The material described by CsMg14Ti crystallizes in the orthorhombic Amm2 space group. Cs(1) is bonded to two equivalent Mg(7); four Mg(3,3,3); four Mg(5,5); and two equivalent Ti(1) atoms to form CsMg10Ti2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with six equivalent Cs(1)Mg10Ti2 cuboctahedra; corners with eight equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with eight Mg(5,5)CsMg10Ti cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; faces with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; and faces with six equivalent Mg(6)Mg11Ti cuboctahedra. There are ten inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2); two equivalent Mg(6); four equivalent Mg(4); and four Mg(5,5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg10Ti2 cuboctahedra; corners with six equivalent Mg(1)Mg12 cuboctahedra; corners with eight Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra; edges with eight Mg(5,5)CsMg10Ti cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; faces with four equivalent Mg(4)Mg12 cuboctahedra; and faces with six equivalent Mg(7)CsMg11 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1); two equivalent Mg(7); four equivalent Mg(4); and four Mg(5,5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Ti(1)Cs2Mg10 cuboctahedra; corners with six equivalent Mg(2)Mg12 cuboctahedra; corners with eight Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra; edges with eight Mg(5,5)CsMg10Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; faces with four equivalent Mg(4)Mg12 cuboctahedra; and faces with six equivalent Mg(6)Mg11Ti cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Cs(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent Ti(1) atoms to form distorted MgCs2Mg8Ti2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six Mg(3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; and faces with eight Mg(5,5)CsMg10Ti cuboctahedra. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg10Ti2 cuboctahedra; corners with four equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; corners with four equivalent Ti(1)Cs2Mg10 cuboctahedra; corners with six equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; and faces with eight Mg(5,5)CsMg10Ti cuboctahedra. In the fifth Mg site, Mg(3) is bonded to two equivalent Cs(1); two equivalent Mg(3); two Mg(5,5); two equivalent Mg(6); two equivalent Mg(7); and two equivalent Ti(1) atoms to form distorted MgCs2Mg8Ti2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six Mg(3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four equivalent Mg(5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; and faces with eight Mg(5,5)CsMg10Ti cuboctahedra. In the sixth Mg site, Mg(5) is bonded to one Cs(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one Ti(1) atom to form distorted MgCsMg10Ti cuboctahedra that share corners with four equivalent Mg(7)CsMg11 cuboctahedra; corners with four equivalent Mg(6)Mg11Ti cuboctahedra; corners with ten Mg(5,5)CsMg10Ti cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Mg(5)CsMg10Ti cuboctahedra; edges with two equivalent Mg(7)CsMg11 cuboctahedra; edges with two equivalent Mg(6)Mg11Ti cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra;  a faceface with one Cs(1)Mg10Ti2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one Ti(1)Cs2Mg10 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the seventh Mg site, Mg(5) is bonded to one Cs(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one Ti(1) atom to form distorted MgCsMg10Ti cuboctahedra that share corners with four equivalent Mg(7)CsMg11 cuboctahedra; corners with four equivalent Mg(6)Mg11Ti cuboctahedra; corners with ten equivalent Mg(5)CsMg10Ti cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Mg(5)CsMg10Ti cuboctahedra; edges with two equivalent Mg(7)CsMg11 cuboctahedra; edges with two equivalent Mg(6)Mg11Ti cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra;  a faceface with one Cs(1)Mg10Ti2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one Ti(1)Cs2Mg10 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with four Mg(3,3)Cs2Mg8Ti2 cuboctahedra; faces with four equivalent Mg(5)CsMg10Ti cuboctahedra; and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the eighth Mg site, Mg(6) is bonded to one Mg(1); two Mg(3,3); two equivalent Mg(4); two equivalent Mg(7); four Mg(5,5); and one Ti(1) atom to form distorted MgMg11Ti cuboctahedra that share corners with four equivalent Mg(7)CsMg11 cuboctahedra; corners with six equivalent Mg(6)Mg11Ti cuboctahedra; corners with eight Mg(5,5)CsMg10Ti cuboctahedra; edges with two equivalent Mg(7)CsMg11 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Ti(1)Cs2Mg10 cuboctahedra; faces with two Mg(3,3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with three equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with three equivalent Mg(2)Mg12 cuboctahedra; and faces with four Mg(5,5)CsMg10Ti cuboctahedra. In the ninth Mg site, Mg(7) is bonded to one Cs(1); one Mg(2); two Mg(3,3); two equivalent Mg(4); two equivalent Mg(6); and four Mg(5,5) atoms to form distorted MgCsMg11 cuboctahedra that share corners with four equivalent Mg(6)Mg11Ti cuboctahedra; corners with six equivalent Mg(7)CsMg11 cuboctahedra; corners with eight Mg(5,5)CsMg10Ti cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(6)Mg11Ti cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra;  a faceface with one Cs(1)Mg10Ti2 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra; faces with two Mg(3,3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with three equivalent Mg(1)Mg12 cuboctahedra; faces with three equivalent Ti(1)Cs2Mg10 cuboctahedra; and faces with four Mg(5,5)CsMg10Ti cuboctahedra. In the tenth Mg site, Mg(3) is bonded to two equivalent Cs(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent Ti(1) atoms to form distorted MgCs2Mg8Ti2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six Mg(3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; and faces with eight Mg(5,5)CsMg10Ti cuboctahedra. Ti(1) is bonded to two equivalent Cs(1); two equivalent Mg(6); four Mg(3,3,3); and four Mg(5,5) atoms to form TiCs2Mg10 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with six equivalent Ti(1)Cs2Mg10 cuboctahedra; corners with eight equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; edges with eight Mg(5,5)CsMg10Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; and faces with six equivalent Mg(7)CsMg11 cuboctahedra. is represented by the CIF card [CIF]
data_CsMg14Ti
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.534
_cell_length_b   6.573
_cell_length_c   10.604
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.199
_symmetry_Int_Tables_number   1
_cell_volume   393.608
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.158  0.829  0.125  1.0
  Mg  Mg1  1  0.165  0.332  0.625  1.0
  Mg  Mg2  1  0.168  0.834  0.625  1.0
  Mg  Mg3  1  0.663  0.332  0.125  1.0
  Mg  Mg4  1  0.666  0.330  0.625  1.0
  Mg  Mg5  1  0.663  0.831  0.125  1.0
  Mg  Mg6  1  0.666  0.837  0.625  1.0
  Mg  Mg7  1  0.336  0.182  0.387  1.0
  Mg  Mg8  1  0.336  0.182  0.863  1.0
  Mg  Mg9  1  0.336  0.655  0.387  1.0
  Mg  Mg10  1  0.336  0.655  0.863  1.0
  Mg  Mg11  1  0.840  0.170  0.368  1.0
  Mg  Mg12  1  0.840  0.170  0.882  1.0
  Mg  Mg13  1  0.819  0.659  0.394  1.0
  Mg  Mg14  1  0.819  0.659  0.856  1.0
  Ti  Ti15  1  0.187  0.344  0.125  1.0
[/CIF]
.
