The structure described by K5Na3TaNb7O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent K sites. In the first K site, K(1) is bonded to one O(13), one O(9), two equivalent O(1), two equivalent O(11), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form KO12 cuboctahedra that share corners with four equivalent K(3)O12 cuboctahedra, corners with eight equivalent Na(2)O12 cuboctahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with four equivalent K(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. In the second K site, K(2) is bonded to one O(1), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(11) atoms to form KO12 cuboctahedra that share corners with four equivalent K(2)O12 cuboctahedra, corners with four equivalent K(4)O12 cuboctahedra, corners with four equivalent Na(1)O12 cuboctahedra, faces with two equivalent K(1)O12 cuboctahedra, faces with two equivalent K(3)O12 cuboctahedra, faces with two equivalent Na(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. In the third K site, K(3) is bonded to one O(13), one O(9), two equivalent O(11), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form KO12 cuboctahedra that share corners with four equivalent K(1)O12 cuboctahedra, corners with eight equivalent Na(2)O12 cuboctahedra, faces with two equivalent K(4)O12 cuboctahedra, faces with four equivalent K(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. In the fourth K site, K(4) is bonded to one O(10), one O(14), two equivalent O(12), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form KO12 cuboctahedra that share corners with four equivalent Na(1)O12 cuboctahedra, corners with eight equivalent K(2)O12 cuboctahedra, faces with two equivalent K(3)O12 cuboctahedra, faces with four equivalent Na(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(10), one O(14), two equivalent O(1), two equivalent O(12), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form NaO12 cuboctahedra that share corners with four equivalent K(4)O12 cuboctahedra, corners with eight equivalent K(2)O12 cuboctahedra, faces with two equivalent K(1)O12 cuboctahedra, faces with four equivalent Na(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. In the second Na site, Na(2) is bonded to one O(1), one O(10), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms to form NaO12 cuboctahedra that share corners with four equivalent K(1)O12 cuboctahedra, corners with four equivalent K(3)O12 cuboctahedra, corners with four equivalent Na(2)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, faces with two equivalent K(4)O12 cuboctahedra, faces with two equivalent Na(1)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. Ta(1) is bonded to one O(10), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form TaO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra, corners with four equivalent Nb(2)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are five inequivalent Nb sites. In the first Nb site, Nb(1) is bonded to one O(10), one O(9), two equivalent O(2), and two equivalent O(6) atoms to form NbO6 octahedra that share corners with two equivalent Ta(1)O6 octahedra, corners with four equivalent Nb(3)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Nb site, Nb(2) is bonded to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(7) atom to form NbO6 octahedra that share corners with two equivalent Ta(1)O6 octahedra, corners with two equivalent Nb(3)O6 octahedra, corners with two equivalent Nb(4)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third Nb site, Nb(3) is bonded to one O(11), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form NbO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra, corners with two equivalent Nb(2)O6 octahedra, corners with two equivalent Nb(5)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the fourth Nb site, Nb(4) is bonded to one O(13), one O(14), two equivalent O(3), and two equivalent O(7) atoms to form NbO6 octahedra that share corners with two equivalent Nb(5)O6 