The crystal structure described by LiAgF4 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a distorted tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. Ag(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Li(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Li(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiAgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.444
_cell_length_b   5.968
_cell_length_c   7.895
_cell_angle_alpha   59.017
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   341.053
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.503  0.361  0.848  1.0
  Li  Li1  1  0.003  0.639  0.652  1.0
  Li  Li2  1  0.997  0.361  0.348  1.0
  Li  Li3  1  0.497  0.639  0.152  1.0
  Ag  Ag4  1  0.164  0.028  0.112  1.0
  Ag  Ag5  1  0.664  0.972  0.388  1.0
  Ag  Ag6  1  0.336  0.028  0.612  1.0
  Ag  Ag7  1  0.836  0.972  0.888  1.0
  F  F8  1  0.989  0.266  0.759  1.0
  F  F9  1  0.698  0.165  0.973  1.0
  F  F10  1  0.516  0.774  0.324  1.0
  F  F11  1  0.297  0.336  0.963  1.0
  F  F12  1  0.797  0.664  0.537  1.0
  F  F13  1  0.198  0.835  0.527  1.0
  F  F14  1  0.489  0.734  0.741  1.0
  F  F15  1  0.984  0.774  0.824  1.0
  F  F16  1  0.016  0.226  0.176  1.0
  F  F17  1  0.511  0.266  0.259  1.0
  F  F18  1  0.802  0.165  0.473  1.0
  F  F19  1  0.203  0.336  0.463  1.0
  F  F20  1  0.703  0.664  0.037  1.0
  F  F21  1  0.484  0.226  0.676  1.0
  F  F22  1  0.302  0.835  0.027  1.0
  F  F23  1  0.011  0.734  0.241  1.0
[/CIF]
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The crystal structure described by LiAgF4 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a distorted tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. Ag(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Li(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Li(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiAgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.444
_cell_length_b   5.968
_cell_length_c   7.895
_cell_angle_alpha   59.017
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   341.053
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.503  0.361  0.848  1.0
  Li  Li1  1  0.003  0.639  0.652  1.0
  Li  Li2  1  0.997  0.361  0.348  1.0
  Li  Li3  1  0.497  0.639  0.152  1.0
  Ag  Ag4  1  0.164  0.028  0.112  1.0
  Ag  Ag5  1  0.664  0.972  0.388  1.0
  Ag  Ag6  1  0.336  0.028  0.612  1.0
  Ag  Ag7  1  0.836  0.972  0.888  1.0
  F  F8  1  0.989  0.266  0.759  1.0
  F  F9  1  0.698  0.165  0.973  1.0
  F  F10  1  0.516  0.774  0.324  1.0
  F  F11  1  0.297  0.336  0.963  1.0
  F  F12  1  0.797  0.664  0.537  1.0
  F  F13  1  0.198  0.835  0.527  1.0
  F  F14  1  0.489  0.734  0.741  1.0
  F  F15  1  0.984  0.774  0.824  1.0
  F  F16  1  0.016  0.226  0.176  1.0
  F  F17  1  0.511  0.266  0.259  1.0
  F  F18  1  0.802  0.165  0.473  1.0
  F  F19  1  0.203  0.336  0.463  1.0
  F  F20  1  0.703  0.664  0.037  1.0
  F  F21  1  0.484  0.226  0.676  1.0
  F  F22  1  0.302  0.835  0.027  1.0
  F  F23  1  0.011  0.734  0.241  1.0
[/CIF]
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