The compound described by Ba4La6Mn(Co3O10)3 is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4/mmm space group. Ba(1) is bonded to two equivalent O(2), two equivalent O(7), four equivalent O(1), and four equivalent O(5) atoms to form BaO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with five equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Mn(1)O6 octahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Co(2)O6 octahedra, and faces with two equivalent Co(4)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to two equivalent O(3), two equivalent O(9), and eight equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra, faces with four equivalent Co(3)O6 octahedra, and faces with four equivalent Co(5)O6 octahedra. In the second La site, La(2) is bonded to two equivalent O(4), two equivalent O(8), four equivalent O(1), and four equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Co(3)O6 octahedra, faces with two equivalent Co(4)O6 octahedra, and faces with two equivalent Co(5)O6 octahedra. Mn(1) is bonded to two equivalent O(2) and four equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Co(4)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(7), one O(8), and four equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the second Co site, Co(2) is bonded to two equivalent O(7) and four equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third Co site, Co(3) is bonded to one O(8), one O(9), and four equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(5)O6 octahedra, faces with four equivalent La(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fourth Co site, Co(4) is bonded to one O(2), one O(4), and four equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the fifth Co site, Co(5) is bonded to one O(3), one O(4), and four equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with four equivalent La(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are nine inequivalent O sites. In the first O site, O(7) is bonded to four equivalent Ba(1), one Co(1), and one Co(2) atom to form distorted OBa4Co2 octahedra that share corners with five equivalent O(7)Ba4Co2 octahedra, corners with eight equivalent O(5)Ba4MnCo octahedra, edges with four equivalent O(2)Ba4MnCo octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-57°. In the second O site, O(8) is bonded in a distorted linear geometry to four equivalent La(2), one Co(1), and one Co(3) atom. In the third O site, O(9) is bonded in a distorted linear geometry to four equivalent La(1) and two equivalent Co(3) atoms. In the fourth O site, O(1) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent La(2), one Co(1), and one Co(4) atom. In the fifth O site, O(2) is bonded to four equivalent Ba(1), one Mn(1), and one Co(4) atom to form distorted OBa4MnCo octahedra that share corners with five equivalent O(2)Ba4MnCo octahedra, corners with eight equivalent O(5)Ba4MnCo octahedra, edges with four equivalent O(7)Ba4Co2 octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the sixth O site, O(3) is bonded in a distorted linear geometry to four equivalent La(1) and two equivalent Co(5) atoms. In the seventh O site, O(4) is bonded in a distorted linear geometry to four equivalent La(2), one Co(4), and one Co(5) atom. In the eighth O site, O(5) is bonded to four equivalent Ba(1), one Mn(1), and one Co(2) atom to form distorted OBa4MnCo octahedra that share corners with two equivalent O(5)Ba4MnCo octahedra, corners with four equivalent O(7)Ba4Co2 octahedra, corners with four equivalent O(2)Ba4MnCo octahedra, edges with two equivalent O(5)Ba4MnCo octahedra, faces with two equivalent O(7)Ba4Co2 octahedra, faces with two equivalent O(2)Ba4MnCo octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the ninth O site, O(6) is bonded to two equivalent La(1), two equivalent La(2), one Co(3), and one Co(5) atom to form a mixture of distorted edge, face, and corner-sharing OLa4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. is represented by the CIF card [CIF]
data_Ba4La6Mn(Co3O10)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.597
_cell_length_b   5.597
