The crystal structure described by P2N2S(OCl3)2 is alpha U structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P2N2S(OCl3)2 clusters. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one Cl(1), one Cl(2), and one Cl(3) atom to form PNCl3 tetrahedra that share  a cornercorner with one S(1)N2O2 tetrahedra. In the second P site, P(2) is bonded to one N(2), one Cl(4), one Cl(5), and one Cl(6) atom to form PNCl3 tetrahedra that share  a cornercorner with one S(1)N2O2 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one S(1) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one P(2) and one S(1) atom. S(1) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form SN2O2 tetrahedra that share  a cornercorner with one P(1)NCl3 tetrahedra and  a cornercorner with one P(2)NCl3 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one P(2) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the sixth Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2SN2(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.025
_cell_length_b   12.548
_cell_length_c   12.926
_cell_angle_alpha   84.437
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1295.364
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.546  0.366  0.672  1.0
  P  P1  1  0.046  0.634  0.828  1.0
  P  P2  1  0.454  0.634  0.328  1.0
  P  P3  1  0.954  0.366  0.172  1.0
  P  P4  1  0.160  0.132  0.817  1.0
  P  P5  1  0.660  0.868  0.683  1.0
  P  P6  1  0.840  0.868  0.183  1.0
  P  P7  1  0.340  0.132  0.317  1.0
  S  S8  1  0.454  0.254  0.871  1.0
  S  S9  1  0.954  0.746  0.629  1.0
  S  S10  1  0.546  0.746  0.129  1.0
  S  S11  1  0.046  0.254  0.371  1.0
  N  N12  1  0.550  0.272  0.760  1.0
  N  N13  1  0.050  0.728  0.740  1.0
  N  N14  1  0.450  0.728  0.240  1.0
  N  N15  1  0.950  0.272  0.260  1.0
  N  N16  1  0.260  0.232  0.844  1.0
  N  N17  1  0.760  0.768  0.656  1.0
  N  N18  1  0.740  0.768  0.156  1.0
  N  N19  1  0.240  0.232  0.344  1.0
  Cl  Cl20  1  0.561  0.516  0.713  1.0
  Cl  Cl21  1  0.061  0.484  0.787  1.0
  Cl  Cl22  1  0.439  0.484  0.287  1.0
  Cl  Cl23  1  0.939  0.516  0.213  1.0
  Cl  Cl24  1  0.349  0.371  0.577  1.0
  Cl  Cl25  1  0.849  0.629  0.923  1.0
  Cl  Cl26  1  0.651  0.629  0.423  1.0
  Cl  Cl27  1  0.151  0.371  0.077  1.0
  Cl  Cl28  1  0.741  0.351  0.580  1.0
  Cl  Cl29  1  0.241  0.649  0.920  1.0
  Cl  Cl30  1  0.259  0.649  0.420  1.0
  Cl  Cl31  1  0.759  0.351  0.080  1.0
  Cl  Cl32  1  0.209  0.992  0.900  1.0
  Cl  Cl33  1  0.709  0.008  0.600  1.0
  Cl  Cl34  1  0.791  0.008  0.100  1.0
  Cl  Cl35  1  0.291  0.992  0.400  1.0
  Cl  Cl36  1  0.169  0.097  0.669  1.0
  Cl  Cl37  1  0.669  0.903  0.831  1.0
  Cl  Cl38  1  0.831  0.903  0.331  1.0
  Cl  Cl39  1  0.331  0.097  0.169  1.0
  Cl  Cl40  1  0.920  0.161  0.841  1.0
  Cl  Cl41  1  0.420  0.839  0.659  1.0
  Cl  Cl42  1  0.080  0.839  0.159  1.0
  Cl  Cl43  1  0.580  0.161  0.341  1.0
  O  O44  1  0.529  0.159  0.925  1.0
  O  O45  1  0.029  0.841  0.575  1.0
  O  O46  1  0.471  0.841  0.075  1.0
  O  O47  1  0.971  0.159  0.425  1.0
  O  O48  1  0.455  0.351  0.923  1.0
  O  O49  1  0.955  0.649  0.577  1.0
  O  O50  1  0.545  0.649  0.077  1.0
  O  O51  1  0.045  0.351  0.423  1.0
[/CIF]
.
