The structure described by Cd(PO3)2 crystallizes in the orthorhombic P2_12_12_1 space group. Cd(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(6) atoms to form distorted CdO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and edges with two equivalent Cd(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second P site, P(2) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-61°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Cd(PO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.384
_cell_length_b   7.417
_cell_length_c   8.536
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.539
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.023  0.142  0.207  1.0
  Cd  Cd1  1  0.977  0.642  0.293  1.0
  Cd  Cd2  1  0.523  0.358  0.793  1.0
  Cd  Cd3  1  0.477  0.858  0.707  1.0
  P  P4  1  0.882  0.060  0.839  1.0
  P  P5  1  0.382  0.440  0.161  1.0
  P  P6  1  0.618  0.940  0.339  1.0
  P  P7  1  0.156  0.162  0.595  1.0
  P  P8  1  0.118  0.560  0.661  1.0
  P  P9  1  0.656  0.338  0.405  1.0
  P  P10  1  0.344  0.838  0.095  1.0
  P  P11  1  0.844  0.662  0.905  1.0
  O  O12  1  0.162  0.098  0.432  1.0
  O  O13  1  0.042  0.687  0.544  1.0
  O  O14  1  0.673  0.647  0.813  1.0
  O  O15  1  0.542  0.813  0.456  1.0
  O  O16  1  0.173  0.853  0.187  1.0
  O  O17  1  0.496  0.441  0.318  1.0
  O  O18  1  0.917  0.863  0.902  1.0
  O  O19  1  0.996  0.059  0.682  1.0
  O  O20  1  0.504  0.941  0.182  1.0
  O  O21  1  0.458  0.313  0.044  1.0
  O  O22  1  0.313  0.580  0.706  1.0
  O  O23  1  0.958  0.187  0.956  1.0
  O  O24  1  0.838  0.598  0.068  1.0
  O  O25  1  0.187  0.420  0.206  1.0
  O  O26  1  0.827  0.353  0.313  1.0
  O  O27  1  0.004  0.559  0.818  1.0
  O  O28  1  0.662  0.402  0.568  1.0
  O  O29  1  0.327  0.147  0.687  1.0
  O  O30  1  0.583  0.137  0.402  1.0
  O  O31  1  0.813  0.920  0.294  1.0
  O  O32  1  0.687  0.080  0.794  1.0
  O  O33  1  0.417  0.637  0.098  1.0
  O  O34  1  0.338  0.902  0.932  1.0
  O  O35  1  0.083  0.363  0.598  1.0
[/CIF]
.
The structure described by Cd(PO3)2 crystallizes in the orthorhombic P2_12_12_1 space group. Cd(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(6) atoms to form distorted CdO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and edges with two equivalent Cd(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second P site, P(2) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-61°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Cd(PO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.384
_cell_length_b   7.417
_cell_length_c   8.536
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.539
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.023  0.142  0.207  1.0
  Cd  Cd1  1  0.977  0.642  0.293  1.0
  Cd  Cd2  1  0.523  0.358  0.793  1.0
  Cd  Cd3  1  0.477  0.858  0.707  1.0
  P  P4  1  0.882  0.060  0.839  1.0
  P  P5  1  0.382  0.440  0.161  1.0
  P  P6  1  0.618  0.940  0.339  1.0
  P  P7  1  0.156  0.162  0.595  1.0
  P  P8  1  0.118  0.560  0.661  1.0
  P  P9  1  0.656  0.338  0.405  1.0
  P  P10  1  0.344  0.838  0.095  1.0
  P  P11  1  0.844  0.662  0.905  1.0
  O  O12  1  0.162  0.098  0.432  1.0
  O  O13  1  0.042  0.687  0.544  1.0
  O  O14  1  0.673  0.647  0.813  1.0
  O  O15  1  0.542  0.813  0.456  1.0
  O  O16  1  0.173  0.853  0.187  1.0
  O  O17  1  0.496  0.441  0.318  1.0
  O  O18  1  0.917  0.863  0.902  1.0
  O  O19  1  0.996  0.059  0.682  1.0
  O  O20  1  0.504  0.941  0.182  1.0
  O  O21  1  0.458  0.313  0.044  1.0
  O  O22  1  0.313  0.580  0.706  1.0
  O  O23  1  0.958  0.187  0.956  1.0
  O  O24  1  0.838  0.598  0.068  1.0
  O  O25  1  0.187  0.420  0.206  1.0
  O  O26  1  0.827  0.353  0.313  1.0
  O  O27  1  0.004  0.559  0.818  1.0
  O  O28  1  0.662  0.402  0.568  1.0
  O  O29  1  0.327  0.147  0.687  1.0
  O  O30  1  0.583  0.137  0.402  1.0
  O  O31  1  0.813  0.920  0.294  1.0
  O  O32  1  0.687  0.080  0.794  1.0
  O  O33  1  0.417  0.637  0.098  1.0
  O  O34  1  0.338  0.902  0.932  1.0
  O  O35  1  0.083  0.363  0.598  1.0
[/CIF]
.