The material described by AuSb2(XeF6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuSb2(XeF6)2 cluster. Xe(1) is bonded in a single-bond geometry to one Au(1) atom. Au(1) is bonded in a linear geometry to two equivalent Xe(1) and two equivalent F(1) atoms. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Au(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_Sb2Au(XeF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.677
_cell_length_b   7.438
_cell_length_c   8.235
_cell_angle_alpha   91.025
_cell_angle_beta   91.143
_cell_angle_gamma   98.068
_symmetry_Int_Tables_number   1
_cell_volume   344.128
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.480  0.724  0.742  1.0
  Sb  Sb1  1  0.520  0.276  0.258  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Xe  Xe3  1  0.978  0.225  0.737  1.0
  Xe  Xe4  1  0.022  0.775  0.263  1.0
  F  F5  1  0.653  0.843  0.944  1.0
  F  F6  1  0.347  0.157  0.056  1.0
  F  F7  1  0.305  0.612  0.558  1.0
  F  F8  1  0.695  0.388  0.442  1.0
  F  F9  1  0.204  0.697  0.875  1.0
  F  F10  1  0.796  0.303  0.125  1.0
  F  F11  1  0.558  0.498  0.817  1.0
  F  F12  1  0.442  0.502  0.183  1.0
  F  F13  1  0.776  0.770  0.635  1.0
  F  F14  1  0.224  0.230  0.365  1.0
  F  F15  1  0.413  0.960  0.689  1.0
  F  F16  1  0.587  0.040  0.311  1.0
[/CIF]
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The material described by AuSb2(XeF6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuSb2(XeF6)2 cluster. Xe(1) is bonded in a single-bond geometry to one Au(1) atom. Au(1) is bonded in a linear geometry to two equivalent Xe(1) and two equivalent F(1) atoms. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Au(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_Sb2Au(XeF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.677
_cell_length_b   7.438
_cell_length_c   8.235
_cell_angle_alpha   91.025
_cell_angle_beta   91.143
_cell_angle_gamma   98.068
_symmetry_Int_Tables_number   1
_cell_volume   344.128
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.480  0.724  0.742  1.0
  Sb  Sb1  1  0.520  0.276  0.258  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Xe  Xe3  1  0.978  0.225  0.737  1.0
  Xe  Xe4  1  0.022  0.775  0.263  1.0
  F  F5  1  0.653  0.843  0.944  1.0
  F  F6  1  0.347  0.157  0.056  1.0
  F  F7  1  0.305  0.612  0.558  1.0
  F  F8  1  0.695  0.388  0.442  1.0
  F  F9  1  0.204  0.697  0.875  1.0
  F  F10  1  0.796  0.303  0.125  1.0
  F  F11  1  0.558  0.498  0.817  1.0
  F  F12  1  0.442  0.502  0.183  1.0
  F  F13  1  0.776  0.770  0.635  1.0
  F  F14  1  0.224  0.230  0.365  1.0
  F  F15  1  0.413  0.960  0.689  1.0
  F  F16  1  0.587  0.040  0.311  1.0
[/CIF]
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