The crystal structure described by Rb(O3I)3 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(10), one O(11), one O(12), one O(14), one O(15), one O(17), one O(5), one O(6), one O(8), and one O(9) atom. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(13), two equivalent O(16), two equivalent O(18), and two equivalent O(3) atoms. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one I(1) and one I(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one I(1) and one I(5) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one I(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(2) and one I(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1) and two equivalent I(2) atoms. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one I(2), and one I(3) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one I(2) and one I(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one I(2), and one I(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one I(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Rb(1), one I(3), and one I(4) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Rb(1) and one I(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Rb(1) and one I(4) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to two equivalent Rb(2) and one I(5) atom. In the fourteenth O site, O(14) is bonded in a 1-coordinate geometry to one Rb(1) and one I(5) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Rb(1) and one I(6) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one I(6) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Rb(1) and one I(6) atom. In the eighteenth O site, O(18) is bonded in a distorted L-shaped geometry to two equivalent Rb(2) atoms. There are six inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second I site, I(2) is bonded to one O(6), one O(7), one O(8), and two equivalent O(5) atoms to form distorted edge-sharing IO5 square pyramids. In the third I site, I(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(6), one O(8), and one O(9) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(10), one O(12), and one O(7) atom. In the fifth I site, I(5) is bonded in a 3-coordinate geometry to one O(1), one O(13), one O(14), and one O(2) atom. In the sixth I site, I(6) is bonded in a distorted trigonal non-coplanar geometry to one O(15), one O(16), and one O(17) atom. is represented by the CIF file [CIF]
data_Rb(IO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.114
_cell_length_b   7.490
_cell_length_c   18.379
_cell_angle_alpha   79.485
_cell_angle_beta   85.093
_cell_angle_gamma   71.515
_symmetry_Int_Tables_number   1
_cell_volume   912.863
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.542  0.091  0.172  1.0
  Rb  Rb1  1  0.458  0.909  0.828  1.0
  Rb  Rb2  1  0.305  0.827  0.495  1.0
  Rb  Rb3  1  0.695  0.173  0.505  1.0
  I  I4  1  0.978  0.492  0.605  1.0
  I  I5  1  0.022  0.508  0.395  1.0
  I  I6  1  0.107  0.138  0.031  1.0
  I  I7  1  0.893  0.862  0.969  1.0
  I  I8  1  0.520  0.639  0.075  1.0
  I  I9  1  0.480  0.361  0.925  1.0
  I  I10  1  0.060  0.566  0.166  1.0
  I  I11  1  0.940  0.434  0.834  1.0
  I  I12  1  0.517  0.597  0.305  1.0
  I  I13  1  0.483  0.403  0.695  1.0
  I  I14  1  0.021  0.949  0.699  1.0
  I  I15  1  0.979  0.051  0.301  1.0
  O  O16  1  0.775  0.612  0.298  1.0
  O  O17  1  0.225  0.388  0.702  1.0
  O  O18  1  0.808  0.488  0.686  1.0
  O  O19  1  0.192  0.512  0.314  1.0
  O  O20  1  0.981  0.739  0.594  1.0
  O  O21  1  0.019  0.261  0.406  1.0
  O  O22  1  0.802  0.518  0.531  1.0
  O  O23  1  0.198  0.482  0.469  1.0
  O  O24  1  0.153  0.997  0.954  1.0
  O  O25  1  0.847  0.003  0.046  1.0
  O  O26  1  0.344  0.219  0.009  1.0
  O  O27  1  0.656  0.781  0.991  1.0
  O  O28  1  0.052  0.595  0.064  1.0
  O  O29  1  0.948  0.405  0.936  1.0
  O  O30  1  0.243  0.947  0.102  1.0
  O  O31  1  0.757  0.053  0.898  1.0
  O  O32  1  0.655  0.397  0.063  1.0
  O  O33  1  0.345  0.603  0.937  1.0
  O  O34  1  0.338  0.528  0.166  1.0
  O  O35  1  0.662  0.472  0.834  1.0
  O  O36  1  0.652  0.672  0.150  1.0
  O  O37  1  0.348  0.328  0.850  1.0
  O  O38  1  0.075  0.316  0.186  1.0
  O  O39  1  0.925  0.684  0.814  1.0
  O  O40  1  0.521  0.531  0.406  1.0
  O  O41  1  0.479  0.469  0.594  1.0
  O  O42  1  0.383  0.853  0.296  1.0
  O  O43  1  0.617  0.147  0.704  1.0
  O  O44  1  0.049  0.067  0.773  1.0
  O  O45  1  0.951  0.933  0.227  1.0
  O  O46  1  0.021  0.123  0.614  1.0
  O  O47  1  0.979  0.877  0.386  1.0
  O  O48  1  0.290  0.794  0.694  1.0
  O  O49  1  0.710  0.206  0.306  1.0
  O  O50  1  0.513  0.082  0.367  1.0
  O  O51  1  0.487  0.918  0.633  1.0
[/CIF]
.
