The material structure described by Na5LiMn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(23), one O(25), one O(7), one O(8), and two equivalent O(1) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(10), one O(24), one O(26), one O(9), and two equivalent O(2) atoms. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(14), one O(3), one O(5), and two equivalent O(7) atoms. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(13), one O(4), one O(6), and two equivalent O(8) atoms. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(12), one O(13), one O(2), one O(4), one O(6), and two equivalent O(9) atoms. In the sixth Na site, Na(6) is bonded in a 7-coordinate geometry to one O(12), one O(14), one O(2), one O(3), one O(5), and two equivalent O(10) atoms. In the seventh Na site, Na(7) is bonded in a 7-coordinate geometry to one O(15), one O(17), one O(23), one O(25), one O(28), and two equivalent O(19) atoms. In the eighth Na site, Na(8) is bonded in a 7-coordinate geometry to one O(16), one O(18), one O(24), one O(26), one O(27), and two equivalent O(21) atoms. In the ninth Na site, Na(9) is bonded in a 7-coordinate geometry to one O(15), one O(18), one O(23), one O(25), one O(27), and two equivalent O(22) atoms. In the tenth Na site, Na(10) is bonded in a 6-coordinate geometry to one O(19), one O(20), one O(4), one O(6), and two equivalent O(28) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(16), one O(17), one O(20), one O(24), one O(26), and one O(28) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(21), one O(22), one O(27), one O(3), and one O(5) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(13), one O(17), one O(4), one O(6), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(14), one O(18), one O(3), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. In the third Mn site, Mn(3) is bonded to one O(11), one O(15), one O(19), one O(22), one O(23), and one O(25) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(16), one O(20), one O(21), one O(24), and one O(26) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(28), one O(4), and one O(6) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(5) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(2), one O(24), and one O(26) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(1), one O(23), and one O(25) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(12), one O(16), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-60°. In the second P site, P(2) is bonded to one O(11), one O(15), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. In the third P site, P(3) is bonded to one O(13), one O(17), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. In the fourth P site, P(4) is bonded to one O(14), one O(18), one O(21), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-57°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Na(3), one Na(4), two equivalent Na(1), and one C(4) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Na(5), one Na(6), two equivalent Na(2), and one C(3) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(3), one Na(6), one Li(2), one Mn(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(10), one Na(4), one Na(5), one Mn(1), and one C(1) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Na(3), one Na(6), one Li(2), one Mn(2), and one C(2) atom. In the sixth O site, O(6) is bonded to one Na(10), one Na(4), one Na(5), one Mn(1), and one C(1) atom to form distorted ONa3MnC trigonal bipyramids that share  a cornercorner with one O(11)Na2MnP tetrahedra,  a cornercorner with one O(12)Na2MnP tetrahedra,  a cornercorner with one O(17)NaLiMnP tetrahedra, and  a cornercorner with one O(20)NaLiMnP trigonal pyramid. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Na(1), two equivalent Na(3), one Mn(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Na(1), two equivalent Na(4), one Mn(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Na(2), two equivalent Na(5), one Mn(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Na(2), two equivalent Na(6), one Mn(2), and one P(1) atom. In the eleventh O site, O(11) is bonded to one Na(3), one Na(4), one Mn(3), and one P(2) atom to form distorted corner-sharing ONa2MnP tetrahedra. In the twelfth O site, O(12) is bonded to one Na(5), one Na(6), one Mn(4), and one P(1) atom to form distorted ONa2MnP tetrahedra that share  a cornercorner with one O(24)Na2LiMnC trigonal bipyramid,  a cornercorner with one O(6)Na3MnC trigonal bipyramid, and  a cornercorner with one O(20)NaLiMnP trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Na(4), one Na(5), one Mn(1), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Na(3), one Na(6), one Mn(2), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Na(7), one Na(9), one Mn(3), and one P(2) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Na(8), one Li(1), one Mn(4), and one P(1) atom. In the seventeenth O site, O(17) is bonded to one Na(7), one Li(1), one Mn(1), and one P(3) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(24)Na2LiMnC trigonal bipyramid,  a cornercorner with one O(23)Na3MnC trigonal bipyramid,  a cornercorner with one O(6)Na3MnC trigonal bipyramid, and corners with two equivalent O(20)NaLiMnP trigonal pyramids. In the eighteenth O site, O(18) is bonded to one Na(8), one Na(9), one Mn(2), and one P(4) atom to form distorted ONa2MnP tetrahedra that share  a cornercorner with one O(24)Na2LiMnC trigonal bipyramid,  a cornercorner with one O(23)Na3MnC trigonal bipyramid, and  an edgeedge with one O(27)Na2LiC trigonal pyramid. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Na(10), two equivalent Na(7), one Mn(3), and one P(3) atom. In the twentieth O site, O(20) is bonded to one Na(10), one Li(1), one Mn(4), and one P(3) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(12)Na2MnP tetrahedra, corners with two equivalent O(17)NaLiMnP tetrahedra,  a cornercorner with one O(6)Na3MnC trigonal bipyramid, and corners with two equivalent O(24)Na2LiMnC trigonal bipyramids. In the twenty-first O site, O(21) is bonded in a 5-coordinate geometry to two equivalent Na(8), one Li(2), one Mn(4), and one P(4) atom. In the twenty-second O site, O(22) is bonded in a 5-coordinate geometry to two equivalent Na(9), one Li(2), one Mn(3), and one P(4) atom. In the twenty-third O site, O(23) is bonded to one Na(1), one Na(7), one Na(9), one Mn(3), and one C(4) atom to form distorted ONa3MnC trigonal bipyramids that share  a cornercorner with one O(11)Na2MnP tetrahedra,  a cornercorner with one O(18)Na2MnP tetrahedra,  a cornercorner with one O(17)NaLiMnP tetrahedra, and  a cornercorner with one O(27)Na2LiC trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Na(2), one Na(8), one Li(1), one Mn(4), and one C(3) atom to form distorted ONa2LiMnC trigonal bipyramids that share  a cornercorner with one O(12)Na2MnP tetrahedra,  a cornercorner with one O(18)Na2MnP tetrahedra,  a cornercorner with one O(17)NaLiMnP tetrahedra,  a cornercorner with one O(27)Na2LiC trigonal pyramid, and corners with two equivalent O(20)NaLiMnP trigonal pyramids. In the twenty-fifth O site, O(25) is bonded in a 5-coordinate geometry to one Na(1), one Na(7), one Na(9), one Mn(3), and one C(4) atom. In the twenty-sixth O site, O(26) is bonded in a 5-coordinate geometry to one Na(2), one Na(8), one Li(1), one Mn(4), and one C(3) atom. In the twenty-seventh O site, O(27) is bonded to one Na(8), one Na(9), one Li(2), and one C(2) atom to form distorted ONa2LiC trigonal pyramids that share  a cornercorner with one O(24)Na2LiMnC trigonal bipyramid,  a cornercorner with one O(23)Na3MnC trigonal bipyramid, and  an edgeedge with one O(18)Na2MnP tetrahedra. In the twenty-eighth O site, O(28) is bonded in a 5-coordinate geometry to one Na(7), two equivalent Na(10), one Li(1), and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5LiMn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.160
_cell_length_b   8.961
_cell_length_c   13.625
_cell_angle_alpha   90.235
_cell_angle_beta   90.120
_cell_angle_gamma   90.200
_symmetry_Int_Tables_number   1
_cell_volume   629.964
