The crystal structure described by AgO2I crystallizes in the tetragonal I4_1/amd space group. Ag(1) is bonded to six equivalent O(1) atoms to form edge-sharing AgO6 octahedra. O(1) is bonded to three equivalent Ag(1) and two equivalent I(1) atoms to form a mixture of distorted edge and corner-sharing OAg3I2 trigonal bipyramids. I(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. is represented by the CIF file [CIF]
data_AgIO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.610
_cell_length_b   7.610
_cell_length_c   7.610
_cell_angle_alpha   128.831
_cell_angle_beta   128.831
_cell_angle_gamma   75.282
_symmetry_Int_Tables_number   1
_cell_volume   260.326
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.875  0.625  0.250  1.0
  Ag  Ag1  1  0.375  0.625  0.750  1.0
  Ag  Ag2  1  0.375  0.625  0.250  1.0
  Ag  Ag3  1  0.375  0.125  0.750  1.0
  I  I4  1  0.375  0.125  0.250  1.0
  I  I5  1  0.875  0.125  0.750  1.0
  I  I6  1  0.875  0.125  0.250  1.0
  I  I7  1  0.875  0.625  0.750  1.0
  O  O8  1  0.179  0.389  0.211  1.0
  O  O9  1  0.179  0.968  0.789  1.0
  O  O10  1  0.139  0.429  0.711  1.0
  O  O11  1  0.571  0.861  0.289  1.0
  O  O12  1  0.718  0.429  0.289  1.0
  O  O13  1  0.571  0.282  0.711  1.0
  O  O14  1  0.611  0.821  0.789  1.0
  O  O15  1  0.032  0.821  0.211  1.0
[/CIF]
.
The crystal structure described by AgO2I crystallizes in the tetragonal I4_1/amd space group. Ag(1) is bonded to six equivalent O(1) atoms to form edge-sharing AgO6 octahedra. O(1) is bonded to three equivalent Ag(1) and two equivalent I(1) atoms to form a mixture of distorted edge and corner-sharing OAg3I2 trigonal bipyramids. I(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. is represented by the CIF file [CIF]
data_AgIO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.610
_cell_length_b   7.610
_cell_length_c   7.610
_cell_angle_alpha   128.831
_cell_angle_beta   128.831
_cell_angle_gamma   75.282
_symmetry_Int_Tables_number   1
_cell_volume   260.326
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.875  0.625  0.250  1.0
  Ag  Ag1  1  0.375  0.625  0.750  1.0
  Ag  Ag2  1  0.375  0.625  0.250  1.0
  Ag  Ag3  1  0.375  0.125  0.750  1.0
  I  I4  1  0.375  0.125  0.250  1.0
  I  I5  1  0.875  0.125  0.750  1.0
  I  I6  1  0.875  0.125  0.250  1.0
  I  I7  1  0.875  0.625  0.750  1.0
  O  O8  1  0.179  0.389  0.211  1.0
  O  O9  1  0.179  0.968  0.789  1.0
  O  O10  1  0.139  0.429  0.711  1.0
  O  O11  1  0.571  0.861  0.289  1.0
  O  O12  1  0.718  0.429  0.289  1.0
  O  O13  1  0.571  0.282  0.711  1.0
  O  O14  1  0.611  0.821  0.789  1.0
  O  O15  1  0.032  0.821  0.211  1.0
[/CIF]
.