The crystal structure described by BN4S4F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four BN4S4F3 clusters. B(1) is bonded in a tetrahedral geometry to one N(4), one F(1), one F(2), and one F(3) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one B(1), one S(1), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one N(3) and one N(4) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. is represented by the CIF card [CIF]
data_BS4N4F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.917
_cell_length_b   7.496
_cell_length_c   12.867
_cell_angle_alpha   59.235
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   904.754
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.403  0.791  0.699  1.0
  B  B1  1  0.903  0.209  0.801  1.0
  B  B2  1  0.597  0.209  0.301  1.0
  B  B3  1  0.097  0.791  0.199  1.0
  S  S4  1  0.927  0.644  0.091  1.0
  S  S5  1  0.427  0.356  0.409  1.0
  S  S6  1  0.073  0.356  0.909  1.0
  S  S7  1  0.573  0.644  0.591  1.0
  S  S8  1  0.952  0.229  0.314  1.0
  S  S9  1  0.452  0.771  0.186  1.0
  S  S10  1  0.048  0.771  0.686  1.0
  S  S11  1  0.548  0.229  0.814  1.0
  S  S12  1  0.844  0.414  0.450  1.0
  S  S13  1  0.344  0.586  0.050  1.0
  S  S14  1  0.156  0.586  0.550  1.0
  S  S15  1  0.656  0.414  0.950  1.0
  S  S16  1  0.834  0.818  0.218  1.0
  S  S17  1  0.334  0.182  0.282  1.0
  S  S18  1  0.166  0.182  0.782  1.0
  S  S19  1  0.666  0.818  0.718  1.0
  N  N20  1  0.438  0.709  0.086  1.0
  N  N21  1  0.438  0.603  0.323  1.0
  N  N22  1  0.062  0.603  0.823  1.0
  N  N23  1  0.562  0.397  0.677  1.0
  N  N24  1  0.938  0.291  0.414  1.0
  N  N25  1  0.562  0.291  0.914  1.0
  N  N26  1  0.062  0.709  0.586  1.0
  N  N27  1  0.938  0.397  0.177  1.0
  N  N28  1  0.802  0.638  0.353  1.0
  N  N29  1  0.302  0.362  0.147  1.0
  N  N30  1  0.198  0.362  0.647  1.0
  N  N31  1  0.460  0.239  0.332  1.0
  N  N32  1  0.540  0.761  0.668  1.0
  N  N33  1  0.040  0.239  0.832  1.0
  N  N34  1  0.960  0.761  0.168  1.0
  N  N35  1  0.698  0.638  0.853  1.0
  F  F36  1  0.152  0.596  0.271  1.0
  F  F37  1  0.590  0.099  0.240  1.0
  F  F38  1  0.910  0.099  0.740  1.0
  F  F39  1  0.410  0.901  0.760  1.0
  F  F40  1  0.090  0.901  0.260  1.0
  F  F41  1  0.839  0.096  0.912  1.0
  F  F42  1  0.661  0.096  0.412  1.0
  F  F43  1  0.161  0.904  0.088  1.0
  F  F44  1  0.348  0.596  0.771  1.0
  F  F45  1  0.848  0.404  0.729  1.0
  F  F46  1  0.652  0.404  0.229  1.0
  F  F47  1  0.339  0.904  0.588  1.0
[/CIF]
.
The crystal structure described by BN4S4F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four BN4S4F3 clusters. B(1) is bonded in a tetrahedral geometry to one N(4), one F(1), one F(2), and one F(3) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one B(1), one S(1), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one N(3) and one N(4) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. is represented by the CIF card [CIF]
data_BS4N4F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.917
_cell_length_b   7.496
_cell_length_c   12.867
_cell_angle_alpha   59.235
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   904.754
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.403  0.791  0.699  1.0
  B  B1  1  0.903  0.209  0.801  1.0
  B  B2  1  0.597  0.209  0.301  1.0
  B  B3  1  0.097  0.791  0.199  1.0
  S  S4  1  0.927  0.644  0.091  1.0
  S  S5  1  0.427  0.356  0.409  1.0
  S  S6  1  0.073  0.356  0.909  1.0
  S  S7  1  0.573  0.644  0.591  1.0
  S  S8  1  0.952  0.229  0.314  1.0
  S  S9  1  0.452  0.771  0.186  1.0
  S  S10  1  0.048  0.771  0.686  1.0
  S  S11  1  0.548  0.229  0.814  1.0
  S  S12  1  0.844  0.414  0.450  1.0
  S  S13  1  0.344  0.586  0.050  1.0
  S  S14  1  0.156  0.586  0.550  1.0
  S  S15  1  0.656  0.414  0.950  1.0
  S  S16  1  0.834  0.818  0.218  1.0
  S  S17  1  0.334  0.182  0.282  1.0
  S  S18  1  0.166  0.182  0.782  1.0
  S  S19  1  0.666  0.818  0.718  1.0
  N  N20  1  0.438  0.709  0.086  1.0
  N  N21  1  0.438  0.603  0.323  1.0
  N  N22  1  0.062  0.603  0.823  1.0
  N  N23  1  0.562  0.397  0.677  1.0
  N  N24  1  0.938  0.291  0.414  1.0
  N  N25  1  0.562  0.291  0.914  1.0
  N  N26  1  0.062  0.709  0.586  1.0
  N  N27  1  0.938  0.397  0.177  1.0
  N  N28  1  0.802  0.638  0.353  1.0
  N  N29  1  0.302  0.362  0.147  1.0
  N  N30  1  0.198  0.362  0.647  1.0
  N  N31  1  0.460  0.239  0.332  1.0
  N  N32  1  0.540  0.761  0.668  1.0
  N  N33  1  0.040  0.239  0.832  1.0
  N  N34  1  0.960  0.761  0.168  1.0
  N  N35  1  0.698  0.638  0.853  1.0
  F  F36  1  0.152  0.596  0.271  1.0
  F  F37  1  0.590  0.099  0.240  1.0
  F  F38  1  0.910  0.099  0.740  1.0
  F  F39  1  0.410  0.901  0.760  1.0
  F  F40  1  0.090  0.901  0.260  1.0
  F  F41  1  0.839  0.096  0.912  1.0
  F  F42  1  0.661  0.096  0.412  1.0
  F  F43  1  0.161  0.904  0.088  1.0
  F  F44  1  0.348  0.596  0.771  1.0
  F  F45  1  0.848  0.404  0.729  1.0
  F  F46  1  0.652  0.404  0.229  1.0
  F  F47  1  0.339  0.904  0.588  1.0
[/CIF]
.