The compound described by Na3PO3S crystallizes in the trigonal R3c space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent O(1) atoms. P(1) is bonded in a distorted tetrahedral geometry to one S(1) and three equivalent O(1) atoms. S(1) is bonded in a 7-coordinate geometry to six equivalent Na(1) and one P(1) atom. O(1) is bonded to four equivalent Na(1) and one P(1) atom to form a mixture of distorted corner and edge-sharing ONa4P trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3PSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.306
_cell_length_b   6.306
_cell_length_c   6.306
_cell_angle_alpha   84.894
_cell_angle_beta   84.894
_cell_angle_gamma   84.894
_symmetry_Int_Tables_number   1
_cell_volume   247.987
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.505  0.882  0.190  1.0
  Na  Na1  1  0.190  0.505  0.882  1.0
  Na  Na2  1  0.882  0.190  0.505  1.0
  Na  Na3  1  0.382  0.005  0.690  1.0
  Na  Na4  1  0.690  0.382  0.005  1.0
  Na  Na5  1  0.005  0.690  0.382  1.0
  P  P6  1  0.907  0.907  0.907  1.0
  P  P7  1  0.407  0.407  0.407  1.0
  S  S8  1  0.584  0.584  0.584  1.0
  S  S9  1  0.084  0.084  0.084  1.0
  O  O10  1  0.864  0.696  0.043  1.0
  O  O11  1  0.043  0.864  0.696  1.0
  O  O12  1  0.696  0.043  0.864  1.0
  O  O13  1  0.196  0.364  0.543  1.0
  O  O14  1  0.543  0.196  0.364  1.0
  O  O15  1  0.364  0.543  0.196  1.0
[/CIF]
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The compound described by Na3PO3S crystallizes in the trigonal R3c space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent O(1) atoms. P(1) is bonded in a distorted tetrahedral geometry to one S(1) and three equivalent O(1) atoms. S(1) is bonded in a 7-coordinate geometry to six equivalent Na(1) and one P(1) atom. O(1) is bonded to four equivalent Na(1) and one P(1) atom to form a mixture of distorted corner and edge-sharing ONa4P trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3PSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.306
_cell_length_b   6.306
_cell_length_c   6.306
_cell_angle_alpha   84.894
_cell_angle_beta   84.894
_cell_angle_gamma   84.894
_symmetry_Int_Tables_number   1
_cell_volume   247.987
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.505  0.882  0.190  1.0
  Na  Na1  1  0.190  0.505  0.882  1.0
  Na  Na2  1  0.882  0.190  0.505  1.0
  Na  Na3  1  0.382  0.005  0.690  1.0
  Na  Na4  1  0.690  0.382  0.005  1.0
  Na  Na5  1  0.005  0.690  0.382  1.0
  P  P6  1  0.907  0.907  0.907  1.0
  P  P7  1  0.407  0.407  0.407  1.0
  S  S8  1  0.584  0.584  0.584  1.0
  S  S9  1  0.084  0.084  0.084  1.0
  O  O10  1  0.864  0.696  0.043  1.0
  O  O11  1  0.043  0.864  0.696  1.0
  O  O12  1  0.696  0.043  0.864  1.0
  O  O13  1  0.196  0.364  0.543  1.0
  O  O14  1  0.543  0.196  0.364  1.0
  O  O15  1  0.364  0.543  0.196  1.0
[/CIF]
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