The crystal structure described by FeOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. Fe(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing FeO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. O(1) is bonded in a trigonal planar geometry to three equivalent Fe(1) atoms. F(1) is bonded in a distorted T-shaped geometry to three equivalent Fe(1) atoms. is represented by the CIF file [CIF]
data_FeOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.676
_cell_length_b   4.672
_cell_length_c   3.070
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   67.051
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.993  0.037  0.000  1.0
  Fe  Fe1  1  0.493  0.463  0.500  1.0
  O  O2  1  0.303  0.309  0.000  1.0
  O  O3  1  0.803  0.191  0.500  1.0
  F  F4  1  0.204  0.805  0.500  1.0
  F  F5  1  0.704  0.695  0.000  1.0
[/CIF]
.
The crystal structure described by FeOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. Fe(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing FeO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. O(1) is bonded in a trigonal planar geometry to three equivalent Fe(1) atoms. F(1) is bonded in a distorted T-shaped geometry to three equivalent Fe(1) atoms. is represented by the CIF file [CIF]
data_FeOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.676
_cell_length_b   4.672
_cell_length_c   3.070
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   67.051
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.993  0.037  0.000  1.0
  Fe  Fe1  1  0.493  0.463  0.500  1.0
  O  O2  1  0.303  0.309  0.000  1.0
  O  O3  1  0.803  0.191  0.500  1.0
  F  F4  1  0.204  0.805  0.500  1.0
  F  F5  1  0.704  0.695  0.000  1.0
[/CIF]
.