The structure described by U3Y2S5O3 crystallizes in the orthorhombic Pnma space group. There are three inequivalent U sites. In the first U site, U(1) is bonded in a 7-coordinate geometry to one S(1), three equivalent S(2), one O(2), and two equivalent O(3) atoms. In the second U site, U(2) is bonded in a 8-coordinate geometry to two equivalent S(3), two equivalent S(4), one O(1), one O(3), and two equivalent O(2) atoms. In the third U site, U(3) is bonded in a 7-coordinate geometry to one S(1), one S(4), two equivalent S(5), one O(2), and two equivalent O(1) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to two equivalent S(2), two equivalent S(3), two equivalent S(4), one O(1), and one O(3) atom. In the second Y site, Y(2) is bonded to one S(3), two equivalent S(1), and three equivalent S(5) atoms to form edge-sharing YS6 octahedra. There are five inequivalent S sites. In the first S site, S(4) is bonded to one U(3), two equivalent U(2), and two equivalent Y(1) atoms to form distorted SY2U3 trigonal bipyramids that share corners with two equivalent S(2)Y2U3 square pyramids, corners with two equivalent S(5)Y3U2 square pyramids, corners with two equivalent O(1)YU3 tetrahedra, corners with three equivalent O(2)U4 tetrahedra,  a cornercorner with one S(1)Y2U2 trigonal pyramid,  an edgeedge with one S(2)Y2U3 square pyramid,  an edgeedge with one O(2)U4 tetrahedra, edges with two equivalent O(1)YU3 tetrahedra, edges with two equivalent O(3)YU3 tetrahedra, and edges with two equivalent S(4)Y2U3 trigonal bipyramids. In the second S site, S(5) is bonded to two equivalent U(3) and three equivalent Y(2) atoms to form SY3U2 square pyramids that share corners with two equivalent O(2)U4 tetrahedra, corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent S(4)Y2U3 trigonal bipyramids, corners with two equivalent S(1)Y2U2 trigonal pyramids, edges with four equivalent S(5)Y3U2 square pyramids,  an edgeedge with one O(1)YU3 tetrahedra, and edges with three equivalent S(1)Y2U2 trigonal pyramids. In the third S site, S(1) is bonded to one U(1), one U(3), and two equivalent Y(2) atoms to form distorted SY2U2 trigonal pyramids that share corners with two equivalent S(5)Y3U2 square pyramids, corners with three equivalent S(2)Y2U3 square pyramids, corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent O(3)YU3 tetrahedra,  a cornercorner with one S(4)Y2U3 trigonal bipyramid, corners with two equivalent S(1)Y2U2 trigonal pyramids, edges with three equivalent S(5)Y3U2 square pyramids, and  an edgeedge with one O(2)U4 tetrahedra. In the fourth S site, S(2) is bonded to three equivalent U(1) and two equivalent Y(1) atoms to form SY2U3 square pyramids that share corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent O(3)YU3 tetrahedra, corners with three equivalent O(2)U4 tetrahedra, corners with two equivalent S(4)Y2U3 trigonal bipyramids, corners with three equivalent S(1)Y2U2 trigonal pyramids, edges with four equivalent S(2)Y2U3 square pyramids, edges with three equivalent O(3)YU3 tetrahedra, and  an edgeedge with one S(4)Y2U3 trigonal bipyramid. In the fifth S site, S(3) is bonded in a 5-coordinate geometry to two equivalent U(2), one Y(2), and two equivalent Y(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one U(2), two equivalent U(3), and one Y(1) atom to form OYU3 tetrahedra that share corners with two equivalent S(2)Y2U3 square pyramids, corners with two equivalent S(5)Y3U2 square pyramids, corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent