The structure described by Zn(H2O)6ZnCl4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnCl4 clusters and two zinkhexahydrat molecules. In each ZnCl4 cluster, Zn(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Zn(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH6Cl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.718
_cell_length_b   6.748
_cell_length_c   14.424
_cell_angle_alpha   90.445
_cell_angle_beta   100.969
_cell_angle_gamma   96.987
_symmetry_Int_Tables_number   1
_cell_volume   636.908
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.886  0.101  0.759  1.0
  Zn  Zn1  1  0.114  0.899  0.241  1.0
  Zn  Zn2  1  0.500  0.500  0.000  1.0
  Zn  Zn3  1  0.500  0.500  0.500  1.0
  H  H4  1  0.846  0.757  0.005  1.0
  H  H5  1  0.154  0.243  0.995  1.0
  H  H6  1  0.838  0.591  0.924  1.0
  H  H7  1  0.162  0.409  0.076  1.0
  H  H8  1  0.764  0.446  0.161  1.0
  H  H9  1  0.236  0.554  0.839  1.0
  H  H10  1  0.552  0.322  0.169  1.0
  H  H11  1  0.448  0.678  0.831  1.0
  H  H12  1  0.535  0.150  0.897  1.0
  H  H13  1  0.465  0.850  0.103  1.0
  H  H14  1  0.670  0.146  0.000  1.0
  H  H15  1  0.330  0.854  1.000  1.0
  H  H16  1  0.466  0.610  0.316  1.0
  H  H17  1  0.534  0.390  0.684  1.0
  H  H18  1  0.682  0.712  0.369  1.0
  H  H19  1  0.318  0.288  0.631  1.0
  H  H20  1  0.844  0.549  0.630  1.0
  H  H21  1  0.156  0.451  0.370  1.0
  H  H22  1  0.840  0.747  0.574  1.0
  H  H23  1  0.160  0.253  0.426  1.0
  H  H24  1  0.705  0.165  0.509  1.0
  H  H25  1  0.295  0.835  0.491  1.0
  H  H26  1  0.562  0.162  0.407  1.0
  H  H27  1  0.438  0.838  0.593  1.0
  Cl  Cl28  1  0.088  0.983  0.886  1.0
  Cl  Cl29  1  0.912  0.017  0.114  1.0
  Cl  Cl30  1  0.882  0.445  0.777  1.0
  Cl  Cl31  1  0.118  0.555  0.223  1.0
  Cl  Cl32  1  0.553  0.959  0.752  1.0
  Cl  Cl33  1  0.447  0.041  0.248  1.0
  Cl  Cl34  1  0.982  0.061  0.617  1.0
  Cl  Cl35  1  0.018  0.939  0.383  1.0
  O  O36  1  0.792  0.619  0.983  1.0
  O  O37  1  0.208  0.381  0.017  1.0
  O  O38  1  0.616  0.442  0.142  1.0
  O  O39  1  0.384  0.558  0.858  1.0
  O  O40  1  0.569  0.217  0.960  1.0
  O  O41  1  0.431  0.783  0.040  1.0
  O  O42  1  0.578  0.598  0.370  1.0
  O  O43  1  0.422  0.402  0.630  1.0
  O  O44  1  0.799  0.601  0.567  1.0
  O  O45  1  0.201  0.399  0.433  1.0
  O  O46  1  0.580  0.212  0.473  1.0
  O  O47  1  0.420  0.788  0.527  1.0
[/CIF]
.
The structure described by Zn(H2O)6ZnCl4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnCl4 clusters and two zinkhexahydrat molecules. In each ZnCl4 cluster, Zn(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Zn(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH6Cl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.718
_cell_length_b   6.748
_cell_length_c   14.424
_cell_angle_alpha   90.445
_cell_angle_beta   100.969
_cell_angle_gamma   96.987
_symmetry_Int_Tables_number   1
_cell_volume   636.908
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.886  0.101  0.759  1.0
  Zn  Zn1  1  0.114  0.899  0.241  1.0
  Zn  Zn2  1  0.500  0.500  0.000  1.0
  Zn  Zn3  1  0.500  0.500  0.500  1.0
  H  H4  1  0.846  0.757  0.005  1.0
  H  H5  1  0.154  0.243  0.995  1.0
  H  H6  1  0.838  0.591  0.924  1.0
  H  H7  1  0.162  0.409  0.076  1.0
  H  H8  1  0.764  0.446  0.161  1.0
  H  H9  1  0.236  0.554  0.839  1.0
  H  H10  1  0.552  0.322  0.169  1.0
  H  H11  1  0.448  0.678  0.831  1.0
  H  H12  1  0.535  0.150  0.897  1.0
  H  H13  1  0.465  0.850  0.103  1.0
  H  H14  1  0.670  0.146  0.000  1.0
  H  H15  1  0.330  0.854  1.000  1.0
  H  H16  1  0.466  0.610  0.316  1.0
  H  H17  1  0.534  0.390  0.684  1.0
  H  H18  1  0.682  0.712  0.369  1.0
  H  H19  1  0.318  0.288  0.631  1.0
  H  H20  1  0.844  0.549  0.630  1.0
  H  H21  1  0.156  0.451  0.370  1.0
  H  H22  1  0.840  0.747  0.574  1.0
  H  H23  1  0.160  0.253  0.426  1.0
  H  H24  1  0.705  0.165  0.509  1.0
  H  H25  1  0.295  0.835  0.491  1.0
  H  H26  1  0.562  0.162  0.407  1.0
  H  H27  1  0.438  0.838  0.593  1.0
  Cl  Cl28  1  0.088  0.983  0.886  1.0
  Cl  Cl29  1  0.912  0.017  0.114  1.0
  Cl  Cl30  1  0.882  0.445  0.777  1.0
  Cl  Cl31  1  0.118  0.555  0.223  1.0
  Cl  Cl32  1  0.553  0.959  0.752  1.0
  Cl  Cl33  1  0.447  0.041  0.248  1.0
  Cl  Cl34  1  0.982  0.061  0.617  1.0
  Cl  Cl35  1  0.018  0.939  0.383  1.0
  O  O36  1  0.792  0.619  0.983  1.0
  O  O37  1  0.208  0.381  0.017  1.0
  O  O38  1  0.616  0.442  0.142  1.0
  O  O39  1  0.384  0.558  0.858  1.0
  O  O40  1  0.569  0.217  0.960  1.0
  O  O41  1  0.431  0.783  0.040  1.0
  O  O42  1  0.578  0.598  0.370  1.0
  O  O43  1  0.422  0.402  0.630  1.0
  O  O44  1  0.799  0.601  0.567  1.0
  O  O45  1  0.201  0.399  0.433  1.0
  O  O46  1  0.580  0.212  0.473  1.0
  O  O47  1  0.420  0.788  0.527  1.0
[/CIF]
.