The material structure described by In4Sn3O12 crystallizes in the triclinic P1 space group. There are eight inequivalent In sites. In the first In site, In(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(13), one O(21), one O(24), one O(5), and one O(7) atom. In the second In site, In(2) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(13), one O(19), one O(4), one O(6), and one O(8) atom. In the third In site, In(3) is bonded in a 7-coordinate geometry to one O(12), one O(14), one O(2), one O(20), one O(4), one O(6), and one O(8) atom. In the fourth In site, In(4) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(15), one O(16), one O(3), one O(7), and one O(9) atom. In the fifth In site, In(5) is bonded in a 7-coordinate geometry to one O(10), one O(14), one O(15), one O(16), one O(18), one O(22), and one O(9) atom. In the sixth In site, In(6) is bonded in a 7-coordinate geometry to one O(11), one O(13), one O(17), one O(19), one O(21), one O(23), and one O(5) atom. In the seventh In site, In(7) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(14), one O(18), one O(20), one O(24), and one O(4) atom. In the eighth In site, In(8) is bonded in a 6-coordinate geometry to one O(16), one O(17), one O(21), one O(23), one O(3), and one O(7) atom. There are six inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 7-coordinate geometry to one O(18), one O(2), one O(22), one O(3), one O(4), one O(8), and one O(9) atom. In the second Sn site, Sn(2) is bonded in an octahedral geometry to one O(10), one O(15), one O(2), one O(22), one O(23), and one O(3) atom. In the third Sn site, Sn(3) is bonded in an octahedral geometry to one O(1), one O(19), one O(20), one O(24), one O(5), and one O(6) atom. In the fourth Sn site, Sn(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(16), one O(17), one O(5), and one O(7) atom. In the fifth Sn site, Sn(5) is bonded in a 6-coordinate geometry to one O(14), one O(15), one O(18), one O(20), one O(8), and one O(9) atom. In the sixth Sn site, Sn(6) is bonded in a 7-coordinate geometry to one O(12), one O(13), one O(17), one O(19), one O(21), one O(24), and one O(6) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one In(1), one In(2), one In(7), and one Sn(3) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one In(3), one Sn(1), and one Sn(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one In(4), one In(8), one Sn(1), and one Sn(2) atom. In the fourth O site, O(4) is bonded to one In(2), one In(3), one In(7), and one Sn(1) atom to form distorted OIn3Sn tetrahedra that share  a cornercorner with one O(8)In2Sn2 tetrahedra,  a cornercorner with one O(9)In2Sn2 tetrahedra,  a cornercorner with one O(12)In3Sn tetrahedra,  a cornercorner with one O(13)In3Sn tetrahedra, corners with two equivalent O(14)In3Sn tetrahedra,  an edgeedge with one O(18)In2Sn2 tetrahedra,  an edgeedge with one O(8)In2Sn2 tetrahedra, and  an edgeedge with one O(12)In3Sn tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one In(1), one In(6), one Sn(3), and one Sn(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one In(2), one In(3), one Sn(3), and one Sn(6) atom. In the seventh O site, O(7) is bonded to one In(1), one In(4), one In(8), and one Sn(4) atom to form distorted OIn3Sn tetrahedra that share  a cornercorner with one O(9)In2Sn2 tetrahedra,  a cornercorner with one O(11)In3Sn tetrahedra,  a cornercorner with one O(13)In3Sn tetrahedra,  a cornercorner with one O(16)In3Sn tetrahedra, corners with two equivalent O(17)In2Sn2 trigonal pyramids,  an edgeedge with one O(11)In3Sn tetrahedra,  an edgeedge with one O(16)In3Sn