The material described by Li2VMnP2(HO5)2 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(19), one O(3), one O(5), and one O(6) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one P(2)O4 tetrahedra, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 52-65°. In the second Li site, Li(2) is bonded to one O(1), one O(17), one O(3), one O(7), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-65°. In the third Li site, Li(3) is bonded to one O(12), one O(14), one O(18), one O(20), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Li(4)O5 square pyramid, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-64°. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(18), one O(2), and one O(20) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one P(3)O4 tetrahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 51-64°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(16), one O(17), one O(20), one O(4), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(4)O5 square pyramid,  an edgeedge with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 52-53°. In the second V site, V(2) is bonded to one O(10), one O(14), one O(16), one O(19), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(4)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(12), one O(13), one O(2), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(4)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 52-53°. In the second Mn site, Mn(2) is bonded to one O(14), one O(15), one O(18), one O(3), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(4)O5 square pyramid,  an edgeedge with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 52°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(3), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 38-56°. In the second P site, P(2) is bonded to one O(11), one O(19), one O(20), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(4)O5 square pyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 40-53°. In the third P site, P(3) is bonded to one O(1), one O(10), one O(15), and one O(2) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 39-53°. In the fourth P site, P(4) is bonded to one O(13), one O(17), one O(18), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(4)O5 square pyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 39-56°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(16) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one P(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(4), one Mn(1), and one P(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(3), one V(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Mn(1), and one H(4) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Li(2), one Mn(1), one Mn(2), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one V(2) and one P(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(2), one V(2), and one P(4) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one V(2) and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(3), one Mn(1), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(4) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Li(3), one V(2), one Mn(2), and one H(3) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Li(4), one Mn(2), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Li(4), one V(1), one V(2), and one H(1) atom. In the seventeenth O site, O(17) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one Mn(2), and one P(4) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(1), one V(2), and one P(2) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one V(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2MnVP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.956
_cell_length_b   7.496
_cell_length_c   7.863
_cell_angle_alpha   116.845
_cell_angle_beta   91.576
_cell_angle_gamma   90.782
_symmetry_Int_Tables_number   1
_cell_volume   365.512
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.161  0.585  0.763  1.0
  Li  Li1  1  0.341  0.914  0.740  1.0
  Li  Li2  1  0.659  0.089  0.261  1.0
  Li  Li3  1  0.838  0.413  0.235  1.0
  Mn  Mn4  1  0.251  0.750  0.249  1.0
  Mn  Mn5  1  0.502  0.500  0.501  1.0
  V  V6  1  0.999  1.000  0.001  1.0
  V  V7  1  0.748  0.251  0.751  1.0
  P  P8  1  0.591  0.727  0.961  1.0
  P  P9  1  0.097  0.227  0.459  1.0
  P  P10  1  0.907  0.775  0.541  1.0
  P  P11  1  0.405  0.271  0.040  1.0
  H  H12  1  0.043  0.321  0.981  1.0
  H  H13  1  0.545  0.813  0.483  1.0
  H  H14  1  0.456  0.185  0.517  1.0
  H  H15  1  0.956  0.679  0.017  1.0
  O  O16  1  0.054  0.838  0.713  1.0
  O  O17  1  0.012  0.693  0.348  1.0
  O  O18  1  0.440  0.670  0.796  1.0
  O  O19  1  0.718  0.907  0.981  1.0
  O  O20  1  0.076  0.756  0.027  1.0
  O  O21  1  0.221  0.409  0.477  1.0
  O  O22  1  0.425  0.736  0.475  1.0
  O  O23  1  0.721  0.549  0.932  1.0
  O  O24  1  0.504  0.188  0.843  1.0
  O  O25  1  0.776  0.951  0.568  1.0
  O  O26  1  0.227  0.053  0.434  1.0
  O  O27  1  0.491  0.810  0.159  1.0
  O  O28  1  0.276  0.447  0.067  1.0
  O  O29  1  0.578  0.261  0.528  1.0
  O  O30  1  0.782  0.593  0.519  1.0
  O  O31  1  0.921  0.243  0.969  1.0
  O  O32  1  0.279  0.092  0.023  1.0
  O  O33  1  0.558  0.329  0.205  1.0
  O  O34  1  0.993  0.309  0.651  1.0
  O  O35  1  0.948  0.164  0.287  1.0
[/CIF]
.
