The material described by WCoN3 crystallizes in the triclinic P-1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one N(3), one N(5), and two equivalent N(2) atoms to form distorted WN5 trigonal bipyramids that share  a cornercorner with one Co(2)N5 square pyramid, corners with three equivalent Co(1)N5 square pyramids,  an edgeedge with one Co(2)N5 square pyramid, and  an edgeedge with one W(1)N5 trigonal bipyramid. In the second W site, W(2) is bonded in a 5-coordinate geometry to one N(5), two equivalent N(4), and two equivalent N(6) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(3), one N(4), one N(6), and two equivalent N(1) atoms to form CoN5 square pyramids that share corners with three equivalent W(1)N5 trigonal bipyramids,  an edgeedge with one Co(1)N5 square pyramid, and edges with three equivalent Co(2)N5 square pyramids. In the second Co site, Co(2) is bonded to one N(1), one N(4), one N(6), and two equivalent N(3) atoms to form distorted CoN5 square pyramids that share  a cornercorner with one W(1)N5 trigonal bipyramid,  an edgeedge with one Co(2)N5 square pyramid, edges with three equivalent Co(1)N5 square pyramids, and  an edgeedge with one W(1)N5 trigonal bipyramid. There are six inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to one W(1), one Co(2), and two equivalent Co(1) atoms. In the second N site, N(2) is bonded in an L-shaped geometry to two equivalent W(1) atoms. In the third N site, N(3) is bonded to one W(1), one Co(1), and two equivalent Co(2) atoms to form distorted edge-sharing NCo3W trigonal pyramids. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to two equivalent W(2), one Co(1), and one Co(2) atom. In the fifth N site, N(5) is bonded in a water-like geometry to one W(1) and one W(2) atom. In the sixth N site, N(6) is bonded in a rectangular see-saw-like geometry to two equivalent W(2), one Co(1), and one Co(2) atom. is represented by the CIF file [CIF]
data_CoWN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.628
_cell_length_b   7.472
_cell_length_c   7.900
_cell_angle_alpha   114.856
_cell_angle_beta   110.182
_cell_angle_gamma   79.031
_symmetry_Int_Tables_number   1
_cell_volume   282.544
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.383  0.168  0.600  1.0
  Co  Co1  1  0.617  0.832  0.400  1.0
  Co  Co2  1  0.126  0.817  0.406  1.0
  Co  Co3  1  0.874  0.183  0.594  1.0
  W  W4  1  0.963  0.035  0.178  1.0
  W  W5  1  0.037  0.965  0.822  1.0
  W  W6  1  0.724  0.428  0.423  1.0
  W  W7  1  0.276  0.572  0.577  1.0
  N  N8  1  0.303  0.967  0.344  1.0
  N  N9  1  0.697  0.033  0.656  1.0
  N  N10  1  0.899  0.833  0.943  1.0
  N  N11  1  0.101  0.167  0.057  1.0
  N  N12  1  0.817  0.955  0.343  1.0
  N  N13  1  0.183  0.045  0.657  1.0
  N  N14  1  0.926  0.665  0.467  1.0
  N  N15  1  0.074  0.335  0.533  1.0
  N  N16  1  0.664  0.242  0.181  1.0
  N  N17  1  0.336  0.758  0.819  1.0
  N  N18  1  0.440  0.646  0.429  1.0
  N  N19  1  0.560  0.354  0.571  1.0
[/CIF]
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The material described by WCoN3 crystallizes in the triclinic P-1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one N(3), one N(5), and two equivalent N(2) atoms to form distorted WN5 trigonal bipyramids that share  a cornercorner with one Co(2)N5 square pyramid, corners with three equivalent Co(1)N5 square pyramids,  an edgeedge with one Co(2)N5 square pyramid, and  an edgeedge with one W(1)N5 trigonal bipyramid. In the second W site, W(2) is bonded in a 5-coordinate geometry to one N(5), two equivalent N(4), and two equivalent N(6) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(3), one N(4), one N(6), and two equivalent N(1) atoms to form CoN5 square pyramids that share corners with three equivalent W(1)N5 trigonal bipyramids,  an edgeedge with one Co(1)N5 square pyramid, and edges with three equivalent Co(2)N5 square pyramids. In the second Co site, Co(2) is bonded to one N(1), one N(4), one N(6), and two equivalent N(3) atoms to form distorted CoN5 square pyramids that share  a cornercorner with one W(1)N5 trigonal bipyramid,  an edgeedge with one Co(2)N5 square pyramid, edges with three equivalent Co(1)N5 square pyramids, and  an edgeedge with one W(1)N5 trigonal bipyramid. There are six inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to one W(1), one Co(2), and two equivalent Co(1) atoms. In the second N site, N(2) is bonded in an L-shaped geometry to two equivalent W(1) atoms. In the third N site, N(3) is bonded to one W(1), one Co(1), and two equivalent Co(2) atoms to form distorted edge-sharing NCo3W trigonal pyramids. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to two equivalent W(2), one Co(1), and one Co(2) atom. In the fifth N site, N(5) is bonded in a water-like geometry to one W(1) and one W(2) atom. In the sixth N site, N(6) is bonded in a rectangular see-saw-like geometry to two equivalent W(2), one Co(1), and one Co(2) atom. is represented by the CIF file [CIF]
data_CoWN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.628
_cell_length_b   7.472
_cell_length_c   7.900
_cell_angle_alpha   114.856
_cell_angle_beta   110.182
_cell_angle_gamma   79.031
_symmetry_Int_Tables_number   1
_cell_volume   282.544
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.383  0.168  0.600  1.0
  Co  Co1  1  0.617  0.832  0.400  1.0
  Co  Co2  1  0.126  0.817  0.406  1.0
  Co  Co3  1  0.874  0.183  0.594  1.0
  W  W4  1  0.963  0.035  0.178  1.0
  W  W5  1  0.037  0.965  0.822  1.0
  W  W6  1  0.724  0.428  0.423  1.0
  W  W7  1  0.276  0.572  0.577  1.0
  N  N8  1  0.303  0.967  0.344  1.0
  N  N9  1  0.697  0.033  0.656  1.0
  N  N10  1  0.899  0.833  0.943  1.0
  N  N11  1  0.101  0.167  0.057  1.0
  N  N12  1  0.817  0.955  0.343  1.0
  N  N13  1  0.183  0.045  0.657  1.0
  N  N14  1  0.926  0.665  0.467  1.0
  N  N15  1  0.074  0.335  0.533  1.0
  N  N16  1  0.664  0.242  0.181  1.0
  N  N17  1  0.336  0.758  0.819  1.0
  N  N18  1  0.440  0.646  0.429  1.0
  N  N19  1  0.560  0.354  0.571  1.0
[/CIF]
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