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.240  0.083  0.875  1.0
  Na  Na1  1  0.240  0.082  0.376  1.0
  Na  Na2  1  0.752  0.259  0.999  1.0
  Na  Na3  1  0.752  0.259  0.751  1.0
  Na  Na4  1  0.752  0.259  0.499  1.0
  Na  Na5  1  0.752  0.259  0.251  1.0
  Na  Na6  1  0.247  0.741  0.748  1.0
  Na  Na7  1  0.248  0.742  0.250  1.0
  Na  Na8  1  0.248  0.742  0.001  1.0
  Na  Na9  1  0.760  0.916  0.623  1.0
  Li  Li10  1  0.240  0.733  0.503  1.0
  Li  Li11  1  0.756  0.915  0.125  1.0
  Mn  Mn12  1  0.222  0.362  0.625  1.0
  Mn  Mn13  1  0.222  0.362  0.125  1.0
  Mn  Mn14  1  0.778  0.640  0.875  1.0
  Mn  Mn15  1  0.779  0.641  0.376  1.0
  P  P16  1  0.299  0.413  0.376  1.0
  P  P17  1  0.298  0.411  0.875  1.0
  P  P18  1  0.703  0.591  0.624  1.0
  P  P19  1  0.703  0.594  0.125  1.0
  C  C20  1  0.264  0.057  0.622  1.0
  C  C21  1  0.265  0.055  0.125  1.0
  C  C22  1  0.735  0.939  0.376  1.0
  C  C23  1  0.736  0.940  0.875  1.0
  O  O24  1  0.714  0.085  0.875  1.0
  O  O25  1  0.713  0.084  0.375  1.0
  O  O26  1  0.029  0.107  0.125  1.0
  O  O27  1  0.037  0.120  0.625  1.0
  O  O28  1  0.463  0.147  0.125  1.0
  O  O29  1  0.471  0.141  0.625  1.0
  O  O30  1  0.215  0.319  0.967  1.0
  O  O31  1  0.215  0.319  0.783  1.0
  O  O32  1  0.217  0.319  0.467  1.0
  O  O33  1  0.211  0.323  0.284  1.0
  O  O34  1  0.599  0.428  0.875  1.0
  O  O35  1  0.601  0.428  0.375  1.0
  O  O36  1  0.818  0.431  0.625  1.0
  O  O37  1  0.825  0.435  0.125  1.0
  O  O38  1  0.177  0.569  0.875  1.0
  O  O39  1  0.183  0.573  0.381  1.0
  O  O40  1  0.399  0.577  0.619  1.0
  O  O41  1  0.402  0.573  0.125  1.0
  O  O42  1  0.781  0.682  0.717  1.0
  O  O43  1  0.800  0.682  0.534  1.0
  O  O44  1  0.785  0.688  0.216  1.0
  O  O45  1  0.783  0.688  0.034  1.0
  O  O46  1  0.529  0.856  0.874  1.0
  O  O47  1  0.528  0.855  0.378  1.0
  O  O48  1  0.963  0.878  0.875  1.0
  O  O49  1  0.962  0.877  0.376  1.0
  O  O50  1  0.307  0.913  0.125  1.0
  O  O51  1  0.283  0.912  0.618  1.0
[/CIF]
.
The material structure described by Na5LiMn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(23), one O(25), one O(7), one O(8), and two equivalent O(1) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(10), one O(24), one O(26), one O(9), and two equivalent O(2) atoms. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(14), one O(3), one O(5), and two equivalent O(7) atoms. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(13), one O(4), one O(6), and two equivalent O(8) atoms. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(12), one O(13), one O(2), one O(4), one O(6), and two equivalent O(9) atoms. In the sixth Na site, Na(6) is bonded in a 7-coordinate geometry to one O(12), one O(14), one O(2), one O(3), one O(5), and two equivalent O(10) atoms. In the seventh Na site, Na(7) is bonded in a 7-coordinate geometry to one O(15), one O(17), one O(23), one O(25), one O(28), and two equivalent O(19) atoms. In the eighth Na site, Na(8) is bonded in a 7-coordinate geometry to one O(16), one O(18), one O(24), one O(26), one O(27), and two equivalent O(21) atoms. In the ninth Na site, Na(9) is bonded in a 7-coordinate geometry to one O(15), one O(18), one O(23), one O(25), one O(27), and two equivalent O(22) atoms. In the tenth Na site, Na(10) is bonded in a 6-coordinate geometry to one O(19), one O(20), one O(4), one O(6), and two equivalent O(28) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(16), one O(17), one O(20), one O(24), one O(26), and one O(28) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(21), one O(22), one O(27), one O(3), and one O(5) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(13), one O(17), one O(4), one O(6), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(14), one O(18), one O(3), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. In the third Mn site, Mn(3) is bonded to one O(11), one O(15), one O(19), one O(22), one O(23), and one O(25) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(16), one O(20), one O(21), one O(24), and one