The structure described by VO2 is Pb(Zr_(1-x)Ti_x)O3-derived structured and crystallizes in the tetragonal P4/ncc space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OV4 tetrahedra. In the second O site, O(2) is bonded in a linear geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.607
_cell_length_b   8.607
_cell_length_c   7.766
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   575.279
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.982  0.202  0.875  1.0
  V  V1  1  0.202  0.982  0.625  1.0
  V  V2  1  0.798  0.982  0.125  1.0
  V  V3  1  0.518  0.298  0.125  1.0
  V  V4  1  0.798  0.018  0.625  1.0
  V  V5  1  0.018  0.202  0.375  1.0
  V  V6  1  0.482  0.298  0.625  1.0
  V  V7  1  0.202  0.018  0.125  1.0
  V  V8  1  0.702  0.518  0.875  1.0
  V  V9  1  0.702  0.482  0.375  1.0
  V  V10  1  0.018  0.798  0.875  1.0
  V  V11  1  0.518  0.702  0.625  1.0
  V  V12  1  0.298  0.518  0.375  1.0
  V  V13  1  0.482  0.702  0.125  1.0
  V  V14  1  0.298  0.482  0.875  1.0
  V  V15  1  0.982  0.798  0.375  1.0
  O  O16  1  0.995  0.850  0.125  1.0
  O  O17  1  0.350  0.505  0.125  1.0
  O  O18  1  0.505  0.650  0.875  1.0
  O  O19  1  0.839  0.660  0.875  1.0
  O  O20  1  0.350  0.495  0.625  1.0
  O  O21  1  0.160  0.339  0.375  1.0
  O  O22  1  0.161  0.340  0.875  1.0
  O  O23  1  0.495  0.650  0.375  1.0
  O  O24  1  0.339  0.840  0.625  1.0
  O  O25  1  0.161  0.660  0.375  1.0
  O  O26  1  0.339  0.160  0.125  1.0
  O  O27  1  0.005  0.150  0.125  1.0
  O  O28  1  0.505  0.350  0.375  1.0
  O  O29  1  0.850  0.005  0.875  1.0
  O  O30  1  0.661  0.160  0.625  1.0
  O  O31  1  0.660  0.161  0.125  1.0
  O  O32  1  0.839  0.340  0.375  1.0
  O  O33  1  0.650  0.505  0.625  1.0
  O  O34  1  0.150  0.005  0.375  1.0
  O  O35  1  0.150  0.995  0.875  1.0
  O  O36  1  0.660  0.839  0.625  1.0
  O  O37  1  0.005  0.850  0.625  1.0
  O  O38  1  0.995  0.150  0.625  1.0
  O  O39  1  0.650  0.495  0.125  1.0
  O  O40  1  0.160  0.661  0.875  1.0
  O  O41  1  0.661  0.840  0.125  1.0
  O  O42  1  0.850  0.995  0.375  1.0
  O  O43  1  0.340  0.839  0.125  1.0
  O  O44  1  0.340  0.161  0.625  1.0
  O  O45  1  0.840  0.339  0.875  1.0
  O  O46  1  0.840  0.661  0.375  1.0
  O  O47  1  0.495  0.350  0.875  1.0
[/CIF]
.
The structure described by VO2 is Pb(Zr_(1-x)Ti_x)O3-derived structured and crystallizes in the tetragonal P4/ncc space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OV4 tetrahedra. In the second O site, O(2) is bonded in a linear geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.607
_cell_length_b   8.607
_cell_length_c   7.766
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   575.279
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.982  0.202  0.875  1.0
  V  V1  1  0.202  0.982  0.625  1.0
  V  V2  1  0.798  0.982  0.125  1.0
  V  V3  1  0.518  0.298  0.125  1.0
  V  V4  1  0.798  0.018  0.625  1.0
  V  V5  1  0.018  0.202  0.375  1.0
  V  V6  1  0.482  0.298  0.625  1.0
  V  V7  1  0.202  0.018  0.125  1.0
  V  V8  1  0.702  0.518  0.875  1.0
  V  V9  1  0.702  0.482  0.375  1.0
  V  V10  1  0.018  0.798  0.875  1.0
  V  V11  1  0.518  0.702  0.625  1.0
  V  V12  1  0.298  0.518  0.375  1.0
  V  V13  1  0.482  0.702  0.125  1.0
  V  V14  1  0.298  0.482  0.875  1.0
  V  V15  1  0.982  0.798  0.375  1.0
  O  O16  1  0.995  0.850  0.125  1.0
  O  O17  1  0.350  0.505  0.125  1.0
  O  O18  1  0.505  0.650  0.875  1.0
  O  O19  1  0.839  0.660  0.875  1.0
  O  O20  1  0.350  0.495  0.625  1.0
  O  O21  1  0.160  0.339  0.375  1.0
  O  O22  1  0.161  0.340  0.875  1.0
  O  O23  1  0.495  0.650  0.375  1.0
  O  O24  1  0.339  0.840  0.625  1.0
  O  O25  1  0.161  0.660  0.375  1.0
  O  O26  1  0.339  0.160  0.125  1.0
  O  O27  1  0.005  0.150  0.125  1.0
  O  O28  1  0.505  0.350  0.375  1.0
  O  O29  1  0.850  0.005  0.875  1.0
  O  O30  1  0.661  0.160  0.625  1.0
  O  O31  1  0.660  0.161  0.125  1.0
  O  O32  1  0.839  0.340  0.375  1.0
  O  O33  1  0.650  0.505  0.625  1.0
  O  O34  1  0.150  0.005  0.375  1.0
  O  O35  1  0.150  0.995  0.875  1.0
  O  O36  1  0.660  0.839  0.625  1.0
  O  O37  1  0.005  0.850  0.625  1.0
  O  O38  1  0.995  0.150  0.625  1.0
  O  O39  1  0.650  0.495  0.125  1.0
  O  O40  1  0.160  0.661  0.875  1.0
  O  O41  1  0.661  0.840  0.125  1.0
  O  O42  1  0.850  0.995  0.375  1.0
  O  O43  1  0.340  0.839  0.125  1.0
  O  O44  1  0.340  0.161  0.625  1.0
  O  O45  1  0.840  0.339  0.875  1.0
  O  O46  1  0.840  0.661  0.375  1.0
  O  O47  1  0.495  0.350  0.875  1.0
[/CIF]
.