The structure described by LiH2PO3 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)HO3 tetrahedra. P(1) is bonded to one H(2), one O(1), one O(2), and one O(3) atom to form distorted PHO3 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1), one P(1), and one H(1) atom. is represented by the CIF file [CIF]
data_LiPH2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.135
_cell_length_b   5.260
_cell_length_c   11.176
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   301.873
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.981  0.262  0.421  1.0
  Li  Li1  1  0.481  0.762  0.079  1.0
  Li  Li2  1  0.519  0.262  0.921  1.0
  Li  Li3  1  0.019  0.762  0.579  1.0
  P  P4  1  0.685  0.745  0.345  1.0
  P  P5  1  0.315  0.245  0.655  1.0
  P  P6  1  0.815  0.745  0.845  1.0
  P  P7  1  0.185  0.245  0.155  1.0
  H  H8  1  0.993  0.619  0.161  1.0
  H  H9  1  0.007  0.119  0.839  1.0
  H  H10  1  0.507  0.619  0.661  1.0
  H  H11  1  0.493  0.119  0.339  1.0
  H  H12  1  0.565  0.150  0.630  1.0
  H  H13  1  0.065  0.650  0.870  1.0
  H  H14  1  0.935  0.150  0.130  1.0
  H  H15  1  0.435  0.650  0.370  1.0
  O  O16  1  0.884  0.627  0.428  1.0
  O  O17  1  0.616  0.627  0.928  1.0
  O  O18  1  0.116  0.127  0.572  1.0
  O  O19  1  0.384  0.127  0.072  1.0
  O  O20  1  0.162  0.542  0.124  1.0
  O  O21  1  0.734  0.706  0.211  1.0
  O  O22  1  0.338  0.542  0.624  1.0
  O  O23  1  0.838  0.042  0.876  1.0
  O  O24  1  0.766  0.706  0.711  1.0
  O  O25  1  0.234  0.206  0.289  1.0
  O  O26  1  0.662  0.042  0.376  1.0
  O  O27  1  0.266  0.206  0.789  1.0
[/CIF]
.
The structure described by LiH2PO3 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)HO3 tetrahedra. P(1) is bonded to one H(2), one O(1), one O(2), and one O(3) atom to form distorted PHO3 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1), one P(1), and one H(1) atom. is represented by the CIF file [CIF]
data_LiPH2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.135
_cell_length_b   5.260
_cell_length_c   11.176
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   301.873
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.981  0.262  0.421  1.0
  Li  Li1  1  0.481  0.762  0.079  1.0
  Li  Li2  1  0.519  0.262  0.921  1.0
  Li  Li3  1  0.019  0.762  0.579  1.0
  P  P4  1  0.685  0.745  0.345  1.0
  P  P5  1  0.315  0.245  0.655  1.0
  P  P6  1  0.815  0.745  0.845  1.0
  P  P7  1  0.185  0.245  0.155  1.0
  H  H8  1  0.993  0.619  0.161  1.0
  H  H9  1  0.007  0.119  0.839  1.0
  H  H10  1  0.507  0.619  0.661  1.0
  H  H11  1  0.493  0.119  0.339  1.0
  H  H12  1  0.565  0.150  0.630  1.0
  H  H13  1  0.065  0.650  0.870  1.0
  H  H14  1  0.935  0.150  0.130  1.0
  H  H15  1  0.435  0.650  0.370  1.0
  O  O16  1  0.884  0.627  0.428  1.0
  O  O17  1  0.616  0.627  0.928  1.0
  O  O18  1  0.116  0.127  0.572  1.0
  O  O19  1  0.384  0.127  0.072  1.0
  O  O20  1  0.162  0.542  0.124  1.0
  O  O21  1  0.734  0.706  0.211  1.0
  O  O22  1  0.338  0.542  0.624  1.0
  O  O23  1  0.838  0.042  0.876  1.0
  O  O24  1  0.766  0.706  0.711  1.0
  O  O25  1  0.234  0.206  0.289  1.0
  O  O26  1  0.662  0.042  0.376  1.0
  O  O27  1  0.266  0.206  0.789  1.0
[/CIF]
.