The structure described by Ca5Sc2(CoO6)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(14), one O(15), one O(22), one O(23), one O(5), and one O(7) atom. In the second Ca site, Ca(2) is bonded in a 8-coordinate geometry to one O(12), one O(13), one O(16), one O(21), one O(24), one O(6), one O(8), and one O(9) atom. In the third Ca site, Ca(3) is bonded in a 8-coordinate geometry to one O(13), one O(15), one O(19), one O(2), one O(21), one O(5), one O(7), and one O(9) atom. In the fourth Ca site, Ca(4) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(14), one O(16), one O(20), one O(22), one O(6), and one O(8) atom. In the fifth Ca site, Ca(5) is bonded in a 8-coordinate geometry to one O(11), one O(13), one O(15), one O(17), one O(23), one O(3), one O(6), and one O(8) atom. In the sixth Ca site, Ca(6) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(16), one O(18), one O(24), one O(4), one O(5), and one O(7) atom. In the seventh Ca site, Ca(7) is bonded in a 8-coordinate geometry to one O(13), one O(17), one O(19), one O(2), one O(21), one O(4), one O(7), and one O(9) atom. In the eighth Ca site, Ca(8) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(14), one O(18), one O(20), one O(22), one O(3), and one O(8) atom. In the ninth Ca site, Ca(9) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(15), one O(17), one O(19), one O(23), one O(3), and one O(6) atom. In the tenth Ca site, Ca(10) is bonded in a 8-coordinate geometry to one O(12), one O(16), one O(18), one O(2), one O(20), one O(24), one O(4), and one O(5) atom. There are four inequivalent Sc sites. In the first Sc site, Sc(1) is bonded to one O(1), one O(14), one O(15), one O(21), one O(24), and one O(3) atom to form distorted ScO6 pentagonal pyramids that share  a faceface with one Co(3)O6 octahedra and  a faceface with one Co(4)O6 octahedra. In the second Sc site, Sc(2) is bonded to one O(13), one O(16), one O(2), one O(22), one O(23), and one O(4) atom to form distorted ScO6 pentagonal pyramids that share  a faceface with one Co(1)O6 octahedra and  a faceface with one Co(2)O6 octahedra. In the third Sc site, Sc(3) is bonded to one O(10), one O(11), one O(18), one O(19), one O(5), and one O(7) atom to form distorted ScO6 pentagonal pyramids that share  a faceface with one Co(3)O6 octahedra and  a faceface with one Co(4)O6 octahedra. In the fourth Sc site, Sc(4) is bonded in a 6-coordinate geometry to one O(12), one O(17), one O(20), one O(6), one O(8), and one O(9) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(16), one O(20), one O(22), one O(4), and one O(8) atom to form CoO6 octahedra that share  a faceface with one Sc(2)O6 pentagonal pyramid. In the second Co site, Co(2) is bonded to one O(13), one O(17), one O(2), one O(23), one O(6), and one O(9) atom to form CoO6 octahedra that share  a faceface with one Sc(2)O6 pentagonal pyramid. In the third Co site, Co(3) is bonded to one O(11), one O(15), one O(19), one O(21), one O(3), and one O(7) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid and  a faceface with one Sc(3)O6 pentagonal pyramid. In the fourth Co site, Co(4) is bonded to one O(1), one O(10), one O(14), one O(18), one O(24), and one O(5) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid and  a faceface with one Sc(3)O6 pentagonal pyramid. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Ca(4), one Ca(8), one Ca(9), one Sc(1), and one Co(4) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(22)Ca3ScCo square pyramids,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(15)Ca4ScCo octahedra,  an edgeedge with one O(6)Ca4ScCo octahedra,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(24)Ca3ScCo square pyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(14)Ca4ScCo octahedra, and  a faceface with one O(10)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 7-69°. In the second O site, O(2) is bonded to one Ca(10), one Ca(3), one Ca(7), one Sc(2), and one Co(2) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(21)Ca3ScCo square pyramids,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(16)Ca4ScCo octahedra,  an edgeedge with one O(5)Ca4ScCo octahedra,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(23)Ca3ScCo square pyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(13)Ca4ScCo octahedra, and  a faceface with one O(9)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 4-68°. In the third O site, O(3) is bonded to one Ca(5), one Ca(8), one Ca(9), one Sc(1), and one Co(3) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(23)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(14)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(21)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(15)Ca4ScCo