The crystal structure described by NaPH6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Na(1) is bonded to six equivalent H(1) atoms to form NaH6 octahedra that share corners with six equivalent P(1)H6 octahedra. The corner-sharing octahedra are not tilted. P(1) is bonded to six equivalent H(1) atoms to form PH6 octahedra that share corners with six equivalent Na(1)H6 octahedra. The corner-sharing octahedra are not tilted. H(1) is bonded in a linear geometry to one Na(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaPH6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.255
_cell_length_b   5.255
_cell_length_c   5.255
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   102.623
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  P  P1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.800  0.200  0.800  1.0
  H  H3  1  0.200  0.200  0.800  1.0
  H  H4  1  0.200  0.800  0.200  1.0
  H  H5  1  0.200  0.800  0.800  1.0
  H  H6  1  0.800  0.200  0.200  1.0
  H  H7  1  0.800  0.800  0.200  1.0
[/CIF]
.
The crystal structure described by NaPH6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Na(1) is bonded to six equivalent H(1) atoms to form NaH6 octahedra that share corners with six equivalent P(1)H6 octahedra. The corner-sharing octahedra are not tilted. P(1) is bonded to six equivalent H(1) atoms to form PH6 octahedra that share corners with six equivalent Na(1)H6 octahedra. The corner-sharing octahedra are not tilted. H(1) is bonded in a linear geometry to one Na(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaPH6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.255
_cell_length_b   5.255
_cell_length_c   5.255
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   102.623
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  P  P1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.800  0.200  0.800  1.0
  H  H3  1  0.200  0.200  0.800  1.0
  H  H4  1  0.200  0.800  0.200  1.0
  H  H5  1  0.200  0.800  0.800  1.0
  H  H6  1  0.800  0.200  0.200  1.0
  H  H7  1  0.800  0.800  0.200  1.0
[/CIF]
.