The structure described by SmPdGe crystallizes in the orthorhombic Pnma space group. There are three inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 12-coordinate geometry to one Pd(2), two equivalent Pd(3), three equivalent Pd(1), one Ge(3), two equivalent Ge(1), and three equivalent Ge(2) atoms. In the second Sm site, Sm(2) is bonded in a 12-coordinate geometry to one Pd(3), two equivalent Pd(2), three equivalent Pd(1), one Ge(1), two equivalent Ge(3), and three equivalent Ge(2) atoms. In the third Sm site, Sm(3) is bonded in a 12-coordinate geometry to three equivalent Pd(2), three equivalent Pd(3), three equivalent Ge(1), and three equivalent Ge(3) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Sm(2), two equivalent Sm(1), three equivalent Sm(3), one Pd(1), one Ge(1), and two equivalent Ge(3) atoms. In the second Pd site, Pd(1) is bonded in a 10-coordinate geometry to three equivalent Sm(1), three equivalent Sm(2), one Pd(3), and three equivalent Ge(2) atoms. In the third Pd site, Pd(2) is bonded in a 10-coordinate geometry to one Sm(1), two equivalent Sm(2), three equivalent Sm(3), one Ge(3), and three equivalent Ge(1) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Sm(2), two equivalent Sm(1), three equivalent Sm(3), one Pd(3), and three equivalent Pd(2) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to three equivalent Sm(1), three equivalent Sm(2), three equivalent Pd(1), and one Ge(3) atom. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Sm(1), two equivalent Sm(2), three equivalent Sm(3), one Pd(2), two equivalent Pd(3), and one Ge(2) atom. is represented by the CIF file [CIF]
data_SmGePd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.446
_cell_length_b   7.634
_cell_length_c   21.530
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   730.702
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.250  0.709  0.333  1.0
  Sm  Sm1  1  0.750  0.291  0.667  1.0
  Sm  Sm2  1  0.750  0.209  0.167  1.0
  Sm  Sm3  1  0.250  0.791  0.833  1.0
  Sm  Sm4  1  0.250  0.791  0.166  1.0
  Sm  Sm5  1  0.750  0.209  0.834  1.0
  Sm  Sm6  1  0.750  0.291  0.334  1.0
  Sm  Sm7  1  0.250  0.709  0.666  1.0
  Sm  Sm8  1  0.250  0.717  0.001  1.0
  Sm  Sm9  1  0.750  0.283  0.999  1.0
  Sm  Sm10  1  0.750  0.217  0.499  1.0
  Sm  Sm11  1  0.250  0.783  0.501  1.0
  Ge  Ge12  1  0.250  0.091  0.073  1.0
  Ge  Ge13  1  0.750  0.909  0.927  1.0
  Ge  Ge14  1  0.750  0.591  0.427  1.0
  Ge  Ge15  1  0.250  0.409  0.573  1.0
  Ge  Ge16  1  0.250  0.086  0.269  1.0
  Ge  Ge17  1  0.750  0.914  0.731  1.0
  Ge  Ge18  1  0.750  0.586  0.231  1.0
  Ge  Ge19  1  0.250  0.414  0.769  1.0
  Ge  Ge20  1  0.250  0.088  0.397  1.0
  Ge  Ge21  1  0.750  0.912  0.603  1.0
  Ge  Ge22  1  0.750  0.588  0.103  1.0
  Ge  Ge23  1  0.250  0.412  0.897  1.0
  Pd  Pd24  1  0.250  0.418  0.237  1.0
  Pd  Pd25  1  0.750  0.582  0.763  1.0
  Pd  Pd26  1  0.750  0.918  0.263  1.0
  Pd  Pd27  1  0.250  0.082  0.737  1.0
  Pd  Pd28  1  0.250  0.417  0.436  1.0
  Pd  Pd29  1  0.750  0.583  0.564  1.0
  Pd  Pd30  1  0.750  0.917  0.064  1.0
  Pd  Pd31  1  0.250  0.083  0.936  1.0
  Pd  Pd32  1  0.250  0.422  0.094  1.0
  Pd  Pd33  1  0.750  0.578  0.906  1.0
  Pd  Pd34  1  0.750  0.922  0.406  1.0
  Pd  Pd35  1  0.250  0.078  0.594  1.0
[/CIF]
