The material structure described by LiAg2(NO2)3 crystallizes in the monoclinic Cc space group. Li(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(2), one O(2), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(1), one N(3), and one O(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(2), one O(1), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one O(2), and one O(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one N(3) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one N(3) atom. In the third O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(2), and one N(1) atom. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(1), and one N(2) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Li(1) and one N(1) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one N(2) atom. is represented by the CIF card [CIF]
data_LiAg2(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.453
_cell_length_b   6.453
_cell_length_c   8.703
_cell_angle_alpha   89.453
_cell_angle_beta   89.453
_cell_angle_gamma   72.316
_symmetry_Int_Tables_number   1
_cell_volume   345.277
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  1.000  0.486  0.998  1.0
  Li  Li1  1  0.486  1.000  0.498  1.0
  Ag  Ag2  1  0.889  0.332  0.556  1.0
  Ag  Ag3  1  0.671  0.074  0.937  1.0
  Ag  Ag4  1  0.074  0.671  0.437  1.0
  Ag  Ag5  1  0.332  0.889  0.056  1.0
  N  N6  1  0.835  0.835  0.747  1.0
  N  N7  1  0.153  0.161  0.750  1.0
  N  N8  1  0.161  0.153  0.250  1.0
  N  N9  1  0.835  0.835  0.247  1.0
  N  N10  1  0.529  0.423  0.985  1.0
  N  N11  1  0.423  0.529  0.485  1.0
  O  O12  1  0.808  0.898  0.608  1.0
  O  O13  1  0.100  0.180  0.893  1.0
  O  O14  1  0.180  0.100  0.393  1.0
  O  O15  1  0.898  0.808  0.108  1.0
  O  O16  1  0.969  0.652  0.772  1.0
  O  O17  1  0.334  0.028  0.719  1.0
  O  O18  1  0.028  0.334  0.219  1.0
  O  O19  1  0.652  0.969  0.272  1.0
  O  O20  1  0.518  0.329  0.507  1.0
  O  O21  1  0.329  0.518  0.007  1.0
  O  O22  1  0.541  0.652  0.499  1.0
  O  O23  1  0.652  0.541  0.999  1.0
[/CIF]
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The material structure described by LiAg2(NO2)3 crystallizes in the monoclinic Cc space group. Li(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(2), one O(2), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(1), one N(3), and one O(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(2), one O(1), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one O(2), and one O(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one N(3) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one N(3) atom. In the third O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(2), and one N(1) atom. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(1), and one N(2) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Li(1) and one N(1) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one N(2) atom. is represented by the CIF card [CIF]
data_LiAg2(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.453
_cell_length_b   6.453
_cell_length_c   8.703
_cell_angle_alpha   89.453
_cell_angle_beta   89.453
_cell_angle_gamma   72.316
_symmetry_Int_Tables_number   1
_cell_volume   345.277
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  1.000  0.486  0.998  1.0
  Li  Li1  1  0.486  1.000  0.498  1.0
  Ag  Ag2  1  0.889  0.332  0.556  1.0
  Ag  Ag3  1  0.671  0.074  0.937  1.0
  Ag  Ag4  1  0.074  0.671  0.437  1.0
  Ag  Ag5  1  0.332  0.889  0.056  1.0
  N  N6  1  0.835  0.835  0.747  1.0
  N  N7  1  0.153  0.161  0.750  1.0
  N  N8  1  0.161  0.153  0.250  1.0
  N  N9  1  0.835  0.835  0.247  1.0
  N  N10  1  0.529  0.423  0.985  1.0
  N  N11  1  0.423  0.529  0.485  1.0
  O  O12  1  0.808  0.898  0.608  1.0
  O  O13  1  0.100  0.180  0.893  1.0
  O  O14  1  0.180  0.100  0.393  1.0
  O  O15  1  0.898  0.808  0.108  1.0
  O  O16  1  0.969  0.652  0.772  1.0
  O  O17  1  0.334  0.028  0.719  1.0
  O  O18  1  0.028  0.334  0.219  1.0
  O  O19  1  0.652  0.969  0.272  1.0
  O  O20  1  0.518  0.329  0.507  1.0
  O  O21  1  0.329  0.518  0.007  1.0
  O  O22  1  0.541  0.652  0.499  1.0
  O  O23  1  0.652  0.541  0.999  1.0
[/CIF]
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