The material described by Pd(NS)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Pd(NS)4 clusters. Pd(1) is bonded in a square co-planar geometry to one N(2), one N(3), one S(1), and one S(2) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(3) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pd(1) and one N(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one N(1) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. is represented by the CIF file [CIF]
data_Pd(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.438
_cell_length_b   8.472
_cell_length_c   9.126
_cell_angle_alpha   67.225
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   957.934
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.357  0.774  0.777  1.0
  Pd  Pd1  1  0.857  0.726  0.223  1.0
  Pd  Pd2  1  0.643  0.226  0.223  1.0
  Pd  Pd3  1  0.143  0.274  0.777  1.0
  S  S4  1  0.516  0.770  0.854  1.0
  S  S5  1  0.016  0.730  0.146  1.0
  S  S6  1  0.484  0.230  0.146  1.0
  S  S7  1  0.984  0.270  0.854  1.0
  S  S8  1  0.399  0.805  0.529  1.0
  S  S9  1  0.899  0.695  0.471  1.0
  S  S10  1  0.601  0.195  0.471  1.0
  S  S11  1  0.101  0.305  0.529  1.0
  S  S12  1  0.195  0.798  0.534  1.0
  S  S13  1  0.695  0.702  0.466  1.0
  S  S14  1  0.805  0.202  0.466  1.0
  S  S15  1  0.305  0.298  0.534  1.0
  S  S16  1  0.404  0.734  0.116  1.0
  S  S17  1  0.904  0.766  0.884  1.0
  S  S18  1  0.596  0.266  0.884  1.0
  S  S19  1  0.096  0.234  0.116  1.0
  N  N20  1  0.296  0.813  0.432  1.0
  N  N21  1  0.796  0.687  0.568  1.0
  N  N22  1  0.704  0.187  0.568  1.0
  N  N23  1  0.204  0.313  0.432  1.0
  N  N24  1  0.214  0.779  0.706  1.0
  N  N25  1  0.714  0.721  0.294  1.0
  N  N26  1  0.786  0.221  0.294  1.0
  N  N27  1  0.286  0.279  0.706  1.0
  N  N28  1  0.319  0.745  0.999  1.0
  N  N29  1  0.819  0.755  0.001  1.0
  N  N30  1  0.681  0.255  0.001  1.0
  N  N31  1  0.181  0.245  0.999  1.0
  N  N32  1  0.515  0.747  0.039  1.0
  N  N33  1  0.015  0.753  0.961  1.0
  N  N34  1  0.485  0.253  0.961  1.0
  N  N35  1  0.985  0.247  0.039  1.0
[/CIF]
.
The material described by Pd(NS)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Pd(NS)4 clusters. Pd(1) is bonded in a square co-planar geometry to one N(2), one N(3), one S(1), and one S(2) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(3) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pd(1) and one N(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one N(1) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. is represented by the CIF file [CIF]
data_Pd(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.438
_cell_length_b   8.472
_cell_length_c   9.126
_cell_angle_alpha   67.225
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   957.934
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.357  0.774  0.777  1.0
  Pd  Pd1  1  0.857  0.726  0.223  1.0
  Pd  Pd2  1  0.643  0.226  0.223  1.0
  Pd  Pd3  1  0.143  0.274  0.777  1.0
  S  S4  1  0.516  0.770  0.854  1.0
  S  S5  1  0.016  0.730  0.146  1.0
  S  S6  1  0.484  0.230  0.146  1.0
  S  S7  1  0.984  0.270  0.854  1.0
  S  S8  1  0.399  0.805  0.529  1.0
  S  S9  1  0.899  0.695  0.471  1.0
  S  S10  1  0.601  0.195  0.471  1.0
  S  S11  1  0.101  0.305  0.529  1.0
  S  S12  1  0.195  0.798  0.534  1.0
  S  S13  1  0.695  0.702  0.466  1.0
  S  S14  1  0.805  0.202  0.466  1.0
  S  S15  1  0.305  0.298  0.534  1.0
  S  S16  1  0.404  0.734  0.116  1.0
  S  S17  1  0.904  0.766  0.884  1.0
  S  S18  1  0.596  0.266  0.884  1.0
  S  S19  1  0.096  0.234  0.116  1.0
  N  N20  1  0.296  0.813  0.432  1.0
  N  N21  1  0.796  0.687  0.568  1.0
  N  N22  1  0.704  0.187  0.568  1.0
  N  N23  1  0.204  0.313  0.432  1.0
  N  N24  1  0.214  0.779  0.706  1.0
  N  N25  1  0.714  0.721  0.294  1.0
  N  N26  1  0.786  0.221  0.294  1.0
  N  N27  1  0.286  0.279  0.706  1.0
  N  N28  1  0.319  0.745  0.999  1.0
  N  N29  1  0.819  0.755  0.001  1.0
  N  N30  1  0.681  0.255  0.001  1.0
  N  N31  1  0.181  0.245  0.999  1.0
  N  N32  1  0.515  0.747  0.039  1.0
  N  N33  1  0.015  0.753  0.961  1.0
  N  N34  1  0.485  0.253  0.961  1.0
  N  N35  1  0.985  0.247  0.039  1.0
[/CIF]
.