The compound described by Mg(Ag2O3)2 crystallizes in the trigonal R-3m space group. Mg(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted see-saw-like geometry to one Mg(1), one Ag(2), and two equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg(Ag2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.884
_cell_length_b   5.884
_cell_length_c   5.884
_cell_angle_alpha   72.016
_cell_angle_beta   72.016
_cell_angle_gamma   72.016
_symmetry_Int_Tables_number   1
_cell_volume   179.047
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.000  0.500  0.500  1.0
  Ag  Ag2  1  0.500  0.500  0.000  1.0
  Ag  Ag3  1  0.500  0.000  0.500  1.0
  Ag  Ag4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.738  0.738  0.326  1.0
  O  O6  1  0.738  0.326  0.738  1.0
  O  O7  1  0.262  0.674  0.262  1.0
  O  O8  1  0.262  0.262  0.674  1.0
  O  O9  1  0.326  0.738  0.738  1.0
  O  O10  1  0.674  0.262  0.262  1.0
[/CIF]
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The compound described by Mg(Ag2O3)2 crystallizes in the trigonal R-3m space group. Mg(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted see-saw-like geometry to one Mg(1), one Ag(2), and two equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg(Ag2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.884
_cell_length_b   5.884
_cell_length_c   5.884
_cell_angle_alpha   72.016
_cell_angle_beta   72.016
_cell_angle_gamma   72.016
_symmetry_Int_Tables_number   1
_cell_volume   179.047
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.000  0.500  0.500  1.0
  Ag  Ag2  1  0.500  0.500  0.000  1.0
  Ag  Ag3  1  0.500  0.000  0.500  1.0
  Ag  Ag4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.738  0.738  0.326  1.0
  O  O6  1  0.738  0.326  0.738  1.0
  O  O7  1  0.262  0.674  0.262  1.0
  O  O8  1  0.262  0.262  0.674  1.0
  O  O9  1  0.326  0.738  0.738  1.0
  O  O10  1  0.674  0.262  0.262  1.0
[/CIF]
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