The material structure described by LiSrEu(CoO3)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(4), two equivalent O(2), and two equivalent O(6) atoms. Sr(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(5), and four equivalent O(4) atoms. Eu(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(5), two equivalent O(6), and four equivalent O(3) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and  a cornercorner with one Co(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 9-17°. In the second Co site, Co(2) is bonded to one O(3), two equivalent O(2), and two equivalent O(6) atoms to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(1)O6 octahedra and corners with four equivalent Co(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Eu(1), and two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Li(1), one Sr(1), and two equivalent Co(2) atoms. In the third O site, O(3) is bonded to four equivalent Eu(1), one Co(1), and one Co(2) atom to form distorted OEu4Co2 octahedra that share  a cornercorner with one O(4)Sr4LiCo octahedra, corners with four equivalent O(3)Eu4Co2 octahedra, corners with four equivalent O(5)Sr2Eu2Co2 octahedra, edges with four equivalent O(3)Eu4Co2 octahedra, and faces with two equivalent O(5)Sr2Eu2Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-57°. In the fourth O site, O(4) is bonded to one Li(1), four equivalent Sr(1), and one Co(1) atom to form distorted OSr4LiCo octahedra that share  a cornercorner with one O(3)Eu4Co2 octahedra, corners with four equivalent O(5)Sr2Eu2Co2 octahedra, corners with four equivalent O(4)Sr4LiCo octahedra, edges with four equivalent O(4)Sr4LiCo octahedra, and faces with two equivalent O(5)Sr2Eu2Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-59°. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Eu(1), and two equivalent Co(1) atoms to form OSr2Eu2Co2 octahedra that share corners with two equivalent O(5)Sr2Eu2Co2 octahedra, corners with four equivalent O(3)Eu4Co2 octahedra, corners with four equivalent O(4)Sr4LiCo octahedra, edges with two equivalent O(5)Sr2Eu2Co2 octahedra, faces with two equivalent O(3)Eu4Co2 octahedra, and faces with two equivalent O(4)Sr4LiCo octahedra. The corner-sharing octahedral tilt angles range from 9-59°. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Li(1), two equivalent Eu(1), and two equivalent Co(2) atoms. is represented by the CIF card [CIF]
data_SrLiEu(CoO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.648
_cell_length_b   3.962
_cell_length_c   9.450
_cell_angle_alpha   78.029
_cell_angle_beta   98.013
_cell_angle_gamma   89.918
_symmetry_Int_Tables_number   1
_cell_volume   132.241
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.103  0.829  0.436  1.0
  Li  Li1  1  0.789  0.212  0.672  1.0
  Eu  Eu2  1  0.965  0.031  0.040  1.0
  Co  Co3  1  0.543  0.427  0.245  1.0
  Co  Co4  1  0.377  0.644  0.809  1.0
  O  O5  1  0.034  0.436  0.217  1.0
  O  O6  1  0.907  0.695  0.705  1.0
  O  O7  1  0.468  0.543  0.013  1.0
  O  O8  1  0.617  0.323  0.454  1.0
  O  O9  1  0.536  0.935  0.229  1.0
  O  O10  1  0.448  0.139  0.820  1.0
[/CIF]
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The material structure described by LiSrEu(CoO3)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(4), two equivalent O(2), and two equivalent O(6) atoms. Sr(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(5), and four equivalent O(4) atoms. Eu(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(5), two equivalent O(6), and four equivalent O(3) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and  a cornercorner with one Co(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 9-17°. In the second Co site, Co(2) is bonded to one O(3), two equivalent O(2), and two equivalent O(6) atoms to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(1)O6 octahedra and corners with four equivalent Co(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Eu(1), and two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Li(1), one Sr(1), and two equivalent Co(2) atoms. In the third O site, O(3) is bonded to four equivalent Eu(1), one Co(1), and one Co(2) atom to form distorted OEu4Co2 octahedra that share  a cornercorner with one O(4)Sr4LiCo octahedra, corners with four equivalent O(3)Eu4Co2 octahedra, corners with four equivalent O(5)Sr2Eu2Co2 octahedra, edges with four equivalent O(3)Eu4Co2 octahedra, and faces with two equivalent O(5)Sr2Eu2Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-57°. In the fourth O site, O(4) is bonded to one Li(1), four equivalent Sr(1), and one Co(1) atom to form distorted OSr4LiCo octahedra that share  a cornercorner with one O(3)Eu4Co2 octahedra, corners with four equivalent O(5)Sr2Eu2Co2 octahedra, corners with four equivalent O(4)Sr4LiCo octahedra, edges with four equivalent O(4)Sr4LiCo octahedra, and faces with two equivalent O(5)Sr2Eu2Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-59°. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Eu(1), and two equivalent Co(1) atoms to form OSr2Eu2Co2 octahedra that share corners with two equivalent O(5)Sr2Eu2Co2 octahedra, corners with four equivalent O(3)Eu4Co2 octahedra, corners with four equivalent O(4)Sr4LiCo octahedra, edges with two equivalent O(5)Sr2Eu2Co2 octahedra, faces with two equivalent O(3)Eu4Co2 octahedra, and faces with two equivalent O(4)Sr4LiCo octahedra. The corner-sharing octahedral tilt angles range from 9-59°. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Li(1), two equivalent Eu(1), and two equivalent Co(2) atoms. is represented by the CIF card [CIF]
data_SrLiEu(CoO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.648
_cell_length_b   3.962
_cell_length_c   9.450
_cell_angle_alpha   78.029
_cell_angle_beta   98.013
_cell_angle_gamma   89.918
_symmetry_Int_Tables_number   1
_cell_volume   132.241
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.103  0.829  0.436  1.0
  Li  Li1  1  0.789  0.212  0.672  1.0
  Eu  Eu2  1  0.965  0.031  0.040  1.0
  Co  Co3  1  0.543  0.427  0.245  1.0
  Co  Co4  1  0.377  0.644  0.809  1.0
  O  O5  1  0.034  0.436  0.217  1.0
  O  O6  1  0.907  0.695  0.705  1.0
  O  O7  1  0.468  0.543  0.013  1.0
  O  O8  1  0.617  0.323  0.454  1.0
  O  O9  1  0.536  0.935  0.229  1.0
  O  O10  1  0.448  0.139  0.820  1.0
[/CIF]
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