The material described by RbLiMnP3HO10 crystallizes in the monoclinic Cc space group. Rb(1) is bonded in a 9-coordinate geometry to one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(3) atoms. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(5), and one O(7) atom. Mn(1) is bonded to one O(2), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-53°. In the second P site, P(2) is bonded to one O(1), one O(10), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the third P site, P(3) is bonded to one O(10), one O(4), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 25-48°. H(1) is bonded in a linear geometry to one O(4) and one O(7) atom. There are ten inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(3), and one H(1) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1), one Li(1), one Mn(1), and one P(2) atom. In the third O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Mn(1), and one P(2) atom. In the fourth O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1), one Li(1), one P(1), and one H(1) atom. In the fifth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Mn(1), and one P(3) atom. In the sixth O site, O(9) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(1), and one P(3) atom. In the seventh O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one P(2), and one P(3) atom. In the eighth O site, O(1) is bonded in a distorted T-shaped geometry to one Li(1), one P(1), and one P(2) atom. In the ninth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Mn(1), and one P(1) atom. In the tenth O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Mn(1), and one P(1) atom. is represented by the CIF card [CIF]
data_RbLiMnP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.459
_cell_length_b   7.459
_cell_length_c   9.591
_cell_angle_alpha   75.127
_cell_angle_beta   75.127
_cell_angle_gamma   75.008
_symmetry_Int_Tables_number   1
_cell_volume   487.759
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.463  0.545  0.735  1.0
  Rb  Rb1  1  0.545  0.463  0.235  1.0
  Li  Li2  1  0.853  0.069  0.482  1.0
  Li  Li3  1  0.069  0.853  0.982  1.0
  Mn  Mn4  1  0.507  0.001  0.000  1.0
  Mn  Mn5  1  0.001  0.507  0.500  1.0
  P  P6  1  0.851  0.717  0.811  1.0
  P  P7  1  0.874  0.123  0.744  1.0
  P  P8  1  0.717  0.851  0.311  1.0
  P  P9  1  0.284  0.151  0.693  1.0
  P  P10  1  0.123  0.874  0.244  1.0
  P  P11  1  0.151  0.284  0.193  1.0
  H  H12  1  0.485  0.004  0.520  1.0
  H  H13  1  0.004  0.485  0.020  1.0
  O  O14  1  0.875  0.929  0.699  1.0
  O  O15  1  0.929  0.875  0.199  1.0
  O  O16  1  0.873  0.593  0.704  1.0
  O  O17  1  0.655  0.748  0.909  1.0
  O  O18  1  0.983  0.372  0.106  1.0
  O  O19  1  0.748  0.655  0.409  1.0
  O  O20  1  0.856  0.262  0.599  1.0
  O  O21  1  0.736  0.153  0.884  1.0
  O  O22  1  0.593  0.873  0.204  1.0
  O  O23  1  0.372  0.983  0.606  1.0
  O  O24  1  0.671  0.015  0.395  1.0
  O  O25  1  0.385  0.140  0.812  1.0
  O  O26  1  0.262  0.856  0.099  1.0
  O  O27  1  0.153  0.736  0.384  1.0
  O  O28  1  0.248  0.342  0.593  1.0
  O  O29  1  0.015  0.671  0.895  1.0
  O  O30  1  0.342  0.248  0.093  1.0
  O  O31  1  0.140  0.385  0.312  1.0
  O  O32  1  0.081  0.087  0.784  1.0
  O  O33  1  0.087  0.081  0.284  1.0
[/CIF]
.
The material described by RbLiMnP3HO10 crystallizes in the monoclinic Cc space group. Rb(1) is bonded in a 9-coordinate geometry to one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(3) atoms. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(5), and one O(7) atom. Mn(1) is bonded to one O(2), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 29-53°. In the second P site, P(2) is bonded to one O(1), one O(10), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the third P site, P(3) is bonded to one O(10), one O(4), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 25-48°. H(1) is bonded in a linear geometry to one O(4) and one O(7) atom. There are ten inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(3), and one H(1) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1), one Li(1), one Mn(1), and one P(2) atom. In the third O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Mn(1), and one P(2) atom. In the fourth O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1), one Li(1), one P(1), and one H(1) atom. In the fifth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Mn(1), and one P(3) atom. In the sixth O site, O(9) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(1), and one P(3) atom. In the seventh O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one P(2), and one P(3) atom. In the eighth O site, O(1) is bonded in a distorted T-shaped geometry to one Li(1), one P(1), and one P(2) atom. In the ninth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Mn(1), and one P(1) atom. In the tenth O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Mn(1), and one P(1) atom. is represented by the CIF card [CIF]
data_RbLiMnP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.459
_cell_length_b   7.459
_cell_length_c   9.591
_cell_angle_alpha   75.127
_cell_angle_beta   75.127
_cell_angle_gamma   75.008
_symmetry_Int_Tables_number   1
_cell_volume   487.759
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.463  0.545  0.735  1.0
  Rb  Rb1  1  0.545  0.463  0.235  1.0
  Li  Li2  1  0.853  0.069  0.482  1.0
  Li  Li3  1  0.069  0.853  0.982  1.0
  Mn  Mn4  1  0.507  0.001  0.000  1.0
  Mn  Mn5  1  0.001  0.507  0.500  1.0
  P  P6  1  0.851  0.717  0.811  1.0
  P  P7  1  0.874  0.123  0.744  1.0
  P  P8  1  0.717  0.851  0.311  1.0
  P  P9  1  0.284  0.151  0.693  1.0
  P  P10  1  0.123  0.874  0.244  1.0
  P  P11  1  0.151  0.284  0.193  1.0
  H  H12  1  0.485  0.004  0.520  1.0
  H  H13  1  0.004  0.485  0.020  1.0
  O  O14  1  0.875  0.929  0.699  1.0
  O  O15  1  0.929  0.875  0.199  1.0
  O  O16  1  0.873  0.593  0.704  1.0
  O  O17  1  0.655  0.748  0.909  1.0
  O  O18  1  0.983  0.372  0.106  1.0
  O  O19  1  0.748  0.655  0.409  1.0
  O  O20  1  0.856  0.262  0.599  1.0
  O  O21  1  0.736  0.153  0.884  1.0
  O  O22  1  0.593  0.873  0.204  1.0
  O  O23  1  0.372  0.983  0.606  1.0
  O  O24  1  0.671  0.015  0.395  1.0
  O  O25  1  0.385  0.140  0.812  1.0
  O  O26  1  0.262  0.856  0.099  1.0
  O  O27  1  0.153  0.736  0.384  1.0
  O  O28  1  0.248  0.342  0.593  1.0
  O  O29  1  0.015  0.671  0.895  1.0
  O  O30  1  0.342  0.248  0.093  1.0
  O  O31  1  0.140  0.385  0.312  1.0
  O  O32  1  0.081  0.087  0.784  1.0
  O  O33  1  0.087  0.081  0.284  1.0
[/CIF]
.