The structure described by Rh7Zn5B3 crystallizes in the orthorhombic Pmma space group. There are five inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted body-centered cubic geometry to four equivalent Zn(3) and four equivalent B(2) atoms. In the second Rh site, Rh(2) is bonded in a 10-coordinate geometry to four equivalent Zn(2), four equivalent Zn(3), and two equivalent B(1) atoms. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to four equivalent Zn(3) and four equivalent B(2) atoms. In the fourth Rh site, Rh(4) is bonded in a distorted body-centered cubic geometry to two equivalent Zn(1), four equivalent Zn(2), and two equivalent B(1) atoms. In the fifth Rh site, Rh(5) is bonded in a 8-coordinate geometry to two equivalent Zn(1), two equivalent Zn(2), two equivalent Zn(3), and two equivalent B(2) atoms. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 8-coordinate geometry to four equivalent Rh(4), four equivalent Rh(5), and one B(1) atom. In the second Zn site, Zn(2) is bonded in a 9-coordinate geometry to two equivalent Rh(2), two equivalent Rh(5), four equivalent Rh(4), and one B(1) atom. In the third Zn site, Zn(3) is bonded in a 8-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), two equivalent Rh(3), and two equivalent Rh(5) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to two equivalent Rh(2), four equivalent Rh(4), one Zn(1), and two equivalent Zn(2) atoms. In the second B site, B(2) is bonded in a 6-coordinate geometry to two equivalent Rh(1), two equivalent Rh(3), and two equivalent Rh(5) atoms. is represented by the CIF card [CIF]
data_Zn5B3Rh7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.837
_cell_length_b   11.016
_cell_length_c   11.695
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   365.552
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.250  0.812  1.0
  Zn  Zn1  1  0.500  0.750  0.188  1.0
  Zn  Zn2  1  0.500  0.951  0.866  1.0
  Zn  Zn3  1  0.500  0.049  0.134  1.0
  Zn  Zn4  1  0.500  0.451  0.134  1.0
  Zn  Zn5  1  0.500  0.549  0.866  1.0
  Zn  Zn6  1  0.500  0.870  0.652  1.0
  Zn  Zn7  1  0.500  0.130  0.348  1.0
  Zn  Zn8  1  0.500  0.370  0.348  1.0
  Zn  Zn9  1  0.500  0.630  0.652  1.0
  B  B10  1  0.500  0.250  0.039  1.0
  B  B11  1  0.500  0.750  0.961  1.0
  B  B12  1  0.500  0.383  0.594  1.0
  B  B13  1  0.500  0.617  0.406  1.0
  B  B14  1  0.500  0.883  0.406  1.0
  B  B15  1  0.500  0.117  0.594  1.0
  Rh  Rh16  1  0.000  0.500  0.500  1.0
  Rh  Rh17  1  0.000  0.000  0.500  1.0
  Rh  Rh18  1  0.000  0.250  0.183  1.0
  Rh  Rh19  1  0.000  0.750  0.817  1.0
  Rh  Rh20  1  0.000  0.250  0.525  1.0
  Rh  Rh21  1  0.000  0.750  0.475  1.0
  Rh  Rh22  1  0.000  0.374  0.963  1.0
  Rh  Rh23  1  0.000  0.626  0.037  1.0
  Rh  Rh24  1  0.000  0.874  0.037  1.0
  Rh  Rh25  1  0.000  0.126  0.963  1.0
  Rh  Rh26  1  0.000  0.422  0.721  1.0
  Rh  Rh27  1  0.000  0.578  0.279  1.0
  Rh  Rh28  1  0.000  0.922  0.279  1.0
  Rh  Rh29  1  0.000  0.078  0.721  1.0
[/CIF]
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The structure described by Rh7Zn5B3 crystallizes in the orthorhombic Pmma space group. There are five inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted body-centered cubic geometry to four equivalent Zn(3) and four equivalent B(2) atoms. In the second Rh site, Rh(2) is bonded in a 10-coordinate geometry to four equivalent Zn(2), four equivalent Zn(3), and two equivalent B(1) atoms. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to four equivalent Zn(3) and four equivalent B(2) atoms. In the fourth Rh site, Rh(4) is bonded in a distorted body-centered cubic geometry to two equivalent Zn(1), four equivalent Zn(2), and two equivalent B(1) atoms. In the fifth Rh site, Rh(5) is bonded in a 8-coordinate geometry to two equivalent Zn(1), two equivalent Zn(2), two equivalent Zn(3), and two equivalent B(2) atoms. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 8-coordinate geometry to four equivalent Rh(4), four equivalent Rh(5), and one B(1) atom. In the second Zn site, Zn(2) is bonded in a 9-coordinate geometry to two equivalent Rh(2), two equivalent Rh(5), four equivalent Rh(4), and one B(1) atom. In the third Zn site, Zn(3) is bonded in a 8-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), two equivalent Rh(3), and two equivalent Rh(5) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to two equivalent Rh(2), four equivalent Rh(4), one Zn(1), and two equivalent Zn(2) atoms. In the second B site, B(2) is bonded in a 6-coordinate geometry to two equivalent Rh(1), two equivalent Rh(3), and two equivalent Rh(5) atoms. is represented by the CIF card [CIF]
data_Zn5B3Rh7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.837
_cell_length_b   11.016
_cell_length_c   11.695
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   365.552
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.250  0.812  1.0
  Zn  Zn1  1  0.500  0.750  0.188  1.0
  Zn  Zn2  1  0.500  0.951  0.866  1.0
  Zn  Zn3  1  0.500  0.049  0.134  1.0
  Zn  Zn4  1  0.500  0.451  0.134  1.0
  Zn  Zn5  1  0.500  0.549  0.866  1.0
  Zn  Zn6  1  0.500  0.870  0.652  1.0
  Zn  Zn7  1  0.500  0.130  0.348  1.0
  Zn  Zn8  1  0.500  0.370  0.348  1.0
  Zn  Zn9  1  0.500  0.630  0.652  1.0
  B  B10  1  0.500  0.250  0.039  1.0
  B  B11  1  0.500  0.750  0.961  1.0
  B  B12  1  0.500  0.383  0.594  1.0
  B  B13  1  0.500  0.617  0.406  1.0
  B  B14  1  0.500  0.883  0.406  1.0
  B  B15  1  0.500  0.117  0.594  1.0
  Rh  Rh16  1  0.000  0.500  0.500  1.0
  Rh  Rh17  1  0.000  0.000  0.500  1.0
  Rh  Rh18  1  0.000  0.250  0.183  1.0
  Rh  Rh19  1  0.000  0.750  0.817  1.0
  Rh  Rh20  1  0.000  0.250  0.525  1.0
  Rh  Rh21  1  0.000  0.750  0.475  1.0
  Rh  Rh22  1  0.000  0.374  0.963  1.0
  Rh  Rh23  1  0.000  0.626  0.037  1.0
  Rh  Rh24  1  0.000  0.874  0.037  1.0
  Rh  Rh25  1  0.000  0.126  0.963  1.0
  Rh  Rh26  1  0.000  0.422  0.721  1.0
  Rh  Rh27  1  0.000  0.578  0.279  1.0
  Rh  Rh28  1  0.000  0.922  0.279  1.0
  Rh  Rh29  1  0.000  0.078  0.721  1.0
[/CIF]
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