The crystal structure described by CsRe2OsSe4Cl3 crystallizes in the monoclinic Cc space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one Se(3), one Se(4), one Se(5), one Se(6), one Se(7), and one Se(8) atom. There are four inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(1), one Se(3), one Se(4), one Se(7), and one Cl(2) atom. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(1), one Se(4), one Se(5), one Se(6), and one Cl(3) atom. In the third Re site, Re(3) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(2), one Se(5), one Se(6), one Se(8), and one Cl(4) atom. In the fourth Re site, Re(4) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(2), one Se(3), one Se(7), one Se(8), and one Cl(6) atom. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 9-coordinate geometry to one Re(1), one Re(2), one Re(3), one Re(4), one Se(1), one Se(3), one Se(5), one Se(8), and one Cl(1) atom. In the second Os site, Os(2) is bonded in a 9-coordinate geometry to one Re(1), one Re(2), one Re(3), one Re(4), one Se(2), one Se(4), one Se(6), one Se(7), and one Cl(5) atom. There are eight inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Os(1) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to one Re(3), one Re(4), and one Os(2) atom. In the third Se site, Se(3) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(4), and one Os(1) atom. In the fourth Se site, Se(4) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(2), and one Os(2) atom. In the fifth Se site, Se(5) is bonded in a 4-coordinate geometry to one Cs(2), one Re(2), one Re(3), and one Os(1) atom. In the sixth Se site, Se(6) is bonded in a 4-coordinate geometry to one Cs(2), one Re(2), one Re(3), and one Os(2) atom. In the seventh Se site, Se(7) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(4), and one Os(2) atom. In the eighth Se site, Se(8) is bonded in a 4-coordinate geometry to one Cs(2), one Re(3), one Re(4), and one Os(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Cs(1) and one Os(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(3) atom. In the fifth Cl site, Cl(5) is bonded in a distorted single-bond geometry to one Cs(1) and one Os(2) atom. In the sixth Cl site, Cl(6) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(4) atom. is represented by the CIF file [CIF]
data_CsRe2OsSe4Cl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.523
_cell_length_b   10.523
_cell_length_c   15.574
_cell_angle_alpha   89.797
_cell_angle_beta   89.797
_cell_angle_gamma   120.057
_symmetry_Int_Tables_number   1
_cell_volume   1492.731
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.999  0.999  0.500  1.0
  Cs  Cs1  1  0.999  0.999  1.000  1.0
  Cs  Cs2  1  0.334  0.667  0.250  1.0
  Cs  Cs3  1  0.667  0.334  0.750  1.0
  Re  Re4  1  0.665  0.477  0.319  1.0
  Re  Re5  1  0.522  0.188  0.319  1.0
  Re  Re6  1  0.477  0.665  0.819  1.0
  Re  Re7  1  0.188  0.522  0.819  1.0
  Re  Re8  1  0.189  0.666  0.681  1.0
  Re  Re9  1  0.478  0.812  0.681  1.0
  Re  Re10  1  0.666  0.189  0.181  1.0
  Re  Re11  1  0.812  0.478  0.181  1.0
  Os  Os12  1  0.813  0.334  0.320  1.0
  Os  Os13  1  0.334  0.813  0.820  1.0
  Os  Os14  1  0.334  0.521  0.680  1.0
  Os  Os15  1  0.521  0.334  0.180  1.0
  Se  Se16  1  0.668  0.332  0.449  1.0
  Se  Se17  1  0.332  0.668  0.949  1.0
  Se  Se18  1  0.334  0.666  0.551  1.0
  Se  Se19  1  0.666  0.334  0.051  1.0
  Se  Se20  1  0.944  0.609  0.318  1.0
  Se  Se21  1  0.387  0.331  0.315  1.0
  Se  Se22  1  0.670  0.058  0.319  1.0
  Se  Se23  1  0.331  0.387  0.815  1.0
  Se  Se24  1  0.609  0.944  0.818  1.0
  Se  Se25  1  0.058  0.670  0.819  1.0
  Se  Se26  1  0.059  0.388  0.682  1.0
  Se  Se27  1  0.610  0.666  0.681  1.0
  Se  Se28  1  0.332  0.945  0.685  1.0
  Se  Se29  1  0.666  0.610  0.181  1.0
  Se  Se30  1  0.388  0.059  0.182  1.0
  Se  Se31  1  0.945  0.332  0.185  1.0
  Cl  Cl32  1  0.005  0.338  0.407  1.0
  Cl  Cl33  1  0.662  0.664  0.405  1.0
  Cl  Cl34  1  0.335  0.995  0.407  1.0
  Cl  Cl35  1  0.664  0.662  0.905  1.0
  Cl  Cl36  1  0.338  0.005  0.907  1.0
  Cl  Cl37  1  0.995  0.335  0.907  1.0
  Cl  Cl38  1  0.997  0.662  0.595  1.0
  Cl  Cl39  1  0.340  0.335  0.592  1.0
  Cl  Cl40  1  0.667  0.004  0.594  1.0
  Cl  Cl41  1  0.335  0.340  0.092  1.0
  Cl  Cl42  1  0.662  0.997  0.095  1.0
  Cl  Cl43  1  0.004  0.667  0.094  1.0
[/CIF]
.
