The material structure described by CeRhAs crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded to six equivalent Rh(1) and six equivalent As(1) atoms to form a mixture of distorted face and edge-sharing CeAs6Rh6 cuboctahedra. Rh(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent As(1) atoms. As(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CeAsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.409
_cell_length_b   7.176
_cell_length_c   7.646
_cell_angle_alpha   89.990
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   241.880
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.768  0.509  1.0
  Ce  Ce1  1  0.750  0.232  0.491  1.0
  Ce  Ce2  1  0.750  0.268  0.991  1.0
  Ce  Ce3  1  0.250  0.732  0.009  1.0
  As  As4  1  0.250  0.406  0.721  1.0
  As  As5  1  0.750  0.594  0.279  1.0
  As  As6  1  0.750  0.906  0.779  1.0
  As  As7  1  0.250  0.094  0.221  1.0
  Rh  Rh8  1  0.250  0.440  0.246  1.0
  Rh  Rh9  1  0.750  0.560  0.754  1.0
  Rh  Rh10  1  0.750  0.940  0.255  1.0
  Rh  Rh11  1  0.250  0.060  0.745  1.0
[/CIF]
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The material structure described by CeRhAs crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded to six equivalent Rh(1) and six equivalent As(1) atoms to form a mixture of distorted face and edge-sharing CeAs6Rh6 cuboctahedra. Rh(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent As(1) atoms. As(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CeAsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.409
_cell_length_b   7.176
_cell_length_c   7.646
_cell_angle_alpha   89.990
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   241.880
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.768  0.509  1.0
  Ce  Ce1  1  0.750  0.232  0.491  1.0
  Ce  Ce2  1  0.750  0.268  0.991  1.0
  Ce  Ce3  1  0.250  0.732  0.009  1.0
  As  As4  1  0.250  0.406  0.721  1.0
  As  As5  1  0.750  0.594  0.279  1.0
  As  As6  1  0.750  0.906  0.779  1.0
  As  As7  1  0.250  0.094  0.221  1.0
  Rh  Rh8  1  0.250  0.440  0.246  1.0
  Rh  Rh9  1  0.750  0.560  0.754  1.0
  Rh  Rh10  1  0.750  0.940  0.255  1.0
  Rh  Rh11  1  0.250  0.060  0.745  1.0
[/CIF]
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