The structure described by Rh(N2O3)3 is Indium-like structured and crystallizes in the trigonal P31m space group. The structure is zero-dimensional and consists of one nsc241243 molecule. Rh(1) is bonded in a distorted octahedral geometry to three equivalent N(2) and three equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_Rh(N2O3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.395
_cell_length_b   7.395
_cell_length_c   4.970
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   235.409
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.000  0.000  0.548  1.0
  N  N1  1  0.617  0.617  0.278  1.0
  N  N2  1  0.000  0.383  0.278  1.0
  N  N3  1  0.383  0.000  0.278  1.0
  N  N4  1  0.000  0.785  0.727  1.0
  N  N5  1  0.785  0.000  0.727  1.0
  N  N6  1  0.215  0.215  0.727  1.0
  O  O7  1  0.794  0.794  0.226  1.0
  O  O8  1  0.000  0.206  0.226  1.0
  O  O9  1  0.206  0.000  0.226  1.0
  O  O10  1  0.567  0.567  0.518  1.0
  O  O11  1  0.000  0.433  0.518  1.0
  O  O12  1  0.433  0.000  0.518  1.0
  O  O13  1  0.516  0.516  0.081  1.0
  O  O14  1  0.000  0.484  0.081  1.0
  O  O15  1  0.484  0.000  0.081  1.0
[/CIF]
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The structure described by Rh(N2O3)3 is Indium-like structured and crystallizes in the trigonal P31m space group. The structure is zero-dimensional and consists of one nsc241243 molecule. Rh(1) is bonded in a distorted octahedral geometry to three equivalent N(2) and three equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_Rh(N2O3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.395
_cell_length_b   7.395
_cell_length_c   4.970
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   235.409
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.000  0.000  0.548  1.0
  N  N1  1  0.617  0.617  0.278  1.0
  N  N2  1  0.000  0.383  0.278  1.0
  N  N3  1  0.383  0.000  0.278  1.0
  N  N4  1  0.000  0.785  0.727  1.0
  N  N5  1  0.785  0.000  0.727  1.0
  N  N6  1  0.215  0.215  0.727  1.0
  O  O7  1  0.794  0.794  0.226  1.0
  O  O8  1  0.000  0.206  0.226  1.0
  O  O9  1  0.206  0.000  0.226  1.0
  O  O10  1  0.567  0.567  0.518  1.0
  O  O11  1  0.000  0.433  0.518  1.0
  O  O12  1  0.433  0.000  0.518  1.0
  O  O13  1  0.516  0.516  0.081  1.0
  O  O14  1  0.000  0.484  0.081  1.0
  O  O15  1  0.484  0.000  0.081  1.0
[/CIF]
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