The compound described by MnAlBiO5 crystallizes in the orthorhombic Pbam space group. Mn(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with four equivalent Al(1)O5 trigonal bipyramids and edges with two equivalent Mn(1)O6 octahedra. Al(1) is bonded to one O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted AlO5 trigonal bipyramids that share corners with four equivalent Mn(1)O6 octahedra and  an edgeedge with one Al(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 48-51°. Bi(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent Mn(1) and one Al(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Al(1) and two equivalent Bi(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Mn(1), one Al(1), and two equivalent Bi(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Mn(1) and two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_MnAlBiO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.777
_cell_length_b   7.487
_cell_length_c   8.531
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   368.944
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.243  0.000  0.500  1.0
  Mn  Mn1  1  0.757  0.000  0.500  1.0
  Mn  Mn2  1  0.757  0.500  0.000  1.0
  Mn  Mn3  1  0.243  0.500  0.000  1.0
  Al  Al4  1  0.000  0.112  0.142  1.0
  Al  Al5  1  0.000  0.888  0.858  1.0
  Al  Al6  1  0.000  0.388  0.642  1.0
  Al  Al7  1  0.000  0.612  0.358  1.0
  Bi  Bi8  1  0.500  0.359  0.335  1.0
  Bi  Bi9  1  0.500  0.641  0.665  1.0
  Bi  Bi10  1  0.500  0.141  0.835  1.0
  Bi  Bi11  1  0.500  0.859  0.165  1.0
  O  O12  1  0.000  0.345  0.075  1.0
  O  O13  1  0.000  0.655  0.925  1.0
  O  O14  1  0.000  0.155  0.575  1.0
  O  O15  1  0.000  0.845  0.425  1.0
  O  O16  1  0.208  0.000  0.000  1.0
  O  O17  1  0.792  0.000  0.000  1.0
  O  O18  1  0.792  0.500  0.500  1.0
  O  O19  1  0.208  0.500  0.500  1.0
  O  O20  1  0.241  0.109  0.293  1.0
  O  O21  1  0.759  0.891  0.707  1.0
  O  O22  1  0.241  0.891  0.707  1.0
  O  O23  1  0.759  0.391  0.793  1.0
  O  O24  1  0.759  0.109  0.293  1.0
  O  O25  1  0.241  0.609  0.207  1.0
  O  O26  1  0.759  0.609  0.207  1.0
  O  O27  1  0.241  0.391  0.793  1.0
  O  O28  1  0.500  0.345  0.055  1.0
  O  O29  1  0.500  0.655  0.945  1.0
  O  O30  1  0.500  0.155  0.555  1.0
  O  O31  1  0.500  0.845  0.445  1.0
[/CIF]
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The compound described by MnAlBiO5 crystallizes in the orthorhombic Pbam space group. Mn(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with four equivalent Al(1)O5 trigonal bipyramids and edges with two equivalent Mn(1)O6 octahedra. Al(1) is bonded to one O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted AlO5 trigonal bipyramids that share corners with four equivalent Mn(1)O6 octahedra and  an edgeedge with one Al(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 48-51°. Bi(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent Mn(1) and one Al(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Al(1) and two equivalent Bi(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Mn(1), one Al(1), and two equivalent Bi(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Mn(1) and two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_MnAlBiO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.777
_cell_length_b   7.487
_cell_length_c   8.531
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   368.944
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.243  0.000  0.500  1.0
  Mn  Mn1  1  0.757  0.000  0.500  1.0
  Mn  Mn2  1  0.757  0.500  0.000  1.0
  Mn  Mn3  1  0.243  0.500  0.000  1.0
  Al  Al4  1  0.000  0.112  0.142  1.0
  Al  Al5  1  0.000  0.888  0.858  1.0
  Al  Al6  1  0.000  0.388  0.642  1.0
  Al  Al7  1  0.000  0.612  0.358  1.0
  Bi  Bi8  1  0.500  0.359  0.335  1.0
  Bi  Bi9  1  0.500  0.641  0.665  1.0
  Bi  Bi10  1  0.500  0.141  0.835  1.0
  Bi  Bi11  1  0.500  0.859  0.165  1.0
  O  O12  1  0.000  0.345  0.075  1.0
  O  O13  1  0.000  0.655  0.925  1.0
  O  O14  1  0.000  0.155  0.575  1.0
  O  O15  1  0.000  0.845  0.425  1.0
  O  O16  1  0.208  0.000  0.000  1.0
  O  O17  1  0.792  0.000  0.000  1.0
  O  O18  1  0.792  0.500  0.500  1.0
  O  O19  1  0.208  0.500  0.500  1.0
  O  O20  1  0.241  0.109  0.293  1.0
  O  O21  1  0.759  0.891  0.707  1.0
  O  O22  1  0.241  0.891  0.707  1.0
  O  O23  1  0.759  0.391  0.793  1.0
  O  O24  1  0.759  0.109  0.293  1.0
  O  O25  1  0.241  0.609  0.207  1.0
  O  O26  1  0.759  0.609  0.207  1.0
  O  O27  1  0.241  0.391  0.793  1.0
  O  O28  1  0.500  0.345  0.055  1.0
  O  O29  1  0.500  0.655  0.945  1.0
  O  O30  1  0.500  0.155  0.555  1.0
  O  O31  1  0.500  0.845  0.445  1.0
[/CIF]
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