The material described by Pt(NO)2O2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules and four Pt(NO)2 clusters. In each Pt(NO)2 cluster, Pt(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a linear geometry to one Pt(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_Pt(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.930
_cell_length_b   8.730
_cell_length_c   16.145
_cell_angle_alpha   75.126
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   671.502
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.000  0.500  1.0
  Pt  Pt1  1  0.000  0.500  0.500  1.0
  Pt  Pt2  1  0.500  0.500  0.000  1.0
  Pt  Pt3  1  0.000  0.000  0.000  1.0
  N  N4  1  0.767  0.879  0.562  1.0
  N  N5  1  0.267  0.621  0.438  1.0
  N  N6  1  0.233  0.121  0.438  1.0
  N  N7  1  0.733  0.379  0.562  1.0
  N  N8  1  0.234  0.555  0.065  1.0
  N  N9  1  0.734  0.945  0.935  1.0
  N  N10  1  0.766  0.445  0.935  1.0
  N  N11  1  0.266  0.055  0.065  1.0
  O  O12  1  0.442  0.699  0.398  1.0
  O  O13  1  0.942  0.801  0.602  1.0
  O  O14  1  0.558  0.301  0.602  1.0
  O  O15  1  0.058  0.199  0.398  1.0
  O  O16  1  0.561  0.907  0.894  1.0
  O  O17  1  0.061  0.593  0.106  1.0
  O  O18  1  0.439  0.093  0.106  1.0
  O  O19  1  0.939  0.407  0.894  1.0
  O  O20  1  0.890  0.878  0.260  1.0
  O  O21  1  0.390  0.622  0.740  1.0
  O  O22  1  0.110  0.122  0.740  1.0
  O  O23  1  0.610  0.378  0.260  1.0
  O  O24  1  0.255  0.711  0.772  1.0
  O  O25  1  0.755  0.789  0.228  1.0
  O  O26  1  0.745  0.289  0.228  1.0
  O  O27  1  0.245  0.211  0.772  1.0
[/CIF]
.
The material described by Pt(NO)2O2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules and four Pt(NO)2 clusters. In each Pt(NO)2 cluster, Pt(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a linear geometry to one Pt(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_Pt(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.930
_cell_length_b   8.730
_cell_length_c   16.145
_cell_angle_alpha   75.126
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   671.502
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.000  0.500  1.0
  Pt  Pt1  1  0.000  0.500  0.500  1.0
  Pt  Pt2  1  0.500  0.500  0.000  1.0
  Pt  Pt3  1  0.000  0.000  0.000  1.0
  N  N4  1  0.767  0.879  0.562  1.0
  N  N5  1  0.267  0.621  0.438  1.0
  N  N6  1  0.233  0.121  0.438  1.0
  N  N7  1  0.733  0.379  0.562  1.0
  N  N8  1  0.234  0.555  0.065  1.0
  N  N9  1  0.734  0.945  0.935  1.0
  N  N10  1  0.766  0.445  0.935  1.0
  N  N11  1  0.266  0.055  0.065  1.0
  O  O12  1  0.442  0.699  0.398  1.0
  O  O13  1  0.942  0.801  0.602  1.0
  O  O14  1  0.558  0.301  0.602  1.0
  O  O15  1  0.058  0.199  0.398  1.0
  O  O16  1  0.561  0.907  0.894  1.0
  O  O17  1  0.061  0.593  0.106  1.0
  O  O18  1  0.439  0.093  0.106  1.0
  O  O19  1  0.939  0.407  0.894  1.0
  O  O20  1  0.890  0.878  0.260  1.0
  O  O21  1  0.390  0.622  0.740  1.0
  O  O22  1  0.110  0.122  0.740  1.0
  O  O23  1  0.610  0.378  0.260  1.0
  O  O24  1  0.255  0.711  0.772  1.0
  O  O25  1  0.755  0.789  0.228  1.0
  O  O26  1  0.745  0.289  0.228  1.0
  O  O27  1  0.245  0.211  0.772  1.0
[/CIF]
.