The material described by RbZnB(PO4)2 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(4), one O(6), one O(7), two equivalent O(3), and two equivalent O(8) atoms. Zn(1) is bonded to one O(2), one O(3), one O(4), and one O(8) atom to form ZnO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. B(1) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form BO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra and corners with two equivalent B(1)O4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(5), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra and corners with two equivalent B(1)O4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one B(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Zn(1), and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one Zn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Zn(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one B(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Rb(1), one B(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Rb(1), one B(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one Zn(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbZnB(PO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.547
_cell_length_b   7.757
_cell_length_c   7.960
_cell_angle_alpha   118.628
_cell_angle_beta   101.662
_cell_angle_gamma   103.709
_symmetry_Int_Tables_number   1
_cell_volume   369.130
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.275  0.662  0.417  1.0
  Rb  Rb1  1  0.725  0.338  0.583  1.0
  Zn  Zn2  1  0.198  0.294  0.741  1.0
  Zn  Zn3  1  0.802  0.706  0.259  1.0
  B  B4  1  0.298  0.074  0.069  1.0
  B  B5  1  0.702  0.926  0.931  1.0
  P  P6  1  0.035  0.110  0.275  1.0
  P  P7  1  0.450  0.779  0.081  1.0
  P  P8  1  0.550  0.221  0.919  1.0
  P  P9  1  0.965  0.890  0.725  1.0
  O  O10  1  0.200  0.186  0.203  1.0
  O  O11  1  0.262  0.581  0.976  1.0
  O  O12  1  0.084  0.296  0.496  1.0
  O  O13  1  0.981  0.101  0.750  1.0
  O  O14  1  0.800  0.814  0.797  1.0
  O  O15  1  0.447  0.245  0.078  1.0
  O  O16  1  0.596  0.015  0.837  1.0
  O  O17  1  0.162  0.905  0.856  1.0
  O  O18  1  0.838  0.095  0.144  1.0
  O  O19  1  0.409  0.185  0.724  1.0
  O  O20  1  0.916  0.704  0.504  1.0
  O  O21  1  0.019  0.899  0.250  1.0
  O  O22  1  0.553  0.755  0.922  1.0
  O  O23  1  0.591  0.815  0.276  1.0
  O  O24  1  0.404  0.985  0.163  1.0
  O  O25  1  0.738  0.419  0.024  1.0
[/CIF]
.
The material described by RbZnB(PO4)2 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(4), one O(6), one O(7), two equivalent O(3), and two equivalent O(8) atoms. Zn(1) is bonded to one O(2), one O(3), one O(4), and one O(8) atom to form ZnO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. B(1) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form BO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra and corners with two equivalent B(1)O4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(5), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra and corners with two equivalent B(1)O4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one B(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Zn(1), and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one Zn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Zn(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one B(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Rb(1), one B(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Rb(1), one B(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one Zn(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbZnB(PO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.547
_cell_length_b   7.757
_cell_length_c   7.960
_cell_angle_alpha   118.628
_cell_angle_beta   101.662
_cell_angle_gamma   103.709
_symmetry_Int_Tables_number   1
_cell_volume   369.130
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.275  0.662  0.417  1.0
  Rb  Rb1  1  0.725  0.338  0.583  1.0
  Zn  Zn2  1  0.198  0.294  0.741  1.0
  Zn  Zn3  1  0.802  0.706  0.259  1.0
  B  B4  1  0.298  0.074  0.069  1.0
  B  B5  1  0.702  0.926  0.931  1.0
  P  P6  1  0.035  0.110  0.275  1.0
  P  P7  1  0.450  0.779  0.081  1.0
  P  P8  1  0.550  0.221  0.919  1.0
  P  P9  1  0.965  0.890  0.725  1.0
  O  O10  1  0.200  0.186  0.203  1.0
  O  O11  1  0.262  0.581  0.976  1.0
  O  O12  1  0.084  0.296  0.496  1.0
  O  O13  1  0.981  0.101  0.750  1.0
  O  O14  1  0.800  0.814  0.797  1.0
  O  O15  1  0.447  0.245  0.078  1.0
  O  O16  1  0.596  0.015  0.837  1.0
  O  O17  1  0.162  0.905  0.856  1.0
  O  O18  1  0.838  0.095  0.144  1.0
  O  O19  1  0.409  0.185  0.724  1.0
  O  O20  1  0.916  0.704  0.504  1.0
  O  O21  1  0.019  0.899  0.250  1.0
  O  O22  1  0.553  0.755  0.922  1.0
  O  O23  1  0.591  0.815  0.276  1.0
  O  O24  1  0.404  0.985  0.163  1.0
  O  O25  1  0.738  0.419  0.024  1.0
[/CIF]
.