The material described by (SeS5)2SeS11 is alpha-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one SeS11 cluster and one SeS5 cluster. In the SeS11 cluster, Se(3) is bonded in a water-like geometry to one S(3) and one S(7) atom. There are eleven inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to one Se(3) and one S(17) atom. In the second S site, S(4) is bonded in a water-like geometry to one S(13) and one S(16) atom. In the third S site, S(7) is bonded in a water-like geometry to one Se(3) and one S(19) atom. In the fourth S site, S(8) is bonded in a water-like geometry to one S(13) and one S(19) atom. In the fifth S site, S(11) is bonded in a water-like geometry to one S(16) and one S(21) atom. In the sixth S site, S(12) is bonded in a water-like geometry to one S(17) and one S(21) atom. In the seventh S site, S(13) is bonded in a water-like geometry to one S(4) and one S(8) atom. In the eighth S site, S(16) is bonded in a water-like geometry to one S(11) and one S(4) atom. In the ninth S site, S(17) is bonded in a water-like geometry to one S(12) and one S(3) atom. In the tenth S site, S(19) is bonded in a water-like geometry to one S(7) and one S(8) atom. In the eleventh S site, S(21) is bonded in a water-like geometry to one S(11) and one S(12) atom. In the SeS5 cluster, there are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one S(1) and one S(5) atom. In the second Se site, Se(2) is bonded in a water-like geometry to one S(2) and one S(6) atom. There are ten inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Se(1) and one S(15) atom. In the second S site, S(2) is bonded in a water-like geometry to one Se(2) and one S(14) atom. In the third S site, S(5) is bonded in a water-like geometry to one Se(1) and one S(18) atom. In the fourth S site, S(6) is bonded in a water-like geometry to one Se(2) and one S(18) atom. In the fifth S site, S(9) is bonded in a water-like geometry to one S(14) and one S(20) atom. In the sixth S site, S(10) is bonded in a water-like geometry to one S(15) and one S(20) atom. In the seventh S site, S(14) is bonded in a water-like geometry to one S(2) and one S(9) atom. In the eighth S site, S(15) is bonded in a water-like geometry to one S(1) and one S(10) atom. In the ninth S site, S(18) is bonded in a water-like geometry to one S(5) and one S(6) atom. In the tenth S site, S(20) is bonded in a water-like geometry to one S(10) and one S(9) atom. is represented by the CIF card [CIF]
data_SeS7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.848
_cell_length_b   9.399
_cell_length_c   15.112
_cell_angle_alpha   89.983
_cell_angle_beta   89.787
_cell_angle_gamma   89.956
_symmetry_Int_Tables_number   1
_cell_volume   688.556
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Se  Se0  1  0.500  0.179  0.613  1.0
  Se  Se1  1  0.492  0.820  0.614  1.0
  Se  Se2  1  0.013  0.322  0.887  1.0
  S  S3  1  0.261  0.229  0.492  1.0
  S  S4  1  0.733  0.768  0.493  1.0
  S  S5  1  0.766  0.274  0.007  1.0
  S  S6  1  0.229  0.733  0.001  1.0
  S  S7  1  0.734  0.374  0.643  1.0
  S  S8  1  0.258  0.624  0.646  1.0
  S  S9  1  0.241  0.123  0.859  1.0
  S  S10  1  0.773  0.868  0.861  1.0
  S  S11  1  0.271  0.631  0.357  1.0
  S  S12  1  0.728  0.369  0.358  1.0
  S  S13  1  0.769  0.870  0.140  1.0
  S  S14  1  0.228  0.130  0.141  1.0
  S  S15  1  0.999  0.690  0.891  1.0
  S  S16  1  0.498  0.810  0.384  1.0
  S  S17  1  0.501  0.190  0.384  1.0
  S  S18  1  0.995  0.690  0.112  1.0
  S  S19  1  0.004  0.311  0.116  1.0
  S  S20  1  0.498  0.499  0.725  1.0
  S  S21  1  0.006  0.996  0.779  1.0
  S  S22  1  0.502  0.500  0.277  1.0
  S  S23  1  0.999  0.998  0.221  1.0
[/CIF]
.
