The structure described by Co3(AsO4)2 crystallizes in the triclinic P1 space group. There are nine inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(20), one O(3), one O(6), and one O(8) atom to form distorted CoO5 square pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(6)O4 tetrahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one Co(5)O5 trigonal bipyramid,  a cornercorner with one Co(7)O5 trigonal bipyramid, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Co site, Co(2) is bonded to one O(13), one O(22), one O(4), one O(5), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one As(6)O5 trigonal bipyramid,  an edgeedge with one Co(3)O5 square pyramid,  an edgeedge with one As(3)O4 tetrahedra, and  an edgeedge with one Co(9)O5 trigonal bipyramid. In the third Co site, Co(3) is bonded to one O(10), one O(11), one O(12), one O(13), and one O(4) atom to form CoO5 square pyramids that share  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Co(6)O4 tetrahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one As(6)O5 trigonal bipyramid, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the fourth Co site, Co(4) is bonded to one O(15), one O(17), one O(19), one O(7), and one O(9) atom to form distorted CoO5 square pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one Co(7)O5 trigonal bipyramid,  a cornercorner with one As(6)O5 trigonal bipyramid,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 44°. In the fifth Co site, Co(5) is bonded to one O(15), one O(16), one O(24), one O(8), and one O(9) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one As(6)O5 trigonal bipyramid,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(4)O5 square pyramid,  an edgeedge with one Co(6)O4 tetrahedra, and  an edgeedge with one Co(9)O5 trigonal bipyramid. In the sixth Co site, Co(6) is bonded to one O(10), one O(16), one O(23), and one O(8) atom to form distorted CoO4 tetrahedra that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one Co(9)O5 trigonal bipyramid,  a cornercorner with one As(6)O5 trigonal bipyramid, and  an edgeedge with one Co(5)O5 trigonal bipyramid. In the seventh Co site, Co(7) is bonded to one O(14), one O(17), one O(2), one O(20), and one O(21) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra, and  a cornercorner with one Co(9)O5 trigonal bipyramid. In the eighth Co site, Co(8) is bonded to one O(1), one O(11), one O(15), one O(19), one O(24), and one O(3) atom to form distorted CoO6 octahedra that share  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one Co(9)O5 trigonal bipyramid,  an edgeedge with one Co(1)O5 square pyramid,  an edgeedge with one Co(4)O5 square pyramid,  an edgeedge with one As(1)O4 tetrahedra,  an edgeedge with one Co(5)O5 trigonal bipyramid, and  an edgeedge with one As(6)O5 trigonal bipyramid. In the ninth Co site, Co(9) is bonded to one O(16), one O(21), one O(22), one O(24), and one O(5) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Co(6)O4 tetrahedra,  a cornercorner with one Co(7)O5 trigonal bipyramid,  a cornercorner with one As(6)O5 trigonal bipyramid,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 54°. There are six inequivalent As sites. In the first As site, As(1) is bonded to one O(11), one O(2), one O(3), and one O(9) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one Co(5)O5 trigonal bipyramid,  a cornercorner with one Co(7)O5 trigonal bipyramid, and  an edgeedge with one Co(8)O6 octahedra. In the second As site, As(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(10), and one O(5) atom. In the third As site, As(3) is bonded to one O(13), one O(14), one O(15), and one O(6) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one Co(5)O5 trigonal bipyramid,  a cornercorner with one Co(7)O5 trigonal bipyramid, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. In the fourth As site, As(4) is bonded in a distorted trigonal non-coplanar geometry to one O(12), one O(17), and one O(7) atom. In the fifth As site, As(5) is bonded in a trigonal non-coplanar geometry to one O(18), one O(20), and one O(22) atom. In the sixth As site, As(6) is bonded to one O(18), one O(19), one