The material described by Li6V2OF11 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one F(10), one F(13), one F(16), one F(19), one F(3), and one F(5) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one F(14), one F(15), one F(20), one F(4), one F(6), and one F(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one F(1), one F(11), one F(15), one F(17), one F(22), and one F(7) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one F(12), one F(16), one F(18), one F(2), one F(21), and one F(8) atom. In the fifth Li site, Li(5) is bonded to one O(1), one F(11), one F(19), one F(4), one F(5), and one F(7) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(8)F6 octahedra,  a cornercorner with one V(1)OF5 octahedra, corners with two equivalent Li(9)OF5 octahedra, corners with two equivalent V(3)OF5 octahedra, edges with two equivalent V(4)OF5 octahedra, and  a faceface with one Li(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the sixth Li site, Li(6) is bonded to one O(2), one F(12), one F(20), one F(3), one F(6), and one F(8) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(7)F6 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent Li(10)OF5 octahedra, corners with two equivalent V(1)OF5 octahedra, edges with two equivalent V(2)OF5 octahedra, and  a faceface with one Li(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. In the seventh Li site, Li(7) is bonded to one F(1), one F(14), one F(15), one F(21), one F(6), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(6)OF5 octahedra,  a cornercorner with one V(4)OF5 octahedra, corners with two equivalent Li(12)F6 octahedra, corners with two equivalent V(2)OF5 octahedra,  an edgeedge with one V(3)OF5 octahedra, and  a faceface with one Li(11)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-66°. In the eighth Li site, Li(8) is bonded to one F(10), one F(13), one F(16), one F(2), one F(22), and one F(5) atom to form LiF6 octahedra that share  a cornercorner with one Li(5)OF5 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(11)F6 octahedra, corners with two equivalent V(4)OF5 octahedra,  an edgeedge with one V(1)OF5 octahedra, and  a faceface with one Li(12)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-66°. In the ninth Li site, Li(9) is bonded to one O(2), one F(12), one F(17), one F(19), one F(3), and one F(7) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(11)F6 octahedra,  a cornercorner with one V(4)OF5 octahedra, corners with two equivalent Li(5)OF5 octahedra, corners with two equivalent V(2)OF5 octahedra, edges with two equivalent V(1)OF5 octahedra, and  a faceface with one Li(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the tenth Li site, Li(10) is bonded to one O(1), one F(11), one F(18), one F(20), one F(4), and one F(8) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(12)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(6)OF5 octahedra, corners with two equivalent V(4)OF5 octahedra, edges with two equivalent V(3)OF5 octahedra, and  a faceface with one Li(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-63°. In the eleventh Li site, Li(11) is bonded to one F(1), one F(10), one F(14), one F(15), one F(17), and one F(22) atom to form LiF6 octahedra that share  a cornercorner with one Li(9)OF5 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent Li(8)F6 octahedra, corners with two equivalent V(1)OF5 octahedra,  an edgeedge with one V(4)OF5 octahedra, and  a faceface with one Li(7)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-66°. In the twelfth Li site, Li(12) is bonded to one F(13), one F(16), one F(18), one F(2), one F(21), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(10)OF5 octahedra,  a cornercorner with one V(1)OF5 octahedra, corners with two equivalent Li(7)F6 octahedra, corners with two equivalent V(3)OF5 octahedra,  an edgeedge with one V(2)OF5 octahedra, and  a faceface with one Li(8)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-66°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one F(12), one F(17), one F(2), one F(22), and one F(7) atom to form