The material structure described by KCNS crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 6-coordinate geometry to one C(1), one N(1), and four equivalent S(1) atoms. C(1) is bonded in a distorted single-bond geometry to one K(1), one N(1), and one S(1) atom. N(1) is bonded in a bent 120 degrees geometry to one K(1) and one C(1) atom. S(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one C(1) atom. is represented by the CIF card [CIF]
data_KCSN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.480
_cell_length_b   6.516
_cell_length_c   11.139
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   470.286
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.772  0.887  1.0
  K  K1  1  0.250  0.228  0.387  1.0
  K  K2  1  0.750  0.772  0.613  1.0
  K  K3  1  0.750  0.228  0.113  1.0
  C  C4  1  0.250  0.252  0.985  1.0
  C  C5  1  0.250  0.748  0.485  1.0
  C  C6  1  0.750  0.252  0.515  1.0
  C  C7  1  0.750  0.748  0.015  1.0
  S  S8  1  0.250  0.900  0.604  1.0
  S  S9  1  0.250  0.100  0.104  1.0
  S  S10  1  0.750  0.900  0.896  1.0
  S  S11  1  0.750  0.100  0.396  1.0
  N  N12  1  0.250  0.354  0.897  1.0
  N  N13  1  0.250  0.646  0.397  1.0
  N  N14  1  0.750  0.354  0.603  1.0
  N  N15  1  0.750  0.646  0.103  1.0
[/CIF]
.
The material structure described by KCNS crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 6-coordinate geometry to one C(1), one N(1), and four equivalent S(1) atoms. C(1) is bonded in a distorted single-bond geometry to one K(1), one N(1), and one S(1) atom. N(1) is bonded in a bent 120 degrees geometry to one K(1) and one C(1) atom. S(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one C(1) atom. is represented by the CIF card [CIF]
data_KCSN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.480
_cell_length_b   6.516
_cell_length_c   11.139
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   470.286
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.772  0.887  1.0
  K  K1  1  0.250  0.228  0.387  1.0
  K  K2  1  0.750  0.772  0.613  1.0
  K  K3  1  0.750  0.228  0.113  1.0
  C  C4  1  0.250  0.252  0.985  1.0
  C  C5  1  0.250  0.748  0.485  1.0
  C  C6  1  0.750  0.252  0.515  1.0
  C  C7  1  0.750  0.748  0.015  1.0
  S  S8  1  0.250  0.900  0.604  1.0
  S  S9  1  0.250  0.100  0.104  1.0
  S  S10  1  0.750  0.900  0.896  1.0
  S  S11  1  0.750  0.100  0.396  1.0
  N  N12  1  0.250  0.354  0.897  1.0
  N  N13  1  0.250  0.646  0.397  1.0
  N  N14  1  0.750  0.354  0.603  1.0
  N  N15  1  0.750  0.646  0.103  1.0
[/CIF]
.