The structure described by C6P2Te(NCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C6P2Te(NCl)2 clusters. There are six inequivalent C sites. In the first C site, C(6) is bonded in a 3-coordinate geometry to one C(4), one C(5), and one P(2) atom. In the second C site, C(1) is bonded in an L-shaped geometry to one C(3) and one P(1) atom. In the third C site, C(2) is bonded in an L-shaped geometry to one C(3) and one P(1) atom. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(1) and one C(2) atom. In the fifth C site, C(4) is bonded in a 3-coordinate geometry to one C(6), one P(2), and one Cl(1) atom. In the sixth C site, C(5) is bonded in a 2-coordinate geometry to one C(6) and one P(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one N(1) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one C(4), one C(5), one C(6), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one P(1) and one Te(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(2) and one Te(1) atom. Te(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(4) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_TeP2C6(NCl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.806
_cell_length_b   11.188
_cell_length_c   13.367
_cell_angle_alpha   79.047
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1439.843
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.483  0.470  0.221  1.0
  Te  Te1  1  0.983  0.030  0.779  1.0
  Te  Te2  1  0.517  0.530  0.779  1.0
  Te  Te3  1  0.017  0.970  0.221  1.0
  P  P4  1  0.194  0.425  0.344  1.0
  P  P5  1  0.694  0.075  0.656  1.0
  P  P6  1  0.806  0.575  0.656  1.0
  P  P7  1  0.306  0.925  0.344  1.0
  P  P8  1  0.468  0.221  0.129  1.0
  P  P9  1  0.968  0.279  0.871  1.0
  P  P10  1  0.532  0.779  0.871  1.0
  P  P11  1  0.032  0.721  0.129  1.0
  C  C12  1  0.218  0.253  0.375  1.0
  C  C13  1  0.718  0.247  0.625  1.0
  C  C14  1  0.782  0.747  0.625  1.0
  C  C15  1  0.282  0.753  0.375  1.0
  C  C16  1  0.202  0.362  0.499  1.0
  C  C17  1  0.702  0.138  0.501  1.0
  C  C18  1  0.798  0.638  0.501  1.0
  C  C19  1  0.298  0.862  0.499  1.0
  C  C20  1  0.262  0.268  0.468  1.0
  C  C21  1  0.762  0.232  0.532  1.0
  C  C22  1  0.738  0.732  0.532  1.0
  C  C23  1  0.238  0.768  0.468  1.0
  C  C24  1  0.621  0.275  0.047  1.0
  C  C25  1  0.121  0.225  0.953  1.0
  C  C26  1  0.379  0.725  0.953  1.0
  C  C27  1  0.879  0.775  0.047  1.0
  C  C28  1  0.599  0.084  0.175  1.0
  C  C29  1  0.099  0.416  0.825  1.0
  C  C30  1  0.401  0.916  0.825  1.0
  C  C31  1  0.901  0.584  0.175  1.0
  C  C32  1  0.665  0.173  0.114  1.0
  C  C33  1  0.165  0.327  0.886  1.0
  C  C34  1  0.335  0.827  0.886  1.0
  C  C35  1  0.835  0.673  0.114  1.0
  N  N36  1  0.315  0.504  0.291  1.0
  N  N37  1  0.815  0.996  0.709  1.0
  N  N38  1  0.685  0.496  0.709  1.0
  N  N39  1  0.185  0.004  0.291  1.0
  N  N40  1  0.446  0.303  0.216  1.0
  N  N41  1  0.946  0.197  0.784  1.0
  N  N42  1  0.554  0.697  0.784  1.0
  N  N43  1  0.054  0.803  0.216  1.0
  Cl  Cl44  1  0.306  0.585  0.991  1.0
  Cl  Cl45  1  0.806  0.915  0.009  1.0
  Cl  Cl46  1  0.694  0.415  0.009  1.0
  Cl  Cl47  1  0.194  0.085  0.991  1.0
  Cl  Cl48  1  0.633  0.461  0.365  1.0
  Cl  Cl49  1  0.133  0.039  0.635  1.0
  Cl  Cl50  1  0.367  0.539  0.635  1.0
  Cl  Cl51  1  0.867  0.961  0.365  1.0
[/CIF]
.
