The material structure described by TmFe5P3 crystallizes in the orthorhombic Pnma space group. Tm(1) is bonded in a 16-coordinate geometry to one Fe(5), three equivalent Fe(2), three equivalent Fe(3), three equivalent Fe(4), two equivalent P(1), two equivalent P(2), and two equivalent P(3) atoms. There are five inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 5-coordinate geometry to one P(3), two equivalent P(1), and two equivalent P(2) atoms. In the second Fe site, Fe(2) is bonded to three equivalent Tm(1), one P(2), and three equivalent P(3) atoms to form distorted FeTm3P4 tetrahedra that share corners with three equivalent Fe(4)Tm3P4 tetrahedra, corners with four equivalent Fe(5)TmP4 tetrahedra, corners with six equivalent Fe(3)Tm3P4 tetrahedra, edges with two equivalent Fe(2)Tm3P4 tetrahedra, edges with two equivalent Fe(3)Tm3P4 tetrahedra, edges with four equivalent Fe(4)Tm3P4 tetrahedra,  a faceface with one Fe(4)Tm3P4 tetrahedra, faces with two equivalent Fe(2)Tm3P4 tetrahedra, and faces with two equivalent Fe(3)Tm3P4 tetrahedra. In the third Fe site, Fe(3) is bonded to three equivalent Tm(1), one P(1), one P(2), and two equivalent P(3) atoms to form distorted FeTm3P4 tetrahedra that share  a cornercorner with one Fe(5)TmP4 tetrahedra, corners with three equivalent Fe(4)Tm3P4 tetrahedra, corners with four equivalent Fe(3)Tm3P4 tetrahedra, corners with six equivalent Fe(2)Tm3P4 tetrahedra, edges with two equivalent Fe(2)Tm3P4 tetrahedra, edges with two equivalent Fe(3)Tm3P4 tetrahedra, edges with three equivalent Fe(5)TmP4 tetrahedra, faces with two equivalent Fe(2)Tm3P4 tetrahedra, and faces with three equivalent Fe(4)Tm3P4 tetrahedra. In the fourth Fe site, Fe(4) is bonded to three equivalent Tm(1), one P(1), one P(3), and two equivalent P(2) atoms to form distorted FeTm3P4 tetrahedra that share corners with two equivalent Fe(5)TmP4 tetrahedra, corners with three equivalent Fe(2)Tm3P4 tetrahedra, corners with three equivalent Fe(3)Tm3P4 tetrahedra, corners with four equivalent Fe(4)Tm3P4 tetrahedra, edges with two equivalent Fe(4)Tm3P4 tetrahedra, edges with four equivalent Fe(2)Tm3P4 tetrahedra,  a faceface with one Fe(2)Tm3P4 tetrahedra, faces with two equivalent Fe(5)TmP4 tetrahedra, and faces with three equivalent Fe(3)Tm3P4 tetrahedra. In the fifth Fe site, Fe(5) is bonded to one Tm(1), one P(2), and three equivalent P(1) atoms to form distorted FeTmP4 tetrahedra that share  a cornercorner with one Fe(3)Tm3P4 tetrahedra, corners with two equivalent Fe(4)Tm3P4 tetrahedra, corners with two equivalent Fe(5)TmP4 tetrahedra, corners with four equivalent Fe(2)Tm3P4 tetrahedra, edges with two equivalent Fe(5)TmP4 tetrahedra, edges with three equivalent Fe(3)Tm3P4 tetrahedra, and faces with two equivalent Fe(4)Tm3P4 tetrahedra. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 9-coordinate geometry to two equivalent Tm(1), one Fe(1), one Fe(4), two equivalent Fe(3), and three equivalent Fe(2) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to two equivalent Tm(1), one Fe(3), one Fe(4), two equivalent Fe(1), and three equivalent Fe(5) atoms. In the third P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Tm(1), one Fe(2), one Fe(3), one Fe(5), two equivalent Fe(1), and two equivalent Fe(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TmFe5P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.631
