The compound described by La2MnRhO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. La(1) is bonded in a 8-coordinate geometry to two equivalent O(3), three equivalent O(1), and three equivalent O(2) atoms. Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-32°. Rh(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form RhO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-32°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent La(1), one Mn(1), and one Rh(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent La(1), one Mn(1), and one Rh(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent La(1), one Mn(1), and one Rh(1) atom. is represented by the CIF file [CIF]
data_La2MnRhO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.654
_cell_length_b   5.831
_cell_length_c   7.753
_cell_angle_alpha   89.997
_cell_angle_beta   88.879
_cell_angle_gamma   89.986
_symmetry_Int_Tables_number   1
_cell_volume   255.549
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.986  0.555  0.249  1.0
  La  La1  1  0.514  0.055  0.251  1.0
  La  La2  1  0.014  0.445  0.751  1.0
  La  La3  1  0.486  0.945  0.749  1.0
  Mn  Mn4  1  0.500  0.500  0.000  1.0
  Mn  Mn5  1  0.000  0.000  0.500  1.0
  O  O6  1  0.200  0.704  0.954  1.0
  O  O7  1  0.300  0.204  0.546  1.0
  O  O8  1  0.800  0.296  0.046  1.0
  O  O9  1  0.700  0.796  0.454  1.0
  O  O10  1  0.798  0.296  0.452  1.0
  O  O11  1  0.702  0.796  0.048  1.0
  O  O12  1  0.202  0.704  0.548  1.0
  O  O13  1  0.298  0.204  0.952  1.0
  O  O14  1  0.093  0.972  0.256  1.0
  O  O15  1  0.407  0.472  0.244  1.0
  O  O16  1  0.907  0.028  0.744  1.0
  O  O17  1  0.593  0.528  0.756  1.0
  Rh  Rh18  1  0.500  0.500  0.500  1.0
  Rh  Rh19  1  1.000  1.000  1.000  1.0
[/CIF]
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The compound described by La2MnRhO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. La(1) is bonded in a 8-coordinate geometry to two equivalent O(3), three equivalent O(1), and three equivalent O(2) atoms. Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-32°. Rh(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form RhO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-32°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent La(1), one Mn(1), and one Rh(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent La(1), one Mn(1), and one Rh(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent La(1), one Mn(1), and one Rh(1) atom. is represented by the CIF file [CIF]
data_La2MnRhO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.654
_cell_length_b   5.831
_cell_length_c   7.753
_cell_angle_alpha   89.997
_cell_angle_beta   88.879
_cell_angle_gamma   89.986
_symmetry_Int_Tables_number   1
_cell_volume   255.549
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.986  0.555  0.249  1.0
  La  La1  1  0.514  0.055  0.251  1.0
  La  La2  1  0.014  0.445  0.751  1.0
  La  La3  1  0.486  0.945  0.749  1.0
  Mn  Mn4  1  0.500  0.500  0.000  1.0
  Mn  Mn5  1  0.000  0.000  0.500  1.0
  O  O6  1  0.200  0.704  0.954  1.0
  O  O7  1  0.300  0.204  0.546  1.0
  O  O8  1  0.800  0.296  0.046  1.0
  O  O9  1  0.700  0.796  0.454  1.0
  O  O10  1  0.798  0.296  0.452  1.0
  O  O11  1  0.702  0.796  0.048  1.0
  O  O12  1  0.202  0.704  0.548  1.0
  O  O13  1  0.298  0.204  0.952  1.0
  O  O14  1  0.093  0.972  0.256  1.0
  O  O15  1  0.407  0.472  0.244  1.0
  O  O16  1  0.907  0.028  0.744  1.0
  O  O17  1  0.593  0.528  0.756  1.0
  Rh  Rh18  1  0.500  0.500  0.500  1.0
  Rh  Rh19  1  1.000  1.000  1.000  1.0
[/CIF]
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