The material described by PNO5PNO4PN2TeO9 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two nitroxyl;phosphoric acid molecules, two PN2TeO9 clusters, and two PNO4 clusters. In each PN2TeO9 cluster, P(2) is bonded to one N(2), one O(11), one O(16), and one O(9) atom to form distorted PNO3 trigonal pyramids that share  a cornercorner with one Te(1)O5 trigonal bipyramid. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one P(2), one O(12), and one O(13) atom. Te(1) is bonded to one O(12), one O(14), one O(4), one O(7), and one O(9) atom to form distorted TeO5 trigonal bipyramids that share  a cornercorner with one P(2)NO3 trigonal pyramid. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one P(2) and one Te(1) atom. In the second O site, O(11) is bonded in a single-bond geometry to one P(2) atom. In the third O site, O(12) is bonded in a distorted water-like geometry to one N(2) and one Te(1) atom. In the fourth O site, O(13) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(14) is bonded in a single-bond geometry to one Te(1) atom. In the sixth O site, O(16) is bonded in a single-bond geometry to one P(2) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the eighth O site, O(4) is bonded in a single-bond geometry to one Te(1) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one N(1) and one Te(1) atom. In each PNO4 cluster, P(3) is bonded in a trigonal planar geometry to one O(10), one O(18), and one O(5) atom. N(4) is bonded in a water-like geometry to one O(1) and one O(10) atom. There are four inequivalent O sites. In the first O site, O(10) is bonded in a distorted water-like geometry to one P(3) and one N(4) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(4) atom. In the third O site, O(18) is bonded in a single-bond geometry to one P(3) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeP3(N2O9)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.877
_cell_length_b   10.701
_cell_length_c   16.154
_cell_angle_alpha   63.987
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   913.067
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.930  0.024  0.463  1.0
  Te  Te1  1  0.070  0.024  0.963  1.0
  P  P2  1  0.573  0.725  0.374  1.0
  P  P3  1  0.427  0.725  0.874  1.0
  P  P4  1  0.949  0.336  0.859  1.0
  P  P5  1  0.051  0.336  0.359  1.0
  P  P6  1  0.601  0.276  0.109  1.0
  P  P7  1  0.399  0.276  0.609  1.0
  N  N8  1  0.161  0.990  0.183  1.0
  N  N9  1  0.839  0.990  0.683  1.0
  N  N10  1  0.770  0.232  0.808  1.0
  N  N11  1  0.230  0.232  0.308  1.0
  N  N12  1  0.532  0.713  0.695  1.0
  N  N13  1  0.468  0.713  0.195  1.0
  N  N14  1  0.964  0.467  0.053  1.0
  N  N15  1  0.036  0.467  0.553  1.0
  O  O16  1  0.990  0.567  0.557  1.0
  O  O17  1  0.010  0.567  0.057  1.0
  O  O18  1  0.174  0.756  0.847  1.0
  O  O19  1  0.826  0.756  0.347  1.0
  O  O20  1  0.020  0.959  0.703  1.0
  O  O21  1  0.980  0.959  0.203  1.0
  O  O22  1  0.730  0.031  0.376  1.0
  O  O23  1  0.270  0.031  0.876  1.0
  O  O24  1  0.395  0.254  0.064  1.0
  O  O25  1  0.605  0.254  0.564  1.0
  O  O26  1  0.484  0.771  0.445  1.0
  O  O27  1  0.516  0.771  0.945  1.0
  O  O28  1  0.750  0.974  0.572  1.0
  O  O29  1  0.250  0.974  0.072  1.0
  O  O30  1  0.585  0.777  0.788  1.0
  O  O31  1  0.415  0.777  0.288  1.0
  O  O32  1  0.956  0.202  0.960  1.0
  O  O33  1  0.044  0.202  0.460  1.0
  O  O34  1  0.661  0.429  0.086  1.0
  O  O35  1  0.339  0.429  0.586  1.0
  O  O36  1  0.160  0.354  0.805  1.0
  O  O37  1  0.840  0.354  0.305  1.0
  O  O38  1  0.215  0.099  0.348  1.0
  O  O39  1  0.785  0.099  0.848  1.0
  O  O40  1  0.334  0.292  0.236  1.0
  O  O41  1  0.666  0.292  0.736  1.0
  O  O42  1  0.112  0.873  0.532  1.0
  O  O43  1  0.888  0.873  0.032  1.0
  O  O44  1  0.412  0.563  0.924  1.0
  O  O45  1  0.588  0.563  0.424  1.0
  O  O46  1  0.803  0.447  0.861  1.0
  O  O47  1  0.197  0.447  0.361  1.0
  O  O48  1  0.350  0.685  0.689  1.0
  O  O49  1  0.650  0.685  0.189  1.0
  O  O50  1  0.766  0.170  0.167  1.0
  O  O51  1  0.234  0.170  0.667  1.0
[/CIF]
.
