The crystal structure described by PbMn(SO4)2 crystallizes in the tetragonal P4_12_12 space group. Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with six equivalent S(1)O4 tetrahedra. Pb(1) is bonded in a 6-coordinate geometry to two equivalent O(4) and four equivalent O(1) atoms. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-51°. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the second O site, O(4) is bonded in a 3-coordinate geometry to one Mn(1), one Pb(1), and one S(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one S(1) atom. is represented by the CIF card [CIF]
data_MnPb(SO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.859
_cell_length_b   6.859
_cell_length_c   13.990
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   658.178
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.166  0.166  0.000  1.0
  Mn  Mn1  1  0.834  0.834  0.500  1.0
  Mn  Mn2  1  0.334  0.666  0.250  1.0
  Mn  Mn3  1  0.666  0.334  0.750  1.0
  Pb  Pb4  1  0.750  0.750  0.000  1.0
  Pb  Pb5  1  0.250  0.250  0.500  1.0
  Pb  Pb6  1  0.750  0.250  0.250  1.0
  Pb  Pb7  1  0.250  0.750  0.750  1.0
  S  S8  1  0.247  0.174  0.243  1.0
  S  S9  1  0.753  0.826  0.743  1.0
  S  S10  1  0.326  0.747  0.493  1.0
  S  S11  1  0.253  0.674  0.007  1.0
  S  S12  1  0.674  0.253  0.993  1.0
  S  S13  1  0.747  0.326  0.507  1.0
  S  S14  1  0.174  0.247  0.757  1.0
  S  S15  1  0.826  0.753  0.257  1.0
  O  O16  1  0.115  0.207  0.326  1.0
  O  O17  1  0.885  0.793  0.826  1.0
  O  O18  1  0.293  0.615  0.576  1.0
  O  O19  1  0.385  0.707  0.924  1.0
  O  O20  1  0.707  0.385  0.076  1.0
  O  O21  1  0.615  0.293  0.424  1.0
  O  O22  1  0.207  0.115  0.674  1.0
  O  O23  1  0.793  0.885  0.174  1.0
  O  O24  1  0.124  0.171  0.155  1.0
  O  O25  1  0.876  0.829  0.655  1.0
  O  O26  1  0.329  0.624  0.405  1.0
  O  O27  1  0.376  0.671  0.095  1.0
  O  O28  1  0.671  0.376  0.905  1.0
  O  O29  1  0.624  0.329  0.595  1.0
  O  O30  1  0.171  0.124  0.845  1.0
  O  O31  1  0.829  0.876  0.345  1.0
  O  O32  1  0.491  0.140  0.004  1.0
  O  O33  1  0.509  0.860  0.504  1.0
  O  O34  1  0.360  0.991  0.254  1.0
  O  O35  1  0.009  0.640  0.246  1.0
  O  O36  1  0.640  0.009  0.754  1.0
  O  O37  1  0.991  0.360  0.746  1.0
  O  O38  1  0.140  0.491  0.996  1.0
  O  O39  1  0.860  0.509  0.496  1.0
  O  O40  1  0.389  0.340  0.237  1.0
  O  O41  1  0.611  0.660  0.737  1.0
  O  O42  1  0.160  0.889  0.487  1.0
  O  O43  1  0.111  0.840  0.013  1.0
  O  O44  1  0.840  0.111  0.987  1.0
  O  O45  1  0.889  0.160  0.513  1.0
  O  O46  1  0.340  0.389  0.763  1.0
  O  O47  1  0.660  0.611  0.263  1.0
[/CIF]
.
The crystal structure described by PbMn(SO4)2 crystallizes in the tetragonal P4_12_12 space group. Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with six equivalent S(1)O4 tetrahedra. Pb(1) is bonded in a 6-coordinate geometry to two equivalent O(4) and four equivalent O(1) atoms. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-51°. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the second O site, O(4) is bonded in a 3-coordinate geometry to one Mn(1), one Pb(1), and one S(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one S(1) atom. is represented by the CIF card [CIF]
data_MnPb(SO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.859
_cell_length_b   6.859
_cell_length_c   13.990
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   658.178
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.166  0.166  0.000  1.0
  Mn  Mn1  1  0.834  0.834  0.500  1.0
  Mn  Mn2  1  0.334  0.666  0.250  1.0
  Mn  Mn3  1  0.666  0.334  0.750  1.0
  Pb  Pb4  1  0.750  0.750  0.000  1.0
  Pb  Pb5  1  0.250  0.250  0.500  1.0
  Pb  Pb6  1  0.750  0.250  0.250  1.0
  Pb  Pb7  1  0.250  0.750  0.750  1.0
  S  S8  1  0.247  0.174  0.243  1.0
  S  S9  1  0.753  0.826  0.743  1.0
  S  S10  1  0.326  0.747  0.493  1.0
  S  S11  1  0.253  0.674  0.007  1.0
  S  S12  1  0.674  0.253  0.993  1.0
  S  S13  1  0.747  0.326  0.507  1.0
  S  S14  1  0.174  0.247  0.757  1.0
  S  S15  1  0.826  0.753  0.257  1.0
  O  O16  1  0.115  0.207  0.326  1.0
  O  O17  1  0.885  0.793  0.826  1.0
  O  O18  1  0.293  0.615  0.576  1.0
  O  O19  1  0.385  0.707  0.924  1.0
  O  O20  1  0.707  0.385  0.076  1.0
  O  O21  1  0.615  0.293  0.424  1.0
  O  O22  1  0.207  0.115  0.674  1.0
  O  O23  1  0.793  0.885  0.174  1.0
  O  O24  1  0.124  0.171  0.155  1.0
  O  O25  1  0.876  0.829  0.655  1.0
  O  O26  1  0.329  0.624  0.405  1.0
  O  O27  1  0.376  0.671  0.095  1.0
  O  O28  1  0.671  0.376  0.905  1.0
  O  O29  1  0.624  0.329  0.595  1.0
  O  O30  1  0.171  0.124  0.845  1.0
  O  O31  1  0.829  0.876  0.345  1.0
  O  O32  1  0.491  0.140  0.004  1.0
  O  O33  1  0.509  0.860  0.504  1.0
  O  O34  1  0.360  0.991  0.254  1.0
  O  O35  1  0.009  0.640  0.246  1.0
  O  O36  1  0.640  0.009  0.754  1.0
  O  O37  1  0.991  0.360  0.746  1.0
  O  O38  1  0.140  0.491  0.996  1.0
  O  O39  1  0.860  0.509  0.496  1.0
  O  O40  1  0.389  0.340  0.237  1.0
  O  O41  1  0.611  0.660  0.737  1.0
  O  O42  1  0.160  0.889  0.487  1.0
  O  O43  1  0.111  0.840  0.013  1.0
  O  O44  1  0.840  0.111  0.987  1.0
  O  O45  1  0.889  0.160  0.513  1.0
  O  O46  1  0.340  0.389  0.763  1.0
  O  O47  1  0.660  0.611  0.263  1.0
[/CIF]
.