The structure described by Li4Co2Cu3Sb3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Cu(1)O6 octahedra,  a cornercorner with one Cu(2)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-64°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra,  an edgeedge with one Cu(2)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-72°. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-68°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted CoO6 octahedra that share corners with two equivalent Cu(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cu(1)O6 octahedra,  an edgeedge with one Cu(2)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the second Co site, Co(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted CoO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Cu(3)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second Cu site, Cu(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-55°. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Cu(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the third Sb site, Sb(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Cu(3)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Co(1), one Cu(3), and one Sb(2) atom to form distorted OLiCoCuSb trigonal pyramids that share  a cornercorner with one O(2)LiCoCu2 tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra,  a cornercorner with one O(4)LiCu2Sb tetrahedra, corners with two equivalent O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(6)LiCoCuSb trigonal pyramid,  an edgeedge with one O(6)LiCoCuSb trigonal pyramid, and  an edgeedge with one O(5)LiCuSb2 trigonal pyramid. In the second O site, O(2) is bonded to one Li(4), one Co(1), one Cu(1), and one Cu(2) atom to form distorted OLiCoCu2 tetrahedra that share corners with two equivalent O(4)LiCu2Sb tetrahedra,  a cornercorner with one O(1)LiCoCuSb trigonal pyramid,  a cornercorner with one O(6)LiCoCuSb trigonal pyramid, and  an edgeedge with one O(3)LiCu2Sb trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Cu(1), one Cu(2), and one Sb(1) atom to form distorted OLiCu2Sb trigonal pyramids that share  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra, corners with three equivalent O(4)LiCu2Sb tetrahedra, and  an edgeedge with one O(2)LiCoCu2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Cu(1), one Cu(2), and one Sb(1) atom to form OLiCu2Sb tetrahedra that share corners with two equivalent O(2)LiCoCu2 tetrahedra,  a cornercorner with one O(1)LiCoCuSb trigonal pyramid,  a cornercorner with one O(6)LiCoCuSb trigonal pyramid, and corners with three equivalent O(3)LiCu2Sb trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Cu(3), one Sb(2), and one Sb(3) atom to form a mixture of distorted edge and corner-sharing OLiCuSb2 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(3), one Co(1), one Cu(3), and one Sb(3) atom to form distorted OLiCoCuSb trigonal pyramids that share  a cornercorner with one O(2)LiCoCu2 tetrahedra,  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(4)LiCu2Sb tetrahedra, corners with two equivalent O(12)LiCoCuSb tetrahedra,  a cornercorner with one O(1)LiCoCuSb trigonal pyramid,  an edgeedge with one O(1)LiCoCuSb trigonal pyramid, and  an edgeedge with one O(5)LiCuSb2 trigonal pyramid. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(1), one Cu(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(1), one Cu(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(2), one Cu(1), and one Cu(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(1), one Sb(2), and one Sb(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Co(2), one Cu(3), and one Sb(2) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(12)LiCoCuSb tetrahedra,  a cornercorner with one O(6)LiCoCuSb trigonal pyramid,  a cornercorner with one O(3)LiCu2Sb trigonal pyramid, corners with two equivalent O(1)LiCoCuSb trigonal pyramids, corners with two equivalent O(5)LiCuSb2 trigonal pyramids, and  an edgeedge with one O(12)LiCoCuSb tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one Co(2), one Cu(3), and one