octahedra, corners with four equivalent Nb(2)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the fifth Nb site, Nb(5) is bonded to one O(13), one O(14), two equivalent O(4), and two equivalent O(8) atoms to form NbO6 octahedra that share corners with two equivalent Nb(4)O6 octahedra, corners with four equivalent Nb(3)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one K(1), one K(2), one Na(1), one Na(2), one Ta(1), and one Nb(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one K(1), one K(2), one Na(1), one Na(2), one Nb(1), and one Nb(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one K(1), one K(2), one Na(1), one Na(2), one Nb(2), and one Nb(4) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one K(1), one K(2), one Na(1), one Na(2), one Nb(3), and one Nb(5) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one K(2), one K(3), one K(4), one Na(2), one Ta(1), and one Nb(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one K(2), one K(3), one K(4), one Na(2), one Nb(1), and one Nb(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one K(2), one K(3), one K(4), one Na(2), one Nb(2), and one Nb(4) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one K(2), one K(3), one K(4), one Na(2), one Nb(3), and one Nb(5) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one K(1), one K(3), two equivalent K(2), one Ta(1), and one Nb(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one K(4), one Na(1), two equivalent Na(2), one Ta(1), and one Nb(1) atom. In the eleventh O site, O(11) is bonded to one K(1), one K(3), two equivalent K(2), one Nb(2), and one Nb(3) atom to form a mixture of distorted corner and edge-sharing OK4Nb2 octahedra. The corner-sharing octahedra are not tilted. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one K(4), one Na(1), two equivalent Na(2), one Nb(2), and one Nb(3) atom. In the thirteenth O site, O(13) is bonded to one K(1), one K(3), two equivalent K(2), one Nb(4), and one Nb(5) atom to form distorted edge-sharing OK4Nb2 octahedra. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one K(4), one Na(1), two equivalent Na(2), one Nb(4), and one Nb(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K5Na3TaNb7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.078
_cell_length_b   8.078
_cell_length_c   8.077
_cell_angle_alpha   89.998
_cell_angle_beta   89.998
_cell_angle_gamma   89.998
_symmetry_Int_Tables_number   1
_cell_volume   526.964
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.750  0.750  1.0
  K  K1  1  0.750  0.250  0.750  1.0
  K  K2  1  0.250  0.750  0.750  1.0
  K  K3  1  0.250  0.250  0.750  1.0
  K  K4  1  0.250  0.250  0.250  1.0
  Na  Na5  1  0.750  0.750  0.250  1.0
  Na  Na6  1  0.750  0.250  0.250  1.0
  Na  Na7  1  0.250  0.750  0.250  1.0
  Ta  Ta8  1  1.000  1.000  0.001  1.0
  Nb  Nb9  1  1.000  1.000  0.499  1.0
  Nb  Nb10  1  1.000  0.500  0.001  1.0
  Nb  Nb11  1  1.000  0.500  0.499  1.0
  Nb  Nb12  1  0.500  1.000  0.001  1.0
  Nb  Nb13  1  0.500  1.000  0.499  1.0
  Nb  Nb14  1  0.500  0.500  0.001  1.0
  Nb  Nb15  1  0.500  0.500  0.499  1.0
  O  O16  1  0.751  1.000  0.002  1.0
  O  O17  1  0.750  1.000  0.498  1.0
  O  O18  1  0.750  0.500  0.002  1.0
  O  O19  1  0.750  0.500  0.498  1.0
  O  O20  1  0.249  0.999  0.001  1.0
  O  O21  1  0.250  0.999  0.499  1.0
  O  O22  1  0.250  0.501  0.001  1.0
  O  O23  1  0.250  0.501  0.499  1.0
  O  O24  1  1.000  0.751  0.002  1.0
  O  O25  1  1.000  0.750  0.498  1.0
  O  O26  1  0.999  0.249  0.001  1.0
  O  O27  1  0.999  0.250  0.499  1.0
  O  O28  1  0.500  0.750  0.002  1.0
  O  O29  1  0.500  0.750  0.498  1.0
  O  O30  1  0.501  0.250  0.001  1.0
  O  O31  1  0.501  0.250  0.499  1.0
  O  O32  1  1.000  1.000  0.751  1.0
  O  O33  1  0.999  0.999  0.249  1.0
  O  O34  1  1.000  0.500  0.750  1.0
  O  O35  1  0.999  0.501  0.250  1.0
  O  O36  1  0.500  1.000  0.750  1.0
  O  O37  1  0.501  0.999  0.250  1.0
  O  O38  1  0.500  0.500  0.750  1.0
  O  O39  1  0.501  0.501  0.250  1.0
[/CIF]
.
