The material described by W3P4O14 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(6), one O(7), and two equivalent O(3) atoms to form WO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, and  an edgeedge with one W(2)O6 octahedra. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent W(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent W(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 34-63°. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-67°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one W(2) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(2) atom. is represented by the CIF card [CIF]
data_P4W3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.140
_cell_length_b   7.639
_cell_length_c   9.753
_cell_angle_alpha   71.107
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   573.789
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.699  0.874  0.303  1.0
  P  P1  1  0.064  0.587  0.795  1.0
  P  P2  1  0.436  0.587  0.295  1.0
  P  P3  1  0.564  0.413  0.705  1.0
  P  P4  1  0.936  0.413  0.205  1.0
  P  P5  1  0.301  0.126  0.697  1.0
  P  P6  1  0.801  0.874  0.803  1.0
  P  P7  1  0.199  0.126  0.197  1.0
  W  W8  1  0.630  0.195  0.471  1.0
  W  W9  1  0.870  0.195  0.971  1.0
  W  W10  1  0.130  0.805  0.029  1.0
  W  W11  1  0.500  0.000  0.000  1.0
  W  W12  1  0.370  0.805  0.529  1.0
  W  W13  1  0.000  0.000  0.500  1.0
  O  O14  1  0.648  0.316  0.851  1.0
  O  O15  1  0.710  0.001  0.142  1.0
  O  O16  1  0.073  0.042  0.112  1.0
  O  O17  1  0.363  0.154  0.122  1.0
  O  O18  1  0.790  0.001  0.642  1.0
  O  O19  1  0.427  0.042  0.612  1.0
  O  O20  1  0.290  0.999  0.858  1.0
  O  O21  1  0.927  0.958  0.888  1.0
  O  O22  1  0.637  0.846  0.878  1.0
  O  O23  1  0.210  0.999  0.358  1.0
  O  O24  1  0.573  0.958  0.388  1.0
  O  O25  1  0.883  0.690  0.794  1.0
  O  O26  1  0.161  0.610  0.921  1.0
  O  O27  1  0.863  0.846  0.378  1.0
  O  O28  1  0.148  0.684  0.649  1.0
  O  O29  1  0.519  0.612  0.686  1.0
  O  O30  1  0.617  0.690  0.294  1.0
  O  O31  1  0.839  0.390  0.079  1.0
  O  O32  1  0.352  0.684  0.149  1.0
  O  O33  1  0.019  0.388  0.814  1.0
  O  O34  1  0.981  0.612  0.186  1.0
  O  O35  1  0.117  0.310  0.206  1.0
  O  O36  1  0.661  0.390  0.579  1.0
  O  O37  1  0.383  0.310  0.706  1.0
  O  O38  1  0.481  0.388  0.314  1.0
  O  O39  1  0.852  0.316  0.351  1.0
  O  O40  1  0.137  0.154  0.622  1.0
  O  O41  1  0.339  0.610  0.421  1.0
[/CIF]
.
The material described by W3P4O14 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(6), one O(7), and two equivalent O(3) atoms to form WO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, and  an edgeedge with one W(2)O6 octahedra. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent W(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent W(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 34-63°. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-67°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one W(2) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(2) atom. is represented by the CIF card [CIF]
data_P4W3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.140
_cell_length_b   7.639
_cell_length_c   9.753
_cell_angle_alpha   71.107
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   573.789
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.699  0.874  0.303  1.0
  P  P1  1  0.064  0.587  0.795  1.0
  P  P2  1  0.436  0.587  0.295  1.0
  P  P3  1  0.564  0.413  0.705  1.0
  P  P4  1  0.936  0.413  0.205  1.0
  P  P5  1  0.301  0.126  0.697  1.0
  P  P6  1  0.801  0.874  0.803  1.0
  P  P7  1  0.199  0.126  0.197  1.0
  W  W8  1  0.630  0.195  0.471  1.0
  W  W9  1  0.870  0.195  0.971  1.0
  W  W10  1  0.130  0.805  0.029  1.0
  W  W11  1  0.500  0.000  0.000  1.0
  W  W12  1  0.370  0.805  0.529  1.0
  W  W13  1  0.000  0.000  0.500  1.0
  O  O14  1  0.648  0.316  0.851  1.0
  O  O15  1  0.710  0.001  0.142  1.0
  O  O16  1  0.073  0.042  0.112  1.0
  O  O17  1  0.363  0.154  0.122  1.0
  O  O18  1  0.790  0.001  0.642  1.0
  O  O19  1  0.427  0.042  0.612  1.0
  O  O20  1  0.290  0.999  0.858  1.0
  O  O21  1  0.927  0.958  0.888  1.0
  O  O22  1  0.637  0.846  0.878  1.0
  O  O23  1  0.210  0.999  0.358  1.0
  O  O24  1  0.573  0.958  0.388  1.0
  O  O25  1  0.883  0.690  0.794  1.0
  O  O26  1  0.161  0.610  0.921  1.0
  O  O27  1  0.863  0.846  0.378  1.0
  O  O28  1  0.148  0.684  0.649  1.0
  O  O29  1  0.519  0.612  0.686  1.0
  O  O30  1  0.617  0.690  0.294  1.0
  O  O31  1  0.839  0.390  0.079  1.0
  O  O32  1  0.352  0.684  0.149  1.0
  O  O33  1  0.019  0.388  0.814  1.0
  O  O34  1  0.981  0.612  0.186  1.0
  O  O35  1  0.117  0.310  0.206  1.0
  O  O36  1  0.661  0.390  0.579  1.0
  O  O37  1  0.383  0.310  0.706  1.0
  O  O38  1  0.481  0.388  0.314  1.0
  O  O39  1  0.852  0.316  0.351  1.0
  O  O40  1  0.137  0.154  0.622  1.0
  O  O41  1  0.339  0.610  0.421  1.0
[/CIF]
.