The material structure described by Ba7SrCoCu7O24 is (Cubic) Perovskite-derived structured and crystallizes in the trigonal R3m space group. There are three inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(4), one O(6), two equivalent O(1), two equivalent O(3), two equivalent O(5), and four equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with four equivalent Ba(2)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Cu(3)O6 octahedra, faces with three equivalent Cu(1)O6 octahedra, and faces with three equivalent Cu(2)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(6), and four equivalent O(5) atoms to form BaO12 cuboctahedra that share corners with four equivalent Ba(3)O12 cuboctahedra, corners with eight equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Ba(1)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Cu(3)O6 octahedra, faces with three equivalent Cu(1)O6 octahedra, and faces with three equivalent Cu(2)O6 octahedra. In the third Ba site, Ba(3) is bonded to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(2)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Cu(3)O6 octahedra, faces with three equivalent Cu(1)O6 octahedra, and faces with three equivalent Cu(2)O6 octahedra. Sr(1) is bonded to three equivalent O(4), three equivalent O(6), and six equivalent O(5) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(2)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Cu(3)O6 octahedra, faces with three equivalent Cu(1)O6 octahedra, and faces with three equivalent Cu(2)O6 octahedra. Co(1) is bonded to three equivalent O(3) and three equivalent O(6) atoms to form CoO6 octahedra that share corners with six equivalent Cu(2)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(5) atoms to form CuO6 octahedra that share corners with two equivalent Cu(3)O6 octahedra, corners with four equivalent Cu(2)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second Cu site, Cu(2) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(5) atoms to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Cu(1)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the third Cu site, Cu(3) is bonded to three equivalent O(1) and three equivalent O(4) atoms to form CuO6 octahedra that share corners with six equivalent Cu(1)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Ba(2), one Ba(3), two equivalent Ba(1), one Cu(1), and one Cu(3) atom to form distorted OBa4Cu2 octahedra that share corners with two equivalent O(4)Ba3SrCu2 octahedra, corners with four equivalent O(5)Ba3SrCu2 octahedra, corners with four equivalent O(2)Ba4Cu2 octahedra, corners with eight equivalent O(3)Ba4CoCu octahedra, edges with four equivalent O(2)Ba4Cu2 octahedra, faces with two equivalent O(4)Ba3SrCu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, faces with two equivalent O(1)Ba4Cu2 octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the second O site, O(2) is bonded to one Ba(2), one Ba(3), two equivalent Ba(1), one Cu(1), and one Cu(2) atom to form distorted OBa4Cu2 octahedra that share corners with two equivalent O(4)Ba3SrCu2 octahedra, corners with two equivalent O(3)Ba4CoCu octahedra, corners with two equivalent O(1)Ba4Cu2 octahedra, corners with six equivalent O(5)Ba3SrCu2 octahedra, corners with eight equivalent O(2)Ba4Cu2 octahedra, edges with two equivalent O(3)Ba4CoCu octahedra, edges with two equivalent O(1)Ba4Cu2 octahedra,  a faceface with one O(4)Ba3SrCu2 octahedra,  a faceface with one O(3)Ba4CoCu octahedra,  a faceface with one O(1)Ba4Cu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the third O site, O(3) is bonded to one Ba(2), one Ba(3), two