The material described by XeF3Sb2F11 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Sb2F11 cluster and two XeF3 clusters. In the Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one F(10), one F(13), one F(2), and one F(4) atom. In the second Sb site, Sb(2) is bonded in a 2-coordinate geometry to one F(11), one F(14), one F(3), and one F(4) atom. There are eleven inequivalent F sites. In the first F site, F(14) is bonded in a bent 120 degrees geometry to one Sb(2) and one F(7) atom. In the second F site, F(1) is bonded in a distorted single-bond geometry to one F(13) atom. In the third F site, F(2) is bonded in a distorted L-shaped geometry to one Sb(1) and one F(5) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth F site, F(4) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the sixth F site, F(5) is bonded in a 2-coordinate geometry to one F(11) and one F(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one F(14) atom. In the eighth F site, F(10) is bonded in a distorted water-like geometry to one Sb(1) and one F(12) atom. In the ninth F site, F(11) is bonded in a single-bond geometry to one Sb(2) and one F(5) atom. In the tenth F site, F(12) is bonded in a single-bond geometry to one F(10) atom. In the eleventh F site, F(13) is bonded in a single-bond geometry to one Sb(1) and one F(1) atom. In each XeF3 cluster, Xe(1) is bonded in a 3-coordinate geometry to one F(6), one F(8), and one F(9) atom. There are three inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(9) is bonded in a distorted single-bond geometry to one Xe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2XeF14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.229
_cell_length_b   8.495
_cell_length_c   9.814
_cell_angle_alpha   112.610
_cell_angle_beta   89.528
_cell_angle_gamma   112.160
_symmetry_Int_Tables_number   1
_cell_volume   578.997
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.206  0.589  0.771  1.0
  Sb  Sb1  1  0.794  0.411  0.229  1.0
  Sb  Sb2  1  0.509  0.418  0.708  1.0
  Sb  Sb3  1  0.491  0.582  0.292  1.0
  Xe  Xe4  1  0.192  0.036  0.259  1.0
  Xe  Xe5  1  0.808  0.964  0.741  1.0
  F  F6  1  0.122  0.805  0.572  1.0
  F  F7  1  0.878  0.195  0.428  1.0
  F  F8  1  0.411  0.857  0.706  1.0
  F  F9  1  0.589  0.143  0.294  1.0
  F  F10  1  0.345  0.125  0.764  1.0
  F  F11  1  0.655  0.875  0.236  1.0
  F  F12  1  0.649  0.589  0.217  1.0
  F  F13  1  0.351  0.411  0.783  1.0
  F  F14  1  0.651  0.318  0.486  1.0
  F  F15  1  0.349  0.682  0.514  1.0
  F  F16  1  0.364  0.258  0.361  1.0
  F  F17  1  0.636  0.742  0.639  1.0
  F  F18  1  0.683  0.653  0.028  1.0
  F  F19  1  0.317  0.347  0.972  1.0
  F  F20  1  0.351  0.821  0.100  1.0
  F  F21  1  0.649  0.179  0.900  1.0
  F  F22  1  0.976  0.702  0.161  1.0
  F  F23  1  0.024  0.298  0.839  1.0
  F  F24  1  0.922  0.246  0.241  1.0
  F  F25  1  0.078  0.754  0.759  1.0
  F  F26  1  0.355  0.568  0.370  1.0
  F  F27  1  0.645  0.432  0.630  1.0
  F  F28  1  0.005  0.817  0.906  1.0
  F  F29  1  0.995  0.183  0.094  1.0
  F  F30  1  0.957  0.324  0.633  1.0
  F  F31  1  0.043  0.676  0.367  1.0
  F  F32  1  0.719  0.559  0.898  1.0
  F  F33  1  0.281  0.441  0.102  1.0
[/CIF]
.
The material described by XeF3Sb2F11 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Sb2F11 cluster and two XeF3 clusters. In the Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one F(10), one F(13), one F(2), and one F(4) atom. In the second Sb site, Sb(2) is bonded in a 2-coordinate geometry to one F(11), one F(14), one F(3), and one F(4) atom. There are eleven inequivalent F sites. In the first F site, F(14) is bonded in a bent 120 degrees geometry to one Sb(2) and one F(7) atom. In the second F site, F(1) is bonded in a distorted single-bond geometry to one F(13) atom. In the third F site, F(2) is bonded in a distorted L-shaped geometry to one Sb(1) and one F(5) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth F site, F(4) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the sixth F site, F(5) is bonded in a 2-coordinate geometry to one F(11) and one F(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one F(14) atom. In the eighth F site, F(10) is bonded in a distorted water-like geometry to one Sb(1) and one F(12) atom. In the ninth F site, F(11) is bonded in a single-bond geometry to one Sb(2) and one F(5) atom. In the tenth F site, F(12) is bonded in a single-bond geometry to one F(10) atom. In the eleventh F site, F(13) is bonded in a single-bond geometry to one Sb(1) and one F(1) atom. In each XeF3 cluster, Xe(1) is bonded in a 3-coordinate geometry to one F(6), one F(8), and one F(9) atom. There are three inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(9) is bonded in a distorted single-bond geometry to one Xe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2XeF14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.229
_cell_length_b   8.495
_cell_length_c   9.814
_cell_angle_alpha   112.610
_cell_angle_beta   89.528
_cell_angle_gamma   112.160
_symmetry_Int_Tables_number   1
_cell_volume   578.997
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.206  0.589  0.771  1.0
  Sb  Sb1  1  0.794  0.411  0.229  1.0
  Sb  Sb2  1  0.509  0.418  0.708  1.0
  Sb  Sb3  1  0.491  0.582  0.292  1.0
  Xe  Xe4  1  0.192  0.036  0.259  1.0
  Xe  Xe5  1  0.808  0.964  0.741  1.0
  F  F6  1  0.122  0.805  0.572  1.0
  F  F7  1  0.878  0.195  0.428  1.0
  F  F8  1  0.411  0.857  0.706  1.0
  F  F9  1  0.589  0.143  0.294  1.0
  F  F10  1  0.345  0.125  0.764  1.0
  F  F11  1  0.655  0.875  0.236  1.0
  F  F12  1  0.649  0.589  0.217  1.0
  F  F13  1  0.351  0.411  0.783  1.0
  F  F14  1  0.651  0.318  0.486  1.0
  F  F15  1  0.349  0.682  0.514  1.0
  F  F16  1  0.364  0.258  0.361  1.0
  F  F17  1  0.636  0.742  0.639  1.0
  F  F18  1  0.683  0.653  0.028  1.0
  F  F19  1  0.317  0.347  0.972  1.0
  F  F20  1  0.351  0.821  0.100  1.0
  F  F21  1  0.649  0.179  0.900  1.0
  F  F22  1  0.976  0.702  0.161  1.0
  F  F23  1  0.024  0.298  0.839  1.0
  F  F24  1  0.922  0.246  0.241  1.0
  F  F25  1  0.078  0.754  0.759  1.0
  F  F26  1  0.355  0.568  0.370  1.0
  F  F27  1  0.645  0.432  0.630  1.0
  F  F28  1  0.005  0.817  0.906  1.0
  F  F29  1  0.995  0.183  0.094  1.0
  F  F30  1  0.957  0.324  0.633  1.0
  F  F31  1  0.043  0.676  0.367  1.0
  F  F32  1  0.719  0.559  0.898  1.0
  F  F33  1  0.281  0.441  0.102  1.0
[/CIF]
.