The material described by HoV2O2 crystallizes in the tetragonal I4_1/amd space group. Ho(1) is bonded in a distorted hexagonal planar geometry to six equivalent O(1) atoms. V(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded to three equivalent Ho(1) and one V(1) atom to form a mixture of distorted edge and corner-sharing OHo3V tetrahedra. is represented by the CIF file [CIF]
data_HoV2O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.669
_cell_length_b   7.669
_cell_length_c   7.669
_cell_angle_alpha   114.329
_cell_angle_beta   114.329
_cell_angle_gamma   100.140
_symmetry_Int_Tables_number   1
_cell_volume   340.445
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.875  0.125  0.250  1.0
  Ho  Ho1  1  0.875  0.625  0.750  1.0
  Ho  Ho2  1  0.375  0.125  0.250  1.0
  Ho  Ho3  1  0.875  0.125  0.750  1.0
  V  V4  1  0.510  0.303  0.793  1.0
  V  V5  1  0.510  0.717  0.207  1.0
  V  V6  1  0.467  0.760  0.707  1.0
  V  V7  1  0.240  0.533  0.293  1.0
  V  V8  1  0.240  0.947  0.707  1.0
  V  V9  1  0.053  0.760  0.293  1.0
  V  V10  1  0.283  0.490  0.793  1.0
  V  V11  1  0.697  0.490  0.207  1.0
  O  O12  1  0.653  0.309  0.657  1.0
  O  O13  1  0.653  0.996  0.343  1.0
  O  O14  1  0.746  0.903  0.843  1.0
  O  O15  1  0.097  0.254  0.157  1.0
  O  O16  1  0.097  0.941  0.843  1.0
  O  O17  1  0.059  0.903  0.157  1.0
  O  O18  1  0.004  0.347  0.657  1.0
  O  O19  1  0.691  0.347  0.343  1.0
[/CIF]
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The material described by HoV2O2 crystallizes in the tetragonal I4_1/amd space group. Ho(1) is bonded in a distorted hexagonal planar geometry to six equivalent O(1) atoms. V(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded to three equivalent Ho(1) and one V(1) atom to form a mixture of distorted edge and corner-sharing OHo3V tetrahedra. is represented by the CIF file [CIF]
data_HoV2O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.669
_cell_length_b   7.669
_cell_length_c   7.669
_cell_angle_alpha   114.329
_cell_angle_beta   114.329
_cell_angle_gamma   100.140
_symmetry_Int_Tables_number   1
_cell_volume   340.445
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.875  0.125  0.250  1.0
  Ho  Ho1  1  0.875  0.625  0.750  1.0
  Ho  Ho2  1  0.375  0.125  0.250  1.0
  Ho  Ho3  1  0.875  0.125  0.750  1.0
  V  V4  1  0.510  0.303  0.793  1.0
  V  V5  1  0.510  0.717  0.207  1.0
  V  V6  1  0.467  0.760  0.707  1.0
  V  V7  1  0.240  0.533  0.293  1.0
  V  V8  1  0.240  0.947  0.707  1.0
  V  V9  1  0.053  0.760  0.293  1.0
  V  V10  1  0.283  0.490  0.793  1.0
  V  V11  1  0.697  0.490  0.207  1.0
  O  O12  1  0.653  0.309  0.657  1.0
  O  O13  1  0.653  0.996  0.343  1.0
  O  O14  1  0.746  0.903  0.843  1.0
  O  O15  1  0.097  0.254  0.157  1.0
  O  O16  1  0.097  0.941  0.843  1.0
  O  O17  1  0.059  0.903  0.157  1.0
  O  O18  1  0.004  0.347  0.657  1.0
  O  O19  1  0.691  0.347  0.343  1.0
[/CIF]
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