The material structure described by LiLa2Co2Sb2(PbO6)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1), one O(12), one O(4), and one O(5) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(6), one O(7), one O(8), and one O(9) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one O(11), one O(2), one O(4), one O(5), and one O(7) atom. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(12), one O(3), one O(6), and one O(8) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 5-coordinate geometry to one Li(1), one O(1), one O(4), one O(8), and one O(9) atom. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in an octahedral geometry to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom. In the second Sb site, Sb(2) is bonded in an octahedral geometry to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one La(2), one Co(2), one Pb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Co(1), one Pb(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(1), one Co(2), one Pb(2), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), one La(2), one Co(1), one Pb(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one La(2), one Co(1), one Pb(2), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one La(1), one Co(2), one Pb(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(1), one Pb(2), and one Sb(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(1), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal pyramidal geometry to one La(1), one La(2), one Pb(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(2), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(1), one La(2), one Co(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_LiLa2Co2Sb2(PbO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.968
_cell_length_b   6.074
_cell_length_c   7.873
_cell_angle_alpha   89.794
_cell_angle_beta   90.048
_cell_angle_gamma   93.284
_symmetry_Int_Tables_number   1
_cell_volume   284.908
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.205  0.653  0.282  1.0
  La  La1  1  0.501  0.433  0.748  1.0
  La  La2  1  0.010  0.085  0.256  1.0
  Co  Co3  1  0.949  0.536  0.526  1.0
  Co  Co4  1  0.500  0.943  0.997  1.0
  Sb  Sb5  1  0.002  0.517  0.987  1.0
  Sb  Sb6  1  0.493  0.988  0.501  1.0
  Pb  Pb7  1  0.553  0.431  0.240  1.0
  Pb  Pb8  1  0.995  0.981  0.748  1.0
  O  O9  1  0.588  0.025  0.245  1.0
  O  O10  1  0.111  0.543  0.751  1.0
  O  O11  1  0.426  0.023  0.753  1.0
  O  O12  1  0.949  0.474  0.247  1.0
  O  O13  1  0.186  0.842  0.456  1.0
  O  O14  1  0.729  0.700  0.941  1.0
  O  O15  1  0.777  0.189  0.533  1.0
  O  O16  1  0.250  0.306  0.028  1.0
  O  O17  1  0.321  0.267  0.466  1.0
  O  O18  1  0.782  0.254  0.956  1.0
  O  O19  1  0.638  0.704  0.532  1.0
  O  O20  1  0.189  0.794  0.064  1.0
[/CIF]
.
The material structure described by LiLa2Co2Sb2(PbO6)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1), one O(12), one O(4), and one O(5) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(6), one O(7), one O(8), and one O(9) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one O(11), one O(2), one O(4), one O(5), and one O(7) atom. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(12), one O(3), one O(6), and one O(8) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 5-coordinate geometry to one Li(1), one O(1), one O(4), one O(8), and one O(9) atom. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in an octahedral geometry to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom. In the second Sb site, Sb(2) is bonded in an octahedral geometry to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one La(2), one Co(2), one Pb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Co(1), one Pb(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(1), one Co(2), one Pb(2), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), one La(2), one Co(1), one Pb(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one La(2), one Co(1), one Pb(2), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one La(1), one Co(2), one Pb(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(1), one Pb(2), and one Sb(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(1), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal pyramidal geometry to one La(1), one La(2), one Pb(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(2), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(1), one La(2), one Co(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_LiLa2Co2Sb2(PbO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.968
_cell_length_b   6.074
_cell_length_c   7.873
_cell_angle_alpha   89.794
_cell_angle_beta   90.048
_cell_angle_gamma   93.284
_symmetry_Int_Tables_number   1
_cell_volume   284.908
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.205  0.653  0.282  1.0
  La  La1  1  0.501  0.433  0.748  1.0
  La  La2  1  0.010  0.085  0.256  1.0
  Co  Co3  1  0.949  0.536  0.526  1.0
  Co  Co4  1  0.500  0.943  0.997  1.0
  Sb  Sb5  1  0.002  0.517  0.987  1.0
  Sb  Sb6  1  0.493  0.988  0.501  1.0
  Pb  Pb7  1  0.553  0.431  0.240  1.0
  Pb  Pb8  1  0.995  0.981  0.748  1.0
  O  O9  1  0.588  0.025  0.245  1.0
  O  O10  1  0.111  0.543  0.751  1.0
  O  O11  1  0.426  0.023  0.753  1.0
  O  O12  1  0.949  0.474  0.247  1.0
  O  O13  1  0.186  0.842  0.456  1.0
  O  O14  1  0.729  0.700  0.941  1.0
  O  O15  1  0.777  0.189  0.533  1.0
  O  O16  1  0.250  0.306  0.028  1.0
  O  O17  1  0.321  0.267  0.466  1.0
  O  O18  1  0.782  0.254  0.956  1.0
  O  O19  1  0.638  0.704  0.532  1.0
  O  O20  1  0.189  0.794  0.064  1.0
[/CIF]
.