The compound described by V4OF11 crystallizes in the triclinic P-1 space group. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(5), and one F(9) atom to form VOF5 octahedra that share corners with three equivalent V(2)F6 octahedra and corners with three equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 25-34°. In the second V site, V(2) is bonded to one F(3), one F(4), one F(5), one F(7), one F(8), and one F(9) atom to form VF6 octahedra that share corners with three equivalent V(4)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 27-32°. In the third V site, V(3) is bonded to one O(1), one F(1), one F(10), one F(11), one F(2), and one F(6) atom to form VOF5 octahedra that share corners with three equivalent V(5)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 25-34°. In the fourth V site, V(4) is bonded to two equivalent F(4), two equivalent F(7), and two equivalent F(8) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 32°. In the fifth V site, V(5) is bonded to two equivalent F(10), two equivalent F(11), and two equivalent F(6) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 31-32°. O(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V4OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.248
_cell_length_b   5.460
_cell_length_c   17.436
_cell_angle_alpha   89.147
_cell_angle_beta   98.192
_cell_angle_gamma   118.409
_symmetry_Int_Tables_number   1
_cell_volume   434.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.507  0.737  0.243  1.0
  V  V1  1  0.493  0.263  0.757  1.0
  V  V2  1  0.252  0.121  0.374  1.0
  V  V3  1  0.254  0.620  0.874  1.0
  V  V4  1  0.000  0.500  0.500  1.0
  V  V5  1  0.000  0.000  0.000  1.0
  V  V6  1  0.746  0.380  0.126  1.0
  V  V7  1  0.748  0.879  0.626  1.0
  O  O8  1  0.579  0.589  0.170  1.0
  O  O9  1  0.421  0.411  0.830  1.0
  F  F10  1  0.078  0.539  0.213  1.0
  F  F11  1  0.519  0.058  0.187  1.0
  F  F12  1  0.521  0.557  0.686  1.0
  F  F13  1  0.479  0.443  0.314  1.0
  F  F14  1  0.073  0.337  0.412  1.0
  F  F15  1  0.077  0.035  0.713  1.0
  F  F16  1  0.076  0.836  0.912  1.0
  F  F17  1  0.923  0.965  0.287  1.0
  F  F18  1  0.922  0.461  0.787  1.0
  F  F19  1  0.927  0.663  0.588  1.0
  F  F20  1  0.024  0.813  0.437  1.0
  F  F21  1  0.481  0.942  0.813  1.0
  F  F22  1  0.572  0.284  0.462  1.0
  F  F23  1  0.574  0.095  0.667  1.0
  F  F24  1  0.573  0.784  0.963  1.0
  F  F25  1  0.924  0.164  0.088  1.0
  F  F26  1  0.428  0.716  0.538  1.0
  F  F27  1  0.426  0.905  0.333  1.0
  F  F28  1  0.023  0.312  0.938  1.0
  F  F29  1  0.977  0.688  0.062  1.0
  F  F30  1  0.976  0.187  0.563  1.0
  F  F31  1  0.427  0.216  0.037  1.0
[/CIF]
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The compound described by V4OF11 crystallizes in the triclinic P-1 space group. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(5), and one F(9) atom to form VOF5 octahedra that share corners with three equivalent V(2)F6 octahedra and corners with three equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 25-34°. In the second V site, V(2) is bonded to one F(3), one F(4), one F(5), one F(7), one F(8), and one F(9) atom to form VF6 octahedra that share corners with three equivalent V(4)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 27-32°. In the third V site, V(3) is bonded to one O(1), one F(1), one F(10), one F(11), one F(2), and one F(6) atom to form VOF5 octahedra that share corners with three equivalent V(5)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 25-34°. In the fourth V site, V(4) is bonded to two equivalent F(4), two equivalent F(7), and two equivalent F(8) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 32°. In the fifth V site, V(5) is bonded to two equivalent F(10), two equivalent F(11), and two equivalent F(6) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 31-32°. O(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V4OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.248
_cell_length_b   5.460
_cell_length_c   17.436
_cell_angle_alpha   89.147
_cell_angle_beta   98.192
_cell_angle_gamma   118.409
_symmetry_Int_Tables_number   1
_cell_volume   434.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.507  0.737  0.243  1.0
  V  V1  1  0.493  0.263  0.757  1.0
  V  V2  1  0.252  0.121  0.374  1.0
  V  V3  1  0.254  0.620  0.874  1.0
  V  V4  1  0.000  0.500  0.500  1.0
  V  V5  1  0.000  0.000  0.000  1.0
  V  V6  1  0.746  0.380  0.126  1.0
  V  V7  1  0.748  0.879  0.626  1.0
  O  O8  1  0.579  0.589  0.170  1.0
  O  O9  1  0.421  0.411  0.830  1.0
  F  F10  1  0.078  0.539  0.213  1.0
  F  F11  1  0.519  0.058  0.187  1.0
  F  F12  1  0.521  0.557  0.686  1.0
  F  F13  1  0.479  0.443  0.314  1.0
  F  F14  1  0.073  0.337  0.412  1.0
  F  F15  1  0.077  0.035  0.713  1.0
  F  F16  1  0.076  0.836  0.912  1.0
  F  F17  1  0.923  0.965  0.287  1.0
  F  F18  1  0.922  0.461  0.787  1.0
  F  F19  1  0.927  0.663  0.588  1.0
  F  F20  1  0.024  0.813  0.437  1.0
  F  F21  1  0.481  0.942  0.813  1.0
  F  F22  1  0.572  0.284  0.462  1.0
  F  F23  1  0.574  0.095  0.667  1.0
  F  F24  1  0.573  0.784  0.963  1.0
  F  F25  1  0.924  0.164  0.088  1.0
  F  F26  1  0.428  0.716  0.538  1.0
  F  F27  1  0.426  0.905  0.333  1.0
  F  F28  1  0.023  0.312  0.938  1.0
  F  F29  1  0.977  0.688  0.062  1.0
  F  F30  1  0.976  0.187  0.563  1.0
  F  F31  1  0.427  0.216  0.037  1.0
[/CIF]
.