The material structure described by AgPO4 crystallizes in the triclinic P-1 space group. There are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(10), one O(2), one O(5), one O(7), and one O(8) atom to form distorted AgO5 square pyramids that share corners with two equivalent P(1)O4 tetrahedra and corners with three equivalent P(3)O4 tetrahedra. In the second Ag site, Ag(2) is bonded to one O(12), one O(14), one O(15), one O(4), and one O(9) atom to form distorted AgO5 square pyramids that share corners with two equivalent P(4)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. In the third Ag site, Ag(3) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(5) atoms. In the fourth Ag site, Ag(4) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(14), one O(16), one O(6), and one O(8) atom. In the fifth Ag site, Ag(5) is bonded in a square co-planar geometry to two equivalent O(15) and two equivalent O(3) atoms. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(13), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent Ag(1)O5 square pyramids. In the second P site, P(2) is bonded to one O(12), one O(4), one O(6), and one O(9) atom to form PO4 tetrahedra that share corners with three equivalent Ag(2)O5 square pyramids. In the third P site, P(3) is bonded to one O(16), one O(2), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with three equivalent Ag(1)O5 square pyramids. In the fourth P site, P(4) is bonded to one O(11), one O(14), one O(15), and one O(3) atom to form PO4 tetrahedra that share corners with two equivalent Ag(2)O5 square pyramids. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(3) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ag(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ag(5) and one P(4) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(3), and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(4) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(4), and one P(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ag(2) and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(4), and one P(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one Ag(4), and one P(2) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one P(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Ag(2), one Ag(4), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one Ag(2), one Ag(5), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Ag(4) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.108
_cell_length_b   9.741
_cell_length_c   15.419
_cell_angle_alpha   95.452
_cell_angle_beta   99.506
_cell_angle_gamma   105.157
_symmetry_Int_Tables_number   1
_cell_volume   722.582
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.617  0.770  0.973  1.0
  Ag  Ag1  1  0.385  0.732  0.528  1.0
  Ag  Ag2  1  0.384  0.230  0.027  1.0
  Ag  Ag3  1  0.000  0.500  0.000  1.0
  Ag  Ag4  1  0.615  0.268  0.472  1.0
  Ag  Ag5  1  0.581  0.251  0.250  1.0
  Ag  Ag6  1  0.419  0.749  0.750  1.0
  Ag  Ag7  1  0.000  0.000  0.500  1.0
  P  P8  1  0.383  0.433  0.867  1.0
  P  P9  1  0.810  0.587  0.617  1.0
  P  P10  1  0.617  0.567  0.133  1.0
  P  P11  1  0.896  0.088  0.117  1.0
  P  P12  1  0.419  0.933  0.367  1.0
  P  P13  1  0.581  0.067  0.633  1.0
  P  P14  1  0.190  0.413  0.383  1.0
  P  P15  1  0.104  0.912  0.883  1.0
  O  O16  1  0.908  0.608  0.104  1.0
  O  O17  1  0.216  0.073  0.917  1.0
  O  O18  1  0.308  0.107  0.606  1.0
  O  O19  1  0.918  0.688  0.552  1.0
  O  O20  1  0.419  0.612  0.056  1.0
  O  O21  1  0.013  0.602  0.706  1.0
  O  O22  1  0.170  0.807  0.946  1.0
  O  O23  1  0.225  0.123  0.136  1.0
  O  O24  1  0.082  0.312  0.448  1.0
  O  O25  1  0.726  0.424  0.584  1.0
  O  O26  1  0.505  0.399  0.131  1.0
  O  O27  1  0.275  0.865  0.274  1.0
  O  O28  1  0.784  0.927  0.083  1.0
  O  O29  1  0.539  0.627  0.636  1.0
  O  O30  1  0.092  0.392  0.896  1.0
  O  O31  1  0.495  0.601  0.869  1.0
  O  O32  1  0.375  0.365  0.775  1.0
  O  O33  1  0.830  0.193  0.054  1.0
  O  O34  1  0.530  0.899  0.633  1.0
  O  O35  1  0.725  0.135  0.726  1.0
  O  O36  1  0.461  0.373  0.364  1.0
  O  O37  1  0.744  0.108  0.555  1.0
  O  O38  1  0.775  0.877  0.864  1.0
  O  O39  1  0.801  0.107  0.207  1.0
  O  O40  1  0.274  0.576  0.416  1.0
  O  O41  1  0.692  0.893  0.394  1.0
  O  O42  1  0.625  0.635  0.225  1.0
  O  O43  1  0.256  0.892  0.445  1.0
  O  O44  1  0.581  0.388  0.944  1.0
  O  O45  1  0.199  0.893  0.793  1.0
  O  O46  1  0.987  0.398  0.294  1.0
  O  O47  1  0.470  0.101  0.367  1.0
[/CIF]
.