octahedra, and  a faceface with one O(11)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 7-69°. In the fourth O site, O(4) is bonded to one Ca(10), one Ca(6), one Ca(7), one Sc(2), and one Co(1) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(5)Ca4ScCo octahedra,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(24)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(13)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(22)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(16)Ca4ScCo octahedra, and  a faceface with one O(12)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 4-69°. In the fifth O site, O(5) is bonded to one Ca(1), one Ca(10), one Ca(3), one Ca(6), one Sc(3), and one Co(4) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids, corners with two equivalent O(12)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid, corners with two equivalent O(4)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(15)Ca4ScCo octahedra,  an edgeedge with one O(16)Ca4ScCo octahedra,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(14)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(10)Ca3ScCo square pyramid,  a faceface with one O(18)Ca3ScCo square pyramid, and  a faceface with one O(24)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 55-59°. In the sixth O site, O(6) is bonded to one Ca(2), one Ca(4), one Ca(5), one Ca(9), one Sc(4), and one Co(2) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids, corners with two equivalent O(12)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, corners with two equivalent O(3)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(15)Ca4ScCo octahedra,  an edgeedge with one O(16)Ca4ScCo octahedra,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(13)Ca4ScCo octahedra,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(17)Ca3ScCo square pyramid,  a faceface with one O(23)Ca3ScCo square pyramid, and  a faceface with one O(9)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 52-60°. In the seventh O site, O(7) is bonded to one Ca(1), one Ca(3), one Ca(6), one Ca(7), one Sc(3), and one Co(3) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(10)Ca3ScCo square pyramids, corners with two equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid, corners with two equivalent O(2)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(13)Ca4ScCo octahedra,  an edgeedge with one O(14)Ca4ScCo octahedra,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(15)Ca4ScCo octahedra,  a faceface with one O(5)Ca4ScCo octahedra,  a faceface with one O(11)Ca3ScCo square pyramid,  a faceface with one O(19)Ca3ScCo square pyramid, and  a faceface with one O(21)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 55-60°. In the eighth O site, O(8) is bonded to one Ca(2), one Ca(4), one Ca(5), one Ca(8), one Sc(4), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(10)Ca3ScCo square pyramids, corners with two equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid, corners with two equivalent O(1)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(13)Ca4ScCo octahedra,  an edgeedge with one O(14)Ca4ScCo octahedra,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(16)Ca4ScCo octahedra,  a faceface with one O(6)Ca4ScCo octahedra,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(20)Ca3ScCo square pyramid, and  a faceface with one O(22)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 52-59°. In the ninth O site, O(9) is bonded to one Ca(2), one Ca(3), one Ca(7), one Sc(4), and one Co(2) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(12)Ca3ScCo square pyramids,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(21)Ca3ScCo square pyramid,  a faceface with one O(13)Ca4ScCo octahedra,  a faceface with one O(6)Ca4ScCo octahedra,  a faceface with one O(17)Ca3ScCo square pyramid, and  a faceface with one O(2)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 31-63°. In the tenth O site, O(10) is bonded to one Ca(1), one Ca(4), one Ca(8), one Sc(3), and one Co(4) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(22)Ca3ScCo square pyramid,  a faceface with one O(14)Ca4ScCo octahedra,  a faceface with one O(5)Ca4ScCo octahedra,  a faceface with one O(18)Ca3ScCo square pyramid, and  a faceface with one O(1)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 31-62°. In the eleventh O site, O(11) is bonded to one Ca(1), one Ca(5), one Ca(9), one Sc(3), and one Co(3) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4ScCo