The structure described by TeBr4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four TeBr4 clusters. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Br(1), one Br(2), one Br(4), one Br(5), and two equivalent Br(7) atoms to form edge-sharing TeBr6 octahedra. In the second Te site, Te(2) is bonded to one Br(3), one Br(6), one Br(7), one Br(8), and two equivalent Br(4) atoms to form edge-sharing TeBr6 octahedra. There are eight inequivalent Br sites. In the first Br site, Br(5) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(6) is bonded in a single-bond geometry to one Te(2) atom. In the third Br site, Br(7) is bonded in a distorted T-shaped geometry to one Te(2) and two equivalent Te(1) atoms. In the fourth Br site, Br(8) is bonded in a single-bond geometry to one Te(2) atom. In the fifth Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Br site, Br(3) is bonded in a single-bond geometry to one Te(2) atom. In the eighth Br site, Br(4) is bonded in a distorted T-shaped geometry to one Te(1) and two equivalent Te(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeBr4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.647
_cell_length_b   10.647
_cell_length_c   15.720
_cell_angle_alpha   95.162
_cell_angle_beta   106.208
_cell_angle_gamma   117.066
_symmetry_Int_Tables_number   1
_cell_volume   1473.875
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.154  0.767  0.390  1.0
  Te  Te1  1  0.846  0.233  0.610  1.0
  Te  Te2  1  0.878  0.764  0.110  1.0
  Te  Te3  1  0.122  0.236  0.890  1.0
  Te  Te4  1  0.798  0.337  0.182  1.0
  Te  Te5  1  0.202  0.663  0.818  1.0
  Te  Te6  1  0.655  0.615  0.318  1.0
  Te  Te7  1  0.345  0.385  0.682  1.0
  Br  Br8  1  0.186  0.873  0.549  1.0
  Br  Br9  1  0.814  0.127  0.451  1.0
  Br  Br10  1  0.824  0.637  0.951  1.0
  Br  Br11  1  0.176  0.363  0.049  1.0
  Br  Br12  1  0.368  0.993  0.376  1.0
  Br  Br13  1  0.632  0.007  0.624  1.0
  Br  Br14  1  0.117  0.992  0.124  1.0
  Br  Br15  1  0.883  0.008  0.876  1.0
  Br  Br16  1  0.568  0.121  0.192  1.0
  Br  Br17  1  0.432  0.879  0.808  1.0
  Br  Br18  1  0.430  0.376  0.308  1.0
  Br  Br19  1  0.570  0.624  0.692  1.0
  Br  Br20  1  0.616  0.490  0.124  1.0
  Br  Br21  1  0.384  0.510  0.876  1.0
  Br  Br22  1  0.866  0.491  0.376  1.0
  Br  Br23  1  0.134  0.509  0.624  1.0
  Br  Br24  1  0.705  0.866  0.063  1.0
  Br  Br25  1  0.295  0.134  0.937  1.0
  Br  Br26  1  0.304  0.642  0.437  1.0
  Br  Br27  1  0.696  0.358  0.563  1.0
  Br  Br28  1  0.739  0.237  0.015  1.0
  Br  Br29  1  0.261  0.763  0.985  1.0
  Br  Br30  1  0.722  0.724  0.485  1.0
  Br  Br31  1  0.278  0.276  0.515  1.0
  Br  Br32  1  0.935  0.879  0.313  1.0
  Br  Br33  1  0.065  0.121  0.687  1.0
  Br  Br34  1  0.065  0.622  0.187  1.0
  Br  Br35  1  0.935  0.378  0.813  1.0
  Br  Br36  1  0.979  0.249  0.247  1.0
  Br  Br37  1  0.021  0.751  0.753  1.0
  Br  Br38  1  0.502  0.733  0.253  1.0
  Br  Br39  1  0.498  0.267  0.747  1.0
[/CIF]
.
The structure described by TeBr4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four TeBr4 clusters. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Br(1), one Br(2), one Br(4), one Br(5), and two equivalent Br(7) atoms to form edge-sharing TeBr6 octahedra. In the second Te site, Te(2) is bonded to one Br(3), one Br(6), one Br(7), one Br(8), and two equivalent Br(4) atoms to form edge-sharing TeBr6 octahedra. There are eight inequivalent Br sites. In the first Br site, Br(5) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(6) is bonded in a single-bond geometry to one Te(2) atom. In the third Br site, Br(7) is bonded in a distorted T-shaped geometry to one Te(2) and two equivalent Te(1) atoms. In the fourth Br site, Br(8) is bonded in a single-bond geometry to one Te(2) atom. In the fifth Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Br site, Br(3) is bonded in a single-bond geometry to one Te(2) atom. In the eighth Br site, Br(4) is bonded in a distorted T-shaped geometry to one Te(1) and two equivalent Te(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeBr4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.647
_cell_length_b   10.647
_cell_length_c   15.720
_cell_angle_alpha   95.162
_cell_angle_beta   106.208
_cell_angle_gamma   117.066
_symmetry_Int_Tables_number   1
_cell_volume   1473.875
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.154  0.767  0.390  1.0
  Te  Te1  1  0.846  0.233  0.610  1.0
  Te  Te2  1  0.878  0.764  0.110  1.0
  Te  Te3  1  0.122  0.236  0.890  1.0
  Te  Te4  1  0.798  0.337  0.182  1.0
  Te  Te5  1  0.202  0.663  0.818  1.0
  Te  Te6  1  0.655  0.615  0.318  1.0
  Te  Te7  1  0.345  0.385  0.682  1.0
  Br  Br8  1  0.186  0.873  0.549  1.0
  Br  Br9  1  0.814  0.127  0.451  1.0
  Br  Br10  1  0.824  0.637  0.951  1.0
  Br  Br11  1  0.176  0.363  0.049  1.0
  Br  Br12  1  0.368  0.993  0.376  1.0
  Br  Br13  1  0.632  0.007  0.624  1.0
  Br  Br14  1  0.117  0.992  0.124  1.0
  Br  Br15  1  0.883  0.008  0.876  1.0
  Br  Br16  1  0.568  0.121  0.192  1.0
  Br  Br17  1  0.432  0.879  0.808  1.0
  Br  Br18  1  0.430  0.376  0.308  1.0
  Br  Br19  1  0.570  0.624  0.692  1.0
  Br  Br20  1  0.616  0.490  0.124  1.0
  Br  Br21  1  0.384  0.510  0.876  1.0
  Br  Br22  1  0.866  0.491  0.376  1.0
  Br  Br23  1  0.134  0.509  0.624  1.0
  Br  Br24  1  0.705  0.866  0.063  1.0
  Br  Br25  1  0.295  0.134  0.937  1.0
  Br  Br26  1  0.304  0.642  0.437  1.0
  Br  Br27  1  0.696  0.358  0.563  1.0
  Br  Br28  1  0.739  0.237  0.015  1.0
  Br  Br29  1  0.261  0.763  0.985  1.0
  Br  Br30  1  0.722  0.724  0.485  1.0
  Br  Br31  1  0.278  0.276  0.515  1.0
  Br  Br32  1  0.935  0.879  0.313  1.0
  Br  Br33  1  0.065  0.121  0.687  1.0
  Br  Br34  1  0.065  0.622  0.187  1.0
  Br  Br35  1  0.935  0.378  0.813  1.0
  Br  Br36  1  0.979  0.249  0.247  1.0
  Br  Br37  1  0.021  0.751  0.753  1.0
  Br  Br38  1  0.502  0.733  0.253  1.0
  Br  Br39  1  0.498  0.267  0.747  1.0
[/CIF]
.