The compound described by CrO6PO4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of eight phosphoric acid molecules and eight CrO6 clusters. In each CrO6 cluster, Cr(1) is bonded in a tetrahedral geometry to one O(15), one O(2), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(15) is bonded in a single-bond geometry to one Cr(1) atom. In the second O site, O(18) is bonded in a bent 120 degrees geometry to one O(2) and one O(5) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Cr(1) and one O(18) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cr(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one O(18) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF card [CIF]
data_CrPO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.344
_cell_length_b   6.344
_cell_length_c   25.607
_cell_angle_alpha   88.097
_cell_angle_beta   88.097
_cell_angle_gamma   74.406
_symmetry_Int_Tables_number   1
_cell_volume   991.863
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.586  0.576  0.906  1.0
  Cr  Cr1  1  0.576  0.586  0.406  1.0
  Cr  Cr2  1  0.472  0.556  0.688  1.0
  Cr  Cr3  1  0.556  0.472  0.188  1.0
  P  P4  1  0.951  0.778  0.559  1.0
  P  P5  1  0.778  0.951  0.059  1.0
  P  P6  1  0.100  0.207  0.793  1.0
  P  P7  1  0.207  0.100  0.293  1.0
  O  O8  1  0.371  0.350  0.657  1.0
  O  O9  1  0.350  0.371  0.157  1.0
  O  O10  1  0.747  0.381  0.444  1.0
  O  O11  1  0.381  0.747  0.944  1.0
  O  O12  1  0.075  0.116  0.739  1.0
  O  O13  1  0.116  0.075  0.239  1.0
  O  O14  1  0.825  0.505  0.936  1.0
  O  O15  1  0.505  0.825  0.436  1.0
  O  O16  1  0.228  0.493  0.003  1.0
  O  O17  1  0.493  0.228  0.503  1.0
  O  O18  1  0.357  0.514  0.394  1.0
  O  O19  1  0.514  0.357  0.894  1.0
  O  O20  1  0.680  0.425  0.618  1.0
  O  O21  1  0.425  0.680  0.118  1.0
  O  O22  1  0.006  0.085  0.837  1.0
  O  O23  1  0.085  0.006  0.337  1.0
  O  O24  1  0.735  0.605  0.687  1.0
  O  O25  1  0.605  0.735  0.187  1.0
  O  O26  1  0.708  0.793  0.548  1.0
  O  O27  1  0.793  0.708  0.048  1.0
  O  O28  1  0.328  0.658  0.738  1.0
  O  O29  1  0.658  0.328  0.238  1.0
  O  O30  1  0.962  0.885  0.612  1.0
  O  O31  1  0.885  0.962  0.112  1.0
  O  O32  1  0.261  0.611  0.210  1.0
  O  O33  1  0.611  0.261  0.710  1.0
  O  O34  1  0.904  0.041  0.015  1.0
  O  O35  1  0.041  0.904  0.515  1.0
  O  O36  1  0.637  0.705  0.851  1.0
  O  O37  1  0.705  0.637  0.351  1.0
  O  O38  1  0.417  0.738  0.635  1.0
  O  O39  1  0.738  0.417  0.135  1.0
  O  O40  1  0.981  0.454  0.791  1.0
  O  O41  1  0.454  0.981  0.291  1.0
  O  O42  1  0.179  0.613  0.965  1.0
  O  O43  1  0.613  0.179  0.465  1.0
  O  O44  1  0.082  0.537  0.560  1.0
  O  O45  1  0.537  0.082  0.060  1.0
  O  O46  1  0.177  0.345  0.302  1.0
  O  O47  1  0.345  0.177  0.802  1.0
[/CIF]
.
The compound described by CrO6PO4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of eight phosphoric acid molecules and eight CrO6 clusters. In each CrO6 cluster, Cr(1) is bonded in a tetrahedral geometry to one O(15), one O(2), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(15) is bonded in a single-bond geometry to one Cr(1) atom. In the second O site, O(18) is bonded in a bent 120 degrees geometry to one O(2) and one O(5) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Cr(1) and one O(18) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cr(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one O(18) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF card [CIF]
data_CrPO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.344
_cell_length_b   6.344
_cell_length_c   25.607
_cell_angle_alpha   88.097
_cell_angle_beta   88.097
_cell_angle_gamma   74.406
_symmetry_Int_Tables_number   1
_cell_volume   991.863
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.586  0.576  0.906  1.0
  Cr  Cr1  1  0.576  0.586  0.406  1.0
  Cr  Cr2  1  0.472  0.556  0.688  1.0
  Cr  Cr3  1  0.556  0.472  0.188  1.0
  P  P4  1  0.951  0.778  0.559  1.0
  P  P5  1  0.778  0.951  0.059  1.0
  P  P6  1  0.100  0.207  0.793  1.0
  P  P7  1  0.207  0.100  0.293  1.0
  O  O8  1  0.371  0.350  0.657  1.0
  O  O9  1  0.350  0.371  0.157  1.0
  O  O10  1  0.747  0.381  0.444  1.0
  O  O11  1  0.381  0.747  0.944  1.0
  O  O12  1  0.075  0.116  0.739  1.0
  O  O13  1  0.116  0.075  0.239  1.0
  O  O14  1  0.825  0.505  0.936  1.0
  O  O15  1  0.505  0.825  0.436  1.0
  O  O16  1  0.228  0.493  0.003  1.0
  O  O17  1  0.493  0.228  0.503  1.0
  O  O18  1  0.357  0.514  0.394  1.0
  O  O19  1  0.514  0.357  0.894  1.0
  O  O20  1  0.680  0.425  0.618  1.0
  O  O21  1  0.425  0.680  0.118  1.0
  O  O22  1  0.006  0.085  0.837  1.0
  O  O23  1  0.085  0.006  0.337  1.0
  O  O24  1  0.735  0.605  0.687  1.0
  O  O25  1  0.605  0.735  0.187  1.0
  O  O26  1  0.708  0.793  0.548  1.0
  O  O27  1  0.793  0.708  0.048  1.0
  O  O28  1  0.328  0.658  0.738  1.0
  O  O29  1  0.658  0.328  0.238  1.0
  O  O30  1  0.962  0.885  0.612  1.0
  O  O31  1  0.885  0.962  0.112  1.0
  O  O32  1  0.261  0.611  0.210  1.0
  O  O33  1  0.611  0.261  0.710  1.0
  O  O34  1  0.904  0.041  0.015  1.0
  O  O35  1  0.041  0.904  0.515  1.0
  O  O36  1  0.637  0.705  0.851  1.0
  O  O37  1  0.705  0.637  0.351  1.0
  O  O38  1  0.417  0.738  0.635  1.0
  O  O39  1  0.738  0.417  0.135  1.0
  O  O40  1  0.981  0.454  0.791  1.0
  O  O41  1  0.454  0.981  0.291  1.0
  O  O42  1  0.179  0.613  0.965  1.0
  O  O43  1  0.613  0.179  0.465  1.0
  O  O44  1  0.082  0.537  0.560  1.0
  O  O45  1  0.537  0.082  0.060  1.0
  O  O46  1  0.177  0.345  0.302  1.0
  O  O47  1  0.345  0.177  0.802  1.0
[/CIF]
.