The material structure described by PuO4(SO4)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of sixteen sulfuric acid molecules and eight PuO4 clusters. In each PuO4 cluster, Pu(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one Pu(1) atom. is represented by the CIF file [CIF]
data_Pu(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.929
_cell_length_b   13.496
_cell_length_c   7.551
_cell_angle_alpha   85.424
_cell_angle_beta   64.300
_cell_angle_gamma   30.275
_symmetry_Int_Tables_number   1
_cell_volume   525.925
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.500  0.500  0.500  1.0
  Pu  Pu1  1  0.750  0.750  0.750  1.0
  S  S2  1  0.443  0.443  0.057  1.0
  S  S3  1  0.057  0.057  0.443  1.0
  S  S4  1  0.807  0.807  0.193  1.0
  S  S5  1  0.193  0.193  0.807  1.0
  O  O6  1  0.686  0.217  0.357  1.0
  O  O7  1  0.741  0.357  0.217  1.0
  O  O8  1  0.357  0.741  0.686  1.0
  O  O9  1  0.217  0.686  0.741  1.0
  O  O10  1  0.564  0.033  0.893  1.0
  O  O11  1  0.509  0.893  0.033  1.0
  O  O12  1  0.893  0.509  0.564  1.0
  O  O13  1  0.033  0.564  0.509  1.0
  O  O14  1  0.526  0.426  0.142  1.0
  O  O15  1  0.906  0.142  0.426  1.0
  O  O16  1  0.142  0.906  0.526  1.0
  O  O17  1  0.426  0.526  0.906  1.0
  O  O18  1  0.724  0.824  0.108  1.0
  O  O19  1  0.344  0.108  0.824  1.0
  O  O20  1  0.108  0.344  0.724  1.0
  O  O21  1  0.824  0.724  0.344  1.0
  O  O22  1  0.192  0.625  0.278  1.0
  O  O23  1  0.906  0.278  0.625  1.0
  O  O24  1  0.278  0.906  0.192  1.0
  O  O25  1  0.625  0.192  0.906  1.0
  O  O26  1  0.058  0.625  0.972  1.0
  O  O27  1  0.344  0.972  0.625  1.0
  O  O28  1  0.972  0.344  0.058  1.0
  O  O29  1  0.625  0.058  0.344  1.0
[/CIF]
.
The material structure described by PuO4(SO4)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of sixteen sulfuric acid molecules and eight PuO4 clusters. In each PuO4 cluster, Pu(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one Pu(1) atom. is represented by the CIF file [CIF]
data_Pu(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.929
_cell_length_b   13.496
_cell_length_c   7.551
_cell_angle_alpha   85.424
_cell_angle_beta   64.300
_cell_angle_gamma   30.275
_symmetry_Int_Tables_number   1
_cell_volume   525.925
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.500  0.500  0.500  1.0
  Pu  Pu1  1  0.750  0.750  0.750  1.0
  S  S2  1  0.443  0.443  0.057  1.0
  S  S3  1  0.057  0.057  0.443  1.0
  S  S4  1  0.807  0.807  0.193  1.0
  S  S5  1  0.193  0.193  0.807  1.0
  O  O6  1  0.686  0.217  0.357  1.0
  O  O7  1  0.741  0.357  0.217  1.0
  O  O8  1  0.357  0.741  0.686  1.0
  O  O9  1  0.217  0.686  0.741  1.0
  O  O10  1  0.564  0.033  0.893  1.0
  O  O11  1  0.509  0.893  0.033  1.0
  O  O12  1  0.893  0.509  0.564  1.0
  O  O13  1  0.033  0.564  0.509  1.0
  O  O14  1  0.526  0.426  0.142  1.0
  O  O15  1  0.906  0.142  0.426  1.0
  O  O16  1  0.142  0.906  0.526  1.0
  O  O17  1  0.426  0.526  0.906  1.0
  O  O18  1  0.724  0.824  0.108  1.0
  O  O19  1  0.344  0.108  0.824  1.0
  O  O20  1  0.108  0.344  0.724  1.0
  O  O21  1  0.824  0.724  0.344  1.0
  O  O22  1  0.192  0.625  0.278  1.0
  O  O23  1  0.906  0.278  0.625  1.0
  O  O24  1  0.278  0.906  0.192  1.0
  O  O25  1  0.625  0.192  0.906  1.0
  O  O26  1  0.058  0.625  0.972  1.0
  O  O27  1  0.344  0.972  0.625  1.0
  O  O28  1  0.972  0.344  0.058  1.0
  O  O29  1  0.625  0.058  0.344  1.0
[/CIF]
.