The compound described by CdWO4 crystallizes in the monoclinic P2/c space group. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted WO6 octahedra that share corners with eight equivalent Cd(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-58°. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted CdO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-58°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Cd(1) atoms. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent W(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_CdWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.906
_cell_length_b   5.047
_cell_length_c   5.089
_cell_angle_alpha   88.795
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   151.670
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.691  0.500  0.250  1.0
  Cd  Cd1  1  0.309  0.500  0.750  1.0
  W  W2  1  0.177  0.000  0.250  1.0
  W  W3  1  0.823  0.000  0.750  1.0
  O  O4  1  0.096  0.799  0.948  1.0
  O  O5  1  0.096  0.201  0.552  1.0
  O  O6  1  0.904  0.201  0.052  1.0
  O  O7  1  0.904  0.799  0.448  1.0
  O  O8  1  0.370  0.757  0.384  1.0
  O  O9  1  0.370  0.243  0.116  1.0
  O  O10  1  0.630  0.243  0.616  1.0
  O  O11  1  0.630  0.757  0.884  1.0
[/CIF]
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The compound described by CdWO4 crystallizes in the monoclinic P2/c space group. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted WO6 octahedra that share corners with eight equivalent Cd(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-58°. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted CdO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-58°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Cd(1) atoms. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent W(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_CdWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.906
_cell_length_b   5.047
_cell_length_c   5.089
_cell_angle_alpha   88.795
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   151.670
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.691  0.500  0.250  1.0
  Cd  Cd1  1  0.309  0.500  0.750  1.0
  W  W2  1  0.177  0.000  0.250  1.0
  W  W3  1  0.823  0.000  0.750  1.0
  O  O4  1  0.096  0.799  0.948  1.0
  O  O5  1  0.096  0.201  0.552  1.0
  O  O6  1  0.904  0.201  0.052  1.0
  O  O7  1  0.904  0.799  0.448  1.0
  O  O8  1  0.370  0.757  0.384  1.0
  O  O9  1  0.370  0.243  0.116  1.0
  O  O10  1  0.630  0.243  0.616  1.0
  O  O11  1  0.630  0.757  0.884  1.0
[/CIF]
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