The structure described by TiMn3Te2(PO4)6 crystallizes in the trigonal R3 space group. Ti(1) is bonded to three equivalent O(4) and three equivalent O(6) atoms to form TiO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(5) atoms. In the second Mn site, Mn(2) is bonded to three equivalent O(1) and three equivalent O(3) atoms to form distorted MnO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. In the third Mn site, Mn(3) is bonded to three equivalent O(7) and three equivalent O(8) atoms to form distorted MnO6 pentagonal pyramids that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 22-57°. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 34-42°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. In the second Te site, Te(2) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(7) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one P(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mn(2), one P(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ti(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mn(3), one P(2), and one Te(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(1) atom. is represented by the CIF card [CIF]
data_TiMn3Te2(PO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.890
_cell_length_b   8.890
_cell_length_c   8.890
_cell_angle_alpha   59.834
_cell_angle_beta   59.834
_cell_angle_gamma   59.834
_symmetry_Int_Tables_number   1
_cell_volume   495.012
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.147  0.147  0.147  1.0
  Mn  Mn1  1  0.838  0.838  0.838  1.0
  Mn  Mn2  1  0.651  0.651  0.651  1.0
  Mn  Mn3  1  0.344  0.344  0.344  1.0
  Te  Te4  1  0.981  0.981  0.981  1.0
  Te  Te5  1  0.489  0.489  0.489  1.0
  P  P6  1  0.544  0.956  0.252  1.0
  P  P7  1  0.252  0.544  0.956  1.0
  P  P8  1  0.956  0.252  0.544  1.0
  P  P9  1  0.057  0.756  0.446  1.0
  P  P10  1  0.756  0.446  0.057  1.0
  P  P11  1  0.446  0.057  0.756  1.0
  O  O12  1  0.472  0.908  0.700  1.0
  O  O13  1  0.908  0.700  0.472  1.0
  O  O14  1  0.745  0.936  0.082  1.0
  O  O15  1  0.700  0.472  0.908  1.0
  O  O16  1  0.560  0.760  0.395  1.0
  O  O17  1  0.393  0.021  0.172  1.0
  O  O18  1  0.082  0.745  0.936  1.0
  O  O19  1  0.395  0.560  0.760  1.0
  O  O20  1  0.760  0.395  0.560  1.0
  O  O21  1  0.032  0.803  0.599  1.0
  O  O22  1  0.089  0.916  0.255  1.0
  O  O23  1  0.803  0.599  0.032  1.0
  O  O24  1  0.172  0.393  0.021  1.0
  O  O25  1  0.936  0.082  0.745  1.0
  O  O26  1  0.021  0.172  0.393  1.0
  O  O27  1  0.256  0.592  0.420  1.0
  O  O28  1  0.592  0.420  0.256  1.0
  O  O29  1  0.916  0.255  0.089  1.0
  O  O30  1  0.599  0.032  0.803  1.0
  O  O31  1  0.420  0.256  0.592  1.0
  O  O32  1  0.315  0.525  0.094  1.0
  O  O33  1  0.255  0.089  0.916  1.0
  O  O34  1  0.094  0.315  0.525  1.0
  O  O35  1  0.525  0.094  0.315  1.0
[/CIF]
.
The structure described by TiMn3Te2(PO4)6 crystallizes in the trigonal R3 space group. Ti(1) is bonded to three equivalent O(4) and three equivalent O(6) atoms to form TiO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(5) atoms. In the second Mn site, Mn(2) is bonded to three equivalent O(1) and three equivalent O(3) atoms to form distorted MnO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. In the third Mn site, Mn(3) is bonded to three equivalent O(7) and three equivalent O(8) atoms to form distorted MnO6 pentagonal pyramids that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 22-57°. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 34-42°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. In the second Te site, Te(2) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(7) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one P(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mn(2), one P(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ti(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mn(3), one P(2), and one Te(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(1) atom. is represented by the CIF card [CIF]
data_TiMn3Te2(PO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.890
_cell_length_b   8.890
_cell_length_c   8.890
_cell_angle_alpha   59.834
_cell_angle_beta   59.834
_cell_angle_gamma   59.834
_symmetry_Int_Tables_number   1
_cell_volume   495.012
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.147  0.147  0.147  1.0
  Mn  Mn1  1  0.838  0.838  0.838  1.0
  Mn  Mn2  1  0.651  0.651  0.651  1.0
  Mn  Mn3  1  0.344  0.344  0.344  1.0
  Te  Te4  1  0.981  0.981  0.981  1.0
  Te  Te5  1  0.489  0.489  0.489  1.0
  P  P6  1  0.544  0.956  0.252  1.0
  P  P7  1  0.252  0.544  0.956  1.0
  P  P8  1  0.956  0.252  0.544  1.0
  P  P9  1  0.057  0.756  0.446  1.0
  P  P10  1  0.756  0.446  0.057  1.0
  P  P11  1  0.446  0.057  0.756  1.0
  O  O12  1  0.472  0.908  0.700  1.0
  O  O13  1  0.908  0.700  0.472  1.0
  O  O14  1  0.745  0.936  0.082  1.0
  O  O15  1  0.700  0.472  0.908  1.0
  O  O16  1  0.560  0.760  0.395  1.0
  O  O17  1  0.393  0.021  0.172  1.0
  O  O18  1  0.082  0.745  0.936  1.0
  O  O19  1  0.395  0.560  0.760  1.0
  O  O20  1  0.760  0.395  0.560  1.0
  O  O21  1  0.032  0.803  0.599  1.0
  O  O22  1  0.089  0.916  0.255  1.0
  O  O23  1  0.803  0.599  0.032  1.0
  O  O24  1  0.172  0.393  0.021  1.0
  O  O25  1  0.936  0.082  0.745  1.0
  O  O26  1  0.021  0.172  0.393  1.0
  O  O27  1  0.256  0.592  0.420  1.0
  O  O28  1  0.592  0.420  0.256  1.0
  O  O29  1  0.916  0.255  0.089  1.0
  O  O30  1  0.599  0.032  0.803  1.0
  O  O31  1  0.420  0.256  0.592  1.0
  O  O32  1  0.315  0.525  0.094  1.0
  O  O33  1  0.255  0.089  0.916  1.0
  O  O34  1  0.094  0.315  0.525  1.0
  O  O35  1  0.525  0.094  0.315  1.0
[/CIF]
.