The material structure described by Pr2Mn4Co13 crystallizes in the trigonal R3m space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 19-coordinate geometry to three equivalent Mn(1), one Co(4), three equivalent Co(2), six equivalent Co(1), and six equivalent Co(3) atoms. In the second Pr site, Pr(2) is bonded in a 19-coordinate geometry to one Mn(2), three equivalent Mn(1), three equivalent Co(3), six equivalent Co(1), and six equivalent Co(2) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 9-coordinate geometry to one Pr(1), one Pr(2), one Mn(2), one Co(4), two equivalent Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. In the second Mn site, Mn(2) is bonded in a 14-coordinate geometry to one Pr(2), three equivalent Mn(1), one Co(4), three equivalent Co(2), and six equivalent Co(1) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to one Pr(1), one Pr(2), one Mn(2), two equivalent Mn(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded to one Pr(1), two equivalent Pr(2), one Mn(2), two equivalent Mn(1), two equivalent Co(3), and four equivalent Co(1) atoms to form distorted CoPr3Mn3Co6 cuboctahedra that share corners with two equivalent Co(2)Pr3Mn3Co6 cuboctahedra, corners with eight equivalent Co(3)Pr3Mn2Co7 cuboctahedra,  an edgeedge with one Co(3)Pr3Mn2Co7 cuboctahedra, edges with four equivalent Co(2)Pr3Mn3Co6 cuboctahedra, faces with three equivalent Co(3)Pr3Mn2Co7 cuboctahedra, and faces with four equivalent Co(2)Pr3Mn3Co6 cuboctahedra. In the third Co site, Co(3) is bonded to one Pr(2), two equivalent Pr(1), two equivalent Mn(1), one Co(4), two equivalent Co(2), and four equivalent Co(1) atoms to form distorted CoPr3Mn2Co7 cuboctahedra that share corners with two equivalent Co(3)Pr3Mn2Co7 cuboctahedra, corners with eight equivalent Co(2)Pr3Mn3Co6 cuboctahedra,  an edgeedge with one Co(2)Pr3Mn3Co6 cuboctahedra, edges with four equivalent Co(3)Pr3Mn2Co7 cuboctahedra, faces with three equivalent Co(2)Pr3Mn3Co6 cuboctahedra, and faces with four equivalent Co(3)Pr3Mn2Co7 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Pr(1), one Mn(2), three equivalent Mn(1), three equivalent Co(3), and six equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr2Mn4Co13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.420
_cell_length_b   6.420
_cell_length_c   6.420
_cell_angle_alpha   82.880
_cell_angle_beta   82.880
_cell_angle_gamma   82.880
_symmetry_Int_Tables_number   1
_cell_volume   258.976
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.659  0.659  0.659  1.0
  Pr  Pr1  1  0.342  0.342  0.342  1.0
  Mn  Mn2  1  0.996  0.996  0.507  1.0
  Mn  Mn3  1  0.996  0.507  0.996  1.0
  Mn  Mn4  1  0.507  0.996  0.996  1.0
  Mn  Mn5  1  0.094  0.094  0.094  1.0
  Co  Co6  1  0.284  0.715  1.000  1.0
  Co  Co7  1  0.715  1.000  0.284  1.0
  Co  Co8  1  1.000  0.284  0.715  1.0
  Co  Co9  1  0.284  1.000  0.715  1.0
  Co  Co10  1  1.000  0.715  0.284  1.0
  Co  Co11  1  0.715  0.284  1.000  1.0
  Co  Co12  1  0.342  0.342  0.843  1.0
  Co  Co13  1  0.342  0.843  0.342  1.0
  Co  Co14  1  0.843  0.342  0.342  1.0
  Co  Co15  1  0.658  0.658  0.161  1.0
  Co  Co16  1  0.658  0.161  0.658  1.0
  Co  Co17  1  0.161  0.658  0.658  1.0
  Co  Co18  1  0.903  0.903  0.903  1.0
[/CIF]
