The material described by AlNSCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AlNSCl3 clusters. Al(1) is bonded in a tetrahedral geometry to one N(1), one Cl(1), one Cl(2), and one Cl(3) atom. N(1) is bonded in a distorted trigonal planar geometry to one Al(1) and two equivalent S(1) atoms. S(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF file [CIF]
data_AlSNCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.027
_cell_length_b   7.398
_cell_length_c   9.575
_cell_angle_alpha   64.811
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   642.728
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.870  0.732  0.164  1.0
  Al  Al1  1  0.130  0.268  0.836  1.0
  Al  Al2  1  0.370  0.268  0.336  1.0
  Al  Al3  1  0.630  0.732  0.664  1.0
  S  S4  1  0.967  0.353  0.117  1.0
  S  S5  1  0.033  0.647  0.883  1.0
  S  S6  1  0.467  0.647  0.383  1.0
  S  S7  1  0.533  0.353  0.617  1.0
  N  N8  1  0.956  0.600  0.048  1.0
  N  N9  1  0.044  0.400  0.952  1.0
  N  N10  1  0.456  0.400  0.452  1.0
  N  N11  1  0.544  0.600  0.548  1.0
  Cl  Cl12  1  0.480  0.905  0.709  1.0
  Cl  Cl13  1  0.520  0.095  0.291  1.0
  Cl  Cl14  1  0.980  0.095  0.791  1.0
  Cl  Cl15  1  0.020  0.905  0.209  1.0
  Cl  Cl16  1  0.695  0.882  0.052  1.0
  Cl  Cl17  1  0.305  0.118  0.948  1.0
  Cl  Cl18  1  0.195  0.118  0.448  1.0
  Cl  Cl19  1  0.805  0.882  0.552  1.0
  Cl  Cl20  1  0.829  0.456  0.362  1.0
  Cl  Cl21  1  0.171  0.544  0.638  1.0
  Cl  Cl22  1  0.329  0.544  0.138  1.0
  Cl  Cl23  1  0.671  0.456  0.862  1.0
[/CIF]
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The material described by AlNSCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AlNSCl3 clusters. Al(1) is bonded in a tetrahedral geometry to one N(1), one Cl(1), one Cl(2), and one Cl(3) atom. N(1) is bonded in a distorted trigonal planar geometry to one Al(1) and two equivalent S(1) atoms. S(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF file [CIF]
data_AlSNCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.027
_cell_length_b   7.398
_cell_length_c   9.575
_cell_angle_alpha   64.811
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   642.728
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.870  0.732  0.164  1.0
  Al  Al1  1  0.130  0.268  0.836  1.0
  Al  Al2  1  0.370  0.268  0.336  1.0
  Al  Al3  1  0.630  0.732  0.664  1.0
  S  S4  1  0.967  0.353  0.117  1.0
  S  S5  1  0.033  0.647  0.883  1.0
  S  S6  1  0.467  0.647  0.383  1.0
  S  S7  1  0.533  0.353  0.617  1.0
  N  N8  1  0.956  0.600  0.048  1.0
  N  N9  1  0.044  0.400  0.952  1.0
  N  N10  1  0.456  0.400  0.452  1.0
  N  N11  1  0.544  0.600  0.548  1.0
  Cl  Cl12  1  0.480  0.905  0.709  1.0
  Cl  Cl13  1  0.520  0.095  0.291  1.0
  Cl  Cl14  1  0.980  0.095  0.791  1.0
  Cl  Cl15  1  0.020  0.905  0.209  1.0
  Cl  Cl16  1  0.695  0.882  0.052  1.0
  Cl  Cl17  1  0.305  0.118  0.948  1.0
  Cl  Cl18  1  0.195  0.118  0.448  1.0
  Cl  Cl19  1  0.805  0.882  0.552  1.0
  Cl  Cl20  1  0.829  0.456  0.362  1.0
  Cl  Cl21  1  0.171  0.544  0.638  1.0
  Cl  Cl22  1  0.329  0.544  0.138  1.0
  Cl  Cl23  1  0.671  0.456  0.862  1.0
[/CIF]
.