The crystal structure described by Ba(SbO2)3 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 10-coordinate geometry to one O(3), two equivalent O(4), two equivalent O(5), two equivalent O(6), and three equivalent O(2) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(5), and one O(6) atom. In the second Sb site, Sb(2) is bonded in a distorted see-saw-like geometry to one O(3), one O(4), and two equivalent O(1) atoms. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Sb(1), and one Sb(3) atom. In the second O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Sb(1), and one Sb(3) atom. In the third O site, O(1) is bonded in a distorted T-shaped geometry to one Sb(1) and two equivalent Sb(2) atoms. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to three equivalent Ba(1) and one Sb(3) atom. In the fifth O site, O(3) is bonded in a 3-coordinate geometry to one Ba(1), one Sb(1), and one Sb(2) atom. In the sixth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Sb(2), and one Sb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba(SbO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.509
_cell_length_b   9.557
_cell_length_c   14.434
_cell_angle_alpha   82.977
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   754.321
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.720  0.949  0.390  1.0
  Ba  Ba1  1  0.220  0.051  0.110  1.0
  Ba  Ba2  1  0.280  0.051  0.610  1.0
  Ba  Ba3  1  0.780  0.949  0.890  1.0
  Sb  Sb4  1  0.190  0.673  0.294  1.0
  Sb  Sb5  1  0.690  0.327  0.206  1.0
  Sb  Sb6  1  0.810  0.327  0.706  1.0
  Sb  Sb7  1  0.310  0.673  0.794  1.0
  Sb  Sb8  1  0.221  0.605  0.023  1.0
  Sb  Sb9  1  0.721  0.395  0.477  1.0
  Sb  Sb10  1  0.779  0.395  0.977  1.0
  Sb  Sb11  1  0.279  0.605  0.523  1.0
  Sb  Sb12  1  0.705  0.767  0.148  1.0
  Sb  Sb13  1  0.205  0.233  0.352  1.0
  Sb  Sb14  1  0.295  0.233  0.852  1.0
  Sb  Sb15  1  0.795  0.767  0.648  1.0
  O  O16  1  0.474  0.553  0.414  1.0
  O  O17  1  0.974  0.447  0.086  1.0
  O  O18  1  0.526  0.447  0.586  1.0
  O  O19  1  0.026  0.553  0.914  1.0
  O  O20  1  0.668  0.949  0.079  1.0
  O  O21  1  0.168  0.051  0.421  1.0
  O  O22  1  0.332  0.051  0.921  1.0
  O  O23  1  0.832  0.949  0.579  1.0
  O  O24  1  0.105  0.733  0.417  1.0
  O  O25  1  0.605  0.267  0.083  1.0
  O  O26  1  0.895  0.267  0.583  1.0
  O  O27  1  0.395  0.733  0.917  1.0
  O  O28  1  0.029  0.761  0.059  1.0
  O  O29  1  0.529  0.239  0.441  1.0
  O  O30  1  0.971  0.239  0.941  1.0
  O  O31  1  0.471  0.761  0.559  1.0
  O  O32  1  0.442  0.814  0.250  1.0
  O  O33  1  0.942  0.186  0.250  1.0
  O  O34  1  0.558  0.186  0.750  1.0
  O  O35  1  0.058  0.814  0.750  1.0
  O  O36  1  0.937  0.820  0.244  1.0
  O  O37  1  0.437  0.180  0.256  1.0
  O  O38  1  0.063  0.180  0.756  1.0
  O  O39  1  0.563  0.820  0.744  1.0
[/CIF]
.
The crystal structure described by Ba(SbO2)3 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 10-coordinate geometry to one O(3), two equivalent O(4), two equivalent O(5), two equivalent O(6), and three equivalent O(2) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(5), and one O(6) atom. In the second Sb site, Sb(2) is bonded in a distorted see-saw-like geometry to one O(3), one O(4), and two equivalent O(1) atoms. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Sb(1), and one Sb(3) atom. In the second O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Sb(1), and one Sb(3) atom. In the third O site, O(1) is bonded in a distorted T-shaped geometry to one Sb(1) and two equivalent Sb(2) atoms. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to three equivalent Ba(1) and one Sb(3) atom. In the fifth O site, O(3) is bonded in a 3-coordinate geometry to one Ba(1), one Sb(1), and one Sb(2) atom. In the sixth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Sb(2), and one Sb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba(SbO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.509
_cell_length_b   9.557
_cell_length_c   14.434
_cell_angle_alpha   82.977
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   754.321
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.720  0.949  0.390  1.0
  Ba  Ba1  1  0.220  0.051  0.110  1.0
  Ba  Ba2  1  0.280  0.051  0.610  1.0
  Ba  Ba3  1  0.780  0.949  0.890  1.0
  Sb  Sb4  1  0.190  0.673  0.294  1.0
  Sb  Sb5  1  0.690  0.327  0.206  1.0
  Sb  Sb6  1  0.810  0.327  0.706  1.0
  Sb  Sb7  1  0.310  0.673  0.794  1.0
  Sb  Sb8  1  0.221  0.605  0.023  1.0
  Sb  Sb9  1  0.721  0.395  0.477  1.0
  Sb  Sb10  1  0.779  0.395  0.977  1.0
  Sb  Sb11  1  0.279  0.605  0.523  1.0
  Sb  Sb12  1  0.705  0.767  0.148  1.0
  Sb  Sb13  1  0.205  0.233  0.352  1.0
  Sb  Sb14  1  0.295  0.233  0.852  1.0
  Sb  Sb15  1  0.795  0.767  0.648  1.0
  O  O16  1  0.474  0.553  0.414  1.0
  O  O17  1  0.974  0.447  0.086  1.0
  O  O18  1  0.526  0.447  0.586  1.0
  O  O19  1  0.026  0.553  0.914  1.0
  O  O20  1  0.668  0.949  0.079  1.0
  O  O21  1  0.168  0.051  0.421  1.0
  O  O22  1  0.332  0.051  0.921  1.0
  O  O23  1  0.832  0.949  0.579  1.0
  O  O24  1  0.105  0.733  0.417  1.0
  O  O25  1  0.605  0.267  0.083  1.0
  O  O26  1  0.895  0.267  0.583  1.0
  O  O27  1  0.395  0.733  0.917  1.0
  O  O28  1  0.029  0.761  0.059  1.0
  O  O29  1  0.529  0.239  0.441  1.0
  O  O30  1  0.971  0.239  0.941  1.0
  O  O31  1  0.471  0.761  0.559  1.0
  O  O32  1  0.442  0.814  0.250  1.0
  O  O33  1  0.942  0.186  0.250  1.0
  O  O34  1  0.558  0.186  0.750  1.0
  O  O35  1  0.058  0.814  0.750  1.0
  O  O36  1  0.937  0.820  0.244  1.0
  O  O37  1  0.437  0.180  0.256  1.0
  O  O38  1  0.063  0.180  0.756  1.0
  O  O39  1  0.563  0.820  0.744  1.0
[/CIF]
.