The structure described by Li7V4O11F crystallizes in the triclinic P1 space group. There are seven inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O5F octahedra,  a cornercorner with one Li(4)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent Li(6)O5 trigonal bipyramids,  an edgeedge with one Li(3)O5F octahedra,  an edgeedge with one Li(4)O5F octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-21°. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one F(1) atom to form distorted LiO5F octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent Li(4)O5F octahedra, and edges with three equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 3-21°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one F(1) atom to form LiO5F octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent Li(3)O5F octahedra, and edges with three equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-26°. In the fifth Li site, Li(5) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one F(1) atom to form LiO5F octahedra that share  a cornercorner with one Li(3)O5F octahedra,  a cornercorner with one Li(4)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  an edgeedge with one Li(3)O5F octahedra,  an edgeedge with one Li(4)O5F octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent V(3)O5F octahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-20°. In the sixth Li site, Li(6) is bonded to one O(10), one O(11), one O(5), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-88°. In the seventh Li site, Li(7) is bonded to one O(10), one O(11), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent V(4)O6 octahedra, and edges with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 5-15°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O5F octahedra,  a cornercorner with one Li(4)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O5F octahedra,  an edgeedge with one Li(4)O5F octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-13°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent Li(3)O5F octahedra, and edges with three equivalent Li(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the third V site, V(3) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O5F octahedra,  a cornercorner with one Li(4)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  an edgeedge with one Li(3)O5F octahedra,  an edgeedge with one Li(4)O5F octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(5)O5F octahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-26°. In the fourth V site, V(4) is bonded to one O(10), one O(11), one O(4), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent Li(7)O6 octahedra, and edges with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-16°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(3)Li3V2 square pyramid,  a cornercorner with one O(4)Li3V2 square pyramid,  a cornercorner with one F(1)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 trigonal bipyramid,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra, edges with three equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(3)Li3V2 square pyramid,  an edgeedge with one O(4)Li3V2 square pyramid,  an edgeedge with one F(1)Li3V2 square pyramid, and  an edgeedge with one O(2)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 5-10°. In the second O site, O(2) is bonded to one Li(3), one Li(4), one Li(5), one V(2), and one V(3) atom to form distorted OLi3V2 trigonal bipyramids that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(3)Li3V2 square pyramid,  a cornercorner with one F(1)Li3V2 square pyramid, corners with two equivalent O(10)Li3V2 square pyramids, corners with two equivalent O(5)Li3V2 square pyramids,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li3V2 square pyramids, edges with two equivalent F(1)Li3V2 square pyramids, and  an edgeedge with one O(11)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 8-18°. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Li(5), one V(2), and one V(3) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one F(1)Li3V2 square pyramid, corners with two equivalent O(10)Li3V2 square pyramids,  a cornercorner with one O(2)Li3V2 trigonal bipyramid, corners with two equivalent O(11)Li3V2 trigonal bipyramids,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(5)Li3V2 square pyramid, edges with two equivalent F(1)Li3V2 square pyramids, and edges with two equivalent O(2)Li3V2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 5-6°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(7), one V(1), and one V(4) atom to form distorted OLi3V2 square pyramids that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra, corners with two equivalent O(10)Li3V2 square pyramids, corners with two equivalent O(11)Li3V2 trigonal bipyramids,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(8)Li4V2 octahedra, edges with two equivalent O(9)Li4V2 octahedra, and  an edgeedge with one O(5)Li3V2 square pyramid. The corner-sharing octahedral tilt angles range from 11-79°. In the fifth O site, O(5) is bonded to one Li(5), one Li(6), one Li(7), one V(3), and one V(4) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(10)Li3V2 square pyramid, corners with two equivalent F(1)Li3V2 