The material structure described by MoOCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MoOCl4 clusters and four SCl3 clusters. In each MoOCl4 cluster, Mo(1) is bonded in a 1-coordinate geometry to one O(1), one Cl(3), one Cl(5), one Cl(6), and two equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to two equivalent Mo(1) atoms. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one Mo(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(2), one Cl(4), and one Cl(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_MoSCl7O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.553
_cell_length_b   10.028
_cell_length_c   12.847
_cell_angle_alpha   65.141
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1116.723
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.839  0.656  0.498  1.0
  Mo  Mo1  1  0.661  0.656  0.998  1.0
  Mo  Mo2  1  0.161  0.344  0.502  1.0
  Mo  Mo3  1  0.339  0.344  0.002  1.0
  S  S4  1  0.738  0.218  0.487  1.0
  S  S5  1  0.262  0.782  0.513  1.0
  S  S6  1  0.238  0.782  0.013  1.0
  S  S7  1  0.762  0.218  0.987  1.0
  Cl  Cl8  1  0.955  0.467  0.386  1.0
  Cl  Cl9  1  0.419  0.680  0.622  1.0
  Cl  Cl10  1  0.500  0.833  0.863  1.0
  Cl  Cl11  1  0.363  0.945  0.383  1.0
  Cl  Cl12  1  0.321  0.281  0.653  1.0
  Cl  Cl13  1  1.000  0.833  0.363  1.0
  Cl  Cl14  1  0.455  0.533  0.114  1.0
  Cl  Cl15  1  0.000  0.167  0.637  1.0
  Cl  Cl16  1  0.581  0.320  0.378  1.0
  Cl  Cl17  1  0.179  0.281  0.153  1.0
  Cl  Cl18  1  0.081  0.680  0.122  1.0
  Cl  Cl19  1  0.500  0.167  0.137  1.0
  Cl  Cl20  1  0.679  0.719  0.347  1.0
  Cl  Cl21  1  0.208  0.564  0.900  1.0
  Cl  Cl22  1  0.863  0.055  0.117  1.0
  Cl  Cl23  1  0.137  0.945  0.883  1.0
  Cl  Cl24  1  0.828  0.105  0.406  1.0
  Cl  Cl25  1  0.919  0.320  0.878  1.0
  Cl  Cl26  1  0.328  0.895  0.094  1.0
  Cl  Cl27  1  0.545  0.467  0.886  1.0
  Cl  Cl28  1  0.045  0.533  0.614  1.0
  Cl  Cl29  1  0.821  0.719  0.847  1.0
  Cl  Cl30  1  0.637  0.055  0.617  1.0
  Cl  Cl31  1  0.672  0.105  0.906  1.0
  Cl  Cl32  1  0.172  0.895  0.594  1.0
  Cl  Cl33  1  0.292  0.564  0.400  1.0
  Cl  Cl34  1  0.708  0.436  0.600  1.0
  Cl  Cl35  1  0.792  0.436  0.100  1.0
  O  O36  1  0.215  0.244  0.430  1.0
  O  O37  1  0.785  0.756  0.570  1.0
  O  O38  1  0.715  0.756  0.070  1.0
  O  O39  1  0.285  0.244  0.930  1.0
[/CIF]
.
The material structure described by MoOCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MoOCl4 clusters and four SCl3 clusters. In each MoOCl4 cluster, Mo(1) is bonded in a 1-coordinate geometry to one O(1), one Cl(3), one Cl(5), one Cl(6), and two equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to two equivalent Mo(1) atoms. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one Mo(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(2), one Cl(4), and one Cl(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_MoSCl7O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.553
_cell_length_b   10.028
_cell_length_c   12.847
_cell_angle_alpha   65.141
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1116.723
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.839  0.656  0.498  1.0
  Mo  Mo1  1  0.661  0.656  0.998  1.0
  Mo  Mo2  1  0.161  0.344  0.502  1.0
  Mo  Mo3  1  0.339  0.344  0.002  1.0
  S  S4  1  0.738  0.218  0.487  1.0
  S  S5  1  0.262  0.782  0.513  1.0
  S  S6  1  0.238  0.782  0.013  1.0
  S  S7  1  0.762  0.218  0.987  1.0
  Cl  Cl8  1  0.955  0.467  0.386  1.0
  Cl  Cl9  1  0.419  0.680  0.622  1.0
  Cl  Cl10  1  0.500  0.833  0.863  1.0
  Cl  Cl11  1  0.363  0.945  0.383  1.0
  Cl  Cl12  1  0.321  0.281  0.653  1.0
  Cl  Cl13  1  1.000  0.833  0.363  1.0
  Cl  Cl14  1  0.455  0.533  0.114  1.0
  Cl  Cl15  1  0.000  0.167  0.637  1.0
  Cl  Cl16  1  0.581  0.320  0.378  1.0
  Cl  Cl17  1  0.179  0.281  0.153  1.0
  Cl  Cl18  1  0.081  0.680  0.122  1.0
  Cl  Cl19  1  0.500  0.167  0.137  1.0
  Cl  Cl20  1  0.679  0.719  0.347  1.0
  Cl  Cl21  1  0.208  0.564  0.900  1.0
  Cl  Cl22  1  0.863  0.055  0.117  1.0
  Cl  Cl23  1  0.137  0.945  0.883  1.0
  Cl  Cl24  1  0.828  0.105  0.406  1.0
  Cl  Cl25  1  0.919  0.320  0.878  1.0
  Cl  Cl26  1  0.328  0.895  0.094  1.0
  Cl  Cl27  1  0.545  0.467  0.886  1.0
  Cl  Cl28  1  0.045  0.533  0.614  1.0
  Cl  Cl29  1  0.821  0.719  0.847  1.0
  Cl  Cl30  1  0.637  0.055  0.617  1.0
  Cl  Cl31  1  0.672  0.105  0.906  1.0
  Cl  Cl32  1  0.172  0.895  0.594  1.0
  Cl  Cl33  1  0.292  0.564  0.400  1.0
  Cl  Cl34  1  0.708  0.436  0.600  1.0
  Cl  Cl35  1  0.792  0.436  0.100  1.0
  O  O36  1  0.215  0.244  0.430  1.0
  O  O37  1  0.785  0.756  0.570  1.0
  O  O38  1  0.715  0.756  0.070  1.0
  O  O39  1  0.285  0.244  0.930  1.0
[/CIF]
.