The material described by Li4Ga4P4O17F3 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(13), one O(17), one O(6), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(14), one O(2), one O(5), one O(7), and one F(1) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(15), one O(3), one O(6), one O(8), and one F(2) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(16), one O(4), one O(5), one O(7), and one F(3) atom. There are four inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(4), one O(6), one O(7), one F(1), and one F(2) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(3)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 46°. In the second Ga site, Ga(2) is bonded to one O(17), one O(2), one O(3), one O(5), one O(8), and one F(3) atom to form GaO5F octahedra that share  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(3)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the third Ga site, Ga(3) is bonded to one O(11), one O(14), one O(16), one O(17), one O(9), and one F(2) atom to form GaO5F octahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the fourth Ga site, Ga(4) is bonded to one O(10), one O(12), one O(13), one O(15), one F(1), and one F(3) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 46°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(13), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra, and  a cornercorner with one Ga(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 35-55°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(2), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra, and  a cornercorner with one Ga(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 37-53°. In the third P site, P(3) is bonded to one O(11), one O(15), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra, and  a cornercorner with one Ga(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 33-54°. In the fourth P site, P(4) is bonded to one O(12), one O(16), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra, and  a cornercorner with one Ga(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 35-53°. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(1), one Ga(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(2), one Ga(2), and one P(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(3), one Ga(2), and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(4), one Ga(1), and one P(4) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(4), one Ga(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one Ga(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(4), one Ga(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one Ga(2), and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Ga(4) and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Ga(3) and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Ga(4) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Li(1), one Ga(4), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(2), one Ga(3), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(3), one Ga(4), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(4), one Ga(3), and one P(4) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Li(1), one Ga(2), and one Ga(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one Ga(1), and one Ga(4) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Ga(1), and one Ga(3) atom. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one Ga(2), and one Ga(4) atom. is represented by the CIF card [CIF]
data_Li4Ga4P4O17F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.834
_cell_length_b   7.454
_cell_length_c   7.645
_cell_angle_alpha   116.415
_cell_angle_beta   90.822
_cell_angle_gamma   90.688
_symmetry_Int_Tables_number   1
_cell_volume   348.701
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.346  0.938  0.722  1.0
  Li  Li1  1  0.844  0.433  0.219  1.0
  Li  Li2  1  0.156  0.565  0.782  1.0
  Li  Li3  1  0.655  0.068  0.281  1.0
  Ga  Ga4  1  0.001  1.000  0.001  1.0
  Ga  Ga5  1  0.498  0.505  0.497  1.0
  Ga  Ga6  1  0.255  0.748  0.253  1.0
  Ga  Ga7  1  0.748  0.250  0.749  1.0
  P  P8  1  0.396  0.282  0.043  1.0
  P  P9  1  0.896  0.783  0.545  1.0
  P  P10  1  0.102  0.217  0.456  1.0
  P  P11  1  0.605  0.716  0.955  1.0
  O  O12  1  0.266  0.102  0.024  1.0
  O  O13  1  0.767  0.602  0.525  1.0
  O  O14  1  0.234  0.397  0.476  1.0
  O  O15  1  0.736  0.896  0.974  1.0
  O  O16  1  0.549  0.335  0.214  1.0
  O  O17  1  0.048  0.839  0.718  1.0
  O  O18  1  0.950  0.163  0.283  1.0
  O  O19  1  0.452  0.660  0.785  1.0
  O  O20  1  0.274  0.462  0.066  1.0
  O  O21  1  0.773  0.964  0.569  1.0
  O  O22  1  0.224  0.037  0.429  1.0
  O  O23  1  0.727  0.535  0.931  1.0
  O  O24  1  0.505  0.193  0.845  1.0
  O  O25  1  0.004  0.694  0.347  1.0
  O  O26  1  0.993  0.306  0.653  1.0
  O  O27  1  0.499  0.808  0.155  1.0
  O  O28  1  0.395  0.728  0.464  1.0
  F  F29  1  0.900  0.229  0.964  1.0
  F  F30  1  0.102  0.771  0.038  1.0
  F  F31  1  0.600  0.273  0.536  1.0
[/CIF]
.
