The material described by Ce2(Pd3Sb)3 crystallizes in the orthorhombic Cmcm space group. Ce(1) is bonded in a 17-coordinate geometry to one Pd(4), two equivalent Pd(1), two equivalent Pd(2), six equivalent Pd(3), two equivalent Sb(1), and four equivalent Sb(2) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 13-coordinate geometry to two equivalent Ce(1), one Pd(1), one Pd(4), two equivalent Pd(3), four equivalent Pd(2), one Sb(1), and two equivalent Sb(2) atoms. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to two equivalent Ce(1), one Pd(4), two equivalent Pd(3), four equivalent Pd(1), and two equivalent Sb(2) atoms. In the third Pd site, Pd(3) is bonded in a 12-coordinate geometry to three equivalent Ce(1), one Pd(1), one Pd(2), one Pd(4), three equivalent Pd(3), one Sb(1), and two equivalent Sb(2) atoms. In the fourth Pd site, Pd(4) is bonded in a 12-coordinate geometry to two equivalent Ce(1), two equivalent Pd(1), two equivalent Pd(2), four equivalent Pd(3), and two equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to four equivalent Ce(1), two equivalent Pd(1), two equivalent Pd(4), and four equivalent Pd(3) atoms to form distorted face-sharing SbCe4Pd8 cuboctahedra. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1), two equivalent Pd(1), two equivalent Pd(2), and four equivalent Pd(3) atoms. is represented by the CIF file [CIF]
data_Ce2(SbPd3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.062
_cell_length_b   8.062
_cell_length_c   9.413
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.710
_symmetry_Int_Tables_number   1
_cell_volume   531.416
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.327  0.019  0.750  1.0
  Ce  Ce1  1  0.673  0.981  0.250  1.0
  Ce  Ce2  1  0.019  0.327  0.750  1.0
  Ce  Ce3  1  0.981  0.673  0.250  1.0
  Sb  Sb4  1  0.000  0.000  0.500  1.0
  Sb  Sb5  1  0.677  0.323  0.000  1.0
  Sb  Sb6  1  0.323  0.677  0.500  1.0
  Sb  Sb7  1  0.323  0.677  0.000  1.0
  Sb  Sb8  1  0.000  0.000  0.000  1.0
  Sb  Sb9  1  0.677  0.323  0.500  1.0
  Pd  Pd10  1  0.331  0.331  0.963  1.0
  Pd  Pd11  1  0.440  0.637  0.750  1.0
  Pd  Pd12  1  0.560  0.363  0.250  1.0
  Pd  Pd13  1  0.637  0.440  0.750  1.0
  Pd  Pd14  1  0.000  0.345  0.090  1.0
  Pd  Pd15  1  1.000  0.655  0.590  1.0
  Pd  Pd16  1  0.345  0.000  0.410  1.0
  Pd  Pd17  1  0.655  1.000  0.910  1.0
  Pd  Pd18  1  1.000  0.655  0.910  1.0
  Pd  Pd19  1  0.000  0.345  0.410  1.0
  Pd  Pd20  1  0.655  1.000  0.590  1.0
  Pd  Pd21  1  0.852  0.852  0.750  1.0
  Pd  Pd22  1  0.331  0.331  0.537  1.0
  Pd  Pd23  1  0.669  0.669  0.037  1.0
  Pd  Pd24  1  0.345  0.000  0.090  1.0
  Pd  Pd25  1  0.669  0.669  0.463  1.0
  Pd  Pd26  1  0.148  0.148  0.250  1.0
  Pd  Pd27  1  0.363  0.560  0.250  1.0
[/CIF]
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The material described by Ce2(Pd3Sb)3 crystallizes in the orthorhombic Cmcm space group. Ce(1) is bonded in a 17-coordinate geometry to one Pd(4), two equivalent Pd(1), two equivalent Pd(2), six equivalent Pd(3), two equivalent Sb(1), and four equivalent Sb(2) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 13-coordinate geometry to two equivalent Ce(1), one Pd(1), one Pd(4), two equivalent Pd(3), four equivalent Pd(2), one Sb(1), and two equivalent Sb(2) atoms. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to two equivalent Ce(1), one Pd(4), two equivalent Pd(3), four equivalent Pd(1), and two equivalent Sb(2) atoms. In the third Pd site, Pd(3) is bonded in a 12-coordinate geometry to three equivalent Ce(1), one Pd(1), one Pd(2), one Pd(4), three equivalent Pd(3), one Sb(1), and two equivalent Sb(2) atoms. In the fourth Pd site, Pd(4) is bonded in a 12-coordinate geometry to two equivalent Ce(1), two equivalent Pd(1), two equivalent Pd(2), four equivalent Pd(3), and two equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to four equivalent Ce(1), two equivalent Pd(1), two equivalent Pd(4), and four equivalent Pd(3) atoms to form distorted face-sharing SbCe4Pd8 cuboctahedra. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1), two equivalent Pd(1), two equivalent Pd(2), and four equivalent Pd(3) atoms. is represented by the CIF file [CIF]
data_Ce2(SbPd3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.062
_cell_length_b   8.062
_cell_length_c   9.413
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.710
_symmetry_Int_Tables_number   1
_cell_volume   531.416
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.327  0.019  0.750  1.0
  Ce  Ce1  1  0.673  0.981  0.250  1.0
  Ce  Ce2  1  0.019  0.327  0.750  1.0
  Ce  Ce3  1  0.981  0.673  0.250  1.0
  Sb  Sb4  1  0.000  0.000  0.500  1.0
  Sb  Sb5  1  0.677  0.323  0.000  1.0
  Sb  Sb6  1  0.323  0.677  0.500  1.0
  Sb  Sb7  1  0.323  0.677  0.000  1.0
  Sb  Sb8  1  0.000  0.000  0.000  1.0
  Sb  Sb9  1  0.677  0.323  0.500  1.0
  Pd  Pd10  1  0.331  0.331  0.963  1.0
  Pd  Pd11  1  0.440  0.637  0.750  1.0
  Pd  Pd12  1  0.560  0.363  0.250  1.0
  Pd  Pd13  1  0.637  0.440  0.750  1.0
  Pd  Pd14  1  0.000  0.345  0.090  1.0
  Pd  Pd15  1  1.000  0.655  0.590  1.0
  Pd  Pd16  1  0.345  0.000  0.410  1.0
  Pd  Pd17  1  0.655  1.000  0.910  1.0
  Pd  Pd18  1  1.000  0.655  0.910  1.0
  Pd  Pd19  1  0.000  0.345  0.410  1.0
  Pd  Pd20  1  0.655  1.000  0.590  1.0
  Pd  Pd21  1  0.852  0.852  0.750  1.0
  Pd  Pd22  1  0.331  0.331  0.537  1.0
  Pd  Pd23  1  0.669  0.669  0.037  1.0
  Pd  Pd24  1  0.345  0.000  0.090  1.0
  Pd  Pd25  1  0.669  0.669  0.463  1.0
  Pd  Pd26  1  0.148  0.148  0.250  1.0
  Pd  Pd27  1  0.363  0.560  0.250  1.0
[/CIF]
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