The material structure described by Ge2SbO6 crystallizes in the monoclinic C2/c space group. Ge(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form GeO4 tetrahedra that share corners with three equivalent Sb(1)O6 octahedra and corners with two equivalent Ge(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-59°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form distorted SbO6 octahedra that share corners with six equivalent Ge(1)O4 tetrahedra and edges with two equivalent Sb(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ge(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ge(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_Ge2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.001
_cell_length_b   7.001
_cell_length_c   5.745
_cell_angle_alpha   76.135
_cell_angle_beta   76.135
_cell_angle_gamma   84.664
_symmetry_Int_Tables_number   1
_cell_volume   265.258
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.217  0.381  0.757  1.0
  Ge  Ge1  1  0.619  0.783  0.743  1.0
  Ge  Ge2  1  0.783  0.619  0.243  1.0
  Ge  Ge3  1  0.381  0.217  0.257  1.0
  Sb  Sb4  1  0.115  0.885  0.750  1.0
  Sb  Sb5  1  0.885  0.115  0.250  1.0
  O  O6  1  0.387  0.336  0.494  1.0
  O  O7  1  0.664  0.613  0.006  1.0
  O  O8  1  0.613  0.664  0.506  1.0
  O  O9  1  0.336  0.387  0.994  1.0
  O  O10  1  0.613  0.098  0.190  1.0
  O  O11  1  0.902  0.387  0.310  1.0
  O  O12  1  0.387  0.902  0.810  1.0
  O  O13  1  0.098  0.613  0.690  1.0
  O  O14  1  0.048  0.178  0.873  1.0
  O  O15  1  0.822  0.952  0.627  1.0
  O  O16  1  0.952  0.822  0.127  1.0
  O  O17  1  0.178  0.048  0.373  1.0
[/CIF]
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The material structure described by Ge2SbO6 crystallizes in the monoclinic C2/c space group. Ge(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form GeO4 tetrahedra that share corners with three equivalent Sb(1)O6 octahedra and corners with two equivalent Ge(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-59°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form distorted SbO6 octahedra that share corners with six equivalent Ge(1)O4 tetrahedra and edges with two equivalent Sb(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ge(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ge(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_Ge2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.001
_cell_length_b   7.001
_cell_length_c   5.745
_cell_angle_alpha   76.135
_cell_angle_beta   76.135
_cell_angle_gamma   84.664
_symmetry_Int_Tables_number   1
_cell_volume   265.258
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.217  0.381  0.757  1.0
  Ge  Ge1  1  0.619  0.783  0.743  1.0
  Ge  Ge2  1  0.783  0.619  0.243  1.0
  Ge  Ge3  1  0.381  0.217  0.257  1.0
  Sb  Sb4  1  0.115  0.885  0.750  1.0
  Sb  Sb5  1  0.885  0.115  0.250  1.0
  O  O6  1  0.387  0.336  0.494  1.0
  O  O7  1  0.664  0.613  0.006  1.0
  O  O8  1  0.613  0.664  0.506  1.0
  O  O9  1  0.336  0.387  0.994  1.0
  O  O10  1  0.613  0.098  0.190  1.0
  O  O11  1  0.902  0.387  0.310  1.0
  O  O12  1  0.387  0.902  0.810  1.0
  O  O13  1  0.098  0.613  0.690  1.0
  O  O14  1  0.048  0.178  0.873  1.0
  O  O15  1  0.822  0.952  0.627  1.0
  O  O16  1  0.952  0.822  0.127  1.0
  O  O17  1  0.178  0.048  0.373  1.0
[/CIF]
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