The crystal structure described by POClF2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight chlorodifluorophosphorus oxide molecules. P(1) is bonded in a distorted tetrahedral geometry to one O(2), one Cl(1), and two equivalent F(1) atoms. O(2) is bonded in a single-bond geometry to one P(1) atom. Cl(1) is bonded in a single-bond geometry to one P(1) atom. F(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PClOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.553
_cell_length_b   9.908
_cell_length_c   13.099
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   720.683
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.750  0.280  0.573  1.0
  P  P1  1  0.750  0.220  0.073  1.0
  P  P2  1  0.250  0.350  0.255  1.0
  P  P3  1  0.750  0.650  0.745  1.0
  P  P4  1  0.750  0.850  0.245  1.0
  P  P5  1  0.250  0.720  0.427  1.0
  P  P6  1  0.250  0.780  0.927  1.0
  P  P7  1  0.250  0.150  0.755  1.0
  Cl  Cl8  1  0.250  0.613  0.006  1.0
  Cl  Cl9  1  0.750  0.666  0.190  1.0
  Cl  Cl10  1  0.750  0.113  0.494  1.0
  Cl  Cl11  1  0.250  0.334  0.810  1.0
  Cl  Cl12  1  0.750  0.834  0.690  1.0
  Cl  Cl13  1  0.250  0.887  0.506  1.0
  Cl  Cl14  1  0.250  0.166  0.310  1.0
  Cl  Cl15  1  0.750  0.387  0.994  1.0
  O  O16  1  0.750  0.634  0.854  1.0
  O  O17  1  0.750  0.228  0.184  1.0
  O  O18  1  0.250  0.134  0.646  1.0
  O  O19  1  0.750  0.866  0.354  1.0
  O  O20  1  0.250  0.728  0.316  1.0
  O  O21  1  0.250  0.772  0.816  1.0
  O  O22  1  0.750  0.272  0.684  1.0
  O  O23  1  0.250  0.366  0.146  1.0
  F  F24  1  0.038  0.640  0.472  1.0
  F  F25  1  0.962  0.140  0.028  1.0
  F  F26  1  0.039  0.418  0.311  1.0
  F  F27  1  0.961  0.918  0.189  1.0
  F  F28  1  0.538  0.360  0.528  1.0
  F  F29  1  0.462  0.640  0.472  1.0
  F  F30  1  0.462  0.860  0.972  1.0
  F  F31  1  0.539  0.582  0.689  1.0
  F  F32  1  0.539  0.918  0.189  1.0
  F  F33  1  0.961  0.582  0.689  1.0
  F  F34  1  0.039  0.082  0.811  1.0
  F  F35  1  0.461  0.418  0.311  1.0
  F  F36  1  0.038  0.860  0.972  1.0
  F  F37  1  0.538  0.140  0.028  1.0
  F  F38  1  0.962  0.360  0.528  1.0
  F  F39  1  0.461  0.082  0.811  1.0
[/CIF]
.
The crystal structure described by POClF2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight chlorodifluorophosphorus oxide molecules. P(1) is bonded in a distorted tetrahedral geometry to one O(2), one Cl(1), and two equivalent F(1) atoms. O(2) is bonded in a single-bond geometry to one P(1) atom. Cl(1) is bonded in a single-bond geometry to one P(1) atom. F(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PClOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.553
_cell_length_b   9.908
_cell_length_c   13.099
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   720.683
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.750  0.280  0.573  1.0
  P  P1  1  0.750  0.220  0.073  1.0
  P  P2  1  0.250  0.350  0.255  1.0
  P  P3  1  0.750  0.650  0.745  1.0
  P  P4  1  0.750  0.850  0.245  1.0
  P  P5  1  0.250  0.720  0.427  1.0
  P  P6  1  0.250  0.780  0.927  1.0
  P  P7  1  0.250  0.150  0.755  1.0
  Cl  Cl8  1  0.250  0.613  0.006  1.0
  Cl  Cl9  1  0.750  0.666  0.190  1.0
  Cl  Cl10  1  0.750  0.113  0.494  1.0
  Cl  Cl11  1  0.250  0.334  0.810  1.0
  Cl  Cl12  1  0.750  0.834  0.690  1.0
  Cl  Cl13  1  0.250  0.887  0.506  1.0
  Cl  Cl14  1  0.250  0.166  0.310  1.0
  Cl  Cl15  1  0.750  0.387  0.994  1.0
  O  O16  1  0.750  0.634  0.854  1.0
  O  O17  1  0.750  0.228  0.184  1.0
  O  O18  1  0.250  0.134  0.646  1.0
  O  O19  1  0.750  0.866  0.354  1.0
  O  O20  1  0.250  0.728  0.316  1.0
  O  O21  1  0.250  0.772  0.816  1.0
  O  O22  1  0.750  0.272  0.684  1.0
  O  O23  1  0.250  0.366  0.146  1.0
  F  F24  1  0.038  0.640  0.472  1.0
  F  F25  1  0.962  0.140  0.028  1.0
  F  F26  1  0.039  0.418  0.311  1.0
  F  F27  1  0.961  0.918  0.189  1.0
  F  F28  1  0.538  0.360  0.528  1.0
  F  F29  1  0.462  0.640  0.472  1.0
  F  F30  1  0.462  0.860  0.972  1.0
  F  F31  1  0.539  0.582  0.689  1.0
  F  F32  1  0.539  0.918  0.189  1.0
  F  F33  1  0.961  0.582  0.689  1.0
  F  F34  1  0.039  0.082  0.811  1.0
  F  F35  1  0.461  0.418  0.311  1.0
  F  F36  1  0.038  0.860  0.972  1.0
  F  F37  1  0.538  0.140  0.028  1.0
  F  F38  1  0.962  0.360  0.528  1.0
  F  F39  1  0.461  0.082  0.811  1.0
[/CIF]
.