The crystal structure described by Os2O3F7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Os2O3F7 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(6), and one F(7) atom. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one F(4), one F(5), and one F(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(2) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Os(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Os(2) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Os(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Os2O3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.946
_cell_length_b   5.464
_cell_length_c   12.190
_cell_angle_alpha   80.717
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   653.834
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.253  0.010  0.999  1.0
  Os  Os1  1  0.753  0.990  0.501  1.0
  Os  Os2  1  0.747  0.990  0.001  1.0
  Os  Os3  1  0.512  0.351  0.280  1.0
  Os  Os4  1  0.247  0.010  0.499  1.0
  Os  Os5  1  0.988  0.351  0.780  1.0
  Os  Os6  1  0.012  0.649  0.220  1.0
  Os  Os7  1  0.488  0.649  0.720  1.0
  O  O8  1  0.565  0.461  0.641  1.0
  O  O9  1  0.074  0.408  0.659  1.0
  O  O10  1  0.662  0.489  0.250  1.0
  O  O11  1  0.935  0.461  0.141  1.0
  O  O12  1  0.065  0.539  0.859  1.0
  O  O13  1  0.338  0.511  0.750  1.0
  O  O14  1  0.926  0.592  0.341  1.0
  O  O15  1  0.435  0.539  0.359  1.0
  O  O16  1  0.574  0.592  0.841  1.0
  O  O17  1  0.838  0.489  0.750  1.0
  O  O18  1  0.162  0.511  0.250  1.0
  O  O19  1  0.426  0.408  0.159  1.0
  F  F20  1  0.401  0.199  0.944  1.0
  F  F21  1  0.834  0.090  0.363  1.0
  F  F22  1  0.175  0.284  0.050  1.0
  F  F23  1  0.842  0.899  0.144  1.0
  F  F24  1  0.939  0.023  0.772  1.0
  F  F25  1  0.599  0.801  0.056  1.0
  F  F26  1  0.334  0.910  0.137  1.0
  F  F27  1  0.323  0.734  0.944  1.0
  F  F28  1  0.158  0.101  0.856  1.0
  F  F29  1  0.675  0.716  0.450  1.0
  F  F30  1  0.825  0.716  0.950  1.0
  F  F31  1  0.177  0.734  0.444  1.0
  F  F32  1  0.677  0.266  0.056  1.0
  F  F33  1  0.658  0.899  0.644  1.0
  F  F34  1  0.906  0.193  0.947  1.0
  F  F35  1  0.594  0.193  0.447  1.0
  F  F36  1  0.901  0.801  0.556  1.0
  F  F37  1  0.325  0.284  0.550  1.0
  F  F38  1  0.166  0.910  0.637  1.0
  F  F39  1  0.406  0.807  0.553  1.0
  F  F40  1  0.342  0.101  0.356  1.0
  F  F41  1  0.823  0.266  0.556  1.0
  F  F42  1  0.666  0.090  0.863  1.0
  F  F43  1  0.439  0.977  0.728  1.0
  F  F44  1  0.061  0.977  0.228  1.0
  F  F45  1  0.094  0.807  0.053  1.0
  F  F46  1  0.099  0.199  0.444  1.0
  F  F47  1  0.561  0.023  0.272  1.0
[/CIF]
.
The crystal structure described by Os2O3F7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Os2O3F7 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(6), and one F(7) atom. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one F(4), one F(5), and one F(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(2) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Os(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Os(2) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Os(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Os2O3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.946
_cell_length_b   5.464
_cell_length_c   12.190
_cell_angle_alpha   80.717
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   653.834
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.253  0.010  0.999  1.0
  Os  Os1  1  0.753  0.990  0.501  1.0
  Os  Os2  1  0.747  0.990  0.001  1.0
  Os  Os3  1  0.512  0.351  0.280  1.0
  Os  Os4  1  0.247  0.010  0.499  1.0
  Os  Os5  1  0.988  0.351  0.780  1.0
  Os  Os6  1  0.012  0.649  0.220  1.0
  Os  Os7  1  0.488  0.649  0.720  1.0
  O  O8  1  0.565  0.461  0.641  1.0
  O  O9  1  0.074  0.408  0.659  1.0
  O  O10  1  0.662  0.489  0.250  1.0
  O  O11  1  0.935  0.461  0.141  1.0
  O  O12  1  0.065  0.539  0.859  1.0
  O  O13  1  0.338  0.511  0.750  1.0
  O  O14  1  0.926  0.592  0.341  1.0
  O  O15  1  0.435  0.539  0.359  1.0
  O  O16  1  0.574  0.592  0.841  1.0
  O  O17  1  0.838  0.489  0.750  1.0
  O  O18  1  0.162  0.511  0.250  1.0
  O  O19  1  0.426  0.408  0.159  1.0
  F  F20  1  0.401  0.199  0.944  1.0
  F  F21  1  0.834  0.090  0.363  1.0
  F  F22  1  0.175  0.284  0.050  1.0
  F  F23  1  0.842  0.899  0.144  1.0
  F  F24  1  0.939  0.023  0.772  1.0
  F  F25  1  0.599  0.801  0.056  1.0
  F  F26  1  0.334  0.910  0.137  1.0
  F  F27  1  0.323  0.734  0.944  1.0
  F  F28  1  0.158  0.101  0.856  1.0
  F  F29  1  0.675  0.716  0.450  1.0
  F  F30  1  0.825  0.716  0.950  1.0
  F  F31  1  0.177  0.734  0.444  1.0
  F  F32  1  0.677  0.266  0.056  1.0
  F  F33  1  0.658  0.899  0.644  1.0
  F  F34  1  0.906  0.193  0.947  1.0
  F  F35  1  0.594  0.193  0.447  1.0
  F  F36  1  0.901  0.801  0.556  1.0
  F  F37  1  0.325  0.284  0.550  1.0
  F  F38  1  0.166  0.910  0.637  1.0
  F  F39  1  0.406  0.807  0.553  1.0
  F  F40  1  0.342  0.101  0.356  1.0
  F  F41  1  0.823  0.266  0.556  1.0
  F  F42  1  0.666  0.090  0.863  1.0
  F  F43  1  0.439  0.977  0.728  1.0
  F  F44  1  0.061  0.977  0.228  1.0
  F  F45  1  0.094  0.807  0.053  1.0
  F  F46  1  0.099  0.199  0.444  1.0
  F  F47  1  0.561  0.023  0.272  1.0
[/CIF]
.