The material structure described by Cs2H6Te(O3Cl)2 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 14-coordinate geometry to one H(1), one H(2), one H(3), two equivalent O(1), two equivalent O(2), three equivalent O(3), and four equivalent Cl(1) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1) and one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one O(3) atom. Te(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Cs(1), one H(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one H(2), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to three equivalent Cs(1), one H(3), and one Te(1) atom. Cl(1) is bonded in a 4-coordinate geometry to four equivalent Cs(1) atoms. is represented by the CIF card [CIF]
data_Cs2TeH6(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.279
_cell_length_b   6.476
_cell_length_c   7.983
_cell_angle_alpha   72.407
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.771
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.129  0.250  0.439  1.0
  Cs  Cs1  1  0.629  0.750  0.061  1.0
  Cs  Cs2  1  0.871  0.750  0.561  1.0
  Cs  Cs3  1  0.371  0.250  0.939  1.0
  Te  Te4  1  0.000  0.000  0.000  1.0
  Te  Te5  1  0.500  0.000  0.500  1.0
  H  H6  1  0.082  0.376  0.928  1.0
  H  H7  1  0.582  0.624  0.572  1.0
  H  H8  1  0.918  0.624  0.072  1.0
  H  H9  1  0.418  0.376  0.428  1.0
  H  H10  1  0.147  0.849  0.831  1.0
  H  H11  1  0.647  0.151  0.669  1.0
  H  H12  1  0.853  0.151  0.169  1.0
  H  H13  1  0.353  0.849  0.331  1.0
  H  H14  1  0.347  0.784  0.699  1.0
  H  H15  1  0.847  0.216  0.801  1.0
  H  H16  1  0.653  0.216  0.301  1.0
  H  H17  1  0.153  0.784  0.199  1.0
  Cl  Cl18  1  0.328  0.624  0.197  1.0
  Cl  Cl19  1  0.828  0.376  0.303  1.0
  Cl  Cl20  1  0.672  0.376  0.803  1.0
  Cl  Cl21  1  0.172  0.624  0.697  1.0
  O  O22  1  0.433  0.260  0.540  1.0
  O  O23  1  0.933  0.740  0.960  1.0
  O  O24  1  0.567  0.740  0.460  1.0
  O  O25  1  0.067  0.260  0.040  1.0
  O  O26  1  0.142  0.986  0.863  1.0
  O  O27  1  0.642  0.014  0.637  1.0
  O  O28  1  0.858  0.014  0.137  1.0
  O  O29  1  0.358  0.986  0.363  1.0
  O  O30  1  0.427  0.832  0.723  1.0
  O  O31  1  0.927  0.168  0.777  1.0
  O  O32  1  0.573  0.168  0.277  1.0
  O  O33  1  0.073  0.832  0.223  1.0
[/CIF]
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The material structure described by Cs2H6Te(O3Cl)2 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 14-coordinate geometry to one H(1), one H(2), one H(3), two equivalent O(1), two equivalent O(2), three equivalent O(3), and four equivalent Cl(1) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1) and one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one O(3) atom. Te(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Cs(1), one H(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one H(2), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to three equivalent Cs(1), one H(3), and one Te(1) atom. Cl(1) is bonded in a 4-coordinate geometry to four equivalent Cs(1) atoms. is represented by the CIF card [CIF]
data_Cs2TeH6(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.279
_cell_length_b   6.476
_cell_length_c   7.983
_cell_angle_alpha   72.407
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.771
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.129  0.250  0.439  1.0
  Cs  Cs1  1  0.629  0.750  0.061  1.0
  Cs  Cs2  1  0.871  0.750  0.561  1.0
  Cs  Cs3  1  0.371  0.250  0.939  1.0
  Te  Te4  1  0.000  0.000  0.000  1.0
  Te  Te5  1  0.500  0.000  0.500  1.0
  H  H6  1  0.082  0.376  0.928  1.0
  H  H7  1  0.582  0.624  0.572  1.0
  H  H8  1  0.918  0.624  0.072  1.0
  H  H9  1  0.418  0.376  0.428  1.0
  H  H10  1  0.147  0.849  0.831  1.0
  H  H11  1  0.647  0.151  0.669  1.0
  H  H12  1  0.853  0.151  0.169  1.0
  H  H13  1  0.353  0.849  0.331  1.0
  H  H14  1  0.347  0.784  0.699  1.0
  H  H15  1  0.847  0.216  0.801  1.0
  H  H16  1  0.653  0.216  0.301  1.0
  H  H17  1  0.153  0.784  0.199  1.0
  Cl  Cl18  1  0.328  0.624  0.197  1.0
  Cl  Cl19  1  0.828  0.376  0.303  1.0
  Cl  Cl20  1  0.672  0.376  0.803  1.0
  Cl  Cl21  1  0.172  0.624  0.697  1.0
  O  O22  1  0.433  0.260  0.540  1.0
  O  O23  1  0.933  0.740  0.960  1.0
  O  O24  1  0.567  0.740  0.460  1.0
  O  O25  1  0.067  0.260  0.040  1.0
  O  O26  1  0.142  0.986  0.863  1.0
  O  O27  1  0.642  0.014  0.637  1.0
  O  O28  1  0.858  0.014  0.137  1.0
  O  O29  1  0.358  0.986  0.363  1.0
  O  O30  1  0.427  0.832  0.723  1.0
  O  O31  1  0.927  0.168  0.777  1.0
  O  O32  1  0.573  0.168  0.277  1.0
  O  O33  1  0.073  0.832  0.223  1.0
[/CIF]
.