The structure described by LiO6O2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and two LiO6 clusters. In each LiO6 cluster, Li(1) is bonded in a distorted hexagonal planar geometry to one O(4), one O(6), two equivalent O(1), and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Li(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1) and one O(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one Li(1) and one O(6) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Li(1) and one O(4) atom. is represented by the CIF card [CIF]
data_LiO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.573
_cell_length_b   5.680
_cell_length_c   5.680
_cell_angle_alpha   69.478
_cell_angle_beta   68.255
_cell_angle_gamma   68.255
_symmetry_Int_Tables_number   1
_cell_volume   123.347
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.009  0.605  0.605  1.0
  O  O1  1  0.848  0.277  0.799  1.0
  O  O2  1  0.161  0.211  0.740  1.0
  O  O3  1  0.161  0.740  0.211  1.0
  O  O4  1  0.848  0.799  0.277  1.0
  O  O5  1  0.830  0.201  0.201  1.0
  O  O6  1  0.175  0.783  0.783  1.0
  O  O7  1  0.131  0.142  0.142  1.0
  O  O8  1  0.864  0.848  0.848  1.0
[/CIF]
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The structure described by LiO6O2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and two LiO6 clusters. In each LiO6 cluster, Li(1) is bonded in a distorted hexagonal planar geometry to one O(4), one O(6), two equivalent O(1), and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Li(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1) and one O(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one Li(1) and one O(6) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Li(1) and one O(4) atom. is represented by the CIF card [CIF]
data_LiO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.573
_cell_length_b   5.680
_cell_length_c   5.680
_cell_angle_alpha   69.478
_cell_angle_beta   68.255
_cell_angle_gamma   68.255
_symmetry_Int_Tables_number   1
_cell_volume   123.347
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.009  0.605  0.605  1.0
  O  O1  1  0.848  0.277  0.799  1.0
  O  O2  1  0.161  0.211  0.740  1.0
  O  O3  1  0.161  0.740  0.211  1.0
  O  O4  1  0.848  0.799  0.277  1.0
  O  O5  1  0.830  0.201  0.201  1.0
  O  O6  1  0.175  0.783  0.783  1.0
  O  O7  1  0.131  0.142  0.142  1.0
  O  O8  1  0.864  0.848  0.848  1.0
[/CIF]
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