The structure described by LiVP3HO10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(6), and one O(7) atom. V(1) is bonded to one O(1), one O(10), one O(2), one O(3), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(4), one O(6), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 30-48°. In the second P site, P(2) is bonded to one O(3), one O(4), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-45°. In the third P site, P(3) is bonded to one O(10), one O(2), one O(5), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 24-48°. H(1) is bonded in a linear geometry to one O(5) and one O(6) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Li(1), one P(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one P(3), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one P(1), and one H(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one P(2), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.433
_cell_length_b   6.517
_cell_length_c   6.363
_cell_angle_alpha   72.960
_cell_angle_beta   106.195
_cell_angle_gamma   93.460
_symmetry_Int_Tables_number   1
_cell_volume   244.830
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.204  0.200  0.495  1.0
  V  V1  1  0.653  0.651  0.002  1.0
  P  P2  1  0.188  0.545  0.107  1.0
  P  P3  1  0.553  0.561  0.500  1.0
  P  P4  1  0.553  0.190  0.901  1.0
  H  H5  1  0.238  0.218  0.973  1.0
  O  O6  1  0.331  0.650  0.952  1.0
  O  O7  1  0.652  0.971  0.968  1.0
  O  O8  1  0.592  0.699  0.657  1.0
  O  O9  1  0.301  0.587  0.360  1.0
  O  O10  1  0.295  0.183  0.850  1.0
  O  O11  1  0.183  0.298  0.165  1.0
  O  O12  1  0.569  0.305  0.641  1.0
  O  O13  1  0.699  0.590  0.346  1.0
  O  O14  1  0.969  0.658  0.028  1.0
  O  O15  1  0.653  0.327  0.055  1.0
[/CIF]
.
The structure described by LiVP3HO10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(6), and one O(7) atom. V(1) is bonded to one O(1), one O(10), one O(2), one O(3), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(4), one O(6), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 30-48°. In the second P site, P(2) is bonded to one O(3), one O(4), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-45°. In the third P site, P(3) is bonded to one O(10), one O(2), one O(5), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 24-48°. H(1) is bonded in a linear geometry to one O(5) and one O(6) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Li(1), one P(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one P(3), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one P(1), and one H(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one P(2), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.433
_cell_length_b   6.517
_cell_length_c   6.363
_cell_angle_alpha   72.960
_cell_angle_beta   106.195
_cell_angle_gamma   93.460
_symmetry_Int_Tables_number   1
_cell_volume   244.830
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.204  0.200  0.495  1.0
  V  V1  1  0.653  0.651  0.002  1.0
  P  P2  1  0.188  0.545  0.107  1.0
  P  P3  1  0.553  0.561  0.500  1.0
  P  P4  1  0.553  0.190  0.901  1.0
  H  H5  1  0.238  0.218  0.973  1.0
  O  O6  1  0.331  0.650  0.952  1.0
  O  O7  1  0.652  0.971  0.968  1.0
  O  O8  1  0.592  0.699  0.657  1.0
  O  O9  1  0.301  0.587  0.360  1.0
  O  O10  1  0.295  0.183  0.850  1.0
  O  O11  1  0.183  0.298  0.165  1.0
  O  O12  1  0.569  0.305  0.641  1.0
  O  O13  1  0.699  0.590  0.346  1.0
  O  O14  1  0.969  0.658  0.028  1.0
  O  O15  1  0.653  0.327  0.055  1.0
[/CIF]
.