O(26) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(28), one O(4), and one O(6) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(5) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(2), one O(24), and one O(26) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(1), one O(23), and one O(25) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(12), one O(16), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-60°. In the second P site, P(2) is bonded to one O(11), one O(15), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. In the third P site, P(3) is bonded to one O(13), one O(17), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. In the fourth P site, P(4) is bonded to one O(14), one O(18), one O(21), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-57°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Na(3), one Na(4), two equivalent Na(1), and one C(4) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Na(5), one Na(6), two equivalent Na(2), and one C(3) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(3), one Na(6), one Li(2), one Mn(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(10), one Na(4), one Na(5), one Mn(1), and one C(1) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Na(3), one Na(6), one Li(2), one Mn(2), and one C(2) atom. In the sixth O site, O(6) is bonded to one Na(10), one Na(4), one Na(5), one Mn(1), and one C(1) atom to form distorted ONa3MnC trigonal bipyramids that share  a cornercorner with one O(11)Na2MnP tetrahedra,  a cornercorner with one O(12)Na2MnP tetrahedra,  a cornercorner with one O(17)NaLiMnP tetrahedra, and  a cornercorner with one O(20)NaLiMnP trigonal pyramid. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Na(1), two equivalent Na(3), one Mn(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Na(1), two equivalent Na(4), one Mn(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Na(2), two equivalent Na(5), one Mn(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Na(2), two equivalent Na(6), one Mn(2), and one P(1) atom. In the eleventh O site, O(11) is bonded to one Na(3), one Na(4), one Mn(3), and one P(2) atom to form distorted corner-sharing ONa2MnP tetrahedra. In the twelfth O site, O(12) is bonded to one Na(5), one Na(6), one Mn(4), and one P(1) atom to form distorted ONa2MnP tetrahedra that share  a cornercorner with one O(24)Na2LiMnC trigonal bipyramid,  a cornercorner with one O(6)Na3MnC trigonal bipyramid, and  a cornercorner with one O(20)NaLiMnP trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Na(4), one Na(5), one Mn(1), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Na(3), one Na(6), one Mn(2), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Na(7), one Na(9), one Mn(3), and one P(2) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Na(8), one Li(1), one Mn(4), and one P(1) atom. In the seventeenth O site, O(17) is bonded to one Na(7), one Li(1), one Mn(1), and one P(3) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(24)Na2LiMnC trigonal bipyramid,  a cornercorner with one O(23)Na3MnC trigonal bipyramid,  a cornercorner with one O(6)Na3MnC trigonal bipyramid, and corners with two equivalent O(20)NaLiMnP trigonal pyramids. In the eighteenth O site, O(18) is bonded to one Na(8), one Na(9), one Mn(2), and one P(4) atom to form distorted ONa2MnP tetrahedra that share  a cornercorner with one O(24)Na2LiMnC trigonal bipyramid,  a cornercorner with one O(23)Na3MnC trigonal bipyramid, and  an edgeedge with one O(27)Na2LiC trigonal pyramid. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Na(10), two equivalent Na(7), one Mn(3), and one P(3) atom. In the twentieth O site, O(20) is bonded to one Na(10), one Li(1), one Mn(4), and one P(3) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(12)Na2MnP tetrahedra, corners with two equivalent O(17)NaLiMnP tetrahedra,  a cornercorner with one O(6)Na3MnC trigonal bipyramid, and corners with two equivalent O(24)Na2LiMnC trigonal bipyramids. In the twenty-first O site, O(21) is bonded in a 5-coordinate geometry to two equivalent Na(8), one Li(2), one Mn(4), and one P(4) atom. In the twenty-second O site, O(22) is bonded in a 5-coordinate geometry to two equivalent Na(9), one Li(2), one Mn(3), and one P(4) atom. In the twenty-third O site, O(23) is bonded to one Na(1), one Na(7), one Na(9), one Mn(3), and one C(4) atom to form distorted ONa3MnC trigonal bipyramids that share  a cornercorner with one O(11)Na2MnP tetrahedra,  a cornercorner with one O(18)Na2MnP tetrahedra,  a cornercorner with one O(17)NaLiMnP tetrahedra, and  a cornercorner with one O(27)Na2LiC trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Na(2), one Na(8), one Li(1), one Mn(4), and one C(3) atom to form distorted ONa2LiMnC trigonal bipyramids that share  a cornercorner with one O(12)Na2MnP tetrahedra,  a cornercorner with one O(18)Na2MnP tetrahedra,  a cornercorner with one O(17)NaLiMnP tetrahedra,  a cornercorner with one O(27)Na2LiC trigonal pyramid, and corners with two equivalent O(20)NaLiMnP trigonal pyramids. In the twenty-fifth O site, O(25) is bonded in a 5-coordinate geometry to one Na(1), one Na(7), one Na(9), one Mn(3), and one C(4) atom. In the twenty-sixth O site, O(26) is bonded in a 5-coordinate geometry to one Na(2), one Na(8), one Li(1), one Mn(4), and one C(3) atom. In the twenty-seventh O site, O(27) is bonded to one Na(8), one Na(9), one Li(2), and one C(2) atom to form distorted ONa2LiC trigonal pyramids that share  a cornercorner with one O(24)Na2LiMnC trigonal bipyramid,  a cornercorner with one O(23)Na3MnC trigonal bipyramid, and  an edgeedge with one O(18)Na2MnP tetrahedra. In the twenty-eighth O site, O(28) is bonded in a 5-coordinate geometry to one Na(7), two equivalent Na(10), one Li(1), and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5LiMn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.160
_cell_length_b   8.961
_cell_length_c   13.625
_cell_angle_alpha   90.235
_cell_angle_beta   90.120
_cell_angle_gamma   90.200
_symmetry_Int_Tables_number   1
_cell_volume   629.964
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.240  0.083  0.875  1.0
  Na  Na1  1  0.240  0.082  0.376  1.0
  Na  Na2  1  0.752  0.259  0.999  1.0
  Na  Na3  1  0.752  0.259  0.751  1.0
  Na  Na4  1  0.752  0.259  0.499  1.0
  Na  Na5  1  0.752  0.259  0.251  1.0
  Na  Na6  1  0.247  0.741  0.748  1.0
  Na  Na7  1  0.248  0.742  0.250  1.0
  Na  Na8  1  0.248  0.742  0.001  1.0
  Na  Na9  1  0.760  0.916  0.623  1.0
  Li  Li10  1  0.240  0.733  0.503  1.0
  Li  Li11  1  0.756  0.915  0.125  1.0
  Mn  Mn12  1  0.222  0.362  0.625  1.0
  Mn  Mn13  1  0.222  0.362  0.125  1.0
  Mn  Mn14  1  0.778  0.640  0.875  1.0
  Mn  Mn15  1  0.779  0.641  0.376  1.0
  P  P16  1  0.299  0.413  0.376  1.0
  P  P17  1  0.298  0.411  0.875  1.0
  P  P18  1  0.703  0.591  0.624  1.0
  P  P19  1  0.703  0.594  0.125  1.0
  C  C20  1  0.264  0.057  0.622  1.0
  C  C21  1  0.265  0.055  0.125  1.0
  C  C22  1  0.735  0.939  0.376  1.0
  C  C23  1  0.736  0.940  0.875  1.0
  O  O24  1  0.714  0.085  0.875  1.0
  O  O25  1  0.713  0.084  0.375  1.0
  O  O26  1  0.029  0.107  0.125  1.0
  O  O27  1  0.037  0.120  0.625  1.0
  O  O28  1  0.463  0.147  0.125  1.0
  O  O29  1  0.471  0.141  0.625  1.0
  O  O30  1  0.215  0.319  0.967  1.0
  O  O31  1  0.215  0.319  0.783  1.0
  O  O32  1  0.217  0.319  0.467  1.0
  O  O33  1  0.211  0.323  0.284  1.0
  O  O34  1  0.599  0.428  0.875  1.0
  O  O35  1  0.601  0.428  0.375  1.0
  O  O36  1  0.818  0.431  0.625  1.0
  O  O37  1  0.825  0.435  0.125  1.0
  O  O38  1  0.177  0.569  0.875  1.0
  O  O39  1  0.183  0.573  0.381  1.0
  O  O40  1  0.399  0.577  0.619  1.0
  O  O41  1  0.402  0.573  0.125  1.0
  O  O42  1  0.781  0.682  0.717  1.0
  O  O43  1  0.800  0.682  0.534  1.0
  O  O44  1  0.785  0.688  0.216  1.0
  O  O45  1  0.783  0.688  0.034  1.0
  O  O46  1  0.529  0.856  0.874  1.0
  O  O47  1  0.528  0.855  0.378  1.0
  O  O48  1  0.963  0.878  0.875  1.0
  O  O49  1  0.962  0.877  0.376  1.0
  O  O50  1  0.307  0.913  0.125  1.0
  O  O51  1  0.283  0.912  0.618  1.0
[/CIF]
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