The structure described by Li4Co5SnO12 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(11), one O(15), one O(21), one O(23), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-53°. In the second Li site, Li(2) is bonded to one O(12), one O(16), one O(2), one O(22), one O(24), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and  a faceface with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-52°. In the third Li site, Li(3) is bonded to one O(13), one O(17), one O(19), one O(3), one O(5), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, and  a faceface with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-53°. In the fourth Li site, Li(4) is bonded to one O(10), one O(14), one O(18), one O(20), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-52°. In the fifth Li site, Li(5) is bonded to one O(11), one O(15), one O(2), one O(21), one O(23), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and  a faceface with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-52°. In the sixth Li site, Li(6) is bonded to one O(1), one O(12), one O(16), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and  a faceface with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-52°. In the seventh Li site, Li(7) is bonded to one O(13), one O(17), one O(19), one O(4), one O(6), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and  a faceface with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-52°. In the eighth Li site, Li(8) is bonded to one O(10), one O(14), one O(18), one O(20), one O(3), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and  a faceface with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-52°. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Co(7)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-11°. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(14), one O(15), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra,  a faceface with one Li(5)O6 octahedra, and  a faceface with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-44°. In the third Co site, Co(3) is bonded to one O(12), one O(13), one O(16), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra,  a faceface with one Li(6)O6 octahedra, and  a faceface with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-44°. In the fourth Co site, Co(4) is bonded to one O(12), one O(13), one O(16), one O(5), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra,  a faceface with one Li(2)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the fifth Co site, Co(5) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Li(8)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra,  a faceface with one Li(1)O6 octahedra, and  a faceface with one Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-43°. In the sixth Co site, Co(6) is bonded to one O(1), one O(17), one O(20), one O(21), one O(24), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Co(10)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-13°. In the seventh Co site, Co(7) is bonded to one O(18), one O(19), one O(2), one O(22), one O(23), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the eighth Co site, Co(8) is bonded to one O(17), one O(19), one O(2), one O(21), one O(23), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Co(10)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-14°. In the ninth Co site, Co(9) is bonded to one O(1), one O(18), one O(20), one O(22), one O(24), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-14°. In the tenth Co site, Co(10) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(10), one O(11), one O(13), one O(16), one O(5), and one O(7) atom to form SnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Li(8)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. In the second Sn site, Sn(2) is bonded to one O(12), one O(14), one O(15), one O(6), one O(8), and one O(9) atom to form SnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(6), one Co(10), one Co(6), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, and  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid. In the second O site, O(2) is bonded to one Li(2), one Li(5), one Co(1), one Co(7), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, and  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid. In the third O site, O(3) is bonded to one Li(3), one Li(8), one Co(10), one Co(6), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid, and  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(7), one Co(1), one Co(7), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid, and  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid. In the fifth O site, O(5) is bonded to one Li(3), one Li(8), one Co(2), one Co(4), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the sixth O site, O(6) is bonded to one Li(4), one Li(7), one Co(3), one Co(5), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(4)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the seventh O site, O(7) is bonded to one Li(2), one Li(5), one Co(2), one Co(4), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid, and  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(6), one Co(3), one Co(5), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the ninth O site, O(9) is bonded to one Li(3), one Li(7), one Co(3), one Co(4), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(19)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(13)Li2Co2Sn trigonal bipyramids. In the tenth O site, O(10) is bonded to one Li(4), one Li(8), one Co(2), one Co(5), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(20)Li2Co3 square