The material structure described by (PdCOCl2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two PdCOCl2 clusters. In each PdCOCl2 cluster, Pd(1) is bonded in a rectangular see-saw-like geometry to two equivalent C(1), one Cl(1), and one Cl(2) atom. C(1) is bonded in a distorted single-bond geometry to two equivalent Pd(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF card [CIF]
data_PdCNCl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.020
_cell_length_b   4.244
_cell_length_c   14.826
_cell_angle_alpha   83.303
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   563.618
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.603  0.194  0.959  1.0
  Pd  Pd1  1  0.103  0.806  0.541  1.0
  Pd  Pd2  1  0.397  0.806  0.041  1.0
  Pd  Pd3  1  0.897  0.194  0.459  1.0
  C  C4  1  0.415  0.999  0.906  1.0
  C  C5  1  0.915  0.001  0.594  1.0
  C  C6  1  0.585  0.001  0.094  1.0
  C  C7  1  0.085  0.999  0.406  1.0
  N  N8  1  0.486  0.977  0.651  1.0
  N  N9  1  0.986  0.023  0.849  1.0
  N  N10  1  0.514  0.023  0.349  1.0
  N  N11  1  0.014  0.977  0.151  1.0
  Cl  Cl12  1  0.801  0.494  0.996  1.0
  Cl  Cl13  1  0.301  0.506  0.504  1.0
  Cl  Cl14  1  0.199  0.506  0.004  1.0
  Cl  Cl15  1  0.699  0.494  0.496  1.0
  Cl  Cl16  1  0.660  0.421  0.816  1.0
  Cl  Cl17  1  0.160  0.579  0.684  1.0
  Cl  Cl18  1  0.340  0.579  0.184  1.0
  Cl  Cl19  1  0.840  0.421  0.316  1.0
  O  O20  1  0.352  0.998  0.838  1.0
  O  O21  1  0.852  0.002  0.662  1.0
  O  O22  1  0.648  0.002  0.162  1.0
  O  O23  1  0.148  0.998  0.338  1.0
[/CIF]
.
The material structure described by (PdCOCl2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two PdCOCl2 clusters. In each PdCOCl2 cluster, Pd(1) is bonded in a rectangular see-saw-like geometry to two equivalent C(1), one Cl(1), and one Cl(2) atom. C(1) is bonded in a distorted single-bond geometry to two equivalent Pd(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF card [CIF]
data_PdCNCl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.020
_cell_length_b   4.244
_cell_length_c   14.826
_cell_angle_alpha   83.303
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   563.618
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.603  0.194  0.959  1.0
  Pd  Pd1  1  0.103  0.806  0.541  1.0
  Pd  Pd2  1  0.397  0.806  0.041  1.0
  Pd  Pd3  1  0.897  0.194  0.459  1.0
  C  C4  1  0.415  0.999  0.906  1.0
  C  C5  1  0.915  0.001  0.594  1.0
  C  C6  1  0.585  0.001  0.094  1.0
  C  C7  1  0.085  0.999  0.406  1.0
  N  N8  1  0.486  0.977  0.651  1.0
  N  N9  1  0.986  0.023  0.849  1.0
  N  N10  1  0.514  0.023  0.349  1.0
  N  N11  1  0.014  0.977  0.151  1.0
  Cl  Cl12  1  0.801  0.494  0.996  1.0
  Cl  Cl13  1  0.301  0.506  0.504  1.0
  Cl  Cl14  1  0.199  0.506  0.004  1.0
  Cl  Cl15  1  0.699  0.494  0.496  1.0
  Cl  Cl16  1  0.660  0.421  0.816  1.0
  Cl  Cl17  1  0.160  0.579  0.684  1.0
  Cl  Cl18  1  0.340  0.579  0.184  1.0
  Cl  Cl19  1  0.840  0.421  0.316  1.0
  O  O20  1  0.352  0.998  0.838  1.0
  O  O21  1  0.852  0.002  0.662  1.0
  O  O22  1  0.648  0.002  0.162  1.0
  O  O23  1  0.148  0.998  0.338  1.0
[/CIF]
.