The structure described by Nb3P crystallizes in the tetragonal P4_2/n space group. There are three inequivalent Nb sites. In the first Nb site, Nb(1) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. In the second Nb site, Nb(2) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. In the third Nb site, Nb(3) is bonded in a 2-coordinate geometry to three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to two equivalent Nb(1), three equivalent Nb(3), and four equivalent Nb(2) atoms. is represented by the CIF file [CIF]
data_Nb3P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.134
_cell_length_b   10.179
_cell_length_c   10.179
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   531.948
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.724  0.164  0.653  1.0
  Nb  Nb1  1  0.224  0.347  0.664  1.0
  Nb  Nb2  1  0.224  0.153  0.836  1.0
  Nb  Nb3  1  0.724  0.336  0.847  1.0
  Nb  Nb4  1  0.276  0.836  0.347  1.0
  Nb  Nb5  1  0.776  0.653  0.336  1.0
  Nb  Nb6  1  0.776  0.847  0.164  1.0
  Nb  Nb7  1  0.276  0.664  0.153  1.0
  Nb  Nb8  1  0.517  0.105  0.263  1.0
  Nb  Nb9  1  0.017  0.737  0.605  1.0
  Nb  Nb10  1  0.017  0.763  0.895  1.0
  Nb  Nb11  1  0.517  0.395  0.237  1.0
  Nb  Nb12  1  0.483  0.895  0.737  1.0
  Nb  Nb13  1  0.983  0.263  0.395  1.0
  Nb  Nb14  1  0.983  0.237  0.105  1.0
  Nb  Nb15  1  0.483  0.605  0.763  1.0
  Nb  Nb16  1  0.239  0.059  0.537  1.0
  Nb  Nb17  1  0.739  0.463  0.559  1.0
  Nb  Nb18  1  0.739  0.037  0.941  1.0
  Nb  Nb19  1  0.239  0.441  0.963  1.0
  Nb  Nb20  1  0.761  0.941  0.463  1.0
  Nb  Nb21  1  0.261  0.537  0.441  1.0
  Nb  Nb22  1  0.261  0.963  0.059  1.0
  Nb  Nb23  1  0.761  0.559  0.037  1.0
  P  P24  1  0.021  0.043  0.275  1.0
  P  P25  1  0.521  0.725  0.543  1.0
  P  P26  1  0.521  0.775  0.957  1.0
  P  P27  1  0.021  0.457  0.225  1.0
  P  P28  1  0.979  0.957  0.725  1.0
  P  P29  1  0.479  0.275  0.457  1.0
  P  P30  1  0.479  0.225  0.043  1.0
  P  P31  1  0.979  0.543  0.775  1.0
[/CIF]
.
The structure described by Nb3P crystallizes in the tetragonal P4_2/n space group. There are three inequivalent Nb sites. In the first Nb site, Nb(1) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. In the second Nb site, Nb(2) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. In the third Nb site, Nb(3) is bonded in a 2-coordinate geometry to three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to two equivalent Nb(1), three equivalent Nb(3), and four equivalent Nb(2) atoms. is represented by the CIF file [CIF]
data_Nb3P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.134
_cell_length_b   10.179
_cell_length_c   10.179
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   531.948
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.724  0.164  0.653  1.0
  Nb  Nb1  1  0.224  0.347  0.664  1.0
  Nb  Nb2  1  0.224  0.153  0.836  1.0
  Nb  Nb3  1  0.724  0.336  0.847  1.0
  Nb  Nb4  1  0.276  0.836  0.347  1.0
  Nb  Nb5  1  0.776  0.653  0.336  1.0
  Nb  Nb6  1  0.776  0.847  0.164  1.0
  Nb  Nb7  1  0.276  0.664  0.153  1.0
  Nb  Nb8  1  0.517  0.105  0.263  1.0
  Nb  Nb9  1  0.017  0.737  0.605  1.0
  Nb  Nb10  1  0.017  0.763  0.895  1.0
  Nb  Nb11  1  0.517  0.395  0.237  1.0
  Nb  Nb12  1  0.483  0.895  0.737  1.0
  Nb  Nb13  1  0.983  0.263  0.395  1.0
  Nb  Nb14  1  0.983  0.237  0.105  1.0
  Nb  Nb15  1  0.483  0.605  0.763  1.0
  Nb  Nb16  1  0.239  0.059  0.537  1.0
  Nb  Nb17  1  0.739  0.463  0.559  1.0
  Nb  Nb18  1  0.739  0.037  0.941  1.0
  Nb  Nb19  1  0.239  0.441  0.963  1.0
  Nb  Nb20  1  0.761  0.941  0.463  1.0
  Nb  Nb21  1  0.261  0.537  0.441  1.0
  Nb  Nb22  1  0.261  0.963  0.059  1.0
  Nb  Nb23  1  0.761  0.559  0.037  1.0
  P  P24  1  0.021  0.043  0.275  1.0
  P  P25  1  0.521  0.725  0.543  1.0
  P  P26  1  0.521  0.775  0.957  1.0
  P  P27  1  0.021  0.457  0.225  1.0
  P  P28  1  0.979  0.957  0.725  1.0
  P  P29  1  0.479  0.275  0.457  1.0
  P  P30  1  0.479  0.225  0.043  1.0
  P  P31  1  0.979  0.543  0.775  1.0
[/CIF]
.