The crystal structure described by NaIn(C2O5)2 crystallizes in the hexagonal P6_222 space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. In(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to two equivalent O(3) atoms. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one In(1) and one C(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Na(1), one In(1), and one C(2) atom. In the third O site, O(2) is bonded in a water-like geometry to two equivalent Na(1) atoms. is represented by the CIF card [CIF]
data_NaIn(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.094
_cell_length_b   8.092
_cell_length_c   12.997
_cell_angle_alpha   90.001
_cell_angle_beta   89.994
_cell_angle_gamma   120.032
_symmetry_Int_Tables_number   1
_cell_volume   736.947
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  1.000  0.000  0.000  1.0
  Na  Na1  1  0.000  0.000  0.333  1.0
  Na  Na2  1  0.000  0.000  0.667  1.0
  In  In3  1  0.500  0.500  1.000  1.0
  In  In4  1  1.000  0.500  0.333  1.0
  In  In5  1  0.500  0.000  0.667  1.0
  C  C6  1  0.693  0.307  0.500  1.0
  C  C7  1  0.614  0.307  0.833  1.0
  C  C8  1  0.307  0.693  0.500  1.0
  C  C9  1  0.386  0.693  0.833  1.0
  C  C10  1  0.693  0.386  0.167  1.0
  C  C11  1  0.307  0.614  0.167  1.0
  C  C12  1  0.804  0.196  0.500  1.0
  C  C13  1  0.391  0.196  0.833  1.0
  C  C14  1  0.196  0.804  0.500  1.0
  C  C15  1  0.609  0.804  0.833  1.0
  C  C16  1  0.804  0.609  0.167  1.0
  C  C17  1  0.196  0.391  0.167  1.0
  O  O18  1  0.691  0.775  0.908  1.0
  O  O19  1  0.084  0.309  0.241  1.0
  O  O20  1  0.309  0.225  0.908  1.0
  O  O21  1  0.916  0.225  0.426  1.0
  O  O22  1  0.225  0.916  0.574  1.0
  O  O23  1  0.916  0.691  0.241  1.0
  O  O24  1  0.775  0.691  0.092  1.0
  O  O25  1  0.084  0.775  0.426  1.0
  O  O26  1  0.775  0.084  0.574  1.0
  O  O27  1  0.225  0.309  0.092  1.0
  O  O28  1  0.309  0.084  0.759  1.0
  O  O29  1  0.691  0.916  0.759  1.0
  O  O30  1  0.797  0.797  0.500  1.0
  O  O31  1  0.000  0.203  0.833  1.0
  O  O32  1  0.203  0.203  0.500  1.0
  O  O33  1  0.203  0.000  0.167  1.0
  O  O34  1  0.000  0.797  0.833  1.0
  O  O35  1  0.797  1.000  0.167  1.0
  O  O36  1  0.694  0.252  0.770  1.0
  O  O37  1  0.558  0.306  0.103  1.0
  O  O38  1  0.306  0.748  0.770  1.0
  O  O39  1  0.442  0.748  0.564  1.0
  O  O40  1  0.748  0.442  0.436  1.0
  O  O41  1  0.442  0.694  0.103  1.0
  O  O42  1  0.252  0.694  0.230  1.0
  O  O43  1  0.558  0.252  0.564  1.0
  O  O44  1  0.252  0.558  0.436  1.0
  O  O45  1  0.748  0.306  0.230  1.0
  O  O46  1  0.306  0.558  0.897  1.0
  O  O47  1  0.694  0.442  0.897  1.0
[/CIF]
.
The crystal structure described by NaIn(C2O5)2 crystallizes in the hexagonal P6_222 space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. In(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to two equivalent O(3) atoms. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one In(1) and one C(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Na(1), one In(1), and one C(2) atom. In the third O site, O(2) is bonded in a water-like geometry to two equivalent Na(1) atoms. is represented by the CIF card [CIF]
data_NaIn(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.094
_cell_length_b   8.092
_cell_length_c   12.997
_cell_angle_alpha   90.001
_cell_angle_beta   89.994
_cell_angle_gamma   120.032
_symmetry_Int_Tables_number   1
_cell_volume   736.947
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  1.000  0.000  0.000  1.0
  Na  Na1  1  0.000  0.000  0.333  1.0
  Na  Na2  1  0.000  0.000  0.667  1.0
  In  In3  1  0.500  0.500  1.000  1.0
  In  In4  1  1.000  0.500  0.333  1.0
  In  In5  1  0.500  0.000  0.667  1.0
  C  C6  1  0.693  0.307  0.500  1.0
  C  C7  1  0.614  0.307  0.833  1.0
  C  C8  1  0.307  0.693  0.500  1.0
  C  C9  1  0.386  0.693  0.833  1.0
  C  C10  1  0.693  0.386  0.167  1.0
  C  C11  1  0.307  0.614  0.167  1.0
  C  C12  1  0.804  0.196  0.500  1.0
  C  C13  1  0.391  0.196  0.833  1.0
  C  C14  1  0.196  0.804  0.500  1.0
  C  C15  1  0.609  0.804  0.833  1.0
  C  C16  1  0.804  0.609  0.167  1.0
  C  C17  1  0.196  0.391  0.167  1.0
  O  O18  1  0.691  0.775  0.908  1.0
  O  O19  1  0.084  0.309  0.241  1.0
  O  O20  1  0.309  0.225  0.908  1.0
  O  O21  1  0.916  0.225  0.426  1.0
  O  O22  1  0.225  0.916  0.574  1.0
  O  O23  1  0.916  0.691  0.241  1.0
  O  O24  1  0.775  0.691  0.092  1.0
  O  O25  1  0.084  0.775  0.426  1.0
  O  O26  1  0.775  0.084  0.574  1.0
  O  O27  1  0.225  0.309  0.092  1.0
  O  O28  1  0.309  0.084  0.759  1.0
  O  O29  1  0.691  0.916  0.759  1.0
  O  O30  1  0.797  0.797  0.500  1.0
  O  O31  1  0.000  0.203  0.833  1.0
  O  O32  1  0.203  0.203  0.500  1.0
  O  O33  1  0.203  0.000  0.167  1.0
  O  O34  1  0.000  0.797  0.833  1.0
  O  O35  1  0.797  1.000  0.167  1.0
  O  O36  1  0.694  0.252  0.770  1.0
  O  O37  1  0.558  0.306  0.103  1.0
  O  O38  1  0.306  0.748  0.770  1.0
  O  O39  1  0.442  0.748  0.564  1.0
  O  O40  1  0.748  0.442  0.436  1.0
  O  O41  1  0.442  0.694  0.103  1.0
  O  O42  1  0.252  0.694  0.230  1.0
  O  O43  1  0.558  0.252  0.564  1.0
  O  O44  1  0.252  0.558  0.436  1.0
  O  O45  1  0.748  0.306  0.230  1.0
  O  O46  1  0.306  0.558  0.897  1.0
  O  O47  1  0.694  0.442  0.897  1.0
[/CIF]
.