The material structure described by Cs2SbF5 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 12-coordinate geometry to four equivalent F(2) and eight equivalent F(1) atoms. In the second Cs site, Cs(2) is bonded in a 9-coordinate geometry to one F(2) and eight equivalent F(1) atoms. Sb(1) is bonded in a square pyramidal geometry to one F(2) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 5-coordinate geometry to two equivalent Cs(1), two equivalent Cs(2), and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Cs(2), four equivalent Cs(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Cs2SbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.837
_cell_length_b   7.837
_cell_length_c   7.160
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   129.907
_symmetry_Int_Tables_number   1
_cell_volume   337.330
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.240  0.760  0.250  1.0
  Cs  Cs1  1  0.760  0.240  0.750  1.0
  Cs  Cs2  1  0.558  0.442  0.250  1.0
  Cs  Cs3  1  0.442  0.558  0.750  1.0
  Sb  Sb4  1  0.912  0.088  0.250  1.0
  Sb  Sb5  1  0.088  0.912  0.750  1.0
  F  F6  1  0.108  0.338  0.052  1.0
  F  F7  1  0.892  0.662  0.948  1.0
  F  F8  1  0.892  0.662  0.552  1.0
  F  F9  1  0.662  0.892  0.448  1.0
  F  F10  1  0.108  0.338  0.448  1.0
  F  F11  1  0.338  0.108  0.552  1.0
  F  F12  1  0.338  0.108  0.948  1.0
  F  F13  1  0.662  0.892  0.052  1.0
  F  F14  1  0.773  0.227  0.250  1.0
  F  F15  1  0.227  0.773  0.750  1.0
[/CIF]
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The material structure described by Cs2SbF5 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 12-coordinate geometry to four equivalent F(2) and eight equivalent F(1) atoms. In the second Cs site, Cs(2) is bonded in a 9-coordinate geometry to one F(2) and eight equivalent F(1) atoms. Sb(1) is bonded in a square pyramidal geometry to one F(2) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 5-coordinate geometry to two equivalent Cs(1), two equivalent Cs(2), and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Cs(2), four equivalent Cs(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Cs2SbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.837
_cell_length_b   7.837
_cell_length_c   7.160
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   129.907
_symmetry_Int_Tables_number   1
_cell_volume   337.330
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.240  0.760  0.250  1.0
  Cs  Cs1  1  0.760  0.240  0.750  1.0
  Cs  Cs2  1  0.558  0.442  0.250  1.0
  Cs  Cs3  1  0.442  0.558  0.750  1.0
  Sb  Sb4  1  0.912  0.088  0.250  1.0
  Sb  Sb5  1  0.088  0.912  0.750  1.0
  F  F6  1  0.108  0.338  0.052  1.0
  F  F7  1  0.892  0.662  0.948  1.0
  F  F8  1  0.892  0.662  0.552  1.0
  F  F9  1  0.662  0.892  0.448  1.0
  F  F10  1  0.108  0.338  0.448  1.0
  F  F11  1  0.338  0.108  0.552  1.0
  F  F12  1  0.338  0.108  0.948  1.0
  F  F13  1  0.662  0.892  0.052  1.0
  F  F14  1  0.773  0.227  0.250  1.0
  F  F15  1  0.227  0.773  0.750  1.0
[/CIF]
.