The structure described by DyCo10V2 crystallizes in the orthorhombic Immm space group. Dy(1) is bonded in a 20-coordinate geometry to two equivalent V(1), two equivalent Co(4), four equivalent Co(1), four equivalent Co(2), and eight equivalent Co(3) atoms. V(1) is bonded in a 14-coordinate geometry to one Dy(1), one V(1), two equivalent Co(1), two equivalent Co(2), four equivalent Co(3), and four equivalent Co(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Dy(1), two equivalent V(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2V2Co8 cuboctahedra. In the second Co site, Co(2) is bonded to two equivalent Dy(1), two equivalent V(1), two equivalent Co(1), two equivalent Co(4), and four equivalent Co(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2V2Co8 cuboctahedra. In the third Co site, Co(3) is bonded to two equivalent Dy(1), two equivalent V(1), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2V2Co8 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Dy(1), four equivalent V(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. is represented by the CIF file [CIF]
data_Dy(VCo5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.665
_cell_length_b   6.335
_cell_length_c   6.335
_cell_angle_alpha   97.646
_cell_angle_beta   111.602
_cell_angle_gamma   68.398
_symmetry_Int_Tables_number   1
_cell_volume   161.824
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.000  0.361  0.361  1.0
  V  V2  1  0.000  0.639  0.639  1.0
  Co  Co3  1  0.718  0.782  0.218  1.0
  Co  Co4  1  0.282  0.218  0.782  1.0
  Co  Co5  1  0.500  0.779  0.779  1.0
  Co  Co6  1  0.500  0.221  0.221  1.0
  Co  Co7  1  0.500  0.000  0.500  1.0
  Co  Co8  1  0.000  0.000  0.500  1.0
  Co  Co9  1  0.500  0.500  0.000  1.0
  Co  Co10  1  0.000  0.500  0.000  1.0
  Co  Co11  1  0.641  0.359  0.641  1.0
  Co  Co12  1  0.359  0.641  0.359  1.0
[/CIF]
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The structure described by DyCo10V2 crystallizes in the orthorhombic Immm space group. Dy(1) is bonded in a 20-coordinate geometry to two equivalent V(1), two equivalent Co(4), four equivalent Co(1), four equivalent Co(2), and eight equivalent Co(3) atoms. V(1) is bonded in a 14-coordinate geometry to one Dy(1), one V(1), two equivalent Co(1), two equivalent Co(2), four equivalent Co(3), and four equivalent Co(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Dy(1), two equivalent V(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2V2Co8 cuboctahedra. In the second Co site, Co(2) is bonded to two equivalent Dy(1), two equivalent V(1), two equivalent Co(1), two equivalent Co(4), and four equivalent Co(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2V2Co8 cuboctahedra. In the third Co site, Co(3) is bonded to two equivalent Dy(1), two equivalent V(1), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2V2Co8 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Dy(1), four equivalent V(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. is represented by the CIF file [CIF]
data_Dy(VCo5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.665
_cell_length_b   6.335
_cell_length_c   6.335
_cell_angle_alpha   97.646
_cell_angle_beta   111.602
_cell_angle_gamma   68.398
_symmetry_Int_Tables_number   1
_cell_volume   161.824
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.000  0.361  0.361  1.0
  V  V2  1  0.000  0.639  0.639  1.0
  Co  Co3  1  0.718  0.782  0.218  1.0
  Co  Co4  1  0.282  0.218  0.782  1.0
  Co  Co5  1  0.500  0.779  0.779  1.0
  Co  Co6  1  0.500  0.221  0.221  1.0
  Co  Co7  1  0.500  0.000  0.500  1.0
  Co  Co8  1  0.000  0.000  0.500  1.0
  Co  Co9  1  0.500  0.500  0.000  1.0
  Co  Co10  1  0.000  0.500  0.000  1.0
  Co  Co11  1  0.641  0.359  0.641  1.0
  Co  Co12  1  0.359  0.641  0.359  1.0
[/CIF]
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