The material described by Li4Ga4P4O17F3 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(13), one O(17), one O(6), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(14), one O(2), one O(5), one O(7), and one F(1) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(15), one O(3), one O(6), one O(8), and one F(2) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(16), one O(4), one O(5), one O(7), and one F(3) atom. There are four inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(4), one O(6), one O(7), one F(1), and one F(2) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(3)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 46°. In the second Ga site, Ga(2) is bonded to one O(17), one O(2), one O(3), one O(5), one O(8), and one F(3) atom to form GaO5F octahedra that share  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(3)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the third Ga site, Ga(3) is bonded to one O(11), one O(14), one O(16), one O(17), one O(9), and one F(2) atom to form GaO5F octahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the fourth Ga site, Ga(4) is bonded to one O(10), one O(12), one O(13), one O(15), one F(1), and one F(3) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 46°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(13), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra, and  a cornercorner with one Ga(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 35-55°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(2), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra, and  a cornercorner with one Ga(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 37-53°. In the third P site, P(3) is bonded to one O(11), one O(15), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra, and  a cornercorner with one Ga(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 33-54°. In the fourth P site, P(4) is bonded to one O(12), one O(16), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4F2 octahedra,  a cornercorner with one Ga(2)O5F octahedra, and  a cornercorner with one Ga(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 35-53°. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(1), one Ga(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(2), one Ga(2), and one P(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(3), one Ga(2), and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(4), one Ga(1), and one P(4) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(4), one Ga(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one Ga(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(4), one Ga(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one Ga(2), and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Ga(4) and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Ga(3) and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Ga(4) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Li(1), one Ga(4), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(2), one Ga(3), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(3), one Ga(4), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(4), one Ga(3), and one P(4) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Li(1), one Ga(2), and one Ga(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one Ga(1), and one Ga(4) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Ga(1), and one Ga(3) atom. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one Ga(2), and one Ga(4) atom. is represented by the CIF card [CIF]
data_Li4Ga4P4O17F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.834
_cell_length_b   7.454
_cell_length_c   7.645
_cell_angle_alpha   116.415
_cell_angle_beta   90.822
_cell_angle_gamma   90.688
_symmetry_Int_Tables_number   1
_cell_volume   348.701
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.346  0.938  0.722  1.0
  Li  Li1  1  0.844  0.433  0.219  1.0
  Li  Li2  1  0.156  0.565  0.782  1.0
  Li  Li3  1  0.655  0.068  0.281  1.0
  Ga  Ga4  1  0.001  1.000  0.001  1.0
  Ga  Ga5  1  0.498  0.505  0.497  1.0
  Ga  Ga6  1  0.255  0.748  0.253  1.0
  Ga  Ga7  1  0.748  0.250  0.749  1.0
  P  P8  1  0.396  0.282  0.043  1.0
  P  P9  1  0.896  0.783  0.545  1.0
  P  P10  1  0.102  0.217  0.456  1.0
  P  P11  1  0.605  0.716  0.955  1.0
  O  O12  1  0.266  0.102  0.024  1.0
  O  O13  1  0.767  0.602  0.525  1.0
  O  O14  1  0.234  0.397  0.476  1.0
  O  O15  1  0.736  0.896  0.974  1.0
  O  O16  1  0.549  0.335  0.214  1.0
  O  O17  1  0.048  0.839  0.718  1.0
  O  O18  1  0.950  0.163  0.283  1.0
  O  O19  1  0.452  0.660  0.785  1.0
  O  O20  1  0.274  0.462  0.066  1.0
  O  O21  1  0.773  0.964  0.569  1.0
  O  O22  1  0.224  0.037  0.429  1.0
  O  O23  1  0.727  0.535  0.931  1.0
  O  O24  1  0.505  0.193  0.845  1.0
  O  O25  1  0.004  0.694  0.347  1.0
  O  O26  1  0.993  0.306  0.653  1.0
  O  O27  1  0.499  0.808  0.155  1.0
  O  O28  1  0.395  0.728  0.464  1.0
  F  F29  1  0.900  0.229  0.964  1.0
  F  F30  1  0.102  0.771  0.038  1.0
  F  F31  1  0.600  0.273  0.536  1.0
[/CIF]
.