The material described by RhBi crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded to two equivalent Rh(1) and six equivalent Bi(1) atoms to form a mixture of distorted edge, corner, and face-sharing RhBi6Rh2 octahedra. The corner-sharing octahedral tilt angles range from 0-51°. Bi(1) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.134
_cell_length_b   4.134
_cell_length_c   5.687
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.002
_symmetry_Int_Tables_number   1
_cell_volume   84.176
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.667  0.333  0.750  1.0
  Bi  Bi1  1  0.333  0.667  0.250  1.0
  Rh  Rh2  1  0.000  0.000  0.500  1.0
  Rh  Rh3  1  0.000  0.000  0.000  1.0
[/CIF]
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The material described by RhBi crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded to two equivalent Rh(1) and six equivalent Bi(1) atoms to form a mixture of distorted edge, corner, and face-sharing RhBi6Rh2 octahedra. The corner-sharing octahedral tilt angles range from 0-51°. Bi(1) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.134
_cell_length_b   4.134
_cell_length_c   5.687
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.002
_symmetry_Int_Tables_number   1
_cell_volume   84.176
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.667  0.333  0.750  1.0
  Bi  Bi1  1  0.333  0.667  0.250  1.0
  Rh  Rh2  1  0.000  0.000  0.500  1.0
  Rh  Rh3  1  0.000  0.000  0.000  1.0
[/CIF]
.