The material structure described by Zn(MoO2)2 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form distorted MoO4 tetrahedra that share corners with six equivalent Mo(2)O6 octahedra and corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-65°. In the second Mo site, Mo(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MoO6 octahedra that share corners with six equivalent Mo(1)O4 tetrahedra, edges with two equivalent Mo(2)O6 octahedra, and edges with four equivalent Zn(1)O6 octahedra. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Mo(1)O4 tetrahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Mo(2)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), two equivalent Mo(2), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(MoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.460
_cell_length_b   6.460
_cell_length_c   6.460
_cell_angle_alpha   124.380
_cell_angle_beta   123.067
_cell_angle_gamma   83.667
_symmetry_Int_Tables_number   1
_cell_volume   178.702
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.000  1.0
  Zn  Zn1  1  0.000  0.000  0.500  1.0
  Mo  Mo2  1  0.621  0.871  0.750  1.0
  Mo  Mo3  1  0.379  0.129  0.250  1.0
  Mo  Mo4  1  0.000  0.500  0.500  1.0
  Mo  Mo5  1  0.500  0.500  0.000  1.0
  O  O6  1  0.775  0.276  0.499  1.0
  O  O7  1  0.225  0.726  0.002  1.0
  O  O8  1  0.277  0.276  0.001  1.0
  O  O9  1  0.225  0.223  0.498  1.0
  O  O10  1  0.775  0.777  0.502  1.0
  O  O11  1  0.775  0.274  0.998  1.0
  O  O12  1  0.723  0.724  0.999  1.0
  O  O13  1  0.225  0.724  0.501  1.0
[/CIF]
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The material structure described by Zn(MoO2)2 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form distorted MoO4 tetrahedra that share corners with six equivalent Mo(2)O6 octahedra and corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-65°. In the second Mo site, Mo(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MoO6 octahedra that share corners with six equivalent Mo(1)O4 tetrahedra, edges with two equivalent Mo(2)O6 octahedra, and edges with four equivalent Zn(1)O6 octahedra. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Mo(1)O4 tetrahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Mo(2)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), two equivalent Mo(2), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(MoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.460
_cell_length_b   6.460
_cell_length_c   6.460
_cell_angle_alpha   124.380
_cell_angle_beta   123.067
_cell_angle_gamma   83.667
_symmetry_Int_Tables_number   1
_cell_volume   178.702
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.000  1.0
  Zn  Zn1  1  0.000  0.000  0.500  1.0
  Mo  Mo2  1  0.621  0.871  0.750  1.0
  Mo  Mo3  1  0.379  0.129  0.250  1.0
  Mo  Mo4  1  0.000  0.500  0.500  1.0
  Mo  Mo5  1  0.500  0.500  0.000  1.0
  O  O6  1  0.775  0.276  0.499  1.0
  O  O7  1  0.225  0.726  0.002  1.0
  O  O8  1  0.277  0.276  0.001  1.0
  O  O9  1  0.225  0.223  0.498  1.0
  O  O10  1  0.775  0.777  0.502  1.0
  O  O11  1  0.775  0.274  0.998  1.0
  O  O12  1  0.723  0.724  0.999  1.0
  O  O13  1  0.225  0.724  0.501  1.0
[/CIF]
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