The crystal structure described by Mn2Fe3Cu10(SnS4)5 is Clathrate-derived structured and crystallizes in the orthorhombic I222 space group. Mn(1) is bonded to two equivalent S(1) and two equivalent S(5) atoms to form MnS4 tetrahedra that share corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Sn(1)S4 tetrahedra, corners with two equivalent Sn(2)S4 tetrahedra, and corners with six equivalent Cu(2)S4 tetrahedra. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent S(2) and two equivalent S(4) atoms to form FeS4 tetrahedra that share corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Cu(3)S4 tetrahedra, corners with two equivalent Sn(1)S4 tetrahedra, corners with two equivalent Sn(3)S4 tetrahedra, and corners with four equivalent Cu(1)S4 tetrahedra. In the second Fe site, Fe(2) is bonded to four equivalent S(3) atoms to form FeS4 tetrahedra that share corners with four equivalent Cu(1)S4 tetrahedra, corners with four equivalent Cu(3)S4 tetrahedra, and corners with four equivalent Sn(2)S4 tetrahedra. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form CuS4 tetrahedra that share  a cornercorner with one Mn(1)S4 tetrahedra,  a cornercorner with one Fe(2)S4 tetrahedra,  a cornercorner with one Sn(1)S4 tetrahedra,  a cornercorner with one Sn(3)S4 tetrahedra, corners with two equivalent Fe(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Cu(3)S4 tetrahedra, and corners with two equivalent Sn(2)S4 tetrahedra. In the second Cu site, Cu(2) is bonded to one S(1), one S(4), and two equivalent S(5) atoms to form CuS4 tetrahedra that share  a cornercorner with one Fe(1)S4 tetrahedra,  a cornercorner with one Sn(2)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with three equivalent Mn(1)S4 tetrahedra, and corners with three equivalent Sn(1)S4 tetrahedra. In the third Cu site, Cu(3) is bonded to two equivalent S(2) and two equivalent S(3) atoms to form CuS4 tetrahedra that share corners with two equivalent Fe(1)S4 tetrahedra, corners with two equivalent Fe(2)S4 tetrahedra, corners with two equivalent Sn(2)S4 tetrahedra, corners with two equivalent Sn(3)S4 tetrahedra, and corners with four equivalent Cu(1)S4 tetrahedra. There are three inequivalent Sn sites. In the first Sn site, Sn(3) is bonded to four equivalent S(2) atoms to form SnS4 tetrahedra that share corners with four equivalent Fe(1)S4 tetrahedra, corners with four equivalent Cu(1)S4 tetrahedra, and corners with four equivalent Cu(3)S4 tetrahedra. In the second Sn site, Sn(1) is bonded to two equivalent S(4) and two equivalent S(5) atoms to form SnS4 tetrahedra that share corners with two equivalent Mn(1)S4 tetrahedra, corners with two equivalent Fe(1)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, and corners with six equivalent Cu(2)S4 tetrahedra. In the third Sn site, Sn(2) is bonded to two equivalent S(1) and two equivalent S(3) atoms to form SnS4 tetrahedra that share corners with two equivalent Mn(1)S4 tetrahedra, corners with two equivalent Fe(2)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Cu(3)S4 tetrahedra, and corners with four equivalent Cu(1)S4 tetrahedra. There are five inequivalent S sites. In the first S site, S(1) is bonded to one Mn(1), one Cu(1), one Cu(2), and one Sn(2) atom to form SMnCu2Sn tetrahedra that share  a cornercorner with one S(2)FeCu2Sn tetrahedra, corners with two equivalent S(4)FeCu2Sn tetrahedra, corners with two