The structure described by SO3IF is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four SO3IF clusters. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one F(1) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(1), one O(5), one O(6), and one F(2) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one S(2) and one I(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one S(1) and one I(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one S(1) and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted single-bond geometry to one O(2) atom. In the second I site, I(2) is bonded in a linear geometry to one O(4) and one O(6) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_SIO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.720
_cell_length_b   12.507
_cell_length_c   13.713
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   981.071
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.841  0.900  0.991  1.0
  S  S1  1  0.341  0.600  0.009  1.0
  S  S2  1  0.159  0.400  0.509  1.0
  S  S3  1  0.659  0.100  0.491  1.0
  S  S4  1  0.541  0.678  0.669  1.0
  S  S5  1  0.041  0.822  0.331  1.0
  S  S6  1  0.459  0.178  0.831  1.0
  S  S7  1  0.959  0.322  0.169  1.0
  I  I8  1  0.045  0.952  0.658  1.0
  I  I9  1  0.545  0.548  0.342  1.0
  I  I10  1  0.955  0.452  0.842  1.0
  I  I11  1  0.455  0.048  0.158  1.0
  I  I12  1  0.198  0.824  0.803  1.0
  I  I13  1  0.698  0.676  0.197  1.0
  I  I14  1  0.802  0.324  0.697  1.0
  I  I15  1  0.302  0.176  0.303  1.0
  O  O16  1  0.095  0.409  0.206  1.0
  O  O17  1  0.099  0.576  0.984  1.0
  O  O18  1  0.401  0.424  0.484  1.0
  O  O19  1  0.901  0.076  0.516  1.0
  O  O20  1  0.405  0.591  0.706  1.0
  O  O21  1  0.905  0.909  0.294  1.0
  O  O22  1  0.595  0.091  0.794  1.0
  O  O23  1  0.599  0.924  0.016  1.0
  O  O24  1  0.970  0.831  0.055  1.0
  O  O25  1  0.470  0.669  0.945  1.0
  O  O26  1  0.030  0.331  0.445  1.0
  O  O27  1  0.530  0.169  0.555  1.0
  O  O28  1  0.857  0.872  0.885  1.0
  O  O29  1  0.357  0.628  0.115  1.0
  O  O30  1  0.143  0.372  0.615  1.0
  O  O31  1  0.643  0.128  0.385  1.0
  O  O32  1  0.716  0.333  0.147  1.0
  O  O33  1  0.216  0.167  0.853  1.0
  O  O34  1  0.284  0.833  0.353  1.0
  O  O35  1  0.784  0.667  0.647  1.0
  O  O36  1  0.987  0.218  0.230  1.0
  O  O37  1  0.487  0.282  0.770  1.0
  O  O38  1  0.013  0.718  0.270  1.0
  O  O39  1  0.513  0.782  0.730  1.0
  F  F40  1  0.972  0.013  0.996  1.0
  F  F41  1  0.584  0.214  0.930  1.0
  F  F42  1  0.916  0.786  0.430  1.0
  F  F43  1  0.416  0.714  0.570  1.0
  F  F44  1  0.528  0.987  0.496  1.0
  F  F45  1  0.028  0.513  0.504  1.0
  F  F46  1  0.472  0.487  0.004  1.0
  F  F47  1  0.084  0.286  0.070  1.0
[/CIF]
.
The structure described by SO3IF is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four SO3IF clusters. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one F(1) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(1), one O(5), one O(6), and one F(2) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one S(2) and one I(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one S(1) and one I(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one S(1) and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted single-bond geometry to one O(2) atom. In the second I site, I(2) is bonded in a linear geometry to one O(4) and one O(6) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_SIO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.720
_cell_length_b   12.507
_cell_length_c   13.713
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   981.071
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.841  0.900  0.991  1.0
  S  S1  1  0.341  0.600  0.009  1.0
  S  S2  1  0.159  0.400  0.509  1.0
  S  S3  1  0.659  0.100  0.491  1.0
  S  S4  1  0.541  0.678  0.669  1.0
  S  S5  1  0.041  0.822  0.331  1.0
  S  S6  1  0.459  0.178  0.831  1.0
  S  S7  1  0.959  0.322  0.169  1.0
  I  I8  1  0.045  0.952  0.658  1.0
  I  I9  1  0.545  0.548  0.342  1.0
  I  I10  1  0.955  0.452  0.842  1.0
  I  I11  1  0.455  0.048  0.158  1.0
  I  I12  1  0.198  0.824  0.803  1.0
  I  I13  1  0.698  0.676  0.197  1.0
  I  I14  1  0.802  0.324  0.697  1.0
  I  I15  1  0.302  0.176  0.303  1.0
  O  O16  1  0.095  0.409  0.206  1.0
  O  O17  1  0.099  0.576  0.984  1.0
  O  O18  1  0.401  0.424  0.484  1.0
  O  O19  1  0.901  0.076  0.516  1.0
  O  O20  1  0.405  0.591  0.706  1.0
  O  O21  1  0.905  0.909  0.294  1.0
  O  O22  1  0.595  0.091  0.794  1.0
  O  O23  1  0.599  0.924  0.016  1.0
  O  O24  1  0.970  0.831  0.055  1.0
  O  O25  1  0.470  0.669  0.945  1.0
  O  O26  1  0.030  0.331  0.445  1.0
  O  O27  1  0.530  0.169  0.555  1.0
  O  O28  1  0.857  0.872  0.885  1.0
  O  O29  1  0.357  0.628  0.115  1.0
  O  O30  1  0.143  0.372  0.615  1.0
  O  O31  1  0.643  0.128  0.385  1.0
  O  O32  1  0.716  0.333  0.147  1.0
  O  O33  1  0.216  0.167  0.853  1.0
  O  O34  1  0.284  0.833  0.353  1.0
  O  O35  1  0.784  0.667  0.647  1.0
  O  O36  1  0.987  0.218  0.230  1.0
  O  O37  1  0.487  0.282  0.770  1.0
  O  O38  1  0.013  0.718  0.270  1.0
  O  O39  1  0.513  0.782  0.730  1.0
  F  F40  1  0.972  0.013  0.996  1.0
  F  F41  1  0.584  0.214  0.930  1.0
  F  F42  1  0.916  0.786  0.430  1.0
  F  F43  1  0.416  0.714  0.570  1.0
  F  F44  1  0.528  0.987  0.496  1.0
  F  F45  1  0.028  0.513  0.504  1.0
  F  F46  1  0.472  0.487  0.004  1.0
  F  F47  1  0.084  0.286  0.070  1.0
[/CIF]
.