The material described by CsMg14Ti crystallizes in the orthorhombic Amm2 space group. Cs(1) is bonded to two equivalent Mg(7); four Mg(3,3,3); four Mg(5,5); and two equivalent Ti(1) atoms to form CsMg10Ti2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with six equivalent Cs(1)Mg10Ti2 cuboctahedra; corners with eight equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with eight Mg(5,5)CsMg10Ti cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; faces with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; and faces with six equivalent Mg(6)Mg11Ti cuboctahedra. There are ten inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2); two equivalent Mg(6); four equivalent Mg(4); and four Mg(5,5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg10Ti2 cuboctahedra; corners with six equivalent Mg(1)Mg12 cuboctahedra; corners with eight Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra; edges with eight Mg(5,5)CsMg10Ti cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; faces with four equivalent Mg(4)Mg12 cuboctahedra; and faces with six equivalent Mg(7)CsMg11 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1); two equivalent Mg(7); four equivalent Mg(4); and four Mg(5,5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Ti(1)Cs2Mg10 cuboctahedra; corners with six equivalent Mg(2)Mg12 cuboctahedra; corners with eight Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra; edges with eight Mg(5,5)CsMg10Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; faces with four equivalent Mg(4)Mg12 cuboctahedra; and faces with six equivalent Mg(6)Mg11Ti cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Cs(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent Ti(1) atoms to form distorted MgCs2Mg8Ti2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six Mg(3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; and faces with eight Mg(5,5)CsMg10Ti cuboctahedra. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg10Ti2 cuboctahedra; corners with four equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; corners with four equivalent Ti(1)Cs2Mg10 cuboctahedra; corners with six equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with two equivalent Mg(2)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; and faces with eight Mg(5,5)CsMg10Ti cuboctahedra. In the fifth Mg site, Mg(3) is bonded to two equivalent Cs(1); two equivalent Mg(3); two Mg(5,5); two equivalent Mg(6); two equivalent Mg(7); and two equivalent Ti(1) atoms to form distorted MgCs2Mg8Ti2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six Mg(3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four equivalent Mg(5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; and faces with eight Mg(5,5)CsMg10Ti cuboctahedra. In the sixth Mg site, Mg(5) is bonded to one Cs(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one Ti(1) atom to form distorted MgCsMg10Ti cuboctahedra that share corners with four equivalent Mg(7)CsMg11 cuboctahedra; corners with four equivalent Mg(6)Mg11Ti cuboctahedra; corners with ten Mg(5,5)CsMg10Ti cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Mg(5)CsMg10Ti cuboctahedra; edges with two equivalent Mg(7)CsMg11 cuboctahedra; edges with two equivalent Mg(6)Mg11Ti cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra;  a faceface with one Cs(1)Mg10Ti2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one Ti(1)Cs2Mg10 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the seventh Mg site, Mg(5) is bonded to one Cs(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one Ti(1) atom to form distorted MgCsMg10Ti cuboctahedra that share corners with four equivalent Mg(7)CsMg11 cuboctahedra; corners with four equivalent Mg(6)Mg11Ti cuboctahedra; corners with ten equivalent Mg(5)CsMg10Ti cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Mg(5)CsMg10Ti cuboctahedra; edges with two equivalent Mg(7)CsMg11 cuboctahedra; edges with two equivalent Mg(6)Mg11Ti cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra;  a faceface with one Cs(1)Mg10Ti2 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra;  a faceface with one Ti(1)Cs2Mg10 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with four Mg(3,3)Cs2Mg8Ti2 cuboctahedra; faces with