The structure described by Tl5Sb10As3S22 crystallizes in the triclinic P1 space group. There are five inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 3-coordinate geometry to one S(19), one S(3), and one S(8) atom. In the second Tl site, Tl(2) is bonded in a 3-coordinate geometry to one S(20), one S(4), and one S(7) atom. In the third Tl site, Tl(3) is bonded in a distorted rectangular see-saw-like geometry to one S(10), one S(4), one S(5), and one S(7) atom. In the fourth Tl site, Tl(4) is bonded in a distorted rectangular see-saw-like geometry to one S(3), one S(6), one S(8), and one S(9) atom. In the fifth Tl site, Tl(5) is bonded in a bent 150 degrees geometry to one S(10) and one S(6) atom. There are ten inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one S(11), one S(18), one S(21), and one S(9) atom. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to one S(10), one S(12), one S(17), and one S(22) atom. In the third Sb site, Sb(3) is bonded in an L-shaped geometry to one S(20) and one S(3) atom. In the fourth Sb site, Sb(4) is bonded in a distorted L-shaped geometry to one S(19), one S(4), and one S(7) atom. In the fifth Sb site, Sb(5) is bonded in a distorted T-shaped geometry to one S(13), one S(15), and one S(16) atom. In the sixth Sb site, Sb(6) is bonded in a T-shaped geometry to one S(14), one S(15), and one S(16) atom. In the seventh Sb site, Sb(7) is bonded in a 4-coordinate geometry to one S(1), one S(22), one S(4), and one S(7) atom. In the eighth Sb site, Sb(8) is bonded in a 5-coordinate geometry to one S(2), one S(21), one S(3), one S(6), and one S(8) atom. In the ninth Sb site, Sb(9) is bonded in a distorted see-saw-like geometry to one S(17), one S(18), one S(5), and one S(9) atom. In the tenth Sb site, Sb(10) is bonded in a 4-coordinate geometry to one S(12), one S(13), one S(15), and one S(7) atom. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted rectangular see-saw-like geometry to one S(11), one S(14), one S(16), and one S(8) atom. In the second As site, As(2) is bonded in a 4-coordinate geometry to one S(17), one S(2), one S(6), and one S(9) atom. In the third As site, As(3) is bonded in a 4-coordinate geometry to one S(1), one S(10), one S(18), and one S(5) atom. There are twenty-two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one Sb(7) and one As(3) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one Sb(8) and one As(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Tl(1), one Tl(4), one Sb(3), and one Sb(8) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Tl(2), one Tl(3), one Sb(4), and one Sb(7) atom. In the fifth S site, S(5) is bonded in a 2-coordinate geometry to one Tl(3), one Sb(9), and one As(3) atom. In the sixth S site, S(6) is bonded in a rectangular see-saw-like geometry to one Tl(4), one Tl(5), one Sb(8), and one As(2) atom. In the seventh S site, S(7) is bonded in a 5-coordinate geometry to one Tl(2), one Tl(3), one Sb(10), one Sb(4), and one Sb(7) atom. In the eighth S site, S(8) is bonded in a 4-coordinate geometry to one Tl(1), one Tl(4), one Sb(8), and one As(1) atom. In the ninth S site, S(9) is bonded in a 4-coordinate geometry to one Tl(4), one Sb(1), one Sb(9), and one As(2) atom. In the tenth S site, S(10) is bonded in