The structure described by HoMnCu4P3 crystallizes in the orthorhombic Pnma space group. Ho(1) is bonded in a 6-coordinate geometry to one Cu(2), two equivalent P(1), two equivalent P(2), and two equivalent P(3) atoms. Mn(1) is bonded in a 13-coordinate geometry to one Cu(3), two equivalent Cu(1), two equivalent Cu(4), three equivalent Cu(2), one P(1), two equivalent P(2), and two equivalent P(3) atoms. There are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent Mn(1), one P(2), and three equivalent P(1) atoms to form distorted edge-sharing CuMn2P4 tetrahedra. In the second Cu site, Cu(2) is bonded in a 12-coordinate geometry to one Ho(1), three equivalent Mn(1), two equivalent Cu(2), two equivalent Cu(3), one P(2), and three equivalent P(3) atoms. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to one Mn(1), two equivalent Cu(2), one P(1), one P(3), and two equivalent P(2) atoms. In the fourth Cu site, Cu(4) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(2), one P(3), and two equivalent P(1) atoms. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 9-coordinate geometry to two equivalent Ho(1), two equivalent Mn(1), one Cu(3), one Cu(4), and three equivalent Cu(2) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to two equivalent Ho(1), one Mn(1), one Cu(3), two equivalent Cu(4), and three equivalent Cu(1) atoms. In the third P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Ho(1), two equivalent Mn(1), one Cu(1), one Cu(2), one Cu(4), and two equivalent Cu(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_HoMnCu4P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.772
_cell_length_b   10.839
_cell_length_c   12.524
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   512.033
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.250  0.584  0.793  1.0
  Ho  Ho1  1  0.250  0.916  0.293  1.0
  Ho  Ho2  1  0.750  0.416  0.207  1.0
  Ho  Ho3  1  0.750  0.084  0.707  1.0
  Mn  Mn4  1  0.250  0.714  0.522  1.0
  Mn  Mn5  1  0.250  0.786  0.022  1.0
  Mn  Mn6  1  0.750  0.286  0.478  1.0
  Mn  Mn7  1  0.750  0.214  0.978  1.0
  Cu  Cu8  1  0.250  0.087  0.506  1.0
  Cu  Cu9  1  0.250  0.413  0.006  1.0
  Cu  Cu10  1  0.750  0.913  0.494  1.0
  Cu  Cu11  1  0.750  0.587  0.994  1.0
  Cu  Cu12  1  0.250  0.463  0.565  1.0
  Cu  Cu13  1  0.250  0.037  0.065  1.0
  Cu  Cu14  1  0.750  0.537  0.435  1.0
  Cu  Cu15  1  0.750  0.963  0.935  1.0
  Cu  Cu16  1  0.250  0.875  0.808  1.0
  Cu  Cu17  1  0.250  0.625  0.308  1.0
  Cu  Cu18  1  0.750  0.125  0.192  1.0
  Cu  Cu19  1  0.750  0.375  0.692  1.0
  Cu  Cu20  1  0.250  0.286  0.818  1.0
  Cu  Cu21  1  0.250  0.214  0.318  1.0
  Cu  Cu22  1  0.750  0.714  0.182  1.0
  Cu  Cu23  1  0.750  0.786  0.682  1.0
  P  P24  1  0.250  0.906  0.617  1.0
  P  P25  1  0.250  0.594  0.117  1.0
  P  P26  1  0.750  0.094  0.383  1.0
  P  P27  1  0.750  0.406  0.883  1.0
  P  P28  1  0.250  0.258  0.624  1.0
  P  P29  1  0.250  0.242  0.124  1.0
  P  P30  1  0.750  0.742  0.376  1.0
  P  P31  1  0.750  0.758  0.876  1.0
  P  P32  1  0.250  0.085  0.879  1.0
  P  P33  1  0.250  0.415  0.379  1.0
  P  P34  1  0.750  0.915  0.121  1.0
  P  P35  1  0.750  0.585  0.621  1.0
[/CIF]
