The compound described by Mn2OF3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(5), one F(5), one F(7), one F(8), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(6)OF5 octahedra, corners with two equivalent Mn(8)OF5 octahedra, corners with four equivalent Mn(10)O2F4 octahedra,  an edgeedge with one Mn(4)OF5 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-59°. In the second Mn site, Mn(2) is bonded to one O(2), one O(4), one F(11), one F(13), one F(4), and one F(6) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(6)OF5 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(7)O2F4 octahedra,  an edgeedge with one Mn(3)O2F4 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. In the third Mn site, Mn(3) is bonded to one O(2), one O(3), one F(10), one F(11), one F(12), and one F(3) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(7)O2F4 octahedra, corners with two equivalent Mn(8)OF5 octahedra, corners with four equivalent Mn(9)OF5 octahedra,  an edgeedge with one Mn(2)O2F4 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 38-58°. In the fourth Mn site, Mn(4) is bonded to one O(4), one F(14), one F(2), one F(5), one F(6), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(7)O2F4 octahedra, corners with four equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(1)O2F4 octahedra, and  an edgeedge with one Mn(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. In the fifth Mn site, Mn(5) is bonded to one O(3), one F(1), one F(10), one F(15), one F(7), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(8)OF5 octahedra,  an edgeedge with one Mn(1)O2F4 octahedra, and  an edgeedge with one Mn(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the sixth Mn site, Mn(6) is bonded to one O(1), one F(13), one F(14), one F(2), one F(6), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with two equivalent Mn(2)O2F4 octahedra, corners with four equivalent Mn(4)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(7)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. In the seventh Mn site, Mn(7) is bonded to one O(2), one O(4), one F(12), one F(13), one F(2), and one F(4) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(3)O2F4 octahedra, corners with two equivalent Mn(4)OF5 octahedra, corners with four equivalent Mn(2)O2F4 octahedra,  an edgeedge with one Mn(6)OF5 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In the eighth Mn site, Mn(8) is bonded to one O(5), one F(1), one F(10), one F(15), one F(3), and one F(7) atom to form MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with two equivalent Mn(3)O2F4 octahedra, corners with four equivalent Mn(5)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. In the ninth Mn site, Mn(9) is bonded to one O(3), one F(11), one F(12), one F(15), one F(3), and one F(4) atom to form MnOF5 octahedra that share corners with two equivalent Mn(2)O2F4 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(3)O2F4 octahedra,  an edgeedge with one Mn(7)O2F4 octahedra, and  an edgeedge with one Mn(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the tenth Mn site, Mn(10) is bonded to one O(1), one O(5), one F(1), one F(14), one F(5), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(4)OF5 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(1)O2F4 octahedra,  an edgeedge with one Mn(6)OF5 octahedra, and  an edgeedge with one Mn(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-57°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(10), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(9) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(7) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(10), and one Mn(8) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(5), and one Mn(8) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(7) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(8), and one Mn(9) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(7), and one Mn(9) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(10), and one Mn(4) atom. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(1), one Mn(10), and one Mn(5) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the twelfth F site, F(12) is bonded in a trigonal planar geometry to one Mn(3), one Mn(7), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(4), and one Mn(6) atom. In the fifteenth F site, F(15) is bonded in a trigonal planar geometry to one Mn(5), one Mn(8), and one Mn(9) atom. is represented by the CIF card [CIF]
data_Mn2OF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.794
_cell_length_b   5.739
_cell_length_c   13.826
_cell_angle_alpha   79.074
_cell_angle_beta   89.107
_cell_angle_gamma   89.348
_symmetry_Int_Tables_number   1
_cell_volume   373.479
_cell_formula_units_Z   5
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.503  0.499  0.999  1.0
  Mn  Mn1  1  0.486  0.696  0.402  1.0
  Mn  Mn2  1  0.542  0.289  0.591  1.0
  Mn  Mn3  1  0.466  0.099  0.214  1.0
  Mn  Mn4  1  0.520  0.908  0.791  1.0
  Mn  Mn5  1  0.966  0.601  0.186  1.0
  Mn  Mn6  1  0.998  0.200  0.400  1.0
  Mn  Mn7  1  0.038  0.398  0.812  1.0
  Mn  Mn8  1  0.985  0.805  0.603  1.0
  Mn  Mn9  1  1.000  0.001  0.000  1.0
  O  O10  1  0.799  0.701  0.049  1.0
  O  O11  1  0.698  0.392  0.456  1.0
  O  O12  1  0.709  0.978  0.657  1.0
  O  O13  1  0.286  0.005  0.351  1.0
  O  O14  1  0.205  0.299  0.949  1.0
  F  F15  1  0.812  0.079  0.864  1.0
  F  F16  1  0.811  0.272  0.262  1.0
  F  F17  1  0.815  0.486  0.669  1.0
  F  F18  1  0.797  0.882  0.464  1.0
  F  F19  1  0.701  0.183  0.070  1.0
  F  F20  1  0.686  0.775  0.265  1.0
  F  F21  1  0.688  0.573  0.860  1.0
  F  F22  1  0.315  0.431  0.138  1.0
  F  F23  1  0.301  0.818  0.930  1.0
  F  F24  1  0.321  0.233  0.728  1.0
  F  F25  1  0.293  0.616  0.545  1.0
  F  F26  1  0.181  0.116  0.540  1.0
  F  F27  1  0.191  0.515  0.331  1.0
  F  F28  1  0.191  0.923  0.135  1.0
  F  F29  1  0.195  0.729  0.739  1.0
[/CIF]
.
