The material structure described by LiSn(PO3)3 crystallizes in the hexagonal P-6c2 space group. Li(1) is bonded to six equivalent O(2) atoms to form LiO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra and edges with three equivalent Sn(1)O6 octahedra. Sn(1) is bonded to six equivalent O(2) atoms to form distorted SnO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra and edges with three equivalent Li(1)O6 octahedra. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form PO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSn(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.623
_cell_length_b   6.623
_cell_length_c   10.016
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   380.525
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.000  0.000  0.500  1.0
  Sn  Sn2  1  0.667  0.333  0.000  1.0
  Sn  Sn3  1  0.667  0.333  0.500  1.0
  P  P4  1  0.606  0.915  0.750  1.0
  P  P5  1  0.606  0.691  0.250  1.0
  P  P6  1  0.085  0.394  0.250  1.0
  P  P7  1  0.309  0.394  0.750  1.0
  P  P8  1  0.085  0.691  0.750  1.0
  P  P9  1  0.309  0.915  0.250  1.0
  O  O10  1  0.353  0.457  0.250  1.0
  O  O11  1  0.543  0.647  0.750  1.0
  O  O12  1  0.353  0.895  0.750  1.0
  O  O13  1  0.543  0.895  0.250  1.0
  O  O14  1  0.724  0.027  0.620  1.0
  O  O15  1  0.724  0.027  0.880  1.0
  O  O16  1  0.105  0.647  0.250  1.0
  O  O17  1  0.973  0.276  0.380  1.0
  O  O18  1  0.973  0.276  0.120  1.0
  O  O19  1  0.724  0.697  0.120  1.0
  O  O20  1  0.724  0.697  0.380  1.0
  O  O21  1  0.105  0.457  0.750  1.0
  O  O22  1  0.973  0.697  0.880  1.0
  O  O23  1  0.973  0.697  0.620  1.0
  O  O24  1  0.303  0.276  0.620  1.0
  O  O25  1  0.303  0.276  0.880  1.0
  O  O26  1  0.303  0.027  0.380  1.0
  O  O27  1  0.303  0.027  0.120  1.0
[/CIF]
.
The material structure described by LiSn(PO3)3 crystallizes in the hexagonal P-6c2 space group. Li(1) is bonded to six equivalent O(2) atoms to form LiO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra and edges with three equivalent Sn(1)O6 octahedra. Sn(1) is bonded to six equivalent O(2) atoms to form distorted SnO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra and edges with three equivalent Li(1)O6 octahedra. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form PO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSn(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.623
_cell_length_b   6.623
_cell_length_c   10.016
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   380.525
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.000  0.000  0.500  1.0
  Sn  Sn2  1  0.667  0.333  0.000  1.0
  Sn  Sn3  1  0.667  0.333  0.500  1.0
  P  P4  1  0.606  0.915  0.750  1.0
  P  P5  1  0.606  0.691  0.250  1.0
  P  P6  1  0.085  0.394  0.250  1.0
  P  P7  1  0.309  0.394  0.750  1.0
  P  P8  1  0.085  0.691  0.750  1.0
  P  P9  1  0.309  0.915  0.250  1.0
  O  O10  1  0.353  0.457  0.250  1.0
  O  O11  1  0.543  0.647  0.750  1.0
  O  O12  1  0.353  0.895  0.750  1.0
  O  O13  1  0.543  0.895  0.250  1.0
  O  O14  1  0.724  0.027  0.620  1.0
  O  O15  1  0.724  0.027  0.880  1.0
  O  O16  1  0.105  0.647  0.250  1.0
  O  O17  1  0.973  0.276  0.380  1.0
  O  O18  1  0.973  0.276  0.120  1.0
  O  O19  1  0.724  0.697  0.120  1.0
  O  O20  1  0.724  0.697  0.380  1.0
  O  O21  1  0.105  0.457  0.750  1.0
  O  O22  1  0.973  0.697  0.880  1.0
  O  O23  1  0.973  0.697  0.620  1.0
  O  O24  1  0.303  0.276  0.620  1.0
  O  O25  1  0.303  0.276  0.880  1.0
  O  O26  1  0.303  0.027  0.380  1.0
  O  O27  1  0.303  0.027  0.120  1.0
[/CIF]
.