octahedra,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(10)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(23)Ca3ScCo square pyramid,  a faceface with one O(15)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(19)Ca3ScCo square pyramid, and  a faceface with one O(3)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 31-62°. In the twelfth O site, O(12) is bonded to one Ca(10), one Ca(2), one Ca(6), one Sc(4), and one Co(1) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4ScCo octahedra,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(24)Ca3ScCo square pyramid,  a faceface with one O(16)Ca4ScCo octahedra,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(20)Ca3ScCo square pyramid, and  a faceface with one O(4)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-63°. In the thirteenth O site, O(13) is bonded to one Ca(2), one Ca(3), one Ca(5), one Ca(7), one Sc(2), and one Co(2) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(15)Ca4ScCo octahedra, corners with two equivalent O(16)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(19)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(6)Ca4ScCo octahedra,  a faceface with one O(21)Ca3ScCo square pyramid,  a faceface with one O(23)Ca3ScCo square pyramid,  a faceface with one O(9)Ca3ScCo square pyramid, and  a faceface with one O(2)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-59°. In the fourteenth O site, O(14) is bonded to one Ca(1), one Ca(4), one Ca(6), one Ca(8), one Sc(1), and one Co(4) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(6)Ca4ScCo octahedra, corners with two equivalent O(15)Ca4ScCo octahedra, corners with two equivalent O(16)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(20)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(5)Ca4ScCo octahedra,  a faceface with one O(10)Ca3ScCo square pyramid,  a faceface with one O(22)Ca3ScCo square pyramid,  a faceface with one O(24)Ca3ScCo square pyramid, and  a faceface with one O(1)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 28-60°. In the fifteenth O site, O(15) is bonded to one Ca(1), one Ca(3), one Ca(5), one Ca(9), one Sc(1), and one Co(3) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(13)Ca4ScCo octahedra, corners with two equivalent O(14)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(17)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(5)Ca4ScCo octahedra,  an edgeedge with one O(6)Ca4ScCo octahedra,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(11)Ca3ScCo square pyramid,  a faceface with one O(21)Ca3ScCo square pyramid,  a faceface with one O(23)Ca3ScCo square pyramid, and  a faceface with one O(3)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 28-59°. In the sixteenth O site, O(16) is bonded to one Ca(10), one Ca(2), one Ca(4), one Ca(6), one Sc(2), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(13)Ca4ScCo octahedra, corners with two equivalent O(14)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(18)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(5)Ca4ScCo octahedra,  an edgeedge with one O(6)Ca4ScCo octahedra,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(22)Ca3ScCo square pyramid,  a faceface with one O(24)Ca3ScCo square pyramid, and  a faceface with one O(4)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-60°. In the seventeenth O site, O(17) is bonded to one Ca(5), one Ca(7), one Ca(9), one Sc(4), and one Co(2) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(15)Ca4ScCo octahedra,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(19)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(13)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(23)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(6)Ca4ScCo octahedra, and  a faceface with one O(9)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 3-52°. In the eighteenth O site, O(18) is bonded to one Ca(10), one Ca(6), one Ca(8), one Sc(3), and one Co(4) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(16)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(20)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(14)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(24)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(5)Ca4ScCo octahedra, and  a faceface with one O(10)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 4-49°. In the nineteenth O site, O(19) is bonded to one Ca(3), one Ca(7), one Ca(9), one Sc(3), and one Co(3) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(13)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(17)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(15)Ca4ScCo octahedra,  