The crystal structure described by AgCd2GaS4 is Stannite-like structured and crystallizes in the orthorhombic Pmn2_1 space group. Ag(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form AgS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra and corners with eight equivalent Cd(1)S4 tetrahedra. Cd(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form CdS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra, corners with four equivalent Cd(1)S4 tetrahedra, and corners with four equivalent Ga(1)S4 tetrahedra. Ga(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form GaS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra and corners with eight equivalent Cd(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(1), two equivalent Cd(1), and one Ga(1) atom to form corner-sharing SCd2GaAg tetrahedra. In the second S site, S(2) is bonded to one Ag(1), two equivalent Cd(1), and one Ga(1) atom to form corner-sharing SCd2GaAg tetrahedra. In the third S site, S(3) is bonded to one Ag(1), two equivalent Cd(1), and one Ga(1) atom to form corner-sharing SCd2GaAg tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cd2GaAgS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.701
_cell_length_b   7.011
_cell_length_c   8.251
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   387.623
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.487  0.175  0.253  1.0
  Cd  Cd1  1  0.987  0.825  0.753  1.0
  Cd  Cd2  1  0.487  0.175  0.747  1.0
  Cd  Cd3  1  0.987  0.825  0.247  1.0
  Ga  Ga4  1  0.491  0.677  0.500  1.0
  Ga  Ga5  1  0.991  0.323  0.000  1.0
  Ag  Ag6  1  0.990  0.341  0.500  1.0
  Ag  Ag7  1  0.490  0.659  0.000  1.0
  S  S8  1  0.106  0.634  0.000  1.0
  S  S9  1  0.606  0.366  0.500  1.0
  S  S10  1  0.146  0.678  0.500  1.0
  S  S11  1  0.646  0.322  0.000  1.0
  S  S12  1  0.604  0.825  0.267  1.0
  S  S13  1  0.104  0.175  0.767  1.0
  S  S14  1  0.104  0.175  0.233  1.0
  S  S15  1  0.604  0.825  0.733  1.0
[/CIF]
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The crystal structure described by AgCd2GaS4 is Stannite-like structured and crystallizes in the orthorhombic Pmn2_1 space group. Ag(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form AgS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra and corners with eight equivalent Cd(1)S4 tetrahedra. Cd(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form CdS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra, corners with four equivalent Cd(1)S4 tetrahedra, and corners with four equivalent Ga(1)S4 tetrahedra. Ga(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form GaS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra and corners with eight equivalent Cd(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(1), two equivalent Cd(1), and one Ga(1) atom to form corner-sharing SCd2GaAg tetrahedra. In the second S site, S(2) is bonded to one Ag(1), two equivalent Cd(1), and one Ga(1) atom to form corner-sharing SCd2GaAg tetrahedra. In the third S site, S(3) is bonded to one Ag(1), two equivalent Cd(1), and one Ga(1) atom to form corner-sharing SCd2GaAg tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cd2GaAgS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.701
_cell_length_b   7.011
_cell_length_c   8.251
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   387.623
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.487  0.175  0.253  1.0
  Cd  Cd1  1  0.987  0.825  0.753  1.0
  Cd  Cd2  1  0.487  0.175  0.747  1.0
  Cd  Cd3  1  0.987  0.825  0.247  1.0
  Ga  Ga4  1  0.491  0.677  0.500  1.0
  Ga  Ga5  1  0.991  0.323  0.000  1.0
  Ag  Ag6  1  0.990  0.341  0.500  1.0
  Ag  Ag7  1  0.490  0.659  0.000  1.0
  S  S8  1  0.106  0.634  0.000  1.0
  S  S9  1  0.606  0.366  0.500  1.0
  S  S10  1  0.146  0.678  0.500  1.0
  S  S11  1  0.646  0.322  0.000  1.0
  S  S12  1  0.604  0.825  0.267  1.0
  S  S13  1  0.104  0.175  0.767  1.0
  S  S14  1  0.104  0.175  0.233  1.0
  S  S15  1  0.604  0.825  0.733  1.0
[/CIF]
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