The structure described by RbMg6Mn crystallizes in the orthorhombic Amm2 space group. Rb(1) is bonded to two equivalent Mg(4), four equivalent Mg(1), four equivalent Mg(2), and two equivalent Mn(1) atoms to form RbMg10Mn2 cuboctahedra that share corners with four equivalent Mn(1)Rb2Mg10 cuboctahedra, corners with six equivalent Rb(1)Mg10Mn2 cuboctahedra, edges with two equivalent Mn(1)Rb2Mg10 cuboctahedra, faces with two equivalent Rb(1)Mg10Mn2 cuboctahedra, and faces with two equivalent Mn(1)Rb2Mg10 cuboctahedra. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a 12-coordinate geometry to two equivalent Rb(1), two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(3), two equivalent Mg(4), and two equivalent Mn(1) atoms. In the second Mg site, Mg(2) is bonded in a 9-coordinate geometry to two equivalent Rb(1), one Mg(2), one Mg(4), two equivalent Mg(1), two equivalent Mg(3), and two equivalent Mn(1) atoms. In the third Mg site, Mg(3) is bonded in a 12-coordinate geometry to two equivalent Mg(4), four equivalent Mg(1), four equivalent Mg(2), and two equivalent Mn(1) atoms. In the fourth Mg site, Mg(4) is bonded in a 10-coordinate geometry to two equivalent Rb(1), two equivalent Mg(2), two equivalent Mg(3), and four equivalent Mg(1) atoms. Mn(1) is bonded to two equivalent Rb(1), two equivalent Mg(3), four equivalent Mg(1), and four equivalent Mg(2) atoms to form MnRb2Mg10 cuboctahedra that share corners with four equivalent Rb(1)Mg10Mn2 cuboctahedra, corners with six equivalent Mn(1)Rb2Mg10 cuboctahedra, edges with two equivalent Rb(1)Mg10Mn2 cuboctahedra, faces with two equivalent Rb(1)Mg10Mn2 cuboctahedra, and faces with two equivalent Mn(1)Rb2Mg10 cuboctahedra. is represented by the CIF card [CIF]
data_RbMg6Mn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.253
_cell_length_b   6.740
_cell_length_c   6.740
_cell_angle_alpha   118.277
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   210.133
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.673  0.836  1.0
  Mg  Mg1  1  0.500  0.164  0.327  1.0
  Mg  Mg2  1  1.000  0.864  0.701  1.0
  Mg  Mg3  1  1.000  0.299  0.136  1.0
  Mg  Mg4  1  0.000  0.329  0.671  1.0
  Mg  Mg5  1  0.000  0.849  0.151  1.0
  Mn  Mn6  1  0.500  0.157  0.843  1.0
  Rb  Rb7  1  0.500  0.664  0.336  1.0
[/CIF]
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The structure described by RbMg6Mn crystallizes in the orthorhombic Amm2 space group. Rb(1) is bonded to two equivalent Mg(4), four equivalent Mg(1), four equivalent Mg(2), and two equivalent Mn(1) atoms to form RbMg10Mn2 cuboctahedra that share corners with four equivalent Mn(1)Rb2Mg10 cuboctahedra, corners with six equivalent Rb(1)Mg10Mn2 cuboctahedra, edges with two equivalent Mn(1)Rb2Mg10 cuboctahedra, faces with two equivalent Rb(1)Mg10Mn2 cuboctahedra, and faces with two equivalent Mn(1)Rb2Mg10 cuboctahedra. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a 12-coordinate geometry to two equivalent Rb(1), two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(3), two equivalent Mg(4), and two equivalent Mn(1) atoms. In the second Mg site, Mg(2) is bonded in a 9-coordinate geometry to two equivalent Rb(1), one Mg(2), one Mg(4), two equivalent Mg(1), two equivalent Mg(3), and two equivalent Mn(1) atoms. In the third Mg site, Mg(3) is bonded in a 12-coordinate geometry to two equivalent Mg(4), four equivalent Mg(1), four equivalent Mg(2), and two equivalent Mn(1) atoms. In the fourth Mg site, Mg(4) is bonded in a 10-coordinate geometry to two equivalent Rb(1), two equivalent Mg(2), two equivalent Mg(3), and four equivalent Mg(1) atoms. Mn(1) is bonded to two equivalent Rb(1), two equivalent Mg(3), four equivalent Mg(1), and four equivalent Mg(2) atoms to form MnRb2Mg10 cuboctahedra that share corners with four equivalent Rb(1)Mg10Mn2 cuboctahedra, corners with six equivalent Mn(1)Rb2Mg10 cuboctahedra, edges with two equivalent Rb(1)Mg10Mn2 cuboctahedra, faces with two equivalent Rb(1)Mg10Mn2 cuboctahedra, and faces with two equivalent Mn(1)Rb2Mg10 cuboctahedra. is represented by the CIF card [CIF]
data_RbMg6Mn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.253
_cell_length_b   6.740
_cell_length_c   6.740
_cell_angle_alpha   118.277
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   210.133
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.673  0.836  1.0
  Mg  Mg1  1  0.500  0.164  0.327  1.0
  Mg  Mg2  1  1.000  0.864  0.701  1.0
  Mg  Mg3  1  1.000  0.299  0.136  1.0
  Mg  Mg4  1  0.000  0.329  0.671  1.0
  Mg  Mg5  1  0.000  0.849  0.151  1.0
  Mn  Mn6  1  0.500  0.157  0.843  1.0
  Rb  Rb7  1  0.500  0.664  0.336  1.0
[/CIF]
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