equivalent S(1)MnCu2Sn tetrahedra, corners with three equivalent S(3)FeCu2Sn tetrahedra, and corners with four equivalent S(5)MnCu2Sn tetrahedra. In the second S site, S(2) is bonded to one Fe(1), one Cu(1), one Cu(3), and one Sn(3) atom to form SFeCu2Sn tetrahedra that share  a cornercorner with one S(1)MnCu2Sn tetrahedra, corners with three equivalent S(3)FeCu2Sn tetrahedra, corners with three equivalent S(4)FeCu2Sn tetrahedra, and corners with five equivalent S(2)FeCu2Sn tetrahedra. In the third S site, S(3) is bonded to one Fe(2), one Cu(1), one Cu(3), and one Sn(2) atom to form SFeCu2Sn tetrahedra that share  a cornercorner with one S(4)FeCu2Sn tetrahedra, corners with three equivalent S(2)FeCu2Sn tetrahedra, corners with three equivalent S(1)MnCu2Sn tetrahedra, and corners with five equivalent S(3)FeCu2Sn tetrahedra. In the fourth S site, S(4) is bonded to one Fe(1), one Cu(1), one Cu(2), and one Sn(1) atom to form SFeCu2Sn tetrahedra that share  a cornercorner with one S(3)FeCu2Sn tetrahedra, corners with two equivalent S(4)FeCu2Sn tetrahedra, corners with two equivalent S(1)MnCu2Sn tetrahedra, corners with three equivalent S(2)FeCu2Sn tetrahedra, and corners with four equivalent S(5)MnCu2Sn tetrahedra. In the fifth S site, S(5) is bonded to one Mn(1), two equivalent Cu(2), and one Sn(1) atom to form SMnCu2Sn tetrahedra that share corners with four equivalent S(4)FeCu2Sn tetrahedra, corners with four equivalent S(1)MnCu2Sn tetrahedra, and corners with four equivalent S(5)MnCu2Sn tetrahedra. is represented by the CIF card [CIF]
data_Mn2Fe3Cu10(SnS4)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.528
_cell_length_b   10.896
_cell_length_c   15.138
_cell_angle_alpha   68.907
_cell_angle_beta   100.521
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   834.251
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.800  0.200  0.600  1.0
  Mn  Mn1  1  0.400  0.600  0.800  1.0
  Fe  Fe2  1  0.000  1.000  0.001  1.0
  Fe  Fe3  1  0.600  0.400  0.200  1.0
  Fe  Fe4  1  0.200  0.800  0.399  1.0
  Cu  Cu5  1  0.502  0.247  0.001  1.0
  Cu  Cu6  1  0.297  0.452  0.599  1.0
  Cu  Cu7  1  0.903  0.851  0.801  1.0
  Cu  Cu8  1  0.100  0.651  0.200  1.0
  Cu  Cu9  1  0.698  0.048  0.399  1.0
  Cu  Cu10  1  0.898  0.348  0.801  1.0
  Cu  Cu11  1  0.701  0.553  0.399  1.0
  Cu  Cu12  1  0.302  0.949  0.599  1.0
  Cu  Cu13  1  0.499  0.752  0.001  1.0
  Cu  Cu14  1  0.100  0.149  0.200  1.0
  Sn  Sn15  1  0.401  0.099  0.802  1.0
  Sn  Sn16  1  0.199  0.301  0.398  1.0
  Sn  Sn17  1  0.799  0.701  0.598  1.0
  Sn  Sn18  1  0.001  0.499  0.002  1.0
  Sn  Sn19  1  0.600  0.900  0.200  1.0
  S  S20  1  0.206  0.416  0.898  1.0
  S  S21  1  0.814  0.821  0.093  1.0
  S  S22  1  0.413  0.221  0.293  1.0
  S  S23  1  0.013  0.622  0.493  1.0
  S  S24  1  0.606  0.016  0.697  1.0
  S  S25  1  0.787  0.314  0.107  1.0
  S  S26  1  0.386  0.715  0.307  1.0
  S  S27  1  0.994  0.114  0.502  1.0
  S  S28  1  0.594  0.513  0.703  1.0
  S  S29  1  0.187  0.915  0.907  1.0
  S  S30  1  0.091  0.287  0.697  1.0
  S  S31  1  0.692  0.686  0.898  1.0
  S  S32  1  0.279  0.085  0.093  1.0
  S  S33  1  0.880  0.486  0.293  1.0
  S  S34  1  0.480  0.885  0.493  1.0
  S  S35  1  0.720  0.178  0.907  1.0
  S  S36  1  0.320  0.579  0.107  1.0
  S  S37  1  0.921  0.979  0.307  1.0
  S  S38  1  0.508  0.384  0.502  1.0
  S  S39  1  0.109  0.784  0.703  1.0
[/CIF]
.
