The structure described by Rb7Th6F32 crystallizes in the triclinic P-1 space group. There are four inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to one F(15), one F(2), one F(4), one F(6), one F(8), one F(9), and two equivalent F(1) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one F(13), one F(3), one F(4), one F(5), one F(7), one F(9), and two equivalent F(2) atoms. In the third Rb site, Rb(3) is bonded in a 8-coordinate geometry to one F(1), one F(14), one F(5), one F(6), one F(7), one F(8), and two equivalent F(3) atoms. In the fourth Rb site, Rb(4) is bonded in an octahedral geometry to two equivalent F(4), two equivalent F(5), and two equivalent F(6) atoms. There are three inequivalent Th sites. In the first Th site, Th(1) is bonded in a 9-coordinate geometry to one F(1), one F(10), one F(11), one F(14), one F(15), one F(16), one F(4), and two equivalent F(7) atoms. In the second Th site, Th(2) is bonded in a 9-coordinate geometry to one F(11), one F(12), one F(13), one F(15), one F(16), one F(2), one F(5), and two equivalent F(8) atoms. In the third Th site, Th(3) is bonded in a 9-coordinate geometry to one F(10), one F(12), one F(13), one F(14), one F(16), one F(3), one F(6), and two equivalent F(9) atoms. There are sixteen inequivalent F sites. In the first F site, F(1) is bonded to one Rb(3), two equivalent Rb(1), and one Th(1) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(9)Rb2Th2 tetrahedra, corners with two equivalent F(2)Rb3Th tetrahedra, corners with two equivalent F(3)Rb3Th tetrahedra,  an edgeedge with one F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(4)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the second F site, F(2) is bonded to one Rb(1), two equivalent Rb(2), and one Th(2) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(7)Rb2Th2 tetrahedra, corners with two equivalent F(1)Rb3Th tetrahedra, corners with two equivalent F(3)Rb3Th tetrahedra,  an edgeedge with one F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra,  an edgeedge with one F(4)Rb3Th tetrahedra, and  an edgeedge with one F(5)Rb3Th tetrahedra. In the third F site, F(3) is bonded to one Rb(2), two equivalent Rb(3), and one Th(3) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(8)Rb2Th2 tetrahedra, corners with two equivalent F(1)Rb3Th tetrahedra, corners with two equivalent F(2)Rb3Th tetrahedra,  an edgeedge with one F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra,  an edgeedge with one F(5)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the fourth F site, F(4) is bonded to one Rb(1), one Rb(2), one Rb(4), and one Th(1) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra,  an edgeedge with one F(5)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the fifth F site, F(5) is bonded to one Rb(2), one Rb(3), one Rb(4), and one Th(2) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra,  an edgeedge with one F(4)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the sixth F site, F(6) is bonded to one Rb(1), one Rb(3), one Rb(4), and one Th(3) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra,  an edgeedge with one F(4)Rb3Th tetrahedra, and  an edgeedge with one F(5)Rb3Th tetrahedra. In the seventh F site, F(7) is bonded to one Rb(2), one Rb(3), and two equivalent Th(1) atoms to form FRb2Th2 tetrahedra that share  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(2)Rb3Th tetrahedra, corners with two equivalent F(5)Rb3Th tetrahedra,  an edgeedge with one F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra, and  