The crystal structure described by AsF6OClF2 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four OClF2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each OClF2 cluster, O(1) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one F(7), and one F(8) atom. There are two inequivalent F sites. In the first F site, F(8) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(7) is bonded in a single-bond geometry to one Cl(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsClOF8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.376
_cell_length_b   8.295
_cell_length_c   15.039
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   670.614
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.388  0.942  0.402  1.0
  As  As1  1  0.612  0.442  0.598  1.0
  As  As2  1  0.888  0.442  0.098  1.0
  As  As3  1  0.112  0.942  0.902  1.0
  Cl  Cl4  1  0.126  0.488  0.387  1.0
  Cl  Cl5  1  0.874  0.988  0.613  1.0
  Cl  Cl6  1  0.626  0.988  0.113  1.0
  Cl  Cl7  1  0.374  0.488  0.887  1.0
  O  O8  1  0.338  0.472  0.334  1.0
  O  O9  1  0.662  0.972  0.666  1.0
  O  O10  1  0.838  0.972  0.166  1.0
  O  O11  1  0.162  0.472  0.834  1.0
  F  F12  1  0.123  0.978  0.337  1.0
  F  F13  1  0.877  0.478  0.663  1.0
  F  F14  1  0.623  0.478  0.163  1.0
  F  F15  1  0.377  0.978  0.837  1.0
  F  F16  1  0.529  0.833  0.315  1.0
  F  F17  1  0.471  0.333  0.685  1.0
  F  F18  1  0.029  0.333  0.185  1.0
  F  F19  1  0.971  0.833  0.815  1.0
  F  F20  1  0.526  0.123  0.367  1.0
  F  F21  1  0.474  0.623  0.633  1.0
  F  F22  1  0.026  0.623  0.133  1.0
  F  F23  1  0.974  0.123  0.867  1.0
  F  F24  1  0.249  0.756  0.441  1.0
  F  F25  1  0.751  0.256  0.559  1.0
  F  F26  1  0.749  0.256  0.059  1.0
  F  F27  1  0.251  0.756  0.941  1.0
  F  F28  1  0.247  0.041  0.494  1.0
  F  F29  1  0.753  0.541  0.506  1.0
  F  F30  1  0.747  0.541  0.006  1.0
  F  F31  1  0.253  0.041  0.994  1.0
  F  F32  1  0.654  0.900  0.471  1.0
  F  F33  1  0.346  0.400  0.529  1.0
  F  F34  1  0.154  0.400  0.029  1.0
  F  F35  1  0.846  0.900  0.971  1.0
  F  F36  1  0.916  0.581  0.327  1.0
  F  F37  1  0.084  0.081  0.673  1.0
  F  F38  1  0.416  0.081  0.173  1.0
  F  F39  1  0.584  0.581  0.827  1.0
  F  F40  1  0.981  0.315  0.380  1.0
  F  F41  1  0.019  0.815  0.620  1.0
  F  F42  1  0.481  0.815  0.120  1.0
  F  F43  1  0.519  0.315  0.880  1.0
[/CIF]
.
The crystal structure described by AsF6OClF2 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four OClF2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each OClF2 cluster, O(1) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one F(7), and one F(8) atom. There are two inequivalent F sites. In the first F site, F(8) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(7) is bonded in a single-bond geometry to one Cl(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsClOF8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.376
_cell_length_b   8.295
_cell_length_c   15.039
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   670.614
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.388  0.942  0.402  1.0
  As  As1  1  0.612  0.442  0.598  1.0
  As  As2  1  0.888  0.442  0.098  1.0
  As  As3  1  0.112  0.942  0.902  1.0
  Cl  Cl4  1  0.126  0.488  0.387  1.0
  Cl  Cl5  1  0.874  0.988  0.613  1.0
  Cl  Cl6  1  0.626  0.988  0.113  1.0
  Cl  Cl7  1  0.374  0.488  0.887  1.0
  O  O8  1  0.338  0.472  0.334  1.0
  O  O9  1  0.662  0.972  0.666  1.0
  O  O10  1  0.838  0.972  0.166  1.0
  O  O11  1  0.162  0.472  0.834  1.0
  F  F12  1  0.123  0.978  0.337  1.0
  F  F13  1  0.877  0.478  0.663  1.0
  F  F14  1  0.623  0.478  0.163  1.0
  F  F15  1  0.377  0.978  0.837  1.0
  F  F16  1  0.529  0.833  0.315  1.0
  F  F17  1  0.471  0.333  0.685  1.0
  F  F18  1  0.029  0.333  0.185  1.0
  F  F19  1  0.971  0.833  0.815  1.0
  F  F20  1  0.526  0.123  0.367  1.0
  F  F21  1  0.474  0.623  0.633  1.0
  F  F22  1  0.026  0.623  0.133  1.0
  F  F23  1  0.974  0.123  0.867  1.0
  F  F24  1  0.249  0.756  0.441  1.0
  F  F25  1  0.751  0.256  0.559  1.0
  F  F26  1  0.749  0.256  0.059  1.0
  F  F27  1  0.251  0.756  0.941  1.0
  F  F28  1  0.247  0.041  0.494  1.0
  F  F29  1  0.753  0.541  0.506  1.0
  F  F30  1  0.747  0.541  0.006  1.0
  F  F31  1  0.253  0.041  0.994  1.0
  F  F32  1  0.654  0.900  0.471  1.0
  F  F33  1  0.346  0.400  0.529  1.0
  F  F34  1  0.154  0.400  0.029  1.0
  F  F35  1  0.846  0.900  0.971  1.0
  F  F36  1  0.916  0.581  0.327  1.0
  F  F37  1  0.084  0.081  0.673  1.0
  F  F38  1  0.416  0.081  0.173  1.0
  F  F39  1  0.584  0.581  0.827  1.0
  F  F40  1  0.981  0.315  0.380  1.0
  F  F41  1  0.019  0.815  0.620  1.0
  F  F42  1  0.481  0.815  0.120  1.0
  F  F43  1  0.519  0.315  0.880  1.0
[/CIF]
.