VOF5 octahedra that share  a cornercorner with one Li(12)F6 octahedra,  a cornercorner with one Li(5)OF5 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(11)F6 octahedra, corners with two equivalent Li(6)OF5 octahedra,  an edgeedge with one Li(8)F6 octahedra, and edges with two equivalent Li(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-51°. In the second V site, V(2) is bonded to one O(2), one F(13), one F(20), one F(3), one F(6), and one F(9) atom to form VOF5 octahedra that share  a cornercorner with one Li(8)F6 octahedra,  a cornercorner with one Li(10)OF5 octahedra,  a cornercorner with one V(1)OF5 octahedra, corners with two equivalent Li(7)F6 octahedra, corners with two equivalent Li(9)OF5 octahedra,  an edgeedge with one Li(12)F6 octahedra, and edges with two equivalent Li(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the third V site, V(3) is bonded to one O(1), one F(1), one F(11), one F(18), one F(21), and one F(8) atom to form VOF5 octahedra that share  a cornercorner with one Li(11)F6 octahedra,  a cornercorner with one Li(6)OF5 octahedra,  a cornercorner with one V(4)OF5 octahedra, corners with two equivalent Li(12)F6 octahedra, corners with two equivalent Li(5)OF5 octahedra,  an edgeedge with one Li(7)F6 octahedra, and edges with two equivalent Li(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the fourth V site, V(4) is bonded to one O(1), one F(10), one F(14), one F(19), one F(4), and one F(5) atom to form VOF5 octahedra that share  a cornercorner with one Li(7)F6 octahedra,  a cornercorner with one Li(9)OF5 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent Li(8)F6 octahedra, corners with two equivalent Li(10)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra, and edges with two equivalent Li(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(10), one Li(5), one V(3), and one V(4) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(6), one Li(9), one V(1), and one V(2) atom. There are twenty-two inequivalent F sites. In the first F site, F(1) is bonded to one Li(11), one Li(3), one Li(7), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(10)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid,  a cornercorner with one F(9)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(11)Li3V trigonal pyramids, corners with two equivalent F(17)Li3V trigonal pyramids,  an edgeedge with one F(14)Li3V trigonal pyramid,  an edgeedge with one F(21)Li3V trigonal pyramid,  an edgeedge with one F(22)Li3V trigonal pyramid, and  an edgeedge with one F(15)Li4 trigonal pyramid. In the second F site, F(2) is bonded to one Li(12), one Li(4), one Li(8), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(10)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid,  a cornercorner with one F(9)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(12)Li3V trigonal pyramids, corners with two equivalent F(18)Li3V trigonal pyramids,  an edgeedge with one F(13)Li3V trigonal pyramid,  an edgeedge with one F(21)Li3V trigonal pyramid,  an edgeedge with one F(22)Li3V trigonal pyramid, and  an edgeedge with one F(16)Li4 trigonal pyramid. In the third F site, F(3) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(6), one Li(9), and one V(2) atom. In the fourth F site, F(4) is bonded in a distorted see-saw-like geometry to one Li(10), one Li(2), one Li(5), and one V(4) atom. In the fifth F site, F(5) is bonded in a 4-coordinate geometry to one Li(1), one Li(5), one Li(8), and one V(4) atom. In the sixth F site, F(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(6), one Li(7), and one V(2) atom. In the seventh F site, F(7) is bonded to one Li(3), one Li(5), one Li(9), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(19)Li3V trigonal pyramids,  an edgeedge with one F(11)Li3V trigonal pyramid,  an edgeedge with one F(12)Li3V trigonal pyramid,  an edgeedge with one F(17)Li3V trigonal pyramid, and  an edgeedge with one F(22)Li3V trigonal pyramid. In the eighth F site, F(8) is bonded to one Li(10), one Li(4), one Li(6), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(20)Li3V