The crystal structure described by UCd(MoO4)4 crystallizes in the monoclinic P2/c space group. U(1) is bonded to one O(9), two equivalent O(1), two equivalent O(5), and two equivalent O(8) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent Cd(1)O7 pentagonal bipyramids. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(7) atom. Cd(1) is bonded to one O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms to form CdO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent Mo(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one U(1), one Mo(1), and one Mo(2) atom. In the third O site, O(2) is bonded in a distorted linear geometry to one Mo(1) and one Mo(2) atom. In the fourth O site, O(3) is bonded in a distorted linear geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Mo(2) and one Cd(1) atom. In the sixth O site, O(5) is bonded in a linear geometry to one U(1) and one Cd(1) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cd(1) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Cd(1) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one U(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_UCd(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.720
_cell_length_b   8.261
_cell_length_c   14.224
_cell_angle_alpha   54.960
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   646.464
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.298  0.000  0.750  1.0
  U  U1  1  0.702  0.000  0.250  1.0
  Cd  Cd2  1  0.699  0.500  0.250  1.0
  Cd  Cd3  1  0.301  0.500  0.750  1.0
  Mo  Mo4  1  0.830  0.802  0.907  1.0
  Mo  Mo5  1  0.170  0.198  0.093  1.0
  Mo  Mo6  1  0.830  0.198  0.593  1.0
  Mo  Mo7  1  0.170  0.802  0.407  1.0
  Mo  Mo8  1  0.828  0.304  0.903  1.0
  Mo  Mo9  1  0.172  0.696  0.097  1.0
  Mo  Mo10  1  0.828  0.696  0.597  1.0
  Mo  Mo11  1  0.172  0.304  0.403  1.0
  O  O12  1  0.848  0.815  0.432  1.0
  O  O13  1  0.152  0.185  0.568  1.0
  O  O14  1  0.848  0.909  0.596  1.0
  O  O15  1  0.152  0.091  0.404  1.0
  O  O16  1  0.843  0.595  0.903  1.0
  O  O17  1  0.157  0.405  0.097  1.0
  O  O18  1  0.934  0.500  0.750  1.0
  O  O19  1  0.066  0.500  0.250  1.0
  O  O20  1  0.299  0.780  0.747  1.0
  O  O21  1  0.701  0.220  0.253  1.0
  O  O22  1  0.424  0.363  0.374  1.0
  O  O23  1  0.576  0.637  0.626  1.0
  O  O24  1  0.152  0.815  0.932  1.0
  O  O25  1  0.848  0.185  0.068  1.0
  O  O26  1  0.299  0.220  0.753  1.0
  O  O27  1  0.701  0.780  0.247  1.0
  O  O28  1  0.851  0.689  0.063  1.0
  O  O29  1  0.149  0.311  0.937  1.0
  O  O30  1  0.574  0.876  0.871  1.0
  O  O31  1  0.426  0.124  0.129  1.0
  O  O32  1  0.576  0.363  0.874  1.0
  O  O33  1  0.424  0.637  0.126  1.0
  O  O34  1  0.157  0.595  0.403  1.0
  O  O35  1  0.843  0.405  0.597  1.0
  O  O36  1  0.942  0.000  0.750  1.0
  O  O37  1  0.058  0.000  0.250  1.0
  O  O38  1  0.574  0.124  0.629  1.0
  O  O39  1  0.426  0.876  0.371  1.0
  O  O40  1  0.848  0.091  0.904  1.0
  O  O41  1  0.152  0.909  0.096  1.0
  O  O42  1  0.851  0.311  0.437  1.0
  O  O43  1  0.149  0.689  0.563  1.0
[/CIF]
.
The crystal structure described by UCd(MoO4)4 crystallizes in the monoclinic P2/c space group. U(1) is bonded to one O(9), two equivalent O(1), two equivalent O(5), and two equivalent O(8) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent Cd(1)O7 pentagonal bipyramids. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(7) atom. Cd(1) is bonded to one O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms to form CdO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent Mo(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one U(1), one Mo(1), and one Mo(2) atom. In the third O site, O(2) is bonded in a distorted linear geometry to one Mo(1) and one Mo(2) atom. In the fourth O site, O(3) is bonded in a distorted linear geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Mo(2) and one Cd(1) atom. In the sixth O site, O(5) is bonded in a linear geometry to one U(1) and one Cd(1) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cd(1) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Cd(1) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one U(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_UCd(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.720
_cell_length_b   8.261
_cell_length_c   14.224
_cell_angle_alpha   54.960
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   646.464
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.298  0.000  0.750  1.0
  U  U1  1  0.702  0.000  0.250  1.0
  Cd  Cd2  1  0.699  0.500  0.250  1.0
  Cd  Cd3  1  0.301  0.500  0.750  1.0
  Mo  Mo4  1  0.830  0.802  0.907  1.0
  Mo  Mo5  1  0.170  0.198  0.093  1.0
  Mo  Mo6  1  0.830  0.198  0.593  1.0
  Mo  Mo7  1  0.170  0.802  0.407  1.0
  Mo  Mo8  1  0.828  0.304  0.903  1.0
  Mo  Mo9  1  0.172  0.696  0.097  1.0
  Mo  Mo10  1  0.828  0.696  0.597  1.0
  Mo  Mo11  1  0.172  0.304  0.403  1.0
  O  O12  1  0.848  0.815  0.432  1.0
  O  O13  1  0.152  0.185  0.568  1.0
  O  O14  1  0.848  0.909  0.596  1.0
  O  O15  1  0.152  0.091  0.404  1.0
  O  O16  1  0.843  0.595  0.903  1.0
  O  O17  1  0.157  0.405  0.097  1.0
  O  O18  1  0.934  0.500  0.750  1.0
  O  O19  1  0.066  0.500  0.250  1.0
  O  O20  1  0.299  0.780  0.747  1.0
  O  O21  1  0.701  0.220  0.253  1.0
  O  O22  1  0.424  0.363  0.374  1.0
  O  O23  1  0.576  0.637  0.626  1.0
  O  O24  1  0.152  0.815  0.932  1.0
  O  O25  1  0.848  0.185  0.068  1.0
  O  O26  1  0.299  0.220  0.753  1.0
  O  O27  1  0.701  0.780  0.247  1.0
  O  O28  1  0.851  0.689  0.063  1.0
  O  O29  1  0.149  0.311  0.937  1.0
  O  O30  1  0.574  0.876  0.871  1.0
  O  O31  1  0.426  0.124  0.129  1.0
  O  O32  1  0.576  0.363  0.874  1.0
  O  O33  1  0.424  0.637  0.126  1.0
  O  O34  1  0.157  0.595  0.403  1.0
  O  O35  1  0.843  0.405  0.597  1.0
  O  O36  1  0.942  0.000  0.750  1.0
  O  O37  1  0.058  0.000  0.250  1.0
  O  O38  1  0.574  0.124  0.629  1.0
  O  O39  1  0.426  0.876  0.371  1.0
  O  O40  1  0.848  0.091  0.904  1.0
  O  O41  1  0.152  0.909  0.096  1.0
  O  O42  1  0.851  0.311  0.437  1.0
  O  O43  1  0.149  0.689  0.563  1.0
[/CIF]
.