The compound described by RbHTeOF4 crystallizes in the monoclinic Cc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one F(1), one F(4), one F(6), one F(8), two equivalent F(2), and two equivalent F(3) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(1), one F(1), one F(4), one F(8), two equivalent F(5), and two equivalent F(7) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one F(8) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a square pyramidal geometry to one O(2), one F(5), one F(6), one F(7), and one F(8) atom. In the second Te site, Te(2) is bonded in a square pyramidal geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one Rb(2), one H(1), and one Te(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Rb(1), one H(2), and one Te(1) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one H(1), and one Te(2) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one Te(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Te(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one Te(1) atom. In the sixth F site, F(6) is bonded in a bent 120 degrees geometry to one Rb(1) and one Te(1) atom. In the seventh F site, F(7) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one Te(1) atom. In the eighth F site, F(8) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one H(2), and one Te(1) atom. is represented by the CIF file [CIF]
data_RbTeHOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.431
_cell_length_b   8.431
_cell_length_c   14.076
_cell_angle_alpha   85.886
_cell_angle_beta   85.886
_cell_angle_gamma   34.382
_symmetry_Int_Tables_number   1
_cell_volume   563.344
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.168  0.360  0.487  1.0
  Rb  Rb1  1  0.360  0.168  0.987  1.0
  Rb  Rb2  1  0.476  0.640  0.250  1.0
  Rb  Rb3  1  0.640  0.476  0.750  1.0
  Te  Te4  1  0.981  0.023  0.503  1.0
  Te  Te5  1  0.023  0.981  0.003  1.0
  Te  Te6  1  0.802  0.836  0.246  1.0
  Te  Te7  1  0.836  0.802  0.746  1.0
  H  H8  1  0.105  0.350  0.246  1.0
  H  H9  1  0.350  0.105  0.746  1.0
  H  H10  1  0.721  0.465  0.994  1.0
  H  H11  1  0.465  0.721  0.494  1.0
  O  O12  1  0.912  0.527  0.273  1.0
  O  O13  1  0.527  0.912  0.773  1.0
  O  O14  1  0.284  0.918  0.470  1.0
  O  O15  1  0.918  0.284  0.970  1.0
  F  F16  1  0.425  0.035  0.216  1.0
  F  F17  1  0.035  0.425  0.716  1.0
  F  F18  1  0.691  0.913  0.386  1.0
  F  F19  1  0.913  0.691  0.886  1.0
  F  F20  1  0.939  0.692  0.109  1.0
  F  F21  1  0.692  0.939  0.609  1.0
  F  F22  1  0.200  0.560  0.277  1.0
  F  F23  1  0.560  0.200  0.777  1.0
  F  F24  1  0.919  0.103  0.142  1.0
  F  F25  1  0.103  0.919  0.642  1.0
  F  F26  1  0.272  0.612  0.489  1.0
  F  F27  1  0.612  0.272  0.989  1.0
  F  F28  1  0.912  0.108  0.361  1.0
  F  F29  1  0.108  0.912  0.861  1.0
  F  F30  1  0.406  0.775  0.033  1.0
  F  F31  1  0.775  0.406  0.533  1.0
[/CIF]
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The compound described by RbHTeOF4 crystallizes in the monoclinic Cc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one F(1), one F(4), one F(6), one F(8), two equivalent F(2), and two equivalent F(3) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(1), one F(1), one F(4), one F(8), two equivalent F(5), and two equivalent F(7) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one F(8) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a square pyramidal geometry to one O(2), one F(5), one F(6), one F(7), and one F(8) atom. In the second Te site, Te(2) is bonded in a square pyramidal geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one Rb(2), one H(1), and one Te(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Rb(1), one H(2), and one Te(1) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one H(1), and one Te(2) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one Te(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Te(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one Te(1) atom. In the sixth F site, F(6) is bonded in a bent 120 degrees geometry to one Rb(1) and one Te(1) atom. In the seventh F site, F(7) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one Te(1) atom. In the eighth F site, F(8) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one H(2), and one Te(1) atom. is represented by the CIF file [CIF]
data_RbTeHOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.431
_cell_length_b   8.431
_cell_length_c   14.076
_cell_angle_alpha   85.886
_cell_angle_beta   85.886
_cell_angle_gamma   34.382
_symmetry_Int_Tables_number   1
_cell_volume   563.344
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.168  0.360  0.487  1.0
  Rb  Rb1  1  0.360  0.168  0.987  1.0
  Rb  Rb2  1  0.476  0.640  0.250  1.0
  Rb  Rb3  1  0.640  0.476  0.750  1.0
  Te  Te4  1  0.981  0.023  0.503  1.0
  Te  Te5  1  0.023  0.981  0.003  1.0
  Te  Te6  1  0.802  0.836  0.246  1.0
  Te  Te7  1  0.836  0.802  0.746  1.0
  H  H8  1  0.105  0.350  0.246  1.0
  H  H9  1  0.350  0.105  0.746  1.0
  H  H10  1  0.721  0.465  0.994  1.0
  H  H11  1  0.465  0.721  0.494  1.0
  O  O12  1  0.912  0.527  0.273  1.0
  O  O13  1  0.527  0.912  0.773  1.0
  O  O14  1  0.284  0.918  0.470  1.0
  O  O15  1  0.918  0.284  0.970  1.0
  F  F16  1  0.425  0.035  0.216  1.0
  F  F17  1  0.035  0.425  0.716  1.0
  F  F18  1  0.691  0.913  0.386  1.0
  F  F19  1  0.913  0.691  0.886  1.0
  F  F20  1  0.939  0.692  0.109  1.0
  F  F21  1  0.692  0.939  0.609  1.0
  F  F22  1  0.200  0.560  0.277  1.0
  F  F23  1  0.560  0.200  0.777  1.0
  F  F24  1  0.919  0.103  0.142  1.0
  F  F25  1  0.103  0.919  0.642  1.0
  F  F26  1  0.272  0.612  0.489  1.0
  F  F27  1  0.612  0.272  0.989  1.0
  F  F28  1  0.912  0.108  0.361  1.0
  F  F29  1  0.108  0.912  0.861  1.0
  F  F30  1  0.406  0.775  0.033  1.0
  F  F31  1  0.775  0.406  0.533  1.0
[/CIF]
.