The material described by (ReSeF)12(SeO)4(O2)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, eight oxyselenide molecules, four trioxidane molecules, and four ReSeF clusters. In each ReSeF cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(3) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(2) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(1) atom. There are three inequivalent Se sites. In the first Se site, Se(3) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second Se site, Se(4) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the third Se site, Se(2) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_Re6Se8O7F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.523
_cell_length_b   11.523
_cell_length_c   10.952
_cell_angle_alpha   66.235
_cell_angle_beta   66.235
_cell_angle_gamma   65.709
_symmetry_Int_Tables_number   1
_cell_volume   1163.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.316  0.056  0.550  1.0
  Re  Re1  1  0.684  0.944  0.450  1.0
  Re  Re2  1  0.944  0.684  0.950  1.0
  Re  Re3  1  0.056  0.316  0.050  1.0
  Re  Re4  1  0.499  0.850  0.655  1.0
  Re  Re5  1  0.501  0.150  0.345  1.0
  Re  Re6  1  0.150  0.501  0.845  1.0
  Re  Re7  1  0.850  0.499  0.155  1.0
  Re  Re8  1  0.493  0.107  0.606  1.0
  Re  Re9  1  0.507  0.893  0.394  1.0
  Re  Re10  1  0.893  0.507  0.894  1.0
  Re  Re11  1  0.107  0.493  0.106  1.0
  Se  Se12  1  0.370  0.974  0.840  1.0
  Se  Se13  1  0.630  0.026  0.160  1.0
  Se  Se14  1  0.026  0.630  0.660  1.0
  Se  Se15  1  0.974  0.370  0.340  1.0
  Se  Se16  1  0.312  0.290  0.515  1.0
  Se  Se17  1  0.688  0.710  0.485  1.0
  Se  Se18  1  0.710  0.688  0.985  1.0
  Se  Se19  1  0.290  0.312  0.015  1.0
  Se  Se20  1  0.317  0.824  0.597  1.0
  Se  Se21  1  0.683  0.176  0.403  1.0
  Se  Se22  1  0.176  0.683  0.903  1.0
  Se  Se23  1  0.824  0.317  0.097  1.0
  Se  Se24  1  0.681  0.901  0.690  1.0
  Se  Se25  1  0.319  0.099  0.310  1.0
  Se  Se26  1  0.099  0.319  0.810  1.0
  Se  Se27  1  0.901  0.681  0.190  1.0
  O  O28  1  0.623  0.377  0.750  1.0
  O  O29  1  0.377  0.623  0.250  1.0
  O  O30  1  0.955  0.043  0.526  1.0
  O  O31  1  0.045  0.957  0.474  1.0
  O  O32  1  0.957  0.045  0.974  1.0
  O  O33  1  0.043  0.955  0.026  1.0
  O  O34  1  0.560  0.087  0.030  1.0
  O  O35  1  0.440  0.913  0.970  1.0
  O  O36  1  0.913  0.440  0.470  1.0
  O  O37  1  0.087  0.560  0.530  1.0
  O  O38  1  0.654  0.303  0.863  1.0
  O  O39  1  0.346  0.697  0.137  1.0
  O  O40  1  0.697  0.346  0.637  1.0
  O  O41  1  0.303  0.654  0.363  1.0
  F  F42  1  0.495  0.211  0.707  1.0
  F  F43  1  0.505  0.789  0.293  1.0
  F  F44  1  0.789  0.505  0.793  1.0
  F  F45  1  0.211  0.495  0.207  1.0
  F  F46  1  0.508  0.685  0.804  1.0
  F  F47  1  0.492  0.315  0.196  1.0
  F  F48  1  0.315  0.492  0.696  1.0
  F  F49  1  0.685  0.508  0.304  1.0
  F  F50  1  0.904  0.861  0.823  1.0
  F  F51  1  0.096  0.139  0.177  1.0
  F  F52  1  0.139  0.096  0.677  1.0
  F  F53  1  0.861  0.904  0.323  1.0
[/CIF]
.
