The structure described by Lu2WO6 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and two equivalent O(1) atoms. In the second Lu site, Lu(2) is bonded to one O(2), one O(3), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted LuO7 pentagonal bipyramids that share corners with three equivalent W(1)O6 octahedra, edges with two equivalent W(1)O6 octahedra, and edges with two equivalent Lu(2)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles range from 40-47°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Lu(2)O7 pentagonal bipyramids and edges with two equivalent Lu(2)O7 pentagonal bipyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Lu(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Lu(1), one Lu(2), and one W(1) atom. In the fifth O site, O(5) is bonded to one Lu(1), two equivalent Lu(2), and one W(1) atom to form a mixture of distorted corner and edge-sharing OLu3W tetrahedra. In the sixth O site, O(6) is bonded to one Lu(1), two equivalent Lu(2), and one W(1) atom to form a mixture of corner and edge-sharing OLu3W tetrahedra. is represented by the CIF file [CIF]
data_Lu2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.103
_cell_length_b   8.888
_cell_length_c   9.706
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   440.224
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Lu  Lu0  1  0.013  0.396  0.033  1.0
  Lu  Lu1  1  0.041  0.281  0.627  1.0
  Lu  Lu2  1  0.459  0.719  0.127  1.0
  Lu  Lu3  1  0.487  0.604  0.533  1.0
  Lu  Lu4  1  0.513  0.104  0.967  1.0
  Lu  Lu5  1  0.541  0.219  0.373  1.0
  Lu  Lu6  1  0.959  0.781  0.873  1.0
  Lu  Lu7  1  0.987  0.896  0.467  1.0
  W  W8  1  0.036  0.005  0.155  1.0
  W  W9  1  0.464  0.995  0.655  1.0
  W  W10  1  0.536  0.495  0.845  1.0
  W  W11  1  0.964  0.505  0.345  1.0
  O  O12  1  0.095  0.659  0.468  1.0
  O  O13  1  0.180  0.544  0.196  1.0
  O  O14  1  0.176  0.861  0.682  1.0
  O  O15  1  0.199  0.857  0.266  1.0
  O  O16  1  0.237  0.383  0.430  1.0
  O  O17  1  0.254  0.089  0.503  1.0
  O  O18  1  0.246  0.911  0.003  1.0
  O  O19  1  0.263  0.617  0.930  1.0
  O  O20  1  0.301  0.143  0.766  1.0
  O  O21  1  0.324  0.139  0.182  1.0
  O  O22  1  0.320  0.456  0.696  1.0
  O  O23  1  0.405  0.341  0.968  1.0
  O  O24  1  0.595  0.841  0.532  1.0
  O  O25  1  0.680  0.956  0.804  1.0
  O  O26  1  0.676  0.639  0.318  1.0
  O  O27  1  0.699  0.643  0.734  1.0
  O  O28  1  0.737  0.117  0.570  1.0
  O  O29  1  0.754  0.411  0.497  1.0
  O  O30  1  0.746  0.589  0.997  1.0
  O  O31  1  0.763  0.883  0.070  1.0
  O  O32  1  0.801  0.357  0.234  1.0
  O  O33  1  0.824  0.361  0.818  1.0
  O  O34  1  0.820  0.044  0.304  1.0
  O  O35  1  0.905  0.159  0.032  1.0
[/CIF]
.
The structure described by Lu2WO6 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and two equivalent O(1) atoms. In the second Lu site, Lu(2) is bonded to one O(2), one O(3), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted LuO7 pentagonal bipyramids that share corners with three equivalent W(1)O6 octahedra, edges with two equivalent W(1)O6 octahedra, and edges with two equivalent Lu(2)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles range from 40-47°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Lu(2)O7 pentagonal bipyramids and edges with two equivalent Lu(2)O7 pentagonal bipyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Lu(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Lu(1), one Lu(2), and one W(1) atom. In the fifth O site, O(5) is bonded to one Lu(1), two equivalent Lu(2), and one W(1) atom to form a mixture of distorted corner and edge-sharing OLu3W tetrahedra. In the sixth O site, O(6) is bonded to one Lu(1), two equivalent Lu(2), and one W(1) atom to form a mixture of corner and edge-sharing OLu3W tetrahedra. is represented by the CIF file [CIF]
data_Lu2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.103
_cell_length_b   8.888
_cell_length_c   9.706
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   440.224
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Lu  Lu0  1  0.013  0.396  0.033  1.0
  Lu  Lu1  1  0.041  0.281  0.627  1.0
  Lu  Lu2  1  0.459  0.719  0.127  1.0
  Lu  Lu3  1  0.487  0.604  0.533  1.0
  Lu  Lu4  1  0.513  0.104  0.967  1.0
  Lu  Lu5  1  0.541  0.219  0.373  1.0
  Lu  Lu6  1  0.959  0.781  0.873  1.0
  Lu  Lu7  1  0.987  0.896  0.467  1.0
  W  W8  1  0.036  0.005  0.155  1.0
  W  W9  1  0.464  0.995  0.655  1.0
  W  W10  1  0.536  0.495  0.845  1.0
  W  W11  1  0.964  0.505  0.345  1.0
  O  O12  1  0.095  0.659  0.468  1.0
  O  O13  1  0.180  0.544  0.196  1.0
  O  O14  1  0.176  0.861  0.682  1.0
  O  O15  1  0.199  0.857  0.266  1.0
  O  O16  1  0.237  0.383  0.430  1.0
  O  O17  1  0.254  0.089  0.503  1.0
  O  O18  1  0.246  0.911  0.003  1.0
  O  O19  1  0.263  0.617  0.930  1.0
  O  O20  1  0.301  0.143  0.766  1.0
  O  O21  1  0.324  0.139  0.182  1.0
  O  O22  1  0.320  0.456  0.696  1.0
  O  O23  1  0.405  0.341  0.968  1.0
  O  O24  1  0.595  0.841  0.532  1.0
  O  O25  1  0.680  0.956  0.804  1.0
  O  O26  1  0.676  0.639  0.318  1.0
  O  O27  1  0.699  0.643  0.734  1.0
  O  O28  1  0.737  0.117  0.570  1.0
  O  O29  1  0.754  0.411  0.497  1.0
  O  O30  1  0.746  0.589  0.997  1.0
  O  O31  1  0.763  0.883  0.070  1.0
  O  O32  1  0.801  0.357  0.234  1.0
  O  O33  1  0.824  0.361  0.818  1.0
  O  O34  1  0.820  0.044  0.304  1.0
  O  O35  1  0.905  0.159  0.032  1.0
[/CIF]
.