The structure described by TcF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four technetium fluoride (tcf6), (oc-6-11)- molecules. Tc(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Tc(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Tc(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Tc(1) atom. is represented by the CIF card [CIF]
data_TcF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.863
_cell_length_b   8.490
_cell_length_c   9.198
_cell_angle_alpha   90.000
_cell_angle_beta   90.005
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   379.712
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.920  0.750  0.629  1.0
  Tc  Tc1  1  0.080  0.250  0.371  1.0
  Tc  Tc2  1  0.420  0.250  0.871  1.0
  Tc  Tc3  1  0.580  0.750  0.129  1.0
  F  F4  1  0.225  0.750  0.511  1.0
  F  F5  1  0.775  0.250  0.489  1.0
  F  F6  1  0.725  0.250  0.989  1.0
  F  F7  1  0.275  0.750  0.011  1.0
  F  F8  1  0.614  0.750  0.748  1.0
  F  F9  1  0.386  0.250  0.252  1.0
  F  F10  1  0.114  0.250  0.752  1.0
  F  F11  1  0.886  0.750  0.248  1.0
  F  F12  1  0.767  0.596  0.517  1.0
  F  F13  1  0.233  0.404  0.483  1.0
  F  F14  1  0.267  0.404  0.982  1.0
  F  F15  1  0.233  0.096  0.483  1.0
  F  F16  1  0.733  0.596  0.018  1.0
  F  F17  1  0.767  0.904  0.517  1.0
  F  F18  1  0.733  0.904  0.018  1.0
  F  F19  1  0.267  0.096  0.982  1.0
  F  F20  1  0.070  0.596  0.741  1.0
  F  F21  1  0.930  0.404  0.259  1.0
  F  F22  1  0.570  0.404  0.759  1.0
  F  F23  1  0.930  0.096  0.259  1.0
  F  F24  1  0.430  0.596  0.241  1.0
  F  F25  1  0.070  0.904  0.741  1.0
  F  F26  1  0.430  0.904  0.241  1.0
  F  F27  1  0.570  0.096  0.759  1.0
[/CIF]
.
The structure described by TcF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four technetium fluoride (tcf6), (oc-6-11)- molecules. Tc(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Tc(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Tc(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Tc(1) atom. is represented by the CIF card [CIF]
data_TcF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.863
_cell_length_b   8.490
_cell_length_c   9.198
_cell_angle_alpha   90.000
_cell_angle_beta   90.005
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   379.712
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.920  0.750  0.629  1.0
  Tc  Tc1  1  0.080  0.250  0.371  1.0
  Tc  Tc2  1  0.420  0.250  0.871  1.0
  Tc  Tc3  1  0.580  0.750  0.129  1.0
  F  F4  1  0.225  0.750  0.511  1.0
  F  F5  1  0.775  0.250  0.489  1.0
  F  F6  1  0.725  0.250  0.989  1.0
  F  F7  1  0.275  0.750  0.011  1.0
  F  F8  1  0.614  0.750  0.748  1.0
  F  F9  1  0.386  0.250  0.252  1.0
  F  F10  1  0.114  0.250  0.752  1.0
  F  F11  1  0.886  0.750  0.248  1.0
  F  F12  1  0.767  0.596  0.517  1.0
  F  F13  1  0.233  0.404  0.483  1.0
  F  F14  1  0.267  0.404  0.982  1.0
  F  F15  1  0.233  0.096  0.483  1.0
  F  F16  1  0.733  0.596  0.018  1.0
  F  F17  1  0.767  0.904  0.517  1.0
  F  F18  1  0.733  0.904  0.018  1.0
  F  F19  1  0.267  0.096  0.982  1.0
  F  F20  1  0.070  0.596  0.741  1.0
  F  F21  1  0.930  0.404  0.259  1.0
  F  F22  1  0.570  0.404  0.759  1.0
  F  F23  1  0.930  0.096  0.259  1.0
  F  F24  1  0.430  0.596  0.241  1.0
  F  F25  1  0.070  0.904  0.741  1.0
  F  F26  1  0.430  0.904  0.241  1.0
  F  F27  1  0.570  0.096  0.759  1.0
[/CIF]
.