The crystal structure described by V4OF11 crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one F(1), one F(17), one F(3), one F(7), and one F(8) atom to form VOF5 octahedra that share corners with three equivalent V(3)F6 octahedra and corners with three equivalent V(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-38°. In the second V site, V(2) is bonded to one F(11), one F(13), one F(18), one F(2), one F(5), and one F(9) atom to form VF6 octahedra that share corners with three equivalent V(4)F6 octahedra and corners with three equivalent V(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 34-40°. In the third V site, V(3) is bonded to one F(10), one F(12), one F(17), one F(3), one F(4), and one F(8) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 31-38°. In the fourth V site, V(4) is bonded to one F(11), one F(14), one F(18), one F(19), one F(6), and one F(9) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 35-38°. In the fifth V site, V(5) is bonded to one O(2), one F(10), one F(12), one F(16), one F(21), and one F(4) atom to form VOF5 octahedra that share corners with three equivalent V(3)F6 octahedra and corners with three equivalent V(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-37°. In the sixth V site, V(6) is bonded to one F(14), one F(15), one F(19), one F(20), one F(22), and one F(6) atom to form VF6 octahedra that share corners with three equivalent V(4)F6 octahedra and corners with three equivalent V(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 35-42°. In the seventh V site, V(7) is bonded to one O(1), one F(1), one F(15), one F(20), one F(22), and one F(7) atom to form VOF5 octahedra that share corners with three equivalent V(6)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-42°. In the eighth V site, V(8) is bonded to one O(2), one F(13), one F(16), one F(2), one F(21), and one F(5) atom to form VOF5 octahedra that share corners with three equivalent V(2)F6 octahedra and corners with three equivalent V(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-40°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. There are twenty-two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the twelfth F site, F(12) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the thirteenth F site, F(13) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the fourteenth F site, F(14) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the fifteenth F site, F(15) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. In the sixteenth F site, F(16) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the seventeenth F site, F(17) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the eighteenth F site, F(18) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the nineteenth F site, F(19) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the twentieth F site, F(20) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. In the twenty-first F site, F(21) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the twenty-second F site, F(22) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V4OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.059
_cell_length_b   5.325
_cell_length_c   16.788
_cell_angle_alpha   88.274
_cell_angle_beta   98.385
_cell_angle_gamma   118.262
_symmetry_Int_Tables_number   1
_cell_volume   393.707
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.746  0.391  0.122  1.0
  V  V1  1  0.754  0.868  0.624  1.0
  V  V2  1  0.499  0.759  0.250  1.0
  V  V3  1  0.499  0.243  0.750  1.0
  V  V4  1  0.247  0.138  0.381  1.0
  V  V5  1  0.244  0.618  0.876  1.0
  V  V6  1  0.975  0.977  0.004  1.0
  V  V7  1  0.013  0.485  0.498  1.0
  O  O8  1  0.788  0.700  0.061  1.0
  O  O9  1  0.173  0.292  0.460  1.0
  F  F10  1  0.321  0.172  0.091  1.0
  F  F11  1  0.752  0.175  0.562  1.0
  F  F12  1  0.733  0.062  0.186  1.0
  F  F13  1  0.320  0.982  0.288  1.0
  F  F14  1  0.312  0.642  0.592  1.0
  F  F15  1  0.312  0.455  0.784  1.0
  F  F16  1  0.815  0.223  0.033  1.0
  F  F17  1  0.178  0.591  0.160  1.0
  F  F18  1  0.195  0.095  0.657  1.0
  F  F19  1  0.256  0.443  0.311  1.0
  F  F20  1  0.754  0.565  0.688  1.0
  F  F21  1  0.817  0.911  0.340  1.0
  F  F22  1  0.827  0.707  0.534  1.0
  F  F23  1  0.803  0.394  0.843  1.0
  F  F24  1  0.198  0.798  0.967  1.0
  F  F25  1  0.684  0.357  0.408  1.0
  F  F26  1  0.684  0.535  0.216  1.0
  F  F27  1  0.684  0.028  0.716  1.0
  F  F28  1  0.243  0.921  0.811  1.0
  F  F29  1  0.232  0.308  0.940  1.0
  F  F30  1  0.253  0.823  0.439  1.0
  F  F31  1  0.688  0.843  0.907  1.0
[/CIF]
.
