The compound described by Na2U2CoH8(C3O7)4 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(13), one O(2), one O(4), and one O(9) atom. U(1) is bonded in a distorted q6 geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. Co(1) is bonded in an octahedral geometry to two equivalent O(13), two equivalent O(14), and two equivalent O(7) atoms. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(8) atom. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(13) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(14) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one U(1), and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Na(1), one U(1), and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(1) and one C(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one C(5) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one U(1) and one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one C(6) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one U(1) and one C(6) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Na(1), one Co(1), one H(1), and one H(2) atom. In the fourteenth O site, O(14) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2U2CoH8(C3O7)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.528
_cell_length_b   7.917
_cell_length_c   13.006
_cell_angle_alpha   75.702
_cell_angle_beta   84.652
_cell_angle_gamma   67.670
_symmetry_Int_Tables_number   1
_cell_volume   602.477
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.747  0.838  0.791  1.0
  Na  Na1  1  0.253  0.162  0.209  1.0
  U  U2  1  0.763  0.337  0.803  1.0
  U  U3  1  0.237  0.663  0.197  1.0
  Co  Co4  1  0.500  0.000  0.500  1.0
  H  H5  1  0.916  0.852  0.576  1.0
  H  H6  1  0.084  0.148  0.424  1.0
  H  H7  1  0.806  0.061  0.594  1.0
  H  H8  1  0.194  0.939  0.406  1.0
  H  H9  1  0.751  0.978  0.319  1.0
  H  H10  1  0.249  0.022  0.681  1.0
  H  H11  1  0.648  0.193  0.326  1.0
  H  H12  1  0.352  0.807  0.674  1.0
  C  C13  1  0.309  0.250  0.774  1.0
  C  C14  1  0.691  0.750  0.226  1.0
  C  C15  1  0.215  0.455  0.781  1.0
  C  C16  1  0.785  0.545  0.219  1.0
  C  C17  1  0.803  0.387  0.544  1.0
  C  C18  1  0.197  0.613  0.456  1.0
  C  C19  1  0.697  0.590  0.561  1.0
  C  C20  1  0.303  0.410  0.439  1.0
  C  C21  1  0.524  0.590  0.979  1.0
  C  C22  1  0.476  0.410  0.021  1.0
  C  C23  1  0.974  0.932  0.975  1.0
  C  C24  1  0.026  0.068  0.025  1.0
  O  O25  1  0.169  0.177  0.767  1.0
  O  O26  1  0.831  0.823  0.233  1.0
  O  O27  1  0.007  0.528  0.790  1.0
  O  O28  1  0.993  0.472  0.210  1.0
  O  O29  1  0.353  0.534  0.776  1.0
  O  O30  1  0.647  0.466  0.224  1.0
  O  O31  1  0.517  0.169  0.775  1.0
  O  O32  1  0.483  0.831  0.225  1.0
  O  O33  1  0.822  0.262  0.632  1.0
  O  O34  1  0.178  0.738  0.368  1.0
  O  O35  1  0.681  0.599  0.658  1.0
  O  O36  1  0.319  0.401  0.342  1.0
  O  O37  1  0.633  0.729  0.483  1.0
  O  O38  1  0.367  0.271  0.517  1.0
  O  O39  1  0.861  0.355  0.455  1.0
  O  O40  1  0.139  0.645  0.545  1.0
  O  O41  1  0.631  0.600  0.892  1.0
  O  O42  1  0.369  0.400  0.108  1.0
  O  O43  1  0.457  0.713  0.033  1.0
  O  O44  1  0.543  0.287  0.967  1.0
  O  O45  1  0.889  0.999  0.882  1.0
  O  O46  1  0.111  0.001  0.118  1.0
  O  O47  1  0.016  0.767  0.029  1.0
  O  O48  1  0.984  0.233  0.971  1.0
  O  O49  1  0.778  0.945  0.598  1.0
  O  O50  1  0.222  0.055  0.402  1.0
  O  O51  1  0.693  0.064  0.368  1.0
  O  O52  1  0.307  0.936  0.632  1.0
[/CIF]
.
