The structure described by N2Sb2OCl6NCl is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of eight ammonia atoms, four chloramine molecules, and two Sb2OCl6 clusters. In each Sb2OCl6 cluster, Sb(1) is bonded to one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(5) atom to form a mixture of distorted corner and edge-sharing SbCl4O trigonal bipyramids. O(1) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Sb(1) atoms. In the second Cl site, Cl(5) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2N3Cl7O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.699
_cell_length_b   11.265
_cell_length_c   13.176
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1588.141
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.160  0.286  0.923  1.0
  Sb  Sb1  1  0.160  0.714  0.077  1.0
  Sb  Sb2  1  0.340  0.786  0.577  1.0
  Sb  Sb3  1  0.340  0.214  0.423  1.0
  Sb  Sb4  1  0.840  0.714  0.077  1.0
  Sb  Sb5  1  0.840  0.286  0.923  1.0
  Sb  Sb6  1  0.660  0.214  0.423  1.0
  Sb  Sb7  1  0.660  0.786  0.577  1.0
  N  N8  1  0.000  0.000  0.000  1.0
  N  N9  1  0.500  0.500  0.500  1.0
  N  N10  1  0.500  0.000  0.000  1.0
  N  N11  1  0.000  0.500  0.500  1.0
  N  N12  1  0.000  0.105  0.595  1.0
  N  N13  1  0.000  0.895  0.405  1.0
  N  N14  1  0.500  0.605  0.905  1.0
  N  N15  1  0.500  0.395  0.095  1.0
  N  N16  1  0.000  0.288  0.229  1.0
  N  N17  1  0.000  0.712  0.771  1.0
  N  N18  1  0.500  0.788  0.272  1.0
  N  N19  1  0.500  0.212  0.729  1.0
  Cl  Cl20  1  0.197  0.139  0.798  1.0
  Cl  Cl21  1  0.197  0.861  0.202  1.0
  Cl  Cl22  1  0.303  0.639  0.702  1.0
  Cl  Cl23  1  0.303  0.361  0.298  1.0
  Cl  Cl24  1  0.803  0.861  0.202  1.0
  Cl  Cl25  1  0.803  0.139  0.798  1.0
  Cl  Cl26  1  0.697  0.361  0.298  1.0
  Cl  Cl27  1  0.697  0.639  0.702  1.0
  Cl  Cl28  1  0.279  0.185  0.049  1.0
  Cl  Cl29  1  0.279  0.815  0.951  1.0
  Cl  Cl30  1  0.221  0.685  0.451  1.0
  Cl  Cl31  1  0.221  0.315  0.549  1.0
  Cl  Cl32  1  0.721  0.815  0.951  1.0
  Cl  Cl33  1  0.721  0.185  0.049  1.0
  Cl  Cl34  1  0.779  0.315  0.549  1.0
  Cl  Cl35  1  0.779  0.685  0.451  1.0
  Cl  Cl36  1  0.000  0.388  0.791  1.0
  Cl  Cl37  1  0.000  0.612  0.209  1.0
  Cl  Cl38  1  0.500  0.888  0.709  1.0
  Cl  Cl39  1  0.500  0.112  0.291  1.0
  Cl  Cl40  1  0.500  0.330  0.799  1.0
  Cl  Cl41  1  0.500  0.670  0.201  1.0
  Cl  Cl42  1  0.000  0.830  0.701  1.0
  Cl  Cl43  1  0.000  0.170  0.299  1.0
  Cl  Cl44  1  0.198  0.500  0.000  1.0
  Cl  Cl45  1  0.302  0.000  0.500  1.0
  Cl  Cl46  1  0.802  0.500  0.000  1.0
  Cl  Cl47  1  0.698  0.000  0.500  1.0
  O  O48  1  0.000  0.238  0.986  1.0
  O  O49  1  0.000  0.762  0.014  1.0
  O  O50  1  0.500  0.738  0.514  1.0
  O  O51  1  0.500  0.262  0.486  1.0
[/CIF]
.
