The compound described by Rb2UH4(OCl)4 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent Cl(1), and three equivalent Cl(2) atoms. U(1) is bonded in a distorted octahedral geometry to two equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Rb(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one U(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one U(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one U(1) atom. is represented by the CIF file [CIF]
data_Rb2UH4(ClO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.245
_cell_length_b   7.163
_cell_length_c   7.543
_cell_angle_alpha   91.898
_cell_angle_beta   99.811
_cell_angle_gamma   119.866
_symmetry_Int_Tables_number   1
_cell_volume   331.289
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.072  0.246  0.253  1.0
  Rb  Rb1  1  0.928  0.754  0.747  1.0
  U  U2  1  0.500  0.000  0.500  1.0
  H  H3  1  0.632  0.772  0.066  1.0
  H  H4  1  0.368  0.228  0.934  1.0
  H  H5  1  0.774  0.682  0.157  1.0
  H  H6  1  0.226  0.318  0.843  1.0
  Cl  Cl7  1  0.691  0.228  0.831  1.0
  Cl  Cl8  1  0.309  0.772  0.169  1.0
  Cl  Cl9  1  0.335  0.623  0.639  1.0
  Cl  Cl10  1  0.665  0.377  0.361  1.0
  O  O11  1  0.775  0.786  0.075  1.0
  O  O12  1  0.225  0.214  0.925  1.0
  O  O13  1  0.257  0.009  0.514  1.0
  O  O14  1  0.743  0.991  0.486  1.0
[/CIF]
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The compound described by Rb2UH4(OCl)4 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent Cl(1), and three equivalent Cl(2) atoms. U(1) is bonded in a distorted octahedral geometry to two equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Rb(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one U(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one U(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one U(1) atom. is represented by the CIF file [CIF]
data_Rb2UH4(ClO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.245
_cell_length_b   7.163
_cell_length_c   7.543
_cell_angle_alpha   91.898
_cell_angle_beta   99.811
_cell_angle_gamma   119.866
_symmetry_Int_Tables_number   1
_cell_volume   331.289
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.072  0.246  0.253  1.0
  Rb  Rb1  1  0.928  0.754  0.747  1.0
  U  U2  1  0.500  0.000  0.500  1.0
  H  H3  1  0.632  0.772  0.066  1.0
  H  H4  1  0.368  0.228  0.934  1.0
  H  H5  1  0.774  0.682  0.157  1.0
  H  H6  1  0.226  0.318  0.843  1.0
  Cl  Cl7  1  0.691  0.228  0.831  1.0
  Cl  Cl8  1  0.309  0.772  0.169  1.0
  Cl  Cl9  1  0.335  0.623  0.639  1.0
  Cl  Cl10  1  0.665  0.377  0.361  1.0
  O  O11  1  0.775  0.786  0.075  1.0
  O  O12  1  0.225  0.214  0.925  1.0
  O  O13  1  0.257  0.009  0.514  1.0
  O  O14  1  0.743  0.991  0.486  1.0
[/CIF]
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