The material described by RhH9(NCl)3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two azane;rhodium(3+);trichloride molecules. Rh(1) is bonded in an octahedral geometry to one N(2), two equivalent N(1), one Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Rh(1), one H(1), one H(2), and one H(3) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Rh(1), one H(5), and two equivalent H(4) atoms. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the CIF file [CIF]
data_H9Rh(NCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.589
_cell_length_b   7.046
_cell_length_c   9.870
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   93.286
_symmetry_Int_Tables_number   1
_cell_volume   388.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.087  0.155  0.389  1.0
  H  H1  1  0.913  0.845  0.889  1.0
  H  H2  1  0.913  0.845  0.611  1.0
  H  H3  1  0.087  0.155  0.111  1.0
  H  H4  1  0.322  0.161  0.491  1.0
  H  H5  1  0.678  0.839  0.991  1.0
  H  H6  1  0.678  0.839  0.509  1.0
  H  H7  1  0.322  0.161  0.009  1.0
  H  H8  1  0.259  0.969  0.399  1.0
  H  H9  1  0.741  0.031  0.899  1.0
  H  H10  1  0.741  0.031  0.601  1.0
  H  H11  1  0.259  0.969  0.101  1.0
  H  H12  1  0.386  0.555  0.335  1.0
  H  H13  1  0.614  0.445  0.835  1.0
  H  H14  1  0.614  0.445  0.665  1.0
  H  H15  1  0.386  0.555  0.165  1.0
  H  H16  1  0.148  0.465  0.250  1.0
  H  H17  1  0.852  0.535  0.750  1.0
  Rh  Rh18  1  0.494  0.220  0.250  1.0
  Rh  Rh19  1  0.506  0.780  0.750  1.0
  N  N20  1  0.260  0.115  0.398  1.0
  N  N21  1  0.740  0.885  0.898  1.0
  N  N22  1  0.740  0.885  0.602  1.0
  N  N23  1  0.260  0.115  0.102  1.0
  N  N24  1  0.333  0.479  0.250  1.0
  N  N25  1  0.667  0.521  0.750  1.0
  Cl  Cl26  1  0.665  0.915  0.250  1.0
  Cl  Cl27  1  0.335  0.085  0.750  1.0
  Cl  Cl28  1  0.756  0.343  0.425  1.0
  Cl  Cl29  1  0.244  0.657  0.925  1.0
  Cl  Cl30  1  0.244  0.657  0.575  1.0
  Cl  Cl31  1  0.756  0.343  0.075  1.0
[/CIF]
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The material described by RhH9(NCl)3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two azane;rhodium(3+);trichloride molecules. Rh(1) is bonded in an octahedral geometry to one N(2), two equivalent N(1), one Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Rh(1), one H(1), one H(2), and one H(3) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Rh(1), one H(5), and two equivalent H(4) atoms. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the CIF file [CIF]
data_H9Rh(NCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.589
_cell_length_b   7.046
_cell_length_c   9.870
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   93.286
_symmetry_Int_Tables_number   1
_cell_volume   388.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.087  0.155  0.389  1.0
  H  H1  1  0.913  0.845  0.889  1.0
  H  H2  1  0.913  0.845  0.611  1.0
  H  H3  1  0.087  0.155  0.111  1.0
  H  H4  1  0.322  0.161  0.491  1.0
  H  H5  1  0.678  0.839  0.991  1.0
  H  H6  1  0.678  0.839  0.509  1.0
  H  H7  1  0.322  0.161  0.009  1.0
  H  H8  1  0.259  0.969  0.399  1.0
  H  H9  1  0.741  0.031  0.899  1.0
  H  H10  1  0.741  0.031  0.601  1.0
  H  H11  1  0.259  0.969  0.101  1.0
  H  H12  1  0.386  0.555  0.335  1.0
  H  H13  1  0.614  0.445  0.835  1.0
  H  H14  1  0.614  0.445  0.665  1.0
  H  H15  1  0.386  0.555  0.165  1.0
  H  H16  1  0.148  0.465  0.250  1.0
  H  H17  1  0.852  0.535  0.750  1.0
  Rh  Rh18  1  0.494  0.220  0.250  1.0
  Rh  Rh19  1  0.506  0.780  0.750  1.0
  N  N20  1  0.260  0.115  0.398  1.0
  N  N21  1  0.740  0.885  0.898  1.0
  N  N22  1  0.740  0.885  0.602  1.0
  N  N23  1  0.260  0.115  0.102  1.0
  N  N24  1  0.333  0.479  0.250  1.0
  N  N25  1  0.667  0.521  0.750  1.0
  Cl  Cl26  1  0.665  0.915  0.250  1.0
  Cl  Cl27  1  0.335  0.085  0.750  1.0
  Cl  Cl28  1  0.756  0.343  0.425  1.0
  Cl  Cl29  1  0.244  0.657  0.925  1.0
  Cl  Cl30  1  0.244  0.657  0.575  1.0
  Cl  Cl31  1  0.756  0.343  0.075  1.0
[/CIF]
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