an edgeedge with one O(5)Ca4ScCo octahedra,  an edgeedge with one O(21)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(7)Ca4ScCo octahedra, and  a faceface with one O(11)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 5-49°. In the twentieth O site, O(20) is bonded to one Ca(10), one Ca(4), one Ca(8), one Sc(4), and one Co(1) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(14)Ca4ScCo octahedra,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(18)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(16)Ca4ScCo octahedra,  an edgeedge with one O(6)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(22)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(8)Ca4ScCo octahedra, and  a faceface with one O(12)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 3-52°. In the twenty-first O site, O(21) is bonded to one Ca(2), one Ca(3), one Ca(7), one Sc(1), and one Co(3) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid, corners with two equivalent O(2)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(24)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(13)Ca4ScCo octahedra,  a faceface with one O(15)Ca4ScCo octahedra, and  a faceface with one O(7)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 39-54°. In the twenty-second O site, O(22) is bonded to one Ca(1), one Ca(4), one Ca(8), one Sc(2), and one Co(1) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid, corners with two equivalent O(1)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(23)Ca3ScCo square pyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(14)Ca4ScCo octahedra,  a faceface with one O(16)Ca4ScCo octahedra, and  a faceface with one O(8)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the twenty-third O site, O(23) is bonded to one Ca(1), one Ca(5), one Ca(9), one Sc(2), and one Co(2) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid, corners with two equivalent O(3)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(22)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(13)Ca4ScCo octahedra,  a faceface with one O(15)Ca4ScCo octahedra, and  a faceface with one O(6)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 43-55°. In the twenty-fourth O site, O(24) is bonded to one Ca(10), one Ca(2), one Ca(6), one Sc(1), and one Co(4) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid, corners with two equivalent O(4)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(21)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(14)Ca4ScCo octahedra,  a faceface with one O(16)Ca4ScCo octahedra, and  a faceface with one O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 39-55°. is represented by the CIF card [CIF]
data_Ca5Sc2(CoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.371
_cell_length_b   9.098
_cell_length_c   9.240
_cell_angle_alpha   89.906
_cell_angle_beta   90.002
_cell_angle_gamma   95.505
_symmetry_Int_Tables_number   1
_cell_volume   533.083
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.250  0.750  0.132  1.0
  Ca  Ca1  1  0.251  0.250  0.637  1.0
  Ca  Ca2  1  0.116  0.563  0.817  1.0
  Ca  Ca3  1  0.108  0.060  0.320  1.0
  Ca  Ca4  1  0.391  0.439  0.320  1.0
  Ca  Ca5  1  0.385  0.938  0.817  1.0
  Ca  Ca6  1  0.625  0.570  0.675  1.0
  Ca  Ca7  1  0.621  0.069  0.182  1.0
  Ca  Ca8  1  0.879  0.429  0.183  1.0
  Ca  Ca9  1  0.875  0.932  0.675  1.0
  Sc  Sc10  1  0.250  0.250  0.003  1.0
  Sc  Sc11  1  0.248  0.751  0.495  1.0
  Sc  Sc12  1  0.750  0.750  0.001  1.0
  Sc  Sc13  1  0.751  0.249  0.511  1.0
  Co  Co14  1  0.492  0.002  0.498  1.0
  Co  Co15  1  0.007  0.499  0.498  1.0
  Co  Co16  1  0.501  0.497  0.997  1.0
  Co  Co17  1  1.000  0.003  0.996  1.0
  O  O18  1  0.975  0.191  0.119  1.0
  O  O19  1  0.968  0.677  0.604  1.0
  O  O20  1  0.526  0.309  0.120  1.0
  O  O21  1  0.530  0.825  0.604  1.0
  O  O22  1  0.042  0.801  0.895  1.0
  O  O23  1  0.051  0.315  0.407  1.0
  O  O24  1  0.459  0.700  0.894  1.0
  O  O25  1  0.449  0.184  0.408  1.0
  O  O26  1  0.929  0.384  0.662  1.0
  O  O27  1  0.922  0.884  0.157  1.0
  O  O28  1  0.577  0.615  0.158  1.0
  O  O29  1  0.576  0.117  0.662  1.0
  O  O30  1  0.298  0.528  0.563  1.0
  O  O31  1  0.293  0.021  0.060  1.0
  O  O32  1  0.208  0.479  0.060  1.0
  O  O33  1  0.202  0.974  0.563  1.0
  O  O34  1  0.718  0.461  0.437  1.0
  O  O35  1  0.720  0.970  0.934  1.0
  O  O36  1  0.780  0.530  0.933  1.0
  O  O37  1  0.781  0.038  0.436  1.0
  O  O38  1  0.397  0.389  0.834  1.0
  O  O39  1  0.387  0.890  0.331  1.0
  O  O40  1  0.109  0.608  0.331  1.0
  O  O41  1  0.104  0.111  0.834  1.0
[/CIF]
.
