The structure described by NiTe(PO4)2 crystallizes in the triclinic P1 space group. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(14), one O(18), one O(20), one O(25), one O(28), and one O(6) atom to form distorted NiO6 octahedra that share corners with two equivalent Te(1)O6 pentagonal pyramids, corners with two equivalent Te(2)O6 pentagonal pyramids,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. In the second Ni site, Ni(2) is bonded to one O(16), one O(22), one O(24), one O(29), one O(32), and one O(8) atom to form distorted NiO6 octahedra that share corners with two equivalent Te(3)O6 pentagonal pyramids, corners with two equivalent Te(4)O6 pentagonal pyramids,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. In the third Ni site, Ni(3) is bonded to one O(13), one O(17), one O(19), one O(26), one O(27), and one O(5) atom to form distorted NiO6 octahedra that share corners with two equivalent Te(1)O6 pentagonal pyramids, corners with two equivalent Te(2)O6 pentagonal pyramids,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  an edgeedge with one P(1)O4 tetrahedra. In the fourth Ni site, Ni(4) is bonded to one O(15), one O(21), one O(23), one O(30), one O(31), and one O(7) atom to form distorted NiO6 octahedra that share corners with two equivalent Te(3)O6 pentagonal pyramids, corners with two equivalent Te(4)O6 pentagonal pyramids,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(17), one O(19), one O(3), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Te(1)O6 pentagonal pyramid,  a cornercorner with one Te(2)O6 pentagonal pyramid,  a cornercorner with one Te(3)O6 pentagonal pyramid, and  an edgeedge with one Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second P site, P(2) is bonded to one O(18), one O(20), one O(4), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Te(1)O6 pentagonal pyramid,  a cornercorner with one Te(2)O6 pentagonal pyramid,  a cornercorner with one Te(4)O6 pentagonal pyramid, and  an edgeedge with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the third P site, P(3) is bonded to one O(1), one O(21), one O(23), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Te(1)O6 pentagonal pyramid,  a cornercorner with one Te(3)O6 pentagonal pyramid,  a cornercorner with one Te(4)O6 pentagonal pyramid, and  an edgeedge with one Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the fourth P site, P(4) is bonded to one O(2), one O(22), one O(24), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Te(2)O6 pentagonal pyramid,  a cornercorner with one Te(3)O6 pentagonal pyramid,  a cornercorner with one Te(4)O6 pentagonal pyramid, and  an edgeedge with one Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the fifth P site, P(5) is bonded to one O(15); one O(25); one O(27); and one O(9,11) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Te(1)O6 pentagonal pyramid, and  an edgeedge with one Te(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-56°. In the sixth P site, P(6) is bonded to one O(10,12); one O(16); one O(26); and one O(28) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Te(2)O6 pentagonal pyramid, and  an edgeedge with one Te(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 36-56°. In the seventh P site, P(7) is bonded to one O(13); one O(29); one O(31); and one O(9,11) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Te(3)O6 pentagonal pyramid, and  an edgeedge with one Te(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-56°. In the eighth P site, P(8) is bonded to one O(10,12); one O(14); one O(30); and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Te(4)O6 pentagonal pyramid, and  an edgeedge with one Te(4)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-56°. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1); one O(18); one O(19); one O(25); one O(27); and one O(9,11) atom to form distorted TeO6 pentagonal pyramids that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-51°. In the second Te site, Te(2) is bonded to one O(10,12); one O(17); one O(2); one O(20); one O(26); and one O(28) atom to form distorted TeO6 pentagonal pyramids that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-51°. In the third Te site, Te(3) is bonded to one O(21); one O(24); one O(29); one O(3); one O(31); and one O(9,11) atom to form distorted TeO6 pentagonal pyramids that share corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-51°. In