The crystal structure described by Ba2CuZnBi2F14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Cu(1) is bonded in a distorted square co-planar geometry to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms. Zn(1) is bonded to two equivalent F(1) and two equivalent F(6) atoms to form distorted ZnF4 tetrahedra that share corners with four equivalent Bi(1)F7 pentagonal bipyramids. Bi(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom to form distorted BiF7 pentagonal bipyramids that share corners with two equivalent Zn(1)F4 tetrahedra. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Bi(1) atom. In the second F site, F(6) is bonded in a distorted trigonal planar geometry to one Ba(1), one Zn(1), and one Bi(1) atom. In the third F site, F(7) is bonded in a 3-coordinate geometry to one Ba(1), one Cu(1), and one Bi(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Zn(1), and one Bi(1) atom. In the fifth F site, F(2) is bonded to two equivalent Ba(1), one Cu(1), and one Bi(1) atom to form a mixture of distorted corner and edge-sharing FBa2CuBi tetrahedra. In the sixth F site, F(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1) and one Bi(1) atom. In the seventh F site, F(4) is bonded in a distorted single-bond geometry to one Ba(1), one Cu(1), and one Bi(1) atom. is represented by the CIF file [CIF]
data_Ba2ZnCuBi2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.770
_cell_length_b   7.770
_cell_length_c   16.183
_cell_angle_alpha   89.944
_cell_angle_beta   89.944
_cell_angle_gamma   40.439
_symmetry_Int_Tables_number   1
_cell_volume   633.671
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.721  0.917  0.626  1.0
  Ba  Ba1  1  0.917  0.721  0.126  1.0
  Ba  Ba2  1  0.279  0.083  0.374  1.0
  Ba  Ba3  1  0.083  0.279  0.874  1.0
  Zn  Zn4  1  0.438  0.562  0.750  1.0
  Zn  Zn5  1  0.562  0.438  0.250  1.0
  Cu  Cu6  1  0.500  0.500  0.000  1.0
  Cu  Cu7  1  0.500  0.500  0.500  1.0
  Bi  Bi8  1  0.841  0.943  0.877  1.0
  Bi  Bi9  1  0.159  0.057  0.123  1.0
  Bi  Bi10  1  0.943  0.841  0.377  1.0
  Bi  Bi11  1  0.057  0.159  0.623  1.0
  F  F12  1  0.864  0.179  0.327  1.0
  F  F13  1  0.574  0.133  0.454  1.0
  F  F14  1  0.426  0.867  0.546  1.0
  F  F15  1  0.107  0.400  0.598  1.0
  F  F16  1  0.610  0.342  0.607  1.0
  F  F17  1  0.658  0.390  0.893  1.0
  F  F18  1  0.133  0.574  0.954  1.0
  F  F19  1  0.821  0.136  0.173  1.0
  F  F20  1  0.993  0.649  0.781  1.0
  F  F21  1  0.893  0.600  0.402  1.0
  F  F22  1  0.562  0.228  0.762  1.0
  F  F23  1  0.600  0.893  0.902  1.0
  F  F24  1  0.228  0.562  0.262  1.0
  F  F25  1  0.438  0.772  0.238  1.0
  F  F26  1  0.342  0.610  0.107  1.0
  F  F27  1  0.007  0.351  0.219  1.0
  F  F28  1  0.281  0.873  0.986  1.0
  F  F29  1  0.136  0.821  0.673  1.0
  F  F30  1  0.719  0.127  0.014  1.0
  F  F31  1  0.873  0.281  0.486  1.0
  F  F32  1  0.867  0.426  0.046  1.0
  F  F33  1  0.772  0.438  0.738  1.0
  F  F34  1  0.649  0.993  0.281  1.0
  F  F35  1  0.127  0.719  0.514  1.0
  F  F36  1  0.390  0.658  0.393  1.0
  F  F37  1  0.179  0.864  0.827  1.0
  F  F38  1  0.351  0.007  0.719  1.0
  F  F39  1  0.400  0.107  0.098  1.0
[/CIF]
.