The structure described by Ca5Sc2(CoO6)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(14), one O(15), one O(22), one O(23), one O(5), and one O(7) atom. In the second Ca site, Ca(2) is bonded in a 8-coordinate geometry to one O(12), one O(13), one O(16), one O(21), one O(24), one O(6), one O(8), and one O(9) atom. In the third Ca site, Ca(3) is bonded in a 8-coordinate geometry to one O(13), one O(15), one O(19), one O(2), one O(21), one O(5), one O(7), and one O(9) atom. In the fourth Ca site, Ca(4) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(14), one O(16), one O(20), one O(22), one O(6), and one O(8) atom. In the fifth Ca site, Ca(5) is bonded in a 8-coordinate geometry to one O(11), one O(13), one O(15), one O(17), one O(23), one O(3), one O(6), and one O(8) atom. In the sixth Ca site, Ca(6) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(16), one O(18), one O(24), one O(4), one O(5), and one O(7) atom. In the seventh Ca site, Ca(7) is bonded in a 8-coordinate geometry to one O(13), one O(17), one O(19), one O(2), one O(21), one O(4), one O(7), and one O(9) atom. In the eighth Ca site, Ca(8) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(14), one O(18), one O(20), one O(22), one O(3), and one O(8) atom. In the ninth Ca site, Ca(9) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(15), one O(17), one O(19), one O(23), one O(3), and one O(6) atom. In the tenth Ca site, Ca(10) is bonded in a 8-coordinate geometry to one O(12), one O(16), one O(18), one O(2), one O(20), one O(24), one O(4), and one O(5) atom. There are four inequivalent Sc sites. In the first Sc site, Sc(1) is bonded to one O(1), one O(14), one O(15), one O(21), one O(24), and one O(3) atom to form distorted ScO6 pentagonal pyramids that share  a faceface with one Co(3)O6 octahedra and  a faceface with one Co(4)O6 octahedra. In the second Sc site, Sc(2) is bonded to one O(13), one O(16), one O(2), one O(22), one O(23), and one O(4) atom to form distorted ScO6 pentagonal pyramids that share  a faceface with one Co(1)O6 octahedra and  a faceface with one Co(2)O6 octahedra. In the third Sc site, Sc(3) is bonded to one O(10), one O(11), one O(18), one O(19), one O(5), and one O(7) atom to form distorted ScO6 pentagonal pyramids that share  a faceface with one Co(3)O6 octahedra and  a faceface with one Co(4)O6 octahedra. In the fourth Sc site, Sc(4) is bonded in a 6-coordinate geometry to one O(12), one O(17), one O(20), one O(6), one O(8), and one O(9) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(16), one O(20), one O(22), one O(4), and one O(8) atom to form CoO6 octahedra that share  a faceface with one Sc(2)O6 pentagonal pyramid. In the second Co site, Co(2) is bonded to one O(13), one O(17), one O(2), one O(23), one O(6), and one O(9) atom to form CoO6 octahedra that share  a faceface with one Sc(2)O6 pentagonal pyramid. In the third Co site, Co(3) is bonded to one O(11), one O(15), one O(19), one O(21), one O(3), and one O(7) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid and  a faceface with one Sc(3)O6 pentagonal pyramid. In the fourth Co site, Co(4) is bonded to one O(1), one O(10), one O(14), one O(18), one O(24), and one O(5) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid and  a faceface with one Sc(3)O6 pentagonal pyramid. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Ca(4), one Ca(8), one Ca(9), one Sc(1), and one Co(4) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(22)Ca3ScCo square pyramids,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(15)Ca4ScCo octahedra,  an edgeedge with one O(6)Ca4ScCo octahedra,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(24)Ca3ScCo square pyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(14)Ca4ScCo octahedra, and  a faceface with one O(10)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 7-69°. In the second O site, O(2) is bonded to one Ca(10), one Ca(3), one Ca(7), one Sc(2), and one Co(2) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(21)Ca3ScCo square pyramids,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(16)Ca4ScCo octahedra,  an edgeedge with one O(5)Ca4ScCo octahedra,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(23)Ca3ScCo square pyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(13)Ca4ScCo octahedra, and  a faceface with one O(9)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 4-68°. In the third O site, O(3) is bonded to one Ca(5), one Ca(8), one Ca(9), one Sc(1), and one Co(3) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(23)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(14)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(21)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(15)Ca4ScCo octahedra, and  a faceface with one O(11)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 7-69°. In the fourth O site, O(4) is bonded to one Ca(10), one