The compound described by VCo2P2NO12 crystallizes in the orthorhombic Pmc2_1 space group. V(1) is bonded to one O(5), one O(6), one O(7), one O(9), and two equivalent O(8) atoms to form VO6 octahedra that share corners with four equivalent Co(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted CoO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), and two equivalent O(8) atoms to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-55°. In the second P site, P(2) is bonded to one O(7), one O(9), and two equivalent O(1) atoms to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-59°. N(1) is bonded in a bent 120 degrees geometry to two equivalent O(4) atoms. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one V(1) and one P(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one P(2) atom. In the third O site, O(2) is bonded in a trigonal planar geometry to two equivalent Co(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one N(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Co(1) atoms. In the seventh O site, O(6) is bonded in a trigonal planar geometry to one V(1) and two equivalent Co(1) atoms. In the eighth O site, O(7) is bonded in a linear geometry to one V(1) and one P(2) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF file [CIF]
data_VCo2P2NO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.283
_cell_length_b   7.492
_cell_length_c   9.934
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.598
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.722  0.779  1.0
  V  V1  1  0.000  0.278  0.279  1.0
  Co  Co2  1  0.238  0.993  0.521  1.0
  Co  Co3  1  0.762  0.993  0.521  1.0
  Co  Co4  1  0.762  0.007  0.021  1.0
  Co  Co5  1  0.238  0.007  0.021  1.0
  P  P6  1  0.500  0.829  0.769  1.0
  P  P7  1  0.500  0.171  0.269  1.0
  P  P8  1  0.000  0.337  0.585  1.0
  P  P9  1  0.000  0.663  0.085  1.0
  N  N10  1  0.500  0.644  0.421  1.0
  N  N11  1  0.500  0.356  0.921  1.0
  O  O12  1  0.205  0.227  0.604  1.0
  O  O13  1  0.795  0.227  0.604  1.0
  O  O14  1  0.795  0.773  0.104  1.0
  O  O15  1  0.205  0.773  0.104  1.0
  O  O16  1  0.500  0.940  0.637  1.0
  O  O17  1  0.500  0.060  0.137  1.0
  O  O18  1  0.500  0.949  0.895  1.0
  O  O19  1  0.500  0.051  0.395  1.0
  O  O20  1  0.323  0.706  0.437  1.0
  O  O21  1  0.677  0.706  0.437  1.0
  O  O22  1  0.677  0.294  0.937  1.0
  O  O23  1  0.323  0.294  0.937  1.0
  O  O24  1  0.000  0.922  0.870  1.0
  O  O25  1  0.000  0.078  0.370  1.0
  O  O26  1  0.000  0.872  0.600  1.0
  O  O27  1  0.000  0.128  0.100  1.0
  O  O28  1  0.000  0.501  0.676  1.0
  O  O29  1  0.000  0.499  0.176  1.0
  O  O30  1  0.302  0.708  0.766  1.0
  O  O31  1  0.698  0.708  0.766  1.0
  O  O32  1  0.698  0.292  0.266  1.0
  O  O33  1  0.302  0.292  0.266  1.0
  O  O34  1  0.000  0.413  0.435  1.0
  O  O35  1  0.000  0.587  0.935  1.0
[/CIF]
.
The compound described by VCo2P2NO12 crystallizes in the orthorhombic Pmc2_1 space group. V(1) is bonded to one O(5), one O(6), one O(7), one O(9), and two equivalent O(8) atoms to form VO6 octahedra that share corners with four equivalent Co(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted CoO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), and two equivalent O(8) atoms to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-55°. In the second P site, P(2) is bonded to one O(7), one O(9), and two equivalent O(1) atoms to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-59°. N(1) is bonded in a bent 120 degrees geometry to two equivalent O(4) atoms. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one V(1) and one P(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one P(2) atom. In the third O site, O(2) is bonded in a trigonal planar geometry to two equivalent Co(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one N(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Co(1) atoms. In the seventh O site, O(6) is bonded in a trigonal planar geometry to one V(1) and two equivalent Co(1) atoms. In the eighth O site, O(7) is bonded in a linear geometry to one V(1) and one P(2) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF file [CIF]
data_VCo2P2NO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.283
_cell_length_b   7.492
_cell_length_c   9.934
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.598
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.722  0.779  1.0
  V  V1  1  0.000  0.278  0.279  1.0
  Co  Co2  1  0.238  0.993  0.521  1.0
  Co  Co3  1  0.762  0.993  0.521  1.0
  Co  Co4  1  0.762  0.007  0.021  1.0
  Co  Co5  1  0.238  0.007  0.021  1.0
  P  P6  1  0.500  0.829  0.769  1.0
  P  P7  1  0.500  0.171  0.269  1.0
  P  P8  1  0.000  0.337  0.585  1.0
  P  P9  1  0.000  0.663  0.085  1.0
  N  N10  1  0.500  0.644  0.421  1.0
  N  N11  1  0.500  0.356  0.921  1.0
  O  O12  1  0.205  0.227  0.604  1.0
  O  O13  1  0.795  0.227  0.604  1.0
  O  O14  1  0.795  0.773  0.104  1.0
  O  O15  1  0.205  0.773  0.104  1.0
  O  O16  1  0.500  0.940  0.637  1.0
  O  O17  1  0.500  0.060  0.137  1.0
  O  O18  1  0.500  0.949  0.895  1.0
  O  O19  1  0.500  0.051  0.395  1.0
  O  O20  1  0.323  0.706  0.437  1.0
  O  O21  1  0.677  0.706  0.437  1.0
  O  O22  1  0.677  0.294  0.937  1.0
  O  O23  1  0.323  0.294  0.937  1.0
  O  O24  1  0.000  0.922  0.870  1.0
  O  O25  1  0.000  0.078  0.370  1.0
  O  O26  1  0.000  0.872  0.600  1.0
  O  O27  1  0.000  0.128  0.100  1.0
  O  O28  1  0.000  0.501  0.676  1.0
  O  O29  1  0.000  0.499  0.176  1.0
  O  O30  1  0.302  0.708  0.766  1.0
  O  O31  1  0.698  0.708  0.766  1.0
  O  O32  1  0.698  0.292  0.266  1.0
  O  O33  1  0.302  0.292  0.266  1.0
  O  O34  1  0.000  0.413  0.435  1.0
  O  O35  1  0.000  0.587  0.935  1.0
[/CIF]
.