The material structure described by LiRhF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiRhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.308
_cell_length_b   5.308
_cell_length_c   5.308
_cell_angle_alpha   55.006
_cell_angle_beta   55.006
_cell_angle_gamma   55.006
_symmetry_Int_Tables_number   1
_cell_volume   93.464
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  Rh  Rh1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.620  0.241  0.897  1.0
  F  F3  1  0.241  0.897  0.620  1.0
  F  F4  1  0.103  0.380  0.759  1.0
  F  F5  1  0.897  0.620  0.241  1.0
  F  F6  1  0.759  0.103  0.380  1.0
  F  F7  1  0.380  0.759  0.103  1.0
[/CIF]
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The material structure described by LiRhF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiRhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.308
_cell_length_b   5.308
_cell_length_c   5.308
_cell_angle_alpha   55.006
_cell_angle_beta   55.006
_cell_angle_gamma   55.006
_symmetry_Int_Tables_number   1
_cell_volume   93.464
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  Rh  Rh1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.620  0.241  0.897  1.0
  F  F3  1  0.241  0.897  0.620  1.0
  F  F4  1  0.103  0.380  0.759  1.0
  F  F5  1  0.897  0.620  0.241  1.0
  F  F6  1  0.759  0.103  0.380  1.0
  F  F7  1  0.380  0.759  0.103  1.0
[/CIF]
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