The structure described by RbSF5 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 8-coordinate geometry to four equivalent F(2) and four equivalent F(3) atoms. S(1) is bonded in a square pyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.063
_cell_length_b   7.604
_cell_length_c   9.769
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.377
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.653  0.659  1.0
  Rb  Rb1  1  0.750  0.347  0.341  1.0
  Rb  Rb2  1  0.750  0.153  0.841  1.0
  Rb  Rb3  1  0.250  0.847  0.159  1.0
  S  S4  1  0.250  0.153  0.593  1.0
  S  S5  1  0.750  0.847  0.407  1.0
  S  S6  1  0.750  0.653  0.907  1.0
  S  S7  1  0.250  0.347  0.093  1.0
  F  F8  1  0.250  0.215  0.751  1.0
  F  F9  1  0.750  0.785  0.249  1.0
  F  F10  1  0.750  0.715  0.749  1.0
  F  F11  1  0.250  0.285  0.251  1.0
  F  F12  1  0.957  0.684  0.426  1.0
  F  F13  1  0.457  0.316  0.574  1.0
  F  F14  1  0.043  0.184  0.074  1.0
  F  F15  1  0.543  0.816  0.926  1.0
  F  F16  1  0.451  0.496  0.145  1.0
  F  F17  1  0.951  0.504  0.855  1.0
  F  F18  1  0.549  0.996  0.355  1.0
  F  F19  1  0.049  0.004  0.645  1.0
  F  F20  1  0.549  0.504  0.855  1.0
  F  F21  1  0.049  0.496  0.145  1.0
  F  F22  1  0.451  0.004  0.645  1.0
  F  F23  1  0.951  0.996  0.355  1.0
  F  F24  1  0.457  0.184  0.074  1.0
  F  F25  1  0.957  0.816  0.926  1.0
  F  F26  1  0.543  0.684  0.426  1.0
  F  F27  1  0.043  0.316  0.574  1.0
[/CIF]
.
The structure described by RbSF5 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 8-coordinate geometry to four equivalent F(2) and four equivalent F(3) atoms. S(1) is bonded in a square pyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.063
_cell_length_b   7.604
_cell_length_c   9.769
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.377
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.653  0.659  1.0
  Rb  Rb1  1  0.750  0.347  0.341  1.0
  Rb  Rb2  1  0.750  0.153  0.841  1.0
  Rb  Rb3  1  0.250  0.847  0.159  1.0
  S  S4  1  0.250  0.153  0.593  1.0
  S  S5  1  0.750  0.847  0.407  1.0
  S  S6  1  0.750  0.653  0.907  1.0
  S  S7  1  0.250  0.347  0.093  1.0
  F  F8  1  0.250  0.215  0.751  1.0
  F  F9  1  0.750  0.785  0.249  1.0
  F  F10  1  0.750  0.715  0.749  1.0
  F  F11  1  0.250  0.285  0.251  1.0
  F  F12  1  0.957  0.684  0.426  1.0
  F  F13  1  0.457  0.316  0.574  1.0
  F  F14  1  0.043  0.184  0.074  1.0
  F  F15  1  0.543  0.816  0.926  1.0
  F  F16  1  0.451  0.496  0.145  1.0
  F  F17  1  0.951  0.504  0.855  1.0
  F  F18  1  0.549  0.996  0.355  1.0
  F  F19  1  0.049  0.004  0.645  1.0
  F  F20  1  0.549  0.504  0.855  1.0
  F  F21  1  0.049  0.496  0.145  1.0
  F  F22  1  0.451  0.004  0.645  1.0
  F  F23  1  0.951  0.996  0.355  1.0
  F  F24  1  0.457  0.184  0.074  1.0
  F  F25  1  0.957  0.816  0.926  1.0
  F  F26  1  0.543  0.684  0.426  1.0
  F  F27  1  0.043  0.316  0.574  1.0
[/CIF]
.