an edgeedge with one F(4)Rb3Th tetrahedra. In the eighth F site, F(8) is bonded to one Rb(1), one Rb(3), and two equivalent Th(2) atoms to form FRb2Th2 tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra, corners with two equivalent F(3)Rb3Th tetrahedra, corners with two equivalent F(6)Rb3Th tetrahedra,  an edgeedge with one F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra, and  an edgeedge with one F(5)Rb3Th tetrahedra. In the ninth F site, F(9) is bonded to one Rb(1), one Rb(2), and two equivalent Th(3) atoms to form FRb2Th2 tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(1)Rb3Th tetrahedra, corners with two equivalent F(4)Rb3Th tetrahedra,  an edgeedge with one F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one Th(1) and one Th(3) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one Th(1) and one Th(2) atom. In the twelfth F site, F(12) is bonded in a bent 150 degrees geometry to one Th(2) and one Th(3) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal non-coplanar geometry to one Rb(2), one Th(2), and one Th(3) atom. In the fourteenth F site, F(14) is bonded in a 3-coordinate geometry to one Rb(3), one Th(1), and one Th(3) atom. In the fifteenth F site, F(15) is bonded in a 3-coordinate geometry to one Rb(1), one Th(1), and one Th(2) atom. In the sixteenth F site, F(16) is bonded in a trigonal non-coplanar geometry to one Th(1), one Th(2), and one Th(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb7Th6F32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.793
_cell_length_b   9.796
_cell_length_c   9.798
_cell_angle_alpha   106.625
_cell_angle_beta   106.665
_cell_angle_gamma   106.593
_symmetry_Int_Tables_number   1
_cell_volume   790.658
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.684  0.217  0.077  1.0
  Rb  Rb1  1  0.077  0.682  0.217  1.0
  Rb  Rb2  1  0.218  0.077  0.683  1.0
  Rb  Rb3  1  0.316  0.783  0.923  1.0
  Rb  Rb4  1  0.923  0.318  0.783  1.0
  Rb  Rb5  1  0.782  0.923  0.317  1.0
  Rb  Rb6  1  0.000  0.000  0.000  1.0
  Th  Th7  1  0.542  0.861  0.619  1.0
  Th  Th8  1  0.619  0.541  0.861  1.0
  Th  Th9  1  0.862  0.619  0.542  1.0
  Th  Th10  1  0.458  0.139  0.381  1.0
  Th  Th11  1  0.381  0.459  0.139  1.0
  Th  Th12  1  0.138  0.381  0.458  1.0
  F  F13  1  0.446  0.971  0.781  1.0
  F  F14  1  0.782  0.446  0.972  1.0
  F  F15  1  0.973  0.781  0.447  1.0
  F  F16  1  0.554  0.029  0.219  1.0
  F  F17  1  0.218  0.554  0.028  1.0
  F  F18  1  0.027  0.219  0.553  1.0
  F  F19  1  0.754  0.055  0.820  1.0
  F  F20  1  0.823  0.753  0.054  1.0
  F  F21  1  0.054  0.823  0.754  1.0
  F  F22  1  0.246  0.945  0.180  1.0
  F  F23  1  0.177  0.247  0.946  1.0
  F  F24  1  0.946  0.177  0.246  1.0
  F  F25  1  0.642  0.055  0.523  1.0
  F  F26  1  0.524  0.640  0.054  1.0
  F  F27  1  0.056  0.525  0.642  1.0
  F  F28  1  0.358  0.945  0.477  1.0
  F  F29  1  0.476  0.360  0.946  1.0
  F  F30  1  0.944  0.475  0.358  1.0
  F  F31  1  0.700  0.348  0.458  1.0
  F  F32  1  0.458  0.702  0.346  1.0
  F  F33  1  0.347  0.459  0.702  1.0
  F  F34  1  0.300  0.652  0.542  1.0
  F  F35  1  0.542  0.298  0.654  1.0
  F  F36  1  0.653  0.541  0.298  1.0
  F  F37  1  0.174  0.415  0.233  1.0
  F  F38  1  0.234  0.175  0.415  1.0
  F  F39  1  0.414  0.233  0.173  1.0
  F  F40  1  0.826  0.585  0.767  1.0
  F  F41  1  0.766  0.825  0.585  1.0
  F  F42  1  0.586  0.767  0.827  1.0
  F  F43  1  0.412  0.411  0.410  1.0
  F  F44  1  0.588  0.589  0.590  1.0
[/CIF]
.
