The material structure described by CoN5O4Cl is Indium structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of eight CoN5O4Cl clusters. Co(1) is bonded in an octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF card [CIF]
data_CoN5ClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.440
_cell_length_b   10.440
_cell_length_c   10.440
_cell_angle_alpha   122.880
_cell_angle_beta   122.880
_cell_angle_gamma   85.080
_symmetry_Int_Tables_number   1
_cell_volume   766.600
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.728  0.728  0.000  1.0
  Co  Co1  1  0.022  0.522  0.500  1.0
  Co  Co2  1  0.272  0.272  0.000  1.0
  Co  Co3  1  0.478  0.978  0.500  1.0
  N  N4  1  0.930  0.812  0.278  1.0
  N  N5  1  0.534  0.652  0.722  1.0
  N  N6  1  0.216  0.598  0.778  1.0
  N  N7  1  0.820  0.438  0.222  1.0
  N  N8  1  0.348  0.070  0.882  1.0
  N  N9  1  0.188  0.466  0.118  1.0
  N  N10  1  0.562  0.784  0.382  1.0
  N  N11  1  0.402  0.180  0.618  1.0
  N  N12  1  0.625  0.625  0.000  1.0
  N  N13  1  0.125  0.625  0.500  1.0
  N  N14  1  0.375  0.375  0.000  1.0
  N  N15  1  0.375  0.875  0.500  1.0
  N  N16  1  0.802  0.552  0.893  1.0
  N  N17  1  0.658  0.909  0.107  1.0
  N  N18  1  0.092  0.341  0.393  1.0
  N  N19  1  0.948  0.698  0.607  1.0
  N  N20  1  0.091  0.198  0.749  1.0
  N  N21  1  0.448  0.342  0.251  1.0
  N  N22  1  0.302  0.908  0.249  1.0
  N  N23  1  0.659  0.052  0.751  1.0
  Cl  Cl24  1  0.873  0.873  0.000  1.0
  Cl  Cl25  1  0.877  0.377  0.500  1.0
  Cl  Cl26  1  0.127  0.127  0.000  1.0
  Cl  Cl27  1  0.623  0.123  0.500  1.0
  O  O28  1  0.907  0.883  0.399  1.0
  O  O29  1  0.484  0.509  0.601  1.0
  O  O30  1  0.266  0.741  0.899  1.0
  O  O31  1  0.843  0.367  0.101  1.0
  O  O32  1  0.491  0.093  0.976  1.0
  O  O33  1  0.117  0.516  0.024  1.0
  O  O34  1  0.633  0.734  0.476  1.0
  O  O35  1  0.259  0.157  0.524  1.0
  O  O36  1  0.051  0.783  0.291  1.0
  O  O37  1  0.492  0.759  0.709  1.0
  O  O38  1  0.258  0.491  0.791  1.0
  O  O39  1  0.699  0.467  0.209  1.0
  O  O40  1  0.241  0.949  0.733  1.0
  O  O41  1  0.217  0.508  0.267  1.0
  O  O42  1  0.533  0.742  0.233  1.0
  O  O43  1  0.509  0.301  0.767  1.0
[/CIF]
.
The material structure described by CoN5O4Cl is Indium structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of eight CoN5O4Cl clusters. Co(1) is bonded in an octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF card [CIF]
data_CoN5ClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.440
_cell_length_b   10.440
_cell_length_c   10.440
_cell_angle_alpha   122.880
_cell_angle_beta   122.880
_cell_angle_gamma   85.080
_symmetry_Int_Tables_number   1
_cell_volume   766.600
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.728  0.728  0.000  1.0
  Co  Co1  1  0.022  0.522  0.500  1.0
  Co  Co2  1  0.272  0.272  0.000  1.0
  Co  Co3  1  0.478  0.978  0.500  1.0
  N  N4  1  0.930  0.812  0.278  1.0
  N  N5  1  0.534  0.652  0.722  1.0
  N  N6  1  0.216  0.598  0.778  1.0
  N  N7  1  0.820  0.438  0.222  1.0
  N  N8  1  0.348  0.070  0.882  1.0
  N  N9  1  0.188  0.466  0.118  1.0
  N  N10  1  0.562  0.784  0.382  1.0
  N  N11  1  0.402  0.180  0.618  1.0
  N  N12  1  0.625  0.625  0.000  1.0
  N  N13  1  0.125  0.625  0.500  1.0
  N  N14  1  0.375  0.375  0.000  1.0
  N  N15  1  0.375  0.875  0.500  1.0
  N  N16  1  0.802  0.552  0.893  1.0
  N  N17  1  0.658  0.909  0.107  1.0
  N  N18  1  0.092  0.341  0.393  1.0
  N  N19  1  0.948  0.698  0.607  1.0
  N  N20  1  0.091  0.198  0.749  1.0
  N  N21  1  0.448  0.342  0.251  1.0
  N  N22  1  0.302  0.908  0.249  1.0
  N  N23  1  0.659  0.052  0.751  1.0
  Cl  Cl24  1  0.873  0.873  0.000  1.0
  Cl  Cl25  1  0.877  0.377  0.500  1.0
  Cl  Cl26  1  0.127  0.127  0.000  1.0
  Cl  Cl27  1  0.623  0.123  0.500  1.0
  O  O28  1  0.907  0.883  0.399  1.0
  O  O29  1  0.484  0.509  0.601  1.0
  O  O30  1  0.266  0.741  0.899  1.0
  O  O31  1  0.843  0.367  0.101  1.0
  O  O32  1  0.491  0.093  0.976  1.0
  O  O33  1  0.117  0.516  0.024  1.0
  O  O34  1  0.633  0.734  0.476  1.0
  O  O35  1  0.259  0.157  0.524  1.0
  O  O36  1  0.051  0.783  0.291  1.0
  O  O37  1  0.492  0.759  0.709  1.0
  O  O38  1  0.258  0.491  0.791  1.0
  O  O39  1  0.699  0.467  0.209  1.0
  O  O40  1  0.241  0.949  0.733  1.0
  O  O41  1  0.217  0.508  0.267  1.0
  O  O42  1  0.533  0.742  0.233  1.0
  O  O43  1  0.509  0.301  0.767  1.0
[/CIF]
.