The material described by Ni(NO4)2(PO2F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four fluoro(hydroxy)oxophosphanium molecules and two Ni(NO4)2 clusters. In each Ni(NO4)2 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(6) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(4) is bonded in a 2-coordinate geometry to one Ni(1) and one O(5) atom. In the third O site, O(5) is bonded in a 2-coordinate geometry to one Ni(1) and one O(4) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Ni(1) and one N(1) atom. is represented by the CIF card [CIF]
data_NiP2N2(O6F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.826
_cell_length_b   5.996
_cell_length_c   9.919
_cell_angle_alpha   87.694
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   762.185
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.500  0.000  0.500  1.0
  Ni  Ni1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.595  0.784  0.103  1.0
  P  P3  1  0.095  0.216  0.397  1.0
  P  P4  1  0.405  0.216  0.897  1.0
  P  P5  1  0.905  0.784  0.603  1.0
  N  N6  1  0.778  0.325  0.900  1.0
  N  N7  1  0.278  0.675  0.600  1.0
  N  N8  1  0.222  0.675  0.100  1.0
  N  N9  1  0.722  0.325  0.400  1.0
  O  O10  1  0.542  0.610  0.186  1.0
  O  O11  1  0.042  0.390  0.314  1.0
  O  O12  1  0.458  0.390  0.814  1.0
  O  O13  1  0.958  0.610  0.686  1.0
  O  O14  1  0.673  0.953  0.129  1.0
  O  O15  1  0.173  0.047  0.371  1.0
  O  O16  1  0.327  0.047  0.871  1.0
  O  O17  1  0.827  0.953  0.629  1.0
  O  O18  1  0.761  0.418  0.004  1.0
  O  O19  1  0.261  0.582  0.496  1.0
  O  O20  1  0.239  0.582  0.996  1.0
  O  O21  1  0.739  0.418  0.504  1.0
  O  O22  1  0.590  0.783  0.569  1.0
  O  O23  1  0.090  0.217  0.931  1.0
  O  O24  1  0.410  0.217  0.431  1.0
  O  O25  1  0.910  0.783  0.069  1.0
  O  O26  1  0.586  0.955  0.649  1.0
  O  O27  1  0.086  0.045  0.851  1.0
  O  O28  1  0.414  0.045  0.351  1.0
  O  O29  1  0.914  0.955  0.149  1.0
  O  O30  1  0.347  0.806  0.629  1.0
  O  O31  1  0.847  0.194  0.871  1.0
  O  O32  1  0.653  0.194  0.371  1.0
  O  O33  1  0.153  0.806  0.129  1.0
  F  F34  1  0.552  0.800  0.955  1.0
  F  F35  1  0.052  0.200  0.545  1.0
  F  F36  1  0.448  0.200  0.045  1.0
  F  F37  1  0.948  0.800  0.455  1.0
[/CIF]
.
The material described by Ni(NO4)2(PO2F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four fluoro(hydroxy)oxophosphanium molecules and two Ni(NO4)2 clusters. In each Ni(NO4)2 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(6) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(4) is bonded in a 2-coordinate geometry to one Ni(1) and one O(5) atom. In the third O site, O(5) is bonded in a 2-coordinate geometry to one Ni(1) and one O(4) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Ni(1) and one N(1) atom. is represented by the CIF card [CIF]
data_NiP2N2(O6F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.826
_cell_length_b   5.996
_cell_length_c   9.919
_cell_angle_alpha   87.694
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   762.185
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.500  0.000  0.500  1.0
  Ni  Ni1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.595  0.784  0.103  1.0
  P  P3  1  0.095  0.216  0.397  1.0
  P  P4  1  0.405  0.216  0.897  1.0
  P  P5  1  0.905  0.784  0.603  1.0
  N  N6  1  0.778  0.325  0.900  1.0
  N  N7  1  0.278  0.675  0.600  1.0
  N  N8  1  0.222  0.675  0.100  1.0
  N  N9  1  0.722  0.325  0.400  1.0
  O  O10  1  0.542  0.610  0.186  1.0
  O  O11  1  0.042  0.390  0.314  1.0
  O  O12  1  0.458  0.390  0.814  1.0
  O  O13  1  0.958  0.610  0.686  1.0
  O  O14  1  0.673  0.953  0.129  1.0
  O  O15  1  0.173  0.047  0.371  1.0
  O  O16  1  0.327  0.047  0.871  1.0
  O  O17  1  0.827  0.953  0.629  1.0
  O  O18  1  0.761  0.418  0.004  1.0
  O  O19  1  0.261  0.582  0.496  1.0
  O  O20  1  0.239  0.582  0.996  1.0
  O  O21  1  0.739  0.418  0.504  1.0
  O  O22  1  0.590  0.783  0.569  1.0
  O  O23  1  0.090  0.217  0.931  1.0
  O  O24  1  0.410  0.217  0.431  1.0
  O  O25  1  0.910  0.783  0.069  1.0
  O  O26  1  0.586  0.955  0.649  1.0
  O  O27  1  0.086  0.045  0.851  1.0
  O  O28  1  0.414  0.045  0.351  1.0
  O  O29  1  0.914  0.955  0.149  1.0
  O  O30  1  0.347  0.806  0.629  1.0
  O  O31  1  0.847  0.194  0.871  1.0
  O  O32  1  0.653  0.194  0.371  1.0
  O  O33  1  0.153  0.806  0.129  1.0
  F  F34  1  0.552  0.800  0.955  1.0
  F  F35  1  0.052  0.200  0.545  1.0
  F  F36  1  0.448  0.200  0.045  1.0
  F  F37  1  0.948  0.800  0.455  1.0
[/CIF]
.