pyramids,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(14)Li2Co2Sn trigonal bipyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(5), one Co(2), one Co(5), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid, corners with two equivalent O(23)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(15)Li2Co2Sn trigonal bipyramids. In the twelfth O site, O(12) is bonded to one Li(2), one Li(6), one Co(3), one Co(4), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid, corners with two equivalent O(24)Li2Co3 square pyramids,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(16)Li2Co2Sn trigonal bipyramids. In the thirteenth O site, O(13) is bonded to one Li(3), one Li(7), one Co(3), one Co(4), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(17)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(9)Li2Co2Sn trigonal bipyramids. In the fourteenth O site, O(14) is bonded to one Li(4), one Li(8), one Co(2), one Co(5), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(18)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(10)Li2Co2Sn trigonal bipyramids. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Co(2), one Co(5), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid, corners with two equivalent O(21)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(11)Li2Co2Sn trigonal bipyramids. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Co(3), one Co(4), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid, corners with two equivalent O(22)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(12)Li2Co2Sn trigonal bipyramids. In the seventeenth O site, O(17) is bonded to one Li(3), one Li(7), one Co(10), one Co(6), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(13)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(19)Li2Co3 square pyramids, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the eighteenth O site, O(18) is bonded to one Li(4), one Li(8), one Co(1), one Co(7), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(14)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(20)Li2Co3 square pyramids, and  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid. In the nineteenth O site, O(19) is bonded to one Li(3), one Li(7), one Co(10), one Co(7), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(9)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(17)Li2Co3 square pyramids, and  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid. In the twentieth O site, O(20) is bonded to one Li(4), one Li(8), one Co(1), one Co(6), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(10)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(18)Li2Co3 square pyramids, and  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(5), one Co(10), one Co(6), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(15)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(23)Li2Co3 square pyramids, and  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(6), one Co(1), one Co(7), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(16)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(24)Li2Co3 square pyramids, and  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(5), one Co(10), one Co(7), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(11)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(21)Li2Co3 square pyramids, and  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(6), one Co(1), one Co(6), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(12)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(22)Li2Co3 square pyramids, and  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid. is represented by the CIF file [CIF]
data_Li4Co5SnO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.041
_cell_length_b   10.852
_cell_length_c   8.798
_cell_angle_alpha   66.051
_cell_angle_beta   89.928
_cell_angle_gamma   85.319
_symmetry_Int_Tables_number   1
_cell_volume   438.108
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.055  0.747  0.463  1.0
  Li  Li1  1  0.530  0.746  0.961  1.0
  Li  Li2  1  0.445  0.253  0.711  1.0
  Li  Li3  1  0.969  0.254  0.207  1.0
  Li  Li4  1  0.545  0.745  0.297  1.0
  Li  Li5  1  0.044  0.746  0.792  1.0
  Li  Li6  1  0.956  0.255  0.541  1.0
  Li  Li7  1  0.456  0.254  0.038  1.0
  Co  Co8  1  0.250  0.500  0.084  1.0
  Co  Co9  1  0.500  1.000  0.167  1.0
  Co  Co10  1  1.000  0.000  0.667  1.0
  Co  Co11  1  0.500  0.000  0.833  1.0
  Co  Co12  1  0.000  1.000  0.333  1.0
  Co  Co13  1  0.249  0.500  0.753  1.0
  Co  Co14  1  0.750  0.500  0.244  1.0
  Co  Co15  1  0.249  0.500  0.412  1.0
  Co  Co16  1  0.749  0.500  0.916  1.0
  Co  Co17  1  0.750  0.500  0.583  1.0
  Sn  Sn18  1  0.999  0.000  0.000  1.0
  Sn  Sn19  1  0.501  0.999  0.500  1.0
  O  O20  1  0.911  0.603  0.708  1.0
  O  O21  1  0.415  0.602  0.188  1.0
  O  O22  1  0.589  0.397  0.810  1.0
  O  O23  1  0.086  0.398  0.292  1.0
  O  O24  1  0.338  0.107  0.947  1.0
  O  O25  1  0.839  0.107  0.447  1.0
  O  O26  1  0.661  0.893  0.053  1.0
  O  O27  1  0.162  0.892  0.554  1.0
  O  O28  1  0.304  0.107  0.625  1.0
  O  O29  1  0.804  0.107  0.125  1.0
  O  O30  1  0.196  0.893  0.232  1.0
  O  O31  1  0.696  0.893  0.733  1.0
  O  O32  1  0.802  0.108  0.768  1.0
  O  O33  1  0.305  0.106  0.269  1.0
  O  O34  1  0.697  0.893  0.375  1.0
  O  O35  1  0.195  0.894  0.876  1.0
  O  O36  1  0.098  0.391  0.631  1.0
  O  O37  1  0.599  0.402  0.130  1.0
  O  O38  1  0.609  0.397  0.454  1.0
  O  O39  1  0.125  0.390  0.992  1.0
  O  O40  1  0.403  0.609  0.522  1.0
  O  O41  1  0.898  0.597  0.033  1.0
  O  O42  1  0.894  0.604  0.351  1.0
  O  O43  1  0.375  0.610  0.882  1.0
[/CIF]
.
