The material structure described by RbMoPO6 crystallizes in the orthorhombic Fddd space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms. Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted MoO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form PO4 tetrahedra that share corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-44°. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the second O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one Mo(1), and one P(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Mo(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMoPO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.266
_cell_length_b   9.822
_cell_length_c   8.475
_cell_angle_alpha   67.797
_cell_angle_beta   62.355
_cell_angle_gamma   49.848
_symmetry_Int_Tables_number   1
_cell_volume   574.728
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.797  0.203  0.203  1.0
  Rb  Rb1  1  0.203  0.797  0.797  1.0
  Rb  Rb2  1  0.453  0.047  0.047  1.0
  Rb  Rb3  1  0.047  0.453  0.453  1.0
  Mo  Mo4  1  0.969  0.531  0.969  1.0
  Mo  Mo5  1  0.531  0.969  0.531  1.0
  Mo  Mo6  1  0.281  0.719  0.281  1.0
  Mo  Mo7  1  0.719  0.281  0.719  1.0
  P  P8  1  0.368  0.368  0.632  1.0
  P  P9  1  0.632  0.632  0.368  1.0
  P  P10  1  0.882  0.882  0.618  1.0
  P  P11  1  0.618  0.618  0.882  1.0
  O  O12  1  0.162  0.455  0.730  1.0
  O  O13  1  0.653  0.730  0.455  1.0
  O  O14  1  0.730  0.653  0.162  1.0
  O  O15  1  0.455  0.162  0.653  1.0
  O  O16  1  0.088  0.795  0.520  1.0
  O  O17  1  0.597  0.520  0.795  1.0
  O  O18  1  0.520  0.597  0.088  1.0
  O  O19  1  0.795  0.088  0.597  1.0
  O  O20  1  0.445  0.394  0.727  1.0
  O  O21  1  0.434  0.727  0.394  1.0
  O  O22  1  0.727  0.434  0.445  1.0
  O  O23  1  0.394  0.445  0.434  1.0
  O  O24  1  0.805  0.856  0.523  1.0
  O  O25  1  0.816  0.523  0.856  1.0
  O  O26  1  0.523  0.816  0.805  1.0
  O  O27  1  0.856  0.805  0.816  1.0
  O  O28  1  0.073  0.571  0.040  1.0
  O  O29  1  0.315  0.040  0.571  1.0
  O  O30  1  0.040  0.315  0.073  1.0
  O  O31  1  0.571  0.073  0.315  1.0
  O  O32  1  0.177  0.679  0.210  1.0
  O  O33  1  0.935  0.210  0.679  1.0
  O  O34  1  0.210  0.935  0.177  1.0
  O  O35  1  0.679  0.177  0.935  1.0
[/CIF]
.
The material structure described by RbMoPO6 crystallizes in the orthorhombic Fddd space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms. Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted MoO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form PO4 tetrahedra that share corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-44°. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the second O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one Mo(1), and one P(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Mo(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMoPO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.266
_cell_length_b   9.822
_cell_length_c   8.475
_cell_angle_alpha   67.797
_cell_angle_beta   62.355
_cell_angle_gamma   49.848
_symmetry_Int_Tables_number   1
_cell_volume   574.728
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.797  0.203  0.203  1.0
  Rb  Rb1  1  0.203  0.797  0.797  1.0
  Rb  Rb2  1  0.453  0.047  0.047  1.0
  Rb  Rb3  1  0.047  0.453  0.453  1.0
  Mo  Mo4  1  0.969  0.531  0.969  1.0
  Mo  Mo5  1  0.531  0.969  0.531  1.0
  Mo  Mo6  1  0.281  0.719  0.281  1.0
  Mo  Mo7  1  0.719  0.281  0.719  1.0
  P  P8  1  0.368  0.368  0.632  1.0
  P  P9  1  0.632  0.632  0.368  1.0
  P  P10  1  0.882  0.882  0.618  1.0
  P  P11  1  0.618  0.618  0.882  1.0
  O  O12  1  0.162  0.455  0.730  1.0
  O  O13  1  0.653  0.730  0.455  1.0
  O  O14  1  0.730  0.653  0.162  1.0
  O  O15  1  0.455  0.162  0.653  1.0
  O  O16  1  0.088  0.795  0.520  1.0
  O  O17  1  0.597  0.520  0.795  1.0
  O  O18  1  0.520  0.597  0.088  1.0
  O  O19  1  0.795  0.088  0.597  1.0
  O  O20  1  0.445  0.394  0.727  1.0
  O  O21  1  0.434  0.727  0.394  1.0
  O  O22  1  0.727  0.434  0.445  1.0
  O  O23  1  0.394  0.445  0.434  1.0
  O  O24  1  0.805  0.856  0.523  1.0
  O  O25  1  0.816  0.523  0.856  1.0
  O  O26  1  0.523  0.816  0.805  1.0
  O  O27  1  0.856  0.805  0.816  1.0
  O  O28  1  0.073  0.571  0.040  1.0
  O  O29  1  0.315  0.040  0.571  1.0
  O  O30  1  0.040  0.315  0.073  1.0
  O  O31  1  0.571  0.073  0.315  1.0
  O  O32  1  0.177  0.679  0.210  1.0
  O  O33  1  0.935  0.210  0.679  1.0
  O  O34  1  0.210  0.935  0.177  1.0
  O  O35  1  0.679  0.177  0.935  1.0
[/CIF]
.