The material structure described by Tm(Rh2Ge)2 crystallizes in the orthorhombic Pnma space group. Tm(1) is bonded in a 13-coordinate geometry to two equivalent Rh(3), three equivalent Rh(1), three equivalent Rh(2), three equivalent Rh(4), and two equivalent Ge(1) atoms. There are four inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 6-coordinate geometry to three equivalent Tm(1), one Ge(2), and three equivalent Ge(1) atoms. In the second Rh site, Rh(2) is bonded in a 5-coordinate geometry to three equivalent Tm(1), three equivalent Rh(4), one Ge(2), and two equivalent Ge(1) atoms. In the third Rh site, Rh(3) is bonded in a 6-coordinate geometry to two equivalent Tm(1), three equivalent Rh(4), one Ge(1), and three equivalent Ge(2) atoms. In the fourth Rh site, Rh(4) is bonded in a 13-coordinate geometry to three equivalent Tm(1), three equivalent Rh(2), three equivalent Rh(3), one Ge(1), and three equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Tm(1), one Rh(3), one Rh(4), two equivalent Rh(2), and three equivalent Rh(1) atoms. In the second Ge site, Ge(2) is bonded in a 8-coordinate geometry to one Rh(1), one Rh(2), three equivalent Rh(3), and three equivalent Rh(4) atoms. is represented by the CIF file [CIF]
data_Tm(GeRh2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.160
_cell_length_b   9.099
_cell_length_c   11.351
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   429.636
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.250  0.148  0.826  1.0
  Tm  Tm1  1  0.250  0.352  0.326  1.0
  Tm  Tm2  1  0.750  0.852  0.174  1.0
  Tm  Tm3  1  0.750  0.648  0.674  1.0
  Ge  Ge4  1  0.250  0.414  0.639  1.0
  Ge  Ge5  1  0.250  0.086  0.139  1.0
  Ge  Ge6  1  0.750  0.586  0.361  1.0
  Ge  Ge7  1  0.750  0.914  0.861  1.0
  Ge  Ge8  1  0.250  0.618  0.059  1.0
  Ge  Ge9  1  0.250  0.882  0.559  1.0
  Ge  Ge10  1  0.750  0.382  0.941  1.0
  Ge  Ge11  1  0.750  0.118  0.441  1.0
  Rh  Rh12  1  0.250  0.616  0.499  1.0
  Rh  Rh13  1  0.250  0.884  0.999  1.0
  Rh  Rh14  1  0.750  0.384  0.501  1.0
  Rh  Rh15  1  0.750  0.116  0.001  1.0
  Rh  Rh16  1  0.250  0.692  0.269  1.0
  Rh  Rh17  1  0.250  0.808  0.769  1.0
  Rh  Rh18  1  0.750  0.308  0.731  1.0
  Rh  Rh19  1  0.750  0.192  0.231  1.0
  Rh  Rh20  1  0.250  0.171  0.562  1.0
  Rh  Rh21  1  0.250  0.329  0.062  1.0
  Rh  Rh22  1  0.750  0.829  0.438  1.0
  Rh  Rh23  1  0.750  0.671  0.938  1.0
  Rh  Rh24  1  0.250  0.005  0.345  1.0
  Rh  Rh25  1  0.250  0.495  0.845  1.0
  Rh  Rh26  1  0.750  0.995  0.655  1.0
  Rh  Rh27  1  0.750  0.505  0.155  1.0
[/CIF]
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The material structure described by Tm(Rh2Ge)2 crystallizes in the orthorhombic Pnma space group. Tm(1) is bonded in a 13-coordinate geometry to two equivalent Rh(3), three equivalent Rh(1), three equivalent Rh(2), three equivalent Rh(4), and two equivalent Ge(1) atoms. There are four inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 6-coordinate geometry to three equivalent Tm(1), one Ge(2), and three equivalent Ge(1) atoms. In the second Rh site, Rh(2) is bonded in a 5-coordinate geometry to three equivalent Tm(1), three equivalent Rh(4), one Ge(2), and two equivalent Ge(1) atoms. In the third Rh site, Rh(3) is bonded in a 6-coordinate geometry to two equivalent Tm(1), three equivalent Rh(4), one Ge(1), and three equivalent Ge(2) atoms. In the fourth Rh site, Rh(4) is bonded in a 13-coordinate geometry to three equivalent Tm(1), three equivalent Rh(2), three equivalent Rh(3), one Ge(1), and three equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Tm(1), one Rh(3), one Rh(4), two equivalent Rh(2), and three equivalent Rh(1) atoms. In the second Ge site, Ge(2) is bonded in a 8-coordinate geometry to one Rh(1), one Rh(2), three equivalent Rh(3), and three equivalent Rh(4) atoms. is represented by the CIF file [CIF]
data_Tm(GeRh2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.160
_cell_length_b   9.099
_cell_length_c   11.351
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   429.636
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.250  0.148  0.826  1.0
  Tm  Tm1  1  0.250  0.352  0.326  1.0
  Tm  Tm2  1  0.750  0.852  0.174  1.0
  Tm  Tm3  1  0.750  0.648  0.674  1.0
  Ge  Ge4  1  0.250  0.414  0.639  1.0
  Ge  Ge5  1  0.250  0.086  0.139  1.0
  Ge  Ge6  1  0.750  0.586  0.361  1.0
  Ge  Ge7  1  0.750  0.914  0.861  1.0
  Ge  Ge8  1  0.250  0.618  0.059  1.0
  Ge  Ge9  1  0.250  0.882  0.559  1.0
  Ge  Ge10  1  0.750  0.382  0.941  1.0
  Ge  Ge11  1  0.750  0.118  0.441  1.0
  Rh  Rh12  1  0.250  0.616  0.499  1.0
  Rh  Rh13  1  0.250  0.884  0.999  1.0
  Rh  Rh14  1  0.750  0.384  0.501  1.0
  Rh  Rh15  1  0.750  0.116  0.001  1.0
  Rh  Rh16  1  0.250  0.692  0.269  1.0
  Rh  Rh17  1  0.250  0.808  0.769  1.0
  Rh  Rh18  1  0.750  0.308  0.731  1.0
  Rh  Rh19  1  0.750  0.192  0.231  1.0
  Rh  Rh20  1  0.250  0.171  0.562  1.0
  Rh  Rh21  1  0.250  0.329  0.062  1.0
  Rh  Rh22  1  0.750  0.829  0.438  1.0
  Rh  Rh23  1  0.750  0.671  0.938  1.0
  Rh  Rh24  1  0.250  0.005  0.345  1.0
  Rh  Rh25  1  0.250  0.495  0.845  1.0
  Rh  Rh26  1  0.750  0.995  0.655  1.0
  Rh  Rh27  1  0.750  0.505  0.155  1.0
[/CIF]
.