The crystal structure described by Li4Mn3Co3(SbO8)2 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(8), and two equivalent O(11) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-63°. In the second Li site, Li(2) is bonded to one O(4), one O(5), and two equivalent O(12) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-65°. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(3), one O(6), and two equivalent O(9) atoms. In the fourth Li site, Li(4) is bonded to one O(1), one O(7), and two equivalent O(10) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra, and corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), two equivalent O(10), and two equivalent O(12) atoms to form MnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. In the second Mn site, Mn(2) is bonded to one O(11), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the second Co site, Co(2) is bonded to one O(4), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form SbO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. In the second Sb site, Sb(2) is bonded to one O(5), one O(8), two equivalent O(11), and two equivalent O(12) atoms to form SbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent Co(1), and one Sb(1) atom. In the second O site, O(2) is bonded to one Li(1), one Mn(1), and two equivalent Co(1) atoms to form distorted OLiMnCo2 trigonal pyramids that share  a cornercorner with one O(8)LiMn2Sb tetrahedra and corners with three equivalent O(3)LiMnCo2 tetrahedra. In the third O site, O(3) is bonded to one Li(3), one Mn(1), and two equivalent Co(1) atoms to form corner-sharing OLiMnCo2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), two equivalent Mn(2), and one Co(2) atom to form OLiMn2Co tetrahedra that share corners with two equivalent O(8)LiMn2Sb tetrahedra and corners with three equivalent O(7)LiMn2Co tetrahedra. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Co(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Mn(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded to one Li(4), two equivalent Mn(2), and one Co(2) atom to form OLiMn2Co tetrahedra that share corners with three equivalent O(4)LiMn2Co tetrahedra and  an edgeedge with one O(8)LiMn2Sb tetrahedra. In the eighth O site, O(8) is bonded to one Li(1), two equivalent Mn(2), and one Sb(2) atom to form distorted OLiMn2Sb tetrahedra that share corners with two equivalent O(4)LiMn2Co tetrahedra,  a cornercorner with one O(2)LiMnCo2 trigonal pyramid, and  an edgeedge with one O(7)LiMn2Co tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(2), one Co(2), and one Sb(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(1), one Co(1), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Mn(2), one Co(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(2), one Mn(1), one Co(1), and one Sb(2) atom. is represented by the CIF file [CIF]
data_Li4Mn3Co3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.882
_cell_length_b   9.746
_cell_length_c   5.961
_cell_angle_alpha   91.672
_cell_angle_beta   119.550
_cell_angle_gamma   90.006
_symmetry_Int_Tables_number   1
_cell_volume   297.089
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.659  0.903  0.318  1.0
  Li  Li1  1  0.005  0.989  0.009  1.0
  Li  Li2  1  0.010  0.489  0.021  1.0
  Li  Li3  1  0.333  0.404  0.667  1.0
  Mn  Mn4  1  0.830  0.208  0.660  1.0
  Mn  Mn5  1  0.664  0.713  0.834  1.0
  Mn  Mn6  1  0.170  0.713  0.834  1.0
  Co  Co7  1  0.830  0.218  0.171  1.0
  Co  Co8  1  0.341  0.218  0.171  1.0
  Co  Co9  1  0.172  0.715  0.345  1.0
  Sb  Sb10  1  0.670  0.489  0.341  1.0
  Sb  Sb11  1  0.326  0.985  0.652  1.0
  O  O12  1  0.518  0.348  0.035  1.0
  O  O13  1  0.665  0.113  0.329  1.0
  O  O14  1  0.997  0.299  0.995  1.0
  O  O15  1  0.006  0.800  0.012  1.0
  O  O16  1  0.166  0.097  0.332  1.0
  O  O17  1  0.843  0.592  0.687  1.0
  O  O18  1  0.331  0.618  0.662  1.0
  O  O19  1  0.476  0.846  0.953  1.0
  O  O20  1  0.847  0.595  0.184  1.0
  O  O21  1  0.337  0.595  0.184  1.0
  O  O22  1  0.966  0.349  0.479  1.0
  O  O23  1  0.513  0.349  0.478  1.0
  O  O24  1  0.466  0.843  0.493  1.0
  O  O25  1  0.027  0.843  0.493  1.0
  O  O26  1  0.668  0.088  0.831  1.0
  O  O27  1  0.164  0.088  0.832  1.0
[/CIF]
.
