The material structure described by Sm2La6V5Cr3O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Pm space group. Sm(1) is bonded to one O(10), one O(13), one O(14), one O(17), one O(18), one O(19), one O(20), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form SmO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra,  a faceface with one V(5)O6 octahedra,  a faceface with one Cr(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra, and  a faceface with one Cr(3)O6 octahedra. There are three inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(10), one O(13), one O(14), one O(17), one O(18), one O(19), one O(2), one O(20), one O(3), one O(4), and one O(9) atom to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra,  a faceface with one V(5)O6 octahedra,  a faceface with one Cr(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra, and  a faceface with one Cr(3)O6 octahedra. In the second La site, La(2) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(17), one O(18), one O(19), one O(2), one O(20), one O(3), and one O(4) atom to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra,  a faceface with one V(5)O6 octahedra,  a faceface with one Cr(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra, and  a faceface with one Cr(3)O6 octahedra. In the third La site, La(3) is bonded to one O(11), one O(12), one O(15), one O(16), one O(17), one O(18), one O(19), one O(20), one O(5), one O(6), one O(7), and one O(8) atom to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra,  a faceface with one V(5)O6 octahedra,  a faceface with one Cr(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra, and  a faceface with one Cr(3)O6 octahedra. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(5), one O(9), and two equivalent O(17) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(2), one O(6), and two equivalent O(17) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third V site, V(3) is bonded to one O(1), one O(13), one O(15), one O(5), and two equivalent O(19) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth V site, V(4) is bonded to one O(14), one O(16), one O(2), one O(6), and two equivalent O(19) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent V(5)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth V site, V(5) is bonded to one O(14), one O(16), one O(4), one O(8), and two equivalent O(20) atoms to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(3), one O(7), one O(9), and two equivalent O(18) atoms to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Cr site, Cr(2) is bonded to one O(10), one O(12), one O(4), one O(8), and two equivalent O(18) atoms to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Cr site, Cr(3) is bonded to one O(13), one O(15), one O(3), one O(7), and two equivalent O(20) atoms to form CrO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent La(1), two equivalent La(2), one V(1), and one V(3) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent La(1), two equivalent La(2), one V(2), and one V(4) atom. In the third O site, O(3) is bonded in a distorted octahedral geometry to two equivalent La(1), two equivalent La(2), one Cr(1), and one Cr(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to two equivalent La(1), two equivalent La(2), one V(5), and one Cr(2) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(3), one V(1), and one V(3) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(3), one V(2), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(3), one Cr(1), and one Cr(3) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(3), one V(5), and one Cr(2) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(1), one V(1), and one Cr(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(1), one V(2), and one Cr(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to two equivalent La(2), two equivalent La(3), one V(1), and one Cr(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to two equivalent La(2), two equivalent La(3), one V(2), and one Cr(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(1), one V(3), and one Cr(3) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(1), one V(4), and one V(5) atom. In the fifteenth O site, O(15) is bonded in a distorted linear geometry to two equivalent La(2), two equivalent La(3), one V(3), and one Cr(3) atom. In the sixteenth O site, O(16) is bonded in a distorted linear geometry to two equivalent La(2), two equivalent La(3), one V(4), and one V(5) atom. In the seventeenth O site, O(17) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(3), one V(1), and one V(2) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(3), one Cr(1), and one Cr(2) atom. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(3), one V(3), and one V(4) atom. In the twentieth O site, O(20) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(3), one V(5), and one Cr(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La6Sm2V5Cr3O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.913
