The structure described by Dy(CoGa)6 crystallizes in the orthorhombic Immm space group. Dy(1) is bonded in a 20-coordinate geometry to four equivalent Co(1), eight equivalent Co(2), two equivalent Ga(1), two equivalent Ga(2), and four equivalent Ga(3) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Dy(1), four equivalent Co(2), two equivalent Ga(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2Ga6Co4 cuboctahedra. In the second Co site, Co(2) is bonded to two equivalent Dy(1), two equivalent Co(1), two equivalent Co(2), two equivalent Ga(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2Ga6Co4 cuboctahedra. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to one Dy(1), two equivalent Co(1), four equivalent Co(2), one Ga(1), and two equivalent Ga(3) atoms. In the second Ga site, Ga(2) is bonded in a 8-coordinate geometry to one Dy(1), two equivalent Co(1), four equivalent Co(2), and one Ga(2) atom. In the third Ga site, Ga(3) is bonded in a 8-coordinate geometry to two equivalent Dy(1), two equivalent Co(1), four equivalent Co(2), and two equivalent Ga(1) atoms. is represented by the CIF file [CIF]
data_Dy(GaCo)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.508
_cell_length_b   6.503
_cell_length_c   6.505
_cell_angle_alpha   135.293
_cell_angle_beta   98.828
_cell_angle_gamma   97.820
_symmetry_Int_Tables_number   1
_cell_volume   179.072
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  Ga  Ga1  1  0.347  0.347  0.000  1.0
  Ga  Ga2  1  0.653  0.653  1.000  1.0
  Ga  Ga3  1  0.344  0.000  0.344  1.0
  Ga  Ga4  1  0.656  1.000  0.656  1.0
  Ga  Ga5  1  0.195  0.695  0.500  1.0
  Ga  Ga6  1  0.805  0.305  0.500  1.0
  Co  Co7  1  0.761  0.500  0.261  1.0
  Co  Co8  1  0.239  0.500  0.739  1.0
  Co  Co9  1  0.500  0.500  0.500  1.0
  Co  Co10  1  0.000  0.000  0.500  1.0
  Co  Co11  1  0.000  0.500  0.000  1.0
  Co  Co12  1  0.500  0.000  0.000  1.0
[/CIF]
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The structure described by Dy(CoGa)6 crystallizes in the orthorhombic Immm space group. Dy(1) is bonded in a 20-coordinate geometry to four equivalent Co(1), eight equivalent Co(2), two equivalent Ga(1), two equivalent Ga(2), and four equivalent Ga(3) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Dy(1), four equivalent Co(2), two equivalent Ga(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2Ga6Co4 cuboctahedra. In the second Co site, Co(2) is bonded to two equivalent Dy(1), two equivalent Co(1), two equivalent Co(2), two equivalent Ga(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoDy2Ga6Co4 cuboctahedra. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to one Dy(1), two equivalent Co(1), four equivalent Co(2), one Ga(1), and two equivalent Ga(3) atoms. In the second Ga site, Ga(2) is bonded in a 8-coordinate geometry to one Dy(1), two equivalent Co(1), four equivalent Co(2), and one Ga(2) atom. In the third Ga site, Ga(3) is bonded in a 8-coordinate geometry to two equivalent Dy(1), two equivalent Co(1), four equivalent Co(2), and two equivalent Ga(1) atoms. is represented by the CIF file [CIF]
data_Dy(GaCo)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.508
_cell_length_b   6.503
_cell_length_c   6.505
_cell_angle_alpha   135.293
_cell_angle_beta   98.828
_cell_angle_gamma   97.820
_symmetry_Int_Tables_number   1
_cell_volume   179.072
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  Ga  Ga1  1  0.347  0.347  0.000  1.0
  Ga  Ga2  1  0.653  0.653  1.000  1.0
  Ga  Ga3  1  0.344  0.000  0.344  1.0
  Ga  Ga4  1  0.656  1.000  0.656  1.0
  Ga  Ga5  1  0.195  0.695  0.500  1.0
  Ga  Ga6  1  0.805  0.305  0.500  1.0
  Co  Co7  1  0.761  0.500  0.261  1.0
  Co  Co8  1  0.239  0.500  0.739  1.0
  Co  Co9  1  0.500  0.500  0.500  1.0
  Co  Co10  1  0.000  0.000  0.500  1.0
  Co  Co11  1  0.000  0.500  0.000  1.0
  Co  Co12  1  0.500  0.000  0.000  1.0
[/CIF]
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