The compound described by MnOF is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(7), one F(2), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the second Mn site, Mn(2) is bonded to one O(1), one O(4), one O(6), one F(1), one F(5), and one F(8) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 41-61°. In the third Mn site, Mn(3) is bonded to one O(2), one O(3), one O(8), one F(3), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 40-61°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(4), one O(5), one F(4), one F(5), and one F(8) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. In the fifth Mn site, Mn(5) is bonded to one O(4), one O(5), one O(8), one F(3), one F(4), and one F(8) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(6), one O(7), one F(1), one F(2), and one F(5) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 41-62°. In the seventh Mn site, Mn(7) is bonded to one O(2), one O(6), one O(7), one F(1), one F(2), and one F(6) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. In the eighth Mn site, Mn(8) is bonded to one O(3), one O(5), one O(8), one F(3), one F(4), and one F(7) atom to form a mixture of distorted edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 40-59°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. is represented by the CIF file [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.623
_cell_length_b   5.124
_cell_length_c   11.540
_cell_angle_alpha   89.614
_cell_angle_beta   87.253
_cell_angle_gamma   89.880
_symmetry_Int_Tables_number   1
_cell_volume   273.037
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.002  0.264  0.578  1.0
  Mn  Mn1  1  0.974  0.768  0.921  1.0
  Mn  Mn2  1  0.003  0.772  0.428  1.0
  Mn  Mn3  1  0.943  0.273  0.072  1.0
  Mn  Mn4  1  0.502  0.770  0.175  1.0
  Mn  Mn5  1  0.479  0.210  0.823  1.0
  Mn  Mn6  1  0.491  0.713  0.674  1.0
  Mn  Mn7  1  0.525  0.226  0.327  1.0
  O  O8  1  0.750  0.077  0.934  1.0
  O  O9  1  0.788  0.586  0.558  1.0
  O  O10  1  0.803  0.092  0.449  1.0
  O  O11  1  0.752  0.602  0.058  1.0
  O  O12  1  0.729  0.085  0.192  1.0
  O  O13  1  0.269  0.889  0.807  1.0
  O  O14  1  0.279  0.394  0.692  1.0
  O  O15  1  0.293  0.924  0.311  1.0
  F  F16  1  0.728  0.527  0.811  1.0
  F  F17  1  0.742  0.026  0.690  1.0
  F  F18  1  0.748  0.552  0.309  1.0
  F  F19  1  0.269  0.450  0.189  1.0
  F  F20  1  0.209  0.439  0.948  1.0
  F  F21  1  0.254  0.948  0.559  1.0
  F  F22  1  0.259  0.443  0.433  1.0
  F  F23  1  0.209  0.970  0.061  1.0
[/CIF]
.
The compound described by MnOF is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(7), one F(2), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the second Mn site, Mn(2) is bonded to one O(1), one O(4), one O(6), one F(1), one F(5), and one F(8) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 41-61°. In the third Mn site, Mn(3) is bonded to one O(2), one O(3), one O(8), one F(3), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 40-61°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(4), one O(5), one F(4), one F(5), and one F(8) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. In the fifth Mn site, Mn(5) is bonded to one O(4), one O(5), one O(8), one F(3), one F(4), and one F(8) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(6), one O(7), one F(1), one F(2), and one F(5) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 41-62°. In the seventh Mn site, Mn(7) is bonded to one O(2), one O(6), one O(7), one F(1), one F(2), and one F(6) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. In the eighth Mn site, Mn(8) is bonded to one O(3), one O(5), one O(8), one F(3), one F(4), and one F(7) atom to form a mixture of distorted edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 40-59°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. is represented by the CIF file [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.623
_cell_length_b   5.124
_cell_length_c   11.540
_cell_angle_alpha   89.614
_cell_angle_beta   87.253
_cell_angle_gamma   89.880
_symmetry_Int_Tables_number   1
_cell_volume   273.037
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.002  0.264  0.578  1.0
  Mn  Mn1  1  0.974  0.768  0.921  1.0
  Mn  Mn2  1  0.003  0.772  0.428  1.0
  Mn  Mn3  1  0.943  0.273  0.072  1.0
  Mn  Mn4  1  0.502  0.770  0.175  1.0
  Mn  Mn5  1  0.479  0.210  0.823  1.0
  Mn  Mn6  1  0.491  0.713  0.674  1.0
  Mn  Mn7  1  0.525  0.226  0.327  1.0
  O  O8  1  0.750  0.077  0.934  1.0
  O  O9  1  0.788  0.586  0.558  1.0
  O  O10  1  0.803  0.092  0.449  1.0
  O  O11  1  0.752  0.602  0.058  1.0
  O  O12  1  0.729  0.085  0.192  1.0
  O  O13  1  0.269  0.889  0.807  1.0
  O  O14  1  0.279  0.394  0.692  1.0
  O  O15  1  0.293  0.924  0.311  1.0
  F  F16  1  0.728  0.527  0.811  1.0
  F  F17  1  0.742  0.026  0.690  1.0
  F  F18  1  0.748  0.552  0.309  1.0
  F  F19  1  0.269  0.450  0.189  1.0
  F  F20  1  0.209  0.439  0.948  1.0
  F  F21  1  0.254  0.948  0.559  1.0
  F  F22  1  0.259  0.443  0.433  1.0
  F  F23  1  0.209  0.970  0.061  1.0
[/CIF]
.