The crystal structure described by EuFeO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Eu(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Fe(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 22-28°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Eu(1) and two equivalent Fe(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Eu(1) and two equivalent Fe(1) atoms. is represented by the CIF file [CIF]
data_EuFeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.522
_cell_length_b   5.522
_cell_length_c   5.522
_cell_angle_alpha   120.335
_cell_angle_beta   119.509
_cell_angle_gamma   90.137
_symmetry_Int_Tables_number   1
_cell_volume   119.222
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.239  0.250  0.989  1.0
  Eu  Eu1  1  0.761  0.750  0.011  1.0
  Fe  Fe2  1  0.000  0.500  0.500  1.0
  Fe  Fe3  1  0.500  0.000  0.500  1.0
  O  O4  1  0.798  0.298  0.000  1.0
  O  O5  1  0.202  0.202  0.500  1.0
  O  O6  1  0.202  0.702  0.000  1.0
  O  O7  1  0.798  0.798  0.500  1.0
  O  O8  1  0.336  0.750  0.586  1.0
  O  O9  1  0.664  0.250  0.414  1.0
[/CIF]
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The crystal structure described by EuFeO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Eu(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Fe(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 22-28°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Eu(1) and two equivalent Fe(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Eu(1) and two equivalent Fe(1) atoms. is represented by the CIF file [CIF]
data_EuFeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.522
_cell_length_b   5.522
_cell_length_c   5.522
_cell_angle_alpha   120.335
_cell_angle_beta   119.509
_cell_angle_gamma   90.137
_symmetry_Int_Tables_number   1
_cell_volume   119.222
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.239  0.250  0.989  1.0
  Eu  Eu1  1  0.761  0.750  0.011  1.0
  Fe  Fe2  1  0.000  0.500  0.500  1.0
  Fe  Fe3  1  0.500  0.000  0.500  1.0
  O  O4  1  0.798  0.298  0.000  1.0
  O  O5  1  0.202  0.202  0.500  1.0
  O  O6  1  0.202  0.702  0.000  1.0
  O  O7  1  0.798  0.798  0.500  1.0
  O  O8  1  0.336  0.750  0.586  1.0
  O  O9  1  0.664  0.250  0.414  1.0
[/CIF]
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