The material structure described by CdGe(BiO3)2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded in a 6-coordinate geometry to one O(2), one O(6), two equivalent O(1), and two equivalent O(4) atoms. Ge(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form GeO4 tetrahedra that share corners with three equivalent Bi(2)O5 square pyramids. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(5), and two equivalent O(6) atoms. In the second Bi site, Bi(2) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted BiO5 square pyramids that share corners with three equivalent Ge(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Cd(1), one Bi(1), and one Bi(2) atom to form a mixture of corner and edge-sharing OCd2Bi2 tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one Ge(1), and one Bi(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ge(1), one Bi(1), and one Bi(2) atom. In the fourth O site, O(4) is bonded to two equivalent Cd(1), one Bi(1), and one Bi(2) atom to form a mixture of corner and edge-sharing OCd2Bi2 tetrahedra. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Ge(1), one Bi(1), and one Bi(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Cd(1), one Ge(1), and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdGe(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.703
_cell_length_b   10.365
_cell_length_c   14.754
_cell_angle_alpha   45.909
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   626.434
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.888  0.498  1.0
  Cd  Cd1  1  0.750  0.112  0.002  1.0
  Cd  Cd2  1  0.250  0.888  0.998  1.0
  Cd  Cd3  1  0.750  0.112  0.502  1.0
  Ge  Ge4  1  0.255  0.346  0.002  1.0
  Ge  Ge5  1  0.755  0.654  0.498  1.0
  Ge  Ge6  1  0.245  0.346  0.502  1.0
  Ge  Ge7  1  0.745  0.654  0.998  1.0
  Bi  Bi8  1  0.715  0.157  0.738  1.0
  Bi  Bi9  1  0.785  0.157  0.238  1.0
  Bi  Bi10  1  0.215  0.843  0.762  1.0
  Bi  Bi11  1  0.286  0.364  0.245  1.0
  Bi  Bi12  1  0.714  0.636  0.755  1.0
  Bi  Bi13  1  0.786  0.636  0.255  1.0
  Bi  Bi14  1  0.285  0.843  0.262  1.0
  Bi  Bi15  1  0.214  0.364  0.745  1.0
  O  O16  1  0.512  0.175  0.855  1.0
  O  O17  1  0.488  0.825  0.145  1.0
  O  O18  1  0.043  0.321  0.925  1.0
  O  O19  1  0.874  0.434  0.623  1.0
  O  O20  1  0.126  0.566  0.377  1.0
  O  O21  1  0.011  0.119  0.853  1.0
  O  O22  1  0.874  0.674  0.879  1.0
  O  O23  1  0.012  0.825  0.645  1.0
  O  O24  1  0.374  0.326  0.621  1.0
  O  O25  1  0.626  0.434  0.123  1.0
  O  O26  1  0.524  0.824  0.920  1.0
  O  O27  1  0.626  0.674  0.379  1.0
  O  O28  1  0.374  0.566  0.877  1.0
  O  O29  1  0.543  0.679  0.575  1.0
  O  O30  1  0.989  0.881  0.147  1.0
  O  O31  1  0.976  0.824  0.420  1.0
  O  O32  1  0.957  0.679  0.075  1.0
  O  O33  1  0.126  0.326  0.121  1.0
  O  O34  1  0.988  0.175  0.355  1.0
  O  O35  1  0.024  0.176  0.580  1.0
  O  O36  1  0.457  0.321  0.425  1.0
  O  O37  1  0.476  0.176  0.080  1.0
  O  O38  1  0.489  0.119  0.353  1.0
  O  O39  1  0.511  0.881  0.647  1.0
[/CIF]
.
The material structure described by CdGe(BiO3)2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded in a 6-coordinate geometry to one O(2), one O(6), two equivalent O(1), and two equivalent O(4) atoms. Ge(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form GeO4 tetrahedra that share corners with three equivalent Bi(2)O5 square pyramids. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(5), and two equivalent O(6) atoms. In the second Bi site, Bi(2) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted BiO5 square pyramids that share corners with three equivalent Ge(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Cd(1), one Bi(1), and one Bi(2) atom to form a mixture of corner and edge-sharing OCd2Bi2 tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one Ge(1), and one Bi(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ge(1), one Bi(1), and one Bi(2) atom. In the fourth O site, O(4) is bonded to two equivalent Cd(1), one Bi(1), and one Bi(2) atom to form a mixture of corner and edge-sharing OCd2Bi2 tetrahedra. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Ge(1), one Bi(1), and one Bi(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Cd(1), one Ge(1), and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdGe(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.703
_cell_length_b   10.365
_cell_length_c   14.754
_cell_angle_alpha   45.909
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   626.434
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.888  0.498  1.0
  Cd  Cd1  1  0.750  0.112  0.002  1.0
  Cd  Cd2  1  0.250  0.888  0.998  1.0
  Cd  Cd3  1  0.750  0.112  0.502  1.0
  Ge  Ge4  1  0.255  0.346  0.002  1.0
  Ge  Ge5  1  0.755  0.654  0.498  1.0
  Ge  Ge6  1  0.245  0.346  0.502  1.0
  Ge  Ge7  1  0.745  0.654  0.998  1.0
  Bi  Bi8  1  0.715  0.157  0.738  1.0
  Bi  Bi9  1  0.785  0.157  0.238  1.0
  Bi  Bi10  1  0.215  0.843  0.762  1.0
  Bi  Bi11  1  0.286  0.364  0.245  1.0
  Bi  Bi12  1  0.714  0.636  0.755  1.0
  Bi  Bi13  1  0.786  0.636  0.255  1.0
  Bi  Bi14  1  0.285  0.843  0.262  1.0
  Bi  Bi15  1  0.214  0.364  0.745  1.0
  O  O16  1  0.512  0.175  0.855  1.0
  O  O17  1  0.488  0.825  0.145  1.0
  O  O18  1  0.043  0.321  0.925  1.0
  O  O19  1  0.874  0.434  0.623  1.0
  O  O20  1  0.126  0.566  0.377  1.0
  O  O21  1  0.011  0.119  0.853  1.0
  O  O22  1  0.874  0.674  0.879  1.0
  O  O23  1  0.012  0.825  0.645  1.0
  O  O24  1  0.374  0.326  0.621  1.0
  O  O25  1  0.626  0.434  0.123  1.0
  O  O26  1  0.524  0.824  0.920  1.0
  O  O27  1  0.626  0.674  0.379  1.0
  O  O28  1  0.374  0.566  0.877  1.0
  O  O29  1  0.543  0.679  0.575  1.0
  O  O30  1  0.989  0.881  0.147  1.0
  O  O31  1  0.976  0.824  0.420  1.0
  O  O32  1  0.957  0.679  0.075  1.0
  O  O33  1  0.126  0.326  0.121  1.0
  O  O34  1  0.988  0.175  0.355  1.0
  O  O35  1  0.024  0.176  0.580  1.0
  O  O36  1  0.457  0.321  0.425  1.0
  O  O37  1  0.476  0.176  0.080  1.0
  O  O38  1  0.489  0.119  0.353  1.0
  O  O39  1  0.511  0.881  0.647  1.0
[/CIF]
.