The compound described by SbCl3Sb3Cl8F3SbCl4F3(SbClF2)2SbCl2F3(Cl2)4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 7782-50-5 molecules, one antimony trichloride molecule, two chloro(difluoro)stibane molecules, one Sb3Cl8F3 cluster, one SbCl2F3 cluster, and one SbCl4F3 cluster. In the Sb3Cl8F3 cluster, there are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted octahedral geometry to one Cl(17), one Cl(24), one Cl(3), one Cl(7), one F(6), and one F(8) atom. In the second Sb site, Sb(5) is bonded in a 1-coordinate geometry to one Cl(19), one Cl(20), one F(13), and one F(6) atom. In the third Sb site, Sb(6) is bonded in a distorted T-shaped geometry to one Cl(14), one Cl(20), and one Cl(21) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(6) atom. In the fourth Cl site, Cl(17) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(19) is bonded in a single-bond geometry to one Sb(5) atom. In the sixth Cl site, Cl(20) is bonded in a distorted bent 150 degrees geometry to one Sb(5) and one Sb(6) atom. In the seventh Cl site, Cl(21) is bonded in a single-bond geometry to one Sb(6) atom. In the eighth Cl site, Cl(24) is bonded in a single-bond geometry to one Sb(1) atom. There are three inequivalent F sites. In the first F site, F(6) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(5) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(13) is bonded in a single-bond geometry to one Sb(5) atom. In the SbCl2F3 cluster, Sb(8) is bonded in a distorted trigonal bipyramidal geometry to one Cl(15), one Cl(26), one F(2), one F(4), and one F(9) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(26) is bonded in a single-bond geometry to one Sb(8) atom. In the second Cl site, Cl(15) is bonded in a single-bond geometry to one Sb(8) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(8) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(8) atom. In the third F site, F(9) is bonded in a single-bond geometry to one Sb(8) atom. In the SbCl4F3 cluster, Sb(2) is bonded in a 6-coordinate geometry to one Cl(16), one Cl(27), one Cl(9), one F(10), one F(12), and one F(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(27) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Cl(9) atom. In the third Cl site, Cl(9) is bonded in a bent 120 degrees geometry to one Sb(2) and one Cl(6) atom. In the fourth Cl site, Cl(16) is bonded in a single-bond geometry to one Sb(2) atom. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(12) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb8Cl27F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.766
_cell_length_b   9.905
_cell_length_c   17.725
_cell_angle_alpha   82.199
_cell_angle_beta   80.368
_cell_angle_gamma   64.194
_symmetry_Int_Tables_number   1
_cell_volume   1518.006
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.868  0.225  0.085  1.0
  Sb  Sb1  1  0.400  0.260  0.594  1.0
  Sb  Sb2  1  0.348  0.190  0.347  1.0
  Sb  Sb3  1  0.209  0.723  0.189  1.0
  Sb  Sb4  1  0.850  0.239  0.853  1.0
  Sb  Sb5  1  0.659  0.723  0.694  1.0
  Sb  Sb6  1  0.696  0.754  0.394  1.0
  Sb  Sb7  1  0.159  0.742  0.908  1.0
