The compound described by P2S3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two P2S3 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one S(1), one S(2), and one S(3) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to two equivalent P(1) and one S(4) atom. In the third P site, P(3) is bonded in a trigonal non-coplanar geometry to one S(4) and two equivalent S(2) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one P(1) and one P(3) atom. In the third S site, S(3) is bonded in an L-shaped geometry to two equivalent P(1) atoms. In the fourth S site, S(4) is bonded in a water-like geometry to one P(2) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.801
_cell_length_b   6.775
_cell_length_c   7.056
_cell_angle_alpha   89.108
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   516.262
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.114  0.754  0.269  1.0
  P  P1  1  0.614  0.246  0.731  1.0
  P  P2  1  0.886  0.246  0.731  1.0
  P  P3  1  0.386  0.754  0.269  1.0
  P  P4  1  0.250  0.792  0.510  1.0
  P  P5  1  0.750  0.208  0.490  1.0
  P  P6  1  0.250  0.331  0.389  1.0
  P  P7  1  0.750  0.669  0.611  1.0
  S  S8  1  0.541  0.892  0.253  1.0
  S  S9  1  0.041  0.108  0.747  1.0
  S  S10  1  0.459  0.108  0.747  1.0
  S  S11  1  0.959  0.892  0.253  1.0
  S  S12  1  0.093  0.444  0.247  1.0
  S  S13  1  0.593  0.556  0.753  1.0
  S  S14  1  0.907  0.556  0.753  1.0
  S  S15  1  0.407  0.444  0.247  1.0
  S  S16  1  0.250  0.851  0.071  1.0
  S  S17  1  0.750  0.149  0.929  1.0
  S  S18  1  0.250  0.517  0.634  1.0
  S  S19  1  0.750  0.483  0.366  1.0
[/CIF]
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The compound described by P2S3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two P2S3 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one S(1), one S(2), and one S(3) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to two equivalent P(1) and one S(4) atom. In the third P site, P(3) is bonded in a trigonal non-coplanar geometry to one S(4) and two equivalent S(2) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one P(1) and one P(3) atom. In the third S site, S(3) is bonded in an L-shaped geometry to two equivalent P(1) atoms. In the fourth S site, S(4) is bonded in a water-like geometry to one P(2) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.801
_cell_length_b   6.775
_cell_length_c   7.056
_cell_angle_alpha   89.108
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   516.262
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.114  0.754  0.269  1.0
  P  P1  1  0.614  0.246  0.731  1.0
  P  P2  1  0.886  0.246  0.731  1.0
  P  P3  1  0.386  0.754  0.269  1.0
  P  P4  1  0.250  0.792  0.510  1.0
  P  P5  1  0.750  0.208  0.490  1.0
  P  P6  1  0.250  0.331  0.389  1.0
  P  P7  1  0.750  0.669  0.611  1.0
  S  S8  1  0.541  0.892  0.253  1.0
  S  S9  1  0.041  0.108  0.747  1.0
  S  S10  1  0.459  0.108  0.747  1.0
  S  S11  1  0.959  0.892  0.253  1.0
  S  S12  1  0.093  0.444  0.247  1.0
  S  S13  1  0.593  0.556  0.753  1.0
  S  S14  1  0.907  0.556  0.753  1.0
  S  S15  1  0.407  0.444  0.247  1.0
  S  S16  1  0.250  0.851  0.071  1.0
  S  S17  1  0.750  0.149  0.929  1.0
  S  S18  1  0.250  0.517  0.634  1.0
  S  S19  1  0.750  0.483  0.366  1.0
[/CIF]
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