The material structure described by ZnGa3N3O is Stannite-like structured and crystallizes in the triclinic P1 space group. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one O(1), one O(3), and one O(4) atom to form ZnNO3 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra, corners with two equivalent Zn(3)N2O2 tetrahedra, corners with two equivalent Ga(3)N2O2 tetrahedra, and corners with two equivalent Ga(2)N3O tetrahedra. In the second Zn site, Zn(2) is bonded to one N(3), one N(4), one N(5), and one O(4) atom to form ZnN3O tetrahedra that share  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra, corners with two equivalent Zn(4)N3O tetrahedra, corners with two equivalent Ga(12)N4 tetrahedra, and corners with two equivalent Ga(6)N4 tetrahedra. In the third Zn site, Zn(3) is bonded to one N(2), one N(9), one O(1), and one O(2) atom to form ZnN2O2 tetrahedra that share  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Zn(1)NO3 tetrahedra, corners with two equivalent Ga(3)N2O2 tetrahedra, and corners with two equivalent Ga(2)N3O tetrahedra. In the fourth Zn site, Zn(4) is bonded to one N(3), one N(5), one N(8), and one O(1) atom to form ZnN3O tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Zn(2)N3O tetrahedra, corners with two equivalent Ga(12)N4 tetrahedra, and corners with two equivalent Ga(6)N4 tetrahedra. There are twelve inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one N(1), one N(6), one O(2), and one O(3) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Ga(11)N2O2 tetrahedra, corners with two equivalent Ga(4)N3O tetrahedra, and corners with two equivalent Ga(5)N3O tetrahedra. In the second Ga site, Ga(2) is bonded to one N(10), one N(2), one N(9), and one O(4) atom to form GaN3O tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Zn(3)N2O2 tetrahedra, corners with two equivalent Zn(1)NO3 tetrahedra, and corners with two equivalent Ga(3)N2O2 tetrahedra. In the third Ga site, Ga(3) is bonded to one N(1), one N(9), one O(1), and one O(4) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Zn(3)N2O2 tetrahedra, corners with two equivalent Zn(1)NO3 tetrahedra, and corners with two equivalent Ga(2)N3O tetrahedra. In the fourth Ga site, Ga(4) is bonded to one N(1), one N(10), one N(12), and one O(2) atom to form GaN3O tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Ga(1)N2O2 tetrahedra, corners with two equivalent Ga(11)N2O2 tetrahedra, and corners with two equivalent Ga(5)N3O tetrahedra. In the fifth Ga site, Ga(5) is bonded to one N(1), one N(10), one N(11), and one O(3) atom to form GaN3O tetrahedra that share  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra, corners with two equivalent Ga(1)N2O2 tetrahedra, corners with two equivalent Ga(11)N2O2 tetrahedra, and corners with two equivalent Ga(4)N3O tetrahedra. In the sixth Ga site, Ga(6) is bonded to one N(3), one N(4), one N(8), and one N(9) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Zn(2)N3O tetrahedra, corners with two equivalent Zn(4)N3O tetrahedra, and corners with two equivalent Ga(12)N4 tetrahedra. In the seventh Ga site, Ga(7) is bonded to one N(11), one N(5), one N(6), and one N(7) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra, corners with two equivalent Ga(10)N4 tetrahedra, corners with two equivalent Ga(8)N4 tetrahedra, and corners with two equivalent Ga(9)N4 tetrahedra. In the eighth Ga site, Ga(8) is bonded to one N(11), one N(12), one N(4), and one N(7) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Ga(10)N4 tetrahedra, corners with two equivalent Ga(7)N4 tetrahedra, and corners with two equivalent Ga(9)N4 tetrahedra. In the ninth Ga site, Ga(9) is bonded to one N(12), one