O(23), one O(24), and one O(4) atom to form distorted AsO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one Co(6)O4 tetrahedra,  a cornercorner with one Co(5)O5 trigonal bipyramid,  a cornercorner with one Co(9)O5 trigonal bipyramid, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles are 46°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Co(1), one Co(8), and one As(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(7) and one As(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Co(1), one Co(8), and one As(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Co(2), one Co(3), and one As(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(2), one Co(9), and one As(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one As(3) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Co(2), one Co(4), and one As(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one Co(6) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Co(4), one Co(5), and one As(1) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Co(3), one Co(6), and one As(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(8), and one As(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Co(3) and one As(4) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Co(2), one Co(3), and one As(3) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Co(7) and one As(3) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Co(4), one Co(5), one Co(8), and one As(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal non-coplanar geometry to one Co(5), one Co(6), and one Co(9) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Co(4), one Co(7), and one As(4) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one As(5) and one As(6) atom. In the nineteenth O site, O(19) is bonded in a trigonal non-coplanar geometry to one Co(4), one Co(8), and one As(6) atom. In the twentieth O site, O(20) is bonded in a trigonal planar geometry to one Co(1), one Co(7), and one As(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Co(7) and one Co(9) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(9), and one As(5) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Co(6) and one As(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal pyramidal geometry to one Co(5), one Co(8), one Co(9), and one As(6) atom. is represented by the CIF card [CIF]
data_Co3(AsO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.502
_cell_length_b   7.713
_cell_length_c   9.710
_cell_angle_alpha   110.796
_cell_angle_beta   107.947
_cell_angle_gamma   92.160
_symmetry_Int_Tables_number   1
_cell_volume   492.858
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.166  0.608  0.754  1.0
  Co  Co1  1  0.191  0.216  0.414  1.0
  Co  Co2  1  0.849  0.911  0.246  1.0
  Co  Co3  1  0.584  0.160  0.732  1.0
  Co  Co4  1  0.417  0.405  0.995  1.0
  Co  Co5  1  0.117  0.561  0.078  1.0
  Co  Co6  1  0.790  0.755  0.603  1.0
  Co  Co7  1  0.476  0.980  0.936  1.0
  Co  Co8  1  0.456  0.393  0.308  1.0
  As  As9  1  0.639  0.649  0.858  1.0
  As  As10  1  0.101  0.978  0.053  1.0
  As  As11  1  0.106  0.132  0.646  1.0
  As  As12  1  0.485  0.947  0.404  1.0
  As  As13  1  0.122  0.642  0.419  1.0
  As  As14  1  0.820  0.288  0.121  1.0
  O  O15  1  0.236  0.874  0.934  1.0
  O  O16  1  0.827  0.691  0.802  1.0
  O  O17  1  0.430  0.692  0.748  1.0
  O  O18  1  0.928  0.170  0.246  1.0
  O  O19  1  0.290  0.128  0.238  1.0
  O  O20  1  0.115  0.331  0.597  1.0
  O  O21  1  0.451  0.183  0.525  1.0
  O  O22  1  0.214  0.497  0.907  1.0
  O  O23  1  0.621  0.438  0.887  1.0
  O  O24  1  0.056  0.802  0.134  1.0
  O  O25  1  0.649  0.819  0.039  1.0
  O  O26  1  0.696  0.974  0.369  1.0
  O  O27  1  0.098  0.992  0.450  1.0
  O  O28  1  0.931  0.066  0.701  1.0
  O  O29  1  0.331  0.147  0.786  1.0
  O  O30  1  0.379  0.542  0.180  1.0
  O  O31  1  0.571  0.894  0.578  1.0
  O  O32  1  0.876  0.537  0.261  1.0
  O  O33  1  0.708  0.098  0.926  1.0
  O  O34  1  0.043  0.692  0.582  1.0
  O  O35  1  0.657  0.504  0.465  1.0
  O  O36  1  0.252  0.449  0.409  1.0
  O  O37  1  0.003  0.334  0.049  1.0
  O  O38  1  0.568  0.272  0.119  1.0
[/CIF]
.
