The crystal structure described by Ba(BF4)(AsF6) crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 9-coordinate geometry to one F(2), one F(3), one F(4), two equivalent F(1), two equivalent F(5), and two equivalent F(7) atoms. B(1) is bonded in a tetrahedral geometry to one F(2), one F(3), and two equivalent F(1) atoms. As(1) is bonded in an octahedral geometry to one F(4), one F(6), two equivalent F(5), and two equivalent F(7) atoms. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted single-bond geometry to one Ba(1) and one As(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a distorted single-bond geometry to one Ba(1) and one B(1) atom. In the fourth F site, F(7) is bonded in a distorted single-bond geometry to one Ba(1) and one As(1) atom. In the fifth F site, F(2) is bonded in a distorted single-bond geometry to one Ba(1) and one B(1) atom. In the sixth F site, F(3) is bonded in a distorted single-bond geometry to one Ba(1) and one B(1) atom. In the seventh F site, F(4) is bonded in a distorted single-bond geometry to one Ba(1) and one As(1) atom. is represented by the CIF card [CIF]
data_BaBAsF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.492
_cell_length_b   10.706
_cell_length_c   12.134
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   843.337
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.750  0.265  0.611  1.0
  Ba  Ba1  1  0.750  0.765  0.889  1.0
  Ba  Ba2  1  0.250  0.735  0.389  1.0
  Ba  Ba3  1  0.250  0.235  0.111  1.0
  B  B4  1  0.750  0.642  0.571  1.0
  B  B5  1  0.750  0.142  0.929  1.0
  B  B6  1  0.250  0.358  0.429  1.0
  B  B7  1  0.250  0.858  0.071  1.0
  As  As8  1  0.250  0.983  0.699  1.0
  As  As9  1  0.250  0.483  0.801  1.0
  As  As10  1  0.750  0.017  0.301  1.0
  As  As11  1  0.750  0.517  0.199  1.0
  F  F12  1  0.573  0.686  0.516  1.0
  F  F13  1  0.927  0.186  0.984  1.0
  F  F14  1  0.073  0.314  0.484  1.0
  F  F15  1  0.427  0.814  0.016  1.0
  F  F16  1  0.427  0.314  0.484  1.0
  F  F17  1  0.073  0.814  0.016  1.0
  F  F18  1  0.927  0.686  0.516  1.0
  F  F19  1  0.573  0.186  0.984  1.0
  F  F20  1  0.750  0.510  0.572  1.0
  F  F21  1  0.750  0.010  0.928  1.0
  F  F22  1  0.250  0.490  0.428  1.0
  F  F23  1  0.250  0.990  0.072  1.0
  F  F24  1  0.750  0.686  0.681  1.0
  F  F25  1  0.750  0.186  0.819  1.0
  F  F26  1  0.250  0.314  0.319  1.0
  F  F27  1  0.250  0.814  0.181  1.0
  F  F28  1  0.250  0.889  0.578  1.0
  F  F29  1  0.250  0.389  0.922  1.0
  F  F30  1  0.750  0.111  0.422  1.0
  F  F31  1  0.750  0.611  0.078  1.0
  F  F32  1  0.443  0.885  0.756  1.0
  F  F33  1  0.057  0.385  0.744  1.0
  F  F34  1  0.943  0.115  0.244  1.0
  F  F35  1  0.557  0.615  0.256  1.0
  F  F36  1  0.557  0.115  0.244  1.0
  F  F37  1  0.943  0.615  0.256  1.0
  F  F38  1  0.057  0.885  0.756  1.0
  F  F39  1  0.443  0.385  0.744  1.0
  F  F40  1  0.250  0.076  0.817  1.0
  F  F41  1  0.250  0.576  0.683  1.0
  F  F42  1  0.750  0.924  0.183  1.0
  F  F43  1  0.750  0.424  0.317  1.0
  F  F44  1  0.055  0.078  0.638  1.0
  F  F45  1  0.445  0.578  0.862  1.0
  F  F46  1  0.555  0.922  0.362  1.0
  F  F47  1  0.945  0.422  0.138  1.0
  F  F48  1  0.945  0.922  0.362  1.0
  F  F49  1  0.555  0.422  0.138  1.0
  F  F50  1  0.445  0.078  0.638  1.0
  F  F51  1  0.055  0.578  0.862  1.0
[/CIF]
.
