The material structure described by LiO4Li13(WO4)7 crystallizes in the cubic P-43m space group. The structure consists of one lioh.3h2o molecule inside a Li13(WO4)7 framework. In the Li13(WO4)7 framework, there are three inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and  an edgeedge with one W(2)O4 tetrahedra. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(4) and three equivalent O(2) atoms. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to four equivalent O(2) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. In the second W site, W(2) is bonded to four equivalent O(1) atoms to form WO4 tetrahedra that share edges with two equivalent Li(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one W(1) atom. In the second O site, O(4) is bonded to one Li(2) and three equivalent Li(1) atoms to form corner-sharing OLi4 tetrahedra. In the third O site, O(1) is bonded in an L-shaped geometry to one Li(1) and one W(2) atom. is represented by the CIF card [CIF]
data_Li14W7O32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.655
_cell_length_b   9.655
_cell_length_c   9.655
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   900.088
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.229  1.0
  Li  Li1  1  0.000  0.771  0.000  1.0
  Li  Li2  1  0.771  0.000  0.000  1.0
  Li  Li3  1  0.000  0.000  0.771  1.0
  Li  Li4  1  0.000  0.229  0.000  1.0
  Li  Li5  1  0.229  0.000  0.000  1.0
  Li  Li6  1  0.787  0.787  0.213  1.0
  Li  Li7  1  0.787  0.213  0.787  1.0
  Li  Li8  1  0.213  0.787  0.787  1.0
  Li  Li9  1  0.213  0.213  0.213  1.0
  Li  Li10  1  0.000  0.500  0.500  1.0
  Li  Li11  1  0.500  0.500  0.000  1.0
  Li  Li12  1  0.500  0.000  0.500  1.0
  Li  Li13  1  0.500  0.500  0.500  1.0
  W  W14  1  0.633  0.633  0.367  1.0
  W  W15  1  0.633  0.367  0.633  1.0
  W  W16  1  0.367  0.633  0.633  1.0
  W  W17  1  0.367  0.367  0.367  1.0
  W  W18  1  0.000  0.000  0.500  1.0
  W  W19  1  0.000  0.500  0.000  1.0
  W  W20  1  0.500  0.000  0.000  1.0
  O  O21  1  0.379  0.898  0.102  1.0
  O  O22  1  0.898  0.898  0.621  1.0
  O  O23  1  0.898  0.379  0.102  1.0
  O  O24  1  0.379  0.102  0.898  1.0
  O  O25  1  0.898  0.102  0.379  1.0
  O  O26  1  0.898  0.621  0.898  1.0
  O  O27  1  0.621  0.898  0.898  1.0
  O  O28  1  0.102  0.898  0.379  1.0
  O  O29  1  0.102  0.379  0.898  1.0
  O  O30  1  0.621  0.102  0.102  1.0
  O  O31  1  0.102  0.102  0.621  1.0
  O  O32  1  0.102  0.621  0.102  1.0
  O  O33  1  0.821  0.618  0.382  1.0
  O  O34  1  0.618  0.618  0.179  1.0
  O  O35  1  0.618  0.821  0.382  1.0
  O  O36  1  0.821  0.382  0.618  1.0
  O  O37  1  0.618  0.382  0.821  1.0
  O  O38  1  0.618  0.179  0.618  1.0
  O  O39  1  0.179  0.618  0.618  1.0
  O  O40  1  0.382  0.618  0.821  1.0
  O  O41  1  0.382  0.821  0.618  1.0
  O  O42  1  0.179  0.382  0.382  1.0
  O  O43  1  0.382  0.382  0.179  1.0
  O  O44  1  0.382  0.179  0.382  1.0
  O  O45  1  0.402  0.402  0.598  1.0
  O  O46  1  0.402  0.598  0.402  1.0
  O  O47  1  0.598  0.402  0.402  1.0
  O  O48  1  0.598  0.598  0.598  1.0
  O  O49  1  0.899  0.899  0.101  1.0
  O  O50  1  0.899  0.101  0.899  1.0
  O  O51  1  0.101  0.899  0.899  1.0
  O  O52  1  0.101  0.101  0.101  1.0
[/CIF]
.
