The compound described by NaAgSO5 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a distorted trigonal pyramidal geometry to one O(1), one O(2), one O(3), and one O(4) atom. Ag(1) is bonded in a 4-coordinate geometry to one S(1), one O(2), one O(3), and one O(5) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one O(1), one O(2), and one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Na(1) and one S(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Ag(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Na(1), one Ag(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Na(1) and one O(5) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ag(1) and one O(4) atom. is represented by the CIF card [CIF]
data_NaAgSO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.456
_cell_length_b   6.007
_cell_length_c   8.651
_cell_angle_alpha   89.828
_cell_angle_beta   105.802
_cell_angle_gamma   91.907
_symmetry_Int_Tables_number   1
_cell_volume   272.674
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.445  0.270  0.712  1.0
  Na  Na1  1  0.555  0.730  0.288  1.0
  Ag  Ag2  1  0.804  0.751  0.968  1.0
  Ag  Ag3  1  0.196  0.249  0.032  1.0
  S  S4  1  0.664  0.244  0.121  1.0
  S  S5  1  0.336  0.756  0.879  1.0
  O  O6  1  0.775  0.433  0.234  1.0
  O  O7  1  0.225  0.567  0.766  1.0
  O  O8  1  0.755  0.025  0.195  1.0
  O  O9  1  0.245  0.975  0.805  1.0
  O  O10  1  0.769  0.272  0.971  1.0
  O  O11  1  0.231  0.728  0.029  1.0
  O  O12  1  0.729  0.899  0.572  1.0
  O  O13  1  0.271  0.101  0.428  1.0
  O  O14  1  0.685  0.732  0.651  1.0
  O  O15  1  0.315  0.268  0.349  1.0
[/CIF]
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The compound described by NaAgSO5 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a distorted trigonal pyramidal geometry to one O(1), one O(2), one O(3), and one O(4) atom. Ag(1) is bonded in a 4-coordinate geometry to one S(1), one O(2), one O(3), and one O(5) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one O(1), one O(2), and one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Na(1) and one S(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Ag(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Na(1), one Ag(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Na(1) and one O(5) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ag(1) and one O(4) atom. is represented by the CIF card [CIF]
data_NaAgSO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.456
_cell_length_b   6.007
_cell_length_c   8.651
_cell_angle_alpha   89.828
_cell_angle_beta   105.802
_cell_angle_gamma   91.907
_symmetry_Int_Tables_number   1
_cell_volume   272.674
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.445  0.270  0.712  1.0
  Na  Na1  1  0.555  0.730  0.288  1.0
  Ag  Ag2  1  0.804  0.751  0.968  1.0
  Ag  Ag3  1  0.196  0.249  0.032  1.0
  S  S4  1  0.664  0.244  0.121  1.0
  S  S5  1  0.336  0.756  0.879  1.0
  O  O6  1  0.775  0.433  0.234  1.0
  O  O7  1  0.225  0.567  0.766  1.0
  O  O8  1  0.755  0.025  0.195  1.0
  O  O9  1  0.245  0.975  0.805  1.0
  O  O10  1  0.769  0.272  0.971  1.0
  O  O11  1  0.231  0.728  0.029  1.0
  O  O12  1  0.729  0.899  0.572  1.0
  O  O13  1  0.271  0.101  0.428  1.0
  O  O14  1  0.685  0.732  0.651  1.0
  O  O15  1  0.315  0.268  0.349  1.0
[/CIF]
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