The compound described by AgP(NO)2 crystallizes in the trigonal P3_121 space group. Ag(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. P(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent O(1) atoms. N(1) is bonded in a 3-coordinate geometry to one Ag(1), one P(1), and one N(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one P(1) atom. is represented by the CIF card [CIF]
data_AgP(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.807
_cell_length_b   5.807
_cell_length_c   12.104
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   353.537
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.894  0.894  0.000  1.0
  Ag  Ag1  1  0.000  0.106  0.667  1.0
  Ag  Ag2  1  0.106  0.000  0.333  1.0
  P  P3  1  0.422  0.000  0.833  1.0
  P  P4  1  0.578  0.578  0.500  1.0
  P  P5  1  0.000  0.422  0.167  1.0
  N  N6  1  0.752  0.112  0.805  1.0
  N  N7  1  0.360  0.248  0.472  1.0
  N  N8  1  0.888  0.640  0.138  1.0
  N  N9  1  0.248  0.360  0.528  1.0
  N  N10  1  0.112  0.752  0.195  1.0
  N  N11  1  0.640  0.888  0.862  1.0
  O  O12  1  0.748  0.646  0.601  1.0
  O  O13  1  0.897  0.252  0.267  1.0
  O  O14  1  0.354  0.103  0.934  1.0
  O  O15  1  0.252  0.897  0.733  1.0
  O  O16  1  0.646  0.748  0.399  1.0
  O  O17  1  0.103  0.354  0.066  1.0
[/CIF]
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The compound described by AgP(NO)2 crystallizes in the trigonal P3_121 space group. Ag(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. P(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent O(1) atoms. N(1) is bonded in a 3-coordinate geometry to one Ag(1), one P(1), and one N(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one P(1) atom. is represented by the CIF card [CIF]
data_AgP(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.807
_cell_length_b   5.807
_cell_length_c   12.104
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   353.537
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.894  0.894  0.000  1.0
  Ag  Ag1  1  0.000  0.106  0.667  1.0
  Ag  Ag2  1  0.106  0.000  0.333  1.0
  P  P3  1  0.422  0.000  0.833  1.0
  P  P4  1  0.578  0.578  0.500  1.0
  P  P5  1  0.000  0.422  0.167  1.0
  N  N6  1  0.752  0.112  0.805  1.0
  N  N7  1  0.360  0.248  0.472  1.0
  N  N8  1  0.888  0.640  0.138  1.0
  N  N9  1  0.248  0.360  0.528  1.0
  N  N10  1  0.112  0.752  0.195  1.0
  N  N11  1  0.640  0.888  0.862  1.0
  O  O12  1  0.748  0.646  0.601  1.0
  O  O13  1  0.897  0.252  0.267  1.0
  O  O14  1  0.354  0.103  0.934  1.0
  O  O15  1  0.252  0.897  0.733  1.0
  O  O16  1  0.646  0.748  0.399  1.0
  O  O17  1  0.103  0.354  0.066  1.0
[/CIF]
.