The structure described by Pd2B is zeta iron carbide structured and crystallizes in the orthorhombic Pnnm space group. Pd(1) is bonded in a distorted trigonal planar geometry to three equivalent B(1) atoms. B(1) is bonded to six equivalent Pd(1) atoms to form a mixture of corner and edge-sharing BPd6 octahedra. The corner-sharing octahedral tilt angles are 52°. is represented by the CIF file [CIF]
data_BPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.151
_cell_length_b   4.718
_cell_length_c   5.140
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   76.424
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.500  0.500  0.500  1.0
  B  B1  1  0.000  0.000  0.000  1.0
  Pd  Pd2  1  0.500  0.755  0.156  1.0
  Pd  Pd3  1  0.500  0.245  0.844  1.0
  Pd  Pd4  1  0.000  0.745  0.656  1.0
  Pd  Pd5  1  0.000  0.255  0.344  1.0
[/CIF]
.
The structure described by Pd2B is zeta iron carbide structured and crystallizes in the orthorhombic Pnnm space group. Pd(1) is bonded in a distorted trigonal planar geometry to three equivalent B(1) atoms. B(1) is bonded to six equivalent Pd(1) atoms to form a mixture of corner and edge-sharing BPd6 octahedra. The corner-sharing octahedral tilt angles are 52°. is represented by the CIF file [CIF]
data_BPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.151
_cell_length_b   4.718
_cell_length_c   5.140
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   76.424
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.500  0.500  0.500  1.0
  B  B1  1  0.000  0.000  0.000  1.0
  Pd  Pd2  1  0.500  0.755  0.156  1.0
  Pd  Pd3  1  0.500  0.245  0.844  1.0
  Pd  Pd4  1  0.000  0.745  0.656  1.0
  Pd  Pd5  1  0.000  0.255  0.344  1.0
[/CIF]
.