The material structure described by KMnHP3O10 crystallizes in the triclinic P1 space group. There are four inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one O(23), one O(25), one O(27), one O(33), one O(37), one O(7), and one O(9) atom. In the second K site, K(2) is bonded in a 7-coordinate geometry to one O(10), one O(24), one O(26), one O(28), one O(34), one O(38), and one O(8) atom. In the third K site, K(3) is bonded in a 7-coordinate geometry to one O(11), one O(21), one O(25), one O(27), one O(35), one O(39), and one O(5) atom. In the fourth K site, K(4) is bonded in a 7-coordinate geometry to one O(12), one O(22), one O(26), one O(28), one O(36), one O(40), and one O(6) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(21), one O(23), one O(29), and one O(31) atom to form MnO6 octahedra that share  a cornercorner with one P(11)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  a cornercorner with one P(9)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(11), one O(22), one O(24), one O(30), one O(32), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(12)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. In the third Mn site, Mn(3) is bonded to one O(17), one O(20), one O(25), one O(28), one O(37), and one O(40) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(11)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one O(18), one O(19), one O(26), one O(27), one O(38), and one O(39) atom to form MnO6 octahedra that share  a cornercorner with one P(12)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  a cornercorner with one P(9)O4 tetrahedra. There are twelve inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(17), one O(34), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and  a cornercorner with one P(12)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-46°. In the second P site, P(2) is bonded to one O(10), one O(18), one O(2), and one O(33) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one P(11)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-46°. In the third P site, P(3) is bonded to one O(11), one O(19), one O(3), and one O(36) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one P(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-46°. In the fourth P site, P(4) is bonded to one O(12), one O(20), one O(35), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and  a cornercorner with one P(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-46°. In the fifth P site, P(5) is bonded to one O(13), one O(21), one O(25), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and  a cornercorner with one P(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the sixth P site, P(6) is bonded to one O(14), one O(22), one O(26), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one P(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the seventh P site, P(7) is bonded to one O(15), one O(23), one O(27), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one P(12)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the eighth P site, P(8) is bonded to one O(16), one O(24), one O(28), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and  a cornercorner with one P(11)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the ninth P site, P(9) is bonded to one O(14), one O(29), one O(39), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the tenth P site, P(10) is bonded to one O(13), one O(3), one O(30), and one O(40) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the eleventh P site, P(11) is bonded to one O(16), one O(2), one O(31), and one O(37) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the twelfth P site, P(12) is bonded to one O(1), one O(15), one O(32), and one O(38) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-54°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(6) and one O(7) atom. In the second H site, H(2) is bonded in a linear geometry to one O(5) and one O(8) atom. In the third H site, H(3) is bonded in a linear geometry to one O(34) and one O(36) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(33) and one O(35) atom. There are forty inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(12) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(11) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(10) and one P(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(4) and one P(9) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(3), one P(6), and one H(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(4), one P(5), and one H(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(8), and one H(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one K(2), one P(7), and one H(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one K(1), one Mn(2), and one P(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one K(2), one Mn(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one K(3), one Mn(2), and one P(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one K(4), one Mn(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one P(10) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one P(6) and one P(9) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one P(12) and one P(7) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one P(11) and one P(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(1) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Mn(4) and one P(2) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Mn(4) and one P(3) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(4) atom. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one K(3), one Mn(1), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one K(4), one Mn(2), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one K(1), one Mn(1), and one P(7) atom. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one K(2), one Mn(2), and one P(8) atom. In the twenty-fifth O site, O(25) is bonded in a 2-coordinate geometry to one K(1), one K(3), one Mn(3), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one K(2), one K(4), one Mn(4), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one K(1), one K(3), one Mn(4), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one K(2), one K(4), one Mn(3), and one P(8) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(9) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one P(10) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(11) atom. In the thirty-second O site, O(32) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one P(12) atom. In the thirty-third O site, O(33) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(2), and one H(4) atom. In the thirty-fourth O site, O(34) is bonded in a distorted bent 120 degrees geometry to one K(2), one P(1), and one H(3) atom. In the thirty-fifth O site, O(35) is bonded in a distorted bent 120 degrees geometry to one K(3), one P(4), and one H(4) atom. In the thirty-sixth O site, O(36) is bonded in a distorted bent 120 degrees geometry to one K(4), one P(3), and one H(3) atom. In the thirty-seventh O site, O(37) is bonded in a 2-coordinate geometry to one K(1), one Mn(3), and one P(11) atom. In the thirty-eighth O site, O(38) is bonded in a 2-coordinate geometry to one K(2), one Mn(4), and one P(12) atom. In the thirty-ninth O site, O(39) is bonded in a 2-coordinate geometry to one K(3), one Mn(4), and one P(9) atom. In the fortieth O site, O(40) is bonded in a 2-coordinate geometry to one K(4), one Mn(3), and one P(10) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KMnP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.300
_cell_length_b   7.428
_cell_length_c   9.299
_cell_angle_alpha   71.185
_cell_angle_beta   73.515
_cell_angle_gamma   70.491
_symmetry_Int_Tables_number   1
_cell_volume   441.029
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  1.000  0.500  0.500  1.0
  H  H1  1  0.500  1.000  1.000  1.0
  K  K2  1  0.422  0.547  0.257  1.0
  K  K3  1  0.578  0.453  0.743  1.0
  Mn  Mn4  1  0.000  0.500  1.000  1.0
  Mn  Mn5  1  0.500  0.000  0.500  1.0
  O  O6  1  0.047  0.054  0.283  1.0
  O  O7  1  0.952  0.946  0.717  1.0
  O  O8  1  0.979  0.398  0.631  1.0
  O  O9  1  0.021  0.602  0.369  1.0
  O  O10  1  0.213  0.329  0.113  1.0
  O  O11  1  0.787  0.670  0.887  1.0
  O  O12  1  0.138  0.095  0.820  1.0
  O  O13  1  0.862  0.905  0.180  1.0
  O  O14  1  0.316  0.109  0.359  1.0
  O  O15  1  0.683  0.891  0.641  1.0
  O  O16  1  0.173  0.420  0.814  1.0
  O  O17  1  0.828  0.580  0.186  1.0
  O  O18  1  0.359  0.271  0.588  1.0
  O  O19  1  0.640  0.729  0.411  1.0
  O  O20  1  0.150  0.735  0.932  1.0
  O  O21  1  0.850  0.265  0.068  1.0
  O  O22  1  0.392  0.964  0.125  1.0
  O  O23  1  0.608  0.036  0.875  1.0
  O  O24  1  0.677  0.149  0.347  1.0
  O  O25  1  0.323  0.851  0.653  1.0
  P  P26  1  0.255  0.117  0.214  1.0
  P  P27  1  0.745  0.883  0.786  1.0
  P  P28  1  0.165  0.307  0.704  1.0
  P  P29  1  0.835  0.693  0.296  1.0
  P  P30  1  0.148  0.896  0.785  1.0
  P  P31  1  0.852  0.104  0.215  1.0
[/CIF]
.
The material structure described by KMnHP3O10 crystallizes in the triclinic P1 space group. There are four inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one O(23), one O(25), one O(27), one O(33), one O(37), one O(7), and one O(9) atom. In the second K site, K(2) is bonded in a 7-coordinate geometry to one O(10), one O(24), one O(26), one O(28), one O(34), one O(38), and one O(8) atom. In the third K site, K(3) is bonded in a 7-coordinate geometry to one O(11), one O(21), one O(25), one O(27), one O(35), one O(39), and one O(5) atom. In the fourth K site, K(4) is bonded in a 7-coordinate geometry to one O(12), one O(22), one O(26), one O(28), one O(36), one O(40), and one O(6) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(21), one O(23), one O(29), and one O(31) atom to form MnO6 octahedra that share  a cornercorner with one P(11)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  a cornercorner with one P(9)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(11), one O(22), one O(24), one O(30), one O(32), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(12)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. In the third Mn site, Mn(3) is bonded to one O(17), one O(20), one O(25), one O(28), one O(37), and one O(40) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(11)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one O(18), one O(19), one O(26), one O(27), one O(38), and one O(39) atom to form MnO6 octahedra that share  a cornercorner with one P(12)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  a cornercorner with one P(9)O4 tetrahedra. There are twelve inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(17), one O(34), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and  a cornercorner with one P(12)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-46°. In the second P site, P(2) is bonded to one O(10), one O(18), one O(2), and one O(33) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one P(11)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-46°. In the third P site, P(3) is bonded to one O(11), one O(19), one O(3), and one O(36) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one P(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-46°. In the fourth P site, P(4) is bonded to one O(12), one O(20), one O(35), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and  a cornercorner with one P(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-46°. In the fifth P site, P(5) is bonded to one O(13), one O(21), one O(25), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and  a cornercorner with one P(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the sixth P site, P(6) is bonded to one O(14), one O(22), one O(26), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one P(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the seventh P site, P(7) is bonded to one O(15), one O(23), one O(27), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one P(12)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the