The compound described by AgPbO2 crystallizes in the monoclinic C2/m space group. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form edge-sharing PbO6 octahedra. In the second Pb site, Pb(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form edge-sharing PbO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Pb(2), and two equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing OAgPb3 tetrahedra. In the second O site, O(2) is bonded to one Ag(1), one Pb(1), and two equivalent Pb(2) atoms to form a mixture of distorted corner and edge-sharing OAgPb3 tetrahedra. is represented by the CIF file [CIF]
data_AgPbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.758
_cell_length_b   6.758
_cell_length_c   6.501
_cell_angle_alpha   81.887
_cell_angle_beta   81.887
_cell_angle_gamma   30.546
_symmetry_Int_Tables_number   1
_cell_volume   149.279
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.750  0.750  0.195  1.0
  Ag  Ag1  1  0.250  0.250  0.805  1.0
  Pb  Pb2  1  0.500  0.500  0.000  1.0
  Pb  Pb3  1  0.000  0.000  0.500  1.0
  O  O4  1  0.912  0.912  0.170  1.0
  O  O5  1  0.412  0.412  0.738  1.0
  O  O6  1  0.588  0.588  0.262  1.0
  O  O7  1  0.088  0.088  0.830  1.0
[/CIF]
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The compound described by AgPbO2 crystallizes in the monoclinic C2/m space group. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form edge-sharing PbO6 octahedra. In the second Pb site, Pb(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form edge-sharing PbO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Pb(2), and two equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing OAgPb3 tetrahedra. In the second O site, O(2) is bonded to one Ag(1), one Pb(1), and two equivalent Pb(2) atoms to form a mixture of distorted corner and edge-sharing OAgPb3 tetrahedra. is represented by the CIF file [CIF]
data_AgPbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.758
_cell_length_b   6.758
_cell_length_c   6.501
_cell_angle_alpha   81.887
_cell_angle_beta   81.887
_cell_angle_gamma   30.546
_symmetry_Int_Tables_number   1
_cell_volume   149.279
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.750  0.750  0.195  1.0
  Ag  Ag1  1  0.250  0.250  0.805  1.0
  Pb  Pb2  1  0.500  0.500  0.000  1.0
  Pb  Pb3  1  0.000  0.000  0.500  1.0
  O  O4  1  0.912  0.912  0.170  1.0
  O  O5  1  0.412  0.412  0.738  1.0
  O  O6  1  0.588  0.588  0.262  1.0
  O  O7  1  0.088  0.088  0.830  1.0
[/CIF]
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