a distorted tetrahedral geometry to one Tl(3), one Tl(5), one Sb(2), and one As(3) atom. In the eleventh S site, S(11) is bonded in a 1-coordinate geometry to one Sb(1) and one As(1) atom. In the twelfth S site, S(12) is bonded in a distorted single-bond geometry to one Sb(10) and one Sb(2) atom. In the thirteenth S site, S(13) is bonded in a water-like geometry to one Sb(10) and one Sb(5) atom. In the fourteenth S site, S(14) is bonded in a water-like geometry to one Sb(6) and one As(1) atom. In the fifteenth S site, S(15) is bonded in a T-shaped geometry to one Sb(10), one Sb(5), and one Sb(6) atom. In the sixteenth S site, S(16) is bonded in a T-shaped geometry to one Sb(5), one Sb(6), and one As(1) atom. In the seventeenth S site, S(17) is bonded in a 3-coordinate geometry to one Sb(2), one Sb(9), and one As(2) atom. In the eighteenth S site, S(18) is bonded in a T-shaped geometry to one Sb(1), one Sb(9), and one As(3) atom. In the nineteenth S site, S(19) is bonded in a bent 150 degrees geometry to one Tl(1) and one Sb(4) atom. In the twentieth S site, S(20) is bonded in a bent 150 degrees geometry to one Tl(2) and one Sb(3) atom. In the twenty-first S site, S(21) is bonded in a distorted water-like geometry to one Sb(1) and one Sb(8) atom. In the twenty-second S site, S(22) is bonded in a distorted water-like geometry to one Sb(2) and one Sb(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tl5Sb10As3S22
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.656
_cell_length_b   8.862
_cell_length_c   17.997
_cell_angle_alpha   103.465
_cell_angle_beta   91.466
_cell_angle_gamma   109.771
_symmetry_Int_Tables_number   1
_cell_volume   1110.139
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.684  0.128  0.623  1.0
  Tl  Tl1  1  0.316  0.873  0.378  1.0
  Tl  Tl2  1  0.229  0.462  0.185  1.0
  Tl  Tl3  1  0.769  0.543  0.815  1.0
  Tl  Tl4  1  0.798  0.957  0.975  1.0
  Sb  Sb5  1  0.286  0.968  0.811  1.0
  Sb  Sb6  1  0.710  0.031  0.191  1.0
  Sb  Sb7  1  0.167  0.202  0.596  1.0
  Sb  Sb8  1  0.839  0.801  0.405  1.0
  Sb  Sb9  1  0.414  0.383  0.412  1.0
  Sb  Sb10  1  0.578  0.615  0.589  1.0
  Sb  Sb11  1  0.762  0.616  0.208  1.0
  Sb  Sb12  1  0.241  0.384  0.798  1.0
  Sb  Sb13  1  0.314  0.053  0.018  1.0
  Sb  Sb14  1  0.864  0.279  0.393  1.0
  As  As15  1  0.139  0.714  0.619  1.0
  As  As16  1  0.264  0.581  0.967  1.0
  As  As17  1  0.751  0.416  0.029  1.0
  S  S18  1  0.913  0.628  0.092  1.0
  S  S19  1  0.071  0.365  0.908  1.0
  S  S20  1  0.444  0.275  0.689  1.0
  S  S21  1  0.565  0.731  0.309  1.0
  S  S22  1  0.485  0.291  0.090  1.0
  S  S23  1  0.498  0.687  0.897  1.0
  S  S24  1  0.014  0.550  0.308  1.0
  S  S25  1  0.996  0.460  0.690  1.0
  S  S26  1  0.092  0.769  0.916  1.0
  S  S27  1  0.916  0.236  0.088  1.0
  S  S28  1  0.052  0.870  0.680  1.0
  S  S29  1  0.964  0.122  0.322  1.0
  S  S30  1  0.545  0.250  0.328  1.0
  S  S31  1  0.443  0.749  0.671  1.0
  S  S32  1  0.719  0.477  0.488  1.0
  S  S33  1  0.275  0.520  0.512  1.0
  S  S34  1  0.482  0.854  0.093  1.0
  S  S35  1  0.498  0.171  0.908  1.0
  S  S36  1  0.694  0.893  0.491  1.0
  S  S37  1  0.306  0.109  0.508  1.0
  S  S38  1  0.030  0.099  0.795  1.0
  S  S39  1  0.962  0.904  0.197  1.0
[/CIF]
.
