The compound described by Eu5Pd2 crystallizes in the monoclinic C2/c space group. There are three inequivalent Eu sites. In the first Eu site, Eu(1) is bonded in a 2-coordinate geometry to three equivalent Pd(1) atoms. In the second Eu site, Eu(3) is bonded to four equivalent Pd(1) atoms to form distorted edge-sharing EuPd4 tetrahedra. In the third Eu site, Eu(2) is bonded in a 3-coordinate geometry to three equivalent Pd(1) atoms. Pd(1) is bonded in a 8-coordinate geometry to two equivalent Eu(3), three equivalent Eu(1), and three equivalent Eu(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Eu5Pd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.820
_cell_length_b   7.826
_cell_length_c   9.138
_cell_angle_alpha   96.847
_cell_angle_beta   111.928
_cell_angle_gamma   89.959
_symmetry_Int_Tables_number   1
_cell_volume   448.738
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.982  0.921  0.184  1.0
  Eu  Eu1  1  0.798  0.580  0.816  1.0
  Eu  Eu2  1  0.018  0.079  0.816  1.0
  Eu  Eu3  1  0.202  0.420  0.184  1.0
  Eu  Eu4  1  0.640  0.817  0.437  1.0
  Eu  Eu5  1  0.203  0.683  0.563  1.0
  Eu  Eu6  1  0.360  0.183  0.563  1.0
  Eu  Eu7  1  0.797  0.317  0.437  1.0
  Eu  Eu8  1  0.420  0.750  0.000  1.0
  Eu  Eu9  1  0.580  0.250  1.000  1.0
  Pd  Pd10  1  0.812  0.579  0.217  1.0
  Pd  Pd11  1  0.595  0.921  0.783  1.0
  Pd  Pd12  1  0.188  0.421  0.783  1.0
  Pd  Pd13  1  0.405  0.079  0.217  1.0
[/CIF]
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The compound described by Eu5Pd2 crystallizes in the monoclinic C2/c space group. There are three inequivalent Eu sites. In the first Eu site, Eu(1) is bonded in a 2-coordinate geometry to three equivalent Pd(1) atoms. In the second Eu site, Eu(3) is bonded to four equivalent Pd(1) atoms to form distorted edge-sharing EuPd4 tetrahedra. In the third Eu site, Eu(2) is bonded in a 3-coordinate geometry to three equivalent Pd(1) atoms. Pd(1) is bonded in a 8-coordinate geometry to two equivalent Eu(3), three equivalent Eu(1), and three equivalent Eu(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Eu5Pd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.820
_cell_length_b   7.826
_cell_length_c   9.138
_cell_angle_alpha   96.847
_cell_angle_beta   111.928
_cell_angle_gamma   89.959
_symmetry_Int_Tables_number   1
_cell_volume   448.738
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.982  0.921  0.184  1.0
  Eu  Eu1  1  0.798  0.580  0.816  1.0
  Eu  Eu2  1  0.018  0.079  0.816  1.0
  Eu  Eu3  1  0.202  0.420  0.184  1.0
  Eu  Eu4  1  0.640  0.817  0.437  1.0
  Eu  Eu5  1  0.203  0.683  0.563  1.0
  Eu  Eu6  1  0.360  0.183  0.563  1.0
  Eu  Eu7  1  0.797  0.317  0.437  1.0
  Eu  Eu8  1  0.420  0.750  0.000  1.0
  Eu  Eu9  1  0.580  0.250  1.000  1.0
  Pd  Pd10  1  0.812  0.579  0.217  1.0
  Pd  Pd11  1  0.595  0.921  0.783  1.0
  Pd  Pd12  1  0.188  0.421  0.783  1.0
  Pd  Pd13  1  0.405  0.079  0.217  1.0
[/CIF]
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