The material structure described by Li3VMn(PO4)3 crystallizes in the monoclinic Cc space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(6), and one O(7) atom. In the second Li site, Li(2) is bonded to one O(10), one O(11), one O(4), one O(5), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  a faceface with one V(1)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(4), one O(5), one O(7), and one O(9) atom. V(1) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. Mn(1) is bonded to one O(11), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-49°. In the second P site, P(2) is bonded to one O(11), one O(12), one O(2), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-48°. In the third P site, P(3) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-49°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(2) atom. In the third O site, O(3) is bonded in a linear geometry to one Mn(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), one V(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal bipyramidal geometry to one Li(1), one Li(2), one Li(3), one Mn(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a linear geometry to one V(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(3), one Mn(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one Li(2), one Li(3), one V(1), and one P(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(1), and one P(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(3), one V(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3MnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.506
_cell_length_b   8.506
_cell_length_c   8.616
_cell_angle_alpha   61.680
_cell_angle_beta   61.680
_cell_angle_gamma   63.159
_symmetry_Int_Tables_number   1
_cell_volume   461.961
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.129  0.252  0.843  1.0
  Li  Li1  1  0.500  0.997  0.999  1.0
  Li  Li2  1  0.252  0.129  0.343  1.0
  Li  Li3  1  0.741  0.872  0.659  1.0
  Li  Li4  1  0.997  0.500  0.499  1.0
  Li  Li5  1  0.872  0.741  0.159  1.0
  Mn  Mn6  1  0.362  0.857  0.850  1.0
  Mn  Mn7  1  0.857  0.362  0.350  1.0
  V  V8  1  0.144  0.637  0.645  1.0
  V  V9  1  0.637  0.144  0.145  1.0
  P  P10  1  0.752  0.550  0.965  1.0
  P  P11  1  0.052  0.947  0.248  1.0
  P  P12  1  0.451  0.251  0.536  1.0
  P  P13  1  0.550  0.752  0.465  1.0
  P  P14  1  0.947  0.052  0.748  1.0
  P  P15  1  0.251  0.451  0.036  1.0
  O  O16  1  0.187  0.464  0.889  1.0
  O  O17  1  0.107  0.034  0.797  1.0
  O  O18  1  0.318  0.616  0.976  1.0
  O  O19  1  0.063  0.760  0.417  1.0
  O  O20  1  0.611  0.745  0.925  1.0
  O  O21  1  0.257  0.396  0.576  1.0
  O  O22  1  0.453  0.086  0.728  1.0
  O  O23  1  0.034  0.107  0.297  1.0
  O  O24  1  0.760  0.063  0.917  1.0
  O  O25  1  0.386  0.682  0.528  1.0
  O  O26  1  0.086  0.453  0.228  1.0
  O  O27  1  0.535  0.815  0.615  1.0
  O  O28  1  0.464  0.187  0.389  1.0
  O  O29  1  0.916  0.541  0.776  1.0
  O  O30  1  0.616  0.318  0.476  1.0
  O  O31  1  0.237  0.936  0.077  1.0
  O  O32  1  0.977  0.884  0.702  1.0
  O  O33  1  0.541  0.916  0.276  1.0
  O  O34  1  0.745  0.611  0.425  1.0
  O  O35  1  0.396  0.257  0.076  1.0
  O  O36  1  0.936  0.237  0.577  1.0
  O  O37  1  0.682  0.386  0.028  1.0
  O  O38  1  0.884  0.977  0.202  1.0
  O  O39  1  0.815  0.535  0.115  1.0
[/CIF]
.
The material structure described by Li3VMn(PO4)3 crystallizes in the monoclinic Cc space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(6), and one O(7) atom. In the second Li site, Li(2) is bonded to one O(10), one O(11), one O(4), one O(5), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  a faceface with one V(1)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(4), one O(5), one O(7), and one O(9) atom. V(1) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. Mn(1) is bonded to one O(11), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-49°. In the second P site, P(2) is bonded to one O(11), one O(12), one O(2), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-48°. In the third P site, P(3) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-49°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(2) atom. In the third O site, O(3) is bonded in a linear geometry to one Mn(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), one V(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal bipyramidal geometry to one Li(1), one Li(2), one Li(3), one Mn(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a linear geometry to one V(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(3), one Mn(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one Li(2), one Li(3), one V(1), and one P(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(1), and one P(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(3), one V(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3MnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.506
_cell_length_b   8.506
_cell_length_c   8.616
_cell_angle_alpha   61.680
_cell_angle_beta   61.680
_cell_angle_gamma   63.159
_symmetry_Int_Tables_number   1
_cell_volume   461.961
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.129  0.252  0.843  1.0
  Li  Li1  1  0.500  0.997  0.999  1.0
  Li  Li2  1  0.252  0.129  0.343  1.0
  Li  Li3  1  0.741  0.872  0.659  1.0
  Li  Li4  1  0.997  0.500  0.499  1.0
  Li  Li5  1  0.872  0.741  0.159  1.0
  Mn  Mn6  1  0.362  0.857  0.850  1.0
  Mn  Mn7  1  0.857  0.362  0.350  1.0
  V  V8  1  0.144  0.637  0.645  1.0
  V  V9  1  0.637  0.144  0.145  1.0
  P  P10  1  0.752  0.550  0.965  1.0
  P  P11  1  0.052  0.947  0.248  1.0
  P  P12  1  0.451  0.251  0.536  1.0
  P  P13  1  0.550  0.752  0.465  1.0
  P  P14  1  0.947  0.052  0.748  1.0
  P  P15  1  0.251  0.451  0.036  1.0
  O  O16  1  0.187  0.464  0.889  1.0
  O  O17  1  0.107  0.034  0.797  1.0
  O  O18  1  0.318  0.616  0.976  1.0
  O  O19  1  0.063  0.760  0.417  1.0
  O  O20  1  0.611  0.745  0.925  1.0
  O  O21  1  0.257  0.396  0.576  1.0
  O  O22  1  0.453  0.086  0.728  1.0
  O  O23  1  0.034  0.107  0.297  1.0
  O  O24  1  0.760  0.063  0.917  1.0
  O  O25  1  0.386  0.682  0.528  1.0
  O  O26  1  0.086  0.453  0.228  1.0
  O  O27  1  0.535  0.815  0.615  1.0
  O  O28  1  0.464  0.187  0.389  1.0
  O  O29  1  0.916  0.541  0.776  1.0
  O  O30  1  0.616  0.318  0.476  1.0
  O  O31  1  0.237  0.936  0.077  1.0
  O  O32  1  0.977  0.884  0.702  1.0
  O  O33  1  0.541  0.916  0.276  1.0
  O  O34  1  0.745  0.611  0.425  1.0
  O  O35  1  0.396  0.257  0.076  1.0
  O  O36  1  0.936  0.237  0.577  1.0
  O  O37  1  0.682  0.386  0.028  1.0
  O  O38  1  0.884  0.977  0.202  1.0
  O  O39  1  0.815  0.535  0.115  1.0
[/CIF]
.