The crystal structure described by LiCuCO3 crystallizes in the triclinic P-1 space group. Li(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form edge-sharing LiO4 tetrahedra. Cu(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Cu(1), and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), two equivalent Cu(1), and one C(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1), one Cu(1), and one C(1) atom. is represented by the CIF card [CIF]
data_LiCuCO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.650
_cell_length_b   5.105
_cell_length_c   5.037
_cell_angle_alpha   61.406
_cell_angle_beta   112.684
_cell_angle_gamma   86.971
_symmetry_Int_Tables_number   1
_cell_volume   132.430
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.669  0.635  0.424  1.0
  Li  Li1  1  0.331  0.365  0.576  1.0
  Cu  Cu2  1  0.772  0.261  0.171  1.0
  Cu  Cu3  1  0.228  0.739  0.829  1.0
  C  C4  1  0.740  0.932  0.805  1.0
  C  C5  1  0.260  0.068  0.195  1.0
  O  O6  1  0.739  0.690  0.063  1.0
  O  O7  1  0.786  0.902  0.591  1.0
  O  O8  1  0.692  0.206  0.762  1.0
  O  O9  1  0.308  0.794  0.238  1.0
  O  O10  1  0.214  0.098  0.409  1.0
  O  O11  1  0.261  0.310  0.937  1.0
[/CIF]
.
The crystal structure described by LiCuCO3 crystallizes in the triclinic P-1 space group. Li(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form edge-sharing LiO4 tetrahedra. Cu(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Cu(1), and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), two equivalent Cu(1), and one C(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1), one Cu(1), and one C(1) atom. is represented by the CIF card [CIF]
data_LiCuCO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.650
_cell_length_b   5.105
_cell_length_c   5.037
_cell_angle_alpha   61.406
_cell_angle_beta   112.684
_cell_angle_gamma   86.971
_symmetry_Int_Tables_number   1
_cell_volume   132.430
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.669  0.635  0.424  1.0
  Li  Li1  1  0.331  0.365  0.576  1.0
  Cu  Cu2  1  0.772  0.261  0.171  1.0
  Cu  Cu3  1  0.228  0.739  0.829  1.0
  C  C4  1  0.740  0.932  0.805  1.0
  C  C5  1  0.260  0.068  0.195  1.0
  O  O6  1  0.739  0.690  0.063  1.0
  O  O7  1  0.786  0.902  0.591  1.0
  O  O8  1  0.692  0.206  0.762  1.0
  O  O9  1  0.308  0.794  0.238  1.0
  O  O10  1  0.214  0.098  0.409  1.0
  O  O11  1  0.261  0.310  0.937  1.0
[/CIF]
.