The structure described by Li2Cu3F11 crystallizes in the monoclinic P2_1/m space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a trigonal non-coplanar geometry to one F(1) and two equivalent F(2) atoms. In the second Li site, Li(2) is bonded in a distorted square co-planar geometry to two equivalent F(4) and two equivalent F(7) atoms. In the third Li site, Li(3) is bonded in a square co-planar geometry to two equivalent F(11) and two equivalent F(9) atoms. In the fourth Li site, Li(4) is bonded in a trigonal non-coplanar geometry to one F(14) and two equivalent F(13) atoms. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one F(1), one F(2), one F(3), one F(5), and two equivalent F(4) atoms to form a mixture of corner and edge-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles range from 35-42°. In the second Cu site, Cu(2) is bonded to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles range from 34-35°. In the third Cu site, Cu(3) is bonded to one F(10), one F(12), one F(13), one F(14), and two equivalent F(11) atoms to form a mixture of corner and edge-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles range from 34-44°. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Cu(1) atoms. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one Cu(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent Cu(1) atoms. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(2) and two equivalent Cu(1) atoms. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Cu(1) and one Cu(2) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to two equivalent Cu(2) atoms. In the seventh F site, F(7) is bonded in a bent 120 degrees geometry to one Li(2) and one Cu(2) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to two equivalent Cu(2) atoms. In the ninth F site, F(9) is bonded in a bent 120 degrees geometry to one Li(3) and one Cu(2) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one Cu(2) and one Cu(3) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal non-coplanar geometry to one Li(3) and two equivalent Cu(3) atoms. In the twelfth F site, F(12) is bonded in a bent 150 degrees geometry to two equivalent Cu(3) atoms. In the thirteenth F site, F(13) is bonded in a bent 150 degrees geometry to one Li(4) and one Cu(3) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Li(4) and two equivalent Cu(3) atoms. is represented by the CIF card [CIF]
data_Li2Cu3F11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.258
_cell_length_b   7.336
_cell_length_c   9.130
_cell_angle_alpha   90.000
_cell_angle_beta   93.551
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   418.341
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.327  0.498  0.875  1.0
  Cu  Cu1  1  0.327  0.002  0.875  1.0
  Cu  Cu2  1  0.500  0.500  0.500  1.0
  Cu  Cu3  1  0.500  0.000  0.500  1.0
  Cu  Cu4  1  0.673  0.502  0.125  1.0
  Cu  Cu5  1  0.673  0.998  0.125  1.0
  F  F6  1  0.254  0.750  0.934  1.0
  F  F7  1  0.036  0.044  0.847  1.0
  F  F8  1  0.036  0.456  0.847  1.0
  F  F9  1  0.413  0.250  0.839  1.0
  F  F10  1  0.636  0.947  0.909  1.0
  F  F11  1  0.636  0.553  0.909  1.0
  F  F12  1  0.352  0.946  0.674  1.0
  F  F13  1  0.352  0.554  0.674  1.0
  F  F14  1  0.544  0.250  0.556  1.0
  F  F15  1  0.749  0.944  0.602  1.0
  F  F16  1  0.749  0.556  0.602  1.0
  F  F17  1  0.456  0.750  0.444  1.0
  F  F18  1  0.251  0.444  0.398  1.0
  F  F19  1  0.251  0.056  0.398  1.0
  F  F20  1  0.648  0.446  0.326  1.0
  F  F21  1  0.648  0.054  0.326  1.0
  F  F22  1  0.364  0.447  0.091  1.0
  F  F23  1  0.364  0.053  0.091  1.0
  F  F24  1  0.587  0.750  0.161  1.0
  F  F25  1  0.964  0.956  0.153  1.0
  F  F26  1  0.964  0.544  0.153  1.0
  F  F27  1  0.746  0.250  0.066  1.0
  Li  Li28  1  0.859  0.250  0.854  1.0
  Li  Li29  1  0.759  0.750  0.747  1.0
  Li  Li30  1  0.241  0.250  0.253  1.0
  Li  Li31  1  0.141  0.750  0.146  1.0
[/CIF]
.