equivalent Ba(1), one Co(1), and one Cu(2) atom to form distorted OBa4CoCu octahedra that share corners with four equivalent O(4)Ba3SrCu2 octahedra, corners with four equivalent O(5)Ba3SrCu2 octahedra, corners with four equivalent O(2)Ba4Cu2 octahedra, corners with eight equivalent O(1)Ba4Cu2 octahedra, edges with four equivalent O(2)Ba4Cu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, faces with two equivalent O(3)Ba4CoCu octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the fourth O site, O(4) is bonded to one Ba(1), two equivalent Ba(2), one Sr(1), one Cu(1), and one Cu(3) atom to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(1)Ba4Cu2 octahedra, corners with four equivalent O(5)Ba3SrCu2 octahedra, corners with four equivalent O(3)Ba4CoCu octahedra, corners with four equivalent O(2)Ba4Cu2 octahedra, edges with four equivalent O(5)Ba3SrCu2 octahedra, faces with two equivalent O(4)Ba3SrCu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, faces with two equivalent O(1)Ba4Cu2 octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the fifth O site, O(5) is bonded to one Ba(1), two equivalent Ba(2), one Sr(1), one Cu(1), and one Cu(2) atom to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(4)Ba3SrCu2 octahedra, corners with two equivalent O(3)Ba4CoCu octahedra, corners with two equivalent O(1)Ba4Cu2 octahedra, corners with six equivalent O(2)Ba4Cu2 octahedra, corners with eight equivalent O(5)Ba3SrCu2 octahedra, edges with two equivalent O(4)Ba3SrCu2 octahedra,  a faceface with one O(4)Ba3SrCu2 octahedra,  a faceface with one O(3)Ba4CoCu octahedra,  a faceface with one O(1)Ba4Cu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Ba(1), two equivalent Ba(2), one Sr(1), one Co(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_Ba7SrCoCu7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.992
_cell_length_b   7.992
_cell_length_c   7.992
_cell_angle_alpha   90.027
_cell_angle_beta   90.027
_cell_angle_gamma   90.027
_symmetry_Int_Tables_number   1
_cell_volume   510.420
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.751  0.249  0.751  1.0
  Ba  Ba1  1  0.751  0.249  0.249  1.0
  Ba  Ba2  1  0.751  0.751  0.751  1.0
  Ba  Ba3  1  0.751  0.751  0.249  1.0
  Ba  Ba4  1  0.249  0.249  0.751  1.0
  Ba  Ba5  1  0.249  0.751  0.751  1.0
  Ba  Ba6  1  0.249  0.751  0.249  1.0
  Sr  Sr7  1  0.248  0.248  0.248  1.0
  Co  Co8  1  0.499  0.499  0.499  1.0
  Cu  Cu9  1  0.500  0.000  0.000  1.0
  Cu  Cu10  1  0.500  1.000  0.500  1.0
  Cu  Cu11  1  0.500  0.500  1.000  1.0
  Cu  Cu12  1  0.000  0.000  0.000  1.0
  Cu  Cu13  1  0.000  0.000  0.500  1.0
  Cu  Cu14  1  0.000  0.500  0.000  1.0
  Cu  Cu15  1  1.000  0.500  0.500  1.0
  O  O16  1  0.750  0.001  0.001  1.0
  O  O17  1  0.749  0.001  0.499  1.0
  O  O18  1  0.749  0.499  0.001  1.0
  O  O19  1  0.742  0.499  0.499  1.0
  O  O20  1  0.250  0.006  0.006  1.0
  O  O21  1  0.251  0.006  0.494  1.0
  O  O22  1  0.251  0.494  0.006  1.0
  O  O23  1  0.257  0.496  0.496  1.0
  O  O24  1  0.494  0.251  0.006  1.0
  O  O25  1  0.496  0.257  0.496  1.0
  O  O26  1  0.499  0.749  0.001  1.0
  O  O27  1  0.499  0.742  0.499  1.0
  O  O28  1  0.006  0.250  0.006  1.0
  O  O29  1  0.006  0.251  0.494  1.0
  O  O30  1  0.001  0.750  0.001  1.0
  O  O31  1  0.001  0.749  0.499  1.0
  O  O32  1  0.499  0.001  0.749  1.0
  O  O33  1  0.494  0.006  0.251  1.0
  O  O34  1  0.499  0.499  0.742  1.0
  O  O35  1  0.496  0.496  0.257  1.0
  O  O36  1  0.001  0.001  0.750  1.0
  O  O37  1  0.006  0.006  0.250  1.0
  O  O38  1  0.001  0.499  0.749  1.0
  O  O39  1  0.006  0.494  0.251  1.0
[/CIF]
.