square pyramids,  a cornercorner with one O(11)Li3V2 trigonal bipyramid, corners with two equivalent O(2)Li3V2 trigonal bipyramids,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra,  an edgeedge with one O(3)Li3V2 square pyramid,  an edgeedge with one O(4)Li3V2 square pyramid, edges with two equivalent O(10)Li3V2 square pyramids, and edges with two equivalent O(11)Li3V2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 6-13°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(3)Li3V2 square pyramid,  a cornercorner with one O(4)Li3V2 square pyramid,  a cornercorner with one F(1)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 trigonal bipyramid,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra, edges with three equivalent O(1)Li4V2 octahedra,  an edgeedge with one O(3)Li3V2 square pyramid,  an edgeedge with one O(4)Li3V2 square pyramid,  an edgeedge with one F(1)Li3V2 square pyramid, and  an edgeedge with one O(2)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-10°. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Li(6), one Li(7), one V(1), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(4)Li3V2 square pyramid,  a cornercorner with one O(5)Li3V2 square pyramid,  a cornercorner with one O(11)Li3V2 trigonal bipyramid,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with three equivalent O(9)Li4V2 octahedra,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(5)Li3V2 square pyramid, edges with two equivalent O(4)Li3V2 square pyramids, and  an edgeedge with one O(11)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles are 10°. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Li(6), one Li(7), one V(1), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(4)Li3V2 square pyramid,  a cornercorner with one O(5)Li3V2 square pyramid,  a cornercorner with one O(11)Li3V2 trigonal bipyramid,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with three equivalent O(8)Li4V2 octahedra,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(5)Li3V2 square pyramid, edges with two equivalent O(4)Li3V2 square pyramids, and  an edgeedge with one O(11)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-5°. In the tenth O site, O(10) is bonded to one Li(5), one Li(6), one Li(7), one V(3), and one V(4) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(5)Li3V2 square pyramid, corners with two equivalent O(3)Li3V2 square pyramids, corners with two equivalent O(4)Li3V2 square pyramids,  a cornercorner with one O(11)Li3V2 trigonal bipyramid, corners with two equivalent O(2)Li3V2 trigonal bipyramids,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra,  an edgeedge with one F(1)Li3V2 square pyramid, edges with two equivalent O(5)Li3V2 square pyramids, and edges with two equivalent O(11)Li3V2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 8-9°. In the eleventh O site, O(11) is bonded to one Li(5), one Li(6), one Li(7), one V(3), and one V(4) atom to form OLi3V2 trigonal bipyramids that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(5)Li3V2 square pyramid, corners with two equivalent O(3)Li3V2 square pyramids, corners with two equivalent O(4)Li3V2 square pyramids, corners with two equivalent F(1)Li3V2 square pyramids,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra, edges with two equivalent O(10)Li3V2 square pyramids, edges with two equivalent O(5)Li3V2 square pyramids, and  an edgeedge with one O(2)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 5-20°. F(1) is bonded to one Li(3), one Li(4), one Li(5), one V(2), and one V(3) atom to form distorted FLi3V2 square pyramids that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(5)Li3V2 square pyramids,  a cornercorner with one O(2)Li3V2 trigonal bipyramid, corners with two equivalent O(11)Li3V2 trigonal bipyramids,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li3V2 square pyramid, edges with two equivalent O(3)Li3V2 square pyramids, and edges with two equivalent O(2)Li3V2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 3-9°. is represented by the CIF card [CIF]
data_Li7V4O11F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.030
_cell_length_b   5.072
_cell_length_c   9.404
_cell_angle_alpha   93.926
_cell_angle_beta   93.093
_cell_angle_gamma   116.013
_symmetry_Int_Tables_number   1
_cell_volume   214.134
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.388  0.865  0.123  1.0
  Li  Li1  1  0.695  0.530  0.121  1.0
  Li  Li2  1  0.778  0.934  0.371  1.0
  Li  Li3  1  0.125  0.643  0.376  1.0
  Li  Li4  1  0.865  0.364  0.626  1.0
  Li  Li5  1  0.279  0.423  0.862  1.0
  Li  Li6  1  0.617  0.141  0.875  1.0
  V  V7  1  0.052  0.230  0.121  1.0
  V  V8  1  0.470  0.272  0.371  1.0
  V  V9  1  0.545  0.744  0.633  1.0
  V  V10  1  0.967  0.794  0.871  1.0
  O  O11  1  0.392  0.541  0.244  1.0
  O  O12  1  0.742  0.609  0.492  1.0
  O  O13  1  0.505  0.998  0.498  1.0
  O  O14  1  0.739  0.867  0.010  1.0
  O  O15  1  0.879  0.042  0.744  1.0
  O  O16  1  0.752  0.249  0.251  1.0
  O  O17  1  0.123  0.979  0.264  1.0
  O  O18  1  0.303  0.141  0.994  1.0
  O  O19  1  0.012  0.495  0.005  1.0
  O  O20  1  0.253  0.737  0.753  1.0
  O  O21  1  0.635  0.485  0.763  1.0
  F  F22  1  0.181  0.370  0.506  1.0
[/CIF]
.
