The material described by MgAgF5 crystallizes in the monoclinic P2_1/c space group. Mg(1) is bonded in a 6-coordinate geometry to one F(1), one F(3), one F(4), one F(5), and two equivalent F(2) atoms. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to two equivalent Mg(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Mg(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Mg(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mg(1) and two equivalent Ag(1) atoms. is represented by the CIF file [CIF]
data_MgAgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.985
_cell_length_b   5.226
_cell_length_c   8.061
_cell_angle_alpha   69.305
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   393.527
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.008  0.526  0.759  1.0
  Mg  Mg1  1  0.508  0.474  0.741  1.0
  Mg  Mg2  1  0.992  0.474  0.241  1.0
  Mg  Mg3  1  0.492  0.526  0.259  1.0
  Ag  Ag4  1  0.753  0.114  0.609  1.0
  Ag  Ag5  1  0.253  0.886  0.891  1.0
  Ag  Ag6  1  0.247  0.886  0.391  1.0
  Ag  Ag7  1  0.747  0.114  0.109  1.0
  F  F8  1  0.888  0.430  0.589  1.0
  F  F9  1  0.388  0.570  0.911  1.0
  F  F10  1  0.112  0.570  0.411  1.0
  F  F11  1  0.612  0.430  0.089  1.0
  F  F12  1  0.598  0.369  0.495  1.0
  F  F13  1  0.098  0.631  0.005  1.0
  F  F14  1  0.402  0.631  0.505  1.0
  F  F15  1  0.902  0.369  0.995  1.0
  F  F16  1  0.406  0.134  0.776  1.0
  F  F17  1  0.906  0.866  0.724  1.0
  F  F18  1  0.594  0.866  0.224  1.0
  F  F19  1  0.094  0.134  0.276  1.0
  F  F20  1  0.130  0.215  0.850  1.0
  F  F21  1  0.630  0.785  0.650  1.0
  F  F22  1  0.870  0.785  0.150  1.0
  F  F23  1  0.370  0.215  0.350  1.0
  F  F24  1  0.660  0.199  0.839  1.0
  F  F25  1  0.160  0.801  0.661  1.0
  F  F26  1  0.340  0.801  0.161  1.0
  F  F27  1  0.840  0.199  0.339  1.0
[/CIF]
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The material described by MgAgF5 crystallizes in the monoclinic P2_1/c space group. Mg(1) is bonded in a 6-coordinate geometry to one F(1), one F(3), one F(4), one F(5), and two equivalent F(2) atoms. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to two equivalent Mg(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Mg(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Mg(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mg(1) and two equivalent Ag(1) atoms. is represented by the CIF file [CIF]
data_MgAgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.985
_cell_length_b   5.226
_cell_length_c   8.061
_cell_angle_alpha   69.305
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   393.527
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.008  0.526  0.759  1.0
  Mg  Mg1  1  0.508  0.474  0.741  1.0
  Mg  Mg2  1  0.992  0.474  0.241  1.0
  Mg  Mg3  1  0.492  0.526  0.259  1.0
  Ag  Ag4  1  0.753  0.114  0.609  1.0
  Ag  Ag5  1  0.253  0.886  0.891  1.0
  Ag  Ag6  1  0.247  0.886  0.391  1.0
  Ag  Ag7  1  0.747  0.114  0.109  1.0
  F  F8  1  0.888  0.430  0.589  1.0
  F  F9  1  0.388  0.570  0.911  1.0
  F  F10  1  0.112  0.570  0.411  1.0
  F  F11  1  0.612  0.430  0.089  1.0
  F  F12  1  0.598  0.369  0.495  1.0
  F  F13  1  0.098  0.631  0.005  1.0
  F  F14  1  0.402  0.631  0.505  1.0
  F  F15  1  0.902  0.369  0.995  1.0
  F  F16  1  0.406  0.134  0.776  1.0
  F  F17  1  0.906  0.866  0.724  1.0
  F  F18  1  0.594  0.866  0.224  1.0
  F  F19  1  0.094  0.134  0.276  1.0
  F  F20  1  0.130  0.215  0.850  1.0
  F  F21  1  0.630  0.785  0.650  1.0
  F  F22  1  0.870  0.785  0.150  1.0
  F  F23  1  0.370  0.215  0.350  1.0
  F  F24  1  0.660  0.199  0.839  1.0
  F  F25  1  0.160  0.801  0.661  1.0
  F  F26  1  0.340  0.801  0.161  1.0
  F  F27  1  0.840  0.199  0.339  1.0
[/CIF]
.