The material structure described by Ba7SrCoCu7O24 is (Cubic) Perovskite-derived structured and crystallizes in the trigonal R3m space group. There are three inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(4), one O(6), two equivalent O(1), two equivalent O(3), two equivalent O(5), and four equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with four equivalent Ba(2)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Cu(3)O6 octahedra, faces with three equivalent Cu(1)O6 octahedra, and faces with three equivalent Cu(2)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(6), and four equivalent O(5) atoms to form BaO12 cuboctahedra that share corners with four equivalent Ba(3)O12 cuboctahedra, corners with eight equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Ba(1)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Cu(3)O6 octahedra, faces with three equivalent Cu(1)O6 octahedra, and faces with three equivalent Cu(2)O6 octahedra. In the third Ba site, Ba(3) is bonded to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(2)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Cu(3)O6 octahedra, faces with three equivalent Cu(1)O6 octahedra, and faces with three equivalent Cu(2)O6 octahedra. Sr(1) is bonded to three equivalent O(4), three equivalent O(6), and six equivalent O(5) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(2)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Cu(3)O6 octahedra, faces with three equivalent Cu(1)O6 octahedra, and faces with three equivalent Cu(2)O6 octahedra. Co(1) is bonded to three equivalent O(3) and three equivalent O(6) atoms to form CoO6 octahedra that share corners with six equivalent Cu(2)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(5) atoms to form CuO6 octahedra that share corners with two equivalent Cu(3)O6 octahedra, corners with four equivalent Cu(2)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second Cu site, Cu(2) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(5) atoms to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Cu(1)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the third Cu site, Cu(3) is bonded to three equivalent O(1) and three equivalent O(4) atoms to form CuO6 octahedra that share corners with six equivalent Cu(1)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Ba(2), one Ba(3), two equivalent Ba(1), one Cu(1), and one Cu(3) atom to form distorted OBa4Cu2 octahedra that share corners with two equivalent O(4)Ba3SrCu2 octahedra, corners with four equivalent O(5)Ba3SrCu2 octahedra, corners with four equivalent O(2)Ba4Cu2 octahedra, corners with eight equivalent O(3)Ba4CoCu octahedra, edges with four equivalent O(2)Ba4Cu2 octahedra, faces with two equivalent O(4)Ba3SrCu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, faces with two equivalent O(1)Ba4Cu2 octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the second O site, O(2) is bonded to one Ba(2), one Ba(3), two equivalent Ba(1), one Cu(1), and one Cu(2) atom to form distorted OBa4Cu2 octahedra that share corners with two equivalent O(4)Ba3SrCu2 octahedra, corners with two equivalent O(3)Ba4CoCu octahedra, corners with two equivalent O(1)Ba4Cu2 octahedra, corners with six equivalent O(5)Ba3SrCu2 octahedra, corners with eight equivalent O(2)Ba4Cu2 octahedra, edges with two equivalent O(3)Ba4CoCu octahedra, edges with two equivalent O(1)Ba4Cu2 octahedra,  a faceface with one O(4)Ba3SrCu2 octahedra,  a faceface with one O(3)Ba4CoCu octahedra,  a faceface with one O(1)Ba4Cu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the third O site, O(3) is bonded to one Ba(2), one Ba(3), two equivalent Ba(1), one Co(1), and one Cu(2) atom