The crystal structure described by P2N2S(OCl3)2 is alpha U structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P2N2S(OCl3)2 clusters. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one Cl(1), one Cl(2), and one Cl(3) atom to form PNCl3 tetrahedra that share  a cornercorner with one S(1)N2O2 tetrahedra. In the second P site, P(2) is bonded to one N(2), one Cl(4), one Cl(5), and one Cl(6) atom to form PNCl3 tetrahedra that share  a cornercorner with one S(1)N2O2 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one S(1) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one P(2) and one S(1) atom. S(1) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form SN2O2 tetrahedra that share  a cornercorner with one P(1)NCl3 tetrahedra and  a cornercorner with one P(2)NCl3 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one P(2) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the sixth Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2SN2(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.025
_cell_length_b   12.548
_cell_length_c   12.926
_cell_angle_alpha   84.437
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1295.364
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.546  0.366  0.672  1.0
  P  P1  1  0.046  0.634  0.828  1.0
  P  P2  1  0.454  0.634  0.328  1.0
  P  P3  1  0.954  0.366  0.172  1.0
  P  P4  1  0.160  0.132  0.817  1.0
  P  P5  1  0.660  0.868  0.683  1.0
  P  P6  1  0.840  0.868  0.183  1.0
  P  P7  1  0.340  0.132  0.317  1.0
  S  S8  1  0.454  0.254  0.871  1.0
  S  S9  1  0.954  0.746  0.629  1.0
  S  S10  1  0.546  0.746  0.129  1.0
  S  S11  1  0.046  0.254  0.371  1.0
  N  N12  1  0.550  0.272  0.760  1.0
  N  N13  1  0.050  0.728  0.740  1.0
  N  N14  1  0.450  0.728  0.240  1.0
  N  N15  1  0.950  0.272  0.260  1.0
  N  N16  1  0.260  0.232  0.844  1.0
  N  N17  1  0.760  0.768  0.656  1.0
  N  N18  1  0.740  0.768  0.156  1.0
  N  N19  1  0.240  0.232  0.344  1.0
  Cl  Cl20  1  0.561  0.516  0.713  1.0
  Cl  Cl21  1  0.061  0.484  0.787  1.0
  Cl  Cl22  1  0.439  0.484  0.287  1.0
  Cl  Cl23  1  0.939  0.516  0.213  1.0
  Cl  Cl24  1  0.349  0.371  0.577  1.0
  Cl  Cl25  1  0.849  0.629  0.923  1.0
  Cl  Cl26  1  0.651  0.629  0.423  1.0
  Cl  Cl27  1  0.151  0.371  0.077  1.0
  Cl  Cl28  1  0.741  0.351  0.580  1.0
  Cl  Cl29  1  0.241  0.649  0.920  1.0
  Cl  Cl30  1  0.259  0.649  0.420  1.0
  Cl  Cl31  1  0.759  0.351  0.080  1.0
  Cl  Cl32  1  0.209  0.992  0.900  1.0
  Cl  Cl33  1  0.709  0.008  0.600  1.0
  Cl  Cl34  1  0.791  0.008  0.100  1.0
  Cl  Cl35  1  0.291  0.992  0.400  1.0
  Cl  Cl36  1  0.169  0.097  0.669  1.0
  Cl  Cl37  1  0.669  0.903  0.831  1.0
  Cl  Cl38  1  0.831  0.903  0.331  1.0
  Cl  Cl39  1  0.331  0.097  0.169  1.0
  Cl  Cl40  1  0.920  0.161  0.841  1.0
  Cl  Cl41  1  0.420  0.839  0.659  1.0
  Cl  Cl42  1  0.080  0.839  0.159  1.0
  Cl  Cl43  1  0.580  0.161  0.341  1.0
  O  O44  1  0.529  0.159  0.925  1.0
  O  O45  1  0.029  0.841  0.575  1.0
  O  O46  1  0.471  0.841  0.075  1.0
  O  O47  1  0.971  0.159  0.425  1.0
  O  O48  1  0.455  0.351  0.923  1.0
  O  O49  1  0.955  0.649  0.577  1.0
  O  O50  1  0.545  0.649  0.077  1.0
  O  O51  1  0.045  0.351  0.423  1.0
[/CIF]
.