The compound described by LiCoS2 is Modderite-derived structured and crystallizes in the monoclinic P2/c space group. Li(1) is bonded to six equivalent S(1) atoms to form distorted LiS6 octahedra that share corners with twelve equivalent Co(1)S6 octahedra, edges with six equivalent Li(1)S6 octahedra, and faces with two equivalent Co(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 48-49°. Co(1) is bonded to six equivalent S(1) atoms to form distorted CoS6 octahedra that share corners with twelve equivalent Li(1)S6 octahedra, edges with six equivalent Co(1)S6 octahedra, and faces with two equivalent Li(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 48-49°. S(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCoS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.379
_cell_length_b   3.380
_cell_length_c   5.703
_cell_angle_alpha   89.975
_cell_angle_beta   90.000
_cell_angle_gamma   119.999
_symmetry_Int_Tables_number   1
_cell_volume   56.413
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.000  1.0
  Li  Li1  1  1.000  0.500  0.500  1.0
  S  S2  1  0.667  0.834  0.794  1.0
  S  S3  1  0.333  0.166  0.206  1.0
[/CIF]
.
The compound described by LiCoS2 is Modderite-derived structured and crystallizes in the monoclinic P2/c space group. Li(1) is bonded to six equivalent S(1) atoms to form distorted LiS6 octahedra that share corners with twelve equivalent Co(1)S6 octahedra, edges with six equivalent Li(1)S6 octahedra, and faces with two equivalent Co(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 48-49°. Co(1) is bonded to six equivalent S(1) atoms to form distorted CoS6 octahedra that share corners with twelve equivalent Li(1)S6 octahedra, edges with six equivalent Co(1)S6 octahedra, and faces with two equivalent Li(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 48-49°. S(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCoS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.379
_cell_length_b   3.380
_cell_length_c   5.703
_cell_angle_alpha   89.975
_cell_angle_beta   90.000
_cell_angle_gamma   119.999
_symmetry_Int_Tables_number   1
_cell_volume   56.413
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.000  1.0
  Li  Li1  1  1.000  0.500  0.500  1.0
  S  S2  1  0.667  0.834  0.794  1.0
  S  S3  1  0.333  0.166  0.206  1.0
[/CIF]
.