The material structure described by B(OH)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight dihydroxyboranyl molecules. B(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(3) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one B(1) and one H(4) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one B(1) and one H(2) atom. is represented by the CIF card [CIF]
data_B(HO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.486
_cell_length_b   8.224
_cell_length_c   9.344
_cell_angle_alpha   58.340
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   620.479
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.930  0.996  0.060  1.0
  B  B1  1  0.070  0.004  0.940  1.0
  B  B2  1  0.430  0.004  0.440  1.0
  B  B3  1  0.570  0.996  0.560  1.0
  B  B4  1  0.557  0.503  0.070  1.0
  B  B5  1  0.443  0.497  0.930  1.0
  B  B6  1  0.057  0.497  0.430  1.0
  B  B7  1  0.943  0.503  0.570  1.0
  H  H8  1  0.774  0.502  0.452  1.0
  H  H9  1  0.226  0.498  0.548  1.0
  H  H10  1  0.274  0.498  0.048  1.0
  H  H11  1  0.726  0.502  0.952  1.0
  H  H12  1  0.721  0.991  0.077  1.0
  H  H13  1  0.279  0.009  0.923  1.0
  H  H14  1  0.221  0.009  0.423  1.0
  H  H15  1  0.779  0.991  0.577  1.0
  H  H16  1  0.573  0.508  0.279  1.0
  H  H17  1  0.427  0.492  0.721  1.0
  H  H18  1  0.073  0.492  0.221  1.0
  H  H19  1  0.927  0.508  0.779  1.0
  H  H20  1  0.546  0.003  0.269  1.0
  H  H21  1  0.454  0.997  0.731  1.0
  H  H22  1  0.046  0.997  0.231  1.0
  H  H23  1  0.954  0.003  0.769  1.0
  O  O24  1  0.502  0.505  0.205  1.0
  O  O25  1  0.498  0.495  0.795  1.0
  O  O26  1  0.002  0.495  0.295  1.0
  O  O27  1  0.998  0.505  0.705  1.0
  O  O28  1  0.701  0.504  0.053  1.0
  O  O29  1  0.299  0.496  0.947  1.0
  O  O30  1  0.201  0.496  0.447  1.0
  O  O31  1  0.799  0.504  0.553  1.0
  O  O32  1  0.946  0.993  0.208  1.0
  O  O33  1  0.054  0.007  0.792  1.0
  O  O34  1  0.446  0.007  0.292  1.0
  O  O35  1  0.554  0.993  0.708  1.0
  O  O36  1  0.796  0.995  0.004  1.0
  O  O37  1  0.204  0.005  0.996  1.0
  O  O38  1  0.296  0.005  0.496  1.0
  O  O39  1  0.704  0.995  0.504  1.0
[/CIF]
.
The material structure described by B(OH)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight dihydroxyboranyl molecules. B(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(3) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one B(1) and one H(4) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one B(1) and one H(2) atom. is represented by the CIF card [CIF]
data_B(HO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.486
_cell_length_b   8.224
_cell_length_c   9.344
_cell_angle_alpha   58.340
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   620.479
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.930  0.996  0.060  1.0
  B  B1  1  0.070  0.004  0.940  1.0
  B  B2  1  0.430  0.004  0.440  1.0
  B  B3  1  0.570  0.996  0.560  1.0
  B  B4  1  0.557  0.503  0.070  1.0
  B  B5  1  0.443  0.497  0.930  1.0
  B  B6  1  0.057  0.497  0.430  1.0
  B  B7  1  0.943  0.503  0.570  1.0
  H  H8  1  0.774  0.502  0.452  1.0
  H  H9  1  0.226  0.498  0.548  1.0
  H  H10  1  0.274  0.498  0.048  1.0
  H  H11  1  0.726  0.502  0.952  1.0
  H  H12  1  0.721  0.991  0.077  1.0
  H  H13  1  0.279  0.009  0.923  1.0
  H  H14  1  0.221  0.009  0.423  1.0
  H  H15  1  0.779  0.991  0.577  1.0
  H  H16  1  0.573  0.508  0.279  1.0
  H  H17  1  0.427  0.492  0.721  1.0
  H  H18  1  0.073  0.492  0.221  1.0
  H  H19  1  0.927  0.508  0.779  1.0
  H  H20  1  0.546  0.003  0.269  1.0
  H  H21  1  0.454  0.997  0.731  1.0
  H  H22  1  0.046  0.997  0.231  1.0
  H  H23  1  0.954  0.003  0.769  1.0
  O  O24  1  0.502  0.505  0.205  1.0
  O  O25  1  0.498  0.495  0.795  1.0
  O  O26  1  0.002  0.495  0.295  1.0
  O  O27  1  0.998  0.505  0.705  1.0
  O  O28  1  0.701  0.504  0.053  1.0
  O  O29  1  0.299  0.496  0.947  1.0
  O  O30  1  0.201  0.496  0.447  1.0
  O  O31  1  0.799  0.504  0.553  1.0
  O  O32  1  0.946  0.993  0.208  1.0
  O  O33  1  0.054  0.007  0.792  1.0
  O  O34  1  0.446  0.007  0.292  1.0
  O  O35  1  0.554  0.993  0.708  1.0
  O  O36  1  0.796  0.995  0.004  1.0
  O  O37  1  0.204  0.005  0.996  1.0
  O  O38  1  0.296  0.005  0.496  1.0
  O  O39  1  0.704  0.995  0.504  1.0
[/CIF]
.