The compound described by Tm(PO)2 is Indium-like structured and crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tm(PO)2 clusters. Tm(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to one Tm(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Tm(PO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.077
_cell_length_b   10.077
_cell_length_c   10.077
_cell_angle_alpha   123.061
_cell_angle_beta   123.061
_cell_angle_gamma   84.775
_symmetry_Int_Tables_number   1
_cell_volume   687.040
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.875  0.125  0.750  1.0
  Tm  Tm1  1  0.375  0.125  0.250  1.0
  Tm  Tm2  1  0.875  0.625  0.750  1.0
  Tm  Tm3  1  0.875  0.125  0.250  1.0
  P  P4  1  0.666  0.306  0.360  1.0
  P  P5  1  0.946  0.306  0.640  1.0
  P  P6  1  0.056  0.196  0.140  1.0
  P  P7  1  0.804  0.944  0.860  1.0
  P  P8  1  0.084  0.944  0.140  1.0
  P  P9  1  0.056  0.916  0.860  1.0
  P  P10  1  0.694  0.054  0.360  1.0
  P  P11  1  0.694  0.334  0.640  1.0
  O  O12  1  0.474  0.268  0.206  1.0
  O  O13  1  0.062  0.268  0.794  1.0
  O  O14  1  0.018  0.312  0.294  1.0
  O  O15  1  0.688  0.982  0.706  1.0
  O  O16  1  0.276  0.982  0.294  1.0
  O  O17  1  0.018  0.724  0.706  1.0
  O  O18  1  0.732  0.938  0.206  1.0
  O  O19  1  0.732  0.526  0.794  1.0
[/CIF]
.
The compound described by Tm(PO)2 is Indium-like structured and crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tm(PO)2 clusters. Tm(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to one Tm(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Tm(PO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.077
_cell_length_b   10.077
_cell_length_c   10.077
_cell_angle_alpha   123.061
_cell_angle_beta   123.061
_cell_angle_gamma   84.775
_symmetry_Int_Tables_number   1
_cell_volume   687.040
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.875  0.125  0.750  1.0
  Tm  Tm1  1  0.375  0.125  0.250  1.0
  Tm  Tm2  1  0.875  0.625  0.750  1.0
  Tm  Tm3  1  0.875  0.125  0.250  1.0
  P  P4  1  0.666  0.306  0.360  1.0
  P  P5  1  0.946  0.306  0.640  1.0
  P  P6  1  0.056  0.196  0.140  1.0
  P  P7  1  0.804  0.944  0.860  1.0
  P  P8  1  0.084  0.944  0.140  1.0
  P  P9  1  0.056  0.916  0.860  1.0
  P  P10  1  0.694  0.054  0.360  1.0
  P  P11  1  0.694  0.334  0.640  1.0
  O  O12  1  0.474  0.268  0.206  1.0
  O  O13  1  0.062  0.268  0.794  1.0
  O  O14  1  0.018  0.312  0.294  1.0
  O  O15  1  0.688  0.982  0.706  1.0
  O  O16  1  0.276  0.982  0.294  1.0
  O  O17  1  0.018  0.724  0.706  1.0
  O  O18  1  0.732  0.938  0.206  1.0
  O  O19  1  0.732  0.526  0.794  1.0
[/CIF]
.