The material structure described by Zn(SbO2)2 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(16), one O(3), and one O(4) atom to form ZnO4 tetrahedra that share  a cornercorner with one Sb(8)O5 square pyramid and corners with two equivalent Zn(5)O5 square pyramids. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(5) atom. In the third Zn site, Zn(3) is bonded in a distorted see-saw-like geometry to one O(12), one O(5), one O(6), and one O(8) atom. In the fourth Zn site, Zn(4) is bonded in a trigonal planar geometry to one O(13), one O(18), and one O(19) atom. In the fifth Zn site, Zn(5) is bonded to one O(21), one O(22), one O(24), one O(3), and one O(4) atom to form ZnO5 square pyramids that share corners with two equivalent Zn(1)O4 tetrahedra and  an edgeedge with one Sb(8)O5 square pyramid. In the sixth Zn site, Zn(6) is bonded in a tetrahedral geometry to one O(14), one O(15), one O(20), and one O(23) atom. There are twelve inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one O(3), one O(4), and one O(9) atom. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(6) atom. In the third Sb site, Sb(3) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(11), and one O(17) atom. In the fourth Sb site, Sb(4) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(8) atom. In the fifth Sb site, Sb(5) is bonded in a 4-coordinate geometry to one O(11), one O(14), one O(5), and one O(7) atom. In the sixth Sb site, Sb(6) is bonded in a trigonal non-coplanar geometry to one O(13), one O(14), and one O(15) atom. In the seventh Sb site, Sb(7) is bonded in a 3-coordinate geometry to one O(17), one O(6), and one O(8) atom. In the eighth Sb site, Sb(8) is bonded to one O(16), one O(18), one O(19), one O(21), and one O(22) atom to form SbO5 square pyramids that share  a cornercorner with one Zn(1)O4 tetrahedra and  an edgeedge with one Zn(5)O5 square pyramid. In the ninth Sb site, Sb(9) is bonded in a 3-coordinate geometry to one O(10), one O(20), and one O(7) atom. In the tenth Sb site, Sb(10) is bonded in a 3-coordinate geometry to one O(19), one O(23), and one O(24) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(18), one O(23), and one O(24) atom. In the twelfth Sb site, Sb(12) is bonded in a distorted T-shaped geometry to one O(21), one O(22), and one O(9) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one Sb(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Sb(2) and one Sb(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(5), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(5), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Zn(2), one Zn(3), and one Sb(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Zn(3), one Sb(2), and one Sb(7) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(5) and one Sb(9) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Zn(3), one Sb(4), and one Sb(7) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(12) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Zn(2), one Sb(3), and one Sb(9) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(2), one Sb(3), and one Sb(5) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Zn(3) and one Sb(4) atom. In the thirteenth O site, O(13) is bonded in a linear geometry to one Zn(4) and one Sb(6) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Zn(6), one Sb(5), and one Sb(6) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one Sb(6) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Sb(3) and one Sb(7) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Zn(4), one Sb(11), and one Sb(8) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Zn(4), one Sb(10), and one Sb(8) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Zn(6) and one Sb(9) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Zn(5), one Sb(12), and one Sb(8) atom. In the twenty-second O site, O(22) is bonded in a distorted T-shaped geometry to one Zn(5), one Sb(12), and one Sb(8) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Zn(6), one Sb(10), and one Sb(11) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal non-coplanar geometry to one Zn(5), one Sb(10), and one Sb(11) atom. is represented by the CIF card [CIF]
