The structure described by PdCl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one 7782-50-5 molecule and one Pd3Cl5 cluster. In the Pd3Cl5 cluster, there are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(2), and one Cl(3) atom. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to one Cl(1), one Cl(2), one Cl(4), and one Cl(5) atom. In the third Pd site, Pd(3) is bonded in a T-shaped geometry to one Cl(3), one Cl(4), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to one Pd(1) and one Pd(2) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Pd(1) and one Pd(2) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one Pd(1) and one Pd(3) atom. In the fourth Cl site, Cl(4) is bonded in an L-shaped geometry to one Pd(2) and one Pd(3) atom. In the fifth Cl site, Cl(5) is bonded in an L-shaped geometry to one Pd(2) and one Pd(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PdCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.259
_cell_length_b   9.473
_cell_length_c   10.716
_cell_angle_alpha   80.765
_cell_angle_beta   85.427
_cell_angle_gamma   78.450
_symmetry_Int_Tables_number   1
_cell_volume   613.693
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.593  0.857  0.011  1.0
  Pd  Pd1  1  0.062  0.321  0.197  1.0
  Pd  Pd2  1  0.166  0.371  0.710  1.0
  Pd  Pd3  1  0.407  0.143  0.989  1.0
  Pd  Pd4  1  0.938  0.679  0.803  1.0
  Pd  Pd5  1  0.834  0.629  0.290  1.0
  Cl  Cl6  1  0.402  0.167  0.204  1.0
  Cl  Cl7  1  0.991  0.768  0.986  1.0
  Cl  Cl8  1  0.447  0.181  0.771  1.0
  Cl  Cl9  1  0.598  0.833  0.796  1.0
  Cl  Cl10  1  0.009  0.232  0.014  1.0
  Cl  Cl11  1  0.553  0.819  0.229  1.0
  Cl  Cl12  1  0.705  0.446  0.210  1.0
  Cl  Cl13  1  0.126  0.442  0.360  1.0
  Cl  Cl14  1  0.106  0.013  0.560  1.0
  Cl  Cl15  1  0.295  0.554  0.790  1.0
  Cl  Cl16  1  0.874  0.558  0.640  1.0
  Cl  Cl17  1  0.894  0.987  0.440  1.0
[/CIF]
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The structure described by PdCl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one 7782-50-5 molecule and one Pd3Cl5 cluster. In the Pd3Cl5 cluster, there are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(2), and one Cl(3) atom. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to one Cl(1), one Cl(2), one Cl(4), and one Cl(5) atom. In the third Pd site, Pd(3) is bonded in a T-shaped geometry to one Cl(3), one Cl(4), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to one Pd(1) and one Pd(2) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Pd(1) and one Pd(2) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one Pd(1) and one Pd(3) atom. In the fourth Cl site, Cl(4) is bonded in an L-shaped geometry to one Pd(2) and one Pd(3) atom. In the fifth Cl site, Cl(5) is bonded in an L-shaped geometry to one Pd(2) and one Pd(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PdCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.259
_cell_length_b   9.473
_cell_length_c   10.716
_cell_angle_alpha   80.765
_cell_angle_beta   85.427
_cell_angle_gamma   78.450
_symmetry_Int_Tables_number   1
_cell_volume   613.693
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.593  0.857  0.011  1.0
  Pd  Pd1  1  0.062  0.321  0.197  1.0
  Pd  Pd2  1  0.166  0.371  0.710  1.0
  Pd  Pd3  1  0.407  0.143  0.989  1.0
  Pd  Pd4  1  0.938  0.679  0.803  1.0
  Pd  Pd5  1  0.834  0.629  0.290  1.0
  Cl  Cl6  1  0.402  0.167  0.204  1.0
  Cl  Cl7  1  0.991  0.768  0.986  1.0
  Cl  Cl8  1  0.447  0.181  0.771  1.0
  Cl  Cl9  1  0.598  0.833  0.796  1.0
  Cl  Cl10  1  0.009  0.232  0.014  1.0
  Cl  Cl11  1  0.553  0.819  0.229  1.0
  Cl  Cl12  1  0.705  0.446  0.210  1.0
  Cl  Cl13  1  0.126  0.442  0.360  1.0
  Cl  Cl14  1  0.106  0.013  0.560  1.0
  Cl  Cl15  1  0.295  0.554  0.790  1.0
  Cl  Cl16  1  0.874  0.558  0.640  1.0
  Cl  Cl17  1  0.894  0.987  0.440  1.0
[/CIF]
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