N(6), one N(7), and one N(8) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Ga(10)N4 tetrahedra, corners with two equivalent Ga(7)N4 tetrahedra, and corners with two equivalent Ga(8)N4 tetrahedra. In the tenth Ga site, Ga(10) is bonded to one N(11), one N(12), one N(3), and one N(6) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Ga(7)N4 tetrahedra, corners with two equivalent Ga(8)N4 tetrahedra, and corners with two equivalent Ga(9)N4 tetrahedra. In the eleventh Ga site, Ga(11) is bonded to one N(10), one N(7), one O(2), and one O(3) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Ga(1)N2O2 tetrahedra, corners with two equivalent Ga(4)N3O tetrahedra, and corners with two equivalent Ga(5)N3O tetrahedra. In the twelfth Ga site, Ga(12) is bonded to one N(2), one N(4), one N(5), and one N(8) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Zn(2)N3O tetrahedra, corners with two equivalent Zn(4)N3O tetrahedra, and corners with two equivalent Ga(6)N4 tetrahedra. There are twelve inequivalent N sites. In the first N site, N(1) is bonded to one Ga(1), one Ga(3), one Ga(4), and one Ga(5) atom to form NGa4 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(10)Ga4 tetrahedra, corners with two equivalent O(2)ZnGa3 tetrahedra, and corners with two equivalent O(3)ZnGa3 tetrahedra. In the second N site, N(2) is bonded to one Zn(1), one Zn(3), one Ga(12), and one Ga(2) atom to form NZn2Ga2 tetrahedra that share  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(9)ZnGa3 tetrahedra, corners with two equivalent O(4)Zn2Ga2 tetrahedra, and corners with two equivalent O(1)Zn3Ga tetrahedra. In the third N site, N(3) is bonded to one Zn(2), one Zn(4), one Ga(10), and one Ga(6) atom to form NZn2Ga2 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(5)Zn2Ga2 tetrahedra, corners with two equivalent N(4)ZnGa3 tetrahedra, and corners with two equivalent N(8)ZnGa3 tetrahedra. In the fourth N site, N(4) is bonded to one Zn(2), one Ga(12), one Ga(6), and one Ga(8) atom to form NZnGa3 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra, corners with two equivalent N(3)Zn2Ga2 tetrahedra, corners with two equivalent N(5)Zn2Ga2 tetrahedra, and corners with two equivalent N(8)ZnGa3 tetrahedra. In the fifth N site, N(5) is bonded to one Zn(2), one Zn(4), one Ga(12), and one Ga(7) atom to form NZn2Ga2 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(3)Zn2Ga2 tetrahedra, corners with two equivalent N(4)ZnGa3 tetrahedra, and corners with two equivalent N(8)ZnGa3 tetrahedra. In the sixth N site, N(6) is bonded to one Ga(1), one Ga(10), one Ga(7), and one Ga(9) atom to form NGa4 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(11)Ga4 tetrahedra, corners with two equivalent N(12)Ga4 tetrahedra, and corners with two equivalent N(7)Ga4 tetrahedra. In the seventh N site, N(7) is bonded to one Ga(11), one Ga(7), one Ga(8), and one Ga(9) atom to form NGa4 tetrahedra that share  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(11)Ga4 tetrahedra, corners with two equivalent N(12)Ga4 tetrahedra, and corners with two equivalent N(6)Ga4 tetrahedra. In the eighth N site, N(8) is bonded to one Zn(4), one Ga(12), one Ga(6), and one Ga(9) atom to form NZnGa3 tetrahedra that share  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(3)Zn2Ga2 tetrahedra, corners with two equivalent N(5)Zn2Ga2 tetrahedra, and corners with two equivalent N(4)ZnGa3 tetrahedra. In the ninth N site, N(9) is bonded to one Zn(3), one Ga(2), one Ga(3), and one Ga(6) atom to form NZnGa3 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra, corners with two equivalent N(2)Zn2Ga2 tetrahedra, corners with two equivalent O(4)Zn2Ga2 tetrahedra, and corners