The material structure described by K2RuN3O5Cl3 crystallizes in the triclinic P1 space group. There are four inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one O(1), one O(10), one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(6) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), one O(8), one Cl(3), and one Cl(6) atom. In the third K site, K(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(5), one Cl(1), and one Cl(4) atom. In the fourth K site, K(4) is bonded in a 7-coordinate geometry to one O(7), one O(8), one Cl(1), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in an octahedral geometry to one N(1), one N(4), one N(6), one Cl(2), one Cl(3), and one Cl(6) atom. In the second Ru site, Ru(2) is bonded in an octahedral geometry to one N(2), one N(3), one N(5), one Cl(1), one Cl(4), and one Cl(5) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ru(1), one O(3), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(2), one O(1), and one O(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Ru(2) and one O(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ru(1), one O(4), and one O(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ru(2), one O(10), and one O(5) atom. In the sixth N site, N(6) is bonded in a linear geometry to one Ru(1) and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one K(3), and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one N(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one N(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(2), one K(4), and one N(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(2), one K(4), and one N(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(6) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one K(1), one K(3), and one N(5) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one K(1), one K(3), one K(4), and one Ru(2) atom to form a mixture of distorted corner and edge-sharing ClK3Ru trigonal pyramids. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one K(1) and one Ru(1) atom. In the third Cl site, Cl(3) is bonded to one K(1), one K(2), one K(4), and one Ru(1) atom to form a mixture of distorted corner and edge-sharing ClK3Ru tetrahedra. In the fourth Cl site, Cl(4) is bonded to one K(1), one K(3), one K(4), and one Ru(2) atom to form a mixture of distorted corner and edge-sharing ClK3Ru tetrahedra. In the fifth Cl site, Cl(5) is bonded in a distorted bent 120 degrees geometry to one K(4) and one Ru(2) atom. In the sixth Cl site, Cl(6) is bonded to one K(1), one K(2), one K(4), and one Ru(1) atom to form a mixture of distorted corner and edge-sharing ClK3Ru tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2RuN3Cl3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.195
_cell_length_b   7.689
_cell_length_c   10.467
_cell_angle_alpha   90.407
_cell_angle_beta   102.118
_cell_angle_gamma   90.538
_symmetry_Int_Tables_number   1
_cell_volume   566.061
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.767  0.745  0.018  1.0
  K  K1  1  0.622  0.249  0.637  1.0
  K  K2  1  0.375  0.748  0.363  1.0
  K  K3  1  0.227  0.252  0.982  1.0
  Ru  Ru4  1  0.133  0.757  0.743  1.0
  Ru  Ru5  1  0.866  0.249  0.263  1.0
  N  N6  1  0.310  0.946  0.697  1.0
  N  N7  1  0.677  0.429  0.298  1.0
  N  N8  1  0.990  0.257  0.430  1.0
  N  N9  1  0.327  0.572  0.707  1.0
  N  N10  1  0.691  0.050  0.307  1.0
  N  N11  1  0.015  0.739  0.576  1.0
  Cl  Cl12  1  0.095  0.030  0.208  1.0
  Cl  Cl13  1  0.288  0.773  0.960  1.0
  Cl  Cl14  1  0.918  0.975  0.795  1.0
  Cl  Cl15  1  0.077  0.480  0.201  1.0
  Cl  Cl16  1  0.705  0.236  0.040  1.0
  Cl  Cl17  1  0.935  0.521  0.798  1.0
  O  O18  1  0.600  0.531  0.202  1.0
  O  O19  1  0.643  0.443  0.411  1.0
  O  O20  1  0.351  0.961  0.586  1.0
  O  O21  1  0.362  0.551  0.596  1.0
  O  O22  1  0.649  0.039  0.413  1.0
  O  O23  1  0.048  0.258  0.538  1.0
  O  O24  1  0.375  0.073  0.778  1.0
  O  O25  1  0.402  0.462  0.796  1.0
  O  O26  1  0.950  0.739  0.460  1.0
  O  O27  1  0.629  0.937  0.217  1.0
[/CIF]
.
