The material described by NaPdO2 is Caswellsilverite structured and crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Pd(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent Pd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. Pd(1) is bonded to six equivalent O(1) atoms to form PdO6 octahedra that share corners with six equivalent Na(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent Pd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. O(1) is bonded to three equivalent Na(1) and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONa3Pd3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_NaPdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.359
_cell_length_b   3.359
_cell_length_c   5.750
_cell_angle_alpha   69.179
_cell_angle_beta   69.179
_cell_angle_gamma   54.741
_symmetry_Int_Tables_number   1
_cell_volume   48.544
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Pd  Pd1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.715  0.715  0.789  1.0
  O  O3  1  0.285  0.285  0.211  1.0
[/CIF]
.
The material described by NaPdO2 is Caswellsilverite structured and crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Pd(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent Pd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. Pd(1) is bonded to six equivalent O(1) atoms to form PdO6 octahedra that share corners with six equivalent Na(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent Pd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. O(1) is bonded to three equivalent Na(1) and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONa3Pd3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_NaPdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.359
_cell_length_b   3.359
_cell_length_c   5.750
_cell_angle_alpha   69.179
_cell_angle_beta   69.179
_cell_angle_gamma   54.741
_symmetry_Int_Tables_number   1
_cell_volume   48.544
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Pd  Pd1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.715  0.715  0.789  1.0
  O  O3  1  0.285  0.285  0.211  1.0
[/CIF]
.