The compound described by RbSb3S5O crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 2-coordinate geometry to one S(1), one S(2), one S(3), and two equivalent O(1) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in an L-shaped geometry to one S(1) and one S(3) atom. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one S(3), one S(4), one S(5), and two equivalent S(2) atoms. In the third Sb site, Sb(3) is bonded in a 4-coordinate geometry to one S(3), one S(4), and two equivalent S(1) atoms. There are five inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Rb(1), one Sb(1), and two equivalent Sb(3) atoms. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1) and two equivalent Sb(2) atoms. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Rb(1), one Sb(1), one Sb(2), and one Sb(3) atom. In the fourth S site, S(4) is bonded in a distorted water-like geometry to one Sb(2) and one Sb(3) atom. In the fifth S site, S(5) is bonded in a distorted single-bond geometry to one Sb(2) and one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Rb(1) and one S(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSb3S5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.897
_cell_length_b   8.934
_cell_length_c   10.728
_cell_angle_alpha   106.209
_cell_angle_beta   99.736
_cell_angle_gamma   93.659
_symmetry_Int_Tables_number   1
_cell_volume   621.217
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.180  0.155  0.176  1.0
  Rb  Rb1  1  0.820  0.845  0.824  1.0
  Sb  Sb2  1  0.330  0.685  0.440  1.0
  Sb  Sb3  1  0.670  0.315  0.560  1.0
  Sb  Sb4  1  0.696  0.541  0.141  1.0
  Sb  Sb5  1  0.304  0.459  0.859  1.0
  Sb  Sb6  1  0.718  0.963  0.386  1.0
  Sb  Sb7  1  0.282  0.037  0.614  1.0
  S  S8  1  0.351  0.906  0.339  1.0
  S  S9  1  0.649  0.094  0.661  1.0
  S  S10  1  0.332  0.506  0.111  1.0
  S  S11  1  0.668  0.494  0.889  1.0
  S  S12  1  0.673  0.651  0.443  1.0
  S  S13  1  0.327  0.349  0.557  1.0
  S  S14  1  0.742  0.840  0.154  1.0
  S  S15  1  0.258  0.160  0.846  1.0
  S  S16  1  0.621  0.213  0.066  1.0
  S  S17  1  0.379  0.787  0.934  1.0
  O  O18  1  0.198  0.863  0.976  1.0
  O  O19  1  0.802  0.137  0.024  1.0
[/CIF]
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The compound described by RbSb3S5O crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 2-coordinate geometry to one S(1), one S(2), one S(3), and two equivalent O(1) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in an L-shaped geometry to one S(1) and one S(3) atom. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one S(3), one S(4), one S(5), and two equivalent S(2) atoms. In the third Sb site, Sb(3) is bonded in a 4-coordinate geometry to one S(3), one S(4), and two equivalent S(1) atoms. There are five inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Rb(1), one Sb(1), and two equivalent Sb(3) atoms. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1) and two equivalent Sb(2) atoms. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Rb(1), one Sb(1), one Sb(2), and one Sb(3) atom. In the fourth S site, S(4) is bonded in a distorted water-like geometry to one Sb(2) and one Sb(3) atom. In the fifth S site, S(5) is bonded in a distorted single-bond geometry to one Sb(2) and one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Rb(1) and one S(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSb3S5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.897
_cell_length_b   8.934
_cell_length_c   10.728
_cell_angle_alpha   106.209
_cell_angle_beta   99.736
_cell_angle_gamma   93.659
_symmetry_Int_Tables_number   1
_cell_volume   621.217
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.180  0.155  0.176  1.0
  Rb  Rb1  1  0.820  0.845  0.824  1.0
  Sb  Sb2  1  0.330  0.685  0.440  1.0
  Sb  Sb3  1  0.670  0.315  0.560  1.0
  Sb  Sb4  1  0.696  0.541  0.141  1.0
  Sb  Sb5  1  0.304  0.459  0.859  1.0
  Sb  Sb6  1  0.718  0.963  0.386  1.0
  Sb  Sb7  1  0.282  0.037  0.614  1.0
  S  S8  1  0.351  0.906  0.339  1.0
  S  S9  1  0.649  0.094  0.661  1.0
  S  S10  1  0.332  0.506  0.111  1.0
  S  S11  1  0.668  0.494  0.889  1.0
  S  S12  1  0.673  0.651  0.443  1.0
  S  S13  1  0.327  0.349  0.557  1.0
  S  S14  1  0.742  0.840  0.154  1.0
  S  S15  1  0.258  0.160  0.846  1.0
  S  S16  1  0.621  0.213  0.066  1.0
  S  S17  1  0.379  0.787  0.934  1.0
  O  O18  1  0.198  0.863  0.976  1.0
  O  O19  1  0.802  0.137  0.024  1.0
[/CIF]
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