The structure described by K5Na3TaNb7O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent K sites. In the first K site, K(1) is bonded to one O(13), one O(9), two equivalent O(1), two equivalent O(11), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form KO12 cuboctahedra that share corners with four equivalent K(3)O12 cuboctahedra, corners with eight equivalent Na(2)O12 cuboctahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with four equivalent K(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. In the second K site, K(2) is bonded to one O(1), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(11) atoms to form KO12 cuboctahedra that share corners with four equivalent K(2)O12 cuboctahedra, corners with four equivalent K(4)O12 cuboctahedra, corners with four equivalent Na(1)O12 cuboctahedra, faces with two equivalent K(1)O12 cuboctahedra, faces with two equivalent K(3)O12 cuboctahedra, faces with two equivalent Na(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. In the third K site, K(3) is bonded to one O(13), one O(9), two equivalent O(11), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form KO12 cuboctahedra that share corners with four equivalent K(1)O12 cuboctahedra, corners with eight equivalent Na(2)O12 cuboctahedra, faces with two equivalent K(4)O12 cuboctahedra, faces with four equivalent K(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. In the fourth K site, K(4) is bonded to one O(10), one O(14), two equivalent O(12), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form KO12 cuboctahedra that share corners with four equivalent Na(1)O12 cuboctahedra, corners with eight equivalent K(2)O12 cuboctahedra, faces with two equivalent K(3)O12 cuboctahedra, faces with four equivalent Na(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(10), one O(14), two equivalent O(1), two equivalent O(12), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form NaO12 cuboctahedra that share corners with four equivalent K(4)O12 cuboctahedra, corners with eight equivalent K(2)O12 cuboctahedra, faces with two equivalent K(1)O12 cuboctahedra, faces with four equivalent Na(2)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. In the second Na site, Na(2) is bonded to one O(1), one O(10), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms to form NaO12 cuboctahedra that share corners with four equivalent K(1)O12 cuboctahedra, corners with four equivalent K(3)O12 cuboctahedra, corners with four equivalent Na(2)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, faces with two equivalent K(4)O12 cuboctahedra, faces with two equivalent Na(1)O12 cuboctahedra,  a faceface with one Ta(1)O6 octahedra,  a faceface with one Nb(1)O6 octahedra,  a faceface with one Nb(4)O6 octahedra,  a faceface with one Nb(5)O6 octahedra, faces with two equivalent Nb(2)O6 octahedra, and faces with two equivalent Nb(3)O6 octahedra. Ta(1) is bonded to one O(10), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form TaO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra, corners with four equivalent Nb(2)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are five inequivalent Nb sites. In the first Nb site, Nb(1) is bonded to one O(10), one O(9), two equivalent O(2), and two equivalent O(6) atoms to form NbO6 octahedra that share corners with two equivalent Ta(1)O6 octahedra, corners with four equivalent Nb(3)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Nb site, Nb(2) is bonded to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(7) atom to form NbO6 octahedra that share corners with two equivalent Ta(1)O6 octahedra, corners with two equivalent Nb(3)O6 octahedra, corners with two equivalent Nb(4)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third Nb site, Nb(3) is bonded to one O(11), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form NbO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra, corners with two equivalent Nb(2)O6 octahedra, corners with two equivalent Nb(5)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the fourth Nb site, Nb(4) is bonded to one O(13), one O(14), two equivalent O(3), and two equivalent O(7) atoms to form NbO6 octahedra that share corners with two equivalent Nb(5)O6 octahedra, corners with four equivalent