The material structure described by LiCr(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with six equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Li(1), one Cr(1), and one C(1) atom. is represented by the CIF card [CIF]
data_LiCr(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.667
_cell_length_b   4.667
_cell_length_c   5.738
_cell_angle_alpha   113.994
_cell_angle_beta   90.005
_cell_angle_gamma   119.995
_symmetry_Int_Tables_number   1
_cell_volume   95.564
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.244  0.487  0.731  1.0
  C  C1  1  0.756  0.513  0.269  1.0
  Cr  Cr2  1  0.500  1.000  0.500  1.0
  Li  Li3  1  0.000  0.000  1.000  1.0
  O  O4  1  0.040  0.781  0.266  1.0
  O  O5  1  0.514  0.474  0.734  1.0
  O  O6  1  0.260  0.774  0.734  1.0
  O  O7  1  0.740  0.226  0.266  1.0
  O  O8  1  0.486  0.526  0.266  1.0
  O  O9  1  0.960  0.219  0.734  1.0
[/CIF]
.
The material structure described by LiCr(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with six equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Li(1), one Cr(1), and one C(1) atom. is represented by the CIF card [CIF]
data_LiCr(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.667
_cell_length_b   4.667
_cell_length_c   5.738
_cell_angle_alpha   113.994
_cell_angle_beta   90.005
_cell_angle_gamma   119.995
_symmetry_Int_Tables_number   1
_cell_volume   95.564
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.244  0.487  0.731  1.0
  C  C1  1  0.756  0.513  0.269  1.0
  Cr  Cr2  1  0.500  1.000  0.500  1.0
  Li  Li3  1  0.000  0.000  1.000  1.0
  O  O4  1  0.040  0.781  0.266  1.0
  O  O5  1  0.514  0.474  0.734  1.0
  O  O6  1  0.260  0.774  0.734  1.0
  O  O7  1  0.740  0.226  0.266  1.0
  O  O8  1  0.486  0.526  0.266  1.0
  O  O9  1  0.960  0.219  0.734  1.0
[/CIF]
.