The crystal structure described by Rb3Ru2N(OCl4)2 crystallizes in the monoclinic C2/m space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted body-centered cubic geometry to four equivalent Cl(1) and four equivalent Cl(2) atoms. In the second Rb site, Rb(2) is bonded in a body-centered cubic geometry to four equivalent Cl(1) and four equivalent Cl(2) atoms. Ru(1) is bonded to one N(1), one O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms to form distorted corner-sharing RuNCl4O octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a linear geometry to two equivalent Ru(1) atoms. O(1) is bonded in a single-bond geometry to one Ru(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one Rb(2), two equivalent Rb(1), and one Ru(1) atom to form a mixture of distorted corner and edge-sharing ClRb3Ru tetrahedra. In the second Cl site, Cl(2) is bonded in a distorted rectangular see-saw-like geometry to one Rb(2), two equivalent Rb(1), and one Ru(1) atom. is represented by the CIF card [CIF]
data_Rb3Ru2N(Cl4O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.675
_cell_length_b   8.675
_cell_length_c   8.596
_cell_angle_alpha   64.271
_cell_angle_beta   64.271
_cell_angle_gamma   55.162
_symmetry_Int_Tables_number   1
_cell_volume   462.856
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.856  0.856  0.036  1.0
  Rb  Rb1  1  0.144  0.144  0.964  1.0
  Rb  Rb2  1  0.500  0.500  0.500  1.0
  Ru  Ru3  1  0.875  0.875  0.510  1.0
  Ru  Ru4  1  0.125  0.125  0.490  1.0
  N  N5  1  0.000  0.000  0.500  1.0
  Cl  Cl6  1  0.034  0.610  0.737  1.0
  Cl  Cl7  1  0.610  0.034  0.737  1.0
  Cl  Cl8  1  0.966  0.390  0.263  1.0
  Cl  Cl9  1  0.390  0.966  0.263  1.0
  Cl  Cl10  1  0.146  0.727  0.282  1.0
  Cl  Cl11  1  0.727  0.146  0.282  1.0
  Cl  Cl12  1  0.854  0.273  0.718  1.0
  Cl  Cl13  1  0.273  0.854  0.718  1.0
  O  O14  1  0.760  0.760  0.519  1.0
  O  O15  1  0.240  0.240  0.481  1.0
[/CIF]
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The crystal structure described by Rb3Ru2N(OCl4)2 crystallizes in the monoclinic C2/m space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted body-centered cubic geometry to four equivalent Cl(1) and four equivalent Cl(2) atoms. In the second Rb site, Rb(2) is bonded in a body-centered cubic geometry to four equivalent Cl(1) and four equivalent Cl(2) atoms. Ru(1) is bonded to one N(1), one O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms to form distorted corner-sharing RuNCl4O octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a linear geometry to two equivalent Ru(1) atoms. O(1) is bonded in a single-bond geometry to one Ru(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one Rb(2), two equivalent Rb(1), and one Ru(1) atom to form a mixture of distorted corner and edge-sharing ClRb3Ru tetrahedra. In the second Cl site, Cl(2) is bonded in a distorted rectangular see-saw-like geometry to one Rb(2), two equivalent Rb(1), and one Ru(1) atom. is represented by the CIF card [CIF]
data_Rb3Ru2N(Cl4O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.675
_cell_length_b   8.675
_cell_length_c   8.596
_cell_angle_alpha   64.271
_cell_angle_beta   64.271
_cell_angle_gamma   55.162
_symmetry_Int_Tables_number   1
_cell_volume   462.856
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.856  0.856  0.036  1.0
  Rb  Rb1  1  0.144  0.144  0.964  1.0
  Rb  Rb2  1  0.500  0.500  0.500  1.0
  Ru  Ru3  1  0.875  0.875  0.510  1.0
  Ru  Ru4  1  0.125  0.125  0.490  1.0
  N  N5  1  0.000  0.000  0.500  1.0
  Cl  Cl6  1  0.034  0.610  0.737  1.0
  Cl  Cl7  1  0.610  0.034  0.737  1.0
  Cl  Cl8  1  0.966  0.390  0.263  1.0
  Cl  Cl9  1  0.390  0.966  0.263  1.0
  Cl  Cl10  1  0.146  0.727  0.282  1.0
  Cl  Cl11  1  0.727  0.146  0.282  1.0
  Cl  Cl12  1  0.854  0.273  0.718  1.0
  Cl  Cl13  1  0.273  0.854  0.718  1.0
  O  O14  1  0.760  0.760  0.519  1.0
  O  O15  1  0.240  0.240  0.481  1.0
[/CIF]
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