The material structure described by V5Cr5Ge6 crystallizes in the monoclinic Cm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 7-coordinate geometry to one Cr(4), one Ge(2), one Ge(5), two equivalent Ge(1), and two equivalent Ge(3) atoms. In the second V site, V(2) is bonded in a 7-coordinate geometry to one Cr(2), one Ge(3), one Ge(4), two equivalent Ge(1), and two equivalent Ge(5) atoms. In the third V site, V(3) is bonded in a 7-coordinate geometry to one Cr(1), one Ge(2), one Ge(5), two equivalent Ge(1), and two equivalent Ge(4) atoms. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to two equivalent V(4), one Ge(2), one Ge(3), one Ge(4), and one Ge(5) atom. There are five inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 7-coordinate geometry to one V(3), one Ge(3), one Ge(5), two equivalent Ge(1), and two equivalent Ge(4) atoms. In the second Cr site, Cr(2) is bonded in a 7-coordinate geometry to one V(2), one Ge(2), one Ge(4), two equivalent Ge(1), and two equivalent Ge(5) atoms. In the third Cr site, Cr(3) is bonded in a 6-coordinate geometry to one Ge(3), one Ge(5), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the fourth Cr site, Cr(4) is bonded in a 7-coordinate geometry to one V(1), one Ge(2), one Ge(4), two equivalent Ge(1), and two equivalent Ge(3) atoms. In the fifth Cr site, Cr(5) is bonded in a 6-coordinate geometry to one Ge(3), one Ge(4), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are five inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one V(1), one V(2), one V(3), one Cr(1), one Cr(2), one Cr(3), one Cr(4), one Cr(5), and two equivalent Ge(1) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to one V(1), one V(3), two equivalent V(4), one Cr(2), one Cr(4), two equivalent Cr(3), and two equivalent Cr(5) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one V(2), two equivalent V(1), two equivalent V(4), one Cr(1), one Cr(3), one Cr(5), and two equivalent Cr(4) atoms. In the fourth Ge site, Ge(4) is bonded in a 10-coordinate geometry to one V(2), two equivalent V(3), two equivalent V(4), one Cr(2), one Cr(4), one Cr(5), and two equivalent Cr(1) atoms. In the fifth Ge site, Ge(5) is bonded in a 10-coordinate geometry to one V(1), one V(3), two equivalent V(2), two equivalent V(4), one Cr(1), one Cr(3), and two equivalent Cr(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V5Cr5Ge6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.817
_cell_length_b   7.133
_cell_length_c   7.118
_cell_angle_alpha   96.317
_cell_angle_beta   109.779
_cell_angle_gamma   70.264
_symmetry_Int_Tables_number   1
_cell_volume   216.640
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.268  0.308  0.843  1.0
  V  V1  1  0.765  0.159  0.689  1.0
  V  V2  1  0.235  0.841  0.310  1.0
  V  V3  1  0.251  0.500  0.501  1.0
  V  V4  1  0.750  0.500  0.501  1.0
  Cr  Cr5  1  0.423  0.844  0.690  1.0
  Cr  Cr6  1  0.574  0.158  0.305  1.0
  Cr  Cr7  1  0.926  0.305  0.157  1.0
  Cr  Cr8  1  0.074  0.695  0.844  1.0
  Cr  Cr9  1  0.733  0.693  0.160  1.0
  Ge  Ge10  1  0.252  0.998  0.000  1.0
  Ge  Ge11  1  0.751  0.998  0.000  1.0
  Ge  Ge12  1  0.331  0.500  0.162  1.0
  Ge  Ge13  1  0.668  0.503  0.840  1.0
  Ge  Ge14  1  0.832  0.835  0.499  1.0
  Ge  Ge15  1  0.167  0.165  0.498  1.0
[/CIF]
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The material structure described by V5Cr5Ge6 crystallizes in the monoclinic Cm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 7-coordinate geometry to one Cr(4), one Ge(2), one Ge(5), two equivalent Ge(1), and two equivalent Ge(3) atoms. In the second V site, V(2) is bonded in a 7-coordinate geometry to one Cr(2), one Ge(3), one Ge(4), two equivalent Ge(1), and two equivalent Ge(5) atoms. In the third V site, V(3) is bonded in a 7-coordinate geometry to one Cr(1), one Ge(2), one Ge(5), two equivalent Ge(1), and two equivalent Ge(4) atoms. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to two equivalent V(4), one Ge(2), one Ge(3), one Ge(4), and one Ge(5) atom. There are five inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 7-coordinate geometry to one V(3), one Ge(3), one Ge(5), two equivalent Ge(1), and two equivalent Ge(4) atoms. In the second Cr site, Cr(2) is bonded in a 7-coordinate geometry to one V(2), one Ge(2), one Ge(4), two equivalent Ge(1), and two equivalent Ge(5) atoms. In the third Cr site, Cr(3) is bonded in a 6-coordinate geometry to one Ge(3), one Ge(5), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the fourth Cr site, Cr(4) is bonded in a 7-coordinate geometry to one V(1), one Ge(2), one Ge(4), two equivalent Ge(1), and two equivalent Ge(3) atoms. In the fifth Cr site, Cr(5) is bonded in a 6-coordinate geometry to one Ge(3), one Ge(4), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are five inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one V(1), one V(2), one V(3), one Cr(1), one Cr(2), one Cr(3), one Cr(4), one Cr(5), and two equivalent Ge(1) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to one V(1), one V(3), two equivalent V(4), one Cr(2), one Cr(4), two equivalent Cr(3), and two equivalent Cr(5) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one V(2), two equivalent V(1), two equivalent V(4), one Cr(1), one Cr(3), one Cr(5), and two equivalent Cr(4) atoms. In the fourth Ge site, Ge(4) is bonded in a 10-coordinate geometry to one V(2), two equivalent V(3), two equivalent V(4), one Cr(2), one Cr(4), one Cr(5), and two equivalent Cr(1) atoms. In the fifth Ge site, Ge(5) is bonded in a 10-coordinate geometry to one V(1), one V(3), two equivalent V(2), two equivalent V(4), one Cr(1), one Cr(3), and two equivalent Cr(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V5Cr5Ge6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.817
_cell_length_b   7.133
_cell_length_c   7.118
_cell_angle_alpha   96.317
_cell_angle_beta   109.779
_cell_angle_gamma   70.264
_symmetry_Int_Tables_number   1
_cell_volume   216.640
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.268  0.308  0.843  1.0
  V  V1  1  0.765  0.159  0.689  1.0
  V  V2  1  0.235  0.841  0.310  1.0
  V  V3  1  0.251  0.500  0.501  1.0
  V  V4  1  0.750  0.500  0.501  1.0
  Cr  Cr5  1  0.423  0.844  0.690  1.0
  Cr  Cr6  1  0.574  0.158  0.305  1.0
  Cr  Cr7  1  0.926  0.305  0.157  1.0
  Cr  Cr8  1  0.074  0.695  0.844  1.0
  Cr  Cr9  1  0.733  0.693  0.160  1.0
  Ge  Ge10  1  0.252  0.998  0.000  1.0
  Ge  Ge11  1  0.751  0.998  0.000  1.0
  Ge  Ge12  1  0.331  0.500  0.162  1.0
  Ge  Ge13  1  0.668  0.503  0.840  1.0
  Ge  Ge14  1  0.832  0.835  0.499  1.0
  Ge  Ge15  1  0.167  0.165  0.498  1.0
[/CIF]
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