The structure described by Li7V4O11F crystallizes in the triclinic P1 space group. There are seven inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O5F octahedra,  a cornercorner with one Li(4)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent Li(6)O5 trigonal bipyramids,  an edgeedge with one Li(3)O5F octahedra,  an edgeedge with one Li(4)O5F octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-21°. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one F(1) atom to form distorted LiO5F octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent Li(4)O5F octahedra, and edges with three equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 3-21°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one F(1) atom to form LiO5F octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent Li(3)O5F octahedra, and edges with three equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-26°. In the fifth Li site, Li(5) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one F(1) atom to form LiO5F octahedra that share  a cornercorner with one Li(3)O5F octahedra,  a cornercorner with one Li(4)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  an edgeedge with one Li(3)O5F octahedra,  an edgeedge with one Li(4)O5F octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent V(3)O5F octahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-20°. In the sixth Li site, Li(6) is bonded to one O(10), one O(11), one O(5), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-88°. In the seventh Li site, Li(7) is bonded to one O(10), one O(11), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent V(4)O6 octahedra, and edges with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 5-15°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O5F octahedra,  a cornercorner with one Li(4)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O5F octahedra,  an edgeedge with one Li(4)O5F octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-13°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent Li(3)O5F octahedra, and edges with three equivalent Li(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the third V site, V(3) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O5F octahedra,  a cornercorner with one Li(4)O5F octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  an edgeedge with one Li(3)O5F octahedra,  an edgeedge with one Li(4)O5F octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(5)O5F octahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-26°. In the fourth V site, V(4) is bonded to one O(10), one O(11), one O(4), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(5)O5F octahedra,  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  an edgeedge with one Li(5)O5F octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(1)O6 octahedra, edges with three equivalent Li(7)O6 octahedra, and edges with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-16°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(3)Li3V2 square pyramid,  a cornercorner with one O(4)Li3V2 square pyramid,  a cornercorner with one F(1)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 trigonal bipyramid,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra, edges with three equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(3)Li3V2 square pyramid,  an edgeedge with one O(4)Li3V2 square pyramid,  an edgeedge with one F(1)Li3V2 square pyramid, and  an edgeedge with one O(2)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 5-10°. In the second O site, O(2) is bonded to one Li(3), one Li(4), one Li(5), one V(2), and one V(3) atom to form distorted OLi3V2 trigonal bipyramids that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(3)Li3V2 square pyramid,  a cornercorner with one F(1)Li3V2 square pyramid, corners with two equivalent O(10)Li3V2 square pyramids, corners with two equivalent O(5)Li3V2 square pyramids,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li3V2 square pyramids, edges with two equivalent F(1)Li3V2 square pyramids, and  an edgeedge with one O(11)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 8-18°. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Li(5), one V(2), and one V(3) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one F(1)Li3V2 square pyramid, corners with two equivalent O(10)Li3V2 square pyramids,  a cornercorner with one O(2)Li3V2 trigonal bipyramid, corners with two equivalent O(11)Li3V2 trigonal bipyramids,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(5)Li3V2 square pyramid, edges with two equivalent F(1)Li3V2 square pyramids, and edges with two equivalent O(2)Li3V2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 5-6°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(7), one V(1), and one V(4) atom to form distorted OLi3V2 square pyramids that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra, corners with two equivalent O(10)Li3V2 square pyramids, corners with two equivalent O(11)Li3V2 trigonal bipyramids,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(8)Li4V2 octahedra, edges with two equivalent O(9)Li4V2 octahedra, and  an edgeedge with one O(5)Li3V2 square pyramid. The corner-sharing octahedral tilt angles range from 11-79°. In the fifth O site, O(5) is bonded to one Li(5), one Li(6), one Li(7), one V(3), and one V(4) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(10)Li3V2 square