The compound described by HfCl6(Te)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two HfCl6 clusters and two Te clusters. In each HfCl6 cluster, Hf(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Hf(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Hf(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Hf(1) atom. In each Te cluster, there are eight inequivalent Te sites. In the first Te site, Te(1) is bonded in a 2-coordinate geometry to one Te(2) and one Te(5) atom. In the second Te site, Te(2) is bonded in a distorted L-shaped geometry to one Te(1) and one Te(4) atom. In the third Te site, Te(3) is bonded in a 3-coordinate geometry to one Te(4), one Te(5), and one Te(7) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to one Te(2), one Te(3), and one Te(6) atom. In the fifth Te site, Te(5) is bonded in a distorted L-shaped geometry to one Te(1) and one Te(3) atom. In the sixth Te site, Te(6) is bonded in an L-shaped geometry to one Te(4) and one Te(8) atom. In the seventh Te site, Te(7) is bonded in a 2-coordinate geometry to one Te(3) and one Te(8) atom. In the eighth Te site, Te(8) is bonded in an L-shaped geometry to one Te(6) and one Te(7) atom. is represented by the CIF file [CIF]
data_Hf(Te4Cl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.323
_cell_length_b   9.004
_cell_length_c   16.998
_cell_angle_alpha   103.948
_cell_angle_beta   100.106
_cell_angle_gamma   93.664
_symmetry_Int_Tables_number   1
_cell_volume   1064.303
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.000  0.000  0.500  1.0
  Hf  Hf1  1  0.000  0.000  0.000  1.0
  Te  Te2  1  0.541  0.713  0.598  1.0
  Te  Te3  1  0.235  0.666  0.670  1.0
  Te  Te4  1  0.765  0.334  0.330  1.0
  Te  Te5  1  0.210  0.448  0.222  1.0
  Te  Te6  1  0.549  0.276  0.174  1.0
  Te  Te7  1  0.451  0.724  0.826  1.0
  Te  Te8  1  0.647  0.428  0.609  1.0
  Te  Te9  1  0.353  0.572  0.391  1.0
  Te  Te10  1  0.790  0.552  0.778  1.0
  Te  Te11  1  0.715  0.500  0.111  1.0
  Te  Te12  1  0.715  0.296  0.837  1.0
  Te  Te13  1  0.285  0.704  0.163  1.0
  Te  Te14  1  0.341  0.251  0.768  1.0
  Te  Te15  1  0.659  0.749  0.232  1.0
  Te  Te16  1  0.285  0.500  0.889  1.0
  Te  Te17  1  0.459  0.287  0.402  1.0
  Cl  Cl18  1  0.904  0.114  0.631  1.0
  Cl  Cl19  1  0.096  0.886  0.369  1.0
  Cl  Cl20  1  0.676  0.984  0.425  1.0
  Cl  Cl21  1  0.324  0.016  0.575  1.0
  Cl  Cl22  1  0.931  0.737  0.518  1.0
  Cl  Cl23  1  0.069  0.263  0.482  1.0
  Cl  Cl24  1  0.995  0.939  0.852  1.0
  Cl  Cl25  1  0.005  0.061  0.148  1.0
  Cl  Cl26  1  0.698  0.106  0.976  1.0
  Cl  Cl27  1  0.302  0.894  0.024  1.0
  Cl  Cl28  1  0.835  0.741  0.985  1.0
  Cl  Cl29  1  0.165  0.259  0.015  1.0
[/CIF]
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The compound described by HfCl6(Te)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two HfCl6 clusters and two Te clusters. In each HfCl6 cluster, Hf(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Hf(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Hf(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Hf(1) atom. In each Te cluster, there are eight inequivalent Te sites. In the first Te site, Te(1) is bonded in a 2-coordinate geometry to one Te(2) and one Te(5) atom. In the second Te site, Te(2) is bonded in a distorted L-shaped geometry to one Te(1) and one Te(4) atom. In the third Te site, Te(3) is bonded in a 3-coordinate geometry to one Te(4), one Te(5), and one Te(7) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to one Te(2), one Te(3), and one Te(6) atom. In the fifth Te site, Te(5) is bonded in a distorted L-shaped geometry to one Te(1) and one Te(3) atom. In the sixth Te site, Te(6) is bonded in an L-shaped geometry to one Te(4) and one Te(8) atom. In the seventh Te site, Te(7) is bonded in a 2-coordinate geometry to one Te(3) and one Te(8) atom. In the eighth Te site, Te(8) is bonded in an L-shaped geometry to one Te(6) and one Te(7) atom. is represented by the CIF file [CIF]
data_Hf(Te4Cl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.323
_cell_length_b   9.004
_cell_length_c   16.998
_cell_angle_alpha   103.948
_cell_angle_beta   100.106
_cell_angle_gamma   93.664
_symmetry_Int_Tables_number   1
_cell_volume   1064.303
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.000  0.000  0.500  1.0
  Hf  Hf1  1  0.000  0.000  0.000  1.0
  Te  Te2  1  0.541  0.713  0.598  1.0
  Te  Te3  1  0.235  0.666  0.670  1.0
  Te  Te4  1  0.765  0.334  0.330  1.0
  Te  Te5  1  0.210  0.448  0.222  1.0
  Te  Te6  1  0.549  0.276  0.174  1.0
  Te  Te7  1  0.451  0.724  0.826  1.0
  Te  Te8  1  0.647  0.428  0.609  1.0
  Te  Te9  1  0.353  0.572  0.391  1.0
  Te  Te10  1  0.790  0.552  0.778  1.0
  Te  Te11  1  0.715  0.500  0.111  1.0
  Te  Te12  1  0.715  0.296  0.837  1.0
  Te  Te13  1  0.285  0.704  0.163  1.0
  Te  Te14  1  0.341  0.251  0.768  1.0
  Te  Te15  1  0.659  0.749  0.232  1.0
  Te  Te16  1  0.285  0.500  0.889  1.0
  Te  Te17  1  0.459  0.287  0.402  1.0
  Cl  Cl18  1  0.904  0.114  0.631  1.0
  Cl  Cl19  1  0.096  0.886  0.369  1.0
  Cl  Cl20  1  0.676  0.984  0.425  1.0
  Cl  Cl21  1  0.324  0.016  0.575  1.0
  Cl  Cl22  1  0.931  0.737  0.518  1.0
  Cl  Cl23  1  0.069  0.263  0.482  1.0
  Cl  Cl24  1  0.995  0.939  0.852  1.0
  Cl  Cl25  1  0.005  0.061  0.148  1.0
  Cl  Cl26  1  0.698  0.106  0.976  1.0
  Cl  Cl27  1  0.302  0.894  0.024  1.0
  Cl  Cl28  1  0.835  0.741  0.985  1.0
  Cl  Cl29  1  0.165  0.259  0.015  1.0
[/CIF]
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