The material described by MoO2 crystallizes in the orthorhombic Fddd space group. Mo(1) is bonded to six equivalent O(1) atoms to form edge-sharing MoO6 octahedra. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_MoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.494
_cell_length_b   6.419
_cell_length_c   6.236
_cell_angle_alpha   61.726
_cell_angle_beta   60.521
_cell_angle_gamma   57.753
_symmetry_Int_Tables_number   1
_cell_volume   183.345
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.125  0.125  0.625  1.0
  Mo  Mo1  1  0.625  0.125  0.125  1.0
  Mo  Mo2  1  0.125  0.625  0.125  1.0
  Mo  Mo3  1  0.125  0.125  0.125  1.0
  O  O4  1  0.345  0.356  0.364  1.0
  O  O5  1  0.356  0.345  0.935  1.0
  O  O6  1  0.905  0.894  0.886  1.0
  O  O7  1  0.315  0.886  0.894  1.0
  O  O8  1  0.894  0.905  0.315  1.0
  O  O9  1  0.886  0.315  0.905  1.0
  O  O10  1  0.935  0.364  0.356  1.0
  O  O11  1  0.364  0.935  0.345  1.0
[/CIF]
.
The material described by MoO2 crystallizes in the orthorhombic Fddd space group. Mo(1) is bonded to six equivalent O(1) atoms to form edge-sharing MoO6 octahedra. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_MoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.494
_cell_length_b   6.419
_cell_length_c   6.236
_cell_angle_alpha   61.726
_cell_angle_beta   60.521
_cell_angle_gamma   57.753
_symmetry_Int_Tables_number   1
_cell_volume   183.345
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.125  0.125  0.625  1.0
  Mo  Mo1  1  0.625  0.125  0.125  1.0
  Mo  Mo2  1  0.125  0.625  0.125  1.0
  Mo  Mo3  1  0.125  0.125  0.125  1.0
  O  O4  1  0.345  0.356  0.364  1.0
  O  O5  1  0.356  0.345  0.935  1.0
  O  O6  1  0.905  0.894  0.886  1.0
  O  O7  1  0.315  0.886  0.894  1.0
  O  O8  1  0.894  0.905  0.315  1.0
  O  O9  1  0.886  0.315  0.905  1.0
  O  O10  1  0.935  0.364  0.356  1.0
  O  O11  1  0.364  0.935  0.345  1.0
[/CIF]
.