The structure described by CoC2N6H16S2(O2Cl)2(CNH4SO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two methanesulfonamide molecules and one CoC2N6H16S2(O2Cl)2 cluster. In the CoC2N6H16S2(O2Cl)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(4), and two equivalent Cl(1) atoms. C(1) is bonded in a trigonal non-coplanar geometry to one H(1); two equivalent H(2,3); and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one S(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one Co(1), one N(1), one H(5), and one H(6) atom. In the third N site, N(4) is bonded in a distorted water-like geometry to one Co(1), one H(11), and one H(12) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one N(4) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF file [CIF]
data_CoH24C4S4N8(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.595
_cell_length_b   8.987
_cell_length_c   9.146
_cell_angle_alpha   74.345
_cell_angle_beta   76.701
_cell_angle_gamma   64.909
_symmetry_Int_Tables_number   1
_cell_volume   610.675
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.601  0.607  0.385  1.0
  H  H2  1  0.399  0.393  0.615  1.0
  H  H3  1  0.733  0.386  0.407  1.0
  H  H4  1  0.267  0.614  0.593  1.0
  H  H5  1  0.824  0.540  0.298  1.0
  H  H6  1  0.176  0.460  0.702  1.0
  H  H7  1  0.825  0.376  0.978  1.0
  H  H8  1  0.175  0.624  0.022  1.0
  H  H9  1  0.668  0.199  0.133  1.0
  H  H10  1  0.332  0.801  0.867  1.0
  H  H11  1  0.814  0.137  0.250  1.0
  H  H12  1  0.186  0.863  0.750  1.0
  H  H13  1  0.648  0.768  0.588  1.0
  H  H14  1  0.352  0.232  0.412  1.0
  H  H15  1  0.769  0.689  0.747  1.0
  H  H16  1  0.231  0.311  0.253  1.0
  H  H17  1  0.868  0.755  0.556  1.0
  H  H18  1  0.132  0.245  0.444  1.0
  H  H19  1  0.850  0.086  0.711  1.0
  H  H20  1  0.150  0.914  0.289  1.0
  H  H21  1  0.676  0.020  0.959  1.0
  H  H22  1  0.324  0.980  0.041  1.0
  H  H23  1  0.822  0.828  0.961  1.0
  H  H24  1  0.178  0.172  0.039  1.0
  C  C25  1  0.708  0.509  0.331  1.0
  C  C26  1  0.292  0.491  0.669  1.0
  C  C27  1  0.748  0.776  0.637  1.0
  C  C28  1  0.252  0.224  0.363  1.0
  S  S29  1  0.639  0.508  0.163  1.0
  S  S30  1  0.361  0.492  0.837  1.0
  S  S31  1  0.668  0.983  0.670  1.0
  S  S32  1  0.332  0.017  0.330  1.0
  N  N33  1  0.804  0.346  0.096  1.0
  N  N34  1  0.196  0.654  0.904  1.0
  N  N35  1  0.792  0.186  0.139  1.0
  N  N36  1  0.208  0.814  0.861  1.0
  N  N37  1  0.824  0.979  0.755  1.0
  N  N38  1  0.176  0.021  0.245  1.0
  N  N39  1  0.802  0.952  0.918  1.0
  N  N40  1  0.198  0.048  0.082  1.0
  Cl  Cl41  1  0.010  0.778  0.218  1.0
  Cl  Cl42  1  0.990  0.222  0.782  1.0
  O  O43  1  0.483  0.473  0.208  1.0
  O  O44  1  0.517  0.527  0.792  1.0
  O  O45  1  0.639  0.655  0.049  1.0
  O  O46  1  0.361  0.345  0.951  1.0
  O  O47  1  0.508  0.011  0.776  1.0
  O  O48  1  0.492  0.989  0.224  1.0
  O  O49  1  0.669  0.099  0.524  1.0
  O  O50  1  0.331  0.901  0.476  1.0
[/CIF]
.
