The material structure described by K3Na2InO4 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), and two equivalent O(4) atoms. In the second K site, K(2) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. In the third K site, K(3) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), and two equivalent O(1) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted NaO4 tetrahedra that share corners with two equivalent In(1)O4 tetrahedra and  an edgeedge with one In(1)O4 tetrahedra. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form InO4 tetrahedra that share corners with two equivalent Na(1)O4 tetrahedra and  an edgeedge with one Na(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one K(2), two equivalent K(3), one Na(1), one Na(2), and one In(1) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to one K(1), one K(3), two equivalent K(2), one Na(1), one Na(2), and one In(1) atom. In the third O site, O(3) is bonded in a 7-coordinate geometry to one K(2), one K(3), two equivalent K(1), one Na(1), one Na(2), and one In(1) atom. In the fourth O site, O(4) is bonded in a 7-coordinate geometry to one K(2), one K(3), two equivalent K(1), one Na(1), one Na(2), and one In(1) atom. is represented by the CIF file [CIF]
data_K3Na2InO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.816
_cell_length_b   7.352
_cell_length_c   12.550
_cell_angle_alpha   54.989
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   741.759
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.993  0.782  0.482  1.0
  K  K1  1  0.662  0.071  0.602  1.0
  K  K2  1  0.255  0.441  0.662  1.0
  K  K3  1  0.162  0.929  0.898  1.0
  K  K4  1  0.338  0.929  0.398  1.0
  K  K5  1  0.507  0.782  0.982  1.0
  K  K6  1  0.838  0.071  0.102  1.0
  K  K7  1  0.007  0.218  0.518  1.0
  K  K8  1  0.493  0.218  0.018  1.0
  K  K9  1  0.755  0.559  0.838  1.0
  K  K10  1  0.745  0.559  0.338  1.0
  K  K11  1  0.245  0.441  0.162  1.0
  Na  Na12  1  0.835  0.748  0.008  1.0
  Na  Na13  1  0.068  0.685  0.775  1.0
  Na  Na14  1  0.932  0.315  0.225  1.0
  Na  Na15  1  0.432  0.685  0.275  1.0
  Na  Na16  1  0.568  0.315  0.725  1.0
  Na  Na17  1  0.665  0.748  0.508  1.0
  Na  Na18  1  0.165  0.252  0.992  1.0
  Na  Na19  1  0.335  0.252  0.492  1.0
  In  In20  1  0.366  0.795  0.729  1.0
  In  In21  1  0.134  0.795  0.229  1.0
  In  In22  1  0.634  0.205  0.271  1.0
  In  In23  1  0.866  0.205  0.771  1.0
  O  O24  1  0.476  0.340  0.318  1.0
  O  O25  1  0.918  0.909  0.790  1.0
  O  O26  1  0.706  0.105  0.908  1.0
  O  O27  1  0.024  0.340  0.818  1.0
  O  O28  1  0.713  0.430  0.083  1.0
  O  O29  1  0.213  0.570  0.417  1.0
  O  O30  1  0.794  0.105  0.408  1.0
  O  O31  1  0.206  0.895  0.592  1.0
  O  O32  1  0.976  0.660  0.182  1.0
  O  O33  1  0.418  0.091  0.710  1.0
  O  O34  1  0.524  0.660  0.682  1.0
  O  O35  1  0.582  0.909  0.290  1.0
  O  O36  1  0.082  0.091  0.210  1.0
  O  O37  1  0.787  0.430  0.583  1.0
  O  O38  1  0.287  0.570  0.917  1.0
  O  O39  1  0.294  0.895  0.092  1.0
[/CIF]
.
The material structure described by K3Na2InO4 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), and two equivalent O(4) atoms. In the second K site, K(2) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. In the third K site, K(3) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), and two equivalent O(1) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted NaO4 tetrahedra that share corners with two equivalent In(1)O4 tetrahedra and  an edgeedge with one In(1)O4 tetrahedra. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form InO4 tetrahedra that share corners with two equivalent Na(1)O4 tetrahedra and  an edgeedge with one Na(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one K(2), two equivalent K(3), one Na(1), one Na(2), and one In(1) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to one K(1), one K(3), two equivalent K(2), one Na(1), one Na(2), and one In(1) atom. In the third O site, O(3) is bonded in a 7-coordinate geometry to one K(2), one K(3), two equivalent K(1), one Na(1), one Na(2), and one In(1) atom. In the fourth O site, O(4) is bonded in a 7-coordinate geometry to one K(2), one K(3), two equivalent K(1), one Na(1), one Na(2), and one In(1) atom. is represented by the CIF file [CIF]
data_K3Na2InO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.816
_cell_length_b   7.352
_cell_length_c   12.550
_cell_angle_alpha   54.989
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   741.759
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.993  0.782  0.482  1.0
  K  K1  1  0.662  0.071  0.602  1.0
  K  K2  1  0.255  0.441  0.662  1.0
  K  K3  1  0.162  0.929  0.898  1.0
  K  K4  1  0.338  0.929  0.398  1.0
  K  K5  1  0.507  0.782  0.982  1.0
  K  K6  1  0.838  0.071  0.102  1.0
  K  K7  1  0.007  0.218  0.518  1.0
  K  K8  1  0.493  0.218  0.018  1.0
  K  K9  1  0.755  0.559  0.838  1.0
  K  K10  1  0.745  0.559  0.338  1.0
  K  K11  1  0.245  0.441  0.162  1.0
  Na  Na12  1  0.835  0.748  0.008  1.0
  Na  Na13  1  0.068  0.685  0.775  1.0
  Na  Na14  1  0.932  0.315  0.225  1.0
  Na  Na15  1  0.432  0.685  0.275  1.0
  Na  Na16  1  0.568  0.315  0.725  1.0
  Na  Na17  1  0.665  0.748  0.508  1.0
  Na  Na18  1  0.165  0.252  0.992  1.0
  Na  Na19  1  0.335  0.252  0.492  1.0
  In  In20  1  0.366  0.795  0.729  1.0
  In  In21  1  0.134  0.795  0.229  1.0
  In  In22  1  0.634  0.205  0.271  1.0
  In  In23  1  0.866  0.205  0.771  1.0
  O  O24  1  0.476  0.340  0.318  1.0
  O  O25  1  0.918  0.909  0.790  1.0
  O  O26  1  0.706  0.105  0.908  1.0
  O  O27  1  0.024  0.340  0.818  1.0
  O  O28  1  0.713  0.430  0.083  1.0
  O  O29  1  0.213  0.570  0.417  1.0
  O  O30  1  0.794  0.105  0.408  1.0
  O  O31  1  0.206  0.895  0.592  1.0
  O  O32  1  0.976  0.660  0.182  1.0
  O  O33  1  0.418  0.091  0.710  1.0
  O  O34  1  0.524  0.660  0.682  1.0
  O  O35  1  0.582  0.909  0.290  1.0
  O  O36  1  0.082  0.091  0.210  1.0
  O  O37  1  0.787  0.430  0.583  1.0
  O  O38  1  0.287  0.570  0.917  1.0
  O  O39  1  0.294  0.895  0.092  1.0
[/CIF]
.