eighth P site, P(8) is bonded to one O(16), one O(24), one O(28), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and  a cornercorner with one P(11)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the ninth P site, P(9) is bonded to one O(14), one O(29), one O(39), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the tenth P site, P(10) is bonded to one O(13), one O(3), one O(30), and one O(40) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the eleventh P site, P(11) is bonded to one O(16), one O(2), one O(31), and one O(37) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the twelfth P site, P(12) is bonded to one O(1), one O(15), one O(32), and one O(38) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-54°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(6) and one O(7) atom. In the second H site, H(2) is bonded in a linear geometry to one O(5) and one O(8) atom. In the third H site, H(3) is bonded in a linear geometry to one O(34) and one O(36) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(33) and one O(35) atom. There are forty inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(12) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(11) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(10) and one P(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(4) and one P(9) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(3), one P(6), and one H(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(4), one P(5), and one H(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(8), and one H(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one K(2), one P(7), and one H(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one K(1), one Mn(2), and one P(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one K(2), one Mn(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one K(3), one Mn(2), and one P(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one K(4), one Mn(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one P(10) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one P(6) and one P(9) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one P(12) and one P(7) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one P(11) and one P(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(1) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Mn(4) and one P(2) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Mn(4) and one P(3) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(4) atom. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one K(3), one Mn(1), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one K(4), one Mn(2), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one K(1), one Mn(1), and one P(7) atom. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one K(2), one Mn(2), and one P(8) atom. In the twenty-fifth O site, O(25) is bonded in a 2-coordinate geometry to one K(1), one K(3), one Mn(3), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one K(2), one K(4), one Mn(4), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one K(1), one K(3), one Mn(4), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one K(2), one K(4), one Mn(3), and one P(8) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(9) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one P(10) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(11) atom. In the thirty-second O site, O(32) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one P(12) atom. In the thirty-third O site, O(33) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(2), and one H(4) atom. In the thirty-fourth O site, O(34) is bonded in a distorted bent 120 degrees geometry to one K(2), one P(1), and one H(3) atom. In the thirty-fifth O site, O(35) is bonded in a distorted bent 120 degrees geometry to one K(3), one P(4), and one H(4) atom. In the thirty-sixth O site, O(36) is bonded in a distorted bent 120 degrees geometry to one K(4), one P(3), and one H(3) atom. In the thirty-seventh O site, O(37) is bonded in a 2-coordinate geometry to one K(1), one Mn(3), and one P(11) atom. In the thirty-eighth O site, O(38) is bonded in a 2-coordinate geometry to one K(2), one Mn(4), and one P(12) atom. In the thirty-ninth O site, O(39) is bonded in a 2-coordinate geometry to one K(3), one Mn(4), and one P(9) atom. In the fortieth O site, O(40) is bonded in a 2-coordinate geometry to one K(4), one Mn(3), and one P(10) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KMnP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.300
_cell_length_b   7.428
_cell_length_c   9.299
_cell_angle_alpha   71.185
_cell_angle_beta   73.515
_cell_angle_gamma   70.491
_symmetry_Int_Tables_number   1
_cell_volume   441.029
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  1.000  0.500  0.500  1.0
  H  H1  1  0.500  1.000  1.000  1.0
  K  K2  1  0.422  0.547  0.257  1.0
  K  K3  1  0.578  0.453  0.743  1.0
  Mn  Mn4  1  0.000  0.500  1.000  1.0
  Mn  Mn5  1  0.500  0.000  0.500  1.0
  O  O6  1  0.047  0.054  0.283  1.0
  O  O7  1  0.952  0.946  0.717  1.0
  O  O8  1  0.979  0.398  0.631  1.0
  O  O9  1  0.021  0.602  0.369  1.0
  O  O10  1  0.213  0.329  0.113  1.0
  O  O11  1  0.787  0.670  0.887  1.0
  O  O12  1  0.138  0.095  0.820  1.0
  O  O13  1  0.862  0.905  0.180  1.0
  O  O14  1  0.316  0.109  0.359  1.0
  O  O15  1  0.683  0.891  0.641  1.0
  O  O16  1  0.173  0.420  0.814  1.0
  O  O17  1  0.828  0.580  0.186  1.0
  O  O18  1  0.359  0.271  0.588  1.0
  O  O19  1  0.640  0.729  0.411  1.0
  O  O20  1  0.150  0.735  0.932  1.0
  O  O21  1  0.850  0.265  0.068  1.0
  O  O22  1  0.392  0.964  0.125  1.0
  O  O23  1  0.608  0.036  0.875  1.0
  O  O24  1  0.677  0.149  0.347  1.0
  O  O25  1  0.323  0.851  0.653  1.0
  P  P26  1  0.255  0.117  0.214  1.0
  P  P27  1  0.745  0.883  0.786  1.0
  P  P28  1  0.165  0.307  0.704  1.0
  P  P29  1  0.835  0.693  0.296  1.0
  P  P30  1  0.148  0.896  0.785  1.0
  P  P31  1  0.852  0.104  0.215  1.0
[/CIF]
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