The material structure described by (U2CuSO13)2CuO4(O2)2 crystallizes in the triclinic P-1 space group. The structure consists of two hydrogen peroxide molecules and one CuO4 cluster inside a U2CuSO13 framework. In the CuO4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(9) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cu(1) and one O(9) atom. In the second O site, O(9) is bonded in a 2-coordinate geometry to one Cu(1) and one O(1) atom. In the U2CuSO13 framework, there are two inequivalent U sites. In the first U site, U(1) is bonded to one O(12), one O(16), one O(5), one O(6), one O(8), and two equivalent O(2) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(2)O7 pentagonal bipyramids, corners with two equivalent S(1)O4 tetrahedra,  an edgeedge with one U(1)O7 pentagonal bipyramid, and  an edgeedge with one U(2)O7 pentagonal bipyramid. In the second U site, U(2) is bonded to one O(11), one O(14), one O(15), one O(17), one O(2), and two equivalent O(5) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent S(1)O4 tetrahedra,  an edgeedge with one U(1)O7 pentagonal bipyramid, and  an edgeedge with one U(2)O7 pentagonal bipyramid. Cu(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(13), and two equivalent O(3) atoms. S(1) is bonded to one O(12), one O(15), one O(16), and one O(17) atom to form SO4 tetrahedra that share corners with two equivalent U(1)O7 pentagonal bipyramids and corners with two equivalent U(2)O7 pentagonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(13) is bonded in a 2-coordinate geometry to one Cu(2) and one O(10) atom. In the second O site, O(14) is bonded in a single-bond geometry to one U(2) atom. In the third O site, O(15) is bonded in a distorted single-bond geometry to one U(2) and one S(1) atom. In the fourth O site, O(16) is bonded in a distorted single-bond geometry to one U(1) and one S(1) atom. In the fifth O site, O(17) is bonded in a distorted single-bond geometry to one U(2) and one S(1) atom. In the sixth O site, O(2) is bonded in a distorted trigonal planar geometry to one U(2) and two equivalent U(1) atoms. In the seventh O site, O(3) is bonded in an L-shaped geometry to two equivalent Cu(2) atoms. In the eighth O site, O(5) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent U(2) atoms. In the ninth O site, O(6) is bonded in a single-bond geometry to one U(1) atom. In the tenth O site, O(8) is bonded in a single-bond geometry to one U(1) atom. In the eleventh O site, O(10) is bonded in a 2-coordinate geometry to one Cu(2) and one O(13) atom. In the twelfth O site, O(11) is bonded in a distorted single-bond geometry to one U(2) and one Cu(2) atom. In the thirteenth O site, O(12) is bonded in a distorted single-bond geometry to one U(1) and one S(1) atom. is represented by the CIF file [CIF]
data_U4Cu3(SO17)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.839
_cell_length_b   8.961
_cell_length_c   9.598
_cell_angle_alpha   71.031
_cell_angle_beta   72.234
_cell_angle_gamma   76.108
_symmetry_Int_Tables_number   1
_cell_volume   676.211
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.569  0.660  0.534  1.0
  U  U1  1  0.431  0.340  0.466  1.0
  U  U2  1  0.912  0.322  0.534  1.0
  U  U3  1  0.088  0.678  0.466  1.0
  Cu  Cu4  1  0.500  0.000  0.000  1.0
  Cu  Cu5  1  0.023  0.841  0.023  1.0
  Cu  Cu6  1  0.977  0.159  0.977  1.0
  S  S7  1  0.251  0.999  0.497  1.0
  S  S8  1  0.749  0.001  0.503  1.0
  O  O9  1  0.397  0.865  0.957  1.0
  O  O10  1  0.603  0.135  0.043  1.0
  O  O11  1  0.645  0.415  0.504  1.0
  O  O12  1  0.355  0.585  0.496  1.0
  O  O13  1  0.125  0.008  0.904  1.0
  O  O14  1  0.875  0.992  0.096  1.0
  O  O15  1  0.768  0.796  0.894  1.0
  O  O16  1  0.232  0.204  0.106  1.0
  O  O17  1  0.855  0.585  0.503  1.0
  O  O18  1  0.145  0.415  0.497  1.0
  O  O19  1  0.519  0.570  0.737  1.0
  O  O20  1  0.481  0.430  0.263  1.0
  O  O21  1  0.738  0.659  0.927  1.0
  O  O22  1  0.262  0.341  0.073  1.0
  O  O23  1  0.614  0.773  0.335  1.0
  O  O24  1  0.386  0.227  0.665  1.0
  O  O25  1  0.580  0.193  0.906  1.0
  O  O26  1  0.420  0.807  0.094  1.0
  O  O27  1  0.116  0.642  0.981  1.0
  O  O28  1  0.884  0.358  0.019  1.0
  O  O29  1  0.861  0.292  0.740  1.0
  O  O30  1  0.139  0.708  0.260  1.0
  O  O31  1  0.340  0.870  0.599  1.0
  O  O32  1  0.660  0.130  0.401  1.0
  O  O33  1  0.985  0.624  0.088  1.0
  O  O34  1  0.015  0.376  0.912  1.0
  O  O35  1  0.968  0.321  0.337  1.0
  O  O36  1  0.032  0.679  0.663  1.0
  O  O37  1  0.211  0.927  0.395  1.0
  O  O38  1  0.789  0.073  0.605  1.0
  O  O39  1  0.348  0.127  0.403  1.0
  O  O40  1  0.652  0.873  0.597  1.0
  O  O41  1  0.101  0.070  0.591  1.0
  O  O42  1  0.899  0.930  0.409  1.0
[/CIF]
.
