The material described by Ce4ZrO10 is Fluorite-derived structured and crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(3) atoms. In the second Ce site, Ce(2) is bonded in a body-centered cubic geometry to four equivalent O(2) and four equivalent O(3) atoms. Zr(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ce(1) and two equivalent Zr(1) atoms to form OCe2Zr2 tetrahedra that share corners with six equivalent O(3)Ce4 tetrahedra, corners with ten equivalent O(1)Ce2Zr2 tetrahedra,  an edgeedge with one O(3)Ce4 tetrahedra, and edges with five equivalent O(1)Ce2Zr2 tetrahedra. In the second O site, O(2) is bonded to four equivalent Ce(2) atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra. In the third O site, O(3) is bonded to two equivalent Ce(1) and two equivalent Ce(2) atoms to form OCe4 tetrahedra that share corners with four equivalent O(3)Ce4 tetrahedra, corners with six equivalent O(1)Ce2Zr2 tetrahedra, corners with six equivalent O(2)Ce4 tetrahedra,  an edgeedge with one O(1)Ce2Zr2 tetrahedra,  an edgeedge with one O(2)Ce4 tetrahedra, and edges with four equivalent O(3)Ce4 tetrahedra. is represented by the CIF card [CIF]
data_Ce4ZrO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.813
_cell_length_b   13.813
_cell_length_c   13.813
_cell_angle_alpha   164.124
_cell_angle_beta   164.124
_cell_angle_gamma   22.525
_symmetry_Int_Tables_number   1
_cell_volume   197.199
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.403  0.403  0.000  1.0
  Ce  Ce1  1  0.801  0.801  0.000  1.0
  Ce  Ce2  1  0.199  0.199  0.000  1.0
  Ce  Ce3  1  0.597  0.597  0.000  1.0
  Zr  Zr4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.546  0.046  0.500  1.0
  O  O6  1  0.750  0.250  0.500  1.0
  O  O7  1  0.148  0.648  0.500  1.0
  O  O8  1  0.954  0.454  0.500  1.0
  O  O9  1  0.352  0.852  0.500  1.0
  O  O10  1  0.454  0.954  0.500  1.0
  O  O11  1  0.648  0.148  0.500  1.0
  O  O12  1  0.046  0.546  0.500  1.0
  O  O13  1  0.852  0.352  0.500  1.0
  O  O14  1  0.250  0.750  0.500  1.0
[/CIF]
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The material described by Ce4ZrO10 is Fluorite-derived structured and crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(3) atoms. In the second Ce site, Ce(2) is bonded in a body-centered cubic geometry to four equivalent O(2) and four equivalent O(3) atoms. Zr(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ce(1) and two equivalent Zr(1) atoms to form OCe2Zr2 tetrahedra that share corners with six equivalent O(3)Ce4 tetrahedra, corners with ten equivalent O(1)Ce2Zr2 tetrahedra,  an edgeedge with one O(3)Ce4 tetrahedra, and edges with five equivalent O(1)Ce2Zr2 tetrahedra. In the second O site, O(2) is bonded to four equivalent Ce(2) atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra. In the third O site, O(3) is bonded to two equivalent Ce(1) and two equivalent Ce(2) atoms to form OCe4 tetrahedra that share corners with four equivalent O(3)Ce4 tetrahedra, corners with six equivalent O(1)Ce2Zr2 tetrahedra, corners with six equivalent O(2)Ce4 tetrahedra,  an edgeedge with one O(1)Ce2Zr2 tetrahedra,  an edgeedge with one O(2)Ce4 tetrahedra, and edges with four equivalent O(3)Ce4 tetrahedra. is represented by the CIF card [CIF]
data_Ce4ZrO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.813
_cell_length_b   13.813
_cell_length_c   13.813
_cell_angle_alpha   164.124
_cell_angle_beta   164.124
_cell_angle_gamma   22.525
_symmetry_Int_Tables_number   1
_cell_volume   197.199
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.403  0.403  0.000  1.0
  Ce  Ce1  1  0.801  0.801  0.000  1.0
  Ce  Ce2  1  0.199  0.199  0.000  1.0
  Ce  Ce3  1  0.597  0.597  0.000  1.0
  Zr  Zr4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.546  0.046  0.500  1.0
  O  O6  1  0.750  0.250  0.500  1.0
  O  O7  1  0.148  0.648  0.500  1.0
  O  O8  1  0.954  0.454  0.500  1.0
  O  O9  1  0.352  0.852  0.500  1.0
  O  O10  1  0.454  0.954  0.500  1.0
  O  O11  1  0.648  0.148  0.500  1.0
  O  O12  1  0.046  0.546  0.500  1.0
  O  O13  1  0.852  0.352  0.500  1.0
  O  O14  1  0.250  0.750  0.500  1.0
[/CIF]
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