The material structure described by C4TeS2(N4Cl)2(SO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur monoxide molecules and two C4TeS2(N4Cl)2 clusters. In each C4TeS2(N4Cl)2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Cl(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(2) atom. Te(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent S(2) atoms. S(2) is bonded in a distorted single-bond geometry to one N(3) and one Te(1) atom. Cl(1) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_TeC4S4N8(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.830
_cell_length_b   7.476
_cell_length_c   10.270
_cell_angle_alpha   70.740
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1002.363
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.500  0.000  0.500  1.0
  Te  Te1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.297  0.957  0.575  1.0
  C  C3  1  0.797  0.043  0.925  1.0
  C  C4  1  0.703  0.043  0.425  1.0
  C  C5  1  0.203  0.957  0.075  1.0
  C  C6  1  0.442  0.847  0.836  1.0
  C  C7  1  0.942  0.153  0.664  1.0
  C  C8  1  0.558  0.153  0.164  1.0
  C  C9  1  0.058  0.847  0.336  1.0
  S  S10  1  0.297  0.222  0.543  1.0
  S  S11  1  0.797  0.778  0.957  1.0
  S  S12  1  0.703  0.778  0.457  1.0
  S  S13  1  0.203  0.222  0.043  1.0
  S  S14  1  0.449  0.186  0.671  1.0
  S  S15  1  0.949  0.814  0.829  1.0
  S  S16  1  0.551  0.814  0.329  1.0
  S  S17  1  0.051  0.186  0.171  1.0
  N  N18  1  0.362  0.900  0.503  1.0
  N  N19  1  0.862  0.100  0.997  1.0
  N  N20  1  0.638  0.100  0.497  1.0
  N  N21  1  0.138  0.900  0.003  1.0
  N  N22  1  0.228  0.876  0.660  1.0
  N  N23  1  0.728  0.124  0.840  1.0
  N  N24  1  0.772  0.124  0.340  1.0
  N  N25  1  0.272  0.876  0.160  1.0
  N  N26  1  0.445  0.029  0.819  1.0
  N  N27  1  0.945  0.971  0.681  1.0
  N  N28  1  0.555  0.971  0.181  1.0
  N  N29  1  0.055  0.029  0.319  1.0
  N  N30  1  0.446  0.683  0.850  1.0
  N  N31  1  0.946  0.317  0.650  1.0
  N  N32  1  0.554  0.317  0.150  1.0
  N  N33  1  0.054  0.683  0.350  1.0
  Cl  Cl34  1  0.224  0.637  0.704  1.0
  Cl  Cl35  1  0.724  0.363  0.796  1.0
  Cl  Cl36  1  0.776  0.363  0.296  1.0
  Cl  Cl37  1  0.276  0.637  0.204  1.0
  O  O38  1  0.276  0.268  0.131  1.0
  O  O39  1  0.776  0.732  0.369  1.0
  O  O40  1  0.724  0.732  0.869  1.0
  O  O41  1  0.224  0.268  0.631  1.0
[/CIF]
.
The material structure described by C4TeS2(N4Cl)2(SO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur monoxide molecules and two C4TeS2(N4Cl)2 clusters. In each C4TeS2(N4Cl)2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Cl(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(2) atom. Te(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent S(2) atoms. S(2) is bonded in a distorted single-bond geometry to one N(3) and one Te(1) atom. Cl(1) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_TeC4S4N8(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.830
_cell_length_b   7.476
_cell_length_c   10.270
_cell_angle_alpha   70.740
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1002.363
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.500  0.000  0.500  1.0
  Te  Te1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.297  0.957  0.575  1.0
  C  C3  1  0.797  0.043  0.925  1.0
  C  C4  1  0.703  0.043  0.425  1.0
  C  C5  1  0.203  0.957  0.075  1.0
  C  C6  1  0.442  0.847  0.836  1.0
  C  C7  1  0.942  0.153  0.664  1.0
  C  C8  1  0.558  0.153  0.164  1.0
  C  C9  1  0.058  0.847  0.336  1.0
  S  S10  1  0.297  0.222  0.543  1.0
  S  S11  1  0.797  0.778  0.957  1.0
  S  S12  1  0.703  0.778  0.457  1.0
  S  S13  1  0.203  0.222  0.043  1.0
  S  S14  1  0.449  0.186  0.671  1.0
  S  S15  1  0.949  0.814  0.829  1.0
  S  S16  1  0.551  0.814  0.329  1.0
  S  S17  1  0.051  0.186  0.171  1.0
  N  N18  1  0.362  0.900  0.503  1.0
  N  N19  1  0.862  0.100  0.997  1.0
  N  N20  1  0.638  0.100  0.497  1.0
  N  N21  1  0.138  0.900  0.003  1.0
  N  N22  1  0.228  0.876  0.660  1.0
  N  N23  1  0.728  0.124  0.840  1.0
  N  N24  1  0.772  0.124  0.340  1.0
  N  N25  1  0.272  0.876  0.160  1.0
  N  N26  1  0.445  0.029  0.819  1.0
  N  N27  1  0.945  0.971  0.681  1.0
  N  N28  1  0.555  0.971  0.181  1.0
  N  N29  1  0.055  0.029  0.319  1.0
  N  N30  1  0.446  0.683  0.850  1.0
  N  N31  1  0.946  0.317  0.650  1.0
  N  N32  1  0.554  0.317  0.150  1.0
  N  N33  1  0.054  0.683  0.350  1.0
  Cl  Cl34  1  0.224  0.637  0.704  1.0
  Cl  Cl35  1  0.724  0.363  0.796  1.0
  Cl  Cl36  1  0.776  0.363  0.296  1.0
  Cl  Cl37  1  0.276  0.637  0.204  1.0
  O  O38  1  0.276  0.268  0.131  1.0
  O  O39  1  0.776  0.732  0.369  1.0
  O  O40  1  0.724  0.732  0.869  1.0
  O  O41  1  0.224  0.268  0.631  1.0
[/CIF]
.