The compound described by Tm3ReB7 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 11-coordinate geometry to two equivalent B(1), two equivalent B(3), three equivalent B(2), and four equivalent B(4) atoms. In the second Tm site, Tm(2) is bonded in a 12-coordinate geometry to one Re(1), one B(1), four equivalent B(3), and six equivalent B(2) atoms. Re(1) is bonded in a 10-coordinate geometry to one Tm(2), two equivalent B(1), four equivalent B(3), and four equivalent B(4) atoms. There are four inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to one Tm(2), four equivalent Tm(1), two equivalent Re(1), and two equivalent B(4) atoms. In the second B site, B(2) is bonded in a 9-coordinate geometry to three equivalent Tm(1), three equivalent Tm(2), one B(3), and two equivalent B(2) atoms. In the third B site, B(3) is bonded in a 9-coordinate geometry to two equivalent Tm(1), two equivalent Tm(2), two equivalent Re(1), one B(2), one B(3), and one B(4) atom. In the fourth B site, B(4) is bonded in a 9-coordinate geometry to four equivalent Tm(1), two equivalent Re(1), one B(1), one B(3), and one B(4) atom. is represented by the CIF card [CIF]
data_Tm3ReB7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.973
_cell_length_b   7.973
_cell_length_c   9.268
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   154.801
_symmetry_Int_Tables_number   1
_cell_volume   250.808
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.894  0.106  0.059  1.0
  Tm  Tm1  1  0.106  0.894  0.559  1.0
  Tm  Tm2  1  0.106  0.894  0.941  1.0
  Tm  Tm3  1  0.894  0.106  0.441  1.0
  Tm  Tm4  1  0.243  0.757  0.250  1.0
  Tm  Tm5  1  0.757  0.243  0.750  1.0
  Re  Re6  1  0.053  0.947  0.250  1.0
  Re  Re7  1  0.947  0.053  0.750  1.0
  B  B8  1  0.453  0.547  0.250  1.0
  B  B9  1  0.547  0.453  0.750  1.0
  B  B10  1  0.728  0.272  0.034  1.0
  B  B11  1  0.272  0.728  0.534  1.0
  B  B12  1  0.272  0.728  0.966  1.0
  B  B13  1  0.728  0.272  0.466  1.0
  B  B14  1  0.633  0.367  0.351  1.0
  B  B15  1  0.367  0.633  0.851  1.0
  B  B16  1  0.367  0.633  0.649  1.0
  B  B17  1  0.633  0.367  0.149  1.0
  B  B18  1  0.519  0.481  0.406  1.0
  B  B19  1  0.481  0.519  0.906  1.0
  B  B20  1  0.481  0.519  0.594  1.0
  B  B21  1  0.519  0.481  0.094  1.0
[/CIF]
.
The compound described by Tm3ReB7 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 11-coordinate geometry to two equivalent B(1), two equivalent B(3), three equivalent B(2), and four equivalent B(4) atoms. In the second Tm site, Tm(2) is bonded in a 12-coordinate geometry to one Re(1), one B(1), four equivalent B(3), and six equivalent B(2) atoms. Re(1) is bonded in a 10-coordinate geometry to one Tm(2), two equivalent B(1), four equivalent B(3), and four equivalent B(4) atoms. There are four inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to one Tm(2), four equivalent Tm(1), two equivalent Re(1), and two equivalent B(4) atoms. In the second B site, B(2) is bonded in a 9-coordinate geometry to three equivalent Tm(1), three equivalent Tm(2), one B(3), and two equivalent B(2) atoms. In the third B site, B(3) is bonded in a 9-coordinate geometry to two equivalent Tm(1), two equivalent Tm(2), two equivalent Re(1), one B(2), one B(3), and one B(4) atom. In the fourth B site, B(4) is bonded in a 9-coordinate geometry to four equivalent Tm(1), two equivalent Re(1), one B(1), one B(3), and one B(4) atom. is represented by the CIF card [CIF]
data_Tm3ReB7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.973
_cell_length_b   7.973
_cell_length_c   9.268
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   154.801
_symmetry_Int_Tables_number   1
_cell_volume   250.808
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.894  0.106  0.059  1.0
  Tm  Tm1  1  0.106  0.894  0.559  1.0
  Tm  Tm2  1  0.106  0.894  0.941  1.0
  Tm  Tm3  1  0.894  0.106  0.441  1.0
  Tm  Tm4  1  0.243  0.757  0.250  1.0
  Tm  Tm5  1  0.757  0.243  0.750  1.0
  Re  Re6  1  0.053  0.947  0.250  1.0
  Re  Re7  1  0.947  0.053  0.750  1.0
  B  B8  1  0.453  0.547  0.250  1.0
  B  B9  1  0.547  0.453  0.750  1.0
  B  B10  1  0.728  0.272  0.034  1.0
  B  B11  1  0.272  0.728  0.534  1.0
  B  B12  1  0.272  0.728  0.966  1.0
  B  B13  1  0.728  0.272  0.466  1.0
  B  B14  1  0.633  0.367  0.351  1.0
  B  B15  1  0.367  0.633  0.851  1.0
  B  B16  1  0.367  0.633  0.649  1.0
  B  B17  1  0.633  0.367  0.149  1.0
  B  B18  1  0.519  0.481  0.406  1.0
  B  B19  1  0.481  0.519  0.906  1.0
  B  B20  1  0.481  0.519  0.594  1.0
  B  B21  1  0.519  0.481  0.094  1.0
[/CIF]
.