O(3)YU3 tetrahedra, corners with two equivalent S(4)Y2U3 trigonal bipyramids, corners with two equivalent S(1)Y2U2 trigonal pyramids,  an edgeedge with one S(5)Y3U2 square pyramid, edges with two equivalent O(2)U4 tetrahedra, and edges with two equivalent S(4)Y2U3 trigonal bipyramids. In the second O site, O(2) is bonded to one U(1), one U(3), and two equivalent U(2) atoms to form OU4 tetrahedra that share corners with two equivalent S(5)Y3U2 square pyramids, corners with three equivalent S(2)Y2U3 square pyramids, corners with two equivalent O(2)U4 tetrahedra, corners with three equivalent S(4)Y2U3 trigonal bipyramids, edges with two equivalent O(1)YU3 tetrahedra, edges with two equivalent O(3)YU3 tetrahedra,  an edgeedge with one S(4)Y2U3 trigonal bipyramid, and  an edgeedge with one S(1)Y2U2 trigonal pyramid. In the third O site, O(3) is bonded to one U(2), two equivalent U(1), and one Y(1) atom to form OYU3 tetrahedra that share corners with two equivalent S(2)Y2U3 square pyramids, corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent O(3)YU3 tetrahedra, corners with two equivalent S(1)Y2U2 trigonal pyramids, edges with three equivalent S(2)Y2U3 square pyramids, edges with two equivalent O(2)U4 tetrahedra, and edges with two equivalent S(4)Y2U3 trigonal bipyramids. is represented by the CIF file [CIF]
data_Y2U3S5O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.837
_cell_length_b   13.981
_cell_length_c   18.748
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1005.732
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.250  0.887  0.338  1.0
  Y  Y1  1  0.750  0.113  0.662  1.0
  Y  Y2  1  0.750  0.613  0.838  1.0
  Y  Y3  1  0.250  0.387  0.162  1.0
  Y  Y4  1  0.250  0.890  0.954  1.0
  Y  Y5  1  0.750  0.110  0.046  1.0
  Y  Y6  1  0.750  0.610  0.454  1.0
  Y  Y7  1  0.250  0.390  0.546  1.0
  U  U8  1  0.250  0.898  0.564  1.0
  U  U9  1  0.750  0.102  0.436  1.0
  U  U10  1  0.750  0.602  0.064  1.0
  U  U11  1  0.250  0.398  0.936  1.0
  U  U12  1  0.250  0.652  0.229  1.0
  U  U13  1  0.750  0.348  0.771  1.0
  U  U14  1  0.750  0.848  0.729  1.0
  U  U15  1  0.250  0.152  0.271  1.0
  U  U16  1  0.250  0.642  0.655  1.0
  U  U17  1  0.750  0.358  0.345  1.0
  U  U18  1  0.750  0.858  0.155  1.0
  U  U19  1  0.250  0.142  0.845  1.0
  S  S20  1  0.250  0.713  0.516  1.0
  S  S21  1  0.750  0.287  0.484  1.0
  S  S22  1  0.750  0.787  0.016  1.0
  S  S23  1  0.250  0.213  0.984  1.0
  S  S24  1  0.250  0.594  0.950  1.0
  S  S25  1  0.750  0.406  0.050  1.0
  S  S26  1  0.750  0.906  0.450  1.0
  S  S27  1  0.250  0.094  0.550  1.0
  S  S28  1  0.250  0.774  0.834  1.0
  S  S29  1  0.750  0.226  0.166  1.0
  S  S30  1  0.750  0.726  0.334  1.0
  S  S31  1  0.250  0.274  0.666  1.0
  S  S32  1  0.250  0.506  0.763  1.0
  S  S33  1  0.750  0.494  0.237  1.0
  S  S34  1  0.750  0.994  0.263  1.0
  S  S35  1  0.250  0.006  0.737  1.0
  S  S36  1  0.250  0.985  0.089  1.0
  S  S37  1  0.750  0.015  0.911  1.0
  S  S38  1  0.750  0.515  0.589  1.0
  S  S39  1  0.250  0.485  0.411  1.0
  O  O40  1  0.250  0.821  0.216  1.0
  O  O41  1  0.750  0.179  0.784  1.0
  O  O42  1  0.750  0.679  0.716  1.0
  O  O43  1  0.250  0.321  0.284  1.0
  O  O44  1  0.250  0.804  0.665  1.0
  O  O45  1  0.750  0.196  0.335  1.0
  O  O46  1  0.750  0.696  0.165  1.0
  O  O47  1  0.250  0.304  0.835  1.0
  O  O48  1  0.250  0.568  0.121  1.0
  O  O49  1  0.750  0.432  0.879  1.0
  O  O50  1  0.750  0.932  0.621  1.0
  O  O51  1  0.250  0.068  0.379  1.0
[/CIF]
.
