The compound described by Li6MnCoP2(CO7)2 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(20), one O(21), one O(23), and one O(3) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(19), one O(22), one O(24), and one O(4) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one O(17), one O(2), one O(25), and one O(27) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(1), one O(18), one O(26), and one O(28) atom. In the fifth Li site, Li(5) is bonded to one O(22), one O(3), one O(6), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Li(7)O5 trigonal bipyramid, and  an edgeedge with one Li(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-85°. In the sixth Li site, Li(6) is bonded to one O(10), one O(21), one O(4), one O(5), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Li(7)O5 trigonal bipyramid, and  an edgeedge with one Li(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-85°. In the seventh Li site, Li(7) is bonded to one O(24), one O(3), one O(5), one O(7), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-85°. In the eighth Li site, Li(8) is bonded to one O(10), one O(23), one O(4), one O(6), and one O(8) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-84°. In the ninth Li site, Li(9) is bonded to one O(11), one O(13), one O(15), one O(17), and one O(28) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Li(11)O5 trigonal bipyramid, and  an edgeedge with one Li(12)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-89°. In the tenth Li site, Li(10) is bonded to one O(12), one O(14), one O(16), one O(18), and one O(27) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Li(11)O5 trigonal bipyramid, and  an edgeedge with one Li(12)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-89°. In the eleventh Li site, Li(11) is bonded to one O(11), one O(14), one O(16), one O(17), and one O(26) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-89°. In the twelfth Li site, Li(12) is bonded to one O(12), one O(13), one O(15), one O(18), and one O(25) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 67-88°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(15), one O(19), one O(26), one O(27), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid,  an edgeedge with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one Li(11)O5 trigonal bipyramid. In the second Mn site, Mn(2) is bonded to one O(10), one O(13), one O(16), one O(20), one O(25), and one O(28) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  an edgeedge with one Li(12)O5 trigonal bipyramid, and  an edgeedge with one Li(9)O5 trigonal bipyramid. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(2), one O(21), one O(24), one O(6), and one O(7) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  an edgeedge with one Li(6)O5 trigonal bipyramid, and  an edgeedge with one Li(7)O5 trigonal bipyramid. In the second Co site, Co(2) is bonded to one O(1), one O(11), one O(22), one O(23), one O(5), and one O(8) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid,  an edgeedge with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(8)O5 trigonal bipyramid. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(17), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(18), one O(2), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(15), one O(19), and one O(3) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(16), one O(20), and one O(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(13), one O(21), one O(23), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid, and  a cornercorner with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 47-64°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(22), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid, and  a cornercorner with one Li(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 47-65°. In the third P site, P(3) is bonded to one O(11), one O(25), one O(27), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid, and  a cornercorner with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-61°. In the fourth P site, P(4) is bonded to one O(12), one O(26), one O(28), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid, and  a cornercorner with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 43-60°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(4), one Co(2), and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Li(3), one Co(1), and one C(2) atom. In the third O site, O(3) is bonded to one Li(1), one Li(5), one Li(7), and one C(3) atom to form OLi3C tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid, and  an edgeedge with one O(9)Li2MnP tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one Li(6), one Li(8), and one C(4) atom to form OLi3C tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid, and  an edgeedge