The structure described by KGeNO crystallizes in the orthorhombic Pca2_1 space group. K(1) is bonded in a 6-coordinate geometry to one N(1) and five equivalent O(1) atoms. Ge(1) is bonded to three equivalent N(1) and one O(1) atom to form corner-sharing GeN3O tetrahedra. N(1) is bonded to one K(1) and three equivalent Ge(1) atoms to form distorted corner-sharing NKGe3 trigonal pyramids. O(1) is bonded in a 6-coordinate geometry to five equivalent K(1) and one Ge(1) atom. is represented by the CIF file [CIF]
data_KGeNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.291
_cell_length_b   5.810
_cell_length_c   8.192
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   251.864
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.023  0.044  0.639  1.0
  K  K1  1  0.523  0.456  0.639  1.0
  K  K2  1  0.523  0.956  0.361  1.0
  K  K3  1  0.023  0.544  0.361  1.0
  Ge  Ge4  1  0.994  0.090  0.095  1.0
  Ge  Ge5  1  0.494  0.910  0.905  1.0
  Ge  Ge6  1  0.494  0.410  0.095  1.0
  Ge  Ge7  1  0.994  0.590  0.905  1.0
  N  N8  1  0.648  0.627  0.958  1.0
  N  N9  1  0.148  0.373  0.042  1.0
  N  N10  1  0.148  0.873  0.958  1.0
  N  N11  1  0.648  0.127  0.042  1.0
  O  O12  1  0.527  0.973  0.697  1.0
  O  O13  1  0.527  0.473  0.303  1.0
  O  O14  1  0.027  0.527  0.697  1.0
  O  O15  1  0.027  0.027  0.303  1.0
[/CIF]
.
The structure described by KGeNO crystallizes in the orthorhombic Pca2_1 space group. K(1) is bonded in a 6-coordinate geometry to one N(1) and five equivalent O(1) atoms. Ge(1) is bonded to three equivalent N(1) and one O(1) atom to form corner-sharing GeN3O tetrahedra. N(1) is bonded to one K(1) and three equivalent Ge(1) atoms to form distorted corner-sharing NKGe3 trigonal pyramids. O(1) is bonded in a 6-coordinate geometry to five equivalent K(1) and one Ge(1) atom. is represented by the CIF file [CIF]
data_KGeNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.291
_cell_length_b   5.810
_cell_length_c   8.192
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   251.864
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.023  0.044  0.639  1.0
  K  K1  1  0.523  0.456  0.639  1.0
  K  K2  1  0.523  0.956  0.361  1.0
  K  K3  1  0.023  0.544  0.361  1.0
  Ge  Ge4  1  0.994  0.090  0.095  1.0
  Ge  Ge5  1  0.494  0.910  0.905  1.0
  Ge  Ge6  1  0.494  0.410  0.095  1.0
  Ge  Ge7  1  0.994  0.590  0.905  1.0
  N  N8  1  0.648  0.627  0.958  1.0
  N  N9  1  0.148  0.373  0.042  1.0
  N  N10  1  0.148  0.873  0.958  1.0
  N  N11  1  0.648  0.127  0.042  1.0
  O  O12  1  0.527  0.973  0.697  1.0
  O  O13  1  0.527  0.473  0.303  1.0
  O  O14  1  0.027  0.527  0.697  1.0
  O  O15  1  0.027  0.027  0.303  1.0
[/CIF]
.