The compound described by MnF3 crystallizes in the monoclinic P2/m space group. Mn(1,2) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 0-18°. There are four inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Mn(1,2) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Mn(1,2) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent Mn(1,2) atoms. In the fourth F site, F(4) is bonded in a linear geometry to two equivalent Mn(1,2) atoms. is represented by the CIF file [CIF]
data_MnF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.829
_cell_length_b   5.329
_cell_length_c   5.363
_cell_angle_alpha   90.010
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   109.417
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.500  1.000  1.0
  Mn  Mn1  1  0.500  1.000  0.500  1.0
  F  F2  1  1.000  0.500  0.000  1.0
  F  F3  1  0.500  0.289  0.291  1.0
  F  F4  1  0.500  0.209  0.790  1.0
  F  F5  1  1.000  1.000  0.500  1.0
  F  F6  1  0.500  0.791  0.210  1.0
  F  F7  1  0.500  0.711  0.709  1.0
[/CIF]
.
The compound described by MnF3 crystallizes in the monoclinic P2/m space group. Mn(1,2) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 0-18°. There are four inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Mn(1,2) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Mn(1,2) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent Mn(1,2) atoms. In the fourth F site, F(4) is bonded in a linear geometry to two equivalent Mn(1,2) atoms. is represented by the CIF file [CIF]
data_MnF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.829
_cell_length_b   5.329
_cell_length_c   5.363
_cell_angle_alpha   90.010
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   109.417
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.500  1.000  1.0
  Mn  Mn1  1  0.500  1.000  0.500  1.0
  F  F2  1  1.000  0.500  0.000  1.0
  F  F3  1  0.500  0.289  0.291  1.0
  F  F4  1  0.500  0.209  0.790  1.0
  F  F5  1  1.000  1.000  0.500  1.0
  F  F6  1  0.500  0.791  0.210  1.0
  F  F7  1  0.500  0.711  0.709  1.0
[/CIF]
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