The structure described by Li2Cu3F11 crystallizes in the monoclinic P2_1/m space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a trigonal non-coplanar geometry to one F(1) and two equivalent F(2) atoms. In the second Li site, Li(2) is bonded in a distorted square co-planar geometry to two equivalent F(4) and two equivalent F(7) atoms. In the third Li site, Li(3) is bonded in a square co-planar geometry to two equivalent F(11) and two equivalent F(9) atoms. In the fourth Li site, Li(4) is bonded in a trigonal non-coplanar geometry to one F(14) and two equivalent F(13) atoms. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one F(1), one F(2), one F(3), one F(5), and two equivalent F(4) atoms to form a mixture of corner and edge-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles range from 35-42°. In the second Cu site, Cu(2) is bonded to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles range from 34-35°. In the third Cu site, Cu(3) is bonded to one F(10), one F(12), one F(13), one F(14), and two equivalent F(11) atoms to form a mixture of corner and edge-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles range from 34-44°. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Cu(1) atoms. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one Cu(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent Cu(1) atoms. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(2) and two equivalent Cu(1) atoms. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Cu(1) and one Cu(2) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to two equivalent Cu(2) atoms. In the seventh F site, F(7) is bonded in a bent 120 degrees geometry to one Li(2) and one Cu(2) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to two equivalent Cu(2) atoms. In the ninth F site, F(9) is bonded in a bent 120 degrees geometry to one Li(3) and one Cu(2) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one Cu(2) and one Cu(3) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal non-coplanar geometry to one Li(3) and two equivalent Cu(3) atoms. In the twelfth F site, F(12) is bonded in a bent 150 degrees geometry to two equivalent Cu(3) atoms. In the thirteenth F site, F(13) is bonded in a bent 150 degrees geometry to one Li(4) and one Cu(3) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Li(4) and two equivalent Cu(3) atoms. is represented by the CIF card [CIF]
data_Li2Cu3F11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.258
_cell_length_b   7.336
_cell_length_c   9.130
_cell_angle_alpha   90.000
_cell_angle_beta   93.551
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   418.341
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.327  0.498  0.875  1.0
  Cu  Cu1  1  0.327  0.002  0.875  1.0
  Cu  Cu2  1  0.500  0.500  0.500  1.0
  Cu  Cu3  1  0.500  0.000  0.500  1.0
  Cu  Cu4  1  0.673  0.502  0.125  1.0
  Cu  Cu5  1  0.673  0.998  0.125  1.0
  F  F6  1  0.254  0.750  0.934  1.0
  F  F7  1  0.036  0.044  0.847  1.0
  F  F8  1  0.036  0.456  0.847  1.0
  F  F9  1  0.413  0.250  0.839  1.0
  F  F10  1  0.636  0.947  0.909  1.0
  F  F11  1  0.636  0.553  0.909  1.0
  F  F12  1  0.352  0.946  0.674  1.0
  F  F13  1  0.352  0.554  0.674  1.0
  F  F14  1  0.544  0.250  0.556  1.0
  F  F15  1  0.749  0.944  0.602  1.0
  F  F16  1  0.749  0.556  0.602  1.0
  F  F17  1  0.456  0.750  0.444  1.0
  F  F18  1  0.251  0.444  0.398  1.0
  F  F19  1  0.251  0.056  0.398  1.0
  F  F20  1  0.648  0.446  0.326  1.0
  F  F21  1  0.648  0.054  0.326  1.0
  F  F22  1  0.364  0.447  0.091  1.0
  F  F23  1  0.364  0.053  0.091  1.0
  F  F24  1  0.587  0.750  0.161  1.0
  F  F25  1  0.964  0.956  0.153  1.0
  F  F26  1  0.964  0.544  0.153  1.0
  F  F27  1  0.746  0.250  0.066  1.0
  Li  Li28  1  0.859  0.250  0.854  1.0
  Li  Li29  1  0.759  0.750  0.747  1.0
  Li  Li30  1  0.241  0.250  0.253  1.0
  Li  Li31  1  0.141  0.750  0.146  1.0
[/CIF]
.