The crystal structure described by VNH4(OF2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four VNH4(OF2)2 clusters. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. N(1) is bonded in a distorted tetrahedral geometry to one H(2), one H(3), one H(4), and one O(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one F(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one N(1) and one H(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one H(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VH4N(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.452
_cell_length_b   5.167
_cell_length_c   14.766
_cell_angle_alpha   90.000
_cell_angle_beta   114.868
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   515.848
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.132  0.069  0.375  1.0
  V  V1  1  0.132  0.431  0.875  1.0
  V  V2  1  0.868  0.931  0.625  1.0
  V  V3  1  0.868  0.569  0.125  1.0
  H  H4  1  0.588  0.004  0.168  1.0
  H  H5  1  0.588  0.496  0.668  1.0
  H  H6  1  0.412  0.996  0.832  1.0
  H  H7  1  0.412  0.504  0.332  1.0
  H  H8  1  0.228  0.124  0.167  1.0
  H  H9  1  0.228  0.376  0.667  1.0
  H  H10  1  0.772  0.876  0.833  1.0
  H  H11  1  0.772  0.624  0.333  1.0
  H  H12  1  0.246  0.986  0.069  1.0
  H  H13  1  0.246  0.514  0.569  1.0
  H  H14  1  0.754  0.014  0.931  1.0
  H  H15  1  0.754  0.486  0.431  1.0
  H  H16  1  0.334  0.829  0.182  1.0
  H  H17  1  0.334  0.671  0.682  1.0
  H  H18  1  0.666  0.171  0.818  1.0
  H  H19  1  0.666  0.329  0.318  1.0
  N  N20  1  0.315  0.006  0.146  1.0
  N  N21  1  0.315  0.494  0.646  1.0
  N  N22  1  0.685  0.994  0.854  1.0
  N  N23  1  0.685  0.506  0.354  1.0
  O  O24  1  0.271  0.903  0.470  1.0
  O  O25  1  0.271  0.597  0.970  1.0
  O  O26  1  0.729  0.097  0.530  1.0
  O  O27  1  0.729  0.403  0.030  1.0
  O  O28  1  0.497  0.138  0.175  1.0
  O  O29  1  0.497  0.362  0.675  1.0
  O  O30  1  0.503  0.862  0.825  1.0
  O  O31  1  0.503  0.638  0.325  1.0
  F  F32  1  0.882  0.982  0.362  1.0
  F  F33  1  0.882  0.518  0.862  1.0
  F  F34  1  0.118  0.018  0.638  1.0
  F  F35  1  0.118  0.482  0.138  1.0
  F  F36  1  0.111  0.373  0.436  1.0
  F  F37  1  0.111  0.127  0.936  1.0
  F  F38  1  0.889  0.627  0.564  1.0
  F  F39  1  0.889  0.873  0.064  1.0
  F  F40  1  0.315  0.233  0.338  1.0
  F  F41  1  0.315  0.267  0.838  1.0
  F  F42  1  0.685  0.767  0.662  1.0
  F  F43  1  0.685  0.733  0.162  1.0
  F  F44  1  0.096  0.839  0.271  1.0
  F  F45  1  0.096  0.661  0.771  1.0
  F  F46  1  0.904  0.161  0.729  1.0
  F  F47  1  0.904  0.339  0.229  1.0
[/CIF]
.
The crystal structure described by VNH4(OF2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four VNH4(OF2)2 clusters. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. N(1) is bonded in a distorted tetrahedral geometry to one H(2), one H(3), one H(4), and one O(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one F(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one N(1) and one H(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one H(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VH4N(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.452
_cell_length_b   5.167
_cell_length_c   14.766
_cell_angle_alpha   90.000
_cell_angle_beta   114.868
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   515.848
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.132  0.069  0.375  1.0
  V  V1  1  0.132  0.431  0.875  1.0
  V  V2  1  0.868  0.931  0.625  1.0
  V  V3  1  0.868  0.569  0.125  1.0
  H  H4  1  0.588  0.004  0.168  1.0
  H  H5  1  0.588  0.496  0.668  1.0
  H  H6  1  0.412  0.996  0.832  1.0
  H  H7  1  0.412  0.504  0.332  1.0
  H  H8  1  0.228  0.124  0.167  1.0
  H  H9  1  0.228  0.376  0.667  1.0
  H  H10  1  0.772  0.876  0.833  1.0
  H  H11  1  0.772  0.624  0.333  1.0
  H  H12  1  0.246  0.986  0.069  1.0
  H  H13  1  0.246  0.514  0.569  1.0
  H  H14  1  0.754  0.014  0.931  1.0
  H  H15  1  0.754  0.486  0.431  1.0
  H  H16  1  0.334  0.829  0.182  1.0
  H  H17  1  0.334  0.671  0.682  1.0
  H  H18  1  0.666  0.171  0.818  1.0
  H  H19  1  0.666  0.329  0.318  1.0
  N  N20  1  0.315  0.006  0.146  1.0
  N  N21  1  0.315  0.494  0.646  1.0
  N  N22  1  0.685  0.994  0.854  1.0
  N  N23  1  0.685  0.506  0.354  1.0
  O  O24  1  0.271  0.903  0.470  1.0
  O  O25  1  0.271  0.597  0.970  1.0
  O  O26  1  0.729  0.097  0.530  1.0
  O  O27  1  0.729  0.403  0.030  1.0
  O  O28  1  0.497  0.138  0.175  1.0
  O  O29  1  0.497  0.362  0.675  1.0
  O  O30  1  0.503  0.862  0.825  1.0
  O  O31  1  0.503  0.638  0.325  1.0
  F  F32  1  0.882  0.982  0.362  1.0
  F  F33  1  0.882  0.518  0.862  1.0
  F  F34  1  0.118  0.018  0.638  1.0
  F  F35  1  0.118  0.482  0.138  1.0
  F  F36  1  0.111  0.373  0.436  1.0
  F  F37  1  0.111  0.127  0.936  1.0
  F  F38  1  0.889  0.627  0.564  1.0
  F  F39  1  0.889  0.873  0.064  1.0
  F  F40  1  0.315  0.233  0.338  1.0
  F  F41  1  0.315  0.267  0.838  1.0
  F  F42  1  0.685  0.767  0.662  1.0
  F  F43  1  0.685  0.733  0.162  1.0
  F  F44  1  0.096  0.839  0.271  1.0
  F  F45  1  0.096  0.661  0.771  1.0
  F  F46  1  0.904  0.161  0.729  1.0
  F  F47  1  0.904  0.339  0.229  1.0
[/CIF]
.