The crystal structure described by SnH6(NF2)2 is alpha structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SnH6(NF2)2 clusters. Sn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent F(1), and two equivalent F(2) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_SnH6(NF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.384
_cell_length_b   5.246
_cell_length_c   8.463
_cell_angle_alpha   66.270
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   259.456
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.500  0.000  0.500  1.0
  Sn  Sn1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.265  0.539  0.572  1.0
  H  H3  1  0.235  0.539  0.072  1.0
  H  H4  1  0.735  0.461  0.428  1.0
  H  H5  1  0.765  0.461  0.928  1.0
  H  H6  1  0.123  0.816  0.455  1.0
  H  H7  1  0.377  0.816  0.955  1.0
  H  H8  1  0.877  0.184  0.545  1.0
  H  H9  1  0.623  0.184  0.045  1.0
  H  H10  1  0.151  0.728  0.669  1.0
  H  H11  1  0.349  0.728  0.169  1.0
  H  H12  1  0.849  0.272  0.331  1.0
  H  H13  1  0.651  0.272  0.831  1.0
  N  N14  1  0.224  0.737  0.558  1.0
  N  N15  1  0.276  0.737  0.059  1.0
  N  N16  1  0.776  0.263  0.442  1.0
  N  N17  1  0.724  0.263  0.942  1.0
  F  F18  1  0.687  0.663  0.576  1.0
  F  F19  1  0.813  0.663  0.076  1.0
  F  F20  1  0.313  0.337  0.424  1.0
  F  F21  1  0.187  0.337  0.924  1.0
  F  F22  1  0.499  0.009  0.259  1.0
  F  F23  1  0.001  0.009  0.759  1.0
  F  F24  1  0.501  0.991  0.741  1.0
  F  F25  1  0.999  0.991  0.241  1.0
[/CIF]
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The crystal structure described by SnH6(NF2)2 is alpha structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SnH6(NF2)2 clusters. Sn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent F(1), and two equivalent F(2) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_SnH6(NF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.384
_cell_length_b   5.246
_cell_length_c   8.463
_cell_angle_alpha   66.270
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   259.456
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.500  0.000  0.500  1.0
  Sn  Sn1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.265  0.539  0.572  1.0
  H  H3  1  0.235  0.539  0.072  1.0
  H  H4  1  0.735  0.461  0.428  1.0
  H  H5  1  0.765  0.461  0.928  1.0
  H  H6  1  0.123  0.816  0.455  1.0
  H  H7  1  0.377  0.816  0.955  1.0
  H  H8  1  0.877  0.184  0.545  1.0
  H  H9  1  0.623  0.184  0.045  1.0
  H  H10  1  0.151  0.728  0.669  1.0
  H  H11  1  0.349  0.728  0.169  1.0
  H  H12  1  0.849  0.272  0.331  1.0
  H  H13  1  0.651  0.272  0.831  1.0
  N  N14  1  0.224  0.737  0.558  1.0
  N  N15  1  0.276  0.737  0.059  1.0
  N  N16  1  0.776  0.263  0.442  1.0
  N  N17  1  0.724  0.263  0.942  1.0
  F  F18  1  0.687  0.663  0.576  1.0
  F  F19  1  0.813  0.663  0.076  1.0
  F  F20  1  0.313  0.337  0.424  1.0
  F  F21  1  0.187  0.337  0.924  1.0
  F  F22  1  0.499  0.009  0.259  1.0
  F  F23  1  0.001  0.009  0.759  1.0
  F  F24  1  0.501  0.991  0.741  1.0
  F  F25  1  0.999  0.991  0.241  1.0
[/CIF]
.