trigonal pyramids,  an edgeedge with one F(11)Li3V trigonal pyramid,  an edgeedge with one F(12)Li3V trigonal pyramid,  an edgeedge with one F(18)Li3V trigonal pyramid, and  an edgeedge with one F(21)Li3V trigonal pyramid. In the ninth F site, F(9) is bonded to one Li(12), one Li(2), one Li(7), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(21)Li3V trigonal pyramids, corners with two equivalent F(15)Li4 trigonal pyramids,  an edgeedge with one F(13)Li3V trigonal pyramid,  an edgeedge with one F(14)Li3V trigonal pyramid, and  an edgeedge with one F(20)Li3V trigonal pyramid. In the tenth F site, F(10) is bonded to one Li(1), one Li(11), one Li(8), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(22)Li3V trigonal pyramids, corners with two equivalent F(16)Li4 trigonal pyramids,  an edgeedge with one F(13)Li3V trigonal pyramid,  an edgeedge with one F(14)Li3V trigonal pyramid, and  an edgeedge with one F(19)Li3V trigonal pyramid. In the eleventh F site, F(11) is bonded to one Li(10), one Li(3), one Li(5), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(1)Li3V trigonal pyramids, corners with two equivalent F(18)Li3V trigonal pyramids,  an edgeedge with one F(7)Li3V trigonal pyramid, and  an edgeedge with one F(8)Li3V trigonal pyramid. In the twelfth F site, F(12) is bonded to one Li(4), one Li(6), one Li(9), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(17)Li3V trigonal pyramids, corners with two equivalent F(2)Li3V trigonal pyramids,  an edgeedge with one F(7)Li3V trigonal pyramid, and  an edgeedge with one F(8)Li3V trigonal pyramid. In the thirteenth F site, F(13) is bonded to one Li(1), one Li(12), one Li(8), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid,  an edgeedge with one F(10)Li3V trigonal pyramid,  an edgeedge with one F(2)Li3V trigonal pyramid,  an edgeedge with one F(9)Li3V trigonal pyramid, and  an edgeedge with one F(16)Li4 trigonal pyramid. In the fourteenth F site, F(14) is bonded to one Li(11), one Li(2), one Li(7), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid,  an edgeedge with one F(1)Li3V trigonal pyramid,  an edgeedge with one F(10)Li3V trigonal pyramid,  an edgeedge with one F(9)Li3V trigonal pyramid, and  an edgeedge with one F(15)Li4 trigonal pyramid. In the fifteenth F site, F(15) is bonded to one Li(11), one Li(2), one Li(3), and one Li(7) atom to form a mixture of distorted corner and edge-sharing FLi4 trigonal pyramids. In the sixteenth F site, F(16) is bonded to one Li(1), one Li(12), one Li(4), and one Li(8) atom to form a mixture of distorted corner and edge-sharing FLi4 trigonal pyramids. In the seventeenth F site, F(17) is bonded to one Li(11), one Li(3), one Li(9), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(10)Li3V trigonal pyramid,  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid, corners with two equivalent F(1)Li3V trigonal pyramids, corners with two equivalent F(12)Li3V trigonal pyramids,  an edgeedge with one F(22)Li3V trigonal pyramid,  an edgeedge with one F(7)Li3V trigonal pyramid, and  an edgeedge with one F(15)Li4 trigonal pyramid. In the eighteenth F site, F(18) is bonded to one Li(10), one Li(12), one Li(4), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid,  a cornercorner with one F(9)Li3V trigonal pyramid, corners with two equivalent F(11)Li3V trigonal pyramids, corners with two equivalent F(2)Li3V trigonal pyramids,  an edgeedge with one F(21)Li3V trigonal pyramid,  an edgeedge with one F(8)Li3V trigonal pyramid, and  an edgeedge with one F(16)Li4 trigonal pyramid. In the nineteenth F site, F(19) is bonded to one Li(1), one Li(5), one Li(9), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(7)Li3V trigonal pyramids, and  an edgeedge with one F(10)Li3V trigonal pyramid. In the twentieth F site, F(20) is bonded to one Li(10), one Li(2), one Li(6), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(8)Li3V trigonal pyramids, and  an edgeedge with one F(9)Li3V trigonal pyramid. In the twenty-first F site, F(21) is bonded to one Li(12), one Li(4), one Li(7), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(9)Li3V