The material described by KSbO3 crystallizes in the triclinic P-1 space group. K(1) is bonded in a distorted pentagonal planar geometry to one O(2), one O(3), and three equivalent O(1) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to three equivalent K(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded to one K(1), two equivalent Sb(1), and one O(3) atom to form edge-sharing OKSb2O tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_KSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.745
_cell_length_b   6.094
_cell_length_c   8.342
_cell_angle_alpha   88.156
_cell_angle_beta   98.908
_cell_angle_gamma   103.297
_symmetry_Int_Tables_number   1
_cell_volume   183.047
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.142  0.299  0.858  1.0
  K  K1  1  0.858  0.701  0.142  1.0
  Sb  Sb2  1  0.704  0.773  0.635  1.0
  Sb  Sb3  1  0.296  0.227  0.365  1.0
  O  O4  1  0.262  0.394  0.170  1.0
  O  O5  1  0.732  0.061  0.347  1.0
  O  O6  1  0.180  0.475  0.528  1.0
  O  O7  1  0.738  0.606  0.830  1.0
  O  O8  1  0.268  0.939  0.653  1.0
  O  O9  1  0.820  0.525  0.472  1.0
[/CIF]
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The material described by KSbO3 crystallizes in the triclinic P-1 space group. K(1) is bonded in a distorted pentagonal planar geometry to one O(2), one O(3), and three equivalent O(1) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to three equivalent K(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded to one K(1), two equivalent Sb(1), and one O(3) atom to form edge-sharing OKSb2O tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_KSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.745
_cell_length_b   6.094
_cell_length_c   8.342
_cell_angle_alpha   88.156
_cell_angle_beta   98.908
_cell_angle_gamma   103.297
_symmetry_Int_Tables_number   1
_cell_volume   183.047
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.142  0.299  0.858  1.0
  K  K1  1  0.858  0.701  0.142  1.0
  Sb  Sb2  1  0.704  0.773  0.635  1.0
  Sb  Sb3  1  0.296  0.227  0.365  1.0
  O  O4  1  0.262  0.394  0.170  1.0
  O  O5  1  0.732  0.061  0.347  1.0
  O  O6  1  0.180  0.475  0.528  1.0
  O  O7  1  0.738  0.606  0.830  1.0
  O  O8  1  0.268  0.939  0.653  1.0
  O  O9  1  0.820  0.525  0.472  1.0
[/CIF]
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