The material structure described by (PN2H)2(P(NH2)2)2(NH2)4H2(NH2Cl)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two azane;hydrochloride molecules, four azane;molecular hydrogen molecules, two P(NH2)2 clusters, and two PN2H clusters. In each P(NH2)2 cluster, P(2) is bonded in a 1-coordinate geometry to one N(3) and one N(4) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(3), and one H(8) atom. In the second N site, N(4) is bonded in a 3-coordinate geometry to one P(2), one H(11), and one H(6) atom. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In each PN2H cluster, P(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one N(6) atom. There are two inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one P(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one P(1) and one H(4) atom. H(4) is bonded in a distorted single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_P2H12N7Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.926
_cell_length_b   7.475
_cell_length_c   11.046
_cell_angle_alpha   109.747
_cell_angle_beta   103.453
_cell_angle_gamma   91.173
_symmetry_Int_Tables_number   1
_cell_volume   445.239
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.233  0.169  0.570  1.0
  P  P1  1  0.401  0.041  0.806  1.0
  P  P2  1  0.599  0.959  0.194  1.0
  P  P3  1  0.767  0.831  0.430  1.0
  H  H4  1  0.215  0.721  0.969  1.0
  H  H5  1  0.188  0.721  0.856  1.0
  H  H6  1  0.183  0.263  0.827  1.0
  H  H7  1  0.154  0.668  0.497  1.0
  H  H8  1  0.097  0.012  0.367  1.0
  H  H9  1  0.251  0.820  0.599  1.0
  H  H10  1  0.195  0.451  0.346  1.0
  H  H11  1  0.475  0.283  0.846  1.0
  H  H12  1  0.213  0.074  0.171  1.0
  H  H13  1  0.385  0.537  0.405  1.0
  H  H14  1  0.508  0.795  0.686  1.0
  H  H15  1  0.236  0.157  0.036  1.0
  H  H16  1  0.764  0.843  0.964  1.0
  H  H17  1  0.492  0.205  0.314  1.0
  H  H18  1  0.615  0.463  0.595  1.0
  H  H19  1  0.787  0.926  0.829  1.0
  H  H20  1  0.525  0.717  0.154  1.0
  H  H21  1  0.805  0.549  0.654  1.0
  H  H22  1  0.749  0.180  0.401  1.0
  H  H23  1  0.903  0.988  0.633  1.0
  H  H24  1  0.846  0.332  0.503  1.0
  H  H25  1  0.817  0.737  0.173  1.0
  H  H26  1  0.812  0.279  0.144  1.0
  H  H27  1  0.785  0.279  0.031  1.0
  N  N28  1  0.217  0.828  0.874  1.0
  N  N29  1  0.051  0.840  0.450  1.0
  N  N30  1  0.347  0.196  0.841  1.0
  N  N31  1  0.334  0.874  0.640  1.0
  N  N32  1  0.246  0.441  0.417  1.0
  N  N33  1  0.367  0.209  0.654  1.0
  N  N34  1  0.318  0.067  0.128  1.0
  N  N35  1  0.682  0.933  0.872  1.0
  N  N36  1  0.633  0.790  0.346  1.0
  N  N37  1  0.754  0.559  0.583  1.0
  N  N38  1  0.666  0.126  0.360  1.0
  N  N39  1  0.653  0.804  0.159  1.0
  N  N40  1  0.949  0.160  0.550  1.0
  N  N41  1  0.783  0.172  0.126  1.0
  Cl  Cl42  1  0.129  0.486  0.177  1.0
  Cl  Cl43  1  0.871  0.514  0.823  1.0
[/CIF]
.
The material structure described by (PN2H)2(P(NH2)2)2(NH2)4H2(NH2Cl)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two azane;hydrochloride molecules, four azane;molecular hydrogen molecules, two P(NH2)2 clusters, and two PN2H clusters. In each P(NH2)2 cluster, P(2) is bonded in a 1-coordinate geometry to one N(3) and one N(4) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(3), and one H(8) atom. In the second N site, N(4) is bonded in a 3-coordinate geometry to one P(2), one H(11), and one H(6) atom. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In each PN2H cluster, P(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one N(6) atom. There are two inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one P(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one P(1) and one H(4) atom. H(4) is bonded in a distorted single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_P2H12N7Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.926
_cell_length_b   7.475
_cell_length_c   11.046
_cell_angle_alpha   109.747
_cell_angle_beta   103.453
_cell_angle_gamma   91.173
_symmetry_Int_Tables_number   1
_cell_volume   445.239
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.233  0.169  0.570  1.0
  P  P1  1  0.401  0.041  0.806  1.0
  P  P2  1  0.599  0.959  0.194  1.0
  P  P3  1  0.767  0.831  0.430  1.0
  H  H4  1  0.215  0.721  0.969  1.0
  H  H5  1  0.188  0.721  0.856  1.0
  H  H6  1  0.183  0.263  0.827  1.0
  H  H7  1  0.154  0.668  0.497  1.0
  H  H8  1  0.097  0.012  0.367  1.0
  H  H9  1  0.251  0.820  0.599  1.0
  H  H10  1  0.195  0.451  0.346  1.0
  H  H11  1  0.475  0.283  0.846  1.0
  H  H12  1  0.213  0.074  0.171  1.0
  H  H13  1  0.385  0.537  0.405  1.0
  H  H14  1  0.508  0.795  0.686  1.0
  H  H15  1  0.236  0.157  0.036  1.0
  H  H16  1  0.764  0.843  0.964  1.0
  H  H17  1  0.492  0.205  0.314  1.0
  H  H18  1  0.615  0.463  0.595  1.0
  H  H19  1  0.787  0.926  0.829  1.0
  H  H20  1  0.525  0.717  0.154  1.0
  H  H21  1  0.805  0.549  0.654  1.0
  H  H22  1  0.749  0.180  0.401  1.0
  H  H23  1  0.903  0.988  0.633  1.0
  H  H24  1  0.846  0.332  0.503  1.0
  H  H25  1  0.817  0.737  0.173  1.0
  H  H26  1  0.812  0.279  0.144  1.0
  H  H27  1  0.785  0.279  0.031  1.0
  N  N28  1  0.217  0.828  0.874  1.0
  N  N29  1  0.051  0.840  0.450  1.0
  N  N30  1  0.347  0.196  0.841  1.0
  N  N31  1  0.334  0.874  0.640  1.0
  N  N32  1  0.246  0.441  0.417  1.0
  N  N33  1  0.367  0.209  0.654  1.0
  N  N34  1  0.318  0.067  0.128  1.0
  N  N35  1  0.682  0.933  0.872  1.0
  N  N36  1  0.633  0.790  0.346  1.0
  N  N37  1  0.754  0.559  0.583  1.0
  N  N38  1  0.666  0.126  0.360  1.0
  N  N39  1  0.653  0.804  0.159  1.0
  N  N40  1  0.949  0.160  0.550  1.0
  N  N41  1  0.783  0.172  0.126  1.0
  Cl  Cl42  1  0.129  0.486  0.177  1.0
  Cl  Cl43  1  0.871  0.514  0.823  1.0
[/CIF]
.