The compound described by MnAs3(PbO3)3 crystallizes in the monoclinic Pc space group. Mn(1) is bonded in an octahedral geometry to one O(1), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to one O(2), one O(4), and one O(8) atom. In the third Pb site, Pb(3) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(9) atom. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second As site, As(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. In the third As site, As(3) is bonded in a distorted trigonal non-coplanar geometry to one O(7), one O(8), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Pb(3), and one As(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Pb(1), one Pb(2), one Pb(3), and one As(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Mn(1), one Pb(1), one Pb(3), and one As(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mn(1), one Pb(1), one Pb(2), and one As(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Pb(1), one Pb(3), and one As(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Pb(1), and one As(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(1), one Pb(3), and one As(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mn(1), one Pb(2), and one As(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(3), and one As(3) atom. is represented by the CIF card [CIF]
data_MnAs3(PbO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.699
_cell_length_b   7.411
_cell_length_c   10.988
_cell_angle_alpha   84.690
_cell_angle_beta   90.011
_cell_angle_gamma   90.006
_symmetry_Int_Tables_number   1
_cell_volume   543.140
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.208  0.711  0.780  1.0
  As  As1  1  0.792  0.211  0.280  1.0
  As  As2  1  0.116  0.758  0.304  1.0
  As  As3  1  0.884  0.258  0.804  1.0
  As  As4  1  0.522  0.885  0.490  1.0
  As  As5  1  0.478  0.385  0.990  1.0
  Mn  Mn6  1  0.986  0.994  0.545  1.0
  Mn  Mn7  1  0.014  0.494  0.045  1.0
  O  O8  1  0.011  0.786  0.671  1.0
  O  O9  1  0.989  0.286  0.171  1.0
  O  O10  1  0.318  0.924  0.821  1.0
  O  O11  1  0.682  0.424  0.321  1.0
  O  O12  1  0.036  0.688  0.910  1.0
  O  O13  1  0.964  0.188  0.410  1.0
  O  O14  1  0.969  0.715  0.170  1.0
  O  O15  1  0.031  0.215  0.670  1.0
  O  O16  1  0.162  0.535  0.373  1.0
  O  O17  1  0.838  0.035  0.873  1.0
  O  O18  1  0.914  0.800  0.406  1.0
  O  O19  1  0.087  0.301  0.906  1.0
  O  O20  1  0.693  0.006  0.587  1.0
  O  O21  1  0.307  0.506  0.087  1.0
  O  O22  1  0.709  0.512  0.038  1.0
  O  O23  1  0.290  0.012  0.538  1.0
  O  O24  1  0.529  0.677  0.577  1.0
  O  O25  1  0.471  0.177  0.077  1.0
  Pb  Pb26  1  0.856  0.499  0.508  1.0
  Pb  Pb27  1  0.144  0.999  0.008  1.0
  Pb  Pb28  1  0.631  0.694  0.194  1.0
  Pb  Pb29  1  0.369  0.194  0.694  1.0
  Pb  Pb30  1  0.711  0.781  0.793  1.0
  Pb  Pb31  1  0.289  0.281  0.293  1.0
[/CIF]
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The compound described by MnAs3(PbO3)3 crystallizes in the monoclinic Pc space group. Mn(1) is bonded in an octahedral geometry to one O(1), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to one O(2), one O(4), and one O(8) atom. In the third Pb site, Pb(3) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(9) atom. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second As site, As(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. In the third As site, As(3) is bonded in a distorted trigonal non-coplanar geometry to one O(7), one O(8), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Pb(3), and one As(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Pb(1), one Pb(2), one Pb(3), and one As(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Mn(1), one Pb(1), one Pb(3), and one As(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mn(1), one Pb(1), one Pb(2), and one As(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Pb(1), one Pb(3), and one As(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Pb(1), and one As(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(1), one Pb(3), and one As(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mn(1), one Pb(2), and one As(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(3), and one As(3) atom. is represented by the CIF card [CIF]
data_MnAs3(PbO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.699
_cell_length_b   7.411
_cell_length_c   10.988
_cell_angle_alpha   84.690
_cell_angle_beta   90.011
_cell_angle_gamma   90.006
_symmetry_Int_Tables_number   1
_cell_volume   543.140
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.208  0.711  0.780  1.0
  As  As1  1  0.792  0.211  0.280  1.0
  As  As2  1  0.116  0.758  0.304  1.0
  As  As3  1  0.884  0.258  0.804  1.0
  As  As4  1  0.522  0.885  0.490  1.0
  As  As5  1  0.478  0.385  0.990  1.0
  Mn  Mn6  1  0.986  0.994  0.545  1.0
  Mn  Mn7  1  0.014  0.494  0.045  1.0
  O  O8  1  0.011  0.786  0.671  1.0
  O  O9  1  0.989  0.286  0.171  1.0
  O  O10  1  0.318  0.924  0.821  1.0
  O  O11  1  0.682  0.424  0.321  1.0
  O  O12  1  0.036  0.688  0.910  1.0
  O  O13  1  0.964  0.188  0.410  1.0
  O  O14  1  0.969  0.715  0.170  1.0
  O  O15  1  0.031  0.215  0.670  1.0
  O  O16  1  0.162  0.535  0.373  1.0
  O  O17  1  0.838  0.035  0.873  1.0
  O  O18  1  0.914  0.800  0.406  1.0
  O  O19  1  0.087  0.301  0.906  1.0
  O  O20  1  0.693  0.006  0.587  1.0
  O  O21  1  0.307  0.506  0.087  1.0
  O  O22  1  0.709  0.512  0.038  1.0
  O  O23  1  0.290  0.012  0.538  1.0
  O  O24  1  0.529  0.677  0.577  1.0
  O  O25  1  0.471  0.177  0.077  1.0
  Pb  Pb26  1  0.856  0.499  0.508  1.0
  Pb  Pb27  1  0.144  0.999  0.008  1.0
  Pb  Pb28  1  0.631  0.694  0.194  1.0
  Pb  Pb29  1  0.369  0.194  0.694  1.0
  Pb  Pb30  1  0.711  0.781  0.793  1.0
  Pb  Pb31  1  0.289  0.281  0.293  1.0
[/CIF]
.