The structure described by Re24Ti5 is alpha-derived structured and crystallizes in the cubic I-43m space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 16-coordinate geometry to four equivalent Ti(2) and twelve equivalent Re(2) atoms. In the second Ti site, Ti(2) is bonded in a 16-coordinate geometry to one Ti(1), six equivalent Re(1), and nine equivalent Re(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 13-coordinate geometry to two equivalent Ti(2), five equivalent Re(2), and six equivalent Re(1) atoms. In the second Re site, Re(2) is bonded to one Ti(1), three equivalent Ti(2), three equivalent Re(2), and five equivalent Re(1) atoms to form a mixture of distorted corner, face, and edge-sharing ReTi4Re8 cuboctahedra. is represented by the CIF card [CIF]
data_Ti5Re24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.328
_cell_length_b   8.328
_cell_length_c   8.328
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   444.705
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.000  0.000  0.000  1.0
  Ti  Ti1  1  0.632  0.632  0.632  1.0
  Ti  Ti2  1  0.368  0.000  0.000  1.0
  Ti  Ti3  1  0.000  0.368  0.000  1.0
  Ti  Ti4  1  0.000  0.000  0.368  1.0
  Re  Re5  1  0.400  0.400  0.718  1.0
  Re  Re6  1  0.600  0.318  0.000  1.0
  Re  Re7  1  0.318  0.600  0.000  1.0
  Re  Re8  1  0.000  0.318  0.600  1.0
  Re  Re9  1  0.282  0.682  0.682  1.0
  Re  Re10  1  0.682  0.282  0.682  1.0
  Re  Re11  1  0.318  0.000  0.600  1.0
  Re  Re12  1  0.600  0.000  0.318  1.0
  Re  Re13  1  0.000  0.600  0.318  1.0
  Re  Re14  1  0.718  0.400  0.400  1.0
  Re  Re15  1  0.400  0.718  0.400  1.0
  Re  Re16  1  0.682  0.682  0.282  1.0
  Re  Re17  1  0.375  0.375  0.183  1.0
  Re  Re18  1  0.625  0.807  0.000  1.0
  Re  Re19  1  0.807  0.625  0.000  1.0
  Re  Re20  1  0.000  0.807  0.625  1.0
  Re  Re21  1  0.817  0.193  0.193  1.0
  Re  Re22  1  0.193  0.817  0.193  1.0
  Re  Re23  1  0.807  0.000  0.625  1.0
  Re  Re24  1  0.625  0.000  0.807  1.0
  Re  Re25  1  0.000  0.625  0.807  1.0
  Re  Re26  1  0.183  0.375  0.375  1.0
  Re  Re27  1  0.375  0.183  0.375  1.0
  Re  Re28  1  0.193  0.193  0.817  1.0
[/CIF]
.
The structure described by Re24Ti5 is alpha-derived structured and crystallizes in the cubic I-43m space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 16-coordinate geometry to four equivalent Ti(2) and twelve equivalent Re(2) atoms. In the second Ti site, Ti(2) is bonded in a 16-coordinate geometry to one Ti(1), six equivalent Re(1), and nine equivalent Re(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 13-coordinate geometry to two equivalent Ti(2), five equivalent Re(2), and six equivalent Re(1) atoms. In the second Re site, Re(2) is bonded to one Ti(1), three equivalent Ti(2), three equivalent Re(2), and five equivalent Re(1) atoms to form a mixture of distorted corner, face, and edge-sharing ReTi4Re8 cuboctahedra. is represented by the CIF card [CIF]
data_Ti5Re24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.328
_cell_length_b   8.328
_cell_length_c   8.328
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   444.705
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.000  0.000  0.000  1.0
  Ti  Ti1  1  0.632  0.632  0.632  1.0
  Ti  Ti2  1  0.368  0.000  0.000  1.0
  Ti  Ti3  1  0.000  0.368  0.000  1.0
  Ti  Ti4  1  0.000  0.000  0.368  1.0
  Re  Re5  1  0.400  0.400  0.718  1.0
  Re  Re6  1  0.600  0.318  0.000  1.0
  Re  Re7  1  0.318  0.600  0.000  1.0
  Re  Re8  1  0.000  0.318  0.600  1.0
  Re  Re9  1  0.282  0.682  0.682  1.0
  Re  Re10  1  0.682  0.282  0.682  1.0
  Re  Re11  1  0.318  0.000  0.600  1.0
  Re  Re12  1  0.600  0.000  0.318  1.0
  Re  Re13  1  0.000  0.600  0.318  1.0
  Re  Re14  1  0.718  0.400  0.400  1.0
  Re  Re15  1  0.400  0.718  0.400  1.0
  Re  Re16  1  0.682  0.682  0.282  1.0
  Re  Re17  1  0.375  0.375  0.183  1.0
  Re  Re18  1  0.625  0.807  0.000  1.0
  Re  Re19  1  0.807  0.625  0.000  1.0
  Re  Re20  1  0.000  0.807  0.625  1.0
  Re  Re21  1  0.817  0.193  0.193  1.0
  Re  Re22  1  0.193  0.817  0.193  1.0
  Re  Re23  1  0.807  0.000  0.625  1.0
  Re  Re24  1  0.625  0.000  0.807  1.0
  Re  Re25  1  0.000  0.625  0.807  1.0
  Re  Re26  1  0.183  0.375  0.375  1.0
  Re  Re27  1  0.375  0.183  0.375  1.0
  Re  Re28  1  0.193  0.193  0.817  1.0
[/CIF]
.