The structure described by BaSr7MnFe7O24 is (Cubic) Perovskite-derived structured and crystallizes in the trigonal R3m space group. Ba(1) is bonded to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Sr(2)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(4), one O(6), two equivalent O(1), two equivalent O(3), two equivalent O(5), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Sr(2)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(6), and four equivalent O(5) atoms to form SrO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with eight equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. In the third Sr site, Sr(3) is bonded to three equivalent O(4), three equivalent O(6), and six equivalent O(5) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(2)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. Mn(1) is bonded to three equivalent O(3) and three equivalent O(6) atoms to form MnO6 octahedra that share corners with six equivalent Fe(2)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(5) atoms to form FeO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Fe site, Fe(2) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(5) atoms to form FeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Fe(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Fe site, Fe(3) is bonded to three equivalent O(1) and three equivalent O(4) atoms to form FeO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Ba(1), one Sr(2), two equivalent Sr(1), one Fe(1), and one Fe(3) atom to form distorted OBaSr3Fe2 octahedra that share corners with four equivalent O(2)BaSr3Fe2 octahedra, corners with eight equivalent O(3)BaSr3MnFe octahedra, edges with four equivalent O(2)BaSr3Fe2 octahedra, faces with two equivalent O(1)BaSr3Fe2 octahedra, and faces with two equivalent O(2)BaSr3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the second O site, O(2) is bonded to one Ba(1), one Sr(2), two equivalent Sr(1), one Fe(1), and one Fe(2) atom to form distorted OBaSr3Fe2 octahedra that share corners with two equivalent O(1)BaSr3Fe2 octahedra, corners with two equivalent O(3)BaSr3MnFe octahedra, corners with eight equivalent O(2)BaSr3Fe2 octahedra, edges with two equivalent O(1)BaSr3Fe2 octahedra, edges with two equivalent O(3)BaSr3MnFe octahedra,  a faceface with one O(1)BaSr3Fe2 octahedra,  a faceface with one O(3)BaSr3MnFe octahedra, and faces with two equivalent O(2)BaSr3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the third O site, O(3) is bonded to one Ba(1), one Sr(2), two equivalent Sr(1), one Mn(1), and one Fe(2) atom to form distorted OBaSr3MnFe octahedra that share corners with four equivalent O(2)BaSr3Fe2 octahedra, corners with eight equivalent O(1)BaSr3Fe2 octahedra, edges with four equivalent O(2)BaSr3Fe2 octahedra, faces with two equivalent O(2)BaSr3Fe2 octahedra, and faces with two equivalent O(3)BaSr3MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), two equivalent Sr(2), one Fe(1), and one Fe(3) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), two equivalent Sr(2), one Fe(1), and one Fe(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), two equivalent Sr(2), one Mn(1), and one Fe(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaSr7MnFe7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.855
_cell_length_b   7.855
_cell_length_c   7.855
_cell_angle_alpha   90.005
_cell_angle_beta   90.005
_cell_angle_gamma   90.005
_symmetry_Int_Tables_number   1
_cell_volume   484.644
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.750  0.750  0.750  1.0
  Sr  Sr1  1  0.750  0.250  0.750  1.0
  Sr  Sr2  1  0.750  0.250  0.250  1.0
  Sr  Sr3  1  0.750  0.750  0.250  1.0
  Sr  Sr4  1  0.250  0.250  0.750  1.0
  Sr  Sr5  1  0.250  0.250  0.250  1.0
  Sr  Sr6  1  0.250  0.750  0.750  1.0
  Sr  Sr7  1  0.250  0.750  0.250  1.0
  Mn  Mn8  1  0.499  0.499  0.499  1.0
  Fe  Fe9  1  0.499  0.001  0.001  1.0
  Fe  Fe10  1  0.499  0.001  0.499  1.0
  Fe  Fe11  1  0.499  0.499  0.001  1.0
  Fe  Fe12  1  0.001  0.001  0.001  1.0
  Fe  Fe13  1  0.001  0.001  0.499  1.0
  Fe  Fe14  1  0.001  0.499  0.001  1.0
  Fe  Fe15  1  0.001  0.499  0.499  1.0
  O  O16  1  0.750  0.004  0.004  1.0
  O  O17  1  0.752  0.004  0.496  1.0
  O  O18  1  0.752  0.496  0.004  1.0
  O  O19  1  0.745  0.496  0.496  1.0
  O  O20  1  0.250  0.001  0.001  1.0
  O  O21  1  0.248  0.001  0.499  1.0
  O  O22  1  0.248  0.499  0.001  1.0
  O  O23  1  0.254  0.499  0.499  1.0
  O  O24  1  0.499  0.248  0.001  1.0
  O  O25  1  0.499  0.254  0.499  1.0
  O  O26  1  0.496  0.752  0.004  1.0
  O  O27  1  0.496  0.745  0.496  1.0
  O  O28  1  0.001  0.250  0.001  1.0
  O  O29  1  0.001  0.248  0.499  1.0
  O  O30  1  0.004  0.750  0.004  1.0
  O  O31  1  0.004  0.752  0.496  1.0
  O  O32  1  0.496  0.004  0.752  1.0
  O  O33  1  0.499  0.001  0.248  1.0
  O  O34  1  0.496  0.496  0.745  1.0
  O  O35  1  0.499  0.499  0.254  1.0
  O  O36  1  0.004  0.004  0.750  1.0
  O  O37  1  0.001  0.001  0.250  1.0
  O  O38  1  0.004  0.496  0.752  1.0
  O  O39  1  0.001  0.499  0.248  1.0
[/CIF]
.
