The material structure described by Sr2Ca6Fe3Co5O24 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Amm2 space group. Sr(1) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(5), two equivalent O(8), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with four equivalent Ca(2)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra, faces with two equivalent Fe(2)O6 octahedra, and faces with two equivalent Co(3)O6 octahedra. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded to one O(1), one O(10), one O(11), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(2) atoms to form CaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Ca(1)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra, faces with two equivalent Fe(2)O6 octahedra, and faces with two equivalent Co(3)O6 octahedra. In the second Ca site, Ca(2) is bonded to one O(1), one O(3), two equivalent O(10), two equivalent O(11), two equivalent O(2), two equivalent O(6), and two equivalent O(7) atoms to form CaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra, faces with two equivalent Fe(2)O6 octahedra, and faces with two equivalent Co(3)O6 octahedra. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms to form FeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Fe site, Fe(2) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent Co(4)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Co site, Co(3) is bonded to one O(10), one O(11), one O(8), one O(9), and two equivalent O(2) atoms to form CoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Co site, Co(4) is bonded to two equivalent O(11), two equivalent O(3), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one Ca(2), two equivalent Ca(1), one Fe(1), and one Co(2) atom to form distorted OSrCa3FeCo octahedra that share corners with two equivalent O(1)SrCa3FeCo octahedra, corners with four equivalent O(9)Sr2Ca2Co2 octahedra, corners with four equivalent O(5)Sr2Ca2FeCo octahedra, corners with four equivalent O(3)SrCa3Co2 octahedra, edges with four equivalent O(2)SrCa3FeCo octahedra, faces with two equivalent O(6)Ca4Fe2 octahedra, faces with two equivalent O(8)Sr2Ca2Co2 octahedra, and faces with two equivalent O(4)Sr2Ca2Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the second O site, O(2) is bonded to one Sr(1), one Ca(2), two equivalent Ca(1), one Fe(2), and one Co(3) atom to form distorted OSrCa3FeCo octahedra that share corners with two equivalent O(6)Ca4Fe2 octahedra, corners with two equivalent O(8)Sr2Ca2Co2 octahedra, corners with two equivalent O(9)Sr2Ca2Co2 octahedra, corners with two equivalent O(4)Sr2Ca2Fe2 octahedra, corners with two equivalent O(5)Sr2Ca2FeCo octahedra, corners with six equivalent O(2)SrCa3FeCo octahedra, edges with two equivalent O(3)SrCa3Co2 octahedra, edges with two equivalent O(1)SrCa3FeCo octahedra,  a faceface with one O(6)Ca4Fe2 octahedra,  a faceface with one O(8)Sr2Ca2Co2 octahedra,  a faceface with one O(9)Sr2Ca2Co2 octahedra,  a faceface with one O(4)Sr2Ca2Fe2 octahedra, and  a faceface with one O(5)Sr2Ca2FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the third O site, O(3) is bonded to one Sr(1), one Ca(2), two equivalent Ca(1), one Co(1), and one Co(4) atom to form distorted OSrCa3Co2 octahedra that share corners with two equivalent O(3)SrCa3Co2 octahedra, corners with four equivalent O(6)Ca4Fe2 octahedra, corners with four equivalent O(8)Sr2Ca2Co2 octahedra, corners with four equivalent O(4)Sr2Ca2Fe2 octahedra, corners with four equivalent O(1)SrCa3FeCo octahedra, edges with four equivalent O(2)SrCa3FeCo octahedra, faces with two equivalent O(9)Sr2Ca2Co2 octahedra, and faces with two equivalent O(5)Sr2Ca2FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent