The material described by (Bi)5(AlCl4)3 is Iron carbide-derived structured and crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of thirty 7440-69-9 atoms and eighteen AlCl4 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF file [CIF]
data_Al3Bi5Cl12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.167
_cell_length_b   12.167
_cell_length_c   12.167
_cell_angle_alpha   58.428
_cell_angle_beta   58.428
_cell_angle_gamma   58.428
_symmetry_Int_Tables_number   1
_cell_volume   1227.798
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.224  0.750  0.276  1.0
  Al  Al1  1  0.776  0.250  0.724  1.0
  Al  Al2  1  0.724  0.776  0.250  1.0
  Al  Al3  1  0.276  0.224  0.750  1.0
  Al  Al4  1  0.250  0.724  0.776  1.0
  Al  Al5  1  0.750  0.276  0.224  1.0
  Bi  Bi6  1  0.909  0.591  0.750  1.0
  Bi  Bi7  1  0.671  0.671  0.671  1.0
  Bi  Bi8  1  0.171  0.171  0.171  1.0
  Bi  Bi9  1  0.409  0.250  0.091  1.0
  Bi  Bi10  1  0.329  0.329  0.329  1.0
  Bi  Bi11  1  0.091  0.409  0.250  1.0
  Bi  Bi12  1  0.829  0.829  0.829  1.0
  Bi  Bi13  1  0.591  0.750  0.909  1.0
  Bi  Bi14  1  0.750  0.909  0.591  1.0
  Bi  Bi15  1  0.250  0.091  0.409  1.0
  Cl  Cl16  1  0.075  0.694  0.960  1.0
  Cl  Cl17  1  0.112  0.268  0.696  1.0
  Cl  Cl18  1  0.460  0.194  0.575  1.0
  Cl  Cl19  1  0.696  0.112  0.268  1.0
  Cl  Cl20  1  0.694  0.960  0.075  1.0
  Cl  Cl21  1  0.306  0.040  0.925  1.0
  Cl  Cl22  1  0.732  0.304  0.888  1.0
  Cl  Cl23  1  0.888  0.732  0.304  1.0
  Cl  Cl24  1  0.575  0.460  0.194  1.0
  Cl  Cl25  1  0.196  0.768  0.612  1.0
  Cl  Cl26  1  0.960  0.075  0.694  1.0
  Cl  Cl27  1  0.040  0.925  0.306  1.0
  Cl  Cl28  1  0.268  0.696  0.112  1.0
  Cl  Cl29  1  0.540  0.806  0.425  1.0
  Cl  Cl30  1  0.806  0.425  0.540  1.0
  Cl  Cl31  1  0.304  0.888  0.732  1.0
  Cl  Cl32  1  0.768  0.612  0.196  1.0
  Cl  Cl33  1  0.388  0.804  0.232  1.0
  Cl  Cl34  1  0.232  0.388  0.804  1.0
  Cl  Cl35  1  0.925  0.306  0.040  1.0
  Cl  Cl36  1  0.804  0.232  0.388  1.0
  Cl  Cl37  1  0.194  0.575  0.460  1.0
  Cl  Cl38  1  0.612  0.196  0.768  1.0
  Cl  Cl39  1  0.425  0.540  0.806  1.0
[/CIF]
.
The material described by (Bi)5(AlCl4)3 is Iron carbide-derived structured and crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of thirty 7440-69-9 atoms and eighteen AlCl4 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF file [CIF]
data_Al3Bi5Cl12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.167
_cell_length_b   12.167
_cell_length_c   12.167
_cell_angle_alpha   58.428
_cell_angle_beta   58.428
_cell_angle_gamma   58.428
_symmetry_Int_Tables_number   1
_cell_volume   1227.798
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.224  0.750  0.276  1.0
  Al  Al1  1  0.776  0.250  0.724  1.0
  Al  Al2  1  0.724  0.776  0.250  1.0
  Al  Al3  1  0.276  0.224  0.750  1.0
  Al  Al4  1  0.250  0.724  0.776  1.0
  Al  Al5  1  0.750  0.276  0.224  1.0
  Bi  Bi6  1  0.909  0.591  0.750  1.0
  Bi  Bi7  1  0.671  0.671  0.671  1.0
  Bi  Bi8  1  0.171  0.171  0.171  1.0
  Bi  Bi9  1  0.409  0.250  0.091  1.0
  Bi  Bi10  1  0.329  0.329  0.329  1.0
  Bi  Bi11  1  0.091  0.409  0.250  1.0
  Bi  Bi12  1  0.829  0.829  0.829  1.0
  Bi  Bi13  1  0.591  0.750  0.909  1.0
  Bi  Bi14  1  0.750  0.909  0.591  1.0
  Bi  Bi15  1  0.250  0.091  0.409  1.0
  Cl  Cl16  1  0.075  0.694  0.960  1.0
  Cl  Cl17  1  0.112  0.268  0.696  1.0
  Cl  Cl18  1  0.460  0.194  0.575  1.0
  Cl  Cl19  1  0.696  0.112  0.268  1.0
  Cl  Cl20  1  0.694  0.960  0.075  1.0
  Cl  Cl21  1  0.306  0.040  0.925  1.0
  Cl  Cl22  1  0.732  0.304  0.888  1.0
  Cl  Cl23  1  0.888  0.732  0.304  1.0
  Cl  Cl24  1  0.575  0.460  0.194  1.0
  Cl  Cl25  1  0.196  0.768  0.612  1.0
  Cl  Cl26  1  0.960  0.075  0.694  1.0
  Cl  Cl27  1  0.040  0.925  0.306  1.0
  Cl  Cl28  1  0.268  0.696  0.112  1.0
  Cl  Cl29  1  0.540  0.806  0.425  1.0
  Cl  Cl30  1  0.806  0.425  0.540  1.0
  Cl  Cl31  1  0.304  0.888  0.732  1.0
  Cl  Cl32  1  0.768  0.612  0.196  1.0
  Cl  Cl33  1  0.388  0.804  0.232  1.0
  Cl  Cl34  1  0.232  0.388  0.804  1.0
  Cl  Cl35  1  0.925  0.306  0.040  1.0
  Cl  Cl36  1  0.804  0.232  0.388  1.0
  Cl  Cl37  1  0.194  0.575  0.460  1.0
  Cl  Cl38  1  0.612  0.196  0.768  1.0
  Cl  Cl39  1  0.425  0.540  0.806  1.0
[/CIF]
.