The material described by CdV3O7 crystallizes in the orthorhombic Pnma space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted square pyramidal geometry to one O(1), two equivalent O(3), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), and two equivalent O(4) atoms. Cd(1) is bonded in a 7-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to one V(1), two equivalent V(2), and one Cd(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and one Cd(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one Cd(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one V(1), two equivalent V(2), and one Cd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3CdO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.385
_cell_length_b   11.364
_cell_length_c   10.529
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   644.370
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.270  0.322  0.750  1.0
  V  V1  1  0.770  0.178  0.250  1.0
  V  V2  1  0.230  0.822  0.750  1.0
  V  V3  1  0.730  0.678  0.250  1.0
  V  V4  1  0.225  0.806  0.469  1.0
  V  V5  1  0.725  0.694  0.531  1.0
  V  V6  1  0.275  0.306  0.031  1.0
  V  V7  1  0.775  0.194  0.969  1.0
  V  V8  1  0.775  0.194  0.531  1.0
  V  V9  1  0.275  0.306  0.469  1.0
  V  V10  1  0.725  0.694  0.969  1.0
  V  V11  1  0.225  0.806  0.031  1.0
  Cd  Cd12  1  0.772  0.437  0.750  1.0
  Cd  Cd13  1  0.272  0.063  0.250  1.0
  Cd  Cd14  1  0.728  0.937  0.750  1.0
  Cd  Cd15  1  0.228  0.563  0.250  1.0
  O  O16  1  0.271  0.968  0.750  1.0
  O  O17  1  0.771  0.532  0.250  1.0
  O  O18  1  0.229  0.468  0.750  1.0
  O  O19  1  0.729  0.032  0.250  1.0
  O  O20  1  0.251  0.944  0.413  1.0
  O  O21  1  0.751  0.556  0.587  1.0
  O  O22  1  0.249  0.444  0.087  1.0
  O  O23  1  0.749  0.056  0.913  1.0
  O  O24  1  0.749  0.056  0.587  1.0
  O  O25  1  0.249  0.444  0.413  1.0
  O  O26  1  0.751  0.556  0.913  1.0
  O  O27  1  0.251  0.944  0.087  1.0
  O  O28  1  0.956  0.722  0.389  1.0
  O  O29  1  0.456  0.778  0.611  1.0
  O  O30  1  0.544  0.222  0.111  1.0
  O  O31  1  0.044  0.278  0.889  1.0
  O  O32  1  0.478  0.704  0.114  1.0
  O  O33  1  0.978  0.796  0.886  1.0
  O  O34  1  0.022  0.204  0.386  1.0
  O  O35  1  0.522  0.296  0.614  1.0
  O  O36  1  0.522  0.296  0.886  1.0
  O  O37  1  0.022  0.204  0.114  1.0
  O  O38  1  0.978  0.796  0.614  1.0
  O  O39  1  0.478  0.704  0.386  1.0
  O  O40  1  0.956  0.722  0.111  1.0
  O  O41  1  0.456  0.778  0.889  1.0
  O  O42  1  0.544  0.222  0.389  1.0
  O  O43  1  0.044  0.278  0.611  1.0
[/CIF]
.
The material described by CdV3O7 crystallizes in the orthorhombic Pnma space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted square pyramidal geometry to one O(1), two equivalent O(3), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), and two equivalent O(4) atoms. Cd(1) is bonded in a 7-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to one V(1), two equivalent V(2), and one Cd(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and one Cd(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one Cd(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one V(1), two equivalent V(2), and one Cd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3CdO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.385
_cell_length_b   11.364
_cell_length_c   10.529
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   644.370
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.270  0.322  0.750  1.0
  V  V1  1  0.770  0.178  0.250  1.0
  V  V2  1  0.230  0.822  0.750  1.0
  V  V3  1  0.730  0.678  0.250  1.0
  V  V4  1  0.225  0.806  0.469  1.0
  V  V5  1  0.725  0.694  0.531  1.0
  V  V6  1  0.275  0.306  0.031  1.0
  V  V7  1  0.775  0.194  0.969  1.0
  V  V8  1  0.775  0.194  0.531  1.0
  V  V9  1  0.275  0.306  0.469  1.0
  V  V10  1  0.725  0.694  0.969  1.0
  V  V11  1  0.225  0.806  0.031  1.0
  Cd  Cd12  1  0.772  0.437  0.750  1.0
  Cd  Cd13  1  0.272  0.063  0.250  1.0
  Cd  Cd14  1  0.728  0.937  0.750  1.0
  Cd  Cd15  1  0.228  0.563  0.250  1.0
  O  O16  1  0.271  0.968  0.750  1.0
  O  O17  1  0.771  0.532  0.250  1.0
  O  O18  1  0.229  0.468  0.750  1.0
  O  O19  1  0.729  0.032  0.250  1.0
  O  O20  1  0.251  0.944  0.413  1.0
  O  O21  1  0.751  0.556  0.587  1.0
  O  O22  1  0.249  0.444  0.087  1.0
  O  O23  1  0.749  0.056  0.913  1.0
  O  O24  1  0.749  0.056  0.587  1.0
  O  O25  1  0.249  0.444  0.413  1.0
  O  O26  1  0.751  0.556  0.913  1.0
  O  O27  1  0.251  0.944  0.087  1.0
  O  O28  1  0.956  0.722  0.389  1.0
  O  O29  1  0.456  0.778  0.611  1.0
  O  O30  1  0.544  0.222  0.111  1.0
  O  O31  1  0.044  0.278  0.889  1.0
  O  O32  1  0.478  0.704  0.114  1.0
  O  O33  1  0.978  0.796  0.886  1.0
  O  O34  1  0.022  0.204  0.386  1.0
  O  O35  1  0.522  0.296  0.614  1.0
  O  O36  1  0.522  0.296  0.886  1.0
  O  O37  1  0.022  0.204  0.114  1.0
  O  O38  1  0.978  0.796  0.614  1.0
  O  O39  1  0.478  0.704  0.386  1.0
  O  O40  1  0.956  0.722  0.111  1.0
  O  O41  1  0.456  0.778  0.889  1.0
  O  O42  1  0.544  0.222  0.389  1.0
  O  O43  1  0.044  0.278  0.611  1.0
[/CIF]
.