The structure described by Li4V3OF11 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(10), one F(2), one F(4), one F(5), and one F(7) atom to form distorted LiF5 trigonal bipyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra,  a cornercorner with one V(1)OF6 pentagonal bipyramid, corners with two equivalent V(3)OF6 pentagonal bipyramids,  an edgeedge with one Li(2)F6 octahedra, and  an edgeedge with one V(1)OF6 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 53-61°. In the second Li site, Li(2) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form distorted LiF6 octahedra that share corners with two equivalent V(2)OF5 octahedra,  a cornercorner with one V(1)OF6 pentagonal bipyramid,  a cornercorner with one V(3)OF6 pentagonal bipyramid,  a cornercorner with one Li(1)F5 trigonal bipyramid,  an edgeedge with one V(1)OF6 pentagonal bipyramid,  an edgeedge with one V(3)OF6 pentagonal bipyramid, and  an edgeedge with one Li(1)F5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 44-53°. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one F(1), one F(4), one F(6), one F(7), and one F(9) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one F(11), one F(2), one F(3), one F(5), one F(7), and one F(9) atom to form distorted VOF6 pentagonal bipyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra,  a cornercorner with one Li(1)F5 trigonal bipyramid,  an edgeedge with one Li(2)F6 octahedra,  an edgeedge with one V(2)OF5 octahedra, edges with two equivalent V(3)OF6 pentagonal bipyramids, and  an edgeedge with one Li(1)F5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 38-52°. In the second V site, V(2) is bonded to one O(1), one F(1), one F(10), one F(11), one F(3), and one F(8) atom to form VOF5 octahedra that share corners with two equivalent Li(2)F6 octahedra,  a cornercorner with one V(1)OF6 pentagonal bipyramid,  a cornercorner with one V(3)OF6 pentagonal bipyramid,  a cornercorner with one Li(1)F5 trigonal bipyramid,  an edgeedge with one V(1)OF6 pentagonal bipyramid, and  an edgeedge with one V(3)OF6 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 44-53°. In the third V site, V(3) is bonded to one O(1), one F(11), one F(2), one F(4), one F(6), one F(8), and one F(9) atom to form distorted VOF6 pentagonal bipyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(1)F5 trigonal bipyramids,  an edgeedge with one Li(2)F6 octahedra,  an edgeedge with one V(2)OF5 octahedra, and edges with two equivalent V(1)OF6 pentagonal bipyramids. The corner-sharing octahedral tilt angles range from 46-57°. O(1) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(2), and one V(3) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(2), one Li(4), and one V(2) atom. In the second F site, F(2) is bonded to one Li(1), one Li(2), one V(1), and one V(3) atom to form FLi2V2 tetrahedra that share  a cornercorner with one F(5)Li3V tetrahedra, corners with two equivalent F(6)Li3V tetrahedra,  an edgeedge with one F(9)Li2V2 tetrahedra, and  an edgeedge with one F(5)Li3V tetrahedra. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one V(1), and one V(2) atom. In the fourth F site, F(4) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Li(4), and one V(3) atom. In the fifth F site, F(5) is bonded to one Li(1), one Li(2), one Li(3), and one V(1) atom to form FLi3V tetrahedra that share  a cornercorner with one F(2)Li2V2 tetrahedra, corners with two equivalent F(9)Li2V2 tetrahedra,  an edgeedge with one F(2)Li2V2 tetrahedra, and  an edgeedge with one F(6)Li3V tetrahedra. In the sixth F site, F(6) is bonded to one Li(2), one Li(3), one Li(4), and one V(3) atom to form distorted FLi3V tetrahedra that share  a cornercorner with one F(9)Li2V2 tetrahedra, corners with two equivalent