The material described by (SeS5)2SeS11 is alpha-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one SeS11 cluster and one SeS5 cluster. In the SeS11 cluster, Se(3) is bonded in a water-like geometry to one S(3) and one S(7) atom. There are eleven inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to one Se(3) and one S(17) atom. In the second S site, S(4) is bonded in a water-like geometry to one S(13) and one S(16) atom. In the third S site, S(7) is bonded in a water-like geometry to one Se(3) and one S(19) atom. In the fourth S site, S(8) is bonded in a water-like geometry to one S(13) and one S(19) atom. In the fifth S site, S(11) is bonded in a water-like geometry to one S(16) and one S(21) atom. In the sixth S site, S(12) is bonded in a water-like geometry to one S(17) and one S(21) atom. In the seventh S site, S(13) is bonded in a water-like geometry to one S(4) and one S(8) atom. In the eighth S site, S(16) is bonded in a water-like geometry to one S(11) and one S(4) atom. In the ninth S site, S(17) is bonded in a water-like geometry to one S(12) and one S(3) atom. In the tenth S site, S(19) is bonded in a water-like geometry to one S(7) and one S(8) atom. In the eleventh S site, S(21) is bonded in a water-like geometry to one S(11) and one S(12) atom. In the SeS5 cluster, there are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one S(1) and one S(5) atom. In the second Se site, Se(2) is bonded in a water-like geometry to one S(2) and one S(6) atom. There are ten inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Se(1) and one S(15) atom. In the second S site, S(2) is bonded in a water-like geometry to one Se(2) and one S(14) atom. In the third S site, S(5) is bonded in a water-like geometry to one Se(1) and one S(18) atom. In the fourth S site, S(6) is bonded in a water-like geometry to one Se(2) and one S(18) atom. In the fifth S site, S(9) is bonded in a water-like geometry to one S(14) and one S(20) atom. In the sixth S site, S(10) is bonded in a water-like geometry to one S(15) and one S(20) atom. In the seventh S site, S(14) is bonded in a water-like geometry to one S(2) and one S(9) atom. In the eighth S site, S(15) is bonded in a water-like geometry to one S(1) and one S(10) atom. In the ninth S site, S(18) is bonded in a water-like geometry to one S(5) and one S(6) atom. In the tenth S site, S(20) is bonded in a water-like geometry to one S(10) and one S(9) atom. is represented by the CIF card [CIF]
data_SeS7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.848
_cell_length_b   9.399
_cell_length_c   15.112
_cell_angle_alpha   89.983
_cell_angle_beta   89.787
_cell_angle_gamma   89.956
_symmetry_Int_Tables_number   1
_cell_volume   688.556
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Se  Se0  1  0.500  0.179  0.613  1.0
  Se  Se1  1  0.492  0.820  0.614  1.0
  Se  Se2  1  0.013  0.322  0.887  1.0
  S  S3  1  0.261  0.229  0.492  1.0
  S  S4  1  0.733  0.768  0.493  1.0
  S  S5  1  0.766  0.274  0.007  1.0
  S  S6  1  0.229  0.733  0.001  1.0
  S  S7  1  0.734  0.374  0.643  1.0
  S  S8  1  0.258  0.624  0.646  1.0
  S  S9  1  0.241  0.123  0.859  1.0
  S  S10  1  0.773  0.868  0.861  1.0
  S  S11  1  0.271  0.631  0.357  1.0
  S  S12  1  0.728  0.369  0.358  1.0
  S  S13  1  0.769  0.870  0.140  1.0
  S  S14  1  0.228  0.130  0.141  1.0
  S  S15  1  0.999  0.690  0.891  1.0
  S  S16  1  0.498  0.810  0.384  1.0
  S  S17  1  0.501  0.190  0.384  1.0
  S  S18  1  0.995  0.690  0.112  1.0
  S  S19  1  0.004  0.311  0.116  1.0
  S  S20  1  0.498  0.499  0.725  1.0
  S  S21  1  0.006  0.996  0.779  1.0
  S  S22  1  0.502  0.500  0.277  1.0
  S  S23  1  0.999  0.998  0.221  1.0
[/CIF]
.