The compound described by AsNS2OF4AsN3S3(OF2)2(AsF3)2N2S2F3(NF2)2SOF2FS2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two arsenic trifluoride molecules, two difluoroamine molecules, one sulfanyl thiohypofluorite molecule, one thionyl fluoride molecule, one AsN3S3(OF2)2 cluster, one AsNS2OF4 cluster, and one N2S2F3 cluster. In the AsN3S3(OF2)2 cluster, As(4) is bonded in a distorted T-shaped geometry to one N(7), one F(21), and one F(23) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one S(10), one S(4), and one F(24) atom. In the third N site, N(7) is bonded in a bent 120 degrees geometry to one As(4) and one S(4) atom. There are three inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to one N(1) and one O(4) atom. In the second S site, S(4) is bonded in a trigonal non-coplanar geometry to one N(1), one N(6), and one N(7) atom. In the third S site, S(10) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one O(1), and one F(20) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(10) atom. In the second O site, O(4) is bonded in a single-bond geometry to one S(3) atom. There are four inequivalent F sites. In the first F site, F(21) is bonded in a single-bond geometry to one As(4) atom. In the second F site, F(23) is bonded in a single-bond geometry to one As(4) atom. In the third F site, F(24) is bonded in a single-bond geometry to one N(6) atom. In the fourth F site, F(20) is bonded in a single-bond geometry to one S(10) atom. In the AsNS2OF4 cluster, As(2) is bonded in a distorted L-shaped geometry to one O(2), one F(1), and one F(22) atom. N(5) is bonded in a bent 150 degrees geometry to one S(2) and one S(5) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a water-like geometry to one N(5) and one O(2) atom. In the second S site, S(5) is bonded in a trigonal non-coplanar geometry to one N(5), one F(15), and one F(18) atom. O(2) is bonded in a distorted bent 150 degrees geometry to one As(2) and one S(2) atom. There are four inequivalent F sites. In the first F site, F(15) is bonded in a single-bond geometry to one S(5) atom. In the second F site, F(18) is bonded in a single-bond geometry to one S(5) atom. In the third F site, F(22) is bonded in a single-bond geometry to one As(2) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one As(2) atom. In the N2S2F3 cluster, there are two inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one F(17) atom. In the second N site, N(8) is bonded in a bent 120 degrees geometry to one S(1) and one S(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(2), one N(8), and one F(19) atom. In the second S site, S(7) is bonded in a water-like geometry to one N(8) and one F(6) atom. There are three inequivalent F sites. In the first F site, F(17) is bonded in a single-bond geometry to one N(2) atom. In the second F site, F(19) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one S(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_As2S5N4(OF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.543
_cell_length_b   10.721
_cell_length_c   11.278
_cell_angle_alpha   85.951
_cell_angle_beta   83.106
_cell_angle_gamma   61.579
_symmetry_Int_Tables_number   1
_cell_volume   1112.887
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.114  0.327  0.418  1.0
  As  As1  1  0.368  0.847  0.914  1.0
  As  As2  1  0.631  0.151  0.009  1.0
  As  As3  1  0.920  0.692  0.655  1.0
  S  S4  1  0.795  0.456  0.116  1.0
