The structure described by KLaC4O11 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 1-coordinate geometry to one O(1), one O(6), one O(8), and two equivalent O(9) atoms. La(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(7) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one O(1) and one O(3) atom. In the second C site, C(2) is bonded in a 2-coordinate geometry to one O(2) and one O(4) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(3), one O(5), and one O(6) atom. In the fourth C site, C(4) is bonded in a 4-coordinate geometry to one C(4), one O(7), and two equivalent O(8) atoms. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a bent 120 degrees geometry to one La(1) and one O(10) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one La(1), and one C(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one C(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one La(1), one C(1), and one O(9) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one C(2) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one C(3) atom. In the seventh O site, O(6) is bonded in a 2-coordinate geometry to one K(1) and one C(3) atom. In the eighth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one La(1) and one C(4) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one K(1) and two equivalent C(4) atoms. In the tenth O site, O(9) is bonded in a 3-coordinate geometry to two equivalent K(1) and one O(3) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one O(11) atom. is represented by the CIF card [CIF]
data_KLaC4O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.608
_cell_length_b   7.766
_cell_length_c   12.314
_cell_angle_alpha   106.861
_cell_angle_beta   100.944
_cell_angle_gamma   98.851
_symmetry_Int_Tables_number   1
_cell_volume   578.808
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.305  0.093  0.326  1.0
  K  K1  1  0.695  0.907  0.674  1.0
  La  La2  1  0.178  0.656  0.214  1.0
  La  La3  1  0.822  0.344  0.786  1.0
  C  C4  1  0.674  0.739  0.243  1.0
  C  C5  1  0.326  0.261  0.757  1.0
  C  C6  1  0.653  0.546  0.224  1.0
  C  C7  1  0.347  0.454  0.776  1.0
  C  C8  1  0.547  0.932  0.970  1.0
  C  C9  1  0.453  0.068  0.030  1.0
  C  C10  1  0.012  0.601  0.503  1.0
  C  C11  1  0.988  0.399  0.497  1.0
  O  O12  1  0.510  0.805  0.253  1.0
  O  O13  1  0.490  0.195  0.747  1.0
  O  O14  1  0.468  0.468  0.226  1.0
  O  O15  1  0.532  0.532  0.774  1.0
  O  O16  1  0.855  0.810  0.249  1.0
  O  O17  1  0.145  0.190  0.751  1.0
  O  O18  1  0.820  0.483  0.212  1.0
  O  O19  1  0.180  0.517  0.788  1.0
  O  O20  1  0.451  0.765  0.015  1.0
  O  O21  1  0.549  0.235  0.985  1.0
  O  O22  1  0.712  0.001  0.881  1.0
  O  O23  1  0.288  0.999  0.119  1.0
  O  O24  1  0.099  0.727  0.407  1.0
  O  O25  1  0.901  0.273  0.593  1.0
  O  O26  1  0.941  0.620  0.603  1.0
  O  O27  1  0.059  0.380  0.397  1.0
  O  O28  1  0.804  0.033  0.346  1.0
  O  O29  1  0.196  0.967  0.654  1.0
  O  O30  1  0.021  0.738  0.946  1.0
  O  O31  1  0.979  0.262  0.054  1.0
  O  O32  1  0.129  0.335  0.080  1.0
  O  O33  1  0.871  0.665  0.920  1.0
[/CIF]
.
The structure described by KLaC4O11 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 1-coordinate geometry to one O(1), one O(6), one O(8), and two equivalent O(9) atoms. La(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(7) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one O(1) and one O(3) atom. In the second C site, C(2) is bonded in a 2-coordinate geometry to one O(2) and one O(4) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(3), one O(5), and one O(6) atom. In the fourth C site, C(4) is bonded in a 4-coordinate geometry to one C(4), one O(7), and two equivalent O(8) atoms. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a bent 120 degrees geometry to one La(1) and one O(10) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one La(1), and one C(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one C(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one La(1), one C(1), and one O(9) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one C(2) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one C(3) atom. In the seventh O site, O(6) is bonded in a 2-coordinate geometry to one K(1) and one C(3) atom. In the eighth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one La(1) and one C(4) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one K(1) and two equivalent C(4) atoms. In the tenth O site, O(9) is bonded in a 3-coordinate geometry to two equivalent K(1) and one O(3) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one O(11) atom. is represented by the CIF card [CIF]
data_KLaC4O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.608
_cell_length_b   7.766
_cell_length_c   12.314
_cell_angle_alpha   106.861
_cell_angle_beta   100.944
_cell_angle_gamma   98.851
_symmetry_Int_Tables_number   1
_cell_volume   578.808
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.305  0.093  0.326  1.0
  K  K1  1  0.695  0.907  0.674  1.0
  La  La2  1  0.178  0.656  0.214  1.0
  La  La3  1  0.822  0.344  0.786  1.0
  C  C4  1  0.674  0.739  0.243  1.0
  C  C5  1  0.326  0.261  0.757  1.0
  C  C6  1  0.653  0.546  0.224  1.0
  C  C7  1  0.347  0.454  0.776  1.0
  C  C8  1  0.547  0.932  0.970  1.0
  C  C9  1  0.453  0.068  0.030  1.0
  C  C10  1  0.012  0.601  0.503  1.0
  C  C11  1  0.988  0.399  0.497  1.0
  O  O12  1  0.510  0.805  0.253  1.0
  O  O13  1  0.490  0.195  0.747  1.0
  O  O14  1  0.468  0.468  0.226  1.0
  O  O15  1  0.532  0.532  0.774  1.0
  O  O16  1  0.855  0.810  0.249  1.0
  O  O17  1  0.145  0.190  0.751  1.0
  O  O18  1  0.820  0.483  0.212  1.0
  O  O19  1  0.180  0.517  0.788  1.0
  O  O20  1  0.451  0.765  0.015  1.0
  O  O21  1  0.549  0.235  0.985  1.0
  O  O22  1  0.712  0.001  0.881  1.0
  O  O23  1  0.288  0.999  0.119  1.0
  O  O24  1  0.099  0.727  0.407  1.0
  O  O25  1  0.901  0.273  0.593  1.0
  O  O26  1  0.941  0.620  0.603  1.0
  O  O27  1  0.059  0.380  0.397  1.0
  O  O28  1  0.804  0.033  0.346  1.0
  O  O29  1  0.196  0.967  0.654  1.0
  O  O30  1  0.021  0.738  0.946  1.0
  O  O31  1  0.979  0.262  0.054  1.0
  O  O32  1  0.129  0.335  0.080  1.0
  O  O33  1  0.871  0.665  0.920  1.0
[/CIF]
.