The compound described by P4(SO2)3 is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P4(SO2)3 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(2), one O(1), one O(2), and one O(4) atom to form distorted corner-sharing PSO3 tetrahedra. In the second P site, P(2) is bonded to one S(3), one O(4), one O(5), and one O(6) atom to form distorted corner-sharing PSO3 tetrahedra. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(5) atom. In the fourth P site, P(4) is bonded to one S(1), one O(2), one O(3), and one O(6) atom to form distorted corner-sharing PSO3 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(4) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one P(2) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P4(SO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.683
_cell_length_b   10.185
_cell_length_c   12.953
_cell_angle_alpha   88.896
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1145.290
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.515  0.329  0.867  1.0
  P  P1  1  0.015  0.171  0.133  1.0
  P  P2  1  0.214  0.950  0.734  1.0
  P  P3  1  0.985  0.829  0.867  1.0
  P  P4  1  0.561  0.599  0.790  1.0
  P  P5  1  0.061  0.901  0.210  1.0
  P  P6  1  0.439  0.401  0.210  1.0
  P  P7  1  0.939  0.099  0.790  1.0
  P  P8  1  0.582  0.376  0.651  1.0
  P  P9  1  0.082  0.124  0.349  1.0
  P  P10  1  0.418  0.624  0.349  1.0
  P  P11  1  0.918  0.876  0.651  1.0
  P  P12  1  0.286  0.450  0.734  1.0
  P  P13  1  0.786  0.050  0.266  1.0
  P  P14  1  0.714  0.550  0.266  1.0
  P  P15  1  0.485  0.671  0.133  1.0
  S  S16  1  0.682  0.307  0.536  1.0
  S  S17  1  0.318  0.693  0.464  1.0
  S  S18  1  0.818  0.807  0.536  1.0
  S  S19  1  0.545  0.210  0.978  1.0
  S  S20  1  0.045  0.290  0.022  1.0
  S  S21  1  0.455  0.790  0.022  1.0
  S  S22  1  0.955  0.710  0.978  1.0
  S  S23  1  0.074  0.459  0.705  1.0
  S  S24  1  0.574  0.041  0.295  1.0
  S  S25  1  0.926  0.541  0.295  1.0
  S  S26  1  0.426  0.959  0.705  1.0
  S  S27  1  0.182  0.193  0.464  1.0
  O  O28  1  0.576  0.478  0.880  1.0
  O  O29  1  0.096  0.212  0.242  1.0
  O  O30  1  0.404  0.712  0.242  1.0
  O  O31  1  0.904  0.788  0.758  1.0
  O  O32  1  0.634  0.520  0.689  1.0
  O  O33  1  0.134  0.980  0.311  1.0
  O  O34  1  0.366  0.480  0.311  1.0
  O  O35  1  0.866  0.020  0.689  1.0
  O  O36  1  0.336  0.353  0.831  1.0
  O  O37  1  0.836  0.147  0.169  1.0
  O  O38  1  0.664  0.647  0.169  1.0
  O  O39  1  0.164  0.853  0.831  1.0
  O  O40  1  0.127  0.085  0.763  1.0
  O  O41  1  0.596  0.288  0.758  1.0
  O  O42  1  0.627  0.415  0.237  1.0
  O  O43  1  0.873  0.915  0.237  1.0
  O  O44  1  0.076  0.022  0.120  1.0
  O  O45  1  0.424  0.522  0.120  1.0
  O  O46  1  0.924  0.978  0.880  1.0
  O  O47  1  0.394  0.393  0.642  1.0
  O  O48  1  0.894  0.107  0.358  1.0
  O  O49  1  0.606  0.607  0.358  1.0
  O  O50  1  0.106  0.893  0.642  1.0
  O  O51  1  0.373  0.585  0.763  1.0
[/CIF]
.
The compound described by P4(SO2)3 is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P4(SO2)3 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(2), one O(1), one O(2), and one O(4) atom to form distorted corner-sharing PSO3 tetrahedra. In the second P site, P(2) is bonded to one S(3), one O(4), one O(5), and one O(6) atom to form distorted corner-sharing PSO3 tetrahedra. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(5) atom. In the fourth P site, P(4) is bonded to one S(1), one O(2), one O(3), and one O(6) atom to form distorted corner-sharing PSO3 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(4) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one P(2) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P4(SO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.683
_cell_length_b   10.185
_cell_length_c   12.953
_cell_angle_alpha   88.896
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1145.290
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.515  0.329  0.867  1.0
  P  P1  1  0.015  0.171  0.133  1.0
  P  P2  1  0.214  0.950  0.734  1.0
  P  P3  1  0.985  0.829  0.867  1.0
  P  P4  1  0.561  0.599  0.790  1.0
  P  P5  1  0.061  0.901  0.210  1.0
  P  P6  1  0.439  0.401  0.210  1.0
  P  P7  1  0.939  0.099  0.790  1.0
  P  P8  1  0.582  0.376  0.651  1.0
  P  P9  1  0.082  0.124  0.349  1.0
  P  P10  1  0.418  0.624  0.349  1.0
  P  P11  1  0.918  0.876  0.651  1.0
  P  P12  1  0.286  0.450  0.734  1.0
  P  P13  1  0.786  0.050  0.266  1.0
  P  P14  1  0.714  0.550  0.266  1.0
  P  P15  1  0.485  0.671  0.133  1.0
  S  S16  1  0.682  0.307  0.536  1.0
  S  S17  1  0.318  0.693  0.464  1.0
  S  S18  1  0.818  0.807  0.536  1.0
  S  S19  1  0.545  0.210  0.978  1.0
  S  S20  1  0.045  0.290  0.022  1.0
  S  S21  1  0.455  0.790  0.022  1.0
  S  S22  1  0.955  0.710  0.978  1.0
  S  S23  1  0.074  0.459  0.705  1.0
  S  S24  1  0.574  0.041  0.295  1.0
  S  S25  1  0.926  0.541  0.295  1.0
  S  S26  1  0.426  0.959  0.705  1.0
  S  S27  1  0.182  0.193  0.464  1.0
  O  O28  1  0.576  0.478  0.880  1.0
  O  O29  1  0.096  0.212  0.242  1.0
  O  O30  1  0.404  0.712  0.242  1.0
  O  O31  1  0.904  0.788  0.758  1.0
  O  O32  1  0.634  0.520  0.689  1.0
  O  O33  1  0.134  0.980  0.311  1.0
  O  O34  1  0.366  0.480  0.311  1.0
  O  O35  1  0.866  0.020  0.689  1.0
  O  O36  1  0.336  0.353  0.831  1.0
  O  O37  1  0.836  0.147  0.169  1.0
  O  O38  1  0.664  0.647  0.169  1.0
  O  O39  1  0.164  0.853  0.831  1.0
  O  O40  1  0.127  0.085  0.763  1.0
  O  O41  1  0.596  0.288  0.758  1.0
  O  O42  1  0.627  0.415  0.237  1.0
  O  O43  1  0.873  0.915  0.237  1.0
  O  O44  1  0.076  0.022  0.120  1.0
  O  O45  1  0.424  0.522  0.120  1.0
  O  O46  1  0.924  0.978  0.880  1.0
  O  O47  1  0.394  0.393  0.642  1.0
  O  O48  1  0.894  0.107  0.358  1.0
  O  O49  1  0.606  0.607  0.358  1.0
  O  O50  1  0.106  0.893  0.642  1.0
  O  O51  1  0.373  0.585  0.763  1.0
[/CIF]
.