The compound described by MnOF2 crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded to one O(1), two equivalent F(1), and two equivalent F(2) atoms to form corner-sharing MnOF4 trigonal bipyramids. O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.116
_cell_length_b   6.771
_cell_length_c   7.915
_cell_angle_alpha   70.499
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   258.471
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.933  0.350  0.326  1.0
  Mn  Mn1  1  0.567  0.850  0.326  1.0
  Mn  Mn2  1  0.433  0.150  0.674  1.0
  Mn  Mn3  1  0.067  0.650  0.674  1.0
  O  O4  1  0.413  0.974  0.062  1.0
  O  O5  1  0.087  0.474  0.062  1.0
  O  O6  1  0.913  0.526  0.938  1.0
  O  O7  1  0.587  0.026  0.938  1.0
  F  F8  1  0.788  0.107  0.260  1.0
  F  F9  1  0.712  0.607  0.260  1.0
  F  F10  1  0.292  0.245  0.419  1.0
  F  F11  1  0.208  0.745  0.419  1.0
  F  F12  1  0.792  0.255  0.581  1.0
  F  F13  1  0.708  0.755  0.581  1.0
  F  F14  1  0.288  0.393  0.740  1.0
  F  F15  1  0.212  0.893  0.740  1.0
[/CIF]
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The compound described by MnOF2 crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded to one O(1), two equivalent F(1), and two equivalent F(2) atoms to form corner-sharing MnOF4 trigonal bipyramids. O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.116
_cell_length_b   6.771
_cell_length_c   7.915
_cell_angle_alpha   70.499
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   258.471
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.933  0.350  0.326  1.0
  Mn  Mn1  1  0.567  0.850  0.326  1.0
  Mn  Mn2  1  0.433  0.150  0.674  1.0
  Mn  Mn3  1  0.067  0.650  0.674  1.0
  O  O4  1  0.413  0.974  0.062  1.0
  O  O5  1  0.087  0.474  0.062  1.0
  O  O6  1  0.913  0.526  0.938  1.0
  O  O7  1  0.587  0.026  0.938  1.0
  F  F8  1  0.788  0.107  0.260  1.0
  F  F9  1  0.712  0.607  0.260  1.0
  F  F10  1  0.292  0.245  0.419  1.0
  F  F11  1  0.208  0.745  0.419  1.0
  F  F12  1  0.792  0.255  0.581  1.0
  F  F13  1  0.708  0.755  0.581  1.0
  F  F14  1  0.288  0.393  0.740  1.0
  F  F15  1  0.212  0.893  0.740  1.0
[/CIF]
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