The structure described by SmLa7Mn3Fe5O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Sm(1) is bonded to one O(13), one O(9), two equivalent O(10), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(10) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, corners with four equivalent La(5)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the second La site, La(2) is bonded to one O(13), one O(9), two equivalent O(1), two equivalent O(10), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(11), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the fourth La site, La(4) is bonded to one O(11), one O(14), two equivalent O(1), two equivalent O(12), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(5)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the fifth La site, La(5) is bonded to one O(11), one O(14), two equivalent O(12), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(4)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(9), two equivalent O(3), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(4)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are four inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(11), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form FeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Fe site, Fe(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Fe site, Fe(3) is bonded to one O(13), one O(14), two equivalent O(2), and two equivalent O(6) atoms to form FeO6 octahedra that share corners with two equivalent Fe(4)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Fe site, Fe(4) is bonded to one O(13), one O(14), two equivalent O(4), and two equivalent O(8) atoms to form FeO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Fe(1), and one Fe(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Fe(2), and one Fe(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Mn(1), and one Mn(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Mn(2), and one Fe(4) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Fe(1), and one Fe(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Fe(2), and one Fe(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Mn(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Mn(2), and one Fe(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Mn(1), and one Fe(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Mn(2), and one Fe(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Mn(1), and one Fe(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Mn(2), and one Fe(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Fe(3), and one Fe(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Fe(3), and one Fe(4) atom. is represented by the CIF card [CIF]
data_La7SmMn3Fe5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.909
_cell_length_b   7.909
_cell_length_c   7.875
_cell_angle_alpha   89.996
_cell_angle_beta   89.996
_cell_angle_gamma   90.005
_symmetry_Int_Tables_number   1
_cell_volume   492.643
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.750  0.250  0.251  1.0
  La  La1  1  0.250  0.250  0.251  1.0
  La  La2  1  0.750  0.250  0.749  1.0
  La  La3  1  0.250  0.250  0.749  1.0
  La  La4  1  0.250  0.750  0.251  1.0
  La  La5  1  0.750  0.750  0.749  1.0
  La  La6  1  0.250  0.750  0.749  1.0
  Sm  Sm7  1  0.750  0.750  0.251  1.0
  Mn  Mn8  1  1.000  1.000  0.500  1.0
  Mn  Mn9  1  0.500  1.000  0.500  1.0
  Mn  Mn10  1  1.000  0.500  0.500  1.0
  Fe  Fe11  1  1.000  1.000  0.000  1.0
  Fe  Fe12  1  0.500  1.000  0.000  1.0
  Fe  Fe13  1  1.000  0.500  0.000  1.0
  Fe  Fe14  1  0.500  0.500  0.000  1.0
  Fe  Fe15  1  0.500  0.500  0.500  1.0
  O  O16  1  1.000  0.250  0.000  1.0
  O  O17  1  0.500  0.250  0.000  1.0
  O  O18  1  1.000  0.249  0.500  1.0
  O  O19  1  0.500  0.253  0.500  1.0
  O  O20  1  0.999  0.750  0.001  1.0
  O  O21  1  0.501  0.750  0.001  1.0
  O  O22  1  0.999  0.751  0.499  1.0
  O  O23  1  0.501  0.747  0.499  1.0
  O  O24  1  0.999  0.999  0.250  1.0
  O  O25  1  0.501  0.999  0.249  1.0
  O  O26  1  1.000  1.000  0.750  1.0
  O  O27  1  0.500  1.000  0.751  1.0
  O  O28  1  0.999  0.501  0.249  1.0
  O  O29  1  0.501  0.501  0.250  1.0
  O  O30  1  1.000  0.500  0.751  1.0
  O  O31  1  0.500  0.500  0.750  1.0
  O  O32  1  0.750  0.999  0.001  1.0
  O  O33  1  0.250  1.000  0.000  1.0
  O  O34  1  0.751  0.999  0.499  1.0
  O  O35  1  0.249  1.000  0.500  1.0
  O  O36  1  0.750  0.501  0.001  1.0
  O  O37  1  0.250  0.500  0.000  1.0
  O  O38  1  0.747  0.501  0.499  1.0
  O  O39  1  0.253  0.500  0.500  1.0
[/CIF]
.
