The material structure described by K2Cu3ZnP3O12F crystallizes in the monoclinic P2_1/m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 11-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(4), two equivalent O(5), two equivalent O(6), and two equivalent F(1) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(4), two equivalent O(6), and four equivalent O(2) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(2), one O(5), one O(7), and one F(1) atom to form distorted CuO4F trigonal bipyramids that share  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and  an edgeedge with one Cu(1)O4F trigonal bipyramid. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to two equivalent O(5) and two equivalent O(6) atoms. Zn(1) is bonded to one O(3), one O(7), and two equivalent O(4) atoms to form ZnO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent Cu(1)O4F trigonal bipyramids. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O4 tetrahedra and corners with two equivalent Cu(1)O4F trigonal bipyramids. In the second P site, P(2) is bonded to one O(3), one O(7), and two equivalent O(1) atoms to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra and corners with four equivalent Cu(1)O4F trigonal bipyramids. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one Cu(1), and one P(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent K(2), one Cu(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one Zn(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one K(1), one K(2), one Zn(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one K(1), one Cu(1), one Cu(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one K(2), one Cu(2), and one P(1) atom. In the seventh O site, O(7) is bonded to two equivalent Cu(1), one Zn(1), and one P(2) atom to form distorted OZnCu2P tetrahedra that share  an edgeedge with one F(1)K2Cu2 tetrahedra. F(1) is bonded to two equivalent K(1) and two equivalent Cu(1) atoms to form distorted FK2Cu2 tetrahedra that share corners with two equivalent F(1)K2Cu2 tetrahedra and  an edgeedge with one O(7)ZnCu2P tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2ZnCu3P3O12F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.366
_cell_length_b   4.880
_cell_length_c   7.870
_cell_angle_alpha   89.911
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   551.701
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.448  0.361  1.0
  K  K1  1  0.500  0.500  0.000  1.0
  K  K2  1  0.750  0.552  0.639  1.0
  K  K3  1  0.000  0.500  0.000  1.0
  Zn  Zn4  1  0.750  0.032  0.954  1.0
  Zn  Zn5  1  0.250  0.968  0.046  1.0
  Cu  Cu6  1  0.638  0.066  0.356  1.0
  Cu  Cu7  1  0.862  0.066  0.356  1.0
  Cu  Cu8  1  0.138  0.934  0.644  1.0
  Cu  Cu9  1  0.362  0.934  0.644  1.0
  Cu  Cu10  1  0.000  0.500  0.500  1.0
  Cu  Cu11  1  0.500  0.500  0.500  1.0
  P  P12  1  0.066  0.997  0.293  1.0
  P  P13  1  0.750  0.528  0.181  1.0
  P  P14  1  0.934  0.003  0.707  1.0
  P  P15  1  0.250  0.472  0.819  1.0
  P  P16  1  0.566  0.003  0.707  1.0
  P  P17  1  0.434  0.997  0.293  1.0
  O  O18  1  0.338  0.563  0.724  1.0
  O  O19  1  0.662  0.437  0.276  1.0
  O  O20  1  0.530  0.057  0.217  1.0
  O  O21  1  0.750  0.422  0.997  1.0
  O  O22  1  0.860  0.916  0.834  1.0
  O  O23  1  0.579  0.831  0.539  1.0
  O  O24  1  0.250  0.578  0.003  1.0
  O  O25  1  0.470  0.943  0.783  1.0
  O  O26  1  0.923  0.308  0.661  1.0
  O  O27  1  0.250  0.153  0.825  1.0
  O  O28  1  0.360  0.084  0.166  1.0
  O  O29  1  0.162  0.563  0.724  1.0
  O  O30  1  0.421  0.169  0.461  1.0
  O  O31  1  0.577  0.308  0.661  1.0
  O  O32  1  0.030  0.943  0.783  1.0
  O  O33  1  0.423  0.692  0.339  1.0
  O  O34  1  0.921  0.831  0.539  1.0
  O  O35  1  0.640  0.916  0.834  1.0
  O  O36  1  0.970  0.057  0.217  1.0
  O  O37  1  0.750  0.847  0.175  1.0
  O  O38  1  0.079  0.169  0.461  1.0
  O  O39  1  0.838  0.437  0.276  1.0
  O  O40  1  0.077  0.692  0.339  1.0
  O  O41  1  0.140  0.084  0.166  1.0
  F  F42  1  0.750  0.061  0.493  1.0
  F  F43  1  0.250  0.939  0.507  1.0
[/CIF]
.