  Cl  Cl8  1  0.765  0.839  0.159  1.0
  Cl  Cl9  1  0.812  0.629  0.209  1.0
  Cl  Cl10  1  0.716  0.457  0.017  1.0
  Cl  Cl11  1  0.217  0.925  0.685  1.0
  Cl  Cl12  1  0.405  0.789  0.123  1.0
  Cl  Cl13  1  0.338  0.693  0.518  1.0
  Cl  Cl14  1  0.667  0.142  0.086  1.0
  Cl  Cl15  1  0.254  0.714  0.725  1.0
  Cl  Cl16  1  0.236  0.554  0.525  1.0
  Cl  Cl17  1  0.316  0.115  0.233  1.0
  Cl  Cl18  1  0.337  0.599  0.301  1.0
  Cl  Cl19  1  0.283  0.495  0.130  1.0
  Cl  Cl20  1  0.086  0.926  0.366  1.0
  Cl  Cl21  1  0.882  0.764  0.663  1.0
  Cl  Cl22  1  0.957  0.677  0.908  1.0
  Cl  Cl23  1  0.156  0.272  0.587  1.0
  Cl  Cl24  1  0.080  0.285  0.068  1.0
  Cl  Cl25  1  0.969  0.142  0.391  1.0
  Cl  Cl26  1  0.807  0.168  0.739  1.0
  Cl  Cl27  1  0.724  0.558  0.815  1.0
  Cl  Cl28  1  0.728  0.521  0.620  1.0
  Cl  Cl29  1  0.510  0.026  0.853  1.0
  Cl  Cl30  1  0.728  0.499  0.416  1.0
  Cl  Cl31  1  0.770  0.312  0.208  1.0
  Cl  Cl32  1  0.585  0.074  0.941  1.0
  Cl  Cl33  1  0.340  0.492  0.906  1.0
  Cl  Cl34  1  0.324  0.361  0.714  1.0
  F  F35  1  0.360  0.006  0.408  1.0
  F  F36  1  0.030  0.938  0.862  1.0
  F  F37  1  0.454  0.210  0.489  1.0
  F  F38  1  0.125  0.792  0.009  1.0
  F  F39  1  0.904  0.705  0.411  1.0
  F  F40  1  0.943  0.140  0.980  1.0
  F  F41  1  0.617  0.803  0.500  1.0
  F  F42  1  0.992  0.026  0.127  1.0
  F  F43  1  0.321  0.803  0.877  1.0
  F  F44  1  0.572  0.306  0.580  1.0
  F  F45  1  0.570  0.103  0.329  1.0
  F  F46  1  0.497  0.057  0.634  1.0
  F  F47  1  0.046  0.234  0.811  1.0
[/CIF]
.
The compound described by SbCl3Sb3Cl8F3SbCl4F3(SbClF2)2SbCl2F3(Cl2)4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 7782-50-5 molecules, one antimony trichloride molecule, two chloro(difluoro)stibane molecules, one Sb3Cl8F3 cluster, one SbCl2F3 cluster, and one SbCl4F3 cluster. In the Sb3Cl8F3 cluster, there are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted octahedral geometry to one Cl(17), one Cl(24), one Cl(3), one Cl(7), one F(6), and one F(8) atom. In the second Sb site, Sb(5) is bonded in a 1-coordinate geometry to one Cl(19), one Cl(20), one F(13), and one F(6) atom. In the third Sb site, Sb(6) is bonded in a distorted T-shaped geometry to one Cl(14), one Cl(20), and one Cl(21) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(6) atom. In the fourth Cl site, Cl(17) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(19) is bonded in a single-bond geometry to one Sb(5) atom. In the sixth Cl site, Cl(20) is bonded in a distorted bent 150 degrees geometry to one Sb(5) and one Sb(6) atom. In the seventh Cl site, Cl(21) is bonded in a single-bond geometry to one Sb(6) atom. In the eighth Cl site, Cl(24) is bonded in a single-bond geometry to one Sb(1) atom. There are three inequivalent F sites. In the first F site, F(6) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(5) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(13) is bonded in a single-bond geometry to one Sb(5) atom. In the SbCl2F3 cluster, Sb(8) is bonded in a distorted trigonal bipyramidal geometry to one Cl(15), one Cl(26), one F(2), one F(4), and