The structure described by LiKGdF5 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one F(4), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Li(1) is bonded to one F(2), one F(4), one F(5), and two equivalent F(1) atoms to form distorted corner-sharing LiF5 trigonal pyramids. Gd(1) is bonded in a 8-coordinate geometry to one F(1), one F(5), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent K(1), two equivalent Li(1), and one Gd(1) atom. In the second F site, F(2) is bonded in a 5-coordinate geometry to two equivalent K(1), one Li(1), and two equivalent Gd(1) atoms. In the third F site, F(3) is bonded to two equivalent K(1) and two equivalent Gd(1) atoms to form distorted FK2Gd2 tetrahedra that share corners with four equivalent F(5)K2LiGd tetrahedra,  an edgeedge with one F(5)K2LiGd tetrahedra, and edges with two equivalent F(3)K2Gd2 tetrahedra. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to one K(1), one Li(1), and two equivalent Gd(1) atoms. In the fifth F site, F(5) is bonded to two equivalent K(1), one Li(1), and one Gd(1) atom to form distorted FK2LiGd tetrahedra that share corners with two equivalent F(5)K2LiGd tetrahedra, corners with four equivalent F(3)K2Gd2 tetrahedra, and  an edgeedge with one F(3)K2Gd2 tetrahedra. is represented by the CIF card [CIF]
data_KLiGdF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.529
_cell_length_b   6.336
_cell_length_c   11.731
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   113.410
_symmetry_Int_Tables_number   1
_cell_volume   445.336
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.946  0.961  0.349  1.0
  K  K1  1  0.054  0.039  0.651  1.0
  K  K2  1  0.054  0.539  0.849  1.0
  K  K3  1  0.946  0.461  0.151  1.0
  Li  Li4  1  0.559  0.960  0.744  1.0
  Li  Li5  1  0.441  0.040  0.256  1.0
  Li  Li6  1  0.441  0.540  0.244  1.0
  Li  Li7  1  0.559  0.460  0.756  1.0
  Gd  Gd8  1  0.683  0.820  0.996  1.0
  Gd  Gd9  1  0.317  0.180  0.004  1.0
  Gd  Gd10  1  0.317  0.680  0.496  1.0
  Gd  Gd11  1  0.683  0.320  0.504  1.0
  F  F12  1  0.721  0.778  0.799  1.0
  F  F13  1  0.279  0.222  0.201  1.0
  F  F14  1  0.279  0.722  0.299  1.0
  F  F15  1  0.721  0.278  0.701  1.0
  F  F16  1  0.666  0.951  0.537  1.0
  F  F17  1  0.334  0.049  0.463  1.0
  F  F18  1  0.334  0.549  0.037  1.0
  F  F19  1  0.666  0.451  0.963  1.0
  F  F20  1  0.957  0.678  0.508  1.0
  F  F21  1  0.043  0.322  0.492  1.0
  F  F22  1  0.043  0.822  0.008  1.0
  F  F23  1  0.957  0.178  0.992  1.0
  F  F24  1  0.459  0.961  0.892  1.0
  F  F25  1  0.541  0.039  0.108  1.0
  F  F26  1  0.541  0.539  0.392  1.0
  F  F27  1  0.459  0.461  0.608  1.0
  F  F28  1  0.289  0.788  0.676  1.0
  F  F29  1  0.711  0.212  0.324  1.0
  F  F30  1  0.711  0.712  0.176  1.0
  F  F31  1  0.289  0.288  0.824  1.0
[/CIF]
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The structure described by LiKGdF5 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one F(4), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Li(1) is bonded to one F(2), one F(4), one F(5), and two equivalent F(1) atoms to form distorted corner-sharing LiF5 trigonal pyramids. Gd(1) is bonded in a 8-coordinate geometry to one F(1), one F(5), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent K(1), two equivalent Li(1), and one Gd(1) atom. In the second F site, F(2) is bonded in a 5-coordinate geometry to two equivalent K(1), one Li(1), and two equivalent Gd(1) atoms. In the third F site, F(3) is bonded to two equivalent K(1) and two equivalent Gd(1) atoms to form distorted FK2Gd2 tetrahedra that share corners with four equivalent F(5)K2LiGd tetrahedra,  an edgeedge with one F(5)K2LiGd tetrahedra, and edges with two equivalent F(3)K2Gd2 tetrahedra. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to one K(1), one Li(1), and two equivalent Gd(1) atoms. In the fifth F site, F(5) is bonded to two equivalent K(1), one Li(1), and one Gd(1) atom to form distorted FK2LiGd tetrahedra that share corners with two equivalent F(5)K2LiGd tetrahedra, corners with four equivalent F(3)K2Gd2 tetrahedra, and  an edgeedge with one F(3)K2Gd2 tetrahedra. is represented by the CIF card [CIF]
data_KLiGdF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.529
_cell_length_b   6.336
_cell_length_c   11.731
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   113.410
_symmetry_Int_Tables_number   1
_cell_volume   445.336
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.946  0.961  0.349  1.0
  K  K1  1  0.054  0.039  0.651  1.0
  K  K2  1  0.054  0.539  0.849  1.0
  K  K3  1  0.946  0.461  0.151  1.0
  Li  Li4  1  0.559  0.960  0.744  1.0
  Li  Li5  1  0.441  0.040  0.256  1.0
  Li  Li6  1  0.441  0.540  0.244  1.0
  Li  Li7  1  0.559  0.460  0.756  1.0
  Gd  Gd8  1  0.683  0.820  0.996  1.0
  Gd  Gd9  1  0.317  0.180  0.004  1.0
  Gd  Gd10  1  0.317  0.680  0.496  1.0
  Gd  Gd11  1  0.683  0.320  0.504  1.0
  F  F12  1  0.721  0.778  0.799  1.0
  F  F13  1  0.279  0.222  0.201  1.0
  F  F14  1  0.279  0.722  0.299  1.0
  F  F15  1  0.721  0.278  0.701  1.0
  F  F16  1  0.666  0.951  0.537  1.0
  F  F17  1  0.334  0.049  0.463  1.0
  F  F18  1  0.334  0.549  0.037  1.0
  F  F19  1  0.666  0.451  0.963  1.0
  F  F20  1  0.957  0.678  0.508  1.0
  F  F21  1  0.043  0.322  0.492  1.0
  F  F22  1  0.043  0.822  0.008  1.0
  F  F23  1  0.957  0.178  0.992  1.0
  F  F24  1  0.459  0.961  0.892  1.0
  F  F25  1  0.541  0.039  0.108  1.0
  F  F26  1  0.541  0.539  0.392  1.0
  F  F27  1  0.459  0.461  0.608  1.0
  F  F28  1  0.289  0.788  0.676  1.0
  F  F29  1  0.711  0.212  0.324  1.0
  F  F30  1  0.711  0.712  0.176  1.0
  F  F31  1  0.289  0.288  0.824  1.0
[/CIF]
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