The material structure described by BaS4O crystallizes in the orthorhombic P2_12_12 space group. Ba(1) is bonded in a distorted bent 120 degrees geometry to one S(2), two equivalent S(3), two equivalent S(4), one O(1), and one O(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to one S(3) atom. In the second S site, S(2) is bonded in a 2-coordinate geometry to one Ba(1) and one S(4) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one S(1), and one S(3) atom. In the fourth S site, S(4) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one S(2), and one S(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Ba(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Ba(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaS4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.224
_cell_length_b   8.743
_cell_length_c   10.535
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   665.351
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.245  0.249  0.623  1.0
  Ba  Ba1  1  0.245  0.751  0.377  1.0
  Ba  Ba2  1  0.755  0.251  0.123  1.0
  Ba  Ba3  1  0.755  0.749  0.877  1.0
  S  S4  1  0.428  0.893  0.657  1.0
  S  S5  1  0.428  0.107  0.343  1.0
  S  S6  1  0.572  0.607  0.157  1.0
  S  S7  1  0.572  0.393  0.843  1.0
  S  S8  1  0.943  0.115  0.848  1.0
  S  S9  1  0.943  0.885  0.152  1.0
  S  S10  1  0.057  0.385  0.348  1.0
  S  S11  1  0.057  0.615  0.652  1.0
  S  S12  1  0.649  0.019  0.599  1.0
  S  S13  1  0.649  0.981  0.401  1.0
  S  S14  1  0.351  0.481  0.099  1.0
  S  S15  1  0.351  0.519  0.901  1.0
  S  S16  1  0.164  0.114  0.967  1.0
  S  S17  1  0.164  0.886  0.033  1.0
  S  S18  1  0.836  0.386  0.467  1.0
  S  S19  1  0.836  0.614  0.533  1.0
  O  O20  1  0.293  0.500  0.500  1.0
  O  O21  1  0.707  0.000  0.000  1.0
  O  O22  1  0.190  0.000  0.500  1.0
  O  O23  1  0.810  0.500  0.000  1.0
[/CIF]
.
The material structure described by BaS4O crystallizes in the orthorhombic P2_12_12 space group. Ba(1) is bonded in a distorted bent 120 degrees geometry to one S(2), two equivalent S(3), two equivalent S(4), one O(1), and one O(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to one S(3) atom. In the second S site, S(2) is bonded in a 2-coordinate geometry to one Ba(1) and one S(4) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one S(1), and one S(3) atom. In the fourth S site, S(4) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one S(2), and one S(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Ba(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Ba(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaS4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.224
_cell_length_b   8.743
_cell_length_c   10.535
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   665.351
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.245  0.249  0.623  1.0
  Ba  Ba1  1  0.245  0.751  0.377  1.0
  Ba  Ba2  1  0.755  0.251  0.123  1.0
  Ba  Ba3  1  0.755  0.749  0.877  1.0
  S  S4  1  0.428  0.893  0.657  1.0
  S  S5  1  0.428  0.107  0.343  1.0
  S  S6  1  0.572  0.607  0.157  1.0
  S  S7  1  0.572  0.393  0.843  1.0
  S  S8  1  0.943  0.115  0.848  1.0
  S  S9  1  0.943  0.885  0.152  1.0
  S  S10  1  0.057  0.385  0.348  1.0
  S  S11  1  0.057  0.615  0.652  1.0
  S  S12  1  0.649  0.019  0.599  1.0
  S  S13  1  0.649  0.981  0.401  1.0
  S  S14  1  0.351  0.481  0.099  1.0
  S  S15  1  0.351  0.519  0.901  1.0
  S  S16  1  0.164  0.114  0.967  1.0
  S  S17  1  0.164  0.886  0.033  1.0
  S  S18  1  0.836  0.386  0.467  1.0
  S  S19  1  0.836  0.614  0.533  1.0
  O  O20  1  0.293  0.500  0.500  1.0
  O  O21  1  0.707  0.000  0.000  1.0
  O  O22  1  0.190  0.000  0.500  1.0
  O  O23  1  0.810  0.500  0.000  1.0
[/CIF]
.