The structure described by CsCu2Cl3 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1) and six equivalent Cl(2) atoms. Cu(1) is bonded to two equivalent Cl(1) and two equivalent Cl(2) atoms to form a mixture of distorted corner and edge-sharing CuCl4 tetrahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to two equivalent Cs(1) and four equivalent Cu(1) atoms. In the second Cl site, Cl(2) is bonded in a 5-coordinate geometry to three equivalent Cs(1) and two equivalent Cu(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsCu2Cl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.300
_cell_length_b   7.810
_cell_length_c   7.810
_cell_angle_alpha   102.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   315.113
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.310  0.690  1.0
  Cs  Cs1  1  0.750  0.690  0.310  1.0
  Cu  Cu2  1  0.000  0.832  0.832  1.0
  Cu  Cu3  1  0.000  0.168  0.168  1.0
  Cu  Cu4  1  0.500  0.168  0.168  1.0
  Cu  Cu5  1  0.500  0.832  0.832  1.0
  Cl  Cl6  1  0.250  0.895  0.105  1.0
  Cl  Cl7  1  0.750  0.105  0.895  1.0
  Cl  Cl8  1  0.250  0.842  0.599  1.0
  Cl  Cl9  1  0.750  0.158  0.401  1.0
  Cl  Cl10  1  0.250  0.401  0.158  1.0
  Cl  Cl11  1  0.750  0.599  0.842  1.0
[/CIF]
.
The structure described by CsCu2Cl3 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1) and six equivalent Cl(2) atoms. Cu(1) is bonded to two equivalent Cl(1) and two equivalent Cl(2) atoms to form a mixture of distorted corner and edge-sharing CuCl4 tetrahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to two equivalent Cs(1) and four equivalent Cu(1) atoms. In the second Cl site, Cl(2) is bonded in a 5-coordinate geometry to three equivalent Cs(1) and two equivalent Cu(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsCu2Cl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.300
_cell_length_b   7.810
_cell_length_c   7.810
_cell_angle_alpha   102.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   315.113
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.310  0.690  1.0
  Cs  Cs1  1  0.750  0.690  0.310  1.0
  Cu  Cu2  1  0.000  0.832  0.832  1.0
  Cu  Cu3  1  0.000  0.168  0.168  1.0
  Cu  Cu4  1  0.500  0.168  0.168  1.0
  Cu  Cu5  1  0.500  0.832  0.832  1.0
  Cl  Cl6  1  0.250  0.895  0.105  1.0
  Cl  Cl7  1  0.750  0.105  0.895  1.0
  Cl  Cl8  1  0.250  0.842  0.599  1.0
  Cl  Cl9  1  0.750  0.158  0.401  1.0
  Cl  Cl10  1  0.250  0.401  0.158  1.0
  Cl  Cl11  1  0.750  0.599  0.842  1.0
[/CIF]
.