with two equivalent O(1)Zn3Ga tetrahedra. In the tenth N site, N(10) is bonded to one Ga(11), one Ga(2), one Ga(4), and one Ga(5) atom to form NGa4 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra, corners with two equivalent N(1)Ga4 tetrahedra, corners with two equivalent O(2)ZnGa3 tetrahedra, and corners with two equivalent O(3)ZnGa3 tetrahedra. In the eleventh N site, N(11) is bonded to one Ga(10), one Ga(5), one Ga(7), and one Ga(8) atom to form NGa4 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(12)Ga4 tetrahedra, corners with two equivalent N(6)Ga4 tetrahedra, and corners with two equivalent N(7)Ga4 tetrahedra. In the twelfth N site, N(12) is bonded to one Ga(10), one Ga(4), one Ga(8), and one Ga(9) atom to form NGa4 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra, corners with two equivalent N(11)Ga4 tetrahedra, corners with two equivalent N(6)Ga4 tetrahedra, and corners with two equivalent N(7)Ga4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Zn(1), one Zn(3), one Zn(4), and one Ga(3) atom to form OZn3Ga tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(2)Zn2Ga2 tetrahedra, corners with two equivalent N(9)ZnGa3 tetrahedra, and corners with two equivalent O(4)Zn2Ga2 tetrahedra. In the second O site, O(2) is bonded to one Zn(3), one Ga(1), one Ga(11), and one Ga(4) atom to form OZnGa3 tetrahedra that share  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(1)Ga4 tetrahedra, corners with two equivalent N(10)Ga4 tetrahedra, and corners with two equivalent O(3)ZnGa3 tetrahedra. In the third O site, O(3) is bonded to one Zn(1), one Ga(1), one Ga(11), and one Ga(5) atom to form OZnGa3 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(1)Ga4 tetrahedra, corners with two equivalent N(10)Ga4 tetrahedra, and corners with two equivalent O(2)ZnGa3 tetrahedra. In the fourth O site, O(4) is bonded to one Zn(1), one Zn(2), one Ga(2), and one Ga(3) atom to form OZn2Ga2 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(2)Zn2Ga2 tetrahedra, corners with two equivalent N(9)ZnGa3 tetrahedra, and corners with two equivalent O(1)Zn3Ga tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnGa3N3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.493
_cell_length_b   6.493
_cell_length_c   10.542
_cell_angle_alpha   90.013
_cell_angle_beta   90.012
_cell_angle_gamma   119.955
_symmetry_Int_Tables_number   1
_cell_volume   385.065
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.173  0.844  0.735  1.0
  Zn  Zn1  1  0.833  0.667  0.487  1.0
  Zn  Zn2  1  0.162  0.323  0.734  1.0
  Zn  Zn3  1  0.334  0.666  0.489  1.0
  Ga  Ga4  1  0.344  0.671  0.007  1.0
  Ga  Ga5  1  0.659  0.322  0.745  1.0
  Ga  Ga6  1  0.669  0.842  0.747  1.0
  Ga  Ga7  1  0.824  0.162  0.005  1.0
  Ga  Ga8  1  0.823  0.661  0.005  1.0
  Ga  Ga9  1  0.831  0.164  0.495  1.0
  Ga  Ga10  1  0.166  0.834  0.256  1.0
  Ga  Ga11  1  0.667  0.333  0.255  1.0
  Ga  Ga12  1  0.165  0.332  0.255  1.0
  Ga  Ga13  1  0.668  0.835  0.257  1.0
  Ga  Ga14  1  0.344  0.172  0.006  1.0
  Ga  Ga15  1  0.334  0.166  0.497  1.0
  N  N16  1  0.668  0.834  0.937  1.0
  N  N17  1  0.345  0.175  0.685  1.0
  N  N18  1  0.671  0.842  0.437  1.0
  N  N19  1  0.663  0.325  0.437  1.0
  N  N20  1  0.172  0.843  0.437  1.0
  N  N21  1  0.333  0.666  0.188  1.0
  N  N22  1  0.333  0.167  0.186  1.0
  N  N23  1  0.162  0.324  0.437  1.0
  N  N24  1  0.824  0.163  0.686  1.0
  N  N25  1  0.668  0.334  0.936  1.0
  N  N26  1  0.833  0.666  0.187  1.0
  N  N27  1  0.834  0.167  0.187  1.0
  O  O28  1  0.345  0.671  0.701  1.0
  O  O29  1  0.167  0.334  0.949  1.0
  O  O30  1  0.167  0.833  0.947  1.0
  O  O31  1  0.821  0.660  0.702  1.0
[/CIF]
.
