The compound described by PrS3(NO3)3 crystallizes in the hexagonal P6_3/m space group. Pr(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. N(1) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pr(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Pr(1) and one S(1) atom. is represented by the CIF file [CIF]
data_PrS3(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.964
_cell_length_b   9.964
_cell_length_c   5.898
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   507.133
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.667  0.333  0.750  1.0
  Pr  Pr1  1  0.333  0.667  0.250  1.0
  S  S2  1  0.600  0.914  0.750  1.0
  S  S3  1  0.400  0.086  0.250  1.0
  S  S4  1  0.314  0.400  0.750  1.0
  S  S5  1  0.686  0.600  0.250  1.0
  S  S6  1  0.086  0.686  0.750  1.0
  S  S7  1  0.914  0.314  0.250  1.0
  N  N8  1  0.729  0.856  0.750  1.0
  N  N9  1  0.271  0.144  0.250  1.0
  N  N10  1  0.126  0.271  0.750  1.0
  N  N11  1  0.874  0.729  0.250  1.0
  N  N12  1  0.144  0.874  0.750  1.0
  N  N13  1  0.856  0.126  0.250  1.0
  O  O14  1  0.916  0.607  0.750  1.0
  O  O15  1  0.084  0.393  0.250  1.0
  O  O16  1  0.691  0.084  0.750  1.0
  O  O17  1  0.309  0.916  0.250  1.0
  O  O18  1  0.393  0.309  0.750  1.0
  O  O19  1  0.607  0.691  0.250  1.0
  O  O20  1  0.508  0.850  0.957  1.0
  O  O21  1  0.492  0.150  0.043  1.0
  O  O22  1  0.341  0.492  0.957  1.0
  O  O23  1  0.492  0.150  0.457  1.0
  O  O24  1  0.659  0.508  0.043  1.0
  O  O25  1  0.508  0.850  0.543  1.0
  O  O26  1  0.150  0.659  0.957  1.0
  O  O27  1  0.659  0.508  0.457  1.0
  O  O28  1  0.850  0.341  0.043  1.0
  O  O29  1  0.341  0.492  0.543  1.0
  O  O30  1  0.850  0.341  0.457  1.0
  O  O31  1  0.150  0.659  0.543  1.0
[/CIF]
.
The compound described by PrS3(NO3)3 crystallizes in the hexagonal P6_3/m space group. Pr(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. N(1) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pr(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Pr(1) and one S(1) atom. is represented by the CIF file [CIF]
data_PrS3(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.964
_cell_length_b   9.964
_cell_length_c   5.898
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   507.133
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.667  0.333  0.750  1.0
  Pr  Pr1  1  0.333  0.667  0.250  1.0
  S  S2  1  0.600  0.914  0.750  1.0
  S  S3  1  0.400  0.086  0.250  1.0
  S  S4  1  0.314  0.400  0.750  1.0
  S  S5  1  0.686  0.600  0.250  1.0
  S  S6  1  0.086  0.686  0.750  1.0
  S  S7  1  0.914  0.314  0.250  1.0
  N  N8  1  0.729  0.856  0.750  1.0
  N  N9  1  0.271  0.144  0.250  1.0
  N  N10  1  0.126  0.271  0.750  1.0
  N  N11  1  0.874  0.729  0.250  1.0
  N  N12  1  0.144  0.874  0.750  1.0
  N  N13  1  0.856  0.126  0.250  1.0
  O  O14  1  0.916  0.607  0.750  1.0
  O  O15  1  0.084  0.393  0.250  1.0
  O  O16  1  0.691  0.084  0.750  1.0
  O  O17  1  0.309  0.916  0.250  1.0
  O  O18  1  0.393  0.309  0.750  1.0
  O  O19  1  0.607  0.691  0.250  1.0
  O  O20  1  0.508  0.850  0.957  1.0
  O  O21  1  0.492  0.150  0.043  1.0
  O  O22  1  0.341  0.492  0.957  1.0
  O  O23  1  0.492  0.150  0.457  1.0
  O  O24  1  0.659  0.508  0.043  1.0
  O  O25  1  0.508  0.850  0.543  1.0
  O  O26  1  0.150  0.659  0.957  1.0
  O  O27  1  0.659  0.508  0.457  1.0
  O  O28  1  0.850  0.341  0.043  1.0
  O  O29  1  0.341  0.492  0.543  1.0
  O  O30  1  0.850  0.341  0.457  1.0
  O  O31  1  0.150  0.659  0.543  1.0
[/CIF]
.