The material described by RbSm(OCl)4 crystallizes in the orthorhombic P2_12_12 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent Cl(2) atoms. Sm(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Rb(1) and one O(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Rb(1), one Sm(1), and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one O(2) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal planar geometry to two equivalent Rb(1) and one Sm(1) atom. is represented by the CIF card [CIF]
data_RbSm(ClO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.086
_cell_length_b   8.403
_cell_length_c   8.705
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   518.301
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.090  0.000  1.0
  Rb  Rb1  1  0.500  0.910  0.500  1.0
  Sm  Sm2  1  0.000  0.409  0.500  1.0
  Sm  Sm3  1  0.500  0.591  0.000  1.0
  Cl  Cl4  1  0.173  0.591  0.209  1.0
  Cl  Cl5  1  0.827  0.591  0.791  1.0
  Cl  Cl6  1  0.327  0.409  0.709  1.0
  Cl  Cl7  1  0.673  0.409  0.291  1.0
  Cl  Cl8  1  0.152  0.174  0.338  1.0
  Cl  Cl9  1  0.848  0.174  0.662  1.0
  Cl  Cl10  1  0.348  0.826  0.838  1.0
  Cl  Cl11  1  0.652  0.826  0.162  1.0
  O  O12  1  0.440  0.162  0.051  1.0
  O  O13  1  0.560  0.162  0.949  1.0
  O  O14  1  0.060  0.838  0.551  1.0
  O  O15  1  0.940  0.838  0.449  1.0
  O  O16  1  0.233  0.571  0.394  1.0
  O  O17  1  0.767  0.571  0.606  1.0
  O  O18  1  0.267  0.429  0.894  1.0
  O  O19  1  0.733  0.429  0.106  1.0
[/CIF]
.
The material described by RbSm(OCl)4 crystallizes in the orthorhombic P2_12_12 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent Cl(2) atoms. Sm(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Rb(1) and one O(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Rb(1), one Sm(1), and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one O(2) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal planar geometry to two equivalent Rb(1) and one Sm(1) atom. is represented by the CIF card [CIF]
data_RbSm(ClO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.086
_cell_length_b   8.403
_cell_length_c   8.705
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   518.301
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.090  0.000  1.0
  Rb  Rb1  1  0.500  0.910  0.500  1.0
  Sm  Sm2  1  0.000  0.409  0.500  1.0
  Sm  Sm3  1  0.500  0.591  0.000  1.0
  Cl  Cl4  1  0.173  0.591  0.209  1.0
  Cl  Cl5  1  0.827  0.591  0.791  1.0
  Cl  Cl6  1  0.327  0.409  0.709  1.0
  Cl  Cl7  1  0.673  0.409  0.291  1.0
  Cl  Cl8  1  0.152  0.174  0.338  1.0
  Cl  Cl9  1  0.848  0.174  0.662  1.0
  Cl  Cl10  1  0.348  0.826  0.838  1.0
  Cl  Cl11  1  0.652  0.826  0.162  1.0
  O  O12  1  0.440  0.162  0.051  1.0
  O  O13  1  0.560  0.162  0.949  1.0
  O  O14  1  0.060  0.838  0.551  1.0
  O  O15  1  0.940  0.838  0.449  1.0
  O  O16  1  0.233  0.571  0.394  1.0
  O  O17  1  0.767  0.571  0.606  1.0
  O  O18  1  0.267  0.429  0.894  1.0
  O  O19  1  0.733  0.429  0.106  1.0
[/CIF]
.