The structure described by Sn3(HO2)2 is Indium structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four Sn3(HO2)2 clusters. There are six inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(8) atom. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the third Sn site, Sn(3) is bonded in a 4-coordinate geometry to one O(3), one O(4), one O(6), and one O(7) atom. In the fourth Sn site, Sn(4) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(7), and one O(8) atom. In the fifth Sn site, Sn(5) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(5), and one O(7) atom. In the sixth Sn site, Sn(6) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sn(1), one Sn(4), one Sn(5), and one H(1) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Sn(3), one Sn(4), one Sn(6), and one H(4) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sn(2), one Sn(3), one Sn(5), and one H(3) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Sn(1), one Sn(2), one Sn(6), and one H(2) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(2), and one Sn(5) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Sn(2), one Sn(3), and one Sn(6) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Sn(3), one Sn(4), and one Sn(5) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(4), and one Sn(6) atom. is represented by the CIF card [CIF]
data_Sn3(HO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.924
_cell_length_b   7.924
_cell_length_c   9.085
_cell_angle_alpha   89.938
_cell_angle_beta   89.938
_cell_angle_gamma   90.010
_symmetry_Int_Tables_number   1
_cell_volume   570.422
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.196  0.110  0.505  1.0
  Sn  Sn1  1  0.696  0.371  0.002  1.0
  Sn  Sn2  1  0.786  0.872  0.509  1.0
  Sn  Sn3  1  0.286  0.610  0.997  1.0
  Sn  Sn4  1  0.371  0.696  0.502  1.0
  Sn  Sn5  1  0.110  0.196  0.005  1.0
  Sn  Sn6  1  0.610  0.286  0.497  1.0
  Sn  Sn7  1  0.872  0.786  0.009  1.0
  Sn  Sn8  1  0.489  0.994  0.780  1.0
  Sn  Sn9  1  0.988  0.492  0.726  1.0
  Sn  Sn10  1  0.492  0.988  0.226  1.0
  Sn  Sn11  1  0.994  0.489  0.280  1.0
  H  H12  1  0.327  0.316  0.737  1.0
  H  H13  1  0.827  0.169  0.766  1.0
  H  H14  1  0.651  0.670  0.744  1.0
  H  H15  1  0.151  0.816  0.766  1.0
  H  H16  1  0.169  0.827  0.266  1.0
  H  H17  1  0.316  0.327  0.237  1.0
  H  H18  1  0.816  0.151  0.266  1.0
  H  H19  1  0.670  0.651  0.244  1.0
  O  O20  1  0.380  0.237  0.668  1.0
  O  O21  1  0.879  0.247  0.836  1.0
  O  O22  1  0.600  0.748  0.673  1.0
  O  O23  1  0.099  0.737  0.836  1.0
  O  O24  1  0.247  0.879  0.336  1.0
  O  O25  1  0.237  0.380  0.168  1.0
  O  O26  1  0.737  0.099  0.336  1.0
  O  O27  1  0.748  0.600  0.173  1.0
  O  O28  1  0.306  0.911  0.625  1.0
  O  O29  1  0.806  0.572  0.883  1.0
  O  O30  1  0.674  0.073  0.625  1.0
  O  O31  1  0.174  0.411  0.879  1.0
  O  O32  1  0.572  0.806  0.383  1.0
  O  O33  1  0.911  0.306  0.125  1.0
  O  O34  1  0.411  0.174  0.379  1.0
  O  O35  1  0.073  0.674  0.125  1.0
[/CIF]
.
The structure described by Sn3(HO2)2 is Indium structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four Sn3(HO2)2 clusters. There are six inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(8) atom. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the third Sn site, Sn(3) is bonded in a 4-coordinate geometry to one O(3), one O(4), one O(6), and one O(7) atom. In the fourth Sn site, Sn(4) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(7), and one O(8) atom. In the fifth Sn site, Sn(5) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(5), and one O(7) atom. In the sixth Sn site, Sn(6) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sn(1), one Sn(4), one Sn(5), and one H(1) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Sn(3), one Sn(4), one Sn(6), and one H(4) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sn(2), one Sn(3), one Sn(5), and one H(3) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Sn(1), one Sn(2), one Sn(6), and one H(2) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(2), and one Sn(5) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Sn(2), one Sn(3), and one Sn(6) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Sn(3), one Sn(4), and one Sn(5) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(4), and one Sn(6) atom. is represented by the CIF card [CIF]
data_Sn3(HO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.924
_cell_length_b   7.924
_cell_length_c   9.085
_cell_angle_alpha   89.938
_cell_angle_beta   89.938
_cell_angle_gamma   90.010
_symmetry_Int_Tables_number   1
_cell_volume   570.422
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.196  0.110  0.505  1.0
  Sn  Sn1  1  0.696  0.371  0.002  1.0
  Sn  Sn2  1  0.786  0.872  0.509  1.0
  Sn  Sn3  1  0.286  0.610  0.997  1.0
  Sn  Sn4  1  0.371  0.696  0.502  1.0
  Sn  Sn5  1  0.110  0.196  0.005  1.0
  Sn  Sn6  1  0.610  0.286  0.497  1.0
  Sn  Sn7  1  0.872  0.786  0.009  1.0
  Sn  Sn8  1  0.489  0.994  0.780  1.0
  Sn  Sn9  1  0.988  0.492  0.726  1.0
  Sn  Sn10  1  0.492  0.988  0.226  1.0
  Sn  Sn11  1  0.994  0.489  0.280  1.0
  H  H12  1  0.327  0.316  0.737  1.0
  H  H13  1  0.827  0.169  0.766  1.0
  H  H14  1  0.651  0.670  0.744  1.0
  H  H15  1  0.151  0.816  0.766  1.0
  H  H16  1  0.169  0.827  0.266  1.0
  H  H17  1  0.316  0.327  0.237  1.0
  H  H18  1  0.816  0.151  0.266  1.0
  H  H19  1  0.670  0.651  0.244  1.0
  O  O20  1  0.380  0.237  0.668  1.0
  O  O21  1  0.879  0.247  0.836  1.0
  O  O22  1  0.600  0.748  0.673  1.0
  O  O23  1  0.099  0.737  0.836  1.0
  O  O24  1  0.247  0.879  0.336  1.0
  O  O25  1  0.237  0.380  0.168  1.0
  O  O26  1  0.737  0.099  0.336  1.0
  O  O27  1  0.748  0.600  0.173  1.0
  O  O28  1  0.306  0.911  0.625  1.0
  O  O29  1  0.806  0.572  0.883  1.0
  O  O30  1  0.674  0.073  0.625  1.0
  O  O31  1  0.174  0.411  0.879  1.0
  O  O32  1  0.572  0.806  0.383  1.0
  O  O33  1  0.911  0.306  0.125  1.0
  O  O34  1  0.411  0.174  0.379  1.0
  O  O35  1  0.073  0.674  0.125  1.0
[/CIF]
.