Sb(3) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(1)LiCoCuSb trigonal pyramid,  a cornercorner with one O(3)LiCu2Sb trigonal pyramid, corners with two equivalent O(6)LiCoCuSb trigonal pyramids, corners with two equivalent O(5)LiCuSb2 trigonal pyramids, and  an edgeedge with one O(11)LiCoCuSb tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Cu(3), one Sb(2), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(2), one Cu(1), and one Sb(1) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Li(1), one Co(2), one Sb(2), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(2), one Cu(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li4Co2Cu3Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.050
_cell_length_b   6.072
_cell_length_c   9.693
_cell_angle_alpha   89.358
_cell_angle_beta   89.214
_cell_angle_gamma   60.233
_symmetry_Int_Tables_number   1
_cell_volume   309.082
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.671  0.670  0.898  1.0
  Li  Li1  1  0.012  0.012  0.006  1.0
  Li  Li2  1  0.025  0.025  0.487  1.0
  Li  Li3  1  0.331  0.330  0.384  1.0
  Co  Co4  1  0.645  0.644  0.475  1.0
  Co  Co5  1  0.323  0.325  0.001  1.0
  Cu  Cu6  1  0.337  0.827  0.211  1.0
  Cu  Cu7  1  0.828  0.338  0.211  1.0
  Cu  Cu8  1  0.167  0.167  0.720  1.0
  Sb  Sb9  1  0.828  0.829  0.215  1.0
  Sb  Sb10  1  0.167  0.661  0.714  1.0
  Sb  Sb11  1  0.661  0.166  0.714  1.0
  O  O12  1  0.320  0.832  0.605  1.0
  O  O13  1  0.524  0.510  0.354  1.0
  O  O14  1  0.664  0.663  0.108  1.0
  O  O15  1  0.001  0.004  0.302  1.0
  O  O16  1  0.987  0.986  0.822  1.0
  O  O17  1  0.835  0.319  0.606  1.0
  O  O18  1  0.520  0.962  0.341  1.0
  O  O19  1  0.963  0.525  0.342  1.0
  O  O20  1  0.167  0.185  0.090  1.0
  O  O21  1  0.842  0.842  0.598  1.0
  O  O22  1  0.036  0.488  0.835  1.0
  O  O23  1  0.486  0.036  0.836  1.0
  O  O24  1  0.344  0.344  0.597  1.0
  O  O25  1  0.155  0.678  0.100  1.0
  O  O26  1  0.483  0.482  0.838  1.0
  O  O27  1  0.676  0.152  0.099  1.0
[/CIF]
.
The structure described by Li4Co2Cu3Sb3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Cu(1)O6 octahedra,  a cornercorner with one Cu(2)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-64°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra,  an edgeedge with one Cu(2)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-72°. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-68°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted CoO6 octahedra that share corners with two equivalent Cu(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cu(1)O6 octahedra,  an edgeedge with one Cu(2)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the second Co site, Co(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted CoO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Cu(3)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second Cu site, Cu(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-55°. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Cu(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the third Sb site, Sb(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Cu(3)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Co(1), one Cu(3), and one Sb(2) atom to form distorted OLiCoCuSb trigonal pyramids that share  a cornercorner with one O(2)LiCoCu2 tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra,  a cornercorner with one O(4)LiCu2Sb tetrahedra, corners with two equivalent O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(6)LiCoCuSb trigonal pyramid,  an edgeedge with one O(6)LiCoCuSb trigonal pyramid, and  an edgeedge with one O(5)LiCuSb2 trigonal pyramid. In the second O site, O(2) is bonded to one Li(4), one Co(1), one Cu(1), and one Cu(2) atom to form distorted OLiCoCu2 tetrahedra that share corners with two equivalent O(4)LiCu2Sb tetrahedra,  a cornercorner with one O(1)LiCoCuSb trigonal pyramid,  a cornercorner with one O(6)LiCoCuSb trigonal pyramid, and  an edgeedge with one O(3)LiCu2Sb trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Cu(1), one Cu(2), and one Sb(1) atom