The compound described by CoZn2SbO6 crystallizes in the monoclinic P2_1/m space group. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, corners with four equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 41-45°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(3), one O(4), and two equivalent O(1) atoms to form distorted ZnO4 trigonal pyramids that share corners with four equivalent Co(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with two equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 63-83°. In the second Zn site, Zn(2) is bonded to one O(3), one O(4), and two equivalent O(2) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with two equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 67-84°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, corners with four equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 43-46°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(1), one Zn(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1), one Zn(2), and one Sb(1) atom. In the third O site, O(3) is bonded to one Zn(1), one Zn(2), and two equivalent Sb(1) atoms to form OZn2Sb2 tetrahedra that share corners with two equivalent O(4)Zn2Co2 tetrahedra and corners with two equivalent O(3)Zn2Sb2 tetrahedra. In the fourth O site, O(4) is bonded to two equivalent Co(1), one Zn(1), and one Zn(2) atom to form distorted OZn2Co2 tetrahedra that share corners with two equivalent O(4)Zn2Co2 tetrahedra and corners with two equivalent O(3)Zn2Sb2 tetrahedra. is represented by the CIF file [CIF]
data_Zn2CoSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.703
_cell_length_b   5.277
_cell_length_c   5.280
_cell_angle_alpha   89.824
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   214.644
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.488  0.451  1.0
  Zn  Zn1  1  0.750  0.512  0.549  1.0
  Zn  Zn2  1  0.250  0.978  0.982  1.0
  Zn  Zn3  1  0.750  0.022  0.018  1.0
  Co  Co4  1  0.500  0.500  0.000  1.0
  Co  Co5  1  0.000  0.500  0.000  1.0
  Sb  Sb6  1  0.500  0.000  0.500  1.0
  Sb  Sb7  1  0.000  0.000  0.500  1.0
  O  O8  1  0.565  0.680  0.325  1.0
  O  O9  1  0.934  0.830  0.825  1.0
  O  O10  1  0.065  0.320  0.675  1.0
  O  O11  1  0.434  0.170  0.175  1.0
  O  O12  1  0.566  0.830  0.825  1.0
  O  O13  1  0.066  0.170  0.175  1.0
  O  O14  1  0.750  0.131  0.419  1.0
  O  O15  1  0.935  0.680  0.325  1.0
  O  O16  1  0.250  0.608  0.083  1.0
  O  O17  1  0.435  0.320  0.675  1.0
  O  O18  1  0.250  0.869  0.581  1.0
  O  O19  1  0.750  0.392  0.917  1.0
[/CIF]
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The compound described by CoZn2SbO6 crystallizes in the monoclinic P2_1/m space group. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, corners with four equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 41-45°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(3), one O(4), and two equivalent O(1) atoms to form distorted ZnO4 trigonal pyramids that share corners with four equivalent Co(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with two equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 63-83°. In the second Zn site, Zn(2) is bonded to one O(3), one O(4), and two equivalent O(2) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with two equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 67-84°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, corners with four equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 43-46°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(1), one Zn(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1), one Zn(2), and one Sb(1) atom. In the third O site, O(3) is bonded to one Zn(1), one Zn(2), and two equivalent Sb(1) atoms to form OZn2Sb2 tetrahedra that share corners with two equivalent O(4)Zn2Co2 tetrahedra and corners with two equivalent O(3)Zn2Sb2 tetrahedra. In the fourth O site, O(4) is bonded to two equivalent Co(1), one Zn(1), and one Zn(2) atom to form distorted OZn2Co2 tetrahedra that share corners with two equivalent O(4)Zn2Co2 tetrahedra and corners with two equivalent O(3)Zn2Sb2 tetrahedra. is represented by the CIF file [CIF]
data_Zn2CoSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.703
_cell_length_b   5.277
_cell_length_c   5.280
_cell_angle_alpha   89.824
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   214.644
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.488  0.451  1.0
  Zn  Zn1  1  0.750  0.512  0.549  1.0
  Zn  Zn2  1  0.250  0.978  0.982  1.0
  Zn  Zn3  1  0.750  0.022  0.018  1.0
  Co  Co4  1  0.500  0.500  0.000  1.0
  Co  Co5  1  0.000  0.500  0.000  1.0
  Sb  Sb6  1  0.500  0.000  0.500  1.0
  Sb  Sb7  1  0.000  0.000  0.500  1.0
  O  O8  1  0.565  0.680  0.325  1.0
  O  O9  1  0.934  0.830  0.825  1.0
  O  O10  1  0.065  0.320  0.675  1.0
  O  O11  1  0.434  0.170  0.175  1.0
  O  O12  1  0.566  0.830  0.825  1.0
  O  O13  1  0.066  0.170  0.175  1.0
  O  O14  1  0.750  0.131  0.419  1.0
  O  O15  1  0.935  0.680  0.325  1.0
  O  O16  1  0.250  0.608  0.083  1.0
  O  O17  1  0.435  0.320  0.675  1.0
  O  O18  1  0.250  0.869  0.581  1.0
  O  O19  1  0.750  0.392  0.917  1.0
[/CIF]
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