The compound described by Fe(RhSe2)2 crystallizes in the monoclinic C2/m space group. Fe(1) is bonded to two equivalent Rh(1), two equivalent Se(2), and four equivalent Se(1) atoms to form distorted edge-sharing FeRh2Se6 octahedra. Rh(1) is bonded in a 7-coordinate geometry to one Fe(1), three equivalent Se(1), and three equivalent Se(2) atoms. There are two inequivalent Se sites. In the first Se site, Se(2) is bonded in a rectangular see-saw-like geometry to one Fe(1) and three equivalent Rh(1) atoms. In the second Se site, Se(1) is bonded in a 5-coordinate geometry to two equivalent Fe(1) and three equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Fe(RhSe2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.532
_cell_length_b   6.532
_cell_length_c   6.482
_cell_angle_alpha   60.828
_cell_angle_beta   60.828
_cell_angle_gamma   33.267
_symmetry_Int_Tables_number   1
_cell_volume   130.624
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.263  0.263  0.720  1.0
  Rh  Rh2  1  0.737  0.737  0.280  1.0
  Se  Se3  1  0.367  0.367  0.975  1.0
  Se  Se4  1  0.633  0.633  0.025  1.0
  Se  Se5  1  0.119  0.119  0.554  1.0
  Se  Se6  1  0.881  0.881  0.446  1.0
[/CIF]
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The compound described by Fe(RhSe2)2 crystallizes in the monoclinic C2/m space group. Fe(1) is bonded to two equivalent Rh(1), two equivalent Se(2), and four equivalent Se(1) atoms to form distorted edge-sharing FeRh2Se6 octahedra. Rh(1) is bonded in a 7-coordinate geometry to one Fe(1), three equivalent Se(1), and three equivalent Se(2) atoms. There are two inequivalent Se sites. In the first Se site, Se(2) is bonded in a rectangular see-saw-like geometry to one Fe(1) and three equivalent Rh(1) atoms. In the second Se site, Se(1) is bonded in a 5-coordinate geometry to two equivalent Fe(1) and three equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Fe(RhSe2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.532
_cell_length_b   6.532
_cell_length_c   6.482
_cell_angle_alpha   60.828
_cell_angle_beta   60.828
_cell_angle_gamma   33.267
_symmetry_Int_Tables_number   1
_cell_volume   130.624
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.263  0.263  0.720  1.0
  Rh  Rh2  1  0.737  0.737  0.280  1.0
  Se  Se3  1  0.367  0.367  0.975  1.0
  Se  Se4  1  0.633  0.633  0.025  1.0
  Se  Se5  1  0.119  0.119  0.554  1.0
  Se  Se6  1  0.881  0.881  0.446  1.0
[/CIF]
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