The structure described by SmLa7Mn3Fe5O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Sm(1) is bonded to one O(13), one O(9), two equivalent O(10), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(10) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, corners with four equivalent La(5)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the second La site, La(2) is bonded to one O(13), one O(9), two equivalent O(1), two equivalent O(10), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(11), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the fourth La site, La(4) is bonded to one O(11), one O(14), two equivalent O(1), two equivalent O(12), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(5)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the fifth La site, La(5) is bonded to one O(11), one O(14), two equivalent O(12), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(4)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(9), two equivalent O(3), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(4)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are four inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(11), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form FeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Fe site, Fe(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Fe site, Fe(3) is bonded to one O(13), one O(14), two equivalent O(2), and two equivalent O(6) atoms to form FeO6 octahedra that share corners with two equivalent Fe(4)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Fe site, Fe(4) is bonded to one O(13), one O(14), two equivalent O(4), and two equivalent O(8) atoms to form FeO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Fe(1), and one Fe(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Fe(2), and one Fe(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Mn(1), and one Mn(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Mn(2), and one Fe(4) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Fe(1), and one Fe(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Fe(2), and one Fe(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Mn(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Mn(2), and one Fe(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Mn(1), and one Fe(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Mn(2), and one Fe(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Mn(1), and one Fe(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Mn(2), and one Fe(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Fe(3), and one Fe(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Fe(3), and one Fe(4) atom. is represented by the CIF card [CIF]
data_La7SmMn3Fe5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.909
_cell_length_b   7.909
_cell_length_c   7.875
_cell_angle_alpha   89.996
_cell_angle_beta   89.996
_cell_angle_gamma   90.005
_symmetry_Int_Tables_number   1
_cell_volume   492.643
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.750  0.250  0.251  1.0
  La  La1  1  0.250  0.250  0.251  1.0
  La  La2  1  0.750  0.250  0.749  1.0
  La  La3  1  0.250  0.250  0.749  1.0
  La  La4  1  0.250  0.750  0.251  1.0
  La  La5  1  0.750  0.750  0.749  1.0
  La  La6  1  0.250  0.750  0.749  1.0
  Sm  Sm7  1  0.750  0.750  0.251  1.0
  Mn  Mn8  1  1.000  1.000  0.500  1.0
  Mn  Mn9  1  0.500  1.000  0.500  1.0
  Mn  Mn10  1  1.000  0.500  0.500  1.0
  Fe  Fe11  1  1.000  1.000  0.000  1.0
  Fe  Fe12  1  0.500  1.000  0.000  1.0
  Fe  Fe13  1  1.000  0.500  0.000  1.0
  Fe  Fe14  1  0.500  0.500  0.000  1.0
  Fe  Fe15  1  0.500  0.500  0.500  1.0
  O  O16  1  1.000  0.250  0.000  1.0
  O  O17  1  0.500  0.250  0.000  1.0
  O  O18  1  1.000  0.249  0.500  1.0
  O  O19  1  0.500  0.253  0.500  1.0
  O  O20  1  0.999  0.750  0.001  1.0
  O  O21  1  0.501  0.750  0.001  1.0
  O  O22  1  0.999  0.751  0.499  1.0
  O  O23  1  0.501  0.747  0.499  1.0
  O  O24  1  0.999  0.999  0.250  1.0
  O  O25  1  0.501  0.999  0.249  1.0
  O  O26  1  1.000  1.000  0.750  1.0
  O  O27  1  0.500  1.000  0.751  1.0
  O  O28  1  0.999  0.501  0.249  1.0
  O  O29  1  0.501  0.501  0.250  1.0
  O  O30  1  1.000  0.500  0.751  1.0
  O  O31  1  0.500  0.500  0.750  1.0
  O  O32  1  0.750  0.999  0.001  1.0
  O  O33  1  0.250  1.000  0.000  1.0
  O  O34  1  0.751  0.999  0.499  1.0
  O  O35  1  0.249  1.000  0.500  1.0
  O  O36  1  0.750  0.501  0.001  1.0
  O  O37  1  0.250  0.500  0.000  1.0
  O  O38  1  0.747  0.501  0.499  1.0
  O  O39  1  0.253  0.500  0.500  1.0
[/CIF]
.