The crystal structure described by WGa2O6 is Rutile-derived structured and crystallizes in the tetragonal P4_2/mnm space group. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form WO6 octahedra that share corners with eight equivalent Ga(1)O6 octahedra and edges with two equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. Ga(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form GaO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Ga(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, and  an edgeedge with one Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ga(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_Ga2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.653
_cell_length_b   4.653
_cell_length_c   9.038
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   195.659
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.500  0.500  0.336  1.0
  Ga  Ga1  1  0.500  0.500  0.664  1.0
  Ga  Ga2  1  0.000  0.000  0.164  1.0
  Ga  Ga3  1  0.000  0.000  0.836  1.0
  W  W4  1  0.500  0.500  0.000  1.0
  W  W5  1  0.000  0.000  0.500  1.0
  O  O6  1  0.696  0.696  0.161  1.0
  O  O7  1  0.696  0.696  0.839  1.0
  O  O8  1  0.700  0.700  0.500  1.0
  O  O9  1  0.800  0.200  0.000  1.0
  O  O10  1  0.804  0.196  0.339  1.0
  O  O11  1  0.804  0.196  0.661  1.0
  O  O12  1  0.196  0.804  0.339  1.0
  O  O13  1  0.196  0.804  0.661  1.0
  O  O14  1  0.200  0.800  0.000  1.0
  O  O15  1  0.300  0.300  0.500  1.0
  O  O16  1  0.304  0.304  0.161  1.0
  O  O17  1  0.304  0.304  0.839  1.0
[/CIF]
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The crystal structure described by WGa2O6 is Rutile-derived structured and crystallizes in the tetragonal P4_2/mnm space group. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form WO6 octahedra that share corners with eight equivalent Ga(1)O6 octahedra and edges with two equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. Ga(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form GaO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Ga(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, and  an edgeedge with one Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ga(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_Ga2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.653
_cell_length_b   4.653
_cell_length_c   9.038
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   195.659
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.500  0.500  0.336  1.0
  Ga  Ga1  1  0.500  0.500  0.664  1.0
  Ga  Ga2  1  0.000  0.000  0.164  1.0
  Ga  Ga3  1  0.000  0.000  0.836  1.0
  W  W4  1  0.500  0.500  0.000  1.0
  W  W5  1  0.000  0.000  0.500  1.0
  O  O6  1  0.696  0.696  0.161  1.0
  O  O7  1  0.696  0.696  0.839  1.0
  O  O8  1  0.700  0.700  0.500  1.0
  O  O9  1  0.800  0.200  0.000  1.0
  O  O10  1  0.804  0.196  0.339  1.0
  O  O11  1  0.804  0.196  0.661  1.0
  O  O12  1  0.196  0.804  0.339  1.0
  O  O13  1  0.196  0.804  0.661  1.0
  O  O14  1  0.200  0.800  0.000  1.0
  O  O15  1  0.300  0.300  0.500  1.0
  O  O16  1  0.304  0.304  0.161  1.0
  O  O17  1  0.304  0.304  0.839  1.0
[/CIF]
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