The structure described by Li4Co7O3F13 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one F(1), one F(12), and one F(2) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(3), one F(4), one F(5), and one F(9) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one F(3), one F(6), one F(7), and one F(8) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(2), one F(10), one F(11), and one F(13) atom. There are seven inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one F(1), and one F(7) atom. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one F(2), one F(4), and one F(9) atom. In the third Co site, Co(3) is bonded in a 2-coordinate geometry to one F(4), one F(8), and one F(9) atom. In the fourth Co site, Co(4) is bonded in a 2-coordinate geometry to one O(1), one F(13), and one F(2) atom. In the fifth Co site, Co(5) is bonded in a 4-coordinate geometry to one O(2), one O(3), one F(1), and one F(7) atom. In the sixth Co site, Co(6) is bonded in a 4-coordinate geometry to one F(11), one F(12), one F(5), and one F(6) atom. In the seventh Co site, Co(7) is bonded in a 2-coordinate geometry to one F(10), one F(13), one F(3), and one F(8) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one Co(2), and one Co(4) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(1), one Co(2), and one Co(5) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(2), one Co(1), and one Co(5) atom. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Co(1), and one Co(5) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Li(1), one Co(2), and one Co(4) atom. In the third F site, F(3) is bonded in a 2-coordinate geometry to one Li(3) and one Co(7) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Li(2), one Co(2), and one Co(3) atom. In the fifth F site, F(5) is bonded in a 2-coordinate geometry to one Li(2) and one Co(6) atom. In the sixth F site, F(6) is bonded in a 1-coordinate geometry to one Li(3) and one Co(6) atom. In the seventh F site, F(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Co(1), and one Co(5) atom. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Li(3), one Co(3), and one Co(7) atom. In the ninth F site, F(9) is bonded in a 3-coordinate geometry to one Li(2), one Co(2), and one Co(3) atom. In the tenth F site, F(10) is bonded in a 2-coordinate geometry to one Li(4) and one Co(7) atom. In the eleventh F site, F(11) is bonded in a distorted single-bond geometry to one Li(4) and one Co(6) atom. In the twelfth F site, F(12) is bonded in a 2-coordinate geometry to one Li(1) and one Co(6) atom. In the thirteenth F site, F(13) is bonded in a 3-coordinate geometry to one Li(4), one Co(4), and one Co(7) atom. is represented by the CIF card [CIF]
data_Li4Co7O3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.065
_cell_length_b   6.093
_cell_length_c   10.540
_cell_angle_alpha   105.485
_cell_angle_beta   91.488
_cell_angle_gamma   118.989
_symmetry_Int_Tables_number   1
_cell_volume   322.719
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.902  0.183  0.939  1.0
  Li  Li1  1  0.130  0.351  0.559  1.0
  Li  Li2  1  0.873  0.665  0.441  1.0
  Li  Li3  1  0.116  0.821  0.058  1.0
  Co  Co4  1  0.478  0.741  0.750  1.0
  Co  Co5  1  0.463  0.228  0.771  1.0
  Co  Co6  1  0.481  0.992  0.500  1.0
  Co  Co7  1  0.497  0.488  0.001  1.0
  Co  Co8  1  0.023  0.750  0.747  1.0
  Co  Co9  1  0.995  0.242  0.251  1.0
  Co  Co10  1  0.492  0.748  0.249  1.0
  O  O11  1  0.306  0.397  0.867  1.0
  O  O12  1  0.274  0.896  0.858  1.0
  O  O13  1  0.269  0.666  0.626  1.0
  F  F14  1  0.758  0.855  0.864  1.0
  F  F15  1  0.749  0.376  0.873  1.0
  F  F16  1  0.742  0.873  0.371  1.0
  F  F17  1  0.726  0.137  0.634  1.0
  F  F18  1  0.240  0.392  0.364  1.0
  F  F19  1  0.754  0.337  0.384  1.0
  F  F20  1  0.746  0.612  0.640  1.0
  F  F21  1  0.259  0.856  0.375  1.0
  F  F22  1  0.266  0.146  0.628  1.0
  F  F23  1  0.243  0.610  0.127  1.0
  F  F24  1  0.235  0.142  0.123  1.0
  F  F25  1  0.756  0.104  0.134  1.0
  F  F26  1  0.726  0.643  0.116  1.0
[/CIF]
.
