The material described by Co2N7O2Br5N2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules and four Co2N7O2Br5 clusters. In each Co2N7O2Br5 cluster, Co(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(4), one N(5), and one Br(1) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one Br(2) atom. In the second N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one O(1) atom. In the third N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent Co(1) atoms. In the fourth N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one Br(3) atom. O(1) is bonded in a single-bond geometry to one N(5) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a 2-coordinate geometry to two equivalent Co(1) atoms. In the second Br site, Br(2) is bonded in a single-bond geometry to one N(4) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF card [CIF]
data_Co2Br5N9O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.109
_cell_length_b   8.109
_cell_length_c   12.185
_cell_angle_alpha   94.216
_cell_angle_beta   94.216
_cell_angle_gamma   97.625
_symmetry_Int_Tables_number   1
_cell_volume   789.250
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.913  0.336  0.193  1.0
  Co  Co1  1  0.664  0.087  0.307  1.0
  Co  Co2  1  0.087  0.664  0.807  1.0
  Co  Co3  1  0.336  0.913  0.693  1.0
  Br  Br4  1  0.617  0.383  0.250  1.0
  Br  Br5  1  0.383  0.617  0.750  1.0
  Br  Br6  1  0.877  0.834  0.378  1.0
  Br  Br7  1  0.166  0.123  0.122  1.0
  Br  Br8  1  0.123  0.166  0.622  1.0
  Br  Br9  1  0.834  0.877  0.878  1.0
  Br  Br10  1  0.278  0.610  0.038  1.0
  Br  Br11  1  0.390  0.722  0.462  1.0
  Br  Br12  1  0.722  0.390  0.962  1.0
  Br  Br13  1  0.610  0.278  0.538  1.0
  N  N14  1  0.848  0.152  0.250  1.0
  N  N15  1  0.152  0.848  0.750  1.0
  N  N16  1  0.883  0.302  0.043  1.0
  N  N17  1  0.698  0.117  0.457  1.0
  N  N18  1  0.117  0.698  0.957  1.0
  N  N19  1  0.302  0.883  0.543  1.0
  N  N20  1  0.012  0.483  0.456  1.0
  N  N21  1  0.517  0.988  0.044  1.0
  N  N22  1  0.988  0.517  0.544  1.0
  N  N23  1  0.483  0.012  0.956  1.0
  N  N24  1  0.123  0.311  0.199  1.0
  N  N25  1  0.689  0.877  0.301  1.0
  N  N26  1  0.877  0.689  0.801  1.0
  N  N27  1  0.311  0.123  0.699  1.0
  N  N28  1  0.950  0.575  0.173  1.0
  N  N29  1  0.425  0.050  0.327  1.0
  N  N30  1  0.050  0.425  0.827  1.0
  N  N31  1  0.575  0.950  0.673  1.0
  O  O32  1  0.888  0.661  0.116  1.0
  O  O33  1  0.339  0.112  0.384  1.0
  O  O34  1  0.112  0.339  0.884  1.0
  O  O35  1  0.661  0.888  0.616  1.0
[/CIF]
.
The material described by Co2N7O2Br5N2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules and four Co2N7O2Br5 clusters. In each Co2N7O2Br5 cluster, Co(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(4), one N(5), and one Br(1) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one Br(2) atom. In the second N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one O(1) atom. In the third N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent Co(1) atoms. In the fourth N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one Br(3) atom. O(1) is bonded in a single-bond geometry to one N(5) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a 2-coordinate geometry to two equivalent Co(1) atoms. In the second Br site, Br(2) is bonded in a single-bond geometry to one N(4) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF card [CIF]
data_Co2Br5N9O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.109
_cell_length_b   8.109
_cell_length_c   12.185
_cell_angle_alpha   94.216
_cell_angle_beta   94.216
_cell_angle_gamma   97.625
_symmetry_Int_Tables_number   1
_cell_volume   789.250
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.913  0.336  0.193  1.0
  Co  Co1  1  0.664  0.087  0.307  1.0
  Co  Co2  1  0.087  0.664  0.807  1.0
  Co  Co3  1  0.336  0.913  0.693  1.0
  Br  Br4  1  0.617  0.383  0.250  1.0
  Br  Br5  1  0.383  0.617  0.750  1.0
  Br  Br6  1  0.877  0.834  0.378  1.0
  Br  Br7  1  0.166  0.123  0.122  1.0
  Br  Br8  1  0.123  0.166  0.622  1.0
  Br  Br9  1  0.834  0.877  0.878  1.0
  Br  Br10  1  0.278  0.610  0.038  1.0
  Br  Br11  1  0.390  0.722  0.462  1.0
  Br  Br12  1  0.722  0.390  0.962  1.0
  Br  Br13  1  0.610  0.278  0.538  1.0
  N  N14  1  0.848  0.152  0.250  1.0
  N  N15  1  0.152  0.848  0.750  1.0
  N  N16  1  0.883  0.302  0.043  1.0
  N  N17  1  0.698  0.117  0.457  1.0
  N  N18  1  0.117  0.698  0.957  1.0
  N  N19  1  0.302  0.883  0.543  1.0
  N  N20  1  0.012  0.483  0.456  1.0
  N  N21  1  0.517  0.988  0.044  1.0
  N  N22  1  0.988  0.517  0.544  1.0
  N  N23  1  0.483  0.012  0.956  1.0
  N  N24  1  0.123  0.311  0.199  1.0
  N  N25  1  0.689  0.877  0.301  1.0
  N  N26  1  0.877  0.689  0.801  1.0
  N  N27  1  0.311  0.123  0.699  1.0
  N  N28  1  0.950  0.575  0.173  1.0
  N  N29  1  0.425  0.050  0.327  1.0
  N  N30  1  0.050  0.425  0.827  1.0
  N  N31  1  0.575  0.950  0.673  1.0
  O  O32  1  0.888  0.661  0.116  1.0
  O  O33  1  0.339  0.112  0.384  1.0
  O  O34  1  0.112  0.339  0.884  1.0
  O  O35  1  0.661  0.888  0.616  1.0
[/CIF]
.