_cell_length_b   10.224
_cell_length_c   11.742
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   435.896
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.250  0.581  0.705  1.0
  Tm  Tm1  1  0.250  0.919  0.205  1.0
  Tm  Tm2  1  0.750  0.419  0.295  1.0
  Tm  Tm3  1  0.750  0.081  0.795  1.0
  Fe  Fe4  1  0.250  0.707  0.988  1.0
  Fe  Fe5  1  0.250  0.793  0.488  1.0
  Fe  Fe6  1  0.750  0.293  0.012  1.0
  Fe  Fe7  1  0.750  0.207  0.512  1.0
  Fe  Fe8  1  0.250  0.406  0.490  1.0
  Fe  Fe9  1  0.250  0.094  0.990  1.0
  Fe  Fe10  1  0.750  0.594  0.510  1.0
  Fe  Fe11  1  0.750  0.906  0.010  1.0
  Fe  Fe12  1  0.250  0.219  0.176  1.0
  Fe  Fe13  1  0.250  0.281  0.676  1.0
  Fe  Fe14  1  0.750  0.781  0.824  1.0
  Fe  Fe15  1  0.750  0.719  0.324  1.0
  Fe  Fe16  1  0.250  0.877  0.700  1.0
  Fe  Fe17  1  0.250  0.623  0.200  1.0
  Fe  Fe18  1  0.750  0.123  0.300  1.0
  Fe  Fe19  1  0.750  0.377  0.800  1.0
  Fe  Fe20  1  0.250  0.463  0.933  1.0
  Fe  Fe21  1  0.250  0.037  0.433  1.0
  Fe  Fe22  1  0.750  0.537  0.067  1.0
  Fe  Fe23  1  0.750  0.963  0.567  1.0
  P  P24  1  0.250  0.421  0.114  1.0
  P  P25  1  0.250  0.079  0.614  1.0
  P  P26  1  0.750  0.579  0.886  1.0
  P  P27  1  0.750  0.921  0.386  1.0
  P  P28  1  0.250  0.266  0.870  1.0
  P  P29  1  0.250  0.234  0.370  1.0
  P  P30  1  0.750  0.734  0.130  1.0
  P  P31  1  0.750  0.766  0.630  1.0
  P  P32  1  0.250  0.601  0.395  1.0
  P  P33  1  0.250  0.899  0.895  1.0
  P  P34  1  0.750  0.399  0.605  1.0
  P  P35  1  0.750  0.101  0.105  1.0
[/CIF]
.
The material structure described by TmFe5P3 crystallizes in the orthorhombic Pnma space group. Tm(1) is bonded in a 16-coordinate geometry to one Fe(5), three equivalent Fe(2), three equivalent Fe(3), three equivalent Fe(4), two equivalent P(1), two equivalent P(2), and two equivalent P(3) atoms. There are five inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 5-coordinate geometry to one P(3), two equivalent P(1), and two equivalent P(2) atoms. In the second Fe site, Fe(2) is bonded to three equivalent Tm(1), one P(2), and three equivalent P(3) atoms to form distorted FeTm3P4 tetrahedra that share corners with three equivalent Fe(4)Tm3P4 tetrahedra, corners with four equivalent Fe(5)TmP4 tetrahedra, corners with six equivalent Fe(3)Tm3P4 tetrahedra, edges with two equivalent Fe(2)Tm3P4 tetrahedra, edges with two equivalent Fe(3)Tm3P4 tetrahedra, edges with four equivalent Fe(4)Tm3P4 tetrahedra,  a faceface with one Fe(4)Tm3P4 tetrahedra, faces with two equivalent Fe(2)Tm3P4 tetrahedra, and faces with two equivalent Fe(3)Tm3P4 tetrahedra. In the third Fe site, Fe(3) is bonded to three equivalent Tm(1), one P(1), one P(2), and two equivalent P(3) atoms to form distorted FeTm3P4 tetrahedra that share  a cornercorner with one Fe(5)TmP4 tetrahedra, corners with three equivalent Fe(4)Tm3P4 tetrahedra, corners with four equivalent Fe(3)Tm3P4 tetrahedra, corners with six equivalent Fe(2)Tm3P4 tetrahedra, edges with two equivalent Fe(2)Tm3P4 tetrahedra, edges with two equivalent Fe(3)Tm3P4 tetrahedra, edges with three equivalent Fe(5)TmP4 tetrahedra, faces with two equivalent Fe(2)Tm3P4 tetrahedra, and faces with three equivalent Fe(4)Tm3P4 tetrahedra. In