The structure described by CoC2N6H16S2(O2Cl)2(CNH4SO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two methanesulfonamide molecules and one CoC2N6H16S2(O2Cl)2 cluster. In the CoC2N6H16S2(O2Cl)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(4), and two equivalent Cl(1) atoms. C(1) is bonded in a trigonal non-coplanar geometry to one H(1); two equivalent H(2,3); and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one S(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one Co(1), one N(1), one H(5), and one H(6) atom. In the third N site, N(4) is bonded in a distorted water-like geometry to one Co(1), one H(11), and one H(12) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one N(4) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF file [CIF]
data_CoH24C4S4N8(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.595
_cell_length_b   8.987
_cell_length_c   9.146
_cell_angle_alpha   74.345
_cell_angle_beta   76.701
_cell_angle_gamma   64.909
_symmetry_Int_Tables_number   1
_cell_volume   610.675
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.601  0.607  0.385  1.0
  H  H2  1  0.399  0.393  0.615  1.0
  H  H3  1  0.733  0.386  0.407  1.0
  H  H4  1  0.267  0.614  0.593  1.0
  H  H5  1  0.824  0.540  0.298  1.0
  H  H6  1  0.176  0.460  0.702  1.0
  H  H7  1  0.825  0.376  0.978  1.0
  H  H8  1  0.175  0.624  0.022  1.0
  H  H9  1  0.668  0.199  0.133  1.0
  H  H10  1  0.332  0.801  0.867  1.0
  H  H11  1  0.814  0.137  0.250  1.0
  H  H12  1  0.186  0.863  0.750  1.0
  H  H13  1  0.648  0.768  0.588  1.0
  H  H14  1  0.352  0.232  0.412  1.0
  H  H15  1  0.769  0.689  0.747  1.0
  H  H16  1  0.231  0.311  0.253  1.0
  H  H17  1  0.868  0.755  0.556  1.0
  H  H18  1  0.132  0.245  0.444  1.0
  H  H19  1  0.850  0.086  0.711  1.0
  H  H20  1  0.150  0.914  0.289  1.0
  H  H21  1  0.676  0.020  0.959  1.0
  H  H22  1  0.324  0.980  0.041  1.0
  H  H23  1  0.822  0.828  0.961  1.0
  H  H24  1  0.178  0.172  0.039  1.0
  C  C25  1  0.708  0.509  0.331  1.0
  C  C26  1  0.292  0.491  0.669  1.0
  C  C27  1  0.748  0.776  0.637  1.0
  C  C28  1  0.252  0.224  0.363  1.0
  S  S29  1  0.639  0.508  0.163  1.0
  S  S30  1  0.361  0.492  0.837  1.0
  S  S31  1  0.668  0.983  0.670  1.0
  S  S32  1  0.332  0.017  0.330  1.0
  N  N33  1  0.804  0.346  0.096  1.0
  N  N34  1  0.196  0.654  0.904  1.0
  N  N35  1  0.792  0.186  0.139  1.0
  N  N36  1  0.208  0.814  0.861  1.0
  N  N37  1  0.824  0.979  0.755  1.0
  N  N38  1  0.176  0.021  0.245  1.0
  N  N39  1  0.802  0.952  0.918  1.0
  N  N40  1  0.198  0.048  0.082  1.0
  Cl  Cl41  1  0.010  0.778  0.218  1.0
  Cl  Cl42  1  0.990  0.222  0.782  1.0
  O  O43  1  0.483  0.473  0.208  1.0
  O  O44  1  0.517  0.527  0.792  1.0
  O  O45  1  0.639  0.655  0.049  1.0
  O  O46  1  0.361  0.345  0.951  1.0
  O  O47  1  0.508  0.011  0.776  1.0
  O  O48  1  0.492  0.989  0.224  1.0
  O  O49  1  0.669  0.099  0.524  1.0
  O  O50  1  0.331  0.901  0.476  1.0
[/CIF]
.