The compound described by TmOs2SiC crystallizes in the orthorhombic Cmcm space group. Tm(1) is bonded in a 4-coordinate geometry to three equivalent Si(1) and four equivalent C(1) atoms. Os(1) is bonded in a 4-coordinate geometry to three equivalent Si(1) and one C(1) atom. Si(1) is bonded in a 9-coordinate geometry to three equivalent Tm(1) and six equivalent Os(1) atoms. C(1) is bonded to four equivalent Tm(1) and two equivalent Os(1) atoms to form a mixture of edge and corner-sharing CTm4Os2 octahedra. The corner-sharing octahedral tilt angles are 22°. is represented by the Crystallographic Information File (CIF) [CIF]
data_TmSiOs2C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.887
_cell_length_b   5.887
_cell_length_c   7.112
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   142.122
_symmetry_Int_Tables_number   1
_cell_volume   151.355
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.546  0.454  0.250  1.0
  Tm  Tm1  1  0.454  0.546  0.750  1.0
  Si  Si2  1  0.267  0.733  0.250  1.0
  Si  Si3  1  0.733  0.267  0.750  1.0
  Os  Os4  1  0.835  0.165  0.058  1.0
  Os  Os5  1  0.165  0.835  0.942  1.0
  Os  Os6  1  0.165  0.835  0.558  1.0
  Os  Os7  1  0.835  0.165  0.442  1.0
  C  C8  1  0.000  0.000  0.000  1.0
  C  C9  1  0.000  0.000  0.500  1.0
[/CIF]
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The compound described by TmOs2SiC crystallizes in the orthorhombic Cmcm space group. Tm(1) is bonded in a 4-coordinate geometry to three equivalent Si(1) and four equivalent C(1) atoms. Os(1) is bonded in a 4-coordinate geometry to three equivalent Si(1) and one C(1) atom. Si(1) is bonded in a 9-coordinate geometry to three equivalent Tm(1) and six equivalent Os(1) atoms. C(1) is bonded to four equivalent Tm(1) and two equivalent Os(1) atoms to form a mixture of edge and corner-sharing CTm4Os2 octahedra. The corner-sharing octahedral tilt angles are 22°. is represented by the Crystallographic Information File (CIF) [CIF]
data_TmSiOs2C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.887
_cell_length_b   5.887
_cell_length_c   7.112
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   142.122
_symmetry_Int_Tables_number   1
_cell_volume   151.355
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.546  0.454  0.250  1.0
  Tm  Tm1  1  0.454  0.546  0.750  1.0
  Si  Si2  1  0.267  0.733  0.250  1.0
  Si  Si3  1  0.733  0.267  0.750  1.0
  Os  Os4  1  0.835  0.165  0.058  1.0
  Os  Os5  1  0.165  0.835  0.942  1.0
  Os  Os6  1  0.165  0.835  0.558  1.0
  Os  Os7  1  0.835  0.165  0.442  1.0
  C  C8  1  0.000  0.000  0.000  1.0
  C  C9  1  0.000  0.000  0.500  1.0
[/CIF]
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