The material described by Sr8Fe7CoO24 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Pm-3m space group. Sr(1) is bonded to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra; faces with six equivalent Sr(1)O12 cuboctahedra;  a faceface with one Fe(3)O6 octahedra;  a faceface with one Co(1)O6 octahedra; faces with three Fe(1,1)O6 octahedra; and faces with three equivalent Fe(2)O6 octahedra. There are four inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Fe site, Fe(2) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Co(1)O6 octahedra; corners with four Fe(1,1)O6 octahedra; and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third Fe site, Fe(3) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six Fe(1,1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the fourth Fe site, Fe(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Co(1) is bonded to six equivalent O(3) atoms to form CoO6 octahedra that share corners with six equivalent Fe(2)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are three inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Sr(1), one Fe(1), and one Fe(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the second O site, O(2) is bonded to four equivalent Sr(1), one Fe(1), and one Fe(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the third O site, O(3) is bonded in a distorted linear geometry to four equivalent Sr(1), one Fe(2), and one Co(1) atom. is represented by the CIF card [CIF]
data_Sr8Fe7CoO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.818
_cell_length_b   7.818
_cell_length_c   7.818
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   477.858
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.251  0.249  0.249  1.0
  Sr  Sr1  1  0.251  0.249  0.751  1.0
  Sr  Sr2  1  0.251  0.751  0.249  1.0
  Sr  Sr3  1  0.251  0.751  0.751  1.0
  Sr  Sr4  1  0.749  0.249  0.249  1.0
  Sr  Sr5  1  0.749  0.249  0.751  1.0
  Sr  Sr6  1  0.749  0.751  0.249  1.0
  Sr  Sr7  1  0.749  0.751  0.751  1.0
  Fe  Fe8  1  0.000  0.000  0.000  1.0
  Fe  Fe9  1  0.000  0.000  0.500  1.0
  Fe  Fe10  1  0.000  0.500  0.000  1.0
  Fe  Fe11  1  0.500  0.000  0.000  1.0
  Fe  Fe12  1  0.500  0.000  0.500  1.0
  Fe  Fe13  1  0.500  0.500  0.000  1.0
  Fe  Fe14  1  0.500  0.500  0.500  1.0
  Co  Co15  1  0.000  0.500  0.500  1.0
  O  O16  1  0.252  0.000  0.000  1.0
  O  O17  1  0.248  0.000  0.500  1.0
  O  O18  1  0.248  0.500  0.000  1.0
  O  O19  1  0.242  0.500  0.500  1.0
  O  O20  1  0.748  0.000  0.000  1.0
  O  O21  1  0.752  0.000  0.500  1.0
  O  O22  1  0.752  0.500  0.000  1.0
  O  O23  1  0.758  0.500  0.500  1.0
  O  O24  1  0.000  0.252  0.000  1.0
  O  O25  1  0.000  0.258  0.500  1.0
  O  O26  1  0.000  0.748  0.000  1.0
  O  O27  1  0.000  0.742  0.500  1.0
  O  O28  1  0.500  0.248  0.000  1.0
  O  O29  1  0.500  0.252  0.500  1.0
  O  O30  1  0.500  0.752  0.000  1.0
  O  O31  1  0.500  0.748  0.500  1.0
  O  O32  1  0.000  0.000  0.252  1.0
  O  O33  1  0.000  0.000  0.748  1.0
  O  O34  1  0.000  0.500  0.258  1.0
  O  O35  1  0.000  0.500  0.742  1.0
  O  O36  1  0.500  0.000  0.248  1.0
  O  O37  1  0.500  0.000  0.752  1.0
  O  O38  1  0.500  0.500  0.252  1.0
  O  O39  1  0.500  0.500  0.748  1.0
[/CIF]
.
The material described by Sr8Fe7CoO24 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Pm-3m space group. Sr(1) is bonded to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra; faces with six equivalent Sr(1)O12 cuboctahedra;  a faceface with one Fe(3)O6 octahedra;  a faceface with one Co(1)O6 octahedra; faces with three Fe(1,1)O6 octahedra; and faces with three equivalent Fe(2)O6 octahedra. There are four inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Fe site, Fe(2) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Co(1)O6 octahedra; corners with four Fe(1,1)O6 octahedra; and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third Fe site, Fe(3) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six Fe(1,1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the fourth Fe site, Fe(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Co(1) is bonded to six equivalent O(3) atoms to form CoO6 octahedra that share corners with six equivalent Fe(2)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are three inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Sr(1), one Fe(1), and one Fe(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the second O site, O(2) is bonded to four equivalent Sr(1), one Fe(1), and one Fe(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the third O site, O(3) is bonded in a distorted linear geometry to four equivalent Sr(1), one Fe(2), and one Co(1) atom. is represented by the CIF card [CIF]
data_Sr8Fe7CoO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.818
_cell_length_b   7.818
_cell_length_c   7.818
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   477.858
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.251  0.249  0.249  1.0
  Sr  Sr1  1  0.251  0.249  0.751  1.0
  Sr  Sr2  1  0.251  0.751  0.249  1.0
  Sr  Sr3  1  0.251  0.751  0.751  1.0
  Sr  Sr4  1  0.749  0.249  0.249  1.0
  Sr  Sr5  1  0.749  0.249  0.751  1.0
  Sr  Sr6  1  0.749  0.751  0.249  1.0
  Sr  Sr7  1  0.749  0.751  0.751  1.0
  Fe  Fe8  1  0.000  0.000  0.000  1.0
  Fe  Fe9  1  0.000  0.000  0.500  1.0
  Fe  Fe10  1  0.000  0.500  0.000  1.0
  Fe  Fe11  1  0.500  0.000  0.000  1.0
  Fe  Fe12  1  0.500  0.000  0.500  1.0
  Fe  Fe13  1  0.500  0.500  0.000  1.0
  Fe  Fe14  1  0.500  0.500  0.500  1.0
  Co  Co15  1  0.000  0.500  0.500  1.0
  O  O16  1  0.252  0.000  0.000  1.0
  O  O17  1  0.248  0.000  0.500  1.0
  O  O18  1  0.248  0.500  0.000  1.0
  O  O19  1  0.242  0.500  0.500  1.0
  O  O20  1  0.748  0.000  0.000  1.0
  O  O21  1  0.752  0.000  0.500  1.0
  O  O22  1  0.752  0.500  0.000  1.0
  O  O23  1  0.758  0.500  0.500  1.0
  O  O24  1  0.000  0.252  0.000  1.0
  O  O25  1  0.000  0.258  0.500  1.0
  O  O26  1  0.000  0.748  0.000  1.0
  O  O27  1  0.000  0.742  0.500  1.0
  O  O28  1  0.500  0.248  0.000  1.0
  O  O29  1  0.500  0.252  0.500  1.0
  O  O30  1  0.500  0.752  0.000  1.0
  O  O31  1  0.500  0.748  0.500  1.0
  O  O32  1  0.000  0.000  0.252  1.0
  O  O33  1  0.000  0.000  0.748  1.0
  O  O34  1  0.000  0.500  0.258  1.0
  O  O35  1  0.000  0.500  0.742  1.0
  O  O36  1  0.500  0.000  0.248  1.0
  O  O37  1  0.500  0.000  0.752  1.0
  O  O38  1  0.500  0.500  0.252  1.0
  O  O39  1  0.500  0.500  0.748  1.0
[/CIF]
.