F(2)Li2V2 tetrahedra,  an edgeedge with one F(9)Li2V2 tetrahedra, and  an edgeedge with one F(5)Li3V tetrahedra. In the seventh F site, F(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Li(4), and one V(1) atom. In the eighth F site, F(8) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one V(2), and one V(3) atom. In the ninth F site, F(9) is bonded to one Li(3), one Li(4), one V(1), and one V(3) atom to form distorted FLi2V2 tetrahedra that share  a cornercorner with one F(6)Li3V tetrahedra, corners with two equivalent F(5)Li3V tetrahedra,  an edgeedge with one F(2)Li2V2 tetrahedra, and  an edgeedge with one F(6)Li3V tetrahedra. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Li(1), one Li(3), and one V(2) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(2), and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4V3OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.600
_cell_length_b   6.425
_cell_length_c   6.203
_cell_angle_alpha   103.170
_cell_angle_beta   97.564
_cell_angle_gamma   101.032
_symmetry_Int_Tables_number   1
_cell_volume   209.669
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.144  0.552  0.337  1.0
  Li  Li1  1  0.385  0.640  0.855  1.0
  Li  Li2  1  0.616  0.357  0.129  1.0
  Li  Li3  1  0.861  0.461  0.667  1.0
  V  V4  1  0.702  0.863  0.381  1.0
  V  V5  1  0.008  0.001  0.025  1.0
  V  V6  1  0.300  0.132  0.605  1.0
  O  O7  1  0.056  0.973  0.326  1.0
  F  F8  1  0.065  0.714  0.891  1.0
  F  F9  1  0.428  0.845  0.586  1.0
  F  F10  1  0.659  0.869  0.047  1.0
  F  F11  1  0.166  0.395  0.583  1.0
  F  F12  1  0.429  0.597  0.201  1.0
  F  F13  1  0.577  0.399  0.792  1.0
  F  F14  1  0.833  0.603  0.424  1.0
  F  F15  1  0.337  0.127  0.944  1.0
  F  F16  1  0.569  0.148  0.406  1.0
  F  F17  1  0.941  0.294  0.104  1.0
  F  F18  1  0.921  0.029  0.697  1.0
[/CIF]
.
The structure described by Li4V3OF11 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(10), one F(2), one F(4), one F(5), and one F(7) atom to form distorted LiF5 trigonal bipyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra,  a cornercorner with one V(1)OF6 pentagonal bipyramid, corners with two equivalent V(3)OF6 pentagonal bipyramids,  an edgeedge with one Li(2)F6 octahedra, and  an edgeedge with one V(1)OF6 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 53-61°. In the second Li site, Li(2) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form distorted LiF6 octahedra that share corners with two equivalent V(2)OF5 octahedra,  a cornercorner with one V(1)OF6 pentagonal bipyramid,  a cornercorner with one V(3)OF6 pentagonal bipyramid,  a cornercorner with one Li(1)F5 trigonal bipyramid,  an edgeedge with one V(1)OF6 pentagonal bipyramid,  an edgeedge with one V(3)OF6 pentagonal bipyramid, and  an edgeedge with one Li(1)F5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 44-53°. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one F(1), one F(4), one F(6), one F(7), and one F(9) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one F(11), one F(2), one F(3), one F(5), one F(7), and one F(9) atom to form distorted VOF6 pentagonal bipyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra,  a cornercorner with one Li(1)F5 trigonal bipyramid,  an edgeedge with one Li(2)F6 octahedra,  an edgeedge with one V(2)OF5 octahedra, edges with two equivalent V(3)OF6 pentagonal bipyramids, and  an edgeedge with one Li(1)F5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 38-52°. In the second V site, V(2) is bonded to one O(1), one F(1), one F(10), one F(11), one F(3), and one F(8) atom to form VOF5 octahedra that share corners with two equivalent Li(2)F6 octahedra,  a cornercorner with one V(1)OF6 pentagonal bipyramid,  a cornercorner with one