The material structure described by Li2TiCo2O5 is Caswellsilverite-derived structured and crystallizes in the monoclinic C2 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the second Li site, Li(2) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth Li site, Li(4) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the second Ti site, Ti(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form TiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. In the fourth Co site, Co(4) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one Ti(2), one Co(1), one Co(2), and one Co(3) atom to form OLi2TiCo3 octahedra that share corners with two equivalent O(1)Li2TiCo3 octahedra, corners with two equivalent O(3)Li3Ti2Co octahedra, corners with two equivalent O(5)Li3TiCo2 octahedra,  an edgeedge with one O(3)Li3Ti2Co octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra, edges with two equivalent O(1)Li2TiCo3 octahedra, edges with four equivalent O(2)Li2TiCo3 octahedra, and edges with four equivalent O(4)Li2TiCo3 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the second O site, O(2) is bonded to one Li(2), one Li(4), one Ti(1), one Co(1), one Co(2), and one Co(3) atom to form OLi2TiCo3 octahedra that share corners with two equivalent O(2)Li2TiCo3 octahedra, corners with two equivalent O(4)Li2TiCo3 octahedra, corners with two equivalent O(3)Li3Ti2Co octahedra,  an edgeedge with one O(4)Li2TiCo3 octahedra,  an edgeedge with one O(3)Li3Ti2Co octahedra, edges with two equivalent O(2)Li2TiCo3 octahedra, edges with four equivalent O(1)Li2TiCo3 octahedra, and edges with four equivalent O(5)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Ti(2), and one Co(4) atom to form OLi3Ti2Co octahedra that share corners with two equivalent O(1)Li2TiCo3 octahedra, corners with two equivalent O(2)Li2TiCo3 octahedra, corners with two equivalent O(3)Li3Ti2Co octahedra,  an edgeedge with one O(1)Li2TiCo3 octahedra,  an edgeedge with one O(2)Li2TiCo3 octahedra, edges with two equivalent O(3)Li3Ti2Co octahedra, edges with four equivalent O(4)Li2TiCo3 octahedra, and edges with four equivalent O(5)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one Ti(2), one Co(2), one Co(3), and one Co(4) atom to form OLi2TiCo3 octahedra that share corners with two equivalent O(2)Li2TiCo3 octahedra, corners with two equivalent O(4)Li2TiCo3 octahedra, corners with two equivalent O(5)Li3TiCo2 octahedra,  an edgeedge with one O(2)Li2TiCo3 octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra, edges with two equivalent O(4)Li2TiCo3 octahedra, edges with four equivalent O(1)Li2TiCo3 octahedra, and edges with four equivalent O(3)Li3Ti2Co octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(4), one Ti(1), one Co(1), and one Co(4) atom to form OLi3TiCo2 octahedra that share corners with two equivalent O(1)Li2TiCo3 octahedra, corners with two equivalent O(4)Li2TiCo3 octahedra, corners with two equivalent O(5)Li3TiCo2 octahedra,  an edgeedge with one O(1)Li2TiCo3 octahedra,  an edgeedge with one O(4)Li2TiCo3 octahedra, edges with two equivalent O(5)Li3TiCo2 octahedra, edges with four equivalent O(2)Li2TiCo3 octahedra, and edges with four equivalent O(3)Li3Ti2Co octahedra. The corner-sharing octahedral tilt angles range from 1-11°. is represented by the CIF file [CIF]
data_Li2TiCo2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.782
_cell_length_b   7.782
_cell_length_c   5.256
_cell_angle_alpha   82.748
_cell_angle_beta   82.748
_cell_angle_gamma   140.793
_symmetry_Int_Tables_number   1
_cell_volume   186.451
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.102  0.898  0.000  1.0
  Li  Li1  1  0.201  0.799  0.500  1.0
  Li  Li2  1  0.500  0.500  0.000  1.0
  Li  Li3  1  0.798  0.202  0.500  1.0
  Ti  Ti4  1  0.695  0.305  0.000  1.0
  Ti  Ti5  1  0.998  0.002  0.500  1.0
  Co  Co6  1  0.300  0.700  0.000  1.0
  Co  Co7  1  0.395  0.605  0.500  1.0
  Co  Co8  1  0.901  0.099  0.000  1.0
  Co  Co9  1  0.604  0.396  0.500  1.0
  O  O10  1  0.151  0.336  0.263  1.0
  O  O11  1  0.041  0.448  0.767  1.0
  O  O12  1  0.353  0.151  0.251  1.0
  O  O13  1  0.552  0.959  0.233  1.0
  O  O14  1  0.664  0.849  0.737  1.0
  O  O15  1  0.229  0.229  0.729  1.0
  O  O16  1  0.476  0.076  0.775  1.0
  O  O17  1  0.771  0.771  0.271  1.0
  O  O18  1  0.924  0.524  0.225  1.0
  O  O19  1  0.849  0.647  0.749  1.0
[/CIF]
.
