The structure described by PdSbS is Spinel-like structured and crystallizes in the cubic P2_13 space group. Pd(1) is bonded to three equivalent Sb(1) and three equivalent S(1) atoms to form PdSb3S3 octahedra that share corners with twelve equivalent Pd(1)Sb3S3 octahedra, corners with three equivalent Sb(1)Pd3S tetrahedra, and corners with three equivalent S(1)SbPd3 tetrahedra. The corner-sharing octahedral tilt angles range from 64-65°. Sb(1) is bonded to three equivalent Pd(1) and one S(1) atom to form distorted SbPd3S tetrahedra that share corners with three equivalent Pd(1)Sb3S3 octahedra, corners with six equivalent Sb(1)Pd3S tetrahedra, and corners with nine equivalent S(1)SbPd3 tetrahedra. The corner-sharing octahedral tilt angles are 77°. S(1) is bonded to three equivalent Pd(1) and one Sb(1) atom to form SSbPd3 tetrahedra that share corners with three equivalent Pd(1)Sb3S3 octahedra, corners with six equivalent S(1)SbPd3 tetrahedra, and corners with nine equivalent Sb(1)Pd3S tetrahedra. The corner-sharing octahedral tilt angles are 78°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbPdS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.275
_cell_length_b   6.275
_cell_length_c   6.275
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   247.080
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.120  0.620  0.880  1.0
  Sb  Sb1  1  0.620  0.880  0.120  1.0
  Sb  Sb2  1  0.880  0.120  0.620  1.0
  Sb  Sb3  1  0.380  0.380  0.380  1.0
  Pd  Pd4  1  0.490  0.990  0.510  1.0
  Pd  Pd5  1  0.990  0.510  0.490  1.0
  Pd  Pd6  1  0.510  0.490  0.990  1.0
  Pd  Pd7  1  0.010  0.010  0.010  1.0
  S  S8  1  0.890  0.390  0.110  1.0
  S  S9  1  0.390  0.110  0.890  1.0
  S  S10  1  0.110  0.890  0.390  1.0
  S  S11  1  0.610  0.610  0.610  1.0
[/CIF]
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The structure described by PdSbS is Spinel-like structured and crystallizes in the cubic P2_13 space group. Pd(1) is bonded to three equivalent Sb(1) and three equivalent S(1) atoms to form PdSb3S3 octahedra that share corners with twelve equivalent Pd(1)Sb3S3 octahedra, corners with three equivalent Sb(1)Pd3S tetrahedra, and corners with three equivalent S(1)SbPd3 tetrahedra. The corner-sharing octahedral tilt angles range from 64-65°. Sb(1) is bonded to three equivalent Pd(1) and one S(1) atom to form distorted SbPd3S tetrahedra that share corners with three equivalent Pd(1)Sb3S3 octahedra, corners with six equivalent Sb(1)Pd3S tetrahedra, and corners with nine equivalent S(1)SbPd3 tetrahedra. The corner-sharing octahedral tilt angles are 77°. S(1) is bonded to three equivalent Pd(1) and one Sb(1) atom to form SSbPd3 tetrahedra that share corners with three equivalent Pd(1)Sb3S3 octahedra, corners with six equivalent S(1)SbPd3 tetrahedra, and corners with nine equivalent Sb(1)Pd3S tetrahedra. The corner-sharing octahedral tilt angles are 78°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbPdS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.275
_cell_length_b   6.275
_cell_length_c   6.275
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   247.080
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.120  0.620  0.880  1.0
  Sb  Sb1  1  0.620  0.880  0.120  1.0
  Sb  Sb2  1  0.880  0.120  0.620  1.0
  Sb  Sb3  1  0.380  0.380  0.380  1.0
  Pd  Pd4  1  0.490  0.990  0.510  1.0
  Pd  Pd5  1  0.990  0.510  0.490  1.0
  Pd  Pd6  1  0.510  0.490  0.990  1.0
  Pd  Pd7  1  0.010  0.010  0.010  1.0
  S  S8  1  0.890  0.390  0.110  1.0
  S  S9  1  0.390  0.110  0.890  1.0
  S  S10  1  0.110  0.890  0.390  1.0
  S  S11  1  0.610  0.610  0.610  1.0
[/CIF]
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