The compound described by ZnH4(O3Cl)2 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(1), one H(2), and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. Cl(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. is represented by the CIF card [CIF]
data_ZnH4(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.088
_cell_length_b   6.439
_cell_length_c   8.667
_cell_angle_alpha   47.920
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   293.590
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.000  0.500  1.0
  Zn  Zn1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.932  0.202  0.195  1.0
  H  H3  1  0.568  0.202  0.695  1.0
  H  H4  1  0.068  0.798  0.805  1.0
  H  H5  1  0.432  0.798  0.305  1.0
  H  H6  1  0.652  0.756  0.356  1.0
  H  H7  1  0.848  0.756  0.856  1.0
  H  H8  1  0.348  0.244  0.644  1.0
  H  H9  1  0.152  0.244  0.144  1.0
  Cl  Cl10  1  0.620  0.354  0.919  1.0
  Cl  Cl11  1  0.880  0.354  0.419  1.0
  Cl  Cl12  1  0.380  0.646  0.081  1.0
  Cl  Cl13  1  0.120  0.646  0.581  1.0
  O  O14  1  0.733  0.217  0.848  1.0
  O  O15  1  0.767  0.217  0.348  1.0
  O  O16  1  0.267  0.783  0.152  1.0
  O  O17  1  0.233  0.783  0.652  1.0
  O  O18  1  0.662  0.680  0.776  1.0
  O  O19  1  0.838  0.680  0.276  1.0
  O  O20  1  0.338  0.320  0.224  1.0
  O  O21  1  0.162  0.320  0.724  1.0
  O  O22  1  0.531  0.809  0.380  1.0
  O  O23  1  0.969  0.809  0.880  1.0
  O  O24  1  0.469  0.191  0.620  1.0
  O  O25  1  0.031  0.191  0.120  1.0
[/CIF]
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The compound described by ZnH4(O3Cl)2 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(1), one H(2), and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. Cl(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. is represented by the CIF card [CIF]
data_ZnH4(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.088
_cell_length_b   6.439
_cell_length_c   8.667
_cell_angle_alpha   47.920
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   293.590
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.000  0.500  1.0
  Zn  Zn1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.932  0.202  0.195  1.0
  H  H3  1  0.568  0.202  0.695  1.0
  H  H4  1  0.068  0.798  0.805  1.0
  H  H5  1  0.432  0.798  0.305  1.0
  H  H6  1  0.652  0.756  0.356  1.0
  H  H7  1  0.848  0.756  0.856  1.0
  H  H8  1  0.348  0.244  0.644  1.0
  H  H9  1  0.152  0.244  0.144  1.0
  Cl  Cl10  1  0.620  0.354  0.919  1.0
  Cl  Cl11  1  0.880  0.354  0.419  1.0
  Cl  Cl12  1  0.380  0.646  0.081  1.0
  Cl  Cl13  1  0.120  0.646  0.581  1.0
  O  O14  1  0.733  0.217  0.848  1.0
  O  O15  1  0.767  0.217  0.348  1.0
  O  O16  1  0.267  0.783  0.152  1.0
  O  O17  1  0.233  0.783  0.652  1.0
  O  O18  1  0.662  0.680  0.776  1.0
  O  O19  1  0.838  0.680  0.276  1.0
  O  O20  1  0.338  0.320  0.224  1.0
  O  O21  1  0.162  0.320  0.724  1.0
  O  O22  1  0.531  0.809  0.380  1.0
  O  O23  1  0.969  0.809  0.880  1.0
  O  O24  1  0.469  0.191  0.620  1.0
  O  O25  1  0.031  0.191  0.120  1.0
[/CIF]
.