trigonal pyramids, corners with two equivalent F(16)Li4 trigonal pyramids,  an edgeedge with one F(1)Li3V trigonal pyramid,  an edgeedge with one F(18)Li3V trigonal pyramid,  an edgeedge with one F(2)Li3V trigonal pyramid, and  an edgeedge with one F(8)Li3V trigonal pyramid. In the twenty-second F site, F(22) is bonded to one Li(11), one Li(3), one Li(8), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(10)Li3V trigonal pyramids, corners with two equivalent F(15)Li4 trigonal pyramids,  an edgeedge with one F(1)Li3V trigonal pyramid,  an edgeedge with one F(17)Li3V trigonal pyramid,  an edgeedge with one F(2)Li3V trigonal pyramid, and  an edgeedge with one F(7)Li3V trigonal pyramid. is represented by the CIF file [CIF]
data_Li6V2OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.124
_cell_length_b   5.507
_cell_length_c   8.800
_cell_angle_alpha   74.020
_cell_angle_beta   89.365
_cell_angle_gamma   62.537
_symmetry_Int_Tables_number   1
_cell_volume   209.841
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.220  0.262  0.294  1.0
  F  F1  1  0.715  0.244  0.780  1.0
  F  F2  1  0.307  0.774  0.865  1.0
  F  F3  1  0.278  0.743  0.528  1.0
  F  F4  1  0.775  0.751  0.027  1.0
  F  F5  1  0.692  0.263  0.465  1.0
  F  F6  1  0.229  0.237  0.963  1.0
  F  F7  1  0.670  0.248  0.125  1.0
  F  F8  1  0.832  0.728  0.385  1.0
  F  F9  1  0.772  0.759  0.724  1.0
  F  F10  1  0.278  0.735  0.239  1.0
  Li  Li11  1  0.800  0.398  0.945  1.0
  Li  Li12  1  0.943  0.102  0.306  1.0
  Li  Li13  1  0.025  0.942  0.667  1.0
  Li  Li14  1  0.242  0.550  0.069  1.0
  Li  Li15  1  0.708  0.562  0.587  1.0
  Li  Li16  1  0.549  0.946  0.185  1.0
  O  O17  1  0.221  0.261  0.615  1.0
  V  V18  1  0.258  0.462  0.436  1.0
  V  V19  1  0.490  0.027  0.830  1.0
[/CIF]
.
The material described by Li6V2OF11 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one F(10), one F(13), one F(16), one F(19), one F(3), and one F(5) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one F(14), one F(15), one F(20), one F(4), one F(6), and one F(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one F(1), one F(11), one F(15), one F(17), one F(22), and one F(7) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one F(12), one F(16), one F(18), one F(2), one F(21), and one F(8) atom. In the fifth Li site, Li(5) is bonded to one O(1), one F(11), one F(19), one F(4), one F(5), and one F(7) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(8)F6 octahedra,  a cornercorner with one V(1)OF5 octahedra, corners with two equivalent Li(9)OF5 octahedra, corners with two equivalent V(3)OF5 octahedra, edges with two equivalent V(4)OF5 octahedra, and  a faceface with one Li(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the sixth Li site, Li(6) is bonded to one O(2), one F(12), one F(20), one F(3), one F(6), and one F(8) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(7)F6 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent Li(10)OF5 octahedra, corners with two equivalent V(1)OF5 octahedra, edges with two equivalent V(2)OF5 octahedra, and  a faceface with one Li(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. In the seventh Li site, Li(7) is bonded to one F(1), one F(14), one F(15), one F(21), one F(6), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(6)OF5 octahedra,  a cornercorner with one V(4)OF5 octahedra, corners with two equivalent Li(12)F6 octahedra, corners with two equivalent V(2)OF5 octahedra,  an edgeedge with one V(3)OF5 octahedra, and  a faceface with one Li(11)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-66°. In the eighth Li site, Li(8) is bonded to one F(10), one F(13), one F(16), one F(2), one F(22), and one F(5) atom to form LiF6 octahedra that share  a cornercorner with one Li(5)OF5 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(11)F6 octahedra, corners with two equivalent V(4)OF5 octahedra,  an edgeedge with one V(1)OF5 octahedra, and  a faceface with one Li(12)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-66°. In the ninth Li site, Li(9) is bonded