The structure described by Ga2Cl7(Te)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two tellurium tetramer molecules and four Ga2Cl7 clusters. In each Ga2Cl7 cluster, there are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom to form corner-sharing GaCl4 tetrahedra. In the second Ga site, Ga(2) is bonded to one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom to form corner-sharing GaCl4 tetrahedra. There are seven inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Ga(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Ga(2) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Ga(2) atom. In the fourth Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the fifth Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the sixth Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the seventh Cl site, Cl(4) is bonded in a water-like geometry to one Ga(1) and one Ga(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga2Te2Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.257
_cell_length_b   9.324
_cell_length_c   13.255
_cell_angle_alpha   87.999
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1390.435
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.579  0.260  0.159  1.0
  Ga  Ga1  1  0.079  0.740  0.341  1.0
  Ga  Ga2  1  0.421  0.740  0.841  1.0
  Ga  Ga3  1  0.921  0.260  0.659  1.0
  Ga  Ga4  1  0.681  0.877  0.204  1.0
  Ga  Ga5  1  0.181  0.123  0.296  1.0
  Ga  Ga6  1  0.319  0.123  0.796  1.0
  Ga  Ga7  1  0.819  0.877  0.704  1.0
  Te  Te8  1  0.844  0.565  0.965  1.0
  Te  Te9  1  0.344  0.435  0.535  1.0
  Te  Te10  1  0.156  0.435  0.035  1.0
  Te  Te11  1  0.656  0.565  0.465  1.0
  Te  Te12  1  0.936  0.322  0.050  1.0
  Te  Te13  1  0.436  0.678  0.450  1.0
  Te  Te14  1  0.064  0.678  0.950  1.0
  Te  Te15  1  0.564  0.322  0.550  1.0
  Cl  Cl16  1  0.418  0.366  0.201  1.0
  Cl  Cl17  1  0.918  0.634  0.299  1.0
  Cl  Cl18  1  0.582  0.634  0.799  1.0
  Cl  Cl19  1  0.082  0.366  0.701  1.0
  Cl  Cl20  1  0.642  0.317  0.007  1.0
  Cl  Cl21  1  0.142  0.683  0.493  1.0
  Cl  Cl22  1  0.358  0.683  0.993  1.0
  Cl  Cl23  1  0.858  0.317  0.507  1.0
  Cl  Cl24  1  0.721  0.270  0.267  1.0
  Cl  Cl25  1  0.221  0.730  0.233  1.0
  Cl  Cl26  1  0.279  0.730  0.733  1.0
  Cl  Cl27  1  0.779  0.270  0.767  1.0
  Cl  Cl28  1  0.526  0.022  0.144  1.0
  Cl  Cl29  1  0.026  0.978  0.356  1.0
  Cl  Cl30  1  0.474  0.978  0.856  1.0
  Cl  Cl31  1  0.974  0.022  0.644  1.0
  Cl  Cl32  1  0.672  0.895  0.367  1.0
  Cl  Cl33  1  0.172  0.105  0.133  1.0
  Cl  Cl34  1  0.328  0.105  0.633  1.0
  Cl  Cl35  1  0.828  0.895  0.867  1.0
  Cl  Cl36  1  0.838  0.957  0.129  1.0
  Cl  Cl37  1  0.338  0.043  0.371  1.0
  Cl  Cl38  1  0.162  0.043  0.871  1.0
  Cl  Cl39  1  0.662  0.957  0.629  1.0
  Cl  Cl40  1  0.624  0.668  0.159  1.0
  Cl  Cl41  1  0.124  0.332  0.341  1.0
  Cl  Cl42  1  0.376  0.332  0.841  1.0
  Cl  Cl43  1  0.876  0.668  0.659  1.0
[/CIF]
.
The structure described by Ga2Cl7(Te)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two tellurium tetramer molecules and four Ga2Cl7 clusters. In each Ga2Cl7 cluster, there are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom to form corner-sharing GaCl4 tetrahedra. In the second Ga site, Ga(2) is bonded to one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom to form corner-sharing GaCl4 tetrahedra. There are seven inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Ga(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Ga(2) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Ga(2) atom. In the fourth Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the fifth Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the sixth Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the seventh Cl site, Cl(4) is bonded in a water-like geometry to one Ga(1) and one Ga(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga2Te2Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.257
_cell_length_b   9.324
_cell_length_c   13.255
_cell_angle_alpha   87.999
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1390.435
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.579  0.260  0.159  1.0
  Ga  Ga1  1  0.079  0.740  0.341  1.0
  Ga  Ga2  1  0.421  0.740  0.841  1.0
  Ga  Ga3  1  0.921  0.260  0.659  1.0
  Ga  Ga4  1  0.681  0.877  0.204  1.0
  Ga  Ga5  1  0.181  0.123  0.296  1.0
  Ga  Ga6  1  0.319  0.123  0.796  1.0
  Ga  Ga7  1  0.819  0.877  0.704  1.0
  Te  Te8  1  0.844  0.565  0.965  1.0
  Te  Te9  1  0.344  0.435  0.535  1.0
  Te  Te10  1  0.156  0.435  0.035  1.0
  Te  Te11  1  0.656  0.565  0.465  1.0
  Te  Te12  1  0.936  0.322  0.050  1.0
  Te  Te13  1  0.436  0.678  0.450  1.0
  Te  Te14  1  0.064  0.678  0.950  1.0
  Te  Te15  1  0.564  0.322  0.550  1.0
  Cl  Cl16  1  0.418  0.366  0.201  1.0
  Cl  Cl17  1  0.918  0.634  0.299  1.0
  Cl  Cl18  1  0.582  0.634  0.799  1.0
  Cl  Cl19  1  0.082  0.366  0.701  1.0
  Cl  Cl20  1  0.642  0.317  0.007  1.0
  Cl  Cl21  1  0.142  0.683  0.493  1.0
  Cl  Cl22  1  0.358  0.683  0.993  1.0
  Cl  Cl23  1  0.858  0.317  0.507  1.0
  Cl  Cl24  1  0.721  0.270  0.267  1.0
  Cl  Cl25  1  0.221  0.730  0.233  1.0
  Cl  Cl26  1  0.279  0.730  0.733  1.0
  Cl  Cl27  1  0.779  0.270  0.767  1.0
  Cl  Cl28  1  0.526  0.022  0.144  1.0
  Cl  Cl29  1  0.026  0.978  0.356  1.0
  Cl  Cl30  1  0.474  0.978  0.856  1.0
  Cl  Cl31  1  0.974  0.022  0.644  1.0
  Cl  Cl32  1  0.672  0.895  0.367  1.0
  Cl  Cl33  1  0.172  0.105  0.133  1.0
  Cl  Cl34  1  0.328  0.105  0.633  1.0
  Cl  Cl35  1  0.828  0.895  0.867  1.0
  Cl  Cl36  1  0.838  0.957  0.129  1.0
  Cl  Cl37  1  0.338  0.043  0.371  1.0
  Cl  Cl38  1  0.162  0.043  0.871  1.0
  Cl  Cl39  1  0.662  0.957  0.629  1.0
  Cl  Cl40  1  0.624  0.668  0.159  1.0
  Cl  Cl41  1  0.124  0.332  0.341  1.0
  Cl  Cl42  1  0.376  0.332  0.841  1.0
  Cl  Cl43  1  0.876  0.668  0.659  1.0
[/CIF]
.