The material structure described by SrLa2(CoO3)3 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one O(11), one O(14), one O(15), one O(18), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(10), one O(12), one O(13), one O(16), one O(17), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to one O(11), one O(15), one O(2), one O(4), one O(6), one O(9), two equivalent O(13), two equivalent O(17), and two equivalent O(7) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(1), one O(10), one O(12), one O(16), one O(3), one O(5), two equivalent O(14), two equivalent O(18), and two equivalent O(8) atoms. In the third La site, La(3) is bonded in a 12-coordinate geometry to one O(1), one O(13), one O(17), one O(3), one O(5), one O(7), two equivalent O(11), two equivalent O(15), and two equivalent O(9) atoms. In the fourth La site, La(4) is bonded in a 12-coordinate geometry to one O(14), one O(18), one O(2), one O(4), one O(6), one O(8), two equivalent O(10), two equivalent O(12), and two equivalent O(16) atoms. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(13), one O(15), one O(17), one O(7), and one O(9) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 13-26°. In the second Co site, Co(2) is bonded to one O(10), one O(12), one O(16), one O(2), one O(4), and one O(6) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 0-25°. In the third Co site, Co(3) is bonded to one O(1), one O(14), one O(18), one O(3), one O(5), and one O(8) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 1-25°. In the fourth Co site, Co(4) is bonded to one O(10), one O(12), one O(14), one O(16), one O(18), and one O(8) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 0-25°. In the fifth Co site, Co(5) is bonded to one O(1), one O(11), one O(15), one O(3), one O(5), and one O(9) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 5-25°. In the sixth Co site, Co(6) is bonded to one O(13), one O(17), one O(2), one O(4), one O(6), and one O(7) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 6-26°. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one La(2), one La(3), one Co(3), and one Co(5) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sr(2), one La(1), one La(4), one Co(2), and one Co(6) atom. In the third O site, O(3) is bonded to two equivalent Sr(1), one La(2), one La(3), one Co(3), and one Co(5) atom to form distorted corner-sharing OSr2La2Co2 octahedra. The corner-sharing octahedral tilt angles are 4°. In the fourth O site, O(4) is bonded to two equivalent Sr(2), one La(1), one La(4), one Co(2), and one Co(6) atom to form distorted corner-sharing OSr2La2Co2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one La(2), one La(3), one Co(3), and one Co(5) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one La(1), one La(4), one Co(2), and one Co(6) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sr(2), one La(3), two equivalent La(1), one Co(1), and one Co(6) atom. In the eighth O site, O(8) is bonded in a 6-coordinate geometry to one Sr(1), one La(4), two equivalent La(2), one Co(3), and one Co(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Co(1), and one Co(5) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Co(2), and one Co(4) atom. In the eleventh O site, O(11) is bonded in a 1-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Co(1), and one Co(5) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Co(2), and one Co(4) atom. In the thirteenth O site, O(13) is bonded in a 1-coordinate geometry to one Sr(2), one La(3), two equivalent La(1), one Co(1), and one Co(6) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one Sr(1), one La(4), two equivalent La(2), one Co(3), and one Co(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Co(1), and one Co(5) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Co(2), and one Co(4) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Sr(2), one La(3), two equivalent La(1), one Co(1), and one Co(6) atom. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one Sr(1), one La(4), two equivalent La(2), one Co(3), and one Co(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrLa2(CoO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.462
_cell_length_b   5.556
_cell_length_c   13.668
_cell_angle_alpha   90.356
_cell_angle_beta   90.155
_cell_angle_gamma   60.357
_symmetry_Int_Tables_number   1
_cell_volume   360.550
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.321  0.337  0.418  1.0
  Sr  Sr1  1  0.346  0.331  0.915  1.0
  La  La2  1  0.682  0.651  0.082  1.0
  La  La3  1  0.665  0.657  0.584  1.0
  La  La4  1  0.983  0.016  0.252  1.0
  La  La5  1  0.003  0.008  0.748  1.0
  Co  Co6  1  0.334  0.333  0.167  1.0
  Co  Co7  1  0.670  0.668  0.839  1.0
  Co  Co8  1  0.997  0.999  0.494  1.0
  Co  Co9  1  0.333  0.333  0.667  1.0
  Co  Co10  1  0.661  0.671  0.337  1.0
  Co  Co11  1  0.006  0.997  0.996  1.0
  O  O12  1  0.790  0.843  0.441  1.0
  O  O13  1  0.876  0.826  0.892  1.0
  O  O14  1  0.825  0.327  0.412  1.0
  O  O15  1  0.841  0.343  0.923  1.0
  O  O16  1  0.305  0.811  0.395  1.0
  O  O17  1  0.361  0.857  0.938  1.0
  O  O18  1  0.124  0.171  0.110  1.0
  O  O19  1  0.218  0.103  0.571  1.0
  O  O20  1  0.543  0.494  0.224  1.0
  O  O21  1  0.449  0.562  0.762  1.0
  O  O22  1  0.476  0.060  0.257  1.0
  O  O23  1  0.487  0.032  0.745  1.0
  O  O24  1  0.192  0.605  0.077  1.0
  O  O25  1  0.179  0.634  0.588  1.0
  O  O26  1  0.978  0.578  0.258  1.0
  O  O27  1  0.972  0.469  0.728  1.0
  O  O28  1  0.690  0.087  0.076  1.0
  O  O29  1  0.695  0.197  0.605  1.0
[/CIF]
.
