The structure described by RbTeOF4 crystallizes in the monoclinic Cc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one F(1), one F(6), one F(8), two equivalent F(2), and two equivalent F(3) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(1), one O(2), one F(1), one F(4), one F(8), two equivalent F(5), and two equivalent F(7) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a square pyramidal geometry to one O(2), one F(5), one F(6), one F(7), and one F(8) atom. In the second Te site, Te(2) is bonded in a square pyramidal geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Te(1) atom. There are eight inequivalent F sites. In the first F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one Te(1) atom. In the second F site, F(6) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one Te(1) atom. In the third F site, F(7) is bonded in a distorted trigonal planar geometry to two equivalent Rb(2) and one Te(1) atom. In the fourth F site, F(8) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1), one Rb(2), and one Te(1) atom. In the fifth F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the sixth F site, F(2) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one Te(2) atom. In the seventh F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one Te(2) atom. In the eighth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Rb(2) and one Te(2) atom. is represented by the CIF card [CIF]
data_RbTeOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.518
_cell_length_b   8.518
_cell_length_c   14.132
_cell_angle_alpha   85.369
_cell_angle_beta   85.369
_cell_angle_gamma   33.068
_symmetry_Int_Tables_number   1
_cell_volume   557.532
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.162  0.358  0.492  1.0
  Rb  Rb1  1  0.358  0.162  0.992  1.0
  Rb  Rb2  1  0.472  0.642  0.252  1.0
  Rb  Rb3  1  0.642  0.472  0.752  1.0
  Te  Te4  1  0.971  0.026  0.503  1.0
  Te  Te5  1  0.026  0.971  0.003  1.0
  Te  Te6  1  0.791  0.849  0.243  1.0
  Te  Te7  1  0.849  0.791  0.743  1.0
  O  O8  1  0.913  0.530  0.271  1.0
  O  O9  1  0.530  0.913  0.771  1.0
  O  O10  1  0.290  0.902  0.467  1.0
  O  O11  1  0.902  0.290  0.967  1.0
  F  F12  1  0.440  0.013  0.216  1.0
  F  F13  1  0.013  0.440  0.716  1.0
  F  F14  1  0.691  0.918  0.384  1.0
  F  F15  1  0.918  0.691  0.884  1.0
  F  F16  1  0.920  0.711  0.106  1.0
  F  F17  1  0.711  0.920  0.606  1.0
  F  F18  1  0.207  0.541  0.270  1.0
  F  F19  1  0.541  0.207  0.770  1.0
  F  F20  1  0.902  0.116  0.138  1.0
  F  F21  1  0.116  0.902  0.638  1.0
  F  F22  1  0.269  0.609  0.483  1.0
  F  F23  1  0.609  0.269  0.983  1.0
  F  F24  1  0.915  0.118  0.360  1.0
  F  F25  1  0.118  0.915  0.860  1.0
  F  F26  1  0.394  0.782  0.029  1.0
  F  F27  1  0.782  0.394  0.529  1.0
[/CIF]
.
The structure described by RbTeOF4 crystallizes in the monoclinic Cc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one F(1), one F(6), one F(8), two equivalent F(2), and two equivalent F(3) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(1), one O(2), one F(1), one F(4), one F(8), two equivalent F(5), and two equivalent F(7) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a square pyramidal geometry to one O(2), one F(5), one F(6), one F(7), and one F(8) atom. In the second Te site, Te(2) is bonded in a square pyramidal geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Te(1) atom. There are eight inequivalent F sites. In the first F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one Te(1) atom. In the second F site, F(6) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one Te(1) atom. In the third F site, F(7) is bonded in a distorted trigonal planar geometry to two equivalent Rb(2) and one Te(1) atom. In the fourth F site, F(8) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1), one Rb(2), and one Te(1) atom. In the fifth F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the sixth F site, F(2) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one Te(2) atom. In the seventh F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one Te(2) atom. In the eighth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Rb(2) and one Te(2) atom. is represented by the CIF card [CIF]
data_RbTeOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.518
_cell_length_b   8.518
_cell_length_c   14.132
_cell_angle_alpha   85.369
_cell_angle_beta   85.369
_cell_angle_gamma   33.068
_symmetry_Int_Tables_number   1
_cell_volume   557.532
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.162  0.358  0.492  1.0
  Rb  Rb1  1  0.358  0.162  0.992  1.0
  Rb  Rb2  1  0.472  0.642  0.252  1.0
  Rb  Rb3  1  0.642  0.472  0.752  1.0
  Te  Te4  1  0.971  0.026  0.503  1.0
  Te  Te5  1  0.026  0.971  0.003  1.0
  Te  Te6  1  0.791  0.849  0.243  1.0
  Te  Te7  1  0.849  0.791  0.743  1.0
  O  O8  1  0.913  0.530  0.271  1.0
  O  O9  1  0.530  0.913  0.771  1.0
  O  O10  1  0.290  0.902  0.467  1.0
  O  O11  1  0.902  0.290  0.967  1.0
  F  F12  1  0.440  0.013  0.216  1.0
  F  F13  1  0.013  0.440  0.716  1.0
  F  F14  1  0.691  0.918  0.384  1.0
  F  F15  1  0.918  0.691  0.884  1.0
  F  F16  1  0.920  0.711  0.106  1.0
  F  F17  1  0.711  0.920  0.606  1.0
  F  F18  1  0.207  0.541  0.270  1.0
  F  F19  1  0.541  0.207  0.770  1.0
  F  F20  1  0.902  0.116  0.138  1.0
  F  F21  1  0.116  0.902  0.638  1.0
  F  F22  1  0.269  0.609  0.483  1.0
  F  F23  1  0.609  0.269  0.983  1.0
  F  F24  1  0.915  0.118  0.360  1.0
  F  F25  1  0.118  0.915  0.860  1.0
  F  F26  1  0.394  0.782  0.029  1.0
  F  F27  1  0.782  0.394  0.529  1.0
[/CIF]
.