The structure described by Mg2WMn3S8 is Spinel-derived structured and crystallizes in the trigonal R-3m space group. Mg(1) is bonded to one S(1) and three equivalent S(2) atoms to form MgS4 tetrahedra that share corners with three equivalent W(1)S6 octahedra and corners with nine equivalent Mn(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 57-60°. W(1) is bonded to six equivalent S(2) atoms to form WS6 octahedra that share corners with six equivalent Mg(1)S4 tetrahedra and edges with six equivalent Mn(1)S6 octahedra. Mn(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form MnS6 octahedra that share corners with six equivalent Mg(1)S4 tetrahedra, edges with two equivalent W(1)S6 octahedra, and edges with four equivalent Mn(1)S6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Mg(1) and three equivalent Mn(1) atoms to form distorted SMgMn3 tetrahedra that share corners with three equivalent S(1)MgMn3 tetrahedra, corners with nine equivalent S(2)MgMn2W trigonal pyramids, and edges with three equivalent S(2)MgMn2W trigonal pyramids. In the second S site, S(2) is bonded to one Mg(1), one W(1), and two equivalent Mn(1) atoms to form distorted SMgMn2W trigonal pyramids that share corners with three equivalent S(1)MgMn3 tetrahedra, corners with nine equivalent S(2)MgMn2W trigonal pyramids,  an edgeedge with one S(1)MgMn3 tetrahedra, and edges with two equivalent S(2)MgMn2W trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg2Mn3WS8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.320
_cell_length_b   7.318
_cell_length_c   7.325
_cell_angle_alpha   60.022
_cell_angle_beta   60.027
_cell_angle_gamma   60.033
_symmetry_Int_Tables_number   1
_cell_volume   277.668
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.870  0.870  0.870  1.0
  Mg  Mg1  1  0.130  0.131  0.130  1.0
  Mn  Mn2  1  0.500  0.500  0.000  1.0
  Mn  Mn3  1  0.000  0.500  0.500  1.0
  Mn  Mn4  1  0.500  1.000  0.500  1.0
  W  W5  1  0.500  0.500  0.500  1.0
  S  S6  1  0.734  0.734  0.734  1.0
  S  S7  1  0.265  0.265  0.721  1.0
  S  S8  1  0.265  0.721  0.265  1.0
  S  S9  1  0.721  0.265  0.265  1.0
  S  S10  1  0.735  0.279  0.735  1.0
  S  S11  1  0.279  0.735  0.735  1.0
  S  S12  1  0.266  0.266  0.266  1.0
  S  S13  1  0.735  0.735  0.279  1.0
[/CIF]
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The structure described by Mg2WMn3S8 is Spinel-derived structured and crystallizes in the trigonal R-3m space group. Mg(1) is bonded to one S(1) and three equivalent S(2) atoms to form MgS4 tetrahedra that share corners with three equivalent W(1)S6 octahedra and corners with nine equivalent Mn(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 57-60°. W(1) is bonded to six equivalent S(2) atoms to form WS6 octahedra that share corners with six equivalent Mg(1)S4 tetrahedra and edges with six equivalent Mn(1)S6 octahedra. Mn(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form MnS6 octahedra that share corners with six equivalent Mg(1)S4 tetrahedra, edges with two equivalent W(1)S6 octahedra, and edges with four equivalent Mn(1)S6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Mg(1) and three equivalent Mn(1) atoms to form distorted SMgMn3 tetrahedra that share corners with three equivalent S(1)MgMn3 tetrahedra, corners with nine equivalent S(2)MgMn2W trigonal pyramids, and edges with three equivalent S(2)MgMn2W trigonal pyramids. In the second S site, S(2) is bonded to one Mg(1), one W(1), and two equivalent Mn(1) atoms to form distorted SMgMn2W trigonal pyramids that share corners with three equivalent S(1)MgMn3 tetrahedra, corners with nine equivalent S(2)MgMn2W trigonal pyramids,  an edgeedge with one S(1)MgMn3 tetrahedra, and edges with two equivalent S(2)MgMn2W trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg2Mn3WS8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.320
_cell_length_b   7.318
_cell_length_c   7.325
_cell_angle_alpha   60.022
_cell_angle_beta   60.027
_cell_angle_gamma   60.033
_symmetry_Int_Tables_number   1
_cell_volume   277.668
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.870  0.870  0.870  1.0
  Mg  Mg1  1  0.130  0.131  0.130  1.0
  Mn  Mn2  1  0.500  0.500  0.000  1.0
  Mn  Mn3  1  0.000  0.500  0.500  1.0
  Mn  Mn4  1  0.500  1.000  0.500  1.0
  W  W5  1  0.500  0.500  0.500  1.0
  S  S6  1  0.734  0.734  0.734  1.0
  S  S7  1  0.265  0.265  0.721  1.0
  S  S8  1  0.265  0.721  0.265  1.0
  S  S9  1  0.721  0.265  0.265  1.0
  S  S10  1  0.735  0.279  0.735  1.0
  S  S11  1  0.279  0.735  0.735  1.0
  S  S12  1  0.266  0.266  0.266  1.0
  S  S13  1  0.735  0.735  0.279  1.0
[/CIF]
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