The material structure described by Rh3Te4 crystallizes in the monoclinic C2/m space group. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to three equivalent Te(1) and three equivalent Te(2) atoms to form a mixture of distorted face, corner, and edge-sharing RhTe6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the second Rh site, Rh(2) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form a mixture of face, corner, and edge-sharing RhTe6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one Rh(2) and three equivalent Rh(1) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to two equivalent Rh(2) and three equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Te4Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.984
_cell_length_b   6.805
_cell_length_c   6.850
_cell_angle_alpha   117.636
_cell_angle_beta   90.000
_cell_angle_gamma   107.019
_symmetry_Int_Tables_number   1
_cell_volume   155.282
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.879  0.758  0.546  1.0
  Te  Te1  1  0.121  0.242  0.454  1.0
  Te  Te2  1  0.634  0.269  0.981  1.0
  Te  Te3  1  0.366  0.731  0.019  1.0
  Rh  Rh4  1  0.735  0.470  0.718  1.0
  Rh  Rh5  1  0.265  0.530  0.282  1.0
  Rh  Rh6  1  0.000  0.000  0.000  1.0
[/CIF]
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The material structure described by Rh3Te4 crystallizes in the monoclinic C2/m space group. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to three equivalent Te(1) and three equivalent Te(2) atoms to form a mixture of distorted face, corner, and edge-sharing RhTe6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the second Rh site, Rh(2) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form a mixture of face, corner, and edge-sharing RhTe6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one Rh(2) and three equivalent Rh(1) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to two equivalent Rh(2) and three equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Te4Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.984
_cell_length_b   6.805
_cell_length_c   6.850
_cell_angle_alpha   117.636
_cell_angle_beta   90.000
_cell_angle_gamma   107.019
_symmetry_Int_Tables_number   1
_cell_volume   155.282
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.879  0.758  0.546  1.0
  Te  Te1  1  0.121  0.242  0.454  1.0
  Te  Te2  1  0.634  0.269  0.981  1.0
  Te  Te3  1  0.366  0.731  0.019  1.0
  Rh  Rh4  1  0.735  0.470  0.718  1.0
  Rh  Rh5  1  0.265  0.530  0.282  1.0
  Rh  Rh6  1  0.000  0.000  0.000  1.0
[/CIF]
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