The material described by PNO5PNO4PN2TeO9 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two nitroxyl;phosphoric acid molecules, two PN2TeO9 clusters, and two PNO4 clusters. In each PN2TeO9 cluster, P(2) is bonded to one N(2), one O(11), one O(16), and one O(9) atom to form distorted PNO3 trigonal pyramids that share  a cornercorner with one Te(1)O5 trigonal bipyramid. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one P(2), one O(12), and one O(13) atom. Te(1) is bonded to one O(12), one O(14), one O(4), one O(7), and one O(9) atom to form distorted TeO5 trigonal bipyramids that share  a cornercorner with one P(2)NO3 trigonal pyramid. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one P(2) and one Te(1) atom. In the second O site, O(11) is bonded in a single-bond geometry to one P(2) atom. In the third O site, O(12) is bonded in a distorted water-like geometry to one N(2) and one Te(1) atom. In the fourth O site, O(13) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(14) is bonded in a single-bond geometry to one Te(1) atom. In the sixth O site, O(16) is bonded in a single-bond geometry to one P(2) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the eighth O site, O(4) is bonded in a single-bond geometry to one Te(1) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one N(1) and one Te(1) atom. In each PNO4 cluster, P(3) is bonded in a trigonal planar geometry to one O(10), one O(18), and one O(5) atom. N(4) is bonded in a water-like geometry to one O(1) and one O(10) atom. There are four inequivalent O sites. In the first O site, O(10) is bonded in a distorted water-like geometry to one P(3) and one N(4) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(4) atom. In the third O site, O(18) is bonded in a single-bond geometry to one P(3) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeP3(N2O9)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.877
_cell_length_b   10.701
_cell_length_c   16.154
_cell_angle_alpha   63.987
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   913.067
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.930  0.024  0.463  1.0
  Te  Te1  1  0.070  0.024  0.963  1.0
  P  P2  1  0.573  0.725  0.374  1.0
  P  P3  1  0.427  0.725  0.874  1.0
  P  P4  1  0.949  0.336  0.859  1.0
  P  P5  1  0.051  0.336  0.359  1.0
  P  P6  1  0.601  0.276  0.109  1.0
  P  P7  1  0.399  0.276  0.609  1.0
  N  N8  1  0.161  0.990  0.183  1.0
  N  N9  1  0.839  0.990  0.683  1.0
  N  N10  1  0.770  0.232  0.808  1.0
  N  N11  1  0.230  0.232  0.308  1.0
  N  N12  1  0.532  0.713  0.695  1.0
  N  N13  1  0.468  0.713  0.195  1.0
  N  N14  1  0.964  0.467  0.053  1.0
  N  N15  1  0.036  0.467  0.553  1.0
  O  O16  1  0.990  0.567  0.557  1.0
  O  O17  1  0.010  0.567  0.057  1.0
  O  O18  1  0.174  0.756  0.847  1.0
  O  O19  1  0.826  0.756  0.347  1.0
  O  O20  1  0.020  0.959  0.703  1.0
  O  O21  1  0.980  0.959  0.203  1.0
  O  O22  1  0.730  0.031  0.376  1.0
  O  O23  1  0.270  0.031  0.876  1.0
  O  O24  1  0.395  0.254  0.064  1.0
  O  O25  1  0.605  0.254  0.564  1.0
  O  O26  1  0.484  0.771  0.445  1.0
  O  O27  1  0.516  0.771  0.945  1.0
  O  O28  1  0.750  0.974  0.572  1.0
  O  O29  1  0.250  0.974  0.072  1.0
  O  O30  1  0.585  0.777  0.788  1.0
  O  O31  1  0.415  0.777  0.288  1.0
  O  O32  1  0.956  0.202  0.960  1.0
  O  O33  1  0.044  0.202  0.460  1.0
  O  O34  1  0.661  0.429  0.086  1.0
  O  O35  1  0.339  0.429  0.586  1.0
  O  O36  1  0.160  0.354  0.805  1.0
  O  O37  1  0.840  0.354  0.305  1.0
  O  O38  1  0.215  0.099  0.348  1.0
  O  O39  1  0.785  0.099  0.848  1.0
  O  O40  1  0.334  0.292  0.236  1.0
  O  O41  1  0.666  0.292  0.736  1.0
  O  O42  1  0.112  0.873  0.532  1.0
  O  O43  1  0.888  0.873  0.032  1.0
  O  O44  1  0.412  0.563  0.924  1.0
  O  O45  1  0.588  0.563  0.424  1.0
  O  O46  1  0.803  0.447  0.861  1.0
  O  O47  1  0.197  0.447  0.361  1.0
  O  O48  1  0.350  0.685  0.689  1.0
  O  O49  1  0.650  0.685  0.189  1.0
  O  O50  1  0.766  0.170  0.167  1.0
  O  O51  1  0.234  0.170  0.667  1.0
[/CIF]
.