The crystal structure described by H9O4Te3Br13 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one hydrogen tetrahydrate molecule and one Te3Br13 cluster. In the Te3Br13 cluster, there are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one Br(10), one Br(11), one Br(12), one Br(3), one Br(6), and one Br(8) atom to form edge-sharing TeBr6 octahedra. In the second Te site, Te(2) is bonded to one Br(10), one Br(11), one Br(13), one Br(4), one Br(7), and one Br(9) atom to form edge-sharing TeBr6 octahedra. In the third Te site, Te(3) is bonded to one Br(1), one Br(11), one Br(2), one Br(5), one Br(6), and one Br(7) atom to form edge-sharing TeBr6 octahedra. There are thirteen inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(3) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(3) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Te(3) atom. In the sixth Br site, Br(6) is bonded in a water-like geometry to one Te(1) and one Te(3) atom. In the seventh Br site, Br(7) is bonded in a water-like geometry to one Te(2) and one Te(3) atom. In the eighth Br site, Br(8) is bonded in a single-bond geometry to one Te(1) atom. In the ninth Br site, Br(9) is bonded in a single-bond geometry to one Te(2) atom. In the tenth Br site, Br(10) is bonded in a water-like geometry to one Te(1) and one Te(2) atom. In the eleventh Br site, Br(11) is bonded in a distorted T-shaped geometry to one Te(1), one Te(2), and one Te(3) atom. In the twelfth Br site, Br(12) is bonded in a single-bond geometry to one Te(1) atom. In the thirteenth Br site, Br(13) is bonded in a single-bond geometry to one Te(2) atom. is represented by the CIF file [CIF]
data_Te3H9Br13O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.589
_cell_length_b   9.611
_cell_length_c   10.334
_cell_angle_alpha   114.603
_cell_angle_beta   114.494
_cell_angle_gamma   95.494
_symmetry_Int_Tables_number   1
_cell_volume   745.318
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.363  0.361  0.723  1.0
  Te  Te1  1  0.640  0.637  0.277  1.0
  Te  Te2  1  0.772  0.226  0.999  1.0
  H  H3  1  0.185  0.888  0.997  1.0
  H  H4  1  0.057  0.694  0.895  1.0
  H  H5  1  0.164  0.800  0.105  1.0
  H  H6  1  0.218  0.145  0.079  1.0
  H  H7  1  0.246  0.070  0.929  1.0
  H  H8  1  0.832  0.482  0.738  1.0
  H  H9  1  0.093  0.745  0.262  1.0
  H  H10  1  0.842  0.576  0.648  1.0
  H  H11  1  0.194  0.928  0.353  1.0
  Br  Br12  1  0.839  0.161  0.767  1.0
  Br  Br13  1  0.073  0.387  0.227  1.0
  Br  Br14  1  0.444  0.265  0.494  1.0
  Br  Br15  1  0.947  0.770  0.502  1.0
  Br  Br16  1  0.788  0.962  1.000  1.0
  Br  Br17  1  0.418  0.075  0.752  1.0
  Br  Br18  1  0.674  0.328  0.252  1.0
  Br  Br19  1  0.064  0.195  0.521  1.0
  Br  Br20  1  0.542  0.674  0.480  1.0
  Br  Br21  1  0.308  0.452  0.999  1.0
  Br  Br22  1  0.727  0.535  0.999  1.0
  Br  Br23  1  0.336  0.625  0.722  1.0
  Br  Br24  1  0.613  0.902  0.276  1.0
  O  O25  1  0.229  0.048  0.006  1.0
  O  O26  1  0.162  0.782  0.998  1.0
  O  O27  1  0.907  0.557  0.737  1.0
  O  O28  1  0.171  0.821  0.264  1.0
[/CIF]
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The crystal structure described by H9O4Te3Br13 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one hydrogen tetrahydrate molecule and one Te3Br13 cluster. In the Te3Br13 cluster, there are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one Br(10), one Br(11), one Br(12), one Br(3), one Br(6), and one Br(8) atom to form edge-sharing TeBr6 octahedra. In the second Te site, Te(2) is bonded to one Br(10), one Br(11), one Br(13), one Br(4), one Br(7), and one Br(9) atom to form edge-sharing TeBr6 octahedra. In the third Te site, Te(3) is bonded to one Br(1), one Br(11), one Br(2), one Br(5), one Br(6), and one Br(7) atom to form edge-sharing TeBr6 octahedra. There are thirteen inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(3) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(3) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Te(3) atom. In the sixth Br site, Br(6) is bonded in a water-like geometry to one Te(1) and one Te(3) atom. In the seventh Br site, Br(7) is bonded in a water-like geometry to one Te(2) and one Te(3) atom. In the eighth Br site, Br(8) is bonded in a single-bond geometry to one Te(1) atom. In the ninth Br site, Br(9) is bonded in a single-bond geometry to one Te(2) atom. In the tenth Br site, Br(10) is bonded in a water-like geometry to one Te(1) and one Te(2) atom. In the eleventh Br site, Br(11) is bonded in a distorted T-shaped geometry to one Te(1), one Te(2), and one Te(3) atom. In the twelfth Br site, Br(12) is bonded in a single-bond geometry to one Te(1) atom. In the thirteenth Br site, Br(13) is bonded in a single-bond geometry to one Te(2) atom. is represented by the CIF file [CIF]
data_Te3H9Br13O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.589
_cell_length_b   9.611
_cell_length_c   10.334
_cell_angle_alpha   114.603
_cell_angle_beta   114.494
_cell_angle_gamma   95.494
_symmetry_Int_Tables_number   1
_cell_volume   745.318
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.363  0.361  0.723  1.0
  Te  Te1  1  0.640  0.637  0.277  1.0
  Te  Te2  1  0.772  0.226  0.999  1.0
  H  H3  1  0.185  0.888  0.997  1.0
  H  H4  1  0.057  0.694  0.895  1.0
  H  H5  1  0.164  0.800  0.105  1.0
  H  H6  1  0.218  0.145  0.079  1.0
  H  H7  1  0.246  0.070  0.929  1.0
  H  H8  1  0.832  0.482  0.738  1.0
  H  H9  1  0.093  0.745  0.262  1.0
  H  H10  1  0.842  0.576  0.648  1.0
  H  H11  1  0.194  0.928  0.353  1.0
  Br  Br12  1  0.839  0.161  0.767  1.0
  Br  Br13  1  0.073  0.387  0.227  1.0
  Br  Br14  1  0.444  0.265  0.494  1.0
  Br  Br15  1  0.947  0.770  0.502  1.0
  Br  Br16  1  0.788  0.962  1.000  1.0
  Br  Br17  1  0.418  0.075  0.752  1.0
  Br  Br18  1  0.674  0.328  0.252  1.0
  Br  Br19  1  0.064  0.195  0.521  1.0
  Br  Br20  1  0.542  0.674  0.480  1.0
  Br  Br21  1  0.308  0.452  0.999  1.0
  Br  Br22  1  0.727  0.535  0.999  1.0
  Br  Br23  1  0.336  0.625  0.722  1.0
  Br  Br24  1  0.613  0.902  0.276  1.0
  O  O25  1  0.229  0.048  0.006  1.0
  O  O26  1  0.162  0.782  0.998  1.0
  O  O27  1  0.907  0.557  0.737  1.0
  O  O28  1  0.171  0.821  0.264  1.0
[/CIF]
.