The material described by CrN6H15OCl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and two CrN6H15O clusters. In each CrN6H15O cluster, Cr(1) is bonded in an octahedral geometry to one N(2), one N(3), one N(4), one N(5), and two equivalent N(1) atoms. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(3), one H(6), and one H(7) atom. In the second N site, N(2) is bonded in a linear geometry to one Cr(1) and one O(1) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(1), and two equivalent H(4) atoms. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(2), and two equivalent H(5) atoms. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(9), and two equivalent H(8) atoms. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. O(1) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrH15N6Cl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.777
_cell_length_b   6.723
_cell_length_c   10.355
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   94.004
_symmetry_Int_Tables_number   1
_cell_volume   470.605
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.806  0.805  0.750  1.0
  Cr  Cr1  1  0.194  0.195  0.250  1.0
  H  H2  1  0.940  0.434  0.750  1.0
  H  H3  1  0.563  0.064  0.250  1.0
  H  H4  1  0.060  0.566  0.250  1.0
  H  H5  1  0.437  0.936  0.750  1.0
  H  H6  1  0.684  0.697  0.512  1.0
  H  H7  1  0.316  0.303  0.488  1.0
  H  H8  1  0.684  0.697  0.988  1.0
  H  H9  1  0.316  0.303  0.012  1.0
  H  H10  1  0.091  0.593  0.670  1.0
  H  H11  1  0.406  0.911  0.329  1.0
  H  H12  1  0.091  0.593  0.830  1.0
  H  H13  1  0.406  0.911  0.171  1.0
  H  H14  1  0.909  0.407  0.330  1.0
  H  H15  1  0.594  0.089  0.671  1.0
  H  H16  1  0.909  0.407  0.170  1.0
  H  H17  1  0.594  0.089  0.829  1.0
  H  H18  1  0.924  0.758  0.510  1.0
  H  H19  1  0.233  0.067  0.487  1.0
  H  H20  1  0.924  0.758  0.990  1.0
  H  H21  1  0.233  0.067  0.013  1.0
  H  H22  1  0.076  0.242  0.490  1.0
  H  H23  1  0.767  0.933  0.513  1.0
  H  H24  1  0.076  0.242  0.010  1.0
  H  H25  1  0.767  0.933  0.987  1.0
  H  H26  1  0.600  0.475  0.670  1.0
  H  H27  1  0.600  0.475  0.830  1.0
  H  H28  1  0.400  0.525  0.330  1.0
  H  H29  1  0.400  0.525  0.170  1.0
  H  H30  1  0.444  0.606  0.750  1.0
  H  H31  1  0.556  0.394  0.250  1.0
  N  N32  1  0.792  0.794  0.548  1.0
  N  N33  1  0.208  0.206  0.452  1.0
  N  N34  1  0.792  0.794  0.952  1.0
  N  N35  1  0.208  0.206  0.048  1.0
  N  N36  1  0.990  0.990  0.750  1.0
  N  N37  1  0.010  0.010  0.250  1.0
  N  N38  1  0.001  0.577  0.750  1.0
  N  N39  1  0.421  0.001  0.250  1.0
  N  N40  1  0.999  0.423  0.250  1.0
  N  N41  1  0.579  0.999  0.750  1.0
  N  N42  1  0.585  0.563  0.750  1.0
  N  N43  1  0.415  0.437  0.250  1.0
  Cl  Cl44  1  0.286  0.715  0.503  1.0
  Cl  Cl45  1  0.286  0.715  0.997  1.0
  Cl  Cl46  1  0.714  0.285  0.497  1.0
  Cl  Cl47  1  0.714  0.285  0.003  1.0
  O  O48  1  0.122  0.121  0.750  1.0
  O  O49  1  0.878  0.879  0.250  1.0
[/CIF]
.
The material described by CrN6H15OCl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and two CrN6H15O clusters. In each CrN6H15O cluster, Cr(1) is bonded in an octahedral geometry to one N(2), one N(3), one N(4), one N(5), and two equivalent N(1) atoms. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(3), one H(6), and one H(7) atom. In the second N site, N(2) is bonded in a linear geometry to one Cr(1) and one O(1) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(1), and two equivalent H(4) atoms. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(2), and two equivalent H(5) atoms. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(9), and two equivalent H(8) atoms. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. O(1) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrH15N6Cl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.777
_cell_length_b   6.723
_cell_length_c   10.355
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   94.004
_symmetry_Int_Tables_number   1
_cell_volume   470.605
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.806  0.805  0.750  1.0
  Cr  Cr1  1  0.194  0.195  0.250  1.0
  H  H2  1  0.940  0.434  0.750  1.0
  H  H3  1  0.563  0.064  0.250  1.0
  H  H4  1  0.060  0.566  0.250  1.0
  H  H5  1  0.437  0.936  0.750  1.0
  H  H6  1  0.684  0.697  0.512  1.0
  H  H7  1  0.316  0.303  0.488  1.0
  H  H8  1  0.684  0.697  0.988  1.0
  H  H9  1  0.316  0.303  0.012  1.0
  H  H10  1  0.091  0.593  0.670  1.0
  H  H11  1  0.406  0.911  0.329  1.0
  H  H12  1  0.091  0.593  0.830  1.0
  H  H13  1  0.406  0.911  0.171  1.0
  H  H14  1  0.909  0.407  0.330  1.0
  H  H15  1  0.594  0.089  0.671  1.0
  H  H16  1  0.909  0.407  0.170  1.0
  H  H17  1  0.594  0.089  0.829  1.0
  H  H18  1  0.924  0.758  0.510  1.0
  H  H19  1  0.233  0.067  0.487  1.0
  H  H20  1  0.924  0.758  0.990  1.0
  H  H21  1  0.233  0.067  0.013  1.0
  H  H22  1  0.076  0.242  0.490  1.0
  H  H23  1  0.767  0.933  0.513  1.0
  H  H24  1  0.076  0.242  0.010  1.0
  H  H25  1  0.767  0.933  0.987  1.0
  H  H26  1  0.600  0.475  0.670  1.0
  H  H27  1  0.600  0.475  0.830  1.0
  H  H28  1  0.400  0.525  0.330  1.0
  H  H29  1  0.400  0.525  0.170  1.0
  H  H30  1  0.444  0.606  0.750  1.0
  H  H31  1  0.556  0.394  0.250  1.0
  N  N32  1  0.792  0.794  0.548  1.0
  N  N33  1  0.208  0.206  0.452  1.0
  N  N34  1  0.792  0.794  0.952  1.0
  N  N35  1  0.208  0.206  0.048  1.0
  N  N36  1  0.990  0.990  0.750  1.0
  N  N37  1  0.010  0.010  0.250  1.0
  N  N38  1  0.001  0.577  0.750  1.0
  N  N39  1  0.421  0.001  0.250  1.0
  N  N40  1  0.999  0.423  0.250  1.0
  N  N41  1  0.579  0.999  0.750  1.0
  N  N42  1  0.585  0.563  0.750  1.0
  N  N43  1  0.415  0.437  0.250  1.0
  Cl  Cl44  1  0.286  0.715  0.503  1.0
  Cl  Cl45  1  0.286  0.715  0.997  1.0
  Cl  Cl46  1  0.714  0.285  0.497  1.0
  Cl  Cl47  1  0.714  0.285  0.003  1.0
  O  O48  1  0.122  0.121  0.750  1.0
  O  O49  1  0.878  0.879  0.250  1.0
[/CIF]
.