The material structure described by Li2TiCo2O5 is Caswellsilverite-derived structured and crystallizes in the monoclinic C2 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the second Li site, Li(2) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth Li site, Li(4) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the second Ti site, Ti(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form TiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. In the fourth Co site, Co(4) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one Ti(2), one Co(1), one Co(2), and one Co(3) atom to form OLi2TiCo3 octahedra that share corners with two equivalent O(1)Li2TiCo3 octahedra, corners with two equivalent O(3)Li3Ti2Co octahedra, corners with two equivalent O(5)Li3TiCo2 octahedra,  an edgeedge with one O(3)Li3Ti2Co octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra, edges with two equivalent O(1)Li2TiCo3 octahedra, edges with four equivalent O(2)Li2TiCo3 octahedra, and edges with four equivalent O(4)Li2TiCo3 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the second O site, O(2) is bonded to one Li(2), one Li(4), one Ti(1), one Co(1), one Co(2), and one Co(3) atom to form OLi2TiCo3 octahedra that share corners with two equivalent O(2)Li2TiCo3 octahedra, corners with two equivalent O(4)Li2TiCo3 octahedra, corners with two equivalent O(3)Li3Ti2Co octahedra,  an edgeedge with one O(4)Li2TiCo3 octahedra,  an edgeedge with one O(3)Li3Ti2Co octahedra, edges with two equivalent O(2)Li2TiCo3 octahedra, edges with four equivalent O(1)Li2TiCo3 octahedra, and edges with four equivalent O(5)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Ti(2), and one Co(4) atom to form OLi3Ti2Co octahedra that share corners with two equivalent O(1)Li2TiCo3 octahedra, corners with two equivalent O(2)Li2TiCo3 octahedra, corners with two equivalent O(3)Li3Ti2Co octahedra,  an edgeedge with one O(1)Li2TiCo3 octahedra,  an edgeedge with one O(2)Li2TiCo3 octahedra, edges with two equivalent O(3)Li3Ti2Co octahedra, edges with four equivalent O(4)Li2TiCo3 octahedra, and edges with four equivalent O(5)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one Ti(2), one Co(2), one Co(3), and one Co(4) atom to form OLi2TiCo3 octahedra that share corners with two equivalent O(2)Li2TiCo3 octahedra, corners with two equivalent O(4)Li2TiCo3 octahedra, corners with two equivalent O(5)Li3TiCo2 octahedra,  an edgeedge with one O(2)Li2TiCo3 octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra, edges with two equivalent O(4)Li2TiCo3 octahedra, edges with four equivalent O(1)Li2TiCo3 octahedra, and edges with four equivalent O(3)Li3Ti2Co octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(4), one Ti(1), one Co(1), and one Co(4) atom to form OLi3TiCo2 octahedra that share corners with two equivalent O(1)Li2TiCo3 octahedra, corners with two equivalent O(4)Li2TiCo3 octahedra, corners with two equivalent O(5)Li3TiCo2 octahedra,  an edgeedge with one O(1)Li2TiCo3 octahedra,  an edgeedge with one O(4)Li2TiCo3 octahedra, edges with two equivalent O(5)Li3TiCo2 octahedra, edges with four equivalent O(2)Li2TiCo3 octahedra, and edges with four equivalent O(3)Li3Ti2Co octahedra. The corner-sharing octahedral tilt angles range from 1-11°. is represented by the CIF file [CIF]
data_Li2TiCo2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.782
_cell_length_b   7.782
_cell_length_c   5.256
_cell_angle_alpha   82.748
_cell_angle_beta   82.748
_cell_angle_gamma   140.793
_symmetry_Int_Tables_number   1
_cell_volume   186.451
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.102  0.898  0.000  1.0
  Li  Li1  1  0.201  0.799  0.500  1.0
  Li  Li2  1  0.500  0.500  0.000  1.0
  Li  Li3  1  0.798  0.202  0.500  1.0
  Ti  Ti4  1  0.695  0.305  0.000  1.0
  Ti  Ti5  1  0.998  0.002  0.500  1.0
  Co  Co6  1  0.300  0.700  0.000  1.0
  Co  Co7  1  0.395  0.605  0.500  1.0
  Co  Co8  1  0.901  0.099  0.000  1.0
  Co  Co9  1  0.604  0.396  0.500  1.0
  O  O10  1  0.151  0.336  0.263  1.0
  O  O11  1  0.041  0.448  0.767  1.0
  O  O12  1  0.353  0.151  0.251  1.0
  O  O13  1  0.552  0.959  0.233  1.0
  O  O14  1  0.664  0.849  0.737  1.0
  O  O15  1  0.229  0.229  0.729  1.0
  O  O16  1  0.476  0.076  0.775  1.0
  O  O17  1  0.771  0.771  0.271  1.0
  O  O18  1  0.924  0.524  0.225  1.0
  O  O19  1  0.849  0.647  0.749  1.0
[/CIF]
.