The structure described by Tl5Sb10As3S22 crystallizes in the triclinic P1 space group. There are five inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 3-coordinate geometry to one S(19), one S(3), and one S(8) atom. In the second Tl site, Tl(2) is bonded in a 3-coordinate geometry to one S(20), one S(4), and one S(7) atom. In the third Tl site, Tl(3) is bonded in a distorted rectangular see-saw-like geometry to one S(10), one S(4), one S(5), and one S(7) atom. In the fourth Tl site, Tl(4) is bonded in a distorted rectangular see-saw-like geometry to one S(3), one S(6), one S(8), and one S(9) atom. In the fifth Tl site, Tl(5) is bonded in a bent 150 degrees geometry to one S(10) and one S(6) atom. There are ten inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one S(11), one S(18), one S(21), and one S(9) atom. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to one S(10), one S(12), one S(17), and one S(22) atom. In the third Sb site, Sb(3) is bonded in an L-shaped geometry to one S(20) and one S(3) atom. In the fourth Sb site, Sb(4) is bonded in a distorted L-shaped geometry to one S(19), one S(4), and one S(7) atom. In the fifth Sb site, Sb(5) is bonded in a distorted T-shaped geometry to one S(13), one S(15), and one S(16) atom. In the sixth Sb site, Sb(6) is bonded in a T-shaped geometry to one S(14), one S(15), and one S(16) atom. In the seventh Sb site, Sb(7) is bonded in a 4-coordinate geometry to one S(1), one S(22), one S(4), and one S(7) atom. In the eighth Sb site, Sb(8) is bonded in a 5-coordinate geometry to one S(2), one S(21), one S(3), one S(6), and one S(8) atom. In the ninth Sb site, Sb(9) is bonded in a distorted see-saw-like geometry to one S(17), one S(18), one S(5), and one S(9) atom. In the tenth Sb site, Sb(10) is bonded in a 4-coordinate geometry to one S(12), one S(13), one S(15), and one S(7) atom. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted rectangular see-saw-like geometry to one S(11), one S(14), one S(16), and one S(8) atom. In the second As site, As(2) is bonded in a 4-coordinate geometry to one S(17), one S(2), one S(6), and one S(9) atom. In the third As site, As(3) is bonded in a 4-coordinate geometry to one S(1), one S(10), one S(18), and one S(5) atom. There are twenty-two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one Sb(7) and one As(3) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one Sb(8) and one As(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Tl(1), one Tl(4), one Sb(3), and one Sb(8) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Tl(2), one Tl(3), one Sb(4), and one Sb(7) atom. In the fifth S site, S(5) is bonded in a 2-coordinate geometry to one Tl(3), one Sb(9), and one As(3) atom. In the sixth S site, S(6) is bonded in a rectangular see-saw-like geometry to one Tl(4), one Tl(5), one Sb(8), and one As(2) atom. In the seventh S site, S(7) is bonded in a 5-coordinate geometry to one Tl(2), one Tl(3), one Sb(10), one Sb(4), and one Sb(7) atom. In the eighth S site, S(8) is bonded in a 4-coordinate geometry to one Tl(1), one Tl(4), one Sb(8), and one As(1) atom. In the ninth S site, S(9) is bonded in a 4-coordinate geometry to one Tl(4), one Sb(1), one Sb(9), and one As(2) atom. In the tenth S site, S(10) is bonded in