The crystal structure described by Cs2CrH8O4Cl5 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a body-centered cubic geometry to one Cl(3), three equivalent Cl(1), and four equivalent Cl(2) atoms. Cr(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) and one Cl(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(1), one H(2), and one H(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cr(1), one H(1), and one H(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cr(1) atom. In the second Cl site, Cl(2) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one H(1), and one H(2) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1) atoms. is represented by the CIF file [CIF]
data_Cs2CrH8Cl5O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.318
_cell_length_b   10.318
_cell_length_c   14.362
_cell_angle_alpha   62.889
_cell_angle_beta   62.889
_cell_angle_gamma   35.216
_symmetry_Int_Tables_number   1
_cell_volume   774.440
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.687  0.714  0.673  1.0
  Cs  Cs1  1  0.313  0.286  0.327  1.0
  Cs  Cs2  1  0.286  0.313  0.827  1.0
  Cs  Cs3  1  0.714  0.687  0.173  1.0
  Cr  Cr4  1  0.000  0.000  0.500  1.0
  Cr  Cr5  1  0.000  0.000  0.000  1.0
  H  H6  1  0.405  0.791  0.500  1.0
  H  H7  1  0.595  0.209  0.500  1.0
  H  H8  1  0.209  0.595  0.000  1.0
  H  H9  1  0.791  0.405  1.000  1.0
  H  H10  1  0.601  0.198  0.999  1.0
  H  H11  1  0.399  0.802  0.001  1.0
  H  H12  1  0.802  0.399  0.501  1.0
  H  H13  1  0.198  0.601  0.499  1.0
  H  H14  1  0.698  0.246  0.879  1.0
  H  H15  1  0.302  0.754  0.121  1.0
  H  H16  1  0.754  0.302  0.621  1.0
  H  H17  1  0.246  0.698  0.379  1.0
  H  H18  1  0.324  0.725  0.616  1.0
  H  H19  1  0.676  0.275  0.384  1.0
  H  H20  1  0.275  0.676  0.884  1.0
  H  H21  1  0.725  0.324  0.116  1.0
  Cl  Cl22  1  0.890  0.895  0.670  1.0
  Cl  Cl23  1  0.110  0.105  0.330  1.0
  Cl  Cl24  1  0.105  0.110  0.830  1.0
  Cl  Cl25  1  0.895  0.890  0.170  1.0
  Cl  Cl26  1  0.681  0.708  0.929  1.0
  Cl  Cl27  1  0.319  0.292  0.071  1.0
  Cl  Cl28  1  0.292  0.319  0.571  1.0
  Cl  Cl29  1  0.708  0.681  0.429  1.0
  Cl  Cl30  1  0.514  0.486  0.750  1.0
  Cl  Cl31  1  0.486  0.514  0.250  1.0
  O  O32  1  0.717  0.188  0.955  1.0
  O  O33  1  0.283  0.812  0.045  1.0
  O  O34  1  0.812  0.283  0.545  1.0
  O  O35  1  0.188  0.717  0.455  1.0
  O  O36  1  0.270  0.837  0.550  1.0
  O  O37  1  0.730  0.163  0.450  1.0
  O  O38  1  0.163  0.730  0.950  1.0
  O  O39  1  0.837  0.270  0.050  1.0
[/CIF]
.
The crystal structure described by Cs2CrH8O4Cl5 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a body-centered cubic geometry to one Cl(3), three equivalent Cl(1), and four equivalent Cl(2) atoms. Cr(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) and one Cl(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(1), one H(2), and one H(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cr(1), one H(1), and one H(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cr(1) atom. In the second Cl site, Cl(2) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one H(1), and one H(2) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1) atoms. is represented by the CIF file [CIF]
data_Cs2CrH8Cl5O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.318
_cell_length_b   10.318
_cell_length_c   14.362
_cell_angle_alpha   62.889
_cell_angle_beta   62.889
_cell_angle_gamma   35.216
_symmetry_Int_Tables_number   1
_cell_volume   774.440
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.687  0.714  0.673  1.0
  Cs  Cs1  1  0.313  0.286  0.327  1.0
  Cs  Cs2  1  0.286  0.313  0.827  1.0
  Cs  Cs3  1  0.714  0.687  0.173  1.0
  Cr  Cr4  1  0.000  0.000  0.500  1.0
  Cr  Cr5  1  0.000  0.000  0.000  1.0
  H  H6  1  0.405  0.791  0.500  1.0
  H  H7  1  0.595  0.209  0.500  1.0
  H  H8  1  0.209  0.595  0.000  1.0
  H  H9  1  0.791  0.405  1.000  1.0
  H  H10  1  0.601  0.198  0.999  1.0
  H  H11  1  0.399  0.802  0.001  1.0
  H  H12  1  0.802  0.399  0.501  1.0
  H  H13  1  0.198  0.601  0.499  1.0
  H  H14  1  0.698  0.246  0.879  1.0
  H  H15  1  0.302  0.754  0.121  1.0
  H  H16  1  0.754  0.302  0.621  1.0
  H  H17  1  0.246  0.698  0.379  1.0
  H  H18  1  0.324  0.725  0.616  1.0
  H  H19  1  0.676  0.275  0.384  1.0
  H  H20  1  0.275  0.676  0.884  1.0
  H  H21  1  0.725  0.324  0.116  1.0
  Cl  Cl22  1  0.890  0.895  0.670  1.0
  Cl  Cl23  1  0.110  0.105  0.330  1.0
  Cl  Cl24  1  0.105  0.110  0.830  1.0
  Cl  Cl25  1  0.895  0.890  0.170  1.0
  Cl  Cl26  1  0.681  0.708  0.929  1.0
  Cl  Cl27  1  0.319  0.292  0.071  1.0
  Cl  Cl28  1  0.292  0.319  0.571  1.0
  Cl  Cl29  1  0.708  0.681  0.429  1.0
  Cl  Cl30  1  0.514  0.486  0.750  1.0
  Cl  Cl31  1  0.486  0.514  0.250  1.0
  O  O32  1  0.717  0.188  0.955  1.0
  O  O33  1  0.283  0.812  0.045  1.0
  O  O34  1  0.812  0.283  0.545  1.0
  O  O35  1  0.188  0.717  0.455  1.0
  O  O36  1  0.270  0.837  0.550  1.0
  O  O37  1  0.730  0.163  0.450  1.0
  O  O38  1  0.163  0.730  0.950  1.0
  O  O39  1  0.837  0.270  0.050  1.0
[/CIF]
.