The material structure described by Rb2Pd3S4 crystallizes in the orthorhombic Fmmm space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pd(2), four equivalent Pd(1), and eight equivalent S(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Rb(1), one Pd(2), and two equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Rb2Pd3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.164
_cell_length_b   6.164
_cell_length_c   7.443
_cell_angle_alpha   102.400
_cell_angle_beta   102.400
_cell_angle_gamma   118.764
_symmetry_Int_Tables_number   1
_cell_volume   224.773
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.842  0.842  0.683  1.0
  Rb  Rb1  1  0.158  0.158  0.317  1.0
  Pd  Pd2  1  0.500  0.000  0.000  1.0
  Pd  Pd3  1  0.500  0.500  0.000  1.0
  Pd  Pd4  1  0.000  0.500  0.000  1.0
  S  S5  1  0.218  0.554  0.773  1.0
  S  S6  1  0.446  0.782  0.227  1.0
  S  S7  1  0.554  0.218  0.773  1.0
  S  S8  1  0.782  0.446  0.227  1.0
[/CIF]
.
The material structure described by Rb2Pd3S4 crystallizes in the orthorhombic Fmmm space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pd(2), four equivalent Pd(1), and eight equivalent S(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Rb(1), one Pd(2), and two equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Rb2Pd3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.164
_cell_length_b   6.164
_cell_length_c   7.443
_cell_angle_alpha   102.400
_cell_angle_beta   102.400
_cell_angle_gamma   118.764
_symmetry_Int_Tables_number   1
_cell_volume   224.773
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.842  0.842  0.683  1.0
  Rb  Rb1  1  0.158  0.158  0.317  1.0
  Pd  Pd2  1  0.500  0.000  0.000  1.0
  Pd  Pd3  1  0.500  0.500  0.000  1.0
  Pd  Pd4  1  0.000  0.500  0.000  1.0
  S  S5  1  0.218  0.554  0.773  1.0
  S  S6  1  0.446  0.782  0.227  1.0
  S  S7  1  0.554  0.218  0.773  1.0
  S  S8  1  0.782  0.446  0.227  1.0
[/CIF]
.