Ca(6), one Ca(7), one Sc(2), and one Co(1) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(5)Ca4ScCo octahedra,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(24)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(13)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(22)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(16)Ca4ScCo octahedra, and  a faceface with one O(12)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 4-69°. In the fifth O site, O(5) is bonded to one Ca(1), one Ca(10), one Ca(3), one Ca(6), one Sc(3), and one Co(4) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids, corners with two equivalent O(12)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid, corners with two equivalent O(4)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(15)Ca4ScCo octahedra,  an edgeedge with one O(16)Ca4ScCo octahedra,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(14)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(10)Ca3ScCo square pyramid,  a faceface with one O(18)Ca3ScCo square pyramid, and  a faceface with one O(24)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 55-59°. In the sixth O site, O(6) is bonded to one Ca(2), one Ca(4), one Ca(5), one Ca(9), one Sc(4), and one Co(2) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids, corners with two equivalent O(12)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, corners with two equivalent O(3)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(15)Ca4ScCo octahedra,  an edgeedge with one O(16)Ca4ScCo octahedra,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(13)Ca4ScCo octahedra,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(17)Ca3ScCo square pyramid,  a faceface with one O(23)Ca3ScCo square pyramid, and  a faceface with one O(9)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 52-60°. In the seventh O site, O(7) is bonded to one Ca(1), one Ca(3), one Ca(6), one Ca(7), one Sc(3), and one Co(3) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(10)Ca3ScCo square pyramids, corners with two equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid, corners with two equivalent O(2)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(13)Ca4ScCo octahedra,  an edgeedge with one O(14)Ca4ScCo octahedra,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(15)Ca4ScCo octahedra,  a faceface with one O(5)Ca4ScCo octahedra,  a faceface with one O(11)Ca3ScCo square pyramid,  a faceface with one O(19)Ca3ScCo square pyramid, and  a faceface with one O(21)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 55-60°. In the eighth O site, O(8) is bonded to one Ca(2), one Ca(4), one Ca(5), one Ca(8), one Sc(4), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(10)Ca3ScCo square pyramids, corners with two equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid, corners with two equivalent O(1)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(13)Ca4ScCo octahedra,  an edgeedge with one O(14)Ca4ScCo octahedra,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(16)Ca4ScCo octahedra,  a faceface with one O(6)Ca4ScCo octahedra,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(20)Ca3ScCo square pyramid, and  a faceface with one O(22)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 52-59°. In the ninth O site, O(9) is bonded to one Ca(2), one Ca(3), one Ca(7), one Sc(4), and one Co(2) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(12)Ca3ScCo square pyramids,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(21)Ca3ScCo square pyramid,  a faceface with one O(13)Ca4ScCo octahedra,  a faceface with one O(6)Ca4ScCo octahedra,  a faceface with one O(17)Ca3ScCo square pyramid, and  a faceface with one O(2)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 31-63°. In the tenth O site, O(10) is bonded to one Ca(1), one Ca(4), one Ca(8), one Sc(3), and one Co(4) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(22)Ca3ScCo square pyramid,  a faceface with one O(14)Ca4ScCo octahedra,  a faceface with one O(5)Ca4ScCo octahedra,  a faceface with one O(18)Ca3ScCo square pyramid, and  a faceface with one O(1)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 31-62°. In the eleventh O site, O(11) is bonded to one Ca(1), one Ca(5), one Ca(9), one Sc(3), and one Co(3) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4ScCo octahedra,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(10)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(23)Ca3ScCo square pyramid,  a faceface with one O(15)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(19)Ca3ScCo square pyramid, and  a faceface with one O(3)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 31-62°. In the twelfth O site, O(12) is bonded to one Ca(10), one Ca(2), one Ca(6), one Sc(4), and one Co(1) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4ScCo octahedra,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(24)Ca3ScCo