The structure described by PdN4H12ZnH4(C2O5)2(H2O)2 is Indium-derived structured and crystallizes in the orthorhombic I222 space group. The structure is zero-dimensional and consists of four water molecules, two PdN4H12 clusters, and two ZnH4(C2O5)2 clusters. In each PdN4H12 cluster, Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In each ZnH4(C2O5)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent O(3) and four equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. H(4) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1) and two equivalent H(4) atoms. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. is represented by the CIF card [CIF]
data_ZnH20PdC4(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.296
_cell_length_b   7.618
_cell_length_c   9.208
_cell_angle_alpha   114.434
_cell_angle_beta   113.339
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   419.481
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.000  1.0
  H  H1  1  0.709  0.364  0.179  1.0
  H  H2  1  0.470  0.815  0.179  1.0
  H  H3  1  0.530  0.636  0.821  1.0
  H  H4  1  0.291  0.185  0.821  1.0
  H  H5  1  0.665  0.298  0.314  1.0
  H  H6  1  0.649  0.016  0.314  1.0
  H  H7  1  0.351  0.702  0.686  1.0
  H  H8  1  0.335  0.984  0.686  1.0
  H  H9  1  0.485  0.369  0.183  1.0
  H  H10  1  0.698  0.814  0.183  1.0
  H  H11  1  0.302  0.631  0.817  1.0
  H  H12  1  0.515  0.186  0.817  1.0
  H  H13  1  0.945  0.090  0.892  1.0
  H  H14  1  0.947  0.802  0.892  1.0
  H  H15  1  0.053  0.910  0.108  1.0
  H  H16  1  0.055  0.198  0.108  1.0
  H  H17  1  0.703  0.812  0.622  1.0
  H  H18  1  0.920  0.811  0.622  1.0
  H  H19  1  0.080  0.188  0.378  1.0
  H  H20  1  0.297  0.189  0.378  1.0
  Pd  Pd21  1  0.500  0.000  0.000  1.0
  C  C22  1  0.710  0.317  0.636  1.0
  C  C23  1  0.926  0.319  0.636  1.0
  C  C24  1  0.074  0.683  0.364  1.0
  C  C25  1  0.290  0.681  0.364  1.0
  N  N26  1  0.600  0.291  0.190  1.0
  N  N27  1  0.589  0.898  0.190  1.0
  N  N28  1  0.411  0.709  0.810  1.0
  N  N29  1  0.400  0.102  0.810  1.0
  O  O30  1  0.706  0.391  0.788  1.0
  O  O31  1  0.081  0.396  0.788  1.0
  O  O32  1  0.919  0.609  0.212  1.0
  O  O33  1  0.294  0.604  0.212  1.0
  O  O34  1  0.559  0.243  0.488  1.0
  O  O35  1  0.929  0.244  0.488  1.0
  O  O36  1  0.071  0.757  0.512  1.0
  O  O37  1  0.441  0.756  0.512  1.0
  O  O38  1  0.000  0.218  0.000  1.0
  O  O39  1  0.000  0.782  0.000  1.0
  O  O40  1  0.851  0.851  0.702  1.0
  O  O41  1  0.149  0.149  0.298  1.0
[/CIF]
.
The structure described by PdN4H12ZnH4(C2O5)2(H2O)2 is Indium-derived structured and crystallizes in the orthorhombic I222 space group. The structure is zero-dimensional and consists of four water molecules, two PdN4H12 clusters, and two ZnH4(C2O5)2 clusters. In each PdN4H12 cluster, Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In each ZnH4(C2O5)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent O(3) and four equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. H(4) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1) and two equivalent H(4) atoms. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. is represented by the CIF card [CIF]
data_ZnH20PdC4(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.296
_cell_length_b   7.618
_cell_length_c   9.208
_cell_angle_alpha   114.434
_cell_angle_beta   113.339
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   419.481
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.000  1.0
  H  H1  1  0.709  0.364  0.179  1.0
  H  H2  1  0.470  0.815  0.179  1.0
  H  H3  1  0.530  0.636  0.821  1.0
  H  H4  1  0.291  0.185  0.821  1.0
  H  H5  1  0.665  0.298  0.314  1.0
  H  H6  1  0.649  0.016  0.314  1.0
  H  H7  1  0.351  0.702  0.686  1.0
  H  H8  1  0.335  0.984  0.686  1.0
  H  H9  1  0.485  0.369  0.183  1.0
  H  H10  1  0.698  0.814  0.183  1.0
  H  H11  1  0.302  0.631  0.817  1.0
  H  H12  1  0.515  0.186  0.817  1.0
  H  H13  1  0.945  0.090  0.892  1.0
  H  H14  1  0.947  0.802  0.892  1.0
  H  H15  1  0.053  0.910  0.108  1.0
  H  H16  1  0.055  0.198  0.108  1.0
  H  H17  1  0.703  0.812  0.622  1.0
  H  H18  1  0.920  0.811  0.622  1.0
  H  H19  1  0.080  0.188  0.378  1.0
  H  H20  1  0.297  0.189  0.378  1.0
  Pd  Pd21  1  0.500  0.000  0.000  1.0
  C  C22  1  0.710  0.317  0.636  1.0
  C  C23  1  0.926  0.319  0.636  1.0
  C  C24  1  0.074  0.683  0.364  1.0
  C  C25  1  0.290  0.681  0.364  1.0
  N  N26  1  0.600  0.291  0.190  1.0
  N  N27  1  0.589  0.898  0.190  1.0
  N  N28  1  0.411  0.709  0.810  1.0
  N  N29  1  0.400  0.102  0.810  1.0
  O  O30  1  0.706  0.391  0.788  1.0
  O  O31  1  0.081  0.396  0.788  1.0
  O  O32  1  0.919  0.609  0.212  1.0
  O  O33  1  0.294  0.604  0.212  1.0
  O  O34  1  0.559  0.243  0.488  1.0
  O  O35  1  0.929  0.244  0.488  1.0
  O  O36  1  0.071  0.757  0.512  1.0
  O  O37  1  0.441  0.756  0.512  1.0
  O  O38  1  0.000  0.218  0.000  1.0
  O  O39  1  0.000  0.782  0.000  1.0
  O  O40  1  0.851  0.851  0.702  1.0
  O  O41  1  0.149  0.149  0.298  1.0
[/CIF]
.