The crystal structure described by Cs3Na2SnP3 crystallizes in the orthorhombic Cmce space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 5-coordinate geometry to one P(2) and four equivalent P(1) atoms. In the second Cs site, Cs(2) is bonded in a 4-coordinate geometry to two equivalent P(1) and three equivalent P(2) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 4-coordinate geometry to two equivalent P(1) and two equivalent P(2) atoms. In the second Na site, Na(2) is bonded to four equivalent P(1) atoms to form distorted NaP4 tetrahedra that share corners with two equivalent Sn(1)P4 tetrahedra,  an edgeedge with one Sn(1)P4 tetrahedra, and edges with two equivalent Na(2)P4 tetrahedra. Sn(1) is bonded to two equivalent P(1) and two equivalent P(2) atoms to form distorted SnP4 tetrahedra that share corners with two equivalent Na(2)P4 tetrahedra,  an edgeedge with one Na(2)P4 tetrahedra, and  an edgeedge with one Sn(1)P4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to one Cs(2), four equivalent Cs(1), one Na(1), two equivalent Na(2), and one Sn(1) atom. In the second P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Cs(1), three equivalent Cs(2), two equivalent Na(1), and two equivalent Sn(1) atoms. is represented by the CIF card [CIF]
data_Cs3Na2SnP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.884
_cell_length_b   10.884
_cell_length_c   16.558
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   142.911
_symmetry_Int_Tables_number   1
_cell_volume   1182.833
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.941  0.607  0.827  1.0
  Cs  Cs1  1  0.559  0.893  0.327  1.0
  Cs  Cs2  1  0.393  0.059  0.173  1.0
  Cs  Cs3  1  0.059  0.393  0.173  1.0
  Cs  Cs4  1  0.893  0.559  0.327  1.0
  Cs  Cs5  1  0.441  0.107  0.673  1.0
  Cs  Cs6  1  0.607  0.941  0.827  1.0
  Cs  Cs7  1  0.267  0.267  0.321  1.0
  Cs  Cs8  1  0.767  0.767  0.179  1.0
  Cs  Cs9  1  0.233  0.233  0.821  1.0
  Cs  Cs10  1  0.733  0.733  0.679  1.0
  Cs  Cs11  1  0.107  0.441  0.673  1.0
  Na  Na12  1  0.919  0.081  0.000  1.0
  Na  Na13  1  0.581  0.419  0.500  1.0
  Na  Na14  1  0.081  0.919  0.000  1.0
  Na  Na15  1  0.419  0.581  0.500  1.0
  Na  Na16  1  0.754  0.246  0.000  1.0
  Na  Na17  1  0.746  0.254  0.500  1.0
  Na  Na18  1  0.246  0.754  0.000  1.0
  Na  Na19  1  0.254  0.746  0.500  1.0
  Sn  Sn20  1  0.587  0.413  0.000  1.0
  Sn  Sn21  1  0.913  0.087  0.500  1.0
  Sn  Sn22  1  0.413  0.587  0.000  1.0
  Sn  Sn23  1  0.087  0.913  0.500  1.0
  P  P24  1  0.875  0.561  0.091  1.0
  P  P25  1  0.439  0.125  0.909  1.0
  P  P26  1  0.625  0.939  0.591  1.0
  P  P27  1  0.939  0.625  0.591  1.0
  P  P28  1  0.125  0.439  0.909  1.0
  P  P29  1  0.561  0.875  0.091  1.0
  P  P30  1  0.375  0.061  0.409  1.0
  P  P31  1  0.201  0.201  0.582  1.0
  P  P32  1  0.701  0.701  0.918  1.0
  P  P33  1  0.299  0.299  0.082  1.0
  P  P34  1  0.061  0.375  0.409  1.0
  P  P35  1  0.799  0.799  0.418  1.0
[/CIF]
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The crystal structure described by Cs3Na2SnP3 crystallizes in the orthorhombic Cmce space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 5-coordinate geometry to one P(2) and four equivalent P(1) atoms. In the second Cs site, Cs(2) is bonded in a 4-coordinate geometry to two equivalent P(1) and three equivalent P(2) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 4-coordinate geometry to two equivalent P(1) and two equivalent P(2) atoms. In the second Na site, Na(2) is bonded to four equivalent P(1) atoms to form distorted NaP4 tetrahedra that share corners with two equivalent Sn(1)P4 tetrahedra,  an edgeedge with one Sn(1)P4 tetrahedra, and edges with two equivalent Na(2)P4 tetrahedra. Sn(1) is bonded to two equivalent P(1) and two equivalent P(2) atoms to form distorted SnP4 tetrahedra that share corners with two equivalent Na(2)P4 tetrahedra,  an edgeedge with one Na(2)P4 tetrahedra, and  an edgeedge with one Sn(1)P4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to one Cs(2), four equivalent Cs(1), one Na(1), two equivalent Na(2), and one Sn(1) atom. In the second P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Cs(1), three equivalent Cs(2), two equivalent Na(1), and two equivalent Sn(1) atoms. is represented by the CIF card [CIF]
data_Cs3Na2SnP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.884
_cell_length_b   10.884
_cell_length_c   16.558
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   142.911
_symmetry_Int_Tables_number   1
_cell_volume   1182.833
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.941  0.607  0.827  1.0
  Cs  Cs1  1  0.559  0.893  0.327  1.0
  Cs  Cs2  1  0.393  0.059  0.173  1.0
  Cs  Cs3  1  0.059  0.393  0.173  1.0
  Cs  Cs4  1  0.893  0.559  0.327  1.0
  Cs  Cs5  1  0.441  0.107  0.673  1.0
  Cs  Cs6  1  0.607  0.941  0.827  1.0
  Cs  Cs7  1  0.267  0.267  0.321  1.0
  Cs  Cs8  1  0.767  0.767  0.179  1.0
  Cs  Cs9  1  0.233  0.233  0.821  1.0
  Cs  Cs10  1  0.733  0.733  0.679  1.0
  Cs  Cs11  1  0.107  0.441  0.673  1.0
  Na  Na12  1  0.919  0.081  0.000  1.0
  Na  Na13  1  0.581  0.419  0.500  1.0
  Na  Na14  1  0.081  0.919  0.000  1.0
  Na  Na15  1  0.419  0.581  0.500  1.0
  Na  Na16  1  0.754  0.246  0.000  1.0
  Na  Na17  1  0.746  0.254  0.500  1.0
  Na  Na18  1  0.246  0.754  0.000  1.0
  Na  Na19  1  0.254  0.746  0.500  1.0
  Sn  Sn20  1  0.587  0.413  0.000  1.0
  Sn  Sn21  1  0.913  0.087  0.500  1.0
  Sn  Sn22  1  0.413  0.587  0.000  1.0
  Sn  Sn23  1  0.087  0.913  0.500  1.0
  P  P24  1  0.875  0.561  0.091  1.0
  P  P25  1  0.439  0.125  0.909  1.0
  P  P26  1  0.625  0.939  0.591  1.0
  P  P27  1  0.939  0.625  0.591  1.0
  P  P28  1  0.125  0.439  0.909  1.0
  P  P29  1  0.561  0.875  0.091  1.0
  P  P30  1  0.375  0.061  0.409  1.0
  P  P31  1  0.201  0.201  0.582  1.0
  P  P32  1  0.701  0.701  0.918  1.0
  P  P33  1  0.299  0.299  0.082  1.0
  P  P34  1  0.061  0.375  0.409  1.0
  P  P35  1  0.799  0.799  0.418  1.0
[/CIF]
.