The structure described by Li10Ge(PO6)2 is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are twenty inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(17), one O(3), one O(4), and one O(9) atom. In the second Li site, Li(2) is bonded to one O(12), one O(13), one O(19), and one O(2) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(18)O4 tetrahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(13), one O(14), one O(21), one O(22), one O(7), and one O(8) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(15), one O(16), one O(23), one O(24), and one O(6) atom. In the fifth Li site, Li(5) is bonded to one O(20), one O(24), one O(6), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Ge(1)O4 tetrahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. In the sixth Li site, Li(6) is bonded to one O(13), one O(19), one O(20), one O(5), and one O(6) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Ge(1)O4 tetrahedra,  a cornercorner with one Li(17)O4 trigonal pyramid,  an edgeedge with one Li(18)O4 tetrahedra,  an edgeedge with one Li(2)O4 tetrahedra,  an edgeedge with one Li(5)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. In the seventh Li site, Li(7) is bonded in a trigonal planar geometry to one O(15), one O(17), and one O(7) atom. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(2), one O(23), and one O(24) atom. In the ninth Li site, Li(9) is bonded to one O(1), one O(14), one O(19), and one O(23) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent Li(11)O4 tetrahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one P(4)O4 tetrahedra. In the tenth Li site, Li(10) is bonded in a 5-coordinate geometry to one O(11), one O(21), one O(22), one O(3), and one O(4) atom. In the eleventh Li site, Li(11) is bonded to one O(1), one O(11), one O(14), and one O(20) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(20)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(9)O4 tetrahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid, and  an edgeedge with one Li(18)O4 tetrahedra. In the twelfth Li site, Li(12) is bonded to one O(16), one O(18), one O(21), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent Li(20)O4 tetrahedra,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Ge(2)O4 tetrahedra. In the thirteenth Li site, Li(13) is bonded in a 4-coordinate geometry to one O(10), one O(15), one O(3), and one O(5) atom. In the fourteenth Li site, Li(14) is bonded in a rectangular see-saw-like geometry to one O(16), one O(23), one O(6), and one O(9) atom. In the fifteenth Li site, Li(15) is bonded to one O(12), one O(17), one O(22), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. In the sixteenth Li site, Li(16) is bonded to one O(15), one O(18), one O(3), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(20)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the seventeenth Li site, Li(17) is bonded to one O(10), one O(16), one O(23), and one O(5) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Li(6)O5 trigonal bipyramid. In the eighteenth Li site, Li(18) is bonded to one O(11), one O(13), one O(2), and one O(20) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(20)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Li(11)O4 tetrahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. In the nineteenth Li site, Li(19) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(14), one O(21), and one O(8) atom. In the twentieth Li site, Li(20) is bonded to one O(11), one O(18), one O(21), and one O(7) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent Li(12)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(10), one O(19), one O(20), and one O(9) atom to form GeO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra, corners with two equivalent Li(6)O5 trigonal bipyramids,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Li(5)O4 tetrahedra. In the second Ge site, Ge(2) is bonded to one O(15), one O(16), one O(21), and one O(22) atom to form GeO4 tetrahedra that share  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(20)O4 tetrahedra,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Li(12)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(20)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. In the second P site, P(2) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Li(6)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(11), one O(12), one O(17), and one O(18) atom to form PO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  an edgeedge with one Li(15)O4 tetrahedra, and  an edgeedge with one Li(20)O4 tetrahedra. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Li(9)O4 tetrahedra. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(11), one Li(8), one Li(9), and one P(1) atom. In the second O site, O(2) is bonded to one Li(18), one Li(2), one Li(8), and one P(1) atom to form OLi3P tetrahedra that share  a cornercorner with one O(19)Li3Ge tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(20)Li4Ge trigonal bipyramid, corners with two equivalent O(13)Li4P trigonal bipyramids,  a cornercorner with one O(12)Li3P trigonal pyramid, and  a cornercorner with one O(24)Li3P trigonal pyramid. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one Li(10), one Li(13), one Li(16), and one P(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Li(10), one Li(12), and one P(2) atom. In the fifth O site, O(5) is bonded to one Li(13), one Li(17), one Li(6), and one P(2) atom to form distorted OLi3P tetrahedra that share  a cornercorner with one O(19)Li3Ge tetrahedra,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(20)Li4Ge trigonal bipyramid,  a cornercorner with one O(13)Li4P trigonal bipyramid, and corners with two equivalent O(10)Li4Ge trigonal bipyramids. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Li(14), one Li(4), one Li(5), one Li(6), and one P(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(20), one Li(3), one Li(7), and one P(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(15), one Li(19), one Li(3), and one P(1) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(1), one Li(14), one Li(16), one Li(5), and one Ge(1) atom. In the tenth O site, O(10) is bonded to one Li(1), one Li(13), one Li(17), one Li(8), and one Ge(1) atom to form OLi4Ge trigonal bipyramids that share  a cornercorner with one O(19)Li3Ge tetrahedra,  a cornercorner with one O(17)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra, corners with two equivalent O(5)Li3P tetrahedra,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(20)Li4Ge trigonal bipyramid, and  a cornercorner with one O(24)Li3P trigonal pyramid. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Li(10), one Li(11), one Li(18), one Li(20), and one P(3) atom. In the twelfth O site, O(12) is bonded to one Li(15), one Li(19), one Li(2), and one P(3) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(19)Li3Ge tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(13)Li4P trigonal bipyramid,  a cornercorner with one O(22)Li3Ge trigonal pyramid, and  an edgeedge with one O(17)Li3P tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(18), one Li(2), one Li(3), one Li(6), and one P(4) atom to form OLi4P trigonal bipyramids that share  a cornercorner with one O(5)Li3P tetrahedra, corners with two equivalent O(2)Li3P tetrahedra,  a cornercorner with one O(22)Li3Ge trigonal pyramid,  a cornercorner with one O(12)Li3P trigonal pyramid,  a cornercorner with one O(24)Li3P trigonal pyramid,  an edgeedge with one O(19)Li3Ge tetrahedra, and  an edgeedge with one O(20)Li4Ge trigonal bipyramid. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Li(11), one Li(19), one Li(3), one Li(9), and one P(4) atom. In the fifteenth O site, O(15) is bonded to one Li(13), one Li(16), one Li(4), one Li(7), and one Ge(2) atom to form OLi4Ge trigonal bipyramids that share  a cornercorner with one O(17)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(22)Li3Ge trigonal pyramid, and  a cornercorner with one O(24)Li3P trigonal pyramid. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one Li(12), one Li(14), one Li(17), one Li(4), and one Ge(2) atom. