The compound described by Ba11(Bi3O10)3 is Orthorhombic Perovskite-like structured and crystallizes in the triclinic P-1 space group. There are six inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(4), two equivalent O(2), and two equivalent O(9) atoms. In the second Ba site, Ba(2) is bonded in a 3-coordinate geometry to one O(1), one O(10), one O(3), one O(5), one O(6), one O(8), and two equivalent O(14) atoms. In the third Ba site, Ba(3) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(13), one O(15), one O(4), one O(5), one O(6), and two equivalent O(7) atoms. In the fourth Ba site, Ba(4) is bonded in a 9-coordinate geometry to one O(11), one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms. In the fifth Ba site, Ba(5) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(8), one O(9), two equivalent O(13), and two equivalent O(3) atoms. In the sixth Ba site, Ba(6) is bonded to two equivalent O(1), two equivalent O(11), and two equivalent O(6) atoms to form BaO6 octahedra that share corners with two equivalent Bi(1)O6 octahedra, corners with two equivalent Bi(2)O6 octahedra, and corners with two equivalent Bi(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-27°. There are five inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to one O(1), one O(12), one O(15), one O(4), one O(7), and one O(9) atom to form BiO6 octahedra that share  a cornercorner with one Ba(6)O6 octahedra, corners with two equivalent Bi(5)O6 octahedra, and corners with three equivalent Bi(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-23°. In the second Bi site, Bi(2) is bonded to two equivalent O(11), two equivalent O(5), and two equivalent O(8) atoms to form BiO6 octahedra that share corners with two equivalent Ba(6)O6 octahedra, corners with two equivalent Bi(4)O6 octahedra, and corners with two equivalent Bi(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-27°. In the third Bi site, Bi(3) is bonded to one O(10), one O(13), one O(14), one O(2), one O(3), and one O(6) atom to form BiO6 octahedra that share  a cornercorner with one Ba(6)O6 octahedra, corners with two equivalent Bi(4)O6 octahedra, and corners with three equivalent Bi(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-23°. In the fourth Bi site, Bi(4) is bonded to one O(10), one O(12), one O(15), one O(2), one O(5), and one O(7) atom to form corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles range from 18-23°. In the fifth Bi site, Bi(5) is bonded to one O(13), one O(14), one O(3), one O(4), one O(8), and one O(9) atom to form corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles range from 16-23°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(3), one Ba(5), one Ba(6), and one Bi(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Ba(4), two equivalent Ba(1), one Bi(3), and one Bi(4) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Ba(2), two equivalent Ba(5), one Bi(3), and one Bi(5) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Ba(1), one Ba(3), one Ba(4), one Bi(1), and one Bi(5) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(3), one Ba(4), one Bi(2), and one Bi(4) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(3), one Ba(4), one Ba(6), and one Bi(3) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Ba(4), two equivalent Ba(3), one Bi(1), and one Bi(4) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(4), one Ba(5), one Bi(2), and one Bi(5) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Ba(5), two equivalent Ba(1), one Bi(1), and one Bi(5) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Ba(1), one Ba(2), one Ba(5), one Bi(3), and one Bi(4) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Ba(3), one Ba(4), one Ba(5), one Ba(6), and one Bi(2) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Ba(5), two equivalent Ba(4), one Bi(1), and one Bi(4) atom. In the thirteenth O site, O(13) is bonded in a 6-coordinate geometry to one Ba(1), one Ba(3), two equivalent Ba(5), one Bi(3), and one Bi(5) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Ba(2), one Bi(3), and one Bi(5) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(3), one Bi(1), and one Bi(4) atom. is represented by the CIF card [CIF]
data_Ba11(Bi3O10)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.883
_cell_length_b   10.782
