The structure described by Sr2CoSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Pm space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(12), one O(13), one O(14), one O(18), one O(2), one O(20), one O(5), one O(8), one O(9), and two equivalent O(17) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(1)O12 cuboctahedra, corners with two equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra,  a faceface with one Sb(2)O6 octahedra,  a faceface with one Sb(4)O6 octahedra, faces with two equivalent Co(1)O6 octahedra, and faces with two equivalent Sb(1)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(10), one O(14), one O(15), one O(17), one O(19), one O(2), one O(3), one O(5), one O(6), one O(9), and two equivalent O(18) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(2)O12 cuboctahedra, corners with two equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Sb(1)O6 octahedra,  a faceface with one Sb(3)O6 octahedra, faces with two equivalent Co(2)O6 octahedra, and faces with two equivalent Sb(2)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(10), one O(11), one O(15), one O(16), one O(18), one O(20), one O(3), one O(4), one O(6), one O(7), and two equivalent O(19) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(1)O12 cuboctahedra, corners with two equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra,  a faceface with one Sb(2)O6 octahedra,  a faceface with one Sb(4)O6 octahedra, faces with two equivalent Co(3)O6 octahedra, and faces with two equivalent Sb(3)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(1), one O(11), one O(12), one O(13), one O(16), one O(17), one O(19), one O(4), one O(7), one O(8), and two equivalent O(20) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(2)O12 cuboctahedra, corners with two equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Sb(1)O6 octahedra,  a faceface with one Sb(3)O6 octahedra, faces with two equivalent Co(4)O6 octahedra, and faces with two equivalent Sb(4)O6 octahedra. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(13), one O(5), one O(9), and two equivalent O(17) atoms to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Co site, Co(2) is bonded to one O(10), one O(14), one O(2), one O(6), and two equivalent O(18) atoms to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the third Co site, Co(3) is bonded to one O(11), one O(15), one O(3), one O(7), and two equivalent O(19) atoms to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with four equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Co site, Co(4) is bonded to one O(12), one O(16), one O(4), one O(8), and two equivalent O(20) atoms to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-4°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(12), one O(14), one O(2), one O(8), and two equivalent O(17) atoms to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the second Sb site, Sb(2) is bonded to one O(15), one O(3), one O(5), one O(9), and two equivalent O(18) atoms to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the third Sb site, Sb(3) is bonded to one O(10), one O(16), one O(4), one O(6), and two equivalent O(19) atoms to form SbO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with four equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the fourth Sb site, Sb(4) is bonded to one O(1), one O(11), one O(13), one O(7), and two equivalent O(20) atoms to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(4), one Co(1), and one Sb(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted linear geometry to two equivalent Sr(2), two equivalent Sr(3), one Co(3), and one Sb(2) atom. In the fourth O site, O(4) is bonded to two equivalent Sr(3), two equivalent Sr(4), one Co(4), and one Sb(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(5) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to two equivalent Sr(2), two equivalent Sr(3), one Co(2), and one Sb(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(3), two equivalent Sr(4), one Co(3), and one Sb(4) atom. In the eighth O site, O(8) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Co(4), and one Sb(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the tenth O site, O(10) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Co(2), and one Sb(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the eleventh O site, O(11) is bonded to two equivalent Sr(3), two equivalent Sr(4), one Co(3), and one Sb(4) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the twelfth O site, O(12) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Co(4), and one Sb(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the thirteenth O site, O(13) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Co(1), and one Sb(4) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the fourteenth O site, O(14) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifteenth O site, O(15) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Co(3), and one Sb(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the sixteenth O site, O(16) is bonded to two equivalent Sr(3), two equivalent Sr(4), one Co(4), and one Sb(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the seventeenth O site, O(17) is bonded to one Sr(2), one Sr(4), two equivalent Sr(1), one Co(1), and one Sb(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the eighteenth O site, O(18) is bonded to one Sr(1), one Sr(3), two equivalent Sr(2), one Co(2), and one Sb(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the nineteenth O site, O(19) is bonded to one Sr(2), one Sr(4), two equivalent Sr(3), one Co(3), and one Sb(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the twentieth O site, O(20) is bonded to one Sr(1), one Sr(3), two equivalent Sr(4), one Co(4), and one Sb(4) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-61°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr2CoSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.620
_cell_length_b   5.630
_cell_length_c   5.650
_cell_angle_alpha   119.257
_cell_angle_beta   119.197
_cell_angle_gamma   91.095
_symmetry_Int_Tables_number   1
_cell_volume   128.119
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  1.000  1.0
  O  O1  1  0.745  0.745  1.000  1.0
  O  O2  1  0.255  0.255  0.000  1.0
  O  O3  1  0.247  0.751  1.000  1.0
  O  O4  1  0.753  0.249  0.000  1.0
  O  O5  1  0.245  0.245  0.490  1.0
  O  O6  1  0.755  0.755  0.510  1.0
  Sb  Sb7  1  1.000  0.000  0.000  1.0
  Sr  Sr8  1  0.250  0.750  0.499  1.0
  Sr  Sr9  1  0.750  0.251  0.501  1.0
[/CIF]
.
