The material structure described by (Mo2NO7)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one Mo2NO7 cluster. In the Mo2NO7 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(6) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(5), and one O(7) atom. N(2) is bonded in a single-bond geometry to one O(5) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(2) and one N(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one O(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom. is represented by the CIF file [CIF]
data_Mo2N2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.259
_cell_length_b   7.612
_cell_length_c   8.138
_cell_angle_alpha   100.190
_cell_angle_beta   88.098
_cell_angle_gamma   104.643
_symmetry_Int_Tables_number   1
_cell_volume   428.192
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.222  0.077  0.661  1.0
  Mo  Mo1  1  0.778  0.923  0.339  1.0
  Mo  Mo2  1  0.268  0.303  0.076  1.0
  Mo  Mo3  1  0.732  0.697  0.924  1.0
  N  N4  1  0.777  0.475  0.405  1.0
  N  N5  1  0.223  0.525  0.595  1.0
  N  N6  1  0.741  0.065  0.839  1.0
  N  N7  1  0.259  0.935  0.161  1.0
  O  O8  1  0.176  0.252  0.849  1.0
  O  O9  1  0.824  0.748  0.151  1.0
  O  O10  1  0.297  0.923  0.756  1.0
  O  O11  1  0.703  0.077  0.244  1.0
  O  O12  1  0.414  0.184  0.556  1.0
  O  O13  1  0.586  0.816  0.444  1.0
  O  O14  1  0.173  0.465  0.200  1.0
  O  O15  1  0.827  0.535  0.800  1.0
  O  O16  1  0.822  0.936  0.838  1.0
  O  O17  1  0.178  0.064  0.162  1.0
  O  O18  1  0.972  0.092  0.505  1.0
  O  O19  1  0.028  0.908  0.495  1.0
  O  O20  1  0.513  0.365  0.091  1.0
  O  O21  1  0.487  0.635  0.909  1.0
[/CIF]
.
The material structure described by (Mo2NO7)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one Mo2NO7 cluster. In the Mo2NO7 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(6) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(5), and one O(7) atom. N(2) is bonded in a single-bond geometry to one O(5) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(2) and one N(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one O(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom. is represented by the CIF file [CIF]
data_Mo2N2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.259
_cell_length_b   7.612
_cell_length_c   8.138
_cell_angle_alpha   100.190
_cell_angle_beta   88.098
_cell_angle_gamma   104.643
_symmetry_Int_Tables_number   1
_cell_volume   428.192
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.222  0.077  0.661  1.0
  Mo  Mo1  1  0.778  0.923  0.339  1.0
  Mo  Mo2  1  0.268  0.303  0.076  1.0
  Mo  Mo3  1  0.732  0.697  0.924  1.0
  N  N4  1  0.777  0.475  0.405  1.0
  N  N5  1  0.223  0.525  0.595  1.0
  N  N6  1  0.741  0.065  0.839  1.0
  N  N7  1  0.259  0.935  0.161  1.0
  O  O8  1  0.176  0.252  0.849  1.0
  O  O9  1  0.824  0.748  0.151  1.0
  O  O10  1  0.297  0.923  0.756  1.0
  O  O11  1  0.703  0.077  0.244  1.0
  O  O12  1  0.414  0.184  0.556  1.0
  O  O13  1  0.586  0.816  0.444  1.0
  O  O14  1  0.173  0.465  0.200  1.0
  O  O15  1  0.827  0.535  0.800  1.0
  O  O16  1  0.822  0.936  0.838  1.0
  O  O17  1  0.178  0.064  0.162  1.0
  O  O18  1  0.972  0.092  0.505  1.0
  O  O19  1  0.028  0.908  0.495  1.0
  O  O20  1  0.513  0.365  0.091  1.0
  O  O21  1  0.487  0.635  0.909  1.0
[/CIF]
.