The structure described by VWZn2O6 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-45°. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent V(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-45°. Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-83°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one W(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one W(1), and one Zn(1) atom. In the third O site, O(3) is bonded to one V(1), one W(1), and two equivalent Zn(1) atoms to form distorted corner-sharing OVZn2W tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_VZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.271
_cell_length_b   7.807
_cell_length_c   5.286
_cell_angle_alpha   89.992
_cell_angle_beta   89.992
_cell_angle_gamma   90.008
_symmetry_Int_Tables_number   1
_cell_volume   217.518
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  V  V1  1  0.000  1.000  0.500  1.0
  Zn  Zn2  1  0.026  0.251  0.011  1.0
  Zn  Zn3  1  0.525  0.249  0.489  1.0
  Zn  Zn4  1  0.974  0.749  0.989  1.0
  Zn  Zn5  1  0.475  0.751  0.511  1.0
  W  W6  1  0.000  0.500  0.500  1.0
  W  W7  1  0.500  0.000  1.000  1.0
  O  O8  1  0.319  0.435  0.667  1.0
  O  O9  1  0.819  0.065  0.833  1.0
  O  O10  1  0.681  0.565  0.333  1.0
  O  O11  1  0.181  0.935  0.167  1.0
  O  O12  1  0.175  0.566  0.172  1.0
  O  O13  1  0.675  0.934  0.328  1.0
  O  O14  1  0.825  0.434  0.828  1.0
  O  O15  1  0.325  0.066  0.672  1.0
  O  O16  1  0.414  0.246  0.116  1.0
  O  O17  1  0.914  0.254  0.384  1.0
  O  O18  1  0.086  0.746  0.616  1.0
  O  O19  1  0.586  0.754  0.884  1.0
[/CIF]
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The structure described by VWZn2O6 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-45°. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent V(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-45°. Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-83°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one W(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one W(1), and one Zn(1) atom. In the third O site, O(3) is bonded to one V(1), one W(1), and two equivalent Zn(1) atoms to form distorted corner-sharing OVZn2W tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_VZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.271
_cell_length_b   7.807
_cell_length_c   5.286
_cell_angle_alpha   89.992
_cell_angle_beta   89.992
_cell_angle_gamma   90.008
_symmetry_Int_Tables_number   1
_cell_volume   217.518
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  V  V1  1  0.000  1.000  0.500  1.0
  Zn  Zn2  1  0.026  0.251  0.011  1.0
  Zn  Zn3  1  0.525  0.249  0.489  1.0
  Zn  Zn4  1  0.974  0.749  0.989  1.0
  Zn  Zn5  1  0.475  0.751  0.511  1.0
  W  W6  1  0.000  0.500  0.500  1.0
  W  W7  1  0.500  0.000  1.000  1.0
  O  O8  1  0.319  0.435  0.667  1.0
  O  O9  1  0.819  0.065  0.833  1.0
  O  O10  1  0.681  0.565  0.333  1.0
  O  O11  1  0.181  0.935  0.167  1.0
  O  O12  1  0.175  0.566  0.172  1.0
  O  O13  1  0.675  0.934  0.328  1.0
  O  O14  1  0.825  0.434  0.828  1.0
  O  O15  1  0.325  0.066  0.672  1.0
  O  O16  1  0.414  0.246  0.116  1.0
  O  O17  1  0.914  0.254  0.384  1.0
  O  O18  1  0.086  0.746  0.616  1.0
  O  O19  1  0.586  0.754  0.884  1.0
[/CIF]
.