The crystal structure described by CsZn4As3 crystallizes in the tetragonal P4/mmm space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent As(1) atoms. Zn(1) is bonded to two equivalent As(1) and two equivalent As(2) atoms to form a mixture of corner and edge-sharing ZnAs4 tetrahedra. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 8-coordinate geometry to four equivalent Cs(1) and four equivalent Zn(1) atoms. In the second As site, As(2) is bonded in a body-centered cubic geometry to eight equivalent Zn(1) atoms. is represented by the CIF card [CIF]
data_CsZn4As3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.175
_cell_length_b   4.175
_cell_length_c   10.672
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   186.011
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.000  0.500  1.0
  Zn  Zn1  1  0.500  0.000  0.846  1.0
  Zn  Zn2  1  0.000  0.500  0.846  1.0
  Zn  Zn3  1  0.500  0.000  0.154  1.0
  Zn  Zn4  1  0.000  0.500  0.154  1.0
  As  As5  1  0.500  0.500  0.719  1.0
  As  As6  1  0.500  0.500  0.281  1.0
  As  As7  1  0.000  0.000  0.000  1.0
[/CIF]
.
The crystal structure described by CsZn4As3 crystallizes in the tetragonal P4/mmm space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent As(1) atoms. Zn(1) is bonded to two equivalent As(1) and two equivalent As(2) atoms to form a mixture of corner and edge-sharing ZnAs4 tetrahedra. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 8-coordinate geometry to four equivalent Cs(1) and four equivalent Zn(1) atoms. In the second As site, As(2) is bonded in a body-centered cubic geometry to eight equivalent Zn(1) atoms. is represented by the CIF card [CIF]
data_CsZn4As3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.175
_cell_length_b   4.175
_cell_length_c   10.672
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   186.011
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.000  0.500  1.0
  Zn  Zn1  1  0.500  0.000  0.846  1.0
  Zn  Zn2  1  0.000  0.500  0.846  1.0
  Zn  Zn3  1  0.500  0.000  0.154  1.0
  Zn  Zn4  1  0.000  0.500  0.154  1.0
  As  As5  1  0.500  0.500  0.719  1.0
  As  As6  1  0.500  0.500  0.281  1.0
  As  As7  1  0.000  0.000  0.000  1.0
[/CIF]
.