The structure described by Ba2Ag2CuZnF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form AgF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Cu(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms to form distorted CuF6 octahedra that share corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Zn(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Ag(1) atom. In the second F site, F(6) is bonded in a 2-coordinate geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the third F site, F(7) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(1), and one Cu(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the fifth F site, F(2) is bonded to two equivalent Ba(1), one Ag(1), and one Cu(1) atom to form a mixture of distorted corner and edge-sharing FBa2CuAg tetrahedra. In the sixth F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one Ag(1) atom. In the seventh F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cu(1), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba2ZnCuAg2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.690
_cell_length_b   7.690
_cell_length_c   15.458
_cell_angle_alpha   88.407
_cell_angle_beta   88.407
_cell_angle_gamma   41.187
_symmetry_Int_Tables_number   1
_cell_volume   601.734
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.100  0.273  0.374  1.0
  Ba  Ba1  1  0.273  0.100  0.874  1.0
  Ba  Ba2  1  0.900  0.727  0.626  1.0
  Ba  Ba3  1  0.727  0.900  0.126  1.0
  Zn  Zn4  1  0.425  0.575  0.250  1.0
  Zn  Zn5  1  0.575  0.425  0.750  1.0
  Cu  Cu6  1  0.500  0.500  0.000  1.0
  Cu  Cu7  1  0.500  0.500  0.500  1.0
  Ag  Ag8  1  0.089  0.145  0.127  1.0
  Ag  Ag9  1  0.911  0.855  0.873  1.0
  Ag  Ag10  1  0.145  0.089  0.627  1.0
  Ag  Ag11  1  0.855  0.911  0.373  1.0
  F  F12  1  0.862  0.110  0.665  1.0
  F  F13  1  0.866  0.419  0.540  1.0
  F  F14  1  0.134  0.581  0.460  1.0
  F  F15  1  0.626  0.863  0.405  1.0
  F  F16  1  0.620  0.469  0.388  1.0
  F  F17  1  0.531  0.380  0.112  1.0
  F  F18  1  0.419  0.866  0.040  1.0
  F  F19  1  0.890  0.138  0.835  1.0
  F  F20  1  0.371  0.979  0.229  1.0
  F  F21  1  0.374  0.137  0.595  1.0
  F  F22  1  0.774  0.435  0.222  1.0
  F  F23  1  0.137  0.374  0.095  1.0
  F  F24  1  0.435  0.774  0.722  1.0
  F  F25  1  0.226  0.565  0.778  1.0
  F  F26  1  0.469  0.620  0.888  1.0
  F  F27  1  0.629  0.021  0.771  1.0
  F  F28  1  0.142  0.708  0.991  1.0
  F  F29  1  0.138  0.890  0.335  1.0
  F  F30  1  0.858  0.292  0.009  1.0
  F  F31  1  0.708  0.142  0.491  1.0
  F  F32  1  0.581  0.134  0.960  1.0
  F  F33  1  0.565  0.226  0.278  1.0
  F  F34  1  0.979  0.371  0.729  1.0
  F  F35  1  0.292  0.858  0.509  1.0
  F  F36  1  0.380  0.531  0.612  1.0
  F  F37  1  0.110  0.862  0.165  1.0
  F  F38  1  0.021  0.629  0.271  1.0
  F  F39  1  0.863  0.626  0.905  1.0
[/CIF]
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The structure described by Ba2Ag2CuZnF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form AgF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Cu(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms to form distorted CuF6 octahedra that share corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Zn(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Ag(1) atom. In the second F site, F(6) is bonded in a 2-coordinate geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the third F site, F(7) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(1), and one Cu(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the fifth F site, F(2) is bonded to two equivalent Ba(1), one Ag(1), and one Cu(1) atom to form a mixture of distorted corner and edge-sharing FBa2CuAg tetrahedra. In the sixth F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one Ag(1) atom. In the seventh F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cu(1), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba2ZnCuAg2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.690
_cell_length_b   7.690
_cell_length_c   15.458
_cell_angle_alpha   88.407
_cell_angle_beta   88.407
_cell_angle_gamma   41.187
_symmetry_Int_Tables_number   1
_cell_volume   601.734
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.100  0.273  0.374  1.0
  Ba  Ba1  1  0.273  0.100  0.874  1.0
  Ba  Ba2  1  0.900  0.727  0.626  1.0
  Ba  Ba3  1  0.727  0.900  0.126  1.0
  Zn  Zn4  1  0.425  0.575  0.250  1.0
  Zn  Zn5  1  0.575  0.425  0.750  1.0
  Cu  Cu6  1  0.500  0.500  0.000  1.0
  Cu  Cu7  1  0.500  0.500  0.500  1.0
  Ag  Ag8  1  0.089  0.145  0.127  1.0
  Ag  Ag9  1  0.911  0.855  0.873  1.0
  Ag  Ag10  1  0.145  0.089  0.627  1.0
  Ag  Ag11  1  0.855  0.911  0.373  1.0
  F  F12  1  0.862  0.110  0.665  1.0
  F  F13  1  0.866  0.419  0.540  1.0
  F  F14  1  0.134  0.581  0.460  1.0
  F  F15  1  0.626  0.863  0.405  1.0
  F  F16  1  0.620  0.469  0.388  1.0
  F  F17  1  0.531  0.380  0.112  1.0
  F  F18  1  0.419  0.866  0.040  1.0
  F  F19  1  0.890  0.138  0.835  1.0
  F  F20  1  0.371  0.979  0.229  1.0
  F  F21  1  0.374  0.137  0.595  1.0
  F  F22  1  0.774  0.435  0.222  1.0
  F  F23  1  0.137  0.374  0.095  1.0
  F  F24  1  0.435  0.774  0.722  1.0
  F  F25  1  0.226  0.565  0.778  1.0
  F  F26  1  0.469  0.620  0.888  1.0
  F  F27  1  0.629  0.021  0.771  1.0
  F  F28  1  0.142  0.708  0.991  1.0
  F  F29  1  0.138  0.890  0.335  1.0
  F  F30  1  0.858  0.292  0.009  1.0
  F  F31  1  0.708  0.142  0.491  1.0
  F  F32  1  0.581  0.134  0.960  1.0
  F  F33  1  0.565  0.226  0.278  1.0
  F  F34  1  0.979  0.371  0.729  1.0
  F  F35  1  0.292  0.858  0.509  1.0
  F  F36  1  0.380  0.531  0.612  1.0
  F  F37  1  0.110  0.862  0.165  1.0
  F  F38  1  0.021  0.629  0.271  1.0
  F  F39  1  0.863  0.626  0.905  1.0
[/CIF]
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