The material described by Na5Mn2P2(CO7)2 crystallizes in the triclinic P-1 space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted hexagonal planar geometry to one O(1), one O(2), one O(4), one O(6), one O(7), and one O(9) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(8) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(14), one O(2), one O(3), one O(5), and one O(9) atom. In the fourth Na site, Na(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(4), and one O(6) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(13), one O(14), one O(2), one O(4), one O(6), one O(7), and one O(8) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(12), one O(3), one O(6), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(13), one O(14), one O(4), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(13), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the second P site, P(2) is bonded to one O(10), one O(12), one O(14), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-57°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Na(2), one Na(4), and one C(2) atom to form a mixture of distorted corner and edge-sharing ONa3C trigonal pyramids. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(3), one Na(5), and one C(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Mn(1), and one C(2) atom. In the fourth O site, O(4) is bonded to one Na(1), one Na(4), one Na(5), one Mn(2), and one C(1) atom to form distorted ONa3MnC trigonal bipyramids that share corners with two equivalent O(1)Na3C trigonal pyramids and  a faceface with one O(6)Na3MnC trigonal bipyramid. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(3), one Mn(2), and one C(1) atom. In the sixth O site, O(6) is bonded to one Na(1), one Na(4), one Na(5), one Mn(1), and one C(2) atom to form distorted ONa3MnC trigonal bipyramids that share  a cornercorner with one O(1)Na3C trigonal pyramid,  an edgeedge with one O(1)Na3C trigonal pyramid, and  a faceface with one O(4)Na3MnC trigonal bipyramid. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(1), one Na(5), one Mn(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(2), one Na(5), one Mn(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Mn(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(3), one Na(4), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(2), one Na(4), one Mn(1), and one P(1) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Na(2), one Na(3), one Mn(1), and one P(2) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Na(4), one Na(5), one Mn(2), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Na(3), one Na(5), one Mn(2), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.462
_cell_length_b   8.481
_cell_length_c   9.014
_cell_angle_alpha   90.657
_cell_angle_beta   90.623
_cell_angle_gamma   103.231
_symmetry_Int_Tables_number   1
_cell_volume   629.618
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.759  0.009  0.920  1.0
  Na  Na1  1  0.613  0.611  0.766  1.0
  Na  Na2  1  0.885  0.387  0.762  1.0
  Na  Na3  1  0.365  0.855  0.747  1.0
  Na  Na4  1  0.130  0.137  0.744  1.0
  Na  Na5  1  0.870  0.863  0.256  1.0
  Na  Na6  1  0.635  0.145  0.253  1.0
  Na  Na7  1  0.387  0.389  0.234  1.0
  Na  Na8  1  0.115  0.613  0.238  1.0
  Na  Na9  1  0.241  0.991  0.080  1.0
  Mn  Mn10  1  0.516  0.265  0.644  1.0
  Mn  Mn11  1  0.014  0.765  0.642  1.0
  Mn  Mn12  1  0.484  0.735  0.356  1.0
  Mn  Mn13  1  0.986  0.235  0.358  1.0
  P  P14  1  0.724  0.975  0.581  1.0
  P  P15  1  0.227  0.476  0.577  1.0
  P  P16  1  0.773  0.524  0.423  1.0
  P  P17  1  0.276  0.025  0.419  1.0
  C  C18  1  0.995  0.748  0.933  1.0
  C  C19  1  0.483  0.231  0.932  1.0
  C  C20  1  0.517  0.769  0.068  1.0
  C  C21  1  0.005  0.252  0.067  1.0
  O  O22  1  0.520  0.776  0.926  1.0
  O  O23  1  0.001  0.244  0.925  1.0
  O  O24  1  0.592  0.339  0.861  1.0
  O  O25  1  0.102  0.854  0.859  1.0
  O  O26  1  0.890  0.644  0.855  1.0
  O  O27  1  0.381  0.128  0.850  1.0
  O  O28  1  0.855  0.922  0.677  1.0
  O  O29  1  0.364  0.422  0.666  1.0
  O  O30  1  0.669  0.108  0.676  1.0
  O  O31  1  0.174  0.611  0.667  1.0
  O  O32  1  0.574  0.827  0.557  1.0
  O  O33  1  0.714  0.464  0.579  1.0
  O  O34  1  0.211  0.962  0.571  1.0
  O  O35  1  0.079  0.327  0.559  1.0
  O  O36  1  0.921  0.673  0.441  1.0
  O  O37  1  0.789  0.038  0.429  1.0
  O  O38  1  0.286  0.536  0.421  1.0
  O  O39  1  0.426  0.173  0.443  1.0
  O  O40  1  0.826  0.389  0.333  1.0
  O  O41  1  0.636  0.578  0.334  1.0
  O  O42  1  0.331  0.892  0.324  1.0
  O  O43  1  0.145  0.078  0.323  1.0
  O  O44  1  0.619  0.872  0.150  1.0
  O  O45  1  0.110  0.356  0.145  1.0
  O  O46  1  0.898  0.146  0.141  1.0
  O  O47  1  0.408  0.661  0.139  1.0
  O  O48  1  0.999  0.756  0.075  1.0
  O  O49  1  0.480  0.224  0.074  1.0
[/CIF]
.