The material structure described by SrLa2(CoO3)3 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one O(11), one O(14), one O(15), one O(18), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(10), one O(12), one O(13), one O(16), one O(17), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to one O(11), one O(15), one O(2), one O(4), one O(6), one O(9), two equivalent O(13), two equivalent O(17), and two equivalent O(7) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(1), one O(10), one O(12), one O(16), one O(3), one O(5), two equivalent O(14), two equivalent O(18), and two equivalent O(8) atoms. In the third La site, La(3) is bonded in a 12-coordinate geometry to one O(1), one O(13), one O(17), one O(3), one O(5), one O(7), two equivalent O(11), two equivalent O(15), and two equivalent O(9) atoms. In the fourth La site, La(4) is bonded in a 12-coordinate geometry to one O(14), one O(18), one O(2), one O(4), one O(6), one O(8), two equivalent O(10), two equivalent O(12), and two equivalent O(16) atoms. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(13), one O(15), one O(17), one O(7), and one O(9) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 13-26°. In the second Co site, Co(2) is bonded to one O(10), one O(12), one O(16), one O(2), one O(4), and one O(6) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 0-25°. In the third Co site, Co(3) is bonded to one O(1), one O(14), one O(18), one O(3), one O(5), and one O(8) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 1-25°. In the fourth Co site, Co(4) is bonded to one O(10), one O(12), one O(14), one O(16), one O(18), and one O(8) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 0-25°. In the fifth Co site, Co(5) is bonded to one O(1), one O(11), one O(15), one O(3), one O(5), and one O(9) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 5-25°. In the sixth Co site, Co(6) is bonded to one O(13), one O(17), one O(2), one O(4), one O(6), and one O(7) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 6-26°. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one La(2), one La(3), one Co(3), and one Co(5) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sr(2), one La(1), one La(4), one Co(2), and one Co(6) atom. In the third O site, O(3) is bonded to two equivalent Sr(1), one La(2), one La(3), one Co(3), and one Co(5) atom to form distorted corner-sharing OSr2La2Co2 octahedra. The corner-sharing octahedral tilt angles are 4°. In the fourth O site, O(4) is bonded to two equivalent Sr(2), one La(1), one La(4), one Co(2), and one Co(6) atom to form distorted corner-sharing OSr2La2Co2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one La(2), one La(3), one Co(3), and one Co(5) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one La(1), one La(4), one Co(2), and one Co(6) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sr(2), one La(3), two equivalent La(1), one Co(1), and one Co(6) atom. In the eighth O site, O(8) is bonded in a 6-coordinate geometry to one Sr(1), one La(4), two equivalent La(2), one Co(3), and one Co(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Co(1), and one Co(5) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Co(2), and one Co(4) atom. In the eleventh O site, O(11) is bonded in a 1-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Co(1), and one Co(5) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Co(2), and one Co(4) atom. In the thirteenth O site, O(13) is bonded in a 1-coordinate geometry to one Sr(2), one La(3), two equivalent La(1), one Co(1), and one Co(6) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one Sr(1), one La(4), two equivalent La(2), one Co(3), and one Co(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Co(1), and one Co(5) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Co(2), and one Co(4) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Sr(2), one La(3), two equivalent La(1), one Co(1), and one Co(6) atom. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one Sr(1), one La(4), two equivalent La(2), one Co(3), and one Co(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrLa2(CoO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.462
_cell_length_b   5.556
_cell_length_c   13.668
_cell_angle_alpha   90.356
_cell_angle_beta   90.155
_cell_angle_gamma   60.357
_symmetry_Int_Tables_number   1
_cell_volume   360.550
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.321  0.337  0.418  1.0
  Sr  Sr1  1  0.346  0.331  0.915  1.0
  La  La2  1  0.682  0.651  0.082  1.0
  La  La3  1  0.665  0.657  0.584  1.0
  La  La4  1  0.983  0.016  0.252  1.0
  La  La5  1  0.003  0.008  0.748  1.0
  Co  Co6  1  0.334  0.333  0.167  1.0
  Co  Co7  1  0.670  0.668  0.839  1.0
  Co  Co8  1  0.997  0.999  0.494  1.0
  Co  Co9  1  0.333  0.333  0.667  1.0
  Co  Co10  1  0.661  0.671  0.337  1.0
  Co  Co11  1  0.006  0.997  0.996  1.0
  O  O12  1  0.790  0.843  0.441  1.0
  O  O13  1  0.876  0.826  0.892  1.0
  O  O14  1  0.825  0.327  0.412  1.0
  O  O15  1  0.841  0.343  0.923  1.0
  O  O16  1  0.305  0.811  0.395  1.0
  O  O17  1  0.361  0.857  0.938  1.0
  O  O18  1  0.124  0.171  0.110  1.0
  O  O19  1  0.218  0.103  0.571  1.0
  O  O20  1  0.543  0.494  0.224  1.0
  O  O21  1  0.449  0.562  0.762  1.0
  O  O22  1  0.476  0.060  0.257  1.0
  O  O23  1  0.487  0.032  0.745  1.0
  O  O24  1  0.192  0.605  0.077  1.0
  O  O25  1  0.179  0.634  0.588  1.0
  O  O26  1  0.978  0.578  0.258  1.0
  O  O27  1  0.972  0.469  0.728  1.0
  O  O28  1  0.690  0.087  0.076  1.0
  O  O29  1  0.695  0.197  0.605  1.0
[/CIF]
.