tetrahedra, and  an edgeedge with one O(21)In3Sn tetrahedra. In the eighth O site, O(8) is bonded to one In(2), one In(3), one Sn(1), and one Sn(5) atom to form distorted OIn2Sn2 tetrahedra that share  a cornercorner with one O(13)In3Sn tetrahedra,  a cornercorner with one O(4)In3Sn tetrahedra, corners with two equivalent O(18)In2Sn2 tetrahedra, corners with two equivalent O(12)In3Sn tetrahedra,  an edgeedge with one O(9)In2Sn2 tetrahedra,  an edgeedge with one O(14)In3Sn tetrahedra, and  an edgeedge with one O(4)In3Sn tetrahedra. In the ninth O site, O(9) is bonded to one In(4), one In(5), one Sn(1), and one Sn(5) atom to form OIn2Sn2 tetrahedra that share  a cornercorner with one O(18)In2Sn2 tetrahedra,  a cornercorner with one O(11)In3Sn tetrahedra,  a cornercorner with one O(4)In3Sn tetrahedra,  a cornercorner with one O(7)In3Sn tetrahedra, corners with two equivalent O(14)In3Sn tetrahedra,  an edgeedge with one O(18)In2Sn2 tetrahedra,  an edgeedge with one O(8)In2Sn2 tetrahedra, and  an edgeedge with one O(16)In3Sn tetrahedra. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one In(4), one In(5), one Sn(2), and one Sn(4) atom. In the eleventh O site, O(11) is bonded to one In(1), one In(4), one In(6), and one Sn(4) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(9)In2Sn2 tetrahedra,  a cornercorner with one O(7)In3Sn tetrahedra, corners with two equivalent O(16)In3Sn tetrahedra, corners with two equivalent O(21)In3Sn tetrahedra,  an edgeedge with one O(13)In3Sn tetrahedra,  an edgeedge with one O(7)In3Sn tetrahedra, and  an edgeedge with one O(17)In2Sn2 trigonal pyramid. In the twelfth O site, O(12) is bonded to one In(2), one In(3), one In(7), and one Sn(6) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(18)In2Sn2 tetrahedra,  a cornercorner with one O(21)In3Sn tetrahedra,  a cornercorner with one O(4)In3Sn tetrahedra, corners with two equivalent O(8)In2Sn2 tetrahedra,  a cornercorner with one O(17)In2Sn2 trigonal pyramid,  an edgeedge with one O(13)In3Sn tetrahedra,  an edgeedge with one O(14)In3Sn tetrahedra, and  an edgeedge with one O(4)In3Sn tetrahedra. In the thirteenth O site, O(13) is bonded to one In(1), one In(2), one In(6), and one Sn(6) atom to form distorted OIn3Sn tetrahedra that share  a cornercorner with one O(8)In2Sn2 tetrahedra,  a cornercorner with one O(21)In3Sn tetrahedra,  a cornercorner with one O(4)In3Sn tetrahedra,  a cornercorner with one O(7)In3Sn tetrahedra, corners with two equivalent O(17)In2Sn2 trigonal pyramids,  an edgeedge with one O(11)In3Sn tetrahedra,  an edgeedge with one O(12)In3Sn tetrahedra, and  an edgeedge with one O(21)In3Sn tetrahedra. In the fourteenth O site, O(14) is bonded to one In(3), one In(5), one In(7), and one Sn(5) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(18)In2Sn2 tetrahedra,  a cornercorner with one O(16)In3Sn tetrahedra, corners with two equivalent O(9)In2Sn2 tetrahedra, corners with two equivalent O(4)In3Sn tetrahedra,  an edgeedge with one O(18)In2Sn2 tetrahedra,  an edgeedge with one O(8)In2Sn2 tetrahedra, and  an edgeedge with one O(12)In3Sn tetrahedra. