The structure described by NdLa3(GaO3)4 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pm space group. Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to two equivalent O(3), two equivalent O(4), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the third La site, La(3) is bonded in a 6-coordinate geometry to one O(3), one O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-25°. In the second Ga site, Ga(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-27°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Ga(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Ga(2) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), two equivalent La(2), and two equivalent Ga(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one La(3), two equivalent La(2), and two equivalent Ga(2) atoms. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one Ga(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La3Nd(GaO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.860
_cell_length_b   5.556
_cell_length_c   5.557
_cell_angle_alpha   89.900
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   242.686
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.527  0.993  1.0
  La  La1  1  0.500  0.975  0.493  1.0
  La  La2  1  0.500  0.472  0.008  1.0
  Nd  Nd3  1  0.000  0.035  0.510  1.0
  Ga  Ga4  1  0.249  0.502  0.500  1.0
  Ga  Ga5  1  0.751  0.999  0.000  1.0
  Ga  Ga6  1  0.751  0.502  0.500  1.0
  Ga  Ga7  1  0.249  0.999  0.000  1.0
  O  O8  1  0.000  0.482  0.424  1.0
  O  O9  1  0.000  0.987  0.084  1.0
  O  O10  1  0.500  0.512  0.577  1.0
  O  O11  1  0.500  0.012  0.924  1.0
  O  O12  1  0.206  0.782  0.718  1.0
  O  O13  1  0.794  0.277  0.776  1.0
  O  O14  1  0.710  0.220  0.279  1.0
  O  O15  1  0.291  0.719  0.219  1.0
  O  O16  1  0.290  0.220  0.279  1.0
  O  O17  1  0.709  0.719  0.219  1.0
  O  O18  1  0.794  0.782  0.718  1.0
  O  O19  1  0.206  0.277  0.776  1.0
[/CIF]
.
The structure described by NdLa3(GaO3)4 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pm space group. Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to two equivalent O(3), two equivalent O(4), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the third La site, La(3) is bonded in a 6-coordinate geometry to one O(3), one O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-25°. In the second Ga site, Ga(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-27°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Ga(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Ga(2) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), two equivalent La(2), and two equivalent Ga(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one La(3), two equivalent La(2), and two equivalent Ga(2) atoms. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one Ga(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La3Nd(GaO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.860
_cell_length_b   5.556
_cell_length_c   5.557
_cell_angle_alpha   89.900
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   242.686
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.527  0.993  1.0
  La  La1  1  0.500  0.975  0.493  1.0
  La  La2  1  0.500  0.472  0.008  1.0
  Nd  Nd3  1  0.000  0.035  0.510  1.0
  Ga  Ga4  1  0.249  0.502  0.500  1.0
  Ga  Ga5  1  0.751  0.999  0.000  1.0
  Ga  Ga6  1  0.751  0.502  0.500  1.0
  Ga  Ga7  1  0.249  0.999  0.000  1.0
  O  O8  1  0.000  0.482  0.424  1.0
  O  O9  1  0.000  0.987  0.084  1.0
  O  O10  1  0.500  0.512  0.577  1.0
  O  O11  1  0.500  0.012  0.924  1.0
  O  O12  1  0.206  0.782  0.718  1.0
  O  O13  1  0.794  0.277  0.776  1.0
  O  O14  1  0.710  0.220  0.279  1.0
  O  O15  1  0.291  0.719  0.219  1.0
  O  O16  1  0.290  0.220  0.279  1.0
  O  O17  1  0.709  0.719  0.219  1.0
  O  O18  1  0.794  0.782  0.718  1.0
  O  O19  1  0.206  0.277  0.776  1.0
[/CIF]
.