The material described by NH3NHONH7Se2O6H2O is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four ammonia molecules, four nitroxyl molecules, four water molecules, and four NH7Se2O6 clusters. In each NH7Se2O6 cluster, N(2) is bonded in a tetrahedral geometry to one H(5), one H(6), one H(7), and one H(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. In the second H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(6) is bonded in a linear geometry to one N(2) and one O(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one O(2) atom. In the seventh H site, H(13) is bonded in a linear geometry to one O(1) and one O(5) atom. There are two inequivalent Se sites. In the first Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(5), one O(6), and one O(7) atom. In the second Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one H(13) and one Se(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one H(11) and one Se(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(6) and one Se(1) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one H(13) and one Se(2) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one H(1) and one Se(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Se(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H13Se2N3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.450
_cell_length_b   6.450
_cell_length_c   17.103
_cell_angle_alpha   75.053
_cell_angle_beta   75.053
_cell_angle_gamma   62.703
_symmetry_Int_Tables_number   1
_cell_volume   602.716
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.133  0.424  0.126  1.0
  H  H1  1  0.424  0.133  0.626  1.0
  H  H2  1  0.356  0.507  0.007  1.0
  H  H3  1  0.507  0.356  0.507  1.0
  H  H4  1  0.599  0.448  0.864  1.0
  H  H5  1  0.448  0.599  0.364  1.0
  H  H6  1  0.771  0.457  0.781  1.0
  H  H7  1  0.457  0.771  0.281  1.0
  H  H8  1  0.239  0.135  0.343  1.0
  H  H9  1  0.135  0.239  0.843  1.0
  H  H10  1  0.395  0.277  0.352  1.0
  H  H11  1  0.277  0.395  0.852  1.0
  H  H12  1  0.284  0.329  0.263  1.0
  H  H13  1  0.329  0.284  0.763  1.0
  H  H14  1  0.093  0.434  0.346  1.0
  H  H15  1  0.434  0.093  0.846  1.0
  H  H16  1  0.773  0.786  0.700  1.0
  H  H17  1  0.786  0.773  0.200  1.0
  H  H18  1  0.873  0.599  0.636  1.0
  H  H19  1  0.599  0.873  0.136  1.0
  H  H20  1  0.736  0.689  0.916  1.0
  H  H21  1  0.689  0.736  0.416  1.0
  H  H22  1  0.588  0.703  0.676  1.0
  H  H23  1  0.703  0.588  0.176  1.0
  H  H24  1  0.968  0.100  0.007  1.0
  H  H25  1  0.100  0.968  0.507  1.0
  Se  Se26  1  0.860  0.008  0.390  1.0
  Se  Se27  1  0.008  0.860  0.890  1.0
  Se  Se28  1  0.032  0.113  0.131  1.0
  Se  Se29  1  0.113  0.032  0.631  1.0
  N  N30  1  0.428  0.605  0.023  1.0
  N  N31  1  0.605  0.428  0.523  1.0
  N  N32  1  0.247  0.297  0.326  1.0
  N  N33  1  0.297  0.247  0.826  1.0
  N  N34  1  0.758  0.647  0.688  1.0
  N  N35  1  0.647  0.758  0.188  1.0
  O  O36  1  0.908  0.923  0.488  1.0
  O  O37  1  0.923  0.908  0.988  1.0
  O  O38  1  0.812  0.764  0.372  1.0
  O  O39  1  0.764  0.812  0.872  1.0
  O  O40  1  0.584  0.233  0.397  1.0
  O  O41  1  0.233  0.584  0.897  1.0
  O  O42  1  0.362  0.762  0.338  1.0
  O  O43  1  0.762  0.362  0.838  1.0
  O  O44  1  0.006  0.222  0.025  1.0
  O  O45  1  0.222  0.006  0.525  1.0
  O  O46  1  0.215  0.252  0.139  1.0
  O  O47  1  0.252  0.215  0.639  1.0
  O  O48  1  0.765  0.268  0.177  1.0
  O  O49  1  0.268  0.765  0.677  1.0
  O  O50  1  0.347  0.634  0.095  1.0
  O  O51  1  0.634  0.347  0.595  1.0
[/CIF]
.
