The material structure described by Li10B14O25Cl2 crystallizes in the cubic F23 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to three equivalent O(1) and one Cl(2) atom. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(2), and one Cl(1) atom to form distorted LiClO4 trigonal bipyramids that share corners with two equivalent B(2)O4 tetrahedra, corners with four equivalent B(3)O4 tetrahedra, and corners with five equivalent Li(2)ClO4 trigonal bipyramids. There are three inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. In the second B site, B(2) is bonded to one O(3) and three equivalent O(1) atoms to form BO4 tetrahedra that share corners with three equivalent B(2)O4 tetrahedra, corners with three equivalent B(3)O4 tetrahedra, and corners with three equivalent Li(2)ClO4 trigonal bipyramids. In the third B site, B(3) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form BO4 tetrahedra that share corners with two equivalent B(2)O4 tetrahedra and corners with four equivalent Li(2)ClO4 trigonal bipyramids. There are three inequivalent O sites. In the first O site, O(3) is bonded to four equivalent B(2) atoms to form corner-sharing OB4 tetrahedra. In the second O site, O(1) is bonded to one Li(1), one Li(2), one B(2), and one B(3) atom to form distorted OLi2B2 tetrahedra that share  a cornercorner with one Cl(1)Li6 octahedra,  a cornercorner with one O(3)B4 tetrahedra,  a cornercorner with one Cl(2)Li4 tetrahedra, and corners with six equivalent O(1)Li2B2 tetrahedra. The corner-sharing octahedral tilt angles are 82°. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(2), one B(1), and one B(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to six equivalent Li(2) atoms to form ClLi6 octahedra that share corners with twelve equivalent O(1)Li2B2 tetrahedra. In the second Cl site, Cl(2) is bonded to four equivalent Li(1) atoms to form ClLi4 tetrahedra that share corners with twelve equivalent O(1)Li2B2 tetrahedra. is represented by the CIF card [CIF]
data_Li10B14Cl2O25
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.652
_cell_length_b   8.652
_cell_length_c   8.652
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   457.958
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.405  0.865  0.865  1.0
  Li  Li1  1  0.865  0.865  0.405  1.0
  Li  Li2  1  0.865  0.405  0.865  1.0
  Li  Li3  1  0.865  0.865  0.865  1.0
  Li  Li4  1  0.043  0.457  0.457  1.0
  Li  Li5  1  0.457  0.043  0.457  1.0
  Li  Li6  1  0.457  0.457  0.043  1.0
  Li  Li7  1  0.043  0.043  0.457  1.0
  Li  Li8  1  0.043  0.457  0.043  1.0
  Li  Li9  1  0.457  0.043  0.043  1.0
  B  B10  1  0.601  0.601  0.601  1.0
  B  B11  1  0.601  0.197  0.601  1.0
  B  B12  1  0.601  0.601  0.197  1.0
  B  B13  1  0.197  0.601  0.601  1.0
  B  B14  1  0.757  0.081  0.081  1.0
  B  B15  1  0.081  0.081  0.757  1.0
  B  B16  1  0.081  0.757  0.081  1.0
  B  B17  1  0.081  0.081  0.081  1.0
  B  B18  1  0.251  0.749  0.749  1.0
  B  B19  1  0.749  0.251  0.749  1.0
  B  B20  1  0.749  0.749  0.251  1.0
  B  B21  1  0.251  0.251  0.749  1.0
  B  B22  1  0.251  0.749  0.251  1.0
  B  B23  1  0.749  0.251  0.251  1.0
  Cl  Cl24  1  0.250  0.250  0.250  1.0
  Cl  Cl25  1  0.750  0.750  0.750  1.0
  O  O26  1  0.936  0.258  0.102  1.0
  O  O27  1  0.102  0.936  0.258  1.0
  O  O28  1  0.258  0.102  0.936  1.0
  O  O29  1  0.936  0.704  0.258  1.0
  O  O30  1  0.936  0.102  0.704  1.0
  O  O31  1  0.258  0.704  0.102  1.0
  O  O32  1  0.704  0.936  0.102  1.0
  O  O33  1  0.704  0.258  0.936  1.0
  O  O34  1  0.102  0.258  0.704  1.0
  O  O35  1  0.258  0.936  0.704  1.0
  O  O36  1  0.102  0.704  0.936  1.0
  O  O37  1  0.704  0.102  0.258  1.0
  O  O38  1  0.607  0.758  0.439  1.0
  O  O39  1  0.439  0.607  0.758  1.0
  O  O40  1  0.758  0.439  0.607  1.0
  O  O41  1  0.607  0.196  0.758  1.0
  O  O42  1  0.607  0.439  0.196  1.0
  O  O43  1  0.758  0.196  0.439  1.0
  O  O44  1  0.196  0.607  0.439  1.0
  O  O45  1  0.196  0.758  0.607  1.0
  O  O46  1  0.439  0.758  0.196  1.0
  O  O47  1  0.758  0.607  0.196  1.0
  O  O48  1  0.439  0.196  0.607  1.0
  O  O49  1  0.196  0.439  0.758  1.0
  O  O50  1  0.000  0.000  0.000  1.0
[/CIF]
.
