The crystal structure described by SrLa7Cu3ZnO16 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(12), one O(15), one O(16), one O(2), one O(5), and two equivalent O(14) atoms. There are seven inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(14), one O(3), one O(4), one O(5), one O(6), one O(9), and two equivalent O(2) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(15), one O(16), one O(2), one O(5), one O(7), and two equivalent O(3) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(2), one O(4), one O(7), one O(8), one O(9), and two equivalent O(6) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(3), one O(4), one O(5), one O(6), one O(9), and two equivalent O(7) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(16), one O(6), one O(8), and two equivalent O(10) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(15), one O(4), one O(7), one O(8), one O(9), and two equivalent O(11) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(16), one O(3), one O(8), and two equivalent O(15) atoms. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(12), one O(14), one O(16), one O(3), and one O(5) atom to form corner-sharing CuO6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second Cu site, Cu(2) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the third Cu site, Cu(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(16), and one O(8) atom to form distorted CuO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. Zn(1) is bonded to one O(11), one O(13), one O(4), one O(6), one O(8), and one O(9) atom to form ZnO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra and corners with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one La(1), one La(2), one La(4), one Cu(1), and one Cu(2) atom to form distorted OSrLa3Cu2 octahedra that share  a cornercorner with one O(9)La4ZnCu octahedra,  a cornercorner with one O(14)Sr2La3Cu octahedra,  a cornercorner with one O(16)SrLa3Cu2 octahedra,  an edgeedge with one O(9)La4ZnCu octahedra,  an edgeedge with one O(16)SrLa3Cu2 octahedra,  a faceface with one O(4)La4ZnCu octahedra,  a faceface with one O(14)Sr2La3Cu octahedra,  a faceface with one O(12)SrLa3Cu2 octahedra, and faces with two equivalent O(5)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-53°. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Sr(1), one La(2), one La(3), two equivalent La(1), and one Cu(2) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one La(1), one La(4), one La(7), two equivalent La(2), and one Cu(1) atom. In the fourth O site, O(4) is bonded to one La(1), one La(3), one La(4), one La(6), one Cu(2), and one Zn(1) atom to form distorted OLa4ZnCu octahedra that share  a cornercorner with one O(13)La4ZnCu octahedra,  a cornercorner with one O(14)Sr2La3Cu octahedra,  a cornercorner with one O(5)SrLa3Cu2 octahedra,  an edgeedge with one O(13)La4ZnCu octahedra,  an edgeedge with one O(5)SrLa3Cu2 octahedra,  a faceface with one O(8)La4ZnCu octahedra,  a faceface with one O(1)SrLa3Cu2 octahedra, and faces with two equivalent O(9)La4ZnCu octahedra. The corner-sharing octahedral tilt angles range from 2-51°. In the fifth O site, O(5) is bonded to one Sr(1), one La(1), one La(2), one La(4), one Cu(1), and one Cu(2) atom to form distorted OSrLa3Cu2 octahedra that share  a cornercorner with one O(4)La4ZnCu octahedra,  a cornercorner with one O(14)Sr2La3Cu octahedra,  a cornercorner with one O(12)SrLa3Cu2 octahedra,  an edgeedge with one O(4)La4ZnCu octahedra,  an edgeedge with one O(12)SrLa3Cu2 octahedra,  a faceface with one O(9)La4ZnCu octahedra,  a faceface with one O(14)Sr2La3Cu octahedra,  a faceface with one O(16)SrLa3Cu2 octahedra, and faces with two equivalent O(1)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 3-51°. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one La(1), one La(4), one La(5), two equivalent La(3), and one Zn(1) atom. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one La(2), one La(3), one La(6), two equivalent La(4), and one Cu(2) atom. In the eighth O site, O(8) is bonded to one La(3), one La(5), one La(6), one La(7), one Cu(3), and one Zn(1) atom to form distorted OLa4ZnCu octahedra that share  a cornercorner with one O(9)La4ZnCu octahedra,  a cornercorner with one O(16)SrLa3Cu2 octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra,  an edgeedge with one O(9)La4ZnCu octahedra,  an edgeedge with one O(16)SrLa3Cu2 octahedra,  a faceface with one O(4)La4ZnCu octahedra,  a faceface with one O(12)SrLa3Cu2 octahedra, and faces with two equivalent O(13)La4ZnCu octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the ninth O site, O(9) is bonded to one La(1), one La(3), one La(4), one La(6), one Cu(2), and one Zn(1) atom to form distorted OLa4ZnCu octahedra that share  a cornercorner with one O(8)La4ZnCu octahedra,  a cornercorner with one O(14)Sr2La3Cu octahedra,  a cornercorner with one O(1)SrLa3Cu2 octahedra,  an edgeedge with one O(8)La4ZnCu octahedra,  an edgeedge with one O(1)SrLa3Cu2 octahedra,  a faceface with one O(13)La4ZnCu octahedra,  a faceface with one O(5)SrLa3Cu2 octahedra, and faces with two equivalent O(4)La4ZnCu octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Sr(1), one La(3), one La(6), two equivalent La(5), and one Cu(3) atom. In the eleventh O site, O(11) is bonded in a 6-coordinate geometry to one La(4), one La(5), one La(7), two equivalent La(6), and one Zn(1) atom. In the twelfth O site, O(12) is bonded to one Sr(1), one La(2), one La(5), one La(7), one Cu(1), and one Cu(3) atom to form distorted OSrLa3Cu2 octahedra that share  a cornercorner with one O(13)La4ZnCu octahedra,  a cornercorner with one O(5)SrLa3Cu2 octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra,  an edgeedge with one O(13)La4ZnCu octahedra,  an edgeedge with one O(5)SrLa3Cu2 octahedra,  a faceface with one O(8)La4ZnCu octahedra,  a faceface with one O(14)Sr2La3Cu octahedra,  a faceface with one O(1)SrLa3Cu2 octahedra, and faces with two equivalent O(16)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-53°. In the thirteenth O site, O(13) is bonded to one La(3), one La(5), one La(6), one La(7), one Cu(3), and one Zn(1) atom to form distorted OLa4ZnCu octahedra that share  a cornercorner with one O(4)La4ZnCu octahedra,  a cornercorner with one O(12)SrLa3Cu2 octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra,  an edgeedge with one O(4)La4ZnCu octahedra,  an edgeedge with one O(12)SrLa3Cu2 octahedra,  a faceface with one O(9)La4ZnCu octahedra,  a faceface with one O(16)SrLa3Cu2 octahedra, and faces with two equivalent O(8)La4ZnCu octahedra. The corner-sharing octahedral tilt angles range from 2-51°. In the fourteenth O site, O(14) is bonded to two equivalent Sr(1), one La(1), one La(5), one La(7), and one Cu(1) atom to form distorted OSr2La3Cu octahedra that share  a cornercorner with one O(4)La4ZnCu octahedra,  a cornercorner with one O(9)La4ZnCu octahedra,  a cornercorner with one O(1)SrLa3Cu2 octahedra,  a cornercorner with one O(5)SrLa3Cu2 octahedra, corners with two equivalent O(13)La4ZnCu octahedra, corners with two equivalent O(8)La4ZnCu octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra, corners with two equivalent O(12)SrLa3Cu2 octahedra, corners with two equivalent O(16)SrLa3Cu2 octahedra,  a faceface with one O(1)SrLa3Cu2 octahedra,  a faceface with one O(12)SrLa3Cu2 octahedra,  a faceface with one O(16)SrLa3Cu2 octahedra, and  a faceface with one O(5)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 21-53°. In the fifteenth O site, O(15) is bonded in a 6-coordinate geometry to one Sr(1), one La(2), one La(6), two equivalent La(7), and one Cu(3) atom. In the sixteenth O site, O(16) is bonded to one Sr(1), one La(2), one La(5), one La(7), one Cu(1), and one Cu(3) atom to