The crystal structure described by Rb(O3I)3 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(10), one O(11), one O(12), one O(14), one O(15), one O(17), one O(5), one O(6), one O(8), and one O(9) atom. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(13), two equivalent O(16), two equivalent O(18), and two equivalent O(3) atoms. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one I(1) and one I(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one I(1) and one I(5) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one I(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(2) and one I(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1) and two equivalent I(2) atoms. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one I(2), and one I(3) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one I(2) and one I(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one I(2), and one I(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one I(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Rb(1), one I(3), and one I(4) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Rb(1) and one I(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Rb(1) and one I(4) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to two equivalent Rb(2) and one I(5) atom. In the fourteenth O site, O(14) is bonded in a 1-coordinate geometry to one Rb(1) and one I(5) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Rb(1) and one I(6) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one I(6) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Rb(1) and one I(6) atom. In the eighteenth O site, O(18) is bonded in a distorted L-shaped geometry to two equivalent Rb(2) atoms. There are six inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second I site, I(2) is bonded to one O(6), one O(7), one O(8), and two equivalent O(5) atoms to form distorted edge-sharing IO5 square pyramids. In the third I site, I(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(6), one O(8), and one O(9) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(10), one O(12), and one O(7) atom. In the fifth I site, I(5) is bonded in a 3-coordinate geometry to one O(1), one O(13), one O(14), and one O(2) atom. In the sixth I site, I(6) is bonded in a distorted trigonal non-coplanar geometry to one O(15), one O(16), and one O(17) atom. is represented by the CIF file [CIF]
data_Rb(IO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.114
_cell_length_b   7.490
_cell_length_c   18.379
_cell_angle_alpha   79.485
_cell_angle_beta   85.093
_cell_angle_gamma   71.515
_symmetry_Int_Tables_number   1
_cell_volume   912.863
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.542  0.091  0.172  1.0
  Rb  Rb1  1  0.458  0.909  0.828  1.0
  Rb  Rb2  1  0.305  0.827  0.495  1.0
  Rb  Rb3  1  0.695  0.173  0.505  1.0
  I  I4  1  0.978  0.492  0.605  1.0
  I  I5  1  0.022  0.508  0.395  1.0
  I  I6  1  0.107  0.138  0.031  1.0
  I  I7  1  0.893  0.862  0.969  1.0
  I  I8  1  0.520  0.639  0.075  1.0
  I  I9  1  0.480  0.361  0.925  1.0
  I  I10  1  0.060  0.566  0.166  1.0
  I  I11  1  0.940  0.434  0.834  1.0
  I  I12  1  0.517  0.597  0.305  1.0
  I  I13  1  0.483  0.403  0.695  1.0
  I  I14  1  0.021  0.949  0.699  1.0
  I  I15  1  0.979  0.051  0.301  1.0
  O  O16  1  0.775  0.612  0.298  1.0
  O  O17  1  0.225  0.388  0.702  1.0
  O  O18  1  0.808  0.488  0.686  1.0
  O  O19  1  0.192  0.512  0.314  1.0
  O  O20  1  0.981  0.739  0.594  1.0
  O  O21  1  0.019  0.261  0.406  1.0
  O  O22  1  0.802  0.518  0.531  1.0
  O  O23  1  0.198  0.482  0.469  1.0
  O  O24  1  0.153  0.997  0.954  1.0
  O  O25  1  0.847  0.003  0.046  1.0
  O  O26  1  0.344  0.219  0.009  1.0
  O  O27  1  0.656  0.781  0.991  1.0
  O  O28  1  0.052  0.595  0.064  1.0
  O  O29  1  0.948  0.405  0.936  1.0
  O  O30  1  0.243  0.947  0.102  1.0
  O  O31  1  0.757  0.053  0.898  1.0
  O  O32  1  0.655  0.397  0.063  1.0
  O  O33  1  0.345  0.603  0.937  1.0
  O  O34  1  0.338  0.528  0.166  1.0
  O  O35  1  0.662  0.472  0.834  1.0
  O  O36  1  0.652  0.672  0.150  1.0
  O  O37  1  0.348  0.328  0.850  1.0
  O  O38  1  0.075  0.316  0.186  1.0
  O  O39  1  0.925  0.684  0.814  1.0
  O  O40  1  0.521  0.531  0.406  1.0
  O  O41  1  0.479  0.469  0.594  1.0
  O  O42  1  0.383  0.853  0.296  1.0
  O  O43  1  0.617  0.147  0.704  1.0
  O  O44  1  0.049  0.067  0.773  1.0
  O  O45  1  0.951  0.933  0.227  1.0
  O  O46  1  0.021  0.123  0.614  1.0
  O  O47  1  0.979  0.877  0.386  1.0
  O  O48  1  0.290  0.794  0.694  1.0
  O  O49  1  0.710  0.206  0.306  1.0
  O  O50  1  0.513  0.082  0.367  1.0
  O  O51  1  0.487  0.918  0.633  1.0
[/CIF]
.