The material described by YCo(WO4)2 crystallizes in the triclinic P1 space group. Y(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom to form YO6 octahedra that share corners with four equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the second W site, W(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. Co(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Y(1), one W(1), and one Co(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Co(1) atom. In the fourth O site, O(4) is bonded to one Y(1), one W(1), one W(2), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OYCoW2 trigonal pyramids. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Y(1), one W(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Co(1) atom. In the eighth O site, O(8) is bonded to one Y(1), one W(1), one W(2), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OYCoW2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_YCo(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.092
_cell_length_b   6.066
_cell_length_c   6.206
_cell_angle_alpha   108.522
_cell_angle_beta   117.187
_cell_angle_gamma   89.850
_symmetry_Int_Tables_number   1
_cell_volume   159.366
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.624  0.722  0.099  1.0
  Co  Co1  1  0.135  0.229  0.106  1.0
  W  W2  1  0.863  0.388  0.580  1.0
  W  W3  1  0.385  0.057  0.618  1.0
  O  O4  1  0.130  0.655  0.826  1.0
  O  O5  1  0.598  0.498  0.332  1.0
  O  O6  1  0.164  0.191  0.797  1.0
  O  O7  1  0.573  0.054  0.394  1.0
  O  O8  1  0.648  0.946  0.865  1.0
  O  O9  1  0.117  0.791  0.372  1.0
  O  O10  1  0.084  0.256  0.402  1.0
  O  O11  1  0.675  0.391  0.804  1.0
[/CIF]
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The material described by YCo(WO4)2 crystallizes in the triclinic P1 space group. Y(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom to form YO6 octahedra that share corners with four equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the second W site, W(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. Co(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Y(1), one W(1), and one Co(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Co(1) atom. In the fourth O site, O(4) is bonded to one Y(1), one W(1), one W(2), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OYCoW2 trigonal pyramids. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Y(1), one W(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Co(1) atom. In the eighth O site, O(8) is bonded to one Y(1), one W(1), one W(2), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OYCoW2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_YCo(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.092
_cell_length_b   6.066
_cell_length_c   6.206
_cell_angle_alpha   108.522
_cell_angle_beta   117.187
_cell_angle_gamma   89.850
_symmetry_Int_Tables_number   1
_cell_volume   159.366
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.624  0.722  0.099  1.0
  Co  Co1  1  0.135  0.229  0.106  1.0
  W  W2  1  0.863  0.388  0.580  1.0
  W  W3  1  0.385  0.057  0.618  1.0
  O  O4  1  0.130  0.655  0.826  1.0
  O  O5  1  0.598  0.498  0.332  1.0
  O  O6  1  0.164  0.191  0.797  1.0
  O  O7  1  0.573  0.054  0.394  1.0
  O  O8  1  0.648  0.946  0.865  1.0
  O  O9  1  0.117  0.791  0.372  1.0
  O  O10  1  0.084  0.256  0.402  1.0
  O  O11  1  0.675  0.391  0.804  1.0
[/CIF]
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