The crystal structure described by Y2Rh3Sn5 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 13-coordinate geometry to one Rh(1), four equivalent Rh(3), two equivalent Sn(2), two equivalent Sn(5), and four equivalent Sn(3) atoms. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to two equivalent Rh(1), two equivalent Sn(1), two equivalent Sn(2), and two equivalent Sn(4) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to one Y(1), two equivalent Y(2), one Sn(1), one Sn(2), two equivalent Sn(3), and two equivalent Sn(5) atoms. In the second Rh site, Rh(2) is bonded in a 7-coordinate geometry to one Sn(5), three equivalent Sn(1), and three equivalent Sn(4) atoms. In the third Rh site, Rh(3) is bonded in a 7-coordinate geometry to four equivalent Y(1), one Sn(5), two equivalent Sn(2), and two equivalent Sn(3) atoms. There are five inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 6-coordinate geometry to two equivalent Y(2), one Rh(1), and three equivalent Rh(2) atoms. In the second Sn site, Sn(2) is bonded in a 3-coordinate geometry to two equivalent Y(1), two equivalent Y(2), one Rh(1), and two equivalent Rh(3) atoms. In the third Sn site, Sn(3) is bonded in a 6-coordinate geometry to four equivalent Y(1), two equivalent Rh(1), and two equivalent Rh(3) atoms. In the fourth Sn site, Sn(4) is bonded in a 5-coordinate geometry to two equivalent Y(2) and three equivalent Rh(2) atoms. In the fifth Sn site, Sn(5) is bonded in a 4-coordinate geometry to two equivalent Y(1), one Rh(2), one Rh(3), and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Y2Sn5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.400
_cell_length_b   13.400
_cell_length_c   7.215
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   161.014
_symmetry_Int_Tables_number   1
_cell_volume   421.470
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.476  0.524  0.238  1.0
  Y  Y1  1  0.172  0.828  0.257  1.0
  Y  Y2  1  0.524  0.476  0.738  1.0
  Y  Y3  1  0.828  0.172  0.757  1.0
  Sn  Sn4  1  0.705  0.295  0.550  1.0
  Sn  Sn5  1  0.596  0.404  0.112  1.0
  Sn  Sn6  1  0.048  0.952  0.401  1.0
  Sn  Sn7  1  0.952  0.048  0.901  1.0
  Sn  Sn8  1  0.710  0.290  0.978  1.0
  Sn  Sn9  1  0.290  0.710  0.478  1.0
  Sn  Sn10  1  0.295  0.705  0.050  1.0
  Sn  Sn11  1  0.880  0.120  0.231  1.0
  Sn  Sn12  1  0.120  0.880  0.731  1.0
  Sn  Sn13  1  0.404  0.596  0.612  1.0
  Rh  Rh14  1  0.394  0.606  0.983  1.0
  Rh  Rh15  1  0.778  0.222  0.265  1.0
  Rh  Rh16  1  0.222  0.778  0.765  1.0
  Rh  Rh17  1  0.050  0.950  0.018  1.0
  Rh  Rh18  1  0.606  0.394  0.483  1.0
  Rh  Rh19  1  0.950  0.050  0.518  1.0
[/CIF]
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The crystal structure described by Y2Rh3Sn5 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 13-coordinate geometry to one Rh(1), four equivalent Rh(3), two equivalent Sn(2), two equivalent Sn(5), and four equivalent Sn(3) atoms. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to two equivalent Rh(1), two equivalent Sn(1), two equivalent Sn(2), and two equivalent Sn(4) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to one Y(1), two equivalent Y(2), one Sn(1), one Sn(2), two equivalent Sn(3), and two equivalent Sn(5) atoms. In the second Rh site, Rh(2) is bonded in a 7-coordinate geometry to one Sn(5), three equivalent Sn(1), and three equivalent Sn(4) atoms. In the third Rh site, Rh(3) is bonded in a 7-coordinate geometry to four equivalent Y(1), one Sn(5), two equivalent Sn(2), and two equivalent Sn(3) atoms. There are five inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 6-coordinate geometry to two equivalent Y(2), one Rh(1), and three equivalent Rh(2) atoms. In the second Sn site, Sn(2) is bonded in a 3-coordinate geometry to two equivalent Y(1), two equivalent Y(2), one Rh(1), and two equivalent Rh(3) atoms. In the third Sn site, Sn(3) is bonded in a 6-coordinate geometry to four equivalent Y(1), two equivalent Rh(1), and two equivalent Rh(3) atoms. In the fourth Sn site, Sn(4) is bonded in a 5-coordinate geometry to two equivalent Y(2) and three equivalent Rh(2) atoms. In the fifth Sn site, Sn(5) is bonded in a 4-coordinate geometry to two equivalent Y(1), one Rh(2), one Rh(3), and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Y2Sn5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.400
_cell_length_b   13.400
_cell_length_c   7.215
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   161.014
_symmetry_Int_Tables_number   1
_cell_volume   421.470
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.476  0.524  0.238  1.0
  Y  Y1  1  0.172  0.828  0.257  1.0
  Y  Y2  1  0.524  0.476  0.738  1.0
  Y  Y3  1  0.828  0.172  0.757  1.0
  Sn  Sn4  1  0.705  0.295  0.550  1.0
  Sn  Sn5  1  0.596  0.404  0.112  1.0
  Sn  Sn6  1  0.048  0.952  0.401  1.0
  Sn  Sn7  1  0.952  0.048  0.901  1.0
  Sn  Sn8  1  0.710  0.290  0.978  1.0
  Sn  Sn9  1  0.290  0.710  0.478  1.0
  Sn  Sn10  1  0.295  0.705  0.050  1.0
  Sn  Sn11  1  0.880  0.120  0.231  1.0
  Sn  Sn12  1  0.120  0.880  0.731  1.0
  Sn  Sn13  1  0.404  0.596  0.612  1.0
  Rh  Rh14  1  0.394  0.606  0.983  1.0
  Rh  Rh15  1  0.778  0.222  0.265  1.0
  Rh  Rh16  1  0.222  0.778  0.765  1.0
  Rh  Rh17  1  0.050  0.950  0.018  1.0
  Rh  Rh18  1  0.606  0.394  0.483  1.0
  Rh  Rh19  1  0.950  0.050  0.518  1.0
[/CIF]
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