The structure described by Rb7Th6F32 crystallizes in the triclinic P-1 space group. There are four inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to one F(15), one F(2), one F(4), one F(6), one F(8), one F(9), and two equivalent F(1) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one F(13), one F(3), one F(4), one F(5), one F(7), one F(9), and two equivalent F(2) atoms. In the third Rb site, Rb(3) is bonded in a 8-coordinate geometry to one F(1), one F(14), one F(5), one F(6), one F(7), one F(8), and two equivalent F(3) atoms. In the fourth Rb site, Rb(4) is bonded in an octahedral geometry to two equivalent F(4), two equivalent F(5), and two equivalent F(6) atoms. There are three inequivalent Th sites. In the first Th site, Th(1) is bonded in a 9-coordinate geometry to one F(1), one F(10), one F(11), one F(14), one F(15), one F(16), one F(4), and two equivalent F(7) atoms. In the second Th site, Th(2) is bonded in a 9-coordinate geometry to one F(11), one F(12), one F(13), one F(15), one F(16), one F(2), one F(5), and two equivalent F(8) atoms. In the third Th site, Th(3) is bonded in a 9-coordinate geometry to one F(10), one F(12), one F(13), one F(14), one F(16), one F(3), one F(6), and two equivalent F(9) atoms. There are sixteen inequivalent F sites. In the first F site, F(1) is bonded to one Rb(3), two equivalent Rb(1), and one Th(1) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(9)Rb2Th2 tetrahedra, corners with two equivalent F(2)Rb3Th tetrahedra, corners with two equivalent F(3)Rb3Th tetrahedra,  an edgeedge with one F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(4)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the second F site, F(2) is bonded to one Rb(1), two equivalent Rb(2), and one Th(2) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(7)Rb2Th2 tetrahedra, corners with two equivalent F(1)Rb3Th tetrahedra, corners with two equivalent F(3)Rb3Th tetrahedra,  an edgeedge with one F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra,  an edgeedge with one F(4)Rb3Th tetrahedra, and  an edgeedge with one F(5)Rb3Th tetrahedra. In the third F site, F(3) is bonded to one Rb(2), two equivalent Rb(3), and one Th(3) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(8)Rb2Th2 tetrahedra, corners with two equivalent F(1)Rb3Th tetrahedra, corners with two equivalent F(2)Rb3Th tetrahedra,  an edgeedge with one F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra,  an edgeedge with one F(5)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the fourth F site, F(4) is bonded to one Rb(1), one Rb(2), one Rb(4), and one Th(1) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra,  an edgeedge with one F(5)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the fifth F site, F(5) is bonded to one Rb(2), one Rb(3), one Rb(4), and one Th(2) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra,  an edgeedge with one F(4)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the sixth F site, F(6) is bonded to one Rb(1), one Rb(3), one Rb(4), and one Th(3) atom to form distorted FRb3Th tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra,  an edgeedge with one F(4)Rb3Th tetrahedra, and  an edgeedge with one F(5)Rb3Th tetrahedra. In the seventh F site, F(7) is bonded to one Rb(2), one Rb(3), and two equivalent Th(1) atoms to form FRb2Th2 tetrahedra that share  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(2)Rb3Th tetrahedra, corners with two equivalent F(5)Rb3Th tetrahedra,  an edgeedge with one F(7)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra, and  an edgeedge with one F(4)Rb3Th tetrahedra. In the eighth F site, F(8) is bonded to one Rb(1), one Rb(3), and two equivalent Th(2) atoms to form FRb2Th2 tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(9)Rb2Th2 tetrahedra,  a cornercorner with one F(1)Rb3Th tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(4)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra, corners with two equivalent F(3)Rb3Th tetrahedra, corners with two equivalent F(6)Rb3Th tetrahedra,  an edgeedge with one F(8)Rb2Th2 tetrahedra,  an edgeedge with one F(1)Rb3Th tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra, and  an edgeedge with one F(5)Rb3Th tetrahedra. In the ninth F site, F(9) is bonded to one Rb(1), one Rb(2), and two equivalent Th(3) atoms to form FRb2Th2 tetrahedra that share  a cornercorner with one F(7)Rb2Th2 tetrahedra,  a cornercorner with one F(8)Rb2Th2 tetrahedra,  a cornercorner with one F(2)Rb3Th tetrahedra,  a cornercorner with one F(3)Rb3Th tetrahedra,  a cornercorner with one F(5)Rb3Th tetrahedra,  a cornercorner with one F(6)Rb3Th tetrahedra, corners with two equivalent F(1)Rb3Th tetrahedra, corners with two equivalent F(4)Rb3Th tetrahedra,  an edgeedge with one F(9)Rb2Th2 tetrahedra,  an edgeedge with one F(2)Rb3Th tetrahedra,  an edgeedge with one F(3)Rb3Th tetrahedra, and  an edgeedge with one F(6)Rb3Th tetrahedra. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one Th(1) and one Th(3) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one Th(1) and one Th(2) atom. In the twelfth F site, F(12) is bonded in a bent 150 degrees geometry to one Th(2) and one Th(3) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal non-coplanar geometry to one Rb(2), one Th(2), and one Th(3) atom. In the fourteenth F site, F(14) is bonded in a 3-coordinate geometry to one Rb(3), one Th(1), and one Th(3) atom. In the fifteenth F site, F(15) is bonded in a 3-coordinate geometry to one Rb(1), one Th(1), and one Th(2) atom. In the sixteenth F site, F(16) is bonded in a trigonal non-coplanar geometry to one Th(1), one Th(2), and one Th(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb7Th6F32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.793
_cell_length_b   9.796
_cell_length_c   9.798
_cell_angle_alpha   106.625
_cell_angle_beta   106.665
_cell_angle_gamma   106.593
_symmetry_Int_Tables_number   1
_cell_volume   790.658
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.684  0.217  0.077  1.0
  Rb  Rb1  1  0.077  0.682  0.217  1.0
  Rb  Rb2  1  0.218  0.077  0.683  1.0
  Rb  Rb3  1  0.316  0.783  0.923  1.0
  Rb  Rb4  1  0.923  0.318  0.783  1.0
  Rb  Rb5  1  0.782  0.923  0.317  1.0
  Rb  Rb6  1  0.000  0.000  0.000  1.0
  Th  Th7  1  0.542  0.861  0.619  1.0
  Th  Th8  1  0.619  0.541  0.861  1.0
  Th  Th9  1  0.862  0.619  0.542  1.0
  Th  Th10  1  0.458  0.139  0.381  1.0
  Th  Th11  1  0.381  0.459  0.139  1.0
  Th  Th12  1  0.138  0.381  0.458  1.0
  F  F13  1  0.446  0.971  0.781  1.0
  F  F14  1  0.782  0.446  0.972  1.0
  F  F15  1  0.973  0.781  0.447  1.0
  F  F16  1  0.554  0.029  0.219  1.0
  F  F17  1  0.218  0.554  0.028  1.0
  F  F18  1  0.027  0.219  0.553  1.0
  F  F19  1  0.754  0.055  0.820  1.0
  F  F20  1  0.823  0.753  0.054  1.0
  F  F21  1  0.054  0.823  0.754  1.0
  F  F22  1  0.246  0.945  0.180  1.0
  F  F23  1  0.177  0.247  0.946  1.0
  F  F24  1  0.946  0.177  0.246  1.0
  F  F25  1  0.642  0.055  0.523  1.0
  F  F26  1  0.524  0.640  0.054  1.0
  F  F27  1  0.056  0.525  0.642  1.0
  F  F28  1  0.358  0.945  0.477  1.0
  F  F29  1  0.476  0.360  0.946  1.0
  F  F30  1  0.944  0.475  0.358  1.0
  F  F31  1  0.700  0.348  0.458  1.0
  F  F32  1  0.458  0.702  0.346  1.0
  F  F33  1  0.347  0.459  0.702  1.0
  F  F34  1  0.300  0.652  0.542  1.0
  F  F35  1  0.542  0.298  0.654  1.0
  F  F36  1  0.653  0.541  0.298  1.0
  F  F37  1  0.174  0.415  0.233  1.0
  F  F38  1  0.234  0.175  0.415  1.0
  F  F39  1  0.414  0.233  0.173  1.0
  F  F40  1  0.826  0.585  0.767  1.0
  F  F41  1  0.766  0.825  0.585  1.0
  F  F42  1  0.586  0.767  0.827  1.0
  F  F43  1  0.412  0.411  0.410  1.0
  F  F44  1  0.588  0.589  0.590  1.0
[/CIF]
.