The crystal structure described by CsRe2OsSe4Cl3 crystallizes in the monoclinic Cc space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one Se(3), one Se(4), one Se(5), one Se(6), one Se(7), and one Se(8) atom. There are four inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(1), one Se(3), one Se(4), one Se(7), and one Cl(2) atom. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(1), one Se(4), one Se(5), one Se(6), and one Cl(3) atom. In the third Re site, Re(3) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(2), one Se(5), one Se(6), one Se(8), and one Cl(4) atom. In the fourth Re site, Re(4) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(2), one Se(3), one Se(7), one Se(8), and one Cl(6) atom. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 9-coordinate geometry to one Re(1), one Re(2), one Re(3), one Re(4), one Se(1), one Se(3), one Se(5), one Se(8), and one Cl(1) atom. In the second Os site, Os(2) is bonded in a 9-coordinate geometry to one Re(1), one Re(2), one Re(3), one Re(4), one Se(2), one Se(4), one Se(6), one Se(7), and one Cl(5) atom. There are eight inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Os(1) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to one Re(3), one Re(4), and one Os(2) atom. In the third Se site, Se(3) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(4), and one Os(1) atom. In the fourth Se site, Se(4) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(2), and one Os(2) atom. In the fifth Se site, Se(5) is bonded in a 4-coordinate geometry to one Cs(2), one Re(2), one Re(3), and one Os(1) atom. In the sixth Se site, Se(6) is bonded in a 4-coordinate geometry to one Cs(2), one Re(2), one Re(3), and one Os(2) atom. In the seventh Se site, Se(7) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(4), and one Os(2) atom. In the eighth Se site, Se(8) is bonded in a 4-coordinate geometry to one Cs(2), one Re(3), one Re(4), and one Os(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Cs(1) and one Os(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(3) atom. In the fifth Cl site, Cl(5) is bonded in a distorted single-bond geometry to one Cs(1) and one Os(2) atom. In the sixth Cl site, Cl(6) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(4) atom. is represented by the CIF file [CIF]
data_CsRe2OsSe4Cl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.523
_cell_length_b   10.523
_cell_length_c   15.574
_cell_angle_alpha   89.797
_cell_angle_beta   89.797
_cell_angle_gamma   120.057
_symmetry_Int_Tables_number   1
_cell_volume   1492.731
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.999  0.999  0.500  1.0
  Cs  Cs1  1  0.999  0.999  1.000  1.0
  Cs  Cs2  1  0.334  0.667  0.250  1.0
  Cs  Cs3  1  0.667  0.334  0.750  1.0
  Re  Re4  1  0.665  0.477  0.319  1.0
  Re  Re5  1  0.522  0.188  0.319  1.0
  Re  Re6  1  0.477  0.665  0.819  1.0
  Re  Re7  1  0.188  0.522  0.819  1.0
  Re  Re8  1  0.189  0.666  0.681  1.0
  Re  Re9  1  0.478  0.812  0.681  1.0
  Re  Re10  1  0.666  0.189  0.181  1.0
  Re  Re11  1  0.812  0.478  0.181  1.0
  Os  Os12  1  0.813  0.334  0.320  1.0
  Os  Os13  1  0.334  0.813  0.820  1.0
  Os  Os14  1  0.334  0.521  0.680  1.0
  Os  Os15  1  0.521  0.334  0.180  1.0
  Se  Se16  1  0.668  0.332  0.449  1.0
  Se  Se17  1  0.332  0.668  0.949  1.0
  Se  Se18  1  0.334  0.666  0.551  1.0
  Se  Se19  1  0.666  0.334  0.051  1.0
  Se  Se20  1  0.944  0.609  0.318  1.0
  Se  Se21  1  0.387  0.331  0.315  1.0
  Se  Se22  1  0.670  0.058  0.319  1.0
  Se  Se23  1  0.331  0.387  0.815  1.0
  Se  Se24  1  0.609  0.944  0.818  1.0
  Se  Se25  1  0.058  0.670  0.819  1.0
  Se  Se26  1  0.059  0.388  0.682  1.0
  Se  Se27  1  0.610  0.666  0.681  1.0
  Se  Se28  1  0.332  0.945  0.685  1.0
  Se  Se29  1  0.666  0.610  0.181  1.0
  Se  Se30  1  0.388  0.059  0.182  1.0
  Se  Se31  1  0.945  0.332  0.185  1.0
  Cl  Cl32  1  0.005  0.338  0.407  1.0
  Cl  Cl33  1  0.662  0.664  0.405  1.0
  Cl  Cl34  1  0.335  0.995  0.407  1.0
  Cl  Cl35  1  0.664  0.662  0.905  1.0
  Cl  Cl36  1  0.338  0.005  0.907  1.0
  Cl  Cl37  1  0.995  0.335  0.907  1.0
  Cl  Cl38  1  0.997  0.662  0.595  1.0
  Cl  Cl39  1  0.340  0.335  0.592  1.0
  Cl  Cl40  1  0.667  0.004  0.594  1.0
  Cl  Cl41  1  0.335  0.340  0.092  1.0
  Cl  Cl42  1  0.662  0.997  0.095  1.0
  Cl  Cl43  1  0.004  0.667  0.094  1.0
[/CIF]
.