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one In(4), one In(5), one Sn(2), and one Sn(5) atom. In the sixteenth O site, O(16) is bonded to one In(4), one In(5), one In(8), and one Sn(4) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(18)In2Sn2 tetrahedra,  a cornercorner with one O(14)In3Sn tetrahedra,  a cornercorner with one O(21)In3Sn tetrahedra,  a cornercorner with one O(7)In3Sn tetrahedra, corners with two equivalent O(11)In3Sn tetrahedra,  an edgeedge with one O(9)In2Sn2 tetrahedra,  an edgeedge with one O(7)In3Sn tetrahedra, and  an edgeedge with one O(17)In2Sn2 trigonal pyramid. In the seventeenth O site, O(17) is bonded to one In(6), one In(8), one Sn(4), and one Sn(6) atom to form a mixture of distorted corner and edge-sharing OIn2Sn2 trigonal pyramids. In the eighteenth O site, O(18) is bonded to one In(5), one In(7), one Sn(1), and one Sn(5) atom to form distorted OIn2Sn2 tetrahedra that share  a cornercorner with one O(9)In2Sn2 tetrahedra,  a cornercorner with one O(12)In3Sn tetrahedra,  a cornercorner with one O(14)In3Sn tetrahedra,  a cornercorner with one O(16)In3Sn tetrahedra, corners with two equivalent O(8)In2Sn2 tetrahedra,  an edgeedge with one O(9)In2Sn2 tetrahedra,  an edgeedge with one O(14)In3Sn tetrahedra, and  an edgeedge with one O(4)In3Sn tetrahedra. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one In(2), one In(6), one Sn(3), and one Sn(6) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one In(3), one In(7), one Sn(3), and one Sn(5) atom. In the twenty-first O site, O(21) is bonded to one In(1), one In(6), one In(8), and one Sn(6) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(12)In3Sn tetrahedra,  a cornercorner with one O(13)In3Sn tetrahedra,  a cornercorner with one O(16)In3Sn tetrahedra, corners with two equivalent O(11)In3Sn tetrahedra,  a cornercorner with one O(17)In2Sn2 trigonal pyramid,  an edgeedge with one O(13)In3Sn tetrahedra,  an edgeedge with one O(7)In3Sn tetrahedra, and  an edgeedge with one O(17)In2Sn2 trigonal pyramid. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one In(5), one Sn(1), and one Sn(2) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal non-coplanar geometry to one In(6), one In(8), and one Sn(2) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one In(1), one In(7), one Sn(3), and one Sn(6) atom. is represented by the CIF card [CIF]
data_In4(SnO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.310
_cell_length_b   6.339
_cell_length_c   12.621
_cell_angle_alpha   99.450
_cell_angle_beta   99.373
_cell_angle_gamma   99.263
_symmetry_Int_Tables_number   1
_cell_volume   482.068
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.397  0.864  0.846  1.0
  In  In1  1  0.309  0.602  0.067  1.0
  In  In2  1  0.860  0.688  0.198  1.0
  In  In3  1  0.313  0.605  0.569  1.0
  In  In4  1  0.691  0.396  0.433  1.0
  In  In5  1  0.138  0.311  0.802  1.0
  In  In6  1  0.602  0.134  0.153  1.0
  In  In7  1  0.603  0.135  0.657  1.0
  Sn  Sn8  1  0.396  0.864  0.345  1.0
  Sn  Sn9  1  0.002  0.999  0.501  1.0
  Sn  Sn10  1  0.001  0.001  0.999  1.0
  Sn  Sn11  1  0.862  0.685  0.699  1.0
  Sn  Sn12  1  0.133  0.316  0.300  1.0
  Sn  Sn13  1  0.686  0.398  0.932  1.0
  O  O14  1  0.312  0.938  0.042  1.0
  O  O15  1  0.068  0.902  0.343  1.0
  O  O16  1  0.317  0.943  0.542  1.0
  O  O17  1  0.575  0.826  0.216  1.0
  O  O18  1  0.048  0.903  0.839  1.0
  O  O19  1  0.901  0.685  0.026  1.0
  O  O20  1  0.588  0.817  0.710  1.0
  O  O21  1  0.180  0.576  0.212  1.0
  O  O22  1  0.411  0.583  0.406  1.0
  O  O23  1  0.907  0.691  0.534  1.0
  O  O24  1  0.166  0.583  0.708  1.0
  O  O25  1  0.586  0.420  0.086  1.0
  O  O26  1  0.430  0.578  0.910  1.0
  O  O27  1  0.825  0.412  0.291  1.0
  O  O28  1  0.094  0.310  0.464  1.0
  O  O29  1  0.594  0.424  0.592  1.0
  O  O30  1  0.820  0.432  0.795  1.0
  O  O31  1  0.405  0.176  0.293  1.0
  O  O32  1  0.086  0.314  0.970  1.0
  O  O33  1  0.950  0.092  0.161  1.0
  O  O34  1  0.429  0.181  0.796  1.0
  O  O35  1  0.683  0.048  0.448  1.0
  O  O36  1  0.942  0.095  0.656  1.0
  O  O37  1  0.691  0.071  0.957  1.0
[/CIF]
.