Nb(2)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the fifth Nb site, Nb(5) is bonded to one O(13), one O(14), two equivalent O(4), and two equivalent O(8) atoms to form NbO6 octahedra that share corners with two equivalent Nb(4)O6 octahedra, corners with four equivalent Nb(3)O6 octahedra,  a faceface with one K(1)O12 cuboctahedra,  a faceface with one K(3)O12 cuboctahedra,  a faceface with one K(4)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with two equivalent K(2)O12 cuboctahedra, and faces with two equivalent Na(2)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one K(1), one K(2), one Na(1), one Na(2), one Ta(1), and one Nb(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one K(1), one K(2), one Na(1), one Na(2), one Nb(1), and one Nb(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one K(1), one K(2), one Na(1), one Na(2), one Nb(2), and one Nb(4) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one K(1), one K(2), one Na(1), one Na(2), one Nb(3), and one Nb(5) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one K(2), one K(3), one K(4), one Na(2), one Ta(1), and one Nb(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one K(2), one K(3), one K(4), one Na(2), one Nb(1), and one Nb(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one K(2), one K(3), one K(4), one Na(2), one Nb(2), and one Nb(4) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one K(2), one K(3), one K(4), one Na(2), one Nb(3), and one Nb(5) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one K(1), one K(3), two equivalent K(2), one Ta(1), and one Nb(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one K(4), one Na(1), two equivalent Na(2), one Ta(1), and one Nb(1) atom. In the eleventh O site, O(11) is bonded to one K(1), one K(3), two equivalent K(2), one Nb(2), and one Nb(3) atom to form a mixture of distorted corner and edge-sharing OK4Nb2 octahedra. The corner-sharing octahedra are not tilted. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one K(4), one Na(1), two equivalent Na(2), one Nb(2), and one Nb(3) atom. In the thirteenth O site, O(13) is bonded to one K(1), one K(3), two equivalent K(2), one Nb(4), and one Nb(5) atom to form distorted edge-sharing OK4Nb2 octahedra. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one K(4), one Na(1), two equivalent Na(2), one Nb(4), and one Nb(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K5Na3TaNb7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.078
_cell_length_b   8.078
_cell_length_c   8.077
_cell_angle_alpha   89.998
_cell_angle_beta   89.998
_cell_angle_gamma   89.998
_symmetry_Int_Tables_number   1
_cell_volume   526.964
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.750  0.750  1.0
  K  K1  1  0.750  0.250  0.750  1.0
  K  K2  1  0.250  0.750  0.750  1.0
  K  K3  1  0.250  0.250  0.750  1.0
  K  K4  1  0.250  0.250  0.250  1.0
  Na  Na5  1  0.750  0.750  0.250  1.0
  Na  Na6  1  0.750  0.250  0.250  1.0
  Na  Na7  1  0.250  0.750  0.250  1.0
  Ta  Ta8  1  1.000  1.000  0.001  1.0
  Nb  Nb9  1  1.000  1.000  0.499  1.0
  Nb  Nb10  1  1.000  0.500  0.001  1.0
  Nb  Nb11  1  1.000  0.500  0.499  1.0
  Nb  Nb12  1  0.500  1.000  0.001  1.0
  Nb  Nb13  1  0.500  1.000  0.499  1.0
  Nb  Nb14  1  0.500  0.500  0.001  1.0
  Nb  Nb15  1  0.500  0.500  0.499  1.0
  O  O16  1  0.751  1.000  0.002  1.0
  O  O17  1  0.750  1.000  0.498  1.0
  O  O18  1  0.750  0.500  0.002  1.0
  O  O19  1  0.750  0.500  0.498  1.0
  O  O20  1  0.249  0.999  0.001  1.0
  O  O21  1  0.250  0.999  0.499  1.0
  O  O22  1  0.250  0.501  0.001  1.0
  O  O23  1  0.250  0.501  0.499  1.0
  O  O24  1  1.000  0.751  0.002  1.0
  O  O25  1  1.000  0.750  0.498  1.0
  O  O26  1  0.999  0.249  0.001  1.0
  O  O27  1  0.999  0.250  0.499  1.0
  O  O28  1  0.500  0.750  0.002  1.0
  O  O29  1  0.500  0.750  0.498  1.0
  O  O30  1  0.501  0.250  0.001  1.0
  O  O31  1  0.501  0.250  0.499  1.0
  O  O32  1  1.000  1.000  0.751  1.0
  O  O33  1  0.999  0.999  0.249  1.0
  O  O34  1  1.000  0.500  0.750  1.0
  O  O35  1  0.999  0.501  0.250  1.0
  O  O36  1  0.500  1.000  0.750  1.0
  O  O37  1  0.501  0.999  0.250  1.0
  O  O38  1  0.500  0.500  0.750  1.0
  O  O39  1  0.501  0.501  0.250  1.0
[/CIF]
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