to one O(2), one F(12), one F(17), one F(19), one F(3), and one F(7) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(11)F6 octahedra,  a cornercorner with one V(4)OF5 octahedra, corners with two equivalent Li(5)OF5 octahedra, corners with two equivalent V(2)OF5 octahedra, edges with two equivalent V(1)OF5 octahedra, and  a faceface with one Li(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the tenth Li site, Li(10) is bonded to one O(1), one F(11), one F(18), one F(20), one F(4), and one F(8) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(12)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(6)OF5 octahedra, corners with two equivalent V(4)OF5 octahedra, edges with two equivalent V(3)OF5 octahedra, and  a faceface with one Li(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-63°. In the eleventh Li site, Li(11) is bonded to one F(1), one F(10), one F(14), one F(15), one F(17), and one F(22) atom to form LiF6 octahedra that share  a cornercorner with one Li(9)OF5 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent Li(8)F6 octahedra, corners with two equivalent V(1)OF5 octahedra,  an edgeedge with one V(4)OF5 octahedra, and  a faceface with one Li(7)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-66°. In the twelfth Li site, Li(12) is bonded to one F(13), one F(16), one F(18), one F(2), one F(21), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(10)OF5 octahedra,  a cornercorner with one V(1)OF5 octahedra, corners with two equivalent Li(7)F6 octahedra, corners with two equivalent V(3)OF5 octahedra,  an edgeedge with one V(2)OF5 octahedra, and  a faceface with one Li(8)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-66°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one F(12), one F(17), one F(2), one F(22), and one F(7) atom to form VOF5 octahedra that share  a cornercorner with one Li(12)F6 octahedra,  a cornercorner with one Li(5)OF5 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(11)F6 octahedra, corners with two equivalent Li(6)OF5 octahedra,  an edgeedge with one Li(8)F6 octahedra, and edges with two equivalent Li(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-51°. In the second V site, V(2) is bonded to one O(2), one F(13), one F(20), one F(3), one F(6), and one F(9) atom to form VOF5 octahedra that share  a cornercorner with one Li(8)F6 octahedra,  a cornercorner with one Li(10)OF5 octahedra,  a cornercorner with one V(1)OF5 octahedra, corners with two equivalent Li(7)F6 octahedra, corners with two equivalent Li(9)OF5 octahedra,  an edgeedge with one Li(12)F6 octahedra, and edges with two equivalent Li(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the third V site, V(3) is bonded to one O(1), one F(1), one F(11), one F(18), one F(21), and one F(8) atom to form VOF5 octahedra that share  a cornercorner with one Li(11)F6 octahedra,  a cornercorner with one Li(6)OF5 octahedra,  a cornercorner with one V(4)OF5 octahedra, corners with two equivalent Li(12)F6 octahedra, corners with two equivalent Li(5)OF5 octahedra,  an edgeedge with one Li(7)F6 octahedra, and edges with two equivalent Li(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the fourth V site, V(4) is bonded to one O(1), one F(10), one F(14), one F(19), one F(4), and one F(5) atom to form VOF5 octahedra that share  a cornercorner with one Li(7)F6 octahedra,  a cornercorner with one Li(9)OF5 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent Li(8)F6 octahedra, corners with two equivalent Li(10)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra, and edges with two equivalent Li(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(10), one Li(5), one V(3), and one V(4) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(6), one Li(9), one V(1), and one V(2) atom. There are twenty-two inequivalent F sites. In the first F site, F(1) is bonded to one Li(11), one Li(3), one Li(7), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(10)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid,  a cornercorner with one F(9)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(11)Li3V