The crystal structure described by Sr3RhN3 crystallizes in the hexagonal P6_3/m space group. Sr(1) is bonded to five equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing SrN5 trigonal bipyramids. Rh(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded to five equivalent Sr(1) and one Rh(1) atom to form a mixture of distorted corner and edge-sharing NSr5Rh octahedra. The corner-sharing octahedral tilt angles range from 12-49°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3RhN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.689
_cell_length_b   7.690
_cell_length_c   5.306
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.996
_symmetry_Int_Tables_number   1
_cell_volume   271.730
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.906  0.637  0.250  1.0
  Sr  Sr1  1  0.731  0.094  0.250  1.0
  Sr  Sr2  1  0.363  0.269  0.250  1.0
  Sr  Sr3  1  0.094  0.363  0.750  1.0
  Sr  Sr4  1  0.269  0.906  0.750  1.0
  Sr  Sr5  1  0.637  0.731  0.750  1.0
  Rh  Rh6  1  0.667  0.333  0.750  1.0
  Rh  Rh7  1  0.333  0.667  0.250  1.0
  N  N8  1  0.894  0.594  0.750  1.0
  N  N9  1  0.701  0.106  0.750  1.0
  N  N10  1  0.406  0.299  0.750  1.0
  N  N11  1  0.106  0.406  0.250  1.0
  N  N12  1  0.299  0.894  0.250  1.0
  N  N13  1  0.594  0.701  0.250  1.0
[/CIF]
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The crystal structure described by Sr3RhN3 crystallizes in the hexagonal P6_3/m space group. Sr(1) is bonded to five equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing SrN5 trigonal bipyramids. Rh(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded to five equivalent Sr(1) and one Rh(1) atom to form a mixture of distorted corner and edge-sharing NSr5Rh octahedra. The corner-sharing octahedral tilt angles range from 12-49°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3RhN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.689
_cell_length_b   7.690
_cell_length_c   5.306
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.996
_symmetry_Int_Tables_number   1
_cell_volume   271.730
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.906  0.637  0.250  1.0
  Sr  Sr1  1  0.731  0.094  0.250  1.0
  Sr  Sr2  1  0.363  0.269  0.250  1.0
  Sr  Sr3  1  0.094  0.363  0.750  1.0
  Sr  Sr4  1  0.269  0.906  0.750  1.0
  Sr  Sr5  1  0.637  0.731  0.750  1.0
  Rh  Rh6  1  0.667  0.333  0.750  1.0
  Rh  Rh7  1  0.333  0.667  0.250  1.0
  N  N8  1  0.894  0.594  0.750  1.0
  N  N9  1  0.701  0.106  0.750  1.0
  N  N10  1  0.406  0.299  0.750  1.0
  N  N11  1  0.106  0.406  0.250  1.0
  N  N12  1  0.299  0.894  0.250  1.0
  N  N13  1  0.594  0.701  0.250  1.0
[/CIF]
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