The material described by NaY(C2O5)2 crystallizes in the monoclinic P2_1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(7) atom. Y(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one O(3) and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one O(5) and one O(6) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(10), one O(7), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Y(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Y(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Na(1), one Y(1), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one C(3) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Na(1) and one C(4) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Y(1) and one C(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Y(1) atom. In the tenth O site, O(10) is bonded in a distorted L-shaped geometry to one Na(1) and one C(4) atom. is represented by the CIF card [CIF]
data_NaY(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.880
_cell_length_b   6.798
_cell_length_c   6.818
_cell_angle_alpha   78.316
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   539.181
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.247  0.309  0.987  1.0
  Na  Na1  1  0.747  0.691  0.013  1.0
  Y  Y2  1  0.985  0.171  0.607  1.0
  Y  Y3  1  0.485  0.829  0.393  1.0
  C  C4  1  0.084  0.633  0.745  1.0
  C  C5  1  0.584  0.367  0.255  1.0
  C  C6  1  0.008  0.958  0.103  1.0
  C  C7  1  0.508  0.042  0.897  1.0
  C  C8  1  0.275  0.155  0.525  1.0
  C  C9  1  0.775  0.845  0.475  1.0
  C  C10  1  0.778  0.385  0.841  1.0
  C  C11  1  0.278  0.615  0.159  1.0
  O  O12  1  0.082  0.456  0.773  1.0
  O  O13  1  0.582  0.544  0.227  1.0
  O  O14  1  0.074  0.807  0.692  1.0
  O  O15  1  0.574  0.193  0.308  1.0
  O  O16  1  0.924  0.862  0.129  1.0
  O  O17  1  0.424  0.138  0.871  1.0
  O  O18  1  0.095  0.034  0.056  1.0
  O  O19  1  0.595  0.966  0.944  1.0
  O  O20  1  0.203  0.179  0.638  1.0
  O  O21  1  0.703  0.821  0.362  1.0
  O  O22  1  0.349  0.097  0.438  1.0
  O  O23  1  0.849  0.903  0.562  1.0
  O  O24  1  0.759  0.562  0.733  1.0
  O  O25  1  0.259  0.438  0.267  1.0
  O  O26  1  0.840  0.256  0.766  1.0
  O  O27  1  0.340  0.744  0.234  1.0
  O  O28  1  0.981  0.246  0.325  1.0
  O  O29  1  0.481  0.754  0.675  1.0
  O  O30  1  0.741  0.335  0.022  1.0
  O  O31  1  0.241  0.665  0.978  1.0
[/CIF]
.
The material described by NaY(C2O5)2 crystallizes in the monoclinic P2_1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(7) atom. Y(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one O(3) and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one O(5) and one O(6) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(10), one O(7), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Y(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Y(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Na(1), one Y(1), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one C(3) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Na(1) and one C(4) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Y(1) and one C(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Y(1) atom. In the tenth O site, O(10) is bonded in a distorted L-shaped geometry to one Na(1) and one C(4) atom. is represented by the CIF card [CIF]
data_NaY(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.880
_cell_length_b   6.798
_cell_length_c   6.818
_cell_angle_alpha   78.316
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   539.181
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.247  0.309  0.987  1.0
  Na  Na1  1  0.747  0.691  0.013  1.0
  Y  Y2  1  0.985  0.171  0.607  1.0
  Y  Y3  1  0.485  0.829  0.393  1.0
  C  C4  1  0.084  0.633  0.745  1.0
  C  C5  1  0.584  0.367  0.255  1.0
  C  C6  1  0.008  0.958  0.103  1.0
  C  C7  1  0.508  0.042  0.897  1.0
  C  C8  1  0.275  0.155  0.525  1.0
  C  C9  1  0.775  0.845  0.475  1.0
  C  C10  1  0.778  0.385  0.841  1.0
  C  C11  1  0.278  0.615  0.159  1.0
  O  O12  1  0.082  0.456  0.773  1.0
  O  O13  1  0.582  0.544  0.227  1.0
  O  O14  1  0.074  0.807  0.692  1.0
  O  O15  1  0.574  0.193  0.308  1.0
  O  O16  1  0.924  0.862  0.129  1.0
  O  O17  1  0.424  0.138  0.871  1.0
  O  O18  1  0.095  0.034  0.056  1.0
  O  O19  1  0.595  0.966  0.944  1.0
  O  O20  1  0.203  0.179  0.638  1.0
  O  O21  1  0.703  0.821  0.362  1.0
  O  O22  1  0.349  0.097  0.438  1.0
  O  O23  1  0.849  0.903  0.562  1.0
  O  O24  1  0.759  0.562  0.733  1.0
  O  O25  1  0.259  0.438  0.267  1.0
  O  O26  1  0.840  0.256  0.766  1.0
  O  O27  1  0.340  0.744  0.234  1.0
  O  O28  1  0.981  0.246  0.325  1.0
  O  O29  1  0.481  0.754  0.675  1.0
  O  O30  1  0.741  0.335  0.022  1.0
  O  O31  1  0.241  0.665  0.978  1.0
[/CIF]
.