The crystal structure described by Mn6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(3), one O(6), one O(7), one F(3), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(3)O3F3 octahedra, corners with three equivalent Mn(6)O3F3 octahedra, corners with three equivalent Mn(2)O4F2 octahedra,  an edgeedge with one Mn(5)O3F3 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-59°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(4), one O(6), one F(3), and one F(4) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with three equivalent Mn(5)O3F3 octahedra, corners with three equivalent Mn(1)O4F2 octahedra,  an edgeedge with one Mn(3)O3F3 octahedra, and  an edgeedge with one Mn(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 43-50°. In the third Mn site, Mn(3) is bonded to one O(3), one O(4), one O(5), one F(1), one F(2), and one F(3) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with three equivalent Mn(5)O3F3 octahedra, corners with three equivalent Mn(4)O4F2 octahedra,  an edgeedge with one Mn(6)O3F3 octahedra, and  an edgeedge with one Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-59°. In the fourth Mn site, Mn(4) is bonded to one O(2), one O(4), one O(5), one O(7), one F(1), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O4F2 octahedra, corners with three equivalent Mn(3)O3F3 octahedra, corners with three equivalent Mn(6)O3F3 octahedra,  an edgeedge with one Mn(5)O3F3 octahedra, and  an edgeedge with one Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(5), one O(6), one F(1), one F(2), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(6)O3F3 octahedra, corners with three equivalent Mn(3)O3F3 octahedra, corners with three equivalent Mn(2)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(3), one O(7), one F(2), one F(4), and one F(5) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(5)O3F3 octahedra, corners with three equivalent Mn(1)O4F2 octahedra, corners with three equivalent Mn(4)O4F2 octahedra,  an edgeedge with one Mn(3)O3F3 octahedra, and  an edgeedge with one Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.551
_cell_length_b   5.581
_cell_length_c   7.353
_cell_angle_alpha   73.828
_cell_angle_beta   72.682
_cell_angle_gamma   71.249
_symmetry_Int_Tables_number   1
_cell_volume   201.657
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.302  0.321  0.162  1.0
  Mn  Mn1  1  0.653  0.674  0.324  1.0
  Mn  Mn2  1  0.370  0.337  0.682  1.0
  Mn  Mn3  1  0.646  0.692  0.836  1.0
  Mn  Mn4  1  0.002  0.024  0.496  1.0
  Mn  Mn5  1  0.009  0.971  0.003  1.0
  O  O6  1  0.347  0.982  0.329  1.0
  O  O7  1  0.765  0.764  0.037  1.0
  O  O8  1  0.226  0.209  0.972  1.0
  O  O9  1  0.574  0.578  0.624  1.0
  O  O10  1  0.663  0.047  0.664  1.0
  O  O11  1  0.962  0.374  0.323  1.0
  O  O12  1  0.301  0.667  0.005  1.0
  F  F13  1  0.049  0.639  0.669  1.0
  F  F14  1  0.130  0.117  0.693  1.0
  F  F15  1  0.418  0.426  0.363  1.0
  F  F16  1  0.893  0.900  0.309  1.0
  F  F17  1  0.691  0.279  0.009  1.0
[/CIF]
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The crystal structure described by Mn6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(3), one O(6), one O(7), one F(3), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(3)O3F3 octahedra, corners with three equivalent Mn(6)O3F3 octahedra, corners with three equivalent Mn(2)O4F2 octahedra,  an edgeedge with one Mn(5)O3F3 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-59°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(4), one O(6), one F(3), and one F(4) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with three equivalent Mn(5)O3F3 octahedra, corners with three equivalent Mn(1)O4F2 octahedra,  an edgeedge with one Mn(3)O3F3 octahedra, and  an edgeedge with one Mn(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 43-50°. In the third Mn site, Mn(3) is bonded to one O(3), one O(4), one O(5), one F(1), one F(2), and one F(3) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with three equivalent Mn(5)O3F3 octahedra, corners with three equivalent Mn(4)O4F2 octahedra,  an edgeedge with one Mn(6)O3F3 octahedra, and  an edgeedge with one Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-59°. In the fourth Mn site, Mn(4) is bonded to one O(2), one O(4), one O(5), one O(7), one F(1), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O4F2 octahedra, corners with three equivalent Mn(3)O3F3 octahedra, corners with three equivalent Mn(6)O3F3 octahedra,  an edgeedge with one Mn(5)O3F3 octahedra, and  an edgeedge with one Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(5), one O(6), one F(1), one F(2), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(6)O3F3 octahedra, corners with three equivalent Mn(3)O3F3 octahedra, corners with three equivalent Mn(2)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(3), one O(7), one F(2), one F(4), and one F(5) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(5)O3F3 octahedra, corners with three equivalent Mn(1)O4F2 octahedra, corners with three equivalent Mn(4)O4F2 octahedra,  an edgeedge with one Mn(3)O3F3 octahedra, and  an edgeedge with one Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.551
_cell_length_b   5.581
_cell_length_c   7.353
_cell_angle_alpha   73.828
_cell_angle_beta   72.682
_cell_angle_gamma   71.249
_symmetry_Int_Tables_number   1
_cell_volume   201.657
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.302  0.321  0.162  1.0
  Mn  Mn1  1  0.653  0.674  0.324  1.0
  Mn  Mn2  1  0.370  0.337  0.682  1.0
  Mn  Mn3  1  0.646  0.692  0.836  1.0
  Mn  Mn4  1  0.002  0.024  0.496  1.0
  Mn  Mn5  1  0.009  0.971  0.003  1.0
  O  O6  1  0.347  0.982  0.329  1.0
  O  O7  1  0.765  0.764  0.037  1.0
  O  O8  1  0.226  0.209  0.972  1.0
  O  O9  1  0.574  0.578  0.624  1.0
  O  O10  1  0.663  0.047  0.664  1.0
  O  O11  1  0.962  0.374  0.323  1.0
  O  O12  1  0.301  0.667  0.005  1.0
  F  F13  1  0.049  0.639  0.669  1.0
  F  F14  1  0.130  0.117  0.693  1.0
  F  F15  1  0.418  0.426  0.363  1.0
  F  F16  1  0.893  0.900  0.309  1.0
  F  F17  1  0.691  0.279  0.009  1.0
[/CIF]
.