The compound described by PdF4 crystallizes in the triclinic P1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to one F(3), one F(4), one F(5), one F(6), one F(7), and one F(8) atom to form corner-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second Pd site, Pd(2) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form corner-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Pd(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Pd(2) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. In the sixth F site, F(6) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Pd(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF file [CIF]
data_PdF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.691
_cell_length_b   5.649
_cell_length_c   5.582
_cell_angle_alpha   73.133
_cell_angle_beta   53.897
_cell_angle_gamma   52.971
_symmetry_Int_Tables_number   1
_cell_volume   135.424
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.256  0.249  0.237  1.0
  Pd  Pd1  1  0.015  0.993  0.991  1.0
  F  F2  1  0.418  0.765  0.795  1.0
  F  F3  1  0.026  0.795  0.754  1.0
  F  F4  1  0.016  0.297  0.692  1.0
  F  F5  1  0.983  0.708  0.297  1.0
  F  F6  1  0.554  0.258  0.237  1.0
  F  F7  1  0.948  0.234  0.265  1.0
  F  F8  1  0.494  0.827  0.228  1.0
  F  F9  1  0.456  0.231  0.831  1.0
[/CIF]
.
The compound described by PdF4 crystallizes in the triclinic P1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to one F(3), one F(4), one F(5), one F(6), one F(7), and one F(8) atom to form corner-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second Pd site, Pd(2) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form corner-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Pd(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Pd(2) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. In the sixth F site, F(6) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Pd(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF file [CIF]
data_PdF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.691
_cell_length_b   5.649
_cell_length_c   5.582
_cell_angle_alpha   73.133
_cell_angle_beta   53.897
_cell_angle_gamma   52.971
_symmetry_Int_Tables_number   1
_cell_volume   135.424
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.256  0.249  0.237  1.0
  Pd  Pd1  1  0.015  0.993  0.991  1.0
  F  F2  1  0.418  0.765  0.795  1.0
  F  F3  1  0.026  0.795  0.754  1.0
  F  F4  1  0.016  0.297  0.692  1.0
  F  F5  1  0.983  0.708  0.297  1.0
  F  F6  1  0.554  0.258  0.237  1.0
  F  F7  1  0.948  0.234  0.265  1.0
  F  F8  1  0.494  0.827  0.228  1.0
  F  F9  1  0.456  0.231  0.831  1.0
[/CIF]
.