The material described by ReP4 is Hausmannite-like structured and crystallizes in the orthorhombic Pbca space group. Re(1) is bonded to one P(2), one P(3), two equivalent P(1), and two equivalent P(4) atoms to form ReP6 octahedra that share corners with two equivalent Re(1)P6 octahedra, corners with three equivalent P(1)Re2P2 tetrahedra, corners with three equivalent P(4)Re2P2 tetrahedra, corners with four equivalent P(2)ReP3 tetrahedra, corners with four equivalent P(3)ReP3 tetrahedra, and  an edgeedge with one Re(1)P6 octahedra. The corner-sharing octahedral tilt angles are 56°. There are four inequivalent P sites. In the first P site, P(4) is bonded to two equivalent Re(1), one P(1), and one P(3) atom to form distorted PRe2P2 tetrahedra that share corners with three equivalent Re(1)P6 octahedra, corners with two equivalent P(3)ReP3 tetrahedra, corners with four equivalent P(1)Re2P2 tetrahedra, corners with five equivalent P(2)ReP3 tetrahedra, and  an edgeedge with one P(4)Re2P2 tetrahedra. The corner-sharing octahedral tilt angles range from 64-73°. In the second P site, P(1) is bonded to two equivalent Re(1), one P(2), and one P(4) atom to form distorted PRe2P2 tetrahedra that share corners with three equivalent Re(1)P6 octahedra, corners with two equivalent P(1)Re2P2 tetrahedra, corners with two equivalent P(2)ReP3 tetrahedra, corners with four equivalent P(4)Re2P2 tetrahedra, and corners with five equivalent P(3)ReP3 tetrahedra. The corner-sharing octahedral tilt angles range from 53-60°. In the third P site, P(2) is bonded to one Re(1), one P(1), and two equivalent P(3) atoms to form distorted PReP3 tetrahedra that share corners with four equivalent Re(1)P6 octahedra,  a cornercorner with one P(3)ReP3 tetrahedra, corners with two equivalent P(1)Re2P2 tetrahedra, corners with two equivalent P(2)ReP3 tetrahedra, and corners with five equivalent P(4)Re2P2 tetrahedra. The corner-sharing octahedral tilt angles range from 56-76°. In the fourth P site, P(3) is bonded to one Re(1), one P(4), and two equivalent P(2) atoms to form distorted PReP3 tetrahedra that share corners with four equivalent Re(1)P6 octahedra,  a cornercorner with one P(2)ReP3 tetrahedra, corners with two equivalent P(4)Re2P2 tetrahedra, corners with two equivalent P(3)ReP3 tetrahedra, and corners with five equivalent P(1)Re2P2 tetrahedra. The corner-sharing octahedral tilt angles range from 48-72°. is represented by the CIF card [CIF]
data_ReP4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.247
_cell_length_b   9.258
_cell_length_c   10.869
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   628.634
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.622  0.110  0.424  1.0
  Re  Re1  1  0.122  0.390  0.576  1.0
  Re  Re2  1  0.378  0.610  0.076  1.0
  Re  Re3  1  0.878  0.890  0.924  1.0
  Re  Re4  1  0.378  0.890  0.576  1.0
  Re  Re5  1  0.878  0.610  0.424  1.0
  Re  Re6  1  0.622  0.390  0.924  1.0
  Re  Re7  1  0.122  0.110  0.076  1.0
  P  P8  1  0.001  0.209  0.430  1.0
  P  P9  1  0.501  0.291  0.570  1.0
  P  P10  1  0.999  0.709  0.070  1.0
  P  P11  1  0.499  0.791  0.930  1.0
  P  P12  1  0.999  0.791  0.570  1.0
  P  P13  1  0.499  0.709  0.430  1.0
  P  P14  1  0.001  0.291  0.930  1.0
  P  P15  1  0.501  0.209  0.070  1.0
  P  P16  1  0.062  0.283  0.236  1.0
  P  P17  1  0.562  0.217  0.764  1.0
  P  P18  1  0.938  0.783  0.264  1.0
  P  P19  1  0.438  0.717  0.736  1.0
  P  P20  1  0.938  0.717  0.764  1.0
  P  P21  1  0.438  0.783  0.236  1.0
  P  P22  1  0.062  0.217  0.736  1.0
  P  P23  1  0.562  0.283  0.264  1.0
  P  P24  1  0.188  0.947  0.239  1.0
  P  P25  1  0.688  0.553  0.761  1.0
  P  P26  1  0.812  0.447  0.261  1.0
  P  P27  1  0.312  0.053  0.739  1.0
  P  P28  1  0.812  0.053  0.761  1.0
  P  P29  1  0.312  0.447  0.239  1.0
  P  P30  1  0.188  0.553  0.739  1.0
  P  P31  1  0.688  0.947  0.261  1.0
  P  P32  1  0.756  0.043  0.082  1.0
  P  P33  1  0.256  0.457  0.918  1.0
  P  P34  1  0.244  0.543  0.418  1.0
  P  P35  1  0.744  0.957  0.582  1.0
  P  P36  1  0.244  0.957  0.918  1.0
  P  P37  1  0.744  0.543  0.082  1.0
  P  P38  1  0.756  0.457  0.582  1.0
  P  P39  1  0.256  0.043  0.418  1.0
[/CIF]
.
