The structure described by Tm(O4Cl)3 crystallizes in the trigonal R3c space group. Tm(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Tm(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Tm(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Tm(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. is represented by the CIF card [CIF]
data_Tm(ClO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.258
_cell_length_b   9.258
_cell_length_c   9.258
_cell_angle_alpha   51.809
_cell_angle_beta   51.809
_cell_angle_gamma   51.809
_symmetry_Int_Tables_number   1
_cell_volume   452.951
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.941  0.941  0.941  1.0
  Tm  Tm1  1  0.441  0.441  0.441  1.0
  Cl  Cl2  1  0.534  0.158  0.808  1.0
  Cl  Cl3  1  0.808  0.534  0.158  1.0
  Cl  Cl4  1  0.658  0.034  0.308  1.0
  Cl  Cl5  1  0.158  0.808  0.534  1.0
  Cl  Cl6  1  0.034  0.308  0.658  1.0
  Cl  Cl7  1  0.308  0.658  0.034  1.0
  O  O8  1  0.921  0.247  0.873  1.0
  O  O9  1  0.873  0.921  0.247  1.0
  O  O10  1  0.721  0.118  0.793  1.0
  O  O11  1  0.999  0.428  0.051  1.0
  O  O12  1  0.582  0.112  0.654  1.0
  O  O13  1  0.928  0.499  0.551  1.0
  O  O14  1  0.618  0.221  0.293  1.0
  O  O15  1  0.247  0.873  0.921  1.0
  O  O16  1  0.428  0.051  0.999  1.0
  O  O17  1  0.747  0.421  0.373  1.0
  O  O18  1  0.793  0.721  0.118  1.0
  O  O19  1  0.654  0.582  0.112  1.0
  O  O20  1  0.421  0.373  0.747  1.0
  O  O21  1  0.499  0.551  0.928  1.0
  O  O22  1  0.221  0.293  0.618  1.0
  O  O23  1  0.293  0.618  0.221  1.0
  O  O24  1  0.551  0.928  0.499  1.0
  O  O25  1  0.373  0.747  0.421  1.0
  O  O26  1  0.612  0.082  0.154  1.0
  O  O27  1  0.112  0.654  0.582  1.0
  O  O28  1  0.118  0.793  0.721  1.0
  O  O29  1  0.051  0.999  0.428  1.0
  O  O30  1  0.082  0.154  0.612  1.0
  O  O31  1  0.154  0.612  0.082  1.0
[/CIF]
.
The structure described by Tm(O4Cl)3 crystallizes in the trigonal R3c space group. Tm(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Tm(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Tm(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Tm(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. is represented by the CIF card [CIF]
data_Tm(ClO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.258
_cell_length_b   9.258
_cell_length_c   9.258
_cell_angle_alpha   51.809
_cell_angle_beta   51.809
_cell_angle_gamma   51.809
_symmetry_Int_Tables_number   1
_cell_volume   452.951
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.941  0.941  0.941  1.0
  Tm  Tm1  1  0.441  0.441  0.441  1.0
  Cl  Cl2  1  0.534  0.158  0.808  1.0
  Cl  Cl3  1  0.808  0.534  0.158  1.0
  Cl  Cl4  1  0.658  0.034  0.308  1.0
  Cl  Cl5  1  0.158  0.808  0.534  1.0
  Cl  Cl6  1  0.034  0.308  0.658  1.0
  Cl  Cl7  1  0.308  0.658  0.034  1.0
  O  O8  1  0.921  0.247  0.873  1.0
  O  O9  1  0.873  0.921  0.247  1.0
  O  O10  1  0.721  0.118  0.793  1.0
  O  O11  1  0.999  0.428  0.051  1.0
  O  O12  1  0.582  0.112  0.654  1.0
  O  O13  1  0.928  0.499  0.551  1.0
  O  O14  1  0.618  0.221  0.293  1.0
  O  O15  1  0.247  0.873  0.921  1.0
  O  O16  1  0.428  0.051  0.999  1.0
  O  O17  1  0.747  0.421  0.373  1.0
  O  O18  1  0.793  0.721  0.118  1.0
  O  O19  1  0.654  0.582  0.112  1.0
  O  O20  1  0.421  0.373  0.747  1.0
  O  O21  1  0.499  0.551  0.928  1.0
  O  O22  1  0.221  0.293  0.618  1.0
  O  O23  1  0.293  0.618  0.221  1.0
  O  O24  1  0.551  0.928  0.499  1.0
  O  O25  1  0.373  0.747  0.421  1.0
  O  O26  1  0.612  0.082  0.154  1.0
  O  O27  1  0.112  0.654  0.582  1.0
  O  O28  1  0.118  0.793  0.721  1.0
  O  O29  1  0.051  0.999  0.428  1.0
  O  O30  1  0.082  0.154  0.612  1.0
  O  O31  1  0.154  0.612  0.082  1.0
[/CIF]
.