The material described by UV2O6 is beta Vanadium nitride-derived structured and crystallizes in the trigonal P-31m space group. U(1) is bonded to six equivalent O(1) atoms to form UO6 octahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent U(1)O6 octahedra and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. O(1) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_UV2O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.958
_cell_length_b   4.958
_cell_length_c   4.853
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   103.308
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.667  0.333  0.500  1.0
  V  V2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.345  0.345  0.727  1.0
  O  O4  1  0.655  0.000  0.727  1.0
  O  O5  1  1.000  0.655  0.727  1.0
  O  O6  1  0.345  0.000  0.273  1.0
  O  O7  1  0.000  0.345  0.273  1.0
  O  O8  1  0.655  0.655  0.273  1.0
[/CIF]
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The material described by UV2O6 is beta Vanadium nitride-derived structured and crystallizes in the trigonal P-31m space group. U(1) is bonded to six equivalent O(1) atoms to form UO6 octahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent U(1)O6 octahedra and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. O(1) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_UV2O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.958
_cell_length_b   4.958
_cell_length_c   4.853
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   103.308
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.667  0.333  0.500  1.0
  V  V2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.345  0.345  0.727  1.0
  O  O4  1  0.655  0.000  0.727  1.0
  O  O5  1  1.000  0.655  0.727  1.0
  O  O6  1  0.345  0.000  0.273  1.0
  O  O7  1  0.000  0.345  0.273  1.0
  O  O8  1  0.655  0.655  0.273  1.0
[/CIF]
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