The structure described by Co3(AsO4)2 crystallizes in the triclinic P1 space group. There are nine inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(20), one O(3), one O(6), and one O(8) atom to form distorted CoO5 square pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(6)O4 tetrahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one Co(5)O5 trigonal bipyramid,  a cornercorner with one Co(7)O5 trigonal bipyramid, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Co site, Co(2) is bonded to one O(13), one O(22), one O(4), one O(5), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one As(6)O5 trigonal bipyramid,  an edgeedge with one Co(3)O5 square pyramid,  an edgeedge with one As(3)O4 tetrahedra, and  an edgeedge with one Co(9)O5 trigonal bipyramid. In the third Co site, Co(3) is bonded to one O(10), one O(11), one O(12), one O(13), and one O(4) atom to form CoO5 square pyramids that share  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Co(6)O4 tetrahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one As(6)O5 trigonal bipyramid, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the fourth Co site, Co(4) is bonded to one O(15), one O(17), one O(19), one O(7), and one O(9) atom to form distorted CoO5 square pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one Co(7)O5 trigonal bipyramid,  a cornercorner with one As(6)O5 trigonal bipyramid,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 44°. In the fifth Co site, Co(5) is bonded to one O(15), one O(16), one O(24), one O(8), and one O(9) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one As(6)O5 trigonal bipyramid,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(4)O5 square pyramid,  an edgeedge with one Co(6)O4 tetrahedra, and  an edgeedge with one Co(9)O5 trigonal bipyramid. In the sixth Co site, Co(6) is bonded to one O(10), one O(16), one O(23), and one O(8) atom to form distorted CoO4 tetrahedra that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one Co(9)O5 trigonal bipyramid,  a cornercorner with one As(6)O5 trigonal bipyramid, and  an edgeedge with one Co(5)O5 trigonal bipyramid. In the seventh Co site, Co(7) is bonded to one O(14), one O(17), one O(2), one O(20), and one O(21) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra, and  a cornercorner with one Co(9)O5 trigonal bipyramid. In the eighth Co site, Co(8) is bonded to one O(1), one O(11), one O(15), one O(19), one O(24), and one O(3) atom to form distorted CoO6 octahedra that share  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one Co(9)O5 trigonal bipyramid,  an edgeedge with one Co(1)O5 square pyramid,  an edgeedge with one Co(4)O5 square pyramid,  an edgeedge with one As(1)O4 tetrahedra,  an edgeedge with one Co(5)O5 trigonal bipyramid, and  an edgeedge with one As(6)O5 trigonal bipyramid. In the ninth Co site, Co(9) is bonded to one O(16), one O(21), one O(22), one O(24), and one O(5) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Co(6)O4 tetrahedra,  a cornercorner with one Co(7)O5 trigonal bipyramid,  a cornercorner with one As(6)O5 trigonal bipyramid,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 54°. There are six inequivalent As sites. In the first As site, As(1) is bonded to one O(11), one O(2), one O(3), and one O(9) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one Co(5)O5 trigonal bipyramid,  a cornercorner with one Co(7)O5 trigonal bipyramid, and  an edgeedge with one Co(8)O6 octahedra. In the second As site, As(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(10), and one O(5) atom. In the third As site, As(3) is bonded to one O(13), one O(14), one O(15), and one O(6) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(8)O6 octahedra,  a cornercorner with one Co(1)O5 square pyramid,  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one Co(5)O5 trigonal bipyramid,  a cornercorner with one Co(7)O5 trigonal bipyramid, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. In the fourth As site, As(4) is bonded in a distorted trigonal non-coplanar geometry to one O(12), one O(17), and one O(7) atom. In the fifth As site, As(5) is bonded in a trigonal non-coplanar geometry to one O(18), one O(20), and one O(22) atom. In the sixth As site, As(6) is bonded to one