The compound described by V2As3O13N2(O2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight ammonia atoms, eight hydrogen peroxide molecules, and two V2As3O13 clusters. In each V2As3O13 cluster, V(1) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal pyramidal geometry to one O(3), one O(5), and two equivalent O(7) atoms. In the second As site, As(2) is bonded in a water-like geometry to two equivalent O(8) atoms. In the third As site, As(3) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), and two equivalent O(9) atoms. There are nine inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one As(1) and one O(2) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent V(1) and one As(1) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to two equivalent V(1) atoms. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one V(1) and one As(1) atom. In the fifth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one As(2) atom. In the sixth O site, O(9) is bonded in a bent 120 degrees geometry to one V(1) and one As(3) atom. In the seventh O site, O(10) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(1) is bonded in a single-bond geometry to one As(3) atom. In the ninth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one As(3) and one O(3) atom. is represented by the CIF card [CIF]
data_V2As3N2O17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.243
_cell_length_b   11.243
_cell_length_c   9.994
_cell_angle_alpha   66.528
_cell_angle_beta   66.528
_cell_angle_gamma   103.451
_symmetry_Int_Tables_number   1
_cell_volume   940.939
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.610  0.423  0.224  1.0
  V  V1  1  0.423  0.610  0.224  1.0
  V  V2  1  0.390  0.577  0.776  1.0
  V  V3  1  0.577  0.390  0.776  1.0
  As  As4  1  0.347  0.347  0.674  1.0
  As  As5  1  0.653  0.653  0.326  1.0
  As  As6  1  0.721  0.279  0.500  1.0
  As  As7  1  0.279  0.721  0.500  1.0
  As  As8  1  0.736  0.736  0.632  1.0
  As  As9  1  0.264  0.264  0.368  1.0
  N  N10  1  0.941  0.381  0.773  1.0
  N  N11  1  0.381  0.941  0.773  1.0
  N  N12  1  0.059  0.619  0.227  1.0
  N  N13  1  0.619  0.059  0.227  1.0
  O  O14  1  0.866  0.866  0.601  1.0
  O  O15  1  0.134  0.134  0.399  1.0
  O  O16  1  0.148  0.148  0.659  1.0
  O  O17  1  0.852  0.852  0.341  1.0
  O  O18  1  0.172  0.172  0.767  1.0
  O  O19  1  0.828  0.828  0.233  1.0
  O  O20  1  0.018  0.682  0.774  1.0
  O  O21  1  0.682  0.018  0.774  1.0
  O  O22  1  0.982  0.318  0.226  1.0
  O  O23  1  0.318  0.982  0.226  1.0
  O  O24  1  0.425  0.425  0.456  1.0
  O  O25  1  0.575  0.575  0.544  1.0
  O  O26  1  0.442  0.442  0.882  1.0
  O  O27  1  0.558  0.558  0.118  1.0
  O  O28  1  0.261  0.423  0.771  1.0
  O  O29  1  0.423  0.261  0.771  1.0
  O  O30  1  0.739  0.577  0.229  1.0
  O  O31  1  0.577  0.739  0.229  1.0
  O  O32  1  0.715  0.388  0.582  1.0
  O  O33  1  0.388  0.715  0.582  1.0
  O  O34  1  0.285  0.612  0.418  1.0
  O  O35  1  0.612  0.285  0.418  1.0
  O  O36  1  0.736  0.569  0.697  1.0
  O  O37  1  0.569  0.736  0.697  1.0
  O  O38  1  0.264  0.431  0.303  1.0
  O  O39  1  0.431  0.264  0.303  1.0
  O  O40  1  0.269  0.572  0.935  1.0
  O  O41  1  0.572  0.269  0.935  1.0
  O  O42  1  0.731  0.428  0.065  1.0
  O  O43  1  0.428  0.731  0.065  1.0
  O  O44  1  0.056  0.771  0.810  1.0
  O  O45  1  0.771  0.056  0.810  1.0
  O  O46  1  0.944  0.229  0.190  1.0
  O  O47  1  0.229  0.944  0.190  1.0
[/CIF]
.
