The compound described by (Dy(NO4)3)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trioxidane molecules and two Dy(NO4)3 clusters. In each Dy(NO4)3 cluster, Dy(1) is bonded in a distorted hexagonal pyramidal geometry to one O(10), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(2), one O(7), and one O(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(13), one O(4), and one O(6) atom. There are twelve inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one O(12) and one O(3) atom. In the third O site, O(2) is bonded in an L-shaped geometry to one Dy(1) and one N(2) atom. In the fourth O site, O(3) is bonded in a water-like geometry to one Dy(1) and one O(1) atom. In the fifth O site, O(4) is bonded in an L-shaped geometry to one Dy(1) and one N(3) atom. In the sixth O site, O(5) is bonded in an L-shaped geometry to one Dy(1) and one N(1) atom. In the seventh O site, O(6) is bonded in an L-shaped geometry to one Dy(1) and one N(3) atom. In the eighth O site, O(7) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Dy(1) and one N(2) atom. In the tenth O site, O(10) is bonded in an L-shaped geometry to one Dy(1) and one N(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one N(1) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.977
_cell_length_b   9.219
_cell_length_c   11.304
_cell_angle_alpha   68.146
_cell_angle_beta   89.177
_cell_angle_gamma   64.703
_symmetry_Int_Tables_number   1
_cell_volume   601.048
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.874  0.643  0.722  1.0
  Dy  Dy1  1  0.126  0.357  0.278  1.0
  N  N2  1  0.946  0.832  0.485  1.0
  N  N3  1  0.054  0.168  0.515  1.0
  N  N4  1  0.861  0.718  0.200  1.0
  N  N5  1  0.139  0.282  0.800  1.0
  N  N6  1  0.894  0.851  0.842  1.0
  N  N7  1  0.106  0.149  0.158  1.0
  O  O8  1  0.554  0.636  0.532  1.0
  O  O9  1  0.446  0.364  0.468  1.0
  O  O10  1  0.015  0.376  0.688  1.0
  O  O11  1  0.985  0.624  0.312  1.0
  O  O12  1  0.530  0.685  0.631  1.0
  O  O13  1  0.470  0.315  0.369  1.0
  O  O14  1  0.717  0.891  0.773  1.0
  O  O15  1  0.283  0.109  0.227  1.0
  O  O16  1  0.098  0.694  0.577  1.0
  O  O17  1  0.902  0.306  0.423  1.0
  O  O18  1  0.052  0.698  0.858  1.0
  O  O19  1  0.948  0.302  0.142  1.0
  O  O20  1  0.731  0.871  0.165  1.0
  O  O21  1  0.269  0.129  0.835  1.0
  O  O22  1  0.535  0.640  0.985  1.0
  O  O23  1  0.465  0.360  0.015  1.0
  O  O24  1  0.113  0.369  0.873  1.0
  O  O25  1  0.887  0.631  0.127  1.0
  O  O26  1  0.754  0.863  0.507  1.0
  O  O27  1  0.246  0.137  0.493  1.0
  O  O28  1  0.985  0.923  0.388  1.0
  O  O29  1  0.015  0.077  0.612  1.0
  O  O30  1  0.577  0.256  0.571  1.0
  O  O31  1  0.423  0.744  0.429  1.0
  O  O32  1  0.913  0.945  0.888  1.0
  O  O33  1  0.087  0.055  0.112  1.0
  O  O34  1  0.654  0.366  0.858  1.0
  O  O35  1  0.346  0.634  0.142  1.0
  O  O36  1  0.616  0.276  0.966  1.0
  O  O37  1  0.384  0.724  0.034  1.0
[/CIF]
.
The compound described by (Dy(NO4)3)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trioxidane molecules and two Dy(NO4)3 clusters. In each Dy(NO4)3 cluster, Dy(1) is bonded in a distorted hexagonal pyramidal geometry to one O(10), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(2), one O(7), and one O(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(13), one O(4), and one O(6) atom. There are twelve inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one O(12) and one O(3) atom. In the third O site, O(2) is bonded in an L-shaped geometry to one Dy(1) and one N(2) atom. In the fourth O site, O(3) is bonded in a water-like geometry to one Dy(1) and one O(1) atom. In the fifth O site, O(4) is bonded in an L-shaped geometry to one Dy(1) and one N(3) atom. In the sixth O site, O(5) is bonded in an L-shaped geometry to one Dy(1) and one N(1) atom. In the seventh O site, O(6) is bonded in an L-shaped geometry to one Dy(1) and one N(3) atom. In the eighth O site, O(7) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Dy(1) and one N(2) atom. In the tenth O site, O(10) is bonded in an L-shaped geometry to one Dy(1) and one N(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one N(1) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.977
_cell_length_b   9.219
_cell_length_c   11.304
_cell_angle_alpha   68.146
_cell_angle_beta   89.177
_cell_angle_gamma   64.703
_symmetry_Int_Tables_number   1
_cell_volume   601.048
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.874  0.643  0.722  1.0
  Dy  Dy1  1  0.126  0.357  0.278  1.0
  N  N2  1  0.946  0.832  0.485  1.0
  N  N3  1  0.054  0.168  0.515  1.0
  N  N4  1  0.861  0.718  0.200  1.0
  N  N5  1  0.139  0.282  0.800  1.0
  N  N6  1  0.894  0.851  0.842  1.0
  N  N7  1  0.106  0.149  0.158  1.0
  O  O8  1  0.554  0.636  0.532  1.0
  O  O9  1  0.446  0.364  0.468  1.0
  O  O10  1  0.015  0.376  0.688  1.0
  O  O11  1  0.985  0.624  0.312  1.0
  O  O12  1  0.530  0.685  0.631  1.0
  O  O13  1  0.470  0.315  0.369  1.0
  O  O14  1  0.717  0.891  0.773  1.0
  O  O15  1  0.283  0.109  0.227  1.0
  O  O16  1  0.098  0.694  0.577  1.0
  O  O17  1  0.902  0.306  0.423  1.0
  O  O18  1  0.052  0.698  0.858  1.0
  O  O19  1  0.948  0.302  0.142  1.0
  O  O20  1  0.731  0.871  0.165  1.0
  O  O21  1  0.269  0.129  0.835  1.0
  O  O22  1  0.535  0.640  0.985  1.0
  O  O23  1  0.465  0.360  0.015  1.0
  O  O24  1  0.113  0.369  0.873  1.0
  O  O25  1  0.887  0.631  0.127  1.0
  O  O26  1  0.754  0.863  0.507  1.0
  O  O27  1  0.246  0.137  0.493  1.0
  O  O28  1  0.985  0.923  0.388  1.0
  O  O29  1  0.015  0.077  0.612  1.0
  O  O30  1  0.577  0.256  0.571  1.0
  O  O31  1  0.423  0.744  0.429  1.0
  O  O32  1  0.913  0.945  0.888  1.0
  O  O33  1  0.087  0.055  0.112  1.0
  O  O34  1  0.654  0.366  0.858  1.0
  O  O35  1  0.346  0.634  0.142  1.0
  O  O36  1  0.616  0.276  0.966  1.0
  O  O37  1  0.384  0.724  0.034  1.0
[/CIF]
.