square pyramid,  a faceface with one O(16)Ca4ScCo octahedra,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(20)Ca3ScCo square pyramid, and  a faceface with one O(4)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-63°. In the thirteenth O site, O(13) is bonded to one Ca(2), one Ca(3), one Ca(5), one Ca(7), one Sc(2), and one Co(2) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(15)Ca4ScCo octahedra, corners with two equivalent O(16)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(19)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(6)Ca4ScCo octahedra,  a faceface with one O(21)Ca3ScCo square pyramid,  a faceface with one O(23)Ca3ScCo square pyramid,  a faceface with one O(9)Ca3ScCo square pyramid, and  a faceface with one O(2)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-59°. In the fourteenth O site, O(14) is bonded to one Ca(1), one Ca(4), one Ca(6), one Ca(8), one Sc(1), and one Co(4) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(6)Ca4ScCo octahedra, corners with two equivalent O(15)Ca4ScCo octahedra, corners with two equivalent O(16)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(20)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(5)Ca4ScCo octahedra,  a faceface with one O(10)Ca3ScCo square pyramid,  a faceface with one O(22)Ca3ScCo square pyramid,  a faceface with one O(24)Ca3ScCo square pyramid, and  a faceface with one O(1)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 28-60°. In the fifteenth O site, O(15) is bonded to one Ca(1), one Ca(3), one Ca(5), one Ca(9), one Sc(1), and one Co(3) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(13)Ca4ScCo octahedra, corners with two equivalent O(14)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(17)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(5)Ca4ScCo octahedra,  an edgeedge with one O(6)Ca4ScCo octahedra,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(11)Ca3ScCo square pyramid,  a faceface with one O(21)Ca3ScCo square pyramid,  a faceface with one O(23)Ca3ScCo square pyramid, and  a faceface with one O(3)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 28-59°. In the sixteenth O site, O(16) is bonded to one Ca(10), one Ca(2), one Ca(4), one Ca(6), one Sc(2), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(13)Ca4ScCo octahedra, corners with two equivalent O(14)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(18)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(5)Ca4ScCo octahedra,  an edgeedge with one O(6)Ca4ScCo octahedra,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(22)Ca3ScCo square pyramid,  a faceface with one O(24)Ca3ScCo square pyramid, and  a faceface with one O(4)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-60°. In the seventeenth O site, O(17) is bonded to one Ca(5), one Ca(7), one Ca(9), one Sc(4), and one Co(2) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(15)Ca4ScCo octahedra,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(19)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(13)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(23)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(6)Ca4ScCo octahedra, and  a faceface with one O(9)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 3-52°. In the eighteenth O site, O(18) is bonded to one Ca(10), one Ca(6), one Ca(8), one Sc(3), and one Co(4) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(16)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid, corners with two equivalent O(20)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(14)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(24)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(5)Ca4ScCo octahedra, and  a faceface with one O(10)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 4-49°. In the nineteenth O site, O(19) is bonded to one Ca(3), one Ca(7), one Ca(9), one Sc(3), and one Co(3) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(13)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(21)Ca3ScCo square pyramid,  a cornercorner with one O(23)Ca3ScCo square pyramid, corners with two equivalent O(17)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(15)Ca4ScCo octahedra,  an edgeedge with one O(5)Ca4ScCo octahedra,  an edgeedge with one O(21)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(7)Ca4ScCo octahedra, and  a faceface with one O(11)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 5-49°. In the twentieth O site, O(20) is bonded to one Ca(10), one Ca(4), one Ca(8), one Sc(4), and one Co(1) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(14)Ca4ScCo octahedra,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(22)Ca3ScCo square pyramid,  a cornercorner with one O(24)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(18)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(16)Ca4ScCo octahedra,  