The material described by Li3Co11O14 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Co(5)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and edges with four equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with four equivalent Co(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the second Co site, Co(2) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with four equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the third Co site, Co(3) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the fourth Co site, Co(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the fifth Co site, Co(5) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and edges with four equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the sixth Co site, Co(6) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Co(1), one Co(2), one Co(3), one Co(4), and one Co(6) atom to form OLiCo5 octahedra that share corners with two equivalent O(1)LiCo5 octahedra, corners with two equivalent O(2)LiCo5 octahedra, corners with two equivalent O(3)LiCo5 octahedra,  an edgeedge with one O(2)LiCo5 octahedra, edges with two equivalent O(1)LiCo5 octahedra, edges with four equivalent O(4)Li2Co4 octahedra, and edges with five equivalent O(3)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(1), one Co(5), two equivalent Co(1), and two equivalent Co(6) atoms to form OLiCo5 octahedra that share corners with two equivalent O(2)LiCo5 octahedra, corners with four equivalent O(1)LiCo5 octahedra, edges with two equivalent O(1)LiCo5 octahedra, edges with two equivalent O(2)LiCo5 octahedra, and edges with eight equivalent O(4)Li2Co4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third O site, O(3) is bonded to one Li(2), one Co(4), two equivalent Co(2), and two equivalent Co(3) atoms to form OLiCo5 octahedra that share corners with two equivalent O(4)Li2Co4 octahedra, corners with two equivalent O(1)LiCo5 octahedra, corners with two equivalent O(3)LiCo5 octahedra,  an edgeedge with one O(4)Li2Co4 octahedra, edges with five equivalent O(1)LiCo5 octahedra, and edges with six equivalent O(3)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Co(1), one Co(4), one Co(5), and one Co(6) atom to form OLi2Co4 octahedra that share corners with two equivalent O(3)LiCo5 octahedra, corners with four equivalent O(4)Li2Co4 octahedra,  an edgeedge with one O(3)LiCo5 octahedra, edges with three equivalent O(4)Li2Co4 octahedra, edges with four equivalent O(1)LiCo5 octahedra, and edges with four equivalent O(2)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. is represented by the CIF card [CIF]
data_Li3Co11O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.772
_cell_length_b   10.772
_cell_length_c   5.133
_cell_angle_alpha   85.610
_cell_angle_beta   85.610
_cell_angle_gamma   152.475
_symmetry_Int_Tables_number   1
_cell_volume   260.634
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Li  Li1  1  0.858  0.142  0.500  1.0
  Li  Li2  1  0.142  0.858  0.500  1.0
  Co  Co3  1  0.429  0.571  0.500  1.0
  Co  Co4  1  0.715  0.285  0.500  1.0
  Co  Co5  1  0.571  0.429  0.500  1.0
  Co  Co6  1  0.285  0.715  0.500  1.0
  Co  Co7  1  0.786  0.214  0.000  1.0
  Co  Co8  1  0.361  0.639  0.000  1.0
  Co  Co9  1  0.000  0.000  0.500  1.0
  Co  Co10  1  0.639  0.361  0.000  1.0
  Co  Co11  1  0.214  0.786  0.000  1.0
  Co  Co12  1  0.071  0.929  0.000  1.0
  Co  Co13  1  0.929  0.071  0.000  1.0
  O  O14  1  0.603  0.886  0.249  1.0
  O  O15  1  0.768  0.768  0.269  1.0
  O  O16  1  0.471  0.041  0.252  1.0
  O  O17  1  0.696  0.830  0.742  1.0
  O  O18  1  0.830  0.696  0.742  1.0
  O  O19  1  0.170  0.304  0.258  1.0
  O  O20  1  0.304  0.170  0.258  1.0
  O  O21  1  0.114  0.397  0.751  1.0
  O  O22  1  0.397  0.114  0.751  1.0
  O  O23  1  0.041  0.471  0.252  1.0
  O  O24  1  0.232  0.232  0.731  1.0
  O  O25  1  0.886  0.603  0.249  1.0
  O  O26  1  0.529  0.959  0.748  1.0
  O  O27  1  0.959  0.529  0.748  1.0
[/CIF]
.