the fourth Te site, Te(4) is bonded to one O(10,12); one O(22); one O(23); one O(30); one O(32); and one O(4) atom to form distorted TeO6 pentagonal pyramids that share corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-52°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(3) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(4) and one Te(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one Te(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one Te(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ni(3) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ni(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Ni(4) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ni(2) and one P(4) atom. In the ninth O site, O(9,11) is bonded in a distorted bent 150 degrees geometry to one P(5) and one Te(1) atom. In the tenth O site, O(10,12) is bonded in a distorted bent 150 degrees geometry to one P(6) and one Te(2) atom. In the eleventh O site, O(13) is bonded in a bent 150 degrees geometry to one Ni(3) and one P(7) atom. In the twelfth O site, O(14) is bonded in a bent 150 degrees geometry to one Ni(1) and one P(8) atom. In the thirteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Ni(4) and one P(5) atom. In the fourteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Ni(2) and one P(6) atom. In the fifteenth O site, O(17) is bonded in a 3-coordinate geometry to one Ni(3), one P(1), and one Te(2) atom. In the sixteenth O site, O(18) is bonded in a 3-coordinate geometry to one Ni(1), one P(2), and one Te(1) atom. In the seventeenth O site, O(19) is bonded in a 3-coordinate geometry to one Ni(3), one P(1), and one Te(1) atom. In the eighteenth O site, O(20) is bonded in a 3-coordinate geometry to one Ni(1), one P(2), and one Te(2) atom. In the nineteenth O site, O(21) is bonded in a 3-coordinate geometry to one Ni(4), one P(3), and one Te(3) atom. In the twentieth O site, O(22) is bonded in a 3-coordinate geometry to one Ni(2), one P(4), and one Te(4) atom. In the twenty-first O site, O(23) is bonded in a 3-coordinate geometry to one Ni(4), one P(3), and one Te(4) atom. In the twenty-second O site, O(24) is bonded in a 3-coordinate geometry to one Ni(2), one P(4), and one Te(3) atom. In the twenty-third O site, O(25) is bonded in a 3-coordinate geometry to one Ni(1), one P(5), and one Te(1) atom. In the twenty-fourth O site, O(26) is bonded in a 3-coordinate geometry to one Ni(3), one P(6), and one Te(2) atom. In the twenty-fifth O site, O(27) is bonded in a 3-coordinate geometry to one Ni(3), one P(5), and one Te(1) atom. In the twenty-sixth O site, O(28) is bonded in a 3-coordinate geometry to one Ni(1), one P(6), and one Te(2) atom. In the twenty-seventh O site, O(29) is bonded in a 3-coordinate geometry to one Ni(2), one P(7), and one Te(3) atom. In the twenty-eighth O site, O(30) is bonded in a 3-coordinate geometry to one Ni(4), one P(8), and one Te(4) atom. In the twenty-ninth O site, O(31) is bonded in a 3-coordinate geometry to one Ni(4), one P(7), and one Te(3) atom. In the thirtieth O site, O(32) is bonded in a 3-coordinate geometry to one Ni(2), one P(8), and one Te(4) atom. is represented by the CIF file [CIF]
data_NiTe(PO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.797
_cell_length_b   6.537
_cell_length_c   9.865
_cell_angle_alpha   89.916
_cell_angle_beta   84.109
_cell_angle_gamma   89.829
_symmetry_Int_Tables_number   1
_cell_volume   307.702
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.931  0.250  0.734  1.0
  Ni  Ni1  1  0.070  0.748  0.266  1.0
  O  O2  1  0.761  0.751  0.936  1.0
  O  O3  1  0.239  0.248  0.064  1.0
  O  O4  1  0.664  0.250  0.899  1.0
  O  O5  1  0.336  0.750  0.101  1.0
  O  O6  1  0.205  0.751  0.625  1.0
  O  O7  1  0.795  0.249  0.375  1.0
  O  O8  1  0.136  0.250  0.552  1.0
  O  O9  1  0.864  0.750  0.448  1.0
  O  O10  1  0.220  0.065  0.834  1.0
  O  O11  1  0.218  0.434  0.834  1.0
  O  O12  1  0.783  0.567  0.166  1.0
  O  O13  1  0.780  0.935  0.166  1.0
  O  O14  1  0.723  0.933  0.677  1.0
  O  O15  1  0.725  0.567  0.677  1.0
  O  O16  1  0.278  0.068  0.323  1.0
  O  O17  1  0.275  0.434  0.323  1.0
  P  P18  1  0.344  0.250  0.910  1.0
  P  P19  1  0.656  0.750  0.090  1.0
  P  P20  1  0.893  0.750  0.598  1.0
  P  P21  1  0.107  0.250  0.402  1.0
  Te  Te22  1  0.427  0.751  0.799  1.0
  Te  Te23  1  0.573  0.249  0.201  1.0
[/CIF]
.
