The crystal structure described by Sm5Co19 crystallizes in the hexagonal P6_3/mmc space group. There are three inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 12-coordinate geometry to three equivalent Co(7) and nine equivalent Co(1) atoms. In the second Sm site, Sm(2) is bonded in a 18-coordinate geometry to three equivalent Co(3), three equivalent Co(4), six equivalent Co(1), and six equivalent Co(2) atoms. In the third Sm site, Sm(3) is bonded in a 18-coordinate geometry to six equivalent Co(5,6) and twelve equivalent Co(2) atoms. There are six inequivalent Co sites. In the first Co site, Co(3) is bonded in a 9-coordinate geometry to three equivalent Sm(2), three equivalent Co(1), and three equivalent Co(2) atoms. In the second Co site, Co(4) is bonded in a 9-coordinate geometry to three equivalent Sm(2), three equivalent Co(1), and three equivalent Co(2) atoms. In the third Co site, Co(1) is bonded to two equivalent Sm(2), three equivalent Sm(1), one Co(3), one Co(4), one Co(7), and four equivalent Co(1) atoms to form distorted CoSm5Co7 cuboctahedra that share corners with two equivalent Co(7)Sm6Co6 cuboctahedra, corners with six equivalent Co(2)Sm4Co8 cuboctahedra, corners with nine equivalent Co(1)Sm5Co7 cuboctahedra, edges with four equivalent Co(2)Sm4Co8 cuboctahedra, edges with four equivalent Co(1)Sm5Co7 cuboctahedra,  a faceface with one Co(2)Sm4Co8 cuboctahedra, faces with three equivalent Co(7)Sm6Co6 cuboctahedra, and faces with ten equivalent Co(1)Sm5Co7 cuboctahedra. In the fourth Co site, Co(5,6) is bonded in a 9-coordinate geometry to three equivalent Sm(3) and six equivalent Co(2) atoms. In the fifth Co site, Co(7) is bonded to six equivalent Sm(1) and six equivalent Co(1) atoms to form CoSm6Co6 cuboctahedra that share corners with twelve equivalent Co(1)Sm5Co7 cuboctahedra, edges with six equivalent Co(7)Sm6Co6 cuboctahedra, and faces with eighteen equivalent Co(1)Sm5Co7 cuboctahedra. In the sixth Co site, Co(2) is bonded to two equivalent Sm(2); two equivalent Sm(3); one Co(3); one Co(4); two equivalent Co(5,6); and four equivalent Co(2) atoms to form CoSm4Co8 cuboctahedra that share corners with six equivalent Co(1)Sm5Co7 cuboctahedra, corners with ten equivalent Co(2)Sm4Co8 cuboctahedra, edges with four equivalent Co(1)Sm5Co7 cuboctahedra, edges with six equivalent Co(2)Sm4Co8 cuboctahedra,  a faceface with one Co(1)Sm5Co7 cuboctahedra, and faces with nine equivalent Co(2)Sm4Co8 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sm5Co19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.990
_cell_length_b   4.990
_cell_length_c   31.911
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   688.195
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.333  0.667  0.979  1.0
  Sm  Sm1  1  0.667  0.333  0.021  1.0
  Sm  Sm2  1  0.667  0.333  0.479  1.0
  Sm  Sm3  1  0.333  0.667  0.521  1.0
  Sm  Sm4  1  0.333  0.667  0.869  1.0
  Sm  Sm5  1  0.667  0.333  0.131  1.0
  Sm  Sm6  1  0.667  0.333  0.369  1.0
  Sm  Sm7  1  0.333  0.667  0.631  1.0
  Sm  Sm8  1  0.333  0.667  0.750  1.0
  Sm  Sm9  1  0.667  0.333  0.250  1.0
