The structure described by BNCl2 is alpha Po structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of three (b n)3 cl6 molecules. B(1) is bonded in a trigonal planar geometry to two equivalent N(1) and one Cl(1) atom. N(1) is bonded in a trigonal planar geometry to two equivalent B(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_BNCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.452
_cell_length_b   6.452
_cell_length_c   6.452
_cell_angle_alpha   89.768
_cell_angle_beta   89.768
_cell_angle_gamma   89.768
_symmetry_Int_Tables_number   1
_cell_volume   268.546
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.935  0.183  0.878  1.0
  B  B1  1  0.183  0.878  0.935  1.0
  B  B2  1  0.878  0.935  0.183  1.0
  N  N3  1  0.060  0.823  0.115  1.0
  N  N4  1  0.823  0.115  0.060  1.0
  N  N5  1  0.115  0.060  0.823  1.0
  Cl  Cl6  1  0.857  0.397  0.732  1.0
  Cl  Cl7  1  0.397  0.732  0.857  1.0
  Cl  Cl8  1  0.732  0.857  0.397  1.0
  Cl  Cl9  1  0.134  0.610  0.256  1.0
  Cl  Cl10  1  0.610  0.256  0.134  1.0
  Cl  Cl11  1  0.256  0.134  0.610  1.0
[/CIF]
.
The structure described by BNCl2 is alpha Po structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of three (b n)3 cl6 molecules. B(1) is bonded in a trigonal planar geometry to two equivalent N(1) and one Cl(1) atom. N(1) is bonded in a trigonal planar geometry to two equivalent B(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_BNCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.452
_cell_length_b   6.452
_cell_length_c   6.452
_cell_angle_alpha   89.768
_cell_angle_beta   89.768
_cell_angle_gamma   89.768
_symmetry_Int_Tables_number   1
_cell_volume   268.546
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.935  0.183  0.878  1.0
  B  B1  1  0.183  0.878  0.935  1.0
  B  B2  1  0.878  0.935  0.183  1.0
  N  N3  1  0.060  0.823  0.115  1.0
  N  N4  1  0.823  0.115  0.060  1.0
  N  N5  1  0.115  0.060  0.823  1.0
  Cl  Cl6  1  0.857  0.397  0.732  1.0
  Cl  Cl7  1  0.397  0.732  0.857  1.0
  Cl  Cl8  1  0.732  0.857  0.397  1.0
  Cl  Cl9  1  0.134  0.610  0.256  1.0
  Cl  Cl10  1  0.610  0.256  0.134  1.0
  Cl  Cl11  1  0.256  0.134  0.610  1.0
[/CIF]
.