The compound described by MnO2(CO2)2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight carbon dioxide molecules and four manganese;dihydrate molecules. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.349
_cell_length_b   6.349
_cell_length_c   11.676
_cell_angle_alpha   67.521
_cell_angle_beta   67.521
_cell_angle_gamma   65.322
_symmetry_Int_Tables_number   1
_cell_volume   381.062
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.171  0.829  0.250  1.0
  Mn  Mn1  1  0.829  0.171  0.750  1.0
  C  C2  1  0.587  0.242  0.422  1.0
  C  C3  1  0.758  0.413  0.078  1.0
  C  C4  1  0.413  0.758  0.578  1.0
  C  C5  1  0.242  0.587  0.922  1.0
  O  O6  1  0.418  0.415  0.422  1.0
  O  O7  1  0.585  0.582  0.078  1.0
  O  O8  1  0.582  0.585  0.578  1.0
  O  O9  1  0.415  0.418  0.922  1.0
  O  O10  1  0.757  0.068  0.422  1.0
  O  O11  1  0.932  0.243  0.078  1.0
  O  O12  1  0.243  0.932  0.578  1.0
  O  O13  1  0.068  0.757  0.922  1.0
  O  O14  1  0.021  0.664  0.246  1.0
  O  O15  1  0.336  0.979  0.254  1.0
  O  O16  1  0.979  0.336  0.754  1.0
  O  O17  1  0.664  0.021  0.746  1.0
[/CIF]
.
The compound described by MnO2(CO2)2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight carbon dioxide molecules and four manganese;dihydrate molecules. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.349
_cell_length_b   6.349
_cell_length_c   11.676
_cell_angle_alpha   67.521
_cell_angle_beta   67.521
_cell_angle_gamma   65.322
_symmetry_Int_Tables_number   1
_cell_volume   381.062
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.171  0.829  0.250  1.0
  Mn  Mn1  1  0.829  0.171  0.750  1.0
  C  C2  1  0.587  0.242  0.422  1.0
  C  C3  1  0.758  0.413  0.078  1.0
  C  C4  1  0.413  0.758  0.578  1.0
  C  C5  1  0.242  0.587  0.922  1.0
  O  O6  1  0.418  0.415  0.422  1.0
  O  O7  1  0.585  0.582  0.078  1.0
  O  O8  1  0.582  0.585  0.578  1.0
  O  O9  1  0.415  0.418  0.922  1.0
  O  O10  1  0.757  0.068  0.422  1.0
  O  O11  1  0.932  0.243  0.078  1.0
  O  O12  1  0.243  0.932  0.578  1.0
  O  O13  1  0.068  0.757  0.922  1.0
  O  O14  1  0.021  0.664  0.246  1.0
  O  O15  1  0.336  0.979  0.254  1.0
  O  O16  1  0.979  0.336  0.754  1.0
  O  O17  1  0.664  0.021  0.746  1.0
[/CIF]
.