The structure described by IrV is beta-prime cadmium gold-like structured and crystallizes in the orthorhombic Immm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to one V(5), two equivalent Ir(1), two equivalent Ir(3), and four equivalent Ir(2) atoms. In the second V site, V(2) is bonded in a 8-coordinate geometry to one V(6), two equivalent Ir(1), two equivalent Ir(3), and four equivalent Ir(2) atoms. In the third V site, V(3) is bonded in a body-centered cubic geometry to four equivalent Ir(2) and four equivalent Ir(3) atoms. In the fourth V site, V(4) is bonded in a 8-coordinate geometry to four equivalent Ir(1) and four equivalent Ir(2) atoms. In the fifth V site, V(5) is bonded to one V(5), one V(6), two equivalent V(1), four equivalent Ir(1), and four equivalent Ir(2) atoms to form a mixture of distorted corner and face-sharing VV4Ir8 cuboctahedra. In the sixth V site, V(6) is bonded to one V(5), one V(6), two equivalent V(2), four equivalent Ir(2), and four equivalent Ir(3) atoms to form a mixture of distorted corner and face-sharing VV4Ir8 cuboctahedra. There are three inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(4), and two equivalent V(5) atoms. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to one V(3), one V(4), one V(5), one V(6), two equivalent V(1), and two equivalent V(2) atoms. In the third Ir site, Ir(3) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(6) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VIr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.667
_cell_length_b   8.667
_cell_length_c   8.667
_cell_angle_alpha   131.004
_cell_angle_beta   100.128
_cell_angle_gamma   99.675
_symmetry_Int_Tables_number   1
_cell_volume   447.045
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.096  0.227  0.869  1.0
  V  V1  1  0.358  0.227  0.131  1.0
  V  V2  1  0.849  0.230  0.619  1.0
  V  V3  1  0.611  0.230  0.381  1.0
  V  V4  1  0.368  0.500  0.868  1.0
  V  V5  1  0.632  0.500  0.132  1.0
  V  V6  1  0.116  0.500  0.616  1.0
  V  V7  1  0.884  0.500  0.384  1.0
  V  V8  1  0.870  0.000  0.870  1.0
  V  V9  1  0.130  0.000  0.130  1.0
  V  V10  1  0.620  0.000  0.620  1.0
  V  V11  1  0.380  0.000  0.380  1.0
  V  V12  1  0.642  0.773  0.869  1.0
  V  V13  1  0.904  0.773  0.131  1.0
  V  V14  1  0.389  0.770  0.619  1.0
  V  V15  1  0.151  0.770  0.381  1.0
  Ir  Ir16  1  0.127  0.384  0.257  1.0
  Ir  Ir17  1  0.127  0.870  0.743  1.0
  Ir  Ir18  1  0.877  0.395  0.019  1.0
  Ir  Ir19  1  0.377  0.859  0.981  1.0
  Ir  Ir20  1  0.877  0.859  0.482  1.0
  Ir  Ir21  1  0.377  0.395  0.518  1.0
  Ir  Ir22  1  0.627  0.850  0.223  1.0
  Ir  Ir23  1  0.627  0.404  0.777  1.0
  Ir  Ir24  1  0.873  0.130  0.257  1.0
  Ir  Ir25  1  0.873  0.616  0.743  1.0
  Ir  Ir26  1  0.623  0.141  0.019  1.0
  Ir  Ir27  1  0.123  0.605  0.981  1.0
  Ir  Ir28  1  0.623  0.605  0.482  1.0
  Ir  Ir29  1  0.123  0.141  0.518  1.0
  Ir  Ir30  1  0.373  0.596  0.223  1.0
  Ir  Ir31  1  0.373  0.150  0.777  1.0
[/CIF]
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The structure described by IrV is beta-prime cadmium gold-like structured and crystallizes in the orthorhombic Immm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to one V(5), two equivalent Ir(1), two equivalent Ir(3), and four equivalent Ir(2) atoms. In the second V site, V(2) is bonded in a 8-coordinate geometry to one V(6), two equivalent Ir(1), two equivalent Ir(3), and four equivalent Ir(2) atoms. In the third V site, V(3) is bonded in a body-centered cubic geometry to four equivalent Ir(2) and four equivalent Ir(3) atoms. In the fourth V site, V(4) is bonded in a 8-coordinate geometry to four equivalent Ir(1) and four equivalent Ir(2) atoms. In the fifth V site, V(5) is bonded to one V(5), one V(6), two equivalent V(1), four equivalent Ir(1), and four equivalent Ir(2) atoms to form a mixture of distorted corner and face-sharing VV4Ir8 cuboctahedra. In the sixth V site, V(6) is bonded to one V(5), one V(6), two equivalent V(2), four equivalent Ir(2), and four equivalent Ir(3) atoms to form a mixture of distorted corner and face-sharing VV4Ir8 cuboctahedra. There are three inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(4), and two equivalent V(5) atoms. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to one V(3), one V(4), one V(5), one V(6), two equivalent V(1), and two equivalent V(2) atoms. In the third Ir site, Ir(3) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(6) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VIr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.667
_cell_length_b   8.667
_cell_length_c   8.667
_cell_angle_alpha   131.004
_cell_angle_beta   100.128
_cell_angle_gamma   99.675
_symmetry_Int_Tables_number   1
_cell_volume   447.045
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.096  0.227  0.869  1.0
  V  V1  1  0.358  0.227  0.131  1.0
  V  V2  1  0.849  0.230  0.619  1.0
  V  V3  1  0.611  0.230  0.381  1.0
  V  V4  1  0.368  0.500  0.868  1.0
  V  V5  1  0.632  0.500  0.132  1.0
  V  V6  1  0.116  0.500  0.616  1.0
  V  V7  1  0.884  0.500  0.384  1.0
  V  V8  1  0.870  0.000  0.870  1.0
  V  V9  1  0.130  0.000  0.130  1.0
  V  V10  1  0.620  0.000  0.620  1.0
  V  V11  1  0.380  0.000  0.380  1.0
  V  V12  1  0.642  0.773  0.869  1.0
  V  V13  1  0.904  0.773  0.131  1.0
  V  V14  1  0.389  0.770  0.619  1.0
  V  V15  1  0.151  0.770  0.381  1.0
  Ir  Ir16  1  0.127  0.384  0.257  1.0
  Ir  Ir17  1  0.127  0.870  0.743  1.0
  Ir  Ir18  1  0.877  0.395  0.019  1.0
  Ir  Ir19  1  0.377  0.859  0.981  1.0
  Ir  Ir20  1  0.877  0.859  0.482  1.0
  Ir  Ir21  1  0.377  0.395  0.518  1.0
  Ir  Ir22  1  0.627  0.850  0.223  1.0
  Ir  Ir23  1  0.627  0.404  0.777  1.0
  Ir  Ir24  1  0.873  0.130  0.257  1.0
  Ir  Ir25  1  0.873  0.616  0.743  1.0
  Ir  Ir26  1  0.623  0.141  0.019  1.0
  Ir  Ir27  1  0.123  0.605  0.981  1.0
  Ir  Ir28  1  0.623  0.605  0.482  1.0
  Ir  Ir29  1  0.123  0.141  0.518  1.0
  Ir  Ir30  1  0.373  0.596  0.223  1.0
  Ir  Ir31  1  0.373  0.150  0.777  1.0
[/CIF]
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