The compound described by Na2U2CoH8(C3O7)4 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(13), one O(2), one O(4), and one O(9) atom. U(1) is bonded in a distorted q6 geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. Co(1) is bonded in an octahedral geometry to two equivalent O(13), two equivalent O(14), and two equivalent O(7) atoms. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(8) atom. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(13) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(14) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one U(1), and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Na(1), one U(1), and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(1) and one C(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one C(5) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one U(1) and one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one C(6) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one U(1) and one C(6) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Na(1), one Co(1), one H(1), and one H(2) atom. In the fourteenth O site, O(14) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2U2CoH8(C3O7)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.528
_cell_length_b   7.917
_cell_length_c   13.006
_cell_angle_alpha   75.702
_cell_angle_beta   84.652
_cell_angle_gamma   67.670
_symmetry_Int_Tables_number   1
_cell_volume   602.477
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.747  0.838  0.791  1.0
  Na  Na1  1  0.253  0.162  0.209  1.0
  U  U2  1  0.763  0.337  0.803  1.0
  U  U3  1  0.237  0.663  0.197  1.0
  Co  Co4  1  0.500  0.000  0.500  1.0
  H  H5  1  0.916  0.852  0.576  1.0
  H  H6  1  0.084  0.148  0.424  1.0
  H  H7  1  0.806  0.061  0.594  1.0
  H  H8  1  0.194  0.939  0.406  1.0
  H  H9  1  0.751  0.978  0.319  1.0
  H  H10  1  0.249  0.022  0.681  1.0
  H  H11  1  0.648  0.193  0.326  1.0
  H  H12  1  0.352  0.807  0.674  1.0
  C  C13  1  0.309  0.250  0.774  1.0
  C  C14  1  0.691  0.750  0.226  1.0
  C  C15  1  0.215  0.455  0.781  1.0
  C  C16  1  0.785  0.545  0.219  1.0
  C  C17  1  0.803  0.387  0.544  1.0
  C  C18  1  0.197  0.613  0.456  1.0
  C  C19  1  0.697  0.590  0.561  1.0
  C  C20  1  0.303  0.410  0.439  1.0
  C  C21  1  0.524  0.590  0.979  1.0
  C  C22  1  0.476  0.410  0.021  1.0
  C  C23  1  0.974  0.932  0.975  1.0
  C  C24  1  0.026  0.068  0.025  1.0
  O  O25  1  0.169  0.177  0.767  1.0
  O  O26  1  0.831  0.823  0.233  1.0
  O  O27  1  0.007  0.528  0.790  1.0
  O  O28  1  0.993  0.472  0.210  1.0
  O  O29  1  0.353  0.534  0.776  1.0
  O  O30  1  0.647  0.466  0.224  1.0
  O  O31  1  0.517  0.169  0.775  1.0
  O  O32  1  0.483  0.831  0.225  1.0
  O  O33  1  0.822  0.262  0.632  1.0
  O  O34  1  0.178  0.738  0.368  1.0
  O  O35  1  0.681  0.599  0.658  1.0
  O  O36  1  0.319  0.401  0.342  1.0
  O  O37  1  0.633  0.729  0.483  1.0
  O  O38  1  0.367  0.271  0.517  1.0
  O  O39  1  0.861  0.355  0.455  1.0
  O  O40  1  0.139  0.645  0.545  1.0
  O  O41  1  0.631  0.600  0.892  1.0
  O  O42  1  0.369  0.400  0.108  1.0
  O  O43  1  0.457  0.713  0.033  1.0
  O  O44  1  0.543  0.287  0.967  1.0
  O  O45  1  0.889  0.999  0.882  1.0
  O  O46  1  0.111  0.001  0.118  1.0
  O  O47  1  0.016  0.767  0.029  1.0
  O  O48  1  0.984  0.233  0.971  1.0
  O  O49  1  0.778  0.945  0.598  1.0
  O  O50  1  0.222  0.055  0.402  1.0
  O  O51  1  0.693  0.064  0.368  1.0
  O  O52  1  0.307  0.936  0.632  1.0
[/CIF]
.