The compound described by ZrF7(NO)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six nitroxyl molecules and one ZrF7 cluster. In the ZrF7 cluster, Zr(1) is bonded in a 8-coordinate geometry to one F(2), one F(3), one F(4), one F(5), one F(6), one F(7), and two equivalent F(1) atoms. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to two equivalent Zr(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one Zr(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Zr(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Zr(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Zr(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Zr(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Zr(1) atom. is represented by the CIF file [CIF]
data_ZrN3O3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.768
_cell_length_b   7.244
_cell_length_c   8.528
_cell_angle_alpha   109.673
_cell_angle_beta   92.199
_cell_angle_gamma   102.530
_symmetry_Int_Tables_number   1
_cell_volume   381.512
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.619  0.720  0.689  1.0
  Zr  Zr1  1  0.381  0.280  0.311  1.0
  N  N2  1  0.858  0.266  0.533  1.0
  N  N3  1  0.142  0.734  0.467  1.0
  N  N4  1  0.051  0.740  0.951  1.0
  N  N5  1  0.949  0.260  0.049  1.0
  N  N6  1  0.429  0.236  0.819  1.0
  N  N7  1  0.571  0.764  0.181  1.0
  O  O8  1  0.839  0.203  0.634  1.0
  O  O9  1  0.161  0.797  0.366  1.0
  O  O10  1  0.157  0.641  0.949  1.0
  O  O11  1  0.843  0.359  0.051  1.0
  O  O12  1  0.269  0.223  0.774  1.0
  O  O13  1  0.731  0.777  0.226  1.0
  F  F14  1  0.539  0.388  0.570  1.0
  F  F15  1  0.461  0.612  0.430  1.0
  F  F16  1  0.827  0.846  0.548  1.0
  F  F17  1  0.173  0.154  0.452  1.0
  F  F18  1  0.894  0.618  0.705  1.0
  F  F19  1  0.106  0.382  0.295  1.0
  F  F20  1  0.318  0.638  0.716  1.0
  F  F21  1  0.682  0.362  0.284  1.0
  F  F22  1  0.487  0.963  0.670  1.0
  F  F23  1  0.513  0.037  0.330  1.0
  F  F24  1  0.613  0.626  0.902  1.0
  F  F25  1  0.387  0.374  0.098  1.0
  F  F26  1  0.778  0.982  0.890  1.0
  F  F27  1  0.222  0.018  0.110  1.0
[/CIF]
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The compound described by ZrF7(NO)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six nitroxyl molecules and one ZrF7 cluster. In the ZrF7 cluster, Zr(1) is bonded in a 8-coordinate geometry to one F(2), one F(3), one F(4), one F(5), one F(6), one F(7), and two equivalent F(1) atoms. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to two equivalent Zr(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one Zr(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Zr(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Zr(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Zr(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Zr(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Zr(1) atom. is represented by the CIF file [CIF]
data_ZrN3O3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.768
_cell_length_b   7.244
_cell_length_c   8.528
_cell_angle_alpha   109.673
_cell_angle_beta   92.199
_cell_angle_gamma   102.530
_symmetry_Int_Tables_number   1
_cell_volume   381.512
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.619  0.720  0.689  1.0
  Zr  Zr1  1  0.381  0.280  0.311  1.0
  N  N2  1  0.858  0.266  0.533  1.0
  N  N3  1  0.142  0.734  0.467  1.0
  N  N4  1  0.051  0.740  0.951  1.0
  N  N5  1  0.949  0.260  0.049  1.0
  N  N6  1  0.429  0.236  0.819  1.0
  N  N7  1  0.571  0.764  0.181  1.0
  O  O8  1  0.839  0.203  0.634  1.0
  O  O9  1  0.161  0.797  0.366  1.0
  O  O10  1  0.157  0.641  0.949  1.0
  O  O11  1  0.843  0.359  0.051  1.0
  O  O12  1  0.269  0.223  0.774  1.0
  O  O13  1  0.731  0.777  0.226  1.0
  F  F14  1  0.539  0.388  0.570  1.0
  F  F15  1  0.461  0.612  0.430  1.0
  F  F16  1  0.827  0.846  0.548  1.0
  F  F17  1  0.173  0.154  0.452  1.0
  F  F18  1  0.894  0.618  0.705  1.0
  F  F19  1  0.106  0.382  0.295  1.0
  F  F20  1  0.318  0.638  0.716  1.0
  F  F21  1  0.682  0.362  0.284  1.0
  F  F22  1  0.487  0.963  0.670  1.0
  F  F23  1  0.513  0.037  0.330  1.0
  F  F24  1  0.613  0.626  0.902  1.0
  F  F25  1  0.387  0.374  0.098  1.0
  F  F26  1  0.778  0.982  0.890  1.0
  F  F27  1  0.222  0.018  0.110  1.0
[/CIF]
.