The material structure described by K2CS3O crystallizes in the monoclinic P2_1/c space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one S(1), one S(3), two equivalent S(2), and two equivalent O(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent S(2), three equivalent S(3), and one O(1) atom. C(1) is bonded in a trigonal planar geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one K(1), one C(1), and one O(1) atom. In the second S site, S(2) is bonded to two equivalent K(1), two equivalent K(2), and one C(1) atom to form a mixture of distorted corner and edge-sharing SK4C square pyramids. In the third S site, S(3) is bonded in a 5-coordinate geometry to one K(1), three equivalent K(2), and one C(1) atom. O(1) is bonded in a distorted see-saw-like geometry to one K(2), two equivalent K(1), and one S(1) atom. is represented by the CIF file [CIF]
data_K2CS3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.093
_cell_length_b   6.616
_cell_length_c   9.182
_cell_angle_alpha   47.959
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   726.102
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.199  0.041  0.064  1.0
  K  K1  1  0.301  0.041  0.564  1.0
  K  K2  1  0.801  0.959  0.936  1.0
  K  K3  1  0.699  0.959  0.436  1.0
  K  K4  1  0.943  0.903  0.322  1.0
  K  K5  1  0.557  0.903  0.822  1.0
  K  K6  1  0.057  0.097  0.678  1.0
  K  K7  1  0.443  0.097  0.178  1.0
  C  C8  1  0.130  0.369  0.221  1.0
  C  C9  1  0.370  0.369  0.721  1.0
  C  C10  1  0.870  0.631  0.779  1.0
  C  C11  1  0.630  0.631  0.279  1.0
  S  S12  1  0.220  0.525  0.085  1.0
  S  S13  1  0.280  0.525  0.585  1.0
  S  S14  1  0.780  0.475  0.915  1.0
  S  S15  1  0.720  0.475  0.415  1.0
  S  S16  1  0.375  0.022  0.899  1.0
  S  S17  1  0.125  0.022  0.399  1.0
  S  S18  1  0.625  0.978  0.101  1.0
  S  S19  1  0.875  0.978  0.601  1.0
  S  S20  1  0.053  0.596  0.159  1.0
  S  S21  1  0.447  0.596  0.659  1.0
  S  S22  1  0.947  0.404  0.841  1.0
  S  S23  1  0.553  0.404  0.341  1.0
  O  O24  1  0.790  0.686  0.344  1.0
  O  O25  1  0.710  0.686  0.844  1.0
  O  O26  1  0.210  0.314  0.656  1.0
  O  O27  1  0.290  0.314  0.156  1.0
[/CIF]
.
The material structure described by K2CS3O crystallizes in the monoclinic P2_1/c space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one S(1), one S(3), two equivalent S(2), and two equivalent O(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent S(2), three equivalent S(3), and one O(1) atom. C(1) is bonded in a trigonal planar geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one K(1), one C(1), and one O(1) atom. In the second S site, S(2) is bonded to two equivalent K(1), two equivalent K(2), and one C(1) atom to form a mixture of distorted corner and edge-sharing SK4C square pyramids. In the third S site, S(3) is bonded in a 5-coordinate geometry to one K(1), three equivalent K(2), and one C(1) atom. O(1) is bonded in a distorted see-saw-like geometry to one K(2), two equivalent K(1), and one S(1) atom. is represented by the CIF file [CIF]
data_K2CS3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.093
_cell_length_b   6.616
_cell_length_c   9.182
_cell_angle_alpha   47.959
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   726.102
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.199  0.041  0.064  1.0
  K  K1  1  0.301  0.041  0.564  1.0
  K  K2  1  0.801  0.959  0.936  1.0
  K  K3  1  0.699  0.959  0.436  1.0
  K  K4  1  0.943  0.903  0.322  1.0
  K  K5  1  0.557  0.903  0.822  1.0
  K  K6  1  0.057  0.097  0.678  1.0
  K  K7  1  0.443  0.097  0.178  1.0
  C  C8  1  0.130  0.369  0.221  1.0
  C  C9  1  0.370  0.369  0.721  1.0
  C  C10  1  0.870  0.631  0.779  1.0
  C  C11  1  0.630  0.631  0.279  1.0
  S  S12  1  0.220  0.525  0.085  1.0
  S  S13  1  0.280  0.525  0.585  1.0
  S  S14  1  0.780  0.475  0.915  1.0
  S  S15  1  0.720  0.475  0.415  1.0
  S  S16  1  0.375  0.022  0.899  1.0
  S  S17  1  0.125  0.022  0.399  1.0
  S  S18  1  0.625  0.978  0.101  1.0
  S  S19  1  0.875  0.978  0.601  1.0
  S  S20  1  0.053  0.596  0.159  1.0
  S  S21  1  0.447  0.596  0.659  1.0
  S  S22  1  0.947  0.404  0.841  1.0
  S  S23  1  0.553  0.404  0.341  1.0
  O  O24  1  0.790  0.686  0.344  1.0
  O  O25  1  0.710  0.686  0.844  1.0
  O  O26  1  0.210  0.314  0.656  1.0
  O  O27  1  0.290  0.314  0.156  1.0
[/CIF]
.