The material described by Li4V(TeO4)3 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(11), one O(21), one O(23), one O(5), and one O(7) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(12), one O(22), one O(24), one O(6), and one O(8) atom. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(21), one O(23), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(12), one O(22), and one O(24) atom. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(15), one O(17), one O(19), and one O(3) atom. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(18), one O(2), one O(20), and one O(4) atom. In the seventh Li site, Li(7) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(15), one O(17), one O(19), and one O(3) atom. In the eighth Li site, Li(8) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(18), one O(2), one O(20), and one O(4) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(18), one O(2), one O(20), one O(4), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and edges with two equivalent Te(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(12), one O(17), one O(19), and one O(3) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and edges with two equivalent Te(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. There are six inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(13), one O(15), one O(3), one O(5), and one O(7) atom to form TeO6 octahedra that share corners with two equivalent V(2)O6 octahedra and edges with two equivalent Te(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. In the second Te site, Te(2) is bonded to one O(14), one O(16), one O(2), one O(4), one O(6), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra and edges with two equivalent Te(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. In the third Te site, Te(3) is bonded to one O(11), one O(18), one O(20), one O(21), one O(23), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Te(5)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. In the fourth Te site, Te(4) is bonded to one O(10), one O(12), one O(17), one O(19), one O(22), and one O(24) atom to form TeO6 octahedra that share corners with two equivalent Te(6)O6 octahedra and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-56°. In the fifth Te site, Te(5) is bonded to one O(13), one O(15), one O(21), one O(23), one O(5), and one O(7) atom to form a mixture of edge and corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. In the sixth Te site, Te(6) is bonded to one O(14), one O(16), one O(22), one O(24), one O(6), and one O(8) atom to form a mixture of edge and corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 53-56°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(5), one Li(7), one V(2), and one Te(1) atom to form a mixture of distorted edge and corner-sharing OLi2VTe trigonal pyramids. In the second O site, O(2) is bonded to one Li(6), one Li(8), one V(1), and one Te(2) atom to form a mixture of distorted edge and corner-sharing OLi2VTe trigonal pyramids. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one V(2), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(6), one Li(8), one V(1), and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one Te(1), and one Te(5) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one Te(2), and one Te(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Li(1), one Te(1), and one Te(5) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(2), one Te(2), and one Te(6) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(3), one V(1), and one Te(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(4), one V(2), and one Te(4) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one V(1), and one Te(3) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one V(2), and one Te(4) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Te(1), and one Te(5) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(6), one Li(8), one Te(2), and one Te(6) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Te(1), and one Te(5) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Li(6), one Li(8), one Te(2), and one Te(6) atom. In the seventeenth O site, O(17) is bonded to one Li(5), one Li(7), one V(2), and one Te(4) atom to form distorted OLi2VTe trigonal pyramids that share  a cornercorner with one O(22)Li2Te2 tetrahedra,  a cornercorner with one O(24)Li2Te2 trigonal pyramid,  a cornercorner with one O(1)Li2VTe trigonal pyramid, corners with two equivalent O(19)Li2VTe trigonal pyramids,  an edgeedge with one O(1)Li2VTe trigonal pyramid, and  an edgeedge with one O(19)Li2VTe trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Li(6), one Li(8), one V(1), and one Te(3) atom to form distorted OLi2VTe trigonal pyramids that share  a cornercorner with one O(21)Li2Te2 tetrahedra,  a cornercorner with one O(23)Li2Te2 tetrahedra,  a cornercorner with one O(2)Li2VTe trigonal pyramid, corners with two equivalent O(20)Li2VTe trigonal pyramids,  an edgeedge with one O(2)Li2VTe trigonal pyramid, and  an edgeedge with one O(20)Li2VTe trigonal pyramid. In the nineteenth O site, O(19) is bonded to one Li(5), one Li(7), one V(2), and one Te(4) atom to form distorted OLi2VTe trigonal pyramids that share  a cornercorner with one O(22)Li2Te2 tetrahedra,  a cornercorner with one O(24)Li2Te2 trigonal pyramid,  a cornercorner with one O(1)Li2VTe trigonal pyramid, corners with two equivalent O(17)Li2VTe trigonal pyramids,  an edgeedge with one O(1)Li2VTe trigonal pyramid, and  an edgeedge with one