The material structure described by VOSb2O4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a 5-coordinate geometry to one O(3) and four equivalent O(2) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2) and three equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VSb2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.440
_cell_length_b   9.440
_cell_length_c   5.585
_cell_angle_alpha   85.422
_cell_angle_beta   85.422
_cell_angle_gamma   31.669
_symmetry_Int_Tables_number   1
_cell_volume   260.397
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.371  0.629  0.250  1.0
  V  V1  1  0.629  0.371  0.750  1.0
  Sb  Sb2  1  0.868  0.455  0.345  1.0
  Sb  Sb3  1  0.545  0.132  0.155  1.0
  Sb  Sb4  1  0.132  0.545  0.655  1.0
  Sb  Sb5  1  0.455  0.868  0.845  1.0
  O  O6  1  0.612  0.801  0.149  1.0
  O  O7  1  0.199  0.388  0.351  1.0
  O  O8  1  0.388  0.199  0.851  1.0
  O  O9  1  0.801  0.612  0.649  1.0
  O  O10  1  0.571  0.571  0.478  1.0
  O  O11  1  0.429  0.429  0.022  1.0
  O  O12  1  0.947  0.053  0.750  1.0
  O  O13  1  0.053  0.947  0.250  1.0
  O  O14  1  0.571  0.571  0.978  1.0
  O  O15  1  0.429  0.429  0.522  1.0
[/CIF]
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The material structure described by VOSb2O4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a 5-coordinate geometry to one O(3) and four equivalent O(2) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2) and three equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VSb2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.440
_cell_length_b   9.440
_cell_length_c   5.585
_cell_angle_alpha   85.422
_cell_angle_beta   85.422
_cell_angle_gamma   31.669
_symmetry_Int_Tables_number   1
_cell_volume   260.397
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.371  0.629  0.250  1.0
  V  V1  1  0.629  0.371  0.750  1.0
  Sb  Sb2  1  0.868  0.455  0.345  1.0
  Sb  Sb3  1  0.545  0.132  0.155  1.0
  Sb  Sb4  1  0.132  0.545  0.655  1.0
  Sb  Sb5  1  0.455  0.868  0.845  1.0
  O  O6  1  0.612  0.801  0.149  1.0
  O  O7  1  0.199  0.388  0.351  1.0
  O  O8  1  0.388  0.199  0.851  1.0
  O  O9  1  0.801  0.612  0.649  1.0
  O  O10  1  0.571  0.571  0.478  1.0
  O  O11  1  0.429  0.429  0.022  1.0
  O  O12  1  0.947  0.053  0.750  1.0
  O  O13  1  0.053  0.947  0.250  1.0
  O  O14  1  0.571  0.571  0.978  1.0
  O  O15  1  0.429  0.429  0.522  1.0
[/CIF]
.