The material structure described by V32N3 crystallizes in the monoclinic P2/m space group. There are sixteen inequivalent V sites. In the first V site, V(1) is bonded in an L-shaped geometry to two equivalent V(11), two equivalent V(8), and two equivalent N(2) atoms. In the second V site, V(2) is bonded in a 14-coordinate geometry to one V(10), one V(13), one V(6), two equivalent V(12), two equivalent V(7), three equivalent V(2), and four equivalent V(16) atoms. In the third V site, V(3) is bonded in an L-shaped geometry to two equivalent V(10), two equivalent V(6), and two equivalent N(1) atoms. In the fourth V site, V(4) is bonded in an L-shaped geometry to two equivalent V(5), two equivalent V(9), and two equivalent N(1) atoms. In the fifth V site, V(5) is bonded in a distorted body-centered cubic geometry to two equivalent V(15), two equivalent V(4), and four equivalent V(11) atoms. In the sixth V site, V(6) is bonded in a distorted body-centered cubic geometry to one V(2), two equivalent V(16), two equivalent V(3), and four equivalent V(12) atoms. In the seventh V site, V(7) is bonded in a distorted body-centered cubic geometry to two equivalent V(10), two equivalent V(13), two equivalent V(2), and two equivalent V(9) atoms. In the eighth V site, V(8) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(10), two equivalent V(14), and two equivalent V(9) atoms. In the ninth V site, V(9) is bonded in a distorted body-centered cubic geometry to two equivalent V(15), two equivalent V(4), two equivalent V(7), and two equivalent V(8) atoms. In the tenth V site, V(10) is bonded in a distorted body-centered cubic geometry to one V(2), two equivalent V(16), two equivalent V(3), two equivalent V(7), and two equivalent V(8) atoms. In the eleventh V site, V(11) is bonded in a distorted body-centered cubic geometry to two equivalent V(1), two equivalent V(14), and four equivalent V(5) atoms. In the twelfth V site, V(12) is bonded in a distorted body-centered cubic geometry to two equivalent V(13), two equivalent V(2), and four equivalent V(6) atoms. In the thirteenth V site, V(13) is bonded in a single-bond geometry to one V(2), two equivalent V(12), two equivalent V(7), and one N(1) atom. In the fourteenth V site, V(14) is bonded in a single-bond geometry to two equivalent V(11), two equivalent V(8), and one N(1) atom. In the fifteenth V site, V(15) is bonded in a single-bond geometry to two equivalent V(5), two equivalent V(9), and one N(2) atom. In the sixteenth V site, V(16) is bonded in a distorted body-centered cubic geometry to two equivalent V(10), two equivalent V(6), and four equivalent V(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to one V(13), one V(14), two equivalent V(3), and two equivalent V(4) atoms to form edge-sharing NV6 octahedra. In the second N site, N(2) is bonded to two equivalent V(15) and four equivalent V(1) atoms to form edge-sharing NV6 octahedra. is represented by the CIF card [CIF]
data_V32N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.966
_cell_length_b   8.631
_cell_length_c   17.273
_cell_angle_alpha   90.795
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   442.170
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.889  0.057  1.0
  V  V1  1  0.500  0.884  0.558  1.0
  V  V2  1  0.500  0.116  0.442  1.0
  V  V3  1  0.500  0.111  0.943  1.0
  V  V4  1  0.000  0.622  0.310  1.0
  V  V5  1  0.000  0.609  0.804  1.0
  V  V6  1  0.000  0.391  0.196  1.0
  V  V7  1  0.000  0.378  0.690  1.0
  V  V8  1  0.500  0.387  0.064  1.0
  V  V9  1  0.500  0.373  0.561  1.0
  V  V10  1  0.500  0.627  0.439  1.0
  V  V11  1  0.500  0.613  0.936  1.0
  V  V12  1  0.000  0.116  0.317  1.0
  V  V13  1  0.000  0.110  0.812  1.0
  V  V14  1  0.000  0.890  0.188  1.0
  V  V15  1  0.000  0.884  0.683  1.0
  V  V16  1  0.500  0.129  0.194  1.0
  V  V17  1  0.500  0.120  0.686  1.0
  V  V18  1  0.500  0.880  0.314  1.0
  V  V19  1  0.500  0.871  0.806  1.0
  V  V20  1  0.000  0.628  0.058  1.0
  V  V21  1  0.000  0.629  0.555  1.0
  V  V22  1  0.000  0.371  0.445  1.0
  V  V23  1  0.000  0.372  0.942  1.0
  V  V24  1  0.500  0.351  0.330  1.0
  V  V25  1  0.500  0.337  0.826  1.0
  V  V26  1  0.500  0.663  0.174  1.0
  V  V27  1  0.500  0.649  0.670  1.0
  V  V28  1  0.000  0.160  0.079  1.0
  V  V29  1  0.000  0.128  0.565  1.0
  V  V30  1  0.000  0.872  0.435  1.0
  V  V31  1  0.000  0.840  0.921  1.0
  N  N32  1  0.500  0.507  0.252  1.0
  N  N33  1  0.500  0.493  0.748  1.0
  N  N34  1  0.000  0.000  0.000  1.0
[/CIF]
.
