The structure described by MgV2(Ag3O4)2 crystallizes in the triclinic P-1 space group. Mg(1) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a distorted water-like geometry to one O(1) and one O(2) atom. In the third Ag site, Ag(3) is bonded in a linear geometry to two equivalent O(1) atoms. In the fourth Ag site, Ag(4) is bonded in a linear geometry to two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one Ag(1), one Ag(2), and one Ag(3) atom to form distorted corner-sharing OVAg3 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Mg(1), one V(1), one Ag(1), and one Ag(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Ag(1) atoms. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Ag(4) atom. is represented by the CIF card [CIF]
data_MgV2(Ag3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.878
_cell_length_b   5.587
_cell_length_c   9.794
_cell_angle_alpha   83.198
_cell_angle_beta   87.221
_cell_angle_gamma   60.359
_symmetry_Int_Tables_number   1
_cell_volume   277.569
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.531  0.708  0.226  1.0
  V  V2  1  0.469  0.292  0.774  1.0
  Ag  Ag3  1  0.299  0.391  0.106  1.0
  Ag  Ag4  1  0.032  0.955  0.634  1.0
  Ag  Ag5  1  0.701  0.609  0.894  1.0
  Ag  Ag6  1  0.968  0.045  0.366  1.0
  Ag  Ag7  1  0.000  0.000  0.000  1.0
  Ag  Ag8  1  0.000  0.500  0.500  1.0
  O  O9  1  0.778  0.005  0.831  1.0
  O  O10  1  0.502  0.588  0.713  1.0
  O  O11  1  0.222  0.995  0.169  1.0
  O  O12  1  0.498  0.412  0.287  1.0
  O  O13  1  0.776  0.646  0.108  1.0
  O  O14  1  0.224  0.354  0.892  1.0
  O  O15  1  0.616  0.755  0.386  1.0
  O  O16  1  0.384  0.245  0.614  1.0
[/CIF]
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The structure described by MgV2(Ag3O4)2 crystallizes in the triclinic P-1 space group. Mg(1) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a distorted water-like geometry to one O(1) and one O(2) atom. In the third Ag site, Ag(3) is bonded in a linear geometry to two equivalent O(1) atoms. In the fourth Ag site, Ag(4) is bonded in a linear geometry to two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one Ag(1), one Ag(2), and one Ag(3) atom to form distorted corner-sharing OVAg3 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Mg(1), one V(1), one Ag(1), and one Ag(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Ag(1) atoms. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Ag(4) atom. is represented by the CIF card [CIF]
data_MgV2(Ag3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.878
_cell_length_b   5.587
_cell_length_c   9.794
_cell_angle_alpha   83.198
_cell_angle_beta   87.221
_cell_angle_gamma   60.359
_symmetry_Int_Tables_number   1
_cell_volume   277.569
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.531  0.708  0.226  1.0
  V  V2  1  0.469  0.292  0.774  1.0
  Ag  Ag3  1  0.299  0.391  0.106  1.0
  Ag  Ag4  1  0.032  0.955  0.634  1.0
  Ag  Ag5  1  0.701  0.609  0.894  1.0
  Ag  Ag6  1  0.968  0.045  0.366  1.0
  Ag  Ag7  1  0.000  0.000  0.000  1.0
  Ag  Ag8  1  0.000  0.500  0.500  1.0
  O  O9  1  0.778  0.005  0.831  1.0
  O  O10  1  0.502  0.588  0.713  1.0
  O  O11  1  0.222  0.995  0.169  1.0
  O  O12  1  0.498  0.412  0.287  1.0
  O  O13  1  0.776  0.646  0.108  1.0
  O  O14  1  0.224  0.354  0.892  1.0
  O  O15  1  0.616  0.755  0.386  1.0
  O  O16  1  0.384  0.245  0.614  1.0
[/CIF]
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