The crystal structure described by (LiSb2P3O10)2(Li2SbPO5)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two water atoms, one Li2SbPO5 cluster, and two LiSb2P3O10 clusters. In the Li2SbPO5 cluster, there are two inequivalent Li sites. In the first Li site, Li(2) is bonded in a 2-coordinate geometry to one Li(3) and one O(11) atom. In the second Li site, Li(3) is bonded in a distorted single-bond geometry to one Li(2), one Sb(1), one O(11), and one O(14) atom. Sb(1) is bonded in a 5-coordinate geometry to one Li(3), one P(4), one O(14), one O(3), and one O(7) atom. P(4) is bonded in a 4-coordinate geometry to one Sb(1), one O(11), one O(14), and one O(9) atom. There are five inequivalent O sites. In the first O site, O(14) is bonded in a distorted single-bond geometry to one Li(3), one Sb(1), one P(4), and one O(3) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to one Sb(1), one O(14), and one O(7) atom. In the third O site, O(7) is bonded in a 3-coordinate geometry to one Sb(1), one O(3), and one O(9) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one P(4) and one O(7) atom. In the fifth O site, O(11) is bonded in a distorted L-shaped geometry to one Li(2), one Li(3), and one P(4) atom. In each LiSb2P3O10 cluster, Li(1) is bonded in a 2-coordinate geometry to one O(1) and one O(12) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(2) is bonded in a distorted single-bond geometry to one O(15), one O(6), and one O(8) atom. In the second Sb site, Sb(3) is bonded in a 3-coordinate geometry to one O(10), one O(5), and one O(8) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to one O(13), one O(4), and one O(5) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one O(12) and one O(6) atom. In the third P site, P(3) is bonded in a distorted L-shaped geometry to one O(10) and one O(16) atom. There are ten inequivalent O sites. In the first O site, O(13) is bonded in a distorted single-bond geometry to one P(1) atom. In the second O site, O(15) is bonded in a single-bond geometry to one Sb(2) atom. In the third O site, O(16) is bonded in a single-bond geometry to one P(3) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one Li(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one P(1) atom. In the sixth O site, O(5) is bonded in a water-like geometry to one Sb(3) and one P(1) atom. In the seventh O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sb(2) and one P(2) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Sb(2) and one Sb(3) atom. In the ninth O site, O(10) is bonded in a water-like geometry to one Sb(3) and one P(3) atom. In the tenth O site, O(12) is bonded in a bent 120 degrees geometry to one Li(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3Sb3(PO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.118
_cell_length_b   9.659
_cell_length_c   10.485
_cell_angle_alpha   108.973
_cell_angle_beta   103.064
_cell_angle_gamma   111.241
_symmetry_Int_Tables_number   1
_cell_volume   749.447
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.786  0.203  0.236  1.0
  Li  Li1  1  0.330  0.285  0.149  1.0
  Li  Li2  1  0.598  0.642  0.708  1.0
  Li  Li3  1  0.402  0.358  0.292  1.0
  Li  Li4  1  0.670  0.715  0.851  1.0
  Li  Li5  1  0.214  0.797  0.764  1.0
  Sb  Sb6  1  0.346  0.588  0.446  1.0
  Sb  Sb7  1  0.027  0.272  0.847  1.0
