The crystal structure described by Te3(Mo2N)2 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in an L-shaped geometry to two equivalent N(1) and four equivalent Te(2) atoms. In the second Mo site, Mo(2) is bonded in a distorted water-like geometry to two equivalent N(1), one Te(1), and two equivalent Te(2) atoms. In the third Mo site, Mo(3) is bonded in a water-like geometry to two equivalent N(1), two equivalent Te(1), and two equivalent Te(2) atoms. N(1) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), and two equivalent Mo(3) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Mo(2) and four equivalent Mo(3) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one Mo(2), two equivalent Mo(1), and two equivalent Mo(3) atoms. is represented by the CIF card [CIF]
data_Te3(Mo2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.516
_cell_length_b   9.766
_cell_length_c   10.356
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   658.935
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.888  0.250  0.188  1.0
  Te  Te1  1  0.388  0.250  0.312  1.0
  Te  Te2  1  0.112  0.750  0.812  1.0
  Te  Te3  1  0.612  0.750  0.688  1.0
  Te  Te4  1  0.658  0.578  0.384  1.0
  Te  Te5  1  0.158  0.922  0.116  1.0
  Te  Te6  1  0.342  0.078  0.616  1.0
  Te  Te7  1  0.842  0.422  0.884  1.0
  Te  Te8  1  0.342  0.422  0.616  1.0
  Te  Te9  1  0.842  0.078  0.884  1.0
  Te  Te10  1  0.658  0.922  0.384  1.0
  Te  Te11  1  0.158  0.578  0.116  1.0
  Mo  Mo12  1  0.513  0.250  0.820  1.0
  Mo  Mo13  1  0.013  0.250  0.680  1.0
  Mo  Mo14  1  0.487  0.750  0.180  1.0
  Mo  Mo15  1  0.987  0.750  0.320  1.0
  Mo  Mo16  1  0.672  0.250  0.535  1.0
  Mo  Mo17  1  0.172  0.250  0.965  1.0
  Mo  Mo18  1  0.328  0.750  0.465  1.0
  Mo  Mo19  1  0.828  0.750  0.035  1.0
  Mo  Mo20  1  0.528  0.395  0.078  1.0
  Mo  Mo21  1  0.028  0.105  0.422  1.0
  Mo  Mo22  1  0.472  0.895  0.922  1.0
  Mo  Mo23  1  0.972  0.605  0.578  1.0
  Mo  Mo24  1  0.472  0.605  0.922  1.0
  Mo  Mo25  1  0.972  0.895  0.578  1.0
  Mo  Mo26  1  0.528  0.105  0.078  1.0
  Mo  Mo27  1  0.028  0.395  0.422  1.0
  N  N28  1  0.642  0.597  0.086  1.0
  N  N29  1  0.142  0.903  0.414  1.0
  N  N30  1  0.358  0.097  0.914  1.0
  N  N31  1  0.858  0.403  0.586  1.0
  N  N32  1  0.358  0.403  0.914  1.0
  N  N33  1  0.858  0.097  0.586  1.0
  N  N34  1  0.642  0.903  0.086  1.0
  N  N35  1  0.142  0.597  0.414  1.0
[/CIF]
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The crystal structure described by Te3(Mo2N)2 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in an L-shaped geometry to two equivalent N(1) and four equivalent Te(2) atoms. In the second Mo site, Mo(2) is bonded in a distorted water-like geometry to two equivalent N(1), one Te(1), and two equivalent Te(2) atoms. In the third Mo site, Mo(3) is bonded in a water-like geometry to two equivalent N(1), two equivalent Te(1), and two equivalent Te(2) atoms. N(1) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), and two equivalent Mo(3) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Mo(2) and four equivalent Mo(3) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one Mo(2), two equivalent Mo(1), and two equivalent Mo(3) atoms. is represented by the CIF card [CIF]
data_Te3(Mo2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.516
_cell_length_b   9.766
_cell_length_c   10.356
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   658.935
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.888  0.250  0.188  1.0
  Te  Te1  1  0.388  0.250  0.312  1.0
  Te  Te2  1  0.112  0.750  0.812  1.0
  Te  Te3  1  0.612  0.750  0.688  1.0
  Te  Te4  1  0.658  0.578  0.384  1.0
  Te  Te5  1  0.158  0.922  0.116  1.0
  Te  Te6  1  0.342  0.078  0.616  1.0
  Te  Te7  1  0.842  0.422  0.884  1.0
  Te  Te8  1  0.342  0.422  0.616  1.0
  Te  Te9  1  0.842  0.078  0.884  1.0
  Te  Te10  1  0.658  0.922  0.384  1.0
  Te  Te11  1  0.158  0.578  0.116  1.0
  Mo  Mo12  1  0.513  0.250  0.820  1.0
  Mo  Mo13  1  0.013  0.250  0.680  1.0
  Mo  Mo14  1  0.487  0.750  0.180  1.0
  Mo  Mo15  1  0.987  0.750  0.320  1.0
  Mo  Mo16  1  0.672  0.250  0.535  1.0
  Mo  Mo17  1  0.172  0.250  0.965  1.0
  Mo  Mo18  1  0.328  0.750  0.465  1.0
  Mo  Mo19  1  0.828  0.750  0.035  1.0
  Mo  Mo20  1  0.528  0.395  0.078  1.0
  Mo  Mo21  1  0.028  0.105  0.422  1.0
  Mo  Mo22  1  0.472  0.895  0.922  1.0
  Mo  Mo23  1  0.972  0.605  0.578  1.0
  Mo  Mo24  1  0.472  0.605  0.922  1.0
  Mo  Mo25  1  0.972  0.895  0.578  1.0
  Mo  Mo26  1  0.528  0.105  0.078  1.0
  Mo  Mo27  1  0.028  0.395  0.422  1.0
  N  N28  1  0.642  0.597  0.086  1.0
  N  N29  1  0.142  0.903  0.414  1.0
  N  N30  1  0.358  0.097  0.914  1.0
  N  N31  1  0.858  0.403  0.586  1.0
  N  N32  1  0.358  0.403  0.914  1.0
  N  N33  1  0.858  0.097  0.586  1.0
  N  N34  1  0.642  0.903  0.086  1.0
  N  N35  1  0.142  0.597  0.414  1.0
[/CIF]
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