The crystal structure described by LiKSO4 crystallizes in the orthorhombic Pna2_1 space group. K(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form LiO4 tetrahedra that share corners with four equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one Li(1), and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Li(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1), one Li(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Li(1), and one S(1) atom. is represented by the CIF file [CIF]
data_KLiSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.168
_cell_length_b   8.951
_cell_length_c   9.103
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   421.109
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.734  0.996  0.711  1.0
  K  K1  1  0.734  0.496  0.789  1.0
  K  K2  1  0.234  0.504  0.211  1.0
  K  K3  1  0.234  0.004  0.289  1.0
  Li  Li4  1  0.711  0.342  0.389  1.0
  Li  Li5  1  0.711  0.842  0.111  1.0
  Li  Li6  1  0.211  0.658  0.611  1.0
  Li  Li7  1  0.211  0.158  0.889  1.0
  S  S8  1  0.207  0.787  0.931  1.0
  S  S9  1  0.707  0.213  0.069  1.0
  S  S10  1  0.707  0.713  0.431  1.0
  S  S11  1  0.207  0.287  0.569  1.0
  O  O12  1  0.929  0.751  0.961  1.0
  O  O13  1  0.856  0.227  0.929  1.0
  O  O14  1  0.231  0.441  0.628  1.0
  O  O15  1  0.809  0.821  0.321  1.0
  O  O16  1  0.429  0.749  0.461  1.0
  O  O17  1  0.356  0.773  0.071  1.0
  O  O18  1  0.809  0.321  0.179  1.0
  O  O19  1  0.231  0.941  0.872  1.0
  O  O20  1  0.356  0.273  0.429  1.0
  O  O21  1  0.309  0.179  0.679  1.0
  O  O22  1  0.856  0.727  0.571  1.0
  O  O23  1  0.309  0.679  0.821  1.0
  O  O24  1  0.929  0.251  0.539  1.0
  O  O25  1  0.429  0.249  0.039  1.0
  O  O26  1  0.731  0.559  0.372  1.0
  O  O27  1  0.731  0.059  0.128  1.0
[/CIF]
.
The crystal structure described by LiKSO4 crystallizes in the orthorhombic Pna2_1 space group. K(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form LiO4 tetrahedra that share corners with four equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one Li(1), and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Li(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1), one Li(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Li(1), and one S(1) atom. is represented by the CIF file [CIF]
data_KLiSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.168
_cell_length_b   8.951
_cell_length_c   9.103
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   421.109
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.734  0.996  0.711  1.0
  K  K1  1  0.734  0.496  0.789  1.0
  K  K2  1  0.234  0.504  0.211  1.0
  K  K3  1  0.234  0.004  0.289  1.0
  Li  Li4  1  0.711  0.342  0.389  1.0
  Li  Li5  1  0.711  0.842  0.111  1.0
  Li  Li6  1  0.211  0.658  0.611  1.0
  Li  Li7  1  0.211  0.158  0.889  1.0
  S  S8  1  0.207  0.787  0.931  1.0
  S  S9  1  0.707  0.213  0.069  1.0
  S  S10  1  0.707  0.713  0.431  1.0
  S  S11  1  0.207  0.287  0.569  1.0
  O  O12  1  0.929  0.751  0.961  1.0
  O  O13  1  0.856  0.227  0.929  1.0
  O  O14  1  0.231  0.441  0.628  1.0
  O  O15  1  0.809  0.821  0.321  1.0
  O  O16  1  0.429  0.749  0.461  1.0
  O  O17  1  0.356  0.773  0.071  1.0
  O  O18  1  0.809  0.321  0.179  1.0
  O  O19  1  0.231  0.941  0.872  1.0
  O  O20  1  0.356  0.273  0.429  1.0
  O  O21  1  0.309  0.179  0.679  1.0
  O  O22  1  0.856  0.727  0.571  1.0
  O  O23  1  0.309  0.679  0.821  1.0
  O  O24  1  0.929  0.251  0.539  1.0
  O  O25  1  0.429  0.249  0.039  1.0
  O  O26  1  0.731  0.559  0.372  1.0
  O  O27  1  0.731  0.059  0.128  1.0
[/CIF]
.