The structure described by AgY(WO4)2 crystallizes in the monoclinic P2/c space group. Y(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form distorted YO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-60°. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form distorted WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra, corners with four equivalent Ag(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-61°. Ag(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted AgO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-61°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Y(1), one W(1), and one Ag(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Y(1) and two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_YAg(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.000
_cell_length_b   5.243
_cell_length_c   11.363
_cell_angle_alpha   65.466
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   325.174
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.687  0.500  0.250  1.0
  Y  Y1  1  0.313  0.500  0.750  1.0
  Ag  Ag2  1  0.306  0.000  0.250  1.0
  Ag  Ag3  1  0.694  0.000  0.750  1.0
  W  W4  1  0.169  0.740  0.007  1.0
  W  W5  1  0.169  0.260  0.493  1.0
  W  W6  1  0.831  0.260  0.993  1.0
  W  W7  1  0.831  0.740  0.507  1.0
  O  O8  1  0.379  0.256  0.377  1.0
  O  O9  1  0.379  0.744  0.123  1.0
  O  O10  1  0.621  0.744  0.623  1.0
  O  O11  1  0.621  0.256  0.877  1.0
  O  O12  1  0.920  0.642  0.893  1.0
  O  O13  1  0.920  0.358  0.607  1.0
  O  O14  1  0.080  0.358  0.107  1.0
  O  O15  1  0.080  0.642  0.393  1.0
  O  O16  1  0.645  0.722  0.383  1.0
  O  O17  1  0.645  0.278  0.117  1.0
  O  O18  1  0.355  0.278  0.617  1.0
  O  O19  1  0.355  0.722  0.883  1.0
  O  O20  1  0.892  0.152  0.406  1.0
  O  O21  1  0.108  0.848  0.594  1.0
  O  O22  1  0.892  0.848  0.094  1.0
  O  O23  1  0.108  0.152  0.906  1.0
[/CIF]
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The structure described by AgY(WO4)2 crystallizes in the monoclinic P2/c space group. Y(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form distorted YO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-60°. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form distorted WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra, corners with four equivalent Ag(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-61°. Ag(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted AgO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-61°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Y(1), one W(1), and one Ag(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Y(1) and two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_YAg(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.000
_cell_length_b   5.243
_cell_length_c   11.363
_cell_angle_alpha   65.466
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   325.174
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.687  0.500  0.250  1.0
  Y  Y1  1  0.313  0.500  0.750  1.0
  Ag  Ag2  1  0.306  0.000  0.250  1.0
  Ag  Ag3  1  0.694  0.000  0.750  1.0
  W  W4  1  0.169  0.740  0.007  1.0
  W  W5  1  0.169  0.260  0.493  1.0
  W  W6  1  0.831  0.260  0.993  1.0
  W  W7  1  0.831  0.740  0.507  1.0
  O  O8  1  0.379  0.256  0.377  1.0
  O  O9  1  0.379  0.744  0.123  1.0
  O  O10  1  0.621  0.744  0.623  1.0
  O  O11  1  0.621  0.256  0.877  1.0
  O  O12  1  0.920  0.642  0.893  1.0
  O  O13  1  0.920  0.358  0.607  1.0
  O  O14  1  0.080  0.358  0.107  1.0
  O  O15  1  0.080  0.642  0.393  1.0
  O  O16  1  0.645  0.722  0.383  1.0
  O  O17  1  0.645  0.278  0.117  1.0
  O  O18  1  0.355  0.278  0.617  1.0
  O  O19  1  0.355  0.722  0.883  1.0
  O  O20  1  0.892  0.152  0.406  1.0
  O  O21  1  0.108  0.848  0.594  1.0
  O  O22  1  0.892  0.848  0.094  1.0
  O  O23  1  0.108  0.152  0.906  1.0
[/CIF]
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