The compound described by Pd5Ce3 crystallizes in the hexagonal P-62m space group. Ce(1) is bonded in a 8-coordinate geometry to four equivalent Pd(2) and six equivalent Pd(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), two equivalent Pd(1), and two equivalent Pd(2) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Ce3Pd5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.945
_cell_length_b   7.100
_cell_length_c   7.100
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   172.256
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.500  0.355  0.355  1.0
  Ce  Ce1  1  0.500  0.000  0.645  1.0
  Ce  Ce2  1  0.500  0.645  0.000  1.0
  Pd  Pd3  1  0.000  0.771  0.771  1.0
  Pd  Pd4  1  0.000  0.000  0.229  1.0
  Pd  Pd5  1  0.000  0.229  0.000  1.0
  Pd  Pd6  1  0.000  0.667  0.333  1.0
  Pd  Pd7  1  0.000  0.333  0.667  1.0
[/CIF]
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The compound described by Pd5Ce3 crystallizes in the hexagonal P-62m space group. Ce(1) is bonded in a 8-coordinate geometry to four equivalent Pd(2) and six equivalent Pd(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), two equivalent Pd(1), and two equivalent Pd(2) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Ce3Pd5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.945
_cell_length_b   7.100
_cell_length_c   7.100
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   172.256
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.500  0.355  0.355  1.0
  Ce  Ce1  1  0.500  0.000  0.645  1.0
  Ce  Ce2  1  0.500  0.645  0.000  1.0
  Pd  Pd3  1  0.000  0.771  0.771  1.0
  Pd  Pd4  1  0.000  0.000  0.229  1.0
  Pd  Pd5  1  0.000  0.229  0.000  1.0
  Pd  Pd6  1  0.000  0.667  0.333  1.0
  Pd  Pd7  1  0.000  0.333  0.667  1.0
[/CIF]
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