trigonal pyramids, corners with two equivalent F(17)Li3V trigonal pyramids,  an edgeedge with one F(14)Li3V trigonal pyramid,  an edgeedge with one F(21)Li3V trigonal pyramid,  an edgeedge with one F(22)Li3V trigonal pyramid, and  an edgeedge with one F(15)Li4 trigonal pyramid. In the second F site, F(2) is bonded to one Li(12), one Li(4), one Li(8), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(10)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid,  a cornercorner with one F(9)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(12)Li3V trigonal pyramids, corners with two equivalent F(18)Li3V trigonal pyramids,  an edgeedge with one F(13)Li3V trigonal pyramid,  an edgeedge with one F(21)Li3V trigonal pyramid,  an edgeedge with one F(22)Li3V trigonal pyramid, and  an edgeedge with one F(16)Li4 trigonal pyramid. In the third F site, F(3) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(6), one Li(9), and one V(2) atom. In the fourth F site, F(4) is bonded in a distorted see-saw-like geometry to one Li(10), one Li(2), one Li(5), and one V(4) atom. In the fifth F site, F(5) is bonded in a 4-coordinate geometry to one Li(1), one Li(5), one Li(8), and one V(4) atom. In the sixth F site, F(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(6), one Li(7), and one V(2) atom. In the seventh F site, F(7) is bonded to one Li(3), one Li(5), one Li(9), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(19)Li3V trigonal pyramids,  an edgeedge with one F(11)Li3V trigonal pyramid,  an edgeedge with one F(12)Li3V trigonal pyramid,  an edgeedge with one F(17)Li3V trigonal pyramid, and  an edgeedge with one F(22)Li3V trigonal pyramid. In the eighth F site, F(8) is bonded to one Li(10), one Li(4), one Li(6), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(20)Li3V trigonal pyramids,  an edgeedge with one F(11)Li3V trigonal pyramid,  an edgeedge with one F(12)Li3V trigonal pyramid,  an edgeedge with one F(18)Li3V trigonal pyramid, and  an edgeedge with one F(21)Li3V trigonal pyramid. In the ninth F site, F(9) is bonded to one Li(12), one Li(2), one Li(7), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(21)Li3V trigonal pyramids, corners with two equivalent F(15)Li4 trigonal pyramids,  an edgeedge with one F(13)Li3V trigonal pyramid,  an edgeedge with one F(14)Li3V trigonal pyramid, and  an edgeedge with one F(20)Li3V trigonal pyramid. In the tenth F site, F(10) is bonded to one Li(1), one Li(11), one Li(8), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(22)Li3V trigonal pyramids, corners with two equivalent F(16)Li4 trigonal pyramids,  an edgeedge with one F(13)Li3V trigonal pyramid,  an edgeedge with one F(14)Li3V trigonal pyramid, and  an edgeedge with one F(19)Li3V trigonal pyramid. In the eleventh F site, F(11) is bonded to one Li(10), one Li(3), one Li(5), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(1)Li3V trigonal pyramids, corners with two equivalent F(18)Li3V trigonal pyramids,  an edgeedge with one F(7)Li3V trigonal pyramid, and  an edgeedge with one F(8)Li3V trigonal pyramid. In the twelfth F site, F(12) is bonded to one Li(4), one Li(6), one Li(9), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(17)Li3V trigonal pyramids, corners with two equivalent F(2)Li3V trigonal pyramids,  an edgeedge with one F(7)Li3V trigonal pyramid, and  an edgeedge with one F(8)Li3V trigonal pyramid. In the thirteenth F site, F(13) is bonded to one Li(1), one Li(12), one Li(8), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid,  an edgeedge with one F(10)Li3V trigonal pyramid,  an edgeedge with one F(2)Li3V trigonal pyramid,  an edgeedge with one F(9)Li3V trigonal pyramid, and  an edgeedge with one F(16)Li4 trigonal pyramid. In the fourteenth F site, F(14) is bonded to one Li(11), one Li(2), one Li(7), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid,  an edgeedge with one F(1)Li3V trigonal pyramid,  an edgeedge with one F(10)Li3V trigonal pyramid,  an edgeedge with one F(9)Li3V trigonal pyramid, and  an edgeedge with one F(15)Li4 trigonal pyramid. In the fifteenth F