The material structure described by RbP4N7 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 9-coordinate geometry to one N(1), four equivalent N(2), and four equivalent N(3) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(2), one N(3), and two equivalent N(4) atoms to form corner-sharing PN4 tetrahedra. There are four inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one P(1), and one P(2) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one P(1) and two equivalent P(2) atoms. In the third N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent P(1) atoms. In the fourth N site, N(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbP4N7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.685
_cell_length_b   9.897
_cell_length_c   12.327
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   571.516
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.272  0.147  0.750  1.0
  Rb  Rb1  1  0.772  0.353  0.250  1.0
  Rb  Rb2  1  0.728  0.853  0.250  1.0
  Rb  Rb3  1  0.228  0.647  0.750  1.0
  P  P4  1  0.786  0.411  0.870  1.0
  P  P5  1  0.286  0.089  0.130  1.0
  P  P6  1  0.214  0.589  0.370  1.0
  P  P7  1  0.714  0.911  0.630  1.0
  P  P8  1  0.214  0.589  0.130  1.0
  P  P9  1  0.714  0.911  0.870  1.0
  P  P10  1  0.786  0.411  0.630  1.0
  P  P11  1  0.286  0.089  0.370  1.0
  P  P12  1  0.779  0.157  0.000  1.0
  P  P13  1  0.279  0.343  1.000  1.0
  P  P14  1  0.221  0.843  0.500  1.0
  P  P15  1  0.721  0.657  0.500  1.0
  P  P16  1  0.221  0.843  1.000  1.0
  P  P17  1  0.721  0.657  0.000  1.0
  P  P18  1  0.779  0.157  0.500  1.0
  P  P19  1  0.279  0.343  0.500  1.0
  N  N20  1  0.703  0.372  0.750  1.0
  N  N21  1  0.203  0.128  0.250  1.0
  N  N22  1  0.297  0.628  0.250  1.0
  N  N23  1  0.797  0.872  0.750  1.0
  N  N24  1  0.116  0.385  0.894  1.0
  N  N25  1  0.616  0.115  0.106  1.0
  N  N26  1  0.884  0.615  0.394  1.0
  N  N27  1  0.384  0.885  0.606  1.0
  N  N28  1  0.884  0.615  0.106  1.0
  N  N29  1  0.384  0.885  0.894  1.0
  N  N30  1  0.116  0.385  0.606  1.0
  N  N31  1  0.616  0.115  0.394  1.0
  N  N32  1  0.818  0.060  0.900  1.0
  N  N33  1  0.318  0.440  0.100  1.0
  N  N34  1  0.182  0.940  0.400  1.0
  N  N35  1  0.682  0.560  0.600  1.0
  N  N36  1  0.182  0.940  0.100  1.0
  N  N37  1  0.682  0.560  0.900  1.0
  N  N38  1  0.818  0.060  0.600  1.0
  N  N39  1  0.318  0.440  0.400  1.0
  N  N40  1  0.614  0.300  0.956  1.0
  N  N41  1  0.114  0.200  0.044  1.0
  N  N42  1  0.386  0.700  0.456  1.0
  N  N43  1  0.886  0.800  0.544  1.0
  N  N44  1  0.386  0.700  0.044  1.0
  N  N45  1  0.886  0.800  0.956  1.0
  N  N46  1  0.614  0.300  0.544  1.0
  N  N47  1  0.114  0.200  0.456  1.0
[/CIF]
.
The material structure described by RbP4N7 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 9-coordinate geometry to one N(1), four equivalent N(2), and four equivalent N(3) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(2), one N(3), and two equivalent N(4) atoms to form corner-sharing PN4 tetrahedra. There are four inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one P(1), and one P(2) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one P(1) and two equivalent P(2) atoms. In the third N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent P(1) atoms. In the fourth N site, N(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbP4N7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.685
_cell_length_b   9.897
_cell_length_c   12.327
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   571.516
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.272  0.147  0.750  1.0
  Rb  Rb1  1  0.772  0.353  0.250  1.0
  Rb  Rb2  1  0.728  0.853  0.250  1.0
  Rb  Rb3  1  0.228  0.647  0.750  1.0
  P  P4  1  0.786  0.411  0.870  1.0
  P  P5  1  0.286  0.089  0.130  1.0
  P  P6  1  0.214  0.589  0.370  1.0
  P  P7  1  0.714  0.911  0.630  1.0
  P  P8  1  0.214  0.589  0.130  1.0
  P  P9  1  0.714  0.911  0.870  1.0
  P  P10  1  0.786  0.411  0.630  1.0
  P  P11  1  0.286  0.089  0.370  1.0
  P  P12  1  0.779  0.157  0.000  1.0
  P  P13  1  0.279  0.343  1.000  1.0
  P  P14  1  0.221  0.843  0.500  1.0
  P  P15  1  0.721  0.657  0.500  1.0
  P  P16  1  0.221  0.843  1.000  1.0
  P  P17  1  0.721  0.657  0.000  1.0
  P  P18  1  0.779  0.157  0.500  1.0
  P  P19  1  0.279  0.343  0.500  1.0
  N  N20  1  0.703  0.372  0.750  1.0
  N  N21  1  0.203  0.128  0.250  1.0
  N  N22  1  0.297  0.628  0.250  1.0
  N  N23  1  0.797  0.872  0.750  1.0
  N  N24  1  0.116  0.385  0.894  1.0
  N  N25  1  0.616  0.115  0.106  1.0
  N  N26  1  0.884  0.615  0.394  1.0
  N  N27  1  0.384  0.885  0.606  1.0
  N  N28  1  0.884  0.615  0.106  1.0
  N  N29  1  0.384  0.885  0.894  1.0
  N  N30  1  0.116  0.385  0.606  1.0
  N  N31  1  0.616  0.115  0.394  1.0
  N  N32  1  0.818  0.060  0.900  1.0
  N  N33  1  0.318  0.440  0.100  1.0
  N  N34  1  0.182  0.940  0.400  1.0
  N  N35  1  0.682  0.560  0.600  1.0
  N  N36  1  0.182  0.940  0.100  1.0
  N  N37  1  0.682  0.560  0.900  1.0
  N  N38  1  0.818  0.060  0.600  1.0
  N  N39  1  0.318  0.440  0.400  1.0
  N  N40  1  0.614  0.300  0.956  1.0
  N  N41  1  0.114  0.200  0.044  1.0
  N  N42  1  0.386  0.700  0.456  1.0
  N  N43  1  0.886  0.800  0.544  1.0
  N  N44  1  0.386  0.700  0.044  1.0
  N  N45  1  0.886  0.800  0.956  1.0
  N  N46  1  0.614  0.300  0.544  1.0
  N  N47  1  0.114  0.200  0.456  1.0
[/CIF]
.