The structure described by Fe4CoZnO8 is Spinel-derived structured and crystallizes in the cubic F-43m space group. Fe(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form FeO6 octahedra that share corners with three equivalent Co(1)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra, and edges with six equivalent Fe(1)O6 octahedra. Co(1) is bonded to four equivalent O(2) atoms to form CoO4 tetrahedra that share corners with twelve equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. Zn(1) is bonded to four equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with twelve equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Fe(1) and one Zn(1) atom to form distorted OZnFe3 trigonal pyramids that share corners with three equivalent O(1)ZnFe3 trigonal pyramids, corners with nine equivalent O(2)Fe3Co trigonal pyramids, and edges with three equivalent O(1)ZnFe3 trigonal pyramids. In the second O site, O(2) is bonded to three equivalent Fe(1) and one Co(1) atom to form distorted OFe3Co trigonal pyramids that share corners with three equivalent O(2)Fe3Co trigonal pyramids, corners with nine equivalent O(1)ZnFe3 trigonal pyramids, and edges with three equivalent O(2)Fe3Co trigonal pyramids. is represented by the CIF file [CIF]
data_ZnFe4CoO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.041
_cell_length_b   6.041
_cell_length_c   6.041
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   155.908
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  Fe  Fe1  1  0.625  0.625  0.125  1.0
  Fe  Fe2  1  0.625  0.125  0.625  1.0
  Fe  Fe3  1  0.125  0.625  0.625  1.0
  Fe  Fe4  1  0.625  0.625  0.625  1.0
  Co  Co5  1  0.250  0.250  0.250  1.0
  O  O6  1  0.865  0.865  0.406  1.0
  O  O7  1  0.865  0.406  0.865  1.0
  O  O8  1  0.406  0.865  0.865  1.0
  O  O9  1  0.865  0.865  0.865  1.0
  O  O10  1  0.385  0.385  0.844  1.0
  O  O11  1  0.385  0.844  0.385  1.0
  O  O12  1  0.844  0.385  0.385  1.0
  O  O13  1  0.385  0.385  0.385  1.0
[/CIF]
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The structure described by Fe4CoZnO8 is Spinel-derived structured and crystallizes in the cubic F-43m space group. Fe(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form FeO6 octahedra that share corners with three equivalent Co(1)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra, and edges with six equivalent Fe(1)O6 octahedra. Co(1) is bonded to four equivalent O(2) atoms to form CoO4 tetrahedra that share corners with twelve equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. Zn(1) is bonded to four equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with twelve equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Fe(1) and one Zn(1) atom to form distorted OZnFe3 trigonal pyramids that share corners with three equivalent O(1)ZnFe3 trigonal pyramids, corners with nine equivalent O(2)Fe3Co trigonal pyramids, and edges with three equivalent O(1)ZnFe3 trigonal pyramids. In the second O site, O(2) is bonded to three equivalent Fe(1) and one Co(1) atom to form distorted OFe3Co trigonal pyramids that share corners with three equivalent O(2)Fe3Co trigonal pyramids, corners with nine equivalent O(1)ZnFe3 trigonal pyramids, and edges with three equivalent O(2)Fe3Co trigonal pyramids. is represented by the CIF file [CIF]
data_ZnFe4CoO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.041
_cell_length_b   6.041
_cell_length_c   6.041
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   155.908
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  Fe  Fe1  1  0.625  0.625  0.125  1.0
  Fe  Fe2  1  0.625  0.125  0.625  1.0
  Fe  Fe3  1  0.125  0.625  0.625  1.0
  Fe  Fe4  1  0.625  0.625  0.625  1.0
  Co  Co5  1  0.250  0.250  0.250  1.0
  O  O6  1  0.865  0.865  0.406  1.0
  O  O7  1  0.865  0.406  0.865  1.0
  O  O8  1  0.406  0.865  0.865  1.0
  O  O9  1  0.865  0.865  0.865  1.0
  O  O10  1  0.385  0.385  0.844  1.0
  O  O11  1  0.385  0.844  0.385  1.0
  O  O12  1  0.844  0.385  0.385  1.0
  O  O13  1  0.385  0.385  0.385  1.0
[/CIF]
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