The compound described by Mn(CoN)2 crystallizes in the orthorhombic Pmmn space group. Mn(1) is bonded in a linear geometry to two equivalent N(1) atoms. Co(1) is bonded to five equivalent N(1) atoms to form a mixture of edge and corner-sharing CoN5 square pyramids. N(1) is bonded to one Mn(1) and five equivalent Co(1) atoms to form a mixture of edge and corner-sharing NMnCo5 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(CoN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.812
_cell_length_b   2.842
_cell_length_c   11.525
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   92.100
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.750  0.833  0.750  1.0
  Mn  Mn1  1  0.250  0.167  0.250  1.0
  Co  Co2  1  0.750  0.712  0.088  1.0
  Co  Co3  1  0.750  0.712  0.412  1.0
  Co  Co4  1  0.250  0.288  0.912  1.0
  Co  Co5  1  0.250  0.288  0.588  1.0
  N  N6  1  0.750  0.754  0.590  1.0
  N  N7  1  0.750  0.754  0.910  1.0
  N  N8  1  0.250  0.246  0.410  1.0
  N  N9  1  0.250  0.246  0.090  1.0
[/CIF]
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The compound described by Mn(CoN)2 crystallizes in the orthorhombic Pmmn space group. Mn(1) is bonded in a linear geometry to two equivalent N(1) atoms. Co(1) is bonded to five equivalent N(1) atoms to form a mixture of edge and corner-sharing CoN5 square pyramids. N(1) is bonded to one Mn(1) and five equivalent Co(1) atoms to form a mixture of edge and corner-sharing NMnCo5 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(CoN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.812
_cell_length_b   2.842
_cell_length_c   11.525
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   92.100
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.750  0.833  0.750  1.0
  Mn  Mn1  1  0.250  0.167  0.250  1.0
  Co  Co2  1  0.750  0.712  0.088  1.0
  Co  Co3  1  0.750  0.712  0.412  1.0
  Co  Co4  1  0.250  0.288  0.912  1.0
  Co  Co5  1  0.250  0.288  0.588  1.0
  N  N6  1  0.750  0.754  0.590  1.0
  N  N7  1  0.750  0.754  0.910  1.0
  N  N8  1  0.250  0.246  0.410  1.0
  N  N9  1  0.250  0.246  0.090  1.0
[/CIF]
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