The compound described by Li8N2Te crystallizes in the tetragonal I4_1md space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted bent 120 degrees geometry to two equivalent N(1) and two equivalent Te(1) atoms. In the second Li site, Li(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent N(1) atoms. In the third Li site, Li(3) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms. In the fourth Li site, Li(4) is bonded in a 2-coordinate geometry to two equivalent N(1) and one Te(1) atom. N(1) is bonded in a 9-coordinate geometry to one Li(3), one Li(4), three equivalent Li(2), and four equivalent Li(1) atoms. Te(1) is bonded in a 9-coordinate geometry to one Li(4) and eight equivalent Li(1) atoms. is represented by the CIF card [CIF]
data_Li8TeN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.236
_cell_length_b   7.236
_cell_length_c   7.236
_cell_angle_alpha   120.166
_cell_angle_beta   120.166
_cell_angle_gamma   89.714
_symmetry_Int_Tables_number   1
_cell_volume   267.244
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.917  0.486  0.058  1.0
  Li  Li1  1  0.428  0.859  0.942  1.0
  Li  Li2  1  0.236  0.167  0.558  1.0
  Li  Li3  1  0.609  0.678  0.442  1.0
  Li  Li4  1  0.917  0.859  0.431  1.0
  Li  Li5  1  0.428  0.486  0.569  1.0
  Li  Li6  1  0.236  0.678  0.069  1.0
  Li  Li7  1  0.609  0.167  0.931  1.0
  Li  Li8  1  0.059  0.404  0.345  1.0
  Li  Li9  1  0.059  0.713  0.655  1.0
  Li  Li10  1  0.154  0.309  0.845  1.0
  Li  Li11  1  0.463  0.309  0.155  1.0
  Li  Li12  1  0.291  0.791  0.500  1.0
  Li  Li13  1  0.541  0.541  0.000  1.0
  Li  Li14  1  0.873  0.373  0.500  1.0
  Li  Li15  1  0.123  0.123  0.000  1.0
  Te  Te16  1  0.853  0.853  0.000  1.0
  Te  Te17  1  0.603  0.103  0.500  1.0
  N  N18  1  0.250  0.481  0.231  1.0
  N  N19  1  0.250  0.019  0.769  1.0
  N  N20  1  0.231  0.500  0.731  1.0
  N  N21  1  0.769  0.500  0.269  1.0
[/CIF]
.
The compound described by Li8N2Te crystallizes in the tetragonal I4_1md space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted bent 120 degrees geometry to two equivalent N(1) and two equivalent Te(1) atoms. In the second Li site, Li(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent N(1) atoms. In the third Li site, Li(3) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms. In the fourth Li site, Li(4) is bonded in a 2-coordinate geometry to two equivalent N(1) and one Te(1) atom. N(1) is bonded in a 9-coordinate geometry to one Li(3), one Li(4), three equivalent Li(2), and four equivalent Li(1) atoms. Te(1) is bonded in a 9-coordinate geometry to one Li(4) and eight equivalent Li(1) atoms. is represented by the CIF card [CIF]
data_Li8TeN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.236
_cell_length_b   7.236
_cell_length_c   7.236
_cell_angle_alpha   120.166
_cell_angle_beta   120.166
_cell_angle_gamma   89.714
_symmetry_Int_Tables_number   1
_cell_volume   267.244
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.917  0.486  0.058  1.0
  Li  Li1  1  0.428  0.859  0.942  1.0
  Li  Li2  1  0.236  0.167  0.558  1.0
  Li  Li3  1  0.609  0.678  0.442  1.0
  Li  Li4  1  0.917  0.859  0.431  1.0
  Li  Li5  1  0.428  0.486  0.569  1.0
  Li  Li6  1  0.236  0.678  0.069  1.0
  Li  Li7  1  0.609  0.167  0.931  1.0
  Li  Li8  1  0.059  0.404  0.345  1.0
  Li  Li9  1  0.059  0.713  0.655  1.0
  Li  Li10  1  0.154  0.309  0.845  1.0
  Li  Li11  1  0.463  0.309  0.155  1.0
  Li  Li12  1  0.291  0.791  0.500  1.0
  Li  Li13  1  0.541  0.541  0.000  1.0
  Li  Li14  1  0.873  0.373  0.500  1.0
  Li  Li15  1  0.123  0.123  0.000  1.0
  Te  Te16  1  0.853  0.853  0.000  1.0
  Te  Te17  1  0.603  0.103  0.500  1.0
  N  N18  1  0.250  0.481  0.231  1.0
  N  N19  1  0.250  0.019  0.769  1.0
  N  N20  1  0.231  0.500  0.731  1.0
  N  N21  1  0.769  0.500  0.269  1.0
[/CIF]
.