The structure described by TlCd(NO2)3 crystallizes in the trigonal R3 space group. The structure consists of three 7440-28-0 atoms inside a Cd(NO2)3 framework. In the Cd(NO2)3 framework, Cd(1) is bonded in a 9-coordinate geometry to three equivalent N(1), three equivalent O(1), and three equivalent O(2) atoms. N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one N(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. is represented by the CIF file [CIF]
data_TlCd(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.495
_cell_length_b   5.495
_cell_length_c   5.495
_cell_angle_alpha   90.613
_cell_angle_beta   90.613
_cell_angle_gamma   90.613
_symmetry_Int_Tables_number   1
_cell_volume   165.888
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.385  0.385  0.385  1.0
  Cd  Cd1  1  0.898  0.898  0.898  1.0
  N  N2  1  0.442  0.887  0.839  1.0
  N  N3  1  0.887  0.839  0.442  1.0
  N  N4  1  0.839  0.442  0.887  1.0
  O  O5  1  0.688  0.837  0.326  1.0
  O  O6  1  0.326  0.688  0.837  1.0
  O  O7  1  0.849  0.316  0.078  1.0
  O  O8  1  0.078  0.849  0.316  1.0
  O  O9  1  0.316  0.078  0.849  1.0
  O  O10  1  0.837  0.326  0.688  1.0
[/CIF]
.
The structure described by TlCd(NO2)3 crystallizes in the trigonal R3 space group. The structure consists of three 7440-28-0 atoms inside a Cd(NO2)3 framework. In the Cd(NO2)3 framework, Cd(1) is bonded in a 9-coordinate geometry to three equivalent N(1), three equivalent O(1), and three equivalent O(2) atoms. N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one N(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. is represented by the CIF file [CIF]
data_TlCd(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.495
_cell_length_b   5.495
_cell_length_c   5.495
_cell_angle_alpha   90.613
_cell_angle_beta   90.613
_cell_angle_gamma   90.613
_symmetry_Int_Tables_number   1
_cell_volume   165.888
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.385  0.385  0.385  1.0
  Cd  Cd1  1  0.898  0.898  0.898  1.0
  N  N2  1  0.442  0.887  0.839  1.0
  N  N3  1  0.887  0.839  0.442  1.0
  N  N4  1  0.839  0.442  0.887  1.0
  O  O5  1  0.688  0.837  0.326  1.0
  O  O6  1  0.326  0.688  0.837  1.0
  O  O7  1  0.849  0.316  0.078  1.0
  O  O8  1  0.078  0.849  0.316  1.0
  O  O9  1  0.316  0.078  0.849  1.0
  O  O10  1  0.837  0.326  0.688  1.0
[/CIF]
.