The compound described by Pd3V crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent Pd(1) atoms to form distorted VPd6 cuboctahedra that share corners with six equivalent Pd(2)Pd12 cuboctahedra, edges with six equivalent V(1)Pd6 cuboctahedra, and edges with six equivalent Pd(2)Pd12 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to three equivalent V(1) and three equivalent Pd(2) atoms to form distorted PdV3Pd3 cuboctahedra that share corners with six equivalent Pd(2)Pd12 cuboctahedra, corners with six equivalent Pd(1)V3Pd3 cuboctahedra, edges with six equivalent Pd(2)Pd12 cuboctahedra, and edges with twelve equivalent Pd(1)V3Pd3 cuboctahedra. In the second Pd site, Pd(2) is bonded to six equivalent Pd(1) and six equivalent Pd(2) atoms to form PdPd12 cuboctahedra that share corners with six equivalent V(1)Pd6 cuboctahedra, corners with six equivalent Pd(2)Pd12 cuboctahedra, corners with twelve equivalent Pd(1)V3Pd3 cuboctahedra, edges with six equivalent V(1)Pd6 cuboctahedra, edges with six equivalent Pd(2)Pd12 cuboctahedra, edges with twelve equivalent Pd(1)V3Pd3 cuboctahedra, and faces with six equivalent Pd(2)Pd12 cuboctahedra. is represented by the CIF card [CIF]
data_VPd3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.090
_cell_length_b   9.090
_cell_length_c   9.090
_cell_angle_alpha   17.554
_cell_angle_beta   17.554
_cell_angle_gamma   17.554
_symmetry_Int_Tables_number   1
_cell_volume   59.627
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Pd  Pd1  1  0.255  0.255  0.255  1.0
  Pd  Pd2  1  0.500  0.500  0.500  1.0
  Pd  Pd3  1  0.745  0.745  0.745  1.0
[/CIF]
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The compound described by Pd3V crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent Pd(1) atoms to form distorted VPd6 cuboctahedra that share corners with six equivalent Pd(2)Pd12 cuboctahedra, edges with six equivalent V(1)Pd6 cuboctahedra, and edges with six equivalent Pd(2)Pd12 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to three equivalent V(1) and three equivalent Pd(2) atoms to form distorted PdV3Pd3 cuboctahedra that share corners with six equivalent Pd(2)Pd12 cuboctahedra, corners with six equivalent Pd(1)V3Pd3 cuboctahedra, edges with six equivalent Pd(2)Pd12 cuboctahedra, and edges with twelve equivalent Pd(1)V3Pd3 cuboctahedra. In the second Pd site, Pd(2) is bonded to six equivalent Pd(1) and six equivalent Pd(2) atoms to form PdPd12 cuboctahedra that share corners with six equivalent V(1)Pd6 cuboctahedra, corners with six equivalent Pd(2)Pd12 cuboctahedra, corners with twelve equivalent Pd(1)V3Pd3 cuboctahedra, edges with six equivalent V(1)Pd6 cuboctahedra, edges with six equivalent Pd(2)Pd12 cuboctahedra, edges with twelve equivalent Pd(1)V3Pd3 cuboctahedra, and faces with six equivalent Pd(2)Pd12 cuboctahedra. is represented by the CIF card [CIF]
data_VPd3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.090
_cell_length_b   9.090
_cell_length_c   9.090
_cell_angle_alpha   17.554
_cell_angle_beta   17.554
_cell_angle_gamma   17.554
_symmetry_Int_Tables_number   1
_cell_volume   59.627
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Pd  Pd1  1  0.255  0.255  0.255  1.0
  Pd  Pd2  1  0.500  0.500  0.500  1.0
  Pd  Pd3  1  0.745  0.745  0.745  1.0
[/CIF]
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