The material described by MoNH5O5F2NHH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two ammonia molecules, and one MoNH5O5F2 cluster. In the MoNH5O5F2 cluster, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one F(1), and one F(2) atom. N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(4), and one O(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one O(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(7) is bonded in a linear geometry to one O(4) and one F(1) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one H(2), and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Mo(1) and one O(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one H(8) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one N(1) and one H(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one H(7) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Mo(1) atom. is represented by the CIF file [CIF]
data_MoH8N2O5F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.631
_cell_length_b   7.467
_cell_length_c   8.783
_cell_angle_alpha   82.035
_cell_angle_beta   71.602
_cell_angle_gamma   87.115
_symmetry_Int_Tables_number   1
_cell_volume   408.682
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.190  0.264  0.734  1.0
  Mo  Mo1  1  0.810  0.736  0.266  1.0
  H  H2  1  0.305  0.727  0.460  1.0
  H  H3  1  0.695  0.273  0.540  1.0
  H  H4  1  0.168  0.835  0.622  1.0
  H  H5  1  0.832  0.165  0.378  1.0
  H  H6  1  0.350  0.653  0.076  1.0
  H  H7  1  0.650  0.347  0.924  1.0
  H  H8  1  0.077  0.630  0.599  1.0
  H  H9  1  0.923  0.370  0.401  1.0
  H  H10  1  0.534  0.351  0.972  1.0
  H  H11  1  0.466  0.649  0.028  1.0
  H  H12  1  0.429  0.118  0.217  1.0
  H  H13  1  0.571  0.882  0.783  1.0
  H  H14  1  0.516  0.377  0.387  1.0
  H  H15  1  0.484  0.623  0.613  1.0
  H  H16  1  0.170  0.269  0.034  1.0
  H  H17  1  0.830  0.731  0.966  1.0
  N  N18  1  0.211  0.708  0.582  1.0
  N  N19  1  0.789  0.292  0.418  1.0
  N  N20  1  0.299  0.184  0.189  1.0
  N  N21  1  0.701  0.816  0.811  1.0
  O  O22  1  0.098  0.058  0.651  1.0
  O  O23  1  0.902  0.942  0.349  1.0
  O  O24  1  0.042  0.042  0.829  1.0
  O  O25  1  0.958  0.958  0.171  1.0
  O  O26  1  0.116  0.328  0.945  1.0
  O  O27  1  0.884  0.672  0.055  1.0
  O  O28  1  0.324  0.605  0.678  1.0
  O  O29  1  0.676  0.395  0.322  1.0
  O  O30  1  0.457  0.212  0.708  1.0
  O  O31  1  0.543  0.788  0.292  1.0
  F  F32  1  0.294  0.353  0.483  1.0
  F  F33  1  0.706  0.647  0.517  1.0
  F  F34  1  0.960  0.430  0.701  1.0
  F  F35  1  0.040  0.570  0.299  1.0
[/CIF]
.
The material described by MoNH5O5F2NHH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two ammonia molecules, and one MoNH5O5F2 cluster. In the MoNH5O5F2 cluster, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one F(1), and one F(2) atom. N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(4), and one O(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one O(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(7) is bonded in a linear geometry to one O(4) and one F(1) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one H(2), and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Mo(1) and one O(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one H(8) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one N(1) and one H(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one H(7) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Mo(1) atom. is represented by the CIF file [CIF]
data_MoH8N2O5F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.631
_cell_length_b   7.467
_cell_length_c   8.783
_cell_angle_alpha   82.035
_cell_angle_beta   71.602
_cell_angle_gamma   87.115
_symmetry_Int_Tables_number   1
_cell_volume   408.682
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.190  0.264  0.734  1.0
  Mo  Mo1  1  0.810  0.736  0.266  1.0
  H  H2  1  0.305  0.727  0.460  1.0
  H  H3  1  0.695  0.273  0.540  1.0
  H  H4  1  0.168  0.835  0.622  1.0
  H  H5  1  0.832  0.165  0.378  1.0
  H  H6  1  0.350  0.653  0.076  1.0
  H  H7  1  0.650  0.347  0.924  1.0
  H  H8  1  0.077  0.630  0.599  1.0
  H  H9  1  0.923  0.370  0.401  1.0
  H  H10  1  0.534  0.351  0.972  1.0
  H  H11  1  0.466  0.649  0.028  1.0
  H  H12  1  0.429  0.118  0.217  1.0
  H  H13  1  0.571  0.882  0.783  1.0
  H  H14  1  0.516  0.377  0.387  1.0
  H  H15  1  0.484  0.623  0.613  1.0
  H  H16  1  0.170  0.269  0.034  1.0
  H  H17  1  0.830  0.731  0.966  1.0
  N  N18  1  0.211  0.708  0.582  1.0
  N  N19  1  0.789  0.292  0.418  1.0
  N  N20  1  0.299  0.184  0.189  1.0
  N  N21  1  0.701  0.816  0.811  1.0
  O  O22  1  0.098  0.058  0.651  1.0
  O  O23  1  0.902  0.942  0.349  1.0
  O  O24  1  0.042  0.042  0.829  1.0
  O  O25  1  0.958  0.958  0.171  1.0
  O  O26  1  0.116  0.328  0.945  1.0
  O  O27  1  0.884  0.672  0.055  1.0
  O  O28  1  0.324  0.605  0.678  1.0
  O  O29  1  0.676  0.395  0.322  1.0
  O  O30  1  0.457  0.212  0.708  1.0
  O  O31  1  0.543  0.788  0.292  1.0
  F  F32  1  0.294  0.353  0.483  1.0
  F  F33  1  0.706  0.647  0.517  1.0
  F  F34  1  0.960  0.430  0.701  1.0
  F  F35  1  0.040  0.570  0.299  1.0
[/CIF]
.