The structure described by NaCdP2NO10 crystallizes in the monoclinic Cc space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(5), one O(9), and two equivalent O(7) atoms. Cd(1) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted CdO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with three equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-58°. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-58°. N(1) is bonded in a single-bond geometry to one O(8) atom. There are ten inequivalent O sites. In the first O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one P(2) atom. In the second O site, O(8) is bonded in a distorted single-bond geometry to one N(1) and one O(9) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one O(8) atom. In the fourth O site, O(10) is bonded in a water-like geometry to one Na(1) and one Cd(1) atom. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1), one P(1), and one P(2) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one P(1) atom. In the seventh O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one P(1) atom. In the eighth O site, O(4) is bonded in a bent 120 degrees geometry to one Cd(1) and one P(1) atom. In the ninth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Cd(1), and one P(2) atom. In the tenth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one P(2) atom. is represented by the CIF card [CIF]
data_NaCdP2NO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.845
_cell_length_b   9.845
_cell_length_c   6.004
_cell_angle_alpha   82.437
_cell_angle_beta   82.437
_cell_angle_gamma   121.063
_symmetry_Int_Tables_number   1
_cell_volume   480.376
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.468  0.604  0.731  1.0
  Na  Na1  1  0.604  0.468  0.231  1.0
  Cd  Cd2  1  0.239  0.792  0.501  1.0
  Cd  Cd3  1  0.792  0.239  0.001  1.0
  P  P4  1  0.414  0.982  0.929  1.0
  P  P5  1  0.982  0.414  0.429  1.0
  P  P6  1  0.815  0.566  0.636  1.0
  P  P7  1  0.566  0.815  0.136  1.0
  N  N8  1  0.061  0.988  0.026  1.0
  N  N9  1  0.988  0.061  0.526  1.0
  O  O10  1  0.841  0.456  0.471  1.0
  O  O11  1  0.456  0.841  0.971  1.0
  O  O12  1  0.977  0.326  0.667  1.0
  O  O13  1  0.326  0.977  0.167  1.0
  O  O14  1  0.305  0.937  0.762  1.0
  O  O15  1  0.937  0.305  0.262  1.0
  O  O16  1  0.147  0.575  0.329  1.0
  O  O17  1  0.575  0.147  0.829  1.0
  O  O18  1  0.784  0.483  0.890  1.0
  O  O19  1  0.483  0.784  0.390  1.0
  O  O20  1  0.975  0.733  0.579  1.0
  O  O21  1  0.733  0.975  0.079  1.0
  O  O22  1  0.568  0.673  0.072  1.0
  O  O23  1  0.673  0.568  0.572  1.0
  O  O24  1  0.132  0.127  0.510  1.0
  O  O25  1  0.127  0.132  0.010  1.0
  O  O26  1  0.256  0.293  0.434  1.0
  O  O27  1  0.293  0.256  0.934  1.0
  O  O28  1  0.191  0.552  0.716  1.0
  O  O29  1  0.552  0.191  0.216  1.0
[/CIF]
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The structure described by NaCdP2NO10 crystallizes in the monoclinic Cc space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(5), one O(9), and two equivalent O(7) atoms. Cd(1) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted CdO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with three equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-58°. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-58°. N(1) is bonded in a single-bond geometry to one O(8) atom. There are ten inequivalent O sites. In the first O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one P(2) atom. In the second O site, O(8) is bonded in a distorted single-bond geometry to one N(1) and one O(9) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one O(8) atom. In the fourth O site, O(10) is bonded in a water-like geometry to one Na(1) and one Cd(1) atom. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1), one P(1), and one P(2) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one P(1) atom. In the seventh O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one P(1) atom. In the eighth O site, O(4) is bonded in a bent 120 degrees geometry to one Cd(1) and one P(1) atom. In the ninth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Cd(1), and one P(2) atom. In the tenth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one P(2) atom. is represented by the CIF card [CIF]
data_NaCdP2NO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.845
_cell_length_b   9.845
_cell_length_c   6.004
_cell_angle_alpha   82.437
_cell_angle_beta   82.437
_cell_angle_gamma   121.063
_symmetry_Int_Tables_number   1
_cell_volume   480.376
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.468  0.604  0.731  1.0
  Na  Na1  1  0.604  0.468  0.231  1.0
  Cd  Cd2  1  0.239  0.792  0.501  1.0
  Cd  Cd3  1  0.792  0.239  0.001  1.0
  P  P4  1  0.414  0.982  0.929  1.0
  P  P5  1  0.982  0.414  0.429  1.0
  P  P6  1  0.815  0.566  0.636  1.0
  P  P7  1  0.566  0.815  0.136  1.0
  N  N8  1  0.061  0.988  0.026  1.0
  N  N9  1  0.988  0.061  0.526  1.0
  O  O10  1  0.841  0.456  0.471  1.0
  O  O11  1  0.456  0.841  0.971  1.0
  O  O12  1  0.977  0.326  0.667  1.0
  O  O13  1  0.326  0.977  0.167  1.0
  O  O14  1  0.305  0.937  0.762  1.0
  O  O15  1  0.937  0.305  0.262  1.0
  O  O16  1  0.147  0.575  0.329  1.0
  O  O17  1  0.575  0.147  0.829  1.0
  O  O18  1  0.784  0.483  0.890  1.0
  O  O19  1  0.483  0.784  0.390  1.0
  O  O20  1  0.975  0.733  0.579  1.0
  O  O21  1  0.733  0.975  0.079  1.0
  O  O22  1  0.568  0.673  0.072  1.0
  O  O23  1  0.673  0.568  0.572  1.0
  O  O24  1  0.132  0.127  0.510  1.0
  O  O25  1  0.127  0.132  0.010  1.0
  O  O26  1  0.256  0.293  0.434  1.0
  O  O27  1  0.293  0.256  0.934  1.0
  O  O28  1  0.191  0.552  0.716  1.0
  O  O29  1  0.552  0.191  0.216  1.0
[/CIF]
.