The crystal structure described by Pd6B(Pd5B)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Pd5B clusters and four Pd6B clusters. In each Pd5B cluster, there are five inequivalent Pd sites. In the first Pd site, Pd(7) is bonded in an L-shaped geometry to two equivalent B(2) atoms. In the second Pd site, Pd(8) is bonded in a single-bond geometry to one B(2) atom. In the third Pd site, Pd(9) is bonded in a single-bond geometry to one B(2) atom. In the fourth Pd site, Pd(3) is bonded in a single-bond geometry to one B(2) atom. In the fifth Pd site, Pd(5) is bonded in a single-bond geometry to one B(2) atom. B(2) is bonded to one Pd(3), one Pd(5), one Pd(8), one Pd(9), and two equivalent Pd(7) atoms to form edge-sharing BPd6 octahedra. In each Pd6B cluster, there are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one B(1) atom. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one B(1) atom. In the third Pd site, Pd(4) is bonded in a single-bond geometry to one B(1) atom. In the fourth Pd site, Pd(6) is bonded in a single-bond geometry to one B(1) atom. B(1) is bonded in an octahedral geometry to one Pd(1), one Pd(2), two equivalent Pd(4), and two equivalent Pd(6) atoms. is represented by the CIF file [CIF]
data_B3Pd16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.110
_cell_length_b   9.076
_cell_length_c   9.026
_cell_angle_alpha   113.740
_cell_angle_beta   90.000
_cell_angle_gamma   116.536
_symmetry_Int_Tables_number   1
_cell_volume   530.818
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.625  0.000  0.750  1.0
  B  B1  1  0.375  0.000  0.250  1.0
  B  B2  1  0.933  0.633  0.501  1.0
  B  B3  1  0.699  0.633  0.001  1.0
  B  B4  1  0.067  0.367  0.499  1.0
  B  B5  1  0.301  0.367  0.999  1.0
  Pd  Pd6  1  0.370  0.000  0.750  1.0
  Pd  Pd7  1  0.630  0.000  0.250  1.0
  Pd  Pd8  1  0.879  0.000  0.750  1.0
  Pd  Pd9  1  0.121  0.000  0.250  1.0
  Pd  Pd10  1  0.066  0.883  0.500  1.0
  Pd  Pd11  1  0.817  0.883  1.000  1.0
  Pd  Pd12  1  0.934  0.117  0.500  1.0
  Pd  Pd13  1  0.183  0.117  0.000  1.0
  Pd  Pd14  1  0.561  0.872  0.493  1.0
  Pd  Pd15  1  0.311  0.872  0.993  1.0
  Pd  Pd16  1  0.439  0.128  0.507  1.0
  Pd  Pd17  1  0.689  0.128  0.007  1.0
  Pd  Pd18  1  0.001  0.753  0.755  1.0
  Pd  Pd19  1  0.752  0.753  0.255  1.0
  Pd  Pd20  1  0.999  0.247  0.245  1.0
  Pd  Pd21  1  0.248  0.247  0.745  1.0
  Pd  Pd22  1  0.499  0.746  0.750  1.0
  Pd  Pd23  1  0.247  0.746  0.250  1.0
  Pd  Pd24  1  0.501  0.254  0.250  1.0
  Pd  Pd25  1  0.753  0.254  0.750  1.0
  Pd  Pd26  1  0.192  0.628  0.501  1.0
  Pd  Pd27  1  0.436  0.628  0.001  1.0
  Pd  Pd28  1  0.808  0.372  0.499  1.0
  Pd  Pd29  1  0.564  0.372  0.999  1.0
  Pd  Pd30  1  0.679  0.626  0.500  1.0
  Pd  Pd31  1  0.947  0.626  1.000  1.0
  Pd  Pd32  1  0.321  0.374  0.500  1.0
  Pd  Pd33  1  0.053  0.374  0.000  1.0
  Pd  Pd34  1  0.873  0.498  0.245  1.0
  Pd  Pd35  1  0.625  0.498  0.745  1.0
  Pd  Pd36  1  0.127  0.502  0.755  1.0
  Pd  Pd37  1  0.375  0.502  0.255  1.0
[/CIF]
.
