The structure described by PNBr2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PNBr2 clusters. There are five inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(5), one Br(5), and one Br(8) atom to form corner-sharing PBr2N2 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(3), one Br(10), and one Br(3) atom to form corner-sharing PBr2N2 tetrahedra. In the third P site, P(3) is bonded to one N(3), one N(5), one Br(7), and one Br(9) atom to form corner-sharing PBr2N2 tetrahedra. In the fourth P site, P(4) is bonded to one N(2), one N(4), one Br(4), and one Br(6) atom to form corner-sharing PBr2N2 tetrahedra. In the fifth P site, P(5) is bonded to one N(1), one N(4), one Br(1), and one Br(2) atom to form corner-sharing PBr2N2 tetrahedra. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(5) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one P(4) and one P(5) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. There are ten inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(5) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one P(5) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one P(4) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one P(4) atom. In the seventh Br site, Br(7) is bonded in a single-bond geometry to one P(3) atom. In the eighth Br site, Br(8) is bonded in a single-bond geometry to one P(1) atom. In the ninth Br site, Br(9) is bonded in a single-bond geometry to one P(3) atom. In the tenth Br site, Br(10) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF card [CIF]
data_PBr2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.573
_cell_length_b   10.510
_cell_length_c   12.161
_cell_angle_alpha   100.823
_cell_angle_beta   112.752
_cell_angle_gamma   93.647
_symmetry_Int_Tables_number   1
_cell_volume   1095.621
_cell_formula_units_Z   10
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.614  0.310  0.403  1.0
  P  P1  1  0.802  0.012  0.147  1.0
  P  P2  1  0.306  0.957  0.660  1.0
  P  P3  1  0.198  0.988  0.853  1.0
  P  P4  1  0.650  0.474  0.249  1.0
  P  P5  1  0.386  0.690  0.597  1.0
  P  P6  1  0.827  0.294  0.167  1.0
  P  P7  1  0.173  0.706  0.833  1.0
  P  P8  1  0.350  0.526  0.751  1.0
  P  P9  1  0.694  0.043  0.340  1.0
  Br  Br10  1  0.993  0.666  0.645  1.0
  Br  Br11  1  0.053  0.628  0.933  1.0
  Br  Br12  1  0.972  0.035  0.839  1.0
  Br  Br13  1  0.575  0.484  0.864  1.0
  Br  Br14  1  0.632  0.731  0.643  1.0
  Br  Br15  1  0.797  0.663  0.306  1.0
  Br  Br16  1  0.473  0.914  0.264  1.0
  Br  Br17  1  0.716  0.350  0.603  1.0
  Br  Br18  1  0.192  0.990  0.477  1.0
  Br  Br19  1  0.203  0.337  0.694  1.0
  Br  Br20  1  0.284  0.650  0.397  1.0
  Br  Br21  1  0.028  0.965  0.161  1.0
  Br  Br22  1  0.368  0.269  0.357  1.0
  Br  Br23  1  0.358  0.140  0.006  1.0
  Br  Br24  1  0.808  0.010  0.523  1.0
  Br  Br25  1  0.642  0.860  0.994  1.0
  Br  Br26  1  0.007  0.334  0.355  1.0
  Br  Br27  1  0.947  0.372  0.067  1.0
  Br  Br28  1  0.425  0.516  0.136  1.0
  Br  Br29  1  0.527  0.086  0.736  1.0
  N  N30  1  0.776  0.144  0.108  1.0
  N  N31  1  0.650  0.442  0.370  1.0
  N  N32  1  0.224  0.856  0.892  1.0
  N  N33  1  0.794  0.993  0.270  1.0
  N  N34  1  0.309  0.628  0.840  1.0
  N  N35  1  0.350  0.558  0.630  1.0
  N  N36  1  0.206  0.007  0.730  1.0
  N  N37  1  0.332  0.811  0.656  1.0
  N  N38  1  0.668  0.189  0.344  1.0
  N  N39  1  0.692  0.372  0.160  1.0
[/CIF]
.
