The structure described by La(MoGa5)8 crystallizes in the trigonal R-3 space group. La(1) is bonded in a 8-coordinate geometry to two equivalent Mo(1) and six equivalent Ga(7) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 10-coordinate geometry to one La(1), three equivalent Ga(4), three equivalent Ga(6), and three equivalent Ga(7) atoms. In the second Mo site, Mo(2) is bonded in a distorted q6 geometry to one Ga(2), one Ga(4), one Ga(6), one Ga(7), two equivalent Ga(3), two equivalent Ga(5), and two equivalent Ga(8) atoms. There are eight inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a cuboctahedral geometry to six equivalent Ga(3) and six equivalent Ga(4) atoms. In the second Ga site, Ga(2) is bonded in a distorted linear geometry to two equivalent Mo(2) atoms. In the third Ga site, Ga(8) is bonded in a 2-coordinate geometry to two equivalent Mo(2) and two equivalent Ga(7) atoms. In the fourth Ga site, Ga(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(2) and one Ga(1) atom. In the fifth Ga site, Ga(4) is bonded in a distorted bent 150 degrees geometry to one Mo(1), one Mo(2), and one Ga(1) atom. In the sixth Ga site, Ga(5) is bonded in a 2-coordinate geometry to two equivalent Mo(2) and one Ga(7) atom. In the seventh Ga site, Ga(6) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(2), and two equivalent Ga(7) atoms. In the eighth Ga site, Ga(7) is bonded in a 8-coordinate geometry to one La(1), one Mo(1), one Mo(2), one Ga(5), two equivalent Ga(6), and two equivalent Ga(8) atoms. is represented by the CIF card [CIF]
data_La(Ga5Mo)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.676
_cell_length_b   9.676
_cell_length_c   9.676
_cell_angle_alpha   94.300
_cell_angle_beta   94.300
_cell_angle_gamma   94.300
_symmetry_Int_Tables_number   1
_cell_volume   897.924
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.000  0.000  1.0
  Ga  Ga1  1  0.500  0.500  0.500  1.0
  Ga  Ga2  1  0.000  0.500  0.500  1.0
  Ga  Ga3  1  0.500  0.000  0.500  1.0
  Ga  Ga4  1  0.500  0.500  0.000  1.0
  Ga  Ga5  1  0.269  0.637  0.611  1.0
  Ga  Ga6  1  0.611  0.269  0.637  1.0
  Ga  Ga7  1  0.637  0.611  0.269  1.0
  Ga  Ga8  1  0.731  0.363  0.389  1.0
  Ga  Ga9  1  0.389  0.731  0.363  1.0
  Ga  Ga10  1  0.363  0.389  0.731  1.0
  Ga  Ga11  1  0.674  0.777  0.532  1.0
  Ga  Ga12  1  0.532  0.674  0.777  1.0
  Ga  Ga13  1  0.777  0.532  0.674  1.0
  Ga  Ga14  1  0.326  0.223  0.468  1.0
  Ga  Ga15  1  0.468  0.326  0.223  1.0
  Ga  Ga16  1  0.223  0.468  0.326  1.0
  Ga  Ga17  1  0.779  0.073  0.444  1.0
  Ga  Ga18  1  0.444  0.779  0.073  1.0
  Ga  Ga19  1  0.073  0.444  0.779  1.0
  Ga  Ga20  1  0.221  0.927  0.556  1.0
  Ga  Ga21  1  0.556  0.221  0.927  1.0
  Ga  Ga22  1  0.927  0.556  0.221  1.0
  Ga  Ga23  1  0.966  0.786  0.597  1.0
  Ga  Ga24  1  0.597  0.966  0.786  1.0
  Ga  Ga25  1  0.786  0.597  0.966  1.0
  Ga  Ga26  1  0.034  0.214  0.403  1.0
  Ga  Ga27  1  0.403  0.034  0.214  1.0
  Ga  Ga28  1  0.214  0.403  0.034  1.0
  Ga  Ga29  1  0.043  0.712  0.859  1.0
  Ga  Ga30  1  0.859  0.043  0.712  1.0
  Ga  Ga31  1  0.712  0.859  0.043  1.0
  Ga  Ga32  1  0.957  0.288  0.141  1.0
  Ga  Ga33  1  0.141  0.957  0.288  1.0
  Ga  Ga34  1  0.288  0.141  0.957  1.0
  Ga  Ga35  1  0.122  0.172  0.687  1.0
  Ga  Ga36  1  0.687  0.122  0.172  1.0
  Ga  Ga37  1  0.172  0.687  0.122  1.0
  Ga  Ga38  1  0.878  0.828  0.313  1.0
  Ga  Ga39  1  0.313  0.878  0.828  1.0
  Ga  Ga40  1  0.828  0.313  0.878  1.0
  Mo  Mo41  1  0.789  0.789  0.789  1.0
  Mo  Mo42  1  0.211  0.211  0.211  1.0
  Mo  Mo43  1  0.291  0.610  0.886  1.0
  Mo  Mo44  1  0.886  0.291  0.610  1.0
  Mo  Mo45  1  0.610  0.886  0.291  1.0
  Mo  Mo46  1  0.709  0.390  0.114  1.0
  Mo  Mo47  1  0.114  0.709  0.390  1.0
  Mo  Mo48  1  0.390  0.114  0.709  1.0
[/CIF]
.