O(17)Li2VTe trigonal pyramid. In the twentieth O site, O(20) is bonded to one Li(6), one Li(8), one V(1), and one Te(3) atom to form distorted OLi2VTe trigonal pyramids that share  a cornercorner with one O(21)Li2Te2 tetrahedra,  a cornercorner with one O(23)Li2Te2 tetrahedra,  a cornercorner with one O(2)Li2VTe trigonal pyramid, corners with two equivalent O(18)Li2VTe trigonal pyramids,  an edgeedge with one O(18)Li2VTe trigonal pyramid, and  an edgeedge with one O(2)Li2VTe trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(3), one Te(3), and one Te(5) atom to form distorted OLi2Te2 tetrahedra that share corners with four equivalent O(23)Li2Te2 tetrahedra,  a cornercorner with one O(18)Li2VTe trigonal pyramid, and  a cornercorner with one O(20)Li2VTe trigonal pyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(4), one Te(4), and one Te(6) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(17)Li2VTe trigonal pyramid,  a cornercorner with one O(19)Li2VTe trigonal pyramid, and corners with four equivalent O(24)Li2Te2 trigonal pyramids. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(3), one Te(3), and one Te(5) atom to form distorted OLi2Te2 tetrahedra that share corners with four equivalent O(21)Li2Te2 tetrahedra,  a cornercorner with one O(18)Li2VTe trigonal pyramid, and  a cornercorner with one O(20)Li2VTe trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(4), one Te(4), and one Te(6) atom to form distorted OLi2Te2 trigonal pyramids that share corners with four equivalent O(22)Li2Te2 tetrahedra,  a cornercorner with one O(17)Li2VTe trigonal pyramid, and  a cornercorner with one O(19)Li2VTe trigonal pyramid. is represented by the CIF file [CIF]
data_Li4V(TeO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.052
_cell_length_b   5.218
_cell_length_c   8.796
_cell_angle_alpha   89.362
_cell_angle_beta   89.966
_cell_angle_gamma   86.378
_symmetry_Int_Tables_number   1
_cell_volume   231.389
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.004  0.999  0.696  1.0
  Li  Li1  1  0.503  0.999  0.869  1.0
  Li  Li2  1  0.988  0.474  0.299  1.0
  Li  Li3  1  0.501  0.494  0.173  1.0
  O  O4  1  0.736  0.153  0.252  1.0
  O  O5  1  0.261  0.873  0.247  1.0
  O  O6  1  0.715  0.149  0.563  1.0
  O  O7  1  0.282  0.855  0.556  1.0
  O  O8  1  0.795  0.193  0.947  1.0
  O  O9  1  0.208  0.805  0.940  1.0
  O  O10  1  0.298  0.336  0.420  1.0
  O  O11  1  0.702  0.672  0.418  1.0
  O  O12  1  0.193  0.325  0.095  1.0
  O  O13  1  0.799  0.689  0.089  1.0
  O  O14  1  0.222  0.311  0.776  1.0
  O  O15  1  0.784  0.680  0.774  1.0
  Te  Te16  1  0.504  0.006  0.399  1.0
  Te  Te17  1  0.005  0.497  0.924  1.0
  Te  Te18  1  0.499  0.502  0.601  1.0
  V  V19  1  0.001  0.988  0.104  1.0
[/CIF]
.
The material described by Li4V(TeO4)3 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(11), one O(21), one O(23), one O(5), and one O(7) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(12), one O(22), one O(24), one O(6), and one O(8) atom. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(21), one O(23), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(12), one O(22), and one O(24) atom. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(15), one O(17), one O(19), and one O(3) atom. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(18), one O(2), one O(20), and one O(4) atom. In the seventh Li site, Li(7) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(15), one O(17), one O(19), and one O(3) atom. In the eighth Li site, Li(8) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(18), one O(2), one O(20), and one O(4) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(18), one O(2), one O(20), one O(4), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and edges with two equivalent Te(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(12), one O(17), one O(19), and one O(3) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and edges with two equivalent Te(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. There are six inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(13), one O(15), one O(3), one O(5), and one O(7) atom to form TeO6 octahedra that share corners with two equivalent V(2)O6 octahedra and edges with two equivalent Te(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. In the second Te site, Te(2) is bonded to one O(14), one O(16), one O(2), one O(4), one O(6), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra and edges with two equivalent Te(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. In the third Te site, Te(3) is bonded to one O(11), one O(18), one O(20), one O(21), one O(23), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Te(5)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. In the fourth Te site, Te(4) is bonded to one O(10), one O(12), one O(17), one O(19), one O(22), and one O(24) atom to form TeO6 octahedra that share corners with two equivalent Te(6)O6 octahedra and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-56°. In the fifth Te site, Te(5) is bonded to one O(13), one O(15), one O(21), one O(23), one O(5), and one O(7) atom to form a mixture of edge and corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. In the sixth Te site, Te(6) is bonded to one O(14), one O(16), one O(22), one O(24), one O(6), and one O(8) atom to form a mixture of edge and corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 53-56°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(5), one Li(7), one V(2), and one Te(1) atom to form a mixture of distorted edge and corner-sharing OLi2VTe trigonal pyramids. In the second O site, O(2) is bonded to one Li(6), one Li(8), one V(1), and one Te(2) atom to form a mixture of distorted edge and corner-sharing OLi2VTe trigonal pyramids. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one V(2), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(6), one Li(8), one V(1), and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one Te(1), and one Te(5) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one Te(2), and one Te(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Li(1), one Te(1), and one Te(5) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(2), one Te(2), and one Te(6) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(3), one V(1), and one Te(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(4), one V(2), and one Te(4) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one V(1), and one Te(3) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one V(2), and one Te(4) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Te(1), and one Te(5) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(6), one Li(8), one Te(2), and one Te(6) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Te(1), and one Te(5) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Li(6), one Li(8), one Te(2), and one Te(6) atom. In the seventeenth O site, O(17) is bonded to one Li(5), one Li(7), one V(2), and one Te(4) atom to form distorted OLi2VTe trigonal pyramids that share  a cornercorner with one O(22)Li2Te2 tetrahedra,  a cornercorner with one O(24)Li2Te2 trigonal pyramid,  a cornercorner with one O(1)Li2VTe trigonal pyramid, corners with two equivalent O(19)Li2VTe trigonal pyramids,  an edgeedge with one O(1)Li2VTe trigonal pyramid, and  an edgeedge with one O(19)Li2VTe trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Li(6), one Li(8), one V(1), and one Te(3) atom to form distorted OLi2VTe trigonal pyramids that share  a cornercorner with one O(21)Li2Te2 tetrahedra,  a cornercorner with one O(23)Li2Te2 tetrahedra,  a cornercorner with one O(2)Li2VTe trigonal pyramid, corners with two equivalent O(20)Li2VTe trigonal pyramids,  an edgeedge with one O(2)Li2VTe trigonal pyramid, and  an edgeedge with one O(20)Li2VTe trigonal pyramid. In the nineteenth O site, O(19) is bonded to one Li(5), one Li(7), one V(2), and one Te(4) atom to form distorted OLi2VTe trigonal pyramids that share  a cornercorner with one O(22)Li2Te2 tetrahedra,  a cornercorner with one O(24)Li2Te2 trigonal pyramid,  a cornercorner with one O(1)Li2VTe trigonal pyramid, corners with two equivalent O(17)Li2VTe trigonal pyramids,  an edgeedge with one O(1)Li2VTe trigonal pyramid, and  an edgeedge with one O(17)Li2VTe trigonal pyramid. In the twentieth O site, O(20) is bonded to one Li(6), one Li(8), one V(1), and one Te(3) atom to form distorted OLi2VTe trigonal pyramids that share  a cornercorner with one O(21)Li2Te2 tetrahedra,  a cornercorner with one O(23)Li2Te2 tetrahedra,  a cornercorner with one O(2)Li2VTe trigonal pyramid, corners with two equivalent O(18)Li2VTe trigonal pyramids,  an edgeedge with one O(18)Li2VTe trigonal pyramid, and  an edgeedge with one O(2)Li2VTe trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(3), one Te(3), and one Te(5) atom to form distorted OLi2Te2 tetrahedra that share corners with four equivalent O(23)Li2Te2 tetrahedra,  a cornercorner with one O(18)Li2VTe trigonal pyramid, and  a cornercorner with one O(20)Li2VTe trigonal pyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(4), one Te(4), and one Te(6) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(17)Li2VTe trigonal pyramid,  a cornercorner with one O(19)Li2VTe trigonal pyramid, and corners with four equivalent O(24)Li2Te2 trigonal pyramids. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(3), one Te(3), and one Te(5) atom to form distorted OLi2Te2 tetrahedra that share corners with four equivalent O(21)Li2Te2 tetrahedra,  a cornercorner with one O(18)Li2VTe trigonal pyramid, and  a cornercorner with one O(20)Li2VTe trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(4), one Te(4), and one Te(6) atom to form distorted OLi2Te2 trigonal pyramids that share corners with four equivalent O(22)Li2Te2 tetrahedra,  a cornercorner with one O(17)Li2VTe trigonal pyramid, and  a cornercorner with one O(19)Li2VTe trigonal pyramid. is represented by the CIF file [CIF]
data_Li4V(TeO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.052
_cell_length_b   5.218
_cell_length_c   8.796
_cell_angle_alpha   89.362
_cell_angle_beta   89.966
_cell_angle_gamma   86.378
_symmetry_Int_Tables_number   1
_cell_volume   231.389
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.004  0.999  0.696  1.0
  Li  Li1  1  0.503  0.999  0.869  1.0
  Li  Li2  1  0.988  0.474  0.299  1.0
  Li  Li3  1  0.501  0.494  0.173  1.0
  O  O4  1  0.736  0.153  0.252  1.0
  O  O5  1  0.261  0.873  0.247  1.0
  O  O6  1  0.715  0.149  0.563  1.0
  O  O7  1  0.282  0.855  0.556  1.0
  O  O8  1  0.795  0.193  0.947  1.0
  O  O9  1  0.208  0.805  0.940  1.0
  O  O10  1  0.298  0.336  0.420  1.0
  O  O11  1  0.702  0.672  0.418  1.0
  O  O12  1  0.193  0.325  0.095  1.0
  O  O13  1  0.799  0.689  0.089  1.0
  O  O14  1  0.222  0.311  0.776  1.0
  O  O15  1  0.784  0.680  0.774  1.0
  Te  Te16  1  0.504  0.006  0.399  1.0
  Te  Te17  1  0.005  0.497  0.924  1.0
  Te  Te18  1  0.499  0.502  0.601  1.0
  V  V19  1  0.001  0.988  0.104  1.0
[/CIF]
.