The compound described by Au2Zn(OCl4)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Au2Zn(OCl4)2 clusters. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. In the second Au site, Au(2) is bonded in a rectangular see-saw-like geometry to one Cl(5), one Cl(6), one Cl(7), and one Cl(8) atom. Zn(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(5), and one Cl(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Zn(1) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a water-like geometry to one Au(2) and one Zn(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one Au(2) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Au(2) atom. In the fourth Cl site, Cl(1) is bonded in an L-shaped geometry to one Au(1) and one Zn(1) atom. In the fifth Cl site, Cl(2) is bonded in an L-shaped geometry to one Au(1) and one Zn(1) atom. In the sixth Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the seventh Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the eighth Cl site, Cl(5) is bonded in an L-shaped geometry to one Au(2) and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAu2(Cl4O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.561
_cell_length_b   7.777
_cell_length_c   15.561
_cell_angle_alpha   75.641
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1472.624
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.759  0.804  0.297  1.0
  Zn  Zn1  1  0.741  0.804  0.797  1.0
  Zn  Zn2  1  0.241  0.196  0.703  1.0
  Zn  Zn3  1  0.259  0.196  0.203  1.0
  Au  Au4  1  0.560  0.493  0.365  1.0
  Au  Au5  1  0.940  0.493  0.865  1.0
  Au  Au6  1  0.440  0.507  0.635  1.0
  Au  Au7  1  0.060  0.507  0.135  1.0
  Au  Au8  1  0.975  0.777  0.447  1.0
  Au  Au9  1  0.525  0.777  0.947  1.0
  Au  Au10  1  0.025  0.223  0.553  1.0
  Au  Au11  1  0.475  0.223  0.053  1.0
  Cl  Cl12  1  0.563  0.803  0.316  1.0
  Cl  Cl13  1  0.937  0.803  0.816  1.0
  Cl  Cl14  1  0.437  0.197  0.684  1.0
  Cl  Cl15  1  0.063  0.197  0.184  1.0
  Cl  Cl16  1  0.739  0.491  0.321  1.0
  Cl  Cl17  1  0.761  0.491  0.821  1.0
  Cl  Cl18  1  0.261  0.509  0.679  1.0
  Cl  Cl19  1  0.239  0.509  0.179  1.0
  Cl  Cl20  1  0.558  0.189  0.416  1.0
  Cl  Cl21  1  0.942  0.189  0.916  1.0
  Cl  Cl22  1  0.442  0.811  0.584  1.0
  Cl  Cl23  1  0.058  0.811  0.084  1.0
  Cl  Cl24  1  0.383  0.502  0.400  1.0
  Cl  Cl25  1  0.117  0.502  0.900  1.0
  Cl  Cl26  1  0.617  0.498  0.600  1.0
  Cl  Cl27  1  0.883  0.498  0.100  1.0
  Cl  Cl28  1  0.967  0.779  0.297  1.0
  Cl  Cl29  1  0.533  0.779  0.797  1.0
  Cl  Cl30  1  0.033  0.221  0.703  1.0
  Cl  Cl31  1  0.467  0.221  0.203  1.0
  Cl  Cl32  1  0.792  0.834  0.444  1.0
  Cl  Cl33  1  0.708  0.834  0.944  1.0
  Cl  Cl34  1  0.208  0.166  0.556  1.0
  Cl  Cl35  1  0.292  0.166  0.056  1.0
  Cl  Cl36  1  0.979  0.765  0.597  1.0
  Cl  Cl37  1  0.521  0.765  0.097  1.0
  Cl  Cl38  1  0.021  0.235  0.403  1.0
  Cl  Cl39  1  0.479  0.235  0.903  1.0
  Cl  Cl40  1  0.156  0.730  0.447  1.0
  Cl  Cl41  1  0.344  0.730  0.947  1.0
  Cl  Cl42  1  0.844  0.270  0.553  1.0
  Cl  Cl43  1  0.656  0.270  0.053  1.0
  O  O44  1  0.775  0.885  0.164  1.0
  O  O45  1  0.725  0.885  0.664  1.0
  O  O46  1  0.225  0.115  0.836  1.0
  O  O47  1  0.275  0.115  0.336  1.0
  O  O48  1  0.773  0.068  0.234  1.0
  O  O49  1  0.727  0.068  0.734  1.0
  O  O50  1  0.227  0.932  0.766  1.0
  O  O51  1  0.273  0.932  0.266  1.0
[/CIF]
.
