The compound described by FeCl4PCl4 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules and four tetrachloroferrat(iii) molecules. is represented by the Crystallographic Information File (CIF) [CIF]
data_FePCl8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.125
_cell_length_b   13.808
_cell_length_c   13.957
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1180.491
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.266  0.023  0.250  1.0
  Fe  Fe1  1  0.266  0.477  0.750  1.0
  Fe  Fe2  1  0.734  0.523  0.250  1.0
  Fe  Fe3  1  0.734  0.977  0.750  1.0
  P  P4  1  0.953  0.250  0.000  1.0
  P  P5  1  0.047  0.750  0.500  1.0
  P  P6  1  0.047  0.750  0.000  1.0
  P  P7  1  0.953  0.250  0.500  1.0
  Cl  Cl8  1  0.396  0.958  0.118  1.0
  Cl  Cl9  1  0.396  0.542  0.882  1.0
  Cl  Cl10  1  0.604  0.458  0.382  1.0
  Cl  Cl11  1  0.604  0.042  0.618  1.0
  Cl  Cl12  1  0.604  0.042  0.882  1.0
  Cl  Cl13  1  0.604  0.458  0.118  1.0
  Cl  Cl14  1  0.396  0.542  0.618  1.0
  Cl  Cl15  1  0.396  0.958  0.382  1.0
  Cl  Cl16  1  0.334  0.180  0.250  1.0
  Cl  Cl17  1  0.334  0.320  0.750  1.0
  Cl  Cl18  1  0.666  0.680  0.250  1.0
  Cl  Cl19  1  0.666  0.820  0.750  1.0
  Cl  Cl20  1  0.911  0.002  0.250  1.0
  Cl  Cl21  1  0.911  0.498  0.750  1.0
  Cl  Cl22  1  0.089  0.502  0.250  1.0
  Cl  Cl23  1  0.089  0.998  0.750  1.0
  Cl  Cl24  1  0.138  0.353  0.050  1.0
  Cl  Cl25  1  0.138  0.147  0.950  1.0
  Cl  Cl26  1  0.862  0.853  0.450  1.0
  Cl  Cl27  1  0.862  0.647  0.550  1.0
  Cl  Cl28  1  0.862  0.647  0.950  1.0
  Cl  Cl29  1  0.862  0.853  0.050  1.0
  Cl  Cl30  1  0.138  0.147  0.550  1.0
  Cl  Cl31  1  0.138  0.353  0.450  1.0
  Cl  Cl32  1  0.768  0.199  0.101  1.0
  Cl  Cl33  1  0.768  0.301  0.899  1.0
  Cl  Cl34  1  0.232  0.699  0.399  1.0
  Cl  Cl35  1  0.232  0.801  0.601  1.0
  Cl  Cl36  1  0.232  0.801  0.899  1.0
  Cl  Cl37  1  0.232  0.699  0.101  1.0
  Cl  Cl38  1  0.768  0.301  0.601  1.0
  Cl  Cl39  1  0.768  0.199  0.399  1.0
[/CIF]
.
The compound described by FeCl4PCl4 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules and four tetrachloroferrat(iii) molecules. is represented by the Crystallographic Information File (CIF) [CIF]
data_FePCl8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.125
_cell_length_b   13.808
_cell_length_c   13.957
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1180.491
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.266  0.023  0.250  1.0
  Fe  Fe1  1  0.266  0.477  0.750  1.0
  Fe  Fe2  1  0.734  0.523  0.250  1.0
  Fe  Fe3  1  0.734  0.977  0.750  1.0
  P  P4  1  0.953  0.250  0.000  1.0
  P  P5  1  0.047  0.750  0.500  1.0
  P  P6  1  0.047  0.750  0.000  1.0
  P  P7  1  0.953  0.250  0.500  1.0
  Cl  Cl8  1  0.396  0.958  0.118  1.0
  Cl  Cl9  1  0.396  0.542  0.882  1.0
  Cl  Cl10  1  0.604  0.458  0.382  1.0
  Cl  Cl11  1  0.604  0.042  0.618  1.0
  Cl  Cl12  1  0.604  0.042  0.882  1.0
  Cl  Cl13  1  0.604  0.458  0.118  1.0
  Cl  Cl14  1  0.396  0.542  0.618  1.0
  Cl  Cl15  1  0.396  0.958  0.382  1.0
  Cl  Cl16  1  0.334  0.180  0.250  1.0
  Cl  Cl17  1  0.334  0.320  0.750  1.0
  Cl  Cl18  1  0.666  0.680  0.250  1.0
  Cl  Cl19  1  0.666  0.820  0.750  1.0
  Cl  Cl20  1  0.911  0.002  0.250  1.0
  Cl  Cl21  1  0.911  0.498  0.750  1.0
  Cl  Cl22  1  0.089  0.502  0.250  1.0
  Cl  Cl23  1  0.089  0.998  0.750  1.0
  Cl  Cl24  1  0.138  0.353  0.050  1.0
  Cl  Cl25  1  0.138  0.147  0.950  1.0
  Cl  Cl26  1  0.862  0.853  0.450  1.0
  Cl  Cl27  1  0.862  0.647  0.550  1.0
  Cl  Cl28  1  0.862  0.647  0.950  1.0
  Cl  Cl29  1  0.862  0.853  0.050  1.0
  Cl  Cl30  1  0.138  0.147  0.550  1.0
  Cl  Cl31  1  0.138  0.353  0.450  1.0
  Cl  Cl32  1  0.768  0.199  0.101  1.0
  Cl  Cl33  1  0.768  0.301  0.899  1.0
  Cl  Cl34  1  0.232  0.699  0.399  1.0
  Cl  Cl35  1  0.232  0.801  0.601  1.0
  Cl  Cl36  1  0.232  0.801  0.899  1.0
  Cl  Cl37  1  0.232  0.699  0.101  1.0
  Cl  Cl38  1  0.768  0.301  0.601  1.0
  Cl  Cl39  1  0.768  0.199  0.399  1.0
[/CIF]
.