The crystal structure described by BaWF7 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms. W(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ba(1) and one W(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Ba(1) and one W(1) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one W(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one W(1) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one W(1) atom. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one W(1) atom. In the seventh F site, F(7) is bonded in a water-like geometry to two equivalent Ba(1) atoms. is represented by the CIF file [CIF]
data_BaWF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.903
_cell_length_b   5.422
_cell_length_c   10.233
_cell_angle_alpha   88.589
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   549.311
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.327  0.298  0.507  1.0
  Ba  Ba1  1  0.827  0.702  0.993  1.0
  Ba  Ba2  1  0.673  0.702  0.493  1.0
  Ba  Ba3  1  0.173  0.298  0.007  1.0
  W  W4  1  0.605  0.176  0.185  1.0
  W  W5  1  0.395  0.824  0.815  1.0
  W  W6  1  0.895  0.176  0.685  1.0
  W  W7  1  0.105  0.824  0.315  1.0
  F  F8  1  0.463  0.120  0.879  1.0
  F  F9  1  0.058  0.321  0.626  1.0
  F  F10  1  0.696  0.460  0.243  1.0
  F  F11  1  0.304  0.540  0.757  1.0
  F  F12  1  0.456  0.886  0.637  1.0
  F  F13  1  0.805  0.241  0.519  1.0
  F  F14  1  0.761  0.981  0.236  1.0
  F  F15  1  0.956  0.114  0.863  1.0
  F  F16  1  0.442  0.321  0.126  1.0
  F  F17  1  0.196  0.540  0.257  1.0
  F  F18  1  0.037  0.120  0.379  1.0
  F  F19  1  0.537  0.880  0.121  1.0
  F  F20  1  0.261  0.019  0.264  1.0
  F  F21  1  0.959  0.390  0.120  1.0
  F  F22  1  0.544  0.114  0.363  1.0
  F  F23  1  0.044  0.886  0.137  1.0
  F  F24  1  0.239  0.019  0.764  1.0
  F  F25  1  0.963  0.880  0.621  1.0
  F  F26  1  0.459  0.610  0.380  1.0
  F  F27  1  0.942  0.679  0.374  1.0
  F  F28  1  0.041  0.610  0.880  1.0
  F  F29  1  0.739  0.981  0.736  1.0
  F  F30  1  0.541  0.390  0.620  1.0
  F  F31  1  0.305  0.759  0.981  1.0
  F  F32  1  0.195  0.759  0.481  1.0
  F  F33  1  0.695  0.241  0.019  1.0
  F  F34  1  0.558  0.679  0.874  1.0
  F  F35  1  0.804  0.460  0.743  1.0
[/CIF]
.
The crystal structure described by BaWF7 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms. W(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ba(1) and one W(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Ba(1) and one W(1) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one W(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one W(1) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one W(1) atom. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one W(1) atom. In the seventh F site, F(7) is bonded in a water-like geometry to two equivalent Ba(1) atoms. is represented by the CIF file [CIF]
data_BaWF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.903
_cell_length_b   5.422
_cell_length_c   10.233
_cell_angle_alpha   88.589
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   549.311
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.327  0.298  0.507  1.0
  Ba  Ba1  1  0.827  0.702  0.993  1.0
  Ba  Ba2  1  0.673  0.702  0.493  1.0
  Ba  Ba3  1  0.173  0.298  0.007  1.0
  W  W4  1  0.605  0.176  0.185  1.0
  W  W5  1  0.395  0.824  0.815  1.0
  W  W6  1  0.895  0.176  0.685  1.0
  W  W7  1  0.105  0.824  0.315  1.0
  F  F8  1  0.463  0.120  0.879  1.0
  F  F9  1  0.058  0.321  0.626  1.0
  F  F10  1  0.696  0.460  0.243  1.0
  F  F11  1  0.304  0.540  0.757  1.0
  F  F12  1  0.456  0.886  0.637  1.0
  F  F13  1  0.805  0.241  0.519  1.0
  F  F14  1  0.761  0.981  0.236  1.0
  F  F15  1  0.956  0.114  0.863  1.0
  F  F16  1  0.442  0.321  0.126  1.0
  F  F17  1  0.196  0.540  0.257  1.0
  F  F18  1  0.037  0.120  0.379  1.0
  F  F19  1  0.537  0.880  0.121  1.0
  F  F20  1  0.261  0.019  0.264  1.0
  F  F21  1  0.959  0.390  0.120  1.0
  F  F22  1  0.544  0.114  0.363  1.0
  F  F23  1  0.044  0.886  0.137  1.0
  F  F24  1  0.239  0.019  0.764  1.0
  F  F25  1  0.963  0.880  0.621  1.0
  F  F26  1  0.459  0.610  0.380  1.0
  F  F27  1  0.942  0.679  0.374  1.0
  F  F28  1  0.041  0.610  0.880  1.0
  F  F29  1  0.739  0.981  0.736  1.0
  F  F30  1  0.541  0.390  0.620  1.0
  F  F31  1  0.305  0.759  0.981  1.0
  F  F32  1  0.195  0.759  0.481  1.0
  F  F33  1  0.695  0.241  0.019  1.0
  F  F34  1  0.558  0.679  0.874  1.0
  F  F35  1  0.804  0.460  0.743  1.0
[/CIF]
.