The compound described by Li6Co6O5F11 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one F(3), one F(5), one F(6), and one F(9) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one F(2), one F(3), one F(8), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(5), one F(4), one F(5), and one F(6) atom. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(4), one F(10), one F(4), and one F(8) atom. In the sixth Li site, Li(6) is bonded in a 4-coordinate geometry to one F(1), one F(10), one F(11), and one F(7) atom. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded in a 2-coordinate geometry to one O(2), one O(3), one O(5), one F(1), and one F(2) atom. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one F(11), and one F(7) atom. In the third Co site, Co(3) is bonded in a 4-coordinate geometry to one O(4), one F(10), one F(4), and one F(8) atom. In the fourth Co site, Co(4) is bonded in a 2-coordinate geometry to one O(2), one O(5), and one F(1) atom. In the fifth Co site, Co(5) is bonded in a 2-coordinate geometry to one O(1), one O(3), one F(3), and one F(9) atom. In the sixth Co site, Co(6) is bonded in a 5-coordinate geometry to one O(4), one F(11), one F(5), one F(6), and one F(7) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Co(2), and one Co(5) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one Co(2), and one Co(4) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one Co(2), and one Co(5) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(5), one Co(3), and one Co(6) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(4), one Co(1), and one Co(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(6), one Co(1), and one Co(4) atom. In the second F site, F(2) is bonded in a distorted water-like geometry to one Li(3) and one Co(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one Co(5) atom. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one Li(5), and one Co(3) atom. In the fifth F site, F(5) is bonded in a 1-coordinate geometry to one Li(2), one Li(4), and one Co(6) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(2), one Li(4), and one Co(6) atom. In the seventh F site, F(7) is bonded in a distorted bent 120 degrees geometry to one Li(6), one Co(2), and one Co(6) atom. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), and one Co(3) atom. In the ninth F site, F(9) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one Co(5) atom. In the tenth F site, F(10) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Li(6), and one Co(3) atom. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Li(6), one Co(2), and one Co(6) atom. is represented by the CIF card [CIF]
data_Li6Co6O5F11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.014
_cell_length_b   6.044
_cell_length_c   10.419
_cell_angle_alpha   106.377
_cell_angle_beta   90.121
_cell_angle_gamma   119.786
_symmetry_Int_Tables_number   1
_cell_volume   310.759
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.757  0.376  0.873  1.0
  Li  Li1  1  0.364  0.189  0.442  1.0
  Li  Li2  1  0.000  0.505  0.506  1.0
  Li  Li3  1  0.751  0.865  0.377  1.0
  Li  Li4  1  0.373  0.435  0.193  1.0
  Li  Li5  1  0.002  0.010  0.995  1.0
  Co  Co6  1  0.395  0.923  0.687  1.0
  Co  Co7  1  0.401  0.686  0.915  1.0
  Co  Co8  1  0.865  0.434  0.189  1.0
  Co  Co9  1  0.839  0.921  0.690  1.0
  Co  Co10  1  0.384  0.453  0.687  1.0
  Co  Co11  1  0.394  0.969  0.180  1.0
  O  O12  1  0.619  0.574  0.813  1.0
  O  O13  1  0.599  0.036  0.812  1.0
  O  O14  1  0.158  0.580  0.810  1.0
  O  O15  1  0.608  0.280  0.081  1.0
  O  O16  1  0.615  0.815  0.571  1.0
  F  F17  1  0.131  0.061  0.796  1.0
  F  F18  1  0.133  0.837  0.571  1.0
  F  F19  1  0.602  0.299  0.567  1.0
  F  F20  1  0.618  0.540  0.308  1.0
  F  F21  1  0.148  0.065  0.308  1.0
  F  F22  1  0.610  0.062  0.311  1.0
  F  F23  1  0.135  0.807  0.069  1.0
  F  F24  1  0.142  0.592  0.294  1.0
  F  F25  1  0.127  0.295  0.567  1.0
  F  F26  1  0.133  0.339  0.069  1.0
  F  F27  1  0.597  0.802  0.070  1.0
[/CIF]
.