The material structure described by AgPO4 crystallizes in the triclinic P-1 space group. There are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(10), one O(2), one O(5), one O(7), and one O(8) atom to form distorted AgO5 square pyramids that share corners with two equivalent P(1)O4 tetrahedra and corners with three equivalent P(3)O4 tetrahedra. In the second Ag site, Ag(2) is bonded to one O(12), one O(14), one O(15), one O(4), and one O(9) atom to form distorted AgO5 square pyramids that share corners with two equivalent P(4)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. In the third Ag site, Ag(3) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(5) atoms. In the fourth Ag site, Ag(4) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(14), one O(16), one O(6), and one O(8) atom. In the fifth Ag site, Ag(5) is bonded in a square co-planar geometry to two equivalent O(15) and two equivalent O(3) atoms. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(13), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent Ag(1)O5 square pyramids. In the second P site, P(2) is bonded to one O(12), one O(4), one O(6), and one O(9) atom to form PO4 tetrahedra that share corners with three equivalent Ag(2)O5 square pyramids. In the third P site, P(3) is bonded to one O(16), one O(2), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with three equivalent Ag(1)O5 square pyramids. In the fourth P site, P(4) is bonded to one O(11), one O(14), one O(15), and one O(3) atom to form PO4 tetrahedra that share corners with two equivalent Ag(2)O5 square pyramids. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(3) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ag(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ag(5) and one P(4) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(3), and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(4) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(4), and one P(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ag(2) and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(4), and one P(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one Ag(4), and one P(2) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one P(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Ag(2), one Ag(4), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one Ag(2), one Ag(5), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Ag(4) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.108
_cell_length_b   9.741
_cell_length_c   15.419
_cell_angle_alpha   95.452
_cell_angle_beta   99.506
_cell_angle_gamma   105.157
_symmetry_Int_Tables_number   1
_cell_volume   722.582
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.617  0.770  0.973  1.0
  Ag  Ag1  1  0.385  0.732  0.528  1.0
  Ag  Ag2  1  0.384  0.230  0.027  1.0
  Ag  Ag3  1  0.000  0.500  0.000  1.0
  Ag  Ag4  1  0.615  0.268  0.472  1.0
  Ag  Ag5  1  0.581  0.251  0.250  1.0
  Ag  Ag6  1  0.419  0.749  0.750  1.0
  Ag  Ag7  1  0.000  0.000  0.500  1.0
  P  P8  1  0.383  0.433  0.867  1.0
  P  P9  1  0.810  0.587  0.617  1.0
  P  P10  1  0.617  0.567  0.133  1.0
  P  P11  1  0.896  0.088  0.117  1.0
  P  P12  1  0.419  0.933  0.367  1.0
  P  P13  1  0.581  0.067  0.633  1.0
  P  P14  1  0.190  0.413  0.383  1.0
  P  P15  1  0.104  0.912  0.883  1.0
  O  O16  1  0.908  0.608  0.104  1.0
  O  O17  1  0.216  0.073  0.917  1.0
  O  O18  1  0.308  0.107  0.606  1.0
  O  O19  1  0.918  0.688  0.552  1.0
  O  O20  1  0.419  0.612  0.056  1.0
  O  O21  1  0.013  0.602  0.706  1.0
  O  O22  1  0.170  0.807  0.946  1.0
  O  O23  1  0.225  0.123  0.136  1.0
  O  O24  1  0.082  0.312  0.448  1.0
  O  O25  1  0.726  0.424  0.584  1.0
  O  O26  1  0.505  0.399  0.131  1.0
  O  O27  1  0.275  0.865  0.274  1.0
  O  O28  1  0.784  0.927  0.083  1.0
  O  O29  1  0.539  0.627  0.636  1.0
  O  O30  1  0.092  0.392  0.896  1.0
  O  O31  1  0.495  0.601  0.869  1.0
  O  O32  1  0.375  0.365  0.775  1.0
  O  O33  1  0.830  0.193  0.054  1.0
  O  O34  1  0.530  0.899  0.633  1.0
  O  O35  1  0.725  0.135  0.726  1.0
  O  O36  1  0.461  0.373  0.364  1.0
  O  O37  1  0.744  0.108  0.555  1.0
  O  O38  1  0.775  0.877  0.864  1.0
  O  O39  1  0.801  0.107  0.207  1.0
  O  O40  1  0.274  0.576  0.416  1.0
  O  O41  1  0.692  0.893  0.394  1.0
  O  O42  1  0.625  0.635  0.225  1.0
  O  O43  1  0.256  0.892  0.445  1.0
  O  O44  1  0.581  0.388  0.944  1.0
  O  O45  1  0.199  0.893  0.793  1.0
  O  O46  1  0.987  0.398  0.294  1.0
  O  O47  1  0.470  0.101  0.367  1.0
[/CIF]
.