The material described by Cd(CoN)2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Cd(1), two equivalent N(1), and three equivalent N(2) atoms to form CoCd2N5 square pyramids that share corners with four equivalent Co(2)N5 square pyramids, edges with two equivalent Co(1)Cd2N5 square pyramids, edges with four equivalent Co(2)N5 square pyramids, and faces with two equivalent Co(1)Cd2N5 square pyramids. In the second Co site, Co(2) is bonded to two equivalent N(2) and three equivalent N(1) atoms to form CoN5 square pyramids that share corners with four equivalent Co(1)Cd2N5 square pyramids, edges with four equivalent Co(1)Cd2N5 square pyramids, and edges with four equivalent Co(2)N5 square pyramids. Cd(1) is bonded in a 6-coordinate geometry to two equivalent Co(1) and four equivalent Cd(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Co(1) and three equivalent Co(2) atoms to form a mixture of edge and corner-sharing NCo5 square pyramids. In the second N site, N(2) is bonded to two equivalent Co(2) and three equivalent Co(1) atoms to form a mixture of edge and corner-sharing NCo5 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cd(CoN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.658
_cell_length_b   2.717
_cell_length_c   15.836
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   243.464
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.865  0.250  0.272  1.0
  Cd  Cd1  1  0.365  0.250  0.228  1.0
  Cd  Cd2  1  0.135  0.750  0.728  1.0
  Cd  Cd3  1  0.635  0.750  0.772  1.0
  Co  Co4  1  0.637  0.250  0.934  1.0
  Co  Co5  1  0.137  0.250  0.566  1.0
  Co  Co6  1  0.363  0.750  0.066  1.0
  Co  Co7  1  0.863  0.750  0.434  1.0
  Co  Co8  1  0.137  0.250  0.933  1.0
  Co  Co9  1  0.637  0.250  0.567  1.0
  Co  Co10  1  0.863  0.750  0.067  1.0
  Co  Co11  1  0.363  0.750  0.433  1.0
  N  N12  1  0.638  0.250  0.441  1.0
  N  N13  1  0.138  0.250  0.059  1.0
  N  N14  1  0.362  0.750  0.559  1.0
  N  N15  1  0.862  0.750  0.941  1.0
  N  N16  1  0.640  0.250  0.062  1.0
  N  N17  1  0.140  0.250  0.438  1.0
  N  N18  1  0.360  0.750  0.938  1.0
  N  N19  1  0.860  0.750  0.562  1.0
[/CIF]
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The material described by Cd(CoN)2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Cd(1), two equivalent N(1), and three equivalent N(2) atoms to form CoCd2N5 square pyramids that share corners with four equivalent Co(2)N5 square pyramids, edges with two equivalent Co(1)Cd2N5 square pyramids, edges with four equivalent Co(2)N5 square pyramids, and faces with two equivalent Co(1)Cd2N5 square pyramids. In the second Co site, Co(2) is bonded to two equivalent N(2) and three equivalent N(1) atoms to form CoN5 square pyramids that share corners with four equivalent Co(1)Cd2N5 square pyramids, edges with four equivalent Co(1)Cd2N5 square pyramids, and edges with four equivalent Co(2)N5 square pyramids. Cd(1) is bonded in a 6-coordinate geometry to two equivalent Co(1) and four equivalent Cd(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Co(1) and three equivalent Co(2) atoms to form a mixture of edge and corner-sharing NCo5 square pyramids. In the second N site, N(2) is bonded to two equivalent Co(2) and three equivalent Co(1) atoms to form a mixture of edge and corner-sharing NCo5 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cd(CoN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.658
_cell_length_b   2.717
_cell_length_c   15.836
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   243.464
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.865  0.250  0.272  1.0
  Cd  Cd1  1  0.365  0.250  0.228  1.0
  Cd  Cd2  1  0.135  0.750  0.728  1.0
  Cd  Cd3  1  0.635  0.750  0.772  1.0
  Co  Co4  1  0.637  0.250  0.934  1.0
  Co  Co5  1  0.137  0.250  0.566  1.0
  Co  Co6  1  0.363  0.750  0.066  1.0
  Co  Co7  1  0.863  0.750  0.434  1.0
  Co  Co8  1  0.137  0.250  0.933  1.0
  Co  Co9  1  0.637  0.250  0.567  1.0
  Co  Co10  1  0.863  0.750  0.067  1.0
  Co  Co11  1  0.363  0.750  0.433  1.0
  N  N12  1  0.638  0.250  0.441  1.0
  N  N13  1  0.138  0.250  0.059  1.0
  N  N14  1  0.362  0.750  0.559  1.0
  N  N15  1  0.862  0.750  0.941  1.0
  N  N16  1  0.640  0.250  0.062  1.0
  N  N17  1  0.140  0.250  0.438  1.0
  N  N18  1  0.360  0.750  0.938  1.0
  N  N19  1  0.860  0.750  0.562  1.0
[/CIF]
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