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The structure described by HoMnCu4P3 crystallizes in the orthorhombic Pnma space group. Ho(1) is bonded in a 6-coordinate geometry to one Cu(2), two equivalent P(1), two equivalent P(2), and two equivalent P(3) atoms. Mn(1) is bonded in a 13-coordinate geometry to one Cu(3), two equivalent Cu(1), two equivalent Cu(4), three equivalent Cu(2), one P(1), two equivalent P(2), and two equivalent P(3) atoms. There are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent Mn(1), one P(2), and three equivalent P(1) atoms to form distorted edge-sharing CuMn2P4 tetrahedra. In the second Cu site, Cu(2) is bonded in a 12-coordinate geometry to one Ho(1), three equivalent Mn(1), two equivalent Cu(2), two equivalent Cu(3), one P(2), and three equivalent P(3) atoms. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to one Mn(1), two equivalent Cu(2), one P(1), one P(3), and two equivalent P(2) atoms. In the fourth Cu site, Cu(4) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(2), one P(3), and two equivalent P(1) atoms. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 9-coordinate geometry to two equivalent Ho(1), two equivalent Mn(1), one Cu(3), one Cu(4), and three equivalent Cu(2) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to two equivalent Ho(1), one Mn(1), one Cu(3), two equivalent Cu(4), and three equivalent Cu(1) atoms. In the third P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Ho(1), two equivalent Mn(1), one Cu(1), one Cu(2), one Cu(4), and two equivalent Cu(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_HoMnCu4P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.772
_cell_length_b   10.839
_cell_length_c   12.524
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   512.033
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.250  0.584  0.793  1.0
  Ho  Ho1  1  0.250  0.916  0.293  1.0
  Ho  Ho2  1  0.750  0.416  0.207  1.0
  Ho  Ho3  1  0.750  0.084  0.707  1.0
  Mn  Mn4  1  0.250  0.714  0.522  1.0
  Mn  Mn5  1  0.250  0.786  0.022  1.0
  Mn  Mn6  1  0.750  0.286  0.478  1.0
  Mn  Mn7  1  0.750  0.214  0.978  1.0
  Cu  Cu8  1  0.250  0.087  0.506  1.0
  Cu  Cu9  1  0.250  0.413  0.006  1.0
  Cu  Cu10  1  0.750  0.913  0.494  1.0
  Cu  Cu11  1  0.750  0.587  0.994  1.0
  Cu  Cu12  1  0.250  0.463  0.565  1.0
  Cu  Cu13  1  0.250  0.037  0.065  1.0
  Cu  Cu14  1  0.750  0.537  0.435  1.0
  Cu  Cu15  1  0.750  0.963  0.935  1.0
  Cu  Cu16  1  0.250  0.875  0.808  1.0
  Cu  Cu17  1  0.250  0.625  0.308  1.0
  Cu  Cu18  1  0.750  0.125  0.192  1.0
  Cu  Cu19  1  0.750  0.375  0.692  1.0
  Cu  Cu20  1  0.250  0.286  0.818  1.0
  Cu  Cu21  1  0.250  0.214  0.318  1.0
  Cu  Cu22  1  0.750  0.714  0.182  1.0
  Cu  Cu23  1  0.750  0.786  0.682  1.0
  P  P24  1  0.250  0.906  0.617  1.0
  P  P25  1  0.250  0.594  0.117  1.0
  P  P26  1  0.750  0.094  0.383  1.0
  P  P27  1  0.750  0.406  0.883  1.0
  P  P28  1  0.250  0.258  0.624  1.0
  P  P29  1  0.250  0.242  0.124  1.0
  P  P30  1  0.750  0.742  0.376  1.0
  P  P31  1  0.750  0.758  0.876  1.0
  P  P32  1  0.250  0.085  0.879  1.0
  P  P33  1  0.250  0.415  0.379  1.0
  P  P34  1  0.750  0.915  0.121  1.0
  P  P35  1  0.750  0.585  0.621  1.0
[/CIF]
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