one F(9) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(26) is bonded in a single-bond geometry to one Sb(8) atom. In the second Cl site, Cl(15) is bonded in a single-bond geometry to one Sb(8) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(8) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(8) atom. In the third F site, F(9) is bonded in a single-bond geometry to one Sb(8) atom. In the SbCl4F3 cluster, Sb(2) is bonded in a 6-coordinate geometry to one Cl(16), one Cl(27), one Cl(9), one F(10), one F(12), and one F(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(27) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Cl(9) atom. In the third Cl site, Cl(9) is bonded in a bent 120 degrees geometry to one Sb(2) and one Cl(6) atom. In the fourth Cl site, Cl(16) is bonded in a single-bond geometry to one Sb(2) atom. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(12) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb8Cl27F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.766
_cell_length_b   9.905
_cell_length_c   17.725
_cell_angle_alpha   82.199
_cell_angle_beta   80.368
_cell_angle_gamma   64.194
_symmetry_Int_Tables_number   1
_cell_volume   1518.006
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.868  0.225  0.085  1.0
  Sb  Sb1  1  0.400  0.260  0.594  1.0
  Sb  Sb2  1  0.348  0.190  0.347  1.0
  Sb  Sb3  1  0.209  0.723  0.189  1.0
  Sb  Sb4  1  0.850  0.239  0.853  1.0
  Sb  Sb5  1  0.659  0.723  0.694  1.0
  Sb  Sb6  1  0.696  0.754  0.394  1.0
  Sb  Sb7  1  0.159  0.742  0.908  1.0
  Cl  Cl8  1  0.765  0.839  0.159  1.0
  Cl  Cl9  1  0.812  0.629  0.209  1.0
  Cl  Cl10  1  0.716  0.457  0.017  1.0
  Cl  Cl11  1  0.217  0.925  0.685  1.0
  Cl  Cl12  1  0.405  0.789  0.123  1.0
  Cl  Cl13  1  0.338  0.693  0.518  1.0
  Cl  Cl14  1  0.667  0.142  0.086  1.0
  Cl  Cl15  1  0.254  0.714  0.725  1.0
  Cl  Cl16  1  0.236  0.554  0.525  1.0
  Cl  Cl17  1  0.316  0.115  0.233  1.0
  Cl  Cl18  1  0.337  0.599  0.301  1.0
  Cl  Cl19  1  0.283  0.495  0.130  1.0
  Cl  Cl20  1  0.086  0.926  0.366  1.0
  Cl  Cl21  1  0.882  0.764  0.663  1.0
  Cl  Cl22  1  0.957  0.677  0.908  1.0
  Cl  Cl23  1  0.156  0.272  0.587  1.0
  Cl  Cl24  1  0.080  0.285  0.068  1.0
  Cl  Cl25  1  0.969  0.142  0.391  1.0
  Cl  Cl26  1  0.807  0.168  0.739  1.0
  Cl  Cl27  1  0.724  0.558  0.815  1.0
  Cl  Cl28  1  0.728  0.521  0.620  1.0
  Cl  Cl29  1  0.510  0.026  0.853  1.0
  Cl  Cl30  1  0.728  0.499  0.416  1.0
  Cl  Cl31  1  0.770  0.312  0.208  1.0
  Cl  Cl32  1  0.585  0.074  0.941  1.0
  Cl  Cl33  1  0.340  0.492  0.906  1.0
  Cl  Cl34  1  0.324  0.361  0.714  1.0
  F  F35  1  0.360  0.006  0.408  1.0
  F  F36  1  0.030  0.938  0.862  1.0
  F  F37  1  0.454  0.210  0.489  1.0
  F  F38  1  0.125  0.792  0.009  1.0
  F  F39  1  0.904  0.705  0.411  1.0
  F  F40  1  0.943  0.140  0.980  1.0
  F  F41  1  0.617  0.803  0.500  1.0
  F  F42  1  0.992  0.026  0.127  1.0
  F  F43  1  0.321  0.803  0.877  1.0
  F  F44  1  0.572  0.306  0.580  1.0
  F  F45  1  0.570  0.103  0.329  1.0
  F  F46  1  0.497  0.057  0.634  1.0
  F  F47  1  0.046  0.234  0.811  1.0
[/CIF]
.