The structure described by U3Y2S5O3 crystallizes in the orthorhombic Pnma space group. There are three inequivalent U sites. In the first U site, U(1) is bonded in a 7-coordinate geometry to one S(1), three equivalent S(2), one O(2), and two equivalent O(3) atoms. In the second U site, U(2) is bonded in a 8-coordinate geometry to two equivalent S(3), two equivalent S(4), one O(1), one O(3), and two equivalent O(2) atoms. In the third U site, U(3) is bonded in a 7-coordinate geometry to one S(1), one S(4), two equivalent S(5), one O(2), and two equivalent O(1) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to two equivalent S(2), two equivalent S(3), two equivalent S(4), one O(1), and one O(3) atom. In the second Y site, Y(2) is bonded to one S(3), two equivalent S(1), and three equivalent S(5) atoms to form edge-sharing YS6 octahedra. There are five inequivalent S sites. In the first S site, S(4) is bonded to one U(3), two equivalent U(2), and two equivalent Y(1) atoms to form distorted SY2U3 trigonal bipyramids that share corners with two equivalent S(2)Y2U3 square pyramids, corners with two equivalent S(5)Y3U2 square pyramids, corners with two equivalent O(1)YU3 tetrahedra, corners with three equivalent O(2)U4 tetrahedra,  a cornercorner with one S(1)Y2U2 trigonal pyramid,  an edgeedge with one S(2)Y2U3 square pyramid,  an edgeedge with one O(2)U4 tetrahedra, edges with two equivalent O(1)YU3 tetrahedra, edges with two equivalent O(3)YU3 tetrahedra, and edges with two equivalent S(4)Y2U3 trigonal bipyramids. In the second S site, S(5) is bonded to two equivalent U(3) and three equivalent Y(2) atoms to form SY3U2 square pyramids that share corners with two equivalent O(2)U4 tetrahedra, corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent S(4)Y2U3 trigonal bipyramids, corners with two equivalent S(1)Y2U2 trigonal pyramids, edges with four equivalent S(5)Y3U2 square pyramids,  an edgeedge with one O(1)YU3 tetrahedra, and edges with three equivalent S(1)Y2U2 trigonal pyramids. In the third S site, S(1) is bonded to one U(1), one U(3), and two equivalent Y(2) atoms to form distorted SY2U2 trigonal pyramids that share corners with two equivalent S(5)Y3U2 square pyramids, corners with three equivalent S(2)Y2U3 square pyramids, corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent O(3)YU3 tetrahedra,  a cornercorner with one S(4)Y2U3 trigonal bipyramid, corners with two equivalent S(1)Y2U2 trigonal pyramids, edges with three equivalent S(5)Y3U2 square pyramids, and  an edgeedge with one O(2)U4 tetrahedra. In the fourth S site, S(2) is bonded to three equivalent U(1) and two equivalent Y(1) atoms to form SY2U3 square pyramids that share corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent O(3)YU3 tetrahedra, corners with three equivalent O(2)U4 tetrahedra, corners with two equivalent S(4)Y2U3 trigonal bipyramids, corners with three equivalent S(1)Y2U2 trigonal pyramids, edges with four equivalent S(2)Y2U3 square pyramids, edges with three equivalent O(3)YU3 tetrahedra, and  an edgeedge with one S(4)Y2U3 trigonal bipyramid. In the fifth S site, S(3) is bonded in a 5-coordinate geometry to two equivalent U(2), one Y(2), and two equivalent Y(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one U(2), two equivalent U(3), and one Y(1) atom to form OYU3 tetrahedra that share corners with two equivalent S(2)Y2U3 square pyramids, corners with two equivalent S(5)Y3U2 square pyramids, corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent O(3)YU3 