Ca(1), one Fe(1), and one Fe(2) atom to form distorted OSr2Ca2Fe2 octahedra that share corners with two equivalent O(6)Ca4Fe2 octahedra, corners with two equivalent O(8)Sr2Ca2Co2 octahedra, corners with four equivalent O(3)SrCa3Co2 octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra, corners with six equivalent O(9)Sr2Ca2Co2 octahedra, edges with two equivalent O(8)Sr2Ca2Co2 octahedra, edges with two equivalent O(5)Sr2Ca2FeCo octahedra,  a faceface with one O(6)Ca4Fe2 octahedra,  a faceface with one O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(5)Sr2Ca2FeCo octahedra, faces with two equivalent O(1)SrCa3FeCo octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Ca(1), one Fe(2), and one Co(1) atom to form distorted OSr2Ca2FeCo octahedra that share corners with two equivalent O(9)Sr2Ca2Co2 octahedra, corners with four equivalent O(1)SrCa3FeCo octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra, corners with six equivalent O(8)Sr2Ca2Co2 octahedra, edges with two equivalent O(9)Sr2Ca2Co2 octahedra, edges with two equivalent O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(6)Ca4Fe2 octahedra,  a faceface with one O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(5)Sr2Ca2FeCo octahedra, faces with two equivalent O(3)SrCa3Co2 octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the sixth O site, O(6) is bonded to two equivalent Ca(1), two equivalent Ca(2), one Fe(1), and one Fe(2) atom to form distorted OCa4Fe2 octahedra that share corners with two equivalent O(8)Sr2Ca2Co2 octahedra, corners with two equivalent O(9)Sr2Ca2Co2 octahedra, corners with two equivalent O(4)Sr2Ca2Fe2 octahedra, corners with four equivalent O(3)SrCa3Co2 octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra,  a faceface with one O(6)Ca4Fe2 octahedra,  a faceface with one O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(5)Sr2Ca2FeCo octahedra, faces with two equivalent O(1)SrCa3FeCo octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Ca(1), two equivalent Ca(2), one Fe(2), and one Co(1) atom. In the eighth O site, O(8) is bonded to two equivalent Sr(1), two equivalent Ca(1), one Co(2), and one Co(3) atom to form distorted OSr2Ca2Co2 octahedra that share corners with two equivalent O(6)Ca4Fe2 octahedra, corners with two equivalent O(4)Sr2Ca2Fe2 octahedra, corners with four equivalent O(3)SrCa3Co2 octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra, corners with six equivalent O(5)Sr2Ca2FeCo octahedra, edges with two equivalent O(9)Sr2Ca2Co2 octahedra, edges with two equivalent O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(8)Sr2Ca2Co2 octahedra,  a faceface with one O(9)Sr2Ca2Co2 octahedra, faces with two equivalent O(1)SrCa3FeCo octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Ca(1), one Co(3), and one Co(4) atom to form distorted OSr2Ca2Co2 octahedra that share corners with two equivalent O(6)Ca4Fe2 octahedra, corners with two equivalent O(5)Sr2Ca2FeCo octahedra, corners with four equivalent O(1)SrCa3FeCo octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra, corners with six equivalent O(4)Sr2Ca2Fe2 octahedra, edges with two equivalent O(8)Sr2Ca2Co2 octahedra, edges with two equivalent O(5)Sr2Ca2FeCo octahedra,  a faceface with one O(8)Sr2Ca2Co2 octahedra,  a faceface with one O(9)Sr2Ca2Co2 octahedra, faces with two equivalent O(3)SrCa3Co2 octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the tenth O site, O(10) is bonded in a distorted linear geometry to two equivalent Ca(1), two equivalent Ca(2), one Co(2), and one Co(3) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to two equivalent Ca(1), two equivalent Ca(2), one Co(3), and one Co(4) atom. is represented by the CIF file [CIF]
