The crystal structure described by SiH3F is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four fluorosilane molecules. Si(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one F(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Si(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Si(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Si(1) atom. F(1) is bonded in a single-bond geometry to one Si(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SiH3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.994
_cell_length_b   4.866
_cell_length_c   8.650
_cell_angle_alpha   64.929
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   304.776
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Si  Si0  1  0.770  0.105  0.091  1.0
  Si  Si1  1  0.270  0.895  0.409  1.0
  Si  Si2  1  0.230  0.895  0.909  1.0
  Si  Si3  1  0.730  0.105  0.591  1.0
  H  H4  1  0.782  0.785  0.220  1.0
  H  H5  1  0.282  0.215  0.280  1.0
  H  H6  1  0.218  0.215  0.780  1.0
  H  H7  1  0.718  0.785  0.720  1.0
  H  H8  1  0.881  0.312  0.128  1.0
  H  H9  1  0.381  0.688  0.372  1.0
  H  H10  1  0.119  0.688  0.872  1.0
  H  H11  1  0.619  0.312  0.628  1.0
  H  H12  1  0.906  0.214  0.561  1.0
  H  H13  1  0.406  0.786  0.939  1.0
  H  H14  1  0.094  0.786  0.439  1.0
  H  H15  1  0.594  0.214  0.061  1.0
  F  F16  1  0.834  0.109  0.909  1.0
  F  F17  1  0.334  0.891  0.591  1.0
  F  F18  1  0.166  0.891  0.091  1.0
  F  F19  1  0.666  0.109  0.409  1.0
[/CIF]
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The crystal structure described by SiH3F is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four fluorosilane molecules. Si(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one F(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Si(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Si(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Si(1) atom. F(1) is bonded in a single-bond geometry to one Si(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SiH3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.994
_cell_length_b   4.866
_cell_length_c   8.650
_cell_angle_alpha   64.929
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   304.776
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Si  Si0  1  0.770  0.105  0.091  1.0
  Si  Si1  1  0.270  0.895  0.409  1.0
  Si  Si2  1  0.230  0.895  0.909  1.0
  Si  Si3  1  0.730  0.105  0.591  1.0
  H  H4  1  0.782  0.785  0.220  1.0
  H  H5  1  0.282  0.215  0.280  1.0
  H  H6  1  0.218  0.215  0.780  1.0
  H  H7  1  0.718  0.785  0.720  1.0
  H  H8  1  0.881  0.312  0.128  1.0
  H  H9  1  0.381  0.688  0.372  1.0
  H  H10  1  0.119  0.688  0.872  1.0
  H  H11  1  0.619  0.312  0.628  1.0
  H  H12  1  0.906  0.214  0.561  1.0
  H  H13  1  0.406  0.786  0.939  1.0
  H  H14  1  0.094  0.786  0.439  1.0
  H  H15  1  0.594  0.214  0.061  1.0
  F  F16  1  0.834  0.109  0.909  1.0
  F  F17  1  0.334  0.891  0.591  1.0
  F  F18  1  0.166  0.891  0.091  1.0
  F  F19  1  0.666  0.109  0.409  1.0
[/CIF]
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