The structure described by K(CrS2)2 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Cr(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form distorted edge-sharing CrS6 octahedra. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 5-coordinate geometry to two equivalent K(1) and three equivalent Cr(1) atoms. In the second S site, S(1) is bonded in a 4-coordinate geometry to one K(1) and three equivalent Cr(1) atoms. is represented by the CIF file [CIF]
data_K(CrS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.148
_cell_length_b   8.148
_cell_length_c   5.542
_cell_angle_alpha   75.611
_cell_angle_beta   75.611
_cell_angle_gamma   22.640
_symmetry_Int_Tables_number   1
_cell_volume   137.016
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.500  1.0
  Cr  Cr1  1  0.753  0.753  0.195  1.0
  Cr  Cr2  1  0.247  0.247  0.805  1.0
  S  S3  1  0.352  0.352  0.008  1.0
  S  S4  1  0.648  0.648  0.992  1.0
  S  S5  1  0.828  0.828  0.522  1.0
  S  S6  1  0.172  0.172  0.478  1.0
[/CIF]
.
The structure described by K(CrS2)2 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Cr(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form distorted edge-sharing CrS6 octahedra. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 5-coordinate geometry to two equivalent K(1) and three equivalent Cr(1) atoms. In the second S site, S(1) is bonded in a 4-coordinate geometry to one K(1) and three equivalent Cr(1) atoms. is represented by the CIF file [CIF]
data_K(CrS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.148
_cell_length_b   8.148
_cell_length_c   5.542
_cell_angle_alpha   75.611
_cell_angle_beta   75.611
_cell_angle_gamma   22.640
_symmetry_Int_Tables_number   1
_cell_volume   137.016
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.500  1.0
  Cr  Cr1  1  0.753  0.753  0.195  1.0
  Cr  Cr2  1  0.247  0.247  0.805  1.0
  S  S3  1  0.352  0.352  0.008  1.0
  S  S4  1  0.648  0.648  0.992  1.0
  S  S5  1  0.828  0.828  0.522  1.0
  S  S6  1  0.172  0.172  0.478  1.0
[/CIF]
.