the fourth Fe site, Fe(4) is bonded to three equivalent Tm(1), one P(1), one P(3), and two equivalent P(2) atoms to form distorted FeTm3P4 tetrahedra that share corners with two equivalent Fe(5)TmP4 tetrahedra, corners with three equivalent Fe(2)Tm3P4 tetrahedra, corners with three equivalent Fe(3)Tm3P4 tetrahedra, corners with four equivalent Fe(4)Tm3P4 tetrahedra, edges with two equivalent Fe(4)Tm3P4 tetrahedra, edges with four equivalent Fe(2)Tm3P4 tetrahedra,  a faceface with one Fe(2)Tm3P4 tetrahedra, faces with two equivalent Fe(5)TmP4 tetrahedra, and faces with three equivalent Fe(3)Tm3P4 tetrahedra. In the fifth Fe site, Fe(5) is bonded to one Tm(1), one P(2), and three equivalent P(1) atoms to form distorted FeTmP4 tetrahedra that share  a cornercorner with one Fe(3)Tm3P4 tetrahedra, corners with two equivalent Fe(4)Tm3P4 tetrahedra, corners with two equivalent Fe(5)TmP4 tetrahedra, corners with four equivalent Fe(2)Tm3P4 tetrahedra, edges with two equivalent Fe(5)TmP4 tetrahedra, edges with three equivalent Fe(3)Tm3P4 tetrahedra, and faces with two equivalent Fe(4)Tm3P4 tetrahedra. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 9-coordinate geometry to two equivalent Tm(1), one Fe(1), one Fe(4), two equivalent Fe(3), and three equivalent Fe(2) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to two equivalent Tm(1), one Fe(3), one Fe(4), two equivalent Fe(1), and three equivalent Fe(5) atoms. In the third P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Tm(1), one Fe(2), one Fe(3), one Fe(5), two equivalent Fe(1), and two equivalent Fe(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TmFe5P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.631
_cell_length_b   10.224
_cell_length_c   11.742
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   435.896
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.250  0.581  0.705  1.0
  Tm  Tm1  1  0.250  0.919  0.205  1.0
  Tm  Tm2  1  0.750  0.419  0.295  1.0
  Tm  Tm3  1  0.750  0.081  0.795  1.0
  Fe  Fe4  1  0.250  0.707  0.988  1.0
  Fe  Fe5  1  0.250  0.793  0.488  1.0
  Fe  Fe6  1  0.750  0.293  0.012  1.0
  Fe  Fe7  1  0.750  0.207  0.512  1.0
  Fe  Fe8  1  0.250  0.406  0.490  1.0
  Fe  Fe9  1  0.250  0.094  0.990  1.0
  Fe  Fe10  1  0.750  0.594  0.510  1.0
  Fe  Fe11  1  0.750  0.906  0.010  1.0
  Fe  Fe12  1  0.250  0.219  0.176  1.0
  Fe  Fe13  1  0.250  0.281  0.676  1.0
  Fe  Fe14  1  0.750  0.781  0.824  1.0
  Fe  Fe15  1  0.750  0.719  0.324  1.0
  Fe  Fe16  1  0.250  0.877  0.700  1.0
  Fe  Fe17  1  0.250  0.623  0.200  1.0
  Fe  Fe18  1  0.750  0.123  0.300  1.0
  Fe  Fe19  1  0.750  0.377  0.800  1.0
  Fe  Fe20  1  0.250  0.463  0.933  1.0
  Fe  Fe21  1  0.250  0.037  0.433  1.0
  Fe  Fe22  1  0.750  0.537  0.067  1.0
  Fe  Fe23  1  0.750  0.963  0.567  1.0
  P  P24  1  0.250  0.421  0.114  1.0
  P  P25  1  0.250  0.079  0.614  1.0
  P  P26  1  0.750  0.579  0.886  1.0
  P  P27  1  0.750  0.921  0.386  1.0
  P  P28  1  0.250  0.266  0.870  1.0
  P  P29  1  0.250  0.234  0.370  1.0
  P  P30  1  0.750  0.734  0.130  1.0
  P  P31  1  0.750  0.766  0.630  1.0
  P  P32  1  0.250  0.601  0.395  1.0
  P  P33  1  0.250  0.899  0.895  1.0
  P  P34  1  0.750  0.399  0.605  1.0
  P  P35  1  0.750  0.101  0.105  1.0
[/CIF]
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