The compound described by CuVO2 crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. Cu(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to three equivalent V(1) and one Cu(1) atom to form a mixture of distorted corner and edge-sharing OV3Cu trigonal pyramids. is represented by the CIF card [CIF]
data_VCuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.050
_cell_length_b   3.050
_cell_length_c   11.588
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   93.348
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.000  0.000  0.500  1.0
  Cu  Cu2  1  0.667  0.333  0.750  1.0
  Cu  Cu3  1  0.333  0.667  0.250  1.0
  O  O4  1  0.667  0.333  0.591  1.0
  O  O5  1  0.667  0.333  0.909  1.0
  O  O6  1  0.333  0.667  0.091  1.0
  O  O7  1  0.333  0.667  0.409  1.0
[/CIF]
.
The compound described by CuVO2 crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. Cu(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to three equivalent V(1) and one Cu(1) atom to form a mixture of distorted corner and edge-sharing OV3Cu trigonal pyramids. is represented by the CIF card [CIF]
data_VCuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.050
_cell_length_b   3.050
_cell_length_c   11.588
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   93.348
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.000  0.000  0.500  1.0
  Cu  Cu2  1  0.667  0.333  0.750  1.0
  Cu  Cu3  1  0.333  0.667  0.250  1.0
  O  O4  1  0.667  0.333  0.591  1.0
  O  O5  1  0.667  0.333  0.909  1.0
  O  O6  1  0.333  0.667  0.091  1.0
  O  O7  1  0.333  0.667  0.409  1.0
[/CIF]
.