The material described by (ReSeF)12(SeO)4(O2)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, eight oxyselenide molecules, four trioxidane molecules, and four ReSeF clusters. In each ReSeF cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(3) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(2) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(1) atom. There are three inequivalent Se sites. In the first Se site, Se(3) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second Se site, Se(4) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the third Se site, Se(2) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_Re6Se8O7F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.523
_cell_length_b   11.523
_cell_length_c   10.952
_cell_angle_alpha   66.235
_cell_angle_beta   66.235
_cell_angle_gamma   65.709
_symmetry_Int_Tables_number   1
_cell_volume   1163.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.316  0.056  0.550  1.0
  Re  Re1  1  0.684  0.944  0.450  1.0
  Re  Re2  1  0.944  0.684  0.950  1.0
  Re  Re3  1  0.056  0.316  0.050  1.0
  Re  Re4  1  0.499  0.850  0.655  1.0
  Re  Re5  1  0.501  0.150  0.345  1.0
  Re  Re6  1  0.150  0.501  0.845  1.0
  Re  Re7  1  0.850  0.499  0.155  1.0
  Re  Re8  1  0.493  0.107  0.606  1.0
  Re  Re9  1  0.507  0.893  0.394  1.0
  Re  Re10  1  0.893  0.507  0.894  1.0
  Re  Re11  1  0.107  0.493  0.106  1.0
  Se  Se12  1  0.370  0.974  0.840  1.0
  Se  Se13  1  0.630  0.026  0.160  1.0
  Se  Se14  1  0.026  0.630  0.660  1.0
  Se  Se15  1  0.974  0.370  0.340  1.0
  Se  Se16  1  0.312  0.290  0.515  1.0
  Se  Se17  1  0.688  0.710  0.485  1.0
  Se  Se18  1  0.710  0.688  0.985  1.0
  Se  Se19  1  0.290  0.312  0.015  1.0
  Se  Se20  1  0.317  0.824  0.597  1.0
  Se  Se21  1  0.683  0.176  0.403  1.0
  Se  Se22  1  0.176  0.683  0.903  1.0
  Se  Se23  1  0.824  0.317  0.097  1.0
  Se  Se24  1  0.681  0.901  0.690  1.0
  Se  Se25  1  0.319  0.099  0.310  1.0
  Se  Se26  1  0.099  0.319  0.810  1.0
  Se  Se27  1  0.901  0.681  0.190  1.0
  O  O28  1  0.623  0.377  0.750  1.0
  O  O29  1  0.377  0.623  0.250  1.0
  O  O30  1  0.955  0.043  0.526  1.0
  O  O31  1  0.045  0.957  0.474  1.0
  O  O32  1  0.957  0.045  0.974  1.0
  O  O33  1  0.043  0.955  0.026  1.0
  O  O34  1  0.560  0.087  0.030  1.0
  O  O35  1  0.440  0.913  0.970  1.0
  O  O36  1  0.913  0.440  0.470  1.0
  O  O37  1  0.087  0.560  0.530  1.0
  O  O38  1  0.654  0.303  0.863  1.0
  O  O39  1  0.346  0.697  0.137  1.0
  O  O40  1  0.697  0.346  0.637  1.0
  O  O41  1  0.303  0.654  0.363  1.0
  F  F42  1  0.495  0.211  0.707  1.0
  F  F43  1  0.505  0.789  0.293  1.0
  F  F44  1  0.789  0.505  0.793  1.0
  F  F45  1  0.211  0.495  0.207  1.0
  F  F46  1  0.508  0.685  0.804  1.0
  F  F47  1  0.492  0.315  0.196  1.0
  F  F48  1  0.315  0.492  0.696  1.0
  F  F49  1  0.685  0.508  0.304  1.0
  F  F50  1  0.904  0.861  0.823  1.0
  F  F51  1  0.096  0.139  0.177  1.0
  F  F52  1  0.139  0.096  0.677  1.0
  F  F53  1  0.861  0.904  0.323  1.0
[/CIF]
.