The compound described by Ni(HO)4(C2O)2(H2O)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 1,3-butadiyne-1,4-diol molecules; eight water molecules; and two Ni(HO)4 clusters. In each Ni(HO)4 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(3) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Ni(1), one H(1), and one H(6) atom. is represented by the CIF card [CIF]
data_NiH12(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.824
_cell_length_b   10.009
_cell_length_c   12.370
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   88.949
_symmetry_Int_Tables_number   1
_cell_volume   720.919
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.500  1.0
  Ni  Ni1  1  0.500  0.000  0.000  1.0
  H  H2  1  0.259  0.196  0.003  1.0
  H  H3  1  0.581  0.718  0.215  1.0
  H  H4  1  0.953  0.432  0.697  1.0
  H  H5  1  0.848  0.346  0.261  1.0
  H  H6  1  0.759  0.196  0.497  1.0
  H  H7  1  0.480  0.757  0.812  1.0
  H  H8  1  0.652  0.654  0.761  1.0
  H  H9  1  0.152  0.654  0.739  1.0
  H  H10  1  0.081  0.718  0.285  1.0
  H  H11  1  0.419  0.282  0.785  1.0
  H  H12  1  0.241  0.804  0.503  1.0
  H  H13  1  0.741  0.804  0.997  1.0
  H  H14  1  0.167  0.085  0.079  1.0
  H  H15  1  0.333  0.915  0.579  1.0
  H  H16  1  0.020  0.243  0.312  1.0
  H  H17  1  0.520  0.243  0.188  1.0
  H  H18  1  0.348  0.346  0.239  1.0
  H  H19  1  0.833  0.915  0.921  1.0
  H  H20  1  0.547  0.568  0.197  1.0
  H  H21  1  0.453  0.432  0.803  1.0
  H  H22  1  0.667  0.085  0.421  1.0
  H  H23  1  0.919  0.282  0.715  1.0
  H  H24  1  0.047  0.568  0.303  1.0
  H  H25  1  0.980  0.757  0.688  1.0
  C  C26  1  0.838  0.335  0.012  1.0
  C  C27  1  0.052  0.556  0.996  1.0
  C  C28  1  0.948  0.444  0.004  1.0
  C  C29  1  0.662  0.665  0.512  1.0
  C  C30  1  0.162  0.665  0.988  1.0
  C  C31  1  0.448  0.444  0.496  1.0
  C  C32  1  0.552  0.556  0.504  1.0
  C  C33  1  0.338  0.335  0.488  1.0
  O  O34  1  0.504  0.013  0.136  1.0
  O  O35  1  0.256  0.768  0.977  1.0
  O  O36  1  0.712  0.103  0.496  1.0
  O  O37  1  0.496  0.987  0.864  1.0
  O  O38  1  0.011  0.333  0.281  1.0
  O  O39  1  0.212  0.103  0.004  1.0
  O  O40  1  0.788  0.897  0.996  1.0
  O  O41  1  0.511  0.333  0.219  1.0
  O  O42  1  0.756  0.768  0.523  1.0
  O  O43  1  0.977  0.655  0.318  1.0
  O  O44  1  0.489  0.667  0.781  1.0
  O  O45  1  0.244  0.232  0.477  1.0
  O  O46  1  0.477  0.655  0.182  1.0
  O  O47  1  0.523  0.345  0.818  1.0
  O  O48  1  0.744  0.232  0.023  1.0
  O  O49  1  0.288  0.897  0.504  1.0
  O  O50  1  0.004  0.013  0.364  1.0
  O  O51  1  0.989  0.667  0.719  1.0
  O  O52  1  0.023  0.345  0.682  1.0
  O  O53  1  0.996  0.987  0.636  1.0
[/CIF]
.
The compound described by Ni(HO)4(C2O)2(H2O)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 1,3-butadiyne-1,4-diol molecules; eight water molecules; and two Ni(HO)4 clusters. In each Ni(HO)4 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(3) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Ni(1), one H(1), and one H(6) atom. is represented by the CIF card [CIF]
data_NiH12(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.824
_cell_length_b   10.009
_cell_length_c   12.370
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   88.949
_symmetry_Int_Tables_number   1
_cell_volume   720.919
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.500  1.0
  Ni  Ni1  1  0.500  0.000  0.000  1.0
  H  H2  1  0.259  0.196  0.003  1.0
  H  H3  1  0.581  0.718  0.215  1.0
  H  H4  1  0.953  0.432  0.697  1.0
  H  H5  1  0.848  0.346  0.261  1.0
  H  H6  1  0.759  0.196  0.497  1.0
  H  H7  1  0.480  0.757  0.812  1.0
  H  H8  1  0.652  0.654  0.761  1.0
  H  H9  1  0.152  0.654  0.739  1.0
  H  H10  1  0.081  0.718  0.285  1.0
  H  H11  1  0.419  0.282  0.785  1.0
  H  H12  1  0.241  0.804  0.503  1.0
  H  H13  1  0.741  0.804  0.997  1.0
  H  H14  1  0.167  0.085  0.079  1.0
  H  H15  1  0.333  0.915  0.579  1.0
  H  H16  1  0.020  0.243  0.312  1.0
  H  H17  1  0.520  0.243  0.188  1.0
  H  H18  1  0.348  0.346  0.239  1.0
  H  H19  1  0.833  0.915  0.921  1.0
  H  H20  1  0.547  0.568  0.197  1.0
  H  H21  1  0.453  0.432  0.803  1.0
  H  H22  1  0.667  0.085  0.421  1.0
  H  H23  1  0.919  0.282  0.715  1.0
  H  H24  1  0.047  0.568  0.303  1.0
  H  H25  1  0.980  0.757  0.688  1.0
  C  C26  1  0.838  0.335  0.012  1.0
  C  C27  1  0.052  0.556  0.996  1.0
  C  C28  1  0.948  0.444  0.004  1.0
  C  C29  1  0.662  0.665  0.512  1.0
  C  C30  1  0.162  0.665  0.988  1.0
  C  C31  1  0.448  0.444  0.496  1.0
  C  C32  1  0.552  0.556  0.504  1.0
  C  C33  1  0.338  0.335  0.488  1.0
  O  O34  1  0.504  0.013  0.136  1.0
  O  O35  1  0.256  0.768  0.977  1.0
  O  O36  1  0.712  0.103  0.496  1.0
  O  O37  1  0.496  0.987  0.864  1.0
  O  O38  1  0.011  0.333  0.281  1.0
  O  O39  1  0.212  0.103  0.004  1.0
  O  O40  1  0.788  0.897  0.996  1.0
  O  O41  1  0.511  0.333  0.219  1.0
  O  O42  1  0.756  0.768  0.523  1.0
  O  O43  1  0.977  0.655  0.318  1.0
  O  O44  1  0.489  0.667  0.781  1.0
  O  O45  1  0.244  0.232  0.477  1.0
  O  O46  1  0.477  0.655  0.182  1.0
  O  O47  1  0.523  0.345  0.818  1.0
  O  O48  1  0.744  0.232  0.023  1.0
  O  O49  1  0.288  0.897  0.504  1.0
  O  O50  1  0.004  0.013  0.364  1.0
  O  O51  1  0.989  0.667  0.719  1.0
  O  O52  1  0.023  0.345  0.682  1.0
  O  O53  1  0.996  0.987  0.636  1.0
[/CIF]
.