The compound described by PrPt2In2 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 7-coordinate geometry to two equivalent Pt(2), two equivalent Pt(3), and three equivalent Pt(4) atoms. In the second Pr site, Pr(2) is bonded in a 14-coordinate geometry to one Pt(2), two equivalent Pt(1), two equivalent Pt(3), one In(3), two equivalent In(2), three equivalent In(1), and three equivalent In(4) atoms. There are four inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 10-coordinate geometry to two equivalent Pr(2), one Pt(2), one Pt(4), one In(4), two equivalent In(3), and three equivalent In(1) atoms. In the second Pt site, Pt(2) is bonded in a 8-coordinate geometry to one Pr(2), two equivalent Pr(1), one Pt(1), two equivalent In(1), and three equivalent In(2) atoms. In the third Pt site, Pt(3) is bonded in a 9-coordinate geometry to two equivalent Pr(1), two equivalent Pr(2), one In(2), one In(3), and three equivalent In(4) atoms. In the fourth Pt site, Pt(4) is bonded in a 6-coordinate geometry to three equivalent Pr(1), one Pt(1), and three equivalent In(3) atoms. There are four inequivalent In sites. In the first In site, In(1) is bonded in a 5-coordinate geometry to three equivalent Pr(2), two equivalent Pt(2), and three equivalent Pt(1) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to two equivalent Pr(2), one Pt(3), and three equivalent Pt(2) atoms. In the third In site, In(3) is bonded in a 6-coordinate geometry to one Pr(2), one Pt(3), two equivalent Pt(1), and three equivalent Pt(4) atoms. In the fourth In site, In(4) is bonded in a 4-coordinate geometry to three equivalent Pr(2), one Pt(1), and three equivalent Pt(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr(InPt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.511
_cell_length_b   10.303
_cell_length_c   10.290
_cell_angle_alpha   62.820
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   425.387
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.250  0.952  0.790  1.0
  Pr  Pr1  1  0.750  0.048  0.210  1.0
  Pr  Pr2  1  0.250  0.596  0.711  1.0
  Pr  Pr3  1  0.750  0.404  0.289  1.0
  In  In4  1  0.250  0.353  0.554  1.0
  In  In5  1  0.750  0.647  0.446  1.0
  In  In6  1  0.250  0.119  0.423  1.0
  In  In7  1  0.750  0.881  0.577  1.0
  In  In8  1  0.250  0.226  0.898  1.0
  In  In9  1  0.750  0.774  0.102  1.0
  In  In10  1  0.250  0.595  0.040  1.0
  In  In11  1  0.750  0.405  0.960  1.0
  Pt  Pt12  1  0.250  0.626  0.297  1.0
  Pt  Pt13  1  0.750  0.374  0.703  1.0
  Pt  Pt14  1  0.250  0.844  0.420  1.0
  Pt  Pt15  1  0.750  0.156  0.580  1.0
  Pt  Pt16  1  0.250  0.297  0.129  1.0
  Pt  Pt17  1  0.750  0.703  0.871  1.0
  Pt  Pt18  1  0.250  0.928  0.101  1.0
  Pt  Pt19  1  0.750  0.072  0.899  1.0
[/CIF]
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The compound described by PrPt2In2 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 7-coordinate geometry to two equivalent Pt(2), two equivalent Pt(3), and three equivalent Pt(4) atoms. In the second Pr site, Pr(2) is bonded in a 14-coordinate geometry to one Pt(2), two equivalent Pt(1), two equivalent Pt(3), one In(3), two equivalent In(2), three equivalent In(1), and three equivalent In(4) atoms. There are four inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 10-coordinate geometry to two equivalent Pr(2), one Pt(2), one Pt(4), one In(4), two equivalent In(3), and three equivalent In(1) atoms. In the second Pt site, Pt(2) is bonded in a 8-coordinate geometry to one Pr(2), two equivalent Pr(1), one Pt(1), two equivalent In(1), and three equivalent In(2) atoms. In the third Pt site, Pt(3) is bonded in a 9-coordinate geometry to two equivalent Pr(1), two equivalent Pr(2), one In(2), one In(3), and three equivalent In(4) atoms. In the fourth Pt site, Pt(4) is bonded in a 6-coordinate geometry to three equivalent Pr(1), one Pt(1), and three equivalent In(3) atoms. There are four inequivalent In sites. In the first In site, In(1) is bonded in a 5-coordinate geometry to three equivalent Pr(2), two equivalent Pt(2), and three equivalent Pt(1) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to two equivalent Pr(2), one Pt(3), and three equivalent Pt(2) atoms. In the third In site, In(3) is bonded in a 6-coordinate geometry to one Pr(2), one Pt(3), two equivalent Pt(1), and three equivalent Pt(4) atoms. In the fourth In site, In(4) is bonded in a 4-coordinate geometry to three equivalent Pr(2), one Pt(1), and three equivalent Pt(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr(InPt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.511
_cell_length_b   10.303
_cell_length_c   10.290
_cell_angle_alpha   62.820
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   425.387
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.250  0.952  0.790  1.0
  Pr  Pr1  1  0.750  0.048  0.210  1.0
  Pr  Pr2  1  0.250  0.596  0.711  1.0
  Pr  Pr3  1  0.750  0.404  0.289  1.0
  In  In4  1  0.250  0.353  0.554  1.0
  In  In5  1  0.750  0.647  0.446  1.0
  In  In6  1  0.250  0.119  0.423  1.0
  In  In7  1  0.750  0.881  0.577  1.0
  In  In8  1  0.250  0.226  0.898  1.0
  In  In9  1  0.750  0.774  0.102  1.0
  In  In10  1  0.250  0.595  0.040  1.0
  In  In11  1  0.750  0.405  0.960  1.0
  Pt  Pt12  1  0.250  0.626  0.297  1.0
  Pt  Pt13  1  0.750  0.374  0.703  1.0
  Pt  Pt14  1  0.250  0.844  0.420  1.0
  Pt  Pt15  1  0.750  0.156  0.580  1.0
  Pt  Pt16  1  0.250  0.297  0.129  1.0
  Pt  Pt17  1  0.750  0.703  0.871  1.0
  Pt  Pt18  1  0.250  0.928  0.101  1.0
  Pt  Pt19  1  0.750  0.072  0.899  1.0
[/CIF]
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