The material described by Cr(H2O)6SiF6 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two chromium;hexahydrate molecules and two SiF6 clusters. In each SiF6 cluster, Si(1,2) is bonded in an octahedral geometry to one F(1), one F(11), one F(3), one F(5), one F(7), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1,2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Si(1,2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Si(1,2) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Si(1,2) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one Si(1,2) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one Si(1,2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrSiH12(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.418
_cell_length_b   6.471
_cell_length_c   6.510
_cell_angle_alpha   97.629
_cell_angle_beta   98.084
_cell_angle_gamma   94.512
_symmetry_Int_Tables_number   1
_cell_volume   264.015
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  1.000  1.0
  F  F1  1  0.695  0.673  0.443  1.0
  F  F2  1  0.437  0.692  0.685  1.0
  F  F3  1  0.321  0.580  0.312  1.0
  F  F4  1  0.679  0.420  0.688  1.0
  F  F5  1  0.563  0.308  0.314  1.0
  F  F6  1  0.305  0.327  0.557  1.0
  H  H7  1  0.319  0.824  0.220  1.0
  H  H8  1  0.184  0.781  0.691  1.0
  H  H9  1  0.776  0.665  0.185  1.0
  H  H10  1  0.224  0.334  0.815  1.0
  H  H11  1  0.817  0.219  0.309  1.0
  H  H12  1  0.681  0.176  0.779  1.0
  H  H13  1  0.596  0.939  0.793  1.0
  H  H14  1  0.939  0.784  0.602  1.0
  H  H15  1  0.210  0.427  0.050  1.0
  H  H16  1  0.789  0.573  0.950  1.0
  H  H17  1  0.062  0.216  0.398  1.0
  H  H18  1  0.404  0.061  0.206  1.0
  O  O19  1  0.303  0.941  0.139  1.0
  O  O20  1  0.058  0.857  0.704  1.0
  O  O21  1  0.852  0.680  0.067  1.0
  O  O22  1  0.147  0.320  0.932  1.0
  O  O23  1  0.942  0.143  0.296  1.0
  O  O24  1  0.697  0.059  0.861  1.0
  Si  Si25  1  0.500  0.500  0.500  1.0
[/CIF]
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The material described by Cr(H2O)6SiF6 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two chromium;hexahydrate molecules and two SiF6 clusters. In each SiF6 cluster, Si(1,2) is bonded in an octahedral geometry to one F(1), one F(11), one F(3), one F(5), one F(7), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1,2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Si(1,2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Si(1,2) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Si(1,2) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one Si(1,2) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one Si(1,2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrSiH12(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.418
_cell_length_b   6.471
_cell_length_c   6.510
_cell_angle_alpha   97.629
_cell_angle_beta   98.084
_cell_angle_gamma   94.512
_symmetry_Int_Tables_number   1
_cell_volume   264.015
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  1.000  1.0
  F  F1  1  0.695  0.673  0.443  1.0
  F  F2  1  0.437  0.692  0.685  1.0
  F  F3  1  0.321  0.580  0.312  1.0
  F  F4  1  0.679  0.420  0.688  1.0
  F  F5  1  0.563  0.308  0.314  1.0
  F  F6  1  0.305  0.327  0.557  1.0
  H  H7  1  0.319  0.824  0.220  1.0
  H  H8  1  0.184  0.781  0.691  1.0
  H  H9  1  0.776  0.665  0.185  1.0
  H  H10  1  0.224  0.334  0.815  1.0
  H  H11  1  0.817  0.219  0.309  1.0
  H  H12  1  0.681  0.176  0.779  1.0
  H  H13  1  0.596  0.939  0.793  1.0
  H  H14  1  0.939  0.784  0.602  1.0
  H  H15  1  0.210  0.427  0.050  1.0
  H  H16  1  0.789  0.573  0.950  1.0
  H  H17  1  0.062  0.216  0.398  1.0
  H  H18  1  0.404  0.061  0.206  1.0
  O  O19  1  0.303  0.941  0.139  1.0
  O  O20  1  0.058  0.857  0.704  1.0
  O  O21  1  0.852  0.680  0.067  1.0
  O  O22  1  0.147  0.320  0.932  1.0
  O  O23  1  0.942  0.143  0.296  1.0
  O  O24  1  0.697  0.059  0.861  1.0
  Si  Si25  1  0.500  0.500  0.500  1.0
[/CIF]
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