The material structure described by Xe2F3SbF6 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four SbF6 clusters and four Xe2F3 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(7), one F(8), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In each Xe2F3 cluster, there are two inequivalent Xe sites. In the first Xe site, Xe(1) is bonded in a linear geometry to one F(5) and one F(6) atom. In the second Xe site, Xe(2) is bonded in a linear geometry to one F(4) and one F(5) atom. There are three inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Xe(2) atom. In the second F site, F(5) is bonded in a bent 150 degrees geometry to one Xe(1) and one Xe(2) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_SbXe2F9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.300
_cell_length_b   8.300
_cell_length_c   9.982
_cell_angle_alpha   55.620
_cell_angle_beta   55.620
_cell_angle_gamma   58.523
_symmetry_Int_Tables_number   1
_cell_volume   447.012
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.969  0.221  0.807  1.0
  Sb  Sb1  1  0.221  0.969  0.307  1.0
  Xe  Xe2  1  0.508  0.338  0.334  1.0
  Xe  Xe3  1  0.338  0.508  0.834  1.0
  Xe  Xe4  1  0.693  0.892  0.757  1.0
  Xe  Xe5  1  0.892  0.693  0.257  1.0
  F  F6  1  0.781  0.100  0.872  1.0
  F  F7  1  0.100  0.781  0.372  1.0
  F  F8  1  0.767  0.480  0.765  1.0
  F  F9  1  0.480  0.767  0.265  1.0
  F  F10  1  0.069  0.262  0.570  1.0
  F  F11  1  0.262  0.069  0.070  1.0
  F  F12  1  0.689  0.840  0.419  1.0
  F  F13  1  0.840  0.689  0.919  1.0
  F  F14  1  0.106  0.515  0.091  1.0
  F  F15  1  0.515  0.106  0.591  1.0
  F  F16  1  0.548  0.472  0.608  1.0
  F  F17  1  0.472  0.548  0.108  1.0
  F  F18  1  0.350  0.148  0.243  1.0
  F  F19  1  0.148  0.350  0.743  1.0
  F  F20  1  0.180  0.863  0.546  1.0
  F  F21  1  0.863  0.180  0.046  1.0
  F  F22  1  0.958  0.164  0.352  1.0
  F  F23  1  0.164  0.958  0.852  1.0
[/CIF]
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The material structure described by Xe2F3SbF6 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four SbF6 clusters and four Xe2F3 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(7), one F(8), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In each Xe2F3 cluster, there are two inequivalent Xe sites. In the first Xe site, Xe(1) is bonded in a linear geometry to one F(5) and one F(6) atom. In the second Xe site, Xe(2) is bonded in a linear geometry to one F(4) and one F(5) atom. There are three inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Xe(2) atom. In the second F site, F(5) is bonded in a bent 150 degrees geometry to one Xe(1) and one Xe(2) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_SbXe2F9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.300
_cell_length_b   8.300
_cell_length_c   9.982
_cell_angle_alpha   55.620
_cell_angle_beta   55.620
_cell_angle_gamma   58.523
_symmetry_Int_Tables_number   1
_cell_volume   447.012
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.969  0.221  0.807  1.0
  Sb  Sb1  1  0.221  0.969  0.307  1.0
  Xe  Xe2  1  0.508  0.338  0.334  1.0
  Xe  Xe3  1  0.338  0.508  0.834  1.0
  Xe  Xe4  1  0.693  0.892  0.757  1.0
  Xe  Xe5  1  0.892  0.693  0.257  1.0
  F  F6  1  0.781  0.100  0.872  1.0
  F  F7  1  0.100  0.781  0.372  1.0
  F  F8  1  0.767  0.480  0.765  1.0
  F  F9  1  0.480  0.767  0.265  1.0
  F  F10  1  0.069  0.262  0.570  1.0
  F  F11  1  0.262  0.069  0.070  1.0
  F  F12  1  0.689  0.840  0.419  1.0
  F  F13  1  0.840  0.689  0.919  1.0
  F  F14  1  0.106  0.515  0.091  1.0
  F  F15  1  0.515  0.106  0.591  1.0
  F  F16  1  0.548  0.472  0.608  1.0
  F  F17  1  0.472  0.548  0.108  1.0
  F  F18  1  0.350  0.148  0.243  1.0
  F  F19  1  0.148  0.350  0.743  1.0
  F  F20  1  0.180  0.863  0.546  1.0
  F  F21  1  0.863  0.180  0.046  1.0
  F  F22  1  0.958  0.164  0.352  1.0
  F  F23  1  0.164  0.958  0.852  1.0
[/CIF]
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