The material structure described by ZnGa3N3O is Stannite-like structured and crystallizes in the triclinic P1 space group. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one O(1), one O(3), and one O(4) atom to form ZnNO3 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra, corners with two equivalent Zn(3)N2O2 tetrahedra, corners with two equivalent Ga(3)N2O2 tetrahedra, and corners with two equivalent Ga(2)N3O tetrahedra. In the second Zn site, Zn(2) is bonded to one N(3), one N(4), one N(5), and one O(4) atom to form ZnN3O tetrahedra that share  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra, corners with two equivalent Zn(4)N3O tetrahedra, corners with two equivalent Ga(12)N4 tetrahedra, and corners with two equivalent Ga(6)N4 tetrahedra. In the third Zn site, Zn(3) is bonded to one N(2), one N(9), one O(1), and one O(2) atom to form ZnN2O2 tetrahedra that share  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Zn(1)NO3 tetrahedra, corners with two equivalent Ga(3)N2O2 tetrahedra, and corners with two equivalent Ga(2)N3O tetrahedra. In the fourth Zn site, Zn(4) is bonded to one N(3), one N(5), one N(8), and one O(1) atom to form ZnN3O tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Zn(2)N3O tetrahedra, corners with two equivalent Ga(12)N4 tetrahedra, and corners with two equivalent Ga(6)N4 tetrahedra. There are twelve inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one N(1), one N(6), one O(2), and one O(3) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Ga(11)N2O2 tetrahedra, corners with two equivalent Ga(4)N3O tetrahedra, and corners with two equivalent Ga(5)N3O tetrahedra. In the second Ga site, Ga(2) is bonded to one N(10), one N(2), one N(9), and one O(4) atom to form GaN3O tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Zn(3)N2O2 tetrahedra, corners with two equivalent Zn(1)NO3 tetrahedra, and corners with two equivalent Ga(3)N2O2 tetrahedra. In the third Ga site, Ga(3) is bonded to one N(1), one N(9), one O(1), and one O(4) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Zn(3)N2O2 tetrahedra, corners with two equivalent Zn(1)NO3 tetrahedra, and corners with two equivalent Ga(2)N3O tetrahedra. In the fourth Ga site, Ga(4) is bonded to one N(1), one N(10), one N(12), and one O(2) atom to form GaN3O tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Ga(1)N2O2 tetrahedra, corners with two equivalent Ga(11)N2O2 tetrahedra, and corners with two equivalent Ga(5)N3O tetrahedra. In the fifth Ga site, Ga(5) is bonded to one N(1), one N(10), one N(11), and one O(3) atom to form GaN3O tetrahedra that share  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra, corners with two equivalent Ga(1)N2O2 tetrahedra, corners with two equivalent Ga(11)N2O2 tetrahedra, and corners with two equivalent Ga(4)N3O tetrahedra. In the sixth Ga site, Ga(6) is bonded to one N(3), one N(4), one N(8), and one N(9) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Ga(3)N2O2 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(10)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Zn(2)N3O tetrahedra, corners with two equivalent Zn(4)N3O tetrahedra, and corners with two equivalent Ga(12)N4 tetrahedra. In the seventh Ga site, Ga(7) is bonded to one N(11), one N(5), one N(6), and one N(7) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra, corners with two equivalent Ga(10)N4 tetrahedra, corners with two equivalent Ga(8)N4 tetrahedra, and corners with two equivalent Ga(9)N4 tetrahedra. In the eighth Ga site, Ga(8) is bonded to one N(11), one N(12), one N(4), and one N(7) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Ga(10)N4 tetrahedra, corners with two equivalent Ga(7)N4 tetrahedra, and corners with two equivalent Ga(9)N4 tetrahedra. In the ninth Ga site, Ga(9) is bonded to one N(12), one N(6), one N(7), and one N(8) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(11)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(12)N4 tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Ga(10)N4 tetrahedra, corners with two equivalent Ga(7)N4 tetrahedra, and corners with two equivalent Ga(8)N4 tetrahedra. In the tenth Ga site, Ga(10) is bonded to one N(11), one N(12), one N(3), and one