The compound described by VZn2SbO6 crystallizes in the monoclinic P2_1/m space group. V(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, corners with four equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 40-45°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form distorted ZnO4 trigonal pyramids that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with two equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 61-84°. In the second Zn site, Zn(2) is bonded to one O(1), one O(2), and two equivalent O(4) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with two equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 67-83°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra, corners with four equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 44-46°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Zn(1), one Zn(2), and two equivalent Sb(1) atoms to form OZn2Sb2 tetrahedra that share corners with two equivalent O(2)V2Zn2 tetrahedra and corners with two equivalent O(1)Zn2Sb2 tetrahedra. In the second O site, O(2) is bonded to two equivalent V(1), one Zn(1), and one Zn(2) atom to form distorted OV2Zn2 tetrahedra that share corners with two equivalent O(2)V2Zn2 tetrahedra and corners with two equivalent O(1)Zn2Sb2 tetrahedra. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one Zn(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one Zn(2), and one Sb(1) atom. is represented by the CIF file [CIF]
data_VZn2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.290
_cell_length_b   5.311
_cell_length_c   7.762
_cell_angle_alpha   90.001
_cell_angle_beta   90.001
_cell_angle_gamma   89.087
_symmetry_Int_Tables_number   1
_cell_volume   218.068
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.130  0.581  0.750  1.0
  O  O1  1  0.870  0.419  0.250  1.0
  O  O2  1  0.608  0.920  0.250  1.0
  O  O3  1  0.392  0.080  0.750  1.0
  O  O4  1  0.677  0.674  0.566  1.0
  O  O5  1  0.323  0.326  0.066  1.0
  O  O6  1  0.677  0.674  0.934  1.0
  O  O7  1  0.323  0.326  0.434  1.0
  O  O8  1  0.835  0.183  0.932  1.0
  O  O9  1  0.165  0.817  0.432  1.0
  O  O10  1  0.835  0.183  0.568  1.0
  O  O11  1  0.165  0.817  0.068  1.0
  Sb  Sb12  1  1.000  0.500  0.500  1.0
  Sb  Sb13  1  0.000  0.500  0.000  1.0
  V  V14  1  0.500  0.000  0.500  1.0
  V  V15  1  0.500  0.000  1.000  1.0
  Zn  Zn16  1  0.486  0.551  0.250  1.0
  Zn  Zn17  1  0.514  0.449  0.750  1.0
  Zn  Zn18  1  0.971  0.014  0.250  1.0
  Zn  Zn19  1  0.029  0.986  0.750  1.0
[/CIF]
.
The compound described by VZn2SbO6 crystallizes in the monoclinic P2_1/m space group. V(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, corners with four equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 40-45°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form distorted ZnO4 trigonal pyramids that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with two equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 61-84°. In the second Zn site, Zn(2) is bonded to one O(1), one O(2), and two equivalent O(4) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with two equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 67-83°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra, corners with four equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 44-46°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Zn(1), one Zn(2), and two equivalent Sb(1) atoms to form OZn2Sb2 tetrahedra that share corners with two equivalent O(2)V2Zn2 tetrahedra and corners with two equivalent O(1)Zn2Sb2 tetrahedra. In the second O site, O(2) is bonded to two equivalent V(1), one Zn(1), and one Zn(2) atom to form distorted OV2Zn2 tetrahedra that share corners with two equivalent O(2)V2Zn2 tetrahedra and corners with two equivalent O(1)Zn2Sb2 tetrahedra. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one Zn(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one Zn(2), and one Sb(1) atom. is represented by the CIF file [CIF]
data_VZn2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.290
_cell_length_b   5.311
_cell_length_c   7.762
_cell_angle_alpha   90.001
_cell_angle_beta   90.001
_cell_angle_gamma   89.087
_symmetry_Int_Tables_number   1
_cell_volume   218.068
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.130  0.581  0.750  1.0
  O  O1  1  0.870  0.419  0.250  1.0
  O  O2  1  0.608  0.920  0.250  1.0
  O  O3  1  0.392  0.080  0.750  1.0
  O  O4  1  0.677  0.674  0.566  1.0
  O  O5  1  0.323  0.326  0.066  1.0
  O  O6  1  0.677  0.674  0.934  1.0
  O  O7  1  0.323  0.326  0.434  1.0
  O  O8  1  0.835  0.183  0.932  1.0
  O  O9  1  0.165  0.817  0.432  1.0
  O  O10  1  0.835  0.183  0.568  1.0
  O  O11  1  0.165  0.817  0.068  1.0
  Sb  Sb12  1  1.000  0.500  0.500  1.0
  Sb  Sb13  1  0.000  0.500  0.000  1.0
  V  V14  1  0.500  0.000  0.500  1.0
  V  V15  1  0.500  0.000  1.000  1.0
  Zn  Zn16  1  0.486  0.551  0.250  1.0
  Zn  Zn17  1  0.514  0.449  0.750  1.0
  Zn  Zn18  1  0.971  0.014  0.250  1.0
  Zn  Zn19  1  0.029  0.986  0.750  1.0
[/CIF]
.