The structure described by Te(CF3)2(TeSO3)2 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four 13494-80-9 atoms, eight trifluoromethane molecules, and eight TeSO3 clusters. In four of the TeSO3 clusters, Te(1) is bonded in a 1-coordinate geometry to one O(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Te(1) and one S(1) atom. In four of the TeSO3 clusters, Te(3) is bonded in a distorted single-bond geometry to one O(4) atom. S(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Te(3) and one S(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(6) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF file [CIF]
data_Te3C2S2(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.395
_cell_length_b   8.395
_cell_length_c   11.311
_cell_angle_alpha   75.037
_cell_angle_beta   75.037
_cell_angle_gamma   62.051
_symmetry_Int_Tables_number   1
_cell_volume   671.543
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.294  0.402  0.532  1.0
  Te  Te1  1  0.598  0.706  0.468  1.0
  Te  Te2  1  0.071  0.735  0.612  1.0
  Te  Te3  1  0.265  0.929  0.388  1.0
  Te  Te4  1  0.401  0.524  0.691  1.0
  Te  Te5  1  0.476  0.599  0.309  1.0
  C  C6  1  0.909  0.219  0.811  1.0
  C  C7  1  0.781  0.091  0.189  1.0
  C  C8  1  0.592  0.817  0.920  1.0
  C  C9  1  0.183  0.408  0.080  1.0
  S  S10  1  0.917  0.232  0.642  1.0
  S  S11  1  0.768  0.083  0.358  1.0
  S  S12  1  0.502  0.876  0.772  1.0
  S  S13  1  0.124  0.498  0.228  1.0
  O  O14  1  0.109  0.113  0.599  1.0
  O  O15  1  0.887  0.891  0.401  1.0
  O  O16  1  0.866  0.427  0.592  1.0
  O  O17  1  0.573  0.134  0.408  1.0
  O  O18  1  0.785  0.166  0.643  1.0
  O  O19  1  0.834  0.215  0.357  1.0
  O  O20  1  0.385  0.780  0.799  1.0
  O  O21  1  0.220  0.615  0.201  1.0
  O  O22  1  0.407  0.074  0.755  1.0
  O  O23  1  0.926  0.593  0.245  1.0
  O  O24  1  0.666  0.799  0.680  1.0
  O  O25  1  0.201  0.334  0.320  1.0
  F  F26  1  0.975  0.044  0.868  1.0
  F  F27  1  0.956  0.025  0.132  1.0
  F  F28  1  0.731  0.307  0.864  1.0
  F  F29  1  0.693  0.269  0.136  1.0
  F  F30  1  0.005  0.300  0.830  1.0
  F  F31  1  0.700  0.995  0.170  1.0
  F  F32  1  0.673  0.634  0.956  1.0
  F  F33  1  0.366  0.327  0.044  1.0
  F  F34  1  0.716  0.883  0.906  1.0
  F  F35  1  0.117  0.284  0.094  1.0
  F  F36  1  0.454  0.891  0.012  1.0
  F  F37  1  0.109  0.546  0.988  1.0
[/CIF]
.
The structure described by Te(CF3)2(TeSO3)2 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four 13494-80-9 atoms, eight trifluoromethane molecules, and eight TeSO3 clusters. In four of the TeSO3 clusters, Te(1) is bonded in a 1-coordinate geometry to one O(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Te(1) and one S(1) atom. In four of the TeSO3 clusters, Te(3) is bonded in a distorted single-bond geometry to one O(4) atom. S(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Te(3) and one S(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(6) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF file [CIF]
data_Te3C2S2(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.395
_cell_length_b   8.395
_cell_length_c   11.311
_cell_angle_alpha   75.037
_cell_angle_beta   75.037
_cell_angle_gamma   62.051
_symmetry_Int_Tables_number   1
_cell_volume   671.543
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.294  0.402  0.532  1.0
  Te  Te1  1  0.598  0.706  0.468  1.0
  Te  Te2  1  0.071  0.735  0.612  1.0
  Te  Te3  1  0.265  0.929  0.388  1.0
  Te  Te4  1  0.401  0.524  0.691  1.0
  Te  Te5  1  0.476  0.599  0.309  1.0
  C  C6  1  0.909  0.219  0.811  1.0
  C  C7  1  0.781  0.091  0.189  1.0
  C  C8  1  0.592  0.817  0.920  1.0
  C  C9  1  0.183  0.408  0.080  1.0
  S  S10  1  0.917  0.232  0.642  1.0
  S  S11  1  0.768  0.083  0.358  1.0
  S  S12  1  0.502  0.876  0.772  1.0
  S  S13  1  0.124  0.498  0.228  1.0
  O  O14  1  0.109  0.113  0.599  1.0
  O  O15  1  0.887  0.891  0.401  1.0
  O  O16  1  0.866  0.427  0.592  1.0
  O  O17  1  0.573  0.134  0.408  1.0
  O  O18  1  0.785  0.166  0.643  1.0
  O  O19  1  0.834  0.215  0.357  1.0
  O  O20  1  0.385  0.780  0.799  1.0
  O  O21  1  0.220  0.615  0.201  1.0
  O  O22  1  0.407  0.074  0.755  1.0
  O  O23  1  0.926  0.593  0.245  1.0
  O  O24  1  0.666  0.799  0.680  1.0
  O  O25  1  0.201  0.334  0.320  1.0
  F  F26  1  0.975  0.044  0.868  1.0
  F  F27  1  0.956  0.025  0.132  1.0
  F  F28  1  0.731  0.307  0.864  1.0
  F  F29  1  0.693  0.269  0.136  1.0
  F  F30  1  0.005  0.300  0.830  1.0
  F  F31  1  0.700  0.995  0.170  1.0
  F  F32  1  0.673  0.634  0.956  1.0
  F  F33  1  0.366  0.327  0.044  1.0
  F  F34  1  0.716  0.883  0.906  1.0
  F  F35  1  0.117  0.284  0.094  1.0
  F  F36  1  0.454  0.891  0.012  1.0
  F  F37  1  0.109  0.546  0.988  1.0
[/CIF]
.