The material structure described by Cu6Zn3(AsS3)4 crystallizes in the triclinic P1 space group. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(11), one S(3), one S(4), and one S(5) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the second Cu site, Cu(2) is bonded to one S(1), one S(12), one S(5), and one S(6) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the third Cu site, Cu(3) is bonded to one S(3), one S(6), one S(7), and one S(8) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the fourth Cu site, Cu(4) is bonded to one S(1), one S(10), one S(11), and one S(7) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the fifth Cu site, Cu(5) is bonded to one S(11), one S(12), one S(2), and one S(8) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the sixth Cu site, Cu(6) is bonded to one S(10), one S(12), one S(3), and one S(9) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(10), one S(2), one S(4), and one S(6) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the second Zn site, Zn(2) is bonded to one S(1), one S(4), one S(8), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the third Zn site, Zn(3) is bonded to one S(2), one S(5), one S(7), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra, and  a cornercorner with one Zn(2)S4 tetrahedra. There are four inequivalent As sites. In the first As site, As(1) is bonded in a trigonal non-coplanar geometry to one S(1), one S(2), and one S(3) atom. In the second As site, As(2) is bonded in a trigonal non-coplanar geometry to one S(12), one S(4), and one S(7) atom. In the third As site, As(3) is bonded in a trigonal non-coplanar geometry to one S(10), one S(5), and one S(8) atom. In the fourth As site, As(4) is bonded in a trigonal non-coplanar geometry to one S(11), one S(6), and one S(9) atom. There are twelve inequivalent S sites. In the first S site, S(1) is bonded to one Cu(2), one Cu(4), one Zn(2), and one As(1) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the second S site, S(2) is bonded to one Cu(5), one Zn(1), one Zn(3), and one As(1) atom to form SZn2CuAs tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the third S site, S(3) is bonded to one Cu(1), one Cu(3), one Cu(6), and one As(1) atom to form SCu3As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the fourth S site, S(4) is bonded to one Cu(1), one Zn(1), one Zn(2), and one As(2) atom to form SZn2CuAs tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the fifth S site, S(5) is bonded to one Cu(1), one Cu(2), one Zn(3), and one As(3) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the sixth S site, S(6) is bonded to one Cu(2), one Cu(3), one Zn(1), and one As(4) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the seventh S site, S(7) is bonded to one Cu(3), one Cu(4), one Zn(3), and one As(2) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the eighth S site, S(8) is bonded to one Cu(3), one Cu(5), one Zn(2), and one As(3) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra, and  a cornercorner with one S(7)ZnCu2As tetrahedra. In the ninth S site, S(9) is bonded to one Cu(6), one Zn(2), one Zn(3), and one As(4) atom to form SZn2CuAs tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the tenth S site, S(10) is bonded to one Cu(4), one Cu(6), one Zn(1), and one As(3) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the eleventh S site, S(11) is bonded to one Cu(1), one Cu(4), one Cu(5), and one As(4) atom to form SCu3As tetrahedra that share  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the twelfth S site, S(12) is bonded to one Cu(2), one Cu(5), one Cu(6), and one As(2) atom to form SCu3As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn3Cu6(AsS3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.355
_cell_length_b   8.413
_cell_length_c   8.433
_cell_angle_alpha   107.551
_cell_angle_beta   107.460
_cell_angle_gamma   107.107
_symmetry_Int_Tables_number   1
_cell_volume   488.609
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.403  0.169  0.460  1.0
  Zn  Zn1  1  0.072  0.217  0.703  1.0
  Zn  Zn2  1  0.229  0.703  0.075  1.0
  Cu  Cu3  1  0.166  0.456  0.393  1.0
  Cu  Cu4  1  0.458  0.399  0.169  1.0
  Cu  Cu5  1  0.706  0.075  0.219  1.0
  Cu  Cu6  1  0.297  0.909  0.762  1.0
  Cu  Cu7  1  0.909  0.761  0.304  1.0
  Cu  Cu8  1  0.763  0.301  0.915  1.0
  As  As9  1  0.975  0.986  0.978  1.0
  As  As10  1  0.564  0.623  0.851  1.0
  As  As11  1  0.621  0.842  0.556  1.0
  As  As12  1  0.842  0.562  0.614  1.0
  S  S13  1  0.224  0.133  0.925  1.0
  S  S14  1  0.127  0.917  0.217  1.0
  S  S15  1  0.920  0.221  0.135  1.0
  S  S16  1  0.292  0.366  0.610  1.0
  S  S17  1  0.363  0.610  0.297  1.0
  S  S18  1  0.617  0.295  0.358  1.0
  S  S19  1  0.450  0.825  0.978  1.0
  S  S20  1  0.814  0.976  0.440  1.0
  S  S21  1  0.975  0.445  0.821  1.0
  S  S22  1  0.510  0.052  0.668  1.0
  S  S23  1  0.052  0.661  0.508  1.0
  S  S24  1  0.663  0.509  0.055  1.0
[/CIF]
.
