The material structure described by LiInW2O8 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted LiO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form InO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-53°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent W(1) and one In(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one In(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one In(1) atom. is represented by the CIF file [CIF]
data_LiIn(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.649
_cell_length_b   7.649
_cell_length_c   5.097
_cell_angle_alpha   88.977
_cell_angle_beta   88.977
_cell_angle_gamma   101.104
_symmetry_Int_Tables_number   1
_cell_volume   292.488
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.842  0.158  0.250  1.0
  Li  Li1  1  0.158  0.842  0.750  1.0
  In  In2  1  0.333  0.667  0.250  1.0
  In  In3  1  0.667  0.333  0.750  1.0
  W  W4  1  0.842  0.671  0.247  1.0
  W  W5  1  0.329  0.158  0.253  1.0
  W  W6  1  0.158  0.329  0.753  1.0
  W  W7  1  0.671  0.842  0.747  1.0
  O  O8  1  0.699  0.591  0.932  1.0
  O  O9  1  0.409  0.301  0.568  1.0
  O  O10  1  0.301  0.409  0.068  1.0
  O  O11  1  0.591  0.699  0.432  1.0
  O  O12  1  0.805  0.445  0.394  1.0
  O  O13  1  0.555  0.195  0.106  1.0
  O  O14  1  0.195  0.555  0.606  1.0
  O  O15  1  0.445  0.805  0.894  1.0
  O  O16  1  0.195  0.094  0.943  1.0
  O  O17  1  0.906  0.805  0.557  1.0
  O  O18  1  0.805  0.906  0.057  1.0
  O  O19  1  0.094  0.195  0.443  1.0
  O  O20  1  0.310  0.934  0.394  1.0
  O  O21  1  0.066  0.690  0.106  1.0
  O  O22  1  0.690  0.066  0.606  1.0
  O  O23  1  0.934  0.310  0.894  1.0
[/CIF]
.
The material structure described by LiInW2O8 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted LiO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form InO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-53°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent W(1) and one In(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one In(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one In(1) atom. is represented by the CIF file [CIF]
data_LiIn(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.649
_cell_length_b   7.649
_cell_length_c   5.097
_cell_angle_alpha   88.977
_cell_angle_beta   88.977
_cell_angle_gamma   101.104
_symmetry_Int_Tables_number   1
_cell_volume   292.488
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.842  0.158  0.250  1.0
  Li  Li1  1  0.158  0.842  0.750  1.0
  In  In2  1  0.333  0.667  0.250  1.0
  In  In3  1  0.667  0.333  0.750  1.0
  W  W4  1  0.842  0.671  0.247  1.0
  W  W5  1  0.329  0.158  0.253  1.0
  W  W6  1  0.158  0.329  0.753  1.0
  W  W7  1  0.671  0.842  0.747  1.0
  O  O8  1  0.699  0.591  0.932  1.0
  O  O9  1  0.409  0.301  0.568  1.0
  O  O10  1  0.301  0.409  0.068  1.0
  O  O11  1  0.591  0.699  0.432  1.0
  O  O12  1  0.805  0.445  0.394  1.0
  O  O13  1  0.555  0.195  0.106  1.0
  O  O14  1  0.195  0.555  0.606  1.0
  O  O15  1  0.445  0.805  0.894  1.0
  O  O16  1  0.195  0.094  0.943  1.0
  O  O17  1  0.906  0.805  0.557  1.0
  O  O18  1  0.805  0.906  0.057  1.0
  O  O19  1  0.094  0.195  0.443  1.0
  O  O20  1  0.310  0.934  0.394  1.0
  O  O21  1  0.066  0.690  0.106  1.0
  O  O22  1  0.690  0.066  0.606  1.0
  O  O23  1  0.934  0.310  0.894  1.0
[/CIF]
.