The compound described by Au2Zn(OCl4)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Au2Zn(OCl4)2 clusters. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. In the second Au site, Au(2) is bonded in a rectangular see-saw-like geometry to one Cl(5), one Cl(6), one Cl(7), and one Cl(8) atom. Zn(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(5), and one Cl(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Zn(1) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a water-like geometry to one Au(2) and one Zn(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one Au(2) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Au(2) atom. In the fourth Cl site, Cl(1) is bonded in an L-shaped geometry to one Au(1) and one Zn(1) atom. In the fifth Cl site, Cl(2) is bonded in an L-shaped geometry to one Au(1) and one Zn(1) atom. In the sixth Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the seventh Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the eighth Cl site, Cl(5) is bonded in an L-shaped geometry to one Au(2) and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAu2(Cl4O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.561
_cell_length_b   7.777
_cell_length_c   15.561
_cell_angle_alpha   75.641
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1472.624
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.759  0.804  0.297  1.0
  Zn  Zn1  1  0.741  0.804  0.797  1.0
  Zn  Zn2  1  0.241  0.196  0.703  1.0
  Zn  Zn3  1  0.259  0.196  0.203  1.0
  Au  Au4  1  0.560  0.493  0.365  1.0
  Au  Au5  1  0.940  0.493  0.865  1.0
  Au  Au6  1  0.440  0.507  0.635  1.0
  Au  Au7  1  0.060  0.507  0.135  1.0
  Au  Au8  1  0.975  0.777  0.447  1.0
  Au  Au9  1  0.525  0.777  0.947  1.0
  Au  Au10  1  0.025  0.223  0.553  1.0
  Au  Au11  1  0.475  0.223  0.053  1.0
  Cl  Cl12  1  0.563  0.803  0.316  1.0
  Cl  Cl13  1  0.937  0.803  0.816  1.0
  Cl  Cl14  1  0.437  0.197  0.684  1.0
  Cl  Cl15  1  0.063  0.197  0.184  1.0
  Cl  Cl16  1  0.739  0.491  0.321  1.0
  Cl  Cl17  1  0.761  0.491  0.821  1.0
  Cl  Cl18  1  0.261  0.509  0.679  1.0
  Cl  Cl19  1  0.239  0.509  0.179  1.0
  Cl  Cl20  1  0.558  0.189  0.416  1.0
  Cl  Cl21  1  0.942  0.189  0.916  1.0
  Cl  Cl22  1  0.442  0.811  0.584  1.0
  Cl  Cl23  1  0.058  0.811  0.084  1.0
  Cl  Cl24  1  0.383  0.502  0.400  1.0
  Cl  Cl25  1  0.117  0.502  0.900  1.0
  Cl  Cl26  1  0.617  0.498  0.600  1.0
  Cl  Cl27  1  0.883  0.498  0.100  1.0
  Cl  Cl28  1  0.967  0.779  0.297  1.0
  Cl  Cl29  1  0.533  0.779  0.797  1.0
  Cl  Cl30  1  0.033  0.221  0.703  1.0
  Cl  Cl31  1  0.467  0.221  0.203  1.0
  Cl  Cl32  1  0.792  0.834  0.444  1.0
  Cl  Cl33  1  0.708  0.834  0.944  1.0
  Cl  Cl34  1  0.208  0.166  0.556  1.0
  Cl  Cl35  1  0.292  0.166  0.056  1.0
  Cl  Cl36  1  0.979  0.765  0.597  1.0
  Cl  Cl37  1  0.521  0.765  0.097  1.0
  Cl  Cl38  1  0.021  0.235  0.403  1.0
  Cl  Cl39  1  0.479  0.235  0.903  1.0
  Cl  Cl40  1  0.156  0.730  0.447  1.0
  Cl  Cl41  1  0.344  0.730  0.947  1.0
  Cl  Cl42  1  0.844  0.270  0.553  1.0
  Cl  Cl43  1  0.656  0.270  0.053  1.0
  O  O44  1  0.775  0.885  0.164  1.0
  O  O45  1  0.725  0.885  0.664  1.0
  O  O46  1  0.225  0.115  0.836  1.0
  O  O47  1  0.275  0.115  0.336  1.0
  O  O48  1  0.773  0.068  0.234  1.0
  O  O49  1  0.727  0.068  0.734  1.0
  O  O50  1  0.227  0.932  0.766  1.0
  O  O51  1  0.273  0.932  0.266  1.0
[/CIF]
.