to form distorted OLiCu2Sb trigonal pyramids that share  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra, corners with three equivalent O(4)LiCu2Sb tetrahedra, and  an edgeedge with one O(2)LiCoCu2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Cu(1), one Cu(2), and one Sb(1) atom to form OLiCu2Sb tetrahedra that share corners with two equivalent O(2)LiCoCu2 tetrahedra,  a cornercorner with one O(1)LiCoCuSb trigonal pyramid,  a cornercorner with one O(6)LiCoCuSb trigonal pyramid, and corners with three equivalent O(3)LiCu2Sb trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Cu(3), one Sb(2), and one Sb(3) atom to form a mixture of distorted edge and corner-sharing OLiCuSb2 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(3), one Co(1), one Cu(3), and one Sb(3) atom to form distorted OLiCoCuSb trigonal pyramids that share  a cornercorner with one O(2)LiCoCu2 tetrahedra,  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(4)LiCu2Sb tetrahedra, corners with two equivalent O(12)LiCoCuSb tetrahedra,  a cornercorner with one O(1)LiCoCuSb trigonal pyramid,  an edgeedge with one O(1)LiCoCuSb trigonal pyramid, and  an edgeedge with one O(5)LiCuSb2 trigonal pyramid. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(1), one Cu(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(1), one Cu(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(2), one Cu(1), and one Cu(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(1), one Sb(2), and one Sb(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Co(2), one Cu(3), and one Sb(2) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(12)LiCoCuSb tetrahedra,  a cornercorner with one O(6)LiCoCuSb trigonal pyramid,  a cornercorner with one O(3)LiCu2Sb trigonal pyramid, corners with two equivalent O(1)LiCoCuSb trigonal pyramids, corners with two equivalent O(5)LiCuSb2 trigonal pyramids, and  an edgeedge with one O(12)LiCoCuSb tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one Co(2), one Cu(3), and one Sb(3) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(1)LiCoCuSb trigonal pyramid,  a cornercorner with one O(3)LiCu2Sb trigonal pyramid, corners with two equivalent O(6)LiCoCuSb trigonal pyramids, corners with two equivalent O(5)LiCuSb2 trigonal pyramids, and  an edgeedge with one O(11)LiCoCuSb tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Cu(3), one Sb(2), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(2), one Cu(1), and one Sb(1) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Li(1), one Co(2), one Sb(2), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(2), one Cu(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li4Co2Cu3Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.050
_cell_length_b   6.072
_cell_length_c   9.693
_cell_angle_alpha   89.358
_cell_angle_beta   89.214
_cell_angle_gamma   60.233
_symmetry_Int_Tables_number   1
_cell_volume   309.082
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.671  0.670  0.898  1.0
  Li  Li1  1  0.012  0.012  0.006  1.0
  Li  Li2  1  0.025  0.025  0.487  1.0
  Li  Li3  1  0.331  0.330  0.384  1.0
  Co  Co4  1  0.645  0.644  0.475  1.0
  Co  Co5  1  0.323  0.325  0.001  1.0
  Cu  Cu6  1  0.337  0.827  0.211  1.0
  Cu  Cu7  1  0.828  0.338  0.211  1.0
  Cu  Cu8  1  0.167  0.167  0.720  1.0
  Sb  Sb9  1  0.828  0.829  0.215  1.0
  Sb  Sb10  1  0.167  0.661  0.714  1.0
  Sb  Sb11  1  0.661  0.166  0.714  1.0
  O  O12  1  0.320  0.832  0.605  1.0
  O  O13  1  0.524  0.510  0.354  1.0
  O  O14  1  0.664  0.663  0.108  1.0
  O  O15  1  0.001  0.004  0.302  1.0
  O  O16  1  0.987  0.986  0.822  1.0
  O  O17  1  0.835  0.319  0.606  1.0
  O  O18  1  0.520  0.962  0.341  1.0
  O  O19  1  0.963  0.525  0.342  1.0
  O  O20  1  0.167  0.185  0.090  1.0
  O  O21  1  0.842  0.842  0.598  1.0
  O  O22  1  0.036  0.488  0.835  1.0
  O  O23  1  0.486  0.036  0.836  1.0
  O  O24  1  0.344  0.344  0.597  1.0
  O  O25  1  0.155  0.678  0.100  1.0
  O  O26  1  0.483  0.482  0.838  1.0
  O  O27  1  0.676  0.152  0.099  1.0
[/CIF]
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