The crystal structure described by CsAg5Te3 crystallizes in the tetragonal P4_2/mnm space group. Cs(1) is bonded in a body-centered cubic geometry to four equivalent Te(1) and four equivalent Te(2) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent Ag(3), two equivalent Te(1), and two equivalent Te(2) atoms to form distorted face-sharing AgAg4Te4 tetrahedra. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to three equivalent Ag(3) and three equivalent Te(2) atoms. In the third Ag site, Ag(3) is bonded in a 9-coordinate geometry to two equivalent Ag(1), three equivalent Ag(2), one Te(1), and three equivalent Te(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 8-coordinate geometry to four equivalent Cs(1), two equivalent Ag(1), and two equivalent Ag(3) atoms. In the second Te site, Te(2) is bonded in a 9-coordinate geometry to two equivalent Cs(1), one Ag(1), three equivalent Ag(2), and three equivalent Ag(3) atoms. is represented by the CIF file [CIF]
data_CsAg5Te3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.797
_cell_length_b   14.797
_cell_length_c   4.604
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1008.051
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.888  0.112  0.500  1.0
  Cs  Cs1  1  0.612  0.612  0.000  1.0
  Cs  Cs2  1  0.388  0.388  0.000  1.0
  Cs  Cs3  1  0.112  0.888  0.500  1.0
  Ag  Ag4  1  0.678  0.322  0.000  1.0
  Ag  Ag5  1  0.822  0.822  0.500  1.0
  Ag  Ag6  1  0.178  0.178  0.500  1.0
  Ag  Ag7  1  0.322  0.678  0.000  1.0
  Ag  Ag8  1  0.398  0.983  0.500  1.0
  Ag  Ag9  1  0.602  0.017  0.500  1.0
  Ag  Ag10  1  0.517  0.898  0.000  1.0
  Ag  Ag11  1  0.483  0.102  0.000  1.0
  Ag  Ag12  1  0.983  0.398  0.500  1.0
  Ag  Ag13  1  0.898  0.517  0.000  1.0
  Ag  Ag14  1  0.102  0.483  0.000  1.0
  Ag  Ag15  1  0.017  0.602  0.500  1.0
  Ag  Ag16  1  0.420  0.788  0.500  1.0
  Ag  Ag17  1  0.580  0.212  0.500  1.0
  Ag  Ag18  1  0.712  0.920  0.000  1.0
  Ag  Ag19  1  0.288  0.080  0.000  1.0
  Ag  Ag20  1  0.212  0.580  0.500  1.0
  Ag  Ag21  1  0.080  0.288  0.000  1.0
  Ag  Ag22  1  0.920  0.712  0.000  1.0
  Ag  Ag23  1  0.788  0.420  0.500  1.0
  Te  Te24  1  0.101  0.101  0.000  1.0
  Te  Te25  1  0.601  0.399  0.500  1.0
  Te  Te26  1  0.399  0.601  0.500  1.0
  Te  Te27  1  0.899  0.899  0.000  1.0
  Te  Te28  1  0.328  0.883  0.000  1.0
  Te  Te29  1  0.672  0.117  0.000  1.0
  Te  Te30  1  0.617  0.828  0.500  1.0
  Te  Te31  1  0.383  0.172  0.500  1.0
  Te  Te32  1  0.883  0.328  0.000  1.0
  Te  Te33  1  0.828  0.617  0.500  1.0
  Te  Te34  1  0.172  0.383  0.500  1.0
  Te  Te35  1  0.117  0.672  0.000  1.0
[/CIF]
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The crystal structure described by CsAg5Te3 crystallizes in the tetragonal P4_2/mnm space group. Cs(1) is bonded in a body-centered cubic geometry to four equivalent Te(1) and four equivalent Te(2) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent Ag(3), two equivalent Te(1), and two equivalent Te(2) atoms to form distorted face-sharing AgAg4Te4 tetrahedra. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to three equivalent Ag(3) and three equivalent Te(2) atoms. In the third Ag site, Ag(3) is bonded in a 9-coordinate geometry to two equivalent Ag(1), three equivalent Ag(2), one Te(1), and three equivalent Te(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 8-coordinate geometry to four equivalent Cs(1), two equivalent Ag(1), and two equivalent Ag(3) atoms. In the second Te site, Te(2) is bonded in a 9-coordinate geometry to two equivalent Cs(1), one Ag(1), three equivalent Ag(2), and three equivalent Ag(3) atoms. is represented by the CIF file [CIF]
data_CsAg5Te3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.797
_cell_length_b   14.797
_cell_length_c   4.604
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1008.051
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.888  0.112  0.500  1.0
  Cs  Cs1  1  0.612  0.612  0.000  1.0
  Cs  Cs2  1  0.388  0.388  0.000  1.0
  Cs  Cs3  1  0.112  0.888  0.500  1.0
  Ag  Ag4  1  0.678  0.322  0.000  1.0
  Ag  Ag5  1  0.822  0.822  0.500  1.0
  Ag  Ag6  1  0.178  0.178  0.500  1.0
  Ag  Ag7  1  0.322  0.678  0.000  1.0
  Ag  Ag8  1  0.398  0.983  0.500  1.0
  Ag  Ag9  1  0.602  0.017  0.500  1.0
  Ag  Ag10  1  0.517  0.898  0.000  1.0
  Ag  Ag11  1  0.483  0.102  0.000  1.0
  Ag  Ag12  1  0.983  0.398  0.500  1.0
  Ag  Ag13  1  0.898  0.517  0.000  1.0
  Ag  Ag14  1  0.102  0.483  0.000  1.0
  Ag  Ag15  1  0.017  0.602  0.500  1.0
  Ag  Ag16  1  0.420  0.788  0.500  1.0
  Ag  Ag17  1  0.580  0.212  0.500  1.0
  Ag  Ag18  1  0.712  0.920  0.000  1.0
  Ag  Ag19  1  0.288  0.080  0.000  1.0
  Ag  Ag20  1  0.212  0.580  0.500  1.0
  Ag  Ag21  1  0.080  0.288  0.000  1.0
  Ag  Ag22  1  0.920  0.712  0.000  1.0
  Ag  Ag23  1  0.788  0.420  0.500  1.0
  Te  Te24  1  0.101  0.101  0.000  1.0
  Te  Te25  1  0.601  0.399  0.500  1.0
  Te  Te26  1  0.399  0.601  0.500  1.0
  Te  Te27  1  0.899  0.899  0.000  1.0
  Te  Te28  1  0.328  0.883  0.000  1.0
  Te  Te29  1  0.672  0.117  0.000  1.0
  Te  Te30  1  0.617  0.828  0.500  1.0
  Te  Te31  1  0.383  0.172  0.500  1.0
  Te  Te32  1  0.883  0.328  0.000  1.0
  Te  Te33  1  0.828  0.617  0.500  1.0
  Te  Te34  1  0.172  0.383  0.500  1.0
  Te  Te35  1  0.117  0.672  0.000  1.0
[/CIF]
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