The compound described by La(AuF4)3 crystallizes in the trigonal R-3c space group. La(1) is bonded in a 9-coordinate geometry to three equivalent F(2) and six equivalent F(1) atoms. Au(1) is bonded in a square co-planar geometry to one F(2), one F(3), and two equivalent F(1) atoms. There are three inequivalent F sites. In the first F site, F(2) is bonded in a linear geometry to one La(1) and one Au(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Au(1) atom. In the third F site, F(1) is bonded in a bent 150 degrees geometry to one La(1) and one Au(1) atom. is represented by the CIF file [CIF]
data_La(AuF4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.180
_cell_length_b   8.180
_cell_length_c   8.180
_cell_angle_alpha   80.974
_cell_angle_beta   80.974
_cell_angle_gamma   80.974
_symmetry_Int_Tables_number   1
_cell_volume   528.894
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.250  0.250  0.250  1.0
  La  La1  1  0.750  0.750  0.750  1.0
  Au  Au2  1  0.163  0.337  0.750  1.0
  Au  Au3  1  0.250  0.837  0.663  1.0
  Au  Au4  1  0.663  0.250  0.837  1.0
  Au  Au5  1  0.837  0.663  0.250  1.0
  Au  Au6  1  0.337  0.750  0.163  1.0
  Au  Au7  1  0.750  0.163  0.337  1.0
  F  F8  1  0.509  0.200  0.376  1.0
  F  F9  1  0.376  0.509  0.200  1.0
  F  F10  1  0.200  0.376  0.509  1.0
  F  F11  1  0.991  0.124  0.300  1.0
  F  F12  1  0.300  0.991  0.124  1.0
  F  F13  1  0.124  0.300  0.991  1.0
  F  F14  1  0.491  0.800  0.624  1.0
  F  F15  1  0.624  0.491  0.800  1.0
  F  F16  1  0.022  0.478  0.250  1.0
  F  F17  1  0.478  0.250  0.022  1.0
  F  F18  1  0.250  0.022  0.478  1.0
  F  F19  1  0.978  0.522  0.750  1.0
  F  F20  1  0.522  0.750  0.978  1.0
  F  F21  1  0.750  0.978  0.522  1.0
  F  F22  1  0.657  0.843  0.250  1.0
  F  F23  1  0.843  0.250  0.657  1.0
  F  F24  1  0.250  0.657  0.843  1.0
  F  F25  1  0.343  0.157  0.750  1.0
  F  F26  1  0.157  0.750  0.343  1.0
  F  F27  1  0.750  0.343  0.157  1.0
  F  F28  1  0.876  0.700  0.009  1.0
  F  F29  1  0.700  0.009  0.876  1.0
  F  F30  1  0.009  0.876  0.700  1.0
  F  F31  1  0.800  0.624  0.491  1.0
[/CIF]
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The compound described by La(AuF4)3 crystallizes in the trigonal R-3c space group. La(1) is bonded in a 9-coordinate geometry to three equivalent F(2) and six equivalent F(1) atoms. Au(1) is bonded in a square co-planar geometry to one F(2), one F(3), and two equivalent F(1) atoms. There are three inequivalent F sites. In the first F site, F(2) is bonded in a linear geometry to one La(1) and one Au(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Au(1) atom. In the third F site, F(1) is bonded in a bent 150 degrees geometry to one La(1) and one Au(1) atom. is represented by the CIF file [CIF]
data_La(AuF4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.180
_cell_length_b   8.180
_cell_length_c   8.180
_cell_angle_alpha   80.974
_cell_angle_beta   80.974
_cell_angle_gamma   80.974
_symmetry_Int_Tables_number   1
_cell_volume   528.894
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.250  0.250  0.250  1.0
  La  La1  1  0.750  0.750  0.750  1.0
  Au  Au2  1  0.163  0.337  0.750  1.0
  Au  Au3  1  0.250  0.837  0.663  1.0
  Au  Au4  1  0.663  0.250  0.837  1.0
  Au  Au5  1  0.837  0.663  0.250  1.0
  Au  Au6  1  0.337  0.750  0.163  1.0
  Au  Au7  1  0.750  0.163  0.337  1.0
  F  F8  1  0.509  0.200  0.376  1.0
  F  F9  1  0.376  0.509  0.200  1.0
  F  F10  1  0.200  0.376  0.509  1.0
  F  F11  1  0.991  0.124  0.300  1.0
  F  F12  1  0.300  0.991  0.124  1.0
  F  F13  1  0.124  0.300  0.991  1.0
  F  F14  1  0.491  0.800  0.624  1.0
  F  F15  1  0.624  0.491  0.800  1.0
  F  F16  1  0.022  0.478  0.250  1.0
  F  F17  1  0.478  0.250  0.022  1.0
  F  F18  1  0.250  0.022  0.478  1.0
  F  F19  1  0.978  0.522  0.750  1.0
  F  F20  1  0.522  0.750  0.978  1.0
  F  F21  1  0.750  0.978  0.522  1.0
  F  F22  1  0.657  0.843  0.250  1.0
  F  F23  1  0.843  0.250  0.657  1.0
  F  F24  1  0.250  0.657  0.843  1.0
  F  F25  1  0.343  0.157  0.750  1.0
  F  F26  1  0.157  0.750  0.343  1.0
  F  F27  1  0.750  0.343  0.157  1.0
  F  F28  1  0.876  0.700  0.009  1.0
  F  F29  1  0.700  0.009  0.876  1.0
  F  F30  1  0.009  0.876  0.700  1.0
  F  F31  1  0.800  0.624  0.491  1.0
[/CIF]
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