The crystal structure described by IrSO4Cl3SO3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and two IrSO4Cl3 clusters. In each IrSO4Cl3 cluster, Ir(1) is bonded to one O(1), one O(2), one Cl(1), and two equivalent Cl(2) atoms to form distorted IrCl3O2 trigonal bipyramids that share  an edgeedge with one S(2)O4 tetrahedra. S(2) is bonded to one O(1), one O(2), and two equivalent O(5) atoms to form SO4 tetrahedra that share  an edgeedge with one Ir(1)Cl3O2 trigonal bipyramid. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ir(1) and one S(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ir(1) and one S(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one S(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom. is represented by the CIF card [CIF]
data_IrS2Cl3O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.498
_cell_length_b   10.275
_cell_length_c   12.756
_cell_angle_alpha   90.000
_cell_angle_beta   85.359
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1110.221
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.792  0.750  0.899  1.0
  Ir  Ir1  1  0.208  0.250  0.101  1.0
  S  S2  1  0.552  0.750  0.648  1.0
  S  S3  1  0.448  0.250  0.352  1.0
  S  S4  1  0.117  0.750  0.882  1.0
  S  S5  1  0.883  0.250  0.118  1.0
  Cl  Cl6  1  0.552  0.750  0.983  1.0
  Cl  Cl7  1  0.448  0.250  0.017  1.0
  Cl  Cl8  1  0.774  0.536  0.867  1.0
  Cl  Cl9  1  0.226  0.036  0.133  1.0
  Cl  Cl10  1  0.226  0.464  0.133  1.0
  Cl  Cl11  1  0.774  0.964  0.867  1.0
  O  O12  1  0.993  0.750  0.798  1.0
  O  O13  1  0.007  0.250  0.202  1.0
  O  O14  1  0.975  0.750  0.980  1.0
  O  O15  1  0.025  0.250  0.020  1.0
  O  O16  1  0.665  0.750  0.559  1.0
  O  O17  1  0.335  0.250  0.441  1.0
  O  O18  1  0.496  0.629  0.694  1.0
  O  O19  1  0.504  0.129  0.306  1.0
  O  O20  1  0.504  0.371  0.306  1.0
  O  O21  1  0.496  0.871  0.694  1.0
  O  O22  1  0.202  0.629  0.885  1.0
  O  O23  1  0.798  0.129  0.115  1.0
  O  O24  1  0.798  0.371  0.115  1.0
  O  O25  1  0.202  0.871  0.885  1.0
[/CIF]
.
The crystal structure described by IrSO4Cl3SO3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and two IrSO4Cl3 clusters. In each IrSO4Cl3 cluster, Ir(1) is bonded to one O(1), one O(2), one Cl(1), and two equivalent Cl(2) atoms to form distorted IrCl3O2 trigonal bipyramids that share  an edgeedge with one S(2)O4 tetrahedra. S(2) is bonded to one O(1), one O(2), and two equivalent O(5) atoms to form SO4 tetrahedra that share  an edgeedge with one Ir(1)Cl3O2 trigonal bipyramid. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ir(1) and one S(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ir(1) and one S(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one S(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom. is represented by the CIF card [CIF]
data_IrS2Cl3O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.498
_cell_length_b   10.275
_cell_length_c   12.756
_cell_angle_alpha   90.000
_cell_angle_beta   85.359
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1110.221
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.792  0.750  0.899  1.0
  Ir  Ir1  1  0.208  0.250  0.101  1.0
  S  S2  1  0.552  0.750  0.648  1.0
  S  S3  1  0.448  0.250  0.352  1.0
  S  S4  1  0.117  0.750  0.882  1.0
  S  S5  1  0.883  0.250  0.118  1.0
  Cl  Cl6  1  0.552  0.750  0.983  1.0
  Cl  Cl7  1  0.448  0.250  0.017  1.0
  Cl  Cl8  1  0.774  0.536  0.867  1.0
  Cl  Cl9  1  0.226  0.036  0.133  1.0
  Cl  Cl10  1  0.226  0.464  0.133  1.0
  Cl  Cl11  1  0.774  0.964  0.867  1.0
  O  O12  1  0.993  0.750  0.798  1.0
  O  O13  1  0.007  0.250  0.202  1.0
  O  O14  1  0.975  0.750  0.980  1.0
  O  O15  1  0.025  0.250  0.020  1.0
  O  O16  1  0.665  0.750  0.559  1.0
  O  O17  1  0.335  0.250  0.441  1.0
  O  O18  1  0.496  0.629  0.694  1.0
  O  O19  1  0.504  0.129  0.306  1.0
  O  O20  1  0.504  0.371  0.306  1.0
  O  O21  1  0.496  0.871  0.694  1.0
  O  O22  1  0.202  0.629  0.885  1.0
  O  O23  1  0.798  0.129  0.115  1.0
  O  O24  1  0.798  0.371  0.115  1.0
  O  O25  1  0.202  0.871  0.885  1.0
[/CIF]
.