with one O(10)Li2MnP tetrahedra. In the fifth O site, O(5) is bonded to one Li(6), one Li(7), one Co(2), and one C(1) atom to form distorted OLi2CoC trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid, and  an edgeedge with one O(7)Li2CoP trigonal pyramid. In the sixth O site, O(6) is bonded to one Li(5), one Li(8), one Co(1), and one C(2) atom to form distorted OLi2CoC trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid, and  an edgeedge with one O(8)Li2CoP trigonal pyramid. In the seventh O site, O(7) is bonded to one Li(6), one Li(7), one Co(1), and one P(3) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  an edgeedge with one O(5)Li2CoC trigonal pyramid,  an edgeedge with one O(21)Li2CoP trigonal pyramid, and  an edgeedge with one O(24)Li2CoP trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(5), one Li(8), one Co(2), and one P(4) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid,  an edgeedge with one O(6)Li2CoC trigonal pyramid,  an edgeedge with one O(22)Li2CoP trigonal pyramid, and  an edgeedge with one O(23)Li2CoP trigonal pyramid. In the ninth O site, O(9) is bonded to one Li(5), one Li(7), one Mn(1), and one P(1) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid, and  an edgeedge with one O(3)Li3C tetrahedra. In the tenth O site, O(10) is bonded to one Li(6), one Li(8), one Mn(2), and one P(2) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(4)Li3C tetrahedra. In the eleventh O site, O(11) is bonded to one Li(11), one Li(9), one Co(2), and one P(3) atom to form distorted OLi2CoP tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(17)Li3C tetrahedra. In the twelfth O site, O(12) is bonded to one Li(10), one Li(12), one Co(1), and one P(4) atom to form distorted OLi2CoP tetrahedra that share  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(18)Li3C tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(12), one Li(9), one Mn(2), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  an edgeedge with one O(15)Li2MnC trigonal pyramid,  an edgeedge with one O(25)Li2MnP trigonal pyramid, and  an edgeedge with one O(28)Li2MnP trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(11), one Mn(1), and one P(2) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  an edgeedge with one O(16)Li2MnC trigonal pyramid,  an edgeedge with one O(26)Li2MnP trigonal pyramid, and  an edgeedge with one O(27)Li2MnP trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(12), one Li(9), one Mn(1), and one C(3) atom to form distorted OLi2MnC trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(13)Li2MnP trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(11), one Mn(2), and one C(4) atom to form distorted OLi2MnC trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(14)Li2MnP trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Li(11), one Li(3), one Li(9), and one C(1) atom to form OLi3C tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(11)Li2CoP tetrahedra. In the eighteenth O site, O(18) is bonded to one Li(10), one Li(12), one Li(4), and one C(2) atom to form distorted OLi3C tetrahedra that share  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(12)Li2CoP tetrahedra. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Li(2), one Mn(1), and one C(3) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Mn(2), and one C(4) atom. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(6), one Co(1), and one P(1) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  an edgeedge with one O(23)Li2CoP trigonal pyramid, and  an edgeedge with one O(7)Li2CoP trigonal pyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(5), one Co(2), and one P(2) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  an edgeedge with one O(24)Li2CoP trigonal pyramid, and  an edgeedge with one O(8)Li2CoP trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(8), one Co(2), and one P(1) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  an edgeedge with one O(21)Li2CoP trigonal pyramid, and  an edgeedge with one O(8)Li2CoP trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(7), one Co(1), and one P(2) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  an edgeedge with one O(22)Li2CoP trigonal pyramid, and  an edgeedge with one O(7)Li2CoP trigonal pyramid. In the twenty-fifth O site, O(25) is bonded to one Li(12), one Li(3), one Mn(2), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid,  an edgeedge with one O(13)Li2MnP trigonal pyramid, and  an edgeedge with one O(27)Li2MnP trigonal pyramid. In the twenty-sixth O site, O(26) is bonded to one Li(11), one Li(4), one Mn(1), and one P(4) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  an edgeedge with one O(14)Li2MnP trigonal pyramid, and  an edgeedge with one O(28)Li2MnP trigonal pyramid. In the twenty-seventh O site, O(27) is bonded to one Li(10), one Li(3), one Mn(1), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  an edgeedge with one O(14)Li2MnP trigonal pyramid, and  an edgeedge with one O(25)Li2MnP trigonal pyramid. In the twenty-eighth O site, O(28) is bonded to one Li(4), one Li(9), one Mn(2), and one P(4) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  an edgeedge with one O(13)Li2MnP trigonal pyramid, and  an edgeedge with one O(26)Li2MnP trigonal pyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li6MnCoP2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.013
