The material structure described by K2BiH5(CO2)5 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(2) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(3), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one H(3) and two equivalent O(5) atoms. Bi(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. There are five inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to two equivalent K(1), one C(2), and one Bi(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one C(3), and one Bi(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to two equivalent K(1), one C(1), and one Bi(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1), one C(1), and one Bi(1) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1), one C(2), and one Bi(1) atom. is represented by the CIF card [CIF]
data_K2BiH5(CO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.247
_cell_length_b   7.247
_cell_length_c   12.382
_cell_angle_alpha   87.465
_cell_angle_beta   87.465
_cell_angle_gamma   112.350
_symmetry_Int_Tables_number   1
_cell_volume   599.523
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.955  0.249  0.881  1.0
  K  K1  1  0.751  0.045  0.619  1.0
  K  K2  1  0.045  0.751  0.119  1.0
  K  K3  1  0.249  0.955  0.381  1.0
  Bi  Bi4  1  0.170  0.830  0.750  1.0
  Bi  Bi5  1  0.830  0.170  0.250  1.0
  H  H6  1  0.651  0.654  0.932  1.0
  H  H7  1  0.346  0.349  0.568  1.0
  H  H8  1  0.349  0.346  0.068  1.0
  H  H9  1  0.654  0.651  0.432  1.0
  H  H10  1  0.514  0.225  0.956  1.0
  H  H11  1  0.775  0.486  0.544  1.0
  H  H12  1  0.486  0.775  0.044  1.0
  H  H13  1  0.225  0.514  0.456  1.0
  H  H14  1  0.505  0.495  0.750  1.0
  H  H15  1  0.495  0.505  0.250  1.0
  C  C16  1  0.798  0.701  0.886  1.0
  C  C17  1  0.299  0.202  0.614  1.0
  C  C18  1  0.202  0.299  0.114  1.0
  C  C19  1  0.701  0.798  0.386  1.0
  C  C20  1  0.430  0.114  0.899  1.0
  C  C21  1  0.886  0.570  0.601  1.0
  C  C22  1  0.570  0.886  0.101  1.0
  C  C23  1  0.114  0.430  0.399  1.0
  C  C24  1  0.413  0.587  0.750  1.0
  C  C25  1  0.587  0.413  0.250  1.0
  O  O26  1  0.839  0.840  0.811  1.0
  O  O27  1  0.160  0.161  0.689  1.0
  O  O28  1  0.161  0.160  0.189  1.0
  O  O29  1  0.840  0.839  0.311  1.0
  O  O30  1  0.914  0.613  0.909  1.0
  O  O31  1  0.387  0.086  0.591  1.0
  O  O32  1  0.086  0.387  0.091  1.0
  O  O33  1  0.613  0.914  0.409  1.0
  O  O34  1  0.241  0.026  0.919  1.0
  O  O35  1  0.974  0.759  0.581  1.0
  O  O36  1  0.759  0.974  0.081  1.0
  O  O37  1  0.026  0.241  0.419  1.0
  O  O38  1  0.526  0.084  0.819  1.0
  O  O39  1  0.916  0.474  0.681  1.0
  O  O40  1  0.474  0.916  0.181  1.0
  O  O41  1  0.084  0.526  0.319  1.0
  O  O42  1  0.418  0.690  0.663  1.0
  O  O43  1  0.310  0.582  0.837  1.0
  O  O44  1  0.582  0.310  0.337  1.0
  O  O45  1  0.690  0.418  0.163  1.0
[/CIF]
.
The material structure described by K2BiH5(CO2)5 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(2) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(3), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one H(3) and two equivalent O(5) atoms. Bi(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. There are five inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to two equivalent K(1), one C(2), and one Bi(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one C(3), and one Bi(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to two equivalent K(1), one C(1), and one Bi(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1), one C(1), and one Bi(1) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1), one C(2), and one Bi(1) atom. is represented by the CIF card [CIF]
data_K2BiH5(CO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.247
_cell_length_b   7.247
_cell_length_c   12.382
_cell_angle_alpha   87.465
_cell_angle_beta   87.465
_cell_angle_gamma   112.350
_symmetry_Int_Tables_number   1
_cell_volume   599.523
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.955  0.249  0.881  1.0
  K  K1  1  0.751  0.045  0.619  1.0
  K  K2  1  0.045  0.751  0.119  1.0
  K  K3  1  0.249  0.955  0.381  1.0
  Bi  Bi4  1  0.170  0.830  0.750  1.0
  Bi  Bi5  1  0.830  0.170  0.250  1.0
  H  H6  1  0.651  0.654  0.932  1.0
  H  H7  1  0.346  0.349  0.568  1.0
  H  H8  1  0.349  0.346  0.068  1.0
  H  H9  1  0.654  0.651  0.432  1.0
  H  H10  1  0.514  0.225  0.956  1.0
  H  H11  1  0.775  0.486  0.544  1.0
  H  H12  1  0.486  0.775  0.044  1.0
  H  H13  1  0.225  0.514  0.456  1.0
  H  H14  1  0.505  0.495  0.750  1.0
  H  H15  1  0.495  0.505  0.250  1.0
  C  C16  1  0.798  0.701  0.886  1.0
  C  C17  1  0.299  0.202  0.614  1.0
  C  C18  1  0.202  0.299  0.114  1.0
  C  C19  1  0.701  0.798  0.386  1.0
  C  C20  1  0.430  0.114  0.899  1.0
  C  C21  1  0.886  0.570  0.601  1.0
  C  C22  1  0.570  0.886  0.101  1.0
  C  C23  1  0.114  0.430  0.399  1.0
  C  C24  1  0.413  0.587  0.750  1.0
  C  C25  1  0.587  0.413  0.250  1.0
  O  O26  1  0.839  0.840  0.811  1.0
  O  O27  1  0.160  0.161  0.689  1.0
  O  O28  1  0.161  0.160  0.189  1.0
  O  O29  1  0.840  0.839  0.311  1.0
  O  O30  1  0.914  0.613  0.909  1.0
  O  O31  1  0.387  0.086  0.591  1.0
  O  O32  1  0.086  0.387  0.091  1.0
  O  O33  1  0.613  0.914  0.409  1.0
  O  O34  1  0.241  0.026  0.919  1.0
  O  O35  1  0.974  0.759  0.581  1.0
  O  O36  1  0.759  0.974  0.081  1.0
  O  O37  1  0.026  0.241  0.419  1.0
  O  O38  1  0.526  0.084  0.819  1.0
  O  O39  1  0.916  0.474  0.681  1.0
  O  O40  1  0.474  0.916  0.181  1.0
  O  O41  1  0.084  0.526  0.319  1.0
  O  O42  1  0.418  0.690  0.663  1.0
  O  O43  1  0.310  0.582  0.837  1.0
  O  O44  1  0.582  0.310  0.337  1.0
  O  O45  1  0.690  0.418  0.163  1.0
[/CIF]
.