The structure described by KPtN crystallizes in the monoclinic Pm space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. In the second K site, K(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a linear geometry to two equivalent N(1) atoms. In the second Pt site, Pt(2) is bonded in a linear geometry to two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to four K(1,1) and two equivalent Pt(1) atoms to form a mixture of distorted corner and edge-sharing NK4Pt2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the second N site, N(2) is bonded to four K(1,1) and two equivalent Pt(2) atoms to form a mixture of distorted corner and edge-sharing NK4Pt2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. is represented by the Crystallographic Information File (CIF) [CIF]
data_KPtN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.482
_cell_length_b   3.685
_cell_length_c   5.217
_cell_angle_alpha   45.012
_cell_angle_beta   119.882
_cell_angle_gamma   110.623
_symmetry_Int_Tables_number   1
_cell_volume   123.575
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.465  0.501  0.141  1.0
  K  K1  1  0.966  0.499  0.642  1.0
  Pt  Pt2  1  0.216  0.501  0.391  1.0
  Pt  Pt3  1  0.716  0.499  0.892  1.0
  N  N4  1  0.216  0.001  0.890  1.0
  N  N5  1  0.716  0.999  0.892  1.0
[/CIF]
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The structure described by KPtN crystallizes in the monoclinic Pm space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. In the second K site, K(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a linear geometry to two equivalent N(1) atoms. In the second Pt site, Pt(2) is bonded in a linear geometry to two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to four K(1,1) and two equivalent Pt(1) atoms to form a mixture of distorted corner and edge-sharing NK4Pt2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the second N site, N(2) is bonded to four K(1,1) and two equivalent Pt(2) atoms to form a mixture of distorted corner and edge-sharing NK4Pt2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. is represented by the Crystallographic Information File (CIF) [CIF]
data_KPtN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.482
_cell_length_b   3.685
_cell_length_c   5.217
_cell_angle_alpha   45.012
_cell_angle_beta   119.882
_cell_angle_gamma   110.623
_symmetry_Int_Tables_number   1
_cell_volume   123.575
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.465  0.501  0.141  1.0
  K  K1  1  0.966  0.499  0.642  1.0
  Pt  Pt2  1  0.216  0.501  0.391  1.0
  Pt  Pt3  1  0.716  0.499  0.892  1.0
  N  N4  1  0.216  0.001  0.890  1.0
  N  N5  1  0.716  0.999  0.892  1.0
[/CIF]
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