form distorted OSrLa3Cu2 octahedra that share  a cornercorner with one O(8)La4ZnCu octahedra,  a cornercorner with one O(1)SrLa3Cu2 octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra,  an edgeedge with one O(8)La4ZnCu octahedra,  an edgeedge with one O(1)SrLa3Cu2 octahedra,  a faceface with one O(13)La4ZnCu octahedra,  a faceface with one O(14)Sr2La3Cu octahedra,  a faceface with one O(5)SrLa3Cu2 octahedra, and faces with two equivalent O(12)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-49°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrLa7ZnCu3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.810
_cell_length_b   5.464
_cell_length_c   7.066
_cell_angle_alpha   89.529
_cell_angle_beta   67.499
_cell_angle_gamma   89.963
_symmetry_Int_Tables_number   1
_cell_volume   385.568
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.930  0.498  0.279  1.0
  La  La1  1  0.175  0.982  0.278  1.0
  La  La2  1  0.067  0.493  0.725  1.0
  La  La3  1  0.429  0.506  0.281  1.0
  La  La4  1  0.320  0.015  0.719  1.0
  La  La5  1  0.685  0.983  0.278  1.0
  La  La6  1  0.573  0.493  0.721  1.0
  La  La7  1  0.822  0.017  0.719  1.0
  Zn  Zn8  1  0.498  0.999  0.007  1.0
  Cu  Cu9  1  0.999  0.998  0.006  1.0
  Cu  Cu10  1  0.249  0.499  0.997  1.0
  Cu  Cu11  1  0.752  0.499  0.998  1.0
  O  O12  1  0.135  0.752  0.979  1.0
  O  O13  1  0.166  0.552  0.377  1.0
  O  O14  1  0.088  0.035  0.637  1.0
  O  O15  1  0.376  0.744  0.981  1.0
  O  O16  1  0.128  0.251  0.000  1.0
  O  O17  1  0.410  0.968  0.355  1.0
  O  O18  1  0.345  0.450  0.625  1.0
  O  O19  1  0.634  0.750  0.989  1.0
  O  O20  1  0.365  0.249  0.013  1.0
  O  O21  1  0.648  0.550  0.378  1.0
  O  O22  1  0.591  0.034  0.642  1.0
  O  O23  1  0.877  0.747  0.985  1.0
  O  O24  1  0.623  0.254  0.022  1.0
  O  O25  1  0.914  0.982  0.357  1.0
  O  O26  1  0.836  0.455  0.644  1.0
  O  O27  1  0.868  0.245  0.009  1.0
[/CIF]
.
The crystal structure described by SrLa7Cu3ZnO16 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(12), one O(15), one O(16), one O(2), one O(5), and two equivalent O(14) atoms. There are seven inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(14), one O(3), one O(4), one O(5), one O(6), one O(9), and two equivalent O(2) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(15), one O(16), one O(2), one O(5), one O(7), and two equivalent O(3) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(2), one O(4), one O(7), one O(8), one O(9), and two equivalent O(6) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(3), one O(4), one O(5), one O(6), one O(9), and two equivalent O(7) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(16), one O(6), one O(8), and two equivalent O(10) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(15), one O(4), one O(7), one O(8), one O(9), and two equivalent O(11) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(16), one O(3), one O(8), and two equivalent O(15) atoms. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(12), one O(14), one O(16), one O(3), and one O(5) atom to form corner-sharing CuO6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second Cu site, Cu(2) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the third Cu site, Cu(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(16), and one O(8) atom to form distorted CuO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. Zn(1) is bonded to one O(11), one O(13), one O(4), one O(6), one O(8), and one O(9) atom to form ZnO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra and corners with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one La(1), one La(2), one La(4), one Cu(1), and one Cu(2) atom to form distorted OSrLa3Cu2 octahedra that share  a cornercorner with one O(9)La4ZnCu octahedra,  a cornercorner with one O(14)Sr2La3Cu octahedra,  a cornercorner with one O(16)SrLa3Cu2 octahedra,  an edgeedge with one O(9)La4ZnCu octahedra,  an edgeedge with one O(16)SrLa3Cu2 octahedra,  a faceface with one O(4)La4ZnCu octahedra,  a faceface with one O(14)Sr2La3Cu octahedra,  a faceface with one O(12)SrLa3Cu2 octahedra, and faces with two equivalent O(5)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-53°. