The compound described by CePd2In4 crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), one In(2), three equivalent In(1), three equivalent In(3), and three equivalent In(4) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(3), three equivalent In(2), and three equivalent In(4) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(2), three equivalent In(1), and three equivalent In(3) atoms. There are four inequivalent In sites. In the first In site, In(1) is bonded in a 3-coordinate geometry to three equivalent Ce(1) and three equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to one Ce(1), one Pd(2), and three equivalent Pd(1) atoms. In the third In site, In(3) is bonded in a 4-coordinate geometry to three equivalent Ce(1), one Pd(1), and three equivalent Pd(2) atoms. In the fourth In site, In(4) is bonded in a 3-coordinate geometry to three equivalent Ce(1) and three equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_Ce(In2Pd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.529
_cell_length_b   7.326
_cell_length_c   18.334
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   608.314
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.540  0.858  1.0
  Ce  Ce1  1  0.750  0.040  0.642  1.0
  Ce  Ce2  1  0.750  0.460  0.142  1.0
  Ce  Ce3  1  0.250  0.960  0.358  1.0
  In  In4  1  0.750  0.254  0.309  1.0
  In  In5  1  0.750  0.512  0.571  1.0
  In  In6  1  0.750  0.655  0.314  1.0
  In  In7  1  0.250  0.012  0.929  1.0
  In  In8  1  0.750  0.354  0.967  1.0
  In  In9  1  0.250  0.754  0.191  1.0
  In  In10  1  0.250  0.646  0.033  1.0
  In  In11  1  0.250  0.854  0.533  1.0
  In  In12  1  0.750  0.246  0.809  1.0
  In  In13  1  0.250  0.488  0.429  1.0
  In  In14  1  0.250  0.155  0.186  1.0
  In  In15  1  0.750  0.845  0.814  1.0
  In  In16  1  0.250  0.746  0.691  1.0
  In  In17  1  0.750  0.988  0.071  1.0
  In  In18  1  0.250  0.345  0.686  1.0
  In  In19  1  0.750  0.146  0.467  1.0
  Pd  Pd20  1  0.250  0.239  0.543  1.0
  Pd  Pd21  1  0.750  0.549  0.722  1.0
  Pd  Pd22  1  0.750  0.761  0.457  1.0
  Pd  Pd23  1  0.250  0.261  0.043  1.0
  Pd  Pd24  1  0.750  0.739  0.957  1.0
  Pd  Pd25  1  0.250  0.451  0.278  1.0
  Pd  Pd26  1  0.750  0.951  0.222  1.0
  Pd  Pd27  1  0.250  0.049  0.778  1.0
[/CIF]
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The compound described by CePd2In4 crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), one In(2), three equivalent In(1), three equivalent In(3), and three equivalent In(4) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(3), three equivalent In(2), and three equivalent In(4) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(2), three equivalent In(1), and three equivalent In(3) atoms. There are four inequivalent In sites. In the first In site, In(1) is bonded in a 3-coordinate geometry to three equivalent Ce(1) and three equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to one Ce(1), one Pd(2), and three equivalent Pd(1) atoms. In the third In site, In(3) is bonded in a 4-coordinate geometry to three equivalent Ce(1), one Pd(1), and three equivalent Pd(2) atoms. In the fourth In site, In(4) is bonded in a 3-coordinate geometry to three equivalent Ce(1) and three equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_Ce(In2Pd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.529
_cell_length_b   7.326
_cell_length_c   18.334
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   608.314
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.540  0.858  1.0
  Ce  Ce1  1  0.750  0.040  0.642  1.0
  Ce  Ce2  1  0.750  0.460  0.142  1.0
  Ce  Ce3  1  0.250  0.960  0.358  1.0
  In  In4  1  0.750  0.254  0.309  1.0
  In  In5  1  0.750  0.512  0.571  1.0
  In  In6  1  0.750  0.655  0.314  1.0
  In  In7  1  0.250  0.012  0.929  1.0
  In  In8  1  0.750  0.354  0.967  1.0
  In  In9  1  0.250  0.754  0.191  1.0
  In  In10  1  0.250  0.646  0.033  1.0
  In  In11  1  0.250  0.854  0.533  1.0
  In  In12  1  0.750  0.246  0.809  1.0
  In  In13  1  0.250  0.488  0.429  1.0
  In  In14  1  0.250  0.155  0.186  1.0
  In  In15  1  0.750  0.845  0.814  1.0
  In  In16  1  0.250  0.746  0.691  1.0
  In  In17  1  0.750  0.988  0.071  1.0
  In  In18  1  0.250  0.345  0.686  1.0
  In  In19  1  0.750  0.146  0.467  1.0
  Pd  Pd20  1  0.250  0.239  0.543  1.0
  Pd  Pd21  1  0.750  0.549  0.722  1.0
  Pd  Pd22  1  0.750  0.761  0.457  1.0
  Pd  Pd23  1  0.250  0.261  0.043  1.0
  Pd  Pd24  1  0.750  0.739  0.957  1.0
  Pd  Pd25  1  0.250  0.451  0.278  1.0
  Pd  Pd26  1  0.750  0.951  0.222  1.0
  Pd  Pd27  1  0.250  0.049  0.778  1.0
[/CIF]
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