a distorted tetrahedral geometry to one Tl(3), one Tl(5), one Sb(2), and one As(3) atom. In the eleventh S site, S(11) is bonded in a 1-coordinate geometry to one Sb(1) and one As(1) atom. In the twelfth S site, S(12) is bonded in a distorted single-bond geometry to one Sb(10) and one Sb(2) atom. In the thirteenth S site, S(13) is bonded in a water-like geometry to one Sb(10) and one Sb(5) atom. In the fourteenth S site, S(14) is bonded in a water-like geometry to one Sb(6) and one As(1) atom. In the fifteenth S site, S(15) is bonded in a T-shaped geometry to one Sb(10), one Sb(5), and one Sb(6) atom. In the sixteenth S site, S(16) is bonded in a T-shaped geometry to one Sb(5), one Sb(6), and one As(1) atom. In the seventeenth S site, S(17) is bonded in a 3-coordinate geometry to one Sb(2), one Sb(9), and one As(2) atom. In the eighteenth S site, S(18) is bonded in a T-shaped geometry to one Sb(1), one Sb(9), and one As(3) atom. In the nineteenth S site, S(19) is bonded in a bent 150 degrees geometry to one Tl(1) and one Sb(4) atom. In the twentieth S site, S(20) is bonded in a bent 150 degrees geometry to one Tl(2) and one Sb(3) atom. In the twenty-first S site, S(21) is bonded in a distorted water-like geometry to one Sb(1) and one Sb(8) atom. In the twenty-second S site, S(22) is bonded in a distorted water-like geometry to one Sb(2) and one Sb(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tl5Sb10As3S22
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.656
_cell_length_b   8.862
_cell_length_c   17.997
_cell_angle_alpha   103.465
_cell_angle_beta   91.466
_cell_angle_gamma   109.771
_symmetry_Int_Tables_number   1
_cell_volume   1110.139
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.684  0.128  0.623  1.0
  Tl  Tl1  1  0.316  0.873  0.378  1.0
  Tl  Tl2  1  0.229  0.462  0.185  1.0
  Tl  Tl3  1  0.769  0.543  0.815  1.0
  Tl  Tl4  1  0.798  0.957  0.975  1.0
  Sb  Sb5  1  0.286  0.968  0.811  1.0
  Sb  Sb6  1  0.710  0.031  0.191  1.0
  Sb  Sb7  1  0.167  0.202  0.596  1.0
  Sb  Sb8  1  0.839  0.801  0.405  1.0
  Sb  Sb9  1  0.414  0.383  0.412  1.0
  Sb  Sb10  1  0.578  0.615  0.589  1.0
  Sb  Sb11  1  0.762  0.616  0.208  1.0
  Sb  Sb12  1  0.241  0.384  0.798  1.0
  Sb  Sb13  1  0.314  0.053  0.018  1.0
  Sb  Sb14  1  0.864  0.279  0.393  1.0
  As  As15  1  0.139  0.714  0.619  1.0
  As  As16  1  0.264  0.581  0.967  1.0
  As  As17  1  0.751  0.416  0.029  1.0
  S  S18  1  0.913  0.628  0.092  1.0
  S  S19  1  0.071  0.365  0.908  1.0
  S  S20  1  0.444  0.275  0.689  1.0
  S  S21  1  0.565  0.731  0.309  1.0
  S  S22  1  0.485  0.291  0.090  1.0
  S  S23  1  0.498  0.687  0.897  1.0
  S  S24  1  0.014  0.550  0.308  1.0
  S  S25  1  0.996  0.460  0.690  1.0
  S  S26  1  0.092  0.769  0.916  1.0
  S  S27  1  0.916  0.236  0.088  1.0
  S  S28  1  0.052  0.870  0.680  1.0
  S  S29  1  0.964  0.122  0.322  1.0
  S  S30  1  0.545  0.250  0.328  1.0
  S  S31  1  0.443  0.749  0.671  1.0
  S  S32  1  0.719  0.477  0.488  1.0
  S  S33  1  0.275  0.520  0.512  1.0
  S  S34  1  0.482  0.854  0.093  1.0
  S  S35  1  0.498  0.171  0.908  1.0
  S  S36  1  0.694  0.893  0.491  1.0
  S  S37  1  0.306  0.109  0.508  1.0
  S  S38  1  0.030  0.099  0.795  1.0
  S  S39  1  0.962  0.904  0.197  1.0
[/CIF]
.