The compound described by Rb2Mn(TeS3)2 crystallizes in the trigonal P-3c1 space group. Rb(1) is bonded in a 7-coordinate geometry to one Te(1) and six equivalent S(1) atoms. Mn(1) is bonded in an octahedral geometry to six equivalent S(1) atoms. Te(1) is bonded in a 3-coordinate geometry to one Rb(1) and three equivalent S(1) atoms. S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Mn(1), and one Te(1) atom. is represented by the CIF card [CIF]
data_Rb2Mn(TeS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.998
_cell_length_b   6.998
_cell_length_c   15.559
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   659.962
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.333  0.667  0.797  1.0
  Rb  Rb1  1  0.667  0.333  0.203  1.0
  Rb  Rb2  1  0.667  0.333  0.703  1.0
  Rb  Rb3  1  0.333  0.667  0.297  1.0
  Mn  Mn4  1  0.000  0.000  0.500  1.0
  Mn  Mn5  1  0.000  0.000  0.000  1.0
  Te  Te6  1  0.333  0.667  0.539  1.0
  Te  Te7  1  0.667  0.333  0.461  1.0
  Te  Te8  1  0.667  0.333  0.961  1.0
  Te  Te9  1  0.333  0.667  0.039  1.0
  S  S10  1  0.109  0.322  0.609  1.0
  S  S11  1  0.891  0.678  0.391  1.0
  S  S12  1  0.678  0.788  0.609  1.0
  S  S13  1  0.322  0.109  0.891  1.0
  S  S14  1  0.322  0.212  0.391  1.0
  S  S15  1  0.678  0.891  0.109  1.0
  S  S16  1  0.212  0.891  0.609  1.0
  S  S17  1  0.788  0.678  0.891  1.0
  S  S18  1  0.788  0.109  0.391  1.0
  S  S19  1  0.212  0.322  0.109  1.0
  S  S20  1  0.891  0.212  0.891  1.0
  S  S21  1  0.109  0.788  0.109  1.0
[/CIF]
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The compound described by Rb2Mn(TeS3)2 crystallizes in the trigonal P-3c1 space group. Rb(1) is bonded in a 7-coordinate geometry to one Te(1) and six equivalent S(1) atoms. Mn(1) is bonded in an octahedral geometry to six equivalent S(1) atoms. Te(1) is bonded in a 3-coordinate geometry to one Rb(1) and three equivalent S(1) atoms. S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Mn(1), and one Te(1) atom. is represented by the CIF card [CIF]
data_Rb2Mn(TeS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.998
_cell_length_b   6.998
_cell_length_c   15.559
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   659.962
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.333  0.667  0.797  1.0
  Rb  Rb1  1  0.667  0.333  0.203  1.0
  Rb  Rb2  1  0.667  0.333  0.703  1.0
  Rb  Rb3  1  0.333  0.667  0.297  1.0
  Mn  Mn4  1  0.000  0.000  0.500  1.0
  Mn  Mn5  1  0.000  0.000  0.000  1.0
  Te  Te6  1  0.333  0.667  0.539  1.0
  Te  Te7  1  0.667  0.333  0.461  1.0
  Te  Te8  1  0.667  0.333  0.961  1.0
  Te  Te9  1  0.333  0.667  0.039  1.0
  S  S10  1  0.109  0.322  0.609  1.0
  S  S11  1  0.891  0.678  0.391  1.0
  S  S12  1  0.678  0.788  0.609  1.0
  S  S13  1  0.322  0.109  0.891  1.0
  S  S14  1  0.322  0.212  0.391  1.0
  S  S15  1  0.678  0.891  0.109  1.0
  S  S16  1  0.212  0.891  0.609  1.0
  S  S17  1  0.788  0.678  0.891  1.0
  S  S18  1  0.788  0.109  0.391  1.0
  S  S19  1  0.212  0.322  0.109  1.0
  S  S20  1  0.891  0.212  0.891  1.0
  S  S21  1  0.109  0.788  0.109  1.0
[/CIF]
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