The compound described by B3N3H5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1-(1,3,5,2,4,6-triazatriborinan-2-yl)-1,3,5,2,4,6-triazatriborinane molecules. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one N(1) and two equivalent N(3) atoms. In the fourth B site, B(4) is bonded in a trigonal planar geometry to two equivalent N(2) and one H(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one B(3) and two equivalent B(2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one B(2), one B(4), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one B(1), one B(3), and one H(1) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to two equivalent B(1) and one H(2) atom. There are six inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one B(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one B(1) atom. In the third H site, H(6) is bonded in a single-bond geometry to one B(2) atom. In the fourth H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_B3H5N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.309
_cell_length_b   11.309
_cell_length_c   5.638
_cell_angle_alpha   76.786
_cell_angle_beta   76.786
_cell_angle_gamma   129.773
_symmetry_Int_Tables_number   1
_cell_volume   466.930
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.819  0.022  0.133  1.0
  B  B1  1  0.181  0.978  0.867  1.0
  B  B2  1  0.978  0.181  0.367  1.0
  B  B3  1  0.022  0.819  0.633  1.0
  B  B4  1  0.607  0.241  0.129  1.0
  B  B5  1  0.393  0.759  0.871  1.0
  B  B6  1  0.759  0.393  0.371  1.0
  B  B7  1  0.241  0.607  0.629  1.0
  B  B8  1  0.792  0.208  0.250  1.0
  B  B9  1  0.208  0.792  0.750  1.0
  B  B10  1  0.576  0.424  0.250  1.0
  B  B11  1  0.424  0.576  0.750  1.0
  H  H12  1  0.678  0.068  0.040  1.0
  H  H13  1  0.322  0.932  0.960  1.0
  H  H14  1  0.932  0.322  0.460  1.0
  H  H15  1  0.068  0.678  0.540  1.0
  H  H16  1  0.983  0.017  0.250  1.0
  H  H17  1  0.017  0.983  0.750  1.0
  H  H18  1  0.466  0.288  0.035  1.0
  H  H19  1  0.534  0.712  0.965  1.0
  H  H20  1  0.712  0.534  0.465  1.0
  H  H21  1  0.288  0.466  0.535  1.0
  H  H22  1  0.517  0.483  0.250  1.0
  H  H23  1  0.483  0.517  0.750  1.0
  H  H24  1  0.778  0.922  0.042  1.0
  H  H25  1  0.222  0.078  0.958  1.0
  H  H26  1  0.078  0.222  0.458  1.0
  H  H27  1  0.922  0.778  0.542  1.0
  H  H28  1  0.563  0.144  0.032  1.0
  H  H29  1  0.437  0.856  0.968  1.0
  H  H30  1  0.856  0.437  0.468  1.0
  H  H31  1  0.144  0.563  0.532  1.0
  N  N32  1  0.719  0.281  0.250  1.0
  N  N33  1  0.281  0.719  0.750  1.0
  N  N34  1  0.544  0.317  0.123  1.0
  N  N35  1  0.456  0.683  0.877  1.0
  N  N36  1  0.683  0.456  0.377  1.0
  N  N37  1  0.317  0.544  0.623  1.0
  N  N38  1  0.756  0.098  0.128  1.0
  N  N39  1  0.244  0.902  0.872  1.0
  N  N40  1  0.902  0.244  0.372  1.0
  N  N41  1  0.098  0.756  0.628  1.0
  N  N42  1  0.933  0.067  0.250  1.0
  N  N43  1  0.067  0.933  0.750  1.0
[/CIF]
.
The compound described by B3N3H5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1-(1,3,5,2,4,6-triazatriborinan-2-yl)-1,3,5,2,4,6-triazatriborinane molecules. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one N(1) and two equivalent N(3) atoms. In the fourth B site, B(4) is bonded in a trigonal planar geometry to two equivalent N(2) and one H(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one B(3) and two equivalent B(2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one B(2), one B(4), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one B(1), one B(3), and one H(1) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to two equivalent B(1) and one H(2) atom. There are six inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one B(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one B(1) atom. In the third H site, H(6) is bonded in a single-bond geometry to one B(2) atom. In the fourth H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_B3H5N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.309
_cell_length_b   11.309
_cell_length_c   5.638
_cell_angle_alpha   76.786
_cell_angle_beta   76.786
_cell_angle_gamma   129.773
_symmetry_Int_Tables_number   1
_cell_volume   466.930
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.819  0.022  0.133  1.0
  B  B1  1  0.181  0.978  0.867  1.0
  B  B2  1  0.978  0.181  0.367  1.0
  B  B3  1  0.022  0.819  0.633  1.0
  B  B4  1  0.607  0.241  0.129  1.0
  B  B5  1  0.393  0.759  0.871  1.0
  B  B6  1  0.759  0.393  0.371  1.0
  B  B7  1  0.241  0.607  0.629  1.0
  B  B8  1  0.792  0.208  0.250  1.0
  B  B9  1  0.208  0.792  0.750  1.0
  B  B10  1  0.576  0.424  0.250  1.0
  B  B11  1  0.424  0.576  0.750  1.0
  H  H12  1  0.678  0.068  0.040  1.0
  H  H13  1  0.322  0.932  0.960  1.0
  H  H14  1  0.932  0.322  0.460  1.0
  H  H15  1  0.068  0.678  0.540  1.0
  H  H16  1  0.983  0.017  0.250  1.0
  H  H17  1  0.017  0.983  0.750  1.0
  H  H18  1  0.466  0.288  0.035  1.0
  H  H19  1  0.534  0.712  0.965  1.0
  H  H20  1  0.712  0.534  0.465  1.0
  H  H21  1  0.288  0.466  0.535  1.0
  H  H22  1  0.517  0.483  0.250  1.0
  H  H23  1  0.483  0.517  0.750  1.0
  H  H24  1  0.778  0.922  0.042  1.0
  H  H25  1  0.222  0.078  0.958  1.0
  H  H26  1  0.078  0.222  0.458  1.0
  H  H27  1  0.922  0.778  0.542  1.0
  H  H28  1  0.563  0.144  0.032  1.0
  H  H29  1  0.437  0.856  0.968  1.0
  H  H30  1  0.856  0.437  0.468  1.0
  H  H31  1  0.144  0.563  0.532  1.0
  N  N32  1  0.719  0.281  0.250  1.0
  N  N33  1  0.281  0.719  0.750  1.0
  N  N34  1  0.544  0.317  0.123  1.0
  N  N35  1  0.456  0.683  0.877  1.0
  N  N36  1  0.683  0.456  0.377  1.0
  N  N37  1  0.317  0.544  0.623  1.0
  N  N38  1  0.756  0.098  0.128  1.0
  N  N39  1  0.244  0.902  0.872  1.0
  N  N40  1  0.902  0.244  0.372  1.0
  N  N41  1  0.098  0.756  0.628  1.0
  N  N42  1  0.933  0.067  0.250  1.0
  N  N43  1  0.067  0.933  0.750  1.0
[/CIF]
.