The material structure described by LiO4Li13(WO4)7 crystallizes in the cubic P-43m space group. The structure consists of one lioh.3h2o molecule inside a Li13(WO4)7 framework. In the Li13(WO4)7 framework, there are three inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and  an edgeedge with one W(2)O4 tetrahedra. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(4) and three equivalent O(2) atoms. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to four equivalent O(2) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. In the second W site, W(2) is bonded to four equivalent O(1) atoms to form WO4 tetrahedra that share edges with two equivalent Li(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one W(1) atom. In the second O site, O(4) is bonded to one Li(2) and three equivalent Li(1) atoms to form corner-sharing OLi4 tetrahedra. In the third O site, O(1) is bonded in an L-shaped geometry to one Li(1) and one W(2) atom. is represented by the CIF card [CIF]
data_Li14W7O32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.655
_cell_length_b   9.655
_cell_length_c   9.655
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   900.088
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.229  1.0
  Li  Li1  1  0.000  0.771  0.000  1.0
  Li  Li2  1  0.771  0.000  0.000  1.0
  Li  Li3  1  0.000  0.000  0.771  1.0
  Li  Li4  1  0.000  0.229  0.000  1.0
  Li  Li5  1  0.229  0.000  0.000  1.0
  Li  Li6  1  0.787  0.787  0.213  1.0
  Li  Li7  1  0.787  0.213  0.787  1.0
  Li  Li8  1  0.213  0.787  0.787  1.0
  Li  Li9  1  0.213  0.213  0.213  1.0
  Li  Li10  1  0.000  0.500  0.500  1.0
  Li  Li11  1  0.500  0.500  0.000  1.0
  Li  Li12  1  0.500  0.000  0.500  1.0
  Li  Li13  1  0.500  0.500  0.500  1.0
  W  W14  1  0.633  0.633  0.367  1.0
  W  W15  1  0.633  0.367  0.633  1.0
  W  W16  1  0.367  0.633  0.633  1.0
  W  W17  1  0.367  0.367  0.367  1.0
  W  W18  1  0.000  0.000  0.500  1.0
  W  W19  1  0.000  0.500  0.000  1.0
  W  W20  1  0.500  0.000  0.000  1.0
  O  O21  1  0.379  0.898  0.102  1.0
  O  O22  1  0.898  0.898  0.621  1.0
  O  O23  1  0.898  0.379  0.102  1.0
  O  O24  1  0.379  0.102  0.898  1.0
  O  O25  1  0.898  0.102  0.379  1.0
  O  O26  1  0.898  0.621  0.898  1.0
  O  O27  1  0.621  0.898  0.898  1.0
  O  O28  1  0.102  0.898  0.379  1.0
  O  O29  1  0.102  0.379  0.898  1.0
  O  O30  1  0.621  0.102  0.102  1.0
  O  O31  1  0.102  0.102  0.621  1.0
  O  O32  1  0.102  0.621  0.102  1.0
  O  O33  1  0.821  0.618  0.382  1.0
  O  O34  1  0.618  0.618  0.179  1.0
  O  O35  1  0.618  0.821  0.382  1.0
  O  O36  1  0.821  0.382  0.618  1.0
  O  O37  1  0.618  0.382  0.821  1.0
  O  O38  1  0.618  0.179  0.618  1.0
  O  O39  1  0.179  0.618  0.618  1.0
  O  O40  1  0.382  0.618  0.821  1.0
  O  O41  1  0.382  0.821  0.618  1.0
  O  O42  1  0.179  0.382  0.382  1.0
  O  O43  1  0.382  0.382  0.179  1.0
  O  O44  1  0.382  0.179  0.382  1.0
  O  O45  1  0.402  0.402  0.598  1.0
  O  O46  1  0.402  0.598  0.402  1.0
  O  O47  1  0.598  0.402  0.402  1.0
  O  O48  1  0.598  0.598  0.598  1.0
  O  O49  1  0.899  0.899  0.101  1.0
  O  O50  1  0.899  0.101  0.899  1.0
  O  O51  1  0.101  0.899  0.899  1.0
  O  O52  1  0.101  0.101  0.101  1.0
[/CIF]
.