The crystal structure described by Mn2Fe3Cu10(SnS4)5 is Clathrate-derived structured and crystallizes in the orthorhombic I222 space group. Mn(1) is bonded to two equivalent S(1) and two equivalent S(5) atoms to form MnS4 tetrahedra that share corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Sn(1)S4 tetrahedra, corners with two equivalent Sn(2)S4 tetrahedra, and corners with six equivalent Cu(2)S4 tetrahedra. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent S(2) and two equivalent S(4) atoms to form FeS4 tetrahedra that share corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Cu(3)S4 tetrahedra, corners with two equivalent Sn(1)S4 tetrahedra, corners with two equivalent Sn(3)S4 tetrahedra, and corners with four equivalent Cu(1)S4 tetrahedra. In the second Fe site, Fe(2) is bonded to four equivalent S(3) atoms to form FeS4 tetrahedra that share corners with four equivalent Cu(1)S4 tetrahedra, corners with four equivalent Cu(3)S4 tetrahedra, and corners with four equivalent Sn(2)S4 tetrahedra. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form CuS4 tetrahedra that share  a cornercorner with one Mn(1)S4 tetrahedra,  a cornercorner with one Fe(2)S4 tetrahedra,  a cornercorner with one Sn(1)S4 tetrahedra,  a cornercorner with one Sn(3)S4 tetrahedra, corners with two equivalent Fe(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Cu(3)S4 tetrahedra, and corners with two equivalent Sn(2)S4 tetrahedra. In the second Cu site, Cu(2) is bonded to one S(1), one S(4), and two equivalent S(5) atoms to form CuS4 tetrahedra that share  a cornercorner with one Fe(1)S4 tetrahedra,  a cornercorner with one Sn(2)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with three equivalent Mn(1)S4 tetrahedra, and corners with three equivalent Sn(1)S4 tetrahedra. In the third Cu site, Cu(3) is bonded to two equivalent S(2) and two equivalent S(3) atoms to form CuS4 tetrahedra that share corners with two equivalent Fe(1)S4 tetrahedra, corners with two equivalent Fe(2)S4 tetrahedra, corners with two equivalent Sn(2)S4 tetrahedra, corners with two equivalent Sn(3)S4 tetrahedra, and corners with four equivalent Cu(1)S4 tetrahedra. There are three inequivalent Sn sites. In the first Sn site, Sn(3) is bonded to four equivalent S(2) atoms to form SnS4 tetrahedra that share corners with four equivalent Fe(1)S4 tetrahedra, corners with four equivalent Cu(1)S4 tetrahedra, and corners with four equivalent Cu(3)S4 tetrahedra. In the second Sn site, Sn(1) is bonded to two equivalent S(4) and two equivalent S(5) atoms to form SnS4 tetrahedra that share corners with two equivalent Mn(1)S4 tetrahedra, corners with two equivalent Fe(1)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, and corners with six equivalent Cu(2)S4 tetrahedra. In the third Sn site, Sn(2) is bonded to two equivalent S(1) and two equivalent S(3) atoms to form SnS4 tetrahedra that share corners with two equivalent Mn(1)S4 tetrahedra, corners with two equivalent Fe(2)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Cu(3)S4 tetrahedra, and corners with four equivalent Cu(1)S4 tetrahedra. There are five inequivalent S sites. In the first S site, S(1) is bonded to one Mn(1), one Cu(1), one Cu(2), and one Sn(2) atom to form SMnCu2Sn tetrahedra that share  a cornercorner with one S(2)FeCu2Sn tetrahedra, corners with two equivalent S(4)FeCu2Sn tetrahedra, corners with two