The crystal structure described by Li4Mn3Co3(SbO8)2 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(8), and two equivalent O(11) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-63°. In the second Li site, Li(2) is bonded to one O(4), one O(5), and two equivalent O(12) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-65°. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(3), one O(6), and two equivalent O(9) atoms. In the fourth Li site, Li(4) is bonded to one O(1), one O(7), and two equivalent O(10) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra, and corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), two equivalent O(10), and two equivalent O(12) atoms to form MnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. In the second Mn site, Mn(2) is bonded to one O(11), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the second Co site, Co(2) is bonded to one O(4), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form SbO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. In the second Sb site, Sb(2) is bonded to one O(5), one O(8), two equivalent O(11), and two equivalent O(12) atoms to form SbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent Co(1), and one Sb(1) atom. In the second O site, O(2) is bonded to one Li(1), one Mn(1), and two equivalent Co(1) atoms to form distorted OLiMnCo2 trigonal pyramids that share  a cornercorner with one O(8)LiMn2Sb tetrahedra and corners with three equivalent O(3)LiMnCo2 tetrahedra. In the third O site, O(3) is bonded to one Li(3), one Mn(1), and two equivalent Co(1) atoms to form corner-sharing OLiMnCo2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), two equivalent Mn(2), and one Co(2) atom to form OLiMn2Co tetrahedra that share corners with two equivalent O(8)LiMn2Sb tetrahedra and corners with three equivalent O(7)LiMn2Co tetrahedra. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Co(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Mn(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded to one Li(4), two equivalent Mn(2), and one Co(2) atom to form OLiMn2Co tetrahedra that share corners with three equivalent O(4)LiMn2Co tetrahedra and  an edgeedge with one O(8)LiMn2Sb tetrahedra. In the eighth O site, O(8) is bonded to one Li(1), two equivalent Mn(2), and one Sb(2) atom to form distorted OLiMn2Sb tetrahedra that share corners with two equivalent O(4)LiMn2Co tetrahedra,  a cornercorner with one O(2)LiMnCo2 trigonal pyramid, and  an edgeedge with one O(7)LiMn2Co tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(2), one Co(2), and one Sb(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(1), one Co(1), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Mn(2), one Co(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(2), one Mn(1), one Co(1), and one Sb(2) atom. is represented by the CIF file [CIF]
data_Li4Mn3Co3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.882
_cell_length_b   9.746
_cell_length_c   5.961
_cell_angle_alpha   91.672
_cell_angle_beta   119.550
_cell_angle_gamma   90.006
_symmetry_Int_Tables_number   1
_cell_volume   297.089
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.659  0.903  0.318  1.0
  Li  Li1  1  0.005  0.989  0.009  1.0
  Li  Li2  1  0.010  0.489  0.021  1.0
  Li  Li3  1  0.333  0.404  0.667  1.0
  Mn  Mn4  1  0.830  0.208  0.660  1.0
  Mn  Mn5  1  0.664  0.713  0.834  1.0
  Mn  Mn6  1  0.170  0.713  0.834  1.0
  Co  Co7  1  0.830  0.218  0.171  1.0
  Co  Co8  1  0.341  0.218  0.171  1.0
  Co  Co9  1  0.172  0.715  0.345  1.0
  Sb  Sb10  1  0.670  0.489  0.341  1.0
  Sb  Sb11  1  0.326  0.985  0.652  1.0
  O  O12  1  0.518  0.348  0.035  1.0
  O  O13  1  0.665  0.113  0.329  1.0
  O  O14  1  0.997  0.299  0.995  1.0
  O  O15  1  0.006  0.800  0.012  1.0
  O  O16  1  0.166  0.097  0.332  1.0
  O  O17  1  0.843  0.592  0.687  1.0
  O  O18  1  0.331  0.618  0.662  1.0
  O  O19  1  0.476  0.846  0.953  1.0
  O  O20  1  0.847  0.595  0.184  1.0
  O  O21  1  0.337  0.595  0.184  1.0
  O  O22  1  0.966  0.349  0.479  1.0
  O  O23  1  0.513  0.349  0.478  1.0
  O  O24  1  0.466  0.843  0.493  1.0
  O  O25  1  0.027  0.843  0.493  1.0
  O  O26  1  0.668  0.088  0.831  1.0
  O  O27  1  0.164  0.088  0.832  1.0
[/CIF]
.