The material structure described by In4Sn3O12 crystallizes in the triclinic P1 space group. There are eight inequivalent In sites. In the first In site, In(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(13), one O(21), one O(24), one O(5), and one O(7) atom. In the second In site, In(2) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(13), one O(19), one O(4), one O(6), and one O(8) atom. In the third In site, In(3) is bonded in a 7-coordinate geometry to one O(12), one O(14), one O(2), one O(20), one O(4), one O(6), and one O(8) atom. In the fourth In site, In(4) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(15), one O(16), one O(3), one O(7), and one O(9) atom. In the fifth In site, In(5) is bonded in a 7-coordinate geometry to one O(10), one O(14), one O(15), one O(16), one O(18), one O(22), and one O(9) atom. In the sixth In site, In(6) is bonded in a 7-coordinate geometry to one O(11), one O(13), one O(17), one O(19), one O(21), one O(23), and one O(5) atom. In the seventh In site, In(7) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(14), one O(18), one O(20), one O(24), and one O(4) atom. In the eighth In site, In(8) is bonded in a 6-coordinate geometry to one O(16), one O(17), one O(21), one O(23), one O(3), and one O(7) atom. There are six inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 7-coordinate geometry to one O(18), one O(2), one O(22), one O(3), one O(4), one O(8), and one O(9) atom. In the second Sn site, Sn(2) is bonded in an octahedral geometry to one O(10), one O(15), one O(2), one O(22), one O(23), and one O(3) atom. In the third Sn site, Sn(3) is bonded in an octahedral geometry to one O(1), one O(19), one O(20), one O(24), one O(5), and one O(6) atom. In the fourth Sn site, Sn(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(16), one O(17), one O(5), and one O(7) atom. In the fifth Sn site, Sn(5) is bonded in a 6-coordinate geometry to one O(14), one O(15), one O(18), one O(20), one O(8), and one O(9) atom. In the sixth Sn site, Sn(6) is bonded in a 7-coordinate geometry to one O(12), one O(13), one O(17), one O(19), one O(21), one O(24), and one O(6) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one In(1), one In(2), one In(7), and one Sn(3) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one In(3), one Sn(1), and one Sn(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one In(4), one In(8), one Sn(1), and one Sn(2) atom. In the fourth O site, O(4) is bonded to one In(2), one In(3), one In(7), and one Sn(1) atom to form distorted OIn3Sn tetrahedra that share  a cornercorner with one O(8)In2Sn2 tetrahedra,  a cornercorner with one O(9)In2Sn2 tetrahedra,  a cornercorner with one O(12)In3Sn tetrahedra,  a cornercorner with one O(13)In3Sn tetrahedra, corners with two equivalent O(14)In3Sn tetrahedra,  an edgeedge with one O(18)In2Sn2 tetrahedra,  an edgeedge with one O(8)In2Sn2 tetrahedra, and  an edgeedge with one O(12)In3Sn tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one In(1), one In(6), one Sn(3), and one Sn(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one In(2), one In(3), one Sn(3), and one Sn(6) atom. In the seventh O site, O(7) is bonded to one In(1), one In(4), one In(8), and one Sn(4) atom to form distorted OIn3Sn tetrahedra that share  a cornercorner with one O(9)In2Sn2 tetrahedra,  a cornercorner with one O(11)In3Sn tetrahedra,  a cornercorner with one O(13)In3Sn tetrahedra,  a cornercorner with one O(16)In3Sn tetrahedra, corners with two equivalent O(17)In2Sn2 trigonal pyramids,  an edgeedge with one O(11)In3Sn tetrahedra,  an edgeedge with one O(16)In3Sn