The material structure described by LiMnVO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent V(1), and one Mn(1) atom to form distorted OLiMnV2 tetrahedra that share corners with six equivalent O(1)LiMnV2 tetrahedra, corners with six equivalent O(2)LiMn2V trigonal pyramids,  an edgeedge with one O(1)LiMnV2 tetrahedra, and edges with two equivalent O(2)LiMn2V trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one V(1), and two equivalent Mn(1) atoms to form distorted OLiMn2V trigonal pyramids that share corners with six equivalent O(1)LiMnV2 tetrahedra, corners with six equivalent O(2)LiMn2V trigonal pyramids, edges with two equivalent O(1)LiMnV2 tetrahedra, and  an edgeedge with one O(2)LiMn2V trigonal pyramid. is represented by the CIF file [CIF]
data_LiMnVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.982
_cell_length_b   5.982
_cell_length_c   5.982
_cell_angle_alpha   121.003
_cell_angle_beta   120.573
_cell_angle_gamma   88.641
_symmetry_Int_Tables_number   1
_cell_volume   149.529
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.129  0.379  0.750  1.0
  Li  Li1  1  0.871  0.621  0.250  1.0
  Mn  Mn2  1  0.500  0.000  0.000  1.0
  Mn  Mn3  1  0.500  0.500  0.500  1.0
  V  V4  1  0.000  0.000  0.000  1.0
  V  V5  1  0.500  0.000  0.500  1.0
  O  O6  1  0.270  0.792  0.023  1.0
  O  O7  1  0.271  0.242  0.029  1.0
  O  O8  1  0.713  0.242  0.471  1.0
  O  O9  1  0.270  0.247  0.477  1.0
  O  O10  1  0.730  0.753  0.523  1.0
  O  O11  1  0.729  0.758  0.971  1.0
  O  O12  1  0.287  0.758  0.529  1.0
  O  O13  1  0.730  0.208  0.977  1.0
[/CIF]
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The material structure described by LiMnVO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent V(1), and one Mn(1) atom to form distorted OLiMnV2 tetrahedra that share corners with six equivalent O(1)LiMnV2 tetrahedra, corners with six equivalent O(2)LiMn2V trigonal pyramids,  an edgeedge with one O(1)LiMnV2 tetrahedra, and edges with two equivalent O(2)LiMn2V trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one V(1), and two equivalent Mn(1) atoms to form distorted OLiMn2V trigonal pyramids that share corners with six equivalent O(1)LiMnV2 tetrahedra, corners with six equivalent O(2)LiMn2V trigonal pyramids, edges with two equivalent O(1)LiMnV2 tetrahedra, and  an edgeedge with one O(2)LiMn2V trigonal pyramid. is represented by the CIF file [CIF]
data_LiMnVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.982
_cell_length_b   5.982
_cell_length_c   5.982
_cell_angle_alpha   121.003
_cell_angle_beta   120.573
_cell_angle_gamma   88.641
_symmetry_Int_Tables_number   1
_cell_volume   149.529
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.129  0.379  0.750  1.0
  Li  Li1  1  0.871  0.621  0.250  1.0
  Mn  Mn2  1  0.500  0.000  0.000  1.0
  Mn  Mn3  1  0.500  0.500  0.500  1.0
  V  V4  1  0.000  0.000  0.000  1.0
  V  V5  1  0.500  0.000  0.500  1.0
  O  O6  1  0.270  0.792  0.023  1.0
  O  O7  1  0.271  0.242  0.029  1.0
  O  O8  1  0.713  0.242  0.471  1.0
  O  O9  1  0.270  0.247  0.477  1.0
  O  O10  1  0.730  0.753  0.523  1.0
  O  O11  1  0.729  0.758  0.971  1.0
  O  O12  1  0.287  0.758  0.529  1.0
  O  O13  1  0.730  0.208  0.977  1.0
[/CIF]
.