The material described by Ni2V crystallizes in the orthorhombic Immm space group. V(1) is bonded to two equivalent V(1) and ten equivalent Ni(1) atoms to form VV2Ni10 cuboctahedra that share corners with two equivalent V(1)V2Ni10 cuboctahedra, corners with ten equivalent Ni(1)V5Ni7 cuboctahedra, edges with twelve equivalent V(1)V2Ni10 cuboctahedra, edges with twelve equivalent Ni(1)V5Ni7 cuboctahedra, faces with four equivalent V(1)V2Ni10 cuboctahedra, and faces with fourteen equivalent Ni(1)V5Ni7 cuboctahedra. Ni(1) is bonded to five equivalent V(1) and seven equivalent Ni(1) atoms to form NiV5Ni7 cuboctahedra that share corners with five equivalent V(1)V2Ni10 cuboctahedra, corners with seven equivalent Ni(1)V5Ni7 cuboctahedra, edges with six equivalent V(1)V2Ni10 cuboctahedra, edges with eighteen equivalent Ni(1)V5Ni7 cuboctahedra, faces with seven equivalent V(1)V2Ni10 cuboctahedra, and faces with eleven equivalent Ni(1)V5Ni7 cuboctahedra. is represented by the CIF card [CIF]
data_VNi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.506
_cell_length_b   3.526
_cell_length_c   4.349
_cell_angle_alpha   113.909
_cell_angle_beta   106.748
_cell_angle_gamma   89.997
_symmetry_Int_Tables_number   1
_cell_volume   33.344
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Ni  Ni1  1  0.668  0.668  0.336  1.0
  Ni  Ni2  1  0.332  0.332  0.664  1.0
[/CIF]
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The material described by Ni2V crystallizes in the orthorhombic Immm space group. V(1) is bonded to two equivalent V(1) and ten equivalent Ni(1) atoms to form VV2Ni10 cuboctahedra that share corners with two equivalent V(1)V2Ni10 cuboctahedra, corners with ten equivalent Ni(1)V5Ni7 cuboctahedra, edges with twelve equivalent V(1)V2Ni10 cuboctahedra, edges with twelve equivalent Ni(1)V5Ni7 cuboctahedra, faces with four equivalent V(1)V2Ni10 cuboctahedra, and faces with fourteen equivalent Ni(1)V5Ni7 cuboctahedra. Ni(1) is bonded to five equivalent V(1) and seven equivalent Ni(1) atoms to form NiV5Ni7 cuboctahedra that share corners with five equivalent V(1)V2Ni10 cuboctahedra, corners with seven equivalent Ni(1)V5Ni7 cuboctahedra, edges with six equivalent V(1)V2Ni10 cuboctahedra, edges with eighteen equivalent Ni(1)V5Ni7 cuboctahedra, faces with seven equivalent V(1)V2Ni10 cuboctahedra, and faces with eleven equivalent Ni(1)V5Ni7 cuboctahedra. is represented by the CIF card [CIF]
data_VNi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.506
_cell_length_b   3.526
_cell_length_c   4.349
_cell_angle_alpha   113.909
_cell_angle_beta   106.748
_cell_angle_gamma   89.997
_symmetry_Int_Tables_number   1
_cell_volume   33.344
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Ni  Ni1  1  0.668  0.668  0.336  1.0
  Ni  Ni2  1  0.332  0.332  0.664  1.0
[/CIF]
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