The compound described by MnCl4(H2O)2(NH4)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four ammonium molecules and two MnCl4(H2O)2 clusters. In each MnCl4(H2O)2 cluster, Mn(1) is bonded in an octahedral geometry to one O(2), one O(3), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(6), and one H(7) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Mn(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Mn(1) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Mn(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF file [CIF]
data_MnH12N2(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.807
_cell_length_b   6.810
_cell_length_c   6.811
_cell_angle_alpha   67.401
_cell_angle_beta   76.629
_cell_angle_gamma   112.617
_symmetry_Int_Tables_number   1
_cell_volume   241.021
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.219  0.000  0.263  1.0
  Cl  Cl1  1  0.782  0.519  0.218  1.0
  Cl  Cl2  1  0.263  0.482  0.737  1.0
  Cl  Cl3  1  0.738  0.000  0.782  1.0
  H  H4  1  0.258  0.000  0.594  1.0
  H  H5  1  0.406  1.000  0.742  1.0
  H  H6  1  0.741  0.148  0.258  1.0
  H  H7  1  0.594  0.852  0.406  1.0
  H  H8  1  0.249  0.483  0.408  1.0
  H  H9  1  0.591  0.484  0.750  1.0
  H  H10  1  0.234  0.342  0.249  1.0
  H  H11  1  0.750  0.341  0.766  1.0
  H  H12  1  0.766  0.516  0.892  1.0
  H  H13  1  0.107  0.516  0.234  1.0
  H  H14  1  0.892  0.658  0.591  1.0
  H  H15  1  0.408  0.658  0.108  1.0
  Mn  Mn16  1  0.001  0.000  0.000  1.0
  N  N17  1  0.750  0.500  0.750  1.0
  N  N18  1  0.249  0.500  0.250  1.0
  O  O19  1  0.738  0.000  0.263  1.0
  O  O20  1  0.263  0.000  0.737  1.0
[/CIF]
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The compound described by MnCl4(H2O)2(NH4)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four ammonium molecules and two MnCl4(H2O)2 clusters. In each MnCl4(H2O)2 cluster, Mn(1) is bonded in an octahedral geometry to one O(2), one O(3), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(6), and one H(7) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Mn(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Mn(1) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Mn(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF file [CIF]
data_MnH12N2(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.807
_cell_length_b   6.810
_cell_length_c   6.811
_cell_angle_alpha   67.401
_cell_angle_beta   76.629
_cell_angle_gamma   112.617
_symmetry_Int_Tables_number   1
_cell_volume   241.021
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.219  0.000  0.263  1.0
  Cl  Cl1  1  0.782  0.519  0.218  1.0
  Cl  Cl2  1  0.263  0.482  0.737  1.0
  Cl  Cl3  1  0.738  0.000  0.782  1.0
  H  H4  1  0.258  0.000  0.594  1.0
  H  H5  1  0.406  1.000  0.742  1.0
  H  H6  1  0.741  0.148  0.258  1.0
  H  H7  1  0.594  0.852  0.406  1.0
  H  H8  1  0.249  0.483  0.408  1.0
  H  H9  1  0.591  0.484  0.750  1.0
  H  H10  1  0.234  0.342  0.249  1.0
  H  H11  1  0.750  0.341  0.766  1.0
  H  H12  1  0.766  0.516  0.892  1.0
  H  H13  1  0.107  0.516  0.234  1.0
  H  H14  1  0.892  0.658  0.591  1.0
  H  H15  1  0.408  0.658  0.108  1.0
  Mn  Mn16  1  0.001  0.000  0.000  1.0
  N  N17  1  0.750  0.500  0.750  1.0
  N  N18  1  0.249  0.500  0.250  1.0
  O  O19  1  0.738  0.000  0.263  1.0
  O  O20  1  0.263  0.000  0.737  1.0
[/CIF]
.