The structure described by SbPOCl8 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four SbPOCl8 clusters. Sb(1) is bonded to one O(1), one Cl(2), one Cl(3), one Cl(4), and two equivalent Cl(5) atoms to form SbCl5O octahedra that share  a cornercorner with one P(1)Cl3O tetrahedra. P(1) is bonded to one O(1), one Cl(6), and two equivalent Cl(1) atoms to form PCl3O tetrahedra that share  a cornercorner with one Sb(1)Cl5O octahedra. The corner-sharing octahedral tilt angles are 37°. O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbPCl8O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.554
_cell_length_b   9.349
_cell_length_c   17.355
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1387.812
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.422  0.354  1.0
  Sb  Sb1  1  0.750  0.578  0.646  1.0
  Sb  Sb2  1  0.750  0.922  0.146  1.0
  Sb  Sb3  1  0.250  0.078  0.854  1.0
  P  P4  1  0.250  0.717  0.924  1.0
  P  P5  1  0.750  0.283  0.076  1.0
  P  P6  1  0.750  0.217  0.576  1.0
  P  P7  1  0.250  0.783  0.424  1.0
  Cl  Cl8  1  0.565  0.136  0.629  1.0
  Cl  Cl9  1  0.935  0.364  0.129  1.0
  Cl  Cl10  1  0.435  0.636  0.871  1.0
  Cl  Cl11  1  0.065  0.864  0.371  1.0
  Cl  Cl12  1  0.250  0.923  0.744  1.0
  Cl  Cl13  1  0.750  0.077  0.256  1.0
  Cl  Cl14  1  0.750  0.423  0.756  1.0
  Cl  Cl15  1  0.250  0.577  0.244  1.0
  Cl  Cl16  1  0.250  0.199  0.975  1.0
  Cl  Cl17  1  0.750  0.801  0.025  1.0
  Cl  Cl18  1  0.750  0.699  0.525  1.0
  Cl  Cl19  1  0.250  0.301  0.475  1.0
  Cl  Cl20  1  0.250  0.288  0.778  1.0
  Cl  Cl21  1  0.750  0.712  0.222  1.0
  Cl  Cl22  1  0.750  0.788  0.722  1.0
  Cl  Cl23  1  0.250  0.212  0.278  1.0
  Cl  Cl24  1  0.974  0.057  0.861  1.0
  Cl  Cl25  1  0.474  0.943  0.139  1.0
  Cl  Cl26  1  0.026  0.557  0.639  1.0
  Cl  Cl27  1  0.526  0.443  0.361  1.0
  Cl  Cl28  1  0.026  0.943  0.139  1.0
  Cl  Cl29  1  0.526  0.057  0.861  1.0
  Cl  Cl30  1  0.974  0.443  0.361  1.0
  Cl  Cl31  1  0.474  0.557  0.639  1.0
  Cl  Cl32  1  0.250  0.863  0.530  1.0
  Cl  Cl33  1  0.750  0.137  0.470  1.0
  Cl  Cl34  1  0.750  0.363  0.970  1.0
  Cl  Cl35  1  0.250  0.637  0.030  1.0
  Cl  Cl36  1  0.065  0.636  0.871  1.0
  Cl  Cl37  1  0.565  0.364  0.129  1.0
  Cl  Cl38  1  0.935  0.136  0.629  1.0
  Cl  Cl39  1  0.435  0.864  0.371  1.0
  O  O40  1  0.250  0.877  0.928  1.0
  O  O41  1  0.250  0.623  0.428  1.0
  O  O42  1  0.750  0.377  0.572  1.0
  O  O43  1  0.750  0.123  0.072  1.0
[/CIF]
.
The structure described by SbPOCl8 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four SbPOCl8 clusters. Sb(1) is bonded to one O(1), one Cl(2), one Cl(3), one Cl(4), and two equivalent Cl(5) atoms to form SbCl5O octahedra that share  a cornercorner with one P(1)Cl3O tetrahedra. P(1) is bonded to one O(1), one Cl(6), and two equivalent Cl(1) atoms to form PCl3O tetrahedra that share  a cornercorner with one Sb(1)Cl5O octahedra. The corner-sharing octahedral tilt angles are 37°. O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbPCl8O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.554
_cell_length_b   9.349
_cell_length_c   17.355
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1387.812
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.422  0.354  1.0
  Sb  Sb1  1  0.750  0.578  0.646  1.0
  Sb  Sb2  1  0.750  0.922  0.146  1.0
  Sb  Sb3  1  0.250  0.078  0.854  1.0
  P  P4  1  0.250  0.717  0.924  1.0
  P  P5  1  0.750  0.283  0.076  1.0
  P  P6  1  0.750  0.217  0.576  1.0
  P  P7  1  0.250  0.783  0.424  1.0
  Cl  Cl8  1  0.565  0.136  0.629  1.0
  Cl  Cl9  1  0.935  0.364  0.129  1.0
  Cl  Cl10  1  0.435  0.636  0.871  1.0
  Cl  Cl11  1  0.065  0.864  0.371  1.0
  Cl  Cl12  1  0.250  0.923  0.744  1.0
  Cl  Cl13  1  0.750  0.077  0.256  1.0
  Cl  Cl14  1  0.750  0.423  0.756  1.0
  Cl  Cl15  1  0.250  0.577  0.244  1.0
  Cl  Cl16  1  0.250  0.199  0.975  1.0
  Cl  Cl17  1  0.750  0.801  0.025  1.0
  Cl  Cl18  1  0.750  0.699  0.525  1.0
  Cl  Cl19  1  0.250  0.301  0.475  1.0
  Cl  Cl20  1  0.250  0.288  0.778  1.0
  Cl  Cl21  1  0.750  0.712  0.222  1.0
  Cl  Cl22  1  0.750  0.788  0.722  1.0
  Cl  Cl23  1  0.250  0.212  0.278  1.0
  Cl  Cl24  1  0.974  0.057  0.861  1.0
  Cl  Cl25  1  0.474  0.943  0.139  1.0
  Cl  Cl26  1  0.026  0.557  0.639  1.0
  Cl  Cl27  1  0.526  0.443  0.361  1.0
  Cl  Cl28  1  0.026  0.943  0.139  1.0
  Cl  Cl29  1  0.526  0.057  0.861  1.0
  Cl  Cl30  1  0.974  0.443  0.361  1.0
  Cl  Cl31  1  0.474  0.557  0.639  1.0
  Cl  Cl32  1  0.250  0.863  0.530  1.0
  Cl  Cl33  1  0.750  0.137  0.470  1.0
  Cl  Cl34  1  0.750  0.363  0.970  1.0
  Cl  Cl35  1  0.250  0.637  0.030  1.0
  Cl  Cl36  1  0.065  0.636  0.871  1.0
  Cl  Cl37  1  0.565  0.364  0.129  1.0
  Cl  Cl38  1  0.935  0.136  0.629  1.0
  Cl  Cl39  1  0.435  0.864  0.371  1.0
  O  O40  1  0.250  0.877  0.928  1.0
  O  O41  1  0.250  0.623  0.428  1.0
  O  O42  1  0.750  0.377  0.572  1.0
  O  O43  1  0.750  0.123  0.072  1.0
[/CIF]
.