The compound described by S7(N3O4)2 is Indium-like structured and crystallizes in the tetragonal P-42_1m space group. The structure is zero-dimensional and consists of two S7(N3O4)2 clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one S(1) and two equivalent S(2) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to two equivalent N(2) atoms. In the second S site, S(2) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form corner-sharing SN2O2 tetrahedra. In the third S site, S(3) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S7(N3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.149
_cell_length_b   12.149
_cell_length_c   5.171
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   763.248
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.500  0.000  0.404  1.0
  S  S1  1  0.538  0.211  0.116  1.0
  S  S2  1  0.462  0.789  0.116  1.0
  S  S3  1  0.211  0.462  0.884  1.0
  S  S4  1  0.789  0.538  0.884  1.0
  S  S5  1  0.711  0.038  0.116  1.0
  S  S6  1  0.962  0.711  0.884  1.0
  S  S7  1  0.038  0.289  0.884  1.0
  S  S8  1  0.289  0.962  0.116  1.0
  S  S9  1  0.000  0.500  0.596  1.0
  S  S10  1  0.245  0.745  0.297  1.0
  S  S11  1  0.255  0.245  0.703  1.0
  S  S12  1  0.745  0.755  0.703  1.0
  S  S13  1  0.755  0.255  0.297  1.0
  N  N14  1  0.635  0.290  0.243  1.0
  N  N15  1  0.210  0.865  0.243  1.0
  N  N16  1  0.421  0.921  0.208  1.0
  N  N17  1  0.079  0.421  0.792  1.0
  N  N18  1  0.921  0.579  0.792  1.0
  N  N19  1  0.579  0.079  0.208  1.0
  N  N20  1  0.365  0.710  0.243  1.0
  N  N21  1  0.290  0.365  0.757  1.0
  N  N22  1  0.710  0.635  0.757  1.0
  N  N23  1  0.790  0.135  0.243  1.0
  N  N24  1  0.865  0.790  0.757  1.0
  N  N25  1  0.135  0.210  0.757  1.0
  O  O26  1  0.545  0.219  0.840  1.0
  O  O27  1  0.266  0.063  0.247  1.0
  O  O28  1  0.437  0.234  0.247  1.0
  O  O29  1  0.937  0.266  0.753  1.0
  O  O30  1  0.063  0.734  0.753  1.0
  O  O31  1  0.734  0.937  0.247  1.0
  O  O32  1  0.766  0.437  0.753  1.0
  O  O33  1  0.234  0.563  0.753  1.0
  O  O34  1  0.563  0.766  0.247  1.0
  O  O35  1  0.219  0.455  0.160  1.0
  O  O36  1  0.281  0.955  0.840  1.0
  O  O37  1  0.045  0.281  0.160  1.0
  O  O38  1  0.955  0.719  0.160  1.0
  O  O39  1  0.719  0.045  0.840  1.0
  O  O40  1  0.781  0.545  0.160  1.0
  O  O41  1  0.455  0.781  0.840  1.0
[/CIF]
.
The compound described by S7(N3O4)2 is Indium-like structured and crystallizes in the tetragonal P-42_1m space group. The structure is zero-dimensional and consists of two S7(N3O4)2 clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one S(1) and two equivalent S(2) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to two equivalent N(2) atoms. In the second S site, S(2) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form corner-sharing SN2O2 tetrahedra. In the third S site, S(3) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S7(N3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.149
_cell_length_b   12.149
_cell_length_c   5.171
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   763.248
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.500  0.000  0.404  1.0
  S  S1  1  0.538  0.211  0.116  1.0
  S  S2  1  0.462  0.789  0.116  1.0
  S  S3  1  0.211  0.462  0.884  1.0
  S  S4  1  0.789  0.538  0.884  1.0
  S  S5  1  0.711  0.038  0.116  1.0
  S  S6  1  0.962  0.711  0.884  1.0
  S  S7  1  0.038  0.289  0.884  1.0
  S  S8  1  0.289  0.962  0.116  1.0
  S  S9  1  0.000  0.500  0.596  1.0
  S  S10  1  0.245  0.745  0.297  1.0
  S  S11  1  0.255  0.245  0.703  1.0
  S  S12  1  0.745  0.755  0.703  1.0
  S  S13  1  0.755  0.255  0.297  1.0
  N  N14  1  0.635  0.290  0.243  1.0
  N  N15  1  0.210  0.865  0.243  1.0
  N  N16  1  0.421  0.921  0.208  1.0
  N  N17  1  0.079  0.421  0.792  1.0
  N  N18  1  0.921  0.579  0.792  1.0
  N  N19  1  0.579  0.079  0.208  1.0
  N  N20  1  0.365  0.710  0.243  1.0
  N  N21  1  0.290  0.365  0.757  1.0
  N  N22  1  0.710  0.635  0.757  1.0
  N  N23  1  0.790  0.135  0.243  1.0
  N  N24  1  0.865  0.790  0.757  1.0
  N  N25  1  0.135  0.210  0.757  1.0
  O  O26  1  0.545  0.219  0.840  1.0
  O  O27  1  0.266  0.063  0.247  1.0
  O  O28  1  0.437  0.234  0.247  1.0
  O  O29  1  0.937  0.266  0.753  1.0
  O  O30  1  0.063  0.734  0.753  1.0
  O  O31  1  0.734  0.937  0.247  1.0
  O  O32  1  0.766  0.437  0.753  1.0
  O  O33  1  0.234  0.563  0.753  1.0
  O  O34  1  0.563  0.766  0.247  1.0
  O  O35  1  0.219  0.455  0.160  1.0
  O  O36  1  0.281  0.955  0.840  1.0
  O  O37  1  0.045  0.281  0.160  1.0
  O  O38  1  0.955  0.719  0.160  1.0
  O  O39  1  0.719  0.045  0.840  1.0
  O  O40  1  0.781  0.545  0.160  1.0
  O  O41  1  0.455  0.781  0.840  1.0
[/CIF]
.