The compound described by PNH2F2 is Ammonia-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four phosphoramidous difluoride molecules. P(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one F(1), and one F(2) atom. N(1) is bonded in a distorted trigonal planar geometry to one P(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_PH2NF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.103
_cell_length_b   4.964
_cell_length_c   5.303
_cell_angle_alpha   64.576
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   311.537
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.588  0.362  0.284  1.0
  P  P1  1  0.912  0.862  0.284  1.0
  P  P2  1  0.088  0.138  0.716  1.0
  P  P3  1  0.412  0.638  0.716  1.0
  H  H4  1  0.127  0.347  0.249  1.0
  H  H5  1  0.228  0.376  0.435  1.0
  H  H6  1  0.373  0.847  0.249  1.0
  H  H7  1  0.728  0.124  0.565  1.0
  H  H8  1  0.272  0.876  0.435  1.0
  H  H9  1  0.627  0.153  0.751  1.0
  H  H10  1  0.772  0.624  0.565  1.0
  H  H11  1  0.873  0.653  0.751  1.0
  N  N12  1  0.163  0.260  0.438  1.0
  N  N13  1  0.663  0.240  0.562  1.0
  N  N14  1  0.337  0.760  0.438  1.0
  N  N15  1  0.837  0.740  0.562  1.0
  F  F16  1  0.826  0.037  0.052  1.0
  F  F17  1  0.583  0.076  0.202  1.0
  F  F18  1  0.674  0.537  0.052  1.0
  F  F19  1  0.917  0.576  0.202  1.0
  F  F20  1  0.083  0.424  0.798  1.0
  F  F21  1  0.326  0.463  0.948  1.0
  F  F22  1  0.417  0.924  0.798  1.0
  F  F23  1  0.174  0.963  0.948  1.0
[/CIF]
.
The compound described by PNH2F2 is Ammonia-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four phosphoramidous difluoride molecules. P(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one F(1), and one F(2) atom. N(1) is bonded in a distorted trigonal planar geometry to one P(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_PH2NF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.103
_cell_length_b   4.964
_cell_length_c   5.303
_cell_angle_alpha   64.576
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   311.537
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.588  0.362  0.284  1.0
  P  P1  1  0.912  0.862  0.284  1.0
  P  P2  1  0.088  0.138  0.716  1.0
  P  P3  1  0.412  0.638  0.716  1.0
  H  H4  1  0.127  0.347  0.249  1.0
  H  H5  1  0.228  0.376  0.435  1.0
  H  H6  1  0.373  0.847  0.249  1.0
  H  H7  1  0.728  0.124  0.565  1.0
  H  H8  1  0.272  0.876  0.435  1.0
  H  H9  1  0.627  0.153  0.751  1.0
  H  H10  1  0.772  0.624  0.565  1.0
  H  H11  1  0.873  0.653  0.751  1.0
  N  N12  1  0.163  0.260  0.438  1.0
  N  N13  1  0.663  0.240  0.562  1.0
  N  N14  1  0.337  0.760  0.438  1.0
  N  N15  1  0.837  0.740  0.562  1.0
  F  F16  1  0.826  0.037  0.052  1.0
  F  F17  1  0.583  0.076  0.202  1.0
  F  F18  1  0.674  0.537  0.052  1.0
  F  F19  1  0.917  0.576  0.202  1.0
  F  F20  1  0.083  0.424  0.798  1.0
  F  F21  1  0.326  0.463  0.948  1.0
  F  F22  1  0.417  0.924  0.798  1.0
  F  F23  1  0.174  0.963  0.948  1.0
[/CIF]
.