_cell_length_c   19.317
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   605.153
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.500  0.000  0.400  1.0
  Ba  Ba1  1  0.000  0.500  0.400  1.0
  Ba  Ba2  1  0.000  0.500  0.600  1.0
  Ba  Ba3  1  0.500  0.000  0.600  1.0
  La  La4  1  0.000  0.500  0.000  1.0
  La  La5  1  0.500  0.000  0.000  1.0
  La  La6  1  0.000  0.500  0.801  1.0
  La  La7  1  0.000  0.500  0.199  1.0
  La  La8  1  0.500  0.000  0.801  1.0
  La  La9  1  0.500  0.000  0.199  1.0
  Mn  Mn10  1  0.500  0.500  0.500  1.0
  Co  Co11  1  0.000  0.000  0.700  1.0
  Co  Co12  1  0.000  0.000  0.500  1.0
  Co  Co13  1  0.000  0.000  0.099  1.0
  Co  Co14  1  0.000  0.000  0.901  1.0
  Co  Co15  1  0.000  0.000  0.300  1.0
  Co  Co16  1  0.500  0.500  0.706  1.0
  Co  Co17  1  0.500  0.500  0.099  1.0
  Co  Co18  1  0.500  0.500  0.901  1.0
  Co  Co19  1  0.500  0.500  0.294  1.0
  O  O20  1  0.742  0.258  0.284  1.0
  O  O21  1  0.500  0.500  0.603  1.0
  O  O22  1  0.500  0.500  0.397  1.0
  O  O23  1  0.500  0.500  0.000  1.0
  O  O24  1  0.500  0.500  0.809  1.0
  O  O25  1  0.500  0.500  0.191  1.0
  O  O26  1  0.751  0.751  0.500  1.0
  O  O27  1  0.742  0.742  0.716  1.0
  O  O28  1  0.750  0.750  0.905  1.0
  O  O29  1  0.750  0.750  0.095  1.0
  O  O30  1  0.742  0.742  0.284  1.0
  O  O31  1  0.742  0.258  0.716  1.0
  O  O32  1  0.258  0.742  0.284  1.0
  O  O33  1  0.000  0.000  0.609  1.0
  O  O34  1  0.751  0.249  0.500  1.0
  O  O35  1  0.750  0.250  0.095  1.0
  O  O36  1  0.000  0.000  0.391  1.0
  O  O37  1  0.750  0.250  0.905  1.0
  O  O38  1  0.000  0.000  0.805  1.0
  O  O39  1  0.000  0.000  0.000  1.0
  O  O40  1  0.000  0.000  0.195  1.0
  O  O41  1  0.258  0.258  0.716  1.0
  O  O42  1  0.249  0.249  0.500  1.0
  O  O43  1  0.250  0.250  0.095  1.0
  O  O44  1  0.250  0.250  0.905  1.0
  O  O45  1  0.258  0.258  0.284  1.0
  O  O46  1  0.249  0.751  0.500  1.0
  O  O47  1  0.258  0.742  0.716  1.0
  O  O48  1  0.250  0.750  0.905  1.0
  O  O49  1  0.250  0.750  0.095  1.0
[/CIF]
.
The compound described by Ba4La6Mn(Co3O10)3 is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4/mmm space group. Ba(1) is bonded to two equivalent O(2), two equivalent O(7), four equivalent O(1), and four equivalent O(5) atoms to form BaO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with five equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Mn(1)O6 octahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Co(2)O6 octahedra, and faces with two equivalent Co(4)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to two equivalent O(3), two equivalent O(9), and eight equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra, faces with four equivalent Co(3)O6 octahedra, and faces with four equivalent Co(5)O6 octahedra. In the second La site, La(2) is bonded to two equivalent O(4), two equivalent O(8), four equivalent O(1), and four equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Co(3)O6 octahedra, faces with two equivalent Co(4)O6 octahedra, and faces with two equivalent Co(5)O6 octahedra. Mn(1) is bonded to two equivalent O(2) and four equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Co(4)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(7), one O(8), and four equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the second Co site, Co(2) is bonded to two equivalent O(7) and four equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third Co site, Co(3) is bonded to one O(8), one O(9), and four equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(5)O6 octahedra, faces with four equivalent La(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fourth Co site, Co(4) is bonded to one O(2), one O(4), and four equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the fifth Co site, Co(5) is bonded to one O(3), one O(4), and four equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with four equivalent La(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are nine inequivalent O sites. In the first O site, O(7) is bonded to four equivalent Ba(1), one Co(1), and one Co(2) atom to