The structure described by AlCl4NS2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four (chlorosulfanylamino) thiohypochlorite molecules and four AlCl4 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(5), one Cl(8), and two equivalent Cl(2) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF card [CIF]
data_AlS2NCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.797
_cell_length_b   6.412
_cell_length_c   13.388
_cell_angle_alpha   84.506
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1178.883
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.750  0.155  0.984  1.0
  Al  Al1  1  0.750  0.006  0.466  1.0
  Al  Al2  1  0.250  0.845  0.016  1.0
  Al  Al3  1  0.250  0.994  0.534  1.0
  S  S4  1  0.407  0.367  0.836  1.0
  S  S5  1  0.480  0.745  0.343  1.0
  S  S6  1  0.593  0.633  0.164  1.0
  S  S7  1  0.020  0.745  0.343  1.0
  S  S8  1  0.907  0.633  0.164  1.0
  S  S9  1  0.980  0.255  0.657  1.0
  S  S10  1  0.093  0.367  0.836  1.0
  S  S11  1  0.520  0.255  0.657  1.0
  N  N12  1  0.949  0.731  0.255  1.0
  N  N13  1  0.051  0.269  0.745  1.0
  N  N14  1  0.551  0.731  0.255  1.0
  N  N15  1  0.449  0.269  0.745  1.0
  Cl  Cl16  1  0.750  0.700  0.414  1.0
  Cl  Cl17  1  0.379  0.946  0.088  1.0
  Cl  Cl18  1  0.881  0.170  0.415  1.0
  Cl  Cl19  1  0.250  0.029  0.371  1.0
  Cl  Cl20  1  0.750  0.024  0.140  1.0
  Cl  Cl21  1  0.619  0.170  0.415  1.0
  Cl  Cl22  1  0.750  0.971  0.629  1.0
  Cl  Cl23  1  0.016  0.625  0.864  1.0
  Cl  Cl24  1  0.984  0.375  0.136  1.0
  Cl  Cl25  1  0.250  0.976  0.860  1.0
  Cl  Cl26  1  0.886  0.499  0.648  1.0
  Cl  Cl27  1  0.621  0.054  0.912  1.0
  Cl  Cl28  1  0.750  0.493  0.981  1.0
  Cl  Cl29  1  0.879  0.054  0.912  1.0
  Cl  Cl30  1  0.250  0.300  0.586  1.0
  Cl  Cl31  1  0.614  0.499  0.648  1.0
  Cl  Cl32  1  0.121  0.946  0.088  1.0
  Cl  Cl33  1  0.250  0.507  0.019  1.0
  Cl  Cl34  1  0.516  0.375  0.136  1.0
  Cl  Cl35  1  0.484  0.625  0.864  1.0
  Cl  Cl36  1  0.386  0.501  0.352  1.0
  Cl  Cl37  1  0.381  0.830  0.585  1.0
  Cl  Cl38  1  0.119  0.830  0.585  1.0
  Cl  Cl39  1  0.114  0.501  0.352  1.0
[/CIF]
.
The structure described by AlCl4NS2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four (chlorosulfanylamino) thiohypochlorite molecules and four AlCl4 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(5), one Cl(8), and two equivalent Cl(2) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF card [CIF]
data_AlS2NCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.797
_cell_length_b   6.412
_cell_length_c   13.388
_cell_angle_alpha   84.506
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1178.883
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.750  0.155  0.984  1.0
  Al  Al1  1  0.750  0.006  0.466  1.0
  Al  Al2  1  0.250  0.845  0.016  1.0
  Al  Al3  1  0.250  0.994  0.534  1.0
  S  S4  1  0.407  0.367  0.836  1.0
  S  S5  1  0.480  0.745  0.343  1.0
  S  S6  1  0.593  0.633  0.164  1.0
  S  S7  1  0.020  0.745  0.343  1.0
  S  S8  1  0.907  0.633  0.164  1.0
  S  S9  1  0.980  0.255  0.657  1.0
  S  S10  1  0.093  0.367  0.836  1.0
  S  S11  1  0.520  0.255  0.657  1.0
  N  N12  1  0.949  0.731  0.255  1.0
  N  N13  1  0.051  0.269  0.745  1.0
  N  N14  1  0.551  0.731  0.255  1.0
  N  N15  1  0.449  0.269  0.745  1.0
  Cl  Cl16  1  0.750  0.700  0.414  1.0
  Cl  Cl17  1  0.379  0.946  0.088  1.0
  Cl  Cl18  1  0.881  0.170  0.415  1.0
  Cl  Cl19  1  0.250  0.029  0.371  1.0
  Cl  Cl20  1  0.750  0.024  0.140  1.0
  Cl  Cl21  1  0.619  0.170  0.415  1.0
  Cl  Cl22  1  0.750  0.971  0.629  1.0
  Cl  Cl23  1  0.016  0.625  0.864  1.0
  Cl  Cl24  1  0.984  0.375  0.136  1.0
  Cl  Cl25  1  0.250  0.976  0.860  1.0
  Cl  Cl26  1  0.886  0.499  0.648  1.0
  Cl  Cl27  1  0.621  0.054  0.912  1.0
  Cl  Cl28  1  0.750  0.493  0.981  1.0
  Cl  Cl29  1  0.879  0.054  0.912  1.0
  Cl  Cl30  1  0.250  0.300  0.586  1.0
  Cl  Cl31  1  0.614  0.499  0.648  1.0
  Cl  Cl32  1  0.121  0.946  0.088  1.0
  Cl  Cl33  1  0.250  0.507  0.019  1.0
  Cl  Cl34  1  0.516  0.375  0.136  1.0
  Cl  Cl35  1  0.484  0.625  0.864  1.0
  Cl  Cl36  1  0.386  0.501  0.352  1.0
  Cl  Cl37  1  0.381  0.830  0.585  1.0
  Cl  Cl38  1  0.119  0.830  0.585  1.0
  Cl  Cl39  1  0.114  0.501  0.352  1.0
[/CIF]
.