The compound described by Li6(TeO6) crystallizes in the trigonal R-3 space group. Li(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Te(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_Li6TeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.673
_cell_length_b   5.673
_cell_length_c   5.673
_cell_angle_alpha   61.712
_cell_angle_beta   61.712
_cell_angle_gamma   61.712
_symmetry_Int_Tables_number   1
_cell_volume   134.073
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.717  0.079  0.515  1.0
  Li  Li1  1  0.921  0.485  0.283  1.0
  Li  Li2  1  0.485  0.283  0.921  1.0
  Li  Li3  1  0.515  0.717  0.079  1.0
  Li  Li4  1  0.079  0.515  0.717  1.0
  Li  Li5  1  0.283  0.921  0.485  1.0
  Te  Te6  1  0.000  0.000  0.000  1.0
  O  O7  1  0.897  0.202  0.653  1.0
  O  O8  1  0.798  0.347  0.103  1.0
  O  O9  1  0.347  0.103  0.798  1.0
  O  O10  1  0.653  0.897  0.202  1.0
  O  O11  1  0.202  0.653  0.897  1.0
  O  O12  1  0.103  0.798  0.347  1.0
[/CIF]
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The compound described by Li6(TeO6) crystallizes in the trigonal R-3 space group. Li(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Te(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_Li6TeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.673
_cell_length_b   5.673
_cell_length_c   5.673
_cell_angle_alpha   61.712
_cell_angle_beta   61.712
_cell_angle_gamma   61.712
_symmetry_Int_Tables_number   1
_cell_volume   134.073
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.717  0.079  0.515  1.0
  Li  Li1  1  0.921  0.485  0.283  1.0
  Li  Li2  1  0.485  0.283  0.921  1.0
  Li  Li3  1  0.515  0.717  0.079  1.0
  Li  Li4  1  0.079  0.515  0.717  1.0
  Li  Li5  1  0.283  0.921  0.485  1.0
  Te  Te6  1  0.000  0.000  0.000  1.0
  O  O7  1  0.897  0.202  0.653  1.0
  O  O8  1  0.798  0.347  0.103  1.0
  O  O9  1  0.347  0.103  0.798  1.0
  O  O10  1  0.653  0.897  0.202  1.0
  O  O11  1  0.202  0.653  0.897  1.0
  O  O12  1  0.103  0.798  0.347  1.0
[/CIF]
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