The crystal structure described by ReP(OCl2)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReP(OCl2)3 clusters. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one Cl(2), one Cl(5), and one Cl(6) atom. P(1) is bonded in a tetrahedral geometry to one O(2), one Cl(1), one Cl(3), and one Cl(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReP(Cl2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.927
_cell_length_b   6.579
_cell_length_c   14.205
_cell_angle_alpha   80.172
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1190.348
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.708  0.384  0.002  1.0
  Re  Re1  1  0.292  0.616  0.998  1.0
  Re  Re2  1  0.792  0.384  0.502  1.0
  Re  Re3  1  0.208  0.616  0.498  1.0
  P  P4  1  0.901  0.093  0.173  1.0
  P  P5  1  0.099  0.907  0.827  1.0
  P  P6  1  0.599  0.093  0.673  1.0
  P  P7  1  0.401  0.907  0.327  1.0
  Cl  Cl8  1  0.982  0.091  0.848  1.0
  Cl  Cl9  1  0.669  0.643  0.491  1.0
  Cl  Cl10  1  0.309  0.076  0.232  1.0
  Cl  Cl11  1  0.037  0.697  0.758  1.0
  Cl  Cl12  1  0.691  0.924  0.768  1.0
  Cl  Cl13  1  0.809  0.924  0.268  1.0
  Cl  Cl14  1  0.186  0.545  0.340  1.0
  Cl  Cl15  1  0.963  0.303  0.242  1.0
  Cl  Cl16  1  0.482  0.909  0.652  1.0
  Cl  Cl17  1  0.191  0.076  0.732  1.0
  Cl  Cl18  1  0.018  0.909  0.152  1.0
  Cl  Cl19  1  0.169  0.357  0.009  1.0
  Cl  Cl20  1  0.381  0.915  0.942  1.0
  Cl  Cl21  1  0.831  0.643  0.991  1.0
  Cl  Cl22  1  0.463  0.697  0.258  1.0
  Cl  Cl23  1  0.686  0.455  0.160  1.0
  Cl  Cl24  1  0.619  0.085  0.058  1.0
  Cl  Cl25  1  0.537  0.303  0.742  1.0
  Cl  Cl26  1  0.314  0.545  0.840  1.0
  Cl  Cl27  1  0.814  0.455  0.660  1.0
  Cl  Cl28  1  0.518  0.091  0.348  1.0
  Cl  Cl29  1  0.881  0.085  0.558  1.0
  Cl  Cl30  1  0.119  0.915  0.442  1.0
  Cl  Cl31  1  0.331  0.357  0.509  1.0
  O  O32  1  0.737  0.285  0.409  1.0
  O  O33  1  0.263  0.715  0.591  1.0
  O  O34  1  0.150  0.818  0.918  1.0
  O  O35  1  0.350  0.818  0.418  1.0
  O  O36  1  0.850  0.182  0.082  1.0
  O  O37  1  0.107  0.471  0.551  1.0
  O  O38  1  0.607  0.529  0.949  1.0
  O  O39  1  0.393  0.471  0.051  1.0
  O  O40  1  0.650  0.182  0.582  1.0
  O  O41  1  0.763  0.285  0.909  1.0
  O  O42  1  0.893  0.529  0.449  1.0
  O  O43  1  0.237  0.715  0.091  1.0
[/CIF]
.
The crystal structure described by ReP(OCl2)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReP(OCl2)3 clusters. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one Cl(2), one Cl(5), and one Cl(6) atom. P(1) is bonded in a tetrahedral geometry to one O(2), one Cl(1), one Cl(3), and one Cl(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReP(Cl2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.927
_cell_length_b   6.579
_cell_length_c   14.205
_cell_angle_alpha   80.172
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1190.348
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.708  0.384  0.002  1.0
  Re  Re1  1  0.292  0.616  0.998  1.0
  Re  Re2  1  0.792  0.384  0.502  1.0
  Re  Re3  1  0.208  0.616  0.498  1.0
  P  P4  1  0.901  0.093  0.173  1.0
  P  P5  1  0.099  0.907  0.827  1.0
  P  P6  1  0.599  0.093  0.673  1.0
  P  P7  1  0.401  0.907  0.327  1.0
  Cl  Cl8  1  0.982  0.091  0.848  1.0
  Cl  Cl9  1  0.669  0.643  0.491  1.0
  Cl  Cl10  1  0.309  0.076  0.232  1.0
  Cl  Cl11  1  0.037  0.697  0.758  1.0
  Cl  Cl12  1  0.691  0.924  0.768  1.0
  Cl  Cl13  1  0.809  0.924  0.268  1.0
  Cl  Cl14  1  0.186  0.545  0.340  1.0
  Cl  Cl15  1  0.963  0.303  0.242  1.0
  Cl  Cl16  1  0.482  0.909  0.652  1.0
  Cl  Cl17  1  0.191  0.076  0.732  1.0
  Cl  Cl18  1  0.018  0.909  0.152  1.0
  Cl  Cl19  1  0.169  0.357  0.009  1.0
  Cl  Cl20  1  0.381  0.915  0.942  1.0
  Cl  Cl21  1  0.831  0.643  0.991  1.0
  Cl  Cl22  1  0.463  0.697  0.258  1.0
  Cl  Cl23  1  0.686  0.455  0.160  1.0
  Cl  Cl24  1  0.619  0.085  0.058  1.0
  Cl  Cl25  1  0.537  0.303  0.742  1.0
  Cl  Cl26  1  0.314  0.545  0.840  1.0
  Cl  Cl27  1  0.814  0.455  0.660  1.0
  Cl  Cl28  1  0.518  0.091  0.348  1.0
  Cl  Cl29  1  0.881  0.085  0.558  1.0
  Cl  Cl30  1  0.119  0.915  0.442  1.0
  Cl  Cl31  1  0.331  0.357  0.509  1.0
  O  O32  1  0.737  0.285  0.409  1.0
  O  O33  1  0.263  0.715  0.591  1.0
  O  O34  1  0.150  0.818  0.918  1.0
  O  O35  1  0.350  0.818  0.418  1.0
  O  O36  1  0.850  0.182  0.082  1.0
  O  O37  1  0.107  0.471  0.551  1.0
  O  O38  1  0.607  0.529  0.949  1.0
  O  O39  1  0.393  0.471  0.051  1.0
  O  O40  1  0.650  0.182  0.582  1.0
  O  O41  1  0.763  0.285  0.909  1.0
  O  O42  1  0.893  0.529  0.449  1.0
  O  O43  1  0.237  0.715  0.091  1.0
[/CIF]
.