tetrahedra, corners with two equivalent S(4)Y2U3 trigonal bipyramids, corners with two equivalent S(1)Y2U2 trigonal pyramids,  an edgeedge with one S(5)Y3U2 square pyramid, edges with two equivalent O(2)U4 tetrahedra, and edges with two equivalent S(4)Y2U3 trigonal bipyramids. In the second O site, O(2) is bonded to one U(1), one U(3), and two equivalent U(2) atoms to form OU4 tetrahedra that share corners with two equivalent S(5)Y3U2 square pyramids, corners with three equivalent S(2)Y2U3 square pyramids, corners with two equivalent O(2)U4 tetrahedra, corners with three equivalent S(4)Y2U3 trigonal bipyramids, edges with two equivalent O(1)YU3 tetrahedra, edges with two equivalent O(3)YU3 tetrahedra,  an edgeedge with one S(4)Y2U3 trigonal bipyramid, and  an edgeedge with one S(1)Y2U2 trigonal pyramid. In the third O site, O(3) is bonded to one U(2), two equivalent U(1), and one Y(1) atom to form OYU3 tetrahedra that share corners with two equivalent S(2)Y2U3 square pyramids, corners with two equivalent O(1)YU3 tetrahedra, corners with two equivalent O(3)YU3 tetrahedra, corners with two equivalent S(1)Y2U2 trigonal pyramids, edges with three equivalent S(2)Y2U3 square pyramids, edges with two equivalent O(2)U4 tetrahedra, and edges with two equivalent S(4)Y2U3 trigonal bipyramids. is represented by the CIF file [CIF]
data_Y2U3S5O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.837
_cell_length_b   13.981
_cell_length_c   18.748
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1005.732
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.250  0.887  0.338  1.0
  Y  Y1  1  0.750  0.113  0.662  1.0
  Y  Y2  1  0.750  0.613  0.838  1.0
  Y  Y3  1  0.250  0.387  0.162  1.0
  Y  Y4  1  0.250  0.890  0.954  1.0
  Y  Y5  1  0.750  0.110  0.046  1.0
  Y  Y6  1  0.750  0.610  0.454  1.0
  Y  Y7  1  0.250  0.390  0.546  1.0
  U  U8  1  0.250  0.898  0.564  1.0
  U  U9  1  0.750  0.102  0.436  1.0
  U  U10  1  0.750  0.602  0.064  1.0
  U  U11  1  0.250  0.398  0.936  1.0
  U  U12  1  0.250  0.652  0.229  1.0
  U  U13  1  0.750  0.348  0.771  1.0
  U  U14  1  0.750  0.848  0.729  1.0
  U  U15  1  0.250  0.152  0.271  1.0
  U  U16  1  0.250  0.642  0.655  1.0
  U  U17  1  0.750  0.358  0.345  1.0
  U  U18  1  0.750  0.858  0.155  1.0
  U  U19  1  0.250  0.142  0.845  1.0
  S  S20  1  0.250  0.713  0.516  1.0
  S  S21  1  0.750  0.287  0.484  1.0
  S  S22  1  0.750  0.787  0.016  1.0
  S  S23  1  0.250  0.213  0.984  1.0
  S  S24  1  0.250  0.594  0.950  1.0
  S  S25  1  0.750  0.406  0.050  1.0
  S  S26  1  0.750  0.906  0.450  1.0
  S  S27  1  0.250  0.094  0.550  1.0
  S  S28  1  0.250  0.774  0.834  1.0
  S  S29  1  0.750  0.226  0.166  1.0
  S  S30  1  0.750  0.726  0.334  1.0
  S  S31  1  0.250  0.274  0.666  1.0
  S  S32  1  0.250  0.506  0.763  1.0
  S  S33  1  0.750  0.494  0.237  1.0
  S  S34  1  0.750  0.994  0.263  1.0
  S  S35  1  0.250  0.006  0.737  1.0
  S  S36  1  0.250  0.985  0.089  1.0
  S  S37  1  0.750  0.015  0.911  1.0
  S  S38  1  0.750  0.515  0.589  1.0
  S  S39  1  0.250  0.485  0.411  1.0
  O  O40  1  0.250  0.821  0.216  1.0
  O  O41  1  0.750  0.179  0.784  1.0
  O  O42  1  0.750  0.679  0.716  1.0
  O  O43  1  0.250  0.321  0.284  1.0
  O  O44  1  0.250  0.804  0.665  1.0
  O  O45  1  0.750  0.196  0.335  1.0
  O  O46  1  0.750  0.696  0.165  1.0
  O  O47  1  0.250  0.304  0.835  1.0
  O  O48  1  0.250  0.568  0.121  1.0
  O  O49  1  0.750  0.432  0.879  1.0
  O  O50  1  0.750  0.932  0.621  1.0
  O  O51  1  0.250  0.068  0.379  1.0
[/CIF]
.