The structure described by GdMoO4F crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(4), and two equivalent F(1) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Gd(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. F(1) is bonded in a distorted water-like geometry to two equivalent Gd(1) atoms. is represented by the CIF card [CIF]
data_GdMoO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.569
_cell_length_b   5.323
_cell_length_c   6.821
_cell_angle_alpha   67.037
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   420.148
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.552  0.639  0.701  1.0
  Gd  Gd1  1  0.948  0.639  0.201  1.0
  Gd  Gd2  1  0.052  0.361  0.799  1.0
  Gd  Gd3  1  0.448  0.361  0.299  1.0
  Mo  Mo4  1  0.357  0.078  0.870  1.0
  Mo  Mo5  1  0.857  0.922  0.630  1.0
  Mo  Mo6  1  0.643  0.922  0.130  1.0
  Mo  Mo7  1  0.143  0.078  0.370  1.0
  O  O8  1  0.347  0.764  0.089  1.0
  O  O9  1  0.066  0.306  0.461  1.0
  O  O10  1  0.225  0.193  0.794  1.0
  O  O11  1  0.725  0.807  0.706  1.0
  O  O12  1  0.275  0.193  0.294  1.0
  O  O13  1  0.569  0.994  0.336  1.0
  O  O14  1  0.069  0.006  0.164  1.0
  O  O15  1  0.434  0.306  0.961  1.0
  O  O16  1  0.934  0.694  0.539  1.0
  O  O17  1  0.931  0.994  0.836  1.0
  O  O18  1  0.431  0.006  0.664  1.0
  O  O19  1  0.153  0.764  0.589  1.0
  O  O20  1  0.775  0.807  0.206  1.0
  O  O21  1  0.566  0.694  0.039  1.0
  O  O22  1  0.847  0.236  0.411  1.0
  O  O23  1  0.653  0.236  0.911  1.0
  F  F24  1  0.402  0.549  0.535  1.0
  F  F25  1  0.902  0.451  0.965  1.0
  F  F26  1  0.098  0.549  0.035  1.0
  F  F27  1  0.598  0.451  0.465  1.0
[/CIF]
.
The structure described by GdMoO4F crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(4), and two equivalent F(1) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Gd(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. F(1) is bonded in a distorted water-like geometry to two equivalent Gd(1) atoms. is represented by the CIF card [CIF]
data_GdMoO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.569
_cell_length_b   5.323
_cell_length_c   6.821
_cell_angle_alpha   67.037
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   420.148
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.552  0.639  0.701  1.0
  Gd  Gd1  1  0.948  0.639  0.201  1.0
  Gd  Gd2  1  0.052  0.361  0.799  1.0
  Gd  Gd3  1  0.448  0.361  0.299  1.0
  Mo  Mo4  1  0.357  0.078  0.870  1.0
  Mo  Mo5  1  0.857  0.922  0.630  1.0
  Mo  Mo6  1  0.643  0.922  0.130  1.0
  Mo  Mo7  1  0.143  0.078  0.370  1.0
  O  O8  1  0.347  0.764  0.089  1.0
  O  O9  1  0.066  0.306  0.461  1.0
  O  O10  1  0.225  0.193  0.794  1.0
  O  O11  1  0.725  0.807  0.706  1.0
  O  O12  1  0.275  0.193  0.294  1.0
  O  O13  1  0.569  0.994  0.336  1.0
  O  O14  1  0.069  0.006  0.164  1.0
  O  O15  1  0.434  0.306  0.961  1.0
  O  O16  1  0.934  0.694  0.539  1.0
  O  O17  1  0.931  0.994  0.836  1.0
  O  O18  1  0.431  0.006  0.664  1.0
  O  O19  1  0.153  0.764  0.589  1.0
  O  O20  1  0.775  0.807  0.206  1.0
  O  O21  1  0.566  0.694  0.039  1.0
  O  O22  1  0.847  0.236  0.411  1.0
  O  O23  1  0.653  0.236  0.911  1.0
  F  F24  1  0.402  0.549  0.535  1.0
  F  F25  1  0.902  0.451  0.965  1.0
  F  F26  1  0.098  0.549  0.035  1.0
  F  F27  1  0.598  0.451  0.465  1.0
[/CIF]
.