The structure described by Li4Co7O3F13 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one F(1), one F(12), and one F(2) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(3), one F(4), one F(5), and one F(9) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one F(3), one F(6), one F(7), and one F(8) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(2), one F(10), one F(11), and one F(13) atom. There are seven inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one F(1), and one F(7) atom. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one F(2), one F(4), and one F(9) atom. In the third Co site, Co(3) is bonded in a 2-coordinate geometry to one F(4), one F(8), and one F(9) atom. In the fourth Co site, Co(4) is bonded in a 2-coordinate geometry to one O(1), one F(13), and one F(2) atom. In the fifth Co site, Co(5) is bonded in a 4-coordinate geometry to one O(2), one O(3), one F(1), and one F(7) atom. In the sixth Co site, Co(6) is bonded in a 4-coordinate geometry to one F(11), one F(12), one F(5), and one F(6) atom. In the seventh Co site, Co(7) is bonded in a 2-coordinate geometry to one F(10), one F(13), one F(3), and one F(8) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one Co(2), and one Co(4) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(1), one Co(2), and one Co(5) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(2), one Co(1), and one Co(5) atom. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Co(1), and one Co(5) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Li(1), one Co(2), and one Co(4) atom. In the third F site, F(3) is bonded in a 2-coordinate geometry to one Li(3) and one Co(7) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Li(2), one Co(2), and one Co(3) atom. In the fifth F site, F(5) is bonded in a 2-coordinate geometry to one Li(2) and one Co(6) atom. In the sixth F site, F(6) is bonded in a 1-coordinate geometry to one Li(3) and one Co(6) atom. In the seventh F site, F(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Co(1), and one Co(5) atom. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Li(3), one Co(3), and one Co(7) atom. In the ninth F site, F(9) is bonded in a 3-coordinate geometry to one Li(2), one Co(2), and one Co(3) atom. In the tenth F site, F(10) is bonded in a 2-coordinate geometry to one Li(4) and one Co(7) atom. In the eleventh F site, F(11) is bonded in a distorted single-bond geometry to one Li(4) and one Co(6) atom. In the twelfth F site, F(12) is bonded in a 2-coordinate geometry to one Li(1) and one Co(6) atom. In the thirteenth F site, F(13) is bonded in a 3-coordinate geometry to one Li(4), one Co(4), and one Co(7) atom. is represented by the CIF card [CIF]
data_Li4Co7O3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.065
_cell_length_b   6.093
_cell_length_c   10.540
_cell_angle_alpha   105.485
_cell_angle_beta   91.488
_cell_angle_gamma   118.989
_symmetry_Int_Tables_number   1
_cell_volume   322.719
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.902  0.183  0.939  1.0
  Li  Li1  1  0.130  0.351  0.559  1.0
  Li  Li2  1  0.873  0.665  0.441  1.0
  Li  Li3  1  0.116  0.821  0.058  1.0
  Co  Co4  1  0.478  0.741  0.750  1.0
  Co  Co5  1  0.463  0.228  0.771  1.0
  Co  Co6  1  0.481  0.992  0.500  1.0
  Co  Co7  1  0.497  0.488  0.001  1.0
  Co  Co8  1  0.023  0.750  0.747  1.0
  Co  Co9  1  0.995  0.242  0.251  1.0
  Co  Co10  1  0.492  0.748  0.249  1.0
  O  O11  1  0.306  0.397  0.867  1.0
  O  O12  1  0.274  0.896  0.858  1.0
  O  O13  1  0.269  0.666  0.626  1.0
  F  F14  1  0.758  0.855  0.864  1.0
  F  F15  1  0.749  0.376  0.873  1.0
  F  F16  1  0.742  0.873  0.371  1.0
  F  F17  1  0.726  0.137  0.634  1.0
  F  F18  1  0.240  0.392  0.364  1.0
  F  F19  1  0.754  0.337  0.384  1.0
  F  F20  1  0.746  0.612  0.640  1.0
  F  F21  1  0.259  0.856  0.375  1.0
  F  F22  1  0.266  0.146  0.628  1.0
  F  F23  1  0.243  0.610  0.127  1.0
  F  F24  1  0.235  0.142  0.123  1.0
  F  F25  1  0.756  0.104  0.134  1.0
  F  F26  1  0.726  0.643  0.116  1.0
[/CIF]
.