The crystal structure described by LiV3Zn2O8 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. In the second Li site, Li(2) is bonded to one O(11), one O(14), one O(16), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(14), one O(2), one O(3), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. In the second V site, V(2) is bonded to one O(10), one O(16), one O(2), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. In the third V site, V(3) is bonded to one O(10), one O(12), one O(14), one O(16), one O(2), and one O(4) atom to form VO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(13), one O(4), one O(5), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. In the fifth V site, V(5) is bonded to one O(1), one O(15), one O(3), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. In the sixth V site, V(6) is bonded to one O(1), one O(11), one O(13), one O(15), one O(3), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(12), one O(3), one O(8), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent V(5)O6 octahedra, and corners with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-63°. In the second Zn site, Zn(2) is bonded to one O(10), one O(11), one O(4), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, and corners with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the third Zn site, Zn(3) is bonded to one O(13), one O(16), one O(2), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and corners with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(14), one O(15), and one O(6) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(5)O6 octahedra, and corners with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one V(4), one V(5), one V(6), and one Zn(4) atom to form distorted edge-sharing OV3Zn trigonal pyramids. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one V(1), one V(2), one V(3), and one Zn(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one V(1), one V(5), one V(6), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one V(2), one V(3), one V(4), and one Zn(2) atom. In the fifth O site, O(5) is bonded to one Li(1), one V(4), one V(5), and one Zn(3) atom to form distorted OLiV2Zn trigonal pyramids that share  a cornercorner with one O(13)LiV2Zn trigonal pyramid,  an edgeedge with one O(13)LiV2Zn trigonal pyramid, and  an edgeedge with one O(1)V3Zn trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(2), and one Zn(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(5), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one V(4), and one Zn(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(5), one V(6), and one Zn(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one V(3), and one Zn(2) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(6), and one Zn(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(3), one V(4), and one Zn(1) atom. In the thirteenth O site, O(13) is bonded to one Li(1), one V(4), one V(6), and one Zn(3) atom to form distorted OLiV2Zn trigonal pyramids that share  a cornercorner with one O(5)LiV2Zn trigonal pyramid,  an edgeedge with one O(5)LiV2Zn trigonal pyramid, and  an edgeedge with one O(1)V3Zn trigonal pyramid. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(3), and one Zn(4) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(5), one V(6), and one Zn(4) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one Zn(3) atom. is represented by the CIF card [CIF]
data_LiV3Zn2O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.974
_cell_length_b   8.446
_cell_length_c   5.994
_cell_angle_alpha   89.930
_cell_angle_beta   89.679
_cell_angle_gamma   89.485
_symmetry_Int_Tables_number   1
_cell_volume   302.443
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.251  0.378  0.997  1.0
  Li  Li1  1  0.744  0.873  0.502  1.0
  V  V2  1  0.251  0.871  0.499  1.0
  V  V3  1  0.499  0.125  0.747  1.0
  V  V4  1  0.503  0.123  0.248  1.0
  V  V5  1  0.746  0.374  0.000  1.0
  V  V6  1  0.000  0.625  0.250  1.0
  V  V7  1  0.999  0.628  0.750  1.0
  Zn  Zn8  1  0.512  0.495  0.501  1.0
  Zn  Zn9  1  0.013  0.996  0.999  1.0
  Zn  Zn10  1  0.993  0.256  0.503  1.0
  Zn  Zn11  1  0.490  0.757  0.002  1.0
  O  O12  1  0.767  0.616  0.001  1.0
  O  O13  1  0.266  0.120  0.508  1.0
  O  O14  1  0.225  0.620  0.500  1.0
  O  O15  1  0.743  0.138  0.988  1.0
  O  O16  1  0.986  0.397  0.234  1.0
  O  O17  1  0.485  0.893  0.734  1.0
  O  O18  1  0.007  0.850  0.261  1.0
  O  O19  1  0.517  0.360  0.768  1.0
  O  O20  1  0.785  0.624  0.502  1.0
  O  O21  1  0.285  0.129  0.989  1.0
  O  O22  1  0.006  0.849  0.739  1.0
  O  O23  1  0.526  0.366  0.224  1.0
  O  O24  1  0.979  0.396  0.774  1.0
  O  O25  1  0.488  0.891  0.270  1.0
  O  O26  1  0.215  0.624  0.999  1.0
  O  O27  1  0.717  0.126  0.511  1.0
[/CIF]
.
