The material structure described by Bi4(BO4)3 crystallizes in the cubic I-43d space group. B(1) is bonded to four equivalent O(1) atoms to form BO4 tetrahedra that share corners with eight equivalent Bi(1)O6 pentagonal pyramids. Bi(1) is bonded to six equivalent O(1) atoms to form distorted BiO6 pentagonal pyramids that share corners with six equivalent B(1)O4 tetrahedra and edges with three equivalent Bi(1)O6 pentagonal pyramids. O(1) is bonded in a distorted single-bond geometry to one B(1) and two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_Bi4(BO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.485
_cell_length_b   8.485
_cell_length_c   8.485
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   470.307
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.851  0.500  0.000  1.0
  Bi  Bi1  1  0.500  0.000  0.351  1.0
  Bi  Bi2  1  0.149  0.149  0.149  1.0
  Bi  Bi3  1  0.351  0.500  0.000  1.0
  Bi  Bi4  1  0.500  0.000  0.851  1.0
  Bi  Bi5  1  0.649  0.649  0.649  1.0
  Bi  Bi6  1  0.000  0.351  0.500  1.0
  Bi  Bi7  1  0.000  0.851  0.500  1.0
  B  B8  1  0.625  0.375  0.250  1.0
  B  B9  1  0.875  0.125  0.750  1.0
  B  B10  1  0.750  0.875  0.125  1.0
  B  B11  1  0.375  0.250  0.625  1.0
  B  B12  1  0.250  0.625  0.375  1.0
  B  B13  1  0.125  0.750  0.875  1.0
  O  O14  1  0.918  0.073  0.258  1.0
  O  O15  1  0.655  0.340  0.082  1.0
  O  O16  1  0.840  0.155  0.582  1.0
  O  O17  1  0.660  0.242  0.315  1.0
  O  O18  1  0.815  0.742  0.160  1.0
  O  O19  1  0.427  0.345  0.185  1.0
  O  O20  1  0.742  0.160  0.815  1.0
  O  O21  1  0.758  0.573  0.418  1.0
  O  O22  1  0.345  0.185  0.427  1.0
  O  O23  1  0.340  0.082  0.655  1.0
  O  O24  1  0.582  0.840  0.155  1.0
  O  O25  1  0.185  0.427  0.345  1.0
  O  O26  1  0.315  0.660  0.242  1.0
  O  O27  1  0.573  0.418  0.758  1.0
  O  O28  1  0.927  0.685  0.845  1.0
  O  O29  1  0.258  0.918  0.073  1.0
  O  O30  1  0.242  0.315  0.660  1.0
  O  O31  1  0.845  0.927  0.685  1.0
  O  O32  1  0.418  0.758  0.573  1.0
  O  O33  1  0.082  0.655  0.340  1.0
  O  O34  1  0.685  0.845  0.927  1.0
  O  O35  1  0.073  0.258  0.918  1.0
  O  O36  1  0.155  0.582  0.840  1.0
  O  O37  1  0.160  0.815  0.742  1.0
[/CIF]
.
The material structure described by Bi4(BO4)3 crystallizes in the cubic I-43d space group. B(1) is bonded to four equivalent O(1) atoms to form BO4 tetrahedra that share corners with eight equivalent Bi(1)O6 pentagonal pyramids. Bi(1) is bonded to six equivalent O(1) atoms to form distorted BiO6 pentagonal pyramids that share corners with six equivalent B(1)O4 tetrahedra and edges with three equivalent Bi(1)O6 pentagonal pyramids. O(1) is bonded in a distorted single-bond geometry to one B(1) and two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_Bi4(BO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.485
_cell_length_b   8.485
_cell_length_c   8.485
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   470.307
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.851  0.500  0.000  1.0
  Bi  Bi1  1  0.500  0.000  0.351  1.0
  Bi  Bi2  1  0.149  0.149  0.149  1.0
  Bi  Bi3  1  0.351  0.500  0.000  1.0
  Bi  Bi4  1  0.500  0.000  0.851  1.0
  Bi  Bi5  1  0.649  0.649  0.649  1.0
  Bi  Bi6  1  0.000  0.351  0.500  1.0
  Bi  Bi7  1  0.000  0.851  0.500  1.0
  B  B8  1  0.625  0.375  0.250  1.0
  B  B9  1  0.875  0.125  0.750  1.0
  B  B10  1  0.750  0.875  0.125  1.0
  B  B11  1  0.375  0.250  0.625  1.0
  B  B12  1  0.250  0.625  0.375  1.0
  B  B13  1  0.125  0.750  0.875  1.0
  O  O14  1  0.918  0.073  0.258  1.0
  O  O15  1  0.655  0.340  0.082  1.0
  O  O16  1  0.840  0.155  0.582  1.0
  O  O17  1  0.660  0.242  0.315  1.0
  O  O18  1  0.815  0.742  0.160  1.0
  O  O19  1  0.427  0.345  0.185  1.0
  O  O20  1  0.742  0.160  0.815  1.0
  O  O21  1  0.758  0.573  0.418  1.0
  O  O22  1  0.345  0.185  0.427  1.0
  O  O23  1  0.340  0.082  0.655  1.0
  O  O24  1  0.582  0.840  0.155  1.0
  O  O25  1  0.185  0.427  0.345  1.0
  O  O26  1  0.315  0.660  0.242  1.0
  O  O27  1  0.573  0.418  0.758  1.0
  O  O28  1  0.927  0.685  0.845  1.0
  O  O29  1  0.258  0.918  0.073  1.0
  O  O30  1  0.242  0.315  0.660  1.0
  O  O31  1  0.845  0.927  0.685  1.0
  O  O32  1  0.418  0.758  0.573  1.0
  O  O33  1  0.082  0.655  0.340  1.0
  O  O34  1  0.685  0.845  0.927  1.0
  O  O35  1  0.073  0.258  0.918  1.0
  O  O36  1  0.155  0.582  0.840  1.0
  O  O37  1  0.160  0.815  0.742  1.0
[/CIF]
.