The compound described by Mn8O13F3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(2), one O(3), one O(6), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, and edges with two equivalent Mn(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-58°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(12), one O(4), one O(5), and one O(7) atom to form MnO6 octahedra that share corners with two equivalent Mn(6)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the third Mn site, Mn(3) is bonded to one O(1), one O(11), one O(13), one O(2), one O(3), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(6)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-58°. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(6), one O(7), one O(8), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(5), one O(7), one O(8), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(13), one O(2), one O(4), one F(2), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 41-63°. In the seventh Mn site, Mn(7) is bonded to one O(10), one O(3), one O(6), one O(8), one F(2), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-63°. In the eighth Mn site, Mn(8) is bonded to one O(11), one O(12), one O(13), one O(4), one O(5), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(6)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-56°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(8) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(8) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(8) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(7) atom. is represented by the CIF file [CIF]
data_Mn8O13F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.997
_cell_length_b   7.090
_cell_length_c   7.148
_cell_angle_alpha   101.682
_cell_angle_beta   90.145
_cell_angle_gamma   90.069
_symmetry_Int_Tables_number   1
_cell_volume   248.002
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.711  0.072  0.436  1.0
  Mn  Mn1  1  0.259  0.427  0.071  1.0
  Mn  Mn2  1  0.775  0.081  0.938  1.0
  Mn  Mn3  1  0.263  0.434  0.578  1.0
  Mn  Mn4  1  0.743  0.583  0.416  1.0
  Mn  Mn5  1  0.259  0.917  0.077  1.0
  Mn  Mn6  1  0.226  0.923  0.582  1.0
  Mn  Mn7  1  0.759  0.571  0.925  1.0
  O  O8  1  0.094  0.173  0.060  1.0
  O  O9  1  0.582  0.061  0.175  1.0
  O  O10  1  0.904  0.063  0.675  1.0
  O  O11  1  0.437  0.667  0.061  1.0
  O  O12  1  0.934  0.562  0.167  1.0
  O  O13  1  0.399  0.174  0.559  1.0
  O  O14  1  0.424  0.437  0.327  1.0
  O  O15  1  0.070  0.666  0.556  1.0
  O  O16  1  0.582  0.561  0.672  1.0
  O  O17  1  0.549  0.834  0.438  1.0
  O  O18  1  0.591  0.327  0.938  1.0
  O  O19  1  0.089  0.439  0.827  1.0
  O  O20  1  0.935  0.828  0.933  1.0
  F  F21  1  0.924  0.314  0.441  1.0
  F  F22  1  0.034  0.941  0.324  1.0
  F  F23  1  0.456  0.945  0.825  1.0
[/CIF]
.
The compound described by Mn8O13F3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(2), one O(3), one O(6), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, and edges with two equivalent Mn(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-58°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(12), one O(4), one O(5), and one O(7) atom to form MnO6 octahedra that share corners with two equivalent Mn(6)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the third Mn site, Mn(3) is bonded to one O(1), one O(11), one O(13), one O(2), one O(3), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(6)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-58°. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(6), one O(7), one O(8), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(5), one O(7), one O(8), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(13), one O(2), one O(4), one F(2), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 41-63°. In the seventh Mn site, Mn(7) is bonded to one O(10), one O(3), one O(6), one O(8), one F(2), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-63°. In the eighth Mn site, Mn(8) is bonded to one O(11), one O(12), one O(13), one O(4), one O(5), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(6)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-56°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(8) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(8) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(8) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(7) atom. is represented by the CIF file [CIF]
data_Mn8O13F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.997
_cell_length_b   7.090
_cell_length_c   7.148
_cell_angle_alpha   101.682
_cell_angle_beta   90.145
_cell_angle_gamma   90.069
_symmetry_Int_Tables_number   1
_cell_volume   248.002
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.711  0.072  0.436  1.0
  Mn  Mn1  1  0.259  0.427  0.071  1.0
  Mn  Mn2  1  0.775  0.081  0.938  1.0
  Mn  Mn3  1  0.263  0.434  0.578  1.0
  Mn  Mn4  1  0.743  0.583  0.416  1.0
  Mn  Mn5  1  0.259  0.917  0.077  1.0
  Mn  Mn6  1  0.226  0.923  0.582  1.0
  Mn  Mn7  1  0.759  0.571  0.925  1.0
  O  O8  1  0.094  0.173  0.060  1.0
  O  O9  1  0.582  0.061  0.175  1.0
  O  O10  1  0.904  0.063  0.675  1.0
  O  O11  1  0.437  0.667  0.061  1.0
  O  O12  1  0.934  0.562  0.167  1.0
  O  O13  1  0.399  0.174  0.559  1.0
  O  O14  1  0.424  0.437  0.327  1.0
  O  O15  1  0.070  0.666  0.556  1.0
  O  O16  1  0.582  0.561  0.672  1.0
  O  O17  1  0.549  0.834  0.438  1.0
  O  O18  1  0.591  0.327  0.938  1.0
  O  O19  1  0.089  0.439  0.827  1.0
  O  O20  1  0.935  0.828  0.933  1.0
  F  F21  1  0.924  0.314  0.441  1.0
  F  F22  1  0.034  0.941  0.324  1.0
  F  F23  1  0.456  0.945  0.825  1.0
[/CIF]
.