The material described by Pt(NH3)4CoH4(C2O5)2(H2O)2 is Indium-derived structured and crystallizes in the orthorhombic I222 space group. The structure is zero-dimensional and consists of four water molecules, two CoH4(C2O5)2 clusters, and two Pt(NH3)4 clusters. In each CoH4(C2O5)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent O(3) and four equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. H(4) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent H(4) atoms. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. In each Pt(NH3)4 cluster, Pt(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_CoH20PtC4(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.177
_cell_length_b   9.177
_cell_length_c   9.177
_cell_angle_alpha   134.084
_cell_angle_beta   132.014
_cell_angle_gamma   68.590
_symmetry_Int_Tables_number   1
_cell_volume   405.096
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.000  1.0
  H  H1  1  0.204  0.795  0.167  1.0
  H  H2  1  0.628  0.037  0.833  1.0
  H  H3  1  0.796  0.963  0.591  1.0
  H  H4  1  0.372  0.205  0.409  1.0
  H  H5  1  0.189  0.015  0.391  1.0
  H  H6  1  0.624  0.798  0.609  1.0
  H  H7  1  0.811  0.202  0.826  1.0
  H  H8  1  0.376  0.985  0.174  1.0
  H  H9  1  0.993  0.819  0.121  1.0
  H  H10  1  0.698  0.872  0.879  1.0
  H  H11  1  0.007  0.128  0.826  1.0
  H  H12  1  0.302  0.181  0.174  1.0
  H  H13  1  0.092  0.445  0.645  1.0
  H  H14  1  0.800  0.447  0.355  1.0
  H  H15  1  0.908  0.553  0.353  1.0
  H  H16  1  0.200  0.555  0.647  1.0
  H  H17  1  0.179  0.574  0.386  1.0
  H  H18  1  0.188  0.794  0.614  1.0
  H  H19  1  0.821  0.206  0.394  1.0
  H  H20  1  0.812  0.426  0.606  1.0
  Pt  Pt21  1  0.000  0.000  0.000  1.0
  C  C22  1  0.321  0.429  0.112  1.0
  C  C23  1  0.316  0.209  0.888  1.0
  C  C24  1  0.679  0.791  0.108  1.0
  C  C25  1  0.684  0.571  0.892  1.0
  N  N26  1  0.110  0.898  0.194  1.0
  N  N27  1  0.704  0.916  0.806  1.0
  N  N28  1  0.890  0.084  0.788  1.0
  N  N29  1  0.296  0.102  0.212  1.0
  O  O30  1  0.398  0.584  0.195  1.0
  O  O31  1  0.390  0.204  0.805  1.0
  O  O32  1  0.602  0.796  0.186  1.0
  O  O33  1  0.610  0.416  0.814  1.0
  O  O34  1  0.249  0.433  0.193  1.0
  O  O35  1  0.240  0.056  0.807  1.0
  O  O36  1  0.751  0.944  0.184  1.0
  O  O37  1  0.760  0.567  0.816  1.0
  O  O38  1  0.222  0.500  0.722  1.0
  O  O39  1  0.778  0.500  0.278  1.0
  O  O40  1  0.144  0.644  0.500  1.0
  O  O41  1  0.856  0.356  0.500  1.0
[/CIF]
.
The material described by Pt(NH3)4CoH4(C2O5)2(H2O)2 is Indium-derived structured and crystallizes in the orthorhombic I222 space group. The structure is zero-dimensional and consists of four water molecules, two CoH4(C2O5)2 clusters, and two Pt(NH3)4 clusters. In each CoH4(C2O5)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent O(3) and four equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. H(4) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent H(4) atoms. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. In each Pt(NH3)4 cluster, Pt(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_CoH20PtC4(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.177
_cell_length_b   9.177
_cell_length_c   9.177
_cell_angle_alpha   134.084
_cell_angle_beta   132.014
_cell_angle_gamma   68.590
_symmetry_Int_Tables_number   1
_cell_volume   405.096
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.000  1.0
  H  H1  1  0.204  0.795  0.167  1.0
  H  H2  1  0.628  0.037  0.833  1.0
  H  H3  1  0.796  0.963  0.591  1.0
  H  H4  1  0.372  0.205  0.409  1.0
  H  H5  1  0.189  0.015  0.391  1.0
  H  H6  1  0.624  0.798  0.609  1.0
  H  H7  1  0.811  0.202  0.826  1.0
  H  H8  1  0.376  0.985  0.174  1.0
  H  H9  1  0.993  0.819  0.121  1.0
  H  H10  1  0.698  0.872  0.879  1.0
  H  H11  1  0.007  0.128  0.826  1.0
  H  H12  1  0.302  0.181  0.174  1.0
  H  H13  1  0.092  0.445  0.645  1.0
  H  H14  1  0.800  0.447  0.355  1.0
  H  H15  1  0.908  0.553  0.353  1.0
  H  H16  1  0.200  0.555  0.647  1.0
  H  H17  1  0.179  0.574  0.386  1.0
  H  H18  1  0.188  0.794  0.614  1.0
  H  H19  1  0.821  0.206  0.394  1.0
  H  H20  1  0.812  0.426  0.606  1.0
  Pt  Pt21  1  0.000  0.000  0.000  1.0
  C  C22  1  0.321  0.429  0.112  1.0
  C  C23  1  0.316  0.209  0.888  1.0
  C  C24  1  0.679  0.791  0.108  1.0
  C  C25  1  0.684  0.571  0.892  1.0
  N  N26  1  0.110  0.898  0.194  1.0
  N  N27  1  0.704  0.916  0.806  1.0
  N  N28  1  0.890  0.084  0.788  1.0
  N  N29  1  0.296  0.102  0.212  1.0
  O  O30  1  0.398  0.584  0.195  1.0
  O  O31  1  0.390  0.204  0.805  1.0
  O  O32  1  0.602  0.796  0.186  1.0
  O  O33  1  0.610  0.416  0.814  1.0
  O  O34  1  0.249  0.433  0.193  1.0
  O  O35  1  0.240  0.056  0.807  1.0
  O  O36  1  0.751  0.944  0.184  1.0
  O  O37  1  0.760  0.567  0.816  1.0
  O  O38  1  0.222  0.500  0.722  1.0
  O  O39  1  0.778  0.500  0.278  1.0
  O  O40  1  0.144  0.644  0.500  1.0
  O  O41  1  0.856  0.356  0.500  1.0
[/CIF]
.