The structure described by Li2UO4 is Spinel-like structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent Li(2)O6 octahedra, corners with four equivalent U(1)O6 octahedra,  an edgeedge with one U(1)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-69°. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with four equivalent U(1)O6 octahedra, corners with two equivalent Li(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent U(1)O6 octahedra, and edges with two equivalent Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-53°. U(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form UO6 octahedra that share corners with four equivalent Li(2)O6 octahedra, corners with four equivalent U(1)O6 octahedra, corners with four equivalent Li(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-53°. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Li(2), and one U(1) atom to form corner-sharing OLi3U tetrahedra. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent Li(2), and one U(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), and two equivalent U(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2UO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.095
_cell_length_b   6.045
_cell_length_c   10.498
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   323.345
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.542  0.750  0.926  1.0
  Li  Li1  1  0.042  0.250  0.574  1.0
  Li  Li2  1  0.458  0.250  0.074  1.0
  Li  Li3  1  0.958  0.750  0.426  1.0
  Li  Li4  1  0.500  0.000  0.500  1.0
  Li  Li5  1  0.000  0.000  0.000  1.0
  Li  Li6  1  0.500  0.500  0.500  1.0
  Li  Li7  1  0.000  0.500  0.000  1.0
  U  U8  1  0.987  0.750  0.738  1.0
  U  U9  1  0.487  0.250  0.762  1.0
  U  U10  1  0.013  0.250  0.262  1.0
  U  U11  1  0.513  0.750  0.238  1.0
  O  O12  1  0.178  0.750  0.897  1.0
  O  O13  1  0.222  0.250  0.414  1.0
  O  O14  1  0.278  0.250  0.914  1.0
  O  O15  1  0.722  0.750  0.086  1.0
  O  O16  1  0.267  0.014  0.164  1.0
  O  O17  1  0.767  0.986  0.336  1.0
  O  O18  1  0.733  0.514  0.836  1.0
  O  O19  1  0.233  0.486  0.664  1.0
  O  O20  1  0.733  0.986  0.836  1.0
  O  O21  1  0.233  0.014  0.664  1.0
  O  O22  1  0.267  0.486  0.164  1.0
  O  O23  1  0.767  0.514  0.336  1.0
  O  O24  1  0.822  0.250  0.103  1.0
  O  O25  1  0.322  0.750  0.397  1.0
  O  O26  1  0.778  0.750  0.586  1.0
  O  O27  1  0.678  0.250  0.603  1.0
[/CIF]
.
The structure described by Li2UO4 is Spinel-like structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent Li(2)O6 octahedra, corners with four equivalent U(1)O6 octahedra,  an edgeedge with one U(1)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-69°. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with four equivalent U(1)O6 octahedra, corners with two equivalent Li(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent U(1)O6 octahedra, and edges with two equivalent Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-53°. U(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form UO6 octahedra that share corners with four equivalent Li(2)O6 octahedra, corners with four equivalent U(1)O6 octahedra, corners with four equivalent Li(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-53°. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Li(2), and one U(1) atom to form corner-sharing OLi3U tetrahedra. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent Li(2), and one U(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), and two equivalent U(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2UO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.095
_cell_length_b   6.045
_cell_length_c   10.498
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   323.345
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.542  0.750  0.926  1.0
  Li  Li1  1  0.042  0.250  0.574  1.0
  Li  Li2  1  0.458  0.250  0.074  1.0
  Li  Li3  1  0.958  0.750  0.426  1.0
  Li  Li4  1  0.500  0.000  0.500  1.0
  Li  Li5  1  0.000  0.000  0.000  1.0
  Li  Li6  1  0.500  0.500  0.500  1.0
  Li  Li7  1  0.000  0.500  0.000  1.0
  U  U8  1  0.987  0.750  0.738  1.0
  U  U9  1  0.487  0.250  0.762  1.0
  U  U10  1  0.013  0.250  0.262  1.0
  U  U11  1  0.513  0.750  0.238  1.0
  O  O12  1  0.178  0.750  0.897  1.0
  O  O13  1  0.222  0.250  0.414  1.0
  O  O14  1  0.278  0.250  0.914  1.0
  O  O15  1  0.722  0.750  0.086  1.0
  O  O16  1  0.267  0.014  0.164  1.0
  O  O17  1  0.767  0.986  0.336  1.0
  O  O18  1  0.733  0.514  0.836  1.0
  O  O19  1  0.233  0.486  0.664  1.0
  O  O20  1  0.733  0.986  0.836  1.0
  O  O21  1  0.233  0.014  0.664  1.0
  O  O22  1  0.267  0.486  0.164  1.0
  O  O23  1  0.767  0.514  0.336  1.0
  O  O24  1  0.822  0.250  0.103  1.0
  O  O25  1  0.322  0.750  0.397  1.0
  O  O26  1  0.778  0.750  0.586  1.0
  O  O27  1  0.678  0.250  0.603  1.0
[/CIF]
.