The material described by (MnO4)2NiO6 is Silicon tetrafluoride-derived structured and crystallizes in the trigonal P3m1 space group. The structure is zero-dimensional and consists of two mangan(iv)-hydroxyd molecules and one NiO6 cluster. In the NiO6 cluster, Ni(1) is bonded in a distorted octahedral geometry to three equivalent O(5) and three equivalent O(6) atoms. There are two inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Ni(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2NiO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.626
_cell_length_b   7.626
_cell_length_c   4.480
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   225.628
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.667  0.333  0.499  1.0
  Mn  Mn1  1  0.333  0.667  0.993  1.0
  Ni  Ni2  1  0.000  0.000  0.254  1.0
  O  O3  1  0.667  0.333  0.861  1.0
  O  O4  1  0.551  0.101  0.391  1.0
  O  O5  1  0.551  0.449  0.391  1.0
  O  O6  1  0.899  0.449  0.391  1.0
  O  O7  1  0.333  0.667  0.354  1.0
  O  O8  1  0.452  0.903  0.884  1.0
  O  O9  1  0.452  0.548  0.884  1.0
  O  O10  1  0.097  0.548  0.884  1.0
  O  O11  1  0.897  0.794  0.966  1.0
  O  O12  1  0.897  0.103  0.966  1.0
  O  O13  1  0.206  0.103  0.966  1.0
  O  O14  1  0.100  0.200  0.554  1.0
  O  O15  1  0.100  0.900  0.554  1.0
  O  O16  1  0.800  0.900  0.554  1.0
[/CIF]
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The material described by (MnO4)2NiO6 is Silicon tetrafluoride-derived structured and crystallizes in the trigonal P3m1 space group. The structure is zero-dimensional and consists of two mangan(iv)-hydroxyd molecules and one NiO6 cluster. In the NiO6 cluster, Ni(1) is bonded in a distorted octahedral geometry to three equivalent O(5) and three equivalent O(6) atoms. There are two inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Ni(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2NiO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.626
_cell_length_b   7.626
_cell_length_c   4.480
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   225.628
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.667  0.333  0.499  1.0
  Mn  Mn1  1  0.333  0.667  0.993  1.0
  Ni  Ni2  1  0.000  0.000  0.254  1.0
  O  O3  1  0.667  0.333  0.861  1.0
  O  O4  1  0.551  0.101  0.391  1.0
  O  O5  1  0.551  0.449  0.391  1.0
  O  O6  1  0.899  0.449  0.391  1.0
  O  O7  1  0.333  0.667  0.354  1.0
  O  O8  1  0.452  0.903  0.884  1.0
  O  O9  1  0.452  0.548  0.884  1.0
  O  O10  1  0.097  0.548  0.884  1.0
  O  O11  1  0.897  0.794  0.966  1.0
  O  O12  1  0.897  0.103  0.966  1.0
  O  O13  1  0.206  0.103  0.966  1.0
  O  O14  1  0.100  0.200  0.554  1.0
  O  O15  1  0.100  0.900  0.554  1.0
  O  O16  1  0.800  0.900  0.554  1.0
[/CIF]
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