The material structure described by (CH3)2SO4 is gamma plutonium structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight dihydroxy(dimethoxy)-lambda4-sulfane molecules. C(1) is bonded to one H(1), one H(2), one H(3), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form SO4 tetrahedra that share corners with two equivalent C(1)H3O tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H6C2SO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.281
_cell_length_b   7.165
_cell_length_c   9.609
_cell_angle_alpha   81.765
_cell_angle_beta   70.924
_cell_angle_gamma   64.005
_symmetry_Int_Tables_number   1
_cell_volume   367.336
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.104  0.328  0.170  1.0
  H  H1  1  0.602  0.672  0.830  1.0
  H  H2  1  0.181  0.172  0.670  1.0
  H  H3  1  0.024  0.828  0.330  1.0
  H  H4  1  0.324  0.410  0.038  1.0
  H  H5  1  0.772  0.590  0.962  1.0
  H  H6  1  0.484  0.090  0.538  1.0
  H  H7  1  0.112  0.910  0.462  1.0
  H  H8  1  0.219  0.243  0.983  1.0
  H  H9  1  0.444  0.757  0.017  1.0
  H  H10  1  0.212  0.257  0.483  1.0
  H  H11  1  0.952  0.743  0.517  1.0
  C  C12  1  0.263  0.284  0.072  1.0
  C  C13  1  0.620  0.716  0.928  1.0
  C  C14  1  0.298  0.216  0.572  1.0
  C  C15  1  0.085  0.784  0.428  1.0
  S  S16  1  0.722  0.000  0.000  1.0
  S  S17  1  0.472  0.500  0.500  1.0
  O  O18  1  0.796  0.156  0.918  1.0
  O  O19  1  0.870  0.844  0.082  1.0
  O  O20  1  0.702  0.344  0.418  1.0
  O  O21  1  0.464  0.656  0.582  1.0
  O  O22  1  0.456  0.103  0.117  1.0
  O  O23  1  0.675  0.897  0.883  1.0
  O  O24  1  0.308  0.397  0.617  1.0
  O  O25  1  0.323  0.603  0.383  1.0
[/CIF]
.
The material structure described by (CH3)2SO4 is gamma plutonium structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight dihydroxy(dimethoxy)-lambda4-sulfane molecules. C(1) is bonded to one H(1), one H(2), one H(3), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form SO4 tetrahedra that share corners with two equivalent C(1)H3O tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H6C2SO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.281
_cell_length_b   7.165
_cell_length_c   9.609
_cell_angle_alpha   81.765
_cell_angle_beta   70.924
_cell_angle_gamma   64.005
_symmetry_Int_Tables_number   1
_cell_volume   367.336
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.104  0.328  0.170  1.0
  H  H1  1  0.602  0.672  0.830  1.0
  H  H2  1  0.181  0.172  0.670  1.0
  H  H3  1  0.024  0.828  0.330  1.0
  H  H4  1  0.324  0.410  0.038  1.0
  H  H5  1  0.772  0.590  0.962  1.0
  H  H6  1  0.484  0.090  0.538  1.0
  H  H7  1  0.112  0.910  0.462  1.0
  H  H8  1  0.219  0.243  0.983  1.0
  H  H9  1  0.444  0.757  0.017  1.0
  H  H10  1  0.212  0.257  0.483  1.0
  H  H11  1  0.952  0.743  0.517  1.0
  C  C12  1  0.263  0.284  0.072  1.0
  C  C13  1  0.620  0.716  0.928  1.0
  C  C14  1  0.298  0.216  0.572  1.0
  C  C15  1  0.085  0.784  0.428  1.0
  S  S16  1  0.722  0.000  0.000  1.0
  S  S17  1  0.472  0.500  0.500  1.0
  O  O18  1  0.796  0.156  0.918  1.0
  O  O19  1  0.870  0.844  0.082  1.0
  O  O20  1  0.702  0.344  0.418  1.0
  O  O21  1  0.464  0.656  0.582  1.0
  O  O22  1  0.456  0.103  0.117  1.0
  O  O23  1  0.675  0.897  0.883  1.0
  O  O24  1  0.308  0.397  0.617  1.0
  O  O25  1  0.323  0.603  0.383  1.0
[/CIF]
.