The material structure described by K2RuN3O5Cl3 crystallizes in the triclinic P1 space group. There are four inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one O(1), one O(10), one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(6) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), one O(8), one Cl(3), and one Cl(6) atom. In the third K site, K(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(5), one Cl(1), and one Cl(4) atom. In the fourth K site, K(4) is bonded in a 7-coordinate geometry to one O(7), one O(8), one Cl(1), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in an octahedral geometry to one N(1), one N(4), one N(6), one Cl(2), one Cl(3), and one Cl(6) atom. In the second Ru site, Ru(2) is bonded in an octahedral geometry to one N(2), one N(3), one N(5), one Cl(1), one Cl(4), and one Cl(5) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ru(1), one O(3), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(2), one O(1), and one O(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Ru(2) and one O(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ru(1), one O(4), and one O(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ru(2), one O(10), and one O(5) atom. In the sixth N site, N(6) is bonded in a linear geometry to one Ru(1) and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one K(3), and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one N(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one N(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(2), one K(4), and one N(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(2), one K(4), and one N(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(6) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one K(1), one K(3), and one N(5) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one K(1), one K(3), one K(4), and one Ru(2) atom to form a mixture of distorted corner and edge-sharing ClK3Ru trigonal pyramids. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one K(1) and one Ru(1) atom. In the third Cl site, Cl(3) is bonded to one K(1), one K(2), one K(4), and one Ru(1) atom to form a mixture of distorted corner and edge-sharing ClK3Ru tetrahedra. In the fourth Cl site, Cl(4) is bonded to one K(1), one K(3), one K(4), and one Ru(2) atom to form a mixture of distorted corner and edge-sharing ClK3Ru tetrahedra. In the fifth Cl site, Cl(5) is bonded in a distorted bent 120 degrees geometry to one K(4) and one Ru(2) atom. In the sixth Cl site, Cl(6) is bonded to one K(1), one K(2), one K(4), and one Ru(1) atom to form a mixture of distorted corner and edge-sharing ClK3Ru tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2RuN3Cl3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.195
_cell_length_b   7.689
_cell_length_c   10.467
_cell_angle_alpha   90.407
_cell_angle_beta   102.118
_cell_angle_gamma   90.538
_symmetry_Int_Tables_number   1
_cell_volume   566.061
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.767  0.745  0.018  1.0
  K  K1  1  0.622  0.249  0.637  1.0
  K  K2  1  0.375  0.748  0.363  1.0
  K  K3  1  0.227  0.252  0.982  1.0
  Ru  Ru4  1  0.133  0.757  0.743  1.0
  Ru  Ru5  1  0.866  0.249  0.263  1.0
  N  N6  1  0.310  0.946  0.697  1.0
  N  N7  1  0.677  0.429  0.298  1.0
  N  N8  1  0.990  0.257  0.430  1.0
  N  N9  1  0.327  0.572  0.707  1.0
  N  N10  1  0.691  0.050  0.307  1.0
  N  N11  1  0.015  0.739  0.576  1.0
  Cl  Cl12  1  0.095  0.030  0.208  1.0
  Cl  Cl13  1  0.288  0.773  0.960  1.0
  Cl  Cl14  1  0.918  0.975  0.795  1.0
  Cl  Cl15  1  0.077  0.480  0.201  1.0
  Cl  Cl16  1  0.705  0.236  0.040  1.0
  Cl  Cl17  1  0.935  0.521  0.798  1.0
  O  O18  1  0.600  0.531  0.202  1.0
  O  O19  1  0.643  0.443  0.411  1.0
  O  O20  1  0.351  0.961  0.586  1.0
  O  O21  1  0.362  0.551  0.596  1.0
  O  O22  1  0.649  0.039  0.413  1.0
  O  O23  1  0.048  0.258  0.538  1.0
  O  O24  1  0.375  0.073  0.778  1.0
  O  O25  1  0.402  0.462  0.796  1.0
  O  O26  1  0.950  0.739  0.460  1.0
  O  O27  1  0.629  0.937  0.217  1.0
[/CIF]
.