The structure described by V5(BO5)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1) and four equivalent O(4) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 57°. In the second V site, V(2) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(5) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the third V site, V(3) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 61°. B(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one V(2), and two equivalent V(3) atoms to form distorted corner-sharing OV4 tetrahedra. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(3) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent V(2) and one B(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one V(3), two equivalent V(1), and one B(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one V(3), two equivalent V(2), and one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V5(BO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.123
_cell_length_b   9.442
_cell_length_c   12.404
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   365.695
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.000  0.500  1.0
  V  V1  1  0.500  0.016  0.791  1.0
  V  V2  1  0.000  0.255  0.611  1.0
  V  V3  1  0.000  0.245  0.111  1.0
  V  V4  1  0.500  0.484  0.291  1.0
  V  V5  1  0.500  0.500  0.000  1.0
  V  V6  1  0.500  0.516  0.709  1.0
  V  V7  1  0.000  0.755  0.889  1.0
  V  V8  1  0.000  0.745  0.389  1.0
  V  V9  1  0.500  0.984  0.209  1.0
  B  B10  1  0.000  0.215  0.356  1.0
  B  B11  1  0.000  0.285  0.856  1.0
  B  B12  1  0.000  0.715  0.144  1.0
  B  B13  1  0.000  0.785  0.644  1.0
  O  O14  1  0.500  0.113  0.648  1.0
  O  O15  1  0.500  0.121  0.091  1.0
  O  O16  1  0.000  0.140  0.845  1.0
  O  O17  1  0.000  0.152  0.457  1.0
  O  O18  1  0.000  0.130  0.264  1.0
  O  O19  1  0.000  0.370  0.764  1.0
  O  O20  1  0.000  0.348  0.957  1.0
  O  O21  1  0.000  0.360  0.345  1.0
  O  O22  1  0.500  0.379  0.591  1.0
  O  O23  1  0.500  0.387  0.148  1.0
  O  O24  1  0.500  0.613  0.852  1.0
  O  O25  1  0.500  0.621  0.409  1.0
  O  O26  1  0.000  0.640  0.655  1.0
  O  O27  1  0.000  0.652  0.043  1.0
  O  O28  1  0.000  0.630  0.236  1.0
  O  O29  1  0.000  0.870  0.736  1.0
  O  O30  1  0.000  0.848  0.543  1.0
  O  O31  1  0.000  0.860  0.155  1.0
  O  O32  1  0.500  0.879  0.909  1.0
  O  O33  1  0.500  0.887  0.352  1.0
[/CIF]
.
The structure described by V5(BO5)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1) and four equivalent O(4) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 57°. In the second V site, V(2) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(5) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the third V site, V(3) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 61°. B(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one V(2), and two equivalent V(3) atoms to form distorted corner-sharing OV4 tetrahedra. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(3) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent V(2) and one B(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one V(3), two equivalent V(1), and one B(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one V(3), two equivalent V(2), and one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V5(BO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.123
_cell_length_b   9.442
_cell_length_c   12.404
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   365.695
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.000  0.500  1.0
  V  V1  1  0.500  0.016  0.791  1.0
  V  V2  1  0.000  0.255  0.611  1.0
  V  V3  1  0.000  0.245  0.111  1.0
  V  V4  1  0.500  0.484  0.291  1.0
  V  V5  1  0.500  0.500  0.000  1.0
  V  V6  1  0.500  0.516  0.709  1.0
  V  V7  1  0.000  0.755  0.889  1.0
  V  V8  1  0.000  0.745  0.389  1.0
  V  V9  1  0.500  0.984  0.209  1.0
  B  B10  1  0.000  0.215  0.356  1.0
  B  B11  1  0.000  0.285  0.856  1.0
  B  B12  1  0.000  0.715  0.144  1.0
  B  B13  1  0.000  0.785  0.644  1.0
  O  O14  1  0.500  0.113  0.648  1.0
  O  O15  1  0.500  0.121  0.091  1.0
  O  O16  1  0.000  0.140  0.845  1.0
  O  O17  1  0.000  0.152  0.457  1.0
  O  O18  1  0.000  0.130  0.264  1.0
  O  O19  1  0.000  0.370  0.764  1.0
  O  O20  1  0.000  0.348  0.957  1.0
  O  O21  1  0.000  0.360  0.345  1.0
  O  O22  1  0.500  0.379  0.591  1.0
  O  O23  1  0.500  0.387  0.148  1.0
  O  O24  1  0.500  0.613  0.852  1.0
  O  O25  1  0.500  0.621  0.409  1.0
  O  O26  1  0.000  0.640  0.655  1.0
  O  O27  1  0.000  0.652  0.043  1.0
  O  O28  1  0.000  0.630  0.236  1.0
  O  O29  1  0.000  0.870  0.736  1.0
  O  O30  1  0.000  0.848  0.543  1.0
  O  O31  1  0.000  0.860  0.155  1.0
  O  O32  1  0.500  0.879  0.909  1.0
  O  O33  1  0.500  0.887  0.352  1.0
[/CIF]
.