The structure described by Ag3SbS3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one S(1) and two equivalent S(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted bent 150 degrees geometry to two equivalent S(3) atoms. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one S(2), one S(3), and two equivalent S(1) atoms. Sb(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Ag(1), two equivalent Ag(3), and one Sb(1) atom. In the second S site, S(2) is bonded to one Ag(3), two equivalent Ag(1), and one Sb(1) atom to form distorted corner-sharing SAg3Sb trigonal pyramids. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Ag(3), two equivalent Ag(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Ag3SbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.967
_cell_length_b   6.271
_cell_length_c   6.904
_cell_angle_alpha   63.737
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   619.901
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.810  0.710  0.070  1.0
  Ag  Ag1  1  0.743  0.309  0.478  1.0
  Ag  Ag2  1  0.310  0.790  0.930  1.0
  Ag  Ag3  1  0.901  0.469  0.592  1.0
  Ag  Ag4  1  0.243  0.191  0.522  1.0
  Ag  Ag5  1  0.599  0.969  0.592  1.0
  Ag  Ag6  1  0.190  0.290  0.930  1.0
  Ag  Ag7  1  0.257  0.691  0.522  1.0
  Ag  Ag8  1  0.099  0.531  0.408  1.0
  Ag  Ag9  1  0.401  0.031  0.408  1.0
  Ag  Ag10  1  0.690  0.210  0.070  1.0
  Ag  Ag11  1  0.757  0.809  0.478  1.0
  Sb  Sb12  1  0.551  0.676  0.196  1.0
  Sb  Sb13  1  0.051  0.824  0.804  1.0
  Sb  Sb14  1  0.449  0.324  0.804  1.0
  Sb  Sb15  1  0.949  0.176  0.196  1.0
  S  S16  1  0.056  0.232  0.779  1.0
  S  S17  1  0.444  0.732  0.779  1.0
  S  S18  1  0.556  0.268  0.221  1.0
  S  S19  1  0.167  0.629  0.052  1.0
  S  S20  1  0.636  0.555  0.534  1.0
  S  S21  1  0.136  0.945  0.466  1.0
  S  S22  1  0.944  0.768  0.221  1.0
  S  S23  1  0.364  0.445  0.466  1.0
  S  S24  1  0.864  0.055  0.534  1.0
  S  S25  1  0.667  0.871  0.948  1.0
  S  S26  1  0.333  0.129  0.052  1.0
  S  S27  1  0.833  0.371  0.948  1.0
[/CIF]
.
The structure described by Ag3SbS3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one S(1) and two equivalent S(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted bent 150 degrees geometry to two equivalent S(3) atoms. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one S(2), one S(3), and two equivalent S(1) atoms. Sb(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Ag(1), two equivalent Ag(3), and one Sb(1) atom. In the second S site, S(2) is bonded to one Ag(3), two equivalent Ag(1), and one Sb(1) atom to form distorted corner-sharing SAg3Sb trigonal pyramids. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Ag(3), two equivalent Ag(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Ag3SbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.967
_cell_length_b   6.271
_cell_length_c   6.904
_cell_angle_alpha   63.737
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   619.901
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.810  0.710  0.070  1.0
  Ag  Ag1  1  0.743  0.309  0.478  1.0
  Ag  Ag2  1  0.310  0.790  0.930  1.0
  Ag  Ag3  1  0.901  0.469  0.592  1.0
  Ag  Ag4  1  0.243  0.191  0.522  1.0
  Ag  Ag5  1  0.599  0.969  0.592  1.0
  Ag  Ag6  1  0.190  0.290  0.930  1.0
  Ag  Ag7  1  0.257  0.691  0.522  1.0
  Ag  Ag8  1  0.099  0.531  0.408  1.0
  Ag  Ag9  1  0.401  0.031  0.408  1.0
  Ag  Ag10  1  0.690  0.210  0.070  1.0
  Ag  Ag11  1  0.757  0.809  0.478  1.0
  Sb  Sb12  1  0.551  0.676  0.196  1.0
  Sb  Sb13  1  0.051  0.824  0.804  1.0
  Sb  Sb14  1  0.449  0.324  0.804  1.0
  Sb  Sb15  1  0.949  0.176  0.196  1.0
  S  S16  1  0.056  0.232  0.779  1.0
  S  S17  1  0.444  0.732  0.779  1.0
  S  S18  1  0.556  0.268  0.221  1.0
  S  S19  1  0.167  0.629  0.052  1.0
  S  S20  1  0.636  0.555  0.534  1.0
  S  S21  1  0.136  0.945  0.466  1.0
  S  S22  1  0.944  0.768  0.221  1.0
  S  S23  1  0.364  0.445  0.466  1.0
  S  S24  1  0.864  0.055  0.534  1.0
  S  S25  1  0.667  0.871  0.948  1.0
  S  S26  1  0.333  0.129  0.052  1.0
  S  S27  1  0.833  0.371  0.948  1.0
[/CIF]
.