The material structure described by AgTeO3 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(3) and two equivalent O(1) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form distorted corner-sharing TeO5 square pyramids. The corner-sharing octahedral tilt angles range from 62-65°. In the second Te site, Te(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form TeO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and corners with four equivalent Te(1)O5 square pyramids. The corner-sharing octahedral tilt angles are 38°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), one Te(1), and one Te(2) atom to form distorted OAg2Te2 tetrahedra that share corners with two equivalent O(3)Ag3Te tetrahedra, corners with four equivalent O(1)Ag2Te2 tetrahedra, and  an edgeedge with one O(3)Ag3Te tetrahedra. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ag(1), one Te(1), and one Te(2) atom. In the third O site, O(3) is bonded to one Ag(2), two equivalent Ag(1), and one Te(1) atom to form distorted OAg3Te tetrahedra that share corners with two equivalent O(3)Ag3Te tetrahedra, corners with four equivalent O(1)Ag2Te2 tetrahedra, and edges with two equivalent O(1)Ag2Te2 tetrahedra. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Te(2) atoms. is represented by the CIF card [CIF]
data_AgTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.462
_cell_length_b   6.918
_cell_length_c   7.400
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.302
_symmetry_Int_Tables_number   1
_cell_volume   274.180
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  1.000  0.500  1.0
  Ag  Ag1  1  0.000  1.000  0.000  1.0
  Ag  Ag2  1  0.569  0.821  0.750  1.0
  Ag  Ag3  1  0.431  0.179  0.250  1.0
  Te  Te4  1  0.519  0.683  0.250  1.0
  Te  Te5  1  0.481  0.317  0.750  1.0
  Te  Te6  1  0.000  0.500  0.000  1.0
  Te  Te7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.229  0.325  0.487  1.0
  O  O9  1  0.739  0.276  0.936  1.0
  O  O10  1  0.662  0.947  0.250  1.0
  O  O11  1  0.899  0.438  0.250  1.0
  O  O12  1  0.229  0.325  0.013  1.0
  O  O13  1  0.101  0.562  0.750  1.0
  O  O14  1  0.739  0.276  0.564  1.0
  O  O15  1  0.261  0.724  0.064  1.0
  O  O16  1  0.770  0.675  0.987  1.0
  O  O17  1  0.770  0.675  0.513  1.0
  O  O18  1  0.261  0.724  0.436  1.0
  O  O19  1  0.338  0.053  0.750  1.0
[/CIF]
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The material structure described by AgTeO3 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(3) and two equivalent O(1) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form distorted corner-sharing TeO5 square pyramids. The corner-sharing octahedral tilt angles range from 62-65°. In the second Te site, Te(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form TeO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and corners with four equivalent Te(1)O5 square pyramids. The corner-sharing octahedral tilt angles are 38°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), one Te(1), and one Te(2) atom to form distorted OAg2Te2 tetrahedra that share corners with two equivalent O(3)Ag3Te tetrahedra, corners with four equivalent O(1)Ag2Te2 tetrahedra, and  an edgeedge with one O(3)Ag3Te tetrahedra. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ag(1), one Te(1), and one Te(2) atom. In the third O site, O(3) is bonded to one Ag(2), two equivalent Ag(1), and one Te(1) atom to form distorted OAg3Te tetrahedra that share corners with two equivalent O(3)Ag3Te tetrahedra, corners with four equivalent O(1)Ag2Te2 tetrahedra, and edges with two equivalent O(1)Ag2Te2 tetrahedra. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Te(2) atoms. is represented by the CIF card [CIF]
data_AgTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.462
_cell_length_b   6.918
_cell_length_c   7.400
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.302
_symmetry_Int_Tables_number   1
_cell_volume   274.180
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  1.000  0.500  1.0
  Ag  Ag1  1  0.000  1.000  0.000  1.0
  Ag  Ag2  1  0.569  0.821  0.750  1.0
  Ag  Ag3  1  0.431  0.179  0.250  1.0
  Te  Te4  1  0.519  0.683  0.250  1.0
  Te  Te5  1  0.481  0.317  0.750  1.0
  Te  Te6  1  0.000  0.500  0.000  1.0
  Te  Te7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.229  0.325  0.487  1.0
  O  O9  1  0.739  0.276  0.936  1.0
  O  O10  1  0.662  0.947  0.250  1.0
  O  O11  1  0.899  0.438  0.250  1.0
  O  O12  1  0.229  0.325  0.013  1.0
  O  O13  1  0.101  0.562  0.750  1.0
  O  O14  1  0.739  0.276  0.564  1.0
  O  O15  1  0.261  0.724  0.064  1.0
  O  O16  1  0.770  0.675  0.987  1.0
  O  O17  1  0.770  0.675  0.513  1.0
  O  O18  1  0.261  0.724  0.436  1.0
  O  O19  1  0.338  0.053  0.750  1.0
[/CIF]
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