The structure described by C6P2Te(NCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C6P2Te(NCl)2 clusters. There are six inequivalent C sites. In the first C site, C(6) is bonded in a 3-coordinate geometry to one C(4), one C(5), and one P(2) atom. In the second C site, C(1) is bonded in an L-shaped geometry to one C(3) and one P(1) atom. In the third C site, C(2) is bonded in an L-shaped geometry to one C(3) and one P(1) atom. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(1) and one C(2) atom. In the fifth C site, C(4) is bonded in a 3-coordinate geometry to one C(6), one P(2), and one Cl(1) atom. In the sixth C site, C(5) is bonded in a 2-coordinate geometry to one C(6) and one P(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one N(1) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one C(4), one C(5), one C(6), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one P(1) and one Te(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(2) and one Te(1) atom. Te(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(4) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_TeP2C6(NCl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.806
_cell_length_b   11.188
_cell_length_c   13.367
_cell_angle_alpha   79.047
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1439.843
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.483  0.470  0.221  1.0
  Te  Te1  1  0.983  0.030  0.779  1.0
  Te  Te2  1  0.517  0.530  0.779  1.0
  Te  Te3  1  0.017  0.970  0.221  1.0
  P  P4  1  0.194  0.425  0.344  1.0
  P  P5  1  0.694  0.075  0.656  1.0
  P  P6  1  0.806  0.575  0.656  1.0
  P  P7  1  0.306  0.925  0.344  1.0
  P  P8  1  0.468  0.221  0.129  1.0
  P  P9  1  0.968  0.279  0.871  1.0
  P  P10  1  0.532  0.779  0.871  1.0
  P  P11  1  0.032  0.721  0.129  1.0
  C  C12  1  0.218  0.253  0.375  1.0
  C  C13  1  0.718  0.247  0.625  1.0
  C  C14  1  0.782  0.747  0.625  1.0
  C  C15  1  0.282  0.753  0.375  1.0
  C  C16  1  0.202  0.362  0.499  1.0
  C  C17  1  0.702  0.138  0.501  1.0
  C  C18  1  0.798  0.638  0.501  1.0
  C  C19  1  0.298  0.862  0.499  1.0
  C  C20  1  0.262  0.268  0.468  1.0
  C  C21  1  0.762  0.232  0.532  1.0
  C  C22  1  0.738  0.732  0.532  1.0
  C  C23  1  0.238  0.768  0.468  1.0
  C  C24  1  0.621  0.275  0.047  1.0
  C  C25  1  0.121  0.225  0.953  1.0
  C  C26  1  0.379  0.725  0.953  1.0
  C  C27  1  0.879  0.775  0.047  1.0
  C  C28  1  0.599  0.084  0.175  1.0
  C  C29  1  0.099  0.416  0.825  1.0
  C  C30  1  0.401  0.916  0.825  1.0
  C  C31  1  0.901  0.584  0.175  1.0
  C  C32  1  0.665  0.173  0.114  1.0
  C  C33  1  0.165  0.327  0.886  1.0
  C  C34  1  0.335  0.827  0.886  1.0
  C  C35  1  0.835  0.673  0.114  1.0
  N  N36  1  0.315  0.504  0.291  1.0
  N  N37  1  0.815  0.996  0.709  1.0
  N  N38  1  0.685  0.496  0.709  1.0
  N  N39  1  0.185  0.004  0.291  1.0
  N  N40  1  0.446  0.303  0.216  1.0
  N  N41  1  0.946  0.197  0.784  1.0
  N  N42  1  0.554  0.697  0.784  1.0
  N  N43  1  0.054  0.803  0.216  1.0
  Cl  Cl44  1  0.306  0.585  0.991  1.0
  Cl  Cl45  1  0.806  0.915  0.009  1.0
  Cl  Cl46  1  0.694  0.415  0.009  1.0
  Cl  Cl47  1  0.194  0.085  0.991  1.0
  Cl  Cl48  1  0.633  0.461  0.365  1.0
  Cl  Cl49  1  0.133  0.039  0.635  1.0
  Cl  Cl50  1  0.367  0.539  0.635  1.0
  Cl  Cl51  1  0.867  0.961  0.365  1.0
[/CIF]
.