The material described by RuN(OCl2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia atoms and four RuN(OCl2)2 clusters. In each RuN(OCl2)2 cluster, Ru(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ru(1) atom. is represented by the CIF card [CIF]
data_RuN3(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.547
_cell_length_b   11.065
_cell_length_c   15.680
_cell_angle_alpha   77.433
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1108.595
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.162  0.732  0.087  1.0
  Ru  Ru1  1  0.662  0.268  0.413  1.0
  Ru  Ru2  1  0.838  0.268  0.913  1.0
  Ru  Ru3  1  0.338  0.732  0.587  1.0
  N  N4  1  0.994  0.589  0.146  1.0
  N  N5  1  0.494  0.411  0.354  1.0
  N  N6  1  0.006  0.411  0.854  1.0
  N  N7  1  0.506  0.589  0.646  1.0
  N  N8  1  0.400  0.950  0.357  1.0
  N  N9  1  0.900  0.050  0.143  1.0
  N  N10  1  0.600  0.050  0.643  1.0
  N  N11  1  0.100  0.950  0.857  1.0
  N  N12  1  0.837  0.692  0.435  1.0
  N  N13  1  0.337  0.308  0.065  1.0
  N  N14  1  0.163  0.308  0.565  1.0
  N  N15  1  0.663  0.692  0.935  1.0
  Cl  Cl16  1  0.437  0.591  0.122  1.0
  Cl  Cl17  1  0.937  0.409  0.378  1.0
  Cl  Cl18  1  0.563  0.409  0.878  1.0
  Cl  Cl19  1  0.063  0.591  0.622  1.0
  Cl  Cl20  1  0.182  0.771  0.229  1.0
  Cl  Cl21  1  0.682  0.229  0.271  1.0
  Cl  Cl22  1  0.818  0.229  0.771  1.0
  Cl  Cl23  1  0.318  0.771  0.729  1.0
  Cl  Cl24  1  0.116  0.662  0.958  1.0
  Cl  Cl25  1  0.616  0.338  0.542  1.0
  Cl  Cl26  1  0.884  0.338  0.042  1.0
  Cl  Cl27  1  0.384  0.662  0.458  1.0
  Cl  Cl28  1  0.856  0.840  0.062  1.0
  Cl  Cl29  1  0.356  0.160  0.438  1.0
  Cl  Cl30  1  0.144  0.160  0.938  1.0
  Cl  Cl31  1  0.644  0.840  0.562  1.0
  O  O32  1  0.313  0.855  0.038  1.0
  O  O33  1  0.813  0.145  0.462  1.0
  O  O34  1  0.687  0.145  0.962  1.0
  O  O35  1  0.187  0.855  0.538  1.0
  O  O36  1  0.902  0.505  0.182  1.0
  O  O37  1  0.402  0.495  0.318  1.0
  O  O38  1  0.098  0.495  0.818  1.0
  O  O39  1  0.598  0.505  0.682  1.0
[/CIF]
.
The material described by RuN(OCl2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia atoms and four RuN(OCl2)2 clusters. In each RuN(OCl2)2 cluster, Ru(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ru(1) atom. is represented by the CIF card [CIF]
data_RuN3(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.547
_cell_length_b   11.065
_cell_length_c   15.680
_cell_angle_alpha   77.433
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1108.595
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.162  0.732  0.087  1.0
  Ru  Ru1  1  0.662  0.268  0.413  1.0
  Ru  Ru2  1  0.838  0.268  0.913  1.0
  Ru  Ru3  1  0.338  0.732  0.587  1.0
  N  N4  1  0.994  0.589  0.146  1.0
  N  N5  1  0.494  0.411  0.354  1.0
  N  N6  1  0.006  0.411  0.854  1.0
  N  N7  1  0.506  0.589  0.646  1.0
  N  N8  1  0.400  0.950  0.357  1.0
  N  N9  1  0.900  0.050  0.143  1.0
  N  N10  1  0.600  0.050  0.643  1.0
  N  N11  1  0.100  0.950  0.857  1.0
  N  N12  1  0.837  0.692  0.435  1.0
  N  N13  1  0.337  0.308  0.065  1.0
  N  N14  1  0.163  0.308  0.565  1.0
  N  N15  1  0.663  0.692  0.935  1.0
  Cl  Cl16  1  0.437  0.591  0.122  1.0
  Cl  Cl17  1  0.937  0.409  0.378  1.0
  Cl  Cl18  1  0.563  0.409  0.878  1.0
  Cl  Cl19  1  0.063  0.591  0.622  1.0
  Cl  Cl20  1  0.182  0.771  0.229  1.0
  Cl  Cl21  1  0.682  0.229  0.271  1.0
  Cl  Cl22  1  0.818  0.229  0.771  1.0
  Cl  Cl23  1  0.318  0.771  0.729  1.0
  Cl  Cl24  1  0.116  0.662  0.958  1.0
  Cl  Cl25  1  0.616  0.338  0.542  1.0
  Cl  Cl26  1  0.884  0.338  0.042  1.0
  Cl  Cl27  1  0.384  0.662  0.458  1.0
  Cl  Cl28  1  0.856  0.840  0.062  1.0
  Cl  Cl29  1  0.356  0.160  0.438  1.0
  Cl  Cl30  1  0.144  0.160  0.938  1.0
  Cl  Cl31  1  0.644  0.840  0.562  1.0
  O  O32  1  0.313  0.855  0.038  1.0
  O  O33  1  0.813  0.145  0.462  1.0
  O  O34  1  0.687  0.145  0.962  1.0
  O  O35  1  0.187  0.855  0.538  1.0
  O  O36  1  0.902  0.505  0.182  1.0
  O  O37  1  0.402  0.495  0.318  1.0
  O  O38  1  0.098  0.495  0.818  1.0
  O  O39  1  0.598  0.505  0.682  1.0
[/CIF]
.