The material described by YbTiCdSbO7 crystallizes in the orthorhombic Imma space group. Yb(1) is bonded to two equivalent O(1), two equivalent O(2), and four equivalent O(4) atoms to form distorted YbO8 hexagonal bipyramids that share edges with two equivalent Yb(1)O8 hexagonal bipyramids, edges with four equivalent Cd(1)O8 hexagonal bipyramids, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Ti(1)O6 octahedra. Ti(1) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, edges with two equivalent Cd(1)O8 hexagonal bipyramids, and edges with four equivalent Yb(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 44-45°. Cd(1) is bonded to two equivalent O(1), two equivalent O(3), and four equivalent O(4) atoms to form distorted CdO8 hexagonal bipyramids that share edges with two equivalent Cd(1)O8 hexagonal bipyramids, edges with four equivalent Yb(1)O8 hexagonal bipyramids, edges with two equivalent Ti(1)O6 octahedra, and edges with four equivalent Sb(1)O6 octahedra. Sb(1) is bonded to two equivalent O(3) and four equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, edges with two equivalent Yb(1)O8 hexagonal bipyramids, and edges with four equivalent Cd(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 45-48°. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Yb(1) and two equivalent Cd(1) atoms to form OYb2Cd2 tetrahedra that share corners with two equivalent O(3)Cd2Sb2 tetrahedra, corners with four equivalent O(1)Yb2Cd2 tetrahedra, and  an edgeedge with one O(3)Cd2Sb2 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Yb(1) and two equivalent Ti(1) atoms. In the third O site, O(3) is bonded to two equivalent Cd(1) and two equivalent Sb(1) atoms to form distorted OCd2Sb2 tetrahedra that share corners with two equivalent O(1)Yb2Cd2 tetrahedra, corners with four equivalent O(3)Cd2Sb2 tetrahedra, and  an edgeedge with one O(1)Yb2Cd2 tetrahedra. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Yb(1), one Ti(1), one Cd(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_YbTiCdSbO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.313
_cell_length_b   7.313
_cell_length_c   7.313
_cell_angle_alpha   120.994
_cell_angle_beta   119.050
_cell_angle_gamma   89.970
_symmetry_Int_Tables_number   1
_cell_volume   276.369
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.000  0.000  0.000  1.0
  Yb  Yb1  1  0.500  0.000  0.500  1.0
  Ti  Ti2  1  0.500  0.500  0.500  1.0
  Ti  Ti3  1  0.500  0.000  0.000  1.0
  Cd  Cd4  1  0.000  0.000  0.500  1.0
  Cd  Cd5  1  0.000  0.500  0.000  1.0
  Sb  Sb6  1  0.500  0.500  0.000  1.0
  Sb  Sb7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.121  0.871  0.250  1.0
  O  O9  1  0.879  0.129  0.750  1.0
  O  O10  1  0.430  0.180  0.250  1.0
  O  O11  1  0.829  0.579  0.250  1.0
  O  O12  1  0.432  0.580  0.259  1.0
  O  O13  1  0.821  0.173  0.241  1.0
  O  O14  1  0.432  0.173  0.852  1.0
  O  O15  1  0.821  0.580  0.648  1.0
  O  O16  1  0.570  0.820  0.750  1.0
  O  O17  1  0.171  0.421  0.750  1.0
  O  O18  1  0.568  0.420  0.741  1.0
  O  O19  1  0.179  0.827  0.759  1.0
  O  O20  1  0.568  0.827  0.148  1.0
  O  O21  1  0.179  0.420  0.352  1.0
[/CIF]
.
The material described by YbTiCdSbO7 crystallizes in the orthorhombic Imma space group. Yb(1) is bonded to two equivalent O(1), two equivalent O(2), and four equivalent O(4) atoms to form distorted YbO8 hexagonal bipyramids that share edges with two equivalent Yb(1)O8 hexagonal bipyramids, edges with four equivalent Cd(1)O8 hexagonal bipyramids, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Ti(1)O6 octahedra. Ti(1) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, edges with two equivalent Cd(1)O8 hexagonal bipyramids, and edges with four equivalent Yb(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 44-45°. Cd(1) is bonded to two equivalent O(1), two equivalent O(3), and four equivalent O(4) atoms to form distorted CdO8 hexagonal bipyramids that share edges with two equivalent Cd(1)O8 hexagonal bipyramids, edges with four equivalent Yb(1)O8 hexagonal bipyramids, edges with two equivalent Ti(1)O6 octahedra, and edges with four equivalent Sb(1)O6 octahedra. Sb(1) is bonded to two equivalent O(3) and four equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, edges with two equivalent Yb(1)O8 hexagonal bipyramids, and edges with four equivalent Cd(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 45-48°. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Yb(1) and two equivalent Cd(1) atoms to form OYb2Cd2 tetrahedra that share corners with two equivalent O(3)Cd2Sb2 tetrahedra, corners with four equivalent O(1)Yb2Cd2 tetrahedra, and  an edgeedge with one O(3)Cd2Sb2 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Yb(1) and two equivalent Ti(1) atoms. In the third O site, O(3) is bonded to two equivalent Cd(1) and two equivalent Sb(1) atoms to form distorted OCd2Sb2 tetrahedra that share corners with two equivalent O(1)Yb2Cd2 tetrahedra, corners with four equivalent O(3)Cd2Sb2 tetrahedra, and  an edgeedge with one O(1)Yb2Cd2 tetrahedra. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Yb(1), one Ti(1), one Cd(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_YbTiCdSbO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.313
_cell_length_b   7.313
_cell_length_c   7.313
_cell_angle_alpha   120.994
_cell_angle_beta   119.050
_cell_angle_gamma   89.970
_symmetry_Int_Tables_number   1
_cell_volume   276.369
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.000  0.000  0.000  1.0
  Yb  Yb1  1  0.500  0.000  0.500  1.0
  Ti  Ti2  1  0.500  0.500  0.500  1.0
  Ti  Ti3  1  0.500  0.000  0.000  1.0
  Cd  Cd4  1  0.000  0.000  0.500  1.0
  Cd  Cd5  1  0.000  0.500  0.000  1.0
  Sb  Sb6  1  0.500  0.500  0.000  1.0
  Sb  Sb7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.121  0.871  0.250  1.0
  O  O9  1  0.879  0.129  0.750  1.0
  O  O10  1  0.430  0.180  0.250  1.0
  O  O11  1  0.829  0.579  0.250  1.0
  O  O12  1  0.432  0.580  0.259  1.0
  O  O13  1  0.821  0.173  0.241  1.0
  O  O14  1  0.432  0.173  0.852  1.0
  O  O15  1  0.821  0.580  0.648  1.0
  O  O16  1  0.570  0.820  0.750  1.0
  O  O17  1  0.171  0.421  0.750  1.0
  O  O18  1  0.568  0.420  0.741  1.0
  O  O19  1  0.179  0.827  0.759  1.0
  O  O20  1  0.568  0.827  0.148  1.0
  O  O21  1  0.179  0.420  0.352  1.0
[/CIF]
.