The material structure described by SbF5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one SbF4 cluster and one SbF6 cluster. In the SbF4 cluster, Sb(1) is bonded in a 4-coordinate geometry to two equivalent F(3) and two equivalent F(4) atoms. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the SbF6 cluster, Sb(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF file [CIF]
data_SbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.536
_cell_length_b   5.549
_cell_length_c   7.918
_cell_angle_alpha   109.552
_cell_angle_beta   96.915
_cell_angle_gamma   110.226
_symmetry_Int_Tables_number   1
_cell_volume   207.255
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.500  0.000  0.500  1.0
  F  F2  1  0.667  0.917  0.248  1.0
  F  F3  1  0.333  0.083  0.752  1.0
  F  F4  1  0.404  0.248  0.382  1.0
  F  F5  1  0.131  0.783  0.117  1.0
  F  F6  1  0.232  0.297  0.050  1.0
  F  F7  1  0.851  0.273  0.449  1.0
  F  F8  1  0.768  0.703  0.950  1.0
  F  F9  1  0.149  0.727  0.551  1.0
  F  F10  1  0.869  0.217  0.883  1.0
  F  F11  1  0.596  0.752  0.618  1.0
[/CIF]
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The material structure described by SbF5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one SbF4 cluster and one SbF6 cluster. In the SbF4 cluster, Sb(1) is bonded in a 4-coordinate geometry to two equivalent F(3) and two equivalent F(4) atoms. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the SbF6 cluster, Sb(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF file [CIF]
data_SbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.536
_cell_length_b   5.549
_cell_length_c   7.918
_cell_angle_alpha   109.552
_cell_angle_beta   96.915
_cell_angle_gamma   110.226
_symmetry_Int_Tables_number   1
_cell_volume   207.255
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.500  0.000  0.500  1.0
  F  F2  1  0.667  0.917  0.248  1.0
  F  F3  1  0.333  0.083  0.752  1.0
  F  F4  1  0.404  0.248  0.382  1.0
  F  F5  1  0.131  0.783  0.117  1.0
  F  F6  1  0.232  0.297  0.050  1.0
  F  F7  1  0.851  0.273  0.449  1.0
  F  F8  1  0.768  0.703  0.950  1.0
  F  F9  1  0.149  0.727  0.551  1.0
  F  F10  1  0.869  0.217  0.883  1.0
  F  F11  1  0.596  0.752  0.618  1.0
[/CIF]
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