The material structure described by Cs3V4Te2O14Cl crystallizes in the orthorhombic Pnnm space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a distorted q6 geometry to four equivalent O(1), four equivalent O(2), and two equivalent Cl(1) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to two equivalent O(4), three equivalent O(3), and three equivalent O(5) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(5), two equivalent O(1), and two equivalent O(4) atoms to form distorted corner-sharing VO5 trigonal bipyramids. In the second V site, V(2) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form corner-sharing VO4 tetrahedra. Te(1) is bonded in a distorted T-shaped geometry to one O(2) and two equivalent O(4) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one V(1), and one V(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one V(2), and one Te(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Cs(2) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(2), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to three equivalent Cs(2) and one V(1) atom. Cl(1) is bonded in a linear geometry to two equivalent Cs(1) atoms. is represented by the CIF file [CIF]
data_Cs3V4Te2ClO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.580
_cell_length_b   6.941
_cell_length_c   24.444
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   946.643
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.500  0.500  1.0
  Cs  Cs1  1  0.500  0.153  0.771  1.0
  Cs  Cs2  1  0.000  0.653  0.729  1.0
  Cs  Cs3  1  0.000  0.347  0.271  1.0
  Cs  Cs4  1  0.500  0.847  0.229  1.0
  Cs  Cs5  1  0.500  0.000  0.000  1.0
  V  V6  1  0.000  0.131  0.637  1.0
  V  V7  1  0.500  0.369  0.137  1.0
  V  V8  1  0.000  0.063  0.116  1.0
  V  V9  1  0.500  0.437  0.616  1.0
  V  V10  1  0.000  0.869  0.363  1.0
  V  V11  1  0.500  0.631  0.863  1.0
  V  V12  1  0.500  0.563  0.384  1.0
  V  V13  1  0.000  0.937  0.884  1.0
  Te  Te14  1  0.500  0.072  0.416  1.0
  Te  Te15  1  0.500  0.928  0.584  1.0
  Te  Te16  1  0.000  0.572  0.084  1.0
  Te  Te17  1  0.000  0.428  0.916  1.0
  Cl  Cl18  1  0.000  0.000  0.500  1.0
  Cl  Cl19  1  0.500  0.500  0.000  1.0
  O  O20  1  0.252  0.794  0.898  1.0
  O  O21  1  0.000  0.851  0.070  1.0
  O  O22  1  0.000  0.149  0.930  1.0
  O  O23  1  0.248  0.294  0.602  1.0
  O  O24  1  0.252  0.206  0.102  1.0
  O  O25  1  0.500  0.502  0.319  1.0
  O  O26  1  0.752  0.706  0.398  1.0
  O  O27  1  0.244  0.081  0.365  1.0
  O  O28  1  0.752  0.294  0.602  1.0
  O  O29  1  0.000  0.799  0.298  1.0
  O  O30  1  0.748  0.206  0.102  1.0
  O  O31  1  0.756  0.919  0.635  1.0
  O  O32  1  0.744  0.419  0.865  1.0
  O  O33  1  0.500  0.498  0.681  1.0
  O  O34  1  0.500  0.351  0.430  1.0
  O  O35  1  0.744  0.581  0.135  1.0
  O  O36  1  0.248  0.706  0.398  1.0
  O  O37  1  0.500  0.701  0.798  1.0
  O  O38  1  0.256  0.581  0.135  1.0
  O  O39  1  0.000  0.201  0.702  1.0
  O  O40  1  0.256  0.419  0.865  1.0
  O  O41  1  0.000  0.998  0.819  1.0
  O  O42  1  0.748  0.794  0.898  1.0
  O  O43  1  0.756  0.081  0.365  1.0
  O  O44  1  0.500  0.299  0.202  1.0
  O  O45  1  0.000  0.002  0.181  1.0
  O  O46  1  0.244  0.919  0.635  1.0
  O  O47  1  0.500  0.649  0.570  1.0
[/CIF]
.
