The crystal structure described by Na5LiCo2P2(CO7)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(19), one O(20), one O(25), one O(27), one O(4), and one O(5) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(19), one O(20), one O(26), one O(28), one O(3), and one O(6) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(1), one O(21), one O(22), one O(3), one O(6), one O(8), and one O(9) atom. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(10), one O(2), one O(21), one O(22), one O(4), one O(5), and one O(7) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(1), one O(23), one O(24), one O(4), one O(5), one O(7), and one O(9) atom. In the sixth Na site, Na(6) is bonded in a 7-coordinate geometry to one O(10), one O(2), one O(23), one O(24), one O(3), one O(6), and one O(8) atom. In the seventh Na site, Na(7) is bonded in a 5-coordinate geometry to one O(11), one O(14), one O(16), one O(19), and one O(28) atom. In the eighth Na site, Na(8) is bonded in a 5-coordinate geometry to one O(12), one O(13), one O(15), one O(20), and one O(27) atom. In the ninth Na site, Na(9) is bonded in a 5-coordinate geometry to one O(11), one O(13), one O(15), one O(19), and one O(26) atom. In the tenth Na site, Na(10) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(16), one O(20), and one O(25) atom. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(18), one O(21), and one O(23) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(17), one O(2), one O(22), and one O(24) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(21), one O(24), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. In the second Co site, Co(2) is bonded to one O(11), one O(22), one O(23), one O(3), one O(5), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. In the third Co site, Co(3) is bonded in a 5-coordinate geometry to one O(14), one O(15), one O(25), one O(28), and one O(9) atom. In the fourth Co site, Co(4) is bonded in a 5-coordinate geometry to one O(10), one O(13), one O(16), one O(26), and one O(27) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(19), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(20), one O(4), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(1), one O(15), and one O(17) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(16), one O(18), and one O(2) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(13), one O(21), one O(23), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and  a cornercorner with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 46°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(22), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and  a cornercorner with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 46°. In the third P site, P(3) is bonded to one O(11), one O(25), one O(27), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and  a cornercorner with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-51°. In the fourth P site, P(4) is bonded to one O(12), one O(26), one O(28), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and  a cornercorner with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-52°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(3), one Na(5), one Li(1), and one C(3) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Na(4), one Na(6), one Li(2), and one C(4) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(2), one Na(3), one Na(6), one Co(2), and one C(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(1), one Na(4), one Na(5), one Co(1), and one C(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Na(1), one Na(4), one Na(5), one Co(2), and one C(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Na(2), one Na(3), one Na(6), one Co(1), and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Na(4), one Na(5), one Co(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(6), one Co(2), and one P(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(3), one Na(5), one Co(3), and one P(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(4), one Na(6), one Co(4), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(7), one Na(9), one Co(2), and one P(3) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Na(10), one Na(8), one Co(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Na(8), one Na(9), one Co(4), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(10), one Na(7), one Co(3), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Na(8), one Na(9), one Co(3), and one C(3) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Na(10), one Na(7), one Co(4), and one C(4) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Li(2) and one C(3) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one C(4) atom. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(7), one Na(9), and one C(1) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Na(1), one Na(10), one Na(2), one Na(8), and one C(2) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Na(3), one Na(4), one Li(1), one Co(1), and one P(1) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Na(3), one Na(4), one Li(2), one Co(2), and one P(2) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Na(5), one Na(6), one Li(1), one Co(2), and one P(1) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Na(5), one Na(6), one Li(2), one Co(1), and one P(2) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one Na(1), one Na(10), one Co(3), and one P(3) atom. In the twenty-sixth O site, O(26) is bonded in a 4-coordinate geometry to one Na(2), one Na(9), one Co(4), and one P(4) atom. In the twenty-seventh O site, O(27) is bonded in a 4-coordinate geometry to one Na(1), one Na(8), one Co(4), and one P(3) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one Na(2), one Na(7), one Co(3), and one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5LiCo2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.202
_cell_length_b   6.745
_cell_length_c   8.836
_cell_angle_alpha   90.005
_cell_angle_beta   92.530
_cell_angle_gamma   90.025
_symmetry_Int_Tables_number   1
_cell_volume   309.718
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.288  0.250  0.059  1.0
  C  C1  1  0.704  0.750  0.949  1.0
  Co  Co2  1  0.224  0.250  0.344  1.0
  Co  Co3  1  0.783  0.750  0.646  1.0
  Li  Li4  1  0.224  0.750  0.106  1.0
  Na  Na5  1  0.776  0.250  0.915  1.0
  Na  Na6  1  0.741  0.992  0.265  1.0
  Na  Na7  1  0.740  0.509  0.265  1.0
  Na  Na8  1  0.264  0.008  0.729  1.0
  Na  Na9  1  0.264  0.493  0.729  1.0
  O  O10  1  0.608  0.750  0.082  1.0
  O  O11  1  0.062  0.248  0.116  1.0
  O  O12  1  0.487  0.251  0.154  1.0
  O  O13  1  0.859  0.250  0.430  1.0
  O  O14  1  0.576  0.750  0.444  1.0
  O  O15  1  0.426  0.249  0.551  1.0
  O  O16  1  0.144  0.750  0.563  1.0
  O  O17  1  0.547  0.750  0.829  1.0
  O  O18  1  0.951  0.749  0.932  1.0
  O  O19  1  0.316  0.250  0.915  1.0
  O  O20  1  0.204  0.932  0.309  1.0
  O  O21  1  0.205  0.567  0.309  1.0
  O  O22  1  0.802  0.435  0.681  1.0
  O  O23  1  0.802  0.065  0.681  1.0
  P  P24  1  0.280  0.750  0.411  1.0
  P  P25  1  0.725  0.250  0.583  1.0
[/CIF]
.