The material described by NH3NHONH7Se2O6H2O is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four ammonia molecules, four nitroxyl molecules, four water molecules, and four NH7Se2O6 clusters. In each NH7Se2O6 cluster, N(2) is bonded in a tetrahedral geometry to one H(5), one H(6), one H(7), and one H(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. In the second H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(6) is bonded in a linear geometry to one N(2) and one O(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one O(2) atom. In the seventh H site, H(13) is bonded in a linear geometry to one O(1) and one O(5) atom. There are two inequivalent Se sites. In the first Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(5), one O(6), and one O(7) atom. In the second Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one H(13) and one Se(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one H(11) and one Se(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(6) and one Se(1) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one H(13) and one Se(2) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one H(1) and one Se(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Se(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H13Se2N3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.450
_cell_length_b   6.450
_cell_length_c   17.103
_cell_angle_alpha   75.053
_cell_angle_beta   75.053
_cell_angle_gamma   62.703
_symmetry_Int_Tables_number   1
_cell_volume   602.716
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.133  0.424  0.126  1.0
  H  H1  1  0.424  0.133  0.626  1.0
  H  H2  1  0.356  0.507  0.007  1.0
  H  H3  1  0.507  0.356  0.507  1.0
  H  H4  1  0.599  0.448  0.864  1.0
  H  H5  1  0.448  0.599  0.364  1.0
  H  H6  1  0.771  0.457  0.781  1.0
  H  H7  1  0.457  0.771  0.281  1.0
  H  H8  1  0.239  0.135  0.343  1.0
  H  H9  1  0.135  0.239  0.843  1.0
  H  H10  1  0.395  0.277  0.352  1.0
  H  H11  1  0.277  0.395  0.852  1.0
  H  H12  1  0.284  0.329  0.263  1.0
  H  H13  1  0.329  0.284  0.763  1.0
  H  H14  1  0.093  0.434  0.346  1.0
  H  H15  1  0.434  0.093  0.846  1.0
  H  H16  1  0.773  0.786  0.700  1.0
  H  H17  1  0.786  0.773  0.200  1.0
  H  H18  1  0.873  0.599  0.636  1.0
  H  H19  1  0.599  0.873  0.136  1.0
  H  H20  1  0.736  0.689  0.916  1.0
  H  H21  1  0.689  0.736  0.416  1.0
  H  H22  1  0.588  0.703  0.676  1.0
  H  H23  1  0.703  0.588  0.176  1.0
  H  H24  1  0.968  0.100  0.007  1.0
  H  H25  1  0.100  0.968  0.507  1.0
  Se  Se26  1  0.860  0.008  0.390  1.0
  Se  Se27  1  0.008  0.860  0.890  1.0
  Se  Se28  1  0.032  0.113  0.131  1.0
  Se  Se29  1  0.113  0.032  0.631  1.0
  N  N30  1  0.428  0.605  0.023  1.0
  N  N31  1  0.605  0.428  0.523  1.0
  N  N32  1  0.247  0.297  0.326  1.0
  N  N33  1  0.297  0.247  0.826  1.0
  N  N34  1  0.758  0.647  0.688  1.0
  N  N35  1  0.647  0.758  0.188  1.0
  O  O36  1  0.908  0.923  0.488  1.0
  O  O37  1  0.923  0.908  0.988  1.0
  O  O38  1  0.812  0.764  0.372  1.0
  O  O39  1  0.764  0.812  0.872  1.0
  O  O40  1  0.584  0.233  0.397  1.0
  O  O41  1  0.233  0.584  0.897  1.0
  O  O42  1  0.362  0.762  0.338  1.0
  O  O43  1  0.762  0.362  0.838  1.0
  O  O44  1  0.006  0.222  0.025  1.0
  O  O45  1  0.222  0.006  0.525  1.0
  O  O46  1  0.215  0.252  0.139  1.0
  O  O47  1  0.252  0.215  0.639  1.0
  O  O48  1  0.765  0.268  0.177  1.0
  O  O49  1  0.268  0.765  0.677  1.0
  O  O50  1  0.347  0.634  0.095  1.0
  O  O51  1  0.634  0.347  0.595  1.0
[/CIF]
.