The structure described by (PbGeO3)6O2 crystallizes in the trigonal R-3 space group. The structure consists of three hydrogen peroxide molecules inside a PbGeO3 framework. In the PbGeO3 framework, Pb(1) is bonded to two equivalent O(2) and three equivalent O(3) atoms to form distorted PbO5 square pyramids that share corners with two equivalent Pb(1)O5 square pyramids, corners with five equivalent Ge(1)O4 tetrahedra, and edges with three equivalent Pb(1)O5 square pyramids. Ge(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form GeO4 tetrahedra that share corners with five equivalent Pb(1)O5 square pyramids and corners with two equivalent Ge(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Pb(1) and one Ge(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Pb(1) and one Ge(1) atom. is represented by the CIF file [CIF]
data_Ge3Pb3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.498
_cell_length_b   9.498
_cell_length_c   9.498
_cell_angle_alpha   113.491
_cell_angle_beta   113.491
_cell_angle_gamma   113.491
_symmetry_Int_Tables_number   1
_cell_volume   539.606
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.846  0.242  0.978  1.0
  Ge  Ge1  1  0.978  0.846  0.242  1.0
  Ge  Ge2  1  0.242  0.978  0.846  1.0
  Ge  Ge3  1  0.154  0.758  0.022  1.0
  Ge  Ge4  1  0.022  0.154  0.758  1.0
  Ge  Ge5  1  0.758  0.022  0.154  1.0
  Pb  Pb6  1  0.489  0.328  0.793  1.0
  Pb  Pb7  1  0.793  0.489  0.328  1.0
  Pb  Pb8  1  0.328  0.793  0.489  1.0
  Pb  Pb9  1  0.511  0.672  0.207  1.0
  Pb  Pb10  1  0.207  0.511  0.672  1.0
  Pb  Pb11  1  0.672  0.207  0.511  1.0
  O  O12  1  0.721  0.022  0.953  1.0
  O  O13  1  0.953  0.721  0.022  1.0
  O  O14  1  0.022  0.953  0.721  1.0
  O  O15  1  0.279  0.978  0.047  1.0
  O  O16  1  0.047  0.279  0.978  1.0
  O  O17  1  0.978  0.047  0.279  1.0
  O  O18  1  0.963  0.468  0.212  1.0
  O  O19  1  0.212  0.963  0.468  1.0
  O  O20  1  0.468  0.212  0.963  1.0
  O  O21  1  0.037  0.532  0.788  1.0
  O  O22  1  0.788  0.037  0.532  1.0
  O  O23  1  0.532  0.788  0.037  1.0
  O  O24  1  0.651  0.179  0.760  1.0
  O  O25  1  0.760  0.651  0.179  1.0
  O  O26  1  0.179  0.760  0.651  1.0
  O  O27  1  0.349  0.821  0.240  1.0
  O  O28  1  0.240  0.349  0.821  1.0
  O  O29  1  0.821  0.240  0.349  1.0
  O  O30  1  0.584  0.584  0.584  1.0
  O  O31  1  0.416  0.416  0.416  1.0
[/CIF]
.
The structure described by (PbGeO3)6O2 crystallizes in the trigonal R-3 space group. The structure consists of three hydrogen peroxide molecules inside a PbGeO3 framework. In the PbGeO3 framework, Pb(1) is bonded to two equivalent O(2) and three equivalent O(3) atoms to form distorted PbO5 square pyramids that share corners with two equivalent Pb(1)O5 square pyramids, corners with five equivalent Ge(1)O4 tetrahedra, and edges with three equivalent Pb(1)O5 square pyramids. Ge(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form GeO4 tetrahedra that share corners with five equivalent Pb(1)O5 square pyramids and corners with two equivalent Ge(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Pb(1) and one Ge(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Pb(1) and one Ge(1) atom. is represented by the CIF file [CIF]
data_Ge3Pb3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.498
_cell_length_b   9.498
_cell_length_c   9.498
_cell_angle_alpha   113.491
_cell_angle_beta   113.491
_cell_angle_gamma   113.491
_symmetry_Int_Tables_number   1
_cell_volume   539.606
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.846  0.242  0.978  1.0
  Ge  Ge1  1  0.978  0.846  0.242  1.0
  Ge  Ge2  1  0.242  0.978  0.846  1.0
  Ge  Ge3  1  0.154  0.758  0.022  1.0
  Ge  Ge4  1  0.022  0.154  0.758  1.0
  Ge  Ge5  1  0.758  0.022  0.154  1.0
  Pb  Pb6  1  0.489  0.328  0.793  1.0
  Pb  Pb7  1  0.793  0.489  0.328  1.0
  Pb  Pb8  1  0.328  0.793  0.489  1.0
  Pb  Pb9  1  0.511  0.672  0.207  1.0
  Pb  Pb10  1  0.207  0.511  0.672  1.0
  Pb  Pb11  1  0.672  0.207  0.511  1.0
  O  O12  1  0.721  0.022  0.953  1.0
  O  O13  1  0.953  0.721  0.022  1.0
  O  O14  1  0.022  0.953  0.721  1.0
  O  O15  1  0.279  0.978  0.047  1.0
  O  O16  1  0.047  0.279  0.978  1.0
  O  O17  1  0.978  0.047  0.279  1.0
  O  O18  1  0.963  0.468  0.212  1.0
  O  O19  1  0.212  0.963  0.468  1.0
  O  O20  1  0.468  0.212  0.963  1.0
  O  O21  1  0.037  0.532  0.788  1.0
  O  O22  1  0.788  0.037  0.532  1.0
  O  O23  1  0.532  0.788  0.037  1.0
  O  O24  1  0.651  0.179  0.760  1.0
  O  O25  1  0.760  0.651  0.179  1.0
  O  O26  1  0.179  0.760  0.651  1.0
  O  O27  1  0.349  0.821  0.240  1.0
  O  O28  1  0.240  0.349  0.821  1.0
  O  O29  1  0.821  0.240  0.349  1.0
  O  O30  1  0.584  0.584  0.584  1.0
  O  O31  1  0.416  0.416  0.416  1.0
[/CIF]
.