The structure described by NiTe(PO4)2 crystallizes in the triclinic P1 space group. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(14), one O(18), one O(20), one O(25), one O(28), and one O(6) atom to form distorted NiO6 octahedra that share corners with two equivalent Te(1)O6 pentagonal pyramids, corners with two equivalent Te(2)O6 pentagonal pyramids,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. In the second Ni site, Ni(2) is bonded to one O(16), one O(22), one O(24), one O(29), one O(32), and one O(8) atom to form distorted NiO6 octahedra that share corners with two equivalent Te(3)O6 pentagonal pyramids, corners with two equivalent Te(4)O6 pentagonal pyramids,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. In the third Ni site, Ni(3) is bonded to one O(13), one O(17), one O(19), one O(26), one O(27), and one O(5) atom to form distorted NiO6 octahedra that share corners with two equivalent Te(1)O6 pentagonal pyramids, corners with two equivalent Te(2)O6 pentagonal pyramids,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  an edgeedge with one P(1)O4 tetrahedra. In the fourth Ni site, Ni(4) is bonded to one O(15), one O(21), one O(23), one O(30), one O(31), and one O(7) atom to form distorted NiO6 octahedra that share corners with two equivalent Te(3)O6 pentagonal pyramids, corners with two equivalent Te(4)O6 pentagonal pyramids,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(17), one O(19), one O(3), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Te(1)O6 pentagonal pyramid,  a cornercorner with one Te(2)O6 pentagonal pyramid,  a cornercorner with one Te(3)O6 pentagonal pyramid, and  an edgeedge with one Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second P site, P(2) is bonded to one O(18), one O(20), one O(4), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Te(1)O6 pentagonal pyramid,  a cornercorner with one Te(2)O6 pentagonal pyramid,  a cornercorner with one Te(4)O6 pentagonal pyramid, and  an edgeedge with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the third P site, P(3) is bonded to one O(1), one O(21), one O(23), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Te(1)O6 pentagonal pyramid,  a cornercorner with one Te(3)O6 pentagonal pyramid,  a cornercorner with one Te(4)O6 pentagonal pyramid, and  an edgeedge with one Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the fourth P site, P(4) is bonded to one O(2), one O(22), one O(24), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Te(2)O6 pentagonal pyramid,  a cornercorner with one Te(3)O6 pentagonal pyramid,  a cornercorner with one Te(4)O6 pentagonal pyramid, and  an edgeedge with one Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the fifth P site, P(5) is bonded to one O(15); one O(25); one O(27); and one O(9,11) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Te(1)O6 pentagonal pyramid, and  an edgeedge with one Te(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-56°. In the sixth P site, P(6) is bonded to one O(10,12); one O(16); one O(26); and one O(28) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Te(2)O6 pentagonal pyramid, and  an edgeedge with one Te(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 36-56°. In the seventh P site, P(7) is bonded to one O(13); one O(29); one O(31); and one O(9,11) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Te(3)O6 pentagonal pyramid, and  an edgeedge with one Te(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-56°. In the eighth P site, P(8) is bonded to one O(10,12); one O(14); one O(30); and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Te(4)O6 pentagonal pyramid, and  an edgeedge with one Te(4)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-56°. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1); one O(18); one O(19); one O(25); one O(27); and one O(9,11) atom to form distorted TeO6 pentagonal pyramids that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-51°. In the second Te site, Te(2) is bonded to one O(10,12); one O(17); one O(2); one O(20); one O(26); and one O(28) atom to form distorted TeO6 pentagonal pyramids that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-51°. In the third Te site, Te(3) is bonded to one O(21); one O(24); one O(29); one O(3); one O(31); and one O(9,11) atom to form distorted TeO6 pentagonal pyramids that share corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-51°. In the fourth Te