The crystal structure described by Y6WO12 crystallizes in the trigonal R-3 space group. Y(1) is bonded in a 7-coordinate geometry to three equivalent O(2) and four equivalent O(1) atoms. W(1) is bonded in an octahedral geometry to six equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 4-coordinate geometry to three equivalent Y(1) and one W(1) atom. In the second O site, O(1) is bonded to four equivalent Y(1) atoms to form a mixture of edge and corner-sharing OY4 tetrahedra. is represented by the CIF card [CIF]
data_Y6WO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.440
_cell_length_b   6.440
_cell_length_c   6.440
_cell_angle_alpha   98.673
_cell_angle_beta   98.673
_cell_angle_gamma   98.673
_symmetry_Int_Tables_number   1
_cell_volume   256.839
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.314  0.143  0.610  1.0
  Y  Y1  1  0.390  0.686  0.857  1.0
  Y  Y2  1  0.857  0.390  0.686  1.0
  Y  Y3  1  0.686  0.857  0.390  1.0
  Y  Y4  1  0.610  0.314  0.143  1.0
  Y  Y5  1  0.143  0.610  0.314  1.0
  W  W6  1  0.000  0.000  0.000  1.0
  O  O7  1  0.177  0.431  0.592  1.0
  O  O8  1  0.592  0.177  0.431  1.0
  O  O9  1  0.431  0.592  0.177  1.0
  O  O10  1  0.823  0.569  0.408  1.0
  O  O11  1  0.408  0.823  0.569  1.0
  O  O12  1  0.569  0.408  0.823  1.0
  O  O13  1  0.924  0.033  0.705  1.0
  O  O14  1  0.967  0.295  0.076  1.0
  O  O15  1  0.295  0.076  0.967  1.0
  O  O16  1  0.076  0.967  0.295  1.0
  O  O17  1  0.033  0.705  0.924  1.0
  O  O18  1  0.705  0.924  0.033  1.0
[/CIF]
.
The crystal structure described by Y6WO12 crystallizes in the trigonal R-3 space group. Y(1) is bonded in a 7-coordinate geometry to three equivalent O(2) and four equivalent O(1) atoms. W(1) is bonded in an octahedral geometry to six equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 4-coordinate geometry to three equivalent Y(1) and one W(1) atom. In the second O site, O(1) is bonded to four equivalent Y(1) atoms to form a mixture of edge and corner-sharing OY4 tetrahedra. is represented by the CIF card [CIF]
data_Y6WO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.440
_cell_length_b   6.440
_cell_length_c   6.440
_cell_angle_alpha   98.673
_cell_angle_beta   98.673
_cell_angle_gamma   98.673
_symmetry_Int_Tables_number   1
_cell_volume   256.839
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.314  0.143  0.610  1.0
  Y  Y1  1  0.390  0.686  0.857  1.0
  Y  Y2  1  0.857  0.390  0.686  1.0
  Y  Y3  1  0.686  0.857  0.390  1.0
  Y  Y4  1  0.610  0.314  0.143  1.0
  Y  Y5  1  0.143  0.610  0.314  1.0
  W  W6  1  0.000  0.000  0.000  1.0
  O  O7  1  0.177  0.431  0.592  1.0
  O  O8  1  0.592  0.177  0.431  1.0
  O  O9  1  0.431  0.592  0.177  1.0
  O  O10  1  0.823  0.569  0.408  1.0
  O  O11  1  0.408  0.823  0.569  1.0
  O  O12  1  0.569  0.408  0.823  1.0
  O  O13  1  0.924  0.033  0.705  1.0
  O  O14  1  0.967  0.295  0.076  1.0
  O  O15  1  0.295  0.076  0.967  1.0
  O  O16  1  0.076  0.967  0.295  1.0
  O  O17  1  0.033  0.705  0.924  1.0
  O  O18  1  0.705  0.924  0.033  1.0
[/CIF]
.