The compound described by VWC2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent C(1) atoms to form VC6 octahedra that share corners with six equivalent W(1)C6 octahedra, edges with six equivalent V(1)C6 octahedra, and edges with six equivalent W(1)C6 octahedra. The corner-sharing octahedral tilt angles are 2°. W(1) is bonded to six equivalent C(1) atoms to form WC6 octahedra that share corners with six equivalent V(1)C6 octahedra, edges with six equivalent V(1)C6 octahedra, and edges with six equivalent W(1)C6 octahedra. The corner-sharing octahedral tilt angles are 2°. C(1) is bonded to three equivalent V(1) and three equivalent W(1) atoms to form a mixture of edge and corner-sharing CV3W3 octahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_VWC2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.236
_cell_length_b   5.236
_cell_length_c   5.236
_cell_angle_alpha   33.686
_cell_angle_beta   33.686
_cell_angle_gamma   33.686
_symmetry_Int_Tables_number   1
_cell_volume   39.335
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.500  1.0
  W  W1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.246  0.246  0.246  1.0
  C  C3  1  0.754  0.754  0.754  1.0
[/CIF]
.
The compound described by VWC2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent C(1) atoms to form VC6 octahedra that share corners with six equivalent W(1)C6 octahedra, edges with six equivalent V(1)C6 octahedra, and edges with six equivalent W(1)C6 octahedra. The corner-sharing octahedral tilt angles are 2°. W(1) is bonded to six equivalent C(1) atoms to form WC6 octahedra that share corners with six equivalent V(1)C6 octahedra, edges with six equivalent V(1)C6 octahedra, and edges with six equivalent W(1)C6 octahedra. The corner-sharing octahedral tilt angles are 2°. C(1) is bonded to three equivalent V(1) and three equivalent W(1) atoms to form a mixture of edge and corner-sharing CV3W3 octahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_VWC2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.236
_cell_length_b   5.236
_cell_length_c   5.236
_cell_angle_alpha   33.686
_cell_angle_beta   33.686
_cell_angle_gamma   33.686
_symmetry_Int_Tables_number   1
_cell_volume   39.335
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.500  1.0
  W  W1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.246  0.246  0.246  1.0
  C  C3  1  0.754  0.754  0.754  1.0
[/CIF]
.