The crystal structure described by Ba(BF4)(AsF6) crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 9-coordinate geometry to one F(2), one F(3), one F(4), two equivalent F(1), two equivalent F(5), and two equivalent F(7) atoms. B(1) is bonded in a tetrahedral geometry to one F(2), one F(3), and two equivalent F(1) atoms. As(1) is bonded in an octahedral geometry to one F(4), one F(6), two equivalent F(5), and two equivalent F(7) atoms. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted single-bond geometry to one Ba(1) and one As(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a distorted single-bond geometry to one Ba(1) and one B(1) atom. In the fourth F site, F(7) is bonded in a distorted single-bond geometry to one Ba(1) and one As(1) atom. In the fifth F site, F(2) is bonded in a distorted single-bond geometry to one Ba(1) and one B(1) atom. In the sixth F site, F(3) is bonded in a distorted single-bond geometry to one Ba(1) and one B(1) atom. In the seventh F site, F(4) is bonded in a distorted single-bond geometry to one Ba(1) and one As(1) atom. is represented by the CIF card [CIF]
data_BaBAsF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.492
_cell_length_b   10.706
_cell_length_c   12.134
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   843.337
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.750  0.265  0.611  1.0
  Ba  Ba1  1  0.750  0.765  0.889  1.0
  Ba  Ba2  1  0.250  0.735  0.389  1.0
  Ba  Ba3  1  0.250  0.235  0.111  1.0
  B  B4  1  0.750  0.642  0.571  1.0
  B  B5  1  0.750  0.142  0.929  1.0
  B  B6  1  0.250  0.358  0.429  1.0
  B  B7  1  0.250  0.858  0.071  1.0
  As  As8  1  0.250  0.983  0.699  1.0
  As  As9  1  0.250  0.483  0.801  1.0
  As  As10  1  0.750  0.017  0.301  1.0
  As  As11  1  0.750  0.517  0.199  1.0
  F  F12  1  0.573  0.686  0.516  1.0
  F  F13  1  0.927  0.186  0.984  1.0
  F  F14  1  0.073  0.314  0.484  1.0
  F  F15  1  0.427  0.814  0.016  1.0
  F  F16  1  0.427  0.314  0.484  1.0
  F  F17  1  0.073  0.814  0.016  1.0
  F  F18  1  0.927  0.686  0.516  1.0
  F  F19  1  0.573  0.186  0.984  1.0
  F  F20  1  0.750  0.510  0.572  1.0
  F  F21  1  0.750  0.010  0.928  1.0
  F  F22  1  0.250  0.490  0.428  1.0
  F  F23  1  0.250  0.990  0.072  1.0
  F  F24  1  0.750  0.686  0.681  1.0
  F  F25  1  0.750  0.186  0.819  1.0
  F  F26  1  0.250  0.314  0.319  1.0
  F  F27  1  0.250  0.814  0.181  1.0
  F  F28  1  0.250  0.889  0.578  1.0
  F  F29  1  0.250  0.389  0.922  1.0
  F  F30  1  0.750  0.111  0.422  1.0
  F  F31  1  0.750  0.611  0.078  1.0
  F  F32  1  0.443  0.885  0.756  1.0
  F  F33  1  0.057  0.385  0.744  1.0
  F  F34  1  0.943  0.115  0.244  1.0
  F  F35  1  0.557  0.615  0.256  1.0
  F  F36  1  0.557  0.115  0.244  1.0
  F  F37  1  0.943  0.615  0.256  1.0
  F  F38  1  0.057  0.885  0.756  1.0
  F  F39  1  0.443  0.385  0.744  1.0
  F  F40  1  0.250  0.076  0.817  1.0
  F  F41  1  0.250  0.576  0.683  1.0
  F  F42  1  0.750  0.924  0.183  1.0
  F  F43  1  0.750  0.424  0.317  1.0
  F  F44  1  0.055  0.078  0.638  1.0
  F  F45  1  0.445  0.578  0.862  1.0
  F  F46  1  0.555  0.922  0.362  1.0
  F  F47  1  0.945  0.422  0.138  1.0
  F  F48  1  0.945  0.922  0.362  1.0
  F  F49  1  0.555  0.422  0.138  1.0
  F  F50  1  0.445  0.078  0.638  1.0
  F  F51  1  0.055  0.578  0.862  1.0
[/CIF]
.