data_Sr2Ca6Fe3Co5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.667
_cell_length_b   7.667
_cell_length_c   7.664
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.156
_symmetry_Int_Tables_number   1
_cell_volume   450.471
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.751  0.751  0.251  1.0
  Sr  Sr1  1  0.751  0.751  0.749  1.0
  Ca  Ca2  1  0.753  0.247  0.250  1.0
  Ca  Ca3  1  0.247  0.247  0.250  1.0
  Ca  Ca4  1  0.247  0.753  0.250  1.0
  Ca  Ca5  1  0.753  0.247  0.750  1.0
  Ca  Ca6  1  0.247  0.247  0.750  1.0
  Ca  Ca7  1  0.247  0.753  0.750  1.0
  Fe  Fe8  1  0.001  0.001  0.000  1.0
  Fe  Fe9  1  0.002  0.499  0.000  1.0
  Fe  Fe10  1  0.499  0.002  0.000  1.0
  Co  Co11  1  0.499  0.499  0.000  1.0
  Co  Co12  1  0.001  0.001  0.500  1.0
  Co  Co13  1  0.002  0.498  0.500  1.0
  Co  Co14  1  0.498  0.002  0.500  1.0
  Co  Co15  1  0.498  0.498  0.500  1.0
  O  O16  1  0.004  0.004  0.251  1.0
  O  O17  1  0.004  0.496  0.252  1.0
  O  O18  1  0.496  0.004  0.252  1.0
  O  O19  1  0.497  0.497  0.260  1.0
  O  O20  1  0.004  0.004  0.749  1.0
  O  O21  1  0.004  0.496  0.748  1.0
  O  O22  1  0.496  0.004  0.748  1.0
  O  O23  1  0.497  0.497  0.740  1.0
  O  O24  1  0.752  0.006  0.000  1.0
  O  O25  1  0.745  0.493  0.000  1.0
  O  O26  1  0.248  0.002  0.000  1.0
  O  O27  1  0.256  0.498  0.000  1.0
  O  O28  1  0.754  0.007  0.500  1.0
  O  O29  1  0.762  0.494  0.500  1.0
  O  O30  1  0.246  0.002  0.500  1.0
  O  O31  1  0.239  0.498  0.500  1.0
  O  O32  1  0.002  0.248  0.000  1.0
  O  O33  1  0.006  0.752  0.000  1.0
  O  O34  1  0.498  0.256  0.000  1.0
  O  O35  1  0.493  0.745  0.000  1.0
  O  O36  1  0.002  0.246  0.500  1.0
  O  O37  1  0.007  0.754  0.500  1.0
  O  O38  1  0.498  0.239  0.500  1.0
  O  O39  1  0.494  0.762  0.500  1.0
[/CIF]
.
The material structure described by Sr2Ca6Fe3Co5O24 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Amm2 space group. Sr(1) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(5), two equivalent O(8), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with four equivalent Ca(2)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra, faces with two equivalent Fe(2)O6 octahedra, and faces with two equivalent Co(3)O6 octahedra. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded to one O(1), one O(10), one O(11), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(2) atoms to form CaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Ca(1)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra, faces with two equivalent Fe(2)O6 octahedra, and faces with two equivalent Co(3)O6 octahedra. In the second Ca site, Ca(2) is bonded to one O(1), one O(3), two equivalent O(10), two equivalent O(11), two equivalent O(2), two equivalent O(6), and two equivalent O(7) atoms to form CaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra, faces with two equivalent Fe(2)O6 octahedra, and faces with two equivalent Co(3)O6 octahedra. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms to form FeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Fe site, Fe(2) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent Co(4)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Co site, Co(3) is bonded to one O(10), one O(11), one O(8), one O(9), and two equivalent O(2) atoms to form CoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Co site, Co(4) is bonded to two equivalent O(11), two equivalent O(3), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one Ca(2), two equivalent Ca(1), one Fe(1), and one Co(2) atom to form distorted OSrCa3FeCo octahedra that share corners with two equivalent O(1)SrCa3FeCo octahedra, corners with four equivalent