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(15), one Li(7), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(22)Li3Ge trigonal pyramid, and  an edgeedge with one O(12)Li3P trigonal pyramid. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one Li(12), one Li(16), one Li(20), and one P(3) atom. In the nineteenth O site, O(19) is bonded to one Li(2), one Li(6), one Li(9), and one Ge(1) atom to form OLi3Ge tetrahedra that share  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid, corners with two equivalent O(20)Li4Ge trigonal bipyramids,  a cornercorner with one O(12)Li3P trigonal pyramid, and  an edgeedge with one O(13)Li4P trigonal bipyramid. In the twentieth O site, O(20) is bonded to one Li(11), one Li(18), one Li(5), one Li(6), and one Ge(1) atom to form OLi4Ge trigonal bipyramids that share  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra, corners with two equivalent O(19)Li3Ge tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(24)Li3P trigonal pyramid, and  an edgeedge with one O(13)Li4P trigonal bipyramid. In the twenty-first O site, O(21) is bonded in a 6-coordinate geometry to one Li(10), one Li(12), one Li(19), one Li(20), one Li(3), and one Ge(2) atom. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(15), one Li(3), and one Ge(2) atom to form distorted OLi3Ge trigonal pyramids that share  a cornercorner with one O(17)Li3P tetrahedra,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(13)Li4P trigonal bipyramid, and  a cornercorner with one O(12)Li3P trigonal pyramid. In the twenty-third O site, O(23) is bonded in a 6-coordinate geometry to one Li(14), one Li(17), one Li(4), one Li(8), one Li(9), and one P(4) atom. In the twenty-fourth O site, O(24) is bonded to one Li(4), one Li(5), one Li(8), and one P(4) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(20)Li4Ge trigonal bipyramid, and  a cornercorner with one O(13)Li4P trigonal bipyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li10Ge(PO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.837
_cell_length_b   7.146
_cell_length_c   10.527
_cell_angle_alpha   89.893
_cell_angle_beta   89.850
_cell_angle_gamma   89.754
_symmetry_Int_Tables_number   1
_cell_volume   514.300
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.016  0.454  0.936  1.0
  Li  Li1  1  0.210  0.357  0.430  1.0
  Li  Li2  1  0.509  0.075  0.561  1.0
  Li  Li3  1  0.522  0.967  0.064  1.0
  Li  Li4  1  0.722  0.741  0.179  1.0
  Li  Li5  1  0.483  0.437  0.248  1.0
  Li  Li6  1  0.862  0.108  0.764  1.0
  Li  Li7  1  0.953  0.081  0.242  1.0
  Li  Li8  1  0.222  0.764  0.332  1.0
  Li  Li9  1  0.554  0.479  0.740  1.0
  Li  Li10  1  0.750  0.709  0.426  1.0
  Li  Li11  1  0.230  0.749  0.826  1.0
  Li  Li12  1  0.744  0.235  0.013  1.0
  Li  Li13  1  0.220  0.802  0.075  1.0
  Li  Li14  1  0.224  0.263  0.687  1.0
  Li  Li15  1  0.820  0.753  0.929  1.0
  Li  Li16  1  0.237  0.183  0.065  1.0
  Li  Li17  1  0.743  0.350  0.435  1.0
  Li  Li18  1  0.296  0.778  0.575  1.0
  Li  Li19  1  0.730  0.788  0.668  1.0
  Ge  Ge20  1  0.984  0.494  0.198  1.0
  Ge  Ge21  1  0.479  0.015  0.821  1.0
  P  P22  1  0.986  0.027  0.502  1.0
  P  P23  1  0.484  0.508  0.994  1.0
  P  P24  1  0.974  0.524  0.672  1.0
  P  P25  1  0.482  0.020  0.313  1.0
  O  O26  1  0.992  0.851  0.417  1.0
  O  O27  1  0.975  0.202  0.413  1.0
  O  O28  1  0.674  0.504  0.913  1.0
  O  O29  1  0.299  0.516  0.911  1.0
  O  O30  1  0.484  0.324  0.076  1.0
  O  O31  1  0.488  0.682  0.084  1.0
  O  O32  1  0.800  0.021  0.588  1.0
  O  O33  1  0.172  0.038  0.585  1.0
  O  O34  1  0.968  0.689  0.087  1.0
  O  O35  1  0.982  0.286  0.102  1.0
  O  O36  1  0.782  0.535  0.591  1.0
  O  O37  1  0.166  0.517  0.591  1.0
  O  O38  1  0.482  0.210  0.387  1.0
  O  O39  1  0.476  0.856  0.413  1.0
  O  O40  1  0.704  0.007  0.910  1.0
  O  O41  1  0.285  0.986  0.933  1.0
  O  O42  1  0.977  0.346  0.758  1.0
  O  O43  1  0.971  0.701  0.759  1.0
  O  O44  1  0.205  0.513  0.282  1.0
  O  O45  1  0.763  0.524  0.290  1.0
  O  O46  1  0.468  0.808  0.723  1.0
  O  O47  1  0.486  0.214  0.723  1.0
  O  O48  1  0.299  0.999  0.224  1.0
  O  O49  1  0.667  0.000  0.228  1.0
[/CIF]
.
