The material described by CSCl(OF)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CSCl(OF)3 clusters. C(1) is bonded to one O(2), one F(1), one F(2), and one F(3) atom to form COF3 tetrahedra that share  a cornercorner with one S(1)ClO3 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form distorted SClO3 tetrahedra that share  a cornercorner with one C(1)OF3 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_CSCl(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   23.680
_cell_length_b   5.282
_cell_length_c   5.397
_cell_angle_alpha   66.996
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   621.396
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.571  0.711  0.179  1.0
  C  C1  1  0.929  0.711  0.679  1.0
  C  C2  1  0.071  0.289  0.321  1.0
  C  C3  1  0.429  0.289  0.821  1.0
  S  S4  1  0.838  0.530  0.509  1.0
  S  S5  1  0.662  0.530  0.009  1.0
  S  S6  1  0.162  0.470  0.491  1.0
  S  S7  1  0.338  0.470  0.991  1.0
  Cl  Cl8  1  0.311  0.117  0.283  1.0
  Cl  Cl9  1  0.811  0.883  0.217  1.0
  Cl  Cl10  1  0.189  0.117  0.783  1.0
  Cl  Cl11  1  0.689  0.883  0.717  1.0
  O  O12  1  0.877  0.399  0.396  1.0
  O  O13  1  0.371  0.348  0.793  1.0
  O  O14  1  0.623  0.399  0.896  1.0
  O  O15  1  0.290  0.606  0.835  1.0
  O  O16  1  0.871  0.652  0.707  1.0
  O  O17  1  0.790  0.395  0.665  1.0
  O  O18  1  0.629  0.652  0.207  1.0
  O  O19  1  0.377  0.601  0.104  1.0
  O  O20  1  0.123  0.601  0.604  1.0
  O  O21  1  0.129  0.348  0.293  1.0
  O  O22  1  0.710  0.395  0.165  1.0
  O  O23  1  0.210  0.606  0.335  1.0
  F  F24  1  0.440  0.150  0.664  1.0
  F  F25  1  0.056  0.133  0.577  1.0
  F  F26  1  0.560  0.850  0.336  1.0
  F  F27  1  0.444  0.133  0.077  1.0
  F  F28  1  0.040  0.521  0.235  1.0
  F  F29  1  0.940  0.850  0.836  1.0
  F  F30  1  0.944  0.867  0.423  1.0
  F  F31  1  0.960  0.479  0.765  1.0
  F  F32  1  0.540  0.479  0.265  1.0
  F  F33  1  0.460  0.521  0.735  1.0
  F  F34  1  0.060  0.150  0.164  1.0
  F  F35  1  0.556  0.867  0.923  1.0
[/CIF]
.
The material described by CSCl(OF)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CSCl(OF)3 clusters. C(1) is bonded to one O(2), one F(1), one F(2), and one F(3) atom to form COF3 tetrahedra that share  a cornercorner with one S(1)ClO3 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form distorted SClO3 tetrahedra that share  a cornercorner with one C(1)OF3 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_CSCl(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   23.680
_cell_length_b   5.282
_cell_length_c   5.397
_cell_angle_alpha   66.996
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   621.396
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.571  0.711  0.179  1.0
  C  C1  1  0.929  0.711  0.679  1.0
  C  C2  1  0.071  0.289  0.321  1.0
  C  C3  1  0.429  0.289  0.821  1.0
  S  S4  1  0.838  0.530  0.509  1.0
  S  S5  1  0.662  0.530  0.009  1.0
  S  S6  1  0.162  0.470  0.491  1.0
  S  S7  1  0.338  0.470  0.991  1.0
  Cl  Cl8  1  0.311  0.117  0.283  1.0
  Cl  Cl9  1  0.811  0.883  0.217  1.0
  Cl  Cl10  1  0.189  0.117  0.783  1.0
  Cl  Cl11  1  0.689  0.883  0.717  1.0
  O  O12  1  0.877  0.399  0.396  1.0
  O  O13  1  0.371  0.348  0.793  1.0
  O  O14  1  0.623  0.399  0.896  1.0
  O  O15  1  0.290  0.606  0.835  1.0
  O  O16  1  0.871  0.652  0.707  1.0
  O  O17  1  0.790  0.395  0.665  1.0
  O  O18  1  0.629  0.652  0.207  1.0
  O  O19  1  0.377  0.601  0.104  1.0
  O  O20  1  0.123  0.601  0.604  1.0
  O  O21  1  0.129  0.348  0.293  1.0
  O  O22  1  0.710  0.395  0.165  1.0
  O  O23  1  0.210  0.606  0.335  1.0
  F  F24  1  0.440  0.150  0.664  1.0
  F  F25  1  0.056  0.133  0.577  1.0
  F  F26  1  0.560  0.850  0.336  1.0
  F  F27  1  0.444  0.133  0.077  1.0
  F  F28  1  0.040  0.521  0.235  1.0
  F  F29  1  0.940  0.850  0.836  1.0
  F  F30  1  0.944  0.867  0.423  1.0
  F  F31  1  0.960  0.479  0.765  1.0
  F  F32  1  0.540  0.479  0.265  1.0
  F  F33  1  0.460  0.521  0.735  1.0
  F  F34  1  0.060  0.150  0.164  1.0
  F  F35  1  0.556  0.867  0.923  1.0
[/CIF]
.