The material structure described by V4N2Te3 crystallizes in the orthorhombic Pnma space group. There are three inequivalent V sites. In the first V site, V(1) is bonded in a distorted L-shaped geometry to two equivalent N(1), one Te(1), and four equivalent Te(2) atoms. In the second V site, V(2) is bonded in a distorted L-shaped geometry to two equivalent N(1) and two equivalent Te(1) atoms. In the third V site, V(3) is bonded in a distorted L-shaped geometry to two equivalent N(1), one Te(1), and three equivalent Te(2) atoms. N(1) is bonded in a see-saw-like geometry to one V(1), one V(2), and two equivalent V(3) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one V(1), two equivalent V(2), and two equivalent V(3) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to two equivalent V(1) and three equivalent V(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V4Te3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.526
_cell_length_b   10.755
_cell_length_c   9.312
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   653.559
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.607  0.250  0.914  1.0
  V  V1  1  0.107  0.250  0.586  1.0
  V  V2  1  0.393  0.750  0.086  1.0
  V  V3  1  0.893  0.750  0.414  1.0
  V  V4  1  0.753  0.250  0.437  1.0
  V  V5  1  0.253  0.250  0.063  1.0
  V  V6  1  0.247  0.750  0.563  1.0
  V  V7  1  0.747  0.750  0.937  1.0
  V  V8  1  0.679  0.475  0.051  1.0
  V  V9  1  0.179  0.025  0.449  1.0
  V  V10  1  0.321  0.975  0.949  1.0
  V  V11  1  0.821  0.525  0.551  1.0
  V  V12  1  0.321  0.525  0.949  1.0
  V  V13  1  0.821  0.975  0.551  1.0
  V  V14  1  0.679  0.025  0.051  1.0
  V  V15  1  0.179  0.475  0.449  1.0
  Te  Te16  1  0.852  0.250  0.158  1.0
  Te  Te17  1  0.352  0.250  0.342  1.0
  Te  Te18  1  0.148  0.750  0.842  1.0
  Te  Te19  1  0.648  0.750  0.658  1.0
  Te  Te20  1  0.556  0.575  0.325  1.0
  Te  Te21  1  0.056  0.925  0.175  1.0
  Te  Te22  1  0.444  0.075  0.675  1.0
  Te  Te23  1  0.944  0.425  0.825  1.0
  Te  Te24  1  0.444  0.425  0.675  1.0
  Te  Te25  1  0.944  0.075  0.825  1.0
  Te  Te26  1  0.556  0.925  0.325  1.0
  Te  Te27  1  0.056  0.575  0.175  1.0
  N  N28  1  0.563  0.625  0.974  1.0
  N  N29  1  0.063  0.875  0.526  1.0
  N  N30  1  0.437  0.125  0.026  1.0
  N  N31  1  0.937  0.375  0.474  1.0
  N  N32  1  0.437  0.375  0.026  1.0
  N  N33  1  0.937  0.125  0.474  1.0
  N  N34  1  0.563  0.875  0.974  1.0
  N  N35  1  0.063  0.625  0.526  1.0
[/CIF]
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The material structure described by V4N2Te3 crystallizes in the orthorhombic Pnma space group. There are three inequivalent V sites. In the first V site, V(1) is bonded in a distorted L-shaped geometry to two equivalent N(1), one Te(1), and four equivalent Te(2) atoms. In the second V site, V(2) is bonded in a distorted L-shaped geometry to two equivalent N(1) and two equivalent Te(1) atoms. In the third V site, V(3) is bonded in a distorted L-shaped geometry to two equivalent N(1), one Te(1), and three equivalent Te(2) atoms. N(1) is bonded in a see-saw-like geometry to one V(1), one V(2), and two equivalent V(3) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one V(1), two equivalent V(2), and two equivalent V(3) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to two equivalent V(1) and three equivalent V(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V4Te3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.526
_cell_length_b   10.755
_cell_length_c   9.312
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   653.559
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.607  0.250  0.914  1.0
  V  V1  1  0.107  0.250  0.586  1.0
  V  V2  1  0.393  0.750  0.086  1.0
  V  V3  1  0.893  0.750  0.414  1.0
  V  V4  1  0.753  0.250  0.437  1.0
  V  V5  1  0.253  0.250  0.063  1.0
  V  V6  1  0.247  0.750  0.563  1.0
  V  V7  1  0.747  0.750  0.937  1.0
  V  V8  1  0.679  0.475  0.051  1.0
  V  V9  1  0.179  0.025  0.449  1.0
  V  V10  1  0.321  0.975  0.949  1.0
  V  V11  1  0.821  0.525  0.551  1.0
  V  V12  1  0.321  0.525  0.949  1.0
  V  V13  1  0.821  0.975  0.551  1.0
  V  V14  1  0.679  0.025  0.051  1.0
  V  V15  1  0.179  0.475  0.449  1.0
  Te  Te16  1  0.852  0.250  0.158  1.0
  Te  Te17  1  0.352  0.250  0.342  1.0
  Te  Te18  1  0.148  0.750  0.842  1.0
  Te  Te19  1  0.648  0.750  0.658  1.0
  Te  Te20  1  0.556  0.575  0.325  1.0
  Te  Te21  1  0.056  0.925  0.175  1.0
  Te  Te22  1  0.444  0.075  0.675  1.0
  Te  Te23  1  0.944  0.425  0.825  1.0
  Te  Te24  1  0.444  0.425  0.675  1.0
  Te  Te25  1  0.944  0.075  0.825  1.0
  Te  Te26  1  0.556  0.925  0.325  1.0
  Te  Te27  1  0.056  0.575  0.175  1.0
  N  N28  1  0.563  0.625  0.974  1.0
  N  N29  1  0.063  0.875  0.526  1.0
  N  N30  1  0.437  0.125  0.026  1.0
  N  N31  1  0.937  0.375  0.474  1.0
  N  N32  1  0.437  0.375  0.026  1.0
  N  N33  1  0.937  0.125  0.474  1.0
  N  N34  1  0.563  0.875  0.974  1.0
  N  N35  1  0.063  0.625  0.526  1.0
[/CIF]
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