four equivalent Mg(5)CsMg10Ti cuboctahedra; and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the eighth Mg site, Mg(6) is bonded to one Mg(1); two Mg(3,3); two equivalent Mg(4); two equivalent Mg(7); four Mg(5,5); and one Ti(1) atom to form distorted MgMg11Ti cuboctahedra that share corners with four equivalent Mg(7)CsMg11 cuboctahedra; corners with six equivalent Mg(6)Mg11Ti cuboctahedra; corners with eight Mg(5,5)CsMg10Ti cuboctahedra; edges with two equivalent Mg(7)CsMg11 cuboctahedra; edges with two equivalent Mg(1)Mg12 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra;  a faceface with one Mg(1)Mg12 cuboctahedra;  a faceface with one Ti(1)Cs2Mg10 cuboctahedra; faces with two Mg(3,3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with three equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with three equivalent Mg(2)Mg12 cuboctahedra; and faces with four Mg(5,5)CsMg10Ti cuboctahedra. In the ninth Mg site, Mg(7) is bonded to one Cs(1); one Mg(2); two Mg(3,3); two equivalent Mg(4); two equivalent Mg(6); and four Mg(5,5) atoms to form distorted MgCsMg11 cuboctahedra that share corners with four equivalent Mg(6)Mg11Ti cuboctahedra; corners with six equivalent Mg(7)CsMg11 cuboctahedra; corners with eight Mg(5,5)CsMg10Ti cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(6)Mg11Ti cuboctahedra; edges with two equivalent Mg(2)Mg12 cuboctahedra; edges with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra;  a faceface with one Cs(1)Mg10Ti2 cuboctahedra;  a faceface with one Mg(2)Mg12 cuboctahedra; faces with two Mg(3,3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with three equivalent Mg(1)Mg12 cuboctahedra; faces with three equivalent Ti(1)Cs2Mg10 cuboctahedra; and faces with four Mg(5,5)CsMg10Ti cuboctahedra. In the tenth Mg site, Mg(3) is bonded to two equivalent Cs(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent Ti(1) atoms to form distorted MgCs2Mg8Ti2 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra; corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with six Mg(3,3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; edges with two equivalent Ti(1)Cs2Mg10 cuboctahedra; edges with four Mg(5,5)CsMg10Ti cuboctahedra; edges with four equivalent Mg(7)CsMg11 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(3)Cs2Mg8Ti2 cuboctahedra; faces with two equivalent Mg(7)CsMg11 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Ti(1)Cs2Mg10 cuboctahedra; and faces with eight Mg(5,5)CsMg10Ti cuboctahedra. Ti(1) is bonded to two equivalent Cs(1); two equivalent Mg(6); four Mg(3,3,3); and four Mg(5,5) atoms to form TiCs2Mg10 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra; corners with six equivalent Ti(1)Cs2Mg10 cuboctahedra; corners with eight equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent Cs(1)Mg10Ti2 cuboctahedra; edges with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; edges with four equivalent Mg(6)Mg11Ti cuboctahedra; edges with eight Mg(5,5)CsMg10Ti cuboctahedra; faces with two equivalent Cs(1)Mg10Ti2 cuboctahedra; faces with two equivalent Mg(6)Mg11Ti cuboctahedra; faces with two equivalent Mg(1)Mg12 cuboctahedra; faces with four Mg(3,3,3)Cs2Mg8Ti2 cuboctahedra; faces with four Mg(5,5)CsMg10Ti cuboctahedra; and faces with six equivalent Mg(7)CsMg11 cuboctahedra. is represented by the CIF card [CIF]
data_CsMg14Ti
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.534
_cell_length_b   6.573
_cell_length_c   10.604
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.199
_symmetry_Int_Tables_number   1
_cell_volume   393.608
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.158  0.829  0.125  1.0
  Mg  Mg1  1  0.165  0.332  0.625  1.0
  Mg  Mg2  1  0.168  0.834  0.625  1.0
  Mg  Mg3  1  0.663  0.332  0.125  1.0
  Mg  Mg4  1  0.666  0.330  0.625  1.0
  Mg  Mg5  1  0.663  0.831  0.125  1.0
  Mg  Mg6  1  0.666  0.837  0.625  1.0
  Mg  Mg7  1  0.336  0.182  0.387  1.0
  Mg  Mg8  1  0.336  0.182  0.863  1.0
  Mg  Mg9  1  0.336  0.655  0.387  1.0
  Mg  Mg10  1  0.336  0.655  0.863  1.0
  Mg  Mg11  1  0.840  0.170  0.368  1.0
  Mg  Mg12  1  0.840  0.170  0.882  1.0
  Mg  Mg13  1  0.819  0.659  0.394  1.0
  Mg  Mg14  1  0.819  0.659  0.856  1.0
  Ti  Ti15  1  0.187  0.344  0.125  1.0
[/CIF]
.