tetrahedra, and  an edgeedge with one O(21)In3Sn tetrahedra. In the eighth O site, O(8) is bonded to one In(2), one In(3), one Sn(1), and one Sn(5) atom to form distorted OIn2Sn2 tetrahedra that share  a cornercorner with one O(13)In3Sn tetrahedra,  a cornercorner with one O(4)In3Sn tetrahedra, corners with two equivalent O(18)In2Sn2 tetrahedra, corners with two equivalent O(12)In3Sn tetrahedra,  an edgeedge with one O(9)In2Sn2 tetrahedra,  an edgeedge with one O(14)In3Sn tetrahedra, and  an edgeedge with one O(4)In3Sn tetrahedra. In the ninth O site, O(9) is bonded to one In(4), one In(5), one Sn(1), and one Sn(5) atom to form OIn2Sn2 tetrahedra that share  a cornercorner with one O(18)In2Sn2 tetrahedra,  a cornercorner with one O(11)In3Sn tetrahedra,  a cornercorner with one O(4)In3Sn tetrahedra,  a cornercorner with one O(7)In3Sn tetrahedra, corners with two equivalent O(14)In3Sn tetrahedra,  an edgeedge with one O(18)In2Sn2 tetrahedra,  an edgeedge with one O(8)In2Sn2 tetrahedra, and  an edgeedge with one O(16)In3Sn tetrahedra. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one In(4), one In(5), one Sn(2), and one Sn(4) atom. In the eleventh O site, O(11) is bonded to one In(1), one In(4), one In(6), and one Sn(4) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(9)In2Sn2 tetrahedra,  a cornercorner with one O(7)In3Sn tetrahedra, corners with two equivalent O(16)In3Sn tetrahedra, corners with two equivalent O(21)In3Sn tetrahedra,  an edgeedge with one O(13)In3Sn tetrahedra,  an edgeedge with one O(7)In3Sn tetrahedra, and  an edgeedge with one O(17)In2Sn2 trigonal pyramid. In the twelfth O site, O(12) is bonded to one In(2), one In(3), one In(7), and one Sn(6) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(18)In2Sn2 tetrahedra,  a cornercorner with one O(21)In3Sn tetrahedra,  a cornercorner with one O(4)In3Sn tetrahedra, corners with two equivalent O(8)In2Sn2 tetrahedra,  a cornercorner with one O(17)In2Sn2 trigonal pyramid,  an edgeedge with one O(13)In3Sn tetrahedra,  an edgeedge with one O(14)In3Sn tetrahedra, and  an edgeedge with one O(4)In3Sn tetrahedra. In the thirteenth O site, O(13) is bonded to one In(1), one In(2), one In(6), and one Sn(6) atom to form distorted OIn3Sn tetrahedra that share  a cornercorner with one O(8)In2Sn2 tetrahedra,  a cornercorner with one O(21)In3Sn tetrahedra,  a cornercorner with one O(4)In3Sn tetrahedra,  a cornercorner with one O(7)In3Sn tetrahedra, corners with two equivalent O(17)In2Sn2 trigonal pyramids,  an edgeedge with one O(11)In3Sn tetrahedra,  an edgeedge with one O(12)In3Sn tetrahedra, and  an edgeedge with one O(21)In3Sn tetrahedra. In the fourteenth O site, O(14) is bonded to one In(3), one In(5), one In(7), and one Sn(5) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(18)In2Sn2 tetrahedra,  a cornercorner with one O(16)In3Sn tetrahedra, corners with two equivalent O(9)In2Sn2 tetrahedra, corners with two equivalent O(4)In3Sn tetrahedra,  an edgeedge with one O(18)In2Sn2 tetrahedra,  an edgeedge with one O(8)In2Sn2 tetrahedra, and  an edgeedge with one O(12)In3Sn tetrahedra. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one In(4), one In(5), one Sn(2), and one Sn(5) atom. In the sixteenth O site, O(16) is bonded to one In(4), one In(5), one In(8), and one Sn(4) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(18)In2Sn2 tetrahedra,  a cornercorner with one O(14)In3Sn tetrahedra,  a cornercorner with one O(21)In3Sn tetrahedra,  a cornercorner with one O(7)In3Sn tetrahedra, corners with two equivalent O(11)In3Sn tetrahedra,  an edgeedge with one O(9)In2Sn2 tetrahedra,  an edgeedge with one O(7)In3Sn tetrahedra, and  an edgeedge with one O(17)In2Sn2 trigonal pyramid. In the seventeenth O site, O(17) is bonded to one In(6), one In(8), one Sn(4), and one Sn(6) atom to form a mixture of distorted corner and edge-sharing OIn2Sn2 trigonal pyramids. In the eighteenth O site, O(18) is bonded to one In(5), one In(7), one Sn(1), and one Sn(5) atom to form distorted OIn2Sn2 tetrahedra that share  a cornercorner with one O(9)In2Sn2 tetrahedra,  a cornercorner with one O(12)In3Sn tetrahedra,  a cornercorner with one O(14)In3Sn tetrahedra,  a cornercorner with one O(16)In3Sn tetrahedra, corners with two equivalent O(8)In2Sn2 tetrahedra,  an edgeedge with one O(9)In2Sn2 tetrahedra,  an edgeedge with one O(14)In3Sn tetrahedra, and  an edgeedge with one O(4)In3Sn tetrahedra. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one In(2), one In(6), one Sn(3), and one Sn(6) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one In(3), one In(7), one Sn(3), and one Sn(5) atom. In the twenty-first O site, O(21) is bonded to one In(1), one In(6), one In(8), and one Sn(6) atom to form OIn3Sn tetrahedra that share  a cornercorner with one O(12)In3Sn tetrahedra,  a cornercorner with one O(13)In3Sn tetrahedra,  a cornercorner with one O(16)In3Sn tetrahedra, corners with two equivalent O(11)In3Sn tetrahedra,  a cornercorner with one O(17)In2Sn2 trigonal pyramid,  an edgeedge with one O(13)In3Sn tetrahedra,  an edgeedge with one O(7)In3Sn tetrahedra, and  an edgeedge with one O(17)In2Sn2 trigonal pyramid. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one In(5), one Sn(1), and one Sn(2) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal non-coplanar geometry to one In(6), one In(8), and one Sn(2) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one In(1), one In(7), one Sn(3), and one Sn(6) atom. is represented by the CIF card [CIF]
data_In4(SnO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.310
_cell_length_b   6.339
_cell_length_c   12.621
_cell_angle_alpha   99.450
_cell_angle_beta   99.373
_cell_angle_gamma   99.263
_symmetry_Int_Tables_number   1
_cell_volume   482.068
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.397  0.864  0.846  1.0
  In  In1  1  0.309  0.602  0.067  1.0
  In  In2  1  0.860  0.688  0.198  1.0
  In  In3  1  0.313  0.605  0.569  1.0
  In  In4  1  0.691  0.396  0.433  1.0
  In  In5  1  0.138  0.311  0.802  1.0
  In  In6  1  0.602  0.134  0.153  1.0
  In  In7  1  0.603  0.135  0.657  1.0
  Sn  Sn8  1  0.396  0.864  0.345  1.0
  Sn  Sn9  1  0.002  0.999  0.501  1.0
  Sn  Sn10  1  0.001  0.001  0.999  1.0
  Sn  Sn11  1  0.862  0.685  0.699  1.0
  Sn  Sn12  1  0.133  0.316  0.300  1.0
  Sn  Sn13  1  0.686  0.398  0.932  1.0
  O  O14  1  0.312  0.938  0.042  1.0
  O  O15  1  0.068  0.902  0.343  1.0
  O  O16  1  0.317  0.943  0.542  1.0
  O  O17  1  0.575  0.826  0.216  1.0
  O  O18  1  0.048  0.903  0.839  1.0
  O  O19  1  0.901  0.685  0.026  1.0
  O  O20  1  0.588  0.817  0.710  1.0
  O  O21  1  0.180  0.576  0.212  1.0
  O  O22  1  0.411  0.583  0.406  1.0
  O  O23  1  0.907  0.691  0.534  1.0
  O  O24  1  0.166  0.583  0.708  1.0
  O  O25  1  0.586  0.420  0.086  1.0
  O  O26  1  0.430  0.578  0.910  1.0
  O  O27  1  0.825  0.412  0.291  1.0
  O  O28  1  0.094  0.310  0.464  1.0
  O  O29  1  0.594  0.424  0.592  1.0
  O  O30  1  0.820  0.432  0.795  1.0
  O  O31  1  0.405  0.176  0.293  1.0
  O  O32  1  0.086  0.314  0.970  1.0
  O  O33  1  0.950  0.092  0.161  1.0
  O  O34  1  0.429  0.181  0.796  1.0
  O  O35  1  0.683  0.048  0.448  1.0
  O  O36  1  0.942  0.095  0.656  1.0
  O  O37  1  0.691  0.071  0.957  1.0
[/CIF]
.