The crystal structure described by Ba2CuZnBi2F14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Cu(1) is bonded in a distorted square co-planar geometry to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms. Zn(1) is bonded to two equivalent F(1) and two equivalent F(6) atoms to form distorted ZnF4 tetrahedra that share corners with four equivalent Bi(1)F7 pentagonal bipyramids. Bi(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom to form distorted BiF7 pentagonal bipyramids that share corners with two equivalent Zn(1)F4 tetrahedra. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Bi(1) atom. In the second F site, F(6) is bonded in a distorted trigonal planar geometry to one Ba(1), one Zn(1), and one Bi(1) atom. In the third F site, F(7) is bonded in a 3-coordinate geometry to one Ba(1), one Cu(1), and one Bi(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Zn(1), and one Bi(1) atom. In the fifth F site, F(2) is bonded to two equivalent Ba(1), one Cu(1), and one Bi(1) atom to form a mixture of distorted corner and edge-sharing FBa2CuBi tetrahedra. In the sixth F site, F(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1) and one Bi(1) atom. In the seventh F site, F(4) is bonded in a distorted single-bond geometry to one Ba(1), one Cu(1), and one Bi(1) atom. is represented by the CIF file [CIF]
data_Ba2ZnCuBi2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.770
_cell_length_b   7.770
_cell_length_c   16.183
_cell_angle_alpha   89.944
_cell_angle_beta   89.944
_cell_angle_gamma   40.439
_symmetry_Int_Tables_number   1
_cell_volume   633.671
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.721  0.917  0.626  1.0
  Ba  Ba1  1  0.917  0.721  0.126  1.0
  Ba  Ba2  1  0.279  0.083  0.374  1.0
  Ba  Ba3  1  0.083  0.279  0.874  1.0
  Zn  Zn4  1  0.438  0.562  0.750  1.0
  Zn  Zn5  1  0.562  0.438  0.250  1.0
  Cu  Cu6  1  0.500  0.500  0.000  1.0
  Cu  Cu7  1  0.500  0.500  0.500  1.0
  Bi  Bi8  1  0.841  0.943  0.877  1.0
  Bi  Bi9  1  0.159  0.057  0.123  1.0
  Bi  Bi10  1  0.943  0.841  0.377  1.0
  Bi  Bi11  1  0.057  0.159  0.623  1.0
  F  F12  1  0.864  0.179  0.327  1.0
  F  F13  1  0.574  0.133  0.454  1.0
  F  F14  1  0.426  0.867  0.546  1.0
  F  F15  1  0.107  0.400  0.598  1.0
  F  F16  1  0.610  0.342  0.607  1.0
  F  F17  1  0.658  0.390  0.893  1.0
  F  F18  1  0.133  0.574  0.954  1.0
  F  F19  1  0.821  0.136  0.173  1.0
  F  F20  1  0.993  0.649  0.781  1.0
  F  F21  1  0.893  0.600  0.402  1.0
  F  F22  1  0.562  0.228  0.762  1.0
  F  F23  1  0.600  0.893  0.902  1.0
  F  F24  1  0.228  0.562  0.262  1.0
  F  F25  1  0.438  0.772  0.238  1.0
  F  F26  1  0.342  0.610  0.107  1.0
  F  F27  1  0.007  0.351  0.219  1.0
  F  F28  1  0.281  0.873  0.986  1.0
  F  F29  1  0.136  0.821  0.673  1.0
  F  F30  1  0.719  0.127  0.014  1.0
  F  F31  1  0.873  0.281  0.486  1.0
  F  F32  1  0.867  0.426  0.046  1.0
  F  F33  1  0.772  0.438  0.738  1.0
  F  F34  1  0.649  0.993  0.281  1.0
  F  F35  1  0.127  0.719  0.514  1.0
  F  F36  1  0.390  0.658  0.393  1.0
  F  F37  1  0.179  0.864  0.827  1.0
  F  F38  1  0.351  0.007  0.719  1.0
  F  F39  1  0.400  0.107  0.098  1.0
[/CIF]
.