The compound described by C3S8 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two [1,3]dithiolo[4,5-f]pentathiepine-7-thione molecules. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one S(5), and one S(6) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one S(1), and one S(7) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one S(6), one S(7), and one S(8) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one C(1) and one S(4) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one C(1) and one C(3) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one C(2) and one C(3) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF file [CIF]
data_C3S8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.998
_cell_length_b   9.376
_cell_length_c   12.562
_cell_angle_alpha   99.950
_cell_angle_beta   98.362
_cell_angle_gamma   90.589
_symmetry_Int_Tables_number   1
_cell_volume   573.259
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.694  0.857  0.791  1.0
  C  C1  1  0.306  0.143  0.209  1.0
  C  C2  1  0.658  0.792  0.683  1.0
  C  C3  1  0.342  0.208  0.317  1.0
  C  C4  1  0.369  0.027  0.688  1.0
  C  C5  1  0.631  0.973  0.312  1.0
  S  S6  1  0.186  0.365  0.375  1.0
  S  S7  1  0.814  0.635  0.625  1.0
  S  S8  1  0.379  0.534  0.327  1.0
  S  S9  1  0.621  0.466  0.673  1.0
  S  S10  1  0.164  0.551  0.176  1.0
  S  S11  1  0.836  0.449  0.824  1.0
  S  S12  1  0.296  0.380  0.072  1.0
  S  S13  1  0.704  0.620  0.928  1.0
  S  S14  1  0.097  0.198  0.099  1.0
  S  S15  1  0.903  0.802  0.901  1.0
  S  S16  1  0.523  0.016  0.821  1.0
  S  S17  1  0.477  0.984  0.179  1.0
  S  S18  1  0.446  0.879  0.594  1.0
  S  S19  1  0.554  0.121  0.406  1.0
  S  S20  1  0.172  0.157  0.657  1.0
  S  S21  1  0.828  0.843  0.343  1.0
[/CIF]
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The compound described by C3S8 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two [1,3]dithiolo[4,5-f]pentathiepine-7-thione molecules. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one S(5), and one S(6) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one S(1), and one S(7) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one S(6), one S(7), and one S(8) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one C(1) and one S(4) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one C(1) and one C(3) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one C(2) and one C(3) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF file [CIF]
data_C3S8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.998
_cell_length_b   9.376
_cell_length_c   12.562
_cell_angle_alpha   99.950
_cell_angle_beta   98.362
_cell_angle_gamma   90.589
_symmetry_Int_Tables_number   1
_cell_volume   573.259
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.694  0.857  0.791  1.0
  C  C1  1  0.306  0.143  0.209  1.0
  C  C2  1  0.658  0.792  0.683  1.0
  C  C3  1  0.342  0.208  0.317  1.0
  C  C4  1  0.369  0.027  0.688  1.0
  C  C5  1  0.631  0.973  0.312  1.0
  S  S6  1  0.186  0.365  0.375  1.0
  S  S7  1  0.814  0.635  0.625  1.0
  S  S8  1  0.379  0.534  0.327  1.0
  S  S9  1  0.621  0.466  0.673  1.0
  S  S10  1  0.164  0.551  0.176  1.0
  S  S11  1  0.836  0.449  0.824  1.0
  S  S12  1  0.296  0.380  0.072  1.0
  S  S13  1  0.704  0.620  0.928  1.0
  S  S14  1  0.097  0.198  0.099  1.0
  S  S15  1  0.903  0.802  0.901  1.0
  S  S16  1  0.523  0.016  0.821  1.0
  S  S17  1  0.477  0.984  0.179  1.0
  S  S18  1  0.446  0.879  0.594  1.0
  S  S19  1  0.554  0.121  0.406  1.0
  S  S20  1  0.172  0.157  0.657  1.0
  S  S21  1  0.828  0.843  0.343  1.0
[/CIF]
.