The material described by LiMn2(PO3)5 crystallizes in the monoclinic Cc space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(14), one O(15), and one O(7) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(2), one O(5), and one O(6) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the second Mn site, Mn(2) is bonded in a 4-coordinate geometry to one O(10), one O(14), one O(15), and one O(8) atom. There are five inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(13), one O(15), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(1), one O(4), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. In the fifth P site, P(5) is bonded to one O(12), one O(13), one O(14), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one P(2) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Li(1) and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one P(3) and one P(5) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one P(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(5) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(1), one Mn(2), and one P(5) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(1), one Mn(2), and one P(1) atom. is represented by the CIF file [CIF]
data_LiMn2(PO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.296
_cell_length_b   7.296
_cell_length_c   12.923
_cell_angle_alpha   86.319
_cell_angle_beta   86.319
_cell_angle_gamma   114.469
_symmetry_Int_Tables_number   1
_cell_volume   621.756
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.123  0.956  0.788  1.0
  Li  Li1  1  0.956  0.123  0.288  1.0
  Mn  Mn2  1  0.780  0.311  0.763  1.0
  Mn  Mn3  1  0.311  0.780  0.263  1.0
  Mn  Mn4  1  0.212  0.278  0.591  1.0
  Mn  Mn5  1  0.278  0.212  0.091  1.0
  P  P6  1  0.357  0.979  0.503  1.0
  P  P7  1  0.686  0.600  0.562  1.0
  P  P8  1  0.619  0.840  0.840  1.0
  P  P9  1  0.979  0.357  0.003  1.0
  P  P10  1  0.600  0.686  0.062  1.0
  P  P11  1  0.840  0.619  0.340  1.0
  P  P12  1  0.805  0.066  0.534  1.0
  P  P13  1  0.066  0.805  0.034  1.0
  P  P14  1  0.239  0.454  0.806  1.0
  P  P15  1  0.454  0.239  0.306  1.0
  O  O16  1  0.825  0.850  0.816  1.0
  O  O17  1  0.850  0.825  0.316  1.0
  O  O18  1  0.734  0.512  0.658  1.0
  O  O19  1  0.512  0.734  0.158  1.0
  O  O20  1  0.781  0.841  0.561  1.0
  O  O21  1  0.841  0.781  0.061  1.0
  O  O22  1  0.557  0.809  0.965  1.0
  O  O23  1  0.809  0.557  0.465  1.0
  O  O24  1  0.566  0.008  0.797  1.0
  O  O25  1  0.008  0.566  0.297  1.0
  O  O26  1  0.801  0.297  0.942  1.0
  O  O27  1  0.297  0.801  0.442  1.0
  O  O28  1  0.162  0.933  0.934  1.0
  O  O29  1  0.467  0.532  0.542  1.0
  O  O30  1  0.933  0.162  0.434  1.0
  O  O31  1  0.458  0.630  0.801  1.0
  O  O32  1  0.532  0.467  0.042  1.0
  O  O33  1  0.630  0.458  0.301  1.0
  O  O34  1  0.897  0.182  0.626  1.0
  O  O35  1  0.182  0.897  0.126  1.0
  O  O36  1  0.583  0.053  0.537  1.0
  O  O37  1  0.053  0.583  0.037  1.0
  O  O38  1  0.089  0.528  0.767  1.0
  O  O39  1  0.528  0.089  0.267  1.0
  O  O40  1  0.180  0.378  0.929  1.0
  O  O41  1  0.378  0.180  0.429  1.0
  O  O42  1  0.255  0.280  0.754  1.0
  O  O43  1  0.280  0.255  0.254  1.0
  O  O44  1  0.231  0.989  0.598  1.0
  O  O45  1  0.989  0.231  0.098  1.0
[/CIF]
.
The material described by LiMn2(PO3)5 crystallizes in the monoclinic Cc space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(14), one O(15), and one O(7) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(2), one O(5), and one O(6) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the second Mn site, Mn(2) is bonded in a 4-coordinate geometry to one O(10), one O(14), one O(15), and one O(8) atom. There are five inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(13), one O(15), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(1), one O(4), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. In the fifth P site, P(5) is bonded to one O(12), one O(13), one O(14), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Mn(1)O5 trigonal bipyramid. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one P(2) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Li(1) and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one P(3) and one P(5) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one P(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(5) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(1), one Mn(2), and one P(5) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(1), one Mn(2), and one P(1) atom. is represented by the CIF file [CIF]
data_LiMn2(PO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.296
_cell_length_b   7.296
_cell_length_c   12.923
_cell_angle_alpha   86.319
_cell_angle_beta   86.319
_cell_angle_gamma   114.469
_symmetry_Int_Tables_number   1
_cell_volume   621.756
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.123  0.956  0.788  1.0
  Li  Li1  1  0.956  0.123  0.288  1.0
  Mn  Mn2  1  0.780  0.311  0.763  1.0
  Mn  Mn3  1  0.311  0.780  0.263  1.0
  Mn  Mn4  1  0.212  0.278  0.591  1.0
  Mn  Mn5  1  0.278  0.212  0.091  1.0
  P  P6  1  0.357  0.979  0.503  1.0
  P  P7  1  0.686  0.600  0.562  1.0
  P  P8  1  0.619  0.840  0.840  1.0
  P  P9  1  0.979  0.357  0.003  1.0
  P  P10  1  0.600  0.686  0.062  1.0
  P  P11  1  0.840  0.619  0.340  1.0
  P  P12  1  0.805  0.066  0.534  1.0
  P  P13  1  0.066  0.805  0.034  1.0
  P  P14  1  0.239  0.454  0.806  1.0
  P  P15  1  0.454  0.239  0.306  1.0
  O  O16  1  0.825  0.850  0.816  1.0
  O  O17  1  0.850  0.825  0.316  1.0
  O  O18  1  0.734  0.512  0.658  1.0
  O  O19  1  0.512  0.734  0.158  1.0
  O  O20  1  0.781  0.841  0.561  1.0
  O  O21  1  0.841  0.781  0.061  1.0
  O  O22  1  0.557  0.809  0.965  1.0
  O  O23  1  0.809  0.557  0.465  1.0
  O  O24  1  0.566  0.008  0.797  1.0
  O  O25  1  0.008  0.566  0.297  1.0
  O  O26  1  0.801  0.297  0.942  1.0
  O  O27  1  0.297  0.801  0.442  1.0
  O  O28  1  0.162  0.933  0.934  1.0
  O  O29  1  0.467  0.532  0.542  1.0
  O  O30  1  0.933  0.162  0.434  1.0
  O  O31  1  0.458  0.630  0.801  1.0
  O  O32  1  0.532  0.467  0.042  1.0
  O  O33  1  0.630  0.458  0.301  1.0
  O  O34  1  0.897  0.182  0.626  1.0
  O  O35  1  0.182  0.897  0.126  1.0
  O  O36  1  0.583  0.053  0.537  1.0
  O  O37  1  0.053  0.583  0.037  1.0
  O  O38  1  0.089  0.528  0.767  1.0
  O  O39  1  0.528  0.089  0.267  1.0
  O  O40  1  0.180  0.378  0.929  1.0
  O  O41  1  0.378  0.180  0.429  1.0
  O  O42  1  0.255  0.280  0.754  1.0
  O  O43  1  0.280  0.255  0.254  1.0
  O  O44  1  0.231  0.989  0.598  1.0
  O  O45  1  0.989  0.231  0.098  1.0
[/CIF]
.