O(9)Sr2Ca2Co2 octahedra, corners with four equivalent O(5)Sr2Ca2FeCo octahedra, corners with four equivalent O(3)SrCa3Co2 octahedra, edges with four equivalent O(2)SrCa3FeCo octahedra, faces with two equivalent O(6)Ca4Fe2 octahedra, faces with two equivalent O(8)Sr2Ca2Co2 octahedra, and faces with two equivalent O(4)Sr2Ca2Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the second O site, O(2) is bonded to one Sr(1), one Ca(2), two equivalent Ca(1), one Fe(2), and one Co(3) atom to form distorted OSrCa3FeCo octahedra that share corners with two equivalent O(6)Ca4Fe2 octahedra, corners with two equivalent O(8)Sr2Ca2Co2 octahedra, corners with two equivalent O(9)Sr2Ca2Co2 octahedra, corners with two equivalent O(4)Sr2Ca2Fe2 octahedra, corners with two equivalent O(5)Sr2Ca2FeCo octahedra, corners with six equivalent O(2)SrCa3FeCo octahedra, edges with two equivalent O(3)SrCa3Co2 octahedra, edges with two equivalent O(1)SrCa3FeCo octahedra,  a faceface with one O(6)Ca4Fe2 octahedra,  a faceface with one O(8)Sr2Ca2Co2 octahedra,  a faceface with one O(9)Sr2Ca2Co2 octahedra,  a faceface with one O(4)Sr2Ca2Fe2 octahedra, and  a faceface with one O(5)Sr2Ca2FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the third O site, O(3) is bonded to one Sr(1), one Ca(2), two equivalent Ca(1), one Co(1), and one Co(4) atom to form distorted OSrCa3Co2 octahedra that share corners with two equivalent O(3)SrCa3Co2 octahedra, corners with four equivalent O(6)Ca4Fe2 octahedra, corners with four equivalent O(8)Sr2Ca2Co2 octahedra, corners with four equivalent O(4)Sr2Ca2Fe2 octahedra, corners with four equivalent O(1)SrCa3FeCo octahedra, edges with four equivalent O(2)SrCa3FeCo octahedra, faces with two equivalent O(9)Sr2Ca2Co2 octahedra, and faces with two equivalent O(5)Sr2Ca2FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent Ca(1), one Fe(1), and one Fe(2) atom to form distorted OSr2Ca2Fe2 octahedra that share corners with two equivalent O(6)Ca4Fe2 octahedra, corners with two equivalent O(8)Sr2Ca2Co2 octahedra, corners with four equivalent O(3)SrCa3Co2 octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra, corners with six equivalent O(9)Sr2Ca2Co2 octahedra, edges with two equivalent O(8)Sr2Ca2Co2 octahedra, edges with two equivalent O(5)Sr2Ca2FeCo octahedra,  a faceface with one O(6)Ca4Fe2 octahedra,  a faceface with one O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(5)Sr2Ca2FeCo octahedra, faces with two equivalent O(1)SrCa3FeCo octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Ca(1), one Fe(2), and one Co(1) atom to form distorted OSr2Ca2FeCo octahedra that share corners with two equivalent O(9)Sr2Ca2Co2 octahedra, corners with four equivalent O(1)SrCa3FeCo octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra, corners with six equivalent O(8)Sr2Ca2Co2 octahedra, edges with two equivalent O(9)Sr2Ca2Co2 octahedra, edges with two equivalent O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(6)Ca4Fe2 octahedra,  a faceface with one O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(5)Sr2Ca2FeCo octahedra, faces with two equivalent O(3)SrCa3Co2 octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the sixth O site, O(6) is bonded to two equivalent Ca(1), two equivalent Ca(2), one Fe(1), and one Fe(2) atom to form distorted OCa4Fe2 octahedra that share corners with two equivalent O(8)Sr2Ca2Co2 octahedra, corners with two equivalent O(9)Sr2Ca2Co2 octahedra, corners with two equivalent O(4)Sr2Ca2Fe2 octahedra, corners with four equivalent O(3)SrCa3Co2 octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra,  a faceface with one O(6)Ca4Fe2 octahedra,  a faceface with one O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(5)Sr2Ca2FeCo