The structure described by La(MoGa5)8 crystallizes in the trigonal R-3 space group. La(1) is bonded in a 8-coordinate geometry to two equivalent Mo(1) and six equivalent Ga(7) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 10-coordinate geometry to one La(1), three equivalent Ga(4), three equivalent Ga(6), and three equivalent Ga(7) atoms. In the second Mo site, Mo(2) is bonded in a distorted q6 geometry to one Ga(2), one Ga(4), one Ga(6), one Ga(7), two equivalent Ga(3), two equivalent Ga(5), and two equivalent Ga(8) atoms. There are eight inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a cuboctahedral geometry to six equivalent Ga(3) and six equivalent Ga(4) atoms. In the second Ga site, Ga(2) is bonded in a distorted linear geometry to two equivalent Mo(2) atoms. In the third Ga site, Ga(8) is bonded in a 2-coordinate geometry to two equivalent Mo(2) and two equivalent Ga(7) atoms. In the fourth Ga site, Ga(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(2) and one Ga(1) atom. In the fifth Ga site, Ga(4) is bonded in a distorted bent 150 degrees geometry to one Mo(1), one Mo(2), and one Ga(1) atom. In the sixth Ga site, Ga(5) is bonded in a 2-coordinate geometry to two equivalent Mo(2) and one Ga(7) atom. In the seventh Ga site, Ga(6) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(2), and two equivalent Ga(7) atoms. In the eighth Ga site, Ga(7) is bonded in a 8-coordinate geometry to one La(1), one Mo(1), one Mo(2), one Ga(5), two equivalent Ga(6), and two equivalent Ga(8) atoms. is represented by the CIF card [CIF]
data_La(Ga5Mo)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.676
_cell_length_b   9.676
_cell_length_c   9.676
_cell_angle_alpha   94.300
_cell_angle_beta   94.300
_cell_angle_gamma   94.300
_symmetry_Int_Tables_number   1
_cell_volume   897.924
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.000  0.000  1.0
  Ga  Ga1  1  0.500  0.500  0.500  1.0
  Ga  Ga2  1  0.000  0.500  0.500  1.0
  Ga  Ga3  1  0.500  0.000  0.500  1.0
  Ga  Ga4  1  0.500  0.500  0.000  1.0
  Ga  Ga5  1  0.269  0.637  0.611  1.0
  Ga  Ga6  1  0.611  0.269  0.637  1.0
  Ga  Ga7  1  0.637  0.611  0.269  1.0
  Ga  Ga8  1  0.731  0.363  0.389  1.0
  Ga  Ga9  1  0.389  0.731  0.363  1.0
  Ga  Ga10  1  0.363  0.389  0.731  1.0
  Ga  Ga11  1  0.674  0.777  0.532  1.0
  Ga  Ga12  1  0.532  0.674  0.777  1.0
  Ga  Ga13  1  0.777  0.532  0.674  1.0
  Ga  Ga14  1  0.326  0.223  0.468  1.0
  Ga  Ga15  1  0.468  0.326  0.223  1.0
  Ga  Ga16  1  0.223  0.468  0.326  1.0
  Ga  Ga17  1  0.779  0.073  0.444  1.0
  Ga  Ga18  1  0.444  0.779  0.073  1.0
  Ga  Ga19  1  0.073  0.444  0.779  1.0
  Ga  Ga20  1  0.221  0.927  0.556  1.0
  Ga  Ga21  1  0.556  0.221  0.927  1.0
  Ga  Ga22  1  0.927  0.556  0.221  1.0
  Ga  Ga23  1  0.966  0.786  0.597  1.0
  Ga  Ga24  1  0.597  0.966  0.786  1.0
  Ga  Ga25  1  0.786  0.597  0.966  1.0
  Ga  Ga26  1  0.034  0.214  0.403  1.0
  Ga  Ga27  1  0.403  0.034  0.214  1.0
  Ga  Ga28  1  0.214  0.403  0.034  1.0
  Ga  Ga29  1  0.043  0.712  0.859  1.0
  Ga  Ga30  1  0.859  0.043  0.712  1.0
  Ga  Ga31  1  0.712  0.859  0.043  1.0
  Ga  Ga32  1  0.957  0.288  0.141  1.0
  Ga  Ga33  1  0.141  0.957  0.288  1.0
  Ga  Ga34  1  0.288  0.141  0.957  1.0
  Ga  Ga35  1  0.122  0.172  0.687  1.0
  Ga  Ga36  1  0.687  0.122  0.172  1.0
  Ga  Ga37  1  0.172  0.687  0.122  1.0
  Ga  Ga38  1  0.878  0.828  0.313  1.0
  Ga  Ga39  1  0.313  0.878  0.828  1.0
  Ga  Ga40  1  0.828  0.313  0.878  1.0
  Mo  Mo41  1  0.789  0.789  0.789  1.0
  Mo  Mo42  1  0.211  0.211  0.211  1.0
  Mo  Mo43  1  0.291  0.610  0.886  1.0
  Mo  Mo44  1  0.886  0.291  0.610  1.0
  Mo  Mo45  1  0.610  0.886  0.291  1.0
  Mo  Mo46  1  0.709  0.390  0.114  1.0
  Mo  Mo47  1  0.114  0.709  0.390  1.0
  Mo  Mo48  1  0.390  0.114  0.709  1.0
[/CIF]
.