The material described by Li3Co11O14 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Co(5)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and edges with four equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with four equivalent Co(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the second Co site, Co(2) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with four equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the third Co site, Co(3) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the fourth Co site, Co(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the fifth Co site, Co(5) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and edges with four equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the sixth Co site, Co(6) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Co(1), one Co(2), one Co(3), one Co(4), and one Co(6) atom to form OLiCo5 octahedra that share corners with two equivalent O(1)LiCo5 octahedra, corners with two equivalent O(2)LiCo5 octahedra, corners with two equivalent O(3)LiCo5 octahedra,  an edgeedge with one O(2)LiCo5 octahedra, edges with two equivalent O(1)LiCo5 octahedra, edges with four equivalent O(4)Li2Co4 octahedra, and edges with five equivalent O(3)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(1), one Co(5), two equivalent Co(1), and two equivalent Co(6) atoms to form OLiCo5 octahedra that share corners with two equivalent O(2)LiCo5 octahedra, corners with four equivalent O(1)LiCo5 octahedra, edges with two equivalent O(1)LiCo5 octahedra, edges with two equivalent O(2)LiCo5 octahedra, and edges with eight equivalent O(4)Li2Co4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third O site, O(3) is bonded to one Li(2), one Co(4), two equivalent Co(2), and two equivalent Co(3) atoms to form OLiCo5 octahedra that share corners with two equivalent O(4)Li2Co4 octahedra, corners with two equivalent O(1)LiCo5 octahedra, corners with two equivalent O(3)LiCo5 octahedra,  an edgeedge with one O(4)Li2Co4 octahedra, edges with five equivalent O(1)LiCo5 octahedra, and edges with six equivalent O(3)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Co(1), one Co(4), one Co(5), and one Co(6) atom to form OLi2Co4 octahedra that share corners with two equivalent O(3)LiCo5 octahedra, corners with four equivalent O(4)Li2Co4 octahedra,  an edgeedge with one O(3)LiCo5 octahedra, edges with three equivalent O(4)Li2Co4 octahedra, edges with four equivalent O(1)LiCo5 octahedra, and edges with four equivalent O(2)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. is represented by the CIF card [CIF]
data_Li3Co11O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.772
_cell_length_b   10.772
_cell_length_c   5.133
_cell_angle_alpha   85.610
_cell_angle_beta   85.610
_cell_angle_gamma   152.475
_symmetry_Int_Tables_number   1
_cell_volume   260.634
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Li  Li1  1  0.858  0.142  0.500  1.0
  Li  Li2  1  0.142  0.858  0.500  1.0
  Co  Co3  1  0.429  0.571  0.500  1.0
  Co  Co4  1  0.715  0.285  0.500  1.0
  Co  Co5  1  0.571  0.429  0.500  1.0
  Co  Co6  1  0.285  0.715  0.500  1.0
  Co  Co7  1  0.786  0.214  0.000  1.0
  Co  Co8  1  0.361  0.639  0.000  1.0
  Co  Co9  1  0.000  0.000  0.500  1.0
  Co  Co10  1  0.639  0.361  0.000  1.0
  Co  Co11  1  0.214  0.786  0.000  1.0
  Co  Co12  1  0.071  0.929  0.000  1.0
  Co  Co13  1  0.929  0.071  0.000  1.0
  O  O14  1  0.603  0.886  0.249  1.0
  O  O15  1  0.768  0.768  0.269  1.0
  O  O16  1  0.471  0.041  0.252  1.0
  O  O17  1  0.696  0.830  0.742  1.0
  O  O18  1  0.830  0.696  0.742  1.0
  O  O19  1  0.170  0.304  0.258  1.0
  O  O20  1  0.304  0.170  0.258  1.0
  O  O21  1  0.114  0.397  0.751  1.0
  O  O22  1  0.397  0.114  0.751  1.0
  O  O23  1  0.041  0.471  0.252  1.0
  O  O24  1  0.232  0.232  0.731  1.0
  O  O25  1  0.886  0.603  0.249  1.0
  O  O26  1  0.529  0.959  0.748  1.0
  O  O27  1  0.959  0.529  0.748  1.0
[/CIF]
.