The crystal structure described by V4OF11 crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one F(1), one F(17), one F(3), one F(7), and one F(8) atom to form VOF5 octahedra that share corners with three equivalent V(3)F6 octahedra and corners with three equivalent V(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-38°. In the second V site, V(2) is bonded to one F(11), one F(13), one F(18), one F(2), one F(5), and one F(9) atom to form VF6 octahedra that share corners with three equivalent V(4)F6 octahedra and corners with three equivalent V(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 34-40°. In the third V site, V(3) is bonded to one F(10), one F(12), one F(17), one F(3), one F(4), and one F(8) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 31-38°. In the fourth V site, V(4) is bonded to one F(11), one F(14), one F(18), one F(19), one F(6), and one F(9) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 35-38°. In the fifth V site, V(5) is bonded to one O(2), one F(10), one F(12), one F(16), one F(21), and one F(4) atom to form VOF5 octahedra that share corners with three equivalent V(3)F6 octahedra and corners with three equivalent V(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-37°. In the sixth V site, V(6) is bonded to one F(14), one F(15), one F(19), one F(20), one F(22), and one F(6) atom to form VF6 octahedra that share corners with three equivalent V(4)F6 octahedra and corners with three equivalent V(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 35-42°. In the seventh V site, V(7) is bonded to one O(1), one F(1), one F(15), one F(20), one F(22), and one F(7) atom to form VOF5 octahedra that share corners with three equivalent V(6)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-42°. In the eighth V site, V(8) is bonded to one O(2), one F(13), one F(16), one F(2), one F(21), and one F(5) atom to form VOF5 octahedra that share corners with three equivalent V(2)F6 octahedra and corners with three equivalent V(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-40°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. There are twenty-two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the twelfth F site, F(12) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the thirteenth F site, F(13) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the fourteenth F site, F(14) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the fifteenth F site, F(15) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. In the sixteenth F site, F(16) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the seventeenth F site, F(17) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the eighteenth F site, F(18) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the nineteenth F site, F(19) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the twentieth F site, F(20) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. In the twenty-first F site, F(21) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the twenty-second F site, F(22) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V4OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.059
_cell_length_b   5.325
_cell_length_c   16.788
_cell_angle_alpha   88.274
_cell_angle_beta   98.385
_cell_angle_gamma   118.262
_symmetry_Int_Tables_number   1
_cell_volume   393.707
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.746  0.391  0.122  1.0
  V  V1  1  0.754  0.868  0.624  1.0
  V  V2  1  0.499  0.759  0.250  1.0
  V  V3  1  0.499  0.243  0.750  1.0
  V  V4  1  0.247  0.138  0.381  1.0
  V  V5  1  0.244  0.618  0.876  1.0
  V  V6  1  0.975  0.977  0.004  1.0
  V  V7  1  0.013  0.485  0.498  1.0
  O  O8  1  0.788  0.700  0.061  1.0
  O  O9  1  0.173  0.292  0.460  1.0
  F  F10  1  0.321  0.172  0.091  1.0
  F  F11  1  0.752  0.175  0.562  1.0
  F  F12  1  0.733  0.062  0.186  1.0
  F  F13  1  0.320  0.982  0.288  1.0
  F  F14  1  0.312  0.642  0.592  1.0
  F  F15  1  0.312  0.455  0.784  1.0
  F  F16  1  0.815  0.223  0.033  1.0
  F  F17  1  0.178  0.591  0.160  1.0
  F  F18  1  0.195  0.095  0.657  1.0
  F  F19  1  0.256  0.443  0.311  1.0
  F  F20  1  0.754  0.565  0.688  1.0
  F  F21  1  0.817  0.911  0.340  1.0
  F  F22  1  0.827  0.707  0.534  1.0
  F  F23  1  0.803  0.394  0.843  1.0
  F  F24  1  0.198  0.798  0.967  1.0
  F  F25  1  0.684  0.357  0.408  1.0
  F  F26  1  0.684  0.535  0.216  1.0
  F  F27  1  0.684  0.028  0.716  1.0
  F  F28  1  0.243  0.921  0.811  1.0
  F  F29  1  0.232  0.308  0.940  1.0
  F  F30  1  0.253  0.823  0.439  1.0
  F  F31  1  0.688  0.843  0.907  1.0
[/CIF]
.