  Co  Co10  1  0.166  0.834  0.434  1.0
  Co  Co11  1  0.166  0.331  0.434  1.0
  Co  Co12  1  0.669  0.834  0.434  1.0
  Co  Co13  1  0.834  0.166  0.566  1.0
  Co  Co14  1  0.834  0.669  0.566  1.0
  Co  Co15  1  0.331  0.166  0.566  1.0
  Co  Co16  1  0.834  0.166  0.934  1.0
  Co  Co17  1  0.834  0.669  0.934  1.0
  Co  Co18  1  0.331  0.166  0.934  1.0
  Co  Co19  1  0.166  0.834  0.066  1.0
  Co  Co20  1  0.166  0.331  0.066  1.0
  Co  Co21  1  0.669  0.834  0.066  1.0
  Co  Co22  1  0.166  0.834  0.312  1.0
  Co  Co23  1  0.166  0.333  0.312  1.0
  Co  Co24  1  0.667  0.834  0.312  1.0
  Co  Co25  1  0.834  0.166  0.688  1.0
  Co  Co26  1  0.834  0.667  0.688  1.0
  Co  Co27  1  0.333  0.166  0.688  1.0
  Co  Co28  1  0.834  0.166  0.812  1.0
  Co  Co29  1  0.834  0.667  0.812  1.0
  Co  Co30  1  0.333  0.166  0.812  1.0
  Co  Co31  1  0.166  0.834  0.188  1.0
  Co  Co32  1  0.166  0.333  0.188  1.0
  Co  Co33  1  0.667  0.834  0.188  1.0
  Co  Co34  1  0.333  0.667  0.374  1.0
  Co  Co35  1  0.667  0.333  0.626  1.0
  Co  Co36  1  0.667  0.333  0.874  1.0
  Co  Co37  1  0.333  0.667  0.126  1.0
  Co  Co38  1  0.000  0.000  0.374  1.0
  Co  Co39  1  0.000  0.000  0.626  1.0
  Co  Co40  1  0.000  0.000  0.874  1.0
  Co  Co41  1  0.000  0.000  0.126  1.0
  Co  Co42  1  0.333  0.667  0.250  1.0
  Co  Co43  1  0.667  0.333  0.750  1.0
  Co  Co44  1  0.000  0.000  0.250  1.0
  Co  Co45  1  0.000  0.000  0.750  1.0
  Co  Co46  1  0.000  0.000  0.500  1.0
  Co  Co47  1  0.000  0.000  0.000  1.0
[/CIF]
.
The crystal structure described by Sm5Co19 crystallizes in the hexagonal P6_3/mmc space group. There are three inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 12-coordinate geometry to three equivalent Co(7) and nine equivalent Co(1) atoms. In the second Sm site, Sm(2) is bonded in a 18-coordinate geometry to three equivalent Co(3), three equivalent Co(4), six equivalent Co(1), and six equivalent Co(2) atoms. In the third Sm site, Sm(3) is bonded in a 18-coordinate geometry to six equivalent Co(5,6) and twelve equivalent Co(2) atoms. There are six inequivalent Co sites. In the first Co site, Co(3) is bonded in a 9-coordinate geometry to three equivalent Sm(2), three equivalent Co(1), and three equivalent Co(2) atoms. In the second Co site, Co(4) is bonded in a 9-coordinate geometry to three equivalent Sm(2), three equivalent Co(1), and three equivalent Co(2) atoms. In the third Co site, Co(1) is bonded to two equivalent Sm(2), three equivalent Sm(1), one Co(3), one Co(4), one Co(7), and four equivalent Co(1) atoms to form distorted CoSm5Co7 cuboctahedra that share corners with two equivalent Co(7)Sm6Co6 cuboctahedra, corners with six equivalent Co(2)Sm4Co8 cuboctahedra, corners with nine equivalent Co(1)Sm5Co7 cuboctahedra, edges with four equivalent Co(2)Sm4Co8 cuboctahedra, edges with four equivalent Co(1)Sm5Co7 cuboctahedra,  a faceface with one Co(2)Sm4Co8 cuboctahedra, faces with three equivalent Co(7)Sm6Co6 cuboctahedra, and faces with ten equivalent Co(1)Sm5Co7 cuboctahedra. In the fourth Co site, Co(5,6) is