The material described by K2PdC4(NS)4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1), two equivalent N(2), and two equivalent S(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to two equivalent K(1) and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pd(1), and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one C(2) atom. is represented by the CIF card [CIF]
data_K2PdC4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.223
_cell_length_b   4.364
_cell_length_c   11.205
_cell_angle_alpha   81.840
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   640.079
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.355  0.309  0.030  1.0
  K  K1  1  0.145  0.309  0.530  1.0
  K  K2  1  0.855  0.691  0.470  1.0
  K  K3  1  0.645  0.691  0.970  1.0
  Pd  Pd4  1  0.000  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.846  0.212  0.205  1.0
  C  C7  1  0.925  0.029  0.727  1.0
  C  C8  1  0.575  0.029  0.227  1.0
  C  C9  1  0.654  0.212  0.705  1.0
  C  C10  1  0.346  0.788  0.295  1.0
  C  C11  1  0.075  0.971  0.273  1.0
  C  C12  1  0.154  0.788  0.795  1.0
  C  C13  1  0.425  0.971  0.773  1.0
  S  S14  1  0.335  0.874  0.434  1.0
  S  S15  1  0.592  0.774  0.350  1.0
  S  S16  1  0.908  0.774  0.850  1.0
  S  S17  1  0.408  0.226  0.650  1.0
  S  S18  1  0.835  0.126  0.066  1.0
  S  S19  1  0.092  0.226  0.150  1.0
  S  S20  1  0.165  0.874  0.934  1.0
  S  S21  1  0.665  0.126  0.566  1.0
  N  N22  1  0.565  0.199  0.136  1.0
  N  N23  1  0.652  0.274  0.804  1.0
  N  N24  1  0.348  0.726  0.196  1.0
  N  N25  1  0.935  0.199  0.636  1.0
  N  N26  1  0.152  0.726  0.696  1.0
  N  N27  1  0.848  0.274  0.304  1.0
  N  N28  1  0.065  0.801  0.364  1.0
  N  N29  1  0.435  0.801  0.864  1.0
[/CIF]
.
The material described by K2PdC4(NS)4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1), two equivalent N(2), and two equivalent S(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to two equivalent K(1) and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pd(1), and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one C(2) atom. is represented by the CIF card [CIF]
data_K2PdC4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.223
_cell_length_b   4.364
_cell_length_c   11.205
_cell_angle_alpha   81.840
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   640.079
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.355  0.309  0.030  1.0
  K  K1  1  0.145  0.309  0.530  1.0
  K  K2  1  0.855  0.691  0.470  1.0
  K  K3  1  0.645  0.691  0.970  1.0
  Pd  Pd4  1  0.000  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.846  0.212  0.205  1.0
  C  C7  1  0.925  0.029  0.727  1.0
  C  C8  1  0.575  0.029  0.227  1.0
  C  C9  1  0.654  0.212  0.705  1.0
  C  C10  1  0.346  0.788  0.295  1.0
  C  C11  1  0.075  0.971  0.273  1.0
  C  C12  1  0.154  0.788  0.795  1.0
  C  C13  1  0.425  0.971  0.773  1.0
  S  S14  1  0.335  0.874  0.434  1.0
  S  S15  1  0.592  0.774  0.350  1.0
  S  S16  1  0.908  0.774  0.850  1.0
  S  S17  1  0.408  0.226  0.650  1.0
  S  S18  1  0.835  0.126  0.066  1.0
  S  S19  1  0.092  0.226  0.150  1.0
  S  S20  1  0.165  0.874  0.934  1.0
  S  S21  1  0.665  0.126  0.566  1.0
  N  N22  1  0.565  0.199  0.136  1.0
  N  N23  1  0.652  0.274  0.804  1.0
  N  N24  1  0.348  0.726  0.196  1.0
  N  N25  1  0.935  0.199  0.636  1.0
  N  N26  1  0.152  0.726  0.696  1.0
  N  N27  1  0.848  0.274  0.304  1.0
  N  N28  1  0.065  0.801  0.364  1.0
  N  N29  1  0.435  0.801  0.864  1.0
[/CIF]
.