The crystal structure described by SbO2F crystallizes in the monoclinic Cc space group. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form corner-sharing SbO4F2 octahedra. The corner-sharing octahedral tilt angles range from 37-44°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_SbO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.008
_cell_length_b   5.461
_cell_length_c   5.008
_cell_angle_alpha   119.047
_cell_angle_beta   61.823
_cell_angle_gamma   119.047
_symmetry_Int_Tables_number   1
_cell_volume   99.524
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.690  0.151  0.751  1.0
  Sb  Sb1  1  0.251  0.651  0.190  1.0
  O  O2  1  0.094  0.414  0.827  1.0
  O  O3  1  0.460  0.400  0.118  1.0
  O  O4  1  0.327  0.914  0.594  1.0
  O  O5  1  0.618  0.900  0.960  1.0
  F  F6  1  0.845  0.399  0.457  1.0
  F  F7  1  0.957  0.899  0.345  1.0
[/CIF]
.
The crystal structure described by SbO2F crystallizes in the monoclinic Cc space group. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form corner-sharing SbO4F2 octahedra. The corner-sharing octahedral tilt angles range from 37-44°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_SbO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.008
_cell_length_b   5.461
_cell_length_c   5.008
_cell_angle_alpha   119.047
_cell_angle_beta   61.823
_cell_angle_gamma   119.047
_symmetry_Int_Tables_number   1
_cell_volume   99.524
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.690  0.151  0.751  1.0
  Sb  Sb1  1  0.251  0.651  0.190  1.0
  O  O2  1  0.094  0.414  0.827  1.0
  O  O3  1  0.460  0.400  0.118  1.0
  O  O4  1  0.327  0.914  0.594  1.0
  O  O5  1  0.618  0.900  0.960  1.0
  F  F6  1  0.845  0.399  0.457  1.0
  F  F7  1  0.957  0.899  0.345  1.0
[/CIF]
.