The structure described by Os2OCl10(N2)2 is Indium-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of eight ammonia atoms and two Os2OCl10 clusters. In each Os2OCl10 cluster, Os(1) is bonded to one O(1), one Cl(1), and four equivalent Cl(2) atoms to form corner-sharing OsCl5O octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a linear geometry to two equivalent Os(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Os(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF card [CIF]
data_Os2N4Cl10O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.926
_cell_length_b   9.926
_cell_length_c   9.926
_cell_angle_alpha   136.724
_cell_angle_beta   136.724
_cell_angle_gamma   62.863
_symmetry_Int_Tables_number   1
_cell_volume   453.833
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.890  0.890  0.000  1.0
  Os  Os1  1  0.110  0.110  0.000  1.0
  N  N2  1  0.000  0.500  0.500  1.0
  N  N3  1  0.500  0.000  0.500  1.0
  N  N4  1  0.250  0.750  0.500  1.0
  N  N5  1  0.750  0.250  0.500  1.0
  Cl  Cl6  1  0.757  0.757  0.000  1.0
  Cl  Cl7  1  0.243  0.243  0.000  1.0
  Cl  Cl8  1  0.114  0.114  0.446  1.0
  Cl  Cl9  1  0.668  0.668  0.554  1.0
  Cl  Cl10  1  0.114  0.668  0.000  1.0
  Cl  Cl11  1  0.668  0.114  0.000  1.0
  Cl  Cl12  1  0.886  0.886  0.554  1.0
  Cl  Cl13  1  0.332  0.332  0.446  1.0
  Cl  Cl14  1  0.886  0.332  0.000  1.0
  Cl  Cl15  1  0.332  0.886  0.000  1.0
  O  O16  1  0.000  0.000  0.000  1.0
[/CIF]
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The structure described by Os2OCl10(N2)2 is Indium-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of eight ammonia atoms and two Os2OCl10 clusters. In each Os2OCl10 cluster, Os(1) is bonded to one O(1), one Cl(1), and four equivalent Cl(2) atoms to form corner-sharing OsCl5O octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a linear geometry to two equivalent Os(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Os(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF card [CIF]
data_Os2N4Cl10O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.926
_cell_length_b   9.926
_cell_length_c   9.926
_cell_angle_alpha   136.724
_cell_angle_beta   136.724
_cell_angle_gamma   62.863
_symmetry_Int_Tables_number   1
_cell_volume   453.833
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.890  0.890  0.000  1.0
  Os  Os1  1  0.110  0.110  0.000  1.0
  N  N2  1  0.000  0.500  0.500  1.0
  N  N3  1  0.500  0.000  0.500  1.0
  N  N4  1  0.250  0.750  0.500  1.0
  N  N5  1  0.750  0.250  0.500  1.0
  Cl  Cl6  1  0.757  0.757  0.000  1.0
  Cl  Cl7  1  0.243  0.243  0.000  1.0
  Cl  Cl8  1  0.114  0.114  0.446  1.0
  Cl  Cl9  1  0.668  0.668  0.554  1.0
  Cl  Cl10  1  0.114  0.668  0.000  1.0
  Cl  Cl11  1  0.668  0.114  0.000  1.0
  Cl  Cl12  1  0.886  0.886  0.554  1.0
  Cl  Cl13  1  0.332  0.332  0.446  1.0
  Cl  Cl14  1  0.886  0.332  0.000  1.0
  Cl  Cl15  1  0.332  0.886  0.000  1.0
  O  O16  1  0.000  0.000  0.000  1.0
[/CIF]
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