_cell_length_c   10.903
_cell_angle_alpha   81.087
_cell_angle_beta   113.718
_cell_angle_gamma   113.379
_symmetry_Int_Tables_number   1
_cell_volume   877.500
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.250  0.999  0.498  1.0
  Ba  Ba1  1  0.649  0.599  0.700  1.0
  Ba  Ba2  1  0.047  0.194  0.897  1.0
  Ba  Ba3  1  0.454  0.802  0.099  1.0
  Ba  Ba4  1  0.851  0.397  0.305  1.0
  Ba  Ba5  1  0.149  0.603  0.695  1.0
  Ba  Ba6  1  0.546  0.198  0.901  1.0
  Ba  Ba7  1  0.953  0.806  0.103  1.0
  Ba  Ba8  1  0.351  0.401  0.300  1.0
  Ba  Ba9  1  0.750  0.001  0.502  1.0
  Ba  Ba10  1  0.000  0.500  0.000  1.0
  Bi  Bi11  1  0.099  0.905  0.795  1.0
  Bi  Bi12  1  0.500  0.500  0.000  1.0
  Bi  Bi13  1  0.901  0.095  0.205  1.0
  Bi  Bi14  1  0.308  0.705  0.406  1.0
  Bi  Bi15  1  0.692  0.295  0.594  1.0
  Bi  Bi16  1  0.397  0.099  0.198  1.0
  Bi  Bi17  1  0.799  0.699  0.401  1.0
  Bi  Bi18  1  0.201  0.301  0.599  1.0
  Bi  Bi19  1  0.603  0.901  0.802  1.0
  O  O20  1  0.001  0.293  0.144  1.0
  O  O21  1  0.401  0.912  0.340  1.0
  O  O22  1  0.790  0.504  0.521  1.0
  O  O23  1  0.200  0.115  0.730  1.0
  O  O24  1  0.608  0.708  0.929  1.0
  O  O25  1  0.784  0.363  0.790  1.0
  O  O26  1  0.208  0.979  0.001  1.0
  O  O27  1  0.600  0.577  0.207  1.0
  O  O28  1  0.007  0.164  0.412  1.0
  O  O29  1  0.411  0.771  0.612  1.0
  O  O30  1  0.262  0.523  0.952  1.0
  O  O31  1  0.643  0.104  0.168  1.0
  O  O32  1  0.049  0.713  0.373  1.0
  O  O33  1  0.433  0.306  0.552  1.0
  O  O34  1  0.855  0.931  0.765  1.0
  O  O35  1  0.999  0.707  0.856  1.0
  O  O36  1  0.392  0.292  0.071  1.0
  O  O37  1  0.800  0.885  0.270  1.0
  O  O38  1  0.210  0.496  0.479  1.0
  O  O39  1  0.599  0.088  0.660  1.0
  O  O40  1  0.216  0.637  0.210  1.0
  O  O41  1  0.589  0.229  0.388  1.0
  O  O42  1  0.993  0.836  0.588  1.0
  O  O43  1  0.400  0.423  0.793  1.0
  O  O44  1  0.792  0.021  0.999  1.0
  O  O45  1  0.738  0.477  0.048  1.0
  O  O46  1  0.145  0.069  0.235  1.0
  O  O47  1  0.567  0.694  0.448  1.0
  O  O48  1  0.951  0.287  0.627  1.0
  O  O49  1  0.357  0.896  0.832  1.0
[/CIF]
.
The compound described by Ba11(Bi3O10)3 is Orthorhombic Perovskite-like structured and crystallizes in the triclinic P-1 space group. There are six inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(4), two equivalent O(2), and two equivalent O(9) atoms. In the second Ba site, Ba(2) is bonded in a 3-coordinate geometry to one O(1), one O(10), one O(3), one O(5), one O(6), one O(8), and two equivalent O(14) atoms. In the third Ba site, Ba(3) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(13), one O(15), one O(4), one O(5), one O(6), and two equivalent O(7) atoms. In the fourth Ba site, Ba(4) is bonded in a 9-coordinate geometry to one O(11), one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms. In the fifth Ba site, Ba(5) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(8), one O(9), two equivalent O(13), and two equivalent O(3) atoms. In the sixth Ba site, Ba(6) is bonded to two equivalent O(1), two equivalent O(11), and two equivalent O(6) atoms to form BaO6 octahedra that share corners with two equivalent Bi(1)O6 octahedra, corners with two equivalent Bi(2)O6 octahedra, and corners with two equivalent Bi(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-27°. There are five inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to one O(1), one O(12), one O(15), one O(4), one O(7), and one O(9) atom to form BiO6 octahedra that share  a cornercorner with one Ba(6)O6 octahedra, corners with two equivalent Bi(5)O6 octahedra, and corners with three equivalent Bi(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-23°. In the second Bi site, Bi(2) is bonded to two equivalent O(11), two equivalent O(5), and two equivalent O(8) atoms to form BiO6 octahedra that share corners with two equivalent Ba(6)O6 octahedra, corners with two equivalent Bi(4)O6 octahedra, and corners with two equivalent Bi(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-27°. In the third Bi site, Bi(3) is bonded to one O(10), one O(13), one O(14), one O(2), one O(3), and one O(6) atom to form BiO6 octahedra that share  a cornercorner with one Ba(6)O6 octahedra, corners with two equivalent Bi(4)O6 octahedra, and