The structure described by UO4U(NO6)2(NO3)2 is Cyanogen Chloride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules, one U(NO6)2 cluster, and one UO4 cluster. In the U(NO6)2 cluster, U(1) is bonded in a distorted linear geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(9) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one U(1) and one O(11) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one U(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one U(1) and one N(1) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(11) is bonded in a single-bond geometry to one O(2) atom. In the UO4 cluster, U(2) is bonded in a square co-planar geometry to four equivalent O(5,6) atoms. O(5,6) is bonded in a single-bond geometry to one U(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_UN2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.903
_cell_length_b   7.224
_cell_length_c   10.238
_cell_angle_alpha   84.986
_cell_angle_beta   80.427
_cell_angle_gamma   68.389
_symmetry_Int_Tables_number   1
_cell_volume   467.840
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.500  0.500  0.500  1.0
  U  U1  1  0.000  0.500  0.000  1.0
  N  N2  1  0.739  0.752  0.530  1.0
  N  N3  1  0.261  0.248  0.470  1.0
  N  N4  1  0.404  0.174  0.115  1.0
  N  N5  1  0.596  0.826  0.885  1.0
  O  O6  1  0.289  0.648  0.616  1.0
  O  O7  1  0.711  0.352  0.384  1.0
  O  O8  1  0.680  0.247  0.689  1.0
  O  O9  1  0.320  0.753  0.311  1.0
  O  O10  1  0.634  0.772  0.433  1.0
  O  O11  1  0.366  0.228  0.567  1.0
  O  O12  1  0.730  0.609  0.615  1.0
  O  O13  1  0.270  0.391  0.385  1.0
  O  O14  1  0.090  0.394  0.834  1.0
  O  O15  1  0.910  0.606  0.166  1.0
  O  O16  1  0.857  0.329  0.046  1.0
  O  O17  1  0.143  0.671  0.954  1.0
  O  O18  1  0.235  0.140  0.122  1.0
  O  O19  1  0.765  0.860  0.878  1.0
  O  O20  1  0.406  0.337  0.057  1.0
  O  O21  1  0.594  0.663  0.943  1.0
  O  O22  1  0.838  0.857  0.541  1.0
  O  O23  1  0.162  0.143  0.459  1.0
  O  O24  1  0.559  0.055  0.161  1.0
  O  O25  1  0.441  0.945  0.839  1.0
  O  O26  1  0.134  0.846  0.301  1.0
  O  O27  1  0.866  0.154  0.699  1.0
[/CIF]
.
The structure described by UO4U(NO6)2(NO3)2 is Cyanogen Chloride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules, one U(NO6)2 cluster, and one UO4 cluster. In the U(NO6)2 cluster, U(1) is bonded in a distorted linear geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(9) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one U(1) and one O(11) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one U(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one U(1) and one N(1) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(11) is bonded in a single-bond geometry to one O(2) atom. In the UO4 cluster, U(2) is bonded in a square co-planar geometry to four equivalent O(5,6) atoms. O(5,6) is bonded in a single-bond geometry to one U(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_UN2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.903
_cell_length_b   7.224
_cell_length_c   10.238
_cell_angle_alpha   84.986
_cell_angle_beta   80.427
_cell_angle_gamma   68.389
_symmetry_Int_Tables_number   1
_cell_volume   467.840
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.500  0.500  0.500  1.0
  U  U1  1  0.000  0.500  0.000  1.0
  N  N2  1  0.739  0.752  0.530  1.0
  N  N3  1  0.261  0.248  0.470  1.0
  N  N4  1  0.404  0.174  0.115  1.0
  N  N5  1  0.596  0.826  0.885  1.0
  O  O6  1  0.289  0.648  0.616  1.0
  O  O7  1  0.711  0.352  0.384  1.0
  O  O8  1  0.680  0.247  0.689  1.0
  O  O9  1  0.320  0.753  0.311  1.0
  O  O10  1  0.634  0.772  0.433  1.0
  O  O11  1  0.366  0.228  0.567  1.0
  O  O12  1  0.730  0.609  0.615  1.0
  O  O13  1  0.270  0.391  0.385  1.0
  O  O14  1  0.090  0.394  0.834  1.0
  O  O15  1  0.910  0.606  0.166  1.0
  O  O16  1  0.857  0.329  0.046  1.0
  O  O17  1  0.143  0.671  0.954  1.0
  O  O18  1  0.235  0.140  0.122  1.0
  O  O19  1  0.765  0.860  0.878  1.0
  O  O20  1  0.406  0.337  0.057  1.0
  O  O21  1  0.594  0.663  0.943  1.0
  O  O22  1  0.838  0.857  0.541  1.0
  O  O23  1  0.162  0.143  0.459  1.0
  O  O24  1  0.559  0.055  0.161  1.0
  O  O25  1  0.441  0.945  0.839  1.0
  O  O26  1  0.134  0.846  0.301  1.0
  O  O27  1  0.866  0.154  0.699  1.0
[/CIF]
.