The material described by NaVO2 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 octahedra that share corners with twelve equivalent V(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and faces with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with twelve equivalent Na(1)O6 octahedra, edges with six equivalent V(1)O6 octahedra, and faces with two equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. O(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaVO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.011
_cell_length_b   3.041
_cell_length_c   5.644
_cell_angle_alpha   90.883
_cell_angle_beta   89.993
_cell_angle_gamma   119.673
_symmetry_Int_Tables_number   1
_cell_volume   44.903
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  1.000  0.000  0.500  1.0
  O  O1  1  0.335  0.669  0.801  1.0
  O  O2  1  0.665  0.331  0.199  1.0
  V  V3  1  0.000  0.000  0.000  1.0
[/CIF]
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The material described by NaVO2 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 octahedra that share corners with twelve equivalent V(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and faces with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with twelve equivalent Na(1)O6 octahedra, edges with six equivalent V(1)O6 octahedra, and faces with two equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. O(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaVO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.011
_cell_length_b   3.041
_cell_length_c   5.644
_cell_angle_alpha   90.883
_cell_angle_beta   89.993
_cell_angle_gamma   119.673
_symmetry_Int_Tables_number   1
_cell_volume   44.903
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  1.000  0.000  0.500  1.0
  O  O1  1  0.335  0.669  0.801  1.0
  O  O2  1  0.665  0.331  0.199  1.0
  V  V3  1  0.000  0.000  0.000  1.0
[/CIF]
.