data_Zn(SbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.526
_cell_length_b   6.965
_cell_length_c   17.429
_cell_angle_alpha   92.775
_cell_angle_beta   89.934
_cell_angle_gamma   117.754
_symmetry_Int_Tables_number   1
_cell_volume   699.978
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.816  0.650  0.044  1.0
  Zn  Zn1  1  0.469  0.963  0.409  1.0
  Zn  Zn2  1  0.219  0.419  0.331  1.0
  Zn  Zn3  1  0.188  0.358  0.740  1.0
  Zn  Zn4  1  0.492  0.978  0.996  1.0
  Zn  Zn5  1  0.481  0.952  0.628  1.0
  Sb  Sb6  1  0.328  0.664  0.120  1.0
  Sb  Sb7  1  0.391  0.222  0.175  1.0
  Sb  Sb8  1  0.945  0.952  0.459  1.0
  Sb  Sb9  1  0.877  0.204  0.195  1.0
  Sb  Sb10  1  0.034  0.514  0.496  1.0
  Sb  Sb11  1  0.892  0.772  0.658  1.0
  Sb  Sb12  1  0.837  0.683  0.259  1.0
  Sb  Sb13  1  0.664  0.323  0.867  1.0
  Sb  Sb14  1  0.490  0.393  0.513  1.0
  Sb  Sb15  1  0.650  0.814  0.821  1.0
  Sb  Sb16  1  0.166  0.809  0.820  1.0
  Sb  Sb17  1  0.172  0.336  0.941  1.0
  O  O18  1  0.692  0.423  0.125  1.0
  O  O19  1  0.539  0.056  0.226  1.0
  O  O20  1  0.620  0.818  0.063  1.0
  O  O21  1  0.182  0.808  0.062  1.0
  O  O22  1  0.300  0.644  0.418  1.0
  O  O23  1  0.497  0.452  0.268  1.0
  O  O24  1  0.173  0.347  0.546  1.0
  O  O25  1  0.972  0.474  0.268  1.0
  O  O26  1  0.205  0.389  0.052  1.0
  O  O27  1  0.300  0.131  0.429  1.0
  O  O28  1  0.799  0.127  0.422  1.0
  O  O29  1  0.036  0.128  0.278  1.0
  O  O30  1  0.048  0.073  0.698  1.0
  O  O31  1  0.147  0.765  0.583  1.0
  O  O32  1  0.647  0.784  0.595  1.0
  O  O33  1  0.795  0.608  0.927  1.0
  O  O34  1  0.856  0.725  0.373  1.0
  O  O35  1  0.014  0.493  0.790  1.0
  O  O36  1  0.498  0.502  0.786  1.0
  O  O37  1  0.560  0.237  0.590  1.0
  O  O38  1  0.811  0.183  0.946  1.0
  O  O39  1  0.370  0.172  0.944  1.0
  O  O40  1  0.439  0.878  0.746  1.0
  O  O41  1  0.392  0.778  0.895  1.0
[/CIF]
.
The material structure described by Zn(SbO2)2 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(16), one O(3), and one O(4) atom to form ZnO4 tetrahedra that share  a cornercorner with one Sb(8)O5 square pyramid and corners with two equivalent Zn(5)O5 square pyramids. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(5) atom. In the third Zn site, Zn(3) is bonded in a distorted see-saw-like geometry to one O(12), one O(5), one O(6), and one O(8) atom. In the fourth Zn site, Zn(4) is bonded in a trigonal planar geometry to one O(13), one O(18), and one O(19) atom. In the fifth Zn site, Zn(5) is bonded to one O(21), one O(22), one O(24), one O(3), and one O(4) atom to form ZnO5 square pyramids that share corners with two equivalent Zn(1)O4 tetrahedra and  an edgeedge with one Sb(8)O5 square pyramid. In the sixth Zn site, Zn(6) is bonded in a tetrahedral geometry to one O(14), one O(15), one O(20), and one O(23) atom. There are twelve inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one O(3), one O(4), and one O(9) atom. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(6) atom. In the third Sb site, Sb(3) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(11), and one O(17) atom. In the fourth Sb site, Sb(4) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(8) atom. In the fifth Sb site, Sb(5) is bonded in a 4-coordinate geometry to one O(11), one O(14), one O(5), and one O(7) atom. In the sixth Sb site, Sb(6) is bonded in a trigonal non-coplanar geometry to one O(13), one O(14), and one O(15) atom. In the seventh Sb site, Sb(7) is bonded in a 3-coordinate geometry to one O(17), one O(6), and one O(8) atom. In the eighth Sb site, Sb(8) is bonded to one O(16), one O(18), one O(19), one O(21), and one O(22) atom to form SbO5 square pyramids that share  a cornercorner with one Zn(1)O4 tetrahedra and  an edgeedge with one Zn(5)O5 square pyramid. In the ninth Sb site, Sb(9) is bonded in a 3-coordinate geometry to one O(10), one O(20), and one O(7) atom. In the tenth Sb site, Sb(10) is