site, Te(4) is bonded to one O(10,12); one O(22); one O(23); one O(30); one O(32); and one O(4) atom to form distorted TeO6 pentagonal pyramids that share corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-52°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(3) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(4) and one Te(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one Te(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one Te(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ni(3) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ni(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Ni(4) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ni(2) and one P(4) atom. In the ninth O site, O(9,11) is bonded in a distorted bent 150 degrees geometry to one P(5) and one Te(1) atom. In the tenth O site, O(10,12) is bonded in a distorted bent 150 degrees geometry to one P(6) and one Te(2) atom. In the eleventh O site, O(13) is bonded in a bent 150 degrees geometry to one Ni(3) and one P(7) atom. In the twelfth O site, O(14) is bonded in a bent 150 degrees geometry to one Ni(1) and one P(8) atom. In the thirteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Ni(4) and one P(5) atom. In the fourteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Ni(2) and one P(6) atom. In the fifteenth O site, O(17) is bonded in a 3-coordinate geometry to one Ni(3), one P(1), and one Te(2) atom. In the sixteenth O site, O(18) is bonded in a 3-coordinate geometry to one Ni(1), one P(2), and one Te(1) atom. In the seventeenth O site, O(19) is bonded in a 3-coordinate geometry to one Ni(3), one P(1), and one Te(1) atom. In the eighteenth O site, O(20) is bonded in a 3-coordinate geometry to one Ni(1), one P(2), and one Te(2) atom. In the nineteenth O site, O(21) is bonded in a 3-coordinate geometry to one Ni(4), one P(3), and one Te(3) atom. In the twentieth O site, O(22) is bonded in a 3-coordinate geometry to one Ni(2), one P(4), and one Te(4) atom. In the twenty-first O site, O(23) is bonded in a 3-coordinate geometry to one Ni(4), one P(3), and one Te(4) atom. In the twenty-second O site, O(24) is bonded in a 3-coordinate geometry to one Ni(2), one P(4), and one Te(3) atom. In the twenty-third O site, O(25) is bonded in a 3-coordinate geometry to one Ni(1), one P(5), and one Te(1) atom. In the twenty-fourth O site, O(26) is bonded in a 3-coordinate geometry to one Ni(3), one P(6), and one Te(2) atom. In the twenty-fifth O site, O(27) is bonded in a 3-coordinate geometry to one Ni(3), one P(5), and one Te(1) atom. In the twenty-sixth O site, O(28) is bonded in a 3-coordinate geometry to one Ni(1), one P(6), and one Te(2) atom. In the twenty-seventh O site, O(29) is bonded in a 3-coordinate geometry to one Ni(2), one P(7), and one Te(3) atom. In the twenty-eighth O site, O(30) is bonded in a 3-coordinate geometry to one Ni(4), one P(8), and one Te(4) atom. In the twenty-ninth O site, O(31) is bonded in a 3-coordinate geometry to one Ni(4), one P(7), and one Te(3) atom. In the thirtieth O site, O(32) is bonded in a 3-coordinate geometry to one Ni(2), one P(8), and one Te(4) atom. is represented by the CIF file [CIF]
data_NiTe(PO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.797
_cell_length_b   6.537
_cell_length_c   9.865
_cell_angle_alpha   89.916
_cell_angle_beta   84.109
_cell_angle_gamma   89.829
_symmetry_Int_Tables_number   1
_cell_volume   307.702
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.931  0.250  0.734  1.0
  Ni  Ni1  1  0.070  0.748  0.266  1.0
  O  O2  1  0.761  0.751  0.936  1.0
  O  O3  1  0.239  0.248  0.064  1.0
  O  O4  1  0.664  0.250  0.899  1.0
  O  O5  1  0.336  0.750  0.101  1.0
  O  O6  1  0.205  0.751  0.625  1.0
  O  O7  1  0.795  0.249  0.375  1.0
  O  O8  1  0.136  0.250  0.552  1.0
  O  O9  1  0.864  0.750  0.448  1.0
  O  O10  1  0.220  0.065  0.834  1.0
  O  O11  1  0.218  0.434  0.834  1.0
  O  O12  1  0.783  0.567  0.166  1.0
  O  O13  1  0.780  0.935  0.166  1.0
  O  O14  1  0.723  0.933  0.677  1.0
  O  O15  1  0.725  0.567  0.677  1.0
  O  O16  1  0.278  0.068  0.323  1.0
  O  O17  1  0.275  0.434  0.323  1.0
  P  P18  1  0.344  0.250  0.910  1.0
  P  P19  1  0.656  0.750  0.090  1.0
  P  P20  1  0.893  0.750  0.598  1.0
  P  P21  1  0.107  0.250  0.402  1.0
  Te  Te22  1  0.427  0.751  0.799  1.0
  Te  Te23  1  0.573  0.249  0.201  1.0
[/CIF]
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