The material structure described by V3Cr3(TeO8)2 is Rutile-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second Cr site, Cr(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CrO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2), one Cr(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cr(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent Cr(1) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent Cr(1) atoms. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to two equivalent V(2) and one Cr(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one V(1), one Cr(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Cr(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent V(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one V(2), one Cr(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to two equivalent V(2) and one Cr(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one V(1), one Cr(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to two equivalent V(2) and one Te(2) atom. is represented by the CIF file [CIF]
data_V3Cr3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.907
_cell_length_b   5.907
_cell_length_c   9.431
_cell_angle_alpha   89.096
_cell_angle_beta   89.096
_cell_angle_gamma   60.153
_symmetry_Int_Tables_number   1
_cell_volume   285.407
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.827  0.827  0.776  1.0
  V  V1  1  0.650  0.180  0.279  1.0
  V  V2  1  0.180  0.650  0.279  1.0
  Cr  Cr3  1  0.831  0.343  0.789  1.0
  Cr  Cr4  1  0.343  0.831  0.789  1.0
  Cr  Cr5  1  0.170  0.170  0.293  1.0
  Te  Te6  1  0.664  0.664  0.509  1.0
  Te  Te7  1  0.332  0.332  0.005  1.0
  O  O8  1  0.827  0.339  0.401  1.0
  O  O9  1  0.522  0.522  0.664  1.0
  O  O10  1  0.676  0.676  0.893  1.0
  O  O11  1  0.997  0.997  0.703  1.0
  O  O12  1  0.999  0.999  0.209  1.0
  O  O13  1  0.339  0.827  0.401  1.0
  O  O14  1  0.961  0.524  0.656  1.0
  O  O15  1  0.524  0.961  0.656  1.0
  O  O16  1  0.167  0.167  0.902  1.0
  O  O17  1  0.828  0.828  0.397  1.0
  O  O18  1  0.481  0.043  0.162  1.0
  O  O19  1  0.043  0.481  0.162  1.0
  O  O20  1  0.338  0.338  0.398  1.0
  O  O21  1  0.660  0.169  0.899  1.0
  O  O22  1  0.481  0.481  0.152  1.0
  O  O23  1  0.169  0.660  0.899  1.0
[/CIF]
.
The material structure described by V3Cr3(TeO8)2 is Rutile-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second Cr site, Cr(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CrO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2), one Cr(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cr(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent Cr(1) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent Cr(1) atoms. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to two equivalent V(2) and one Cr(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one V(1), one Cr(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Cr(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent V(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one V(2), one Cr(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to two equivalent V(2) and one Cr(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one V(1), one Cr(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to two equivalent V(2) and one Te(2) atom. is represented by the CIF file [CIF]
data_V3Cr3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.907
_cell_length_b   5.907
_cell_length_c   9.431
_cell_angle_alpha   89.096
_cell_angle_beta   89.096
_cell_angle_gamma   60.153
_symmetry_Int_Tables_number   1
_cell_volume   285.407
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.827  0.827  0.776  1.0
  V  V1  1  0.650  0.180  0.279  1.0
  V  V2  1  0.180  0.650  0.279  1.0
  Cr  Cr3  1  0.831  0.343  0.789  1.0
  Cr  Cr4  1  0.343  0.831  0.789  1.0
  Cr  Cr5  1  0.170  0.170  0.293  1.0
  Te  Te6  1  0.664  0.664  0.509  1.0
  Te  Te7  1  0.332  0.332  0.005  1.0
  O  O8  1  0.827  0.339  0.401  1.0
  O  O9  1  0.522  0.522  0.664  1.0
  O  O10  1  0.676  0.676  0.893  1.0
  O  O11  1  0.997  0.997  0.703  1.0
  O  O12  1  0.999  0.999  0.209  1.0
  O  O13  1  0.339  0.827  0.401  1.0
  O  O14  1  0.961  0.524  0.656  1.0
  O  O15  1  0.524  0.961  0.656  1.0
  O  O16  1  0.167  0.167  0.902  1.0
  O  O17  1  0.828  0.828  0.397  1.0
  O  O18  1  0.481  0.043  0.162  1.0
  O  O19  1  0.043  0.481  0.162  1.0
  O  O20  1  0.338  0.338  0.398  1.0
  O  O21  1  0.660  0.169  0.899  1.0
  O  O22  1  0.481  0.481  0.152  1.0
  O  O23  1  0.169  0.660  0.899  1.0
[/CIF]
.