The compound described by Pr2OsP2O crystallizes in the tetragonal P4/mmm space group. Pr(1) is bonded in a distorted single-bond geometry to one P(1) and one O(1) atom. Os(1) is bonded to four equivalent Os(1) and two equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing OsP2Os4 octahedra. The corner-sharing octahedra are not tilted. P(1) is bonded in a linear geometry to one Pr(1) and one Os(1) atom. O(1) is bonded in a linear geometry to two equivalent Pr(1) atoms. is represented by the CIF file [CIF]
data_Pr2P2OsO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.141
_cell_length_b   3.141
_cell_length_c   14.646
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   144.449
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.500  0.500  0.645  1.0
  Pr  Pr1  1  0.500  0.500  0.355  1.0
  P  P2  1  0.500  0.500  0.152  1.0
  P  P3  1  0.500  0.500  0.848  1.0
  Os  Os4  1  0.500  0.500  0.000  1.0
  O  O5  1  0.500  0.500  0.500  1.0
[/CIF]
.
The compound described by Pr2OsP2O crystallizes in the tetragonal P4/mmm space group. Pr(1) is bonded in a distorted single-bond geometry to one P(1) and one O(1) atom. Os(1) is bonded to four equivalent Os(1) and two equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing OsP2Os4 octahedra. The corner-sharing octahedra are not tilted. P(1) is bonded in a linear geometry to one Pr(1) and one Os(1) atom. O(1) is bonded in a linear geometry to two equivalent Pr(1) atoms. is represented by the CIF file [CIF]
data_Pr2P2OsO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.141
_cell_length_b   3.141
_cell_length_c   14.646
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   144.449
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.500  0.500  0.645  1.0
  Pr  Pr1  1  0.500  0.500  0.355  1.0
  P  P2  1  0.500  0.500  0.152  1.0
  P  P3  1  0.500  0.500  0.848  1.0
  Os  Os4  1  0.500  0.500  0.000  1.0
  O  O5  1  0.500  0.500  0.500  1.0
[/CIF]
.