The material structure described by W(OF2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four ammonia atoms and two W(OF2)2 clusters. In each W(OF2)2 cluster, W(1) is bonded in a distorted pentagonal pyramidal geometry to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one W(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one W(1) and one O(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WN2(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.850
_cell_length_b   6.198
_cell_length_c   7.959
_cell_angle_alpha   73.048
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   370.357
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.260  0.354  0.260  1.0
  W  W1  1  0.760  0.646  0.740  1.0
  N  N2  1  0.746  0.254  0.462  1.0
  N  N3  1  0.246  0.746  0.538  1.0
  N  N4  1  0.256  0.069  0.885  1.0
  N  N5  1  0.756  0.931  0.115  1.0
  O  O6  1  0.194  0.547  0.036  1.0
  O  O7  1  0.694  0.453  0.964  1.0
  O  O8  1  0.108  0.604  0.187  1.0
  O  O9  1  0.608  0.396  0.813  1.0
  F  F10  1  0.221  0.299  0.504  1.0
  F  F11  1  0.721  0.701  0.496  1.0
  F  F12  1  0.913  0.824  0.826  1.0
  F  F13  1  0.454  0.517  0.293  1.0
  F  F14  1  0.598  0.877  0.725  1.0
  F  F15  1  0.954  0.483  0.707  1.0
  F  F16  1  0.098  0.123  0.275  1.0
  F  F17  1  0.413  0.176  0.174  1.0
[/CIF]
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The material structure described by W(OF2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four ammonia atoms and two W(OF2)2 clusters. In each W(OF2)2 cluster, W(1) is bonded in a distorted pentagonal pyramidal geometry to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one W(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one W(1) and one O(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WN2(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.850
_cell_length_b   6.198
_cell_length_c   7.959
_cell_angle_alpha   73.048
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   370.357
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.260  0.354  0.260  1.0
  W  W1  1  0.760  0.646  0.740  1.0
  N  N2  1  0.746  0.254  0.462  1.0
  N  N3  1  0.246  0.746  0.538  1.0
  N  N4  1  0.256  0.069  0.885  1.0
  N  N5  1  0.756  0.931  0.115  1.0
  O  O6  1  0.194  0.547  0.036  1.0
  O  O7  1  0.694  0.453  0.964  1.0
  O  O8  1  0.108  0.604  0.187  1.0
  O  O9  1  0.608  0.396  0.813  1.0
  F  F10  1  0.221  0.299  0.504  1.0
  F  F11  1  0.721  0.701  0.496  1.0
  F  F12  1  0.913  0.824  0.826  1.0
  F  F13  1  0.454  0.517  0.293  1.0
  F  F14  1  0.598  0.877  0.725  1.0
  F  F15  1  0.954  0.483  0.707  1.0
  F  F16  1  0.098  0.123  0.275  1.0
  F  F17  1  0.413  0.176  0.174  1.0
[/CIF]
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