The material described by Rb2LiPu(OCl2)2 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 4-coordinate geometry to one Cl(2), one Cl(3), one Cl(4), and two equivalent Cl(1) atoms. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to one O(1), one O(2), two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Li(1) is bonded in a 4-coordinate geometry to one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. Pu(1) is bonded in a distorted linear geometry to one O(1), one O(2), one Cl(1), and one Cl(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2) and one Pu(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Rb(2), one Li(1), and one Pu(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to two equivalent Rb(1), two equivalent Rb(2), one Li(1), and one Pu(1) atom. In the second Cl site, Cl(2) is bonded in a 5-coordinate geometry to one Rb(1), two equivalent Rb(2), one Li(1), and one Pu(1) atom. In the third Cl site, Cl(3) is bonded in a 1-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Li(1) atom. In the fourth Cl site, Cl(4) is bonded in a 1-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Li(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2LiPu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.124
_cell_length_b   7.151
_cell_length_c   6.981
_cell_angle_alpha   63.947
_cell_angle_beta   80.111
_cell_angle_gamma   81.444
_symmetry_Int_Tables_number   1
_cell_volume   269.628
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.828  0.874  0.887  1.0
  Rb  Rb1  1  0.165  0.183  0.160  1.0
  Li  Li2  1  0.410  0.760  0.727  1.0
  Pu  Pu3  1  0.508  0.485  0.490  1.0
  Cl  Cl4  1  0.696  0.851  0.393  1.0
  Cl  Cl5  1  0.695  0.357  0.863  1.0
  Cl  Cl6  1  0.289  0.118  0.648  1.0
  Cl  Cl7  1  0.305  0.661  0.108  1.0
  O  O8  1  0.745  0.379  0.364  1.0
  O  O9  1  0.275  0.600  0.620  1.0
[/CIF]
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The material described by Rb2LiPu(OCl2)2 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 4-coordinate geometry to one Cl(2), one Cl(3), one Cl(4), and two equivalent Cl(1) atoms. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to one O(1), one O(2), two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Li(1) is bonded in a 4-coordinate geometry to one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. Pu(1) is bonded in a distorted linear geometry to one O(1), one O(2), one Cl(1), and one Cl(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2) and one Pu(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Rb(2), one Li(1), and one Pu(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to two equivalent Rb(1), two equivalent Rb(2), one Li(1), and one Pu(1) atom. In the second Cl site, Cl(2) is bonded in a 5-coordinate geometry to one Rb(1), two equivalent Rb(2), one Li(1), and one Pu(1) atom. In the third Cl site, Cl(3) is bonded in a 1-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Li(1) atom. In the fourth Cl site, Cl(4) is bonded in a 1-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Li(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2LiPu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.124
_cell_length_b   7.151
_cell_length_c   6.981
_cell_angle_alpha   63.947
_cell_angle_beta   80.111
_cell_angle_gamma   81.444
_symmetry_Int_Tables_number   1
_cell_volume   269.628
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.828  0.874  0.887  1.0
  Rb  Rb1  1  0.165  0.183  0.160  1.0
  Li  Li2  1  0.410  0.760  0.727  1.0
  Pu  Pu3  1  0.508  0.485  0.490  1.0
  Cl  Cl4  1  0.696  0.851  0.393  1.0
  Cl  Cl5  1  0.695  0.357  0.863  1.0
  Cl  Cl6  1  0.289  0.118  0.648  1.0
  Cl  Cl7  1  0.305  0.661  0.108  1.0
  O  O8  1  0.745  0.379  0.364  1.0
  O  O9  1  0.275  0.600  0.620  1.0
[/CIF]
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