The compound described by RePOCl8 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four RePOCl8 clusters. Re(1) is bonded to one O(1), one Cl(2), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms to form ReCl5O octahedra that share  a cornercorner with one P(1)Cl3O tetrahedra. P(1) is bonded to one O(1), one Cl(4), and two equivalent Cl(1) atoms to form PCl3O tetrahedra that share  a cornercorner with one Re(1)Cl5O octahedra. The corner-sharing octahedral tilt angles are 36°. O(1) is bonded in a bent 150 degrees geometry to one Re(1) and one P(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RePCl8O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.397
_cell_length_b   9.106
_cell_length_c   17.114
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1308.673
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.250  0.923  0.148  1.0
  Re  Re1  1  0.750  0.077  0.852  1.0
  Re  Re2  1  0.750  0.423  0.352  1.0
  Re  Re3  1  0.250  0.577  0.648  1.0
  P  P4  1  0.750  0.782  0.423  1.0
  P  P5  1  0.250  0.282  0.077  1.0
  P  P6  1  0.750  0.718  0.923  1.0
  P  P7  1  0.250  0.218  0.577  1.0
  Cl  Cl8  1  0.061  0.133  0.630  1.0
  Cl  Cl9  1  0.561  0.867  0.370  1.0
  Cl  Cl10  1  0.750  0.211  0.967  1.0
  Cl  Cl11  1  0.478  0.445  0.359  1.0
  Cl  Cl12  1  0.522  0.555  0.641  1.0
  Cl  Cl13  1  0.439  0.133  0.630  1.0
  Cl  Cl14  1  0.561  0.633  0.870  1.0
  Cl  Cl15  1  0.939  0.867  0.370  1.0
  Cl  Cl16  1  0.522  0.945  0.141  1.0
  Cl  Cl17  1  0.250  0.140  0.469  1.0
  Cl  Cl18  1  0.750  0.219  0.278  1.0
  Cl  Cl19  1  0.750  0.575  0.241  1.0
  Cl  Cl20  1  0.022  0.445  0.359  1.0
  Cl  Cl21  1  0.022  0.055  0.859  1.0
  Cl  Cl22  1  0.978  0.555  0.641  1.0
  Cl  Cl23  1  0.750  0.860  0.531  1.0
  Cl  Cl24  1  0.439  0.367  0.130  1.0
  Cl  Cl25  1  0.061  0.367  0.130  1.0
  Cl  Cl26  1  0.750  0.289  0.467  1.0
  Cl  Cl27  1  0.939  0.633  0.870  1.0
  Cl  Cl28  1  0.250  0.789  0.033  1.0
  Cl  Cl29  1  0.250  0.360  0.969  1.0
  Cl  Cl30  1  0.250  0.719  0.222  1.0
  Cl  Cl31  1  0.750  0.925  0.741  1.0
  Cl  Cl32  1  0.978  0.945  0.141  1.0
  Cl  Cl33  1  0.750  0.640  0.031  1.0
  Cl  Cl34  1  0.250  0.781  0.722  1.0
  Cl  Cl35  1  0.250  0.425  0.759  1.0
  Cl  Cl36  1  0.478  0.055  0.859  1.0
  Cl  Cl37  1  0.250  0.075  0.259  1.0
  Cl  Cl38  1  0.250  0.711  0.533  1.0
  Cl  Cl39  1  0.750  0.281  0.778  1.0
  O  O40  1  0.250  0.118  0.075  1.0
  O  O41  1  0.750  0.882  0.925  1.0
  O  O42  1  0.250  0.382  0.575  1.0
  O  O43  1  0.750  0.618  0.425  1.0
[/CIF]
.
The compound described by RePOCl8 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four RePOCl8 clusters. Re(1) is bonded to one O(1), one Cl(2), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms to form ReCl5O octahedra that share  a cornercorner with one P(1)Cl3O tetrahedra. P(1) is bonded to one O(1), one Cl(4), and two equivalent Cl(1) atoms to form PCl3O tetrahedra that share  a cornercorner with one Re(1)Cl5O octahedra. The corner-sharing octahedral tilt angles are 36°. O(1) is bonded in a bent 150 degrees geometry to one Re(1) and one P(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RePCl8O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.397
_cell_length_b   9.106
_cell_length_c   17.114
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1308.673
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.250  0.923  0.148  1.0
  Re  Re1  1  0.750  0.077  0.852  1.0
  Re  Re2  1  0.750  0.423  0.352  1.0
  Re  Re3  1  0.250  0.577  0.648  1.0
  P  P4  1  0.750  0.782  0.423  1.0
  P  P5  1  0.250  0.282  0.077  1.0
  P  P6  1  0.750  0.718  0.923  1.0
  P  P7  1  0.250  0.218  0.577  1.0
  Cl  Cl8  1  0.061  0.133  0.630  1.0
  Cl  Cl9  1  0.561  0.867  0.370  1.0
  Cl  Cl10  1  0.750  0.211  0.967  1.0
  Cl  Cl11  1  0.478  0.445  0.359  1.0
  Cl  Cl12  1  0.522  0.555  0.641  1.0
  Cl  Cl13  1  0.439  0.133  0.630  1.0
  Cl  Cl14  1  0.561  0.633  0.870  1.0
  Cl  Cl15  1  0.939  0.867  0.370  1.0
  Cl  Cl16  1  0.522  0.945  0.141  1.0
  Cl  Cl17  1  0.250  0.140  0.469  1.0
  Cl  Cl18  1  0.750  0.219  0.278  1.0
  Cl  Cl19  1  0.750  0.575  0.241  1.0
  Cl  Cl20  1  0.022  0.445  0.359  1.0
  Cl  Cl21  1  0.022  0.055  0.859  1.0
  Cl  Cl22  1  0.978  0.555  0.641  1.0
  Cl  Cl23  1  0.750  0.860  0.531  1.0
  Cl  Cl24  1  0.439  0.367  0.130  1.0
  Cl  Cl25  1  0.061  0.367  0.130  1.0
  Cl  Cl26  1  0.750  0.289  0.467  1.0
  Cl  Cl27  1  0.939  0.633  0.870  1.0
  Cl  Cl28  1  0.250  0.789  0.033  1.0
  Cl  Cl29  1  0.250  0.360  0.969  1.0
  Cl  Cl30  1  0.250  0.719  0.222  1.0
  Cl  Cl31  1  0.750  0.925  0.741  1.0
  Cl  Cl32  1  0.978  0.945  0.141  1.0
  Cl  Cl33  1  0.750  0.640  0.031  1.0
  Cl  Cl34  1  0.250  0.781  0.722  1.0
  Cl  Cl35  1  0.250  0.425  0.759  1.0
  Cl  Cl36  1  0.478  0.055  0.859  1.0
  Cl  Cl37  1  0.250  0.075  0.259  1.0
  Cl  Cl38  1  0.250  0.711  0.533  1.0
  Cl  Cl39  1  0.750  0.281  0.778  1.0
  O  O40  1  0.250  0.118  0.075  1.0
  O  O41  1  0.750  0.882  0.925  1.0
  O  O42  1  0.250  0.382  0.575  1.0
  O  O43  1  0.750  0.618  0.425  1.0
[/CIF]
.