The crystal structure described by C4NZnP2H3O8 crystallizes in the orthorhombic Fdd2 space group. The structure consists of eight C4N clusters inside a ZnP2H3O8 framework. In each C4N cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(2), and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. N(1) is bonded in a distorted bent 150 degrees geometry to two equivalent C(1) and two equivalent C(2) atoms. In the ZnP2H3O8 framework, Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to two equivalent O(3) atoms. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a trigonal planar geometry to one P(1), one H(1), and one H(2) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one H(2) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. is represented by the CIF card [CIF]
data_ZnP2H3C4NO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.951
_cell_length_b   8.951
_cell_length_c   9.446
_cell_angle_alpha   107.179
_cell_angle_beta   107.179
_cell_angle_gamma   112.123
_symmetry_Int_Tables_number   1
_cell_volume   594.975
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.515  0.485  0.000  1.0
  Zn  Zn1  1  0.265  0.735  0.500  1.0
  P  P2  1  0.258  0.548  0.743  1.0
  P  P3  1  0.452  0.742  0.257  1.0
  P  P4  1  0.265  0.055  0.757  1.0
  P  P5  1  0.945  0.735  0.243  1.0
  H  H6  1  0.275  0.725  0.000  1.0
  H  H7  1  0.025  0.975  0.500  1.0
  H  H8  1  0.111  0.259  0.678  1.0
  H  H9  1  0.741  0.889  0.322  1.0
  H  H10  1  0.183  0.831  0.822  1.0
  H  H11  1  0.169  0.817  0.178  1.0
  C  C12  1  0.619  0.496  0.476  1.0
  C  C13  1  0.504  0.381  0.524  1.0
  C  C14  1  0.892  0.270  0.024  1.0
  C  C15  1  0.730  0.108  0.976  1.0
  C  C16  1  0.619  0.330  0.622  1.0
  C  C17  1  0.670  0.381  0.378  1.0
  C  C18  1  0.747  0.958  0.878  1.0
  C  C19  1  0.042  0.253  0.122  1.0
  N  N20  1  0.669  0.331  0.500  1.0
  N  N21  1  0.919  0.081  0.000  1.0
  O  O22  1  0.439  0.555  0.826  1.0
  O  O23  1  0.445  0.561  0.174  1.0
  O  O24  1  0.363  0.978  0.674  1.0
  O  O25  1  0.022  0.637  0.326  1.0
  O  O26  1  0.407  0.227  0.919  1.0
  O  O27  1  0.773  0.593  0.081  1.0
  O  O28  1  0.238  0.557  0.581  1.0
  O  O29  1  0.443  0.762  0.419  1.0
  O  O30  1  0.249  0.705  0.861  1.0
  O  O31  1  0.295  0.751  0.139  1.0
  O  O32  1  0.138  0.093  0.639  1.0
  O  O33  1  0.907  0.862  0.361  1.0
  O  O34  1  0.093  0.368  0.708  1.0
  O  O35  1  0.632  0.907  0.292  1.0
  O  O36  1  0.135  0.910  0.792  1.0
  O  O37  1  0.090  0.865  0.208  1.0
[/CIF]
.
The crystal structure described by C4NZnP2H3O8 crystallizes in the orthorhombic Fdd2 space group. The structure consists of eight C4N clusters inside a ZnP2H3O8 framework. In each C4N cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(2), and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. N(1) is bonded in a distorted bent 150 degrees geometry to two equivalent C(1) and two equivalent C(2) atoms. In the ZnP2H3O8 framework, Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to two equivalent O(3) atoms. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a trigonal planar geometry to one P(1), one H(1), and one H(2) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one H(2) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. is represented by the CIF card [CIF]
data_ZnP2H3C4NO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.951
_cell_length_b   8.951
_cell_length_c   9.446
_cell_angle_alpha   107.179
_cell_angle_beta   107.179
_cell_angle_gamma   112.123
_symmetry_Int_Tables_number   1
_cell_volume   594.975
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.515  0.485  0.000  1.0
  Zn  Zn1  1  0.265  0.735  0.500  1.0
  P  P2  1  0.258  0.548  0.743  1.0
  P  P3  1  0.452  0.742  0.257  1.0
  P  P4  1  0.265  0.055  0.757  1.0
  P  P5  1  0.945  0.735  0.243  1.0
  H  H6  1  0.275  0.725  0.000  1.0
  H  H7  1  0.025  0.975  0.500  1.0
  H  H8  1  0.111  0.259  0.678  1.0
  H  H9  1  0.741  0.889  0.322  1.0
  H  H10  1  0.183  0.831  0.822  1.0
  H  H11  1  0.169  0.817  0.178  1.0
  C  C12  1  0.619  0.496  0.476  1.0
  C  C13  1  0.504  0.381  0.524  1.0
  C  C14  1  0.892  0.270  0.024  1.0
  C  C15  1  0.730  0.108  0.976  1.0
  C  C16  1  0.619  0.330  0.622  1.0
  C  C17  1  0.670  0.381  0.378  1.0
  C  C18  1  0.747  0.958  0.878  1.0
  C  C19  1  0.042  0.253  0.122  1.0
  N  N20  1  0.669  0.331  0.500  1.0
  N  N21  1  0.919  0.081  0.000  1.0
  O  O22  1  0.439  0.555  0.826  1.0
  O  O23  1  0.445  0.561  0.174  1.0
  O  O24  1  0.363  0.978  0.674  1.0
  O  O25  1  0.022  0.637  0.326  1.0
  O  O26  1  0.407  0.227  0.919  1.0
  O  O27  1  0.773  0.593  0.081  1.0
  O  O28  1  0.238  0.557  0.581  1.0
  O  O29  1  0.443  0.762  0.419  1.0
  O  O30  1  0.249  0.705  0.861  1.0
  O  O31  1  0.295  0.751  0.139  1.0
  O  O32  1  0.138  0.093  0.639  1.0
  O  O33  1  0.907  0.862  0.361  1.0
  O  O34  1  0.093  0.368  0.708  1.0
  O  O35  1  0.632  0.907  0.292  1.0
  O  O36  1  0.135  0.910  0.792  1.0
  O  O37  1  0.090  0.865  0.208  1.0
[/CIF]
.