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Sr(1), one La(2), one La(3), two equivalent La(1), and one Cu(2) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one La(1), one La(4), one La(7), two equivalent La(2), and one Cu(1) atom. In the fourth O site, O(4) is bonded to one La(1), one La(3), one La(4), one La(6), one Cu(2), and one Zn(1) atom to form distorted OLa4ZnCu octahedra that share  a cornercorner with one O(13)La4ZnCu octahedra,  a cornercorner with one O(14)Sr2La3Cu octahedra,  a cornercorner with one O(5)SrLa3Cu2 octahedra,  an edgeedge with one O(13)La4ZnCu octahedra,  an edgeedge with one O(5)SrLa3Cu2 octahedra,  a faceface with one O(8)La4ZnCu octahedra,  a faceface with one O(1)SrLa3Cu2 octahedra, and faces with two equivalent O(9)La4ZnCu octahedra. The corner-sharing octahedral tilt angles range from 2-51°. In the fifth O site, O(5) is bonded to one Sr(1), one La(1), one La(2), one La(4), one Cu(1), and one Cu(2) atom to form distorted OSrLa3Cu2 octahedra that share  a cornercorner with one O(4)La4ZnCu octahedra,  a cornercorner with one O(14)Sr2La3Cu octahedra,  a cornercorner with one O(12)SrLa3Cu2 octahedra,  an edgeedge with one O(4)La4ZnCu octahedra,  an edgeedge with one O(12)SrLa3Cu2 octahedra,  a faceface with one O(9)La4ZnCu octahedra,  a faceface with one O(14)Sr2La3Cu octahedra,  a faceface with one O(16)SrLa3Cu2 octahedra, and faces with two equivalent O(1)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 3-51°. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one La(1), one La(4), one La(5), two equivalent La(3), and one Zn(1) atom. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one La(2), one La(3), one La(6), two equivalent La(4), and one Cu(2) atom. In the eighth O site, O(8) is bonded to one La(3), one La(5), one La(6), one La(7), one Cu(3), and one Zn(1) atom to form distorted OLa4ZnCu octahedra that share  a cornercorner with one O(9)La4ZnCu octahedra,  a cornercorner with one O(16)SrLa3Cu2 octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra,  an edgeedge with one O(9)La4ZnCu octahedra,  an edgeedge with one O(16)SrLa3Cu2 octahedra,  a faceface with one O(4)La4ZnCu octahedra,  a faceface with one O(12)SrLa3Cu2 octahedra, and faces with two equivalent O(13)La4ZnCu octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the ninth O site, O(9) is bonded to one La(1), one La(3), one La(4), one La(6), one Cu(2), and one Zn(1) atom to form distorted OLa4ZnCu octahedra that share  a cornercorner with one O(8)La4ZnCu octahedra,  a cornercorner with one O(14)Sr2La3Cu octahedra,  a cornercorner with one O(1)SrLa3Cu2 octahedra,  an edgeedge with one O(8)La4ZnCu octahedra,  an edgeedge with one O(1)SrLa3Cu2 octahedra,  a faceface with one O(13)La4ZnCu octahedra,  a faceface with one O(5)SrLa3Cu2 octahedra, and faces with two equivalent O(4)La4ZnCu octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Sr(1), one La(3), one La(6), two equivalent La(5), and one Cu(3) atom. In the eleventh O site, O(11) is bonded in a 6-coordinate geometry to one La(4), one La(5), one La(7), two equivalent La(6), and one Zn(1) atom. In the twelfth O site, O(12) is bonded to one Sr(1), one La(2), one La(5), one La(7), one Cu(1), and one Cu(3) atom to form distorted OSrLa3Cu2 octahedra that share  a cornercorner with one O(13)La4ZnCu octahedra,  a cornercorner with one O(5)SrLa3Cu2 octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra,  an edgeedge with one O(13)La4ZnCu octahedra,  an edgeedge with one O(5)SrLa3Cu2 octahedra,  a faceface with