The material described by Na2TcF6 crystallizes in the trigonal P-3m1 space group. Na(1) is bonded in a 12-coordinate geometry to twelve equivalent F(1) atoms. Tc(1) is bonded in an octahedral geometry to six equivalent F(1) atoms. F(1) is bonded in a 5-coordinate geometry to four equivalent Na(1) and one Tc(1) atom. is represented by the CIF card [CIF]
data_Na2TcF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.544
_cell_length_b   5.544
_cell_length_c   4.214
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   112.162
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.333  0.667  0.675  1.0
  Na  Na1  1  0.667  0.333  0.325  1.0
  Tc  Tc2  1  0.000  0.000  0.000  1.0
  F  F3  1  0.343  0.171  0.757  1.0
  F  F4  1  0.829  0.657  0.757  1.0
  F  F5  1  0.829  0.171  0.757  1.0
  F  F6  1  0.657  0.829  0.243  1.0
  F  F7  1  0.171  0.343  0.243  1.0
  F  F8  1  0.171  0.829  0.243  1.0
[/CIF]
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The material described by Na2TcF6 crystallizes in the trigonal P-3m1 space group. Na(1) is bonded in a 12-coordinate geometry to twelve equivalent F(1) atoms. Tc(1) is bonded in an octahedral geometry to six equivalent F(1) atoms. F(1) is bonded in a 5-coordinate geometry to four equivalent Na(1) and one Tc(1) atom. is represented by the CIF card [CIF]
data_Na2TcF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.544
_cell_length_b   5.544
_cell_length_c   4.214
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   112.162
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.333  0.667  0.675  1.0
  Na  Na1  1  0.667  0.333  0.325  1.0
  Tc  Tc2  1  0.000  0.000  0.000  1.0
  F  F3  1  0.343  0.171  0.757  1.0
  F  F4  1  0.829  0.657  0.757  1.0
  F  F5  1  0.829  0.171  0.757  1.0
  F  F6  1  0.657  0.829  0.243  1.0
  F  F7  1  0.171  0.343  0.243  1.0
  F  F8  1  0.171  0.829  0.243  1.0
[/CIF]
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