The compound described by Mn2OF3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(5), one F(5), one F(7), one F(8), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(6)OF5 octahedra, corners with two equivalent Mn(8)OF5 octahedra, corners with four equivalent Mn(10)O2F4 octahedra,  an edgeedge with one Mn(4)OF5 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-59°. In the second Mn site, Mn(2) is bonded to one O(2), one O(4), one F(11), one F(13), one F(4), and one F(6) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(6)OF5 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(7)O2F4 octahedra,  an edgeedge with one Mn(3)O2F4 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. In the third Mn site, Mn(3) is bonded to one O(2), one O(3), one F(10), one F(11), one F(12), and one F(3) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(7)O2F4 octahedra, corners with two equivalent Mn(8)OF5 octahedra, corners with four equivalent Mn(9)OF5 octahedra,  an edgeedge with one Mn(2)O2F4 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 38-58°. In the fourth Mn site, Mn(4) is bonded to one O(4), one F(14), one F(2), one F(5), one F(6), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(7)O2F4 octahedra, corners with four equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(1)O2F4 octahedra, and  an edgeedge with one Mn(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. In the fifth Mn site, Mn(5) is bonded to one O(3), one F(1), one F(10), one F(15), one F(7), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(8)OF5 octahedra,  an edgeedge with one Mn(1)O2F4 octahedra, and  an edgeedge with one Mn(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the sixth Mn site, Mn(6) is bonded to one O(1), one F(13), one F(14), one F(2), one F(6), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with two equivalent Mn(2)O2F4 octahedra, corners with four equivalent Mn(4)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(7)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. In the seventh Mn site, Mn(7) is bonded to one O(2), one O(4), one F(12), one F(13), one F(2), and one F(4) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(3)O2F4 octahedra, corners with two equivalent Mn(4)OF5 octahedra, corners with four equivalent Mn(2)O2F4 octahedra,  an edgeedge with one Mn(6)OF5 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In the eighth Mn site, Mn(8) is bonded to one O(5), one F(1), one F(10), one F(15), one F(3), and one F(7) atom to form MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with two equivalent Mn(3)O2F4 octahedra, corners with four equivalent Mn(5)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. In the ninth Mn site, Mn(9) is bonded to one O(3), one F(11), one F(12), one F(15), one F(3), and one F(4) atom to form MnOF5 octahedra that share corners with two equivalent Mn(2)O2F4 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(3)O2F4 octahedra,  an edgeedge with one Mn(7)O2F4 octahedra, and  an edgeedge with one Mn(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the tenth Mn site, Mn(10) is bonded to one O(1), one O(5), one F(1), one F(14), one F(5), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(4)OF5 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(1)O2F4 octahedra,  an edgeedge with one Mn(6)OF5 octahedra, and  an edgeedge with one Mn(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-57°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(10), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(9) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(7) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(10), and one Mn(8) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(5), and one Mn(8) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(7) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(8), and one Mn(9) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(7), and one Mn(9) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(10), and one Mn(4) atom. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(1), one Mn(10), and one Mn(5) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the twelfth F site, F(12) is bonded in a trigonal planar geometry to one Mn(3), one Mn(7), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(4), and one Mn(6) atom. In the fifteenth F site, F(15) is bonded in a trigonal planar geometry to one Mn(5), one Mn(8), and one Mn(9) atom. is represented by the CIF card [CIF]
data_Mn2OF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.794
_cell_length_b   5.739
_cell_length_c   13.826
_cell_angle_alpha   79.074
_cell_angle_beta   89.107
_cell_angle_gamma   89.348
_symmetry_Int_Tables_number   1
_cell_volume   373.479
_cell_formula_units_Z   5
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.503  0.499  0.999  1.0
  Mn  Mn1  1  0.486  0.696  0.402  1.0
  Mn  Mn2  1  0.542  0.289  0.591  1.0
  Mn  Mn3  1  0.466  0.099  0.214  1.0
  Mn  Mn4  1  0.520  0.908  0.791  1.0
  Mn  Mn5  1  0.966  0.601  0.186  1.0
  Mn  Mn6  1  0.998  0.200  0.400  1.0
  Mn  Mn7  1  0.038  0.398  0.812  1.0
  Mn  Mn8  1  0.985  0.805  0.603  1.0
  Mn  Mn9  1  1.000  0.001  0.000  1.0
  O  O10  1  0.799  0.701  0.049  1.0
  O  O11  1  0.698  0.392  0.456  1.0
  O  O12  1  0.709  0.978  0.657  1.0
  O  O13  1  0.286  0.005  0.351  1.0
  O  O14  1  0.205  0.299  0.949  1.0
  F  F15  1  0.812  0.079  0.864  1.0
  F  F16  1  0.811  0.272  0.262  1.0
  F  F17  1  0.815  0.486  0.669  1.0
  F  F18  1  0.797  0.882  0.464  1.0
  F  F19  1  0.701  0.183  0.070  1.0
  F  F20  1  0.686  0.775  0.265  1.0
  F  F21  1  0.688  0.573  0.860  1.0
  F  F22  1  0.315  0.431  0.138  1.0
  F  F23  1  0.301  0.818  0.930  1.0
  F  F24  1  0.321  0.233  0.728  1.0
  F  F25  1  0.293  0.616  0.545  1.0
  F  F26  1  0.181  0.116  0.540  1.0
  F  F27  1  0.191  0.515  0.331  1.0
  F  F28  1  0.191  0.923  0.135  1.0
  F  F29  1  0.195  0.729  0.739  1.0
[/CIF]
.