The compound described by LiMn(PO3)4 crystallizes in the triclinic P1 space group. Li(1) is bonded to one O(1), one O(3), one O(4), one O(6), and one O(8) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. Mn(1) is bonded in a rectangular see-saw-like geometry to one O(11), one O(12), one O(4), and one O(8) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. In the second P site, P(2) is bonded to one O(11), one O(2), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(12), one O(2), one O(3), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. In the fourth P site, P(4) is bonded to one O(1), one O(10), one O(4), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent Li(1)O5 trigonal bipyramids. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one P(4) atom. In the second O site, O(2) is bonded in a linear geometry to one P(2) and one P(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one P(1) atom. In the tenth O site, O(10) is bonded in a linear geometry to one P(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. is represented by the CIF file [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.940
_cell_length_b   7.109
_cell_length_c   7.531
_cell_angle_alpha   113.538
_cell_angle_beta   83.000
_cell_angle_gamma   110.097
_symmetry_Int_Tables_number   1
_cell_volume   227.672
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.040  0.725  0.548  1.0
  Mn  Mn1  1  0.999  0.005  0.004  1.0
  P  P2  1  0.562  0.199  0.792  1.0
  P  P3  1  0.439  0.801  0.206  1.0
  P  P4  1  0.565  0.398  0.214  1.0
  P  P5  1  0.435  0.603  0.785  1.0
  O  O6  1  0.246  0.564  0.628  1.0
  O  O7  1  0.536  0.611  0.206  1.0
  O  O8  1  0.759  0.457  0.375  1.0
  O  O9  1  0.744  0.765  0.802  1.0
  O  O10  1  0.718  0.306  0.007  1.0
  O  O11  1  0.228  0.859  0.357  1.0
  O  O12  1  0.281  0.696  0.993  1.0
  O  O13  1  0.275  0.025  0.805  1.0
  O  O14  1  0.767  0.127  0.645  1.0
  O  O15  1  0.462  0.388  0.787  1.0
  O  O16  1  0.716  0.979  0.196  1.0
  O  O17  1  0.263  0.234  0.199  1.0
[/CIF]
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The compound described by LiMn(PO3)4 crystallizes in the triclinic P1 space group. Li(1) is bonded to one O(1), one O(3), one O(4), one O(6), and one O(8) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. Mn(1) is bonded in a rectangular see-saw-like geometry to one O(11), one O(12), one O(4), and one O(8) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. In the second P site, P(2) is bonded to one O(11), one O(2), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(12), one O(2), one O(3), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. In the fourth P site, P(4) is bonded to one O(1), one O(10), one O(4), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent Li(1)O5 trigonal bipyramids. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one P(4) atom. In the second O site, O(2) is bonded in a linear geometry to one P(2) and one P(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one P(1) atom. In the tenth O site, O(10) is bonded in a linear geometry to one P(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. is represented by the CIF file [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.940
_cell_length_b   7.109
_cell_length_c   7.531
_cell_angle_alpha   113.538
_cell_angle_beta   83.000
_cell_angle_gamma   110.097
_symmetry_Int_Tables_number   1
_cell_volume   227.672
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.040  0.725  0.548  1.0
  Mn  Mn1  1  0.999  0.005  0.004  1.0
  P  P2  1  0.562  0.199  0.792  1.0
  P  P3  1  0.439  0.801  0.206  1.0
  P  P4  1  0.565  0.398  0.214  1.0
  P  P5  1  0.435  0.603  0.785  1.0
  O  O6  1  0.246  0.564  0.628  1.0
  O  O7  1  0.536  0.611  0.206  1.0
  O  O8  1  0.759  0.457  0.375  1.0
  O  O9  1  0.744  0.765  0.802  1.0
  O  O10  1  0.718  0.306  0.007  1.0
  O  O11  1  0.228  0.859  0.357  1.0
  O  O12  1  0.281  0.696  0.993  1.0
  O  O13  1  0.275  0.025  0.805  1.0
  O  O14  1  0.767  0.127  0.645  1.0
  O  O15  1  0.462  0.388  0.787  1.0
  O  O16  1  0.716  0.979  0.196  1.0
  O  O17  1  0.263  0.234  0.199  1.0
[/CIF]
.