The structure described by Sr2CoSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Pm space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(12), one O(13), one O(14), one O(18), one O(2), one O(20), one O(5), one O(8), one O(9), and two equivalent O(17) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(1)O12 cuboctahedra, corners with two equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra,  a faceface with one Sb(2)O6 octahedra,  a faceface with one Sb(4)O6 octahedra, faces with two equivalent Co(1)O6 octahedra, and faces with two equivalent Sb(1)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(10), one O(14), one O(15), one O(17), one O(19), one O(2), one O(3), one O(5), one O(6), one O(9), and two equivalent O(18) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(2)O12 cuboctahedra, corners with two equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Sb(1)O6 octahedra,  a faceface with one Sb(3)O6 octahedra, faces with two equivalent Co(2)O6 octahedra, and faces with two equivalent Sb(2)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(10), one O(11), one O(15), one O(16), one O(18), one O(20), one O(3), one O(4), one O(6), one O(7), and two equivalent O(19) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(1)O12 cuboctahedra, corners with two equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(4)O6 octahedra,  a faceface with one Sb(2)O6 octahedra,  a faceface with one Sb(4)O6 octahedra, faces with two equivalent Co(3)O6 octahedra, and faces with two equivalent Sb(3)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(1), one O(11), one O(12), one O(13), one O(16), one O(17), one O(19), one O(4), one O(7), one O(8), and two equivalent O(20) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(2)O12 cuboctahedra, corners with two equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Sb(1)O6 octahedra,  a faceface with one Sb(3)O6 octahedra, faces with two equivalent Co(4)O6 octahedra, and faces with two equivalent Sb(4)O6 octahedra. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(13), one O(5), one O(9), and two equivalent O(17) atoms to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Co site, Co(2) is bonded to one O(10), one O(14), one O(2), one O(6), and two equivalent O(18) atoms to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the third Co site, Co(3) is bonded to one O(11), one O(15), one O(3), one O(7), and two equivalent O(19) atoms to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with four equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Co site, Co(4) is bonded to one O(12), one O(16), one O(4), one O(8), and two equivalent O(20) atoms to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-4°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(12), one O(14), one O(2), one O(8), and two equivalent O(17) atoms to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the second Sb site, Sb(2) is bonded to one O(15), one O(3), one O(5), one O(9), and two equivalent O(18) atoms to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the third Sb site, Sb(3) is bonded to one O(10), one O(16), one O(4), one O(6), and two equivalent O(19) atoms to form SbO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with four equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the fourth Sb site, Sb(4) is bonded to one O(1), one O(11), one O(13), one O(7), and two equivalent O(20) atoms to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(4), one Co(1), and one Sb(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted linear geometry to two equivalent Sr(2), two equivalent Sr(3), one Co(3), and one Sb(2) atom. In the fourth O site, O(4) is bonded to two equivalent Sr(3), two equivalent Sr(4), one Co(4), and one Sb(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(5) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to two equivalent Sr(2), two equivalent Sr(3), one Co(2), and one Sb(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(3), two equivalent Sr(4), one Co(3), and one Sb(4) atom. In the eighth O site, O(8) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Co(4), and one Sb(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the tenth O site, O(10) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Co(2), and one Sb(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the eleventh O site, O(11) is bonded to two equivalent Sr(3), two equivalent Sr(4), one Co(3), and one Sb(4) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the twelfth O site, O(12) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Co(4), and one Sb(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the thirteenth O site, O(13) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Co(1), and one Sb(4) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the fourteenth O site, O(14) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifteenth O site, O(15) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Co(3), and one Sb(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the sixteenth O site, O(16) is bonded to two equivalent Sr(3), two equivalent Sr(4), one Co(4), and one Sb(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the seventeenth O site, O(17) is bonded to one Sr(2), one Sr(4), two equivalent Sr(1), one Co(1), and one Sb(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the eighteenth O site, O(18) is bonded to one Sr(1), one Sr(3), two equivalent Sr(2), one Co(2), and one Sb(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the nineteenth O site, O(19) is bonded to one Sr(2), one Sr(4), two equivalent Sr(3), one Co(3), and one Sb(3) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the twentieth O site, O(20) is bonded to one Sr(1), one Sr(3), two equivalent Sr(4), one Co(4), and one Sb(4) atom to form a mixture of distorted edge, corner, and face-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 1-61°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr2CoSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.620
_cell_length_b   5.630
_cell_length_c   5.650
_cell_angle_alpha   119.257
_cell_angle_beta   119.197
_cell_angle_gamma   91.095
_symmetry_Int_Tables_number   1
_cell_volume   128.119
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  1.000  1.0
  O  O1  1  0.745  0.745  1.000  1.0
  O  O2  1  0.255  0.255  0.000  1.0
  O  O3  1  0.247  0.751  1.000  1.0
  O  O4  1  0.753  0.249  0.000  1.0
  O  O5  1  0.245  0.245  0.490  1.0
  O  O6  1  0.755  0.755  0.510  1.0
  Sb  Sb7  1  1.000  0.000  0.000  1.0
  Sr  Sr8  1  0.250  0.750  0.499  1.0
  Sr  Sr9  1  0.750  0.251  0.501  1.0
[/CIF]
.