The structure described by Li4Co5SnO12 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(11), one O(15), one O(21), one O(23), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-53°. In the second Li site, Li(2) is bonded to one O(12), one O(16), one O(2), one O(22), one O(24), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and  a faceface with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-52°. In the third Li site, Li(3) is bonded to one O(13), one O(17), one O(19), one O(3), one O(5), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, and  a faceface with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-53°. In the fourth Li site, Li(4) is bonded to one O(10), one O(14), one O(18), one O(20), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-52°. In the fifth Li site, Li(5) is bonded to one O(11), one O(15), one O(2), one O(21), one O(23), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and  a faceface with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-52°. In the sixth Li site, Li(6) is bonded to one O(1), one O(12), one O(16), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and  a faceface with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-52°. In the seventh Li site, Li(7) is bonded to one O(13), one O(17), one O(19), one O(4), one O(6), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and  a faceface with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-52°. In the eighth Li site, Li(8) is bonded to one O(10), one O(14), one O(18), one O(20), one O(3), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and  a faceface with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-52°. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Co(7)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-11°. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(14), one O(15), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra,  a faceface with one Li(5)O6 octahedra, and  a faceface with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-44°. In the third Co site, Co(3) is bonded to one O(12), one O(13), one O(16), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra,  a faceface with one Li(6)O6 octahedra, and  a faceface with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-44°. In the fourth Co site, Co(4) is bonded to one O(12), one O(13), one O(16), one O(5), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra,  a faceface with one Li(2)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the fifth Co site, Co(5) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Li(8)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra,  a faceface with one Li(1)O6 octahedra, and  a faceface with one Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-43°. In the sixth Co site, Co(6) is bonded to one O(1), one O(17), one O(20), one O(21), one O(24), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Co(10)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-13°. In the seventh Co site, Co(7) is bonded to one O(18), one O(19), one O(2), one O(22), one O(23), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the eighth Co site, Co(8) is bonded to one O(17), one O(19), one O(2), one O(21), one O(23), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Co(10)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-14°. In the ninth Co site, Co(9) is bonded to one O(1), one O(18), one O(20), one O(22), one O(24), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-14°. In the tenth Co site, Co(10) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(10), one O(11), one O(13), one O(16), one O(5), and one O(7) atom to form SnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Li(8)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. In the second Sn site, Sn(2) is bonded to one O(12), one O(14), one O(15), one O(6), one O(8), and one O(9) atom to form SnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(6), one Co(10), one Co(6), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, and  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid. In the second O site, O(2) is bonded to one Li(2), one Li(5), one Co(1), one Co(7), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, and  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid. In the third O site, O(3) is bonded to one Li(3), one Li(8), one Co(10), one Co(6), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid, and  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(7), one Co(1), one Co(7), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid, and  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid. In the fifth O site, O(5) is bonded to one Li(3), one Li(8), one Co(2), one Co(4), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the sixth O site, O(6) is bonded to one Li(4), one Li(7), one Co(3), one Co(5), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(4)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the seventh O site, O(7) is bonded to one Li(2), one Li(5), one Co(2), one Co(4), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid, and  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(6), one Co(3), one Co(5), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the ninth O site, O(9) is bonded to one Li(3), one Li(7), one Co(3), one Co(4), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(19)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(13)Li2Co2Sn trigonal bipyramids. In the tenth O site, O(10) is bonded to one Li(4), one Li(8), one Co(2), one Co(5), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(20)Li2Co3 square pyramids,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(14)Li2Co2Sn