The structure described by MnSbO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(15), one O(6), one O(7), one O(9), and two equivalent O(1) atoms to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Mn(4)O6 pentagonal pyramid, corners with two equivalent Mn(1)O6 pentagonal pyramids,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(16), one O(7), one O(8), and two equivalent O(2) atoms to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O6 pentagonal pyramid, corners with two equivalent Mn(2)O6 pentagonal pyramids,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles are 25°. In the third Mn site, Mn(3) is bonded to one O(11), one O(13), one O(5), one O(8), and two equivalent O(3) atoms to form distorted MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Mn(4)O6 pentagonal pyramid,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles are 28°. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(14), one O(5), one O(6), and two equivalent O(4) atoms to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O6 pentagonal pyramid, corners with two equivalent Mn(4)O6 pentagonal pyramids,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles are 27°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(13), one O(14), one O(5), and two equivalent O(9) atoms to form SbO6 octahedra that share  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 pentagonal pyramid, and edges with two equivalent Mn(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 19-28°. In the second Sb site, Sb(2) is bonded to one O(14), one O(15), one O(2), one O(6), and two equivalent O(10) atoms to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Mn(4)O6 pentagonal pyramid, and edges with two equivalent Mn(2)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 15-28°. In the third Sb site, Sb(3) is bonded to one O(15), one O(16), one O(3), one O(7), and two equivalent O(11) atoms to form distorted SbO6 octahedra that share  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Mn(1)O6 pentagonal pyramid, and  an edgeedge with one Mn(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 15-26°. In the fourth Sb site, Sb(4) is bonded to one O(13), one O(16), one O(4), one O(8), and two equivalent O(12) atoms to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(2)O6 pentagonal pyramid, and edges with two equivalent Mn(4)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 21-25°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Mn(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Mn(2) and one Sb(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Mn(3) and one Sb(3) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to two equivalent Mn(4) and one Sb(4) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Mn(3), one Mn(4), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(4), and one Sb(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Mn(2), and one Sb(3) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Sb(4) atom. In the ninth O site, O(9) is bonded in a T-shaped geometry to one Mn(1) and two equivalent Sb(1) atoms. In the tenth O site, O(10) is bonded in a T-shaped geometry to one Mn(2) and two equivalent Sb(2) atoms. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Mn(3) and two equivalent Sb(3) atoms. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Mn(4) and two equivalent Sb(4) atoms. In the thirteenth O site, O(13) is bonded in a T-shaped geometry to one Mn(3), one Sb(1), and one Sb(4) atom. In the fourteenth O site, O(14) is bonded in a distorted T-shaped geometry to one Mn(4), one Sb(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded in a T-shaped geometry to one Mn(1), one Sb(2), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Mn(2), one Sb(3), and one Sb(4) atom. is represented by the CIF card [CIF]
data_MnSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.960
_cell_length_b   5.678
_cell_length_c   7.964
_cell_angle_alpha   69.485
_cell_angle_beta   90.001
_cell_angle_gamma   69.589
_symmetry_Int_Tables_number   1
_cell_volume   155.653
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.990  0.020  0.998  1.0
  Mn  Mn1  1  0.010  0.980  0.502  1.0
  O  O2  1  0.545  0.910  0.028  1.0
  O  O3  1  0.553  0.894  0.522  1.0
  O  O4  1  0.947  0.105  0.214  1.0
  O  O5  1  0.953  0.093  0.737  1.0
  O  O6  1  0.206  0.588  0.108  1.0
  O  O7  1  0.213  0.573  0.602  1.0
  O  O8  1  0.783  0.433  0.891  1.0
  O  O9  1  0.797  0.405  0.399  1.0
  Sb  Sb10  1  0.746  0.508  0.126  1.0
  Sb  Sb11  1  0.755  0.490  0.625  1.0
[/CIF]
.
The structure described by MnSbO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(15), one O(6), one O(7), one O(9), and two equivalent O(1) atoms to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Mn(4)O6 pentagonal pyramid, corners with two equivalent Mn(1)O6 pentagonal pyramids,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(16), one O(7), one O(8), and two equivalent O(2) atoms to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O6 pentagonal pyramid, corners with two equivalent Mn(2)O6 pentagonal pyramids,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles are 25°. In the third Mn site, Mn(3) is bonded to one O(11), one O(13), one O(5), one O(8), and two equivalent O(3) atoms to form distorted MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Mn(4)O6 pentagonal pyramid,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles are 28°. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(14), one O(5), one O(6), and two equivalent O(4) atoms to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O6 pentagonal pyramid, corners with two equivalent Mn(4)O6 pentagonal pyramids,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles are 27°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(13), one O(14), one O(5), and two equivalent O(9) atoms to form SbO6 octahedra that share  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 pentagonal pyramid, and edges with two equivalent Mn(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 19-28°. In the second Sb site, Sb(2) is bonded to one O(14), one O(15), one O(2), one O(6), and two equivalent O(10) atoms to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Mn(4)O6 pentagonal pyramid, and edges with two equivalent Mn(2)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 15-28°. In the third Sb site, Sb(3) is bonded to one O(15), one O(16), one O(3), one O(7), and two equivalent O(11) atoms to form distorted SbO6 octahedra that share  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Mn(1)O6 pentagonal pyramid, and  an edgeedge with one Mn(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 15-26°. In the fourth Sb site, Sb(4) is bonded to one O(13), one O(16), one O(4), one O(8), and two equivalent O(12) atoms to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(2)O6 pentagonal pyramid, and edges with two equivalent Mn(4)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 21-25°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Mn(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Mn(2) and one Sb(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Mn(3) and one Sb(3) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to two equivalent Mn(4) and one Sb(4) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Mn(3), one Mn(4), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(4), and one Sb(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Mn(2), and one Sb(3) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Sb(4) atom. In the ninth O site, O(9) is bonded in a T-shaped geometry to one Mn(1) and two equivalent Sb(1) atoms. In the tenth O site, O(10) is bonded in a T-shaped geometry to one Mn(2) and two equivalent Sb(2) atoms. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Mn(3) and two equivalent Sb(3) atoms. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Mn(4) and two equivalent Sb(4) atoms. In the thirteenth O site, O(13) is bonded in a T-shaped geometry to one Mn(3), one Sb(1), and one Sb(4) atom. In the fourteenth O site, O(14) is bonded in a distorted T-shaped geometry to one Mn(4), one Sb(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded in a T-shaped geometry to one Mn(1), one Sb(2), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Mn(2), one Sb(3), and one Sb(4) atom. is represented by the CIF card [CIF]
data_MnSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.960
_cell_length_b   5.678
_cell_length_c   7.964
_cell_angle_alpha   69.485
_cell_angle_beta   90.001
_cell_angle_gamma   69.589
_symmetry_Int_Tables_number   1
_cell_volume   155.653
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.990  0.020  0.998  1.0
  Mn  Mn1  1  0.010  0.980  0.502  1.0
  O  O2  1  0.545  0.910  0.028  1.0
  O  O3  1  0.553  0.894  0.522  1.0
  O  O4  1  0.947  0.105  0.214  1.0
  O  O5  1  0.953  0.093  0.737  1.0
  O  O6  1  0.206  0.588  0.108  1.0
  O  O7  1  0.213  0.573  0.602  1.0
  O  O8  1  0.783  0.433  0.891  1.0
  O  O9  1  0.797  0.405  0.399  1.0
  Sb  Sb10  1  0.746  0.508  0.126  1.0
  Sb  Sb11  1  0.755  0.490  0.625  1.0
[/CIF]
.