The structure described by (LaP3H5O6)2H2 crystallizes in the triclinic P-1 space group. The structure consists of one 1333-74-0 molecule inside a LaP3H5O6 framework. In the LaP3H5O6 framework, La(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(6), two equivalent O(1), and two equivalent O(3) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one O(1), and one O(2) atom. In the second P site, P(2) is bonded in a distorted tetrahedral geometry to one H(3), one H(4), one O(3), and one O(4) atom. In the third P site, P(3) is bonded in a distorted tetrahedral geometry to one H(5), one H(6), one O(5), and one O(6) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one P(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one P(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one P(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one P(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent La(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one La(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent La(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(1) and one P(3) atom. is represented by the CIF file [CIF]
data_LaP3(HO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.937
_cell_length_b   7.299
_cell_length_c   8.806
_cell_angle_alpha   83.509
_cell_angle_beta   76.641
_cell_angle_gamma   76.553
_symmetry_Int_Tables_number   1
_cell_volume   421.097
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.734  0.412  0.642  1.0
  La  La1  1  0.266  0.588  0.358  1.0
  P  P2  1  0.892  0.870  0.680  1.0
  P  P3  1  0.108  0.130  0.320  1.0
  P  P4  1  0.271  0.231  0.695  1.0
  P  P5  1  0.729  0.769  0.305  1.0
  P  P6  1  0.359  0.705  0.927  1.0
  P  P7  1  0.641  0.295  0.073  1.0
  H  H8  1  0.775  0.830  0.832  1.0
  H  H9  1  0.225  0.170  0.168  1.0
  H  H10  1  0.020  0.039  0.975  1.0
  H  H11  1  0.980  0.961  0.025  1.0
  H  H12  1  0.323  0.072  0.604  1.0
  H  H13  1  0.677  0.928  0.396  1.0
  H  H14  1  0.361  0.168  0.826  1.0
  H  H15  1  0.639  0.832  0.174  1.0
  H  H16  1  0.252  0.891  0.915  1.0
  H  H17  1  0.748  0.109  0.085  1.0
  H  H18  1  0.212  0.594  0.934  1.0
  H  H19  1  0.788  0.406  0.066  1.0
  O  O20  1  0.928  0.693  0.587  1.0
  O  O21  1  0.072  0.307  0.413  1.0
  O  O22  1  0.781  0.060  0.616  1.0
  O  O23  1  0.219  0.940  0.384  1.0
  O  O24  1  0.381  0.384  0.601  1.0
  O  O25  1  0.619  0.616  0.399  1.0
  O  O26  1  0.042  0.290  0.752  1.0
  O  O27  1  0.958  0.710  0.248  1.0
  O  O28  1  0.519  0.678  0.776  1.0
  O  O29  1  0.481  0.322  0.224  1.0
  O  O30  1  0.422  0.678  0.084  1.0
  O  O31  1  0.578  0.322  0.916  1.0
[/CIF]
.
The structure described by (LaP3H5O6)2H2 crystallizes in the triclinic P-1 space group. The structure consists of one 1333-74-0 molecule inside a LaP3H5O6 framework. In the LaP3H5O6 framework, La(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(6), two equivalent O(1), and two equivalent O(3) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one O(1), and one O(2) atom. In the second P site, P(2) is bonded in a distorted tetrahedral geometry to one H(3), one H(4), one O(3), and one O(4) atom. In the third P site, P(3) is bonded in a distorted tetrahedral geometry to one H(5), one H(6), one O(5), and one O(6) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one P(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one P(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one P(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one P(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent La(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one La(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent La(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(1) and one P(3) atom. is represented by the CIF file [CIF]
data_LaP3(HO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.937
_cell_length_b   7.299
_cell_length_c   8.806
_cell_angle_alpha   83.509
_cell_angle_beta   76.641
_cell_angle_gamma   76.553
_symmetry_Int_Tables_number   1
_cell_volume   421.097
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.734  0.412  0.642  1.0
  La  La1  1  0.266  0.588  0.358  1.0
  P  P2  1  0.892  0.870  0.680  1.0
  P  P3  1  0.108  0.130  0.320  1.0
  P  P4  1  0.271  0.231  0.695  1.0
  P  P5  1  0.729  0.769  0.305  1.0
  P  P6  1  0.359  0.705  0.927  1.0
  P  P7  1  0.641  0.295  0.073  1.0
  H  H8  1  0.775  0.830  0.832  1.0
  H  H9  1  0.225  0.170  0.168  1.0
  H  H10  1  0.020  0.039  0.975  1.0
  H  H11  1  0.980  0.961  0.025  1.0
  H  H12  1  0.323  0.072  0.604  1.0
  H  H13  1  0.677  0.928  0.396  1.0
  H  H14  1  0.361  0.168  0.826  1.0
  H  H15  1  0.639  0.832  0.174  1.0
  H  H16  1  0.252  0.891  0.915  1.0
  H  H17  1  0.748  0.109  0.085  1.0
  H  H18  1  0.212  0.594  0.934  1.0
  H  H19  1  0.788  0.406  0.066  1.0
  O  O20  1  0.928  0.693  0.587  1.0
  O  O21  1  0.072  0.307  0.413  1.0
  O  O22  1  0.781  0.060  0.616  1.0
  O  O23  1  0.219  0.940  0.384  1.0
  O  O24  1  0.381  0.384  0.601  1.0
  O  O25  1  0.619  0.616  0.399  1.0
  O  O26  1  0.042  0.290  0.752  1.0
  O  O27  1  0.958  0.710  0.248  1.0
  O  O28  1  0.519  0.678  0.776  1.0
  O  O29  1  0.481  0.322  0.224  1.0
  O  O30  1  0.422  0.678  0.084  1.0
  O  O31  1  0.578  0.322  0.916  1.0
[/CIF]
.