The structure described by Te(OBr3)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and two Te(OBr3)2 clusters. In each Te(OBr3)2 cluster, Te(1) is bonded in an octahedral geometry to two equivalent Br(1), two equivalent Br(2), and two equivalent Br(3) atoms. O(1) is bonded in a single-bond geometry to one Br(1) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted water-like geometry to one Te(1) and one O(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_Te(Br3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.909
_cell_length_b   8.841
_cell_length_c   14.091
_cell_angle_alpha   54.673
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   905.503
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.500  0.000  0.500  1.0
  Te  Te1  1  0.000  0.000  0.000  1.0
  Br  Br2  1  0.215  0.319  0.858  1.0
  Br  Br3  1  0.785  0.681  0.142  1.0
  Br  Br4  1  0.715  0.681  0.642  1.0
  Br  Br5  1  0.285  0.319  0.358  1.0
  Br  Br6  1  0.307  0.801  0.675  1.0
  Br  Br7  1  0.693  0.199  0.325  1.0
  Br  Br8  1  0.807  0.199  0.825  1.0
  Br  Br9  1  0.193  0.801  0.175  1.0
  Br  Br10  1  0.098  0.836  0.903  1.0
  Br  Br11  1  0.902  0.164  0.097  1.0
  Br  Br12  1  0.598  0.164  0.597  1.0
  Br  Br13  1  0.402  0.836  0.403  1.0
  O  O14  1  0.871  0.747  0.680  1.0
  O  O15  1  0.129  0.253  0.320  1.0
  O  O16  1  0.371  0.253  0.820  1.0
  O  O17  1  0.629  0.747  0.180  1.0
  O  O18  1  0.167  0.489  0.571  1.0
  O  O19  1  0.833  0.511  0.429  1.0
  O  O20  1  0.667  0.511  0.929  1.0
  O  O21  1  0.333  0.489  0.071  1.0
  O  O22  1  0.081  0.612  0.564  1.0
  O  O23  1  0.919  0.388  0.436  1.0
  O  O24  1  0.581  0.388  0.936  1.0
  O  O25  1  0.419  0.612  0.064  1.0
  O  O26  1  0.480  0.734  0.965  1.0
  O  O27  1  0.520  0.266  0.035  1.0
  O  O28  1  0.980  0.266  0.535  1.0
  O  O29  1  0.020  0.734  0.465  1.0
[/CIF]
.
The structure described by Te(OBr3)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and two Te(OBr3)2 clusters. In each Te(OBr3)2 cluster, Te(1) is bonded in an octahedral geometry to two equivalent Br(1), two equivalent Br(2), and two equivalent Br(3) atoms. O(1) is bonded in a single-bond geometry to one Br(1) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted water-like geometry to one Te(1) and one O(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_Te(Br3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.909
_cell_length_b   8.841
_cell_length_c   14.091
_cell_angle_alpha   54.673
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   905.503
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.500  0.000  0.500  1.0
  Te  Te1  1  0.000  0.000  0.000  1.0
  Br  Br2  1  0.215  0.319  0.858  1.0
  Br  Br3  1  0.785  0.681  0.142  1.0
  Br  Br4  1  0.715  0.681  0.642  1.0
  Br  Br5  1  0.285  0.319  0.358  1.0
  Br  Br6  1  0.307  0.801  0.675  1.0
  Br  Br7  1  0.693  0.199  0.325  1.0
  Br  Br8  1  0.807  0.199  0.825  1.0
  Br  Br9  1  0.193  0.801  0.175  1.0
  Br  Br10  1  0.098  0.836  0.903  1.0
  Br  Br11  1  0.902  0.164  0.097  1.0
  Br  Br12  1  0.598  0.164  0.597  1.0
  Br  Br13  1  0.402  0.836  0.403  1.0
  O  O14  1  0.871  0.747  0.680  1.0
  O  O15  1  0.129  0.253  0.320  1.0
  O  O16  1  0.371  0.253  0.820  1.0
  O  O17  1  0.629  0.747  0.180  1.0
  O  O18  1  0.167  0.489  0.571  1.0
  O  O19  1  0.833  0.511  0.429  1.0
  O  O20  1  0.667  0.511  0.929  1.0
  O  O21  1  0.333  0.489  0.071  1.0
  O  O22  1  0.081  0.612  0.564  1.0
  O  O23  1  0.919  0.388  0.436  1.0
  O  O24  1  0.581  0.388  0.936  1.0
  O  O25  1  0.419  0.612  0.064  1.0
  O  O26  1  0.480  0.734  0.965  1.0
  O  O27  1  0.520  0.266  0.035  1.0
  O  O28  1  0.980  0.266  0.535  1.0
  O  O29  1  0.020  0.734  0.465  1.0
[/CIF]
.