The material described by OsO2F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two OsO2F3 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in an octahedral geometry to one O(3), one F(1), one F(3), one F(4), one F(5), and one F(6) atom. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one F(2), one F(5), and one F(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Os(2) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the second F site, F(6) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Os(2) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF card [CIF]
data_OsO2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.329
_cell_length_b   5.764
_cell_length_c   12.910
_cell_angle_alpha   78.518
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   753.151
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.742  0.971  0.497  1.0
  Os  Os1  1  0.008  0.659  0.217  1.0
  Os  Os2  1  0.258  0.029  0.503  1.0
  Os  Os3  1  0.992  0.341  0.783  1.0
  Os  Os4  1  0.492  0.659  0.717  1.0
  Os  Os5  1  0.508  0.341  0.283  1.0
  Os  Os6  1  0.242  0.029  0.003  1.0
  Os  Os7  1  0.758  0.971  0.997  1.0
  O  O8  1  0.155  0.531  0.253  1.0
  O  O9  1  0.441  0.529  0.355  1.0
  O  O10  1  0.666  0.741  0.460  1.0
  O  O11  1  0.422  0.395  0.167  1.0
  O  O12  1  0.578  0.605  0.833  1.0
  O  O13  1  0.845  0.469  0.747  1.0
  O  O14  1  0.559  0.471  0.645  1.0
  O  O15  1  0.834  0.741  0.960  1.0
  O  O16  1  0.059  0.529  0.855  1.0
  O  O17  1  0.334  0.259  0.540  1.0
  O  O18  1  0.655  0.469  0.247  1.0
  O  O19  1  0.078  0.395  0.667  1.0
  O  O20  1  0.922  0.605  0.333  1.0
  O  O21  1  0.345  0.531  0.753  1.0
  O  O22  1  0.166  0.259  0.040  1.0
  O  O23  1  0.941  0.471  0.145  1.0
  F  F24  1  0.835  0.092  0.371  1.0
  F  F25  1  0.444  0.974  0.725  1.0
  F  F26  1  0.394  0.183  0.945  1.0
  F  F27  1  0.665  0.092  0.871  1.0
  F  F28  1  0.944  0.026  0.775  1.0
  F  F29  1  0.556  0.026  0.275  1.0
  F  F30  1  0.106  0.183  0.445  1.0
  F  F31  1  0.790  0.239  0.551  1.0
  F  F32  1  0.335  0.908  0.129  1.0
  F  F33  1  0.844  0.883  0.143  1.0
  F  F34  1  0.056  0.974  0.225  1.0
  F  F35  1  0.210  0.761  0.449  1.0
  F  F36  1  0.894  0.817  0.555  1.0
  F  F37  1  0.590  0.187  0.442  1.0
  F  F38  1  0.606  0.817  0.055  1.0
  F  F39  1  0.344  0.117  0.357  1.0
  F  F40  1  0.290  0.761  0.949  1.0
  F  F41  1  0.910  0.187  0.942  1.0
  F  F42  1  0.656  0.883  0.643  1.0
  F  F43  1  0.410  0.813  0.558  1.0
  F  F44  1  0.710  0.239  0.051  1.0
  F  F45  1  0.165  0.908  0.629  1.0
  F  F46  1  0.090  0.813  0.058  1.0
  F  F47  1  0.156  0.117  0.857  1.0
[/CIF]
.
The material described by OsO2F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two OsO2F3 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in an octahedral geometry to one O(3), one F(1), one F(3), one F(4), one F(5), and one F(6) atom. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one F(2), one F(5), and one F(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Os(2) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the second F site, F(6) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Os(2) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF card [CIF]
data_OsO2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.329
_cell_length_b   5.764
_cell_length_c   12.910
_cell_angle_alpha   78.518
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   753.151
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.742  0.971  0.497  1.0
  Os  Os1  1  0.008  0.659  0.217  1.0
  Os  Os2  1  0.258  0.029  0.503  1.0
  Os  Os3  1  0.992  0.341  0.783  1.0
  Os  Os4  1  0.492  0.659  0.717  1.0
  Os  Os5  1  0.508  0.341  0.283  1.0
  Os  Os6  1  0.242  0.029  0.003  1.0
  Os  Os7  1  0.758  0.971  0.997  1.0
  O  O8  1  0.155  0.531  0.253  1.0
  O  O9  1  0.441  0.529  0.355  1.0
  O  O10  1  0.666  0.741  0.460  1.0
  O  O11  1  0.422  0.395  0.167  1.0
  O  O12  1  0.578  0.605  0.833  1.0
  O  O13  1  0.845  0.469  0.747  1.0
  O  O14  1  0.559  0.471  0.645  1.0
  O  O15  1  0.834  0.741  0.960  1.0
  O  O16  1  0.059  0.529  0.855  1.0
  O  O17  1  0.334  0.259  0.540  1.0
  O  O18  1  0.655  0.469  0.247  1.0
  O  O19  1  0.078  0.395  0.667  1.0
  O  O20  1  0.922  0.605  0.333  1.0
  O  O21  1  0.345  0.531  0.753  1.0
  O  O22  1  0.166  0.259  0.040  1.0
  O  O23  1  0.941  0.471  0.145  1.0
  F  F24  1  0.835  0.092  0.371  1.0
  F  F25  1  0.444  0.974  0.725  1.0
  F  F26  1  0.394  0.183  0.945  1.0
  F  F27  1  0.665  0.092  0.871  1.0
  F  F28  1  0.944  0.026  0.775  1.0
  F  F29  1  0.556  0.026  0.275  1.0
  F  F30  1  0.106  0.183  0.445  1.0
  F  F31  1  0.790  0.239  0.551  1.0
  F  F32  1  0.335  0.908  0.129  1.0
  F  F33  1  0.844  0.883  0.143  1.0
  F  F34  1  0.056  0.974  0.225  1.0
  F  F35  1  0.210  0.761  0.449  1.0
  F  F36  1  0.894  0.817  0.555  1.0
  F  F37  1  0.590  0.187  0.442  1.0
  F  F38  1  0.606  0.817  0.055  1.0
  F  F39  1  0.344  0.117  0.357  1.0
  F  F40  1  0.290  0.761  0.949  1.0
  F  F41  1  0.910  0.187  0.942  1.0
  F  F42  1  0.656  0.883  0.643  1.0
  F  F43  1  0.410  0.813  0.558  1.0
  F  F44  1  0.710  0.239  0.051  1.0
  F  F45  1  0.165  0.908  0.629  1.0
  F  F46  1  0.090  0.813  0.058  1.0
  F  F47  1  0.156  0.117  0.857  1.0
[/CIF]
.