The compound described by RbGaCl4 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 10-coordinate geometry to one Cl(1), three equivalent Cl(2), and six equivalent Cl(3) atoms. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted linear geometry to one Rb(1) and one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Ga(1) atom. is represented by the CIF file [CIF]
data_RbGaCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.098
_cell_length_b   9.364
_cell_length_c   11.190
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   743.775
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.827  0.683  1.0
  Rb  Rb1  1  0.250  0.173  0.317  1.0
  Rb  Rb2  1  0.250  0.327  0.817  1.0
  Rb  Rb3  1  0.750  0.673  0.183  1.0
  Ga  Ga4  1  0.250  0.811  0.932  1.0
  Ga  Ga5  1  0.750  0.189  0.068  1.0
  Ga  Ga6  1  0.750  0.311  0.568  1.0
  Ga  Ga7  1  0.250  0.689  0.432  1.0
  Cl  Cl8  1  0.250  0.923  0.103  1.0
  Cl  Cl9  1  0.750  0.077  0.897  1.0
  Cl  Cl10  1  0.750  0.423  0.397  1.0
  Cl  Cl11  1  0.250  0.577  0.603  1.0
  Cl  Cl12  1  0.250  0.955  0.780  1.0
  Cl  Cl13  1  0.750  0.045  0.220  1.0
  Cl  Cl14  1  0.750  0.455  0.720  1.0
  Cl  Cl15  1  0.250  0.545  0.280  1.0
  Cl  Cl16  1  0.499  0.826  0.420  1.0
  Cl  Cl17  1  0.999  0.174  0.580  1.0
  Cl  Cl18  1  0.501  0.326  0.080  1.0
  Cl  Cl19  1  0.001  0.674  0.920  1.0
  Cl  Cl20  1  0.501  0.174  0.580  1.0
  Cl  Cl21  1  0.001  0.826  0.420  1.0
  Cl  Cl22  1  0.499  0.674  0.920  1.0
  Cl  Cl23  1  0.999  0.326  0.080  1.0
[/CIF]
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The compound described by RbGaCl4 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 10-coordinate geometry to one Cl(1), three equivalent Cl(2), and six equivalent Cl(3) atoms. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted linear geometry to one Rb(1) and one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Ga(1) atom. is represented by the CIF file [CIF]
data_RbGaCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.098
_cell_length_b   9.364
_cell_length_c   11.190
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   743.775
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.827  0.683  1.0
  Rb  Rb1  1  0.250  0.173  0.317  1.0
  Rb  Rb2  1  0.250  0.327  0.817  1.0
  Rb  Rb3  1  0.750  0.673  0.183  1.0
  Ga  Ga4  1  0.250  0.811  0.932  1.0
  Ga  Ga5  1  0.750  0.189  0.068  1.0
  Ga  Ga6  1  0.750  0.311  0.568  1.0
  Ga  Ga7  1  0.250  0.689  0.432  1.0
  Cl  Cl8  1  0.250  0.923  0.103  1.0
  Cl  Cl9  1  0.750  0.077  0.897  1.0
  Cl  Cl10  1  0.750  0.423  0.397  1.0
  Cl  Cl11  1  0.250  0.577  0.603  1.0
  Cl  Cl12  1  0.250  0.955  0.780  1.0
  Cl  Cl13  1  0.750  0.045  0.220  1.0
  Cl  Cl14  1  0.750  0.455  0.720  1.0
  Cl  Cl15  1  0.250  0.545  0.280  1.0
  Cl  Cl16  1  0.499  0.826  0.420  1.0
  Cl  Cl17  1  0.999  0.174  0.580  1.0
  Cl  Cl18  1  0.501  0.326  0.080  1.0
  Cl  Cl19  1  0.001  0.674  0.920  1.0
  Cl  Cl20  1  0.501  0.174  0.580  1.0
  Cl  Cl21  1  0.001  0.826  0.420  1.0
  Cl  Cl22  1  0.499  0.674  0.920  1.0
  Cl  Cl23  1  0.999  0.326  0.080  1.0
[/CIF]
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