The compound described by Ba2Co3Zn2Tl2O10 crystallizes in the triclinic P1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 9-coordinate geometry to one O(9), two equivalent O(6), two equivalent O(8), and four equivalent O(7) atoms. In the second Ba site, Ba(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. In the second Co site, Co(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(6) and two equivalent O(8) atoms. In the third Co site, Co(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(10) and two equivalent O(5) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(5), and two equivalent O(3) atoms. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one O(10), one O(5), one O(6), and one O(8) atom. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a see-saw-like geometry to one O(4), one O(7), and two equivalent O(9) atoms. In the second Tl site, Tl(2) is bonded in a see-saw-like geometry to one O(2), one O(9), and two equivalent O(4) atoms. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ba(2), two equivalent Co(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to four equivalent Ba(2) and one Tl(2) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Ba(2), two equivalent Co(1), and two equivalent Zn(1) atoms. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one Ba(2), one Tl(1), and two equivalent Tl(2) atoms. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Co(3), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded to two equivalent Ba(1), two equivalent Co(2), and one Zn(2) atom to form distorted corner-sharing OBa2ZnCo2 square pyramids. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to four equivalent Ba(1) and one Tl(1) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to two equivalent Ba(1), two equivalent Co(2), and one Zn(2) atom. In the ninth O site, O(9) is bonded in a distorted see-saw-like geometry to one Ba(1), one Tl(2), and two equivalent Tl(1) atoms. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to two equivalent Co(3), one Zn(1), and one Zn(2) atom. is represented by the CIF card [CIF]
data_Ba2Tl2Zn2Co3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.874
_cell_length_b   3.954
_cell_length_c   18.107
_cell_angle_alpha   94.699
_cell_angle_beta   95.938
_cell_angle_gamma   90.455
_symmetry_Int_Tables_number   1
_cell_volume   274.887
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.121  0.162  0.276  1.0
  Ba  Ba1  1  0.839  0.826  0.720  1.0
  Tl  Tl2  1  0.634  0.721  0.435  1.0
  Tl  Tl3  1  0.195  0.269  0.564  1.0
  Zn  Zn4  1  0.858  0.899  0.910  1.0
  Zn  Zn5  1  0.972  0.043  0.083  1.0
  Co  Co6  1  0.390  0.373  0.843  1.0
  Co  Co7  1  0.571  0.608  0.155  1.0
  Co  Co8  1  0.311  0.530  1.000  1.0
  O  O9  1  0.425  0.871  0.836  1.0
  O  O10  1  0.317  0.312  0.681  1.0
  O  O11  1  0.900  0.379  0.845  1.0
  O  O12  1  0.833  0.763  0.553  1.0
  O  O13  1  0.799  0.581  0.014  1.0
  O  O14  1  0.086  0.628  0.170  1.0
  O  O15  1  0.641  0.677  0.319  1.0
  O  O16  1  0.586  0.110  0.149  1.0
  O  O17  1  0.286  0.223  0.447  1.0
  O  O18  1  0.235  0.042  0.991  1.0
[/CIF]
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The compound described by Ba2Co3Zn2Tl2O10 crystallizes in the triclinic P1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 9-coordinate geometry to one O(9), two equivalent O(6), two equivalent O(8), and four equivalent O(7) atoms. In the second Ba site, Ba(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. In the second Co site, Co(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(6) and two equivalent O(8) atoms. In the third Co site, Co(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(10) and two equivalent O(5) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(5), and two equivalent O(3) atoms. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one O(10), one O(5), one O(6), and one O(8) atom. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a see-saw-like geometry to one O(4), one O(7), and two equivalent O(9) atoms. In the second Tl site, Tl(2) is bonded in a see-saw-like geometry to one O(2), one O(9), and two equivalent O(4) atoms. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ba(2), two equivalent Co(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to four equivalent Ba(2) and one Tl(2) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Ba(2), two equivalent Co(1), and two equivalent Zn(1) atoms. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one Ba(2), one Tl(1), and two equivalent Tl(2) atoms. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Co(3), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded to two equivalent Ba(1), two equivalent Co(2), and one Zn(2) atom to form distorted corner-sharing OBa2ZnCo2 square pyramids. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to four equivalent Ba(1) and one Tl(1) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to two equivalent Ba(1), two equivalent Co(2), and one Zn(2) atom. In the ninth O site, O(9) is bonded in a distorted see-saw-like geometry to one Ba(1), one Tl(2), and two equivalent Tl(1) atoms. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to two equivalent Co(3), one Zn(1), and one Zn(2) atom. is represented by the CIF card [CIF]
data_Ba2Tl2Zn2Co3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.874
_cell_length_b   3.954
_cell_length_c   18.107
_cell_angle_alpha   94.699
_cell_angle_beta   95.938
_cell_angle_gamma   90.455
_symmetry_Int_Tables_number   1
_cell_volume   274.887
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.121  0.162  0.276  1.0
  Ba  Ba1  1  0.839  0.826  0.720  1.0
  Tl  Tl2  1  0.634  0.721  0.435  1.0
  Tl  Tl3  1  0.195  0.269  0.564  1.0
  Zn  Zn4  1  0.858  0.899  0.910  1.0
  Zn  Zn5  1  0.972  0.043  0.083  1.0
  Co  Co6  1  0.390  0.373  0.843  1.0
  Co  Co7  1  0.571  0.608  0.155  1.0
  Co  Co8  1  0.311  0.530  1.000  1.0
  O  O9  1  0.425  0.871  0.836  1.0
  O  O10  1  0.317  0.312  0.681  1.0
  O  O11  1  0.900  0.379  0.845  1.0
  O  O12  1  0.833  0.763  0.553  1.0
  O  O13  1  0.799  0.581  0.014  1.0
  O  O14  1  0.086  0.628  0.170  1.0
  O  O15  1  0.641  0.677  0.319  1.0
  O  O16  1  0.586  0.110  0.149  1.0
  O  O17  1  0.286  0.223  0.447  1.0
  O  O18  1  0.235  0.042  0.991  1.0
[/CIF]
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