pyramid, corners with two equivalent F(1)Li3V2 square pyramids,  a cornercorner with one O(11)Li3V2 trigonal bipyramid, corners with two equivalent O(2)Li3V2 trigonal bipyramids,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra,  an edgeedge with one O(3)Li3V2 square pyramid,  an edgeedge with one O(4)Li3V2 square pyramid, edges with two equivalent O(10)Li3V2 square pyramids, and edges with two equivalent O(11)Li3V2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 6-13°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(3)Li3V2 square pyramid,  a cornercorner with one O(4)Li3V2 square pyramid,  a cornercorner with one F(1)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 trigonal bipyramid,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra, edges with three equivalent O(1)Li4V2 octahedra,  an edgeedge with one O(3)Li3V2 square pyramid,  an edgeedge with one O(4)Li3V2 square pyramid,  an edgeedge with one F(1)Li3V2 square pyramid, and  an edgeedge with one O(2)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-10°. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Li(6), one Li(7), one V(1), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(4)Li3V2 square pyramid,  a cornercorner with one O(5)Li3V2 square pyramid,  a cornercorner with one O(11)Li3V2 trigonal bipyramid,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with three equivalent O(9)Li4V2 octahedra,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(5)Li3V2 square pyramid, edges with two equivalent O(4)Li3V2 square pyramids, and  an edgeedge with one O(11)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles are 10°. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Li(6), one Li(7), one V(1), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(4)Li3V2 square pyramid,  a cornercorner with one O(5)Li3V2 square pyramid,  a cornercorner with one O(11)Li3V2 trigonal bipyramid,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with three equivalent O(8)Li4V2 octahedra,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(5)Li3V2 square pyramid, edges with two equivalent O(4)Li3V2 square pyramids, and  an edgeedge with one O(11)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-5°. In the tenth O site, O(10) is bonded to one Li(5), one Li(6), one Li(7), one V(3), and one V(4) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(5)Li3V2 square pyramid, corners with two equivalent O(3)Li3V2 square pyramids, corners with two equivalent O(4)Li3V2 square pyramids,  a cornercorner with one O(11)Li3V2 trigonal bipyramid, corners with two equivalent O(2)Li3V2 trigonal bipyramids,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra,  an edgeedge with one F(1)Li3V2 square pyramid, edges with two equivalent O(5)Li3V2 square pyramids, and edges with two equivalent O(11)Li3V2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 8-9°. In the eleventh O site, O(11) is bonded to one Li(5), one Li(6), one Li(7), one V(3), and one V(4) atom to form OLi3V2 trigonal bipyramids that share  a cornercorner with one O(8)Li4V2 octahedra,  a cornercorner with one O(9)Li4V2 octahedra,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(5)Li3V2 square pyramid, corners with two equivalent O(3)Li3V2 square pyramids, corners with two equivalent O(4)Li3V2 square pyramids, corners with two equivalent F(1)Li3V2 square pyramids,  an edgeedge with one O(8)Li4V2 octahedra,  an edgeedge with one O(9)Li4V2 octahedra, edges with two equivalent O(10)Li3V2 square pyramids, edges with two equivalent O(5)Li3V2 square pyramids, and  an edgeedge with one O(2)Li3V2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 5-20°. F(1) is bonded to one Li(3), one Li(4), one Li(5), one V(2), and one V(3) atom to form distorted FLi3V2 square pyramids that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(5)Li3V2 square pyramids,  a cornercorner with one O(2)Li3V2 trigonal bipyramid, corners with two equivalent O(11)Li3V2 trigonal bipyramids,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li3V2 square pyramid, edges with two equivalent O(3)Li3V2 square pyramids, and edges with two equivalent O(2)Li3V2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 3-9°. is represented by the CIF card [CIF]
data_Li7V4O11F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.030
_cell_length_b   5.072
_cell_length_c   9.404
_cell_angle_alpha   93.926
_cell_angle_beta   93.093
_cell_angle_gamma   116.013
_symmetry_Int_Tables_number   1
_cell_volume   214.134
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.388  0.865  0.123  1.0
  Li  Li1  1  0.695  0.530  0.121  1.0
  Li  Li2  1  0.778  0.934  0.371  1.0
  Li  Li3  1  0.125  0.643  0.376  1.0
  Li  Li4  1  0.865  0.364  0.626  1.0
  Li  Li5  1  0.279  0.423  0.862  1.0
  Li  Li6  1  0.617  0.141  0.875  1.0
  V  V7  1  0.052  0.230  0.121  1.0
  V  V8  1  0.470  0.272  0.371  1.0
  V  V9  1  0.545  0.744  0.633  1.0
  V  V10  1  0.967  0.794  0.871  1.0
  O  O11  1  0.392  0.541  0.244  1.0
  O  O12  1  0.742  0.609  0.492  1.0
  O  O13  1  0.505  0.998  0.498  1.0
  O  O14  1  0.739  0.867  0.010  1.0
  O  O15  1  0.879  0.042  0.744  1.0
  O  O16  1  0.752  0.249  0.251  1.0
  O  O17  1  0.123  0.979  0.264  1.0
  O  O18  1  0.303  0.141  0.994  1.0
  O  O19  1  0.012  0.495  0.005  1.0
  O  O20  1  0.253  0.737  0.753  1.0
  O  O21  1  0.635  0.485  0.763  1.0
  F  F22  1  0.181  0.370  0.506  1.0
[/CIF]
.