The material structure described by Rb2ReF6 crystallizes in the trigonal P-3m1 space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form distorted RbF12 cuboctahedra that share corners with six equivalent Rb(1)F12 cuboctahedra, corners with three equivalent Re(1)F6 octahedra, faces with eight equivalent Rb(1)F12 cuboctahedra, and faces with three equivalent Re(1)F6 octahedra. The corner-sharing octahedral tilt angles are 19°. Re(1) is bonded to six equivalent F(1) atoms to form ReF6 octahedra that share corners with six equivalent Rb(1)F12 cuboctahedra and faces with six equivalent Rb(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Re(1) atom. is represented by the CIF file [CIF]
data_Rb2ReF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.023
_cell_length_b   6.023
_cell_length_c   4.709
_cell_angle_alpha   90.001
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   147.945
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.333  0.667  0.294  1.0
  Rb  Rb1  1  0.667  0.333  0.706  1.0
  Re  Re2  1  1.000  0.000  1.000  1.0
  F  F3  1  0.840  0.160  0.225  1.0
  F  F4  1  0.160  0.840  0.775  1.0
  F  F5  1  0.840  0.681  0.225  1.0
  F  F6  1  0.160  0.319  0.775  1.0
  F  F7  1  0.319  0.160  0.225  1.0
  F  F8  1  0.681  0.840  0.775  1.0
[/CIF]
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The material structure described by Rb2ReF6 crystallizes in the trigonal P-3m1 space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form distorted RbF12 cuboctahedra that share corners with six equivalent Rb(1)F12 cuboctahedra, corners with three equivalent Re(1)F6 octahedra, faces with eight equivalent Rb(1)F12 cuboctahedra, and faces with three equivalent Re(1)F6 octahedra. The corner-sharing octahedral tilt angles are 19°. Re(1) is bonded to six equivalent F(1) atoms to form ReF6 octahedra that share corners with six equivalent Rb(1)F12 cuboctahedra and faces with six equivalent Rb(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Re(1) atom. is represented by the CIF file [CIF]
data_Rb2ReF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.023
_cell_length_b   6.023
_cell_length_c   4.709
_cell_angle_alpha   90.001
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   147.945
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.333  0.667  0.294  1.0
  Rb  Rb1  1  0.667  0.333  0.706  1.0
  Re  Re2  1  1.000  0.000  1.000  1.0
  F  F3  1  0.840  0.160  0.225  1.0
  F  F4  1  0.160  0.840  0.775  1.0
  F  F5  1  0.840  0.681  0.225  1.0
  F  F6  1  0.160  0.319  0.775  1.0
  F  F7  1  0.319  0.160  0.225  1.0
  F  F8  1  0.681  0.840  0.775  1.0
[/CIF]
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