The structure described by W2NCl9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two W2NCl9 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in an octahedral geometry to one N(1), one Cl(1), one Cl(2), one Cl(4), one Cl(5), and one Cl(6) atom. In the second W site, W(2) is bonded in a 6-coordinate geometry to one N(1), one Cl(3), one Cl(8), one Cl(9), and two equivalent Cl(7) atoms. N(1) is bonded in a linear geometry to one W(1) and one W(2) atom. There are nine inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one W(1) atom. In the seventh Cl site, Cl(7) is bonded in a water-like geometry to two equivalent W(2) atoms. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one W(2) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one W(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_W2NCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.924
_cell_length_b   8.779
_cell_length_c   12.342
_cell_angle_alpha   45.056
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1297.862
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.189  0.188  0.461  1.0
  W  W1  1  0.311  0.188  0.961  1.0
  W  W2  1  0.689  0.812  0.039  1.0
  W  W3  1  0.907  0.814  0.043  1.0
  W  W4  1  0.093  0.186  0.957  1.0
  W  W5  1  0.593  0.814  0.543  1.0
  W  W6  1  0.811  0.812  0.539  1.0
  W  W7  1  0.407  0.186  0.457  1.0
  N  N8  1  0.695  0.817  0.542  1.0
  N  N9  1  0.195  0.183  0.958  1.0
  N  N10  1  0.305  0.183  0.458  1.0
  N  N11  1  0.805  0.817  0.042  1.0
  Cl  Cl12  1  0.812  0.130  0.473  1.0
  Cl  Cl13  1  0.446  0.202  0.964  1.0
  Cl  Cl14  1  0.570  0.497  0.615  1.0
  Cl  Cl15  1  0.430  0.503  0.385  1.0
  Cl  Cl16  1  0.054  0.202  0.464  1.0
  Cl  Cl17  1  0.190  0.371  0.208  1.0
  Cl  Cl18  1  0.197  1.000  0.715  1.0
  Cl  Cl19  1  0.188  0.870  0.527  1.0
  Cl  Cl20  1  0.799  0.494  0.607  1.0
  Cl  Cl21  1  0.075  0.849  0.035  1.0
  Cl  Cl22  1  0.299  0.506  0.893  1.0
  Cl  Cl23  1  0.201  0.506  0.393  1.0
  Cl  Cl24  1  0.575  0.000  0.290  1.0
  Cl  Cl25  1  0.690  0.629  0.292  1.0
  Cl  Cl26  1  0.310  0.371  0.708  1.0
  Cl  Cl27  1  0.575  0.651  0.790  1.0
  Cl  Cl28  1  0.697  0.000  0.785  1.0
  Cl  Cl29  1  0.925  0.000  0.790  1.0
  Cl  Cl30  1  0.575  0.151  0.465  1.0
  Cl  Cl31  1  0.925  0.651  0.290  1.0
  Cl  Cl32  1  0.425  0.349  0.210  1.0
  Cl  Cl33  1  0.070  0.503  0.885  1.0
  Cl  Cl34  1  0.701  0.494  0.107  1.0
  Cl  Cl35  1  0.425  0.849  0.535  1.0
  Cl  Cl36  1  0.554  0.798  0.036  1.0
  Cl  Cl37  1  0.946  0.798  0.536  1.0
  Cl  Cl38  1  0.803  0.000  0.285  1.0
  Cl  Cl39  1  0.688  0.130  0.973  1.0
  Cl  Cl40  1  0.810  0.629  0.792  1.0
  Cl  Cl41  1  0.425  1.000  0.710  1.0
  Cl  Cl42  1  0.075  0.349  0.710  1.0
  Cl  Cl43  1  0.075  1.000  0.210  1.0
  Cl  Cl44  1  0.925  0.151  0.965  1.0
  Cl  Cl45  1  0.312  0.870  0.027  1.0
  Cl  Cl46  1  0.303  1.000  0.215  1.0
  Cl  Cl47  1  0.930  0.497  0.115  1.0
[/CIF]
.
