The crystal structure described by W3Ru3C2 is H-Phase-like structured and crystallizes in the trigonal P-3m1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to three equivalent W(2), six equivalent W(1), and three equivalent Ru(1) atoms to form WRu3W9 cuboctahedra that share corners with nine equivalent W(1)Ru3W9 cuboctahedra, corners with six equivalent C(1)Ru6 octahedra, edges with six equivalent W(2)W12 cuboctahedra, edges with nine equivalent W(1)Ru3W9 cuboctahedra, faces with six equivalent W(1)Ru3W9 cuboctahedra, faces with six equivalent W(2)W12 cuboctahedra, and  a faceface with one C(1)Ru6 octahedra. The corner-sharing octahedral tilt angles are 44°. In the second W site, W(2) is bonded to six equivalent W(1) and six equivalent W(2) atoms to form WW12 cuboctahedra that share corners with six equivalent W(2)W12 cuboctahedra, edges with six equivalent W(2)W12 cuboctahedra, edges with twelve equivalent W(1)Ru3W9 cuboctahedra, faces with six equivalent W(2)W12 cuboctahedra, and faces with twelve equivalent W(1)Ru3W9 cuboctahedra. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 3-coordinate geometry to three equivalent W(1) and three equivalent C(1) atoms. In the second Ru site, Ru(2) is bonded to six equivalent C(1) atoms to form edge-sharing RuC6 octahedra. C(1) is bonded to three equivalent Ru(1) and three equivalent Ru(2) atoms to form CRu6 octahedra that share corners with six equivalent W(1)Ru3W9 cuboctahedra, corners with three equivalent C(1)Ru6 octahedra, edges with nine equivalent C(1)Ru6 octahedra, and  a faceface with one W(1)Ru3W9 cuboctahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_Ru3W3C2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.862
_cell_length_b   2.862
_cell_length_c   14.543
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   103.161
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.667  0.333  0.184  1.0
  Ru  Ru1  1  0.000  0.000  0.000  1.0
  Ru  Ru2  1  0.333  0.667  0.816  1.0
  W  W3  1  0.667  0.333  0.664  1.0
  W  W4  1  0.000  0.000  0.500  1.0
  W  W5  1  0.333  0.667  0.336  1.0
  C  C6  1  0.333  0.667  0.099  1.0
  C  C7  1  0.667  0.333  0.901  1.0
[/CIF]
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The crystal structure described by W3Ru3C2 is H-Phase-like structured and crystallizes in the trigonal P-3m1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to three equivalent W(2), six equivalent W(1), and three equivalent Ru(1) atoms to form WRu3W9 cuboctahedra that share corners with nine equivalent W(1)Ru3W9 cuboctahedra, corners with six equivalent C(1)Ru6 octahedra, edges with six equivalent W(2)W12 cuboctahedra, edges with nine equivalent W(1)Ru3W9 cuboctahedra, faces with six equivalent W(1)Ru3W9 cuboctahedra, faces with six equivalent W(2)W12 cuboctahedra, and  a faceface with one C(1)Ru6 octahedra. The corner-sharing octahedral tilt angles are 44°. In the second W site, W(2) is bonded to six equivalent W(1) and six equivalent W(2) atoms to form WW12 cuboctahedra that share corners with six equivalent W(2)W12 cuboctahedra, edges with six equivalent W(2)W12 cuboctahedra, edges with twelve equivalent W(1)Ru3W9 cuboctahedra, faces with six equivalent W(2)W12 cuboctahedra, and faces with twelve equivalent W(1)Ru3W9 cuboctahedra. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 3-coordinate geometry to three equivalent W(1) and three equivalent C(1) atoms. In the second Ru site, Ru(2) is bonded to six equivalent C(1) atoms to form edge-sharing RuC6 octahedra. C(1) is bonded to three equivalent Ru(1) and three equivalent Ru(2) atoms to form CRu6 octahedra that share corners with six equivalent W(1)Ru3W9 cuboctahedra, corners with three equivalent C(1)Ru6 octahedra, edges with nine equivalent C(1)Ru6 octahedra, and  a faceface with one W(1)Ru3W9 cuboctahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_Ru3W3C2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.862
_cell_length_b   2.862
_cell_length_c   14.543
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   103.161
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.667  0.333  0.184  1.0
  Ru  Ru1  1  0.000  0.000  0.000  1.0
  Ru  Ru2  1  0.333  0.667  0.816  1.0
  W  W3  1  0.667  0.333  0.664  1.0
  W  W4  1  0.000  0.000  0.500  1.0
  W  W5  1  0.333  0.667  0.336  1.0
  C  C6  1  0.333  0.667  0.099  1.0
  C  C7  1  0.667  0.333  0.901  1.0
[/CIF]
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