The crystal structure described by RbPH3O4F crystallizes in the orthorhombic Pna2_1 space group. Rb(1) is bonded in a 11-coordinate geometry to two equivalent H(2), one O(1), one O(4), two equivalent O(2), two equivalent O(3), and three equivalent F(1) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. In the second H site, H(2) is bonded in a linear geometry to two equivalent Rb(1), one O(1), and one F(1) atom. In the third H site, H(3) is bonded in a linear geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one P(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one P(1), one H(1), and one H(3) atom. F(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one H(2) atom. is represented by the CIF file [CIF]
data_RbPH3O4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.658
_cell_length_b   9.171
_cell_length_c   12.113
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   517.472
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.368  0.155  0.699  1.0
  Rb  Rb1  1  0.868  0.345  0.199  1.0
  Rb  Rb2  1  0.132  0.655  0.699  1.0
  Rb  Rb3  1  0.632  0.845  0.199  1.0
  P  P4  1  0.079  0.022  0.956  1.0
  P  P5  1  0.579  0.478  0.456  1.0
  P  P6  1  0.421  0.522  0.956  1.0
  P  P7  1  0.921  0.978  0.456  1.0
  H  H8  1  0.637  0.103  0.993  1.0
  H  H9  1  0.249  0.101  0.295  1.0
  H  H10  1  0.816  0.213  0.490  1.0
  H  H11  1  0.316  0.287  0.990  1.0
  H  H12  1  0.749  0.399  0.795  1.0
  H  H13  1  0.137  0.397  0.493  1.0
  H  H14  1  0.863  0.603  0.993  1.0
  H  H15  1  0.251  0.601  0.295  1.0
  H  H16  1  0.684  0.713  0.490  1.0
  H  H17  1  0.184  0.787  0.990  1.0
  H  H18  1  0.751  0.899  0.795  1.0
  H  H19  1  0.363  0.897  0.493  1.0
  O  O20  1  0.034  0.025  0.344  1.0
  O  O21  1  0.837  0.098  0.028  1.0
  O  O22  1  0.817  0.112  0.528  1.0
  O  O23  1  0.332  0.130  0.948  1.0
  O  O24  1  0.832  0.370  0.448  1.0
  O  O25  1  0.317  0.388  0.028  1.0
  O  O26  1  0.337  0.402  0.528  1.0
  O  O27  1  0.534  0.475  0.844  1.0
  O  O28  1  0.466  0.525  0.344  1.0
  O  O29  1  0.663  0.598  0.028  1.0
  O  O30  1  0.683  0.612  0.528  1.0
  O  O31  1  0.168  0.630  0.948  1.0
  O  O32  1  0.668  0.870  0.448  1.0
  O  O33  1  0.183  0.888  0.028  1.0
  O  O34  1  0.163  0.902  0.528  1.0
  O  O35  1  0.966  0.975  0.844  1.0
  F  F36  1  0.398  0.156  0.248  1.0
  F  F37  1  0.898  0.344  0.748  1.0
  F  F38  1  0.102  0.656  0.248  1.0
  F  F39  1  0.602  0.844  0.748  1.0
[/CIF]
.
The crystal structure described by RbPH3O4F crystallizes in the orthorhombic Pna2_1 space group. Rb(1) is bonded in a 11-coordinate geometry to two equivalent H(2), one O(1), one O(4), two equivalent O(2), two equivalent O(3), and three equivalent F(1) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. In the second H site, H(2) is bonded in a linear geometry to two equivalent Rb(1), one O(1), and one F(1) atom. In the third H site, H(3) is bonded in a linear geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one P(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one P(1), one H(1), and one H(3) atom. F(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one H(2) atom. is represented by the CIF file [CIF]
data_RbPH3O4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.658
_cell_length_b   9.171
_cell_length_c   12.113
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   517.472
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.368  0.155  0.699  1.0
  Rb  Rb1  1  0.868  0.345  0.199  1.0
  Rb  Rb2  1  0.132  0.655  0.699  1.0
  Rb  Rb3  1  0.632  0.845  0.199  1.0
  P  P4  1  0.079  0.022  0.956  1.0
  P  P5  1  0.579  0.478  0.456  1.0
  P  P6  1  0.421  0.522  0.956  1.0
  P  P7  1  0.921  0.978  0.456  1.0
  H  H8  1  0.637  0.103  0.993  1.0
  H  H9  1  0.249  0.101  0.295  1.0
  H  H10  1  0.816  0.213  0.490  1.0
  H  H11  1  0.316  0.287  0.990  1.0
  H  H12  1  0.749  0.399  0.795  1.0
  H  H13  1  0.137  0.397  0.493  1.0
  H  H14  1  0.863  0.603  0.993  1.0
  H  H15  1  0.251  0.601  0.295  1.0
  H  H16  1  0.684  0.713  0.490  1.0
  H  H17  1  0.184  0.787  0.990  1.0
  H  H18  1  0.751  0.899  0.795  1.0
  H  H19  1  0.363  0.897  0.493  1.0
  O  O20  1  0.034  0.025  0.344  1.0
  O  O21  1  0.837  0.098  0.028  1.0
  O  O22  1  0.817  0.112  0.528  1.0
  O  O23  1  0.332  0.130  0.948  1.0
  O  O24  1  0.832  0.370  0.448  1.0
  O  O25  1  0.317  0.388  0.028  1.0
  O  O26  1  0.337  0.402  0.528  1.0
  O  O27  1  0.534  0.475  0.844  1.0
  O  O28  1  0.466  0.525  0.344  1.0
  O  O29  1  0.663  0.598  0.028  1.0
  O  O30  1  0.683  0.612  0.528  1.0
  O  O31  1  0.168  0.630  0.948  1.0
  O  O32  1  0.668  0.870  0.448  1.0
  O  O33  1  0.183  0.888  0.028  1.0
  O  O34  1  0.163  0.902  0.528  1.0
  O  O35  1  0.966  0.975  0.844  1.0
  F  F36  1  0.398  0.156  0.248  1.0
  F  F37  1  0.898  0.344  0.748  1.0
  F  F38  1  0.102  0.656  0.248  1.0
  F  F39  1  0.602  0.844  0.748  1.0
[/CIF]
.