The structure described by As(IF2)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two As(IF2)3 clusters. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one I(3) and one F(5) atom. In the second I site, I(2) is bonded in a 1-coordinate geometry to one I(3) atom. In the third I site, I(3) is bonded in a distorted water-like geometry to one I(1) and one I(2) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) and one I(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_As(IF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.839
_cell_length_b   8.013
_cell_length_c   10.435
_cell_angle_alpha   90.175
_cell_angle_beta   102.280
_cell_angle_gamma   100.373
_symmetry_Int_Tables_number   1
_cell_volume   468.852
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.556  0.773  0.809  1.0
  As  As1  1  0.444  0.227  0.191  1.0
  I  I2  1  0.768  0.765  0.464  1.0
  I  I3  1  0.232  0.235  0.536  1.0
  I  I4  1  0.090  0.622  0.171  1.0
  I  I5  1  0.910  0.378  0.829  1.0
  I  I6  1  0.805  0.831  0.216  1.0
  I  I7  1  0.195  0.169  0.784  1.0
  F  F8  1  0.331  0.671  0.684  1.0
  F  F9  1  0.669  0.329  0.316  1.0
  F  F10  1  0.537  0.968  0.736  1.0
  F  F11  1  0.463  0.032  0.264  1.0
  F  F12  1  0.354  0.806  0.902  1.0
  F  F13  1  0.646  0.194  0.098  1.0
  F  F14  1  0.586  0.578  0.882  1.0
  F  F15  1  0.414  0.422  0.118  1.0
  F  F16  1  0.230  0.258  0.281  1.0
  F  F17  1  0.770  0.742  0.719  1.0
  F  F18  1  0.209  0.124  0.067  1.0
  F  F19  1  0.791  0.876  0.933  1.0
[/CIF]
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The structure described by As(IF2)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two As(IF2)3 clusters. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one I(3) and one F(5) atom. In the second I site, I(2) is bonded in a 1-coordinate geometry to one I(3) atom. In the third I site, I(3) is bonded in a distorted water-like geometry to one I(1) and one I(2) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) and one I(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_As(IF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.839
_cell_length_b   8.013
_cell_length_c   10.435
_cell_angle_alpha   90.175
_cell_angle_beta   102.280
_cell_angle_gamma   100.373
_symmetry_Int_Tables_number   1
_cell_volume   468.852
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.556  0.773  0.809  1.0
  As  As1  1  0.444  0.227  0.191  1.0
  I  I2  1  0.768  0.765  0.464  1.0
  I  I3  1  0.232  0.235  0.536  1.0
  I  I4  1  0.090  0.622  0.171  1.0
  I  I5  1  0.910  0.378  0.829  1.0
  I  I6  1  0.805  0.831  0.216  1.0
  I  I7  1  0.195  0.169  0.784  1.0
  F  F8  1  0.331  0.671  0.684  1.0
  F  F9  1  0.669  0.329  0.316  1.0
  F  F10  1  0.537  0.968  0.736  1.0
  F  F11  1  0.463  0.032  0.264  1.0
  F  F12  1  0.354  0.806  0.902  1.0
  F  F13  1  0.646  0.194  0.098  1.0
  F  F14  1  0.586  0.578  0.882  1.0
  F  F15  1  0.414  0.422  0.118  1.0
  F  F16  1  0.230  0.258  0.281  1.0
  F  F17  1  0.770  0.742  0.719  1.0
  F  F18  1  0.209  0.124  0.067  1.0
  F  F19  1  0.791  0.876  0.933  1.0
[/CIF]
.