The structure described by W2NCl9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two W2NCl9 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in an octahedral geometry to one N(1), one Cl(1), one Cl(2), one Cl(4), one Cl(5), and one Cl(6) atom. In the second W site, W(2) is bonded in a 6-coordinate geometry to one N(1), one Cl(3), one Cl(8), one Cl(9), and two equivalent Cl(7) atoms. N(1) is bonded in a linear geometry to one W(1) and one W(2) atom. There are nine inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one W(1) atom. In the seventh Cl site, Cl(7) is bonded in a water-like geometry to two equivalent W(2) atoms. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one W(2) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one W(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_W2NCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.924
_cell_length_b   8.779
_cell_length_c   12.342
_cell_angle_alpha   45.056
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1297.862
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.189  0.188  0.461  1.0
  W  W1  1  0.311  0.188  0.961  1.0
  W  W2  1  0.689  0.812  0.039  1.0
  W  W3  1  0.907  0.814  0.043  1.0
  W  W4  1  0.093  0.186  0.957  1.0
  W  W5  1  0.593  0.814  0.543  1.0
  W  W6  1  0.811  0.812  0.539  1.0
  W  W7  1  0.407  0.186  0.457  1.0
  N  N8  1  0.695  0.817  0.542  1.0
  N  N9  1  0.195  0.183  0.958  1.0
  N  N10  1  0.305  0.183  0.458  1.0
  N  N11  1  0.805  0.817  0.042  1.0
  Cl  Cl12  1  0.812  0.130  0.473  1.0
  Cl  Cl13  1  0.446  0.202  0.964  1.0
  Cl  Cl14  1  0.570  0.497  0.615  1.0
  Cl  Cl15  1  0.430  0.503  0.385  1.0
  Cl  Cl16  1  0.054  0.202  0.464  1.0
  Cl  Cl17  1  0.190  0.371  0.208  1.0
  Cl  Cl18  1  0.197  1.000  0.715  1.0
  Cl  Cl19  1  0.188  0.870  0.527  1.0
  Cl  Cl20  1  0.799  0.494  0.607  1.0
  Cl  Cl21  1  0.075  0.849  0.035  1.0
  Cl  Cl22  1  0.299  0.506  0.893  1.0
  Cl  Cl23  1  0.201  0.506  0.393  1.0
  Cl  Cl24  1  0.575  0.000  0.290  1.0
  Cl  Cl25  1  0.690  0.629  0.292  1.0
  Cl  Cl26  1  0.310  0.371  0.708  1.0
  Cl  Cl27  1  0.575  0.651  0.790  1.0
  Cl  Cl28  1  0.697  0.000  0.785  1.0
  Cl  Cl29  1  0.925  0.000  0.790  1.0
  Cl  Cl30  1  0.575  0.151  0.465  1.0
  Cl  Cl31  1  0.925  0.651  0.290  1.0
  Cl  Cl32  1  0.425  0.349  0.210  1.0
  Cl  Cl33  1  0.070  0.503  0.885  1.0
  Cl  Cl34  1  0.701  0.494  0.107  1.0
  Cl  Cl35  1  0.425  0.849  0.535  1.0
  Cl  Cl36  1  0.554  0.798  0.036  1.0
  Cl  Cl37  1  0.946  0.798  0.536  1.0
  Cl  Cl38  1  0.803  0.000  0.285  1.0
  Cl  Cl39  1  0.688  0.130  0.973  1.0
  Cl  Cl40  1  0.810  0.629  0.792  1.0
  Cl  Cl41  1  0.425  1.000  0.710  1.0
  Cl  Cl42  1  0.075  0.349  0.710  1.0
  Cl  Cl43  1  0.075  1.000  0.210  1.0
  Cl  Cl44  1  0.925  0.151  0.965  1.0
  Cl  Cl45  1  0.312  0.870  0.027  1.0
  Cl  Cl46  1  0.303  1.000  0.215  1.0
  Cl  Cl47  1  0.930  0.497  0.115  1.0
[/CIF]
.