The crystal structure described by XeF5Sb2F11 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Sb2F11 clusters and two XeF5 clusters. In each Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(10), one F(11), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 35°. In the second Sb site, Sb(2) is bonded to one F(11), one F(12), one F(13), one F(14), one F(15), and one F(16) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 35°. There are eleven inequivalent F sites. In the first F site, F(14) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(15) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(16) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(10) is bonded in a single-bond geometry to one Sb(1) atom. In the ninth F site, F(11) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the tenth F site, F(12) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh F site, F(13) is bonded in a single-bond geometry to one Sb(2) atom. In each XeF5 cluster, Xe(1) is bonded in a square pyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_Sb2XeF16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.869
_cell_length_b   8.901
_cell_length_c   9.596
_cell_angle_alpha   68.818
_cell_angle_beta   75.599
_cell_angle_gamma   76.702
_symmetry_Int_Tables_number   1
_cell_volume   675.952
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.900  0.291  0.753  1.0
  Sb  Sb1  1  0.100  0.709  0.247  1.0
  Sb  Sb2  1  0.733  0.920  0.742  1.0
  Sb  Sb3  1  0.267  0.080  0.258  1.0
  Xe  Xe4  1  0.738  0.374  0.296  1.0
  Xe  Xe5  1  0.262  0.626  0.704  1.0
  F  F6  1  0.575  0.465  0.170  1.0
  F  F7  1  0.425  0.535  0.830  1.0
  F  F8  1  0.873  0.455  0.098  1.0
  F  F9  1  0.127  0.545  0.902  1.0
  F  F10  1  0.691  0.597  0.308  1.0
  F  F11  1  0.309  0.403  0.692  1.0
  F  F12  1  0.551  0.326  0.455  1.0
  F  F13  1  0.449  0.674  0.545  1.0
  F  F14  1  0.735  0.180  0.247  1.0
  F  F15  1  0.265  0.820  0.753  1.0
  F  F16  1  0.063  0.197  0.626  1.0
  F  F17  1  0.937  0.803  0.374  1.0
  F  F18  1  0.720  0.360  0.883  1.0
  F  F19  1  0.280  0.640  0.117  1.0
  F  F20  1  0.006  0.190  0.919  1.0
  F  F21  1  0.994  0.810  0.081  1.0
  F  F22  1  0.983  0.490  0.690  1.0
  F  F23  1  0.017  0.510  0.310  1.0
  F  F24  1  0.779  0.373  0.591  1.0
  F  F25  1  0.221  0.627  0.409  1.0
  F  F26  1  0.806  0.078  0.818  1.0
  F  F27  1  0.194  0.922  0.182  1.0
  F  F28  1  0.532  0.050  0.760  1.0
  F  F29  1  0.468  0.950  0.240  1.0
  F  F30  1  0.692  0.792  0.949  1.0
  F  F31  1  0.308  0.208  0.051  1.0
  F  F32  1  0.669  0.778  0.669  1.0
  F  F33  1  0.331  0.222  0.331  1.0
  F  F34  1  0.949  0.815  0.726  1.0
  F  F35  1  0.051  0.185  0.274  1.0
  F  F36  1  0.794  0.069  0.542  1.0
  F  F37  1  0.206  0.931  0.458  1.0
[/CIF]
.
The crystal structure described by XeF5Sb2F11 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Sb2F11 clusters and two XeF5 clusters. In each Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(10), one F(11), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 35°. In the second Sb site, Sb(2) is bonded to one F(11), one F(12), one F(13), one F(14), one F(15), and one F(16) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 35°. There are eleven inequivalent F sites. In the first F site, F(14) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(15) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(16) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(10) is bonded in a single-bond geometry to one Sb(1) atom. In the ninth F site, F(11) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the tenth F site, F(12) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh F site, F(13) is bonded in a single-bond geometry to one Sb(2) atom. In each XeF5 cluster, Xe(1) is bonded in a square pyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_Sb2XeF16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.869
_cell_length_b   8.901
_cell_length_c   9.596
_cell_angle_alpha   68.818
_cell_angle_beta   75.599
_cell_angle_gamma   76.702
_symmetry_Int_Tables_number   1
_cell_volume   675.952
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.900  0.291  0.753  1.0
  Sb  Sb1  1  0.100  0.709  0.247  1.0
  Sb  Sb2  1  0.733  0.920  0.742  1.0
  Sb  Sb3  1  0.267  0.080  0.258  1.0
  Xe  Xe4  1  0.738  0.374  0.296  1.0
  Xe  Xe5  1  0.262  0.626  0.704  1.0
  F  F6  1  0.575  0.465  0.170  1.0
  F  F7  1  0.425  0.535  0.830  1.0
  F  F8  1  0.873  0.455  0.098  1.0
  F  F9  1  0.127  0.545  0.902  1.0
  F  F10  1  0.691  0.597  0.308  1.0
  F  F11  1  0.309  0.403  0.692  1.0
  F  F12  1  0.551  0.326  0.455  1.0
  F  F13  1  0.449  0.674  0.545  1.0
  F  F14  1  0.735  0.180  0.247  1.0
  F  F15  1  0.265  0.820  0.753  1.0
  F  F16  1  0.063  0.197  0.626  1.0
  F  F17  1  0.937  0.803  0.374  1.0
  F  F18  1  0.720  0.360  0.883  1.0
  F  F19  1  0.280  0.640  0.117  1.0
  F  F20  1  0.006  0.190  0.919  1.0
  F  F21  1  0.994  0.810  0.081  1.0
  F  F22  1  0.983  0.490  0.690  1.0
  F  F23  1  0.017  0.510  0.310  1.0
  F  F24  1  0.779  0.373  0.591  1.0
  F  F25  1  0.221  0.627  0.409  1.0
  F  F26  1  0.806  0.078  0.818  1.0
  F  F27  1  0.194  0.922  0.182  1.0
  F  F28  1  0.532  0.050  0.760  1.0
  F  F29  1  0.468  0.950  0.240  1.0
  F  F30  1  0.692  0.792  0.949  1.0
  F  F31  1  0.308  0.208  0.051  1.0
  F  F32  1  0.669  0.778  0.669  1.0
  F  F33  1  0.331  0.222  0.331  1.0
  F  F34  1  0.949  0.815  0.726  1.0
  F  F35  1  0.051  0.185  0.274  1.0
  F  F36  1  0.794  0.069  0.542  1.0
  F  F37  1  0.206  0.931  0.458  1.0
[/CIF]
.