The crystal structure described by LiVP3HO10 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 3-coordinate geometry to one O(1), one O(8), and one O(9) atom. V(1) is bonded to one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form VO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one V(1)O5 trigonal bipyramid. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent V(1)O5 trigonal bipyramids. In the third P site, P(3) is bonded to one O(10), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent V(1)O5 trigonal bipyramids. H(1) is bonded in a single-bond geometry to one O(4) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one V(1) and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one P(3) atom. is represented by the CIF card [CIF]
data_LiVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.512
_cell_length_b   7.908
_cell_length_c   8.553
_cell_angle_alpha   96.178
_cell_angle_beta   97.315
_cell_angle_gamma   110.479
_symmetry_Int_Tables_number   1
_cell_volume   403.760
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.707  0.969  0.700  1.0
  Li  Li1  1  0.293  0.031  0.300  1.0
  V  V2  1  0.130  0.338  0.664  1.0
  V  V3  1  0.870  0.662  0.336  1.0
  P  P4  1  0.734  0.903  0.078  1.0
  P  P5  1  0.372  0.670  0.229  1.0
  P  P6  1  0.808  0.214  0.330  1.0
  P  P7  1  0.192  0.786  0.670  1.0
  P  P8  1  0.628  0.330  0.771  1.0
  P  P9  1  0.266  0.097  0.922  1.0
  H  H10  1  0.119  0.399  0.129  1.0
  H  H11  1  0.881  0.601  0.871  1.0
  O  O12  1  0.730  0.885  0.904  1.0
  O  O13  1  0.552  0.645  0.344  1.0
  O  O14  1  0.484  0.812  0.113  1.0
  O  O15  1  0.244  0.492  0.097  1.0
  O  O16  1  0.119  0.176  0.823  1.0
  O  O17  1  0.027  0.225  0.440  1.0
  O  O18  1  0.819  0.116  0.153  1.0
  O  O19  1  0.401  0.896  0.620  1.0
  O  O20  1  0.209  0.737  0.301  1.0
  O  O21  1  0.838  0.408  0.296  1.0
  O  O22  1  0.162  0.592  0.704  1.0
  O  O23  1  0.791  0.263  0.699  1.0
  O  O24  1  0.599  0.104  0.380  1.0
  O  O25  1  0.181  0.884  0.847  1.0
  O  O26  1  0.973  0.775  0.560  1.0
  O  O27  1  0.881  0.824  0.177  1.0
  O  O28  1  0.756  0.508  0.903  1.0
  O  O29  1  0.516  0.188  0.887  1.0
  O  O30  1  0.448  0.355  0.656  1.0
  O  O31  1  0.270  0.115  0.096  1.0
[/CIF]
.
The crystal structure described by LiVP3HO10 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 3-coordinate geometry to one O(1), one O(8), and one O(9) atom. V(1) is bonded to one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form VO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one V(1)O5 trigonal bipyramid. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent V(1)O5 trigonal bipyramids. In the third P site, P(3) is bonded to one O(10), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent V(1)O5 trigonal bipyramids. H(1) is bonded in a single-bond geometry to one O(4) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one V(1) and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one P(3) atom. is represented by the CIF card [CIF]
data_LiVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.512
_cell_length_b   7.908
_cell_length_c   8.553
_cell_angle_alpha   96.178
_cell_angle_beta   97.315
_cell_angle_gamma   110.479
_symmetry_Int_Tables_number   1
_cell_volume   403.760
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.707  0.969  0.700  1.0
  Li  Li1  1  0.293  0.031  0.300  1.0
  V  V2  1  0.130  0.338  0.664  1.0
  V  V3  1  0.870  0.662  0.336  1.0
  P  P4  1  0.734  0.903  0.078  1.0
  P  P5  1  0.372  0.670  0.229  1.0
  P  P6  1  0.808  0.214  0.330  1.0
  P  P7  1  0.192  0.786  0.670  1.0
  P  P8  1  0.628  0.330  0.771  1.0
  P  P9  1  0.266  0.097  0.922  1.0
  H  H10  1  0.119  0.399  0.129  1.0
  H  H11  1  0.881  0.601  0.871  1.0
  O  O12  1  0.730  0.885  0.904  1.0
  O  O13  1  0.552  0.645  0.344  1.0
  O  O14  1  0.484  0.812  0.113  1.0
  O  O15  1  0.244  0.492  0.097  1.0
  O  O16  1  0.119  0.176  0.823  1.0
  O  O17  1  0.027  0.225  0.440  1.0
  O  O18  1  0.819  0.116  0.153  1.0
  O  O19  1  0.401  0.896  0.620  1.0
  O  O20  1  0.209  0.737  0.301  1.0
  O  O21  1  0.838  0.408  0.296  1.0
  O  O22  1  0.162  0.592  0.704  1.0
  O  O23  1  0.791  0.263  0.699  1.0
  O  O24  1  0.599  0.104  0.380  1.0
  O  O25  1  0.181  0.884  0.847  1.0
  O  O26  1  0.973  0.775  0.560  1.0
  O  O27  1  0.881  0.824  0.177  1.0
  O  O28  1  0.756  0.508  0.903  1.0
  O  O29  1  0.516  0.188  0.887  1.0
  O  O30  1  0.448  0.355  0.656  1.0
  O  O31  1  0.270  0.115  0.096  1.0
[/CIF]
.