site, F(15) is bonded to one Li(11), one Li(2), one Li(3), and one Li(7) atom to form a mixture of distorted corner and edge-sharing FLi4 trigonal pyramids. In the sixteenth F site, F(16) is bonded to one Li(1), one Li(12), one Li(4), and one Li(8) atom to form a mixture of distorted corner and edge-sharing FLi4 trigonal pyramids. In the seventeenth F site, F(17) is bonded to one Li(11), one Li(3), one Li(9), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(10)Li3V trigonal pyramid,  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(22)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid, corners with two equivalent F(1)Li3V trigonal pyramids, corners with two equivalent F(12)Li3V trigonal pyramids,  an edgeedge with one F(22)Li3V trigonal pyramid,  an edgeedge with one F(7)Li3V trigonal pyramid, and  an edgeedge with one F(15)Li4 trigonal pyramid. In the eighteenth F site, F(18) is bonded to one Li(10), one Li(12), one Li(4), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(20)Li3V trigonal pyramid,  a cornercorner with one F(21)Li3V trigonal pyramid,  a cornercorner with one F(8)Li3V trigonal pyramid,  a cornercorner with one F(9)Li3V trigonal pyramid, corners with two equivalent F(11)Li3V trigonal pyramids, corners with two equivalent F(2)Li3V trigonal pyramids,  an edgeedge with one F(21)Li3V trigonal pyramid,  an edgeedge with one F(8)Li3V trigonal pyramid, and  an edgeedge with one F(16)Li4 trigonal pyramid. In the nineteenth F site, F(19) is bonded to one Li(1), one Li(5), one Li(9), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(7)Li3V trigonal pyramids, and  an edgeedge with one F(10)Li3V trigonal pyramid. In the twentieth F site, F(20) is bonded to one Li(10), one Li(2), one Li(6), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(8)Li3V trigonal pyramids, and  an edgeedge with one F(9)Li3V trigonal pyramid. In the twenty-first F site, F(21) is bonded to one Li(12), one Li(4), one Li(7), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(18)Li3V trigonal pyramid,  a cornercorner with one F(15)Li4 trigonal pyramid, corners with two equivalent F(9)Li3V trigonal pyramids, corners with two equivalent F(16)Li4 trigonal pyramids,  an edgeedge with one F(1)Li3V trigonal pyramid,  an edgeedge with one F(18)Li3V trigonal pyramid,  an edgeedge with one F(2)Li3V trigonal pyramid, and  an edgeedge with one F(8)Li3V trigonal pyramid. In the twenty-second F site, F(22) is bonded to one Li(11), one Li(3), one Li(8), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(11)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(13)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(16)Li4 trigonal pyramid, corners with two equivalent F(10)Li3V trigonal pyramids, corners with two equivalent F(15)Li4 trigonal pyramids,  an edgeedge with one F(1)Li3V trigonal pyramid,  an edgeedge with one F(17)Li3V trigonal pyramid,  an edgeedge with one F(2)Li3V trigonal pyramid, and  an edgeedge with one F(7)Li3V trigonal pyramid. is represented by the CIF file [CIF]
data_Li6V2OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.124
_cell_length_b   5.507
_cell_length_c   8.800
_cell_angle_alpha   74.020
_cell_angle_beta   89.365
_cell_angle_gamma   62.537
_symmetry_Int_Tables_number   1
_cell_volume   209.841
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.220  0.262  0.294  1.0
  F  F1  1  0.715  0.244  0.780  1.0
  F  F2  1  0.307  0.774  0.865  1.0
  F  F3  1  0.278  0.743  0.528  1.0
  F  F4  1  0.775  0.751  0.027  1.0
  F  F5  1  0.692  0.263  0.465  1.0
  F  F6  1  0.229  0.237  0.963  1.0
  F  F7  1  0.670  0.248  0.125  1.0
  F  F8  1  0.832  0.728  0.385  1.0
  F  F9  1  0.772  0.759  0.724  1.0
  F  F10  1  0.278  0.735  0.239  1.0
  Li  Li11  1  0.800  0.398  0.945  1.0
  Li  Li12  1  0.943  0.102  0.306  1.0
  Li  Li13  1  0.025  0.942  0.667  1.0
  Li  Li14  1  0.242  0.550  0.069  1.0
  Li  Li15  1  0.708  0.562  0.587  1.0
  Li  Li16  1  0.549  0.946  0.185  1.0
  O  O17  1  0.221  0.261  0.615  1.0
  V  V18  1  0.258  0.462  0.436  1.0
  V  V19  1  0.490  0.027  0.830  1.0
[/CIF]
.