The compound described by Li6Co6O5F11 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one F(3), one F(5), one F(6), and one F(9) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one F(2), one F(3), one F(8), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(5), one F(4), one F(5), and one F(6) atom. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(4), one F(10), one F(4), and one F(8) atom. In the sixth Li site, Li(6) is bonded in a 4-coordinate geometry to one F(1), one F(10), one F(11), and one F(7) atom. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded in a 2-coordinate geometry to one O(2), one O(3), one O(5), one F(1), and one F(2) atom. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one F(11), and one F(7) atom. In the third Co site, Co(3) is bonded in a 4-coordinate geometry to one O(4), one F(10), one F(4), and one F(8) atom. In the fourth Co site, Co(4) is bonded in a 2-coordinate geometry to one O(2), one O(5), and one F(1) atom. In the fifth Co site, Co(5) is bonded in a 2-coordinate geometry to one O(1), one O(3), one F(3), and one F(9) atom. In the sixth Co site, Co(6) is bonded in a 5-coordinate geometry to one O(4), one F(11), one F(5), one F(6), and one F(7) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Co(2), and one Co(5) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one Co(2), and one Co(4) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one Co(2), and one Co(5) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(5), one Co(3), and one Co(6) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(4), one Co(1), and one Co(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(6), one Co(1), and one Co(4) atom. In the second F site, F(2) is bonded in a distorted water-like geometry to one Li(3) and one Co(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one Co(5) atom. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one Li(5), and one Co(3) atom. In the fifth F site, F(5) is bonded in a 1-coordinate geometry to one Li(2), one Li(4), and one Co(6) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(2), one Li(4), and one Co(6) atom. In the seventh F site, F(7) is bonded in a distorted bent 120 degrees geometry to one Li(6), one Co(2), and one Co(6) atom. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), and one Co(3) atom. In the ninth F site, F(9) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one Co(5) atom. In the tenth F site, F(10) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Li(6), and one Co(3) atom. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Li(6), one Co(2), and one Co(6) atom. is represented by the CIF card [CIF]
data_Li6Co6O5F11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.014
_cell_length_b   6.044
_cell_length_c   10.419
_cell_angle_alpha   106.377
_cell_angle_beta   90.121
_cell_angle_gamma   119.786
_symmetry_Int_Tables_number   1
_cell_volume   310.759
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.757  0.376  0.873  1.0
  Li  Li1  1  0.364  0.189  0.442  1.0
  Li  Li2  1  0.000  0.505  0.506  1.0
  Li  Li3  1  0.751  0.865  0.377  1.0
  Li  Li4  1  0.373  0.435  0.193  1.0
  Li  Li5  1  0.002  0.010  0.995  1.0
  Co  Co6  1  0.395  0.923  0.687  1.0
  Co  Co7  1  0.401  0.686  0.915  1.0
  Co  Co8  1  0.865  0.434  0.189  1.0
  Co  Co9  1  0.839  0.921  0.690  1.0
  Co  Co10  1  0.384  0.453  0.687  1.0
  Co  Co11  1  0.394  0.969  0.180  1.0
  O  O12  1  0.619  0.574  0.813  1.0
  O  O13  1  0.599  0.036  0.812  1.0
  O  O14  1  0.158  0.580  0.810  1.0
  O  O15  1  0.608  0.280  0.081  1.0
  O  O16  1  0.615  0.815  0.571  1.0
  F  F17  1  0.131  0.061  0.796  1.0
  F  F18  1  0.133  0.837  0.571  1.0
  F  F19  1  0.602  0.299  0.567  1.0
  F  F20  1  0.618  0.540  0.308  1.0
  F  F21  1  0.148  0.065  0.308  1.0
  F  F22  1  0.610  0.062  0.311  1.0
  F  F23  1  0.135  0.807  0.069  1.0
  F  F24  1  0.142  0.592  0.294  1.0
  F  F25  1  0.127  0.295  0.567  1.0
  F  F26  1  0.133  0.339  0.069  1.0
  F  F27  1  0.597  0.802  0.070  1.0
[/CIF]
.