_cell_length_b   6.516
_cell_length_c   8.547
_cell_angle_alpha   90.052
_cell_angle_beta   83.954
_cell_angle_gamma   90.022
_symmetry_Int_Tables_number   1
_cell_volume   277.655
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.682  0.750  0.042  1.0
  C  C1  1  0.323  0.250  0.964  1.0
  Co  Co2  1  0.790  0.751  0.334  1.0
  Li  Li3  1  0.791  0.250  0.102  1.0
  Li  Li4  1  0.209  0.750  0.895  1.0
  Li  Li5  1  0.265  0.018  0.271  1.0
  Li  Li6  1  0.265  0.482  0.271  1.0
  Li  Li7  1  0.734  0.520  0.728  1.0
  Li  Li8  1  0.734  0.980  0.729  1.0
  Mn  Mn9  1  0.220  0.250  0.660  1.0
  O  O10  1  0.932  0.750  0.068  1.0
  O  O11  1  0.391  0.250  0.107  1.0
  O  O12  1  0.502  0.749  0.164  1.0
  O  O13  1  0.164  0.750  0.424  1.0
  O  O14  1  0.417  0.250  0.423  1.0
  O  O15  1  0.579  0.749  0.567  1.0
  O  O16  1  0.818  0.249  0.576  1.0
  O  O17  1  0.509  0.250  0.844  1.0
  O  O18  1  0.610  0.750  0.900  1.0
  O  O19  1  0.075  0.250  0.936  1.0
  O  O20  1  0.840  0.063  0.307  1.0
  O  O21  1  0.841  0.437  0.308  1.0
  O  O22  1  0.158  0.934  0.692  1.0
  O  O23  1  0.158  0.565  0.692  1.0
  P  P24  1  0.730  0.250  0.408  1.0
  P  P25  1  0.265  0.750  0.588  1.0
[/CIF]
.
The compound described by Li6MnCoP2(CO7)2 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(20), one O(21), one O(23), and one O(3) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(19), one O(22), one O(24), and one O(4) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one O(17), one O(2), one O(25), and one O(27) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(1), one O(18), one O(26), and one O(28) atom. In the fifth Li site, Li(5) is bonded to one O(22), one O(3), one O(6), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Li(7)O5 trigonal bipyramid, and  an edgeedge with one Li(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-85°. In the sixth Li site, Li(6) is bonded to one O(10), one O(21), one O(4), one O(5), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Li(7)O5 trigonal bipyramid, and  an edgeedge with one Li(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-85°. In the seventh Li site, Li(7) is bonded to one O(24), one O(3), one O(5), one O(7), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-85°. In the eighth Li site, Li(8) is bonded to one O(10), one O(23), one O(4), one O(6), and one O(8) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(6)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-84°. In the ninth Li site, Li(9) is bonded to one O(11), one O(13), one O(15), one O(17), and one O(28) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Li(11)O5 trigonal bipyramid, and  an edgeedge with one Li(12)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-89°. In the tenth Li site, Li(10) is bonded to one O(12), one O(14), one O(16), one O(18), and one O(27) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Li(11)O5 trigonal bipyramid, and  an edgeedge with one Li(12)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-89°. In the eleventh Li site, Li(11) is bonded to one O(11), one O(14), one O(16), one O(17), and one O(26) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 66-89°. In the twelfth Li site, Li(12) is bonded to one O(12), one O(13), one O(15), one O(18), and one O(25) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 67-88°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(15), one O(19), one O(26), one O(27), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid,  an edgeedge with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one Li(11)O5 trigonal bipyramid. In the second Mn site, Mn(2) is bonded to one O(10), one O(13), one O(16), one O(20), one O(25), and one O(28) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  an edgeedge with one Li(12)O5 trigonal bipyramid, and  an edgeedge with one Li(9)O5 trigonal bipyramid. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(2), one O(21), one O(24), one O(6), and one O(7) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  an edgeedge with one Li(6)O5 trigonal bipyramid, and  an edgeedge with one Li(7)O5 trigonal bipyramid. In the second Co site, Co(2) is bonded to one O(1), one O(11), one O(22), one O(23), one O(5), and one O(8) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid,  an edgeedge with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(8)O5 trigonal bipyramid. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(17), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(18), one O(2), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(15), one O(19), and one O(3) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(16), one O(20), and one O(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(13), one O(21), one O(23), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid, and  a cornercorner with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 47-64°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(22), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid, and  a cornercorner with one Li(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 47-65°. In the third P site, P(3) is bonded to one O(11), one O(25), one O(27), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid, and  a cornercorner with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-61°. In the fourth P site, P(4) is bonded to one O(12), one O(26), one O(28), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(11)O5 trigonal bipyramid,  a cornercorner with one Li(12)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid, and  a cornercorner with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 43-60°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(4), one Co(2), and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Li(3), one Co(1), and one C(2) atom. In the third O site, O(3) is bonded to one Li(1), one Li(5), one Li(7), and one C(3) atom to form OLi3C tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid, and  an edgeedge with one O(9)Li2MnP tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one Li(6), one Li(8), and one C(4) atom to form OLi3C tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid, and  an edgeedge with one O(10)Li2MnP tetrahedra. In the fifth O site, O(5) is bonded to one Li(6), one Li(7), one Co(2), and one C(1) atom to form distorted OLi2CoC trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid, and  an edgeedge with one O(7)Li2CoP trigonal pyramid. In the sixth O site, O(6) is bonded to one Li(5), one Li(8), one Co(1), and one C(2) atom to form distorted OLi2CoC trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid, and  an edgeedge with one O(8)Li2CoP trigonal pyramid. In the seventh O site, O(7) is bonded to one Li(6), one Li(7), one Co(1), and one P(3) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  an edgeedge with one O(5)Li2CoC trigonal pyramid,  an edgeedge with one O(21)Li2CoP trigonal pyramid, and  an edgeedge with one O(24)Li2CoP trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(5), one Li(8), one Co(2), and one P(4) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid,  an edgeedge with one O(6)Li2CoC trigonal pyramid,  an edgeedge with one O(22)Li2CoP trigonal pyramid, and  an edgeedge with one O(23)Li2CoP trigonal pyramid. In the ninth O site, O(9) is bonded to one Li(5), one Li(7), one Mn(1), and one P(1) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid, and  an edgeedge with one O(3)Li3C tetrahedra. In the tenth O site, O(10) is bonded to one Li(6), one Li(8), one Mn(2), and one P(2) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(4)Li3C tetrahedra. In the eleventh O site, O(11) is bonded to one Li(11), one Li(9), one Co(2), and one P(3) atom to form distorted OLi2CoP tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(17)Li3C tetrahedra. In the twelfth O site, O(12) is bonded to one Li(10), one Li(12), one Co(1), and one P(4) atom to form distorted OLi2CoP tetrahedra that share  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(18)Li3C tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(12), one Li(9), one Mn(2), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  an edgeedge with one O(15)Li2MnC trigonal pyramid,  an edgeedge with one O(25)Li2MnP trigonal pyramid, and  an edgeedge with one O(28)Li2MnP trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(11), one Mn(1), and one P(2) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  an edgeedge with one O(16)Li2MnC trigonal pyramid,  an edgeedge with one O(26)Li2MnP trigonal pyramid, and  an edgeedge with one O(27)Li2MnP trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(12), one Li(9), one Mn(1), and one C(3) atom to form distorted OLi2MnC trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(13)Li2MnP trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(11), one Mn(2), and one C(4) atom to form distorted OLi2MnC trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(14)Li2MnP trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Li(11), one Li(3), one Li(9), and one C(1) atom to form OLi3C tetrahedra that share  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(11)Li2CoP tetrahedra. In the eighteenth O site, O(18) is bonded to one Li(10), one Li(12), one Li(4), and one C(2) atom to form distorted OLi3C tetrahedra that share  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid, and  an edgeedge with one O(12)Li2CoP tetrahedra. