The material described by HMn(CO)5 is gamma plutonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight HMn(CO)5 clusters. Mn(1) is bonded in an octahedral geometry to one C(1), one C(2), one C(3), one C(4), one C(5), and one H(1) atom. There are five inequivalent C sites. In the first C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(5) atom. In the second C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the third C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2,4) atom. In the fourth C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(3) atom. In the fifth C site, C(4) is bonded in a linear geometry to one Mn(1) and one O(2,4) atom. H(1) is bonded in a single-bond geometry to one Mn(1) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(2,4) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_MnH(CO)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.460
_cell_length_b   7.049
_cell_length_c   20.014
_cell_angle_alpha   91.464
_cell_angle_beta   90.000
_cell_angle_gamma   117.276
_symmetry_Int_Tables_number   1
_cell_volume   809.670
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.180  0.845  0.875  1.0
  Mn  Mn1  1  0.335  0.155  0.625  1.0
  Mn  Mn2  1  0.820  0.155  0.125  1.0
  Mn  Mn3  1  0.665  0.845  0.375  1.0
  H  H4  1  0.122  0.924  0.807  1.0
  H  H5  1  0.197  0.076  0.693  1.0
  H  H6  1  0.878  0.076  0.193  1.0
  H  H7  1  0.803  0.924  0.307  1.0
  C  C8  1  0.252  0.755  0.953  1.0
  C  C9  1  0.497  0.245  0.547  1.0
  C  C10  1  0.748  0.245  0.047  1.0
  C  C11  1  0.503  0.755  0.453  1.0
  C  C12  1  0.163  0.080  0.912  1.0
  C  C13  1  0.083  0.920  0.588  1.0
  C  C14  1  0.837  0.920  0.088  1.0
  C  C15  1  0.917  0.080  0.412  1.0
  C  C16  1  0.179  0.629  0.819  1.0
  C  C17  1  0.550  0.371  0.681  1.0
  C  C18  1  0.821  0.371  0.181  1.0
  C  C19  1  0.450  0.629  0.319  1.0
  C  C20  1  0.481  0.018  0.849  1.0
  C  C21  1  0.463  0.982  0.651  1.0
  C  C22  1  0.519  0.982  0.151  1.0
  C  C23  1  0.537  0.018  0.349  1.0
  C  C24  1  0.859  0.695  0.880  1.0
  C  C25  1  0.164  0.305  0.620  1.0
  C  C26  1  0.141  0.305  0.120  1.0
  C  C27  1  0.836  0.695  0.380  1.0
  O  O28  1  0.300  0.704  0.003  1.0
  O  O29  1  0.596  0.296  0.497  1.0
  O  O30  1  0.700  0.296  0.997  1.0
  O  O31  1  0.404  0.704  0.503  1.0
  O  O32  1  0.148  0.228  0.932  1.0
  O  O33  1  0.920  0.772  0.568  1.0
  O  O34  1  0.852  0.772  0.068  1.0
  O  O35  1  0.080  0.228  0.432  1.0
  O  O36  1  0.179  0.499  0.783  1.0
  O  O37  1  0.680  0.501  0.717  1.0
  O  O38  1  0.821  0.501  0.217  1.0
  O  O39  1  0.320  0.499  0.283  1.0
  O  O40  1  0.666  0.129  0.829  1.0
  O  O41  1  0.537  0.871  0.671  1.0
  O  O42  1  0.334  0.871  0.171  1.0
  O  O43  1  0.463  0.129  0.329  1.0
  O  O44  1  0.658  0.608  0.881  1.0
  O  O45  1  0.050  0.392  0.619  1.0
  O  O46  1  0.342  0.392  0.119  1.0
  O  O47  1  0.950  0.608  0.381  1.0
[/CIF]
.
The material described by HMn(CO)5 is gamma plutonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight HMn(CO)5 clusters. Mn(1) is bonded in an octahedral geometry to one C(1), one C(2), one C(3), one C(4), one C(5), and one H(1) atom. There are five inequivalent C sites. In the first C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(5) atom. In the second C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the third C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2,4) atom. In the fourth C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(3) atom. In the fifth C site, C(4) is bonded in a linear geometry to one Mn(1) and one O(2,4) atom. H(1) is bonded in a single-bond geometry to one Mn(1) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(2,4) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_MnH(CO)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.460
_cell_length_b   7.049
_cell_length_c   20.014
_cell_angle_alpha   91.464
_cell_angle_beta   90.000
_cell_angle_gamma   117.276
_symmetry_Int_Tables_number   1
_cell_volume   809.670
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.180  0.845  0.875  1.0
  Mn  Mn1  1  0.335  0.155  0.625  1.0
  Mn  Mn2  1  0.820  0.155  0.125  1.0
  Mn  Mn3  1  0.665  0.845  0.375  1.0
  H  H4  1  0.122  0.924  0.807  1.0
  H  H5  1  0.197  0.076  0.693  1.0
  H  H6  1  0.878  0.076  0.193  1.0
  H  H7  1  0.803  0.924  0.307  1.0
  C  C8  1  0.252  0.755  0.953  1.0
  C  C9  1  0.497  0.245  0.547  1.0
  C  C10  1  0.748  0.245  0.047  1.0
  C  C11  1  0.503  0.755  0.453  1.0
  C  C12  1  0.163  0.080  0.912  1.0
  C  C13  1  0.083  0.920  0.588  1.0
  C  C14  1  0.837  0.920  0.088  1.0
  C  C15  1  0.917  0.080  0.412  1.0
  C  C16  1  0.179  0.629  0.819  1.0
  C  C17  1  0.550  0.371  0.681  1.0
  C  C18  1  0.821  0.371  0.181  1.0
  C  C19  1  0.450  0.629  0.319  1.0
  C  C20  1  0.481  0.018  0.849  1.0
  C  C21  1  0.463  0.982  0.651  1.0
  C  C22  1  0.519  0.982  0.151  1.0
  C  C23  1  0.537  0.018  0.349  1.0
  C  C24  1  0.859  0.695  0.880  1.0
  C  C25  1  0.164  0.305  0.620  1.0
  C  C26  1  0.141  0.305  0.120  1.0
  C  C27  1  0.836  0.695  0.380  1.0
  O  O28  1  0.300  0.704  0.003  1.0
  O  O29  1  0.596  0.296  0.497  1.0
  O  O30  1  0.700  0.296  0.997  1.0
  O  O31  1  0.404  0.704  0.503  1.0
  O  O32  1  0.148  0.228  0.932  1.0
  O  O33  1  0.920  0.772  0.568  1.0
  O  O34  1  0.852  0.772  0.068  1.0
  O  O35  1  0.080  0.228  0.432  1.0
  O  O36  1  0.179  0.499  0.783  1.0
  O  O37  1  0.680  0.501  0.717  1.0
  O  O38  1  0.821  0.501  0.217  1.0
  O  O39  1  0.320  0.499  0.283  1.0
  O  O40  1  0.666  0.129  0.829  1.0
  O  O41  1  0.537  0.871  0.671  1.0
  O  O42  1  0.334  0.871  0.171  1.0
  O  O43  1  0.463  0.129  0.329  1.0
  O  O44  1  0.658  0.608  0.881  1.0
  O  O45  1  0.050  0.392  0.619  1.0
  O  O46  1  0.342  0.392  0.119  1.0
  O  O47  1  0.950  0.608  0.381  1.0
[/CIF]
.