  S  S5  1  0.345  0.906  0.249  1.0
  S  S6  1  0.414  0.085  0.704  1.0
  S  S7  1  0.685  0.960  0.564  1.0
  S  S8  1  0.031  0.999  0.255  1.0
  S  S9  1  0.095  0.809  0.023  1.0
  S  S10  1  0.038  0.398  0.931  1.0
  S  S11  1  0.026  0.036  0.734  1.0
  S  S12  1  0.298  0.673  0.002  1.0
  S  S13  1  0.807  0.792  0.332  1.0
  N  N14  1  0.509  0.073  0.585  1.0
  N  N15  1  0.702  0.396  0.069  1.0
  N  N16  1  0.452  0.550  0.543  1.0
  N  N17  1  0.551  0.393  0.517  1.0
  N  N18  1  0.174  0.954  0.301  1.0
  N  N19  1  0.640  0.917  0.409  1.0
  N  N20  1  0.724  0.830  0.647  1.0
  N  N21  1  0.890  0.489  0.997  1.0
  O  O22  1  0.928  0.800  0.375  1.0
  O  O23  1  0.357  0.929  0.116  1.0
  O  O24  1  0.885  0.090  0.798  1.0
  O  O25  1  0.264  0.197  0.695  1.0
  F  F26  1  0.368  0.785  0.769  1.0
  F  F27  1  0.048  0.404  0.280  1.0
  F  F28  1  0.470  0.230  0.105  1.0
  F  F29  1  0.636  0.384  0.408  1.0
  F  F30  1  0.150  0.464  0.456  1.0
  F  F31  1  0.171  0.373  0.011  1.0
  F  F32  1  0.002  0.120  0.605  1.0
  F  F33  1  0.367  0.642  0.134  1.0
  F  F34  1  0.545  0.169  0.878  1.0
  F  F35  1  0.059  0.887  0.675  1.0
  F  F36  1  0.291  0.214  0.357  1.0
  F  F37  1  0.650  0.360  0.603  1.0
  F  F38  1  0.361  0.586  0.451  1.0
  F  F39  1  0.533  0.622  0.508  1.0
  F  F40  1  0.002  0.133  0.157  1.0
  F  F41  1  0.668  0.974  0.043  1.0
  F  F42  1  0.651  0.450  0.953  1.0
  F  F43  1  0.916  0.101  0.363  1.0
  F  F44  1  0.702  0.629  0.146  1.0
  F  F45  1  0.793  0.663  0.410  1.0
  F  F46  1  0.918  0.710  0.811  1.0
  F  F47  1  0.558  0.762  0.911  1.0
  F  F48  1  0.883  0.546  0.669  1.0
  F  F49  1  0.618  0.042  0.338  1.0
[/CIF]
.
The compound described by AsNS2OF4AsN3S3(OF2)2(AsF3)2N2S2F3(NF2)2SOF2FS2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two arsenic trifluoride molecules, two difluoroamine molecules, one sulfanyl thiohypofluorite molecule, one thionyl fluoride molecule, one AsN3S3(OF2)2 cluster, one AsNS2OF4 cluster, and one N2S2F3 cluster. In the AsN3S3(OF2)2 cluster, As(4) is bonded in a distorted T-shaped geometry to one N(7), one F(21), and one F(23) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one S(10), one S(4), and one F(24) atom. In the third N site, N(7) is bonded in a bent 120 degrees geometry to one As(4) and one S(4) atom. There are three inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to one N(1) and one O(4) atom. In the second S site, S(4) is bonded in a trigonal non-coplanar geometry to one N(1), one N(6), and one N(7) atom. In the third S site, S(10) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one O(1), and one F(20) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(10) atom. In the second O site, O(4) is bonded in a single-bond geometry to one S(3) atom. There are four inequivalent F sites. In the first F site, F(21) is bonded in a single-bond geometry to one As(4) atom. In the second F site, F(23) is bonded in a single-bond geometry to one As(4) atom. In the third F site, F(24) is bonded in a single-bond geometry to one N(6) atom. In the fourth F site, F(20) is bonded in a single-bond geometry to one S(10) atom. In the AsNS2OF4 cluster, As(2) is bonded in a distorted L-shaped geometry to one O(2), one F(1), and one F(22) atom. N(5) is bonded in a bent 150 degrees geometry to one S(2) and one S(5) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a