The material described by ReP4 is Hausmannite-like structured and crystallizes in the orthorhombic Pbca space group. Re(1) is bonded to one P(2), one P(3), two equivalent P(1), and two equivalent P(4) atoms to form ReP6 octahedra that share corners with two equivalent Re(1)P6 octahedra, corners with three equivalent P(1)Re2P2 tetrahedra, corners with three equivalent P(4)Re2P2 tetrahedra, corners with four equivalent P(2)ReP3 tetrahedra, corners with four equivalent P(3)ReP3 tetrahedra, and  an edgeedge with one Re(1)P6 octahedra. The corner-sharing octahedral tilt angles are 56°. There are four inequivalent P sites. In the first P site, P(4) is bonded to two equivalent Re(1), one P(1), and one P(3) atom to form distorted PRe2P2 tetrahedra that share corners with three equivalent Re(1)P6 octahedra, corners with two equivalent P(3)ReP3 tetrahedra, corners with four equivalent P(1)Re2P2 tetrahedra, corners with five equivalent P(2)ReP3 tetrahedra, and  an edgeedge with one P(4)Re2P2 tetrahedra. The corner-sharing octahedral tilt angles range from 64-73°. In the second P site, P(1) is bonded to two equivalent Re(1), one P(2), and one P(4) atom to form distorted PRe2P2 tetrahedra that share corners with three equivalent Re(1)P6 octahedra, corners with two equivalent P(1)Re2P2 tetrahedra, corners with two equivalent P(2)ReP3 tetrahedra, corners with four equivalent P(4)Re2P2 tetrahedra, and corners with five equivalent P(3)ReP3 tetrahedra. The corner-sharing octahedral tilt angles range from 53-60°. In the third P site, P(2) is bonded to one Re(1), one P(1), and two equivalent P(3) atoms to form distorted PReP3 tetrahedra that share corners with four equivalent Re(1)P6 octahedra,  a cornercorner with one P(3)ReP3 tetrahedra, corners with two equivalent P(1)Re2P2 tetrahedra, corners with two equivalent P(2)ReP3 tetrahedra, and corners with five equivalent P(4)Re2P2 tetrahedra. The corner-sharing octahedral tilt angles range from 56-76°. In the fourth P site, P(3) is bonded to one Re(1), one P(4), and two equivalent P(2) atoms to form distorted PReP3 tetrahedra that share corners with four equivalent Re(1)P6 octahedra,  a cornercorner with one P(2)ReP3 tetrahedra, corners with two equivalent P(4)Re2P2 tetrahedra, corners with two equivalent P(3)ReP3 tetrahedra, and corners with five equivalent P(1)Re2P2 tetrahedra. The corner-sharing octahedral tilt angles range from 48-72°. is represented by the CIF card [CIF]
data_ReP4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.247
_cell_length_b   9.258
_cell_length_c   10.869
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   628.634
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.622  0.110  0.424  1.0
  Re  Re1  1  0.122  0.390  0.576  1.0
  Re  Re2  1  0.378  0.610  0.076  1.0
  Re  Re3  1  0.878  0.890  0.924  1.0
  Re  Re4  1  0.378  0.890  0.576  1.0
  Re  Re5  1  0.878  0.610  0.424  1.0
  Re  Re6  1  0.622  0.390  0.924  1.0
  Re  Re7  1  0.122  0.110  0.076  1.0
  P  P8  1  0.001  0.209  0.430  1.0
  P  P9  1  0.501  0.291  0.570  1.0
  P  P10  1  0.999  0.709  0.070  1.0
  P  P11  1  0.499  0.791  0.930  1.0
  P  P12  1  0.999  0.791  0.570  1.0
  P  P13  1  0.499  0.709  0.430  1.0
  P  P14  1  0.001  0.291  0.930  1.0
  P  P15  1  0.501  0.209  0.070  1.0
  P  P16  1  0.062  0.283  0.236  1.0
  P  P17  1  0.562  0.217  0.764  1.0
  P  P18  1  0.938  0.783  0.264  1.0
  P  P19  1  0.438  0.717  0.736  1.0
  P  P20  1  0.938  0.717  0.764  1.0
  P  P21  1  0.438  0.783  0.236  1.0
  P  P22  1  0.062  0.217  0.736  1.0
  P  P23  1  0.562  0.283  0.264  1.0
  P  P24  1  0.188  0.947  0.239  1.0
  P  P25  1  0.688  0.553  0.761  1.0
  P  P26  1  0.812  0.447  0.261  1.0
  P  P27  1  0.312  0.053  0.739  1.0
  P  P28  1  0.812  0.053  0.761  1.0
  P  P29  1  0.312  0.447  0.239  1.0
  P  P30  1  0.188  0.553  0.739  1.0
  P  P31  1  0.688  0.947  0.261  1.0
  P  P32  1  0.756  0.043  0.082  1.0
  P  P33  1  0.256  0.457  0.918  1.0
  P  P34  1  0.244  0.543  0.418  1.0
  P  P35  1  0.744  0.957  0.582  1.0
  P  P36  1  0.244  0.957  0.918  1.0
  P  P37  1  0.744  0.543  0.082  1.0
  P  P38  1  0.756  0.457  0.582  1.0
  P  P39  1  0.256  0.043  0.418  1.0
[/CIF]
.