The material structure described by K2PdN2(O2Cl)2 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 10-coordinate geometry to six equivalent O(1) and four equivalent Cl(1) atoms. Pd(1) is bonded to four equivalent N(1) and two equivalent Cl(1) atoms to form edge-sharing PdN4Cl2 octahedra. N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Pd(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one N(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one Pd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2PdN2(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.732
_cell_length_b   7.931
_cell_length_c   7.944
_cell_angle_alpha   119.766
_cell_angle_beta   103.244
_cell_angle_gamma   90.668
_symmetry_Int_Tables_number   1
_cell_volume   196.502
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.846  0.346  0.691  1.0
  K  K1  1  0.154  0.654  0.309  1.0
  Pd  Pd2  1  0.500  0.000  0.000  1.0
  N  N3  1  0.865  0.865  0.730  1.0
  N  N4  1  0.135  0.135  0.270  1.0
  Cl  Cl5  1  0.485  0.706  0.000  1.0
  Cl  Cl6  1  0.515  0.294  0.000  1.0
  O  O7  1  0.836  0.953  0.634  1.0
  O  O8  1  0.202  0.319  0.366  1.0
  O  O9  1  0.798  0.681  0.634  1.0
  O  O10  1  0.164  0.047  0.366  1.0
[/CIF]
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The material structure described by K2PdN2(O2Cl)2 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 10-coordinate geometry to six equivalent O(1) and four equivalent Cl(1) atoms. Pd(1) is bonded to four equivalent N(1) and two equivalent Cl(1) atoms to form edge-sharing PdN4Cl2 octahedra. N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Pd(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one N(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one Pd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2PdN2(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.732
_cell_length_b   7.931
_cell_length_c   7.944
_cell_angle_alpha   119.766
_cell_angle_beta   103.244
_cell_angle_gamma   90.668
_symmetry_Int_Tables_number   1
_cell_volume   196.502
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.846  0.346  0.691  1.0
  K  K1  1  0.154  0.654  0.309  1.0
  Pd  Pd2  1  0.500  0.000  0.000  1.0
  N  N3  1  0.865  0.865  0.730  1.0
  N  N4  1  0.135  0.135  0.270  1.0
  Cl  Cl5  1  0.485  0.706  0.000  1.0
  Cl  Cl6  1  0.515  0.294  0.000  1.0
  O  O7  1  0.836  0.953  0.634  1.0
  O  O8  1  0.202  0.319  0.366  1.0
  O  O9  1  0.798  0.681  0.634  1.0
  O  O10  1  0.164  0.047  0.366  1.0
[/CIF]
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