The material described by SbCl5 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two SbCl5 clusters. Sb(1) is bonded in a trigonal bipyramidal geometry to two equivalent Cl(2) and three equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.541
_cell_length_b   7.541
_cell_length_c   8.059
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   396.908
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.667  0.333  0.750  1.0
  Sb  Sb1  1  0.333  0.667  0.250  1.0
  Cl  Cl2  1  0.843  0.687  0.750  1.0
  Cl  Cl3  1  0.157  0.843  0.250  1.0
  Cl  Cl4  1  0.333  0.667  0.957  1.0
  Cl  Cl5  1  0.667  0.333  0.457  1.0
  Cl  Cl6  1  0.667  0.333  0.043  1.0
  Cl  Cl7  1  0.333  0.667  0.543  1.0
  Cl  Cl8  1  0.157  0.313  0.250  1.0
  Cl  Cl9  1  0.843  0.157  0.750  1.0
  Cl  Cl10  1  0.313  0.157  0.750  1.0
  Cl  Cl11  1  0.687  0.843  0.250  1.0
[/CIF]
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The material described by SbCl5 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two SbCl5 clusters. Sb(1) is bonded in a trigonal bipyramidal geometry to two equivalent Cl(2) and three equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.541
_cell_length_b   7.541
_cell_length_c   8.059
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   396.908
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.667  0.333  0.750  1.0
  Sb  Sb1  1  0.333  0.667  0.250  1.0
  Cl  Cl2  1  0.843  0.687  0.750  1.0
  Cl  Cl3  1  0.157  0.843  0.250  1.0
  Cl  Cl4  1  0.333  0.667  0.957  1.0
  Cl  Cl5  1  0.667  0.333  0.457  1.0
  Cl  Cl6  1  0.667  0.333  0.043  1.0
  Cl  Cl7  1  0.333  0.667  0.543  1.0
  Cl  Cl8  1  0.157  0.313  0.250  1.0
  Cl  Cl9  1  0.843  0.157  0.750  1.0
  Cl  Cl10  1  0.313  0.157  0.750  1.0
  Cl  Cl11  1  0.687  0.843  0.250  1.0
[/CIF]
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