V(3)OF6 pentagonal bipyramid,  a cornercorner with one Li(1)F5 trigonal bipyramid,  an edgeedge with one V(1)OF6 pentagonal bipyramid, and  an edgeedge with one V(3)OF6 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 44-53°. In the third V site, V(3) is bonded to one O(1), one F(11), one F(2), one F(4), one F(6), one F(8), and one F(9) atom to form distorted VOF6 pentagonal bipyramids that share  a cornercorner with one Li(2)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(1)F5 trigonal bipyramids,  an edgeedge with one Li(2)F6 octahedra,  an edgeedge with one V(2)OF5 octahedra, and edges with two equivalent V(1)OF6 pentagonal bipyramids. The corner-sharing octahedral tilt angles range from 46-57°. O(1) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(2), and one V(3) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(2), one Li(4), and one V(2) atom. In the second F site, F(2) is bonded to one Li(1), one Li(2), one V(1), and one V(3) atom to form FLi2V2 tetrahedra that share  a cornercorner with one F(5)Li3V tetrahedra, corners with two equivalent F(6)Li3V tetrahedra,  an edgeedge with one F(9)Li2V2 tetrahedra, and  an edgeedge with one F(5)Li3V tetrahedra. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one V(1), and one V(2) atom. In the fourth F site, F(4) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Li(4), and one V(3) atom. In the fifth F site, F(5) is bonded to one Li(1), one Li(2), one Li(3), and one V(1) atom to form FLi3V tetrahedra that share  a cornercorner with one F(2)Li2V2 tetrahedra, corners with two equivalent F(9)Li2V2 tetrahedra,  an edgeedge with one F(2)Li2V2 tetrahedra, and  an edgeedge with one F(6)Li3V tetrahedra. In the sixth F site, F(6) is bonded to one Li(2), one Li(3), one Li(4), and one V(3) atom to form distorted FLi3V tetrahedra that share  a cornercorner with one F(9)Li2V2 tetrahedra, corners with two equivalent F(2)Li2V2 tetrahedra,  an edgeedge with one F(9)Li2V2 tetrahedra, and  an edgeedge with one F(5)Li3V tetrahedra. In the seventh F site, F(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Li(4), and one V(1) atom. In the eighth F site, F(8) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one V(2), and one V(3) atom. In the ninth F site, F(9) is bonded to one Li(3), one Li(4), one V(1), and one V(3) atom to form distorted FLi2V2 tetrahedra that share  a cornercorner with one F(6)Li3V tetrahedra, corners with two equivalent F(5)Li3V tetrahedra,  an edgeedge with one F(2)Li2V2 tetrahedra, and  an edgeedge with one F(6)Li3V tetrahedra. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Li(1), one Li(3), and one V(2) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(2), and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4V3OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.600
_cell_length_b   6.425
_cell_length_c   6.203
_cell_angle_alpha   103.170
_cell_angle_beta   97.564
_cell_angle_gamma   101.032
_symmetry_Int_Tables_number   1
_cell_volume   209.669
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.144  0.552  0.337  1.0
  Li  Li1  1  0.385  0.640  0.855  1.0
  Li  Li2  1  0.616  0.357  0.129  1.0
  Li  Li3  1  0.861  0.461  0.667  1.0
  V  V4  1  0.702  0.863  0.381  1.0
  V  V5  1  0.008  0.001  0.025  1.0
  V  V6  1  0.300  0.132  0.605  1.0
  O  O7  1  0.056  0.973  0.326  1.0
  F  F8  1  0.065  0.714  0.891  1.0
  F  F9  1  0.428  0.845  0.586  1.0
  F  F10  1  0.659  0.869  0.047  1.0
  F  F11  1  0.166  0.395  0.583  1.0
  F  F12  1  0.429  0.597  0.201  1.0
  F  F13  1  0.577  0.399  0.792  1.0
  F  F14  1  0.833  0.603  0.424  1.0
  F  F15  1  0.337  0.127  0.944  1.0
  F  F16  1  0.569  0.148  0.406  1.0
  F  F17  1  0.941  0.294  0.104  1.0
  F  F18  1  0.921  0.029  0.697  1.0
[/CIF]
.