The compound described by V2As3O13N2(O2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight ammonia atoms, eight hydrogen peroxide molecules, and two V2As3O13 clusters. In each V2As3O13 cluster, V(1) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal pyramidal geometry to one O(3), one O(5), and two equivalent O(7) atoms. In the second As site, As(2) is bonded in a water-like geometry to two equivalent O(8) atoms. In the third As site, As(3) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), and two equivalent O(9) atoms. There are nine inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one As(1) and one O(2) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent V(1) and one As(1) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to two equivalent V(1) atoms. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one V(1) and one As(1) atom. In the fifth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one As(2) atom. In the sixth O site, O(9) is bonded in a bent 120 degrees geometry to one V(1) and one As(3) atom. In the seventh O site, O(10) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(1) is bonded in a single-bond geometry to one As(3) atom. In the ninth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one As(3) and one O(3) atom. is represented by the CIF card [CIF]
data_V2As3N2O17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.243
_cell_length_b   11.243
_cell_length_c   9.994
_cell_angle_alpha   66.528
_cell_angle_beta   66.528
_cell_angle_gamma   103.451
_symmetry_Int_Tables_number   1
_cell_volume   940.939
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.610  0.423  0.224  1.0
  V  V1  1  0.423  0.610  0.224  1.0
  V  V2  1  0.390  0.577  0.776  1.0
  V  V3  1  0.577  0.390  0.776  1.0
  As  As4  1  0.347  0.347  0.674  1.0
  As  As5  1  0.653  0.653  0.326  1.0
  As  As6  1  0.721  0.279  0.500  1.0
  As  As7  1  0.279  0.721  0.500  1.0
  As  As8  1  0.736  0.736  0.632  1.0
  As  As9  1  0.264  0.264  0.368  1.0
  N  N10  1  0.941  0.381  0.773  1.0
  N  N11  1  0.381  0.941  0.773  1.0
  N  N12  1  0.059  0.619  0.227  1.0
  N  N13  1  0.619  0.059  0.227  1.0
  O  O14  1  0.866  0.866  0.601  1.0
  O  O15  1  0.134  0.134  0.399  1.0
  O  O16  1  0.148  0.148  0.659  1.0
  O  O17  1  0.852  0.852  0.341  1.0
  O  O18  1  0.172  0.172  0.767  1.0
  O  O19  1  0.828  0.828  0.233  1.0
  O  O20  1  0.018  0.682  0.774  1.0
  O  O21  1  0.682  0.018  0.774  1.0
  O  O22  1  0.982  0.318  0.226  1.0
  O  O23  1  0.318  0.982  0.226  1.0
  O  O24  1  0.425  0.425  0.456  1.0
  O  O25  1  0.575  0.575  0.544  1.0
  O  O26  1  0.442  0.442  0.882  1.0
  O  O27  1  0.558  0.558  0.118  1.0
  O  O28  1  0.261  0.423  0.771  1.0
  O  O29  1  0.423  0.261  0.771  1.0
  O  O30  1  0.739  0.577  0.229  1.0
  O  O31  1  0.577  0.739  0.229  1.0
  O  O32  1  0.715  0.388  0.582  1.0
  O  O33  1  0.388  0.715  0.582  1.0
  O  O34  1  0.285  0.612  0.418  1.0
  O  O35  1  0.612  0.285  0.418  1.0
  O  O36  1  0.736  0.569  0.697  1.0
  O  O37  1  0.569  0.736  0.697  1.0
  O  O38  1  0.264  0.431  0.303  1.0
  O  O39  1  0.431  0.264  0.303  1.0
  O  O40  1  0.269  0.572  0.935  1.0
  O  O41  1  0.572  0.269  0.935  1.0
  O  O42  1  0.731  0.428  0.065  1.0
  O  O43  1  0.428  0.731  0.065  1.0
  O  O44  1  0.056  0.771  0.810  1.0
  O  O45  1  0.771  0.056  0.810  1.0
  O  O46  1  0.944  0.229  0.190  1.0
  O  O47  1  0.229  0.944  0.190  1.0
[/CIF]
.