The material described by NaSbO3 crystallizes in the triclinic P-1 space group. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(5), one O(7), and one O(9) atom. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms. In the third Na site, Na(3) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), one O(8), and one O(9) atom. In the fourth Na site, Na(4) is bonded in a distorted hexagonal planar geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(7) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the second Sb site, Sb(2) is bonded to one O(1), one O(4), one O(6), one O(7), and two equivalent O(8) atoms to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sb site, Sb(3) is bonded to one O(2), one O(5), one O(6), one O(7), and two equivalent O(9) atoms to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Sb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Na(2), one Na(4), one Sb(1), and one Sb(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1) and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded to one Na(3), one Na(4), one Sb(1), and one Sb(2) atom to form a mixture of edge and corner-sharing ONa2Sb2 tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Sb(1), and one Sb(3) atom. In the sixth O site, O(6) is bonded to one Na(2), one Na(3), one Sb(2), and one Sb(3) atom to form distorted corner-sharing ONa2Sb2 tetrahedra. In the seventh O site, O(7) is bonded to one Na(1), one Na(4), one Sb(2), and one Sb(3) atom to form a mixture of edge and corner-sharing ONa2Sb2 tetrahedra. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Na(3) and two equivalent Sb(2) atoms. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), and two equivalent Sb(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.105
_cell_length_b   8.164
_cell_length_c   8.248
_cell_angle_alpha   109.399
_cell_angle_beta   109.319
_cell_angle_gamma   108.452
_symmetry_Int_Tables_number   1
_cell_volume   426.446
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.014  0.983  0.322  1.0
  Na  Na1  1  0.500  0.000  0.000  1.0
  Na  Na2  1  0.671  0.652  0.702  1.0
  Na  Na3  1  0.329  0.348  0.298  1.0
  Na  Na4  1  0.000  0.500  0.000  1.0
  Na  Na5  1  0.986  0.017  0.678  1.0
  Sb  Sb6  1  0.499  0.840  0.337  1.0
  Sb  Sb7  1  0.159  0.663  0.501  1.0
  Sb  Sb8  1  0.660  0.497  0.160  1.0
  Sb  Sb9  1  0.340  0.503  0.840  1.0
  Sb  Sb10  1  0.841  0.337  0.499  1.0
  Sb  Sb11  1  0.501  0.160  0.663  1.0
  O  O12  1  0.274  0.956  0.661  1.0
  O  O13  1  0.335  0.720  0.046  1.0
  O  O14  1  0.638  0.991  0.635  1.0
  O  O15  1  0.283  0.622  0.328  1.0
  O  O16  1  0.663  0.705  0.381  1.0
  O  O17  1  0.384  0.673  0.714  1.0
  O  O18  1  0.952  0.665  0.282  1.0
  O  O19  1  0.010  0.363  0.366  1.0
  O  O20  1  0.359  0.363  0.003  1.0
  O  O21  1  0.641  0.637  0.997  1.0
  O  O22  1  0.990  0.637  0.634  1.0
  O  O23  1  0.048  0.335  0.718  1.0
  O  O24  1  0.616  0.327  0.286  1.0
  O  O25  1  0.337  0.295  0.619  1.0
  O  O26  1  0.717  0.378  0.672  1.0
  O  O27  1  0.362  0.009  0.365  1.0
  O  O28  1  0.665  0.280  0.954  1.0
  O  O29  1  0.726  0.044  0.339  1.0
[/CIF]
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The material described by NaSbO3 crystallizes in the triclinic P-1 space group. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(5), one O(7), and one O(9) atom. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms. In the third Na site, Na(3) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), one O(8), and one O(9) atom. In the fourth Na site, Na(4) is bonded in a distorted hexagonal planar geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(7) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the second Sb site, Sb(2) is bonded to one O(1), one O(4), one O(6), one O(7), and two equivalent O(8) atoms to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sb site, Sb(3) is bonded to one O(2), one O(5), one O(6), one O(7), and two equivalent O(9) atoms to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Sb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Na(2), one Na(4), one Sb(1), and one Sb(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1) and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded to one Na(3), one Na(4), one Sb(1), and one Sb(2) atom to form a mixture of edge and corner-sharing ONa2Sb2 tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Sb(1), and one Sb(3) atom. In the sixth O site, O(6) is bonded to one Na(2), one Na(3), one Sb(2), and one Sb(3) atom to form distorted corner-sharing ONa2Sb2 tetrahedra. In the seventh O site, O(7) is bonded to one Na(1), one Na(4), one Sb(2), and one Sb(3) atom to form a mixture of edge and corner-sharing ONa2Sb2 tetrahedra. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Na(3) and two equivalent Sb(2) atoms. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), and two equivalent Sb(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.105
_cell_length_b   8.164
_cell_length_c   8.248
_cell_angle_alpha   109.399
_cell_angle_beta   109.319
_cell_angle_gamma   108.452
_symmetry_Int_Tables_number   1
_cell_volume   426.446
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.014  0.983  0.322  1.0
  Na  Na1  1  0.500  0.000  0.000  1.0
  Na  Na2  1  0.671  0.652  0.702  1.0
  Na  Na3  1  0.329  0.348  0.298  1.0
  Na  Na4  1  0.000  0.500  0.000  1.0
  Na  Na5  1  0.986  0.017  0.678  1.0
  Sb  Sb6  1  0.499  0.840  0.337  1.0
  Sb  Sb7  1  0.159  0.663  0.501  1.0
  Sb  Sb8  1  0.660  0.497  0.160  1.0
  Sb  Sb9  1  0.340  0.503  0.840  1.0
  Sb  Sb10  1  0.841  0.337  0.499  1.0
  Sb  Sb11  1  0.501  0.160  0.663  1.0
  O  O12  1  0.274  0.956  0.661  1.0
  O  O13  1  0.335  0.720  0.046  1.0
  O  O14  1  0.638  0.991  0.635  1.0
  O  O15  1  0.283  0.622  0.328  1.0
  O  O16  1  0.663  0.705  0.381  1.0
  O  O17  1  0.384  0.673  0.714  1.0
  O  O18  1  0.952  0.665  0.282  1.0
  O  O19  1  0.010  0.363  0.366  1.0
  O  O20  1  0.359  0.363  0.003  1.0
  O  O21  1  0.641  0.637  0.997  1.0
  O  O22  1  0.990  0.637  0.634  1.0
  O  O23  1  0.048  0.335  0.718  1.0
  O  O24  1  0.616  0.327  0.286  1.0
  O  O25  1  0.337  0.295  0.619  1.0
  O  O26  1  0.717  0.378  0.672  1.0
  O  O27  1  0.362  0.009  0.365  1.0
  O  O28  1  0.665  0.280  0.954  1.0
  O  O29  1  0.726  0.044  0.339  1.0
[/CIF]
.