O(18), one O(19), one O(23), one O(24), and one O(4) atom to form distorted AsO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O5 square pyramid,  a cornercorner with one Co(4)O5 square pyramid,  a cornercorner with one Co(6)O4 tetrahedra,  a cornercorner with one Co(5)O5 trigonal bipyramid,  a cornercorner with one Co(9)O5 trigonal bipyramid, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles are 46°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Co(1), one Co(8), and one As(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(7) and one As(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Co(1), one Co(8), and one As(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Co(2), one Co(3), and one As(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(2), one Co(9), and one As(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one As(3) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Co(2), one Co(4), and one As(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one Co(6) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Co(4), one Co(5), and one As(1) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Co(3), one Co(6), and one As(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(8), and one As(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Co(3) and one As(4) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Co(2), one Co(3), and one As(3) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Co(7) and one As(3) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Co(4), one Co(5), one Co(8), and one As(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal non-coplanar geometry to one Co(5), one Co(6), and one Co(9) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Co(4), one Co(7), and one As(4) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one As(5) and one As(6) atom. In the nineteenth O site, O(19) is bonded in a trigonal non-coplanar geometry to one Co(4), one Co(8), and one As(6) atom. In the twentieth O site, O(20) is bonded in a trigonal planar geometry to one Co(1), one Co(7), and one As(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Co(7) and one Co(9) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(9), and one As(5) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Co(6) and one As(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal pyramidal geometry to one Co(5), one Co(8), one Co(9), and one As(6) atom. is represented by the CIF card [CIF]
data_Co3(AsO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.502
_cell_length_b   7.713
_cell_length_c   9.710
_cell_angle_alpha   110.796
_cell_angle_beta   107.947
_cell_angle_gamma   92.160
_symmetry_Int_Tables_number   1
_cell_volume   492.858
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.166  0.608  0.754  1.0
  Co  Co1  1  0.191  0.216  0.414  1.0
  Co  Co2  1  0.849  0.911  0.246  1.0
  Co  Co3  1  0.584  0.160  0.732  1.0
  Co  Co4  1  0.417  0.405  0.995  1.0
  Co  Co5  1  0.117  0.561  0.078  1.0
  Co  Co6  1  0.790  0.755  0.603  1.0
  Co  Co7  1  0.476  0.980  0.936  1.0
  Co  Co8  1  0.456  0.393  0.308  1.0
  As  As9  1  0.639  0.649  0.858  1.0
  As  As10  1  0.101  0.978  0.053  1.0
  As  As11  1  0.106  0.132  0.646  1.0
  As  As12  1  0.485  0.947  0.404  1.0
  As  As13  1  0.122  0.642  0.419  1.0
  As  As14  1  0.820  0.288  0.121  1.0
  O  O15  1  0.236  0.874  0.934  1.0
  O  O16  1  0.827  0.691  0.802  1.0
  O  O17  1  0.430  0.692  0.748  1.0
  O  O18  1  0.928  0.170  0.246  1.0
  O  O19  1  0.290  0.128  0.238  1.0
  O  O20  1  0.115  0.331  0.597  1.0
  O  O21  1  0.451  0.183  0.525  1.0
  O  O22  1  0.214  0.497  0.907  1.0
  O  O23  1  0.621  0.438  0.887  1.0
  O  O24  1  0.056  0.802  0.134  1.0
  O  O25  1  0.649  0.819  0.039  1.0
  O  O26  1  0.696  0.974  0.369  1.0
  O  O27  1  0.098  0.992  0.450  1.0
  O  O28  1  0.931  0.066  0.701  1.0
  O  O29  1  0.331  0.147  0.786  1.0
  O  O30  1  0.379  0.542  0.180  1.0
  O  O31  1  0.571  0.894  0.578  1.0
  O  O32  1  0.876  0.537  0.261  1.0
  O  O33  1  0.708  0.098  0.926  1.0
  O  O34  1  0.043  0.692  0.582  1.0
  O  O35  1  0.657  0.504  0.465  1.0
  O  O36  1  0.252  0.449  0.409  1.0
  O  O37  1  0.003  0.334  0.049  1.0
  O  O38  1  0.568  0.272  0.119  1.0
[/CIF]
.