The compound described by (In)3In2Cl9 is Indium-like structured and crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of eighteen 7440-74-6 atoms and six In2Cl9 clusters. In each In2Cl9 cluster, In(1) is bonded to three equivalent Cl(1) and three equivalent Cl(2) atoms to form distorted face-sharing InCl6 octahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in an L-shaped geometry to two equivalent In(1) atoms. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one In(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_In5Cl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.301
_cell_length_b   9.301
_cell_length_c   9.301
_cell_angle_alpha   83.489
_cell_angle_beta   83.489
_cell_angle_gamma   83.489
_symmetry_Int_Tables_number   1
_cell_volume   790.083
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.148  0.148  0.148  1.0
  In  In1  1  0.352  0.352  0.352  1.0
  In  In2  1  0.852  0.852  0.852  1.0
  In  In3  1  0.648  0.648  0.648  1.0
  In  In4  1  0.566  0.250  0.934  1.0
  In  In5  1  0.250  0.934  0.566  1.0
  In  In6  1  0.934  0.566  0.250  1.0
  In  In7  1  0.434  0.750  0.066  1.0
  In  In8  1  0.750  0.066  0.434  1.0
  In  In9  1  0.066  0.434  0.750  1.0
  Cl  Cl10  1  0.418  0.579  0.771  1.0
  Cl  Cl11  1  0.579  0.771  0.418  1.0
  Cl  Cl12  1  0.771  0.418  0.579  1.0
  Cl  Cl13  1  0.729  0.921  0.082  1.0
  Cl  Cl14  1  0.921  0.082  0.729  1.0
  Cl  Cl15  1  0.082  0.729  0.921  1.0
  Cl  Cl16  1  0.582  0.421  0.229  1.0
  Cl  Cl17  1  0.421  0.229  0.582  1.0
  Cl  Cl18  1  0.229  0.582  0.421  1.0
  Cl  Cl19  1  0.271  0.079  0.918  1.0
  Cl  Cl20  1  0.250  0.407  0.093  1.0
  Cl  Cl21  1  0.093  0.250  0.407  1.0
  Cl  Cl22  1  0.407  0.093  0.250  1.0
  Cl  Cl23  1  0.750  0.593  0.907  1.0
  Cl  Cl24  1  0.907  0.750  0.593  1.0
  Cl  Cl25  1  0.593  0.907  0.750  1.0
  Cl  Cl26  1  0.918  0.271  0.079  1.0
  Cl  Cl27  1  0.079  0.918  0.271  1.0
[/CIF]
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The compound described by (In)3In2Cl9 is Indium-like structured and crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of eighteen 7440-74-6 atoms and six In2Cl9 clusters. In each In2Cl9 cluster, In(1) is bonded to three equivalent Cl(1) and three equivalent Cl(2) atoms to form distorted face-sharing InCl6 octahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in an L-shaped geometry to two equivalent In(1) atoms. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one In(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_In5Cl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.301
_cell_length_b   9.301
_cell_length_c   9.301
_cell_angle_alpha   83.489
_cell_angle_beta   83.489
_cell_angle_gamma   83.489
_symmetry_Int_Tables_number   1
_cell_volume   790.083
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.148  0.148  0.148  1.0
  In  In1  1  0.352  0.352  0.352  1.0
  In  In2  1  0.852  0.852  0.852  1.0
  In  In3  1  0.648  0.648  0.648  1.0
  In  In4  1  0.566  0.250  0.934  1.0
  In  In5  1  0.250  0.934  0.566  1.0
  In  In6  1  0.934  0.566  0.250  1.0
  In  In7  1  0.434  0.750  0.066  1.0
  In  In8  1  0.750  0.066  0.434  1.0
  In  In9  1  0.066  0.434  0.750  1.0
  Cl  Cl10  1  0.418  0.579  0.771  1.0
  Cl  Cl11  1  0.579  0.771  0.418  1.0
  Cl  Cl12  1  0.771  0.418  0.579  1.0
  Cl  Cl13  1  0.729  0.921  0.082  1.0
  Cl  Cl14  1  0.921  0.082  0.729  1.0
  Cl  Cl15  1  0.082  0.729  0.921  1.0
  Cl  Cl16  1  0.582  0.421  0.229  1.0
  Cl  Cl17  1  0.421  0.229  0.582  1.0
  Cl  Cl18  1  0.229  0.582  0.421  1.0
  Cl  Cl19  1  0.271  0.079  0.918  1.0
  Cl  Cl20  1  0.250  0.407  0.093  1.0
  Cl  Cl21  1  0.093  0.250  0.407  1.0
  Cl  Cl22  1  0.407  0.093  0.250  1.0
  Cl  Cl23  1  0.750  0.593  0.907  1.0
  Cl  Cl24  1  0.907  0.750  0.593  1.0
  Cl  Cl25  1  0.593  0.907  0.750  1.0
  Cl  Cl26  1  0.918  0.271  0.079  1.0
  Cl  Cl27  1  0.079  0.918  0.271  1.0
[/CIF]
.