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The structure described by SmPdGe crystallizes in the orthorhombic Pnma space group. There are three inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 12-coordinate geometry to one Pd(2), two equivalent Pd(3), three equivalent Pd(1), one Ge(3), two equivalent Ge(1), and three equivalent Ge(2) atoms. In the second Sm site, Sm(2) is bonded in a 12-coordinate geometry to one Pd(3), two equivalent Pd(2), three equivalent Pd(1), one Ge(1), two equivalent Ge(3), and three equivalent Ge(2) atoms. In the third Sm site, Sm(3) is bonded in a 12-coordinate geometry to three equivalent Pd(2), three equivalent Pd(3), three equivalent Ge(1), and three equivalent Ge(3) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Sm(2), two equivalent Sm(1), three equivalent Sm(3), one Pd(1), one Ge(1), and two equivalent Ge(3) atoms. In the second Pd site, Pd(1) is bonded in a 10-coordinate geometry to three equivalent Sm(1), three equivalent Sm(2), one Pd(3), and three equivalent Ge(2) atoms. In the third Pd site, Pd(2) is bonded in a 10-coordinate geometry to one Sm(1), two equivalent Sm(2), three equivalent Sm(3), one Ge(3), and three equivalent Ge(1) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Sm(2), two equivalent Sm(1), three equivalent Sm(3), one Pd(3), and three equivalent Pd(2) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to three equivalent Sm(1), three equivalent Sm(2), three equivalent Pd(1), and one Ge(3) atom. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Sm(1), two equivalent Sm(2), three equivalent Sm(3), one Pd(2), two equivalent Pd(3), and one Ge(2) atom. is represented by the CIF file [CIF]
data_SmGePd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.446
_cell_length_b   7.634
_cell_length_c   21.530
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   730.702
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.250  0.709  0.333  1.0
  Sm  Sm1  1  0.750  0.291  0.667  1.0
  Sm  Sm2  1  0.750  0.209  0.167  1.0
  Sm  Sm3  1  0.250  0.791  0.833  1.0
  Sm  Sm4  1  0.250  0.791  0.166  1.0
  Sm  Sm5  1  0.750  0.209  0.834  1.0
  Sm  Sm6  1  0.750  0.291  0.334  1.0
  Sm  Sm7  1  0.250  0.709  0.666  1.0
  Sm  Sm8  1  0.250  0.717  0.001  1.0
  Sm  Sm9  1  0.750  0.283  0.999  1.0
  Sm  Sm10  1  0.750  0.217  0.499  1.0
  Sm  Sm11  1  0.250  0.783  0.501  1.0
  Ge  Ge12  1  0.250  0.091  0.073  1.0
  Ge  Ge13  1  0.750  0.909  0.927  1.0
  Ge  Ge14  1  0.750  0.591  0.427  1.0
  Ge  Ge15  1  0.250  0.409  0.573  1.0
  Ge  Ge16  1  0.250  0.086  0.269  1.0
  Ge  Ge17  1  0.750  0.914  0.731  1.0
  Ge  Ge18  1  0.750  0.586  0.231  1.0
  Ge  Ge19  1  0.250  0.414  0.769  1.0
  Ge  Ge20  1  0.250  0.088  0.397  1.0
  Ge  Ge21  1  0.750  0.912  0.603  1.0
  Ge  Ge22  1  0.750  0.588  0.103  1.0
  Ge  Ge23  1  0.250  0.412  0.897  1.0
  Pd  Pd24  1  0.250  0.418  0.237  1.0
  Pd  Pd25  1  0.750  0.582  0.763  1.0
  Pd  Pd26  1  0.750  0.918  0.263  1.0
  Pd  Pd27  1  0.250  0.082  0.737  1.0
  Pd  Pd28  1  0.250  0.417  0.436  1.0
  Pd  Pd29  1  0.750  0.583  0.564  1.0
  Pd  Pd30  1  0.750  0.917  0.064  1.0
  Pd  Pd31  1  0.250  0.083  0.936  1.0
  Pd  Pd32  1  0.250  0.422  0.094  1.0
  Pd  Pd33  1  0.750  0.578  0.906  1.0
  Pd  Pd34  1  0.750  0.922  0.406  1.0
  Pd  Pd35  1  0.250  0.078  0.594  1.0
[/CIF]
.