form distorted OBa4Co2 octahedra that share corners with five equivalent O(7)Ba4Co2 octahedra, corners with eight equivalent O(5)Ba4MnCo octahedra, edges with four equivalent O(2)Ba4MnCo octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-57°. In the second O site, O(8) is bonded in a distorted linear geometry to four equivalent La(2), one Co(1), and one Co(3) atom. In the third O site, O(9) is bonded in a distorted linear geometry to four equivalent La(1) and two equivalent Co(3) atoms. In the fourth O site, O(1) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent La(2), one Co(1), and one Co(4) atom. In the fifth O site, O(2) is bonded to four equivalent Ba(1), one Mn(1), and one Co(4) atom to form distorted OBa4MnCo octahedra that share corners with five equivalent O(2)Ba4MnCo octahedra, corners with eight equivalent O(5)Ba4MnCo octahedra, edges with four equivalent O(7)Ba4Co2 octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the sixth O site, O(3) is bonded in a distorted linear geometry to four equivalent La(1) and two equivalent Co(5) atoms. In the seventh O site, O(4) is bonded in a distorted linear geometry to four equivalent La(2), one Co(4), and one Co(5) atom. In the eighth O site, O(5) is bonded to four equivalent Ba(1), one Mn(1), and one Co(2) atom to form distorted OBa4MnCo octahedra that share corners with two equivalent O(5)Ba4MnCo octahedra, corners with four equivalent O(7)Ba4Co2 octahedra, corners with four equivalent O(2)Ba4MnCo octahedra, edges with two equivalent O(5)Ba4MnCo octahedra, faces with two equivalent O(7)Ba4Co2 octahedra, faces with two equivalent O(2)Ba4MnCo octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the ninth O site, O(6) is bonded to two equivalent La(1), two equivalent La(2), one Co(3), and one Co(5) atom to form a mixture of distorted edge, face, and corner-sharing OLa4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. is represented by the CIF card [CIF]
data_Ba4La6Mn(Co3O10)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.597
_cell_length_b   5.597
_cell_length_c   19.317
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   605.153
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.500  0.000  0.400  1.0
  Ba  Ba1  1  0.000  0.500  0.400  1.0
  Ba  Ba2  1  0.000  0.500  0.600  1.0
  Ba  Ba3  1  0.500  0.000  0.600  1.0
  La  La4  1  0.000  0.500  0.000  1.0
  La  La5  1  0.500  0.000  0.000  1.0
  La  La6  1  0.000  0.500  0.801  1.0
  La  La7  1  0.000  0.500  0.199  1.0
  La  La8  1  0.500  0.000  0.801  1.0
  La  La9  1  0.500  0.000  0.199  1.0
  Mn  Mn10  1  0.500  0.500  0.500  1.0
  Co  Co11  1  0.000  0.000  0.700  1.0
  Co  Co12  1  0.000  0.000  0.500  1.0
  Co  Co13  1  0.000  0.000  0.099  1.0
  Co  Co14  1  0.000  0.000  0.901  1.0
  Co  Co15  1  0.000  0.000  0.300  1.0
  Co  Co16  1  0.500  0.500  0.706  1.0
  Co  Co17  1  0.500  0.500  0.099  1.0
  Co  Co18  1  0.500  0.500  0.901  1.0
  Co  Co19  1  0.500  0.500  0.294  1.0
  O  O20  1  0.742  0.258  0.284  1.0
  O  O21  1  0.500  0.500  0.603  1.0
  O  O22  1  0.500  0.500  0.397  1.0
  O  O23  1  0.500  0.500  0.000  1.0
  O  O24  1  0.500  0.500  0.809  1.0
  O  O25  1  0.500  0.500  0.191  1.0
  O  O26  1  0.751  0.751  0.500  1.0
  O  O27  1  0.742  0.742  0.716  1.0
  O  O28  1  0.750  0.750  0.905  1.0
  O  O29  1  0.750  0.750  0.095  1.0
  O  O30  1  0.742  0.742  0.284  1.0
  O  O31  1  0.742  0.258  0.716  1.0
  O  O32  1  0.258  0.742  0.284  1.0
  O  O33  1  0.000  0.000  0.609  1.0
  O  O34  1  0.751  0.249  0.500  1.0
  O  O35  1  0.750  0.250  0.095  1.0
  O  O36  1  0.000  0.000  0.391  1.0
  O  O37  1  0.750  0.250  0.905  1.0
  O  O38  1  0.000  0.000  0.805  1.0
  O  O39  1  0.000  0.000  0.000  1.0
  O  O40  1  0.000  0.000  0.195  1.0
  O  O41  1  0.258  0.258  0.716  1.0
  O  O42  1  0.249  0.249  0.500  1.0
  O  O43  1  0.250  0.250  0.095  1.0
  O  O44  1  0.250  0.250  0.905  1.0
  O  O45  1  0.258  0.258  0.284  1.0
  O  O46  1  0.249  0.751  0.500  1.0
  O  O47  1  0.258  0.742  0.716  1.0
  O  O48  1  0.250  0.750  0.905  1.0
  O  O49  1  0.250  0.750  0.095  1.0
[/CIF]
.