The structure described by (TlCl4)2N2 is Indium-derived structured and crystallizes in the orthorhombic Amm2 space group. The structure is zero-dimensional and consists of two ammonia atoms and two TlCl4 clusters. In each TlCl4 cluster, Tl(1) is bonded in a distorted tetrahedral geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Tl(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Tl(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TlNCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.259
_cell_length_b   7.259
_cell_length_c   5.208
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.567
_symmetry_Int_Tables_number   1
_cell_volume   273.127
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.059  0.941  0.000  1.0
  N  N1  1  0.427  0.573  0.500  1.0
  Cl  Cl2  1  0.916  0.631  0.000  1.0
  Cl  Cl3  1  0.369  0.084  0.000  1.0
  Cl  Cl4  1  0.849  0.151  0.258  1.0
  Cl  Cl5  1  0.849  0.151  0.742  1.0
[/CIF]
.
The structure described by (TlCl4)2N2 is Indium-derived structured and crystallizes in the orthorhombic Amm2 space group. The structure is zero-dimensional and consists of two ammonia atoms and two TlCl4 clusters. In each TlCl4 cluster, Tl(1) is bonded in a distorted tetrahedral geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Tl(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Tl(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TlNCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.259
_cell_length_b   7.259
_cell_length_c   5.208
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.567
_symmetry_Int_Tables_number   1
_cell_volume   273.127
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.059  0.941  0.000  1.0
  N  N1  1  0.427  0.573  0.500  1.0
  Cl  Cl2  1  0.916  0.631  0.000  1.0
  Cl  Cl3  1  0.369  0.084  0.000  1.0
  Cl  Cl4  1  0.849  0.151  0.258  1.0
  Cl  Cl5  1  0.849  0.151  0.742  1.0
[/CIF]
.