The material structure described by LiVMn(PO4)3 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(10), one O(2), one O(5), and one O(6) atom. V(1) is bonded to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. Mn(1) is bonded to one O(11), one O(12), one O(2), one O(7), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-49°. In the second P site, P(2) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-45°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-48°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. is represented by the CIF file [CIF]
data_LiMnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.272
_cell_length_b   8.288
_cell_length_c   8.853
_cell_angle_alpha   89.631
_cell_angle_beta   116.704
_cell_angle_gamma   119.047
_symmetry_Int_Tables_number   1
_cell_volume   456.270
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.947  0.260  0.876  1.0
  Li  Li1  1  0.053  0.740  0.124  1.0
  Mn  Mn2  1  0.289  0.153  0.434  1.0
  Mn  Mn3  1  0.711  0.847  0.566  1.0
  V  V4  1  0.309  0.657  0.948  1.0
  V  V5  1  0.691  0.343  0.052  1.0
  P  P6  1  0.220  0.260  0.752  1.0
  P  P7  1  0.502  0.971  0.746  1.0
  P  P8  1  0.794  0.545  0.753  1.0
  P  P9  1  0.206  0.455  0.247  1.0
  P  P10  1  0.498  0.029  0.254  1.0
  P  P11  1  0.780  0.740  0.248  1.0
  O  O12  1  0.397  0.232  0.895  1.0
  O  O13  1  0.012  0.137  0.749  1.0
  O  O14  1  0.299  0.479  0.813  1.0
  O  O15  1  0.361  0.835  0.822  1.0
  O  O16  1  0.682  0.170  0.890  1.0
  O  O17  1  0.755  0.528  0.913  1.0
  O  O18  1  0.201  0.227  0.575  1.0
  O  O19  1  0.622  0.889  0.725  1.0
  O  O20  1  0.352  0.988  0.576  1.0
  O  O21  1  0.003  0.536  0.818  1.0
  O  O22  1  0.857  0.748  0.738  1.0
  O  O23  1  0.613  0.385  0.589  1.0
  O  O24  1  0.387  0.615  0.411  1.0
  O  O25  1  0.143  0.252  0.262  1.0
  O  O26  1  0.997  0.464  0.182  1.0
  O  O27  1  0.648  0.012  0.424  1.0
  O  O28  1  0.378  0.111  0.275  1.0
  O  O29  1  0.799  0.773  0.425  1.0
  O  O30  1  0.245  0.472  0.087  1.0
  O  O31  1  0.318  0.830  0.110  1.0
  O  O32  1  0.639  0.165  0.178  1.0
  O  O33  1  0.701  0.521  0.187  1.0
  O  O34  1  0.988  0.863  0.251  1.0
  O  O35  1  0.603  0.768  0.105  1.0
[/CIF]
.
The material structure described by LiVMn(PO4)3 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(10), one O(2), one O(5), and one O(6) atom. V(1) is bonded to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. Mn(1) is bonded to one O(11), one O(12), one O(2), one O(7), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-49°. In the second P site, P(2) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-45°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-48°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. is represented by the CIF file [CIF]
data_LiMnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.272
_cell_length_b   8.288
_cell_length_c   8.853
_cell_angle_alpha   89.631
_cell_angle_beta   116.704
_cell_angle_gamma   119.047
_symmetry_Int_Tables_number   1
_cell_volume   456.270
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.947  0.260  0.876  1.0
  Li  Li1  1  0.053  0.740  0.124  1.0
  Mn  Mn2  1  0.289  0.153  0.434  1.0
  Mn  Mn3  1  0.711  0.847  0.566  1.0
  V  V4  1  0.309  0.657  0.948  1.0
  V  V5  1  0.691  0.343  0.052  1.0
  P  P6  1  0.220  0.260  0.752  1.0
  P  P7  1  0.502  0.971  0.746  1.0
  P  P8  1  0.794  0.545  0.753  1.0
  P  P9  1  0.206  0.455  0.247  1.0
  P  P10  1  0.498  0.029  0.254  1.0
  P  P11  1  0.780  0.740  0.248  1.0
  O  O12  1  0.397  0.232  0.895  1.0
  O  O13  1  0.012  0.137  0.749  1.0
  O  O14  1  0.299  0.479  0.813  1.0
  O  O15  1  0.361  0.835  0.822  1.0
  O  O16  1  0.682  0.170  0.890  1.0
  O  O17  1  0.755  0.528  0.913  1.0
  O  O18  1  0.201  0.227  0.575  1.0
  O  O19  1  0.622  0.889  0.725  1.0
  O  O20  1  0.352  0.988  0.576  1.0
  O  O21  1  0.003  0.536  0.818  1.0
  O  O22  1  0.857  0.748  0.738  1.0
  O  O23  1  0.613  0.385  0.589  1.0
  O  O24  1  0.387  0.615  0.411  1.0
  O  O25  1  0.143  0.252  0.262  1.0
  O  O26  1  0.997  0.464  0.182  1.0
  O  O27  1  0.648  0.012  0.424  1.0
  O  O28  1  0.378  0.111  0.275  1.0
  O  O29  1  0.799  0.773  0.425  1.0
  O  O30  1  0.245  0.472  0.087  1.0
  O  O31  1  0.318  0.830  0.110  1.0
  O  O32  1  0.639  0.165  0.178  1.0
  O  O33  1  0.701  0.521  0.187  1.0
  O  O34  1  0.988  0.863  0.251  1.0
  O  O35  1  0.603  0.768  0.105  1.0
[/CIF]
.