The compound described by AlPH9(CCl)3 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two AlPH9(CCl)3 clusters. Al(1) is bonded to one P(1), one Cl(2), and two equivalent Cl(1) atoms to form AlPCl3 tetrahedra that share  a cornercorner with one C(2)PH3 tetrahedra and corners with two equivalent C(1)PH3 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded to one P(1), one H(1), one H(2), and one H(3) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one Al(1)PCl3 tetrahedra,  a cornercorner with one C(1)PH3 tetrahedra, and  a cornercorner with one C(2)PH3 tetrahedra. In the second C site, C(2) is bonded to one P(1), one H(4), and two equivalent H(5) atoms to form distorted CPH3 tetrahedra that share  a cornercorner with one Al(1)PCl3 tetrahedra and corners with two equivalent C(1)PH3 tetrahedra. P(1) is bonded in a tetrahedral geometry to one Al(1), one C(2), and two equivalent C(1) atoms. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF file [CIF]
data_AlPH9(CCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.775
_cell_length_b   8.040
_cell_length_c   10.878
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   113.599
_symmetry_Int_Tables_number   1
_cell_volume   542.983
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.402  0.925  0.750  1.0
  Al  Al1  1  0.598  0.075  0.250  1.0
  P  P2  1  0.428  0.236  0.750  1.0
  P  P3  1  0.572  0.764  0.250  1.0
  H  H4  1  0.372  0.259  0.532  1.0
  H  H5  1  0.628  0.741  0.032  1.0
  H  H6  1  0.628  0.741  0.468  1.0
  H  H7  1  0.372  0.259  0.968  1.0
  H  H8  1  0.127  0.196  0.617  1.0
  H  H9  1  0.873  0.804  0.117  1.0
  H  H10  1  0.873  0.804  0.383  1.0
  H  H11  1  0.127  0.196  0.883  1.0
  H  H12  1  0.319  0.427  0.619  1.0
  H  H13  1  0.681  0.573  0.119  1.0
  H  H14  1  0.681  0.573  0.381  1.0
  H  H15  1  0.319  0.427  0.881  1.0
  H  H16  1  0.708  0.540  0.750  1.0
  H  H17  1  0.292  0.460  0.250  1.0
  H  H18  1  0.788  0.385  0.832  1.0
  H  H19  1  0.212  0.615  0.332  1.0
  H  H20  1  0.212  0.615  0.168  1.0
  H  H21  1  0.788  0.385  0.668  1.0
  C  C22  1  0.299  0.284  0.616  1.0
  C  C23  1  0.701  0.716  0.116  1.0
  C  C24  1  0.701  0.716  0.384  1.0
  C  C25  1  0.299  0.284  0.884  1.0
  C  C26  1  0.705  0.403  0.750  1.0
  C  C27  1  0.295  0.597  0.250  1.0
  Cl  Cl28  1  0.229  0.793  0.588  1.0
  Cl  Cl29  1  0.771  0.207  0.088  1.0
  Cl  Cl30  1  0.771  0.207  0.412  1.0
  Cl  Cl31  1  0.229  0.793  0.912  1.0
  Cl  Cl32  1  0.720  0.927  0.750  1.0
  Cl  Cl33  1  0.280  0.073  0.250  1.0
[/CIF]
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The compound described by AlPH9(CCl)3 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two AlPH9(CCl)3 clusters. Al(1) is bonded to one P(1), one Cl(2), and two equivalent Cl(1) atoms to form AlPCl3 tetrahedra that share  a cornercorner with one C(2)PH3 tetrahedra and corners with two equivalent C(1)PH3 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded to one P(1), one H(1), one H(2), and one H(3) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one Al(1)PCl3 tetrahedra,  a cornercorner with one C(1)PH3 tetrahedra, and  a cornercorner with one C(2)PH3 tetrahedra. In the second C site, C(2) is bonded to one P(1), one H(4), and two equivalent H(5) atoms to form distorted CPH3 tetrahedra that share  a cornercorner with one Al(1)PCl3 tetrahedra and corners with two equivalent C(1)PH3 tetrahedra. P(1) is bonded in a tetrahedral geometry to one Al(1), one C(2), and two equivalent C(1) atoms. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF file [CIF]
data_AlPH9(CCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.775
_cell_length_b   8.040
_cell_length_c   10.878
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   113.599
_symmetry_Int_Tables_number   1
_cell_volume   542.983
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.402  0.925  0.750  1.0
  Al  Al1  1  0.598  0.075  0.250  1.0
  P  P2  1  0.428  0.236  0.750  1.0
  P  P3  1  0.572  0.764  0.250  1.0
  H  H4  1  0.372  0.259  0.532  1.0
  H  H5  1  0.628  0.741  0.032  1.0
  H  H6  1  0.628  0.741  0.468  1.0
  H  H7  1  0.372  0.259  0.968  1.0
  H  H8  1  0.127  0.196  0.617  1.0
  H  H9  1  0.873  0.804  0.117  1.0
  H  H10  1  0.873  0.804  0.383  1.0
  H  H11  1  0.127  0.196  0.883  1.0
  H  H12  1  0.319  0.427  0.619  1.0
  H  H13  1  0.681  0.573  0.119  1.0
  H  H14  1  0.681  0.573  0.381  1.0
  H  H15  1  0.319  0.427  0.881  1.0
  H  H16  1  0.708  0.540  0.750  1.0
  H  H17  1  0.292  0.460  0.250  1.0
  H  H18  1  0.788  0.385  0.832  1.0
  H  H19  1  0.212  0.615  0.332  1.0
  H  H20  1  0.212  0.615  0.168  1.0
  H  H21  1  0.788  0.385  0.668  1.0
  C  C22  1  0.299  0.284  0.616  1.0
  C  C23  1  0.701  0.716  0.116  1.0
  C  C24  1  0.701  0.716  0.384  1.0
  C  C25  1  0.299  0.284  0.884  1.0
  C  C26  1  0.705  0.403  0.750  1.0
  C  C27  1  0.295  0.597  0.250  1.0
  Cl  Cl28  1  0.229  0.793  0.588  1.0
  Cl  Cl29  1  0.771  0.207  0.088  1.0
  Cl  Cl30  1  0.771  0.207  0.412  1.0
  Cl  Cl31  1  0.229  0.793  0.912  1.0
  Cl  Cl32  1  0.720  0.927  0.750  1.0
  Cl  Cl33  1  0.280  0.073  0.250  1.0
[/CIF]
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