The material described by Eu2WZnO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Zn(1)O6 octahedra. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Eu(1), one W(1), and one Zn(1) atom to form a mixture of distorted corner, edge, and face-sharing OEu4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF file [CIF]
data_Eu2ZnWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.609
_cell_length_b   5.609
_cell_length_c   5.609
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   124.775
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.250  0.250  0.250  1.0
  Eu  Eu1  1  0.750  0.750  0.750  1.0
  Zn  Zn2  1  0.000  0.000  0.000  1.0
  W  W3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.742  0.258  0.258  1.0
  O  O5  1  0.258  0.742  0.742  1.0
  O  O6  1  0.742  0.258  0.742  1.0
  O  O7  1  0.258  0.742  0.258  1.0
  O  O8  1  0.742  0.742  0.258  1.0
  O  O9  1  0.258  0.258  0.742  1.0
[/CIF]
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The material described by Eu2WZnO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Zn(1)O6 octahedra. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Eu(1), one W(1), and one Zn(1) atom to form a mixture of distorted corner, edge, and face-sharing OEu4ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF file [CIF]
data_Eu2ZnWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.609
_cell_length_b   5.609
_cell_length_c   5.609
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   124.775
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.250  0.250  0.250  1.0
  Eu  Eu1  1  0.750  0.750  0.750  1.0
  Zn  Zn2  1  0.000  0.000  0.000  1.0
  W  W3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.742  0.258  0.258  1.0
  O  O5  1  0.258  0.742  0.742  1.0
  O  O6  1  0.742  0.258  0.742  1.0
  O  O7  1  0.258  0.742  0.258  1.0
  O  O8  1  0.742  0.742  0.258  1.0
  O  O9  1  0.258  0.258  0.742  1.0
[/CIF]
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