N(6) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(2)N3O tetrahedra,  a cornercorner with one Zn(4)N3O tetrahedra,  a cornercorner with one Ga(1)N2O2 tetrahedra,  a cornercorner with one Ga(4)N3O tetrahedra,  a cornercorner with one Ga(5)N3O tetrahedra,  a cornercorner with one Ga(6)N4 tetrahedra, corners with two equivalent Ga(7)N4 tetrahedra, corners with two equivalent Ga(8)N4 tetrahedra, and corners with two equivalent Ga(9)N4 tetrahedra. In the eleventh Ga site, Ga(11) is bonded to one N(10), one N(7), one O(2), and one O(3) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Ga(1)N2O2 tetrahedra, corners with two equivalent Ga(4)N3O tetrahedra, and corners with two equivalent Ga(5)N3O tetrahedra. In the twelfth Ga site, Ga(12) is bonded to one N(2), one N(4), one N(5), and one N(8) atom to form GaN4 tetrahedra that share  a cornercorner with one Zn(3)N2O2 tetrahedra,  a cornercorner with one Zn(1)NO3 tetrahedra,  a cornercorner with one Ga(2)N3O tetrahedra,  a cornercorner with one Ga(7)N4 tetrahedra,  a cornercorner with one Ga(8)N4 tetrahedra,  a cornercorner with one Ga(9)N4 tetrahedra, corners with two equivalent Zn(2)N3O tetrahedra, corners with two equivalent Zn(4)N3O tetrahedra, and corners with two equivalent Ga(6)N4 tetrahedra. There are twelve inequivalent N sites. In the first N site, N(1) is bonded to one Ga(1), one Ga(3), one Ga(4), and one Ga(5) atom to form NGa4 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(10)Ga4 tetrahedra, corners with two equivalent O(2)ZnGa3 tetrahedra, and corners with two equivalent O(3)ZnGa3 tetrahedra. In the second N site, N(2) is bonded to one Zn(1), one Zn(3), one Ga(12), and one Ga(2) atom to form NZn2Ga2 tetrahedra that share  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(9)ZnGa3 tetrahedra, corners with two equivalent O(4)Zn2Ga2 tetrahedra, and corners with two equivalent O(1)Zn3Ga tetrahedra. In the third N site, N(3) is bonded to one Zn(2), one Zn(4), one Ga(10), and one Ga(6) atom to form NZn2Ga2 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(5)Zn2Ga2 tetrahedra, corners with two equivalent N(4)ZnGa3 tetrahedra, and corners with two equivalent N(8)ZnGa3 tetrahedra. In the fourth N site, N(4) is bonded to one Zn(2), one Ga(12), one Ga(6), and one Ga(8) atom to form NZnGa3 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra, corners with two equivalent N(3)Zn2Ga2 tetrahedra, corners with two equivalent N(5)Zn2Ga2 tetrahedra, and corners with two equivalent N(8)ZnGa3 tetrahedra. In the fifth N site, N(5) is bonded to one Zn(2), one Zn(4), one Ga(12), and one Ga(7) atom to form NZn2Ga2 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(3)Zn2Ga2 tetrahedra, corners with two equivalent N(4)ZnGa3 tetrahedra, and corners with two equivalent N(8)ZnGa3 tetrahedra. In the sixth N site, N(6) is bonded to one Ga(1), one Ga(10), one Ga(7), and one Ga(9) atom to form NGa4 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(11)Ga4 tetrahedra, corners with two equivalent N(12)Ga4 tetrahedra, and corners with two equivalent N(7)Ga4 tetrahedra. In the seventh N site, N(7) is bonded to one Ga(11), one Ga(7), one Ga(8), and one Ga(9) atom to form NGa4 tetrahedra that share  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(11)Ga4 tetrahedra, corners with two equivalent N(12)Ga4 tetrahedra, and corners with two equivalent N(6)Ga4 tetrahedra. In the eighth N site, N(8) is bonded to one Zn(4), one Ga(12), one Ga(6), and one Ga(9) atom to form NZnGa3 tetrahedra that share  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(3)Zn2Ga2 tetrahedra, corners with two equivalent N(5)Zn2Ga2 tetrahedra, and corners with two equivalent N(4)ZnGa3 tetrahedra. In the ninth N site, N(9) is bonded to one Zn(3), one Ga(2), one Ga(3), and one Ga(6) atom to form NZnGa3 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra, corners with two equivalent N(2)Zn2Ga2 tetrahedra, corners with two equivalent O(4)Zn2Ga2 tetrahedra, and corners with two equivalent O(1)Zn3Ga tetrahedra. In the tenth N site, N(10) is bonded to one Ga(11), one Ga(2), one Ga(4), and one Ga(5) atom to form NGa4 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra, corners with two equivalent