The structure described by BaSr7MnFe7O24 is (Cubic) Perovskite-derived structured and crystallizes in the trigonal R3m space group. Ba(1) is bonded to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Sr(2)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(4), one O(6), two equivalent O(1), two equivalent O(3), two equivalent O(5), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Sr(2)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(6), and four equivalent O(5) atoms to form SrO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with eight equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. In the third Sr site, Sr(3) is bonded to three equivalent O(4), three equivalent O(6), and six equivalent O(5) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(2)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Fe(3)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Fe(2)O6 octahedra. Mn(1) is bonded to three equivalent O(3) and three equivalent O(6) atoms to form MnO6 octahedra that share corners with six equivalent Fe(2)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(5) atoms to form FeO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Fe site, Fe(2) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(5) atoms to form FeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Fe(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Fe site, Fe(3) is bonded to three equivalent O(1) and three equivalent O(4) atoms to form FeO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Ba(1), one Sr(2), two equivalent Sr(1), one Fe(1), and one Fe(3) atom to form distorted OBaSr3Fe2 octahedra that share corners with four equivalent O(2)BaSr3Fe2 octahedra, corners with eight equivalent O(3)BaSr3MnFe octahedra, edges with four equivalent O(2)BaSr3Fe2 octahedra, faces with two equivalent O(1)BaSr3Fe2 octahedra, and faces with two equivalent O(2)BaSr3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the second O site, O(2) is bonded to one Ba(1), one Sr(2), two equivalent Sr(1), one Fe(1), and one Fe(2) atom to form distorted OBaSr3Fe2 octahedra that share corners with two equivalent O(1)BaSr3Fe2 octahedra, corners with two equivalent O(3)BaSr3MnFe octahedra, corners with eight equivalent O(2)BaSr3Fe2 octahedra, edges with two equivalent O(1)BaSr3Fe2 octahedra, edges with two equivalent O(3)BaSr3MnFe octahedra,  a faceface with one O(1)BaSr3Fe2 octahedra,  a faceface with one O(3)BaSr3MnFe octahedra, and faces with two equivalent O(2)BaSr3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the third O site, O(3) is bonded to one Ba(1), one Sr(2), two equivalent Sr(1), one Mn(1), and one Fe(2) atom to form distorted OBaSr3MnFe octahedra that share corners with four equivalent O(2)BaSr3Fe2 octahedra, corners with eight equivalent O(1)BaSr3Fe2 octahedra, edges with four equivalent O(2)BaSr3Fe2 octahedra, faces with two equivalent O(2)BaSr3Fe2 octahedra, and faces with two equivalent O(3)BaSr3MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), two equivalent Sr(2), one Fe(1), and one Fe(3) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), two equivalent Sr(2), one Fe(1), and one Fe(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), two equivalent Sr(2), one Mn(1), and one Fe(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaSr7MnFe7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.855
_cell_length_b   7.855
_cell_length_c   7.855
_cell_angle_alpha   90.005
_cell_angle_beta   90.005
_cell_angle_gamma   90.005
_symmetry_Int_Tables_number   1
_cell_volume   484.644
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.750  0.750  0.750  1.0
  Sr  Sr1  1  0.750  0.250  0.750  1.0
  Sr  Sr2  1  0.750  0.250  0.250  1.0
  Sr  Sr3  1  0.750  0.750  0.250  1.0
  Sr  Sr4  1  0.250  0.250  0.750  1.0
  Sr  Sr5  1  0.250  0.250  0.250  1.0
  Sr  Sr6  1  0.250  0.750  0.750  1.0
  Sr  Sr7  1  0.250  0.750  0.250  1.0
  Mn  Mn8  1  0.499  0.499  0.499  1.0
  Fe  Fe9  1  0.499  0.001  0.001  1.0
  Fe  Fe10  1  0.499  0.001  0.499  1.0
  Fe  Fe11  1  0.499  0.499  0.001  1.0
  Fe  Fe12  1  0.001  0.001  0.001  1.0
  Fe  Fe13  1  0.001  0.001  0.499  1.0
  Fe  Fe14  1  0.001  0.499  0.001  1.0
  Fe  Fe15  1  0.001  0.499  0.499  1.0
  O  O16  1  0.750  0.004  0.004  1.0
  O  O17  1  0.752  0.004  0.496  1.0
  O  O18  1  0.752  0.496  0.004  1.0
  O  O19  1  0.745  0.496  0.496  1.0
  O  O20  1  0.250  0.001  0.001  1.0
  O  O21  1  0.248  0.001  0.499  1.0
  O  O22  1  0.248  0.499  0.001  1.0
  O  O23  1  0.254  0.499  0.499  1.0
  O  O24  1  0.499  0.248  0.001  1.0
  O  O25  1  0.499  0.254  0.499  1.0
  O  O26  1  0.496  0.752  0.004  1.0
  O  O27  1  0.496  0.745  0.496  1.0
  O  O28  1  0.001  0.250  0.001  1.0
  O  O29  1  0.001  0.248  0.499  1.0
  O  O30  1  0.004  0.750  0.004  1.0
  O  O31  1  0.004  0.752  0.496  1.0
  O  O32  1  0.496  0.004  0.752  1.0
  O  O33  1  0.499  0.001  0.248  1.0
  O  O34  1  0.496  0.496  0.745  1.0
  O  O35  1  0.499  0.499  0.254  1.0
  O  O36  1  0.004  0.004  0.750  1.0
  O  O37  1  0.001  0.001  0.250  1.0
  O  O38  1  0.004  0.496  0.752  1.0
  O  O39  1  0.001  0.499  0.248  1.0
[/CIF]
.