The material described by Na5Mn2P2(CO7)2 crystallizes in the triclinic P-1 space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted hexagonal planar geometry to one O(1), one O(2), one O(4), one O(6), one O(7), and one O(9) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(8) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(14), one O(2), one O(3), one O(5), and one O(9) atom. In the fourth Na site, Na(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(4), and one O(6) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(13), one O(14), one O(2), one O(4), one O(6), one O(7), and one O(8) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(12), one O(3), one O(6), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(13), one O(14), one O(4), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(13), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the second P site, P(2) is bonded to one O(10), one O(12), one O(14), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-57°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Na(2), one Na(4), and one C(2) atom to form a mixture of distorted corner and edge-sharing ONa3C trigonal pyramids. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(3), one Na(5), and one C(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Mn(1), and one C(2) atom. In the fourth O site, O(4) is bonded to one Na(1), one Na(4), one Na(5), one Mn(2), and one C(1) atom to form distorted ONa3MnC trigonal bipyramids that share corners with two equivalent O(1)Na3C trigonal pyramids and  a faceface with one O(6)Na3MnC trigonal bipyramid. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(3), one Mn(2), and one C(1) atom. In the sixth O site, O(6) is bonded to one Na(1), one Na(4), one Na(5), one Mn(1), and one C(2) atom to form distorted ONa3MnC trigonal bipyramids that share  a cornercorner with one O(1)Na3C trigonal pyramid,  an edgeedge with one O(1)Na3C trigonal pyramid, and  a faceface with one O(4)Na3MnC trigonal bipyramid. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(1), one Na(5), one Mn(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(2), one Na(5), one Mn(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Mn(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(3), one Na(4), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(2), one Na(4), one Mn(1), and one P(1) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Na(2), one Na(3), one Mn(1), and one P(2) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Na(4), one Na(5), one Mn(2), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Na(3), one Na(5), one Mn(2), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.462
_cell_length_b   8.481
_cell_length_c   9.014
_cell_angle_alpha   90.657
_cell_angle_beta   90.623
_cell_angle_gamma   103.231
_symmetry_Int_Tables_number   1
_cell_volume   629.618
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.759  0.009  0.920  1.0
  Na  Na1  1  0.613  0.611  0.766  1.0
  Na  Na2  1  0.885  0.387  0.762  1.0
  Na  Na3  1  0.365  0.855  0.747  1.0
  Na  Na4  1  0.130  0.137  0.744  1.0
  Na  Na5  1  0.870  0.863  0.256  1.0
  Na  Na6  1  0.635  0.145  0.253  1.0
  Na  Na7  1  0.387  0.389  0.234  1.0
  Na  Na8  1  0.115  0.613  0.238  1.0
  Na  Na9  1  0.241  0.991  0.080  1.0
  Mn  Mn10  1  0.516  0.265  0.644  1.0
  Mn  Mn11  1  0.014  0.765  0.642  1.0
  Mn  Mn12  1  0.484  0.735  0.356  1.0
  Mn  Mn13  1  0.986  0.235  0.358  1.0
  P  P14  1  0.724  0.975  0.581  1.0
  P  P15  1  0.227  0.476  0.577  1.0
  P  P16  1  0.773  0.524  0.423  1.0
  P  P17  1  0.276  0.025  0.419  1.0
  C  C18  1  0.995  0.748  0.933  1.0
  C  C19  1  0.483  0.231  0.932  1.0
  C  C20  1  0.517  0.769  0.068  1.0
  C  C21  1  0.005  0.252  0.067  1.0
  O  O22  1  0.520  0.776  0.926  1.0
  O  O23  1  0.001  0.244  0.925  1.0
  O  O24  1  0.592  0.339  0.861  1.0
  O  O25  1  0.102  0.854  0.859  1.0
  O  O26  1  0.890  0.644  0.855  1.0
  O  O27  1  0.381  0.128  0.850  1.0
  O  O28  1  0.855  0.922  0.677  1.0
  O  O29  1  0.364  0.422  0.666  1.0
  O  O30  1  0.669  0.108  0.676  1.0
  O  O31  1  0.174  0.611  0.667  1.0
  O  O32  1  0.574  0.827  0.557  1.0
  O  O33  1  0.714  0.464  0.579  1.0
  O  O34  1  0.211  0.962  0.571  1.0
  O  O35  1  0.079  0.327  0.559  1.0
  O  O36  1  0.921  0.673  0.441  1.0
  O  O37  1  0.789  0.038  0.429  1.0
  O  O38  1  0.286  0.536  0.421  1.0
  O  O39  1  0.426  0.173  0.443  1.0
  O  O40  1  0.826  0.389  0.333  1.0
  O  O41  1  0.636  0.578  0.334  1.0
  O  O42  1  0.331  0.892  0.324  1.0
  O  O43  1  0.145  0.078  0.323  1.0
  O  O44  1  0.619  0.872  0.150  1.0
  O  O45  1  0.110  0.356  0.145  1.0
  O  O46  1  0.898  0.146  0.141  1.0
  O  O47  1  0.408  0.661  0.139  1.0
  O  O48  1  0.999  0.756  0.075  1.0
  O  O49  1  0.480  0.224  0.074  1.0
[/CIF]
.