The structure described by Rb3CoNO3Cl4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(1), two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(1), one Cl(2), one Cl(3), and four equivalent Cl(1) atoms. Co(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. N(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one N(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), two equivalent Rb(2), and one Co(1) atom. In the second Cl site, Cl(2) is bonded to one Rb(2), four equivalent Rb(1), and one Co(1) atom to form distorted edge-sharing ClRb5Co octahedra. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Rb(2), four equivalent Rb(1), and one Co(1) atom. is represented by the CIF file [CIF]
data_Rb3CoNCl4O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.616
_cell_length_b   10.278
_cell_length_c   12.796
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1264.574
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.882  0.505  0.681  1.0
  Rb  Rb1  1  0.382  0.995  0.819  1.0
  Rb  Rb2  1  0.915  0.250  0.967  1.0
  Rb  Rb3  1  0.882  0.995  0.681  1.0
  Rb  Rb4  1  0.618  0.495  0.181  1.0
  Rb  Rb5  1  0.118  0.495  0.319  1.0
  Rb  Rb6  1  0.085  0.750  0.033  1.0
  Rb  Rb7  1  0.618  0.005  0.181  1.0
  Rb  Rb8  1  0.585  0.750  0.467  1.0
  Rb  Rb9  1  0.415  0.250  0.533  1.0
  Rb  Rb10  1  0.118  0.005  0.319  1.0
  Rb  Rb11  1  0.382  0.505  0.819  1.0
  Co  Co12  1  0.680  0.750  0.908  1.0
  Co  Co13  1  0.180  0.750  0.592  1.0
  Co  Co14  1  0.820  0.250  0.408  1.0
  Co  Co15  1  0.320  0.250  0.092  1.0
  N  N16  1  0.659  0.250  0.726  1.0
  N  N17  1  0.841  0.750  0.226  1.0
  N  N18  1  0.159  0.250  0.774  1.0
  N  N19  1  0.341  0.750  0.274  1.0
  Cl  Cl20  1  0.198  0.434  0.054  1.0
  Cl  Cl21  1  0.873  0.250  0.233  1.0
  Cl  Cl22  1  0.802  0.566  0.946  1.0
  Cl  Cl23  1  0.302  0.934  0.554  1.0
  Cl  Cl24  1  0.302  0.566  0.554  1.0
  Cl  Cl25  1  0.698  0.434  0.446  1.0
  Cl  Cl26  1  0.198  0.066  0.054  1.0
  Cl  Cl27  1  0.525  0.250  0.999  1.0
  Cl  Cl28  1  0.802  0.934  0.946  1.0
  Cl  Cl29  1  0.698  0.066  0.446  1.0
  Cl  Cl30  1  0.475  0.750  0.001  1.0
  Cl  Cl31  1  0.373  0.250  0.267  1.0
  Cl  Cl32  1  0.025  0.250  0.501  1.0
  Cl  Cl33  1  0.975  0.750  0.499  1.0
  Cl  Cl34  1  0.627  0.750  0.733  1.0
  Cl  Cl35  1  0.127  0.750  0.767  1.0
  O  O36  1  0.599  0.143  0.707  1.0
  O  O37  1  0.599  0.357  0.707  1.0
  O  O38  1  0.901  0.643  0.207  1.0
  O  O39  1  0.283  0.250  0.740  1.0
  O  O40  1  0.717  0.750  0.260  1.0
  O  O41  1  0.099  0.143  0.793  1.0
  O  O42  1  0.217  0.750  0.240  1.0
  O  O43  1  0.783  0.250  0.760  1.0
  O  O44  1  0.401  0.643  0.293  1.0
  O  O45  1  0.901  0.857  0.207  1.0
  O  O46  1  0.401  0.857  0.293  1.0
  O  O47  1  0.099  0.357  0.793  1.0
[/CIF]
.
The structure described by Rb3CoNO3Cl4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(1), two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(1), one Cl(2), one Cl(3), and four equivalent Cl(1) atoms. Co(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. N(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one N(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), two equivalent Rb(2), and one Co(1) atom. In the second Cl site, Cl(2) is bonded to one Rb(2), four equivalent Rb(1), and one Co(1) atom to form distorted edge-sharing ClRb5Co octahedra. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Rb(2), four equivalent Rb(1), and one Co(1) atom. is represented by the CIF file [CIF]
data_Rb3CoNCl4O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.616
_cell_length_b   10.278
_cell_length_c   12.796
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1264.574
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.882  0.505  0.681  1.0
  Rb  Rb1  1  0.382  0.995  0.819  1.0
  Rb  Rb2  1  0.915  0.250  0.967  1.0
  Rb  Rb3  1  0.882  0.995  0.681  1.0
  Rb  Rb4  1  0.618  0.495  0.181  1.0
  Rb  Rb5  1  0.118  0.495  0.319  1.0
  Rb  Rb6  1  0.085  0.750  0.033  1.0
  Rb  Rb7  1  0.618  0.005  0.181  1.0
  Rb  Rb8  1  0.585  0.750  0.467  1.0
  Rb  Rb9  1  0.415  0.250  0.533  1.0
  Rb  Rb10  1  0.118  0.005  0.319  1.0
  Rb  Rb11  1  0.382  0.505  0.819  1.0
  Co  Co12  1  0.680  0.750  0.908  1.0
  Co  Co13  1  0.180  0.750  0.592  1.0
  Co  Co14  1  0.820  0.250  0.408  1.0
  Co  Co15  1  0.320  0.250  0.092  1.0
  N  N16  1  0.659  0.250  0.726  1.0
  N  N17  1  0.841  0.750  0.226  1.0
  N  N18  1  0.159  0.250  0.774  1.0
  N  N19  1  0.341  0.750  0.274  1.0
  Cl  Cl20  1  0.198  0.434  0.054  1.0
  Cl  Cl21  1  0.873  0.250  0.233  1.0
  Cl  Cl22  1  0.802  0.566  0.946  1.0
  Cl  Cl23  1  0.302  0.934  0.554  1.0
  Cl  Cl24  1  0.302  0.566  0.554  1.0
  Cl  Cl25  1  0.698  0.434  0.446  1.0
  Cl  Cl26  1  0.198  0.066  0.054  1.0
  Cl  Cl27  1  0.525  0.250  0.999  1.0
  Cl  Cl28  1  0.802  0.934  0.946  1.0
  Cl  Cl29  1  0.698  0.066  0.446  1.0
  Cl  Cl30  1  0.475  0.750  0.001  1.0
  Cl  Cl31  1  0.373  0.250  0.267  1.0
  Cl  Cl32  1  0.025  0.250  0.501  1.0
  Cl  Cl33  1  0.975  0.750  0.499  1.0
  Cl  Cl34  1  0.627  0.750  0.733  1.0
  Cl  Cl35  1  0.127  0.750  0.767  1.0
  O  O36  1  0.599  0.143  0.707  1.0
  O  O37  1  0.599  0.357  0.707  1.0
  O  O38  1  0.901  0.643  0.207  1.0
  O  O39  1  0.283  0.250  0.740  1.0
  O  O40  1  0.717  0.750  0.260  1.0
  O  O41  1  0.099  0.143  0.793  1.0
  O  O42  1  0.217  0.750  0.240  1.0
  O  O43  1  0.783  0.250  0.760  1.0
  O  O44  1  0.401  0.643  0.293  1.0
  O  O45  1  0.901  0.857  0.207  1.0
  O  O46  1  0.401  0.857  0.293  1.0
  O  O47  1  0.099  0.357  0.793  1.0
[/CIF]
.