The crystal structure described by TmRhIn5 crystallizes in the tetragonal P4/mmm space group. Tm(1) is bonded to four equivalent In(2) and eight equivalent In(1) atoms to form TmIn12 cuboctahedra that share corners with four equivalent Tm(1)In12 cuboctahedra, faces with four equivalent Tm(1)In12 cuboctahedra, and faces with four equivalent In(2)Tm4In8 cuboctahedra. Rh(1) is bonded in a body-centered cubic geometry to eight equivalent In(1) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to two equivalent Tm(1), two equivalent Rh(1), and two equivalent In(2) atoms. In the second In site, In(2) is bonded to four equivalent Tm(1) and eight equivalent In(1) atoms to form InTm4In8 cuboctahedra that share corners with four equivalent In(2)Tm4In8 cuboctahedra, faces with four equivalent Tm(1)In12 cuboctahedra, and faces with four equivalent In(2)Tm4In8 cuboctahedra. is represented by the CIF file [CIF]
data_TmIn5Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.624
_cell_length_b   4.624
_cell_length_c   7.379
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   157.734
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.000  0.000  0.000  1.0
  In  In1  1  0.000  0.500  0.299  1.0
  In  In2  1  0.000  0.500  0.701  1.0
  In  In3  1  0.500  0.000  0.299  1.0
  In  In4  1  0.500  0.000  0.701  1.0
  In  In5  1  0.500  0.500  0.000  1.0
  Rh  Rh6  1  0.000  0.000  0.500  1.0
[/CIF]
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The crystal structure described by TmRhIn5 crystallizes in the tetragonal P4/mmm space group. Tm(1) is bonded to four equivalent In(2) and eight equivalent In(1) atoms to form TmIn12 cuboctahedra that share corners with four equivalent Tm(1)In12 cuboctahedra, faces with four equivalent Tm(1)In12 cuboctahedra, and faces with four equivalent In(2)Tm4In8 cuboctahedra. Rh(1) is bonded in a body-centered cubic geometry to eight equivalent In(1) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to two equivalent Tm(1), two equivalent Rh(1), and two equivalent In(2) atoms. In the second In site, In(2) is bonded to four equivalent Tm(1) and eight equivalent In(1) atoms to form InTm4In8 cuboctahedra that share corners with four equivalent In(2)Tm4In8 cuboctahedra, faces with four equivalent Tm(1)In12 cuboctahedra, and faces with four equivalent In(2)Tm4In8 cuboctahedra. is represented by the CIF file [CIF]
data_TmIn5Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.624
_cell_length_b   4.624
_cell_length_c   7.379
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   157.734
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.000  0.000  0.000  1.0
  In  In1  1  0.000  0.500  0.299  1.0
  In  In2  1  0.000  0.500  0.701  1.0
  In  In3  1  0.500  0.000  0.299  1.0
  In  In4  1  0.500  0.000  0.701  1.0
  In  In5  1  0.500  0.500  0.000  1.0
  Rh  Rh6  1  0.000  0.000  0.500  1.0
[/CIF]
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