The material structure described by (U2CuSO13)2CuO4(O2)2 crystallizes in the triclinic P-1 space group. The structure consists of two hydrogen peroxide molecules and one CuO4 cluster inside a U2CuSO13 framework. In the CuO4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(9) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cu(1) and one O(9) atom. In the second O site, O(9) is bonded in a 2-coordinate geometry to one Cu(1) and one O(1) atom. In the U2CuSO13 framework, there are two inequivalent U sites. In the first U site, U(1) is bonded to one O(12), one O(16), one O(5), one O(6), one O(8), and two equivalent O(2) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(2)O7 pentagonal bipyramids, corners with two equivalent S(1)O4 tetrahedra,  an edgeedge with one U(1)O7 pentagonal bipyramid, and  an edgeedge with one U(2)O7 pentagonal bipyramid. In the second U site, U(2) is bonded to one O(11), one O(14), one O(15), one O(17), one O(2), and two equivalent O(5) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent S(1)O4 tetrahedra,  an edgeedge with one U(1)O7 pentagonal bipyramid, and  an edgeedge with one U(2)O7 pentagonal bipyramid. Cu(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(13), and two equivalent O(3) atoms. S(1) is bonded to one O(12), one O(15), one O(16), and one O(17) atom to form SO4 tetrahedra that share corners with two equivalent U(1)O7 pentagonal bipyramids and corners with two equivalent U(2)O7 pentagonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(13) is bonded in a 2-coordinate geometry to one Cu(2) and one O(10) atom. In the second O site, O(14) is bonded in a single-bond geometry to one U(2) atom. In the third O site, O(15) is bonded in a distorted single-bond geometry to one U(2) and one S(1) atom. In the fourth O site, O(16) is bonded in a distorted single-bond geometry to one U(1) and one S(1) atom. In the fifth O site, O(17) is bonded in a distorted single-bond geometry to one U(2) and one S(1) atom. In the sixth O site, O(2) is bonded in a distorted trigonal planar geometry to one U(2) and two equivalent U(1) atoms. In the seventh O site, O(3) is bonded in an L-shaped geometry to two equivalent Cu(2) atoms. In the eighth O site, O(5) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent U(2) atoms. In the ninth O site, O(6) is bonded in a single-bond geometry to one U(1) atom. In the tenth O site, O(8) is bonded in a single-bond geometry to one U(1) atom. In the eleventh O site, O(10) is bonded in a 2-coordinate geometry to one Cu(2) and one O(13) atom. In the twelfth O site, O(11) is bonded in a distorted single-bond geometry to one U(2) and one Cu(2) atom. In the thirteenth O site, O(12) is bonded in a distorted single-bond geometry to one U(1) and one S(1) atom. is represented by the CIF file [CIF]
data_U4Cu3(SO17)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.839
_cell_length_b   8.961
_cell_length_c   9.598
_cell_angle_alpha   71.031
_cell_angle_beta   72.234
_cell_angle_gamma   76.108
_symmetry_Int_Tables_number   1
_cell_volume   676.211
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.569  0.660  0.534  1.0
  U  U1  1  0.431  0.340  0.466  1.0
  U  U2  1  0.912  0.322  0.534  1.0
  U  U3  1  0.088  0.678  0.466  1.0
  Cu  Cu4  1  0.500  0.000  0.000  1.0
  Cu  Cu5  1  0.023  0.841  0.023  1.0
  Cu  Cu6  1  0.977  0.159  0.977  1.0
  S  S7  1  0.251  0.999  0.497  1.0
  S  S8  1  0.749  0.001  0.503  1.0
  O  O9  1  0.397  0.865  0.957  1.0
  O  O10  1  0.603  0.135  0.043  1.0
  O  O11  1  0.645  0.415  0.504  1.0
  O  O12  1  0.355  0.585  0.496  1.0
  O  O13  1  0.125  0.008  0.904  1.0
  O  O14  1  0.875  0.992  0.096  1.0
  O  O15  1  0.768  0.796  0.894  1.0
  O  O16  1  0.232  0.204  0.106  1.0
  O  O17  1  0.855  0.585  0.503  1.0
  O  O18  1  0.145  0.415  0.497  1.0
  O  O19  1  0.519  0.570  0.737  1.0
  O  O20  1  0.481  0.430  0.263  1.0
  O  O21  1  0.738  0.659  0.927  1.0
  O  O22  1  0.262  0.341  0.073  1.0
  O  O23  1  0.614  0.773  0.335  1.0
  O  O24  1  0.386  0.227  0.665  1.0
  O  O25  1  0.580  0.193  0.906  1.0
  O  O26  1  0.420  0.807  0.094  1.0
  O  O27  1  0.116  0.642  0.981  1.0
  O  O28  1  0.884  0.358  0.019  1.0
  O  O29  1  0.861  0.292  0.740  1.0
  O  O30  1  0.139  0.708  0.260  1.0
  O  O31  1  0.340  0.870  0.599  1.0
  O  O32  1  0.660  0.130  0.401  1.0
  O  O33  1  0.985  0.624  0.088  1.0
  O  O34  1  0.015  0.376  0.912  1.0
  O  O35  1  0.968  0.321  0.337  1.0
  O  O36  1  0.032  0.679  0.663  1.0
  O  O37  1  0.211  0.927  0.395  1.0
  O  O38  1  0.789  0.073  0.605  1.0
  O  O39  1  0.348  0.127  0.403  1.0
  O  O40  1  0.652  0.873  0.597  1.0
  O  O41  1  0.101  0.070  0.591  1.0
  O  O42  1  0.899  0.930  0.409  1.0
[/CIF]
.