The structure described by Li4Co3Cu2Sb3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with three equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-68°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with three equivalent Cu(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-72°. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and corners with three equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cu(1)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 46°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Cu(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Cu(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted CuO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. In the second Cu site, Cu(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 trigonal pyramids,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cu(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 55-56°. In the second Sb site, Sb(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cu(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sb site, Sb(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Cu(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(2), one Cu(1), and one Sb(3) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Cu(1), one Sb(1), and one Sb(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(1), one Sb(1), and one Sb(2) atom. In the fifth O site, O(5) is bonded to one Li(2), one Co(2), one Co(3), and one Sb(3) atom to form distorted OLiCo2Sb tetrahedra that share corners with two equivalent O(15)LiCo2Cu tetrahedra, corners with two equivalent O(11)LiCoCuSb tetrahedra, corners with two equivalent O(12)LiCoCuSb tetrahedra, and  an edgeedge with one O(10)LiCo2Cu trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(3), one Cu(1), and one Sb(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Co(1), one Cu(1), and one Sb(1) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(8)LiCoCuSb tetrahedra,  a cornercorner with one O(10)LiCo2Cu trigonal pyramid, and  an edgeedge with one O(8)LiCoCuSb tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Co(1), one Cu(1), and one Sb(2) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(7)LiCoCuSb tetrahedra,  a cornercorner with one O(10)LiCo2Cu trigonal pyramid, and  an edgeedge with one O(7)LiCoCuSb tetrahedra. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Cu(2), one Sb(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one Co(2), one Co(3), and one Cu(1) atom to form distorted OLiCo2Cu trigonal pyramids that share  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra,  a cornercorner with one O(7)LiCoCuSb tetrahedra,  a cornercorner with one O(8)LiCoCuSb tetrahedra, corners with two equivalent O(15)LiCo2Cu tetrahedra, and  an edgeedge with one O(5)LiCo2Sb tetrahedra. In the eleventh O site, O(11) is bonded to one Li(1), one Co(2), one Cu(2), and one Sb(3) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(15)LiCo2Cu tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra, corners with two equivalent O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(10)LiCo2Cu trigonal pyramid,  an edgeedge with one O(15)LiCo2Cu tetrahedra, and  an edgeedge with one O(12)LiCoCuSb tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one Co(3), one Cu(2), and one Sb(3) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(15)LiCo2Cu tetrahedra,  a cornercorner with one O(11)LiCoCuSb tetrahedra, corners with two equivalent O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(10)LiCo2Cu trigonal pyramid,  an edgeedge with one O(15)LiCo2Cu tetrahedra, and  an edgeedge with one O(11)LiCoCuSb tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(2), one Co(3), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Cu(2), and one Sb(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Co(2), one Co(3), and one Cu(2) atom to form distorted OLiCo2Cu tetrahedra that share  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra, corners with two equivalent O(5)LiCo2Sb tetrahedra, corners with two equivalent O(10)LiCo2Cu trigonal pyramids,  an edgeedge with one O(11)LiCoCuSb tetrahedra, and  an edgeedge with one O(12)LiCoCuSb tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Cu(2), and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Co3Cu2Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.014
_cell_length_b   5.966
_cell_length_c   9.778
_cell_angle_alpha   90.337
_cell_angle_beta   91.553
_cell_angle_gamma   119.503
_symmetry_Int_Tables_number   1
_cell_volume   305.142
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.357  0.677  0.884  1.0
  Li  Li1  1  0.929  0.968  0.987  1.0
  Li  Li2  1  0.981  0.986  0.504  1.0
  Li  Li3  1  0.648  0.326  0.398  1.0
  Co  Co4  1  0.642  0.824  0.217  1.0
  Co  Co5  1  0.857  0.671  0.714  1.0
  Co  Co6  1  0.858  0.180  0.714  1.0
  Cu  Cu7  1  0.350  0.674  0.505  1.0
  Cu  Cu8  1  0.702  0.353  0.982  1.0
  Sb  Sb9  1  0.149  0.825  0.215  1.0
  Sb  Sb10  1  0.149  0.330  0.216  1.0
  Sb  Sb11  1  0.363  0.179  0.716  1.0
  O  O12  1  0.173  0.844  0.604  1.0
  O  O13  1  0.003  0.506  0.331  1.0
  O  O14  1  0.294  0.648  0.097  1.0
  O  O15  1  0.994  0.001  0.321  1.0
  O  O16  1  0.025  0.011  0.811  1.0
  O  O17  1  0.169  0.317  0.604  1.0
  O  O18  1  0.458  0.963  0.337  1.0
  O  O19  1  0.456  0.503  0.341  1.0
  O  O20  1  0.281  0.143  0.100  1.0
  O  O21  1  0.703  0.849  0.617  1.0
  O  O22  1  0.561  0.503  0.835  1.0
  O  O23  1  0.561  0.054  0.835  1.0
  O  O24  1  0.689  0.341  0.609  1.0
  O  O25  1  0.824  0.670  0.101  1.0
  O  O26  1  0.998  0.494  0.812  1.0
  O  O27  1  0.824  0.161  0.101  1.0
[/CIF]
.