corners with three equivalent Bi(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-23°. In the fourth Bi site, Bi(4) is bonded to one O(10), one O(12), one O(15), one O(2), one O(5), and one O(7) atom to form corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles range from 18-23°. In the fifth Bi site, Bi(5) is bonded to one O(13), one O(14), one O(3), one O(4), one O(8), and one O(9) atom to form corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles range from 16-23°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(3), one Ba(5), one Ba(6), and one Bi(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Ba(4), two equivalent Ba(1), one Bi(3), and one Bi(4) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Ba(2), two equivalent Ba(5), one Bi(3), and one Bi(5) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Ba(1), one Ba(3), one Ba(4), one Bi(1), and one Bi(5) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(3), one Ba(4), one Bi(2), and one Bi(4) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(3), one Ba(4), one Ba(6), and one Bi(3) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Ba(4), two equivalent Ba(3), one Bi(1), and one Bi(4) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(4), one Ba(5), one Bi(2), and one Bi(5) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Ba(5), two equivalent Ba(1), one Bi(1), and one Bi(5) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Ba(1), one Ba(2), one Ba(5), one Bi(3), and one Bi(4) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Ba(3), one Ba(4), one Ba(5), one Ba(6), and one Bi(2) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Ba(5), two equivalent Ba(4), one Bi(1), and one Bi(4) atom. In the thirteenth O site, O(13) is bonded in a 6-coordinate geometry to one Ba(1), one Ba(3), two equivalent Ba(5), one Bi(3), and one Bi(5) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Ba(2), one Bi(3), and one Bi(5) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(3), one Bi(1), and one Bi(4) atom. is represented by the CIF card [CIF]
data_Ba11(Bi3O10)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.883
_cell_length_b   10.782
_cell_length_c   10.903
_cell_angle_alpha   81.087
_cell_angle_beta   113.718
_cell_angle_gamma   113.379
_symmetry_Int_Tables_number   1
_cell_volume   877.500
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.250  0.999  0.498  1.0
  Ba  Ba1  1  0.649  0.599  0.700  1.0
  Ba  Ba2  1  0.047  0.194  0.897  1.0
  Ba  Ba3  1  0.454  0.802  0.099  1.0
  Ba  Ba4  1  0.851  0.397  0.305  1.0
  Ba  Ba5  1  0.149  0.603  0.695  1.0
  Ba  Ba6  1  0.546  0.198  0.901  1.0
  Ba  Ba7  1  0.953  0.806  0.103  1.0
  Ba  Ba8  1  0.351  0.401  0.300  1.0
  Ba  Ba9  1  0.750  0.001  0.502  1.0
  Ba  Ba10  1  0.000  0.500  0.000  1.0
  Bi  Bi11  1  0.099  0.905  0.795  1.0
  Bi  Bi12  1  0.500  0.500  0.000  1.0
  Bi  Bi13  1  0.901  0.095  0.205  1.0
  Bi  Bi14  1  0.308  0.705  0.406  1.0
  Bi  Bi15  1  0.692  0.295  0.594  1.0
  Bi  Bi16  1  0.397  0.099  0.198  1.0
  Bi  Bi17  1  0.799  0.699  0.401  1.0
  Bi  Bi18  1  0.201  0.301  0.599  1.0
  Bi  Bi19  1  0.603  0.901  0.802  1.0
  O  O20  1  0.001  0.293  0.144  1.0
  O  O21  1  0.401  0.912  0.340  1.0
  O  O22  1  0.790  0.504  0.521  1.0
  O  O23  1  0.200  0.115  0.730  1.0
  O  O24  1  0.608  0.708  0.929  1.0
  O  O25  1  0.784  0.363  0.790  1.0
  O  O26  1  0.208  0.979  0.001  1.0
  O  O27  1  0.600  0.577  0.207  1.0
  O  O28  1  0.007  0.164  0.412  1.0
  O  O29  1  0.411  0.771  0.612  1.0
  O  O30  1  0.262  0.523  0.952  1.0
  O  O31  1  0.643  0.104  0.168  1.0
  O  O32  1  0.049  0.713  0.373  1.0
  O  O33  1  0.433  0.306  0.552  1.0
  O  O34  1  0.855  0.931  0.765  1.0
  O  O35  1  0.999  0.707  0.856  1.0
  O  O36  1  0.392  0.292  0.071  1.0
  O  O37  1  0.800  0.885  0.270  1.0
  O  O38  1  0.210  0.496  0.479  1.0
  O  O39  1  0.599  0.088  0.660  1.0
  O  O40  1  0.216  0.637  0.210  1.0
  O  O41  1  0.589  0.229  0.388  1.0
  O  O42  1  0.993  0.836  0.588  1.0
  O  O43  1  0.400  0.423  0.793  1.0
  O  O44  1  0.792  0.021  0.999  1.0
  O  O45  1  0.738  0.477  0.048  1.0
  O  O46  1  0.145  0.069  0.235  1.0
  O  O47  1  0.567  0.694  0.448  1.0
  O  O48  1  0.951  0.287  0.627  1.0
  O  O49  1  0.357  0.896  0.832  1.0
[/CIF]
.