The crystal structure described by Li3SbF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Li site, Li(2) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. In the third Li site, Li(3) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a T-shaped geometry to one Li(2), one Li(3), and one Sb(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Li(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a T-shaped geometry to one Li(2), one Li(3), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Li3SbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.468
_cell_length_b   7.788
_cell_length_c   7.639
_cell_angle_alpha   77.953
_cell_angle_beta   104.656
_cell_angle_gamma   129.581
_symmetry_Int_Tables_number   1
_cell_volume   242.065
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.500  1.0
  Li  Li1  1  0.500  0.500  0.000  1.0
  Li  Li2  1  0.000  0.500  0.000  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.047  0.307  0.911  1.0
  F  F5  1  0.953  0.693  0.089  1.0
  F  F6  1  0.927  0.911  0.726  1.0
  F  F7  1  0.073  0.089  0.274  1.0
  F  F8  1  0.472  0.732  0.997  1.0
  F  F9  1  0.528  0.268  0.003  1.0
[/CIF]
.
The crystal structure described by Li3SbF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Li site, Li(2) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. In the third Li site, Li(3) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a T-shaped geometry to one Li(2), one Li(3), and one Sb(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Li(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a T-shaped geometry to one Li(2), one Li(3), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Li3SbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.468
_cell_length_b   7.788
_cell_length_c   7.639
_cell_angle_alpha   77.953
_cell_angle_beta   104.656
_cell_angle_gamma   129.581
_symmetry_Int_Tables_number   1
_cell_volume   242.065
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.500  1.0
  Li  Li1  1  0.500  0.500  0.000  1.0
  Li  Li2  1  0.000  0.500  0.000  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.047  0.307  0.911  1.0
  F  F5  1  0.953  0.693  0.089  1.0
  F  F6  1  0.927  0.911  0.726  1.0
  F  F7  1  0.073  0.089  0.274  1.0
  F  F8  1  0.472  0.732  0.997  1.0
  F  F9  1  0.528  0.268  0.003  1.0
[/CIF]
.