The material structure described by K2Cu3ZnP3O12F crystallizes in the monoclinic P2_1/m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 11-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(4), two equivalent O(5), two equivalent O(6), and two equivalent F(1) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(4), two equivalent O(6), and four equivalent O(2) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(2), one O(5), one O(7), and one F(1) atom to form distorted CuO4F trigonal bipyramids that share  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and  an edgeedge with one Cu(1)O4F trigonal bipyramid. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to two equivalent O(5) and two equivalent O(6) atoms. Zn(1) is bonded to one O(3), one O(7), and two equivalent O(4) atoms to form ZnO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent Cu(1)O4F trigonal bipyramids. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O4 tetrahedra and corners with two equivalent Cu(1)O4F trigonal bipyramids. In the second P site, P(2) is bonded to one O(3), one O(7), and two equivalent O(1) atoms to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra and corners with four equivalent Cu(1)O4F trigonal bipyramids. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one Cu(1), and one P(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent K(2), one Cu(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one Zn(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one K(1), one K(2), one Zn(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one K(1), one Cu(1), one Cu(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one K(2), one Cu(2), and one P(1) atom. In the seventh O site, O(7) is bonded to two equivalent Cu(1), one Zn(1), and one P(2) atom to form distorted OZnCu2P tetrahedra that share  an edgeedge with one F(1)K2Cu2 tetrahedra. F(1) is bonded to two equivalent K(1) and two equivalent Cu(1) atoms to form distorted FK2Cu2 tetrahedra that share corners with two equivalent F(1)K2Cu2 tetrahedra and  an edgeedge with one O(7)ZnCu2P tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2ZnCu3P3O12F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.366
_cell_length_b   4.880
_cell_length_c   7.870
_cell_angle_alpha   89.911
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   551.701
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.448  0.361  1.0
  K  K1  1  0.500  0.500  0.000  1.0
  K  K2  1  0.750  0.552  0.639  1.0
  K  K3  1  0.000  0.500  0.000  1.0
  Zn  Zn4  1  0.750  0.032  0.954  1.0
  Zn  Zn5  1  0.250  0.968  0.046  1.0
  Cu  Cu6  1  0.638  0.066  0.356  1.0
  Cu  Cu7  1  0.862  0.066  0.356  1.0
  Cu  Cu8  1  0.138  0.934  0.644  1.0
  Cu  Cu9  1  0.362  0.934  0.644  1.0
  Cu  Cu10  1  0.000  0.500  0.500  1.0
  Cu  Cu11  1  0.500  0.500  0.500  1.0
  P  P12  1  0.066  0.997  0.293  1.0
  P  P13  1  0.750  0.528  0.181  1.0
  P  P14  1  0.934  0.003  0.707  1.0
  P  P15  1  0.250  0.472  0.819  1.0
  P  P16  1  0.566  0.003  0.707  1.0
  P  P17  1  0.434  0.997  0.293  1.0
  O  O18  1  0.338  0.563  0.724  1.0
  O  O19  1  0.662  0.437  0.276  1.0
  O  O20  1  0.530  0.057  0.217  1.0
  O  O21  1  0.750  0.422  0.997  1.0
  O  O22  1  0.860  0.916  0.834  1.0
  O  O23  1  0.579  0.831  0.539  1.0
  O  O24  1  0.250  0.578  0.003  1.0
  O  O25  1  0.470  0.943  0.783  1.0
  O  O26  1  0.923  0.308  0.661  1.0
  O  O27  1  0.250  0.153  0.825  1.0
  O  O28  1  0.360  0.084  0.166  1.0
  O  O29  1  0.162  0.563  0.724  1.0
  O  O30  1  0.421  0.169  0.461  1.0
  O  O31  1  0.577  0.308  0.661  1.0
  O  O32  1  0.030  0.943  0.783  1.0
  O  O33  1  0.423  0.692  0.339  1.0
  O  O34  1  0.921  0.831  0.539  1.0
  O  O35  1  0.640  0.916  0.834  1.0
  O  O36  1  0.970  0.057  0.217  1.0
  O  O37  1  0.750  0.847  0.175  1.0
  O  O38  1  0.079  0.169  0.461  1.0
  O  O39  1  0.838  0.437  0.276  1.0
  O  O40  1  0.077  0.692  0.339  1.0
  O  O41  1  0.140  0.084  0.166  1.0
  F  F42  1  0.750  0.061  0.493  1.0
  F  F43  1  0.250  0.939  0.507  1.0
[/CIF]
.