The structure described by Sr2GdMoO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(3), three equivalent O(1), and three equivalent O(2) atoms. Gd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form GdO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-30°. Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MoO6 octahedra that share corners with six equivalent Gd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-30°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Sr(1), one Gd(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Sr(1), one Gd(1), and one Mo(1) atom. In the third O site, O(3) is bonded to two equivalent Sr(1), one Gd(1), and one Mo(1) atom to form distorted corner-sharing OSr2GdMo tetrahedra. is represented by the CIF file [CIF]
data_Sr2GdMoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.898
_cell_length_b   5.982
_cell_length_c   10.155
_cell_angle_alpha   90.000
_cell_angle_beta   124.808
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   294.205
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.237  0.463  0.749  1.0
  Sr  Sr1  1  0.237  0.037  0.249  1.0
  Sr  Sr2  1  0.763  0.537  0.251  1.0
  Sr  Sr3  1  0.763  0.963  0.751  1.0
  Gd  Gd4  1  0.500  0.500  0.500  1.0
  Gd  Gd5  1  0.500  0.000  0.000  1.0
  Mo  Mo6  1  0.000  0.000  0.500  1.0
  Mo  Mo7  1  0.000  0.500  0.000  1.0
  O  O8  1  0.774  0.198  0.541  1.0
  O  O9  1  0.774  0.302  0.041  1.0
  O  O10  1  0.226  0.802  0.459  1.0
  O  O11  1  0.226  0.698  0.959  1.0
  O  O12  1  0.148  0.228  0.948  1.0
  O  O13  1  0.148  0.272  0.448  1.0
  O  O14  1  0.852  0.772  0.052  1.0
  O  O15  1  0.852  0.728  0.552  1.0
  O  O16  1  0.321  0.024  0.731  1.0
  O  O17  1  0.321  0.476  0.231  1.0
  O  O18  1  0.679  0.976  0.269  1.0
  O  O19  1  0.679  0.524  0.769  1.0
[/CIF]
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The structure described by Sr2GdMoO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(3), three equivalent O(1), and three equivalent O(2) atoms. Gd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form GdO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-30°. Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MoO6 octahedra that share corners with six equivalent Gd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-30°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Sr(1), one Gd(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Sr(1), one Gd(1), and one Mo(1) atom. In the third O site, O(3) is bonded to two equivalent Sr(1), one Gd(1), and one Mo(1) atom to form distorted corner-sharing OSr2GdMo tetrahedra. is represented by the CIF file [CIF]
data_Sr2GdMoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.898
_cell_length_b   5.982
_cell_length_c   10.155
_cell_angle_alpha   90.000
_cell_angle_beta   124.808
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   294.205
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.237  0.463  0.749  1.0
  Sr  Sr1  1  0.237  0.037  0.249  1.0
  Sr  Sr2  1  0.763  0.537  0.251  1.0
  Sr  Sr3  1  0.763  0.963  0.751  1.0
  Gd  Gd4  1  0.500  0.500  0.500  1.0
  Gd  Gd5  1  0.500  0.000  0.000  1.0
  Mo  Mo6  1  0.000  0.000  0.500  1.0
  Mo  Mo7  1  0.000  0.500  0.000  1.0
  O  O8  1  0.774  0.198  0.541  1.0
  O  O9  1  0.774  0.302  0.041  1.0
  O  O10  1  0.226  0.802  0.459  1.0
  O  O11  1  0.226  0.698  0.959  1.0
  O  O12  1  0.148  0.228  0.948  1.0
  O  O13  1  0.148  0.272  0.448  1.0
  O  O14  1  0.852  0.772  0.052  1.0
  O  O15  1  0.852  0.728  0.552  1.0
  O  O16  1  0.321  0.024  0.731  1.0
  O  O17  1  0.321  0.476  0.231  1.0
  O  O18  1  0.679  0.976  0.269  1.0
  O  O19  1  0.679  0.524  0.769  1.0
[/CIF]
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