The material described by Bi(MoO5)2 crystallizes in the monoclinic P2_1/m space group. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), and two equivalent O(3) atoms. Bi(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Bi(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mo(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Mo(1) and one Bi(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(1) and one Bi(1) atom. is represented by the CIF card [CIF]
data_Bi(MoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.691
_cell_length_b   5.964
_cell_length_c   11.551
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.044
_symmetry_Int_Tables_number   1
_cell_volume   370.583
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.629  0.263  0.250  1.0
  Bi  Bi1  1  0.371  0.737  0.750  1.0
  Mo  Mo2  1  0.193  0.651  0.404  1.0
  Mo  Mo3  1  0.807  0.349  0.904  1.0
  Mo  Mo4  1  0.807  0.349  0.596  1.0
  Mo  Mo5  1  0.193  0.651  0.096  1.0
  O  O6  1  0.901  0.059  0.250  1.0
  O  O7  1  0.099  0.941  0.750  1.0
  O  O8  1  0.025  0.590  0.250  1.0
  O  O9  1  0.975  0.410  0.750  1.0
  O  O10  1  0.846  0.375  0.432  1.0
  O  O11  1  0.154  0.625  0.932  1.0
  O  O12  1  0.154  0.625  0.568  1.0
  O  O13  1  0.846  0.375  0.068  1.0
  O  O14  1  0.949  0.888  0.416  1.0
  O  O15  1  0.051  0.112  0.916  1.0
  O  O16  1  0.051  0.112  0.584  1.0
  O  O17  1  0.949  0.888  0.084  1.0
  O  O18  1  0.400  0.497  0.376  1.0
  O  O19  1  0.600  0.503  0.876  1.0
  O  O20  1  0.600  0.503  0.624  1.0
  O  O21  1  0.400  0.497  0.124  1.0
  O  O22  1  0.382  0.954  0.379  1.0
  O  O23  1  0.618  0.046  0.879  1.0
  O  O24  1  0.618  0.046  0.621  1.0
  O  O25  1  0.382  0.954  0.121  1.0
[/CIF]
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The material described by Bi(MoO5)2 crystallizes in the monoclinic P2_1/m space group. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), and two equivalent O(3) atoms. Bi(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Bi(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mo(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Mo(1) and one Bi(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(1) and one Bi(1) atom. is represented by the CIF card [CIF]
data_Bi(MoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.691
_cell_length_b   5.964
_cell_length_c   11.551
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.044
_symmetry_Int_Tables_number   1
_cell_volume   370.583
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.629  0.263  0.250  1.0
  Bi  Bi1  1  0.371  0.737  0.750  1.0
  Mo  Mo2  1  0.193  0.651  0.404  1.0
  Mo  Mo3  1  0.807  0.349  0.904  1.0
  Mo  Mo4  1  0.807  0.349  0.596  1.0
  Mo  Mo5  1  0.193  0.651  0.096  1.0
  O  O6  1  0.901  0.059  0.250  1.0
  O  O7  1  0.099  0.941  0.750  1.0
  O  O8  1  0.025  0.590  0.250  1.0
  O  O9  1  0.975  0.410  0.750  1.0
  O  O10  1  0.846  0.375  0.432  1.0
  O  O11  1  0.154  0.625  0.932  1.0
  O  O12  1  0.154  0.625  0.568  1.0
  O  O13  1  0.846  0.375  0.068  1.0
  O  O14  1  0.949  0.888  0.416  1.0
  O  O15  1  0.051  0.112  0.916  1.0
  O  O16  1  0.051  0.112  0.584  1.0
  O  O17  1  0.949  0.888  0.084  1.0
  O  O18  1  0.400  0.497  0.376  1.0
  O  O19  1  0.600  0.503  0.876  1.0
  O  O20  1  0.600  0.503  0.624  1.0
  O  O21  1  0.400  0.497  0.124  1.0
  O  O22  1  0.382  0.954  0.379  1.0
  O  O23  1  0.618  0.046  0.879  1.0
  O  O24  1  0.618  0.046  0.621  1.0
  O  O25  1  0.382  0.954  0.121  1.0
[/CIF]
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