The material described by CrOF is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. Cr(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing CrO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent Cr(1) atoms. F(1) is bonded in a trigonal planar geometry to three equivalent Cr(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.601
_cell_length_b   5.626
_cell_length_c   5.123
_cell_angle_alpha   91.466
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   132.564
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.984  0.149  0.275  1.0
  Cr  Cr1  1  0.484  0.351  0.725  1.0
  Cr  Cr2  1  0.516  0.649  0.275  1.0
  Cr  Cr3  1  0.016  0.851  0.725  1.0
  O  O4  1  0.776  0.885  0.419  1.0
  O  O5  1  0.724  0.385  0.419  1.0
  O  O6  1  0.276  0.615  0.581  1.0
  O  O7  1  0.224  0.115  0.581  1.0
  F  F8  1  0.241  0.888  0.079  1.0
  F  F9  1  0.259  0.387  0.079  1.0
  F  F10  1  0.741  0.612  0.921  1.0
  F  F11  1  0.759  0.113  0.921  1.0
[/CIF]
.
The material described by CrOF is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. Cr(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing CrO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent Cr(1) atoms. F(1) is bonded in a trigonal planar geometry to three equivalent Cr(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.601
_cell_length_b   5.626
_cell_length_c   5.123
_cell_angle_alpha   91.466
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   132.564
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.984  0.149  0.275  1.0
  Cr  Cr1  1  0.484  0.351  0.725  1.0
  Cr  Cr2  1  0.516  0.649  0.275  1.0
  Cr  Cr3  1  0.016  0.851  0.725  1.0
  O  O4  1  0.776  0.885  0.419  1.0
  O  O5  1  0.724  0.385  0.419  1.0
  O  O6  1  0.276  0.615  0.581  1.0
  O  O7  1  0.224  0.115  0.581  1.0
  F  F8  1  0.241  0.888  0.079  1.0
  F  F9  1  0.259  0.387  0.079  1.0
  F  F10  1  0.741  0.612  0.921  1.0
  F  F11  1  0.759  0.113  0.921  1.0
[/CIF]
.