The structure described by PNBr2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PNBr2 clusters. There are five inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(5), one Br(5), and one Br(8) atom to form corner-sharing PBr2N2 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(3), one Br(10), and one Br(3) atom to form corner-sharing PBr2N2 tetrahedra. In the third P site, P(3) is bonded to one N(3), one N(5), one Br(7), and one Br(9) atom to form corner-sharing PBr2N2 tetrahedra. In the fourth P site, P(4) is bonded to one N(2), one N(4), one Br(4), and one Br(6) atom to form corner-sharing PBr2N2 tetrahedra. In the fifth P site, P(5) is bonded to one N(1), one N(4), one Br(1), and one Br(2) atom to form corner-sharing PBr2N2 tetrahedra. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(5) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one P(4) and one P(5) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. There are ten inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(5) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one P(5) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one P(4) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one P(4) atom. In the seventh Br site, Br(7) is bonded in a single-bond geometry to one P(3) atom. In the eighth Br site, Br(8) is bonded in a single-bond geometry to one P(1) atom. In the ninth Br site, Br(9) is bonded in a single-bond geometry to one P(3) atom. In the tenth Br site, Br(10) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF card [CIF]
data_PBr2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.573
_cell_length_b   10.510
_cell_length_c   12.161
_cell_angle_alpha   100.823
_cell_angle_beta   112.752
_cell_angle_gamma   93.647
_symmetry_Int_Tables_number   1
_cell_volume   1095.621
_cell_formula_units_Z   10
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.614  0.310  0.403  1.0
  P  P1  1  0.802  0.012  0.147  1.0
  P  P2  1  0.306  0.957  0.660  1.0
  P  P3  1  0.198  0.988  0.853  1.0
  P  P4  1  0.650  0.474  0.249  1.0
  P  P5  1  0.386  0.690  0.597  1.0
  P  P6  1  0.827  0.294  0.167  1.0
  P  P7  1  0.173  0.706  0.833  1.0
  P  P8  1  0.350  0.526  0.751  1.0
  P  P9  1  0.694  0.043  0.340  1.0
  Br  Br10  1  0.993  0.666  0.645  1.0
  Br  Br11  1  0.053  0.628  0.933  1.0
  Br  Br12  1  0.972  0.035  0.839  1.0
  Br  Br13  1  0.575  0.484  0.864  1.0
  Br  Br14  1  0.632  0.731  0.643  1.0
  Br  Br15  1  0.797  0.663  0.306  1.0
  Br  Br16  1  0.473  0.914  0.264  1.0
  Br  Br17  1  0.716  0.350  0.603  1.0
  Br  Br18  1  0.192  0.990  0.477  1.0
  Br  Br19  1  0.203  0.337  0.694  1.0
  Br  Br20  1  0.284  0.650  0.397  1.0
  Br  Br21  1  0.028  0.965  0.161  1.0
  Br  Br22  1  0.368  0.269  0.357  1.0
  Br  Br23  1  0.358  0.140  0.006  1.0
  Br  Br24  1  0.808  0.010  0.523  1.0
  Br  Br25  1  0.642  0.860  0.994  1.0
  Br  Br26  1  0.007  0.334  0.355  1.0
  Br  Br27  1  0.947  0.372  0.067  1.0
  Br  Br28  1  0.425  0.516  0.136  1.0
  Br  Br29  1  0.527  0.086  0.736  1.0
  N  N30  1  0.776  0.144  0.108  1.0
  N  N31  1  0.650  0.442  0.370  1.0
  N  N32  1  0.224  0.856  0.892  1.0
  N  N33  1  0.794  0.993  0.270  1.0
  N  N34  1  0.309  0.628  0.840  1.0
  N  N35  1  0.350  0.558  0.630  1.0
  N  N36  1  0.206  0.007  0.730  1.0
  N  N37  1  0.332  0.811  0.656  1.0
  N  N38  1  0.668  0.189  0.344  1.0
  N  N39  1  0.692  0.372  0.160  1.0
[/CIF]
.