bonded in a 9-coordinate geometry to three equivalent Sm(3) and six equivalent Co(2) atoms. In the fifth Co site, Co(7) is bonded to six equivalent Sm(1) and six equivalent Co(1) atoms to form CoSm6Co6 cuboctahedra that share corners with twelve equivalent Co(1)Sm5Co7 cuboctahedra, edges with six equivalent Co(7)Sm6Co6 cuboctahedra, and faces with eighteen equivalent Co(1)Sm5Co7 cuboctahedra. In the sixth Co site, Co(2) is bonded to two equivalent Sm(2); two equivalent Sm(3); one Co(3); one Co(4); two equivalent Co(5,6); and four equivalent Co(2) atoms to form CoSm4Co8 cuboctahedra that share corners with six equivalent Co(1)Sm5Co7 cuboctahedra, corners with ten equivalent Co(2)Sm4Co8 cuboctahedra, edges with four equivalent Co(1)Sm5Co7 cuboctahedra, edges with six equivalent Co(2)Sm4Co8 cuboctahedra,  a faceface with one Co(1)Sm5Co7 cuboctahedra, and faces with nine equivalent Co(2)Sm4Co8 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sm5Co19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.990
_cell_length_b   4.990
_cell_length_c   31.911
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   688.195
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.333  0.667  0.979  1.0
  Sm  Sm1  1  0.667  0.333  0.021  1.0
  Sm  Sm2  1  0.667  0.333  0.479  1.0
  Sm  Sm3  1  0.333  0.667  0.521  1.0
  Sm  Sm4  1  0.333  0.667  0.869  1.0
  Sm  Sm5  1  0.667  0.333  0.131  1.0
  Sm  Sm6  1  0.667  0.333  0.369  1.0
  Sm  Sm7  1  0.333  0.667  0.631  1.0
  Sm  Sm8  1  0.333  0.667  0.750  1.0
  Sm  Sm9  1  0.667  0.333  0.250  1.0
  Co  Co10  1  0.166  0.834  0.434  1.0
  Co  Co11  1  0.166  0.331  0.434  1.0
  Co  Co12  1  0.669  0.834  0.434  1.0
  Co  Co13  1  0.834  0.166  0.566  1.0
  Co  Co14  1  0.834  0.669  0.566  1.0
  Co  Co15  1  0.331  0.166  0.566  1.0
  Co  Co16  1  0.834  0.166  0.934  1.0
  Co  Co17  1  0.834  0.669  0.934  1.0
  Co  Co18  1  0.331  0.166  0.934  1.0
  Co  Co19  1  0.166  0.834  0.066  1.0
  Co  Co20  1  0.166  0.331  0.066  1.0
  Co  Co21  1  0.669  0.834  0.066  1.0
  Co  Co22  1  0.166  0.834  0.312  1.0
  Co  Co23  1  0.166  0.333  0.312  1.0
  Co  Co24  1  0.667  0.834  0.312  1.0
  Co  Co25  1  0.834  0.166  0.688  1.0
  Co  Co26  1  0.834  0.667  0.688  1.0
  Co  Co27  1  0.333  0.166  0.688  1.0
  Co  Co28  1  0.834  0.166  0.812  1.0
  Co  Co29  1  0.834  0.667  0.812  1.0
  Co  Co30  1  0.333  0.166  0.812  1.0
  Co  Co31  1  0.166  0.834  0.188  1.0
  Co  Co32  1  0.166  0.333  0.188  1.0
  Co  Co33  1  0.667  0.834  0.188  1.0
  Co  Co34  1  0.333  0.667  0.374  1.0
  Co  Co35  1  0.667  0.333  0.626  1.0
  Co  Co36  1  0.667  0.333  0.874  1.0
  Co  Co37  1  0.333  0.667  0.126  1.0
  Co  Co38  1  0.000  0.000  0.374  1.0
  Co  Co39  1  0.000  0.000  0.626  1.0
  Co  Co40  1  0.000  0.000  0.874  1.0
  Co  Co41  1  0.000  0.000  0.126  1.0
  Co  Co42  1  0.333  0.667  0.250  1.0
  Co  Co43  1  0.667  0.333  0.750  1.0
  Co  Co44  1  0.000  0.000  0.250  1.0
  Co  Co45  1  0.000  0.000  0.750  1.0
  Co  Co46  1  0.000  0.000  0.500  1.0
  Co  Co47  1  0.000  0.000  0.000  1.0
[/CIF]
.