The material described by SbCl6SCl3 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four SCl3 clusters and four SbCl6 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to three equivalent Cl(5,6) atoms. Cl(5,6) is bonded in a single-bond geometry to one S(1) atom. In two of the SbCl6 clusters, Sb(1,2) is bonded in an octahedral geometry to six equivalent Cl(3,4) atoms. Cl(3,4) is bonded in a single-bond geometry to one Sb(1,2) atom. In two of the SbCl6 clusters, Sb(1,2) is bonded in an octahedral geometry to six equivalent Cl(3,4) atoms. Cl(1,2) is bonded in a single-bond geometry to one Sb(1,2) atom. is represented by the CIF card [CIF]
data_SbSCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.704
_cell_length_b   8.704
_cell_length_c   8.716
_cell_angle_alpha   75.536
_cell_angle_beta   75.536
_cell_angle_gamma   75.577
_symmetry_Int_Tables_number   1
_cell_volume   606.781
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.706  0.706  0.707  1.0
  S  S3  1  0.294  0.294  0.293  1.0
  Cl  Cl4  1  0.031  0.031  0.714  1.0
  Cl  Cl5  1  0.969  0.969  0.286  1.0
  Cl  Cl6  1  0.286  0.969  0.969  1.0
  Cl  Cl7  1  0.031  0.714  0.031  1.0
  Cl  Cl8  1  0.714  0.031  0.031  1.0
  Cl  Cl9  1  0.969  0.286  0.969  1.0
  Cl  Cl10  1  0.680  0.362  0.680  1.0
  Cl  Cl11  1  0.638  0.320  0.320  1.0
  Cl  Cl12  1  0.320  0.638  0.320  1.0
  Cl  Cl13  1  0.362  0.680  0.680  1.0
  Cl  Cl14  1  0.319  0.319  0.638  1.0
  Cl  Cl15  1  0.681  0.681  0.362  1.0
  Cl  Cl16  1  0.345  0.054  0.345  1.0
  Cl  Cl17  1  0.946  0.655  0.655  1.0
  Cl  Cl18  1  0.655  0.946  0.655  1.0
  Cl  Cl19  1  0.054  0.345  0.345  1.0
  Cl  Cl20  1  0.345  0.345  0.054  1.0
  Cl  Cl21  1  0.655  0.655  0.946  1.0
[/CIF]
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The material described by SbCl6SCl3 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four SCl3 clusters and four SbCl6 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to three equivalent Cl(5,6) atoms. Cl(5,6) is bonded in a single-bond geometry to one S(1) atom. In two of the SbCl6 clusters, Sb(1,2) is bonded in an octahedral geometry to six equivalent Cl(3,4) atoms. Cl(3,4) is bonded in a single-bond geometry to one Sb(1,2) atom. In two of the SbCl6 clusters, Sb(1,2) is bonded in an octahedral geometry to six equivalent Cl(3,4) atoms. Cl(1,2) is bonded in a single-bond geometry to one Sb(1,2) atom. is represented by the CIF card [CIF]
data_SbSCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.704
_cell_length_b   8.704
_cell_length_c   8.716
_cell_angle_alpha   75.536
_cell_angle_beta   75.536
_cell_angle_gamma   75.577
_symmetry_Int_Tables_number   1
_cell_volume   606.781
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.706  0.706  0.707  1.0
  S  S3  1  0.294  0.294  0.293  1.0
  Cl  Cl4  1  0.031  0.031  0.714  1.0
  Cl  Cl5  1  0.969  0.969  0.286  1.0
  Cl  Cl6  1  0.286  0.969  0.969  1.0
  Cl  Cl7  1  0.031  0.714  0.031  1.0
  Cl  Cl8  1  0.714  0.031  0.031  1.0
  Cl  Cl9  1  0.969  0.286  0.969  1.0
  Cl  Cl10  1  0.680  0.362  0.680  1.0
  Cl  Cl11  1  0.638  0.320  0.320  1.0
  Cl  Cl12  1  0.320  0.638  0.320  1.0
  Cl  Cl13  1  0.362  0.680  0.680  1.0
  Cl  Cl14  1  0.319  0.319  0.638  1.0
  Cl  Cl15  1  0.681  0.681  0.362  1.0
  Cl  Cl16  1  0.345  0.054  0.345  1.0
  Cl  Cl17  1  0.946  0.655  0.655  1.0
  Cl  Cl18  1  0.655  0.946  0.655  1.0
  Cl  Cl19  1  0.054  0.345  0.345  1.0
  Cl  Cl20  1  0.345  0.345  0.054  1.0
  Cl  Cl21  1  0.655  0.655  0.946  1.0
[/CIF]
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