The material structure described by Zn(AgO2)2 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form AgO4 tetrahedra that share corners with six equivalent Ag(2)O6 octahedra and corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-77°. In the second Ag site, Ag(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form AgO6 octahedra that share corners with six equivalent Ag(1)O4 tetrahedra, edges with two equivalent Ag(2)O6 octahedra, and edges with four equivalent Zn(1)O6 octahedra. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Ag(1)O4 tetrahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Ag(2)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Zn(1) atoms to form OZn2Ag2 trigonal pyramids that share corners with six equivalent O(1)Zn2Ag2 trigonal pyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(1)Zn2Ag2 trigonal pyramid, and edges with two equivalent O(2)ZnAg3 trigonal pyramids. In the second O site, O(2) is bonded to one Ag(1), two equivalent Ag(2), and one Zn(1) atom to form OZnAg3 trigonal pyramids that share corners with six equivalent O(1)Zn2Ag2 trigonal pyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(2)ZnAg3 trigonal pyramid, and edges with two equivalent O(1)Zn2Ag2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.228
_cell_length_b   6.228
_cell_length_c   6.228
_cell_angle_alpha   117.513
_cell_angle_beta   114.238
_cell_angle_gamma   97.326
_symmetry_Int_Tables_number   1
_cell_volume   179.715
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.000  1.0
  Zn  Zn1  1  0.000  0.000  0.500  1.0
  Ag  Ag2  1  0.599  0.849  0.750  1.0
  Ag  Ag3  1  0.401  0.151  0.250  1.0
  Ag  Ag4  1  0.000  0.500  0.500  1.0
  Ag  Ag5  1  0.500  0.500  0.000  1.0
  O  O6  1  0.800  0.250  0.550  1.0
  O  O7  1  0.260  0.720  0.960  1.0
  O  O8  1  0.200  0.250  0.950  1.0
  O  O9  1  0.260  0.301  0.540  1.0
  O  O10  1  0.740  0.699  0.460  1.0
  O  O11  1  0.740  0.280  0.040  1.0
  O  O12  1  0.800  0.750  0.050  1.0
  O  O13  1  0.200  0.750  0.450  1.0
[/CIF]
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The material structure described by Zn(AgO2)2 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form AgO4 tetrahedra that share corners with six equivalent Ag(2)O6 octahedra and corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-77°. In the second Ag site, Ag(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form AgO6 octahedra that share corners with six equivalent Ag(1)O4 tetrahedra, edges with two equivalent Ag(2)O6 octahedra, and edges with four equivalent Zn(1)O6 octahedra. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Ag(1)O4 tetrahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Ag(2)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Zn(1) atoms to form OZn2Ag2 trigonal pyramids that share corners with six equivalent O(1)Zn2Ag2 trigonal pyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(1)Zn2Ag2 trigonal pyramid, and edges with two equivalent O(2)ZnAg3 trigonal pyramids. In the second O site, O(2) is bonded to one Ag(1), two equivalent Ag(2), and one Zn(1) atom to form OZnAg3 trigonal pyramids that share corners with six equivalent O(1)Zn2Ag2 trigonal pyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(2)ZnAg3 trigonal pyramid, and edges with two equivalent O(1)Zn2Ag2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.228
_cell_length_b   6.228
_cell_length_c   6.228
_cell_angle_alpha   117.513
_cell_angle_beta   114.238
_cell_angle_gamma   97.326
_symmetry_Int_Tables_number   1
_cell_volume   179.715
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.000  1.0
  Zn  Zn1  1  0.000  0.000  0.500  1.0
  Ag  Ag2  1  0.599  0.849  0.750  1.0
  Ag  Ag3  1  0.401  0.151  0.250  1.0
  Ag  Ag4  1  0.000  0.500  0.500  1.0
  Ag  Ag5  1  0.500  0.500  0.000  1.0
  O  O6  1  0.800  0.250  0.550  1.0
  O  O7  1  0.260  0.720  0.960  1.0
  O  O8  1  0.200  0.250  0.950  1.0
  O  O9  1  0.260  0.301  0.540  1.0
  O  O10  1  0.740  0.699  0.460  1.0
  O  O11  1  0.740  0.280  0.040  1.0
  O  O12  1  0.800  0.750  0.050  1.0
  O  O13  1  0.200  0.750  0.450  1.0
[/CIF]
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