The compound described by LiSb(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(11), one O(2), one O(3), and one O(8) atom. Sb(1) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(2), one O(4), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(12), one O(5), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Sb(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Sb(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Li(1), one Sb(1), and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Sb(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one Li(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(3) atom. is represented by the CIF card [CIF]
data_LiSb(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.058
_cell_length_b   7.024
_cell_length_c   7.527
_cell_angle_alpha   85.913
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   477.640
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.982  0.795  0.804  1.0
  Li  Li1  1  0.482  0.205  0.196  1.0
  Sb  Sb2  1  0.627  0.749  0.281  1.0
  Sb  Sb3  1  0.127  0.251  0.719  1.0
  P  P4  1  0.635  0.997  0.579  1.0
  P  P5  1  0.435  0.892  0.883  1.0
  P  P6  1  0.266  0.614  0.409  1.0
  P  P7  1  0.619  0.551  0.913  1.0
  P  P8  1  0.119  0.449  0.087  1.0
  P  P9  1  0.766  0.386  0.591  1.0
  P  P10  1  0.935  0.108  0.117  1.0
  P  P11  1  0.135  0.003  0.421  1.0
  O  O12  1  0.056  0.982  0.235  1.0
  O  O13  1  0.473  0.923  0.076  1.0
  O  O14  1  0.032  0.975  0.582  1.0
  O  O15  1  0.285  0.947  0.816  1.0
  O  O16  1  0.254  0.841  0.411  1.0
  O  O17  1  0.715  0.808  0.568  1.0
  O  O18  1  0.474  0.676  0.839  1.0
  O  O19  1  0.742  0.686  0.952  1.0
  O  O20  1  0.217  0.530  0.588  1.0
  O  O21  1  0.150  0.567  0.260  1.0
  O  O22  1  0.069  0.585  0.939  1.0
  O  O23  1  0.424  0.584  0.353  1.0
  O  O24  1  0.924  0.416  0.647  1.0
  O  O25  1  0.569  0.415  0.061  1.0
  O  O26  1  0.650  0.433  0.740  1.0
  O  O27  1  0.717  0.470  0.412  1.0
  O  O28  1  0.242  0.314  0.048  1.0
  O  O29  1  0.974  0.324  0.161  1.0
  O  O30  1  0.215  0.192  0.432  1.0
  O  O31  1  0.754  0.159  0.589  1.0
  O  O32  1  0.785  0.053  0.184  1.0
  O  O33  1  0.532  0.025  0.418  1.0
  O  O34  1  0.973  0.077  0.924  1.0
  O  O35  1  0.556  0.018  0.765  1.0
[/CIF]
.
The compound described by LiSb(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(11), one O(2), one O(3), and one O(8) atom. Sb(1) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(2), one O(4), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(12), one O(5), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Sb(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Sb(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Li(1), one Sb(1), and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Sb(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one Li(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(3) atom. is represented by the CIF card [CIF]
data_LiSb(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.058
_cell_length_b   7.024
_cell_length_c   7.527
_cell_angle_alpha   85.913
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   477.640
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.982  0.795  0.804  1.0
  Li  Li1  1  0.482  0.205  0.196  1.0
  Sb  Sb2  1  0.627  0.749  0.281  1.0
  Sb  Sb3  1  0.127  0.251  0.719  1.0
  P  P4  1  0.635  0.997  0.579  1.0
  P  P5  1  0.435  0.892  0.883  1.0
  P  P6  1  0.266  0.614  0.409  1.0
  P  P7  1  0.619  0.551  0.913  1.0
  P  P8  1  0.119  0.449  0.087  1.0
  P  P9  1  0.766  0.386  0.591  1.0
  P  P10  1  0.935  0.108  0.117  1.0
  P  P11  1  0.135  0.003  0.421  1.0
  O  O12  1  0.056  0.982  0.235  1.0
  O  O13  1  0.473  0.923  0.076  1.0
  O  O14  1  0.032  0.975  0.582  1.0
  O  O15  1  0.285  0.947  0.816  1.0
  O  O16  1  0.254  0.841  0.411  1.0
  O  O17  1  0.715  0.808  0.568  1.0
  O  O18  1  0.474  0.676  0.839  1.0
  O  O19  1  0.742  0.686  0.952  1.0
  O  O20  1  0.217  0.530  0.588  1.0
  O  O21  1  0.150  0.567  0.260  1.0
  O  O22  1  0.069  0.585  0.939  1.0
  O  O23  1  0.424  0.584  0.353  1.0
  O  O24  1  0.924  0.416  0.647  1.0
  O  O25  1  0.569  0.415  0.061  1.0
  O  O26  1  0.650  0.433  0.740  1.0
  O  O27  1  0.717  0.470  0.412  1.0
  O  O28  1  0.242  0.314  0.048  1.0
  O  O29  1  0.974  0.324  0.161  1.0
  O  O30  1  0.215  0.192  0.432  1.0
  O  O31  1  0.754  0.159  0.589  1.0
  O  O32  1  0.785  0.053  0.184  1.0
  O  O33  1  0.532  0.025  0.418  1.0
  O  O34  1  0.973  0.077  0.924  1.0
  O  O35  1  0.556  0.018  0.765  1.0
[/CIF]
.