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The material structure described by Pr2Mn4Co13 crystallizes in the trigonal R3m space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 19-coordinate geometry to three equivalent Mn(1), one Co(4), three equivalent Co(2), six equivalent Co(1), and six equivalent Co(3) atoms. In the second Pr site, Pr(2) is bonded in a 19-coordinate geometry to one Mn(2), three equivalent Mn(1), three equivalent Co(3), six equivalent Co(1), and six equivalent Co(2) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 9-coordinate geometry to one Pr(1), one Pr(2), one Mn(2), one Co(4), two equivalent Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. In the second Mn site, Mn(2) is bonded in a 14-coordinate geometry to one Pr(2), three equivalent Mn(1), one Co(4), three equivalent Co(2), and six equivalent Co(1) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to one Pr(1), one Pr(2), one Mn(2), two equivalent Mn(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded to one Pr(1), two equivalent Pr(2), one Mn(2), two equivalent Mn(1), two equivalent Co(3), and four equivalent Co(1) atoms to form distorted CoPr3Mn3Co6 cuboctahedra that share corners with two equivalent Co(2)Pr3Mn3Co6 cuboctahedra, corners with eight equivalent Co(3)Pr3Mn2Co7 cuboctahedra,  an edgeedge with one Co(3)Pr3Mn2Co7 cuboctahedra, edges with four equivalent Co(2)Pr3Mn3Co6 cuboctahedra, faces with three equivalent Co(3)Pr3Mn2Co7 cuboctahedra, and faces with four equivalent Co(2)Pr3Mn3Co6 cuboctahedra. In the third Co site, Co(3) is bonded to one Pr(2), two equivalent Pr(1), two equivalent Mn(1), one Co(4), two equivalent Co(2), and four equivalent Co(1) atoms to form distorted CoPr3Mn2Co7 cuboctahedra that share corners with two equivalent Co(3)Pr3Mn2Co7 cuboctahedra, corners with eight equivalent Co(2)Pr3Mn3Co6 cuboctahedra,  an edgeedge with one Co(2)Pr3Mn3Co6 cuboctahedra, edges with four equivalent Co(3)Pr3Mn2Co7 cuboctahedra, faces with three equivalent Co(2)Pr3Mn3Co6 cuboctahedra, and faces with four equivalent Co(3)Pr3Mn2Co7 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Pr(1), one Mn(2), three equivalent Mn(1), three equivalent Co(3), and six equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr2Mn4Co13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.420
_cell_length_b   6.420
_cell_length_c   6.420
_cell_angle_alpha   82.880
_cell_angle_beta   82.880
_cell_angle_gamma   82.880
_symmetry_Int_Tables_number   1
_cell_volume   258.976
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.659  0.659  0.659  1.0
  Pr  Pr1  1  0.342  0.342  0.342  1.0
  Mn  Mn2  1  0.996  0.996  0.507  1.0
  Mn  Mn3  1  0.996  0.507  0.996  1.0
  Mn  Mn4  1  0.507  0.996  0.996  1.0
  Mn  Mn5  1  0.094  0.094  0.094  1.0
  Co  Co6  1  0.284  0.715  1.000  1.0
  Co  Co7  1  0.715  1.000  0.284  1.0
  Co  Co8  1  1.000  0.284  0.715  1.0
  Co  Co9  1  0.284  1.000  0.715  1.0
  Co  Co10  1  1.000  0.715  0.284  1.0
  Co  Co11  1  0.715  0.284  1.000  1.0
  Co  Co12  1  0.342  0.342  0.843  1.0
  Co  Co13  1  0.342  0.843  0.342  1.0
  Co  Co14  1  0.843  0.342  0.342  1.0
  Co  Co15  1  0.658  0.658  0.161  1.0
  Co  Co16  1  0.658  0.161  0.658  1.0
  Co  Co17  1  0.161  0.658  0.658  1.0
  Co  Co18  1  0.903  0.903  0.903  1.0
[/CIF]
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