N(1)Ga4 tetrahedra, corners with two equivalent O(2)ZnGa3 tetrahedra, and corners with two equivalent O(3)ZnGa3 tetrahedra. In the eleventh N site, N(11) is bonded to one Ga(10), one Ga(5), one Ga(7), and one Ga(8) atom to form NGa4 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(12)Ga4 tetrahedra, corners with two equivalent N(6)Ga4 tetrahedra, and corners with two equivalent N(7)Ga4 tetrahedra. In the twelfth N site, N(12) is bonded to one Ga(10), one Ga(4), one Ga(8), and one Ga(9) atom to form NGa4 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra, corners with two equivalent N(11)Ga4 tetrahedra, corners with two equivalent N(6)Ga4 tetrahedra, and corners with two equivalent N(7)Ga4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Zn(1), one Zn(3), one Zn(4), and one Ga(3) atom to form OZn3Ga tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(8)ZnGa3 tetrahedra,  a cornercorner with one O(2)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(2)Zn2Ga2 tetrahedra, corners with two equivalent N(9)ZnGa3 tetrahedra, and corners with two equivalent O(4)Zn2Ga2 tetrahedra. In the second O site, O(2) is bonded to one Zn(3), one Ga(1), one Ga(11), and one Ga(4) atom to form OZnGa3 tetrahedra that share  a cornercorner with one N(12)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one N(9)ZnGa3 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(1)Ga4 tetrahedra, corners with two equivalent N(10)Ga4 tetrahedra, and corners with two equivalent O(3)ZnGa3 tetrahedra. In the third O site, O(3) is bonded to one Zn(1), one Ga(1), one Ga(11), and one Ga(5) atom to form OZnGa3 tetrahedra that share  a cornercorner with one N(11)Ga4 tetrahedra,  a cornercorner with one N(6)Ga4 tetrahedra,  a cornercorner with one N(7)Ga4 tetrahedra,  a cornercorner with one N(2)Zn2Ga2 tetrahedra,  a cornercorner with one O(4)Zn2Ga2 tetrahedra,  a cornercorner with one O(1)Zn3Ga tetrahedra, corners with two equivalent N(1)Ga4 tetrahedra, corners with two equivalent N(10)Ga4 tetrahedra, and corners with two equivalent O(2)ZnGa3 tetrahedra. In the fourth O site, O(4) is bonded to one Zn(1), one Zn(2), one Ga(2), and one Ga(3) atom to form OZn2Ga2 tetrahedra that share  a cornercorner with one N(1)Ga4 tetrahedra,  a cornercorner with one N(10)Ga4 tetrahedra,  a cornercorner with one N(3)Zn2Ga2 tetrahedra,  a cornercorner with one N(5)Zn2Ga2 tetrahedra,  a cornercorner with one N(4)ZnGa3 tetrahedra,  a cornercorner with one O(3)ZnGa3 tetrahedra, corners with two equivalent N(2)Zn2Ga2 tetrahedra, corners with two equivalent N(9)ZnGa3 tetrahedra, and corners with two equivalent O(1)Zn3Ga tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnGa3N3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.493
_cell_length_b   6.493
_cell_length_c   10.542
_cell_angle_alpha   90.013
_cell_angle_beta   90.012
_cell_angle_gamma   119.955
_symmetry_Int_Tables_number   1
_cell_volume   385.065
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.173  0.844  0.735  1.0
  Zn  Zn1  1  0.833  0.667  0.487  1.0
  Zn  Zn2  1  0.162  0.323  0.734  1.0
  Zn  Zn3  1  0.334  0.666  0.489  1.0
  Ga  Ga4  1  0.344  0.671  0.007  1.0
  Ga  Ga5  1  0.659  0.322  0.745  1.0
  Ga  Ga6  1  0.669  0.842  0.747  1.0
  Ga  Ga7  1  0.824  0.162  0.005  1.0
  Ga  Ga8  1  0.823  0.661  0.005  1.0
  Ga  Ga9  1  0.831  0.164  0.495  1.0
  Ga  Ga10  1  0.166  0.834  0.256  1.0
  Ga  Ga11  1  0.667  0.333  0.255  1.0
  Ga  Ga12  1  0.165  0.332  0.255  1.0
  Ga  Ga13  1  0.668  0.835  0.257  1.0
  Ga  Ga14  1  0.344  0.172  0.006  1.0
  Ga  Ga15  1  0.334  0.166  0.497  1.0
  N  N16  1  0.668  0.834  0.937  1.0
  N  N17  1  0.345  0.175  0.685  1.0
  N  N18  1  0.671  0.842  0.437  1.0
  N  N19  1  0.663  0.325  0.437  1.0
  N  N20  1  0.172  0.843  0.437  1.0
  N  N21  1  0.333  0.666  0.188  1.0
  N  N22  1  0.333  0.167  0.186  1.0
  N  N23  1  0.162  0.324  0.437  1.0
  N  N24  1  0.824  0.163  0.686  1.0
  N  N25  1  0.668  0.334  0.936  1.0
  N  N26  1  0.833  0.666  0.187  1.0
  N  N27  1  0.834  0.167  0.187  1.0
  O  O28  1  0.345  0.671  0.701  1.0
  O  O29  1  0.167  0.334  0.949  1.0
  O  O30  1  0.167  0.833  0.947  1.0
  O  O31  1  0.821  0.660  0.702  1.0
[/CIF]
.