The crystal structure described by KSmHP3O10 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Sm(1) is bonded in a 8-coordinate geometry to one O(5), one O(6), one O(8), one O(9), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form corner-sharing PO4 tetrahedra. H(1) is bonded in a linear geometry to one O(1) and one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one K(1), one P(1), and one H(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1), two equivalent Sm(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one Sm(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one Sm(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one K(1), one P(2), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(1), one Sm(1), and one P(3) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to one K(1), one Sm(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one P(3) and one H(1) atom. is represented by the CIF card [CIF]
data_KSmP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.041
_cell_length_b   7.819
_cell_length_c   8.669
_cell_angle_alpha   73.730
_cell_angle_beta   73.583
_cell_angle_gamma   82.565
_symmetry_Int_Tables_number   1
_cell_volume   438.827
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.789  0.285  0.464  1.0
  K  K1  1  0.211  0.715  0.536  1.0
  Sm  Sm2  1  0.773  0.369  0.989  1.0
  Sm  Sm3  1  0.227  0.631  0.011  1.0
  P  P4  1  0.672  0.692  0.158  1.0
  P  P5  1  0.328  0.308  0.842  1.0
  P  P6  1  0.855  0.961  0.861  1.0
  P  P7  1  0.145  0.039  0.139  1.0
  P  P8  1  0.673  0.769  0.686  1.0
  P  P9  1  0.327  0.231  0.314  1.0
  H  H10  1  0.689  0.801  0.421  1.0
  H  H11  1  0.311  0.199  0.579  1.0
  O  O12  1  0.589  0.702  0.335  1.0
  O  O13  1  0.411  0.298  0.665  1.0
  O  O14  1  0.534  0.630  0.077  1.0
  O  O15  1  0.466  0.370  0.923  1.0
  O  O16  1  0.866  0.572  0.127  1.0
  O  O17  1  0.134  0.428  0.873  1.0
  O  O18  1  0.723  0.897  0.050  1.0
  O  O19  1  0.277  0.103  0.950  1.0
  O  O20  1  0.955  0.153  0.164  1.0
  O  O21  1  0.045  0.847  0.836  1.0
  O  O22  1  0.864  0.160  0.826  1.0
  O  O23  1  0.136  0.840  0.174  1.0
  O  O24  1  0.721  0.935  0.747  1.0
  O  O25  1  0.279  0.065  0.253  1.0
  O  O26  1  0.548  0.251  0.256  1.0
  O  O27  1  0.452  0.749  0.744  1.0
  O  O28  1  0.805  0.607  0.741  1.0
  O  O29  1  0.195  0.393  0.259  1.0
  O  O30  1  0.746  0.854  0.493  1.0
  O  O31  1  0.254  0.146  0.507  1.0
[/CIF]
.
The crystal structure described by KSmHP3O10 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Sm(1) is bonded in a 8-coordinate geometry to one O(5), one O(6), one O(8), one O(9), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form corner-sharing PO4 tetrahedra. H(1) is bonded in a linear geometry to one O(1) and one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one K(1), one P(1), and one H(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1), two equivalent Sm(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one Sm(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one Sm(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one K(1), one P(2), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(1), one Sm(1), and one P(3) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to one K(1), one Sm(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one P(3) and one H(1) atom. is represented by the CIF card [CIF]
data_KSmP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.041
_cell_length_b   7.819
_cell_length_c   8.669
_cell_angle_alpha   73.730
_cell_angle_beta   73.583
_cell_angle_gamma   82.565
_symmetry_Int_Tables_number   1
_cell_volume   438.827
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.789  0.285  0.464  1.0
  K  K1  1  0.211  0.715  0.536  1.0
  Sm  Sm2  1  0.773  0.369  0.989  1.0
  Sm  Sm3  1  0.227  0.631  0.011  1.0
  P  P4  1  0.672  0.692  0.158  1.0
  P  P5  1  0.328  0.308  0.842  1.0
  P  P6  1  0.855  0.961  0.861  1.0
  P  P7  1  0.145  0.039  0.139  1.0
  P  P8  1  0.673  0.769  0.686  1.0
  P  P9  1  0.327  0.231  0.314  1.0
  H  H10  1  0.689  0.801  0.421  1.0
  H  H11  1  0.311  0.199  0.579  1.0
  O  O12  1  0.589  0.702  0.335  1.0
  O  O13  1  0.411  0.298  0.665  1.0
  O  O14  1  0.534  0.630  0.077  1.0
  O  O15  1  0.466  0.370  0.923  1.0
  O  O16  1  0.866  0.572  0.127  1.0
  O  O17  1  0.134  0.428  0.873  1.0
  O  O18  1  0.723  0.897  0.050  1.0
  O  O19  1  0.277  0.103  0.950  1.0
  O  O20  1  0.955  0.153  0.164  1.0
  O  O21  1  0.045  0.847  0.836  1.0
  O  O22  1  0.864  0.160  0.826  1.0
  O  O23  1  0.136  0.840  0.174  1.0
  O  O24  1  0.721  0.935  0.747  1.0
  O  O25  1  0.279  0.065  0.253  1.0
  O  O26  1  0.548  0.251  0.256  1.0
  O  O27  1  0.452  0.749  0.744  1.0
  O  O28  1  0.805  0.607  0.741  1.0
  O  O29  1  0.195  0.393  0.259  1.0
  O  O30  1  0.746  0.854  0.493  1.0
  O  O31  1  0.254  0.146  0.507  1.0
[/CIF]
.