The compound described by CrN4H14OCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two CrN4H14OCl3 clusters. Cr(1) is bonded in an octahedral geometry to one N(2), one N(3), two equivalent N(1), one O(1), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(5), and two equivalent H(4) atoms. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(7), and two equivalent H(6) atoms. In the third N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(1), one H(2), and one H(3) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. O(1) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1) and two equivalent H(8) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one H(8) atom. is represented by the CIF file [CIF]
data_CrH14N4Cl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.533
_cell_length_b   10.580
_cell_length_c   6.589
_cell_angle_alpha   90.000
_cell_angle_beta   94.260
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   454.197
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.171  0.250  0.226  1.0
  Cr  Cr1  1  0.829  0.750  0.774  1.0
  H  H2  1  0.218  0.021  0.087  1.0
  H  H3  1  0.782  0.521  0.913  1.0
  H  H4  1  0.782  0.979  0.913  1.0
  H  H5  1  0.218  0.479  0.087  1.0
  H  H6  1  0.034  0.016  0.243  1.0
  H  H7  1  0.966  0.516  0.757  1.0
  H  H8  1  0.966  0.984  0.757  1.0
  H  H9  1  0.034  0.484  0.243  1.0
  H  H10  1  0.278  0.016  0.332  1.0
  H  H11  1  0.722  0.516  0.667  1.0
  H  H12  1  0.722  0.984  0.667  1.0
  H  H13  1  0.278  0.484  0.332  1.0
  H  H14  1  0.839  0.328  0.392  1.0
  H  H15  1  0.161  0.828  0.608  1.0
  H  H16  1  0.161  0.672  0.608  1.0
  H  H17  1  0.839  0.172  0.392  1.0
  H  H18  1  0.976  0.250  0.572  1.0
  H  H19  1  0.024  0.750  0.428  1.0
  H  H20  1  0.411  0.328  0.951  1.0
  H  H21  1  0.589  0.828  0.049  1.0
  H  H22  1  0.589  0.672  0.049  1.0
  H  H23  1  0.411  0.172  0.951  1.0
  H  H24  1  0.553  0.250  0.125  1.0
  H  H25  1  0.447  0.750  0.875  1.0
  H  H26  1  0.366  0.326  0.561  1.0
  H  H27  1  0.634  0.826  0.439  1.0
  H  H28  1  0.634  0.674  0.439  1.0
  H  H29  1  0.366  0.174  0.561  1.0
  N  N30  1  0.176  0.054  0.223  1.0
  N  N31  1  0.824  0.554  0.777  1.0
  N  N32  1  0.824  0.946  0.777  1.0
  N  N33  1  0.176  0.446  0.223  1.0
  N  N34  1  0.931  0.250  0.420  1.0
  N  N35  1  0.069  0.750  0.580  1.0
  N  N36  1  0.415  0.250  0.044  1.0
  N  N37  1  0.585  0.750  0.957  1.0
  Cl  Cl38  1  0.934  0.250  0.948  1.0
  Cl  Cl39  1  0.066  0.750  0.052  1.0
  Cl  Cl40  1  0.678  0.986  0.279  1.0
  Cl  Cl41  1  0.322  0.486  0.721  1.0
  Cl  Cl42  1  0.322  0.014  0.721  1.0
  Cl  Cl43  1  0.678  0.514  0.279  1.0
  O  O44  1  0.374  0.250  0.473  1.0
  O  O45  1  0.626  0.750  0.527  1.0
[/CIF]
.
The compound described by CrN4H14OCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two CrN4H14OCl3 clusters. Cr(1) is bonded in an octahedral geometry to one N(2), one N(3), two equivalent N(1), one O(1), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(5), and two equivalent H(4) atoms. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(7), and two equivalent H(6) atoms. In the third N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(1), one H(2), and one H(3) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. O(1) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1) and two equivalent H(8) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one H(8) atom. is represented by the CIF file [CIF]
data_CrH14N4Cl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.533
_cell_length_b   10.580
_cell_length_c   6.589
_cell_angle_alpha   90.000
_cell_angle_beta   94.260
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   454.197
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.171  0.250  0.226  1.0
  Cr  Cr1  1  0.829  0.750  0.774  1.0
  H  H2  1  0.218  0.021  0.087  1.0
  H  H3  1  0.782  0.521  0.913  1.0
  H  H4  1  0.782  0.979  0.913  1.0
  H  H5  1  0.218  0.479  0.087  1.0
  H  H6  1  0.034  0.016  0.243  1.0
  H  H7  1  0.966  0.516  0.757  1.0
  H  H8  1  0.966  0.984  0.757  1.0
  H  H9  1  0.034  0.484  0.243  1.0
  H  H10  1  0.278  0.016  0.332  1.0
  H  H11  1  0.722  0.516  0.667  1.0
  H  H12  1  0.722  0.984  0.667  1.0
  H  H13  1  0.278  0.484  0.332  1.0
  H  H14  1  0.839  0.328  0.392  1.0
  H  H15  1  0.161  0.828  0.608  1.0
  H  H16  1  0.161  0.672  0.608  1.0
  H  H17  1  0.839  0.172  0.392  1.0
  H  H18  1  0.976  0.250  0.572  1.0
  H  H19  1  0.024  0.750  0.428  1.0
  H  H20  1  0.411  0.328  0.951  1.0
  H  H21  1  0.589  0.828  0.049  1.0
  H  H22  1  0.589  0.672  0.049  1.0
  H  H23  1  0.411  0.172  0.951  1.0
  H  H24  1  0.553  0.250  0.125  1.0
  H  H25  1  0.447  0.750  0.875  1.0
  H  H26  1  0.366  0.326  0.561  1.0
  H  H27  1  0.634  0.826  0.439  1.0
  H  H28  1  0.634  0.674  0.439  1.0
  H  H29  1  0.366  0.174  0.561  1.0
  N  N30  1  0.176  0.054  0.223  1.0
  N  N31  1  0.824  0.554  0.777  1.0
  N  N32  1  0.824  0.946  0.777  1.0
  N  N33  1  0.176  0.446  0.223  1.0
  N  N34  1  0.931  0.250  0.420  1.0
  N  N35  1  0.069  0.750  0.580  1.0
  N  N36  1  0.415  0.250  0.044  1.0
  N  N37  1  0.585  0.750  0.957  1.0
  Cl  Cl38  1  0.934  0.250  0.948  1.0
  Cl  Cl39  1  0.066  0.750  0.052  1.0
  Cl  Cl40  1  0.678  0.986  0.279  1.0
  Cl  Cl41  1  0.322  0.486  0.721  1.0
  Cl  Cl42  1  0.322  0.014  0.721  1.0
  Cl  Cl43  1  0.678  0.514  0.279  1.0
  O  O44  1  0.374  0.250  0.473  1.0
  O  O45  1  0.626  0.750  0.527  1.0
[/CIF]
.