The compound described by MgPtZnC4H16(N2O5)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two water molecules and one MgPtZnC4H16(N2O5)2 cluster. In the MgPtZnC4H16(N2O5)2 cluster, Mg(1) is bonded in a distorted trigonal bipyramidal geometry to one Pt(1), one N(3), one N(4), one O(7), and one O(8) atom. Pt(1) is bonded in a T-shaped geometry to one Mg(1), one N(1), and one N(2) atom. Zn(1) is bonded in an octahedral geometry to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(9) atom. There are two inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. In the second C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1); one H(5,6); and two equivalent H(1,2,9,10) atoms. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1); one H(5,6); and two equivalent H(1,2,9,10) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one H(11), one H(3), and one H(7) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1); one H(8); and two equivalent H(4,12) atoms. There are eleven inequivalent H sites. In the first H site, H(1,2,9,10) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(4,12) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one O(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one O(10) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3,4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3,4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(1,2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(1,2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Mg(1) and one C(3,4) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Mg(1) and one C(3,4) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Zn(1), one H(13), and one H(16) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Zn(1), one H(14), and one H(15) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgZnH20PtC4(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.566
_cell_length_b   7.988
_cell_length_c   9.171
_cell_angle_alpha   115.848
_cell_angle_beta   114.335
_cell_angle_gamma   90.140
_symmetry_Int_Tables_number   1
_cell_volume   443.147
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.392  0.891  0.783  1.0
  Zn  Zn1  1  0.008  0.508  0.016  1.0
  H  H2  1  0.454  0.747  0.128  1.0
  H  H3  1  0.675  0.383  0.130  1.0
  H  H4  1  0.292  0.235  0.804  1.0
  H  H5  1  0.510  0.566  0.800  1.0
  H  H6  1  0.657  0.889  0.311  1.0
  H  H7  1  0.656  0.424  0.313  1.0
  H  H8  1  0.302  0.114  0.614  1.0
  H  H9  1  0.309  0.500  0.613  1.0
  H  H10  1  0.675  0.748  0.128  1.0
  H  H11  1  0.454  0.382  0.130  1.0
  H  H12  1  0.508  0.234  0.798  1.0
  H  H13  1  0.291  0.564  0.798  1.0
  H  H14  1  0.948  0.789  0.898  1.0
  H  H15  1  0.950  0.109  0.898  1.0
  H  H16  1  0.059  0.210  0.116  1.0
  H  H17  1  0.056  0.907  0.115  1.0
  H  H18  1  0.924  0.818  0.635  1.0
  H  H19  1  0.712  0.818  0.635  1.0
  H  H20  1  0.292  0.184  0.370  1.0
  H  H21  1  0.078  0.184  0.370  1.0
  Pt  Pt22  1  0.568  0.068  0.135  1.0
  C  C23  1  0.927  0.321  0.644  1.0
  C  C24  1  0.717  0.321  0.644  1.0
  C  C25  1  0.301  0.698  0.395  1.0
  C  C26  1  0.094  0.697  0.395  1.0
  N  N27  1  0.586  0.832  0.172  1.0
  N  N28  1  0.587  0.342  0.174  1.0
  N  N29  1  0.373  0.148  0.749  1.0
  N  N30  1  0.375  0.600  0.748  1.0
  O  O31  1  0.080  0.403  0.803  1.0
  O  O32  1  0.723  0.399  0.802  1.0
  O  O33  1  0.301  0.622  0.241  1.0
  O  O34  1  0.941  0.620  0.241  1.0
  O  O35  1  0.933  0.245  0.495  1.0
  O  O36  1  0.562  0.247  0.495  1.0
  O  O37  1  0.453  0.775  0.550  1.0
  O  O38  1  0.097  0.774  0.550  1.0
  O  O39  1  0.002  0.776  0.010  1.0
  O  O40  1  0.008  0.235  0.010  1.0
  O  O41  1  0.858  0.858  0.715  1.0
  O  O42  1  0.146  0.146  0.292  1.0
[/CIF]
.