to form distorted OBa4CoCu octahedra that share corners with four equivalent O(4)Ba3SrCu2 octahedra, corners with four equivalent O(5)Ba3SrCu2 octahedra, corners with four equivalent O(2)Ba4Cu2 octahedra, corners with eight equivalent O(1)Ba4Cu2 octahedra, edges with four equivalent O(2)Ba4Cu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, faces with two equivalent O(3)Ba4CoCu octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the fourth O site, O(4) is bonded to one Ba(1), two equivalent Ba(2), one Sr(1), one Cu(1), and one Cu(3) atom to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(1)Ba4Cu2 octahedra, corners with four equivalent O(5)Ba3SrCu2 octahedra, corners with four equivalent O(3)Ba4CoCu octahedra, corners with four equivalent O(2)Ba4Cu2 octahedra, edges with four equivalent O(5)Ba3SrCu2 octahedra, faces with two equivalent O(4)Ba3SrCu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, faces with two equivalent O(1)Ba4Cu2 octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the fifth O site, O(5) is bonded to one Ba(1), two equivalent Ba(2), one Sr(1), one Cu(1), and one Cu(2) atom to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(4)Ba3SrCu2 octahedra, corners with two equivalent O(3)Ba4CoCu octahedra, corners with two equivalent O(1)Ba4Cu2 octahedra, corners with six equivalent O(2)Ba4Cu2 octahedra, corners with eight equivalent O(5)Ba3SrCu2 octahedra, edges with two equivalent O(4)Ba3SrCu2 octahedra,  a faceface with one O(4)Ba3SrCu2 octahedra,  a faceface with one O(3)Ba4CoCu octahedra,  a faceface with one O(1)Ba4Cu2 octahedra, faces with two equivalent O(5)Ba3SrCu2 octahedra, and faces with two equivalent O(2)Ba4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Ba(1), two equivalent Ba(2), one Sr(1), one Co(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_Ba7SrCoCu7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.992
_cell_length_b   7.992
_cell_length_c   7.992
_cell_angle_alpha   90.027
_cell_angle_beta   90.027
_cell_angle_gamma   90.027
_symmetry_Int_Tables_number   1
_cell_volume   510.420
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.751  0.249  0.751  1.0
  Ba  Ba1  1  0.751  0.249  0.249  1.0
  Ba  Ba2  1  0.751  0.751  0.751  1.0
  Ba  Ba3  1  0.751  0.751  0.249  1.0
  Ba  Ba4  1  0.249  0.249  0.751  1.0
  Ba  Ba5  1  0.249  0.751  0.751  1.0
  Ba  Ba6  1  0.249  0.751  0.249  1.0
  Sr  Sr7  1  0.248  0.248  0.248  1.0
  Co  Co8  1  0.499  0.499  0.499  1.0
  Cu  Cu9  1  0.500  0.000  0.000  1.0
  Cu  Cu10  1  0.500  1.000  0.500  1.0
  Cu  Cu11  1  0.500  0.500  1.000  1.0
  Cu  Cu12  1  0.000  0.000  0.000  1.0
  Cu  Cu13  1  0.000  0.000  0.500  1.0
  Cu  Cu14  1  0.000  0.500  0.000  1.0
  Cu  Cu15  1  1.000  0.500  0.500  1.0
  O  O16  1  0.750  0.001  0.001  1.0
  O  O17  1  0.749  0.001  0.499  1.0
  O  O18  1  0.749  0.499  0.001  1.0
  O  O19  1  0.742  0.499  0.499  1.0
  O  O20  1  0.250  0.006  0.006  1.0
  O  O21  1  0.251  0.006  0.494  1.0
  O  O22  1  0.251  0.494  0.006  1.0
  O  O23  1  0.257  0.496  0.496  1.0
  O  O24  1  0.494  0.251  0.006  1.0
  O  O25  1  0.496  0.257  0.496  1.0
  O  O26  1  0.499  0.749  0.001  1.0
  O  O27  1  0.499  0.742  0.499  1.0
  O  O28  1  0.006  0.250  0.006  1.0
  O  O29  1  0.006  0.251  0.494  1.0
  O  O30  1  0.001  0.750  0.001  1.0
  O  O31  1  0.001  0.749  0.499  1.0
  O  O32  1  0.499  0.001  0.749  1.0
  O  O33  1  0.494  0.006  0.251  1.0
  O  O34  1  0.499  0.499  0.742  1.0
  O  O35  1  0.496  0.496  0.257  1.0
  O  O36  1  0.001  0.001  0.750  1.0
  O  O37  1  0.006  0.006  0.250  1.0
  O  O38  1  0.001  0.499  0.749  1.0
  O  O39  1  0.006  0.494  0.251  1.0
[/CIF]
.