The material structure described by V32N3 crystallizes in the monoclinic P2/m space group. There are sixteen inequivalent V sites. In the first V site, V(1) is bonded in an L-shaped geometry to two equivalent V(11), two equivalent V(8), and two equivalent N(2) atoms. In the second V site, V(2) is bonded in a 14-coordinate geometry to one V(10), one V(13), one V(6), two equivalent V(12), two equivalent V(7), three equivalent V(2), and four equivalent V(16) atoms. In the third V site, V(3) is bonded in an L-shaped geometry to two equivalent V(10), two equivalent V(6), and two equivalent N(1) atoms. In the fourth V site, V(4) is bonded in an L-shaped geometry to two equivalent V(5), two equivalent V(9), and two equivalent N(1) atoms. In the fifth V site, V(5) is bonded in a distorted body-centered cubic geometry to two equivalent V(15), two equivalent V(4), and four equivalent V(11) atoms. In the sixth V site, V(6) is bonded in a distorted body-centered cubic geometry to one V(2), two equivalent V(16), two equivalent V(3), and four equivalent V(12) atoms. In the seventh V site, V(7) is bonded in a distorted body-centered cubic geometry to two equivalent V(10), two equivalent V(13), two equivalent V(2), and two equivalent V(9) atoms. In the eighth V site, V(8) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(10), two equivalent V(14), and two equivalent V(9) atoms. In the ninth V site, V(9) is bonded in a distorted body-centered cubic geometry to two equivalent V(15), two equivalent V(4), two equivalent V(7), and two equivalent V(8) atoms. In the tenth V site, V(10) is bonded in a distorted body-centered cubic geometry to one V(2), two equivalent V(16), two equivalent V(3), two equivalent V(7), and two equivalent V(8) atoms. In the eleventh V site, V(11) is bonded in a distorted body-centered cubic geometry to two equivalent V(1), two equivalent V(14), and four equivalent V(5) atoms. In the twelfth V site, V(12) is bonded in a distorted body-centered cubic geometry to two equivalent V(13), two equivalent V(2), and four equivalent V(6) atoms. In the thirteenth V site, V(13) is bonded in a single-bond geometry to one V(2), two equivalent V(12), two equivalent V(7), and one N(1) atom. In the fourteenth V site, V(14) is bonded in a single-bond geometry to two equivalent V(11), two equivalent V(8), and one N(1) atom. In the fifteenth V site, V(15) is bonded in a single-bond geometry to two equivalent V(5), two equivalent V(9), and one N(2) atom. In the sixteenth V site, V(16) is bonded in a distorted body-centered cubic geometry to two equivalent V(10), two equivalent V(6), and four equivalent V(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to one V(13), one V(14), two equivalent V(3), and two equivalent V(4) atoms to form edge-sharing NV6 octahedra. In the second N site, N(2) is bonded to two equivalent V(15) and four equivalent V(1) atoms to form edge-sharing NV6 octahedra. is represented by the CIF card [CIF]
data_V32N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.966
_cell_length_b   8.631
_cell_length_c   17.273
_cell_angle_alpha   90.795
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   442.170
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.889  0.057  1.0
  V  V1  1  0.500  0.884  0.558  1.0
  V  V2  1  0.500  0.116  0.442  1.0
  V  V3  1  0.500  0.111  0.943  1.0
  V  V4  1  0.000  0.622  0.310  1.0
  V  V5  1  0.000  0.609  0.804  1.0
  V  V6  1  0.000  0.391  0.196  1.0
  V  V7  1  0.000  0.378  0.690  1.0
  V  V8  1  0.500  0.387  0.064  1.0
  V  V9  1  0.500  0.373  0.561  1.0
  V  V10  1  0.500  0.627  0.439  1.0
  V  V11  1  0.500  0.613  0.936  1.0
  V  V12  1  0.000  0.116  0.317  1.0
  V  V13  1  0.000  0.110  0.812  1.0
  V  V14  1  0.000  0.890  0.188  1.0
  V  V15  1  0.000  0.884  0.683  1.0
  V  V16  1  0.500  0.129  0.194  1.0
  V  V17  1  0.500  0.120  0.686  1.0
  V  V18  1  0.500  0.880  0.314  1.0
  V  V19  1  0.500  0.871  0.806  1.0
  V  V20  1  0.000  0.628  0.058  1.0
  V  V21  1  0.000  0.629  0.555  1.0
  V  V22  1  0.000  0.371  0.445  1.0
  V  V23  1  0.000  0.372  0.942  1.0
  V  V24  1  0.500  0.351  0.330  1.0
  V  V25  1  0.500  0.337  0.826  1.0
  V  V26  1  0.500  0.663  0.174  1.0
  V  V27  1  0.500  0.649  0.670  1.0
  V  V28  1  0.000  0.160  0.079  1.0
  V  V29  1  0.000  0.128  0.565  1.0
  V  V30  1  0.000  0.872  0.435  1.0
  V  V31  1  0.000  0.840  0.921  1.0
  N  N32  1  0.500  0.507  0.252  1.0
  N  N33  1  0.500  0.493  0.748  1.0
  N  N34  1  0.000  0.000  0.000  1.0
[/CIF]
.