an edgeedge with one O(6)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(22)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(8)Ca4ScCo octahedra, and  a faceface with one O(12)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 3-52°. In the twenty-first O site, O(21) is bonded to one Ca(2), one Ca(3), one Ca(7), one Sc(1), and one Co(3) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid, corners with two equivalent O(2)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(19)Ca3ScCo square pyramid,  an edgeedge with one O(24)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(3)Ca3ScCo trigonal bipyramid,  a faceface with one O(13)Ca4ScCo octahedra,  a faceface with one O(15)Ca4ScCo octahedra, and  a faceface with one O(7)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 39-54°. In the twenty-second O site, O(22) is bonded to one Ca(1), one Ca(4), one Ca(8), one Sc(2), and one Co(1) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid, corners with two equivalent O(1)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(20)Ca3ScCo square pyramid,  an edgeedge with one O(23)Ca3ScCo square pyramid,  an edgeedge with one O(4)Ca3ScCo trigonal bipyramid,  a faceface with one O(14)Ca4ScCo octahedra,  a faceface with one O(16)Ca4ScCo octahedra, and  a faceface with one O(8)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the twenty-third O site, O(23) is bonded to one Ca(1), one Ca(5), one Ca(9), one Sc(2), and one Co(2) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(14)Ca4ScCo octahedra,  a cornercorner with one O(16)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(17)Ca3ScCo square pyramid,  a cornercorner with one O(19)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(4)Ca3ScCo trigonal bipyramid, corners with two equivalent O(3)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(17)Ca3ScCo square pyramid,  an edgeedge with one O(22)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(13)Ca4ScCo octahedra,  a faceface with one O(15)Ca4ScCo octahedra, and  a faceface with one O(6)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 43-55°. In the twenty-fourth O site, O(24) is bonded to one Ca(10), one Ca(2), one Ca(6), one Sc(1), and one Co(4) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(13)Ca4ScCo octahedra,  a cornercorner with one O(15)Ca4ScCo octahedra,  a cornercorner with one O(6)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(18)Ca3ScCo square pyramid,  a cornercorner with one O(20)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(3)Ca3ScCo trigonal bipyramid, corners with two equivalent O(4)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(18)Ca3ScCo square pyramid,  an edgeedge with one O(21)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(14)Ca4ScCo octahedra,  a faceface with one O(16)Ca4ScCo octahedra, and  a faceface with one O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 39-55°. is represented by the CIF card [CIF]
data_Ca5Sc2(CoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.371
_cell_length_b   9.098
_cell_length_c   9.240
_cell_angle_alpha   89.906
_cell_angle_beta   90.002
_cell_angle_gamma   95.505
_symmetry_Int_Tables_number   1
_cell_volume   533.083
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.250  0.750  0.132  1.0
  Ca  Ca1  1  0.251  0.250  0.637  1.0
  Ca  Ca2  1  0.116  0.563  0.817  1.0
  Ca  Ca3  1  0.108  0.060  0.320  1.0
  Ca  Ca4  1  0.391  0.439  0.320  1.0
  Ca  Ca5  1  0.385  0.938  0.817  1.0
  Ca  Ca6  1  0.625  0.570  0.675  1.0
  Ca  Ca7  1  0.621  0.069  0.182  1.0
  Ca  Ca8  1  0.879  0.429  0.183  1.0
  Ca  Ca9  1  0.875  0.932  0.675  1.0
  Sc  Sc10  1  0.250  0.250  0.003  1.0
  Sc  Sc11  1  0.248  0.751  0.495  1.0
  Sc  Sc12  1  0.750  0.750  0.001  1.0
  Sc  Sc13  1  0.751  0.249  0.511  1.0
  Co  Co14  1  0.492  0.002  0.498  1.0
  Co  Co15  1  0.007  0.499  0.498  1.0
  Co  Co16  1  0.501  0.497  0.997  1.0
  Co  Co17  1  1.000  0.003  0.996  1.0
  O  O18  1  0.975  0.191  0.119  1.0
  O  O19  1  0.968  0.677  0.604  1.0
  O  O20  1  0.526  0.309  0.120  1.0
  O  O21  1  0.530  0.825  0.604  1.0
  O  O22  1  0.042  0.801  0.895  1.0
  O  O23  1  0.051  0.315  0.407  1.0
  O  O24  1  0.459  0.700  0.894  1.0
  O  O25  1  0.449  0.184  0.408  1.0
  O  O26  1  0.929  0.384  0.662  1.0
  O  O27  1  0.922  0.884  0.157  1.0
  O  O28  1  0.577  0.615  0.158  1.0
  O  O29  1  0.576  0.117  0.662  1.0
  O  O30  1  0.298  0.528  0.563  1.0
  O  O31  1  0.293  0.021  0.060  1.0
  O  O32  1  0.208  0.479  0.060  1.0
  O  O33  1  0.202  0.974  0.563  1.0
  O  O34  1  0.718  0.461  0.437  1.0
  O  O35  1  0.720  0.970  0.934  1.0
  O  O36  1  0.780  0.530  0.933  1.0
  O  O37  1  0.781  0.038  0.436  1.0
  O  O38  1  0.397  0.389  0.834  1.0
  O  O39  1  0.387  0.890  0.331  1.0
  O  O40  1  0.109  0.608  0.331  1.0
  O  O41  1  0.104  0.111  0.834  1.0
[/CIF]
.