The material structure described by Cs3V4Te2O14Cl crystallizes in the orthorhombic Pnnm space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a distorted q6 geometry to four equivalent O(1), four equivalent O(2), and two equivalent Cl(1) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to two equivalent O(4), three equivalent O(3), and three equivalent O(5) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(5), two equivalent O(1), and two equivalent O(4) atoms to form distorted corner-sharing VO5 trigonal bipyramids. In the second V site, V(2) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form corner-sharing VO4 tetrahedra. Te(1) is bonded in a distorted T-shaped geometry to one O(2) and two equivalent O(4) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one V(1), and one V(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one V(2), and one Te(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Cs(2) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(2), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to three equivalent Cs(2) and one V(1) atom. Cl(1) is bonded in a linear geometry to two equivalent Cs(1) atoms. is represented by the CIF file [CIF]
data_Cs3V4Te2ClO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.580
_cell_length_b   6.941
_cell_length_c   24.444
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   946.643
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.500  0.500  1.0
  Cs  Cs1  1  0.500  0.153  0.771  1.0
  Cs  Cs2  1  0.000  0.653  0.729  1.0
  Cs  Cs3  1  0.000  0.347  0.271  1.0
  Cs  Cs4  1  0.500  0.847  0.229  1.0
  Cs  Cs5  1  0.500  0.000  0.000  1.0
  V  V6  1  0.000  0.131  0.637  1.0
  V  V7  1  0.500  0.369  0.137  1.0
  V  V8  1  0.000  0.063  0.116  1.0
  V  V9  1  0.500  0.437  0.616  1.0
  V  V10  1  0.000  0.869  0.363  1.0
  V  V11  1  0.500  0.631  0.863  1.0
  V  V12  1  0.500  0.563  0.384  1.0
  V  V13  1  0.000  0.937  0.884  1.0
  Te  Te14  1  0.500  0.072  0.416  1.0
  Te  Te15  1  0.500  0.928  0.584  1.0
  Te  Te16  1  0.000  0.572  0.084  1.0
  Te  Te17  1  0.000  0.428  0.916  1.0
  Cl  Cl18  1  0.000  0.000  0.500  1.0
  Cl  Cl19  1  0.500  0.500  0.000  1.0
  O  O20  1  0.252  0.794  0.898  1.0
  O  O21  1  0.000  0.851  0.070  1.0
  O  O22  1  0.000  0.149  0.930  1.0
  O  O23  1  0.248  0.294  0.602  1.0
  O  O24  1  0.252  0.206  0.102  1.0
  O  O25  1  0.500  0.502  0.319  1.0
  O  O26  1  0.752  0.706  0.398  1.0
  O  O27  1  0.244  0.081  0.365  1.0
  O  O28  1  0.752  0.294  0.602  1.0
  O  O29  1  0.000  0.799  0.298  1.0
  O  O30  1  0.748  0.206  0.102  1.0
  O  O31  1  0.756  0.919  0.635  1.0
  O  O32  1  0.744  0.419  0.865  1.0
  O  O33  1  0.500  0.498  0.681  1.0
  O  O34  1  0.500  0.351  0.430  1.0
  O  O35  1  0.744  0.581  0.135  1.0
  O  O36  1  0.248  0.706  0.398  1.0
  O  O37  1  0.500  0.701  0.798  1.0
  O  O38  1  0.256  0.581  0.135  1.0
  O  O39  1  0.000  0.201  0.702  1.0
  O  O40  1  0.256  0.419  0.865  1.0
  O  O41  1  0.000  0.998  0.819  1.0
  O  O42  1  0.748  0.794  0.898  1.0
  O  O43  1  0.756  0.081  0.365  1.0
  O  O44  1  0.500  0.299  0.202  1.0
  O  O45  1  0.000  0.002  0.181  1.0
  O  O46  1  0.244  0.919  0.635  1.0
  O  O47  1  0.500  0.649  0.570  1.0
[/CIF]
.