The crystal structure described by Tb2PdGe6 crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 10-coordinate geometry to two equivalent Ge(2), two equivalent Ge(4), two equivalent Ge(5), and four equivalent Ge(6) atoms. In the second Tb site, Tb(2) is bonded in a 14-coordinate geometry to four equivalent Pd(1), two equivalent Ge(1), two equivalent Ge(3), two equivalent Ge(6), and four equivalent Ge(5) atoms. Pd(1) is bonded in a 9-coordinate geometry to four equivalent Tb(2), one Ge(5), two equivalent Ge(1), and two equivalent Ge(3) atoms. There are six inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Tb(2), two equivalent Pd(1), one Ge(2), and four equivalent Ge(3) atoms. In the second Ge site, Ge(2) is bonded in a 7-coordinate geometry to two equivalent Tb(1), one Ge(1), and four equivalent Ge(4) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Tb(2), two equivalent Pd(1), one Ge(4), and four equivalent Ge(1) atoms. In the fourth Ge site, Ge(4) is bonded in a 7-coordinate geometry to two equivalent Tb(1), one Ge(3), and four equivalent Ge(2) atoms. In the fifth Ge site, Ge(5) is bonded in a 9-coordinate geometry to two equivalent Tb(1), four equivalent Tb(2), one Pd(1), and two equivalent Ge(6) atoms. In the sixth Ge site, Ge(6) is bonded in a 8-coordinate geometry to two equivalent Tb(2), four equivalent Tb(1), and two equivalent Ge(5) atoms. is represented by the CIF file [CIF]
data_Tb2Ge6Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.064
_cell_length_b   4.103
_cell_length_c   11.191
_cell_angle_alpha   90.000
_cell_angle_beta   100.462
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   183.529
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.777  0.500  0.555  1.0
  Tb  Tb1  1  0.118  0.500  0.236  1.0
  Ge  Ge2  1  0.493  0.500  0.986  1.0
  Ge  Ge3  1  0.379  0.500  0.759  1.0
  Ge  Ge4  1  0.992  0.000  0.984  1.0
  Ge  Ge5  1  0.878  0.000  0.756  1.0
  Ge  Ge6  1  0.670  0.000  0.339  1.0
  Ge  Ge7  1  0.241  0.000  0.482  1.0
  Pd  Pd8  1  0.559  0.000  0.118  1.0
[/CIF]
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The crystal structure described by Tb2PdGe6 crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 10-coordinate geometry to two equivalent Ge(2), two equivalent Ge(4), two equivalent Ge(5), and four equivalent Ge(6) atoms. In the second Tb site, Tb(2) is bonded in a 14-coordinate geometry to four equivalent Pd(1), two equivalent Ge(1), two equivalent Ge(3), two equivalent Ge(6), and four equivalent Ge(5) atoms. Pd(1) is bonded in a 9-coordinate geometry to four equivalent Tb(2), one Ge(5), two equivalent Ge(1), and two equivalent Ge(3) atoms. There are six inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Tb(2), two equivalent Pd(1), one Ge(2), and four equivalent Ge(3) atoms. In the second Ge site, Ge(2) is bonded in a 7-coordinate geometry to two equivalent Tb(1), one Ge(1), and four equivalent Ge(4) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Tb(2), two equivalent Pd(1), one Ge(4), and four equivalent Ge(1) atoms. In the fourth Ge site, Ge(4) is bonded in a 7-coordinate geometry to two equivalent Tb(1), one Ge(3), and four equivalent Ge(2) atoms. In the fifth Ge site, Ge(5) is bonded in a 9-coordinate geometry to two equivalent Tb(1), four equivalent Tb(2), one Pd(1), and two equivalent Ge(6) atoms. In the sixth Ge site, Ge(6) is bonded in a 8-coordinate geometry to two equivalent Tb(2), four equivalent Tb(1), and two equivalent Ge(5) atoms. is represented by the CIF file [CIF]
data_Tb2Ge6Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.064
_cell_length_b   4.103
_cell_length_c   11.191
_cell_angle_alpha   90.000
_cell_angle_beta   100.462
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   183.529
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.777  0.500  0.555  1.0
  Tb  Tb1  1  0.118  0.500  0.236  1.0
  Ge  Ge2  1  0.493  0.500  0.986  1.0
  Ge  Ge3  1  0.379  0.500  0.759  1.0
  Ge  Ge4  1  0.992  0.000  0.984  1.0
  Ge  Ge5  1  0.878  0.000  0.756  1.0
  Ge  Ge6  1  0.670  0.000  0.339  1.0
  Ge  Ge7  1  0.241  0.000  0.482  1.0
  Pd  Pd8  1  0.559  0.000  0.118  1.0
[/CIF]
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