The structure described by LiMg14V crystallizes in the orthorhombic Amm2 space group. Li(1) is bonded to two equivalent Mg(7), four equivalent Mg(3), four equivalent Mg(5), and two equivalent V(1) atoms to form LiMg10V2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with six equivalent Li(1)Mg10V2 cuboctahedra; corners with eight Mg(4,4)Mg12 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra; edges with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with eight Mg(5,5)LiMg10V cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent V(1)Li2Mg10 cuboctahedra; faces with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; and faces with six equivalent Mg(6)Mg11V cuboctahedra. There are nine inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2); two equivalent Mg(6); four Mg(4,4); and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Li(1)Mg10V2 cuboctahedra; corners with six equivalent Mg(1)Mg12 cuboctahedra; corners with eight equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with eight Mg(5,5)LiMg10V cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent V(1)Li2Mg10 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with six equivalent Mg(7)LiMg11 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1); two equivalent Mg(7); four Mg(4,4); and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent V(1)Li2Mg10 cuboctahedra; corners with six equivalent Mg(2)Mg12 cuboctahedra; corners with eight equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with eight Mg(5,5)LiMg10V cuboctahedra; faces with two equivalent Li(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with six equivalent Mg(6)Mg11V cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Li(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent V(1) atoms to form distorted MgLi2Mg8V2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra; edges with four equivalent Mg(5)LiMg10V cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Li(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent V(1)Li2Mg10 cuboctahedra; and faces with eight Mg(5,5)LiMg10V cuboctahedra. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Li(1)Mg10V2 cuboctahedra; corners with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; corners with four equivalent V(1)Li2Mg10 cuboctahedra; corners with six equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(5)LiMg10V cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; and faces with eight Mg(5,5)LiMg10V cuboctahedra. In the fifth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Li(1)Mg10V2 cuboctahedra; corners with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; corners with four equivalent V(1)Li2Mg10 cuboctahedra; corners with six equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(5)LiMg10V cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; and faces with eight Mg(5,5)LiMg10V cuboctahedra. In the sixth Mg site, Mg(5) is bonded to one Li(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one V(1) atom to form distorted MgLiMg10V cuboctahedra that share corners with four equivalent Mg(7)LiMg11 cuboctahedra; corners with four equivalent Mg(6)Mg11V cuboctahedra; corners with ten Mg(5,5)LiMg10V cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Mg(5)LiMg10V cuboctahedra; edges with two equivalent Mg(7)LiMg11 cuboctahedra; edges with two equivalent Mg(6)Mg11V cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra;  a faceface with one Li(1)Mg10V2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Li2Mg10 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with four Mg(5,5)LiMg10V cuboctahedra; and faces with four Mg(4,4)Mg12 cuboctahedra. In the seventh Mg site, Mg(5) is bonded to one Li(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one V(1) atom to form distorted MgLiMg10V cuboctahedra that share corners with four equivalent Mg(7)LiMg11 cuboctahedra; corners with four equivalent Mg(6)Mg11V cuboctahedra; corners with ten equivalent Mg(5)LiMg10V cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Mg(5)LiMg10V cuboctahedra; edges with two equivalent Mg(7)LiMg11 cuboctahedra; edges with two equivalent Mg(6)Mg11V cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra;  a faceface with one Li(1)Mg10V2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Li2Mg10 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; and faces with four Mg(4,4)Mg12 cuboctahedra. In the eighth Mg site, Mg(6) is bonded to one Mg(1); two equivalent Mg(3); two Mg(4,4); two equivalent Mg(7); four Mg(5,5); and one V(1) atom to form distorted MgMg11V cuboctahedra that share corners with four equivalent Mg(7)LiMg11 cuboctahedra; corners with six equivalent Mg(6)Mg11V cuboctahedra; corners with eight Mg(5,5)LiMg10V cuboctahedra; edges with two equivalent Mg(7)LiMg11 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra; edges with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with four Mg(5,5)LiMg10V cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one V(1)Li2Mg10 cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two Mg(4,4)Mg12 cuboctahedra; faces with three equivalent Li(1)Mg10V2 cuboctahedra; faces with three equivalent Mg(2)Mg12 cuboctahedra; and