The material structure described by KTh2F9 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 6-coordinate geometry to two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Th(1) is bonded in a 9-coordinate geometry to one F(4), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(4) is bonded in a linear geometry to two equivalent Th(1) atoms. In the second F site, F(5) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Th(1) atoms. In the third F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Th(1) atoms. In the fourth F site, F(2) is bonded in a trigonal planar geometry to one K(1) and two equivalent Th(1) atoms. In the fifth F site, F(3) is bonded in a trigonal planar geometry to one K(1) and two equivalent Th(1) atoms. is represented by the CIF card [CIF]
data_KTh2F9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.170
_cell_length_b   8.857
_cell_length_c   11.644
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   739.469
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.646  0.035  0.250  1.0
  K  K1  1  0.354  0.965  0.750  1.0
  K  K2  1  0.146  0.465  0.750  1.0
  K  K3  1  0.854  0.535  0.250  1.0
  Th  Th4  1  0.154  0.175  0.050  1.0
  Th  Th5  1  0.846  0.825  0.950  1.0
  Th  Th6  1  0.654  0.325  0.950  1.0
  Th  Th7  1  0.846  0.825  0.550  1.0
  Th  Th8  1  0.346  0.675  0.050  1.0
  Th  Th9  1  0.154  0.175  0.450  1.0
  Th  Th10  1  0.346  0.675  0.450  1.0
  Th  Th11  1  0.654  0.325  0.550  1.0
  F  F12  1  0.199  0.435  0.080  1.0
  F  F13  1  0.801  0.565  0.920  1.0
  F  F14  1  0.699  0.065  0.920  1.0
  F  F15  1  0.801  0.565  0.580  1.0
  F  F16  1  0.301  0.935  0.080  1.0
  F  F17  1  0.199  0.435  0.420  1.0
  F  F18  1  0.301  0.935  0.420  1.0
  F  F19  1  0.699  0.065  0.580  1.0
  F  F20  1  0.077  0.003  0.599  1.0
  F  F21  1  0.923  0.997  0.401  1.0
  F  F22  1  0.577  0.497  0.401  1.0
  F  F23  1  0.923  0.997  0.099  1.0
  F  F24  1  0.423  0.503  0.599  1.0
  F  F25  1  0.077  0.003  0.901  1.0
  F  F26  1  0.423  0.503  0.901  1.0
  F  F27  1  0.577  0.497  0.099  1.0
  F  F28  1  0.473  0.208  0.097  1.0
  F  F29  1  0.527  0.792  0.903  1.0
  F  F30  1  0.973  0.292  0.903  1.0
  F  F31  1  0.527  0.792  0.597  1.0
  F  F32  1  0.027  0.708  0.097  1.0
  F  F33  1  0.473  0.208  0.403  1.0
  F  F34  1  0.027  0.708  0.403  1.0
  F  F35  1  0.973  0.292  0.597  1.0
  F  F36  1  0.163  0.176  0.250  1.0
  F  F37  1  0.837  0.824  0.750  1.0
  F  F38  1  0.663  0.324  0.750  1.0
  F  F39  1  0.337  0.676  0.250  1.0
  F  F40  1  0.357  0.215  0.608  1.0
  F  F41  1  0.643  0.785  0.392  1.0
  F  F42  1  0.857  0.285  0.392  1.0
  F  F43  1  0.643  0.785  0.108  1.0
  F  F44  1  0.143  0.715  0.608  1.0
  F  F45  1  0.357  0.215  0.892  1.0
  F  F46  1  0.143  0.715  0.892  1.0
  F  F47  1  0.857  0.285  0.108  1.0
[/CIF]
.
The material structure described by KTh2F9 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 6-coordinate geometry to two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Th(1) is bonded in a 9-coordinate geometry to one F(4), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(4) is bonded in a linear geometry to two equivalent Th(1) atoms. In the second F site, F(5) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Th(1) atoms. In the third F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Th(1) atoms. In the fourth F site, F(2) is bonded in a trigonal planar geometry to one K(1) and two equivalent Th(1) atoms. In the fifth F site, F(3) is bonded in a trigonal planar geometry to one K(1) and two equivalent Th(1) atoms. is represented by the CIF card [CIF]
data_KTh2F9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.170
_cell_length_b   8.857
_cell_length_c   11.644
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   739.469
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.646  0.035  0.250  1.0
  K  K1  1  0.354  0.965  0.750  1.0
  K  K2  1  0.146  0.465  0.750  1.0
  K  K3  1  0.854  0.535  0.250  1.0
  Th  Th4  1  0.154  0.175  0.050  1.0
  Th  Th5  1  0.846  0.825  0.950  1.0
  Th  Th6  1  0.654  0.325  0.950  1.0
  Th  Th7  1  0.846  0.825  0.550  1.0
  Th  Th8  1  0.346  0.675  0.050  1.0
  Th  Th9  1  0.154  0.175  0.450  1.0
  Th  Th10  1  0.346  0.675  0.450  1.0
  Th  Th11  1  0.654  0.325  0.550  1.0
  F  F12  1  0.199  0.435  0.080  1.0
  F  F13  1  0.801  0.565  0.920  1.0
  F  F14  1  0.699  0.065  0.920  1.0
  F  F15  1  0.801  0.565  0.580  1.0
  F  F16  1  0.301  0.935  0.080  1.0
  F  F17  1  0.199  0.435  0.420  1.0
  F  F18  1  0.301  0.935  0.420  1.0
  F  F19  1  0.699  0.065  0.580  1.0
  F  F20  1  0.077  0.003  0.599  1.0
  F  F21  1  0.923  0.997  0.401  1.0
  F  F22  1  0.577  0.497  0.401  1.0
  F  F23  1  0.923  0.997  0.099  1.0
  F  F24  1  0.423  0.503  0.599  1.0
  F  F25  1  0.077  0.003  0.901  1.0
  F  F26  1  0.423  0.503  0.901  1.0
  F  F27  1  0.577  0.497  0.099  1.0
  F  F28  1  0.473  0.208  0.097  1.0
  F  F29  1  0.527  0.792  0.903  1.0
  F  F30  1  0.973  0.292  0.903  1.0
  F  F31  1  0.527  0.792  0.597  1.0
  F  F32  1  0.027  0.708  0.097  1.0
  F  F33  1  0.473  0.208  0.403  1.0
  F  F34  1  0.027  0.708  0.403  1.0
  F  F35  1  0.973  0.292  0.597  1.0
  F  F36  1  0.163  0.176  0.250  1.0
  F  F37  1  0.837  0.824  0.750  1.0
  F  F38  1  0.663  0.324  0.750  1.0
  F  F39  1  0.337  0.676  0.250  1.0
  F  F40  1  0.357  0.215  0.608  1.0
  F  F41  1  0.643  0.785  0.392  1.0
  F  F42  1  0.857  0.285  0.392  1.0
  F  F43  1  0.643  0.785  0.108  1.0
  F  F44  1  0.143  0.715  0.608  1.0
  F  F45  1  0.357  0.215  0.892  1.0
  F  F46  1  0.143  0.715  0.892  1.0
  F  F47  1  0.857  0.285  0.108  1.0
[/CIF]
.