The crystal structure described by (BiPO4)3O2 crystallizes in the monoclinic C2 space group. The structure consists of two hydrogen peroxide molecules inside a BiPO4 framework. In the BiPO4 framework, there are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Bi(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Bi(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Bi(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Bi(1), one Bi(2), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Bi(1), one Bi(2), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Bi3P3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.159
_cell_length_b   7.159
_cell_length_c   6.491
_cell_angle_alpha   89.490
_cell_angle_beta   89.490
_cell_angle_gamma   59.872
_symmetry_Int_Tables_number   1
_cell_volume   287.678
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.512  0.996  0.336  1.0
  Bi  Bi1  1  0.493  0.507  0.000  1.0
  Bi  Bi2  1  0.004  0.488  0.664  1.0
  P  P3  1  0.554  1.000  0.832  1.0
  P  P4  1  0.450  0.550  0.500  1.0
  P  P5  1  0.000  0.446  0.168  1.0
  O  O6  1  0.753  0.849  0.696  1.0
  O  O7  1  0.404  0.752  0.372  1.0
  O  O8  1  0.844  0.403  0.040  1.0
  O  O9  1  0.248  0.596  0.628  1.0
  O  O10  1  0.151  0.247  0.304  1.0
  O  O11  1  0.597  0.156  0.960  1.0
  O  O12  1  0.500  0.872  0.995  1.0
  O  O13  1  0.633  0.489  0.660  1.0
  O  O14  1  0.878  0.633  0.325  1.0
  O  O15  1  0.511  0.367  0.340  1.0
  O  O16  1  0.128  0.500  0.005  1.0
  O  O17  1  0.367  0.122  0.675  1.0
  O  O18  1  0.054  0.964  0.906  1.0
  O  O19  1  0.036  0.946  0.094  1.0
[/CIF]
.
The crystal structure described by (BiPO4)3O2 crystallizes in the monoclinic C2 space group. The structure consists of two hydrogen peroxide molecules inside a BiPO4 framework. In the BiPO4 framework, there are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Bi(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Bi(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Bi(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Bi(1), one Bi(2), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Bi(1), one Bi(2), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Bi3P3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.159
_cell_length_b   7.159
_cell_length_c   6.491
_cell_angle_alpha   89.490
_cell_angle_beta   89.490
_cell_angle_gamma   59.872
_symmetry_Int_Tables_number   1
_cell_volume   287.678
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.512  0.996  0.336  1.0
  Bi  Bi1  1  0.493  0.507  0.000  1.0
  Bi  Bi2  1  0.004  0.488  0.664  1.0
  P  P3  1  0.554  1.000  0.832  1.0
  P  P4  1  0.450  0.550  0.500  1.0
  P  P5  1  0.000  0.446  0.168  1.0
  O  O6  1  0.753  0.849  0.696  1.0
  O  O7  1  0.404  0.752  0.372  1.0
  O  O8  1  0.844  0.403  0.040  1.0
  O  O9  1  0.248  0.596  0.628  1.0
  O  O10  1  0.151  0.247  0.304  1.0
  O  O11  1  0.597  0.156  0.960  1.0
  O  O12  1  0.500  0.872  0.995  1.0
  O  O13  1  0.633  0.489  0.660  1.0
  O  O14  1  0.878  0.633  0.325  1.0
  O  O15  1  0.511  0.367  0.340  1.0
  O  O16  1  0.128  0.500  0.005  1.0
  O  O17  1  0.367  0.122  0.675  1.0
  O  O18  1  0.054  0.964  0.906  1.0
  O  O19  1  0.036  0.946  0.094  1.0
[/CIF]
.