The structure described by Li10Ge(PO6)2 is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are twenty inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(17), one O(3), one O(4), and one O(9) atom. In the second Li site, Li(2) is bonded to one O(12), one O(13), one O(19), and one O(2) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(18)O4 tetrahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(13), one O(14), one O(21), one O(22), one O(7), and one O(8) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(15), one O(16), one O(23), one O(24), and one O(6) atom. In the fifth Li site, Li(5) is bonded to one O(20), one O(24), one O(6), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Ge(1)O4 tetrahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. In the sixth Li site, Li(6) is bonded to one O(13), one O(19), one O(20), one O(5), and one O(6) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Ge(1)O4 tetrahedra,  a cornercorner with one Li(17)O4 trigonal pyramid,  an edgeedge with one Li(18)O4 tetrahedra,  an edgeedge with one Li(2)O4 tetrahedra,  an edgeedge with one Li(5)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. In the seventh Li site, Li(7) is bonded in a trigonal planar geometry to one O(15), one O(17), and one O(7) atom. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(2), one O(23), and one O(24) atom. In the ninth Li site, Li(9) is bonded to one O(1), one O(14), one O(19), and one O(23) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent Li(11)O4 tetrahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one P(4)O4 tetrahedra. In the tenth Li site, Li(10) is bonded in a 5-coordinate geometry to one O(11), one O(21), one O(22), one O(3), and one O(4) atom. In the eleventh Li site, Li(11) is bonded to one O(1), one O(11), one O(14), and one O(20) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(20)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(9)O4 tetrahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid, and  an edgeedge with one Li(18)O4 tetrahedra. In the twelfth Li site, Li(12) is bonded to one O(16), one O(18), one O(21), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent Li(20)O4 tetrahedra,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Ge(2)O4 tetrahedra. In the thirteenth Li site, Li(13) is bonded in a 4-coordinate geometry to one O(10), one O(15), one O(3), and one O(5) atom. In the fourteenth Li site, Li(14) is bonded in a rectangular see-saw-like geometry to one O(16), one O(23), one O(6), and one O(9) atom. In the fifteenth Li site, Li(15) is bonded to one O(12), one O(17), one O(22), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. In the sixteenth Li site, Li(16) is bonded to one O(15), one O(18), one O(3), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(20)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the seventeenth Li site, Li(17) is bonded to one O(10), one O(16), one O(23), and one O(5) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Li(6)O5 trigonal bipyramid. In the eighteenth Li site, Li(18) is bonded to one O(11), one O(13), one O(2), and one O(20) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(20)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Li(11)O4 tetrahedra, and  an edgeedge with one Li(6)O5 trigonal bipyramid. In the nineteenth Li site, Li(19) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(14), one O(21), and one O(8) atom. In the twentieth Li site, Li(20) is bonded to one O(11), one O(18), one O(21), and one O(7) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent Li(12)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(10), one O(19), one O(20), and one O(9) atom to form GeO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra, corners with two equivalent Li(6)O5 trigonal bipyramids,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Li(5)O4 tetrahedra. In the second Ge site, Ge(2) is bonded to one O(15), one O(16), one O(21), and one O(22) atom to form GeO4 tetrahedra that share  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(20)O4 tetrahedra,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Li(12)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(20)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. In the second P site, P(2) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Li(6)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(11), one O(12), one O(17), and one O(18) atom to form PO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  an edgeedge with one Li(15)O4 tetrahedra, and  an edgeedge with one Li(20)O4 tetrahedra. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O5 trigonal bipyramid,  a cornercorner with one Li(17)O4 trigonal pyramid, and  an edgeedge with one Li(9)O4 tetrahedra. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(11), one Li(8), one Li(9), and one P(1) atom. In the second O site, O(2) is bonded to one Li(18), one Li(2), one Li(8), and one P(1) atom to form OLi3P tetrahedra that share  a cornercorner with one O(19)Li3Ge tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(20)Li4Ge trigonal bipyramid, corners with two equivalent O(13)Li4P trigonal bipyramids,  a cornercorner with one O(12)Li3P trigonal pyramid, and  a cornercorner with one O(24)Li3P trigonal pyramid. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one Li(10), one Li(13), one Li(16), and one P(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Li(10), one Li(12), and one P(2) atom. In the fifth O site, O(5) is bonded to one Li(13), one Li(17), one Li(6), and one P(2) atom to form distorted OLi3P tetrahedra that share  a cornercorner with one O(19)Li3Ge tetrahedra,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(20)Li4Ge trigonal bipyramid,  a cornercorner with one O(13)Li4P trigonal bipyramid, and corners with two equivalent O(10)Li4Ge trigonal bipyramids. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Li(14), one Li(4), one Li(5), one Li(6), and one P(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(20), one Li(3), one Li(7), and one P(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(15), one Li(19), one Li(3), and one P(1) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(1), one Li(14), one Li(16), one Li(5), and one Ge(1) atom. In the tenth O site, O(10) is bonded to one Li(1), one Li(13), one Li(17), one Li(8), and one Ge(1) atom to form OLi4Ge trigonal bipyramids that share  a cornercorner with one O(19)Li3Ge tetrahedra,  a cornercorner with one O(17)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra, corners with two equivalent O(5)Li3P tetrahedra,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(20)Li4Ge trigonal bipyramid, and  a cornercorner with one O(24)Li3P trigonal pyramid. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Li(10), one Li(11), one Li(18), one Li(20), and one P(3) atom. In the twelfth O site, O(12) is bonded to one Li(15), one Li(19), one Li(2), and one P(3) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(19)Li3Ge tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(13)Li4P trigonal bipyramid,  a cornercorner with one O(22)Li3Ge trigonal pyramid, and  an edgeedge with one O(17)Li3P tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(18), one Li(2), one Li(3), one Li(6), and one P(4) atom to form OLi4P trigonal bipyramids that share  a cornercorner with one O(5)Li3P tetrahedra, corners with two equivalent O(2)Li3P tetrahedra,  a cornercorner with one O(22)Li3Ge trigonal pyramid,  a cornercorner with one O(12)Li3P trigonal pyramid,  a cornercorner with one O(24)Li3P trigonal pyramid,  an edgeedge with one O(19)Li3Ge tetrahedra, and  an edgeedge with one O(20)Li4Ge trigonal bipyramid. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Li(11), one Li(19), one Li(3), one Li(9), and one P(4) atom. In the fifteenth O site, O(15) is bonded to one Li(13), one Li(16), one Li(4), one Li(7), and one Ge(2) atom to form OLi4Ge trigonal bipyramids that share  a cornercorner with one O(17)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(22)Li3Ge trigonal pyramid, and  a cornercorner with one O(24)Li3P trigonal pyramid. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one Li(12), one Li(14), one Li(17), one Li(4), and one Ge(2) atom. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(15), one Li(7), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(22)Li3Ge trigonal pyramid, and  an edgeedge with one O(12)Li3P trigonal pyramid. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one Li(12), one Li(16), one Li(20), and one P(3) atom. In the nineteenth O site, O(19) is bonded to one Li(2), one Li(6), one Li(9), and one Ge(1) atom to form OLi3Ge tetrahedra that share  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid, corners with two equivalent O(20)Li4Ge trigonal bipyramids,  a cornercorner with one O(12)Li3P trigonal pyramid, and  an edgeedge with one O(13)Li4P trigonal bipyramid. In the twentieth O site, O(20) is bonded to one Li(11), one Li(18), one Li(5), one Li(6), and one Ge(1) atom to form OLi4Ge trigonal bipyramids that share  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra, corners with two equivalent O(19)Li3Ge tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(24)Li3P trigonal pyramid, and  an edgeedge with one O(13)Li4P trigonal bipyramid. In the twenty-first O site, O(21) is bonded in a 6-coordinate geometry to one Li(10), one Li(12), one Li(19), one Li(20), one Li(3), and one Ge(2) atom. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(15), one Li(3), and one Ge(2) atom to form distorted OLi3Ge trigonal pyramids that share  a cornercorner with one O(17)Li3P tetrahedra,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(13)Li4P trigonal bipyramid, and  a cornercorner with one O(12)Li3P trigonal pyramid. In the twenty-third O site, O(23) is bonded in a 6-coordinate geometry to one Li(14), one Li(17), one Li(4), one Li(8), one Li(9), and one P(4) atom. In the twenty-fourth O site, O(24) is bonded to one Li(4), one Li(5), one Li(8), and one P(4) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(10)Li4Ge trigonal bipyramid,  a cornercorner with one O(15)Li4Ge trigonal bipyramid,  a cornercorner with one O(20)Li4Ge trigonal bipyramid, and  a cornercorner with one O(13)Li4P trigonal bipyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li10Ge(PO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.837
_cell_length_b   7.146
_cell_length_c   10.527
_cell_angle_alpha   89.893
_cell_angle_beta   89.850
_cell_angle_gamma   89.754
_symmetry_Int_Tables_number   1
_cell_volume   514.300
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.016  0.454  0.936  1.0
  Li  Li1  1  0.210  0.357  0.430  1.0
  Li  Li2  1  0.509  0.075  0.561  1.0
  Li  Li3  1  0.522  0.967  0.064  1.0
  Li  Li4  1  0.722  0.741  0.179  1.0
  Li  Li5  1  0.483  0.437  0.248  1.0
  Li  Li6  1  0.862  0.108  0.764  1.0
  Li  Li7  1  0.953  0.081  0.242  1.0
  Li  Li8  1  0.222  0.764  0.332  1.0
  Li  Li9  1  0.554  0.479  0.740  1.0
  Li  Li10  1  0.750  0.709  0.426  1.0
  Li  Li11  1  0.230  0.749  0.826  1.0
  Li  Li12  1  0.744  0.235  0.013  1.0
  Li  Li13  1  0.220  0.802  0.075  1.0
  Li  Li14  1  0.224  0.263  0.687  1.0
  Li  Li15  1  0.820  0.753  0.929  1.0
  Li  Li16  1  0.237  0.183  0.065  1.0
  Li  Li17  1  0.743  0.350  0.435  1.0
  Li  Li18  1  0.296  0.778  0.575  1.0
  Li  Li19  1  0.730  0.788  0.668  1.0
  Ge  Ge20  1  0.984  0.494  0.198  1.0
  Ge  Ge21  1  0.479  0.015  0.821  1.0
  P  P22  1  0.986  0.027  0.502  1.0
  P  P23  1  0.484  0.508  0.994  1.0
  P  P24  1  0.974  0.524  0.672  1.0
  P  P25  1  0.482  0.020  0.313  1.0
  O  O26  1  0.992  0.851  0.417  1.0
  O  O27  1  0.975  0.202  0.413  1.0
  O  O28  1  0.674  0.504  0.913  1.0
  O  O29  1  0.299  0.516  0.911  1.0
  O  O30  1  0.484  0.324  0.076  1.0
  O  O31  1  0.488  0.682  0.084  1.0
  O  O32  1  0.800  0.021  0.588  1.0
  O  O33  1  0.172  0.038  0.585  1.0
  O  O34  1  0.968  0.689  0.087  1.0
  O  O35  1  0.982  0.286  0.102  1.0
  O  O36  1  0.782  0.535  0.591  1.0
  O  O37  1  0.166  0.517  0.591  1.0
  O  O38  1  0.482  0.210  0.387  1.0
  O  O39  1  0.476  0.856  0.413  1.0
  O  O40  1  0.704  0.007  0.910  1.0
  O  O41  1  0.285  0.986  0.933  1.0
  O  O42  1  0.977  0.346  0.758  1.0
  O  O43  1  0.971  0.701  0.759  1.0
  O  O44  1  0.205  0.513  0.282  1.0
  O  O45  1  0.763  0.524  0.290  1.0
  O  O46  1  0.468  0.808  0.723  1.0
  O  O47  1  0.486  0.214  0.723  1.0
  O  O48  1  0.299  0.999  0.224  1.0
  O  O49  1  0.667  0.000  0.228  1.0
[/CIF]
.