The crystal structure described by LiV3Zn2O8 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. In the second Li site, Li(2) is bonded to one O(11), one O(14), one O(16), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(14), one O(2), one O(3), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. In the second V site, V(2) is bonded to one O(10), one O(16), one O(2), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. In the third V site, V(3) is bonded to one O(10), one O(12), one O(14), one O(16), one O(2), and one O(4) atom to form VO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(13), one O(4), one O(5), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. In the fifth V site, V(5) is bonded to one O(1), one O(15), one O(3), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. In the sixth V site, V(6) is bonded to one O(1), one O(11), one O(13), one O(15), one O(3), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(12), one O(3), one O(8), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent V(5)O6 octahedra, and corners with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-63°. In the second Zn site, Zn(2) is bonded to one O(10), one O(11), one O(4), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, and corners with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the third Zn site, Zn(3) is bonded to one O(13), one O(16), one O(2), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and corners with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(14), one O(15), and one O(6) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(5)O6 octahedra, and corners with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one V(4), one V(5), one V(6), and one Zn(4) atom to form distorted edge-sharing OV3Zn trigonal pyramids. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one V(1), one V(2), one V(3), and one Zn(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one V(1), one V(5), one V(6), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one V(2), one V(3), one V(4), and one Zn(2) atom. In the fifth O site, O(5) is bonded to one Li(1), one V(4), one V(5), and one Zn(3) atom to form distorted OLiV2Zn trigonal pyramids that share  a cornercorner with one O(13)LiV2Zn trigonal pyramid,  an edgeedge with one O(13)LiV2Zn trigonal pyramid, and  an edgeedge with one O(1)V3Zn trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(2), and one Zn(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(5), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one V(4), and one Zn(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(5), one V(6), and one Zn(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one V(3), and one Zn(2) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(6), and one Zn(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(3), one V(4), and one Zn(1) atom. In the thirteenth O site, O(13) is bonded to one Li(1), one V(4), one V(6), and one Zn(3) atom to form distorted OLiV2Zn trigonal pyramids that share  a cornercorner with one O(5)LiV2Zn trigonal pyramid,  an edgeedge with one O(5)LiV2Zn trigonal pyramid, and  an edgeedge with one O(1)V3Zn trigonal pyramid. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(3), and one Zn(4) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(5), one V(6), and one Zn(4) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one Zn(3) atom. is represented by the CIF card [CIF]
data_LiV3Zn2O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.974
_cell_length_b   8.446
_cell_length_c   5.994
_cell_angle_alpha   89.930
_cell_angle_beta   89.679
_cell_angle_gamma   89.485
_symmetry_Int_Tables_number   1
_cell_volume   302.443
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.251  0.378  0.997  1.0
  Li  Li1  1  0.744  0.873  0.502  1.0
  V  V2  1  0.251  0.871  0.499  1.0
  V  V3  1  0.499  0.125  0.747  1.0
  V  V4  1  0.503  0.123  0.248  1.0
  V  V5  1  0.746  0.374  0.000  1.0
  V  V6  1  0.000  0.625  0.250  1.0
  V  V7  1  0.999  0.628  0.750  1.0
  Zn  Zn8  1  0.512  0.495  0.501  1.0
  Zn  Zn9  1  0.013  0.996  0.999  1.0
  Zn  Zn10  1  0.993  0.256  0.503  1.0
  Zn  Zn11  1  0.490  0.757  0.002  1.0
  O  O12  1  0.767  0.616  0.001  1.0
  O  O13  1  0.266  0.120  0.508  1.0
  O  O14  1  0.225  0.620  0.500  1.0
  O  O15  1  0.743  0.138  0.988  1.0
  O  O16  1  0.986  0.397  0.234  1.0
  O  O17  1  0.485  0.893  0.734  1.0
  O  O18  1  0.007  0.850  0.261  1.0
  O  O19  1  0.517  0.360  0.768  1.0
  O  O20  1  0.785  0.624  0.502  1.0
  O  O21  1  0.285  0.129  0.989  1.0
  O  O22  1  0.006  0.849  0.739  1.0
  O  O23  1  0.526  0.366  0.224  1.0
  O  O24  1  0.979  0.396  0.774  1.0
  O  O25  1  0.488  0.891  0.270  1.0
  O  O26  1  0.215  0.624  0.999  1.0
  O  O27  1  0.717  0.126  0.511  1.0
[/CIF]
.