faces with four Mg(5,5)LiMg10V cuboctahedra. In the ninth Mg site, Mg(7) is bonded to one Li(1); one Mg(2); two equivalent Mg(3); two Mg(4,4); two equivalent Mg(6); and four Mg(5,5) atoms to form distorted MgLiMg11 cuboctahedra that share corners with four equivalent Mg(6)Mg11V cuboctahedra; corners with six equivalent Mg(7)LiMg11 cuboctahedra; corners with eight Mg(5,5)LiMg10V cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with two equivalent Mg(6)Mg11V cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with four Mg(5,5)LiMg10V cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra;  a faceface with one Li(1)Mg10V2 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two Mg(4,4)Mg12 cuboctahedra; faces with three equivalent Mg(1)Mg12 cuboctahedra; faces with three equivalent V(1)Li2Mg10 cuboctahedra; and faces with four Mg(5,5)LiMg10V cuboctahedra. V(1) is bonded to two equivalent Li(1), two equivalent Mg(6), four equivalent Mg(3), and four equivalent Mg(5) atoms to form VLi2Mg10 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with six equivalent V(1)Li2Mg10 cuboctahedra; corners with eight Mg(4,4)Mg12 cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; edges with eight Mg(5,5)LiMg10V cuboctahedra; faces with two equivalent Li(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; and faces with six equivalent Mg(7)LiMg11 cuboctahedra. is represented by the CIF file [CIF]
data_LiMg14V
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.331
_cell_length_b   6.371
_cell_length_c   10.104
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.209
_symmetry_Int_Tables_number   1
_cell_volume   352.133
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.168  0.834  0.125  1.0
  Mg  Mg1  1  0.167  0.334  0.625  1.0
  Mg  Mg2  1  0.168  0.834  0.625  1.0
  Mg  Mg3  1  0.666  0.332  0.125  1.0
  Mg  Mg4  1  0.666  0.333  0.625  1.0
  Mg  Mg5  1  0.666  0.834  0.125  1.0
  Mg  Mg6  1  0.666  0.833  0.625  1.0
  Mg  Mg7  1  0.329  0.168  0.370  1.0
  Mg  Mg8  1  0.329  0.168  0.880  1.0
  Mg  Mg9  1  0.329  0.662  0.370  1.0
  Mg  Mg10  1  0.329  0.662  0.880  1.0
  Mg  Mg11  1  0.839  0.169  0.371  1.0
  Mg  Mg12  1  0.839  0.169  0.879  1.0
  Mg  Mg13  1  0.835  0.667  0.374  1.0
  Mg  Mg14  1  0.835  0.667  0.876  1.0
  V  V15  1  0.167  0.333  0.125  1.0
[/CIF]
.
The structure described by LiMg14V crystallizes in the orthorhombic Amm2 space group. Li(1) is bonded to two equivalent Mg(7), four equivalent Mg(3), four equivalent Mg(5), and two equivalent V(1) atoms to form LiMg10V2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with six equivalent Li(1)Mg10V2 cuboctahedra; corners with eight Mg(4,4)Mg12 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra; edges with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with eight Mg(5,5)LiMg10V cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent V(1)Li2Mg10 cuboctahedra; faces with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; and faces with six equivalent Mg(6)Mg11V cuboctahedra. There are nine inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2); two equivalent Mg(6); four Mg(4,4); and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Li(1)Mg10V2 cuboctahedra; corners with six equivalent Mg(1)Mg12 cuboctahedra; corners with eight equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with eight Mg(5,5)LiMg10V cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent V(1)Li2Mg10 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with six equivalent Mg(7)LiMg11 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1); two equivalent Mg(7); four Mg(4,4); and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent V(1)Li2Mg10 cuboctahedra; corners with six equivalent Mg(2)Mg12 cuboctahedra; corners with eight equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra; edges with eight Mg(5,5)LiMg10V cuboctahedra; faces with two equivalent Li(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; faces with four Mg(4,4)Mg12 cuboctahedra; and faces with six equivalent Mg(6)Mg11V cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Li(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent V(1) atoms to form distorted MgLi2Mg8V2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra; edges with four equivalent Mg(5)LiMg10V cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Li(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent V(1)Li2Mg10 cuboctahedra; and faces with eight Mg(5,5)LiMg10V cuboctahedra. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Li(1)Mg10V2 cuboctahedra; corners with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; corners with four equivalent V(1)Li2Mg10 cuboctahedra; corners with six equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(5)LiMg10V cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; and faces with eight Mg(5,5)LiMg10V cuboctahedra. In the fifth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Li(1)Mg10V2 cuboctahedra; corners with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; corners with four equivalent V(1)Li2Mg10 cuboctahedra; corners with six equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(5)LiMg10V cuboctahedra; edges with four equivalent Mg(7)LiMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; and faces with eight Mg(5,5)LiMg10V cuboctahedra. In the sixth Mg site, Mg(5) is bonded to one Li(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one V(1) atom to form distorted MgLiMg10V cuboctahedra that share corners with four equivalent Mg(7)LiMg11 cuboctahedra; corners with four equivalent Mg(6)Mg11V cuboctahedra; corners with ten Mg(5,5)LiMg10V cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Mg(5)LiMg10V cuboctahedra; edges with two equivalent Mg(7)LiMg11 cuboctahedra; edges with two equivalent Mg(6)Mg11V cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra;  a faceface with one Li(1)Mg10V2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Li2Mg10 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with four Mg(5,5)LiMg10V cuboctahedra; and faces with four Mg(4,4)Mg12 cuboctahedra. In the seventh Mg site, Mg(5) is bonded to one Li(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one V(1) atom to form distorted MgLiMg10V cuboctahedra that share corners with four equivalent Mg(7)LiMg11 cuboctahedra; corners with four equivalent Mg(6)Mg11V cuboctahedra; corners with ten equivalent Mg(5)LiMg10V cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with two equivalent Mg(5)LiMg10V cuboctahedra; edges with two equivalent Mg(7)LiMg11 cuboctahedra; edges with two equivalent Mg(6)Mg11V cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra;  a faceface with one Li(1)Mg10V2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one V(1)Li2Mg10 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; and faces with four Mg(4,4)Mg12 cuboctahedra. In the eighth Mg site, Mg(6) is bonded to one Mg(1); two equivalent Mg(3); two Mg(4,4); two equivalent Mg(7); four Mg(5,5); and one V(1) atom to form distorted MgMg11V cuboctahedra that share corners with four equivalent Mg(7)LiMg11 cuboctahedra; corners with six equivalent Mg(6)Mg11V cuboctahedra; corners with eight Mg(5,5)LiMg10V cuboctahedra; edges with two equivalent Mg(7)LiMg11 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent V(1)Li2Mg10 cuboctahedra; edges with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with four Mg(5,5)LiMg10V cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one V(1)Li2Mg10 cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two Mg(4,4)Mg12 cuboctahedra; faces with three equivalent Li(1)Mg10V2 cuboctahedra; faces with three equivalent Mg(2)Mg12 cuboctahedra; and faces with four Mg(5,5)LiMg10V cuboctahedra. In the ninth Mg site, Mg(7) is bonded to one Li(1); one Mg(2); two equivalent Mg(3); two Mg(4,4); two equivalent Mg(6); and four Mg(5,5) atoms to form distorted MgLiMg11 cuboctahedra that share corners with four equivalent Mg(6)Mg11V cuboctahedra; corners with six equivalent Mg(7)LiMg11 cuboctahedra; corners with eight Mg(5,5)LiMg10V cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with two equivalent Mg(6)Mg11V cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with four Mg(5,5)LiMg10V cuboctahedra; edges with four Mg(4,4)Mg12 cuboctahedra;  a faceface with one Li(1)Mg10V2 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with two equivalent Mg(7)LiMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two Mg(4,4)Mg12 cuboctahedra; faces with three equivalent Mg(1)Mg12 cuboctahedra; faces with three equivalent V(1)Li2Mg10 cuboctahedra; and faces with four Mg(5,5)LiMg10V cuboctahedra. V(1) is bonded to two equivalent Li(1), two equivalent Mg(6), four equivalent Mg(3), and four equivalent Mg(5) atoms to form VLi2Mg10 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with six equivalent V(1)Li2Mg10 cuboctahedra; corners with eight Mg(4,4)Mg12 cuboctahedra; edges with two equivalent Li(1)Mg10V2 cuboctahedra; edges with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; edges with four equivalent Mg(6)Mg11V cuboctahedra; edges with eight Mg(5,5)LiMg10V cuboctahedra; faces with two equivalent Li(1)Mg10V2 cuboctahedra; faces with two equivalent Mg(6)Mg11V cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with four equivalent Mg(3)Li2Mg8V2 cuboctahedra; faces with four equivalent Mg(5)LiMg10V cuboctahedra; and faces with six equivalent Mg(7)LiMg11 cuboctahedra. is represented by the CIF file [CIF]
data_LiMg14V
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.331
_cell_length_b   6.371
_cell_length_c   10.104
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.209
_symmetry_Int_Tables_number   1
_cell_volume   352.133
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.168  0.834  0.125  1.0
  Mg  Mg1  1  0.167  0.334  0.625  1.0
  Mg  Mg2  1  0.168  0.834  0.625  1.0
  Mg  Mg3  1  0.666  0.332  0.125  1.0
  Mg  Mg4  1  0.666  0.333  0.625  1.0
  Mg  Mg5  1  0.666  0.834  0.125  1.0
  Mg  Mg6  1  0.666  0.833  0.625  1.0
  Mg  Mg7  1  0.329  0.168  0.370  1.0
  Mg  Mg8  1  0.329  0.168  0.880  1.0
  Mg  Mg9  1  0.329  0.662  0.370  1.0
  Mg  Mg10  1  0.329  0.662  0.880  1.0
  Mg  Mg11  1  0.839  0.169  0.371  1.0
  Mg  Mg12  1  0.839  0.169  0.879  1.0
  Mg  Mg13  1  0.835  0.667  0.374  1.0
  Mg  Mg14  1  0.835  0.667  0.876  1.0
  V  V15  1  0.167  0.333  0.125  1.0
[/CIF]
.