The crystal structure described by (V3Pb5O12)2F2 crystallizes in the hexagonal P6_3/m space group. The structure consists of two hydrofluoric acid atoms inside a V3Pb5O12 framework. In the V3Pb5O12 framework, V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the second Pb site, Pb(2) is bonded in a distorted pentagonal planar geometry to one O(2) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1), one Pb(2), and two equivalent Pb(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(2) atoms. is represented by the CIF card [CIF]
data_V3Pb5O12F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.380
_cell_length_b   10.380
_cell_length_c   7.317
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   682.729
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.026  0.616  0.750  1.0
  V  V1  1  0.384  0.410  0.750  1.0
  V  V2  1  0.590  0.974  0.750  1.0
  V  V3  1  0.974  0.384  0.250  1.0
  V  V4  1  0.616  0.590  0.250  1.0
  V  V5  1  0.410  0.026  0.250  1.0
  Pb  Pb6  1  0.667  0.333  0.507  1.0
  Pb  Pb7  1  0.333  0.667  0.007  1.0
  Pb  Pb8  1  0.333  0.667  0.493  1.0
  Pb  Pb9  1  0.667  0.333  0.993  1.0
  Pb  Pb10  1  0.225  0.981  0.750  1.0
  Pb  Pb11  1  0.019  0.243  0.750  1.0
  Pb  Pb12  1  0.757  0.775  0.750  1.0
  Pb  Pb13  1  0.775  0.019  0.250  1.0
  Pb  Pb14  1  0.981  0.757  0.250  1.0
  Pb  Pb15  1  0.243  0.225  0.250  1.0
  O  O16  1  0.833  0.503  0.750  1.0
  O  O17  1  0.497  0.330  0.750  1.0
  O  O18  1  0.670  0.167  0.750  1.0
  O  O19  1  0.167  0.497  0.250  1.0
  O  O20  1  0.503  0.670  0.250  1.0
  O  O21  1  0.330  0.833  0.250  1.0
  O  O22  1  0.116  0.510  0.750  1.0
  O  O23  1  0.490  0.606  0.750  1.0
  O  O24  1  0.394  0.884  0.750  1.0
  O  O25  1  0.884  0.490  0.250  1.0
  O  O26  1  0.510  0.394  0.250  1.0
  O  O27  1  0.606  0.116  0.250  1.0
  O  O28  1  0.089  0.735  0.561  1.0
  O  O29  1  0.265  0.355  0.561  1.0
  O  O30  1  0.645  0.911  0.561  1.0
  O  O31  1  0.911  0.265  0.061  1.0
  O  O32  1  0.735  0.645  0.061  1.0
  O  O33  1  0.355  0.089  0.061  1.0
  O  O34  1  0.911  0.265  0.439  1.0
  O  O35  1  0.735  0.645  0.439  1.0
  O  O36  1  0.355  0.089  0.439  1.0
  O  O37  1  0.089  0.735  0.939  1.0
  O  O38  1  0.265  0.355  0.939  1.0
  O  O39  1  0.645  0.911  0.939  1.0
  F  F40  1  0.000  0.000  0.500  1.0
  F  F41  1  0.000  0.000  0.000  1.0
[/CIF]
.
The crystal structure described by (V3Pb5O12)2F2 crystallizes in the hexagonal P6_3/m space group. The structure consists of two hydrofluoric acid atoms inside a V3Pb5O12 framework. In the V3Pb5O12 framework, V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the second Pb site, Pb(2) is bonded in a distorted pentagonal planar geometry to one O(2) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1), one Pb(2), and two equivalent Pb(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(2) atoms. is represented by the CIF card [CIF]
data_V3Pb5O12F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.380
_cell_length_b   10.380
_cell_length_c   7.317
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   682.729
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.026  0.616  0.750  1.0
  V  V1  1  0.384  0.410  0.750  1.0
  V  V2  1  0.590  0.974  0.750  1.0
  V  V3  1  0.974  0.384  0.250  1.0
  V  V4  1  0.616  0.590  0.250  1.0
  V  V5  1  0.410  0.026  0.250  1.0
  Pb  Pb6  1  0.667  0.333  0.507  1.0
  Pb  Pb7  1  0.333  0.667  0.007  1.0
  Pb  Pb8  1  0.333  0.667  0.493  1.0
  Pb  Pb9  1  0.667  0.333  0.993  1.0
  Pb  Pb10  1  0.225  0.981  0.750  1.0
  Pb  Pb11  1  0.019  0.243  0.750  1.0
  Pb  Pb12  1  0.757  0.775  0.750  1.0
  Pb  Pb13  1  0.775  0.019  0.250  1.0
  Pb  Pb14  1  0.981  0.757  0.250  1.0
  Pb  Pb15  1  0.243  0.225  0.250  1.0
  O  O16  1  0.833  0.503  0.750  1.0
  O  O17  1  0.497  0.330  0.750  1.0
  O  O18  1  0.670  0.167  0.750  1.0
  O  O19  1  0.167  0.497  0.250  1.0
  O  O20  1  0.503  0.670  0.250  1.0
  O  O21  1  0.330  0.833  0.250  1.0
  O  O22  1  0.116  0.510  0.750  1.0
  O  O23  1  0.490  0.606  0.750  1.0
  O  O24  1  0.394  0.884  0.750  1.0
  O  O25  1  0.884  0.490  0.250  1.0
  O  O26  1  0.510  0.394  0.250  1.0
  O  O27  1  0.606  0.116  0.250  1.0
  O  O28  1  0.089  0.735  0.561  1.0
  O  O29  1  0.265  0.355  0.561  1.0
  O  O30  1  0.645  0.911  0.561  1.0
  O  O31  1  0.911  0.265  0.061  1.0
  O  O32  1  0.735  0.645  0.061  1.0
  O  O33  1  0.355  0.089  0.061  1.0
  O  O34  1  0.911  0.265  0.439  1.0
  O  O35  1  0.735  0.645  0.439  1.0
  O  O36  1  0.355  0.089  0.439  1.0
  O  O37  1  0.089  0.735  0.939  1.0
  O  O38  1  0.265  0.355  0.939  1.0
  O  O39  1  0.645  0.911  0.939  1.0
  F  F40  1  0.000  0.000  0.500  1.0
  F  F41  1  0.000  0.000  0.000  1.0
[/CIF]
.