The material described by Cs2WO4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to two equivalent O(2), three equivalent O(1), and four equivalent O(3) atoms. In the second Cs site, Cs(2) is bonded in a 10-coordinate geometry to one O(1), three equivalent O(2), and six equivalent O(3) atoms. W(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Cs(2), three equivalent Cs(1), and one W(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1), three equivalent Cs(2), and one W(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1), three equivalent Cs(2), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2WO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.577
_cell_length_b   8.559
_cell_length_c   11.663
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   656.546
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.510  0.793  1.0
  Cs  Cs1  1  0.750  0.010  0.707  1.0
  Cs  Cs2  1  0.250  0.490  0.207  1.0
  Cs  Cs3  1  0.250  0.990  0.293  1.0
  Cs  Cs4  1  0.750  0.830  0.083  1.0
  Cs  Cs5  1  0.750  0.330  0.417  1.0
  Cs  Cs6  1  0.250  0.170  0.917  1.0
  Cs  Cs7  1  0.250  0.670  0.583  1.0
  W  W8  1  0.750  0.275  0.079  1.0
  W  W9  1  0.750  0.775  0.421  1.0
  W  W10  1  0.250  0.725  0.921  1.0
  W  W11  1  0.250  0.225  0.579  1.0
  O  O12  1  0.750  0.484  0.081  1.0
  O  O13  1  0.750  0.984  0.419  1.0
  O  O14  1  0.250  0.516  0.919  1.0
  O  O15  1  0.250  0.016  0.581  1.0
  O  O16  1  0.750  0.205  0.934  1.0
  O  O17  1  0.750  0.705  0.566  1.0
  O  O18  1  0.250  0.795  0.066  1.0
  O  O19  1  0.250  0.295  0.434  1.0
  O  O20  1  0.973  0.203  0.150  1.0
  O  O21  1  0.527  0.703  0.350  1.0
  O  O22  1  0.473  0.797  0.850  1.0
  O  O23  1  0.027  0.297  0.650  1.0
  O  O24  1  0.027  0.797  0.850  1.0
  O  O25  1  0.473  0.297  0.650  1.0
  O  O26  1  0.527  0.203  0.150  1.0
  O  O27  1  0.973  0.703  0.350  1.0
[/CIF]
.
The material described by Cs2WO4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to two equivalent O(2), three equivalent O(1), and four equivalent O(3) atoms. In the second Cs site, Cs(2) is bonded in a 10-coordinate geometry to one O(1), three equivalent O(2), and six equivalent O(3) atoms. W(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Cs(2), three equivalent Cs(1), and one W(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1), three equivalent Cs(2), and one W(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1), three equivalent Cs(2), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2WO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.577
_cell_length_b   8.559
_cell_length_c   11.663
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   656.546
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.510  0.793  1.0
  Cs  Cs1  1  0.750  0.010  0.707  1.0
  Cs  Cs2  1  0.250  0.490  0.207  1.0
  Cs  Cs3  1  0.250  0.990  0.293  1.0
  Cs  Cs4  1  0.750  0.830  0.083  1.0
  Cs  Cs5  1  0.750  0.330  0.417  1.0
  Cs  Cs6  1  0.250  0.170  0.917  1.0
  Cs  Cs7  1  0.250  0.670  0.583  1.0
  W  W8  1  0.750  0.275  0.079  1.0
  W  W9  1  0.750  0.775  0.421  1.0
  W  W10  1  0.250  0.725  0.921  1.0
  W  W11  1  0.250  0.225  0.579  1.0
  O  O12  1  0.750  0.484  0.081  1.0
  O  O13  1  0.750  0.984  0.419  1.0
  O  O14  1  0.250  0.516  0.919  1.0
  O  O15  1  0.250  0.016  0.581  1.0
  O  O16  1  0.750  0.205  0.934  1.0
  O  O17  1  0.750  0.705  0.566  1.0
  O  O18  1  0.250  0.795  0.066  1.0
  O  O19  1  0.250  0.295  0.434  1.0
  O  O20  1  0.973  0.203  0.150  1.0
  O  O21  1  0.527  0.703  0.350  1.0
  O  O22  1  0.473  0.797  0.850  1.0
  O  O23  1  0.027  0.297  0.650  1.0
  O  O24  1  0.027  0.797  0.850  1.0
  O  O25  1  0.473  0.297  0.650  1.0
  O  O26  1  0.527  0.203  0.150  1.0
  O  O27  1  0.973  0.703  0.350  1.0
[/CIF]
.