one O(8)La4ZnCu octahedra,  a faceface with one O(14)Sr2La3Cu octahedra,  a faceface with one O(1)SrLa3Cu2 octahedra, and faces with two equivalent O(16)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-53°. In the thirteenth O site, O(13) is bonded to one La(3), one La(5), one La(6), one La(7), one Cu(3), and one Zn(1) atom to form distorted OLa4ZnCu octahedra that share  a cornercorner with one O(4)La4ZnCu octahedra,  a cornercorner with one O(12)SrLa3Cu2 octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra,  an edgeedge with one O(4)La4ZnCu octahedra,  an edgeedge with one O(12)SrLa3Cu2 octahedra,  a faceface with one O(9)La4ZnCu octahedra,  a faceface with one O(16)SrLa3Cu2 octahedra, and faces with two equivalent O(8)La4ZnCu octahedra. The corner-sharing octahedral tilt angles range from 2-51°. In the fourteenth O site, O(14) is bonded to two equivalent Sr(1), one La(1), one La(5), one La(7), and one Cu(1) atom to form distorted OSr2La3Cu octahedra that share  a cornercorner with one O(4)La4ZnCu octahedra,  a cornercorner with one O(9)La4ZnCu octahedra,  a cornercorner with one O(1)SrLa3Cu2 octahedra,  a cornercorner with one O(5)SrLa3Cu2 octahedra, corners with two equivalent O(13)La4ZnCu octahedra, corners with two equivalent O(8)La4ZnCu octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra, corners with two equivalent O(12)SrLa3Cu2 octahedra, corners with two equivalent O(16)SrLa3Cu2 octahedra,  a faceface with one O(1)SrLa3Cu2 octahedra,  a faceface with one O(12)SrLa3Cu2 octahedra,  a faceface with one O(16)SrLa3Cu2 octahedra, and  a faceface with one O(5)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 21-53°. In the fifteenth O site, O(15) is bonded in a 6-coordinate geometry to one Sr(1), one La(2), one La(6), two equivalent La(7), and one Cu(3) atom. In the sixteenth O site, O(16) is bonded to one Sr(1), one La(2), one La(5), one La(7), one Cu(1), and one Cu(3) atom to form distorted OSrLa3Cu2 octahedra that share  a cornercorner with one O(8)La4ZnCu octahedra,  a cornercorner with one O(1)SrLa3Cu2 octahedra, corners with two equivalent O(14)Sr2La3Cu octahedra,  an edgeedge with one O(8)La4ZnCu octahedra,  an edgeedge with one O(1)SrLa3Cu2 octahedra,  a faceface with one O(13)La4ZnCu octahedra,  a faceface with one O(14)Sr2La3Cu octahedra,  a faceface with one O(5)SrLa3Cu2 octahedra, and faces with two equivalent O(12)SrLa3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-49°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrLa7ZnCu3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.810
_cell_length_b   5.464
_cell_length_c   7.066
_cell_angle_alpha   89.529
_cell_angle_beta   67.499
_cell_angle_gamma   89.963
_symmetry_Int_Tables_number   1
_cell_volume   385.568
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.930  0.498  0.279  1.0
  La  La1  1  0.175  0.982  0.278  1.0
  La  La2  1  0.067  0.493  0.725  1.0
  La  La3  1  0.429  0.506  0.281  1.0
  La  La4  1  0.320  0.015  0.719  1.0
  La  La5  1  0.685  0.983  0.278  1.0
  La  La6  1  0.573  0.493  0.721  1.0
  La  La7  1  0.822  0.017  0.719  1.0
  Zn  Zn8  1  0.498  0.999  0.007  1.0
  Cu  Cu9  1  0.999  0.998  0.006  1.0
  Cu  Cu10  1  0.249  0.499  0.997  1.0
  Cu  Cu11  1  0.752  0.499  0.998  1.0
  O  O12  1  0.135  0.752  0.979  1.0
  O  O13  1  0.166  0.552  0.377  1.0
  O  O14  1  0.088  0.035  0.637  1.0
  O  O15  1  0.376  0.744  0.981  1.0
  O  O16  1  0.128  0.251  0.000  1.0
  O  O17  1  0.410  0.968  0.355  1.0
  O  O18  1  0.345  0.450  0.625  1.0
  O  O19  1  0.634  0.750  0.989  1.0
  O  O20  1  0.365  0.249  0.013  1.0
  O  O21  1  0.648  0.550  0.378  1.0
  O  O22  1  0.591  0.034  0.642  1.0
  O  O23  1  0.877  0.747  0.985  1.0
  O  O24  1  0.623  0.254  0.022  1.0
  O  O25  1  0.914  0.982  0.357  1.0
  O  O26  1  0.836  0.455  0.644  1.0
  O  O27  1  0.868  0.245  0.009  1.0
[/CIF]
.