The structure described by VF5 is Copper structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two VF5 clusters. V(1) is bonded to one F(2), one F(3), one F(4), one F(5), and two equivalent F(1) atoms to form edge-sharing VF6 octahedra. There are five inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.720
_cell_length_b   6.339
_cell_length_c   8.773
_cell_angle_alpha   48.889
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   365.352
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.629  0.116  0.062  1.0
  V  V1  1  0.129  0.884  0.438  1.0
  V  V2  1  0.871  0.116  0.562  1.0
  V  V3  1  0.371  0.884  0.938  1.0
  F  F4  1  0.400  0.084  0.041  1.0
  F  F5  1  0.828  0.104  0.057  1.0
  F  F6  1  0.601  0.288  0.153  1.0
  F  F7  1  0.384  0.575  0.196  1.0
  F  F8  1  0.113  0.222  0.195  1.0
  F  F9  1  0.884  0.425  0.304  1.0
  F  F10  1  0.613  0.778  0.305  1.0
  F  F11  1  0.101  0.712  0.347  1.0
  F  F12  1  0.328  0.896  0.443  1.0
  F  F13  1  0.900  0.916  0.459  1.0
  F  F14  1  0.100  0.084  0.541  1.0
  F  F15  1  0.672  0.104  0.557  1.0
  F  F16  1  0.899  0.288  0.653  1.0
  F  F17  1  0.387  0.222  0.695  1.0
  F  F18  1  0.116  0.575  0.696  1.0
  F  F19  1  0.887  0.778  0.805  1.0
  F  F20  1  0.616  0.425  0.804  1.0
  F  F21  1  0.399  0.712  0.847  1.0
  F  F22  1  0.172  0.896  0.943  1.0
  F  F23  1  0.600  0.916  0.959  1.0
[/CIF]
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The structure described by VF5 is Copper structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two VF5 clusters. V(1) is bonded to one F(2), one F(3), one F(4), one F(5), and two equivalent F(1) atoms to form edge-sharing VF6 octahedra. There are five inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.720
_cell_length_b   6.339
_cell_length_c   8.773
_cell_angle_alpha   48.889
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   365.352
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.629  0.116  0.062  1.0
  V  V1  1  0.129  0.884  0.438  1.0
  V  V2  1  0.871  0.116  0.562  1.0
  V  V3  1  0.371  0.884  0.938  1.0
  F  F4  1  0.400  0.084  0.041  1.0
  F  F5  1  0.828  0.104  0.057  1.0
  F  F6  1  0.601  0.288  0.153  1.0
  F  F7  1  0.384  0.575  0.196  1.0
  F  F8  1  0.113  0.222  0.195  1.0
  F  F9  1  0.884  0.425  0.304  1.0
  F  F10  1  0.613  0.778  0.305  1.0
  F  F11  1  0.101  0.712  0.347  1.0
  F  F12  1  0.328  0.896  0.443  1.0
  F  F13  1  0.900  0.916  0.459  1.0
  F  F14  1  0.100  0.084  0.541  1.0
  F  F15  1  0.672  0.104  0.557  1.0
  F  F16  1  0.899  0.288  0.653  1.0
  F  F17  1  0.387  0.222  0.695  1.0
  F  F18  1  0.116  0.575  0.696  1.0
  F  F19  1  0.887  0.778  0.805  1.0
  F  F20  1  0.616  0.425  0.804  1.0
  F  F21  1  0.399  0.712  0.847  1.0
  F  F22  1  0.172  0.896  0.943  1.0
  F  F23  1  0.600  0.916  0.959  1.0
[/CIF]
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