The structure described by (K4Mo2H(OF5)2)2H2 crystallizes in the monoclinic C2 space group. The structure consists of two 1333-74-0 atoms inside a K4Mo2H(OF5)2 framework. In the K4Mo2H(OF5)2 framework, there are three inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one H(1), one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. In the second K site, K(2) is bonded in a 12-coordinate geometry to two equivalent F(2), two equivalent F(3), two equivalent F(4), two equivalent F(5), and four equivalent F(1) atoms. In the third K site, K(3) is bonded in a distorted q6 geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. Mo(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. H(1) is bonded in a bent 120 degrees geometry to two equivalent K(1) atoms. O(1) is bonded in a distorted linear geometry to one K(1) and one Mo(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 1-coordinate geometry to one K(1), one K(3), two equivalent K(2), and one Mo(1) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. In the fifth F site, F(5) is bonded in a 4-coordinate geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. is represented by the CIF card [CIF]
data_K2MoHOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.364
_cell_length_b   6.364
_cell_length_c   9.193
_cell_angle_alpha   85.621
_cell_angle_beta   85.621
_cell_angle_gamma   90.032
_symmetry_Int_Tables_number   1
_cell_volume   370.104
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.533  0.044  0.709  1.0
  K  K1  1  0.956  0.467  0.291  1.0
  K  K2  1  0.995  0.005  0.000  1.0
  K  K3  1  0.482  0.518  0.000  1.0
  Mo  Mo4  1  0.457  0.983  0.239  1.0
  Mo  Mo5  1  0.017  0.543  0.761  1.0
  H  H6  1  0.563  0.437  0.500  1.0
  H  H7  1  0.995  0.005  0.500  1.0
  O  O8  1  0.440  0.997  0.427  1.0
  O  O9  1  0.003  0.560  0.573  1.0
  F  F10  1  0.481  0.972  0.013  1.0
  F  F11  1  0.028  0.519  0.987  1.0
  F  F12  1  0.233  0.767  0.224  1.0
  F  F13  1  0.233  0.767  0.776  1.0
  F  F14  1  0.675  0.757  0.225  1.0
  F  F15  1  0.243  0.325  0.775  1.0
  F  F16  1  0.685  0.203  0.191  1.0
  F  F17  1  0.797  0.315  0.809  1.0
  F  F18  1  0.244  0.207  0.192  1.0
  F  F19  1  0.793  0.756  0.808  1.0
[/CIF]
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The structure described by (K4Mo2H(OF5)2)2H2 crystallizes in the monoclinic C2 space group. The structure consists of two 1333-74-0 atoms inside a K4Mo2H(OF5)2 framework. In the K4Mo2H(OF5)2 framework, there are three inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one H(1), one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. In the second K site, K(2) is bonded in a 12-coordinate geometry to two equivalent F(2), two equivalent F(3), two equivalent F(4), two equivalent F(5), and four equivalent F(1) atoms. In the third K site, K(3) is bonded in a distorted q6 geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. Mo(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. H(1) is bonded in a bent 120 degrees geometry to two equivalent K(1) atoms. O(1) is bonded in a distorted linear geometry to one K(1) and one Mo(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 1-coordinate geometry to one K(1), one K(3), two equivalent K(2), and one Mo(1) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. In the fifth F site, F(5) is bonded in a 4-coordinate geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. is represented by the CIF card [CIF]
data_K2MoHOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.364
_cell_length_b   6.364
_cell_length_c   9.193
_cell_angle_alpha   85.621
_cell_angle_beta   85.621
_cell_angle_gamma   90.032
_symmetry_Int_Tables_number   1
_cell_volume   370.104
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.533  0.044  0.709  1.0
  K  K1  1  0.956  0.467  0.291  1.0
  K  K2  1  0.995  0.005  0.000  1.0
  K  K3  1  0.482  0.518  0.000  1.0
  Mo  Mo4  1  0.457  0.983  0.239  1.0
  Mo  Mo5  1  0.017  0.543  0.761  1.0
  H  H6  1  0.563  0.437  0.500  1.0
  H  H7  1  0.995  0.005  0.500  1.0
  O  O8  1  0.440  0.997  0.427  1.0
  O  O9  1  0.003  0.560  0.573  1.0
  F  F10  1  0.481  0.972  0.013  1.0
  F  F11  1  0.028  0.519  0.987  1.0
  F  F12  1  0.233  0.767  0.224  1.0
  F  F13  1  0.233  0.767  0.776  1.0
  F  F14  1  0.675  0.757  0.225  1.0
  F  F15  1  0.243  0.325  0.775  1.0
  F  F16  1  0.685  0.203  0.191  1.0
  F  F17  1  0.797  0.315  0.809  1.0
  F  F18  1  0.244  0.207  0.192  1.0
  F  F19  1  0.793  0.756  0.808  1.0
[/CIF]
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