The material structure described by TbMn5Ge3 crystallizes in the orthorhombic Pnma space group. Tb(1) is bonded in a 6-coordinate geometry to two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one Ge(3) and three equivalent Ge(2) atoms to form a mixture of distorted edge and corner-sharing MnGe4 tetrahedra. In the second Mn site, Mn(2) is bonded to one Ge(1), one Ge(2), and two equivalent Ge(3) atoms to form a mixture of distorted edge and corner-sharing MnGe4 tetrahedra. In the third Mn site, Mn(3) is bonded to one Ge(2), one Ge(3), and two equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing MnGe4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one Ge(3) and three equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing MnGe4 tetrahedra. In the fifth Mn site, Mn(5) is bonded in a 5-coordinate geometry to one Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Tb(1), one Mn(2), one Mn(5), two equivalent Mn(3), and three equivalent Mn(4) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Tb(1), one Mn(2), one Mn(3), two equivalent Mn(5), and three equivalent Mn(1) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Tb(1), one Mn(1), one Mn(3), one Mn(4), two equivalent Mn(2), and two equivalent Mn(5) atoms. is represented by the CIF card [CIF]
data_TbMn5Ge3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.120
_cell_length_b   12.191
_cell_length_c   13.989
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   702.615
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.750  0.412  0.293  1.0
  Tb  Tb1  1  0.250  0.588  0.707  1.0
  Tb  Tb2  1  0.250  0.912  0.207  1.0
  Tb  Tb3  1  0.750  0.088  0.793  1.0
  Mn  Mn4  1  0.750  0.966  0.563  1.0
  Mn  Mn5  1  0.750  0.117  0.313  1.0
  Mn  Mn6  1  0.250  0.293  0.685  1.0
  Mn  Mn7  1  0.750  0.383  0.813  1.0
  Mn  Mn8  1  0.250  0.411  0.498  1.0
  Mn  Mn9  1  0.250  0.617  0.187  1.0
  Mn  Mn10  1  0.750  0.793  0.815  1.0
  Mn  Mn11  1  0.250  0.207  0.185  1.0
  Mn  Mn12  1  0.250  0.089  0.998  1.0
  Mn  Mn13  1  0.750  0.534  0.063  1.0
  Mn  Mn14  1  0.250  0.883  0.687  1.0
  Mn  Mn15  1  0.750  0.291  0.019  1.0
  Mn  Mn16  1  0.750  0.707  0.315  1.0
  Mn  Mn17  1  0.250  0.791  0.481  1.0
  Mn  Mn18  1  0.750  0.911  0.002  1.0
  Mn  Mn19  1  0.750  0.209  0.519  1.0
  Mn  Mn20  1  0.250  0.466  0.937  1.0
  Mn  Mn21  1  0.750  0.589  0.502  1.0
  Mn  Mn22  1  0.250  0.709  0.981  1.0
  Mn  Mn23  1  0.250  0.034  0.437  1.0
  Ge  Ge24  1  0.750  0.411  0.620  1.0
  Ge  Ge25  1  0.250  0.589  0.380  1.0
  Ge  Ge26  1  0.250  0.911  0.880  1.0
  Ge  Ge27  1  0.750  0.910  0.380  1.0
  Ge  Ge28  1  0.250  0.090  0.620  1.0
  Ge  Ge29  1  0.250  0.240  0.378  1.0
  Ge  Ge30  1  0.750  0.590  0.880  1.0
  Ge  Ge31  1  0.750  0.740  0.122  1.0
  Ge  Ge32  1  0.750  0.760  0.622  1.0
  Ge  Ge33  1  0.750  0.089  0.120  1.0
  Ge  Ge34  1  0.250  0.410  0.120  1.0
  Ge  Ge35  1  0.250  0.260  0.878  1.0
[/CIF]
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The material structure described by TbMn5Ge3 crystallizes in the orthorhombic Pnma space group. Tb(1) is bonded in a 6-coordinate geometry to two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one Ge(3) and three equivalent Ge(2) atoms to form a mixture of distorted edge and corner-sharing MnGe4 tetrahedra. In the second Mn site, Mn(2) is bonded to one Ge(1), one Ge(2), and two equivalent Ge(3) atoms to form a mixture of distorted edge and corner-sharing MnGe4 tetrahedra. In the third Mn site, Mn(3) is bonded to one Ge(2), one Ge(3), and two equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing MnGe4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one Ge(3) and three equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing MnGe4 tetrahedra. In the fifth Mn site, Mn(5) is bonded in a 5-coordinate geometry to one Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Tb(1), one Mn(2), one Mn(5), two equivalent Mn(3), and three equivalent Mn(4) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Tb(1), one Mn(2), one Mn(3), two equivalent Mn(5), and three equivalent Mn(1) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Tb(1), one Mn(1), one Mn(3), one Mn(4), two equivalent Mn(2), and two equivalent Mn(5) atoms. is represented by the CIF card [CIF]
data_TbMn5Ge3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.120
_cell_length_b   12.191
_cell_length_c   13.989
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   702.615
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.750  0.412  0.293  1.0
  Tb  Tb1  1  0.250  0.588  0.707  1.0
  Tb  Tb2  1  0.250  0.912  0.207  1.0
  Tb  Tb3  1  0.750  0.088  0.793  1.0
  Mn  Mn4  1  0.750  0.966  0.563  1.0
  Mn  Mn5  1  0.750  0.117  0.313  1.0
  Mn  Mn6  1  0.250  0.293  0.685  1.0
  Mn  Mn7  1  0.750  0.383  0.813  1.0
  Mn  Mn8  1  0.250  0.411  0.498  1.0
  Mn  Mn9  1  0.250  0.617  0.187  1.0
  Mn  Mn10  1  0.750  0.793  0.815  1.0
  Mn  Mn11  1  0.250  0.207  0.185  1.0
  Mn  Mn12  1  0.250  0.089  0.998  1.0
  Mn  Mn13  1  0.750  0.534  0.063  1.0
  Mn  Mn14  1  0.250  0.883  0.687  1.0
  Mn  Mn15  1  0.750  0.291  0.019  1.0
  Mn  Mn16  1  0.750  0.707  0.315  1.0
  Mn  Mn17  1  0.250  0.791  0.481  1.0
  Mn  Mn18  1  0.750  0.911  0.002  1.0
  Mn  Mn19  1  0.750  0.209  0.519  1.0
  Mn  Mn20  1  0.250  0.466  0.937  1.0
  Mn  Mn21  1  0.750  0.589  0.502  1.0
  Mn  Mn22  1  0.250  0.709  0.981  1.0
  Mn  Mn23  1  0.250  0.034  0.437  1.0
  Ge  Ge24  1  0.750  0.411  0.620  1.0
  Ge  Ge25  1  0.250  0.589  0.380  1.0
  Ge  Ge26  1  0.250  0.911  0.880  1.0
  Ge  Ge27  1  0.750  0.910  0.380  1.0
  Ge  Ge28  1  0.250  0.090  0.620  1.0
  Ge  Ge29  1  0.250  0.240  0.378  1.0
  Ge  Ge30  1  0.750  0.590  0.880  1.0
  Ge  Ge31  1  0.750  0.740  0.122  1.0
  Ge  Ge32  1  0.750  0.760  0.622  1.0
  Ge  Ge33  1  0.750  0.089  0.120  1.0
  Ge  Ge34  1  0.250  0.410  0.120  1.0
  Ge  Ge35  1  0.250  0.260  0.878  1.0
[/CIF]
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