The compound described by Rh2Au(N5Cl3)2AuCl4Cl2O is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two chlorine monoxide molecules, two AuCl4 clusters, and two Rh2Au(N5Cl3)2 clusters. In each AuCl4 cluster, Au(2) is bonded in a square co-planar geometry to two equivalent Cl(1) and two equivalent Cl(5) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(2) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Au(2) atom. In each Rh2Au(N5Cl3)2 cluster, Rh(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. Au(1) is bonded in a square co-planar geometry to one Cl(3), one Cl(4), and two equivalent Cl(7) atoms. There are five inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Rh(1) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(7) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(7) is bonded in a distorted water-like geometry to one Au(1) and one N(5) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_Rh2Au2N10Cl12O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.479
_cell_length_b   8.415
_cell_length_c   11.592
_cell_angle_alpha   93.990
_cell_angle_beta   90.000
_cell_angle_gamma   59.751
_symmetry_Int_Tables_number   1
_cell_volume   712.181
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.737  0.519  0.794  1.0
  Rh  Rh1  1  0.255  0.481  0.206  1.0
  Au  Au2  1  0.015  0.000  0.000  1.0
  Au  Au3  1  0.499  0.000  0.500  1.0
  N  N4  1  0.566  0.616  0.697  1.0
  N  N5  1  0.875  0.636  0.764  1.0
  N  N6  1  0.510  0.364  0.236  1.0
  N  N7  1  0.181  0.384  0.303  1.0
  N  N8  1  0.637  0.603  0.951  1.0
  N  N9  1  0.240  0.397  0.049  1.0
  N  N10  1  0.631  0.325  0.807  1.0
  N  N11  1  0.970  0.285  0.781  1.0
  N  N12  1  0.255  0.715  0.219  1.0
  N  N13  1  0.957  0.675  0.193  1.0
  Cl  Cl14  1  0.652  0.681  0.495  1.0
  Cl  Cl15  1  0.333  0.319  0.505  1.0
  Cl  Cl16  1  0.772  0.549  0.059  1.0
  Cl  Cl17  1  0.322  0.451  0.941  1.0
  Cl  Cl18  1  0.286  0.000  0.000  1.0
  Cl  Cl19  1  0.746  0.000  0.000  1.0
  Cl  Cl20  1  0.507  0.987  0.300  1.0
  Cl  Cl21  1  0.495  0.013  0.700  1.0
  Cl  Cl22  1  0.893  0.193  0.479  1.0
  Cl  Cl23  1  0.085  0.807  0.521  1.0
  Cl  Cl24  1  0.082  0.919  0.236  1.0
  Cl  Cl25  1  0.001  0.081  0.764  1.0
  O  O26  1  0.878  0.000  0.500  1.0
[/CIF]
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The compound described by Rh2Au(N5Cl3)2AuCl4Cl2O is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two chlorine monoxide molecules, two AuCl4 clusters, and two Rh2Au(N5Cl3)2 clusters. In each AuCl4 cluster, Au(2) is bonded in a square co-planar geometry to two equivalent Cl(1) and two equivalent Cl(5) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(2) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Au(2) atom. In each Rh2Au(N5Cl3)2 cluster, Rh(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. Au(1) is bonded in a square co-planar geometry to one Cl(3), one Cl(4), and two equivalent Cl(7) atoms. There are five inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Rh(1) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(7) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(7) is bonded in a distorted water-like geometry to one Au(1) and one N(5) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_Rh2Au2N10Cl12O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.479
_cell_length_b   8.415
_cell_length_c   11.592
_cell_angle_alpha   93.990
_cell_angle_beta   90.000
_cell_angle_gamma   59.751
_symmetry_Int_Tables_number   1
_cell_volume   712.181
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.737  0.519  0.794  1.0
  Rh  Rh1  1  0.255  0.481  0.206  1.0
  Au  Au2  1  0.015  0.000  0.000  1.0
  Au  Au3  1  0.499  0.000  0.500  1.0
  N  N4  1  0.566  0.616  0.697  1.0
  N  N5  1  0.875  0.636  0.764  1.0
  N  N6  1  0.510  0.364  0.236  1.0
  N  N7  1  0.181  0.384  0.303  1.0
  N  N8  1  0.637  0.603  0.951  1.0
  N  N9  1  0.240  0.397  0.049  1.0
  N  N10  1  0.631  0.325  0.807  1.0
  N  N11  1  0.970  0.285  0.781  1.0
  N  N12  1  0.255  0.715  0.219  1.0
  N  N13  1  0.957  0.675  0.193  1.0
  Cl  Cl14  1  0.652  0.681  0.495  1.0
  Cl  Cl15  1  0.333  0.319  0.505  1.0
  Cl  Cl16  1  0.772  0.549  0.059  1.0
  Cl  Cl17  1  0.322  0.451  0.941  1.0
  Cl  Cl18  1  0.286  0.000  0.000  1.0
  Cl  Cl19  1  0.746  0.000  0.000  1.0
  Cl  Cl20  1  0.507  0.987  0.300  1.0
  Cl  Cl21  1  0.495  0.013  0.700  1.0
  Cl  Cl22  1  0.893  0.193  0.479  1.0
  Cl  Cl23  1  0.085  0.807  0.521  1.0
  Cl  Cl24  1  0.082  0.919  0.236  1.0
  Cl  Cl25  1  0.001  0.081  0.764  1.0
  O  O26  1  0.878  0.000  0.500  1.0
[/CIF]
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