The structure described by BiOF is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Bi(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing BiO4F3 pentagonal bipyramids. O(1) is bonded to four equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OBi4 tetrahedra. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_BiOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.773
_cell_length_b   5.818
_cell_length_c   6.038
_cell_angle_alpha   81.802
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   200.726
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.519  0.289  0.300  1.0
  Bi  Bi1  1  0.981  0.789  0.300  1.0
  Bi  Bi2  1  0.019  0.211  0.700  1.0
  Bi  Bi3  1  0.481  0.711  0.700  1.0
  O  O4  1  0.247  0.010  0.469  1.0
  O  O5  1  0.253  0.510  0.469  1.0
  O  O6  1  0.747  0.490  0.531  1.0
  O  O7  1  0.753  0.990  0.531  1.0
  F  F8  1  0.816  0.135  0.061  1.0
  F  F9  1  0.684  0.635  0.061  1.0
  F  F10  1  0.316  0.365  0.939  1.0
  F  F11  1  0.184  0.865  0.939  1.0
[/CIF]
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The structure described by BiOF is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Bi(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing BiO4F3 pentagonal bipyramids. O(1) is bonded to four equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OBi4 tetrahedra. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_BiOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.773
_cell_length_b   5.818
_cell_length_c   6.038
_cell_angle_alpha   81.802
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   200.726
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.519  0.289  0.300  1.0
  Bi  Bi1  1  0.981  0.789  0.300  1.0
  Bi  Bi2  1  0.019  0.211  0.700  1.0
  Bi  Bi3  1  0.481  0.711  0.700  1.0
  O  O4  1  0.247  0.010  0.469  1.0
  O  O5  1  0.253  0.510  0.469  1.0
  O  O6  1  0.747  0.490  0.531  1.0
  O  O7  1  0.753  0.990  0.531  1.0
  F  F8  1  0.816  0.135  0.061  1.0
  F  F9  1  0.684  0.635  0.061  1.0
  F  F10  1  0.316  0.365  0.939  1.0
  F  F11  1  0.184  0.865  0.939  1.0
[/CIF]
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