The crystal structure described by Pd6B(Pd5B)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Pd5B clusters and four Pd6B clusters. In each Pd5B cluster, there are five inequivalent Pd sites. In the first Pd site, Pd(7) is bonded in an L-shaped geometry to two equivalent B(2) atoms. In the second Pd site, Pd(8) is bonded in a single-bond geometry to one B(2) atom. In the third Pd site, Pd(9) is bonded in a single-bond geometry to one B(2) atom. In the fourth Pd site, Pd(3) is bonded in a single-bond geometry to one B(2) atom. In the fifth Pd site, Pd(5) is bonded in a single-bond geometry to one B(2) atom. B(2) is bonded to one Pd(3), one Pd(5), one Pd(8), one Pd(9), and two equivalent Pd(7) atoms to form edge-sharing BPd6 octahedra. In each Pd6B cluster, there are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one B(1) atom. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one B(1) atom. In the third Pd site, Pd(4) is bonded in a single-bond geometry to one B(1) atom. In the fourth Pd site, Pd(6) is bonded in a single-bond geometry to one B(1) atom. B(1) is bonded in an octahedral geometry to one Pd(1), one Pd(2), two equivalent Pd(4), and two equivalent Pd(6) atoms. is represented by the CIF file [CIF]
data_B3Pd16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.110
_cell_length_b   9.076
_cell_length_c   9.026
_cell_angle_alpha   113.740
_cell_angle_beta   90.000
_cell_angle_gamma   116.536
_symmetry_Int_Tables_number   1
_cell_volume   530.818
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.625  0.000  0.750  1.0
  B  B1  1  0.375  0.000  0.250  1.0
  B  B2  1  0.933  0.633  0.501  1.0
  B  B3  1  0.699  0.633  0.001  1.0
  B  B4  1  0.067  0.367  0.499  1.0
  B  B5  1  0.301  0.367  0.999  1.0
  Pd  Pd6  1  0.370  0.000  0.750  1.0
  Pd  Pd7  1  0.630  0.000  0.250  1.0
  Pd  Pd8  1  0.879  0.000  0.750  1.0
  Pd  Pd9  1  0.121  0.000  0.250  1.0
  Pd  Pd10  1  0.066  0.883  0.500  1.0
  Pd  Pd11  1  0.817  0.883  1.000  1.0
  Pd  Pd12  1  0.934  0.117  0.500  1.0
  Pd  Pd13  1  0.183  0.117  0.000  1.0
  Pd  Pd14  1  0.561  0.872  0.493  1.0
  Pd  Pd15  1  0.311  0.872  0.993  1.0
  Pd  Pd16  1  0.439  0.128  0.507  1.0
  Pd  Pd17  1  0.689  0.128  0.007  1.0
  Pd  Pd18  1  0.001  0.753  0.755  1.0
  Pd  Pd19  1  0.752  0.753  0.255  1.0
  Pd  Pd20  1  0.999  0.247  0.245  1.0
  Pd  Pd21  1  0.248  0.247  0.745  1.0
  Pd  Pd22  1  0.499  0.746  0.750  1.0
  Pd  Pd23  1  0.247  0.746  0.250  1.0
  Pd  Pd24  1  0.501  0.254  0.250  1.0
  Pd  Pd25  1  0.753  0.254  0.750  1.0
  Pd  Pd26  1  0.192  0.628  0.501  1.0
  Pd  Pd27  1  0.436  0.628  0.001  1.0
  Pd  Pd28  1  0.808  0.372  0.499  1.0
  Pd  Pd29  1  0.564  0.372  0.999  1.0
  Pd  Pd30  1  0.679  0.626  0.500  1.0
  Pd  Pd31  1  0.947  0.626  1.000  1.0
  Pd  Pd32  1  0.321  0.374  0.500  1.0
  Pd  Pd33  1  0.053  0.374  0.000  1.0
  Pd  Pd34  1  0.873  0.498  0.245  1.0
  Pd  Pd35  1  0.625  0.498  0.745  1.0
  Pd  Pd36  1  0.127  0.502  0.755  1.0
  Pd  Pd37  1  0.375  0.502  0.255  1.0
[/CIF]
.