The material described by Co(ReO6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Co(ReO6)2 cluster. Re(1) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form ReO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. Co(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Re(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Co(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Re(1) and one Co(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Co(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(ReO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.539
_cell_length_b   7.085
_cell_length_c   7.160
_cell_angle_alpha   64.492
_cell_angle_beta   69.400
_cell_angle_gamma   71.235
_symmetry_Int_Tables_number   1
_cell_volume   274.474
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.000  0.000  1.0
  Re  Re1  1  0.906  0.679  0.718  1.0
  Re  Re2  1  0.094  0.321  0.282  1.0
  O  O3  1  0.187  0.690  0.612  1.0
  O  O4  1  0.813  0.310  0.388  1.0
  O  O5  1  0.521  0.264  0.820  1.0
  O  O6  1  0.479  0.736  0.180  1.0
  O  O7  1  0.875  0.426  0.908  1.0
  O  O8  1  0.125  0.574  0.092  1.0
  O  O9  1  0.772  0.892  0.827  1.0
  O  O10  1  0.228  0.108  0.173  1.0
  O  O11  1  0.347  0.916  0.899  1.0
  O  O12  1  0.653  0.084  0.101  1.0
  O  O13  1  0.796  0.721  0.511  1.0
  O  O14  1  0.204  0.279  0.489  1.0
[/CIF]
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The material described by Co(ReO6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Co(ReO6)2 cluster. Re(1) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form ReO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. Co(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Re(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Co(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Re(1) and one Co(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Co(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(ReO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.539
_cell_length_b   7.085
_cell_length_c   7.160
_cell_angle_alpha   64.492
_cell_angle_beta   69.400
_cell_angle_gamma   71.235
_symmetry_Int_Tables_number   1
_cell_volume   274.474
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.000  0.000  1.0
  Re  Re1  1  0.906  0.679  0.718  1.0
  Re  Re2  1  0.094  0.321  0.282  1.0
  O  O3  1  0.187  0.690  0.612  1.0
  O  O4  1  0.813  0.310  0.388  1.0
  O  O5  1  0.521  0.264  0.820  1.0
  O  O6  1  0.479  0.736  0.180  1.0
  O  O7  1  0.875  0.426  0.908  1.0
  O  O8  1  0.125  0.574  0.092  1.0
  O  O9  1  0.772  0.892  0.827  1.0
  O  O10  1  0.228  0.108  0.173  1.0
  O  O11  1  0.347  0.916  0.899  1.0
  O  O12  1  0.653  0.084  0.101  1.0
  O  O13  1  0.796  0.721  0.511  1.0
  O  O14  1  0.204  0.279  0.489  1.0
[/CIF]
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