The structure described by TlGaCl4 is Iron carbide-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four GaCl4 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF card [CIF]
data_TlGaCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.063
_cell_length_b   9.449
_cell_length_c   10.720
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   715.414
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.750  0.290  0.195  1.0
  Tl  Tl1  1  0.750  0.210  0.695  1.0
  Tl  Tl2  1  0.250  0.790  0.305  1.0
  Tl  Tl3  1  0.250  0.710  0.805  1.0
  Ga  Ga4  1  0.750  0.814  0.062  1.0
  Ga  Ga5  1  0.750  0.686  0.562  1.0
  Ga  Ga6  1  0.250  0.314  0.438  1.0
  Ga  Ga7  1  0.250  0.186  0.938  1.0
  Cl  Cl8  1  1.000  0.677  0.066  1.0
  Cl  Cl9  1  0.250  0.061  0.108  1.0
  Cl  Cl10  1  0.000  0.177  0.434  1.0
  Cl  Cl11  1  0.750  0.561  0.392  1.0
  Cl  Cl12  1  0.750  0.943  0.231  1.0
  Cl  Cl13  1  0.500  0.823  0.566  1.0
  Cl  Cl14  1  0.500  0.323  0.934  1.0
  Cl  Cl15  1  0.750  0.557  0.731  1.0
  Cl  Cl16  1  0.750  0.939  0.892  1.0
  Cl  Cl17  1  1.000  0.823  0.566  1.0
  Cl  Cl18  1  0.500  0.177  0.434  1.0
  Cl  Cl19  1  0.250  0.439  0.608  1.0
  Cl  Cl20  1  0.000  0.323  0.934  1.0
  Cl  Cl21  1  0.250  0.443  0.269  1.0
  Cl  Cl22  1  0.250  0.057  0.769  1.0
  Cl  Cl23  1  0.500  0.677  0.066  1.0
[/CIF]
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The structure described by TlGaCl4 is Iron carbide-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four GaCl4 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF card [CIF]
data_TlGaCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.063
_cell_length_b   9.449
_cell_length_c   10.720
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   715.414
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.750  0.290  0.195  1.0
  Tl  Tl1  1  0.750  0.210  0.695  1.0
  Tl  Tl2  1  0.250  0.790  0.305  1.0
  Tl  Tl3  1  0.250  0.710  0.805  1.0
  Ga  Ga4  1  0.750  0.814  0.062  1.0
  Ga  Ga5  1  0.750  0.686  0.562  1.0
  Ga  Ga6  1  0.250  0.314  0.438  1.0
  Ga  Ga7  1  0.250  0.186  0.938  1.0
  Cl  Cl8  1  1.000  0.677  0.066  1.0
  Cl  Cl9  1  0.250  0.061  0.108  1.0
  Cl  Cl10  1  0.000  0.177  0.434  1.0
  Cl  Cl11  1  0.750  0.561  0.392  1.0
  Cl  Cl12  1  0.750  0.943  0.231  1.0
  Cl  Cl13  1  0.500  0.823  0.566  1.0
  Cl  Cl14  1  0.500  0.323  0.934  1.0
  Cl  Cl15  1  0.750  0.557  0.731  1.0
  Cl  Cl16  1  0.750  0.939  0.892  1.0
  Cl  Cl17  1  1.000  0.823  0.566  1.0
  Cl  Cl18  1  0.500  0.177  0.434  1.0
  Cl  Cl19  1  0.250  0.439  0.608  1.0
  Cl  Cl20  1  0.000  0.323  0.934  1.0
  Cl  Cl21  1  0.250  0.443  0.269  1.0
  Cl  Cl22  1  0.250  0.057  0.769  1.0
  Cl  Cl23  1  0.500  0.677  0.066  1.0
[/CIF]
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