The crystal structure described by ZnF2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pbcn space group. Zn(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing ZnF6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. F(1) is bonded in a trigonal planar geometry to three equivalent Zn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.681
_cell_length_b   5.143
_cell_length_c   5.656
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   136.178
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.750  0.337  1.0
  Zn  Zn1  1  0.000  0.250  0.163  1.0
  Zn  Zn2  1  0.500  0.250  0.663  1.0
  Zn  Zn3  1  0.000  0.750  0.837  1.0
  F  F4  1  0.731  0.081  0.389  1.0
  F  F5  1  0.231  0.919  0.111  1.0
  F  F6  1  0.769  0.581  0.111  1.0
  F  F7  1  0.269  0.419  0.389  1.0
  F  F8  1  0.731  0.581  0.611  1.0
  F  F9  1  0.231  0.419  0.889  1.0
  F  F10  1  0.769  0.081  0.889  1.0
  F  F11  1  0.269  0.919  0.611  1.0
[/CIF]
.
The crystal structure described by ZnF2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pbcn space group. Zn(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing ZnF6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. F(1) is bonded in a trigonal planar geometry to three equivalent Zn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.681
_cell_length_b   5.143
_cell_length_c   5.656
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   136.178
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.750  0.337  1.0
  Zn  Zn1  1  0.000  0.250  0.163  1.0
  Zn  Zn2  1  0.500  0.250  0.663  1.0
  Zn  Zn3  1  0.000  0.750  0.837  1.0
  F  F4  1  0.731  0.081  0.389  1.0
  F  F5  1  0.231  0.919  0.111  1.0
  F  F6  1  0.769  0.581  0.111  1.0
  F  F7  1  0.269  0.419  0.389  1.0
  F  F8  1  0.731  0.581  0.611  1.0
  F  F9  1  0.231  0.419  0.889  1.0
  F  F10  1  0.769  0.081  0.889  1.0
  F  F11  1  0.269  0.919  0.611  1.0
[/CIF]
.