The material described by KTl(CN)4 crystallizes in the tetragonal I4_1/a space group. The structure consists of a KTl(CN)4 framework. K(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. Tl(1) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Tl(1) and one N(1) atom. N(1) is bonded in a bent 120 degrees geometry to one K(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTl(CN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.484
_cell_length_b   9.484
_cell_length_c   9.484
_cell_angle_alpha   131.489
_cell_angle_beta   131.489
_cell_angle_gamma   71.038
_symmetry_Int_Tables_number   1
_cell_volume   468.637
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.750  0.500  1.0
  K  K1  1  0.500  0.500  0.000  1.0
  Tl  Tl2  1  0.000  0.000  0.000  1.0
  Tl  Tl3  1  0.750  0.250  0.500  1.0
  C  C4  1  0.100  0.045  0.316  1.0
  C  C5  1  0.534  0.350  0.555  1.0
  C  C6  1  0.795  0.979  0.445  1.0
  C  C7  1  0.729  0.784  0.684  1.0
  C  C8  1  0.955  0.271  0.055  1.0
  C  C9  1  0.021  0.466  0.816  1.0
  C  C10  1  0.650  0.205  0.184  1.0
  C  C11  1  0.216  0.900  0.945  1.0
  N  N12  1  0.584  0.672  0.524  1.0
  N  N13  1  0.811  0.834  0.412  1.0
  N  N14  1  0.422  0.398  0.588  1.0
  N  N15  1  0.148  0.061  0.476  1.0
  N  N16  1  0.939  0.416  0.088  1.0
  N  N17  1  0.166  0.578  0.976  1.0
  N  N18  1  0.602  0.189  0.024  1.0
  N  N19  1  0.328  0.852  0.912  1.0
[/CIF]
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The material described by KTl(CN)4 crystallizes in the tetragonal I4_1/a space group. The structure consists of a KTl(CN)4 framework. K(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. Tl(1) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Tl(1) and one N(1) atom. N(1) is bonded in a bent 120 degrees geometry to one K(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTl(CN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.484
_cell_length_b   9.484
_cell_length_c   9.484
_cell_angle_alpha   131.489
_cell_angle_beta   131.489
_cell_angle_gamma   71.038
_symmetry_Int_Tables_number   1
_cell_volume   468.637
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.750  0.500  1.0
  K  K1  1  0.500  0.500  0.000  1.0
  Tl  Tl2  1  0.000  0.000  0.000  1.0
  Tl  Tl3  1  0.750  0.250  0.500  1.0
  C  C4  1  0.100  0.045  0.316  1.0
  C  C5  1  0.534  0.350  0.555  1.0
  C  C6  1  0.795  0.979  0.445  1.0
  C  C7  1  0.729  0.784  0.684  1.0
  C  C8  1  0.955  0.271  0.055  1.0
  C  C9  1  0.021  0.466  0.816  1.0
  C  C10  1  0.650  0.205  0.184  1.0
  C  C11  1  0.216  0.900  0.945  1.0
  N  N12  1  0.584  0.672  0.524  1.0
  N  N13  1  0.811  0.834  0.412  1.0
  N  N14  1  0.422  0.398  0.588  1.0
  N  N15  1  0.148  0.061  0.476  1.0
  N  N16  1  0.939  0.416  0.088  1.0
  N  N17  1  0.166  0.578  0.976  1.0
  N  N18  1  0.602  0.189  0.024  1.0
  N  N19  1  0.328  0.852  0.912  1.0
[/CIF]
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