water-like geometry to one N(5) and one O(2) atom. In the second S site, S(5) is bonded in a trigonal non-coplanar geometry to one N(5), one F(15), and one F(18) atom. O(2) is bonded in a distorted bent 150 degrees geometry to one As(2) and one S(2) atom. There are four inequivalent F sites. In the first F site, F(15) is bonded in a single-bond geometry to one S(5) atom. In the second F site, F(18) is bonded in a single-bond geometry to one S(5) atom. In the third F site, F(22) is bonded in a single-bond geometry to one As(2) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one As(2) atom. In the N2S2F3 cluster, there are two inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one F(17) atom. In the second N site, N(8) is bonded in a bent 120 degrees geometry to one S(1) and one S(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(2), one N(8), and one F(19) atom. In the second S site, S(7) is bonded in a water-like geometry to one N(8) and one F(6) atom. There are three inequivalent F sites. In the first F site, F(17) is bonded in a single-bond geometry to one N(2) atom. In the second F site, F(19) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one S(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_As2S5N4(OF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.543
_cell_length_b   10.721
_cell_length_c   11.278
_cell_angle_alpha   85.951
_cell_angle_beta   83.106
_cell_angle_gamma   61.579
_symmetry_Int_Tables_number   1
_cell_volume   1112.887
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.114  0.327  0.418  1.0
  As  As1  1  0.368  0.847  0.914  1.0
  As  As2  1  0.631  0.151  0.009  1.0
  As  As3  1  0.920  0.692  0.655  1.0
  S  S4  1  0.795  0.456  0.116  1.0
  S  S5  1  0.345  0.906  0.249  1.0
  S  S6  1  0.414  0.085  0.704  1.0
  S  S7  1  0.685  0.960  0.564  1.0
  S  S8  1  0.031  0.999  0.255  1.0
  S  S9  1  0.095  0.809  0.023  1.0
  S  S10  1  0.038  0.398  0.931  1.0
  S  S11  1  0.026  0.036  0.734  1.0
  S  S12  1  0.298  0.673  0.002  1.0
  S  S13  1  0.807  0.792  0.332  1.0
  N  N14  1  0.509  0.073  0.585  1.0
  N  N15  1  0.702  0.396  0.069  1.0
  N  N16  1  0.452  0.550  0.543  1.0
  N  N17  1  0.551  0.393  0.517  1.0
  N  N18  1  0.174  0.954  0.301  1.0
  N  N19  1  0.640  0.917  0.409  1.0
  N  N20  1  0.724  0.830  0.647  1.0
  N  N21  1  0.890  0.489  0.997  1.0
  O  O22  1  0.928  0.800  0.375  1.0
  O  O23  1  0.357  0.929  0.116  1.0
  O  O24  1  0.885  0.090  0.798  1.0
  O  O25  1  0.264  0.197  0.695  1.0
  F  F26  1  0.368  0.785  0.769  1.0
  F  F27  1  0.048  0.404  0.280  1.0
  F  F28  1  0.470  0.230  0.105  1.0
  F  F29  1  0.636  0.384  0.408  1.0
  F  F30  1  0.150  0.464  0.456  1.0
  F  F31  1  0.171  0.373  0.011  1.0
  F  F32  1  0.002  0.120  0.605  1.0
  F  F33  1  0.367  0.642  0.134  1.0
  F  F34  1  0.545  0.169  0.878  1.0
  F  F35  1  0.059  0.887  0.675  1.0
  F  F36  1  0.291  0.214  0.357  1.0
  F  F37  1  0.650  0.360  0.603  1.0
  F  F38  1  0.361  0.586  0.451  1.0
  F  F39  1  0.533  0.622  0.508  1.0
  F  F40  1  0.002  0.133  0.157  1.0
  F  F41  1  0.668  0.974  0.043  1.0
  F  F42  1  0.651  0.450  0.953  1.0
  F  F43  1  0.916  0.101  0.363  1.0
  F  F44  1  0.702  0.629  0.146  1.0
  F  F45  1  0.793  0.663  0.410  1.0
  F  F46  1  0.918  0.710  0.811  1.0
  F  F47  1  0.558  0.762  0.911  1.0
  F  F48  1  0.883  0.546  0.669  1.0
  F  F49  1  0.618  0.042  0.338  1.0
[/CIF]
.