The crystal structure described by PH2F3 is Indium-like structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four trifluorophosphanium molecules. P(1) is bonded in a distorted trigonal bipyramidal geometry to two equivalent H(1), one F(1), one F(2), and one F(3) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_PH2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.843
_cell_length_b   4.843
_cell_length_c   6.036
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.357
_symmetry_Int_Tables_number   1
_cell_volume   132.757
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.685  0.315  0.250  1.0
  P  P1  1  0.315  0.685  0.750  1.0
  H  H2  1  0.834  0.614  0.270  1.0
  H  H3  1  0.166  0.386  0.770  1.0
  H  H4  1  0.386  0.166  0.270  1.0
  H  H5  1  0.614  0.834  0.770  1.0
  F  F6  1  0.642  0.358  0.981  1.0
  F  F7  1  0.726  0.274  0.517  1.0
  F  F8  1  0.123  0.877  0.696  1.0
  F  F9  1  0.877  0.123  0.196  1.0
  F  F10  1  0.274  0.726  0.017  1.0
  F  F11  1  0.358  0.642  0.481  1.0
[/CIF]
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The crystal structure described by PH2F3 is Indium-like structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four trifluorophosphanium molecules. P(1) is bonded in a distorted trigonal bipyramidal geometry to two equivalent H(1), one F(1), one F(2), and one F(3) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_PH2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.843
_cell_length_b   4.843
_cell_length_c   6.036
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.357
_symmetry_Int_Tables_number   1
_cell_volume   132.757
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.685  0.315  0.250  1.0
  P  P1  1  0.315  0.685  0.750  1.0
  H  H2  1  0.834  0.614  0.270  1.0
  H  H3  1  0.166  0.386  0.770  1.0
  H  H4  1  0.386  0.166  0.270  1.0
  H  H5  1  0.614  0.834  0.770  1.0
  F  F6  1  0.642  0.358  0.981  1.0
  F  F7  1  0.726  0.274  0.517  1.0
  F  F8  1  0.123  0.877  0.696  1.0
  F  F9  1  0.877  0.123  0.196  1.0
  F  F10  1  0.274  0.726  0.017  1.0
  F  F11  1  0.358  0.642  0.481  1.0
[/CIF]
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