  Sb  Sb8  1  0.735  0.320  0.750  1.0
  Sb  Sb9  1  0.265  0.680  0.250  1.0
  Sb  Sb10  1  0.973  0.728  0.153  1.0
  Sb  Sb11  1  0.654  0.412  0.554  1.0
  P  P12  1  0.151  0.867  0.415  1.0
  P  P13  1  0.907  0.098  0.078  1.0
  P  P14  1  0.658  0.328  0.941  1.0
  P  P15  1  0.564  0.745  0.507  1.0
  P  P16  1  0.436  0.255  0.493  1.0
  P  P17  1  0.342  0.672  0.059  1.0
  P  P18  1  0.093  0.902  0.922  1.0
  P  P19  1  0.849  0.133  0.585  1.0
  O  O20  1  0.666  0.923  0.120  1.0
  O  O21  1  0.422  0.021  0.083  1.0
  O  O22  1  0.277  0.530  0.588  1.0
  O  O23  1  0.063  0.721  0.397  1.0
  O  O24  1  0.338  0.881  0.402  1.0
  O  O25  1  0.911  0.928  0.151  1.0
  O  O26  1  0.868  0.669  0.577  1.0
  O  O27  1  0.934  0.457  0.864  1.0
  O  O28  1  0.717  0.707  0.455  1.0
  O  O29  1  0.664  0.389  0.842  1.0
  O  O30  1  0.282  0.130  0.301  1.0
  O  O31  1  0.880  0.200  0.116  1.0
  O  O32  1  0.739  0.022  0.379  1.0
  O  O33  1  0.541  0.357  0.361  1.0
  O  O34  1  0.165  0.321  0.906  1.0
  O  O35  1  0.404  0.569  0.028  1.0
  O  O36  1  0.596  0.431  0.972  1.0
  O  O37  1  0.835  0.679  0.094  1.0
  O  O38  1  0.459  0.643  0.639  1.0
  O  O39  1  0.261  0.978  0.621  1.0
  O  O40  1  0.120  0.800  0.884  1.0
  O  O41  1  0.718  0.870  0.699  1.0
  O  O42  1  0.336  0.611  0.158  1.0
  O  O43  1  0.283  0.293  0.545  1.0
  O  O44  1  0.066  0.543  0.136  1.0
  O  O45  1  0.132  0.331  0.423  1.0
  O  O46  1  0.089  0.072  0.849  1.0
  O  O47  1  0.662  0.119  0.598  1.0
  O  O48  1  0.937  0.279  0.603  1.0
  O  O49  1  0.723  0.470  0.412  1.0
  O  O50  1  0.578  0.979  0.917  1.0
  O  O51  1  0.334  0.077  0.880  1.0
[/CIF]
.
The crystal structure described by (LiSb2P3O10)2(Li2SbPO5)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two water atoms, one Li2SbPO5 cluster, and two LiSb2P3O10 clusters. In the Li2SbPO5 cluster, there are two inequivalent Li sites. In the first Li site, Li(2) is bonded in a 2-coordinate geometry to one Li(3) and one O(11) atom. In the second Li site, Li(3) is bonded in a distorted single-bond geometry to one Li(2), one Sb(1), one O(11), and one O(14) atom. Sb(1) is bonded in a 5-coordinate geometry to one Li(3), one P(4), one O(14), one O(3), and one O(7) atom. P(4) is bonded in a 4-coordinate geometry to one Sb(1), one O(11), one O(14), and one O(9) atom. There are five inequivalent O sites. In the first O site, O(14) is bonded in a distorted single-bond geometry to one Li(3), one Sb(1), one P(4), and one O(3) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to one Sb(1), one O(14), and one O(7) atom. In the third O site, O(7) is bonded in a 3-coordinate geometry to one Sb(1), one O(3), and one O(9) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one P(4) and one O(7) atom. In the fifth O site, O(11) is bonded in a distorted L-shaped geometry to one Li(2), one Li(3), and one P(4) atom. In each LiSb2P3O10 cluster, Li(1) is bonded in a 2-coordinate geometry to one O(1) and one O(12) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(2) is bonded in a distorted single-bond geometry to one O(15), one O(6), and one O(8) atom. In the second Sb site, Sb(3) is bonded in a 3-coordinate geometry to one O(10), one O(5), and one O(8) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to one O(13), one O(4), and one