The material described by Mn2Si(P2O7)2 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. Si(1) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form SiO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra,  a cornercorner with one Si(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-55°. In the second P site, P(2) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra,  a cornercorner with one Si(1)O4 tetrahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-62°. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one P(1) atom. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Si(1) and one P(2) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(2) atom. In the sixth O site, O(7) is bonded in a trigonal planar geometry to two equivalent Mn(1) and one P(2) atom. In the seventh O site, O(1) is bonded in a linear geometry to one Si(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2Si(P2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.047
_cell_length_b   9.047
_cell_length_c   12.562
_cell_angle_alpha   77.425
_cell_angle_beta   77.425
_cell_angle_gamma   33.225
_symmetry_Int_Tables_number   1
_cell_volume   548.636
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.910  0.597  0.631  1.0
  Mn  Mn1  1  0.403  0.090  0.869  1.0
  Mn  Mn2  1  0.090  0.403  0.369  1.0
  Mn  Mn3  1  0.597  0.910  0.131  1.0
  Si  Si4  1  0.860  0.140  0.750  1.0
  Si  Si5  1  0.140  0.860  0.250  1.0
  P  P6  1  0.704  0.029  0.417  1.0
  P  P7  1  0.971  0.296  0.083  1.0
  P  P8  1  0.296  0.971  0.583  1.0
  P  P9  1  0.029  0.704  0.917  1.0
  P  P10  1  0.527  0.227  0.634  1.0
  P  P11  1  0.773  0.473  0.866  1.0
  P  P12  1  0.473  0.773  0.366  1.0
  P  P13  1  0.227  0.527  0.134  1.0
  O  O14  1  0.897  0.980  0.332  1.0
  O  O15  1  0.020  0.103  0.168  1.0
  O  O16  1  0.103  0.020  0.668  1.0
  O  O17  1  0.980  0.897  0.832  1.0
  O  O18  1  0.162  0.233  0.547  1.0
  O  O19  1  0.767  0.838  0.953  1.0
  O  O20  1  0.838  0.767  0.453  1.0
  O  O21  1  0.233  0.162  0.047  1.0
  O  O22  1  0.572  0.739  0.627  1.0
  O  O23  1  0.261  0.428  0.873  1.0
  O  O24  1  0.428  0.261  0.373  1.0
  O  O25  1  0.739  0.572  0.127  1.0
  O  O26  1  0.697  0.119  0.518  1.0
  O  O27  1  0.881  0.303  0.982  1.0
  O  O28  1  0.285  0.625  0.180  1.0
  O  O29  1  0.375  0.715  0.320  1.0
  O  O30  1  0.715  0.375  0.820  1.0
  O  O31  1  0.625  0.285  0.680  1.0
  O  O32  1  0.490  0.228  0.121  1.0
  O  O33  1  0.772  0.510  0.379  1.0
  O  O34  1  0.510  0.772  0.879  1.0
  O  O35  1  0.228  0.490  0.621  1.0
  O  O36  1  0.377  0.002  0.297  1.0
  O  O37  1  0.998  0.623  0.203  1.0
  O  O38  1  0.623  0.998  0.703  1.0
  O  O39  1  0.002  0.377  0.797  1.0
  O  O40  1  0.119  0.697  0.018  1.0
  O  O41  1  0.303  0.881  0.482  1.0
[/CIF]
.
The material described by Mn2Si(P2O7)2 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. Si(1) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form SiO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra,  a cornercorner with one Si(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-55°. In the second P site, P(2) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra,  a cornercorner with one Si(1)O4 tetrahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-62°. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one P(1) atom. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Si(1) and one P(2) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(2) atom. In the sixth O site, O(7) is bonded in a trigonal planar geometry to two equivalent Mn(1) and one P(2) atom. In the seventh O site, O(1) is bonded in a linear geometry to one Si(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2Si(P2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.047
_cell_length_b   9.047
_cell_length_c   12.562
_cell_angle_alpha   77.425
_cell_angle_beta   77.425
_cell_angle_gamma   33.225
_symmetry_Int_Tables_number   1
_cell_volume   548.636
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.910  0.597  0.631  1.0
  Mn  Mn1  1  0.403  0.090  0.869  1.0
  Mn  Mn2  1  0.090  0.403  0.369  1.0
  Mn  Mn3  1  0.597  0.910  0.131  1.0
  Si  Si4  1  0.860  0.140  0.750  1.0
  Si  Si5  1  0.140  0.860  0.250  1.0
  P  P6  1  0.704  0.029  0.417  1.0
  P  P7  1  0.971  0.296  0.083  1.0
  P  P8  1  0.296  0.971  0.583  1.0
  P  P9  1  0.029  0.704  0.917  1.0
  P  P10  1  0.527  0.227  0.634  1.0
  P  P11  1  0.773  0.473  0.866  1.0
  P  P12  1  0.473  0.773  0.366  1.0
  P  P13  1  0.227  0.527  0.134  1.0
  O  O14  1  0.897  0.980  0.332  1.0
  O  O15  1  0.020  0.103  0.168  1.0
  O  O16  1  0.103  0.020  0.668  1.0
  O  O17  1  0.980  0.897  0.832  1.0
  O  O18  1  0.162  0.233  0.547  1.0
  O  O19  1  0.767  0.838  0.953  1.0
  O  O20  1  0.838  0.767  0.453  1.0
  O  O21  1  0.233  0.162  0.047  1.0
  O  O22  1  0.572  0.739  0.627  1.0
  O  O23  1  0.261  0.428  0.873  1.0
  O  O24  1  0.428  0.261  0.373  1.0
  O  O25  1  0.739  0.572  0.127  1.0
  O  O26  1  0.697  0.119  0.518  1.0
  O  O27  1  0.881  0.303  0.982  1.0
  O  O28  1  0.285  0.625  0.180  1.0
  O  O29  1  0.375  0.715  0.320  1.0
  O  O30  1  0.715  0.375  0.820  1.0
  O  O31  1  0.625  0.285  0.680  1.0
  O  O32  1  0.490  0.228  0.121  1.0
  O  O33  1  0.772  0.510  0.379  1.0
  O  O34  1  0.510  0.772  0.879  1.0
  O  O35  1  0.228  0.490  0.621  1.0
  O  O36  1  0.377  0.002  0.297  1.0
  O  O37  1  0.998  0.623  0.203  1.0
  O  O38  1  0.623  0.998  0.703  1.0
  O  O39  1  0.002  0.377  0.797  1.0
  O  O40  1  0.119  0.697  0.018  1.0
  O  O41  1  0.303  0.881  0.482  1.0
[/CIF]
.