The structure described by FeCl2(O)4SbCl6(O2)2 is Indium-derived structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one dichloroiron;tetrahydrate molecule, four water atoms, and one SbCl6 cluster. In the SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_FeSb(ClO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.910
_cell_length_b   6.910
_cell_length_c   8.877
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.500  0.500  0.500  1.0
  Cl  Cl2  1  0.000  0.000  0.752  1.0
  Cl  Cl3  1  0.000  0.000  0.248  1.0
  Cl  Cl4  1  0.500  0.500  0.766  1.0
  Cl  Cl5  1  0.500  0.500  0.234  1.0
  Cl  Cl6  1  0.250  0.250  0.500  1.0
  Cl  Cl7  1  0.750  0.750  0.500  1.0
  Cl  Cl8  1  0.750  0.250  0.500  1.0
  Cl  Cl9  1  0.250  0.750  0.500  1.0
  O  O10  1  0.000  0.263  0.000  1.0
  O  O11  1  0.000  0.737  0.000  1.0
  O  O12  1  0.737  0.000  0.000  1.0
  O  O13  1  0.263  0.000  0.000  1.0
  O  O14  1  0.500  0.000  0.687  1.0
  O  O15  1  0.000  0.500  0.687  1.0
  O  O16  1  0.500  0.000  0.313  1.0
  O  O17  1  0.000  0.500  0.313  1.0
[/CIF]
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The structure described by FeCl2(O)4SbCl6(O2)2 is Indium-derived structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one dichloroiron;tetrahydrate molecule, four water atoms, and one SbCl6 cluster. In the SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_FeSb(ClO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.910
_cell_length_b   6.910
_cell_length_c   8.877
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.500  0.500  0.500  1.0
  Cl  Cl2  1  0.000  0.000  0.752  1.0
  Cl  Cl3  1  0.000  0.000  0.248  1.0
  Cl  Cl4  1  0.500  0.500  0.766  1.0
  Cl  Cl5  1  0.500  0.500  0.234  1.0
  Cl  Cl6  1  0.250  0.250  0.500  1.0
  Cl  Cl7  1  0.750  0.750  0.500  1.0
  Cl  Cl8  1  0.750  0.250  0.500  1.0
  Cl  Cl9  1  0.250  0.750  0.500  1.0
  O  O10  1  0.000  0.263  0.000  1.0
  O  O11  1  0.000  0.737  0.000  1.0
  O  O12  1  0.737  0.000  0.000  1.0
  O  O13  1  0.263  0.000  0.000  1.0
  O  O14  1  0.500  0.000  0.687  1.0
  O  O15  1  0.000  0.500  0.687  1.0
  O  O16  1  0.500  0.000  0.313  1.0
  O  O17  1  0.000  0.500  0.313  1.0
[/CIF]
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