The material described by MnSb2O6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MnO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms. In the second O site, O(1) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.716
_cell_length_b   4.717
_cell_length_c   9.442
_cell_angle_alpha   90.016
_cell_angle_beta   90.000
_cell_angle_gamma   90.003
_symmetry_Int_Tables_number   1
_cell_volume   210.015
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.667  1.0
  Mn  Mn1  1  0.500  0.500  0.167  1.0
  O  O2  1  0.813  0.813  0.167  1.0
  O  O3  1  0.687  0.313  0.667  1.0
  O  O4  1  0.313  0.687  0.667  1.0
  O  O5  1  0.187  0.187  0.167  1.0
  O  O6  1  0.799  0.799  0.842  1.0
  O  O7  1  0.799  0.799  0.491  1.0
  O  O8  1  0.701  0.299  0.991  1.0
  O  O9  1  0.701  0.299  0.342  1.0
  O  O10  1  0.299  0.701  0.991  1.0
  O  O11  1  0.299  0.701  0.342  1.0
  O  O12  1  0.201  0.201  0.842  1.0
  O  O13  1  0.201  0.201  0.491  1.0
  Sb  Sb14  1  1.000  1.000  0.999  1.0
  Sb  Sb15  1  1.000  1.000  0.334  1.0
  Sb  Sb16  1  0.500  0.500  0.834  1.0
  Sb  Sb17  1  0.500  0.500  0.499  1.0
[/CIF]
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The material described by MnSb2O6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MnO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms. In the second O site, O(1) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.716
_cell_length_b   4.717
_cell_length_c   9.442
_cell_angle_alpha   90.016
_cell_angle_beta   90.000
_cell_angle_gamma   90.003
_symmetry_Int_Tables_number   1
_cell_volume   210.015
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.667  1.0
  Mn  Mn1  1  0.500  0.500  0.167  1.0
  O  O2  1  0.813  0.813  0.167  1.0
  O  O3  1  0.687  0.313  0.667  1.0
  O  O4  1  0.313  0.687  0.667  1.0
  O  O5  1  0.187  0.187  0.167  1.0
  O  O6  1  0.799  0.799  0.842  1.0
  O  O7  1  0.799  0.799  0.491  1.0
  O  O8  1  0.701  0.299  0.991  1.0
  O  O9  1  0.701  0.299  0.342  1.0
  O  O10  1  0.299  0.701  0.991  1.0
  O  O11  1  0.299  0.701  0.342  1.0
  O  O12  1  0.201  0.201  0.842  1.0
  O  O13  1  0.201  0.201  0.491  1.0
  Sb  Sb14  1  1.000  1.000  0.999  1.0
  Sb  Sb15  1  1.000  1.000  0.334  1.0
  Sb  Sb16  1  0.500  0.500  0.834  1.0
  Sb  Sb17  1  0.500  0.500  0.499  1.0
[/CIF]
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