equivalent S(1)MnCu2Sn tetrahedra, corners with three equivalent S(3)FeCu2Sn tetrahedra, and corners with four equivalent S(5)MnCu2Sn tetrahedra. In the second S site, S(2) is bonded to one Fe(1), one Cu(1), one Cu(3), and one Sn(3) atom to form SFeCu2Sn tetrahedra that share  a cornercorner with one S(1)MnCu2Sn tetrahedra, corners with three equivalent S(3)FeCu2Sn tetrahedra, corners with three equivalent S(4)FeCu2Sn tetrahedra, and corners with five equivalent S(2)FeCu2Sn tetrahedra. In the third S site, S(3) is bonded to one Fe(2), one Cu(1), one Cu(3), and one Sn(2) atom to form SFeCu2Sn tetrahedra that share  a cornercorner with one S(4)FeCu2Sn tetrahedra, corners with three equivalent S(2)FeCu2Sn tetrahedra, corners with three equivalent S(1)MnCu2Sn tetrahedra, and corners with five equivalent S(3)FeCu2Sn tetrahedra. In the fourth S site, S(4) is bonded to one Fe(1), one Cu(1), one Cu(2), and one Sn(1) atom to form SFeCu2Sn tetrahedra that share  a cornercorner with one S(3)FeCu2Sn tetrahedra, corners with two equivalent S(4)FeCu2Sn tetrahedra, corners with two equivalent S(1)MnCu2Sn tetrahedra, corners with three equivalent S(2)FeCu2Sn tetrahedra, and corners with four equivalent S(5)MnCu2Sn tetrahedra. In the fifth S site, S(5) is bonded to one Mn(1), two equivalent Cu(2), and one Sn(1) atom to form SMnCu2Sn tetrahedra that share corners with four equivalent S(4)FeCu2Sn tetrahedra, corners with four equivalent S(1)MnCu2Sn tetrahedra, and corners with four equivalent S(5)MnCu2Sn tetrahedra. is represented by the CIF card [CIF]
data_Mn2Fe3Cu10(SnS4)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.528
_cell_length_b   10.896
_cell_length_c   15.138
_cell_angle_alpha   68.907
_cell_angle_beta   100.521
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   834.251
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.800  0.200  0.600  1.0
  Mn  Mn1  1  0.400  0.600  0.800  1.0
  Fe  Fe2  1  0.000  1.000  0.001  1.0
  Fe  Fe3  1  0.600  0.400  0.200  1.0
  Fe  Fe4  1  0.200  0.800  0.399  1.0
  Cu  Cu5  1  0.502  0.247  0.001  1.0
  Cu  Cu6  1  0.297  0.452  0.599  1.0
  Cu  Cu7  1  0.903  0.851  0.801  1.0
  Cu  Cu8  1  0.100  0.651  0.200  1.0
  Cu  Cu9  1  0.698  0.048  0.399  1.0
  Cu  Cu10  1  0.898  0.348  0.801  1.0
  Cu  Cu11  1  0.701  0.553  0.399  1.0
  Cu  Cu12  1  0.302  0.949  0.599  1.0
  Cu  Cu13  1  0.499  0.752  0.001  1.0
  Cu  Cu14  1  0.100  0.149  0.200  1.0
  Sn  Sn15  1  0.401  0.099  0.802  1.0
  Sn  Sn16  1  0.199  0.301  0.398  1.0
  Sn  Sn17  1  0.799  0.701  0.598  1.0
  Sn  Sn18  1  0.001  0.499  0.002  1.0
  Sn  Sn19  1  0.600  0.900  0.200  1.0
  S  S20  1  0.206  0.416  0.898  1.0
  S  S21  1  0.814  0.821  0.093  1.0
  S  S22  1  0.413  0.221  0.293  1.0
  S  S23  1  0.013  0.622  0.493  1.0
  S  S24  1  0.606  0.016  0.697  1.0
  S  S25  1  0.787  0.314  0.107  1.0
  S  S26  1  0.386  0.715  0.307  1.0
  S  S27  1  0.994  0.114  0.502  1.0
  S  S28  1  0.594  0.513  0.703  1.0
  S  S29  1  0.187  0.915  0.907  1.0
  S  S30  1  0.091  0.287  0.697  1.0
  S  S31  1  0.692  0.686  0.898  1.0
  S  S32  1  0.279  0.085  0.093  1.0
  S  S33  1  0.880  0.486  0.293  1.0
  S  S34  1  0.480  0.885  0.493  1.0
  S  S35  1  0.720  0.178  0.907  1.0
  S  S36  1  0.320  0.579  0.107  1.0
  S  S37  1  0.921  0.979  0.307  1.0
  S  S38  1  0.508  0.384  0.502  1.0
  S  S39  1  0.109  0.784  0.703  1.0
[/CIF]
.