The crystal structure described by Dy3SbO3 crystallizes in the monoclinic C2/m space group. There are three inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1), one O(1), and three equivalent O(3) atoms. In the second Dy site, Dy(2) is bonded in a distorted see-saw-like geometry to two equivalent Sb(1), one O(2), one O(3), and two equivalent O(1) atoms. In the third Dy site, Dy(3) is bonded in a distorted see-saw-like geometry to two equivalent Sb(1), one O(1), and three equivalent O(2) atoms. Sb(1) is bonded in a body-centered cubic geometry to two equivalent Dy(2), two equivalent Dy(3), and four equivalent Dy(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Dy(1), one Dy(3), and two equivalent Dy(2) atoms to form a mixture of distorted corner and edge-sharing ODy4 trigonal pyramids. In the second O site, O(2) is bonded to one Dy(2) and three equivalent Dy(3) atoms to form a mixture of corner and edge-sharing ODy4 trigonal pyramids. In the third O site, O(3) is bonded to one Dy(2) and three equivalent Dy(1) atoms to form a mixture of corner and edge-sharing ODy4 tetrahedra. is represented by the CIF file [CIF]
data_Dy3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.849
_cell_length_b   6.849
_cell_length_c   11.779
_cell_angle_alpha   62.972
_cell_angle_beta   62.972
_cell_angle_gamma   32.811
_symmetry_Int_Tables_number   1
_cell_volume   263.719
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.121  0.121  0.557  1.0
  Dy  Dy1  1  0.879  0.879  0.443  1.0
  Dy  Dy2  1  0.342  0.342  0.208  1.0
  Dy  Dy3  1  0.658  0.658  0.792  1.0
  Dy  Dy4  1  0.872  0.872  0.902  1.0
  Dy  Dy5  1  0.128  0.128  0.098  1.0
  Sb  Sb6  1  0.382  0.382  0.681  1.0
  Sb  Sb7  1  0.618  0.618  0.319  1.0
  O  O8  1  0.937  0.937  0.192  1.0
  O  O9  1  0.063  0.063  0.808  1.0
  O  O10  1  0.335  0.335  0.016  1.0
  O  O11  1  0.665  0.665  0.984  1.0
  O  O12  1  0.310  0.310  0.409  1.0
  O  O13  1  0.690  0.690  0.591  1.0
[/CIF]
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The crystal structure described by Dy3SbO3 crystallizes in the monoclinic C2/m space group. There are three inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1), one O(1), and three equivalent O(3) atoms. In the second Dy site, Dy(2) is bonded in a distorted see-saw-like geometry to two equivalent Sb(1), one O(2), one O(3), and two equivalent O(1) atoms. In the third Dy site, Dy(3) is bonded in a distorted see-saw-like geometry to two equivalent Sb(1), one O(1), and three equivalent O(2) atoms. Sb(1) is bonded in a body-centered cubic geometry to two equivalent Dy(2), two equivalent Dy(3), and four equivalent Dy(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Dy(1), one Dy(3), and two equivalent Dy(2) atoms to form a mixture of distorted corner and edge-sharing ODy4 trigonal pyramids. In the second O site, O(2) is bonded to one Dy(2) and three equivalent Dy(3) atoms to form a mixture of corner and edge-sharing ODy4 trigonal pyramids. In the third O site, O(3) is bonded to one Dy(2) and three equivalent Dy(1) atoms to form a mixture of corner and edge-sharing ODy4 tetrahedra. is represented by the CIF file [CIF]
data_Dy3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.849
_cell_length_b   6.849
_cell_length_c   11.779
_cell_angle_alpha   62.972
_cell_angle_beta   62.972
_cell_angle_gamma   32.811
_symmetry_Int_Tables_number   1
_cell_volume   263.719
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.121  0.121  0.557  1.0
  Dy  Dy1  1  0.879  0.879  0.443  1.0
  Dy  Dy2  1  0.342  0.342  0.208  1.0
  Dy  Dy3  1  0.658  0.658  0.792  1.0
  Dy  Dy4  1  0.872  0.872  0.902  1.0
  Dy  Dy5  1  0.128  0.128  0.098  1.0
  Sb  Sb6  1  0.382  0.382  0.681  1.0
  Sb  Sb7  1  0.618  0.618  0.319  1.0
  O  O8  1  0.937  0.937  0.192  1.0
  O  O9  1  0.063  0.063  0.808  1.0
  O  O10  1  0.335  0.335  0.016  1.0
  O  O11  1  0.665  0.665  0.984  1.0
  O  O12  1  0.310  0.310  0.409  1.0
  O  O13  1  0.690  0.690  0.591  1.0
[/CIF]
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