The material described by NaClO4 is Zircon-like structured and crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. is represented by the CIF card [CIF]
data_NaClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.719
_cell_length_b   4.719
_cell_length_c   6.986
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.614
_symmetry_Int_Tables_number   1
_cell_volume   154.801
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.656  0.656  0.250  1.0
  Na  Na1  1  0.344  0.344  0.750  1.0
  Cl  Cl2  1  0.159  0.159  0.250  1.0
  Cl  Cl3  1  0.841  0.841  0.750  1.0
  O  O4  1  0.141  0.807  0.750  1.0
  O  O5  1  0.859  0.193  0.250  1.0
  O  O6  1  0.807  0.141  0.750  1.0
  O  O7  1  0.193  0.859  0.250  1.0
  O  O8  1  0.294  0.294  0.083  1.0
  O  O9  1  0.706  0.706  0.583  1.0
  O  O10  1  0.294  0.294  0.417  1.0
  O  O11  1  0.706  0.706  0.917  1.0
[/CIF]
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The material described by NaClO4 is Zircon-like structured and crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. is represented by the CIF card [CIF]
data_NaClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.719
_cell_length_b   4.719
_cell_length_c   6.986
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.614
_symmetry_Int_Tables_number   1
_cell_volume   154.801
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.656  0.656  0.250  1.0
  Na  Na1  1  0.344  0.344  0.750  1.0
  Cl  Cl2  1  0.159  0.159  0.250  1.0
  Cl  Cl3  1  0.841  0.841  0.750  1.0
  O  O4  1  0.141  0.807  0.750  1.0
  O  O5  1  0.859  0.193  0.250  1.0
  O  O6  1  0.807  0.141  0.750  1.0
  O  O7  1  0.193  0.859  0.250  1.0
  O  O8  1  0.294  0.294  0.083  1.0
  O  O9  1  0.706  0.706  0.583  1.0
  O  O10  1  0.294  0.294  0.417  1.0
  O  O11  1  0.706  0.706  0.917  1.0
[/CIF]
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