The material described by AgS16SbF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgS16 clusters and four SbF6 clusters. In each AgS16 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(5) and two equivalent S(6) atoms. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(8) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(1) and one S(7) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(5) and one S(6) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(4), and one S(7) atom. In the sixth S site, S(6) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(4), and one S(8) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one S(2) and one S(6) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3) atoms. There are two inequivalent F sites. In the first F site, F(1,3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgSb(S8F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.112
_cell_length_b   10.112
_cell_length_c   16.378
_cell_angle_alpha   79.529
_cell_angle_beta   79.529
_cell_angle_gamma   48.176
_symmetry_Int_Tables_number   1
_cell_volume   1223.005
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.167  0.833  0.750  1.0
  Ag  Ag1  1  0.833  0.167  0.250  1.0
  Sb  Sb2  1  0.500  0.500  0.000  1.0
  Sb  Sb3  1  0.500  0.500  0.500  1.0
  S  S4  1  0.087  0.276  0.583  1.0
  S  S5  1  0.990  0.715  0.937  1.0
  S  S6  1  0.299  0.899  0.171  1.0
  S  S7  1  0.959  0.360  0.333  1.0
  S  S8  1  0.101  0.701  0.329  1.0
  S  S9  1  0.098  0.066  0.849  1.0
  S  S10  1  0.524  0.216  0.258  1.0
  S  S11  1  0.902  0.934  0.151  1.0
  S  S12  1  0.216  0.524  0.758  1.0
  S  S13  1  0.784  0.476  0.242  1.0
  S  S14  1  0.899  0.299  0.671  1.0
  S  S15  1  0.701  0.101  0.829  1.0
  S  S16  1  0.066  0.098  0.349  1.0
  S  S17  1  0.913  0.724  0.417  1.0
  S  S18  1  0.010  0.285  0.063  1.0
  S  S19  1  0.041  0.640  0.667  1.0
  S  S20  1  0.715  0.990  0.437  1.0
  S  S21  1  0.640  0.041  0.167  1.0
  S  S22  1  0.682  0.066  0.714  1.0
  S  S23  1  0.934  0.902  0.651  1.0
  S  S24  1  0.066  0.682  0.214  1.0
  S  S25  1  0.318  0.934  0.286  1.0
  S  S26  1  0.285  0.010  0.563  1.0
  S  S27  1  0.499  0.899  0.628  1.0
  S  S28  1  0.899  0.499  0.128  1.0
  S  S29  1  0.724  0.913  0.917  1.0
  S  S30  1  0.476  0.784  0.742  1.0
  S  S31  1  0.101  0.501  0.872  1.0
  S  S32  1  0.501  0.101  0.372  1.0
  S  S33  1  0.934  0.318  0.786  1.0
  S  S34  1  0.360  0.959  0.833  1.0
  S  S35  1  0.276  0.087  0.083  1.0
  F  F36  1  0.258  0.706  0.478  1.0
  F  F37  1  0.568  0.641  0.465  1.0
  F  F38  1  0.742  0.294  0.522  1.0
  F  F39  1  0.563  0.451  0.113  1.0
  F  F40  1  0.359  0.432  0.035  1.0
  F  F41  1  0.451  0.563  0.613  1.0
  F  F42  1  0.437  0.549  0.887  1.0
  F  F43  1  0.641  0.568  0.965  1.0
  F  F44  1  0.706  0.258  0.978  1.0
  F  F45  1  0.549  0.437  0.387  1.0
  F  F46  1  0.294  0.742  0.022  1.0
  F  F47  1  0.432  0.359  0.535  1.0
[/CIF]
.
The material described by AgS16SbF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgS16 clusters and four SbF6 clusters. In each AgS16 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(5) and two equivalent S(6) atoms. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(8) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(1) and one S(7) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(5) and one S(6) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(4), and one S(7) atom. In the sixth S site, S(6) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(4), and one S(8) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one S(2) and one S(6) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3) atoms. There are two inequivalent F sites. In the first F site, F(1,3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgSb(S8F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.112
_cell_length_b   10.112
_cell_length_c   16.378
_cell_angle_alpha   79.529
_cell_angle_beta   79.529
_cell_angle_gamma   48.176
_symmetry_Int_Tables_number   1
_cell_volume   1223.005
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.167  0.833  0.750  1.0
  Ag  Ag1  1  0.833  0.167  0.250  1.0
  Sb  Sb2  1  0.500  0.500  0.000  1.0
  Sb  Sb3  1  0.500  0.500  0.500  1.0
  S  S4  1  0.087  0.276  0.583  1.0
  S  S5  1  0.990  0.715  0.937  1.0
  S  S6  1  0.299  0.899  0.171  1.0
  S  S7  1  0.959  0.360  0.333  1.0
  S  S8  1  0.101  0.701  0.329  1.0
  S  S9  1  0.098  0.066  0.849  1.0
  S  S10  1  0.524  0.216  0.258  1.0
  S  S11  1  0.902  0.934  0.151  1.0
  S  S12  1  0.216  0.524  0.758  1.0
  S  S13  1  0.784  0.476  0.242  1.0
  S  S14  1  0.899  0.299  0.671  1.0
  S  S15  1  0.701  0.101  0.829  1.0
  S  S16  1  0.066  0.098  0.349  1.0
  S  S17  1  0.913  0.724  0.417  1.0
  S  S18  1  0.010  0.285  0.063  1.0
  S  S19  1  0.041  0.640  0.667  1.0
  S  S20  1  0.715  0.990  0.437  1.0
  S  S21  1  0.640  0.041  0.167  1.0
  S  S22  1  0.682  0.066  0.714  1.0
  S  S23  1  0.934  0.902  0.651  1.0
  S  S24  1  0.066  0.682  0.214  1.0
  S  S25  1  0.318  0.934  0.286  1.0
  S  S26  1  0.285  0.010  0.563  1.0
  S  S27  1  0.499  0.899  0.628  1.0
  S  S28  1  0.899  0.499  0.128  1.0
  S  S29  1  0.724  0.913  0.917  1.0
  S  S30  1  0.476  0.784  0.742  1.0
  S  S31  1  0.101  0.501  0.872  1.0
  S  S32  1  0.501  0.101  0.372  1.0
  S  S33  1  0.934  0.318  0.786  1.0
  S  S34  1  0.360  0.959  0.833  1.0
  S  S35  1  0.276  0.087  0.083  1.0
  F  F36  1  0.258  0.706  0.478  1.0
  F  F37  1  0.568  0.641  0.465  1.0
  F  F38  1  0.742  0.294  0.522  1.0
  F  F39  1  0.563  0.451  0.113  1.0
  F  F40  1  0.359  0.432  0.035  1.0
  F  F41  1  0.451  0.563  0.613  1.0
  F  F42  1  0.437  0.549  0.887  1.0
  F  F43  1  0.641  0.568  0.965  1.0
  F  F44  1  0.706  0.258  0.978  1.0
  F  F45  1  0.549  0.437  0.387  1.0
  F  F46  1  0.294  0.742  0.022  1.0
  F  F47  1  0.432  0.359  0.535  1.0
[/CIF]
.