The material described by Co2BBi(PO5)2 crystallizes in the monoclinic P2_1/m space group. Co(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms to form distorted CoO6 octahedra that share corners with two equivalent B(1)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Bi(1)O6 pentagonal pyramids. B(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form BO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and  an edgeedge with one Bi(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 55-56°. Bi(1) is bonded to one O(1), one O(2), two equivalent O(4), and two equivalent O(5) atoms to form distorted BiO6 pentagonal pyramids that share corners with four equivalent P(1)O4 tetrahedra, edges with four equivalent Co(1)O6 octahedra, and  an edgeedge with one B(1)O4 tetrahedra. P(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra, corners with two equivalent Bi(1)O6 pentagonal pyramids, and  a cornercorner with one B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-55°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Co(1), one B(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to two equivalent Co(1), one B(1), and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one B(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Co(1), one Bi(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Co(1), one Bi(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Co2BiB(PO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.121
_cell_length_b   6.505
_cell_length_c   11.390
_cell_angle_alpha   90.000
_cell_angle_beta   89.999
_cell_angle_gamma   107.900
_symmetry_Int_Tables_number   1
_cell_volume   361.059
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.353  0.338  0.395  1.0
  Co  Co1  1  0.647  0.662  0.895  1.0
  Co  Co2  1  0.648  0.661  0.604  1.0
  Co  Co3  1  0.352  0.339  0.104  1.0
  Bi  Bi4  1  0.252  0.937  0.750  1.0
  Bi  Bi5  1  0.748  0.063  0.250  1.0
  B  B6  1  0.064  0.485  0.750  1.0
  B  B7  1  0.936  0.515  0.250  1.0
  P  P8  1  0.796  0.214  0.564  1.0
  P  P9  1  0.204  0.786  0.064  1.0
  P  P10  1  0.204  0.786  0.436  1.0
  P  P11  1  0.796  0.214  0.936  1.0
  O  O12  1  0.878  0.617  0.750  1.0
  O  O13  1  0.122  0.383  0.250  1.0
  O  O14  1  0.354  0.636  0.750  1.0
  O  O15  1  0.646  0.364  0.250  1.0
  O  O16  1  0.038  0.345  0.645  1.0
  O  O17  1  0.962  0.655  0.145  1.0
  O  O18  1  0.962  0.655  0.355  1.0
  O  O19  1  0.038  0.345  0.855  1.0
  O  O20  1  0.644  0.996  0.624  1.0
  O  O21  1  0.356  0.004  0.124  1.0
  O  O22  1  0.356  0.004  0.375  1.0
  O  O23  1  0.644  0.996  0.875  1.0
  O  O24  1  0.932  0.179  0.448  1.0
  O  O25  1  0.068  0.821  0.948  1.0
  O  O26  1  0.068  0.821  0.552  1.0
  O  O27  1  0.932  0.179  0.052  1.0
  O  O28  1  0.593  0.347  0.546  1.0
  O  O29  1  0.407  0.653  0.046  1.0
  O  O30  1  0.407  0.653  0.454  1.0
  O  O31  1  0.594  0.347  0.954  1.0
[/CIF]
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The material described by Co2BBi(PO5)2 crystallizes in the monoclinic P2_1/m space group. Co(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms to form distorted CoO6 octahedra that share corners with two equivalent B(1)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Bi(1)O6 pentagonal pyramids. B(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form BO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and  an edgeedge with one Bi(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 55-56°. Bi(1) is bonded to one O(1), one O(2), two equivalent O(4), and two equivalent O(5) atoms to form distorted BiO6 pentagonal pyramids that share corners with four equivalent P(1)O4 tetrahedra, edges with four equivalent Co(1)O6 octahedra, and  an edgeedge with one B(1)O4 tetrahedra. P(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra, corners with two equivalent Bi(1)O6 pentagonal pyramids, and  a cornercorner with one B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-55°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Co(1), one B(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to two equivalent Co(1), one B(1), and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one B(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Co(1), one Bi(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Co(1), one Bi(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Co2BiB(PO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.121
_cell_length_b   6.505
_cell_length_c   11.390
_cell_angle_alpha   90.000
_cell_angle_beta   89.999
_cell_angle_gamma   107.900
_symmetry_Int_Tables_number   1
_cell_volume   361.059
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.353  0.338  0.395  1.0
  Co  Co1  1  0.647  0.662  0.895  1.0
  Co  Co2  1  0.648  0.661  0.604  1.0
  Co  Co3  1  0.352  0.339  0.104  1.0
  Bi  Bi4  1  0.252  0.937  0.750  1.0
  Bi  Bi5  1  0.748  0.063  0.250  1.0
  B  B6  1  0.064  0.485  0.750  1.0
  B  B7  1  0.936  0.515  0.250  1.0
  P  P8  1  0.796  0.214  0.564  1.0
  P  P9  1  0.204  0.786  0.064  1.0
  P  P10  1  0.204  0.786  0.436  1.0
  P  P11  1  0.796  0.214  0.936  1.0
  O  O12  1  0.878  0.617  0.750  1.0
  O  O13  1  0.122  0.383  0.250  1.0
  O  O14  1  0.354  0.636  0.750  1.0
  O  O15  1  0.646  0.364  0.250  1.0
  O  O16  1  0.038  0.345  0.645  1.0
  O  O17  1  0.962  0.655  0.145  1.0
  O  O18  1  0.962  0.655  0.355  1.0
  O  O19  1  0.038  0.345  0.855  1.0
  O  O20  1  0.644  0.996  0.624  1.0
  O  O21  1  0.356  0.004  0.124  1.0
  O  O22  1  0.356  0.004  0.375  1.0
  O  O23  1  0.644  0.996  0.875  1.0
  O  O24  1  0.932  0.179  0.448  1.0
  O  O25  1  0.068  0.821  0.948  1.0
  O  O26  1  0.068  0.821  0.552  1.0
  O  O27  1  0.932  0.179  0.052  1.0
  O  O28  1  0.593  0.347  0.546  1.0
  O  O29  1  0.407  0.653  0.046  1.0
  O  O30  1  0.407  0.653  0.454  1.0
  O  O31  1  0.594  0.347  0.954  1.0
[/CIF]
.