The structure described by LaPbCoSbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-30°. Pb(1) is bonded in a 3-coordinate geometry to one O(2), one O(4), and one O(5) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-30°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one Co(1), one Pb(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent La(1), one Co(1), one Pb(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent La(1), one Co(1), one Pb(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LaCoSbPbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.721
_cell_length_b   5.778
_cell_length_c   8.095
_cell_angle_alpha   89.985
_cell_angle_beta   90.022
_cell_angle_gamma   90.018
_symmetry_Int_Tables_number   1
_cell_volume   267.625
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.999  0.510  0.498  1.0
  Co  Co1  1  0.499  0.990  0.998  1.0
  La  La2  1  0.489  0.455  0.248  1.0
  La  La3  1  0.989  0.045  0.748  1.0
  O  O4  1  0.411  0.991  0.743  1.0
  O  O5  1  0.911  0.509  0.243  1.0
  O  O6  1  0.565  0.026  0.257  1.0
  O  O7  1  0.065  0.474  0.757  1.0
  O  O8  1  0.787  0.802  0.546  1.0
  O  O9  1  0.287  0.698  0.046  1.0
  O  O10  1  0.226  0.211  0.465  1.0
  O  O11  1  0.726  0.289  0.965  1.0
  O  O12  1  0.712  0.271  0.539  1.0
  O  O13  1  0.212  0.229  0.039  1.0
  O  O14  1  0.309  0.708  0.457  1.0
  O  O15  1  0.809  0.793  0.957  1.0
  Pb  Pb16  1  0.503  0.516  0.747  1.0
  Pb  Pb17  1  0.003  0.984  0.247  1.0
  Sb  Sb18  1  0.999  0.506  0.001  1.0
  Sb  Sb19  1  0.499  0.994  0.501  1.0
[/CIF]
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The structure described by LaPbCoSbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-30°. Pb(1) is bonded in a 3-coordinate geometry to one O(2), one O(4), and one O(5) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-30°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one Co(1), one Pb(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent La(1), one Co(1), one Pb(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent La(1), one Co(1), one Pb(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LaCoSbPbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.721
_cell_length_b   5.778
_cell_length_c   8.095
_cell_angle_alpha   89.985
_cell_angle_beta   90.022
_cell_angle_gamma   90.018
_symmetry_Int_Tables_number   1
_cell_volume   267.625
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.999  0.510  0.498  1.0
  Co  Co1  1  0.499  0.990  0.998  1.0
  La  La2  1  0.489  0.455  0.248  1.0
  La  La3  1  0.989  0.045  0.748  1.0
  O  O4  1  0.411  0.991  0.743  1.0
  O  O5  1  0.911  0.509  0.243  1.0
  O  O6  1  0.565  0.026  0.257  1.0
  O  O7  1  0.065  0.474  0.757  1.0
  O  O8  1  0.787  0.802  0.546  1.0
  O  O9  1  0.287  0.698  0.046  1.0
  O  O10  1  0.226  0.211  0.465  1.0
  O  O11  1  0.726  0.289  0.965  1.0
  O  O12  1  0.712  0.271  0.539  1.0
  O  O13  1  0.212  0.229  0.039  1.0
  O  O14  1  0.309  0.708  0.457  1.0
  O  O15  1  0.809  0.793  0.957  1.0
  Pb  Pb16  1  0.503  0.516  0.747  1.0
  Pb  Pb17  1  0.003  0.984  0.247  1.0
  Sb  Sb18  1  0.999  0.506  0.001  1.0
  Sb  Sb19  1  0.499  0.994  0.501  1.0
[/CIF]
.