The material structure described by UVO5 crystallizes in the orthorhombic Pbcm space group. U(1) is bonded to one O(4), two equivalent O(2), and four equivalent O(1) atoms to form a mixture of edge and corner-sharing UO7 pentagonal bipyramids. V(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent U(1) and one V(1) atom. In the second O site, O(2) is bonded in a linear geometry to two equivalent U(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one U(1) and two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_UVO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.119
_cell_length_b   7.265
_cell_length_c   12.640
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   378.245
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.992  0.750  0.528  1.0
  U  U1  1  0.992  0.250  0.972  1.0
  U  U2  1  0.008  0.250  0.472  1.0
  U  U3  1  0.008  0.750  0.028  1.0
  V  V4  1  0.901  0.500  0.250  1.0
  V  V5  1  0.099  0.000  0.750  1.0
  V  V6  1  0.099  0.500  0.750  1.0
  V  V7  1  0.901  0.000  0.250  1.0
  O  O8  1  0.013  0.448  0.596  1.0
  O  O9  1  0.013  0.552  0.904  1.0
  O  O10  1  0.987  0.948  0.404  1.0
  O  O11  1  0.987  0.052  0.096  1.0
  O  O12  1  0.987  0.552  0.404  1.0
  O  O13  1  0.987  0.448  0.096  1.0
  O  O14  1  0.013  0.052  0.596  1.0
  O  O15  1  0.013  0.948  0.904  1.0
  O  O16  1  0.508  0.750  0.027  1.0
  O  O17  1  0.508  0.250  0.473  1.0
  O  O18  1  0.492  0.250  0.973  1.0
  O  O19  1  0.492  0.750  0.527  1.0
  O  O20  1  0.500  0.000  0.250  1.0
  O  O21  1  0.500  0.500  0.750  1.0
  O  O22  1  0.500  0.000  0.750  1.0
  O  O23  1  0.500  0.500  0.250  1.0
  O  O24  1  0.996  0.750  0.198  1.0
  O  O25  1  0.996  0.250  0.302  1.0
  O  O26  1  0.004  0.250  0.802  1.0
  O  O27  1  0.004  0.750  0.698  1.0
[/CIF]
.
The material structure described by UVO5 crystallizes in the orthorhombic Pbcm space group. U(1) is bonded to one O(4), two equivalent O(2), and four equivalent O(1) atoms to form a mixture of edge and corner-sharing UO7 pentagonal bipyramids. V(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent U(1) and one V(1) atom. In the second O site, O(2) is bonded in a linear geometry to two equivalent U(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one U(1) and two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_UVO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.119
_cell_length_b   7.265
_cell_length_c   12.640
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   378.245
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.992  0.750  0.528  1.0
  U  U1  1  0.992  0.250  0.972  1.0
  U  U2  1  0.008  0.250  0.472  1.0
  U  U3  1  0.008  0.750  0.028  1.0
  V  V4  1  0.901  0.500  0.250  1.0
  V  V5  1  0.099  0.000  0.750  1.0
  V  V6  1  0.099  0.500  0.750  1.0
  V  V7  1  0.901  0.000  0.250  1.0
  O  O8  1  0.013  0.448  0.596  1.0
  O  O9  1  0.013  0.552  0.904  1.0
  O  O10  1  0.987  0.948  0.404  1.0
  O  O11  1  0.987  0.052  0.096  1.0
  O  O12  1  0.987  0.552  0.404  1.0
  O  O13  1  0.987  0.448  0.096  1.0
  O  O14  1  0.013  0.052  0.596  1.0
  O  O15  1  0.013  0.948  0.904  1.0
  O  O16  1  0.508  0.750  0.027  1.0
  O  O17  1  0.508  0.250  0.473  1.0
  O  O18  1  0.492  0.250  0.973  1.0
  O  O19  1  0.492  0.750  0.527  1.0
  O  O20  1  0.500  0.000  0.250  1.0
  O  O21  1  0.500  0.500  0.750  1.0
  O  O22  1  0.500  0.000  0.750  1.0
  O  O23  1  0.500  0.500  0.250  1.0
  O  O24  1  0.996  0.750  0.198  1.0
  O  O25  1  0.996  0.250  0.302  1.0
  O  O26  1  0.004  0.250  0.802  1.0
  O  O27  1  0.004  0.750  0.698  1.0
[/CIF]
.