The material described by Rb(O3I)3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one I(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one I(1), and one I(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), one I(1), and one I(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one I(2), and one I(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Rb(1) and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1) and one I(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Rb(1), one I(1), and one I(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one I(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one I(3) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(3), and one O(7) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(7), one O(8), and one O(9) atom. is represented by the CIF card [CIF]
data_Rb(IO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.247
_cell_length_b   8.328
_cell_length_c   8.384
_cell_angle_alpha   71.498
_cell_angle_beta   66.916
_cell_angle_gamma   61.222
_symmetry_Int_Tables_number   1
_cell_volume   458.373
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.753  0.726  0.219  1.0
  Rb  Rb1  1  0.247  0.274  0.781  1.0
  I  I2  1  0.215  0.707  0.296  1.0
  I  I3  1  0.785  0.293  0.704  1.0
  I  I4  1  0.774  0.233  0.233  1.0
  I  I5  1  0.226  0.767  0.767  1.0
  I  I6  1  0.746  0.809  0.694  1.0
  I  I7  1  0.254  0.191  0.306  1.0
  O  O8  1  0.252  0.614  0.513  1.0
  O  O9  1  0.748  0.386  0.487  1.0
  O  O10  1  0.844  0.472  0.725  1.0
  O  O11  1  0.156  0.528  0.275  1.0
  O  O12  1  0.042  0.123  0.634  1.0
  O  O13  1  0.958  0.877  0.366  1.0
  O  O14  1  0.009  0.253  0.153  1.0
  O  O15  1  0.991  0.747  0.847  1.0
  O  O16  1  0.188  0.867  0.953  1.0
  O  O17  1  0.812  0.133  0.047  1.0
  O  O18  1  0.616  0.475  0.170  1.0
  O  O19  1  0.384  0.525  0.830  1.0
  O  O20  1  0.673  0.061  0.676  1.0
  O  O21  1  0.327  0.939  0.324  1.0
  O  O22  1  0.598  0.788  0.924  1.0
  O  O23  1  0.402  0.212  0.076  1.0
  O  O24  1  0.574  0.840  0.582  1.0
  O  O25  1  0.426  0.160  0.418  1.0
[/CIF]
.
The material described by Rb(O3I)3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one I(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one I(1), and one I(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), one I(1), and one I(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one I(2), and one I(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Rb(1) and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1) and one I(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Rb(1), one I(1), and one I(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one I(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one I(3) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(3), and one O(7) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(7), one O(8), and one O(9) atom. is represented by the CIF card [CIF]
data_Rb(IO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.247
_cell_length_b   8.328
_cell_length_c   8.384
_cell_angle_alpha   71.498
_cell_angle_beta   66.916
_cell_angle_gamma   61.222
_symmetry_Int_Tables_number   1
_cell_volume   458.373
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.753  0.726  0.219  1.0
  Rb  Rb1  1  0.247  0.274  0.781  1.0
  I  I2  1  0.215  0.707  0.296  1.0
  I  I3  1  0.785  0.293  0.704  1.0
  I  I4  1  0.774  0.233  0.233  1.0
  I  I5  1  0.226  0.767  0.767  1.0
  I  I6  1  0.746  0.809  0.694  1.0
  I  I7  1  0.254  0.191  0.306  1.0
  O  O8  1  0.252  0.614  0.513  1.0
  O  O9  1  0.748  0.386  0.487  1.0
  O  O10  1  0.844  0.472  0.725  1.0
  O  O11  1  0.156  0.528  0.275  1.0
  O  O12  1  0.042  0.123  0.634  1.0
  O  O13  1  0.958  0.877  0.366  1.0
  O  O14  1  0.009  0.253  0.153  1.0
  O  O15  1  0.991  0.747  0.847  1.0
  O  O16  1  0.188  0.867  0.953  1.0
  O  O17  1  0.812  0.133  0.047  1.0
  O  O18  1  0.616  0.475  0.170  1.0
  O  O19  1  0.384  0.525  0.830  1.0
  O  O20  1  0.673  0.061  0.676  1.0
  O  O21  1  0.327  0.939  0.324  1.0
  O  O22  1  0.598  0.788  0.924  1.0
  O  O23  1  0.402  0.212  0.076  1.0
  O  O24  1  0.574  0.840  0.582  1.0
  O  O25  1  0.426  0.160  0.418  1.0
[/CIF]
.