The crystal structure described by Na5LiCo2P2(CO7)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(19), one O(20), one O(25), one O(27), one O(4), and one O(5) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(19), one O(20), one O(26), one O(28), one O(3), and one O(6) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(1), one O(21), one O(22), one O(3), one O(6), one O(8), and one O(9) atom. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(10), one O(2), one O(21), one O(22), one O(4), one O(5), and one O(7) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(1), one O(23), one O(24), one O(4), one O(5), one O(7), and one O(9) atom. In the sixth Na site, Na(6) is bonded in a 7-coordinate geometry to one O(10), one O(2), one O(23), one O(24), one O(3), one O(6), and one O(8) atom. In the seventh Na site, Na(7) is bonded in a 5-coordinate geometry to one O(11), one O(14), one O(16), one O(19), and one O(28) atom. In the eighth Na site, Na(8) is bonded in a 5-coordinate geometry to one O(12), one O(13), one O(15), one O(20), and one O(27) atom. In the ninth Na site, Na(9) is bonded in a 5-coordinate geometry to one O(11), one O(13), one O(15), one O(19), and one O(26) atom. In the tenth Na site, Na(10) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(16), one O(20), and one O(25) atom. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(18), one O(21), and one O(23) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(17), one O(2), one O(22), and one O(24) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(21), one O(24), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. In the second Co site, Co(2) is bonded to one O(11), one O(22), one O(23), one O(3), one O(5), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. In the third Co site, Co(3) is bonded in a 5-coordinate geometry to one O(14), one O(15), one O(25), one O(28), and one O(9) atom. In the fourth Co site, Co(4) is bonded in a 5-coordinate geometry to one O(10), one O(13), one O(16), one O(26), and one O(27) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(19), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(20), one O(4), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(1), one O(15), and one O(17) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(16), one O(18), and one O(2) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(13), one O(21), one O(23), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and  a cornercorner with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 46°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(22), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and  a cornercorner with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 46°. In the third P site, P(3) is bonded to one O(11), one O(25), one O(27), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and  a cornercorner with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-51°. In the fourth P site, P(4) is bonded to one O(12), one O(26), one O(28), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and  a cornercorner with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-52°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(3), one Na(5), one Li(1), and one C(3) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Na(4), one Na(6), one Li(2), and one C(4) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(2), one Na(3), one Na(6), one Co(2), and one C(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(1), one Na(4), one Na(5), one Co(1), and one C(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Na(1), one Na(4), one Na(5), one Co(2), and one C(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Na(2), one Na(3), one Na(6), one Co(1), and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Na(4), one Na(5), one Co(1), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(6), one Co(2), and one P(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(3), one Na(5), one Co(3), and one P(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(4), one Na(6), one Co(4), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(7), one Na(9), one Co(2), and one P(3) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Na(10), one Na(8), one Co(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Na(8), one Na(9), one Co(4), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(10), one Na(7), one Co(3), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Na(8), one Na(9), one Co(3), and one C(3) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Na(10), one Na(7), one Co(4), and one C(4) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Li(2) and one C(3) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one C(4) atom. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(7), one Na(9), and one C(1) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Na(1), one Na(10), one Na(2), one Na(8), and one C(2) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Na(3), one Na(4), one Li(1), one Co(1), and one P(1) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Na(3), one Na(4), one Li(2), one Co(2), and one P(2) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Na(5), one Na(6), one Li(1), one Co(2), and one P(1) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Na(5), one Na(6), one Li(2), one Co(1), and one P(2) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one Na(1), one Na(10), one Co(3), and one P(3) atom. In the twenty-sixth O site, O(26) is bonded in a 4-coordinate geometry to one Na(2), one Na(9), one Co(4), and one P(4) atom. In the twenty-seventh O site, O(27) is bonded in a 4-coordinate geometry to one Na(1), one Na(8), one Co(4), and one P(3) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one Na(2), one Na(7), one Co(3), and one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5LiCo2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.202
_cell_length_b   6.745
_cell_length_c   8.836
_cell_angle_alpha   90.005
_cell_angle_beta   92.530
_cell_angle_gamma   90.025
_symmetry_Int_Tables_number   1
_cell_volume   309.718
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.288  0.250  0.059  1.0
  C  C1  1  0.704  0.750  0.949  1.0
  Co  Co2  1  0.224  0.250  0.344  1.0
  Co  Co3  1  0.783  0.750  0.646  1.0
  Li  Li4  1  0.224  0.750  0.106  1.0
  Na  Na5  1  0.776  0.250  0.915  1.0
  Na  Na6  1  0.741  0.992  0.265  1.0
  Na  Na7  1  0.740  0.509  0.265  1.0
  Na  Na8  1  0.264  0.008  0.729  1.0
  Na  Na9  1  0.264  0.493  0.729  1.0
  O  O10  1  0.608  0.750  0.082  1.0
  O  O11  1  0.062  0.248  0.116  1.0
  O  O12  1  0.487  0.251  0.154  1.0
  O  O13  1  0.859  0.250  0.430  1.0
  O  O14  1  0.576  0.750  0.444  1.0
  O  O15  1  0.426  0.249  0.551  1.0
  O  O16  1  0.144  0.750  0.563  1.0
  O  O17  1  0.547  0.750  0.829  1.0
  O  O18  1  0.951  0.749  0.932  1.0
  O  O19  1  0.316  0.250  0.915  1.0
  O  O20  1  0.204  0.932  0.309  1.0
  O  O21  1  0.205  0.567  0.309  1.0
  O  O22  1  0.802  0.435  0.681  1.0
  O  O23  1  0.802  0.065  0.681  1.0
  P  P24  1  0.280  0.750  0.411  1.0
  P  P25  1  0.725  0.250  0.583  1.0
[/CIF]
.