The structure described by KMnO2 crystallizes in the monoclinic P2/c space group. K(1) is bonded to six equivalent O(1) atoms to form distorted edge-sharing KO6 octahedra. Mn(1) is bonded in a distorted square co-planar geometry to six equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to three equivalent K(1) and three equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_KMnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.946
_cell_length_b   3.510
_cell_length_c   6.215
_cell_angle_alpha   88.712
_cell_angle_beta   76.292
_cell_angle_gamma   65.189
_symmetry_Int_Tables_number   1
_cell_volume   56.464
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  1.000  0.500  0.500  1.0
  Mn  Mn1  1  0.000  1.000  1.000  1.0
  O  O2  1  0.504  0.176  0.815  1.0
  O  O3  1  0.496  0.824  0.185  1.0
[/CIF]
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The structure described by KMnO2 crystallizes in the monoclinic P2/c space group. K(1) is bonded to six equivalent O(1) atoms to form distorted edge-sharing KO6 octahedra. Mn(1) is bonded in a distorted square co-planar geometry to six equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to three equivalent K(1) and three equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_KMnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.946
_cell_length_b   3.510
_cell_length_c   6.215
_cell_angle_alpha   88.712
_cell_angle_beta   76.292
_cell_angle_gamma   65.189
_symmetry_Int_Tables_number   1
_cell_volume   56.464
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  1.000  0.500  0.500  1.0
  Mn  Mn1  1  0.000  1.000  1.000  1.0
  O  O2  1  0.504  0.176  0.815  1.0
  O  O3  1  0.496  0.824  0.185  1.0
[/CIF]
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