The material described by K4Mn(SO5)4MnO4 crystallizes in the monoclinic C2/m space group. The structure consists of two MnO4 clusters inside a K4Mn(SO5)4 framework. In each MnO4 cluster, Mn(1) is bonded in a square co-planar geometry to four equivalent O(5) atoms. O(5) is bonded in a single-bond geometry to one Mn(1) atom. In the K4Mn(SO5)4 framework, there are two inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(4) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms. Mn(2) is bonded in a square co-planar geometry to four equivalent O(6) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(1) and one S(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to one K(2) and one Mn(2) atom. In the third O site, O(1) is bonded in a distorted linear geometry to one K(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one K(2) and one S(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one K(2) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Mn(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.635
_cell_length_b   7.635
_cell_length_c   11.351
_cell_angle_alpha   88.059
_cell_angle_beta   88.059
_cell_angle_gamma   71.332
_symmetry_Int_Tables_number   1
_cell_volume   626.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.329  0.329  0.052  1.0
  K  K1  1  0.671  0.671  0.948  1.0
  K  K2  1  0.135  0.135  0.603  1.0
  K  K3  1  0.865  0.865  0.397  1.0
  Mn  Mn4  1  0.000  0.000  0.000  1.0
  Mn  Mn5  1  0.500  0.500  0.500  1.0
  S  S6  1  0.410  0.918  0.256  1.0
  S  S7  1  0.918  0.410  0.256  1.0
  S  S8  1  0.590  0.082  0.744  1.0
  S  S9  1  0.082  0.590  0.744  1.0
  O  O10  1  0.492  0.826  0.145  1.0
  O  O11  1  0.826  0.492  0.145  1.0
  O  O12  1  0.508  0.174  0.855  1.0
  O  O13  1  0.174  0.508  0.855  1.0
  O  O14  1  0.528  0.820  0.356  1.0
  O  O15  1  0.820  0.528  0.356  1.0
  O  O16  1  0.472  0.180  0.644  1.0
  O  O17  1  0.180  0.472  0.644  1.0
  O  O18  1  0.218  0.915  0.274  1.0
  O  O19  1  0.915  0.218  0.274  1.0
  O  O20  1  0.782  0.085  0.726  1.0
  O  O21  1  0.085  0.782  0.726  1.0
  O  O22  1  0.411  0.112  0.252  1.0
  O  O23  1  0.112  0.411  0.252  1.0
  O  O24  1  0.589  0.888  0.748  1.0
  O  O25  1  0.888  0.589  0.748  1.0
  O  O26  1  0.230  0.946  0.961  1.0
  O  O27  1  0.946  0.230  0.961  1.0
  O  O28  1  0.770  0.054  0.039  1.0
  O  O29  1  0.054  0.770  0.039  1.0
  O  O30  1  0.581  0.287  0.435  1.0
  O  O31  1  0.287  0.581  0.435  1.0
  O  O32  1  0.419  0.713  0.565  1.0
  O  O33  1  0.713  0.419  0.565  1.0
[/CIF]
.
The material described by K4Mn(SO5)4MnO4 crystallizes in the monoclinic C2/m space group. The structure consists of two MnO4 clusters inside a K4Mn(SO5)4 framework. In each MnO4 cluster, Mn(1) is bonded in a square co-planar geometry to four equivalent O(5) atoms. O(5) is bonded in a single-bond geometry to one Mn(1) atom. In the K4Mn(SO5)4 framework, there are two inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(4) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms. Mn(2) is bonded in a square co-planar geometry to four equivalent O(6) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(1) and one S(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to one K(2) and one Mn(2) atom. In the third O site, O(1) is bonded in a distorted linear geometry to one K(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one K(2) and one S(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one K(2) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Mn(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.635
_cell_length_b   7.635
_cell_length_c   11.351
_cell_angle_alpha   88.059
_cell_angle_beta   88.059
_cell_angle_gamma   71.332
_symmetry_Int_Tables_number   1
_cell_volume   626.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.329  0.329  0.052  1.0
  K  K1  1  0.671  0.671  0.948  1.0
  K  K2  1  0.135  0.135  0.603  1.0
  K  K3  1  0.865  0.865  0.397  1.0
  Mn  Mn4  1  0.000  0.000  0.000  1.0
  Mn  Mn5  1  0.500  0.500  0.500  1.0
  S  S6  1  0.410  0.918  0.256  1.0
  S  S7  1  0.918  0.410  0.256  1.0
  S  S8  1  0.590  0.082  0.744  1.0
  S  S9  1  0.082  0.590  0.744  1.0
  O  O10  1  0.492  0.826  0.145  1.0
  O  O11  1  0.826  0.492  0.145  1.0
  O  O12  1  0.508  0.174  0.855  1.0
  O  O13  1  0.174  0.508  0.855  1.0
  O  O14  1  0.528  0.820  0.356  1.0
  O  O15  1  0.820  0.528  0.356  1.0
  O  O16  1  0.472  0.180  0.644  1.0
  O  O17  1  0.180  0.472  0.644  1.0
  O  O18  1  0.218  0.915  0.274  1.0
  O  O19  1  0.915  0.218  0.274  1.0
  O  O20  1  0.782  0.085  0.726  1.0
  O  O21  1  0.085  0.782  0.726  1.0
  O  O22  1  0.411  0.112  0.252  1.0
  O  O23  1  0.112  0.411  0.252  1.0
  O  O24  1  0.589  0.888  0.748  1.0
  O  O25  1  0.888  0.589  0.748  1.0
  O  O26  1  0.230  0.946  0.961  1.0
  O  O27  1  0.946  0.230  0.961  1.0
  O  O28  1  0.770  0.054  0.039  1.0
  O  O29  1  0.054  0.770  0.039  1.0
  O  O30  1  0.581  0.287  0.435  1.0
  O  O31  1  0.287  0.581  0.435  1.0
  O  O32  1  0.419  0.713  0.565  1.0
  O  O33  1  0.713  0.419  0.565  1.0
[/CIF]
.