The structure described by Sr2CoSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Fdd2 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(5), one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra; faces with six equivalent Sr(2)O12 cuboctahedra; faces with two equivalent Co(1)O6 octahedra; faces with two Co(2,2)O6 octahedra; faces with two equivalent Sb(1)O6 octahedra; and faces with two equivalent Sb(2)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(5), one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(2)O12 cuboctahedra; faces with six equivalent Sr(1)O12 cuboctahedra; faces with two equivalent Co(1)O6 octahedra; faces with two Co(2,2)O6 octahedra; faces with two equivalent Sb(1)O6 octahedra; and faces with two equivalent Sb(2)O6 octahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(6), one O(8), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Co site, Co(2) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Co site, Co(2) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(5), one O(8), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with three equivalent Co(1)O6 octahedra; corners with three Co(2,2)O6 octahedra; faces with four equivalent Sr(1)O12 cuboctahedra; and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Sb site, Sb(2) is bonded to one O(6), one O(7), two equivalent O(1), and two equivalent O(2) atoms to form SbO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(2) atom. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(1) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(1) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(1) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the sixth O site, O(6) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(2) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the seventh O site, O(7) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(2) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the eighth O site, O(8) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(1) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF file [CIF]
data_Sr2CoSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.614
_cell_length_b   5.630
_cell_length_c   5.669
_cell_angle_alpha   119.755
_cell_angle_beta   119.654
_cell_angle_gamma   90.033
_symmetry_Int_Tables_number   1
_cell_volume   127.793
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.000  1.0
  O  O1  1  0.252  0.749  1.000  1.0
  O  O2  1  0.748  0.251  0.000  1.0
  O  O3  1  0.754  0.754  0.508  1.0
  O  O4  1  0.246  0.246  0.492  1.0
  O  O5  1  0.252  0.251  1.000  1.0
  O  O6  1  0.748  0.749  1.000  1.0
  Sb  Sb7  1  0.000  0.000  0.000  1.0
  Sr  Sr8  1  0.250  0.750  0.500  1.0
  Sr  Sr9  1  0.750  0.250  0.500  1.0
[/CIF]
.
The structure described by Sr2CoSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Fdd2 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(5), one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra; faces with six equivalent Sr(2)O12 cuboctahedra; faces with two equivalent Co(1)O6 octahedra; faces with two Co(2,2)O6 octahedra; faces with two equivalent Sb(1)O6 octahedra; and faces with two equivalent Sb(2)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(5), one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(2)O12 cuboctahedra; faces with six equivalent Sr(1)O12 cuboctahedra; faces with two equivalent Co(1)O6 octahedra; faces with two Co(2,2)O6 octahedra; faces with two equivalent Sb(1)O6 octahedra; and faces with two equivalent Sb(2)O6 octahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(6), one O(8), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Co site, Co(2) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Co site, Co(2) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(5), one O(8), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with three equivalent Co(1)O6 octahedra; corners with three Co(2,2)O6 octahedra; faces with four equivalent Sr(1)O12 cuboctahedra; and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Sb site, Sb(2) is bonded to one O(6), one O(7), two equivalent O(1), and two equivalent O(2) atoms to form SbO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(2) atom. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(1) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(1) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(1) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the sixth O site, O(6) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(2) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the seventh O site, O(7) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Sb(2) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the eighth O site, O(8) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(1), and one Sb(1) atom to form a mixture of distorted corner, face, and edge-sharing OSr4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF file [CIF]
data_Sr2CoSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.614
_cell_length_b   5.630
_cell_length_c   5.669
_cell_angle_alpha   119.755
_cell_angle_beta   119.654
_cell_angle_gamma   90.033
_symmetry_Int_Tables_number   1
_cell_volume   127.793
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.000  1.0
  O  O1  1  0.252  0.749  1.000  1.0
  O  O2  1  0.748  0.251  0.000  1.0
  O  O3  1  0.754  0.754  0.508  1.0
  O  O4  1  0.246  0.246  0.492  1.0
  O  O5  1  0.252  0.251  1.000  1.0
  O  O6  1  0.748  0.749  1.000  1.0
  Sb  Sb7  1  0.000  0.000  0.000  1.0
  Sr  Sr8  1  0.250  0.750  0.500  1.0
  Sr  Sr9  1  0.750  0.250  0.500  1.0
[/CIF]
.