The crystal structure described by ZnI4(I)2 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydriodic acid atoms and two ZnI4 clusters. In each ZnI4 cluster, Zn(1) is bonded in a distorted square co-planar geometry to four equivalent I(2) atoms. I(2) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnI6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.577
_cell_length_b   10.577
_cell_length_c   54.872
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.591
_symmetry_Int_Tables_number   1
_cell_volume   5746.481
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  I  I1  1  0.000  0.000  0.250  1.0
  I  I2  1  0.000  0.000  0.750  1.0
  I  I3  1  0.256  0.013  0.000  1.0
  I  I4  1  0.744  0.987  0.000  1.0
  I  I5  1  0.013  0.256  0.000  1.0
  I  I6  1  0.987  0.744  0.000  1.0
[/CIF]
.
The crystal structure described by ZnI4(I)2 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydriodic acid atoms and two ZnI4 clusters. In each ZnI4 cluster, Zn(1) is bonded in a distorted square co-planar geometry to four equivalent I(2) atoms. I(2) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnI6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.577
_cell_length_b   10.577
_cell_length_c   54.872
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.591
_symmetry_Int_Tables_number   1
_cell_volume   5746.481
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  I  I1  1  0.000  0.000  0.250  1.0
  I  I2  1  0.000  0.000  0.750  1.0
  I  I3  1  0.256  0.013  0.000  1.0
  I  I4  1  0.744  0.987  0.000  1.0
  I  I5  1  0.013  0.256  0.000  1.0
  I  I6  1  0.987  0.744  0.000  1.0
[/CIF]
.