trigonal bipyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(5), one Co(2), one Co(5), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid, corners with two equivalent O(23)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(15)Li2Co2Sn trigonal bipyramids. In the twelfth O site, O(12) is bonded to one Li(2), one Li(6), one Co(3), one Co(4), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid, corners with two equivalent O(24)Li2Co3 square pyramids,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(16)Li2Co2Sn trigonal bipyramids. In the thirteenth O site, O(13) is bonded to one Li(3), one Li(7), one Co(3), one Co(4), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(17)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(9)Li2Co2Sn trigonal bipyramids. In the fourteenth O site, O(14) is bonded to one Li(4), one Li(8), one Co(2), one Co(5), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(18)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(10)Li2Co2Sn trigonal bipyramids. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Co(2), one Co(5), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid, corners with two equivalent O(21)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(11)Li2Co2Sn trigonal bipyramids. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Co(3), one Co(4), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid, corners with two equivalent O(22)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, and edges with two equivalent O(12)Li2Co2Sn trigonal bipyramids. In the seventeenth O site, O(17) is bonded to one Li(3), one Li(7), one Co(10), one Co(6), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(13)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(19)Li2Co3 square pyramids, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the eighteenth O site, O(18) is bonded to one Li(4), one Li(8), one Co(1), one Co(7), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(14)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(20)Li2Co3 square pyramids, and  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid. In the nineteenth O site, O(19) is bonded to one Li(3), one Li(7), one Co(10), one Co(7), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(9)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(17)Li2Co3 square pyramids, and  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid. In the twentieth O site, O(20) is bonded to one Li(4), one Li(8), one Co(1), one Co(6), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(10)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(18)Li2Co3 square pyramids, and  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(5), one Co(10), one Co(6), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(15)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(23)Li2Co3 square pyramids, and  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(6), one Co(1), one Co(7), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(16)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(24)Li2Co3 square pyramids, and  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(5), one Co(10), one Co(7), and one Co(8) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(11)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(21)Li2Co3 square pyramids, and  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(6), one Co(1), one Co(6), and one Co(9) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid, corners with two equivalent O(12)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(22)Li2Co3 square pyramids, and  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid. is represented by the CIF file [CIF]
data_Li4Co5SnO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.041
_cell_length_b   10.852
_cell_length_c   8.798
_cell_angle_alpha   66.051
_cell_angle_beta   89.928
_cell_angle_gamma   85.319
_symmetry_Int_Tables_number   1
_cell_volume   438.108
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.055  0.747  0.463  1.0
  Li  Li1  1  0.530  0.746  0.961  1.0
  Li  Li2  1  0.445  0.253  0.711  1.0
  Li  Li3  1  0.969  0.254  0.207  1.0
  Li  Li4  1  0.545  0.745  0.297  1.0
  Li  Li5  1  0.044  0.746  0.792  1.0
  Li  Li6  1  0.956  0.255  0.541  1.0
  Li  Li7  1  0.456  0.254  0.038  1.0
  Co  Co8  1  0.250  0.500  0.084  1.0
  Co  Co9  1  0.500  1.000  0.167  1.0
  Co  Co10  1  1.000  0.000  0.667  1.0
  Co  Co11  1  0.500  0.000  0.833  1.0
  Co  Co12  1  0.000  1.000  0.333  1.0
  Co  Co13  1  0.249  0.500  0.753  1.0
  Co  Co14  1  0.750  0.500  0.244  1.0
  Co  Co15  1  0.249  0.500  0.412  1.0
  Co  Co16  1  0.749  0.500  0.916  1.0
  Co  Co17  1  0.750  0.500  0.583  1.0
  Sn  Sn18  1  0.999  0.000  0.000  1.0
  Sn  Sn19  1  0.501  0.999  0.500  1.0
  O  O20  1  0.911  0.603  0.708  1.0
  O  O21  1  0.415  0.602  0.188  1.0
  O  O22  1  0.589  0.397  0.810  1.0
  O  O23  1  0.086  0.398  0.292  1.0
  O  O24  1  0.338  0.107  0.947  1.0
  O  O25  1  0.839  0.107  0.447  1.0
  O  O26  1  0.661  0.893  0.053  1.0
  O  O27  1  0.162  0.892  0.554  1.0
  O  O28  1  0.304  0.107  0.625  1.0
  O  O29  1  0.804  0.107  0.125  1.0
  O  O30  1  0.196  0.893  0.232  1.0
  O  O31  1  0.696  0.893  0.733  1.0
  O  O32  1  0.802  0.108  0.768  1.0
  O  O33  1  0.305  0.106  0.269  1.0
  O  O34  1  0.697  0.893  0.375  1.0
  O  O35  1  0.195  0.894  0.876  1.0
  O  O36  1  0.098  0.391  0.631  1.0
  O  O37  1  0.599  0.402  0.130  1.0
  O  O38  1  0.609  0.397  0.454  1.0
  O  O39  1  0.125  0.390  0.992  1.0
  O  O40  1  0.403  0.609  0.522  1.0
  O  O41  1  0.898  0.597  0.033  1.0
  O  O42  1  0.894  0.604  0.351  1.0
  O  O43  1  0.375  0.610  0.882  1.0
[/CIF]
.