The structure described by Bi(TeO3)(NO3) crystallizes in the monoclinic P2_1/c space group. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. N(1) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Bi(1) and one Te(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Bi(1) and one Te(1) atom. In the fourth O site, O(3) is bonded in a water-like geometry to one Bi(1) and one Te(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one N(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Bi(1) and one N(1) atom. is represented by the CIF file [CIF]
data_BiTeNO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.045
_cell_length_b   7.394
_cell_length_c   8.192
_cell_angle_alpha   65.832
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   499.865
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.697  0.474  0.696  1.0
  Bi  Bi1  1  0.197  0.026  0.304  1.0
  Bi  Bi2  1  0.303  0.526  0.304  1.0
  Bi  Bi3  1  0.803  0.974  0.696  1.0
  Te  Te4  1  0.590  0.892  0.347  1.0
  Te  Te5  1  0.090  0.608  0.653  1.0
  Te  Te6  1  0.410  0.108  0.653  1.0
  Te  Te7  1  0.910  0.392  0.347  1.0
  N  N8  1  0.387  0.368  0.951  1.0
  N  N9  1  0.887  0.132  0.049  1.0
  N  N10  1  0.613  0.632  0.049  1.0
  N  N11  1  0.113  0.868  0.951  1.0
  O  O12  1  0.392  0.806  0.357  1.0
  O  O13  1  0.892  0.694  0.643  1.0
  O  O14  1  0.608  0.194  0.643  1.0
  O  O15  1  0.108  0.306  0.357  1.0
  O  O16  1  0.608  0.848  0.593  1.0
  O  O17  1  0.108  0.652  0.407  1.0
  O  O18  1  0.392  0.152  0.407  1.0
  O  O19  1  0.892  0.348  0.593  1.0
  O  O20  1  0.664  0.636  0.404  1.0
  O  O21  1  0.164  0.864  0.596  1.0
  O  O22  1  0.336  0.364  0.596  1.0
  O  O23  1  0.836  0.136  0.404  1.0
  O  O24  1  0.778  0.133  0.950  1.0
  O  O25  1  0.278  0.367  0.050  1.0
  O  O26  1  0.222  0.867  0.050  1.0
  O  O27  1  0.722  0.633  0.950  1.0
  O  O28  1  0.429  0.530  0.832  1.0
  O  O29  1  0.929  0.970  0.168  1.0
  O  O30  1  0.571  0.470  0.168  1.0
  O  O31  1  0.071  0.030  0.832  1.0
  O  O32  1  0.551  0.792  0.028  1.0
  O  O33  1  0.051  0.708  0.972  1.0
  O  O34  1  0.449  0.208  0.972  1.0
  O  O35  1  0.949  0.292  0.028  1.0
[/CIF]
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The structure described by Bi(TeO3)(NO3) crystallizes in the monoclinic P2_1/c space group. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. N(1) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Bi(1) and one Te(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Bi(1) and one Te(1) atom. In the fourth O site, O(3) is bonded in a water-like geometry to one Bi(1) and one Te(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one N(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Bi(1) and one N(1) atom. is represented by the CIF file [CIF]
data_BiTeNO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.045
_cell_length_b   7.394
_cell_length_c   8.192
_cell_angle_alpha   65.832
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   499.865
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.697  0.474  0.696  1.0
  Bi  Bi1  1  0.197  0.026  0.304  1.0
  Bi  Bi2  1  0.303  0.526  0.304  1.0
  Bi  Bi3  1  0.803  0.974  0.696  1.0
  Te  Te4  1  0.590  0.892  0.347  1.0
  Te  Te5  1  0.090  0.608  0.653  1.0
  Te  Te6  1  0.410  0.108  0.653  1.0
  Te  Te7  1  0.910  0.392  0.347  1.0
  N  N8  1  0.387  0.368  0.951  1.0
  N  N9  1  0.887  0.132  0.049  1.0
  N  N10  1  0.613  0.632  0.049  1.0
  N  N11  1  0.113  0.868  0.951  1.0
  O  O12  1  0.392  0.806  0.357  1.0
  O  O13  1  0.892  0.694  0.643  1.0
  O  O14  1  0.608  0.194  0.643  1.0
  O  O15  1  0.108  0.306  0.357  1.0
  O  O16  1  0.608  0.848  0.593  1.0
  O  O17  1  0.108  0.652  0.407  1.0
  O  O18  1  0.392  0.152  0.407  1.0
  O  O19  1  0.892  0.348  0.593  1.0
  O  O20  1  0.664  0.636  0.404  1.0
  O  O21  1  0.164  0.864  0.596  1.0
  O  O22  1  0.336  0.364  0.596  1.0
  O  O23  1  0.836  0.136  0.404  1.0
  O  O24  1  0.778  0.133  0.950  1.0
  O  O25  1  0.278  0.367  0.050  1.0
  O  O26  1  0.222  0.867  0.050  1.0
  O  O27  1  0.722  0.633  0.950  1.0
  O  O28  1  0.429  0.530  0.832  1.0
  O  O29  1  0.929  0.970  0.168  1.0
  O  O30  1  0.571  0.470  0.168  1.0
  O  O31  1  0.071  0.030  0.832  1.0
  O  O32  1  0.551  0.792  0.028  1.0
  O  O33  1  0.051  0.708  0.972  1.0
  O  O34  1  0.449  0.208  0.972  1.0
  O  O35  1  0.949  0.292  0.028  1.0
[/CIF]
.