The material described by VCoPdNi crystallizes in the trigonal R3m space group. V(1) is bonded to six equivalent V(1), three equivalent Co(1), and three equivalent Pd(1) atoms to form distorted VV6Co3Pd3 cuboctahedra that share corners with six equivalent V(1)V6Co3Pd3 cuboctahedra, corners with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, edges with six equivalent V(1)V6Co3Pd3 cuboctahedra, edges with six equivalent Co(1)V3Co6Ni3 cuboctahedra, edges with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, faces with six equivalent V(1)V6Co3Pd3 cuboctahedra, faces with six equivalent Co(1)V3Co6Ni3 cuboctahedra, and faces with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra. Co(1) is bonded to three equivalent V(1), six equivalent Co(1), and three equivalent Ni(1) atoms to form distorted CoV3Co6Ni3 cuboctahedra that share corners with six equivalent Co(1)V3Co6Ni3 cuboctahedra, corners with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent V(1)V6Co3Pd3 cuboctahedra, edges with six equivalent Co(1)V3Co6Ni3 cuboctahedra, edges with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, faces with six equivalent V(1)V6Co3Pd3 cuboctahedra, faces with six equivalent Co(1)V3Co6Ni3 cuboctahedra, and faces with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra. Pd(1) is bonded to three equivalent V(1), six equivalent Pd(1), and three equivalent Ni(1) atoms to form distorted PdV3Ni3Pd6 cuboctahedra that share corners with six equivalent Co(1)V3Co6Ni3 cuboctahedra, corners with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent V(1)V6Co3Pd3 cuboctahedra, edges with six equivalent Co(1)V3Co6Ni3 cuboctahedra, edges with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, faces with six equivalent V(1)V6Co3Pd3 cuboctahedra, faces with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, and faces with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra. Ni(1) is bonded to three equivalent Co(1), three equivalent Pd(1), and six equivalent Ni(1) atoms to form NiCo3Ni6Pd3 cuboctahedra that share corners with six equivalent V(1)V6Co3Pd3 cuboctahedra, corners with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, edges with six equivalent V(1)V6Co3Pd3 cuboctahedra, edges with six equivalent Co(1)V3Co6Ni3 cuboctahedra, edges with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, faces with six equivalent Co(1)V3Co6Ni3 cuboctahedra, faces with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, and faces with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra. is represented by the CIF file [CIF]
data_VCoNiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.555
_cell_length_b   8.555
_cell_length_c   8.555
_cell_angle_alpha   17.708
_cell_angle_beta   17.708
_cell_angle_gamma   17.708
_symmetry_Int_Tables_number   1
_cell_volume   50.555
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.254  0.254  0.254  1.0
  Co  Co1  1  0.001  0.001  0.001  1.0
  Ni  Ni2  1  0.745  0.745  0.745  1.0
  Pd  Pd3  1  0.500  0.500  0.500  1.0
[/CIF]
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The material described by VCoPdNi crystallizes in the trigonal R3m space group. V(1) is bonded to six equivalent V(1), three equivalent Co(1), and three equivalent Pd(1) atoms to form distorted VV6Co3Pd3 cuboctahedra that share corners with six equivalent V(1)V6Co3Pd3 cuboctahedra, corners with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, edges with six equivalent V(1)V6Co3Pd3 cuboctahedra, edges with six equivalent Co(1)V3Co6Ni3 cuboctahedra, edges with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, faces with six equivalent V(1)V6Co3Pd3 cuboctahedra, faces with six equivalent Co(1)V3Co6Ni3 cuboctahedra, and faces with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra. Co(1) is bonded to three equivalent V(1), six equivalent Co(1), and three equivalent Ni(1) atoms to form distorted CoV3Co6Ni3 cuboctahedra that share corners with six equivalent Co(1)V3Co6Ni3 cuboctahedra, corners with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent V(1)V6Co3Pd3 cuboctahedra, edges with six equivalent Co(1)V3Co6Ni3 cuboctahedra, edges with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, faces with six equivalent V(1)V6Co3Pd3 cuboctahedra, faces with six equivalent Co(1)V3Co6Ni3 cuboctahedra, and faces with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra. Pd(1) is bonded to three equivalent V(1), six equivalent Pd(1), and three equivalent Ni(1) atoms to form distorted PdV3Ni3Pd6 cuboctahedra that share corners with six equivalent Co(1)V3Co6Ni3 cuboctahedra, corners with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent V(1)V6Co3Pd3 cuboctahedra, edges with six equivalent Co(1)V3Co6Ni3 cuboctahedra, edges with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, faces with six equivalent V(1)V6Co3Pd3 cuboctahedra, faces with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, and faces with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra. Ni(1) is bonded to three equivalent Co(1), three equivalent Pd(1), and six equivalent Ni(1) atoms to form NiCo3Ni6Pd3 cuboctahedra that share corners with six equivalent V(1)V6Co3Pd3 cuboctahedra, corners with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, edges with six equivalent V(1)V6Co3Pd3 cuboctahedra, edges with six equivalent Co(1)V3Co6Ni3 cuboctahedra, edges with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, edges with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra, faces with six equivalent Co(1)V3Co6Ni3 cuboctahedra, faces with six equivalent Pd(1)V3Ni3Pd6 cuboctahedra, and faces with six equivalent Ni(1)Co3Ni6Pd3 cuboctahedra. is represented by the CIF file [CIF]
data_VCoNiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.555
_cell_length_b   8.555
_cell_length_c   8.555
_cell_angle_alpha   17.708
_cell_angle_beta   17.708
_cell_angle_gamma   17.708
_symmetry_Int_Tables_number   1
_cell_volume   50.555
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.254  0.254  0.254  1.0
  Co  Co1  1  0.001  0.001  0.001  1.0
  Ni  Ni2  1  0.745  0.745  0.745  1.0
  Pd  Pd3  1  0.500  0.500  0.500  1.0
[/CIF]
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