bonded in a 3-coordinate geometry to one O(19), one O(23), and one O(24) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(18), one O(23), and one O(24) atom. In the twelfth Sb site, Sb(12) is bonded in a distorted T-shaped geometry to one O(21), one O(22), and one O(9) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one Sb(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Sb(2) and one Sb(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(5), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(5), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Zn(2), one Zn(3), and one Sb(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Zn(3), one Sb(2), and one Sb(7) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(5) and one Sb(9) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Zn(3), one Sb(4), and one Sb(7) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(12) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Zn(2), one Sb(3), and one Sb(9) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(2), one Sb(3), and one Sb(5) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Zn(3) and one Sb(4) atom. In the thirteenth O site, O(13) is bonded in a linear geometry to one Zn(4) and one Sb(6) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Zn(6), one Sb(5), and one Sb(6) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one Sb(6) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Sb(3) and one Sb(7) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Zn(4), one Sb(11), and one Sb(8) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Zn(4), one Sb(10), and one Sb(8) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Zn(6) and one Sb(9) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Zn(5), one Sb(12), and one Sb(8) atom. In the twenty-second O site, O(22) is bonded in a distorted T-shaped geometry to one Zn(5), one Sb(12), and one Sb(8) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Zn(6), one Sb(10), and one Sb(11) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal non-coplanar geometry to one Zn(5), one Sb(10), and one Sb(11) atom. is represented by the CIF card [CIF]
data_Zn(SbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.526
_cell_length_b   6.965
_cell_length_c   17.429
_cell_angle_alpha   92.775
_cell_angle_beta   89.934
_cell_angle_gamma   117.754
_symmetry_Int_Tables_number   1
_cell_volume   699.978
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.816  0.650  0.044  1.0
  Zn  Zn1  1  0.469  0.963  0.409  1.0
  Zn  Zn2  1  0.219  0.419  0.331  1.0
  Zn  Zn3  1  0.188  0.358  0.740  1.0
  Zn  Zn4  1  0.492  0.978  0.996  1.0
  Zn  Zn5  1  0.481  0.952  0.628  1.0
  Sb  Sb6  1  0.328  0.664  0.120  1.0
  Sb  Sb7  1  0.391  0.222  0.175  1.0
  Sb  Sb8  1  0.945  0.952  0.459  1.0
  Sb  Sb9  1  0.877  0.204  0.195  1.0
  Sb  Sb10  1  0.034  0.514  0.496  1.0
  Sb  Sb11  1  0.892  0.772  0.658  1.0
  Sb  Sb12  1  0.837  0.683  0.259  1.0
  Sb  Sb13  1  0.664  0.323  0.867  1.0
  Sb  Sb14  1  0.490  0.393  0.513  1.0
  Sb  Sb15  1  0.650  0.814  0.821  1.0
  Sb  Sb16  1  0.166  0.809  0.820  1.0
  Sb  Sb17  1  0.172  0.336  0.941  1.0
  O  O18  1  0.692  0.423  0.125  1.0
  O  O19  1  0.539  0.056  0.226  1.0
  O  O20  1  0.620  0.818  0.063  1.0
  O  O21  1  0.182  0.808  0.062  1.0
  O  O22  1  0.300  0.644  0.418  1.0
  O  O23  1  0.497  0.452  0.268  1.0
  O  O24  1  0.173  0.347  0.546  1.0
  O  O25  1  0.972  0.474  0.268  1.0
  O  O26  1  0.205  0.389  0.052  1.0
  O  O27  1  0.300  0.131  0.429  1.0
  O  O28  1  0.799  0.127  0.422  1.0
  O  O29  1  0.036  0.128  0.278  1.0
  O  O30  1  0.048  0.073  0.698  1.0
  O  O31  1  0.147  0.765  0.583  1.0
  O  O32  1  0.647  0.784  0.595  1.0
  O  O33  1  0.795  0.608  0.927  1.0
  O  O34  1  0.856  0.725  0.373  1.0
  O  O35  1  0.014  0.493  0.790  1.0
  O  O36  1  0.498  0.502  0.786  1.0
  O  O37  1  0.560  0.237  0.590  1.0
  O  O38  1  0.811  0.183  0.946  1.0
  O  O39  1  0.370  0.172  0.944  1.0
  O  O40  1  0.439  0.878  0.746  1.0
  O  O41  1  0.392  0.778  0.895  1.0
[/CIF]
.