The compound described by Dy5CoBi2 crystallizes in the orthorhombic Pnma space group. There are four inequivalent Dy sites. In the first Dy site, Dy(1) is bonded to one Co(1) and four equivalent Bi(1) atoms to form a mixture of distorted corner, face, and edge-sharing DyCoBi4 trigonal bipyramids. In the second Dy site, Dy(2) is bonded in a 5-coordinate geometry to one Co(1) and four equivalent Bi(1) atoms. In the third Dy site, Dy(3) is bonded to one Co(1) and four equivalent Bi(1) atoms to form a mixture of distorted corner, face, and edge-sharing DyCoBi4 trigonal bipyramids. In the fourth Dy site, Dy(4) is bonded in a 5-coordinate geometry to two equivalent Co(1) and three equivalent Bi(1) atoms. Co(1) is bonded to one Dy(1), one Dy(2), one Dy(3), and four equivalent Dy(4) atoms to form distorted edge-sharing CoDy7 pentagonal bipyramids. Bi(1) is bonded in a 9-coordinate geometry to two equivalent Dy(1), two equivalent Dy(2), two equivalent Dy(3), and three equivalent Dy(4) atoms. is represented by the CIF file [CIF]
data_Dy5CoBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.046
_cell_length_b   8.801
_cell_length_c   12.351
_cell_angle_alpha   89.999
_cell_angle_beta   90.009
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   874.608
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.848  0.750  0.802  1.0
  Dy  Dy1  1  0.152  0.250  0.198  1.0
  Dy  Dy2  1  0.348  0.250  0.698  1.0
  Dy  Dy3  1  0.653  0.750  0.302  1.0
  Dy  Dy4  1  0.383  0.750  0.689  1.0
  Dy  Dy5  1  0.617  0.250  0.311  1.0
  Dy  Dy6  1  0.883  0.250  0.811  1.0
  Dy  Dy7  1  0.117  0.750  0.189  1.0
  Dy  Dy8  1  0.949  0.750  0.502  1.0
  Dy  Dy9  1  0.051  0.250  0.498  1.0
  Dy  Dy10  1  0.449  0.250  0.998  1.0
  Dy  Dy11  1  0.551  0.750  0.002  1.0
  Dy  Dy12  1  0.675  0.036  0.563  1.0
  Dy  Dy13  1  0.325  0.964  0.437  1.0
  Dy  Dy14  1  0.175  0.964  0.937  1.0
  Dy  Dy15  1  0.325  0.536  0.437  1.0
  Dy  Dy16  1  0.825  0.036  0.063  1.0
  Dy  Dy17  1  0.675  0.464  0.563  1.0
  Dy  Dy18  1  0.825  0.464  0.063  1.0
  Dy  Dy19  1  0.175  0.536  0.937  1.0
  Co  Co20  1  0.563  0.750  0.508  1.0
  Co  Co21  1  0.437  0.250  0.492  1.0
  Co  Co22  1  0.062  0.250  0.992  1.0
  Co  Co23  1  0.937  0.750  0.008  1.0
  Bi  Bi24  1  0.570  0.491  0.827  1.0
  Bi  Bi25  1  0.430  0.509  0.173  1.0
  Bi  Bi26  1  0.070  0.509  0.673  1.0
  Bi  Bi27  1  0.430  0.991  0.173  1.0
  Bi  Bi28  1  0.930  0.491  0.327  1.0
  Bi  Bi29  1  0.570  0.009  0.827  1.0
  Bi  Bi30  1  0.930  0.009  0.327  1.0
  Bi  Bi31  1  0.070  0.991  0.673  1.0
[/CIF]
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The compound described by Dy5CoBi2 crystallizes in the orthorhombic Pnma space group. There are four inequivalent Dy sites. In the first Dy site, Dy(1) is bonded to one Co(1) and four equivalent Bi(1) atoms to form a mixture of distorted corner, face, and edge-sharing DyCoBi4 trigonal bipyramids. In the second Dy site, Dy(2) is bonded in a 5-coordinate geometry to one Co(1) and four equivalent Bi(1) atoms. In the third Dy site, Dy(3) is bonded to one Co(1) and four equivalent Bi(1) atoms to form a mixture of distorted corner, face, and edge-sharing DyCoBi4 trigonal bipyramids. In the fourth Dy site, Dy(4) is bonded in a 5-coordinate geometry to two equivalent Co(1) and three equivalent Bi(1) atoms. Co(1) is bonded to one Dy(1), one Dy(2), one Dy(3), and four equivalent Dy(4) atoms to form distorted edge-sharing CoDy7 pentagonal bipyramids. Bi(1) is bonded in a 9-coordinate geometry to two equivalent Dy(1), two equivalent Dy(2), two equivalent Dy(3), and three equivalent Dy(4) atoms. is represented by the CIF file [CIF]
data_Dy5CoBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.046
_cell_length_b   8.801
_cell_length_c   12.351
_cell_angle_alpha   89.999
_cell_angle_beta   90.009
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   874.608
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.848  0.750  0.802  1.0
  Dy  Dy1  1  0.152  0.250  0.198  1.0
  Dy  Dy2  1  0.348  0.250  0.698  1.0
  Dy  Dy3  1  0.653  0.750  0.302  1.0
  Dy  Dy4  1  0.383  0.750  0.689  1.0
  Dy  Dy5  1  0.617  0.250  0.311  1.0
  Dy  Dy6  1  0.883  0.250  0.811  1.0
  Dy  Dy7  1  0.117  0.750  0.189  1.0
  Dy  Dy8  1  0.949  0.750  0.502  1.0
  Dy  Dy9  1  0.051  0.250  0.498  1.0
  Dy  Dy10  1  0.449  0.250  0.998  1.0
  Dy  Dy11  1  0.551  0.750  0.002  1.0
  Dy  Dy12  1  0.675  0.036  0.563  1.0
  Dy  Dy13  1  0.325  0.964  0.437  1.0
  Dy  Dy14  1  0.175  0.964  0.937  1.0
  Dy  Dy15  1  0.325  0.536  0.437  1.0
  Dy  Dy16  1  0.825  0.036  0.063  1.0
  Dy  Dy17  1  0.675  0.464  0.563  1.0
  Dy  Dy18  1  0.825  0.464  0.063  1.0
  Dy  Dy19  1  0.175  0.536  0.937  1.0
  Co  Co20  1  0.563  0.750  0.508  1.0
  Co  Co21  1  0.437  0.250  0.492  1.0
  Co  Co22  1  0.062  0.250  0.992  1.0
  Co  Co23  1  0.937  0.750  0.008  1.0
  Bi  Bi24  1  0.570  0.491  0.827  1.0
  Bi  Bi25  1  0.430  0.509  0.173  1.0
  Bi  Bi26  1  0.070  0.509  0.673  1.0
  Bi  Bi27  1  0.430  0.991  0.173  1.0
  Bi  Bi28  1  0.930  0.491  0.327  1.0
  Bi  Bi29  1  0.570  0.009  0.827  1.0
  Bi  Bi30  1  0.930  0.009  0.327  1.0
  Bi  Bi31  1  0.070  0.991  0.673  1.0
[/CIF]
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