_cell_length_b   7.861
_cell_length_c   7.915
_cell_angle_alpha   89.949
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   492.372
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.752  0.749  0.248  1.0
  La  La1  1  0.248  0.749  0.248  1.0
  La  La2  1  0.753  0.251  0.247  1.0
  La  La3  1  0.247  0.251  0.247  1.0
  La  La4  1  0.753  0.251  0.752  1.0
  La  La5  1  0.247  0.251  0.752  1.0
  Sm  Sm6  1  0.753  0.749  0.753  1.0
  Sm  Sm7  1  0.247  0.749  0.753  1.0
  V  V8  1  0.000  0.999  0.999  1.0
  V  V9  1  0.500  0.999  0.999  1.0
  V  V10  1  0.000  0.999  0.501  1.0
  V  V11  1  0.500  1.000  0.501  1.0
  V  V12  1  0.500  0.501  0.501  1.0
  Cr  Cr13  1  0.000  0.500  0.999  1.0
  Cr  Cr14  1  0.500  0.500  1.000  1.0
  Cr  Cr15  1  0.000  0.500  0.501  1.0
  O  O16  1  0.000  0.000  0.247  1.0
  O  O17  1  0.500  1.000  0.250  1.0
  O  O18  1  0.000  0.500  0.250  1.0
  O  O19  1  0.500  0.500  0.246  1.0
  O  O20  1  0.000  0.997  0.753  1.0
  O  O21  1  0.500  0.998  0.750  1.0
  O  O22  1  0.000  0.503  0.750  1.0
  O  O23  1  0.500  0.504  0.754  1.0
  O  O24  1  0.000  0.745  0.997  1.0
  O  O25  1  0.500  0.750  0.997  1.0
  O  O26  1  0.000  0.254  0.000  1.0
  O  O27  1  0.500  0.250  1.000  1.0
  O  O28  1  0.000  0.748  0.503  1.0
  O  O29  1  0.500  0.750  0.503  1.0
  O  O30  1  0.000  0.252  0.500  1.0
  O  O31  1  0.500  0.250  0.500  1.0
  O  O32  1  0.753  0.998  0.999  1.0
  O  O33  1  0.247  0.998  0.999  1.0
  O  O34  1  0.750  0.502  0.998  1.0
  O  O35  1  0.250  0.502  0.998  1.0
  O  O36  1  0.753  0.999  0.502  1.0
  O  O37  1  0.247  0.999  0.502  1.0
  O  O38  1  0.751  0.501  0.502  1.0
  O  O39  1  0.249  0.501  0.502  1.0
[/CIF]
.
The material structure described by Sm2La6V5Cr3O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Pm space group. Sm(1) is bonded to one O(10), one O(13), one O(14), one O(17), one O(18), one O(19), one O(20), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form SmO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra,  a faceface with one V(5)O6 octahedra,  a faceface with one Cr(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra, and  a faceface with one Cr(3)O6 octahedra. There are three inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(10), one O(13), one O(14), one O(17), one O(18), one O(19), one O(2), one O(20), one O(3), one O(4), and one O(9) atom to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra,  a faceface with one V(5)O6 octahedra,  a faceface with one Cr(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra, and  a faceface with one Cr(3)O6 octahedra. In the second La site, La(2) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(17), one O(18), one O(19), one O(2), one O(20), one O(3), and one O(4) atom to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra,  a faceface with one V(5)O6 octahedra,  a faceface with one Cr(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra, and  a faceface with one Cr(3)O6 octahedra. In the third La site, La(3) is bonded to one O(11), one O(12), one O(15), one O(16), one O(17), one O(18), one O(19), one O(20), one O(5), one O(6), one O(7), and one O(8) atom to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(2)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra,  a faceface with one V(5)O6 octahedra,  a faceface with one Cr(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra, and  a faceface with one Cr(3)O6 octahedra. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(5), one O(9), and two equivalent O(17) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(2), one O(6), and two equivalent O(17) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third V site, V(3) is bonded to one O(1), one O(13), one O(15), one O(5), and two equivalent O(19) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth V site, V(4) is bonded to one O(14), one O(16), one O(2), one O(6), and two equivalent O(19) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent V(5)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth V site, V(5) is bonded to one O(14), one O(16), one O(4), one O(8), and two equivalent O(20) atoms to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(3), one O(7), one O(9), and two equivalent O(18) atoms to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Cr site, Cr(2) is bonded to one O(10), one O(12), one O(4), one O(8), and two equivalent O(18) atoms to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Cr site, Cr(3) is bonded to one O(13), one O(15), one O(3), one O(7), and two equivalent O(20) atoms to form CrO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent La(1), two equivalent La(2), one V(1), and one V(3) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent La(1), two equivalent La(2), one V(2), and one V(4) atom. In the third O site, O(3) is bonded in a distorted octahedral geometry to two equivalent La(1), two equivalent La(2), one Cr(1), and one Cr(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to two equivalent La(1), two equivalent La(2), one V(5), and one Cr(2) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(3), one V(1), and one V(3) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(3), one V(2), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(3), one Cr(1), and one Cr(3) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(3), one V(5), and one Cr(2) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(1), one V(1), and one Cr(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(1), one V(2), and one Cr(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to two equivalent La(2), two equivalent La(3), one V(1), and one Cr(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to two equivalent La(2), two equivalent La(3), one V(2), and one Cr(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(1), one V(3), and one Cr(3) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to two equivalent Sm(1), two equivalent La(1), one V(4), and one V(5) atom. In the fifteenth O site, O(15) is bonded in a distorted linear geometry to two equivalent La(2), two equivalent La(3), one V(3), and one Cr(3) atom. In the sixteenth O site, O(16) is bonded in a distorted linear geometry to two equivalent La(2), two equivalent La(3), one V(4), and one V(5) atom. In the seventeenth O site, O(17) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(3), one V(1), and one V(2) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(3), one Cr(1), and one Cr(2) atom. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(3), one V(3), and one V(4) atom. In the twentieth O site, O(20) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(2), one La(3), one V(5), and one Cr(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La6Sm2V5Cr3O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.913
_cell_length_b   7.861
_cell_length_c   7.915
_cell_angle_alpha   89.949
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   492.372
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.752  0.749  0.248  1.0
  La  La1  1  0.248  0.749  0.248  1.0
  La  La2  1  0.753  0.251  0.247  1.0
  La  La3  1  0.247  0.251  0.247  1.0
  La  La4  1  0.753  0.251  0.752  1.0
  La  La5  1  0.247  0.251  0.752  1.0
  Sm  Sm6  1  0.753  0.749  0.753  1.0
  Sm  Sm7  1  0.247  0.749  0.753  1.0
  V  V8  1  0.000  0.999  0.999  1.0
  V  V9  1  0.500  0.999  0.999  1.0
  V  V10  1  0.000  0.999  0.501  1.0
  V  V11  1  0.500  1.000  0.501  1.0
  V  V12  1  0.500  0.501  0.501  1.0
  Cr  Cr13  1  0.000  0.500  0.999  1.0
  Cr  Cr14  1  0.500  0.500  1.000  1.0
  Cr  Cr15  1  0.000  0.500  0.501  1.0
  O  O16  1  0.000  0.000  0.247  1.0
  O  O17  1  0.500  1.000  0.250  1.0
  O  O18  1  0.000  0.500  0.250  1.0
  O  O19  1  0.500  0.500  0.246  1.0
  O  O20  1  0.000  0.997  0.753  1.0
  O  O21  1  0.500  0.998  0.750  1.0
  O  O22  1  0.000  0.503  0.750  1.0
  O  O23  1  0.500  0.504  0.754  1.0
  O  O24  1  0.000  0.745  0.997  1.0
  O  O25  1  0.500  0.750  0.997  1.0
  O  O26  1  0.000  0.254  0.000  1.0
  O  O27  1  0.500  0.250  1.000  1.0
  O  O28  1  0.000  0.748  0.503  1.0
  O  O29  1  0.500  0.750  0.503  1.0
  O  O30  1  0.000  0.252  0.500  1.0
  O  O31  1  0.500  0.250  0.500  1.0
  O  O32  1  0.753  0.998  0.999  1.0
  O  O33  1  0.247  0.998  0.999  1.0
  O  O34  1  0.750  0.502  0.998  1.0
  O  O35  1  0.250  0.502  0.998  1.0
  O  O36  1  0.753  0.999  0.502  1.0
  O  O37  1  0.247  0.999  0.502  1.0
  O  O38  1  0.751  0.501  0.502  1.0
  O  O39  1  0.249  0.501  0.502  1.0
[/CIF]
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