The compound described by MgTm2Mo2(O4Cl)2 crystallizes in the monoclinic C2 space group. Mg(1) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. Tm(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(4), and one Cl(1) atom. Mo(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Tm(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), two equivalent Tm(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a T-shaped geometry to one Mg(1), one Tm(1), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Tm(1) and one Mo(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Mg(1) and one Tm(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tm2MgMo2(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.588
_cell_length_b   6.588
_cell_length_c   7.087
_cell_angle_alpha   75.976
_cell_angle_beta   75.976
_cell_angle_gamma   61.921
_symmetry_Int_Tables_number   1
_cell_volume   260.272
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.267  0.286  0.879  1.0
  Tm  Tm1  1  0.714  0.733  0.121  1.0
  Mg  Mg2  1  0.757  0.243  0.000  1.0
  Mo  Mo3  1  0.624  0.674  0.706  1.0
  Mo  Mo4  1  0.326  0.376  0.294  1.0
  Cl  Cl5  1  0.064  0.047  0.205  1.0
  Cl  Cl6  1  0.953  0.936  0.795  1.0
  O  O7  1  0.295  0.295  0.557  1.0
  O  O8  1  0.705  0.705  0.443  1.0
  O  O9  1  0.518  0.117  0.144  1.0
  O  O10  1  0.551  0.494  0.198  1.0
  O  O11  1  0.883  0.482  0.856  1.0
  O  O12  1  0.096  0.519  0.134  1.0
  O  O13  1  0.506  0.449  0.802  1.0
  O  O14  1  0.481  0.904  0.866  1.0
[/CIF]
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The compound described by MgTm2Mo2(O4Cl)2 crystallizes in the monoclinic C2 space group. Mg(1) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. Tm(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(4), and one Cl(1) atom. Mo(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Tm(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), two equivalent Tm(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a T-shaped geometry to one Mg(1), one Tm(1), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Tm(1) and one Mo(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Mg(1) and one Tm(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tm2MgMo2(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.588
_cell_length_b   6.588
_cell_length_c   7.087
_cell_angle_alpha   75.976
_cell_angle_beta   75.976
_cell_angle_gamma   61.921
_symmetry_Int_Tables_number   1
_cell_volume   260.272
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.267  0.286  0.879  1.0
  Tm  Tm1  1  0.714  0.733  0.121  1.0
  Mg  Mg2  1  0.757  0.243  0.000  1.0
  Mo  Mo3  1  0.624  0.674  0.706  1.0
  Mo  Mo4  1  0.326  0.376  0.294  1.0
  Cl  Cl5  1  0.064  0.047  0.205  1.0
  Cl  Cl6  1  0.953  0.936  0.795  1.0
  O  O7  1  0.295  0.295  0.557  1.0
  O  O8  1  0.705  0.705  0.443  1.0
  O  O9  1  0.518  0.117  0.144  1.0
  O  O10  1  0.551  0.494  0.198  1.0
  O  O11  1  0.883  0.482  0.856  1.0
  O  O12  1  0.096  0.519  0.134  1.0
  O  O13  1  0.506  0.449  0.802  1.0
  O  O14  1  0.481  0.904  0.866  1.0
[/CIF]
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