The structure described by Li4Co3Cu2Sb3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with three equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-68°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with three equivalent Cu(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-72°. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and corners with three equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cu(1)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 46°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Cu(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Cu(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted CuO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. In the second Cu site, Cu(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 trigonal pyramids,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cu(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 55-56°. In the second Sb site, Sb(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cu(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sb site, Sb(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Cu(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(2), one Cu(1), and one Sb(3) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Cu(1), one Sb(1), and one Sb(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(1), one Sb(1), and one Sb(2) atom. In the fifth O site, O(5) is bonded to one Li(2), one Co(2), one Co(3), and one Sb(3) atom to form distorted OLiCo2Sb tetrahedra that share corners with two equivalent O(15)LiCo2Cu tetrahedra, corners with two equivalent O(11)LiCoCuSb tetrahedra, corners with two equivalent O(12)LiCoCuSb tetrahedra, and  an edgeedge with one O(10)LiCo2Cu trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(3), one Cu(1), and one Sb(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Co(1), one Cu(1), and one Sb(1) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(8)LiCoCuSb tetrahedra,  a cornercorner with one O(10)LiCo2Cu trigonal pyramid, and  an edgeedge with one O(8)LiCoCuSb tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Co(1), one Cu(1), and one Sb(2) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(7)LiCoCuSb tetrahedra,  a cornercorner with one O(10)LiCo2Cu trigonal pyramid, and  an edgeedge with one O(7)LiCoCuSb tetrahedra. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Cu(2), one Sb(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one Co(2), one Co(3), and one Cu(1) atom to form distorted OLiCo2Cu trigonal pyramids that share  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra,  a cornercorner with one O(7)LiCoCuSb tetrahedra,  a cornercorner with one O(8)LiCoCuSb tetrahedra, corners with two equivalent O(15)LiCo2Cu tetrahedra, and  an edgeedge with one O(5)LiCo2Sb tetrahedra. In the eleventh O site, O(11) is bonded to one Li(1), one Co(2), one Cu(2), and one Sb(3) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(15)LiCo2Cu tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra, corners with two equivalent O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(10)LiCo2Cu trigonal pyramid,  an edgeedge with one O(15)LiCo2Cu tetrahedra, and  an edgeedge with one O(12)LiCoCuSb tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one Co(3), one Cu(2), and one Sb(3) atom to form distorted OLiCoCuSb tetrahedra that share  a cornercorner with one O(15)LiCo2Cu tetrahedra,  a cornercorner with one O(11)LiCoCuSb tetrahedra, corners with two equivalent O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(10)LiCo2Cu trigonal pyramid,  an edgeedge with one O(15)LiCo2Cu tetrahedra, and  an edgeedge with one O(11)LiCoCuSb tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(2), one Co(3), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Cu(2), and one Sb(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Co(2), one Co(3), and one Cu(2) atom to form distorted OLiCo2Cu tetrahedra that share  a cornercorner with one O(11)LiCoCuSb tetrahedra,  a cornercorner with one O(12)LiCoCuSb tetrahedra, corners with two equivalent O(5)LiCo2Sb tetrahedra, corners with two equivalent O(10)LiCo2Cu trigonal pyramids,  an edgeedge with one O(11)LiCoCuSb tetrahedra, and  an edgeedge with one O(12)LiCoCuSb tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Cu(2), and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Co3Cu2Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.014
_cell_length_b   5.966
_cell_length_c   9.778
_cell_angle_alpha   90.337
_cell_angle_beta   91.553
_cell_angle_gamma   119.503
_symmetry_Int_Tables_number   1
_cell_volume   305.142
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.357  0.677  0.884  1.0
  Li  Li1  1  0.929  0.968  0.987  1.0
  Li  Li2  1  0.981  0.986  0.504  1.0
  Li  Li3  1  0.648  0.326  0.398  1.0
  Co  Co4  1  0.642  0.824  0.217  1.0
  Co  Co5  1  0.857  0.671  0.714  1.0
  Co  Co6  1  0.858  0.180  0.714  1.0
  Cu  Cu7  1  0.350  0.674  0.505  1.0
  Cu  Cu8  1  0.702  0.353  0.982  1.0
  Sb  Sb9  1  0.149  0.825  0.215  1.0
  Sb  Sb10  1  0.149  0.330  0.216  1.0
  Sb  Sb11  1  0.363  0.179  0.716  1.0
  O  O12  1  0.173  0.844  0.604  1.0
  O  O13  1  0.003  0.506  0.331  1.0
  O  O14  1  0.294  0.648  0.097  1.0
  O  O15  1  0.994  0.001  0.321  1.0
  O  O16  1  0.025  0.011  0.811  1.0
  O  O17  1  0.169  0.317  0.604  1.0
  O  O18  1  0.458  0.963  0.337  1.0
  O  O19  1  0.456  0.503  0.341  1.0
  O  O20  1  0.281  0.143  0.100  1.0
  O  O21  1  0.703  0.849  0.617  1.0
  O  O22  1  0.561  0.503  0.835  1.0
  O  O23  1  0.561  0.054  0.835  1.0
  O  O24  1  0.689  0.341  0.609  1.0
  O  O25  1  0.824  0.670  0.101  1.0
  O  O26  1  0.998  0.494  0.812  1.0
  O  O27  1  0.824  0.161  0.101  1.0
[/CIF]
.