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Li(2), one Mn(1), and one C(3) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Mn(2), and one C(4) atom. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(6), one Co(1), and one P(1) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(24)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  an edgeedge with one O(23)Li2CoP trigonal pyramid, and  an edgeedge with one O(7)Li2CoP trigonal pyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(5), one Co(2), and one P(2) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(23)Li2CoP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  an edgeedge with one O(24)Li2CoP trigonal pyramid, and  an edgeedge with one O(8)Li2CoP trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(8), one Co(2), and one P(1) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li2MnP trigonal pyramid,  an edgeedge with one O(21)Li2CoP trigonal pyramid, and  an edgeedge with one O(8)Li2CoP trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(7), one Co(1), and one P(2) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(3)Li3C tetrahedra,  a cornercorner with one O(4)Li3C tetrahedra,  a cornercorner with one O(5)Li2CoC trigonal pyramid,  a cornercorner with one O(6)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(14)Li2MnP trigonal pyramid,  an edgeedge with one O(22)Li2CoP trigonal pyramid, and  an edgeedge with one O(7)Li2CoP trigonal pyramid. In the twenty-fifth O site, O(25) is bonded to one Li(12), one Li(3), one Mn(2), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(28)Li2MnP trigonal pyramid,  an edgeedge with one O(13)Li2MnP trigonal pyramid, and  an edgeedge with one O(27)Li2MnP trigonal pyramid. In the twenty-sixth O site, O(26) is bonded to one Li(11), one Li(4), one Mn(1), and one P(4) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(27)Li2MnP trigonal pyramid,  an edgeedge with one O(14)Li2MnP trigonal pyramid, and  an edgeedge with one O(28)Li2MnP trigonal pyramid. In the twenty-seventh O site, O(27) is bonded to one Li(10), one Li(3), one Mn(1), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(9)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(7)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(26)Li2MnP trigonal pyramid,  an edgeedge with one O(14)Li2MnP trigonal pyramid, and  an edgeedge with one O(25)Li2MnP trigonal pyramid. In the twenty-eighth O site, O(28) is bonded to one Li(4), one Li(9), one Mn(2), and one P(4) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2CoP tetrahedra,  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2MnP tetrahedra,  a cornercorner with one O(17)Li3C tetrahedra,  a cornercorner with one O(18)Li3C tetrahedra,  a cornercorner with one O(8)Li2CoP trigonal pyramid,  a cornercorner with one O(15)Li2MnC trigonal pyramid,  a cornercorner with one O(16)Li2MnC trigonal pyramid,  a cornercorner with one O(25)Li2MnP trigonal pyramid,  an edgeedge with one O(13)Li2MnP trigonal pyramid, and  an edgeedge with one O(26)Li2MnP trigonal pyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li6MnCoP2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.013
_cell_length_b   6.516
_cell_length_c   8.547
_cell_angle_alpha   90.052
_cell_angle_beta   83.954
_cell_angle_gamma   90.022
_symmetry_Int_Tables_number   1
_cell_volume   277.655
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.682  0.750  0.042  1.0
  C  C1  1  0.323  0.250  0.964  1.0
  Co  Co2  1  0.790  0.751  0.334  1.0
  Li  Li3  1  0.791  0.250  0.102  1.0
  Li  Li4  1  0.209  0.750  0.895  1.0
  Li  Li5  1  0.265  0.018  0.271  1.0
  Li  Li6  1  0.265  0.482  0.271  1.0
  Li  Li7  1  0.734  0.520  0.728  1.0
  Li  Li8  1  0.734  0.980  0.729  1.0
  Mn  Mn9  1  0.220  0.250  0.660  1.0
  O  O10  1  0.932  0.750  0.068  1.0
  O  O11  1  0.391  0.250  0.107  1.0
  O  O12  1  0.502  0.749  0.164  1.0
  O  O13  1  0.164  0.750  0.424  1.0
  O  O14  1  0.417  0.250  0.423  1.0
  O  O15  1  0.579  0.749  0.567  1.0
  O  O16  1  0.818  0.249  0.576  1.0
  O  O17  1  0.509  0.250  0.844  1.0
  O  O18  1  0.610  0.750  0.900  1.0
  O  O19  1  0.075  0.250  0.936  1.0
  O  O20  1  0.840  0.063  0.307  1.0
  O  O21  1  0.841  0.437  0.308  1.0
  O  O22  1  0.158  0.934  0.692  1.0
  O  O23  1  0.158  0.565  0.692  1.0
  P  P24  1  0.730  0.250  0.408  1.0
  P  P25  1  0.265  0.750  0.588  1.0
[/CIF]
.