The structure described by Mg14LaCo crystallizes in the orthorhombic Amm2 space group. There are seven inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2), two equivalent Mg(6), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent La(1)Mg10Co2 cuboctahedra, corners with six equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, and faces with two equivalent Mg(2)Mg12 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1), two equivalent Mg(7), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with six equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, and faces with two equivalent La(1)Mg10Co2 cuboctahedra. In the third Mg site, Mg(3) is bonded in a distorted single-bond geometry to two equivalent Mg(5), two equivalent Mg(7), two equivalent La(1), and one Co(1) atom. In the fourth Mg site, Mg(4) is bonded in a 10-coordinate geometry to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), and two equivalent Mg(7) atoms. In the fifth Mg site, Mg(5) is bonded in a 12-coordinate geometry to one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), one La(1), and one Co(1) atom. In the sixth Mg site, Mg(6) is bonded in a distorted single-bond geometry to one Mg(1), two equivalent Mg(7), four equivalent Mg(5), and one Co(1) atom. In the seventh Mg site, Mg(7) is bonded in a 12-coordinate geometry to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), four equivalent Mg(5), and one La(1) atom. La(1) is bonded to two equivalent Mg(7), four equivalent Mg(3), four equivalent Mg(5), and two equivalent Co(1) atoms to form distorted LaMg10Co2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra, corners with six equivalent La(1)Mg10Co2 cuboctahedra, and faces with two equivalent Mg(2)Mg12 cuboctahedra. Co(1) is bonded in a 10-coordinate geometry to two equivalent Mg(3), two equivalent Mg(6), four equivalent Mg(5), and two equivalent La(1) atoms. is represented by the CIF file [CIF]
data_LaMg14Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.580
_cell_length_b   6.054
_cell_length_c   10.347
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   117.391
_symmetry_Int_Tables_number   1
_cell_volume   365.996
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.126  0.813  0.125  1.0
  Mg  Mg1  1  0.155  0.328  0.625  1.0
  Mg  Mg2  1  0.166  0.833  0.625  1.0
  Mg  Mg3  1  0.617  0.319  0.125  1.0
  Mg  Mg4  1  0.660  0.327  0.625  1.0
  Mg  Mg5  1  0.617  0.797  0.125  1.0
  Mg  Mg6  1  0.660  0.832  0.625  1.0
  Mg  Mg7  1  0.346  0.178  0.377  1.0
  Mg  Mg8  1  0.346  0.178  0.873  1.0
  Mg  Mg9  1  0.346  0.668  0.377  1.0
  Mg  Mg10  1  0.346  0.668  0.873  1.0
  Mg  Mg11  1  0.877  0.188  0.338  1.0
  Mg  Mg12  1  0.877  0.188  0.912  1.0
  Mg  Mg13  1  0.833  0.667  0.392  1.0
  Mg  Mg14  1  0.833  0.667  0.858  1.0
  Co  Co15  1  0.197  0.348  0.125  1.0
[/CIF]
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The structure described by Mg14LaCo crystallizes in the orthorhombic Amm2 space group. There are seven inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2), two equivalent Mg(6), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent La(1)Mg10Co2 cuboctahedra, corners with six equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, and faces with two equivalent Mg(2)Mg12 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1), two equivalent Mg(7), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with six equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, and faces with two equivalent La(1)Mg10Co2 cuboctahedra. In the third Mg site, Mg(3) is bonded in a distorted single-bond geometry to two equivalent Mg(5), two equivalent Mg(7), two equivalent La(1), and one Co(1) atom. In the fourth Mg site, Mg(4) is bonded in a 10-coordinate geometry to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), and two equivalent Mg(7) atoms. In the fifth Mg site, Mg(5) is bonded in a 12-coordinate geometry to one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), one La(1), and one Co(1) atom. In the sixth Mg site, Mg(6) is bonded in a distorted single-bond geometry to one Mg(1), two equivalent Mg(7), four equivalent Mg(5), and one Co(1) atom. In the seventh Mg site, Mg(7) is bonded in a 12-coordinate geometry to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), four equivalent Mg(5), and one La(1) atom. La(1) is bonded to two equivalent Mg(7), four equivalent Mg(3), four equivalent Mg(5), and two equivalent Co(1) atoms to form distorted LaMg10Co2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra, corners with six equivalent La(1)Mg10Co2 cuboctahedra, and faces with two equivalent Mg(2)Mg12 cuboctahedra. Co(1) is bonded in a 10-coordinate geometry to two equivalent Mg(3), two equivalent Mg(6), four equivalent Mg(5), and two equivalent La(1) atoms. is represented by the CIF file [CIF]
data_LaMg14Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.580
_cell_length_b   6.054
_cell_length_c   10.347
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   117.391
_symmetry_Int_Tables_number   1
_cell_volume   365.996
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.126  0.813  0.125  1.0
  Mg  Mg1  1  0.155  0.328  0.625  1.0
  Mg  Mg2  1  0.166  0.833  0.625  1.0
  Mg  Mg3  1  0.617  0.319  0.125  1.0
  Mg  Mg4  1  0.660  0.327  0.625  1.0
  Mg  Mg5  1  0.617  0.797  0.125  1.0
  Mg  Mg6  1  0.660  0.832  0.625  1.0
  Mg  Mg7  1  0.346  0.178  0.377  1.0
  Mg  Mg8  1  0.346  0.178  0.873  1.0
  Mg  Mg9  1  0.346  0.668  0.377  1.0
  Mg  Mg10  1  0.346  0.668  0.873  1.0
  Mg  Mg11  1  0.877  0.188  0.338  1.0
  Mg  Mg12  1  0.877  0.188  0.912  1.0
  Mg  Mg13  1  0.833  0.667  0.392  1.0
  Mg  Mg14  1  0.833  0.667  0.858  1.0
  Co  Co15  1  0.197  0.348  0.125  1.0
[/CIF]
.