octahedra, faces with two equivalent O(1)SrCa3FeCo octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Ca(1), two equivalent Ca(2), one Fe(2), and one Co(1) atom. In the eighth O site, O(8) is bonded to two equivalent Sr(1), two equivalent Ca(1), one Co(2), and one Co(3) atom to form distorted OSr2Ca2Co2 octahedra that share corners with two equivalent O(6)Ca4Fe2 octahedra, corners with two equivalent O(4)Sr2Ca2Fe2 octahedra, corners with four equivalent O(3)SrCa3Co2 octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra, corners with six equivalent O(5)Sr2Ca2FeCo octahedra, edges with two equivalent O(9)Sr2Ca2Co2 octahedra, edges with two equivalent O(4)Sr2Ca2Fe2 octahedra,  a faceface with one O(8)Sr2Ca2Co2 octahedra,  a faceface with one O(9)Sr2Ca2Co2 octahedra, faces with two equivalent O(1)SrCa3FeCo octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Ca(1), one Co(3), and one Co(4) atom to form distorted OSr2Ca2Co2 octahedra that share corners with two equivalent O(6)Ca4Fe2 octahedra, corners with two equivalent O(5)Sr2Ca2FeCo octahedra, corners with four equivalent O(1)SrCa3FeCo octahedra, corners with four equivalent O(2)SrCa3FeCo octahedra, corners with six equivalent O(4)Sr2Ca2Fe2 octahedra, edges with two equivalent O(8)Sr2Ca2Co2 octahedra, edges with two equivalent O(5)Sr2Ca2FeCo octahedra,  a faceface with one O(8)Sr2Ca2Co2 octahedra,  a faceface with one O(9)Sr2Ca2Co2 octahedra, faces with two equivalent O(3)SrCa3Co2 octahedra, and faces with two equivalent O(2)SrCa3FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the tenth O site, O(10) is bonded in a distorted linear geometry to two equivalent Ca(1), two equivalent Ca(2), one Co(2), and one Co(3) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to two equivalent Ca(1), two equivalent Ca(2), one Co(3), and one Co(4) atom. is represented by the CIF file [CIF]
data_Sr2Ca6Fe3Co5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.667
_cell_length_b   7.667
_cell_length_c   7.664
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.156
_symmetry_Int_Tables_number   1
_cell_volume   450.471
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.751  0.751  0.251  1.0
  Sr  Sr1  1  0.751  0.751  0.749  1.0
  Ca  Ca2  1  0.753  0.247  0.250  1.0
  Ca  Ca3  1  0.247  0.247  0.250  1.0
  Ca  Ca4  1  0.247  0.753  0.250  1.0
  Ca  Ca5  1  0.753  0.247  0.750  1.0
  Ca  Ca6  1  0.247  0.247  0.750  1.0
  Ca  Ca7  1  0.247  0.753  0.750  1.0
  Fe  Fe8  1  0.001  0.001  0.000  1.0
  Fe  Fe9  1  0.002  0.499  0.000  1.0
  Fe  Fe10  1  0.499  0.002  0.000  1.0
  Co  Co11  1  0.499  0.499  0.000  1.0
  Co  Co12  1  0.001  0.001  0.500  1.0
  Co  Co13  1  0.002  0.498  0.500  1.0
  Co  Co14  1  0.498  0.002  0.500  1.0
  Co  Co15  1  0.498  0.498  0.500  1.0
  O  O16  1  0.004  0.004  0.251  1.0
  O  O17  1  0.004  0.496  0.252  1.0
  O  O18  1  0.496  0.004  0.252  1.0
  O  O19  1  0.497  0.497  0.260  1.0
  O  O20  1  0.004  0.004  0.749  1.0
  O  O21  1  0.004  0.496  0.748  1.0
  O  O22  1  0.496  0.004  0.748  1.0
  O  O23  1  0.497  0.497  0.740  1.0
  O  O24  1  0.752  0.006  0.000  1.0
  O  O25  1  0.745  0.493  0.000  1.0
  O  O26  1  0.248  0.002  0.000  1.0
  O  O27  1  0.256  0.498  0.000  1.0
  O  O28  1  0.754  0.007  0.500  1.0
  O  O29  1  0.762  0.494  0.500  1.0
  O  O30  1  0.246  0.002  0.500  1.0
  O  O31  1  0.239  0.498  0.500  1.0
  O  O32  1  0.002  0.248  0.000  1.0
  O  O33  1  0.006  0.752  0.000  1.0
  O  O34  1  0.498  0.256  0.000  1.0
  O  O35  1  0.493  0.745  0.000  1.0
  O  O36  1  0.002  0.246  0.500  1.0
  O  O37  1  0.007  0.754  0.500  1.0
  O  O38  1  0.498  0.239  0.500  1.0
  O  O39  1  0.494  0.762  0.500  1.0
[/CIF]
.