The compound described by VOF is Baddeleyite-derived structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F3 hexagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.308
_cell_length_b   5.255
_cell_length_c   7.238
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   125.809
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.634  0.655  1.0
  V  V1  1  0.250  0.134  0.845  1.0
  V  V2  1  0.750  0.866  0.155  1.0
  V  V3  1  0.250  0.366  0.345  1.0
  O  O4  1  0.250  0.397  0.626  1.0
  O  O5  1  0.750  0.897  0.874  1.0
  O  O6  1  0.250  0.103  0.126  1.0
  O  O7  1  0.750  0.603  0.374  1.0
  F  F8  1  0.250  0.882  0.615  1.0
  F  F9  1  0.750  0.382  0.885  1.0
  F  F10  1  0.250  0.618  0.115  1.0
  F  F11  1  0.750  0.118  0.385  1.0
[/CIF]
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The compound described by VOF is Baddeleyite-derived structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F3 hexagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.308
_cell_length_b   5.255
_cell_length_c   7.238
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   125.809
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.634  0.655  1.0
  V  V1  1  0.250  0.134  0.845  1.0
  V  V2  1  0.750  0.866  0.155  1.0
  V  V3  1  0.250  0.366  0.345  1.0
  O  O4  1  0.250  0.397  0.626  1.0
  O  O5  1  0.750  0.897  0.874  1.0
  O  O6  1  0.250  0.103  0.126  1.0
  O  O7  1  0.750  0.603  0.374  1.0
  F  F8  1  0.250  0.882  0.615  1.0
  F  F9  1  0.750  0.382  0.885  1.0
  F  F10  1  0.250  0.618  0.115  1.0
  F  F11  1  0.750  0.118  0.385  1.0
[/CIF]
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