The crystal structure described by Ag6GeSO8 crystallizes in the tetragonal I4_1/amd space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Ge(1) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one S(1) atom. In the second O site, O(2) is bonded to one Ag(2), two equivalent Ag(1), and one Ge(1) atom to form corner-sharing OAg3Ge tetrahedra. is represented by the CIF file [CIF]
data_Ag6GeSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.547
_cell_length_b   10.547
_cell_length_c   10.547
_cell_angle_alpha   140.527
_cell_angle_beta   140.527
_cell_angle_gamma   57.053
_symmetry_Int_Tables_number   1
_cell_volume   470.240
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.375  0.418  0.543  1.0
  Ag  Ag1  1  0.486  0.986  0.500  1.0
  Ag  Ag2  1  0.875  0.832  0.457  1.0
  Ag  Ag3  1  0.264  0.264  0.000  1.0
  Ag  Ag4  1  0.582  0.125  0.957  1.0
  Ag  Ag5  1  0.875  0.418  0.043  1.0
  Ag  Ag6  1  0.168  0.625  0.043  1.0
  Ag  Ag7  1  0.582  0.625  0.457  1.0
  Ag  Ag8  1  0.168  0.125  0.543  1.0
  Ag  Ag9  1  0.375  0.832  0.957  1.0
  Ag  Ag10  1  0.014  0.514  0.500  1.0
  Ag  Ag11  1  0.736  0.736  0.000  1.0
  Ge  Ge12  1  0.250  0.750  0.500  1.0
  Ge  Ge13  1  0.500  0.500  0.000  1.0
  S  S14  1  0.750  0.250  0.500  1.0
  S  S15  1  0.000  0.000  0.000  1.0
  O  O16  1  0.953  0.781  0.828  1.0
  O  O17  1  0.652  0.445  0.207  1.0
  O  O18  1  0.875  0.047  0.828  1.0
  O  O19  1  0.555  0.761  0.207  1.0
  O  O20  1  0.875  0.203  0.672  1.0
  O  O21  1  0.195  0.489  0.293  1.0
  O  O22  1  0.195  0.902  0.707  1.0
  O  O23  1  0.511  0.805  0.707  1.0
  O  O24  1  0.219  0.047  0.172  1.0
  O  O25  1  0.239  0.445  0.793  1.0
  O  O26  1  0.531  0.203  0.328  1.0
  O  O27  1  0.555  0.348  0.793  1.0
  O  O28  1  0.797  0.469  0.672  1.0
  O  O29  1  0.953  0.125  0.172  1.0
  O  O30  1  0.098  0.805  0.293  1.0
  O  O31  1  0.797  0.125  0.328  1.0
[/CIF]
.
The crystal structure described by Ag6GeSO8 crystallizes in the tetragonal I4_1/amd space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Ge(1) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one S(1) atom. In the second O site, O(2) is bonded to one Ag(2), two equivalent Ag(1), and one Ge(1) atom to form corner-sharing OAg3Ge tetrahedra. is represented by the CIF file [CIF]
data_Ag6GeSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.547
_cell_length_b   10.547
_cell_length_c   10.547
_cell_angle_alpha   140.527
_cell_angle_beta   140.527
_cell_angle_gamma   57.053
_symmetry_Int_Tables_number   1
_cell_volume   470.240
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.375  0.418  0.543  1.0
  Ag  Ag1  1  0.486  0.986  0.500  1.0
  Ag  Ag2  1  0.875  0.832  0.457  1.0
  Ag  Ag3  1  0.264  0.264  0.000  1.0
  Ag  Ag4  1  0.582  0.125  0.957  1.0
  Ag  Ag5  1  0.875  0.418  0.043  1.0
  Ag  Ag6  1  0.168  0.625  0.043  1.0
  Ag  Ag7  1  0.582  0.625  0.457  1.0
  Ag  Ag8  1  0.168  0.125  0.543  1.0
  Ag  Ag9  1  0.375  0.832  0.957  1.0
  Ag  Ag10  1  0.014  0.514  0.500  1.0
  Ag  Ag11  1  0.736  0.736  0.000  1.0
  Ge  Ge12  1  0.250  0.750  0.500  1.0
  Ge  Ge13  1  0.500  0.500  0.000  1.0
  S  S14  1  0.750  0.250  0.500  1.0
  S  S15  1  0.000  0.000  0.000  1.0
  O  O16  1  0.953  0.781  0.828  1.0
  O  O17  1  0.652  0.445  0.207  1.0
  O  O18  1  0.875  0.047  0.828  1.0
  O  O19  1  0.555  0.761  0.207  1.0
  O  O20  1  0.875  0.203  0.672  1.0
  O  O21  1  0.195  0.489  0.293  1.0
  O  O22  1  0.195  0.902  0.707  1.0
  O  O23  1  0.511  0.805  0.707  1.0
  O  O24  1  0.219  0.047  0.172  1.0
  O  O25  1  0.239  0.445  0.793  1.0
  O  O26  1  0.531  0.203  0.328  1.0
  O  O27  1  0.555  0.348  0.793  1.0
  O  O28  1  0.797  0.469  0.672  1.0
  O  O29  1  0.953  0.125  0.172  1.0
  O  O30  1  0.098  0.805  0.293  1.0
  O  O31  1  0.797  0.125  0.328  1.0
[/CIF]
.