O(5) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one O(12) and one O(6) atom. In the third P site, P(3) is bonded in a distorted L-shaped geometry to one O(10) and one O(16) atom. There are ten inequivalent O sites. In the first O site, O(13) is bonded in a distorted single-bond geometry to one P(1) atom. In the second O site, O(15) is bonded in a single-bond geometry to one Sb(2) atom. In the third O site, O(16) is bonded in a single-bond geometry to one P(3) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one Li(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one P(1) atom. In the sixth O site, O(5) is bonded in a water-like geometry to one Sb(3) and one P(1) atom. In the seventh O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sb(2) and one P(2) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Sb(2) and one Sb(3) atom. In the ninth O site, O(10) is bonded in a water-like geometry to one Sb(3) and one P(3) atom. In the tenth O site, O(12) is bonded in a bent 120 degrees geometry to one Li(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3Sb3(PO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.118
_cell_length_b   9.659
_cell_length_c   10.485
_cell_angle_alpha   108.973
_cell_angle_beta   103.064
_cell_angle_gamma   111.241
_symmetry_Int_Tables_number   1
_cell_volume   749.447
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.786  0.203  0.236  1.0
  Li  Li1  1  0.330  0.285  0.149  1.0
  Li  Li2  1  0.598  0.642  0.708  1.0
  Li  Li3  1  0.402  0.358  0.292  1.0
  Li  Li4  1  0.670  0.715  0.851  1.0
  Li  Li5  1  0.214  0.797  0.764  1.0
  Sb  Sb6  1  0.346  0.588  0.446  1.0
  Sb  Sb7  1  0.027  0.272  0.847  1.0
  Sb  Sb8  1  0.735  0.320  0.750  1.0
  Sb  Sb9  1  0.265  0.680  0.250  1.0
  Sb  Sb10  1  0.973  0.728  0.153  1.0
  Sb  Sb11  1  0.654  0.412  0.554  1.0
  P  P12  1  0.151  0.867  0.415  1.0
  P  P13  1  0.907  0.098  0.078  1.0
  P  P14  1  0.658  0.328  0.941  1.0
  P  P15  1  0.564  0.745  0.507  1.0
  P  P16  1  0.436  0.255  0.493  1.0
  P  P17  1  0.342  0.672  0.059  1.0
  P  P18  1  0.093  0.902  0.922  1.0
  P  P19  1  0.849  0.133  0.585  1.0
  O  O20  1  0.666  0.923  0.120  1.0
  O  O21  1  0.422  0.021  0.083  1.0
  O  O22  1  0.277  0.530  0.588  1.0
  O  O23  1  0.063  0.721  0.397  1.0
  O  O24  1  0.338  0.881  0.402  1.0
  O  O25  1  0.911  0.928  0.151  1.0
  O  O26  1  0.868  0.669  0.577  1.0
  O  O27  1  0.934  0.457  0.864  1.0
  O  O28  1  0.717  0.707  0.455  1.0
  O  O29  1  0.664  0.389  0.842  1.0
  O  O30  1  0.282  0.130  0.301  1.0
  O  O31  1  0.880  0.200  0.116  1.0
  O  O32  1  0.739  0.022  0.379  1.0
  O  O33  1  0.541  0.357  0.361  1.0
  O  O34  1  0.165  0.321  0.906  1.0
  O  O35  1  0.404  0.569  0.028  1.0
  O  O36  1  0.596  0.431  0.972  1.0
  O  O37  1  0.835  0.679  0.094  1.0
  O  O38  1  0.459  0.643  0.639  1.0
  O  O39  1  0.261  0.978  0.621  1.0
  O  O40  1  0.120  0.800  0.884  1.0
  O  O41  1  0.718  0.870  0.699  1.0
  O  O42  1  0.336  0.611  0.158  1.0
  O  O43  1  0.283  0.293  0.545  1.0
  O  O44  1  0.066  0.543  0.136  1.0
  O  O45  1  0.132  0.331  0.423  1.0
  O  O46  1  0.089  0.072  0.849  1.0
  O  O47  1  0.662  0.119  0.598  1.0
  O  O48  1  0.937  0.279  0.603  1.0
  O  O49  1  0.723  0.470  0.412  1.0
  O  O50  1  0.578  0.979  0.917  1.0
  O  O51  1  0.334  0.077  0.880  1.0
[/CIF]
.