The material described by P2S2O3 is alpha Po structured and crystallizes in the tetragonal I-4c2 space group. The structure is zero-dimensional and consists of four P2S2O3 clusters. P(1) is bonded to one S(1), one O(1), and two equivalent O(2) atoms to form distorted corner-sharing PSO3 tetrahedra. S(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_P2S2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.400
_cell_length_b   9.400
_cell_length_c   9.398
_cell_angle_alpha   122.183
_cell_angle_beta   122.184
_cell_angle_gamma   86.270
_symmetry_Int_Tables_number   1
_cell_volume   566.449
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.025  0.720  0.392  1.0
  P  P1  1  0.328  0.633  0.608  1.0
  P  P2  1  0.525  0.133  0.305  1.0
  P  P3  1  0.280  0.672  0.305  1.0
  P  P4  1  0.367  0.975  0.695  1.0
  P  P5  1  0.780  0.475  0.608  1.0
  P  P6  1  0.867  0.172  0.392  1.0
  P  P7  1  0.828  0.220  0.695  1.0
  S  S8  1  0.786  0.687  0.277  1.0
  S  S9  1  0.910  0.187  0.901  1.0
  S  S10  1  0.313  0.590  0.099  1.0
  S  S11  1  0.491  0.214  0.901  1.0
  S  S12  1  0.813  0.714  0.723  1.0
  S  S13  1  0.991  0.090  0.277  1.0
  S  S14  1  0.286  0.009  0.099  1.0
  S  S15  1  0.410  0.509  0.723  1.0
  O  O16  1  0.121  0.621  0.500  1.0
  O  O17  1  0.843  0.419  0.763  1.0
  O  O18  1  0.656  0.080  0.237  1.0
  O  O19  1  0.581  0.344  0.423  1.0
  O  O20  1  0.342  0.580  0.423  1.0
  O  O21  1  0.156  0.919  0.577  1.0
  O  O22  1  0.920  0.158  0.577  1.0
  O  O23  1  0.420  0.844  0.763  1.0
  O  O24  1  0.379  0.879  0.500  1.0
  O  O25  1  0.879  0.379  0.500  1.0
  O  O26  1  0.621  0.121  0.500  1.0
  O  O27  1  0.081  0.657  0.237  1.0
[/CIF]
.
The material described by P2S2O3 is alpha Po structured and crystallizes in the tetragonal I-4c2 space group. The structure is zero-dimensional and consists of four P2S2O3 clusters. P(1) is bonded to one S(1), one O(1), and two equivalent O(2) atoms to form distorted corner-sharing PSO3 tetrahedra. S(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_P2S2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.400
_cell_length_b   9.400
_cell_length_c   9.398
_cell_angle_alpha   122.183
_cell_angle_beta   122.184
_cell_angle_gamma   86.270
_symmetry_Int_Tables_number   1
_cell_volume   566.449
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.025  0.720  0.392  1.0
  P  P1  1  0.328  0.633  0.608  1.0
  P  P2  1  0.525  0.133  0.305  1.0
  P  P3  1  0.280  0.672  0.305  1.0
  P  P4  1  0.367  0.975  0.695  1.0
  P  P5  1  0.780  0.475  0.608  1.0
  P  P6  1  0.867  0.172  0.392  1.0
  P  P7  1  0.828  0.220  0.695  1.0
  S  S8  1  0.786  0.687  0.277  1.0
  S  S9  1  0.910  0.187  0.901  1.0
  S  S10  1  0.313  0.590  0.099  1.0
  S  S11  1  0.491  0.214  0.901  1.0
  S  S12  1  0.813  0.714  0.723  1.0
  S  S13  1  0.991  0.090  0.277  1.0
  S  S14  1  0.286  0.009  0.099  1.0
  S  S15  1  0.410  0.509  0.723  1.0
  O  O16  1  0.121  0.621  0.500  1.0
  O  O17  1  0.843  0.419  0.763  1.0
  O  O18  1  0.656  0.080  0.237  1.0
  O  O19  1  0.581  0.344  0.423  1.0
  O  O20  1  0.342  0.580  0.423  1.0
  O  O21  1  0.156  0.919  0.577  1.0
  O  O22  1  0.920  0.158  0.577  1.0
  O  O23  1  0.420  0.844  0.763  1.0
  O  O24  1  0.379  0.879  0.500  1.0
  O  O25  1  0.879  0.379  0.500  1.0
  O  O26  1  0.621  0.121  0.500  1.0
  O  O27  1  0.081  0.657  0.237  1.0
[/CIF]
.