The material structure described by Cu6Zn3(AsS3)4 crystallizes in the triclinic P1 space group. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(11), one S(3), one S(4), and one S(5) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the second Cu site, Cu(2) is bonded to one S(1), one S(12), one S(5), and one S(6) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the third Cu site, Cu(3) is bonded to one S(3), one S(6), one S(7), and one S(8) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the fourth Cu site, Cu(4) is bonded to one S(1), one S(10), one S(11), and one S(7) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the fifth Cu site, Cu(5) is bonded to one S(11), one S(12), one S(2), and one S(8) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the sixth Cu site, Cu(6) is bonded to one S(10), one S(12), one S(3), and one S(9) atom to form CuS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(10), one S(2), one S(4), and one S(6) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the second Zn site, Zn(2) is bonded to one S(1), one S(4), one S(8), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra, and  a cornercorner with one Zn(3)S4 tetrahedra. In the third Zn site, Zn(3) is bonded to one S(2), one S(5), one S(7), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Cu(3)S4 tetrahedra,  a cornercorner with one Cu(4)S4 tetrahedra,  a cornercorner with one Cu(5)S4 tetrahedra,  a cornercorner with one Cu(6)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra, and  a cornercorner with one Zn(2)S4 tetrahedra. There are four inequivalent As sites. In the first As site, As(1) is bonded in a trigonal non-coplanar geometry to one S(1), one S(2), and one S(3) atom. In the second As site, As(2) is bonded in a trigonal non-coplanar geometry to one S(12), one S(4), and one S(7) atom. In the third As site, As(3) is bonded in a trigonal non-coplanar geometry to one S(10), one S(5), and one S(8) atom. In the fourth As site, As(4) is bonded in a trigonal non-coplanar geometry to one S(11), one S(6), and one S(9) atom. There are twelve inequivalent S sites. In the first S site, S(1) is bonded to one Cu(2), one Cu(4), one Zn(2), and one As(1) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the second S site, S(2) is bonded to one Cu(5), one Zn(1), one Zn(3), and one As(1) atom to form SZn2CuAs tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the third S site, S(3) is bonded to one Cu(1), one Cu(3), one Cu(6), and one As(1) atom to form SCu3As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the fourth S site, S(4) is bonded to one Cu(1), one Zn(1), one Zn(2), and one As(2) atom to form SZn2CuAs tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the fifth S site, S(5) is bonded to one Cu(1), one Cu(2), one Zn(3), and one As(3) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the sixth S site, S(6) is bonded to one Cu(2), one Cu(3), one Zn(1), and one As(4) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the seventh S site, S(7) is bonded to one Cu(3), one Cu(4), one Zn(3), and one As(2) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the eighth S site, S(8) is bonded to one Cu(3), one Cu(5), one Zn(2), and one As(3) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra, and  a cornercorner with one S(7)ZnCu2As tetrahedra. In the ninth S site, S(9) is bonded to one Cu(6), one Zn(2), one Zn(3), and one As(4) atom to form SZn2CuAs tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the tenth S site, S(10) is bonded to one Cu(4), one Cu(6), one Zn(1), and one As(3) atom to form SZnCu2As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the eleventh S site, S(11) is bonded to one Cu(1), one Cu(4), one Cu(5), and one As(4) atom to form SCu3As tetrahedra that share  a cornercorner with one S(12)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. In the twelfth S site, S(12) is bonded to one Cu(2), one Cu(5), one Cu(6), and one As(2) atom to form SCu3As tetrahedra that share  a cornercorner with one S(11)Cu3As tetrahedra,  a cornercorner with one S(3)Cu3As tetrahedra,  a cornercorner with one S(2)Zn2CuAs tetrahedra,  a cornercorner with one S(4)Zn2CuAs tetrahedra,  a cornercorner with one S(9)Zn2CuAs tetrahedra,  a cornercorner with one S(1)ZnCu2As tetrahedra,  a cornercorner with one S(10)ZnCu2As tetrahedra,  a cornercorner with one S(5)ZnCu2As tetrahedra,  a cornercorner with one S(6)ZnCu2As tetrahedra,  a cornercorner with one S(7)ZnCu2As tetrahedra, and  a cornercorner with one S(8)ZnCu2As tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn3Cu6(AsS3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.355
_cell_length_b   8.413
_cell_length_c   8.433
_cell_angle_alpha   107.551
_cell_angle_beta   107.460
_cell_angle_gamma   107.107
_symmetry_Int_Tables_number   1
_cell_volume   488.609
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.403  0.169  0.460  1.0
  Zn  Zn1  1  0.072  0.217  0.703  1.0
  Zn  Zn2  1  0.229  0.703  0.075  1.0
  Cu  Cu3  1  0.166  0.456  0.393  1.0
  Cu  Cu4  1  0.458  0.399  0.169  1.0
  Cu  Cu5  1  0.706  0.075  0.219  1.0
  Cu  Cu6  1  0.297  0.909  0.762  1.0
  Cu  Cu7  1  0.909  0.761  0.304  1.0
  Cu  Cu8  1  0.763  0.301  0.915  1.0
  As  As9  1  0.975  0.986  0.978  1.0
  As  As10  1  0.564  0.623  0.851  1.0
  As  As11  1  0.621  0.842  0.556  1.0
  As  As12  1  0.842  0.562  0.614  1.0
  S  S13  1  0.224  0.133  0.925  1.0
  S  S14  1  0.127  0.917  0.217  1.0
  S  S15  1  0.920  0.221  0.135  1.0
  S  S16  1  0.292  0.366  0.610  1.0
  S  S17  1  0.363  0.610  0.297  1.0
  S  S18  1  0.617  0.295  0.358  1.0
  S  S19  1  0.450  0.825  0.978  1.0
  S  S20  1  0.814  0.976  0.440  1.0
  S  S21  1  0.975  0.445  0.821  1.0
  S  S22  1  0.510  0.052  0.668  1.0
  S  S23  1  0.052  0.661  0.508  1.0
  S  S24  1  0.663  0.509  0.055  1.0
[/CIF]
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