The material described by Li2VMnP2(HO5)2 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(19), one O(3), one O(5), and one O(6) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one P(2)O4 tetrahedra, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 52-65°. In the second Li site, Li(2) is bonded to one O(1), one O(17), one O(3), one O(7), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-65°. In the third Li site, Li(3) is bonded to one O(12), one O(14), one O(18), one O(20), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Li(4)O5 square pyramid, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-64°. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(18), one O(2), and one O(20) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one P(3)O4 tetrahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 51-64°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(16), one O(17), one O(20), one O(4), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(4)O5 square pyramid,  an edgeedge with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 52-53°. In the second V site, V(2) is bonded to one O(10), one O(14), one O(16), one O(19), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(4)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(12), one O(13), one O(2), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(4)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 52-53°. In the second Mn site, Mn(2) is bonded to one O(14), one O(15), one O(18), one O(3), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(4)O5 square pyramid,  an edgeedge with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 52°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(3), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 38-56°. In the second P site, P(2) is bonded to one O(11), one O(19), one O(20), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(4)O5 square pyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 40-53°. In the third P site, P(3) is bonded to one O(1), one O(10), one O(15), and one O(2) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 39-53°. In the fourth P site, P(4) is bonded to one O(13), one O(17), one O(18), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(4)O5 square pyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 39-56°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(16) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one P(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(4), one Mn(1), and one P(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(3), one V(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Mn(1), and one H(4) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Li(2), one Mn(1), one Mn(2), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one V(2) and one P(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(2), one V(2), and one P(4) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one V(2) and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(3), one Mn(1), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(4) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Li(3), one V(2), one Mn(2), and one H(3) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Li(4), one Mn(2), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Li(4), one V(1), one V(2), and one H(1) atom. In the seventeenth O site, O(17) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one Mn(2), and one P(4) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(1), one V(2), and one P(2) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one V(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2MnVP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.956
_cell_length_b   7.496
_cell_length_c   7.863
_cell_angle_alpha   116.845
_cell_angle_beta   91.576
_cell_angle_gamma   90.782
_symmetry_Int_Tables_number   1
_cell_volume   365.512
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.161  0.585  0.763  1.0
  Li  Li1  1  0.341  0.914  0.740  1.0
  Li  Li2  1  0.659  0.089  0.261  1.0
  Li  Li3  1  0.838  0.413  0.235  1.0
  Mn  Mn4  1  0.251  0.750  0.249  1.0
  Mn  Mn5  1  0.502  0.500  0.501  1.0
  V  V6  1  0.999  1.000  0.001  1.0
  V  V7  1  0.748  0.251  0.751  1.0
  P  P8  1  0.591  0.727  0.961  1.0
  P  P9  1  0.097  0.227  0.459  1.0
  P  P10  1  0.907  0.775  0.541  1.0
  P  P11  1  0.405  0.271  0.040  1.0
  H  H12  1  0.043  0.321  0.981  1.0
  H  H13  1  0.545  0.813  0.483  1.0
  H  H14  1  0.456  0.185  0.517  1.0
  H  H15  1  0.956  0.679  0.017  1.0
  O  O16  1  0.054  0.838  0.713  1.0
  O  O17  1  0.012  0.693  0.348  1.0
  O  O18  1  0.440  0.670  0.796  1.0
  O  O19  1  0.718  0.907  0.981  1.0
  O  O20  1  0.076  0.756  0.027  1.0
  O  O21  1  0.221  0.409  0.477  1.0
  O  O22  1  0.425  0.736  0.475  1.0
  O  O23  1  0.721  0.549  0.932  1.0
  O  O24  1  0.504  0.188  0.843  1.0
  O  O25  1  0.776  0.951  0.568  1.0
  O  O26  1  0.227  0.053  0.434  1.0
  O  O27  1  0.491  0.810  0.159  1.0
  O  O28  1  0.276  0.447  0.067  1.0
  O  O29  1  0.578  0.261  0.528  1.0
  O  O30  1  0.782  0.593  0.519  1.0
  O  O31  1  0.921  0.243  0.969  1.0
  O  O32  1  0.279  0.092  0.023  1.0
  O  O33  1  0.558  0.329  0.205  1.0
  O  O34  1  0.993  0.309  0.651  1.0
  O  O35  1  0.948  0.164  0.287  1.0
[/CIF]
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