The compound described by MgPtZnC4H16(N2O5)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two water molecules and one MgPtZnC4H16(N2O5)2 cluster. In the MgPtZnC4H16(N2O5)2 cluster, Mg(1) is bonded in a distorted trigonal bipyramidal geometry to one Pt(1), one N(3), one N(4), one O(7), and one O(8) atom. Pt(1) is bonded in a T-shaped geometry to one Mg(1), one N(1), and one N(2) atom. Zn(1) is bonded in an octahedral geometry to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(9) atom. There are two inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. In the second C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1); one H(5,6); and two equivalent H(1,2,9,10) atoms. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1); one H(5,6); and two equivalent H(1,2,9,10) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one H(11), one H(3), and one H(7) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1); one H(8); and two equivalent H(4,12) atoms. There are eleven inequivalent H sites. In the first H site, H(1,2,9,10) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(4,12) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one O(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one O(10) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3,4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3,4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(1,2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(1,2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Mg(1) and one C(3,4) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Mg(1) and one C(3,4) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Zn(1), one H(13), and one H(16) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Zn(1), one H(14), and one H(15) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgZnH20PtC4(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.566
_cell_length_b   7.988
_cell_length_c   9.171
_cell_angle_alpha   115.848
_cell_angle_beta   114.335
_cell_angle_gamma   90.140
_symmetry_Int_Tables_number   1
_cell_volume   443.147
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.392  0.891  0.783  1.0
  Zn  Zn1  1  0.008  0.508  0.016  1.0
  H  H2  1  0.454  0.747  0.128  1.0
  H  H3  1  0.675  0.383  0.130  1.0
  H  H4  1  0.292  0.235  0.804  1.0
  H  H5  1  0.510  0.566  0.800  1.0
  H  H6  1  0.657  0.889  0.311  1.0
  H  H7  1  0.656  0.424  0.313  1.0
  H  H8  1  0.302  0.114  0.614  1.0
  H  H9  1  0.309  0.500  0.613  1.0
  H  H10  1  0.675  0.748  0.128  1.0
  H  H11  1  0.454  0.382  0.130  1.0
  H  H12  1  0.508  0.234  0.798  1.0
  H  H13  1  0.291  0.564  0.798  1.0
  H  H14  1  0.948  0.789  0.898  1.0
  H  H15  1  0.950  0.109  0.898  1.0
  H  H16  1  0.059  0.210  0.116  1.0
  H  H17  1  0.056  0.907  0.115  1.0
  H  H18  1  0.924  0.818  0.635  1.0
  H  H19  1  0.712  0.818  0.635  1.0
  H  H20  1  0.292  0.184  0.370  1.0
  H  H21  1  0.078  0.184  0.370  1.0
  Pt  Pt22  1  0.568  0.068  0.135  1.0
  C  C23  1  0.927  0.321  0.644  1.0
  C  C24  1  0.717  0.321  0.644  1.0
  C  C25  1  0.301  0.698  0.395  1.0
  C  C26  1  0.094  0.697  0.395  1.0
  N  N27  1  0.586  0.832  0.172  1.0
  N  N28  1  0.587  0.342  0.174  1.0
  N  N29  1  0.373  0.148  0.749  1.0
  N  N30  1  0.375  0.600  0.748  1.0
  O  O31  1  0.080  0.403  0.803  1.0
  O  O32  1  0.723  0.399  0.802  1.0
  O  O33  1  0.301  0.622  0.241  1.0
  O  O34  1  0.941  0.620  0.241  1.0
  O  O35  1  0.933  0.245  0.495  1.0
  O  O36  1  0.562  0.247  0.495  1.0
  O  O37  1  0.453  0.775  0.550  1.0
  O  O38  1  0.097  0.774  0.550  1.0
  O  O39  1  0.002  0.776  0.010  1.0
  O  O40  1  0.008  0.235  0.010  1.0
  O  O41  1  0.858  0.858  0.715  1.0
  O  O42  1  0.146  0.146  0.292  1.0
[/CIF]
.