The compound described by Mo2NOCl9(N2)2 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of sixteen ammonia atoms and four Mo2NOCl9 clusters. In each Mo2NOCl9 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(3), one Cl(6), and two equivalent Cl(2) atoms to form corner-sharing MoCl5 trigonal bipyramids. In the second Mo site, Mo(2) is bonded to one Cl(4), one Cl(6), one Cl(7), and two equivalent Cl(5) atoms to form corner-sharing MoCl5 trigonal bipyramids. N(1) is bonded in a distorted single-bond geometry to one O(1) and one Cl(4) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one Mo(2) and one N(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth Cl site, Cl(6) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the fifth Cl site, Cl(7) is bonded in a single-bond geometry to one Mo(2) atom. In the sixth Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the CIF card [CIF]
data_Mo2N5Cl9O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.779
_cell_length_b   8.779
_cell_length_c   14.268
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.603
_symmetry_Int_Tables_number   1
_cell_volume   1077.167
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.026  0.974  0.941  1.0
  Mo  Mo1  1  0.974  0.026  0.441  1.0
  Mo  Mo2  1  0.255  0.745  0.211  1.0
  Mo  Mo3  1  0.745  0.255  0.711  1.0
  N  N4  1  0.552  0.448  0.158  1.0
  N  N5  1  0.448  0.552  0.658  1.0
  N  N6  1  0.724  0.802  0.216  1.0
  N  N7  1  0.198  0.276  0.216  1.0
  N  N8  1  0.276  0.198  0.716  1.0
  N  N9  1  0.802  0.724  0.716  1.0
  N  N10  1  0.435  0.031  0.420  1.0
  N  N11  1  0.969  0.565  0.420  1.0
  N  N12  1  0.565  0.969  0.920  1.0
  N  N13  1  0.031  0.435  0.920  1.0
  Cl  Cl14  1  0.892  0.108  0.046  1.0
  Cl  Cl15  1  0.108  0.892  0.546  1.0
  Cl  Cl16  1  0.254  0.149  0.973  1.0
  Cl  Cl17  1  0.851  0.746  0.973  1.0
  Cl  Cl18  1  0.746  0.851  0.473  1.0
  Cl  Cl19  1  0.149  0.254  0.473  1.0
  Cl  Cl20  1  0.165  0.835  0.842  1.0
  Cl  Cl21  1  0.835  0.165  0.342  1.0
  Cl  Cl22  1  0.404  0.596  0.102  1.0
  Cl  Cl23  1  0.596  0.404  0.602  1.0
  Cl  Cl24  1  0.407  0.963  0.148  1.0
  Cl  Cl25  1  0.037  0.593  0.148  1.0
  Cl  Cl26  1  0.593  0.037  0.648  1.0
  Cl  Cl27  1  0.963  0.407  0.648  1.0
  Cl  Cl28  1  0.096  0.904  0.289  1.0
  Cl  Cl29  1  0.904  0.096  0.789  1.0
  Cl  Cl30  1  0.351  0.649  0.343  1.0
  Cl  Cl31  1  0.649  0.351  0.843  1.0
  O  O32  1  0.559  0.441  0.237  1.0
  O  O33  1  0.441  0.559  0.737  1.0
[/CIF]
.
The compound described by Mo2NOCl9(N2)2 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of sixteen ammonia atoms and four Mo2NOCl9 clusters. In each Mo2NOCl9 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(3), one Cl(6), and two equivalent Cl(2) atoms to form corner-sharing MoCl5 trigonal bipyramids. In the second Mo site, Mo(2) is bonded to one Cl(4), one Cl(6), one Cl(7), and two equivalent Cl(5) atoms to form corner-sharing MoCl5 trigonal bipyramids. N(1) is bonded in a distorted single-bond geometry to one O(1) and one Cl(4) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one Mo(2) and one N(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth Cl site, Cl(6) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the fifth Cl site, Cl(7) is bonded in a single-bond geometry to one Mo(2) atom. In the sixth Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the CIF card [CIF]
data_Mo2N5Cl9O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.779
_cell_length_b   8.779
_cell_length_c   14.268
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.603
_symmetry_Int_Tables_number   1
_cell_volume   1077.167
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.026  0.974  0.941  1.0
  Mo  Mo1  1  0.974  0.026  0.441  1.0
  Mo  Mo2  1  0.255  0.745  0.211  1.0
  Mo  Mo3  1  0.745  0.255  0.711  1.0
  N  N4  1  0.552  0.448  0.158  1.0
  N  N5  1  0.448  0.552  0.658  1.0
  N  N6  1  0.724  0.802  0.216  1.0
  N  N7  1  0.198  0.276  0.216  1.0
  N  N8  1  0.276  0.198  0.716  1.0
  N  N9  1  0.802  0.724  0.716  1.0
  N  N10  1  0.435  0.031  0.420  1.0
  N  N11  1  0.969  0.565  0.420  1.0
  N  N12  1  0.565  0.969  0.920  1.0
  N  N13  1  0.031  0.435  0.920  1.0
  Cl  Cl14  1  0.892  0.108  0.046  1.0
  Cl  Cl15  1  0.108  0.892  0.546  1.0
  Cl  Cl16  1  0.254  0.149  0.973  1.0
  Cl  Cl17  1  0.851  0.746  0.973  1.0
  Cl  Cl18  1  0.746  0.851  0.473  1.0
  Cl  Cl19  1  0.149  0.254  0.473  1.0
  Cl  Cl20  1  0.165  0.835  0.842  1.0
  Cl  Cl21  1  0.835  0.165  0.342  1.0
  Cl  Cl22  1  0.404  0.596  0.102  1.0
  Cl  Cl23  1  0.596  0.404  0.602  1.0
  Cl  Cl24  1  0.407  0.963  0.148  1.0
  Cl  Cl25  1  0.037  0.593  0.148  1.0
  Cl  Cl26  1  0.593  0.037  0.648  1.0
  Cl  Cl27  1  0.963  0.407  0.648  1.0
  Cl  Cl28  1  0.096  0.904  0.289  1.0
  Cl  Cl29  1  0.904  0.096  0.789  1.0
  Cl  Cl30  1  0.351  0.649  0.343  1.0
  Cl  Cl31  1  0.649  0.351  0.843  1.0
  O  O32  1  0.559  0.441  0.237  1.0
  O  O33  1  0.441  0.559  0.737  1.0
[/CIF]
.