The structure described by AsNO3NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four AsNO3 clusters. In each AsNO3 cluster, As(1) is bonded in a water-like geometry to one O(1) and one O(3) atom. N(1) is bonded in a water-like geometry to one O(2) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one As(1) and one N(1) atom. is represented by the CIF card [CIF]
data_As(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.746
_cell_length_b   8.853
_cell_length_c   10.850
_cell_angle_alpha   67.477
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   598.517
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.333  0.083  0.320  1.0
  As  As1  1  0.833  0.417  0.680  1.0
  As  As2  1  0.667  0.917  0.680  1.0
  As  As3  1  0.167  0.583  0.320  1.0
  N  N4  1  0.756  0.355  0.438  1.0
  N  N5  1  0.256  0.145  0.562  1.0
  N  N6  1  0.244  0.645  0.562  1.0
  N  N7  1  0.744  0.855  0.438  1.0
  N  N8  1  0.874  0.233  0.110  1.0
  N  N9  1  0.374  0.267  0.890  1.0
  N  N10  1  0.126  0.767  0.890  1.0
  N  N11  1  0.626  0.733  0.110  1.0
  O  O12  1  0.373  0.281  0.256  1.0
  O  O13  1  0.873  0.219  0.744  1.0
  O  O14  1  0.627  0.719  0.744  1.0
  O  O15  1  0.127  0.781  0.256  1.0
  O  O16  1  0.677  0.896  0.326  1.0
  O  O17  1  0.177  0.604  0.674  1.0
  O  O18  1  0.323  0.104  0.674  1.0
  O  O19  1  0.823  0.396  0.326  1.0
  O  O20  1  0.287  0.023  0.512  1.0
  O  O21  1  0.787  0.477  0.488  1.0
  O  O22  1  0.713  0.977  0.488  1.0
  O  O23  1  0.213  0.523  0.512  1.0
  O  O24  1  0.270  0.162  0.957  1.0
  O  O25  1  0.770  0.338  0.043  1.0
  O  O26  1  0.730  0.838  0.043  1.0
  O  O27  1  0.230  0.662  0.957  1.0
[/CIF]
.
The structure described by AsNO3NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four AsNO3 clusters. In each AsNO3 cluster, As(1) is bonded in a water-like geometry to one O(1) and one O(3) atom. N(1) is bonded in a water-like geometry to one O(2) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one As(1) and one N(1) atom. is represented by the CIF card [CIF]
data_As(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.746
_cell_length_b   8.853
_cell_length_c   10.850
_cell_angle_alpha   67.477
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   598.517
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.333  0.083  0.320  1.0
  As  As1  1  0.833  0.417  0.680  1.0
  As  As2  1  0.667  0.917  0.680  1.0
  As  As3  1  0.167  0.583  0.320  1.0
  N  N4  1  0.756  0.355  0.438  1.0
  N  N5  1  0.256  0.145  0.562  1.0
  N  N6  1  0.244  0.645  0.562  1.0
  N  N7  1  0.744  0.855  0.438  1.0
  N  N8  1  0.874  0.233  0.110  1.0
  N  N9  1  0.374  0.267  0.890  1.0
  N  N10  1  0.126  0.767  0.890  1.0
  N  N11  1  0.626  0.733  0.110  1.0
  O  O12  1  0.373  0.281  0.256  1.0
  O  O13  1  0.873  0.219  0.744  1.0
  O  O14  1  0.627  0.719  0.744  1.0
  O  O15  1  0.127  0.781  0.256  1.0
  O  O16  1  0.677  0.896  0.326  1.0
  O  O17  1  0.177  0.604  0.674  1.0
  O  O18  1  0.323  0.104  0.674  1.0
  O  O19  1  0.823  0.396  0.326  1.0
  O  O20  1  0.287  0.023  0.512  1.0
  O  O21  1  0.787  0.477  0.488  1.0
  O  O22  1  0.713  0.977  0.488  1.0
  O  O23  1  0.213  0.523  0.512  1.0
  O  O24  1  0.270  0.162  0.957  1.0
  O  O25  1  0.770  0.338  0.043  1.0
  O  O26  1  0.730  0.838  0.043  1.0
  O  O27  1  0.230  0.662  0.957  1.0
[/CIF]
.