The structure described by Rb3EuF6 crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. In the second Rb site, Rb(2) is bonded in a linear geometry to two equivalent F(2) atoms. Eu(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Rb(1) and one Eu(1) atom. In the second F site, F(2) is bonded in a linear geometry to one Rb(2) and one Eu(1) atom. is represented by the CIF file [CIF]
data_Rb3EuF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.069
_cell_length_b   7.069
_cell_length_c   7.069
_cell_angle_alpha   119.003
_cell_angle_beta   119.003
_cell_angle_gamma   91.736
_symmetry_Int_Tables_number   1
_cell_volume   253.463
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.250  0.500  1.0
  Rb  Rb1  1  0.250  0.750  0.500  1.0
  Rb  Rb2  1  0.500  0.500  0.000  1.0
  Eu  Eu3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.000  0.311  0.311  1.0
  F  F5  1  0.000  0.689  0.689  1.0
  F  F6  1  0.311  0.000  0.311  1.0
  F  F7  1  0.689  0.000  0.689  1.0
  F  F8  1  0.234  0.234  0.000  1.0
  F  F9  1  0.766  0.766  0.000  1.0
[/CIF]
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The structure described by Rb3EuF6 crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. In the second Rb site, Rb(2) is bonded in a linear geometry to two equivalent F(2) atoms. Eu(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Rb(1) and one Eu(1) atom. In the second F site, F(2) is bonded in a linear geometry to one Rb(2) and one Eu(1) atom. is represented by the CIF file [CIF]
data_Rb3EuF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.069
_cell_length_b   7.069
_cell_length_c   7.069
_cell_angle_alpha   119.003
_cell_angle_beta   119.003
_cell_angle_gamma   91.736
_symmetry_Int_Tables_number   1
_cell_volume   253.463
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.250  0.500  1.0
  Rb  Rb1  1  0.250  0.750  0.500  1.0
  Rb  Rb2  1  0.500  0.500  0.000  1.0
  Eu  Eu3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.000  0.311  0.311  1.0
  F  F5  1  0.000  0.689  0.689  1.0
  F  F6  1  0.311  0.000  0.311  1.0
  F  F7  1  0.689  0.000  0.689  1.0
  F  F8  1  0.234  0.234  0.000  1.0
  F  F9  1  0.766  0.766  0.000  1.0
[/CIF]
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