The material structure described by Li10B14O25Cl2 crystallizes in the cubic F23 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to three equivalent O(1) and one Cl(2) atom. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(2), and one Cl(1) atom to form distorted LiClO4 trigonal bipyramids that share corners with two equivalent B(2)O4 tetrahedra, corners with four equivalent B(3)O4 tetrahedra, and corners with five equivalent Li(2)ClO4 trigonal bipyramids. There are three inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. In the second B site, B(2) is bonded to one O(3) and three equivalent O(1) atoms to form BO4 tetrahedra that share corners with three equivalent B(2)O4 tetrahedra, corners with three equivalent B(3)O4 tetrahedra, and corners with three equivalent Li(2)ClO4 trigonal bipyramids. In the third B site, B(3) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form BO4 tetrahedra that share corners with two equivalent B(2)O4 tetrahedra and corners with four equivalent Li(2)ClO4 trigonal bipyramids. There are three inequivalent O sites. In the first O site, O(3) is bonded to four equivalent B(2) atoms to form corner-sharing OB4 tetrahedra. In the second O site, O(1) is bonded to one Li(1), one Li(2), one B(2), and one B(3) atom to form distorted OLi2B2 tetrahedra that share  a cornercorner with one Cl(1)Li6 octahedra,  a cornercorner with one O(3)B4 tetrahedra,  a cornercorner with one Cl(2)Li4 tetrahedra, and corners with six equivalent O(1)Li2B2 tetrahedra. The corner-sharing octahedral tilt angles are 82°. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(2), one B(1), and one B(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to six equivalent Li(2) atoms to form ClLi6 octahedra that share corners with twelve equivalent O(1)Li2B2 tetrahedra. In the second Cl site, Cl(2) is bonded to four equivalent Li(1) atoms to form ClLi4 tetrahedra that share corners with twelve equivalent O(1)Li2B2 tetrahedra. is represented by the CIF card [CIF]
data_Li10B14Cl2O25
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.652
_cell_length_b   8.652
_cell_length_c   8.652
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   457.958
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.405  0.865  0.865  1.0
  Li  Li1  1  0.865  0.865  0.405  1.0
  Li  Li2  1  0.865  0.405  0.865  1.0
  Li  Li3  1  0.865  0.865  0.865  1.0
  Li  Li4  1  0.043  0.457  0.457  1.0
  Li  Li5  1  0.457  0.043  0.457  1.0
  Li  Li6  1  0.457  0.457  0.043  1.0
  Li  Li7  1  0.043  0.043  0.457  1.0
  Li  Li8  1  0.043  0.457  0.043  1.0
  Li  Li9  1  0.457  0.043  0.043  1.0
  B  B10  1  0.601  0.601  0.601  1.0
  B  B11  1  0.601  0.197  0.601  1.0
  B  B12  1  0.601  0.601  0.197  1.0
  B  B13  1  0.197  0.601  0.601  1.0
  B  B14  1  0.757  0.081  0.081  1.0
  B  B15  1  0.081  0.081  0.757  1.0
  B  B16  1  0.081  0.757  0.081  1.0
  B  B17  1  0.081  0.081  0.081  1.0
  B  B18  1  0.251  0.749  0.749  1.0
  B  B19  1  0.749  0.251  0.749  1.0
  B  B20  1  0.749  0.749  0.251  1.0
  B  B21  1  0.251  0.251  0.749  1.0
  B  B22  1  0.251  0.749  0.251  1.0
  B  B23  1  0.749  0.251  0.251  1.0
  Cl  Cl24  1  0.250  0.250  0.250  1.0
  Cl  Cl25  1  0.750  0.750  0.750  1.0
  O  O26  1  0.936  0.258  0.102  1.0
  O  O27  1  0.102  0.936  0.258  1.0
  O  O28  1  0.258  0.102  0.936  1.0
  O  O29  1  0.936  0.704  0.258  1.0
  O  O30  1  0.936  0.102  0.704  1.0
  O  O31  1  0.258  0.704  0.102  1.0
  O  O32  1  0.704  0.936  0.102  1.0
  O  O33  1  0.704  0.258  0.936  1.0
  O  O34  1  0.102  0.258  0.704  1.0
  O  O35  1  0.258  0.936  0.704  1.0
  O  O36  1  0.102  0.704  0.936  1.0
  O  O37  1  0.704  0.102  0.258  1.0
  O  O38  1  0.607  0.758  0.439  1.0
  O  O39  1  0.439  0.607  0.758  1.0
  O  O40  1  0.758  0.439  0.607  1.0
  O  O41  1  0.607  0.196  0.758  1.0
  O  O42  1  0.607  0.439  0.196  1.0
  O  O43  1  0.758  0.196  0.439  1.0
  O  O44  1  0.196  0.607  0.439  1.0
  O  O45  1  0.196  0.758  0.607  1.0
  O  O46  1  0.439  0.758  0.196  1.0
  O  O47  1  0.758  0.607  0.196  1.0
  O  O48  1  0.439  0.196  0.607  1.0
  O  O49  1  0.196  0.439  0.758  1.0
  O  O50  1  0.000  0.000  0.000  1.0
[/CIF]
.