The compound described by Pr2Rh2Cd crystallizes in the tetragonal P4/mbm space group. Pr(1) is bonded in a 6-coordinate geometry to six equivalent Rh(1) and four equivalent Cd(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to six equivalent Pr(1), one Rh(1), and two equivalent Cd(1) atoms. Cd(1) is bonded to eight equivalent Pr(1) and four equivalent Rh(1) atoms to form a mixture of distorted corner and face-sharing CdPr8Rh4 cuboctahedra. is represented by the CIF file [CIF]
data_Pr2CdRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.583
_cell_length_b   7.583
_cell_length_c   3.975
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   228.594
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.671  0.171  0.500  1.0
  Pr  Pr1  1  0.329  0.829  0.500  1.0
  Pr  Pr2  1  0.171  0.329  0.500  1.0
  Pr  Pr3  1  0.829  0.671  0.500  1.0
  Cd  Cd4  1  0.000  0.000  0.000  1.0
  Cd  Cd5  1  0.500  0.500  0.000  1.0
  Rh  Rh6  1  0.130  0.630  0.000  1.0
  Rh  Rh7  1  0.870  0.370  0.000  1.0
  Rh  Rh8  1  0.630  0.870  0.000  1.0
  Rh  Rh9  1  0.370  0.130  0.000  1.0
[/CIF]
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The compound described by Pr2Rh2Cd crystallizes in the tetragonal P4/mbm space group. Pr(1) is bonded in a 6-coordinate geometry to six equivalent Rh(1) and four equivalent Cd(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to six equivalent Pr(1), one Rh(1), and two equivalent Cd(1) atoms. Cd(1) is bonded to eight equivalent Pr(1) and four equivalent Rh(1) atoms to form a mixture of distorted corner and face-sharing CdPr8Rh4 cuboctahedra. is represented by the CIF file [CIF]
data_Pr2CdRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.583
_cell_length_b   7.583
_cell_length_c   3.975
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   228.594
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.671  0.171  0.500  1.0
  Pr  Pr1  1  0.329  0.829  0.500  1.0
  Pr  Pr2  1  0.171  0.329  0.500  1.0
  Pr  Pr3  1  0.829  0.671  0.500  1.0
  Cd  Cd4  1  0.000  0.000  0.000  1.0
  Cd  Cd5  1  0.500  0.500  0.000  1.0
  Rh  Rh6  1  0.130  0.630  0.000  1.0
  Rh  Rh7  1  0.870  0.370  0.000  1.0
  Rh  Rh8  1  0.630  0.870  0.000  1.0
  Rh  Rh9  1  0.370  0.130  0.000  1.0
[/CIF]
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