The structure described by N2Sb2OCl6NCl is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of eight ammonia atoms, four chloramine molecules, and two Sb2OCl6 clusters. In each Sb2OCl6 cluster, Sb(1) is bonded to one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(5) atom to form a mixture of distorted corner and edge-sharing SbCl4O trigonal bipyramids. O(1) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Sb(1) atoms. In the second Cl site, Cl(5) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2N3Cl7O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.699
_cell_length_b   11.265
_cell_length_c   13.176
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1588.141
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.160  0.286  0.923  1.0
  Sb  Sb1  1  0.160  0.714  0.077  1.0
  Sb  Sb2  1  0.340  0.786  0.577  1.0
  Sb  Sb3  1  0.340  0.214  0.423  1.0
  Sb  Sb4  1  0.840  0.714  0.077  1.0
  Sb  Sb5  1  0.840  0.286  0.923  1.0
  Sb  Sb6  1  0.660  0.214  0.423  1.0
  Sb  Sb7  1  0.660  0.786  0.577  1.0
  N  N8  1  0.000  0.000  0.000  1.0
  N  N9  1  0.500  0.500  0.500  1.0
  N  N10  1  0.500  0.000  0.000  1.0
  N  N11  1  0.000  0.500  0.500  1.0
  N  N12  1  0.000  0.105  0.595  1.0
  N  N13  1  0.000  0.895  0.405  1.0
  N  N14  1  0.500  0.605  0.905  1.0
  N  N15  1  0.500  0.395  0.095  1.0
  N  N16  1  0.000  0.288  0.229  1.0
  N  N17  1  0.000  0.712  0.771  1.0
  N  N18  1  0.500  0.788  0.272  1.0
  N  N19  1  0.500  0.212  0.729  1.0
  Cl  Cl20  1  0.197  0.139  0.798  1.0
  Cl  Cl21  1  0.197  0.861  0.202  1.0
  Cl  Cl22  1  0.303  0.639  0.702  1.0
  Cl  Cl23  1  0.303  0.361  0.298  1.0
  Cl  Cl24  1  0.803  0.861  0.202  1.0
  Cl  Cl25  1  0.803  0.139  0.798  1.0
  Cl  Cl26  1  0.697  0.361  0.298  1.0
  Cl  Cl27  1  0.697  0.639  0.702  1.0
  Cl  Cl28  1  0.279  0.185  0.049  1.0
  Cl  Cl29  1  0.279  0.815  0.951  1.0
  Cl  Cl30  1  0.221  0.685  0.451  1.0
  Cl  Cl31  1  0.221  0.315  0.549  1.0
  Cl  Cl32  1  0.721  0.815  0.951  1.0
  Cl  Cl33  1  0.721  0.185  0.049  1.0
  Cl  Cl34  1  0.779  0.315  0.549  1.0
  Cl  Cl35  1  0.779  0.685  0.451  1.0
  Cl  Cl36  1  0.000  0.388  0.791  1.0
  Cl  Cl37  1  0.000  0.612  0.209  1.0
  Cl  Cl38  1  0.500  0.888  0.709  1.0
  Cl  Cl39  1  0.500  0.112  0.291  1.0
  Cl  Cl40  1  0.500  0.330  0.799  1.0
  Cl  Cl41  1  0.500  0.670  0.201  1.0
  Cl  Cl42  1  0.000  0.830  0.701  1.0
  Cl  Cl43  1  0.000  0.170  0.299  1.0
  Cl  Cl44  1  0.198  0.500  0.000  1.0
  Cl  Cl45  1  0.302  0.000  0.500  1.0
  Cl  Cl46  1  0.802  0.500  0.000  1.0
  Cl  Cl47  1  0.698  0.000  0.500  1.0
  O  O48  1  0.000  0.238  0.986  1.0
  O  O49  1  0.000  0.762  0.014  1.0
  O  O50  1  0.500  0.738  0.514  1.0
  O  O51  1  0.500  0.262  0.486  1.0
[/CIF]
.