The structure described by Ag2SO3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one O(1), one O(2), and one O(3) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one S(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one S(1) atom. is represented by the CIF card [CIF]
data_Ag2SO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.110
_cell_length_b   4.718
_cell_length_c   10.503
_cell_angle_alpha   68.258
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   373.289
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.113  0.128  0.566  1.0
  Ag  Ag1  1  0.387  0.128  0.066  1.0
  Ag  Ag2  1  0.887  0.872  0.434  1.0
  Ag  Ag3  1  0.613  0.872  0.934  1.0
  Ag  Ag4  1  0.021  0.432  0.201  1.0
  Ag  Ag5  1  0.521  0.568  0.299  1.0
  Ag  Ag6  1  0.979  0.568  0.799  1.0
  Ag  Ag7  1  0.479  0.432  0.701  1.0
  S  S8  1  0.212  0.807  0.879  1.0
  S  S9  1  0.788  0.193  0.121  1.0
  S  S10  1  0.712  0.193  0.621  1.0
  S  S11  1  0.288  0.807  0.379  1.0
  O  O12  1  0.121  0.657  0.373  1.0
  O  O13  1  0.621  0.343  0.127  1.0
  O  O14  1  0.879  0.343  0.627  1.0
  O  O15  1  0.379  0.657  0.873  1.0
  O  O16  1  0.197  0.806  0.025  1.0
  O  O17  1  0.697  0.194  0.475  1.0
  O  O18  1  0.803  0.194  0.975  1.0
  O  O19  1  0.224  0.140  0.783  1.0
  O  O20  1  0.276  0.140  0.283  1.0
  O  O21  1  0.776  0.860  0.217  1.0
  O  O22  1  0.724  0.860  0.717  1.0
  O  O23  1  0.303  0.806  0.525  1.0
[/CIF]
.
The structure described by Ag2SO3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one O(1), one O(2), and one O(3) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one S(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one S(1) atom. is represented by the CIF card [CIF]
data_Ag2SO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.110
_cell_length_b   4.718
_cell_length_c   10.503
_cell_angle_alpha   68.258
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   373.289
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.113  0.128  0.566  1.0
  Ag  Ag1  1  0.387  0.128  0.066  1.0
  Ag  Ag2  1  0.887  0.872  0.434  1.0
  Ag  Ag3  1  0.613  0.872  0.934  1.0
  Ag  Ag4  1  0.021  0.432  0.201  1.0
  Ag  Ag5  1  0.521  0.568  0.299  1.0
  Ag  Ag6  1  0.979  0.568  0.799  1.0
  Ag  Ag7  1  0.479  0.432  0.701  1.0
  S  S8  1  0.212  0.807  0.879  1.0
  S  S9  1  0.788  0.193  0.121  1.0
  S  S10  1  0.712  0.193  0.621  1.0
  S  S11  1  0.288  0.807  0.379  1.0
  O  O12  1  0.121  0.657  0.373  1.0
  O  O13  1  0.621  0.343  0.127  1.0
  O  O14  1  0.879  0.343  0.627  1.0
  O  O15  1  0.379  0.657  0.873  1.0
  O  O16  1  0.197  0.806  0.025  1.0
  O  O17  1  0.697  0.194  0.475  1.0
  O  O18  1  0.803  0.194  0.975  1.0
  O  O19  1  0.224  0.140  0.783  1.0
  O  O20  1  0.276  0.140  0.283  1.0
  O  O21  1  0.776  0.860  0.217  1.0
  O  O22  1  0.724  0.860  0.717  1.0
  O  O23  1  0.303  0.806  0.525  1.0
[/CIF]
.