The structure described by RuNOCl5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four RuNOCl5 clusters. In each RuNOCl5 cluster, Ru(1) is bonded in an octahedral geometry to one N(2), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. N(2) is bonded in a linear geometry to one Ru(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Ru(1) atom. is represented by the CIF card [CIF]
data_RuN3Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.892
_cell_length_b   10.528
_cell_length_c   13.473
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   977.579
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.322  0.750  0.110  1.0
  Ru  Ru1  1  0.822  0.250  0.390  1.0
  Ru  Ru2  1  0.678  0.250  0.890  1.0
  Ru  Ru3  1  0.178  0.750  0.610  1.0
  N  N4  1  0.167  0.501  0.859  1.0
  N  N5  1  0.667  0.499  0.641  1.0
  N  N6  1  0.833  0.001  0.141  1.0
  N  N7  1  0.333  0.999  0.359  1.0
  N  N8  1  0.167  0.999  0.859  1.0
  N  N9  1  0.667  0.001  0.641  1.0
  N  N10  1  0.833  0.499  0.141  1.0
  N  N11  1  0.333  0.501  0.359  1.0
  N  N12  1  0.492  0.750  0.009  1.0
  N  N13  1  0.992  0.250  0.491  1.0
  N  N14  1  0.508  0.250  0.991  1.0
  N  N15  1  0.008  0.750  0.509  1.0
  Cl  Cl16  1  0.423  0.250  0.775  1.0
  Cl  Cl17  1  0.923  0.750  0.725  1.0
  Cl  Cl18  1  0.577  0.750  0.225  1.0
  Cl  Cl19  1  0.077  0.250  0.275  1.0
  Cl  Cl20  1  0.315  0.972  0.112  1.0
  Cl  Cl21  1  0.815  0.028  0.388  1.0
  Cl  Cl22  1  0.685  0.472  0.888  1.0
  Cl  Cl23  1  0.185  0.528  0.612  1.0
  Cl  Cl24  1  0.315  0.528  0.112  1.0
  Cl  Cl25  1  0.815  0.472  0.388  1.0
  Cl  Cl26  1  0.685  0.028  0.888  1.0
  Cl  Cl27  1  0.185  0.972  0.612  1.0
  Cl  Cl28  1  0.053  0.750  0.005  1.0
  Cl  Cl29  1  0.553  0.250  0.495  1.0
  Cl  Cl30  1  0.947  0.250  0.995  1.0
  Cl  Cl31  1  0.447  0.750  0.505  1.0
  Cl  Cl32  1  0.112  0.750  0.243  1.0
  Cl  Cl33  1  0.612  0.250  0.257  1.0
  Cl  Cl34  1  0.888  0.250  0.757  1.0
  Cl  Cl35  1  0.388  0.750  0.743  1.0
  O  O36  1  0.607  0.750  0.947  1.0
  O  O37  1  0.107  0.250  0.553  1.0
  O  O38  1  0.393  0.250  0.053  1.0
  O  O39  1  0.893  0.750  0.447  1.0
[/CIF]
.
The structure described by RuNOCl5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four RuNOCl5 clusters. In each RuNOCl5 cluster, Ru(1) is bonded in an octahedral geometry to one N(2), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. N(2) is bonded in a linear geometry to one Ru(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Ru(1) atom. is represented by the CIF card [CIF]
data_RuN3Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.892
_cell_length_b   10.528
_cell_length_c   13.473
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   977.579
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.322  0.750  0.110  1.0
  Ru  Ru1  1  0.822  0.250  0.390  1.0
  Ru  Ru2  1  0.678  0.250  0.890  1.0
  Ru  Ru3  1  0.178  0.750  0.610  1.0
  N  N4  1  0.167  0.501  0.859  1.0
  N  N5  1  0.667  0.499  0.641  1.0
  N  N6  1  0.833  0.001  0.141  1.0
  N  N7  1  0.333  0.999  0.359  1.0
  N  N8  1  0.167  0.999  0.859  1.0
  N  N9  1  0.667  0.001  0.641  1.0
  N  N10  1  0.833  0.499  0.141  1.0
  N  N11  1  0.333  0.501  0.359  1.0
  N  N12  1  0.492  0.750  0.009  1.0
  N  N13  1  0.992  0.250  0.491  1.0
  N  N14  1  0.508  0.250  0.991  1.0
  N  N15  1  0.008  0.750  0.509  1.0
  Cl  Cl16  1  0.423  0.250  0.775  1.0
  Cl  Cl17  1  0.923  0.750  0.725  1.0
  Cl  Cl18  1  0.577  0.750  0.225  1.0
  Cl  Cl19  1  0.077  0.250  0.275  1.0
  Cl  Cl20  1  0.315  0.972  0.112  1.0
  Cl  Cl21  1  0.815  0.028  0.388  1.0
  Cl  Cl22  1  0.685  0.472  0.888  1.0
  Cl  Cl23  1  0.185  0.528  0.612  1.0
  Cl  Cl24  1  0.315  0.528  0.112  1.0
  Cl  Cl25  1  0.815  0.472  0.388  1.0
  Cl  Cl26  1  0.685  0.028  0.888  1.0
  Cl  Cl27  1  0.185  0.972  0.612  1.0
  Cl  Cl28  1  0.053  0.750  0.005  1.0
  Cl  Cl29  1  0.553  0.250  0.495  1.0
  Cl  Cl30  1  0.947  0.250  0.995  1.0
  Cl  Cl31  1  0.447  0.750  0.505  1.0
  Cl  Cl32  1  0.112  0.750  0.243  1.0
  Cl  Cl33  1  0.612  0.250  0.257  1.0
  Cl  Cl34  1  0.888  0.250  0.757  1.0
  Cl  Cl35  1  0.388  0.750  0.743  1.0
  O  O36  1  0.607  0.750  0.947  1.0
  O  O37  1  0.107  0.250  0.553  1.0
  O  O38  1  0.393  0.250  0.053  1.0
  O  O39  1  0.893  0.750  0.447  1.0
[/CIF]
.