The material described by (Sb3O13)2O2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two water atoms inside a Sb3O13 framework. In the Sb3O13 framework, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 39-60°. In the second Sb site, Sb(2) is bonded to one O(3), one O(4), one O(5), one O(8), and two equivalent O(6) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 39-60°. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to two equivalent O(5) atoms. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one Sb(2) and one O(2) atom. In the fifth O site, O(6) is bonded in a trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. In the sixth O site, O(7) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_Sb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.981
_cell_length_b   5.711
_cell_length_c   5.758
_cell_angle_alpha   73.433
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   472.197
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.500  0.000  0.000  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  Sb  Sb2  1  0.419  0.401  0.363  1.0
  Sb  Sb3  1  0.919  0.599  0.637  1.0
  Sb  Sb4  1  0.581  0.599  0.637  1.0
  Sb  Sb5  1  0.081  0.401  0.363  1.0
  O  O6  1  0.250  0.887  0.842  1.0
  O  O7  1  0.750  0.113  0.158  1.0
  O  O8  1  0.250  0.151  0.315  1.0
  O  O9  1  0.750  0.849  0.685  1.0
  O  O10  1  0.499  0.778  0.785  1.0
  O  O11  1  0.999  0.222  0.215  1.0
  O  O12  1  0.501  0.222  0.215  1.0
  O  O13  1  0.001  0.778  0.785  1.0
  O  O14  1  0.651  0.409  0.918  1.0
  O  O15  1  0.151  0.591  0.082  1.0
  O  O16  1  0.349  0.591  0.082  1.0
  O  O17  1  0.849  0.409  0.918  1.0
  O  O18  1  0.675  0.911  0.543  1.0
  O  O19  1  0.175  0.089  0.457  1.0
  O  O20  1  0.325  0.089  0.457  1.0
  O  O21  1  0.825  0.911  0.543  1.0
  O  O22  1  0.492  0.308  0.682  1.0
  O  O23  1  0.992  0.692  0.318  1.0
  O  O24  1  0.508  0.692  0.318  1.0
  O  O25  1  0.008  0.308  0.682  1.0
  O  O26  1  0.631  0.029  0.975  1.0
  O  O27  1  0.131  0.971  0.025  1.0
  O  O28  1  0.369  0.971  0.025  1.0
  O  O29  1  0.869  0.029  0.975  1.0
  O  O30  1  0.326  0.546  0.522  1.0
  O  O31  1  0.826  0.454  0.478  1.0
  O  O32  1  0.674  0.454  0.478  1.0
  O  O33  1  0.174  0.546  0.522  1.0
[/CIF]
.
The material described by (Sb3O13)2O2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two water atoms inside a Sb3O13 framework. In the Sb3O13 framework, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 39-60°. In the second Sb site, Sb(2) is bonded to one O(3), one O(4), one O(5), one O(8), and two equivalent O(6) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 39-60°. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to two equivalent O(5) atoms. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one Sb(2) and one O(2) atom. In the fifth O site, O(6) is bonded in a trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. In the sixth O site, O(7) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_Sb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.981
_cell_length_b   5.711
_cell_length_c   5.758
_cell_angle_alpha   73.433
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   472.197
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.500  0.000  0.000  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  Sb  Sb2  1  0.419  0.401  0.363  1.0
  Sb  Sb3  1  0.919  0.599  0.637  1.0
  Sb  Sb4  1  0.581  0.599  0.637  1.0
  Sb  Sb5  1  0.081  0.401  0.363  1.0
  O  O6  1  0.250  0.887  0.842  1.0
  O  O7  1  0.750  0.113  0.158  1.0
  O  O8  1  0.250  0.151  0.315  1.0
  O  O9  1  0.750  0.849  0.685  1.0
  O  O10  1  0.499  0.778  0.785  1.0
  O  O11  1  0.999  0.222  0.215  1.0
  O  O12  1  0.501  0.222  0.215  1.0
  O  O13  1  0.001  0.778  0.785  1.0
  O  O14  1  0.651  0.409  0.918  1.0
  O  O15  1  0.151  0.591  0.082  1.0
  O  O16  1  0.349  0.591  0.082  1.0
  O  O17  1  0.849  0.409  0.918  1.0
  O  O18  1  0.675  0.911  0.543  1.0
  O  O19  1  0.175  0.089  0.457  1.0
  O  O20  1  0.325  0.089  0.457  1.0
  O  O21  1  0.825  0.911  0.543  1.0
  O  O22  1  0.492  0.308  0.682  1.0
  O  O23  1  0.992  0.692  0.318  1.0
  O  O24  1  0.508  0.692  0.318  1.0
  O  O25  1  0.008  0.308  0.682  1.0
  O  O26  1  0.631  0.029  0.975  1.0
  O  O27  1  0.131  0.971  0.025  1.0
  O  O28  1  0.369  0.971  0.025  1.0
  O  O29  1  0.869  0.029  0.975  1.0
  O  O30  1  0.326  0.546  0.522  1.0
  O  O31  1  0.826  0.454  0.478  1.0
  O  O32  1  0.674  0.454  0.478  1.0
  O  O33  1  0.174  0.546  0.522  1.0
[/CIF]
.