The structure described by LiLa2S2O8F3 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(2), two equivalent O(3), and one F(2) atom to form distorted LiO4F trigonal bipyramids that share corners with four equivalent S(1)O4 tetrahedra. La(1) is bonded in a 10-coordinate geometry to one O(2), one O(3), two equivalent O(1), two equivalent O(4), one F(2), and three equivalent F(1) atoms. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Li(1)O4F trigonal bipyramids. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent La(1) and one S(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one La(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent La(1) and one S(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to three equivalent La(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent La(1) atoms. is represented by the CIF file [CIF]
data_LiLa2S2O8F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.661
_cell_length_b   8.661
_cell_length_c   8.333
_cell_angle_alpha   65.725
_cell_angle_beta   65.725
_cell_angle_gamma   47.826
_symmetry_Int_Tables_number   1
_cell_volume   413.777
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.593  0.407  0.250  1.0
  Li  Li1  1  0.407  0.593  0.750  1.0
  La  La2  1  0.787  0.973  0.966  1.0
  La  La3  1  0.973  0.787  0.466  1.0
  La  La4  1  0.027  0.213  0.534  1.0
  La  La5  1  0.213  0.027  0.034  1.0
  S  S6  1  0.242  0.411  0.155  1.0
  S  S7  1  0.758  0.589  0.845  1.0
  S  S8  1  0.411  0.242  0.655  1.0
  S  S9  1  0.589  0.758  0.345  1.0
  O  O10  1  0.182  0.279  0.170  1.0
  O  O11  1  0.279  0.182  0.670  1.0
  O  O12  1  0.604  0.155  0.511  1.0
  O  O13  1  0.396  0.845  0.489  1.0
  O  O14  1  0.155  0.604  0.011  1.0
  O  O15  1  0.710  0.524  0.380  1.0
  O  O16  1  0.845  0.396  0.989  1.0
  O  O17  1  0.476  0.290  0.120  1.0
  O  O18  1  0.290  0.476  0.620  1.0
  O  O19  1  0.148  0.466  0.337  1.0
  O  O20  1  0.466  0.148  0.837  1.0
  O  O21  1  0.818  0.721  0.830  1.0
  O  O22  1  0.534  0.852  0.163  1.0
  O  O23  1  0.721  0.818  0.330  1.0
  O  O24  1  0.524  0.710  0.880  1.0
  O  O25  1  0.852  0.534  0.663  1.0
  F  F26  1  0.006  0.089  0.336  1.0
  F  F27  1  0.089  0.006  0.836  1.0
  F  F28  1  0.994  0.911  0.664  1.0
  F  F29  1  0.911  0.994  0.164  1.0
  F  F30  1  0.306  0.694  0.250  1.0
  F  F31  1  0.694  0.306  0.750  1.0
[/CIF]
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The structure described by LiLa2S2O8F3 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(2), two equivalent O(3), and one F(2) atom to form distorted LiO4F trigonal bipyramids that share corners with four equivalent S(1)O4 tetrahedra. La(1) is bonded in a 10-coordinate geometry to one O(2), one O(3), two equivalent O(1), two equivalent O(4), one F(2), and three equivalent F(1) atoms. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Li(1)O4F trigonal bipyramids. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent La(1) and one S(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one La(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent La(1) and one S(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to three equivalent La(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent La(1) atoms. is represented by the CIF file [CIF]
data_LiLa2S2O8F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.661
_cell_length_b   8.661
_cell_length_c   8.333
_cell_angle_alpha   65.725
_cell_angle_beta   65.725
_cell_angle_gamma   47.826
_symmetry_Int_Tables_number   1
_cell_volume   413.777
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.593  0.407  0.250  1.0
  Li  Li1  1  0.407  0.593  0.750  1.0
  La  La2  1  0.787  0.973  0.966  1.0
  La  La3  1  0.973  0.787  0.466  1.0
  La  La4  1  0.027  0.213  0.534  1.0
  La  La5  1  0.213  0.027  0.034  1.0
  S  S6  1  0.242  0.411  0.155  1.0
  S  S7  1  0.758  0.589  0.845  1.0
  S  S8  1  0.411  0.242  0.655  1.0
  S  S9  1  0.589  0.758  0.345  1.0
  O  O10  1  0.182  0.279  0.170  1.0
  O  O11  1  0.279  0.182  0.670  1.0
  O  O12  1  0.604  0.155  0.511  1.0
  O  O13  1  0.396  0.845  0.489  1.0
  O  O14  1  0.155  0.604  0.011  1.0
  O  O15  1  0.710  0.524  0.380  1.0
  O  O16  1  0.845  0.396  0.989  1.0
  O  O17  1  0.476  0.290  0.120  1.0
  O  O18  1  0.290  0.476  0.620  1.0
  O  O19  1  0.148  0.466  0.337  1.0
  O  O20  1  0.466  0.148  0.837  1.0
  O  O21  1  0.818  0.721  0.830  1.0
  O  O22  1  0.534  0.852  0.163  1.0
  O  O23  1  0.721  0.818  0.330  1.0
  O  O24  1  0.524  0.710  0.880  1.0
  O  O25  1  0.852  0.534  0.663  1.0
  F  F26  1  0.006  0.089  0.336  1.0
  F  F27  1  0.089  0.006  0.836  1.0
  F  F28  1  0.994  0.911  0.664  1.0
  F  F29  1  0.911  0.994  0.164  1.0
  F  F30  1  0.306  0.694  0.250  1.0
  F  F31  1  0.694  0.306  0.750  1.0
[/CIF]
.