The compound described by U(NO6)2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two U(NO6)2 clusters. In each U(NO6)2 cluster, U(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a water-like geometry to one O(4) and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one U(1) and one O(6) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one U(1) and one O(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one N(1) and one O(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_U(N2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.993
_cell_length_b   10.194
_cell_length_c   11.972
_cell_angle_alpha   90.000
_cell_angle_beta   70.669
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   805.358
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.500  0.500  1.0
  U  U1  1  0.000  0.000  0.000  1.0
  N  N2  1  0.245  0.102  0.708  1.0
  N  N3  1  0.755  0.602  0.792  1.0
  N  N4  1  0.755  0.898  0.292  1.0
  N  N5  1  0.245  0.398  0.208  1.0
  N  N6  1  0.613  0.156  0.420  1.0
  N  N7  1  0.387  0.656  0.080  1.0
  N  N8  1  0.387  0.844  0.580  1.0
  N  N9  1  0.613  0.344  0.920  1.0
  O  O10  1  0.181  0.512  0.578  1.0
  O  O11  1  0.819  0.012  0.922  1.0
  O  O12  1  0.819  0.488  0.422  1.0
  O  O13  1  0.181  0.988  0.078  1.0
  O  O14  1  0.861  0.321  0.652  1.0
  O  O15  1  0.139  0.821  0.848  1.0
  O  O16  1  0.139  0.679  0.348  1.0
  O  O17  1  0.861  0.179  0.152  1.0
  O  O18  1  0.168  0.325  0.402  1.0
  O  O19  1  0.832  0.825  0.098  1.0
  O  O20  1  0.832  0.675  0.598  1.0
  O  O21  1  0.168  0.175  0.902  1.0
  O  O22  1  0.240  0.128  0.612  1.0
  O  O23  1  0.760  0.628  0.888  1.0
  O  O24  1  0.760  0.872  0.388  1.0
  O  O25  1  0.240  0.372  0.112  1.0
  O  O26  1  0.160  0.288  0.291  1.0
  O  O27  1  0.840  0.788  0.209  1.0
  O  O28  1  0.840  0.712  0.709  1.0
  O  O29  1  0.160  0.212  0.791  1.0
  O  O30  1  0.785  0.220  0.620  1.0
  O  O31  1  0.215  0.720  0.880  1.0
  O  O32  1  0.215  0.780  0.380  1.0
  O  O33  1  0.785  0.280  0.120  1.0
  O  O34  1  0.641  0.247  0.467  1.0
  O  O35  1  0.359  0.747  0.033  1.0
  O  O36  1  0.359  0.753  0.533  1.0
  O  O37  1  0.641  0.253  0.967  1.0
[/CIF]
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The compound described by U(NO6)2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two U(NO6)2 clusters. In each U(NO6)2 cluster, U(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a water-like geometry to one O(4) and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one U(1) and one O(6) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one U(1) and one O(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one N(1) and one O(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_U(N2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.993
_cell_length_b   10.194
_cell_length_c   11.972
_cell_angle_alpha   90.000
_cell_angle_beta   70.669
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   805.358
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.500  0.500  1.0
  U  U1  1  0.000  0.000  0.000  1.0
  N  N2  1  0.245  0.102  0.708  1.0
  N  N3  1  0.755  0.602  0.792  1.0
  N  N4  1  0.755  0.898  0.292  1.0
  N  N5  1  0.245  0.398  0.208  1.0
  N  N6  1  0.613  0.156  0.420  1.0
  N  N7  1  0.387  0.656  0.080  1.0
  N  N8  1  0.387  0.844  0.580  1.0
  N  N9  1  0.613  0.344  0.920  1.0
  O  O10  1  0.181  0.512  0.578  1.0
  O  O11  1  0.819  0.012  0.922  1.0
  O  O12  1  0.819  0.488  0.422  1.0
  O  O13  1  0.181  0.988  0.078  1.0
  O  O14  1  0.861  0.321  0.652  1.0
  O  O15  1  0.139  0.821  0.848  1.0
  O  O16  1  0.139  0.679  0.348  1.0
  O  O17  1  0.861  0.179  0.152  1.0
  O  O18  1  0.168  0.325  0.402  1.0
  O  O19  1  0.832  0.825  0.098  1.0
  O  O20  1  0.832  0.675  0.598  1.0
  O  O21  1  0.168  0.175  0.902  1.0
  O  O22  1  0.240  0.128  0.612  1.0
  O  O23  1  0.760  0.628  0.888  1.0
  O  O24  1  0.760  0.872  0.388  1.0
  O  O25  1  0.240  0.372  0.112  1.0
  O  O26  1  0.160  0.288  0.291  1.0
  O  O27  1  0.840  0.788  0.209  1.0
  O  O28  1  0.840  0.712  0.709  1.0
  O  O29  1  0.160  0.212  0.791  1.0
  O  O30  1  0.785  0.220  0.620  1.0
  O  O31  1  0.215  0.720  0.880  1.0
  O  O32  1  0.215  0.780  0.380  1.0
  O  O33  1  0.785  0.280  0.120  1.0
  O  O34  1  0.641  0.247  0.467  1.0
  O  O35  1  0.359  0.747  0.033  1.0
  O  O36  1  0.359  0.753  0.533  1.0
  O  O37  1  0.641  0.253  0.967  1.0
[/CIF]
.