The compound described by LaBiO3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. La(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form distorted corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles are 47°. O(1) is bonded to two equivalent La(1) and two equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OLa2Bi2 trigonal pyramids. is represented by the CIF file [CIF]
data_LaBiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.272
_cell_length_b   6.272
_cell_length_c   6.272
_cell_angle_alpha   59.998
_cell_angle_beta   59.998
_cell_angle_gamma   59.998
_symmetry_Int_Tables_number   1
_cell_volume   174.440
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.720  0.720  0.720  1.0
  La  La1  1  0.220  0.220  0.220  1.0
  Bi  Bi2  1  0.999  0.999  0.999  1.0
  Bi  Bi3  1  0.499  0.499  0.499  1.0
  O  O4  1  0.827  0.096  0.375  1.0
  O  O5  1  0.596  0.327  0.875  1.0
  O  O6  1  0.875  0.596  0.327  1.0
  O  O7  1  0.096  0.375  0.827  1.0
  O  O8  1  0.375  0.827  0.096  1.0
  O  O9  1  0.327  0.875  0.596  1.0
[/CIF]
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The compound described by LaBiO3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. La(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form distorted corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles are 47°. O(1) is bonded to two equivalent La(1) and two equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OLa2Bi2 trigonal pyramids. is represented by the CIF file [CIF]
data_LaBiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.272
_cell_length_b   6.272
_cell_length_c   6.272
_cell_angle_alpha   59.998
_cell_angle_beta   59.998
_cell_angle_gamma   59.998
_symmetry_Int_Tables_number   1
_cell_volume   174.440
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.720  0.720  0.720  1.0
  La  La1  1  0.220  0.220  0.220  1.0
  Bi  Bi2  1  0.999  0.999  0.999  1.0
  Bi  Bi3  1  0.499  0.499  0.499  1.0
  O  O4  1  0.827  0.096  0.375  1.0
  O  O5  1  0.596  0.327  0.875  1.0
  O  O6  1  0.875  0.596  0.327  1.0
  O  O7  1  0.096  0.375  0.827  1.0
  O  O8  1  0.375  0.827  0.096  1.0
  O  O9  1  0.327  0.875  0.596  1.0
[/CIF]
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