The crystal structure described by Sb2Cl7F3 is Indium-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two Sb2Cl7F3 clusters. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one Cl(4), one Cl(5), one Cl(7), one F(1), one F(2), and one F(3) atom to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles range from 13-14°. In the second Sb site, Sb(2) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(6), one F(1), and one F(3) atom to form corner-sharing SbCl4F2 octahedra. The corner-sharing octahedral tilt angles range from 13-14°. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Sb(1) and one Sb(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a linear geometry to one Sb(1) and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2Cl7F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.090
_cell_length_b   10.090
_cell_length_c   13.169
_cell_angle_alpha   49.610
_cell_angle_beta   49.610
_cell_angle_gamma   44.172
_symmetry_Int_Tables_number   1
_cell_volume   667.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.273  0.158  0.830  1.0
  Sb  Sb1  1  0.842  0.727  0.170  1.0
  Sb  Sb2  1  0.977  0.936  0.261  1.0
  Sb  Sb3  1  0.064  0.023  0.739  1.0
  Cl  Cl4  1  0.048  0.079  0.290  1.0
  Cl  Cl5  1  0.921  0.952  0.710  1.0
  Cl  Cl6  1  0.701  0.232  0.192  1.0
  Cl  Cl7  1  0.768  0.299  0.808  1.0
  Cl  Cl8  1  0.365  0.716  0.740  1.0
  Cl  Cl9  1  0.284  0.635  0.260  1.0
  Cl  Cl10  1  0.330  0.260  0.905  1.0
  Cl  Cl11  1  0.740  0.670  0.095  1.0
  Cl  Cl12  1  0.389  0.312  0.589  1.0
  Cl  Cl13  1  0.688  0.611  0.411  1.0
  Cl  Cl14  1  0.797  0.812  0.492  1.0
  Cl  Cl15  1  0.188  0.203  0.508  1.0
  Cl  Cl16  1  0.557  0.836  0.845  1.0
  Cl  Cl17  1  0.164  0.443  0.155  1.0
  F  F18  1  0.181  0.056  0.805  1.0
  F  F19  1  0.944  0.819  0.195  1.0
  F  F20  1  0.003  0.375  0.850  1.0
  F  F21  1  0.625  0.997  0.150  1.0
  F  F22  1  0.137  0.021  0.039  1.0
  F  F23  1  0.979  0.863  0.961  1.0
[/CIF]
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The crystal structure described by Sb2Cl7F3 is Indium-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two Sb2Cl7F3 clusters. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one Cl(4), one Cl(5), one Cl(7), one F(1), one F(2), and one F(3) atom to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles range from 13-14°. In the second Sb site, Sb(2) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(6), one F(1), and one F(3) atom to form corner-sharing SbCl4F2 octahedra. The corner-sharing octahedral tilt angles range from 13-14°. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Sb(1) and one Sb(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a linear geometry to one Sb(1) and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2Cl7F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.090
_cell_length_b   10.090
_cell_length_c   13.169
_cell_angle_alpha   49.610
_cell_angle_beta   49.610
_cell_angle_gamma   44.172
_symmetry_Int_Tables_number   1
_cell_volume   667.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.273  0.158  0.830  1.0
  Sb  Sb1  1  0.842  0.727  0.170  1.0
  Sb  Sb2  1  0.977  0.936  0.261  1.0
  Sb  Sb3  1  0.064  0.023  0.739  1.0
  Cl  Cl4  1  0.048  0.079  0.290  1.0
  Cl  Cl5  1  0.921  0.952  0.710  1.0
  Cl  Cl6  1  0.701  0.232  0.192  1.0
  Cl  Cl7  1  0.768  0.299  0.808  1.0
  Cl  Cl8  1  0.365  0.716  0.740  1.0
  Cl  Cl9  1  0.284  0.635  0.260  1.0
  Cl  Cl10  1  0.330  0.260  0.905  1.0
  Cl  Cl11  1  0.740  0.670  0.095  1.0
  Cl  Cl12  1  0.389  0.312  0.589  1.0
  Cl  Cl13  1  0.688  0.611  0.411  1.0
  Cl  Cl14  1  0.797  0.812  0.492  1.0
  Cl  Cl15  1  0.188  0.203  0.508  1.0
  Cl  Cl16  1  0.557  0.836  0.845  1.0
  Cl  Cl17  1  0.164  0.443  0.155  1.0
  F  F18  1  0.181  0.056  0.805  1.0
  F  F19  1  0.944  0.819  0.195  1.0
  F  F20  1  0.003  0.375  0.850  1.0
  F  F21  1  0.625  0.997  0.150  1.0
  F  F22  1  0.137  0.021  0.039  1.0
  F  F23  1  0.979  0.863  0.961  1.0
[/CIF]
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