The crystal structure described by VOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_12_12 space group. V(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. O(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.632
_cell_length_b   4.632
_cell_length_c   6.127
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.002
_symmetry_Int_Tables_number   1
_cell_volume   131.447
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.970  0.970  0.000  1.0
  V  V1  1  0.030  0.030  0.500  1.0
  V  V2  1  0.530  0.470  0.250  1.0
  V  V3  1  0.470  0.530  0.750  1.0
  O  O4  1  0.183  0.817  0.750  1.0
  O  O5  1  0.317  0.317  0.500  1.0
  O  O6  1  0.683  0.683  0.000  1.0
  O  O7  1  0.817  0.183  0.250  1.0
  F  F8  1  0.209  0.791  0.250  1.0
  F  F9  1  0.291  0.291  1.000  1.0
  F  F10  1  0.709  0.709  0.500  1.0
  F  F11  1  0.791  0.209  0.750  1.0
[/CIF]
.
The crystal structure described by VOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_12_12 space group. V(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. O(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.632
_cell_length_b   4.632
_cell_length_c   6.127
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.002
_symmetry_Int_Tables_number   1
_cell_volume   131.447
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.970  0.970  0.000  1.0
  V  V1  1  0.030  0.030  0.500  1.0
  V  V2  1  0.530  0.470  0.250  1.0
  V  V3  1  0.470  0.530  0.750  1.0
  O  O4  1  0.183  0.817  0.750  1.0
  O  O5  1  0.317  0.317  0.500  1.0
  O  O6  1  0.683  0.683  0.000  1.0
  O  O7  1  0.817  0.183  0.250  1.0
  F  F8  1  0.209  0.791  0.250  1.0
  F  F9  1  0.291  0.291  1.000  1.0
  F  F10  1  0.709  0.709  0.500  1.0
  F  F11  1  0.791  0.209  0.750  1.0
[/CIF]
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