14  1  0.227  0.241  0.318  1.0
  Cl  Cl15  1  0.273  0.591  0.014  1.0
  Cl  Cl16  1  0.605  0.074  0.816  1.0
  Cl  Cl17  1  0.895  0.711  0.469  1.0
  Cl  Cl18  1  0.742  0.926  0.531  1.0
  Cl  Cl19  1  0.758  0.289  0.184  1.0
  Cl  Cl20  1  0.395  0.926  0.184  1.0
  Cl  Cl21  1  0.105  0.289  0.531  1.0
  Cl  Cl22  1  0.258  0.074  0.469  1.0
  Cl  Cl23  1  0.242  0.711  0.816  1.0
  Cl  Cl24  1  0.395  0.832  0.437  1.0
  Cl  Cl25  1  0.105  0.542  0.437  1.0
  Cl  Cl26  1  0.605  0.168  0.563  1.0
  Cl  Cl27  1  0.895  0.458  0.563  1.0
  Cl  Cl28  1  0.068  0.690  0.258  1.0
  Cl  Cl29  1  0.432  0.690  0.622  1.0
  Cl  Cl30  1  0.568  0.310  0.378  1.0
  Cl  Cl31  1  0.932  0.310  0.742  1.0
  Cl  Cl32  1  0.395  0.317  0.922  1.0
  Cl  Cl33  1  0.105  0.026  0.922  1.0
  Cl  Cl34  1  0.605  0.683  0.078  1.0
  Cl  Cl35  1  0.895  0.974  0.078  1.0
  Cl  Cl36  1  0.250  0.370  0.120  1.0
  Cl  Cl37  1  0.750  0.630  0.880  1.0
  Cl  Cl38  1  0.250  0.975  0.725  1.0
  Cl  Cl39  1  0.750  0.025  0.275  1.0
[/CIF]
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