The material described by CrH10S2(NO2)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CrH10S2(NO2)4 cluster. Cr(1) is bonded in a 4-coordinate geometry to two equivalent N(2) and two equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one H(2), one H(3), and one H(5) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Cr(1), one H(1), and one H(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a 2-coordinate geometry to one N(1) and one O(3) atom. S(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cr(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one H(5) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_CrH10S2(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.348
_cell_length_b   5.536
_cell_length_c   5.804
_cell_angle_alpha   97.498
_cell_angle_beta   91.813
_cell_angle_gamma   103.367
_symmetry_Int_Tables_number   1
_cell_volume   227.305
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.709  0.268  0.917  1.0
  H  H2  1  0.555  0.169  0.244  1.0
  H  H3  1  0.789  0.285  0.443  1.0
  H  H4  1  0.929  0.376  0.123  1.0
  H  H5  1  0.597  0.408  0.292  1.0
  H  H6  1  0.403  0.592  0.708  1.0
  H  H7  1  0.071  0.624  0.877  1.0
  H  H8  1  0.211  0.715  0.557  1.0
  H  H9  1  0.445  0.831  0.756  1.0
  H  H10  1  0.291  0.732  0.083  1.0
  S  S11  1  0.251  0.227  0.656  1.0
  S  S12  1  0.749  0.773  0.344  1.0
  N  N13  1  0.678  0.280  0.276  1.0
  N  N14  1  0.819  0.257  0.075  1.0
  N  N15  1  0.181  0.743  0.925  1.0
  N  N16  1  0.322  0.720  0.724  1.0
  O  O17  1  0.268  0.120  0.861  1.0
  O  O18  1  0.240  0.094  0.408  1.0
  O  O19  1  0.466  0.355  0.707  1.0
  O  O20  1  0.041  0.339  0.671  1.0
  O  O21  1  0.959  0.661  0.329  1.0
  O  O22  1  0.534  0.645  0.293  1.0
  O  O23  1  0.760  0.906  0.592  1.0
  O  O24  1  0.732  0.880  0.139  1.0
[/CIF]
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The material described by CrH10S2(NO2)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CrH10S2(NO2)4 cluster. Cr(1) is bonded in a 4-coordinate geometry to two equivalent N(2) and two equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one H(2), one H(3), and one H(5) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Cr(1), one H(1), and one H(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a 2-coordinate geometry to one N(1) and one O(3) atom. S(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cr(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one H(5) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_CrH10S2(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.348
_cell_length_b   5.536
_cell_length_c   5.804
_cell_angle_alpha   97.498
_cell_angle_beta   91.813
_cell_angle_gamma   103.367
_symmetry_Int_Tables_number   1
_cell_volume   227.305
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.709  0.268  0.917  1.0
  H  H2  1  0.555  0.169  0.244  1.0
  H  H3  1  0.789  0.285  0.443  1.0
  H  H4  1  0.929  0.376  0.123  1.0
  H  H5  1  0.597  0.408  0.292  1.0
  H  H6  1  0.403  0.592  0.708  1.0
  H  H7  1  0.071  0.624  0.877  1.0
  H  H8  1  0.211  0.715  0.557  1.0
  H  H9  1  0.445  0.831  0.756  1.0
  H  H10  1  0.291  0.732  0.083  1.0
  S  S11  1  0.251  0.227  0.656  1.0
  S  S12  1  0.749  0.773  0.344  1.0
  N  N13  1  0.678  0.280  0.276  1.0
  N  N14  1  0.819  0.257  0.075  1.0
  N  N15  1  0.181  0.743  0.925  1.0
  N  N16  1  0.322  0.720  0.724  1.0
  O  O17  1  0.268  0.120  0.861  1.0
  O  O18  1  0.240  0.094  0.408  1.0
  O  O19  1  0.466  0.355  0.707  1.0
  O  O20  1  0.041  0.339  0.671  1.0
  O  O21  1  0.959  0.661  0.329  1.0
  O  O22  1  0.534  0.645  0.293  1.0
  O  O23  1  0.760  0.906  0.592  1.0
  O  O24  1  0.732  0.880  0.139  1.0
[/CIF]
.