The structure described by ZnBiF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedral tilt angles are 30°. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 30°. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnBiF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.750
_cell_length_b   5.750
_cell_length_c   5.750
_cell_angle_alpha   57.580
_cell_angle_beta   57.580
_cell_angle_gamma   57.580
_symmetry_Int_Tables_number   1
_cell_volume   126.958
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Bi  Bi1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.641  0.837  0.261  1.0
  F  F3  1  0.837  0.261  0.641  1.0
  F  F4  1  0.739  0.359  0.163  1.0
  F  F5  1  0.163  0.739  0.359  1.0
  F  F6  1  0.359  0.163  0.739  1.0
  F  F7  1  0.261  0.641  0.837  1.0
[/CIF]
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The structure described by ZnBiF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedral tilt angles are 30°. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 30°. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnBiF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.750
_cell_length_b   5.750
_cell_length_c   5.750
_cell_angle_alpha   57.580
_cell_angle_beta   57.580
_cell_angle_gamma   57.580
_symmetry_Int_Tables_number   1
_cell_volume   126.958
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Bi  Bi1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.641  0.837  0.261  1.0
  F  F3  1  0.837  0.261  0.641  1.0
  F  F4  1  0.739  0.359  0.163  1.0
  F  F5  1  0.163  0.739  0.359  1.0
  F  F6  1  0.359  0.163  0.739  1.0
  F  F7  1  0.261  0.641  0.837  1.0
[/CIF]
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