The material structure described by FS(O2)O(O2)SF is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of four FS(O2)O(O2)SF clusters. S(1) is bonded to one O(1), one O(2), one O(3), and one F(1) atom to form corner-sharing SO3F tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent S(1) atoms. F(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S2O5F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.494
_cell_length_b   7.494
_cell_length_c   9.249
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   519.481
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.578  0.174  0.636  1.0
  S  S1  1  0.422  0.826  0.636  1.0
  S  S2  1  0.326  0.922  0.136  1.0
  S  S3  1  0.826  0.578  0.364  1.0
  S  S4  1  0.174  0.422  0.364  1.0
  S  S5  1  0.922  0.674  0.864  1.0
  S  S6  1  0.078  0.326  0.864  1.0
  S  S7  1  0.674  0.078  0.136  1.0
  O  O8  1  0.525  0.791  0.512  1.0
  O  O9  1  0.386  0.705  0.747  1.0
  O  O10  1  0.205  0.886  0.247  1.0
  O  O11  1  0.705  0.614  0.253  1.0
  O  O12  1  0.295  0.386  0.253  1.0
  O  O13  1  0.886  0.795  0.753  1.0
  O  O14  1  0.114  0.205  0.753  1.0
  O  O15  1  0.795  0.114  0.247  1.0
  O  O16  1  0.500  0.000  0.218  1.0
  O  O17  1  0.000  0.500  0.782  1.0
  O  O18  1  0.000  0.500  0.282  1.0
  O  O19  1  0.500  0.000  0.718  1.0
  O  O20  1  0.709  0.975  0.012  1.0
  O  O21  1  0.475  0.209  0.512  1.0
  O  O22  1  0.025  0.709  0.988  1.0
  O  O23  1  0.209  0.525  0.488  1.0
  O  O24  1  0.791  0.475  0.488  1.0
  O  O25  1  0.291  0.025  0.012  1.0
  O  O26  1  0.975  0.291  0.988  1.0
  O  O27  1  0.614  0.295  0.747  1.0
  F  F28  1  0.593  0.258  0.085  1.0
  F  F29  1  0.258  0.407  0.915  1.0
  F  F30  1  0.742  0.593  0.915  1.0
  F  F31  1  0.093  0.242  0.415  1.0
  F  F32  1  0.907  0.758  0.415  1.0
  F  F33  1  0.407  0.742  0.085  1.0
  F  F34  1  0.242  0.907  0.585  1.0
  F  F35  1  0.758  0.093  0.585  1.0
[/CIF]
.
The material structure described by FS(O2)O(O2)SF is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of four FS(O2)O(O2)SF clusters. S(1) is bonded to one O(1), one O(2), one O(3), and one F(1) atom to form corner-sharing SO3F tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent S(1) atoms. F(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S2O5F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.494
_cell_length_b   7.494
_cell_length_c   9.249
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   519.481
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.578  0.174  0.636  1.0
  S  S1  1  0.422  0.826  0.636  1.0
  S  S2  1  0.326  0.922  0.136  1.0
  S  S3  1  0.826  0.578  0.364  1.0
  S  S4  1  0.174  0.422  0.364  1.0
  S  S5  1  0.922  0.674  0.864  1.0
  S  S6  1  0.078  0.326  0.864  1.0
  S  S7  1  0.674  0.078  0.136  1.0
  O  O8  1  0.525  0.791  0.512  1.0
  O  O9  1  0.386  0.705  0.747  1.0
  O  O10  1  0.205  0.886  0.247  1.0
  O  O11  1  0.705  0.614  0.253  1.0
  O  O12  1  0.295  0.386  0.253  1.0
  O  O13  1  0.886  0.795  0.753  1.0
  O  O14  1  0.114  0.205  0.753  1.0
  O  O15  1  0.795  0.114  0.247  1.0
  O  O16  1  0.500  0.000  0.218  1.0
  O  O17  1  0.000  0.500  0.782  1.0
  O  O18  1  0.000  0.500  0.282  1.0
  O  O19  1  0.500  0.000  0.718  1.0
  O  O20  1  0.709  0.975  0.012  1.0
  O  O21  1  0.475  0.209  0.512  1.0
  O  O22  1  0.025  0.709  0.988  1.0
  O  O23  1  0.209  0.525  0.488  1.0
  O  O24  1  0.791  0.475  0.488  1.0
  O  O25  1  0.291  0.025  0.012  1.0
  O  O26  1  0.975  0.291  0.988  1.0
  O  O27  1  0.614  0.295  0.747  1.0
  F  F28  1  0.593  0.258  0.085  1.0
  F  F29  1  0.258  0.407  0.915  1.0
  F  F30  1  0.742  0.593  0.915  1.0
  F  F31  1  0.093  0.242  0.415  1.0
  F  F32  1  0.907  0.758  0.415  1.0
  F  F33  1  0.407  0.742  0.085  1.0
  F  F34  1  0.242  0.907  0.585  1.0
  F  F35  1  0.758  0.093  0.585  1.0
[/CIF]
.