The crystal structure described by CsAuS crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 7-coordinate geometry to two equivalent Au(1) and five equivalent S(1) atoms. Au(1) is bonded in a 4-coordinate geometry to two equivalent Cs(1) and two equivalent S(1) atoms. S(1) is bonded to five equivalent Cs(1) and two equivalent Au(1) atoms to form a mixture of distorted corner and edge-sharing SCs5Au2 pentagonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsAuS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.543
_cell_length_b   5.543
_cell_length_c   6.782
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   100.815
_symmetry_Int_Tables_number   1
_cell_volume   204.704
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.627  0.373  0.750  1.0
  Cs  Cs1  1  0.373  0.627  0.250  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Au  Au3  1  0.000  0.000  0.500  1.0
  S  S4  1  0.185  0.815  0.750  1.0
  S  S5  1  0.815  0.185  0.250  1.0
[/CIF]
.
The crystal structure described by CsAuS crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 7-coordinate geometry to two equivalent Au(1) and five equivalent S(1) atoms. Au(1) is bonded in a 4-coordinate geometry to two equivalent Cs(1) and two equivalent S(1) atoms. S(1) is bonded to five equivalent Cs(1) and two equivalent Au(1) atoms to form a mixture of distorted corner and edge-sharing SCs5Au2 pentagonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsAuS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.543
_cell_length_b   5.543
_cell_length_c   6.782
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   100.815
_symmetry_Int_Tables_number   1
_cell_volume   204.704
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.627  0.373  0.750  1.0
  Cs  Cs1  1  0.373  0.627  0.250  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Au  Au3  1  0.000  0.000  0.500  1.0
  S  S4  1  0.185  0.815  0.750  1.0
  S  S5  1  0.815  0.185  0.250  1.0
[/CIF]
.