The structure described by LiP3(OBr3)3POBr3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphorus oxybromide molecule and one LiP3(OBr3)3 cluster. In the LiP3(OBr3)3 cluster, Li(1) is bonded in a 5-coordinate geometry to one Br(10), one Br(11), one Br(2), one Br(4), and one Br(9) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted tetrahedral geometry to one O(3), one Br(10), one Br(12), and one Br(5) atom. In the second P site, P(3) is bonded in a distorted tetrahedral geometry to one O(2), one Br(4), one Br(8), and one Br(9) atom. In the third P site, P(4) is bonded in a distorted tetrahedral geometry to one O(4), one Br(11), one Br(2), and one Br(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one P(3) atom. In the second O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one P(4) atom. There are nine inequivalent Br sites. In the first Br site, Br(2) is bonded in an L-shaped geometry to one Li(1) and one P(4) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one P(4) atom. In the third Br site, Br(4) is bonded in an L-shaped geometry to one Li(1) and one P(3) atom. In the fourth Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the fifth Br site, Br(8) is bonded in a single-bond geometry to one P(3) atom. In the sixth Br site, Br(9) is bonded in an L-shaped geometry to one Li(1) and one P(3) atom. In the seventh Br site, Br(10) is bonded in an L-shaped geometry to one Li(1) and one P(1) atom. In the eighth Br site, Br(11) is bonded in a distorted L-shaped geometry to one Li(1) and one P(4) atom. In the ninth Br site, Br(12) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_LiP4(Br3O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.690
_cell_length_b   10.114
_cell_length_c   10.752
_cell_angle_alpha   91.355
_cell_angle_beta   91.279
_cell_angle_gamma   94.897
_symmetry_Int_Tables_number   1
_cell_volume   724.494
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.087  0.051  0.048  1.0
  P  P1  1  0.390  0.315  0.245  1.0
  P  P2  1  0.614  0.692  0.745  1.0
  P  P3  1  0.900  0.188  0.745  1.0
  P  P4  1  0.110  0.813  0.245  1.0
  Br  Br5  1  0.806  0.656  0.587  1.0
  Br  Br6  1  0.882  0.991  0.235  1.0
  Br  Br7  1  0.299  0.836  0.431  1.0
  Br  Br8  1  0.716  0.153  0.913  1.0
  Br  Br9  1  0.201  0.352  0.404  1.0
  Br  Br10  1  0.804  0.663  0.911  1.0
  Br  Br11  1  0.383  0.523  0.742  1.0
  Br  Br12  1  0.703  0.127  0.586  1.0
  Br  Br13  1  0.115  0.034  0.761  1.0
  Br  Br14  1  0.189  0.335  0.077  1.0
  Br  Br15  1  0.306  0.862  0.048  1.0
  Br  Br16  1  0.613  0.485  0.240  1.0
  O  O17  1  0.532  0.823  0.744  1.0
  O  O18  1  0.998  0.324  0.741  1.0
  O  O19  1  0.472  0.184  0.243  1.0
  O  O20  1  0.993  0.682  0.235  1.0
[/CIF]
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The structure described by LiP3(OBr3)3POBr3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphorus oxybromide molecule and one LiP3(OBr3)3 cluster. In the LiP3(OBr3)3 cluster, Li(1) is bonded in a 5-coordinate geometry to one Br(10), one Br(11), one Br(2), one Br(4), and one Br(9) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted tetrahedral geometry to one O(3), one Br(10), one Br(12), and one Br(5) atom. In the second P site, P(3) is bonded in a distorted tetrahedral geometry to one O(2), one Br(4), one Br(8), and one Br(9) atom. In the third P site, P(4) is bonded in a distorted tetrahedral geometry to one O(4), one Br(11), one Br(2), and one Br(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one P(3) atom. In the second O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one P(4) atom. There are nine inequivalent Br sites. In the first Br site, Br(2) is bonded in an L-shaped geometry to one Li(1) and one P(4) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one P(4) atom. In the third Br site, Br(4) is bonded in an L-shaped geometry to one Li(1) and one P(3) atom. In the fourth Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the fifth Br site, Br(8) is bonded in a single-bond geometry to one P(3) atom. In the sixth Br site, Br(9) is bonded in an L-shaped geometry to one Li(1) and one P(3) atom. In the seventh Br site, Br(10) is bonded in an L-shaped geometry to one Li(1) and one P(1) atom. In the eighth Br site, Br(11) is bonded in a distorted L-shaped geometry to one Li(1) and one P(4) atom. In the ninth Br site, Br(12) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_LiP4(Br3O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.690
_cell_length_b   10.114
_cell_length_c   10.752
_cell_angle_alpha   91.355
_cell_angle_beta   91.279
_cell_angle_gamma   94.897
_symmetry_Int_Tables_number   1
_cell_volume   724.494
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.087  0.051  0.048  1.0
  P  P1  1  0.390  0.315  0.245  1.0
  P  P2  1  0.614  0.692  0.745  1.0
  P  P3  1  0.900  0.188  0.745  1.0
  P  P4  1  0.110  0.813  0.245  1.0
  Br  Br5  1  0.806  0.656  0.587  1.0
  Br  Br6  1  0.882  0.991  0.235  1.0
  Br  Br7  1  0.299  0.836  0.431  1.0
  Br  Br8  1  0.716  0.153  0.913  1.0
  Br  Br9  1  0.201  0.352  0.404  1.0
  Br  Br10  1  0.804  0.663  0.911  1.0
  Br  Br11  1  0.383  0.523  0.742  1.0
  Br  Br12  1  0.703  0.127  0.586  1.0
  Br  Br13  1  0.115  0.034  0.761  1.0
  Br  Br14  1  0.189  0.335  0.077  1.0
  Br  Br15  1  0.306  0.862  0.048  1.0
  Br  Br16  1  0.613  0.485  0.240  1.0
  O  O17  1  0.532  0.823  0.744  1.0
  O  O18  1  0.998  0.324  0.741  1.0
  O  O19  1  0.472  0.184  0.243  1.0
  O  O20  1  0.993  0.682  0.235  1.0
[/CIF]
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