The compound described by RbSO2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. S(1) is bonded in a water-like geometry to two equivalent O(1) atoms. O(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one S(1) atom. is represented by the CIF file [CIF]
data_RbSO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.460
_cell_length_b   8.171
_cell_length_c   7.465
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   394.066
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.857  0.358  1.0
  Rb  Rb1  1  0.250  0.143  0.642  1.0
  Rb  Rb2  1  0.250  0.643  0.858  1.0
  Rb  Rb3  1  0.750  0.357  0.142  1.0
  S  S4  1  0.750  0.895  0.849  1.0
  S  S5  1  0.250  0.105  0.151  1.0
  S  S6  1  0.250  0.605  0.349  1.0
  S  S7  1  0.750  0.395  0.651  1.0
  O  O8  1  0.946  0.889  0.734  1.0
  O  O9  1  0.054  0.111  0.266  1.0
  O  O10  1  0.054  0.611  0.234  1.0
  O  O11  1  0.446  0.111  0.266  1.0
  O  O12  1  0.946  0.389  0.766  1.0
  O  O13  1  0.554  0.889  0.734  1.0
  O  O14  1  0.554  0.389  0.766  1.0
  O  O15  1  0.446  0.611  0.234  1.0
[/CIF]
.
The compound described by RbSO2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. S(1) is bonded in a water-like geometry to two equivalent O(1) atoms. O(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one S(1) atom. is represented by the CIF file [CIF]
data_RbSO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.460
_cell_length_b   8.171
_cell_length_c   7.465
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   394.066
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.857  0.358  1.0
  Rb  Rb1  1  0.250  0.143  0.642  1.0
  Rb  Rb2  1  0.250  0.643  0.858  1.0
  Rb  Rb3  1  0.750  0.357  0.142  1.0
  S  S4  1  0.750  0.895  0.849  1.0
  S  S5  1  0.250  0.105  0.151  1.0
  S  S6  1  0.250  0.605  0.349  1.0
  S  S7  1  0.750  0.395  0.651  1.0
  O  O8  1  0.946  0.889  0.734  1.0
  O  O9  1  0.054  0.111  0.266  1.0
  O  O10  1  0.054  0.611  0.234  1.0
  O  O11  1  0.446  0.111  0.266  1.0
  O  O12  1  0.946  0.389  0.766  1.0
  O  O13  1  0.554  0.889  0.734  1.0
  O  O14  1  0.554  0.389  0.766  1.0
  O  O15  1  0.446  0.611  0.234  1.0
[/CIF]
.