The crystal structure described by Rb2NS2O6 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(2), and three equivalent O(3) atoms. N(1) is bonded in a bent 120 degrees geometry to two equivalent S(1) atoms. S(1) is bonded to one N(1), one O(1), one O(2), and one O(3) atom to form corner-sharing SNO3 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one S(1) atom. is represented by the CIF file [CIF]
data_Rb2S2NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.529
_cell_length_b   7.529
_cell_length_c   7.757
_cell_angle_alpha   86.456
_cell_angle_beta   86.456
_cell_angle_gamma   62.366
_symmetry_Int_Tables_number   1
_cell_volume   388.545
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.289  0.008  0.137  1.0
  Rb  Rb1  1  0.992  0.711  0.363  1.0
  Rb  Rb2  1  0.711  0.992  0.863  1.0
  Rb  Rb3  1  0.008  0.289  0.637  1.0
  S  S4  1  0.769  0.427  0.136  1.0
  S  S5  1  0.573  0.231  0.364  1.0
  S  S6  1  0.231  0.573  0.864  1.0
  S  S7  1  0.427  0.769  0.636  1.0
  N  N8  1  0.569  0.431  0.250  1.0
  N  N9  1  0.431  0.569  0.750  1.0
  O  O10  1  0.816  0.287  0.996  1.0
  O  O11  1  0.713  0.184  0.504  1.0
  O  O12  1  0.184  0.713  0.004  1.0
  O  O13  1  0.287  0.816  0.496  1.0
  O  O14  1  0.697  0.636  0.075  1.0
  O  O15  1  0.364  0.303  0.425  1.0
  O  O16  1  0.303  0.364  0.925  1.0
  O  O17  1  0.636  0.697  0.575  1.0
  O  O18  1  0.933  0.360  0.256  1.0
  O  O19  1  0.640  0.067  0.244  1.0
  O  O20  1  0.067  0.640  0.744  1.0
  O  O21  1  0.360  0.933  0.756  1.0
[/CIF]
.
The crystal structure described by Rb2NS2O6 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(2), and three equivalent O(3) atoms. N(1) is bonded in a bent 120 degrees geometry to two equivalent S(1) atoms. S(1) is bonded to one N(1), one O(1), one O(2), and one O(3) atom to form corner-sharing SNO3 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one S(1) atom. is represented by the CIF file [CIF]
data_Rb2S2NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.529
_cell_length_b   7.529
_cell_length_c   7.757
_cell_angle_alpha   86.456
_cell_angle_beta   86.456
_cell_angle_gamma   62.366
_symmetry_Int_Tables_number   1
_cell_volume   388.545
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.289  0.008  0.137  1.0
  Rb  Rb1  1  0.992  0.711  0.363  1.0
  Rb  Rb2  1  0.711  0.992  0.863  1.0
  Rb  Rb3  1  0.008  0.289  0.637  1.0
  S  S4  1  0.769  0.427  0.136  1.0
  S  S5  1  0.573  0.231  0.364  1.0
  S  S6  1  0.231  0.573  0.864  1.0
  S  S7  1  0.427  0.769  0.636  1.0
  N  N8  1  0.569  0.431  0.250  1.0
  N  N9  1  0.431  0.569  0.750  1.0
  O  O10  1  0.816  0.287  0.996  1.0
  O  O11  1  0.713  0.184  0.504  1.0
  O  O12  1  0.184  0.713  0.004  1.0
  O  O13  1  0.287  0.816  0.496  1.0
  O  O14  1  0.697  0.636  0.075  1.0
  O  O15  1  0.364  0.303  0.425  1.0
  O  O16  1  0.303  0.364  0.925  1.0
  O  O17  1  0.636  0.697  0.575  1.0
  O  O18  1  0.933  0.360  0.256  1.0
  O  O19  1  0.640  0.067  0.244  1.0
  O  O20  1  0.067  0.640  0.744  1.0
  O  O21  1  0.360  0.933  0.756  1.0
[/CIF]
.