The compound described by Li3V4O11F crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(4), one O(5), one O(6), and one O(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(3), one O(8), one O(9), and one F(1) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(10), one O(4), one O(5), one O(6), and one O(7) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(4), one O(7), one O(9), and one F(1) atom. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(3), one O(5), one O(6), and one O(8) atom. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(7), one O(9), and one F(1) atom. In the fourth V site, V(4) is bonded in a distorted octahedral geometry to one O(10), one O(11), one O(3), one O(5), one O(6), and one O(8) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one V(3) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one V(1) and one V(3) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one V(2), and one V(4) atom. In the fourth O site, O(4) is bonded in a tetrahedral geometry to one Li(1), one Li(3), one V(1), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one V(2), and one V(4) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(3), one V(2), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one V(1), and one V(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(2), one V(2), and one V(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one V(1), and one V(3) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one V(2), and one V(4) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Li(2), one V(2), and one V(4) atom. F(1) is bonded in a T-shaped geometry to one Li(2), one V(1), and one V(3) atom. is represented by the CIF card [CIF]
data_Li3V4O11F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.991
_cell_length_b   4.991
_cell_length_c   10.018
_cell_angle_alpha   90.506
_cell_angle_beta   97.979
_cell_angle_gamma   117.467
_symmetry_Int_Tables_number   1
_cell_volume   218.528
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.457  0.492  0.983  1.0
  Li  Li1  1  0.777  0.898  0.524  1.0
  Li  Li2  1  0.127  0.902  0.975  1.0
  V  V3  1  0.558  0.115  0.235  1.0
  V  V4  1  0.752  0.492  0.723  1.0
  V  V5  1  0.193  0.467  0.264  1.0
  V  V6  1  0.428  0.840  0.776  1.0
  O  O7  1  0.947  0.201  0.358  1.0
  O  O8  1  0.892  0.460  0.152  1.0
  O  O9  1  0.676  0.135  0.651  1.0
  O  O10  1  0.273  0.214  0.144  1.0
  O  O11  1  0.475  0.170  0.864  1.0
  O  O12  1  0.734  0.781  0.867  1.0
  O  O13  1  0.511  0.838  0.125  1.0
  O  O14  1  0.450  0.544  0.640  1.0
  O  O15  1  0.347  0.849  0.353  1.0
  O  O16  1  0.134  0.568  0.863  1.0
  O  O17  1  0.044  0.759  0.642  1.0
  F  F18  1  0.583  0.481  0.360  1.0
[/CIF]
.
The compound described by Li3V4O11F crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(4), one O(5), one O(6), and one O(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(3), one O(8), one O(9), and one F(1) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(10), one O(4), one O(5), one O(6), and one O(7) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(4), one O(7), one O(9), and one F(1) atom. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(3), one O(5), one O(6), and one O(8) atom. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(7), one O(9), and one F(1) atom. In the fourth V site, V(4) is bonded in a distorted octahedral geometry to one O(10), one O(11), one O(3), one O(5), one O(6), and one O(8) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one V(3) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one V(1) and one V(3) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one V(2), and one V(4) atom. In the fourth O site, O(4) is bonded in a tetrahedral geometry to one Li(1), one Li(3), one V(1), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one V(2), and one V(4) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(3), one V(2), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one V(1), and one V(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(2), one V(2), and one V(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one V(1), and one V(3) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one V(2), and one V(4) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Li(2), one V(2), and one V(4) atom. F(1) is bonded in a T-shaped geometry to one Li(2), one V(1), and one V(3) atom. is represented by the CIF card [CIF]
data_Li3V4O11F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.991
_cell_length_b   4.991
_cell_length_c   10.018
_cell_angle_alpha   90.506
_cell_angle_beta   97.979
_cell_angle_gamma   117.467
_symmetry_Int_Tables_number   1
_cell_volume   218.528
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.457  0.492  0.983  1.0
  Li  Li1  1  0.777  0.898  0.524  1.0
  Li  Li2  1  0.127  0.902  0.975  1.0
  V  V3  1  0.558  0.115  0.235  1.0
  V  V4  1  0.752  0.492  0.723  1.0
  V  V5  1  0.193  0.467  0.264  1.0
  V  V6  1  0.428  0.840  0.776  1.0
  O  O7  1  0.947  0.201  0.358  1.0
  O  O8  1  0.892  0.460  0.152  1.0
  O  O9  1  0.676  0.135  0.651  1.0
  O  O10  1  0.273  0.214  0.144  1.0
  O  O11  1  0.475  0.170  0.864  1.0
  O  O12  1  0.734  0.781  0.867  1.0
  O  O13  1  0.511  0.838  0.125  1.0
  O  O14  1  0.450  0.544  0.640  1.0
  O  O15  1  0.347  0.849  0.353  1.0
  O  O16  1  0.134  0.568  0.863  1.0
  O  O17  1  0.044  0.759  0.642  1.0
  F  F18  1  0.583  0.481  0.360  1.0
[/CIF]
.