The compound described by RbLu(WO4)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(6), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. Lu(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), one O(6), one O(8), two equivalent O(1), and two equivalent O(7) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(1), one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one W(2) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Lu(1), one W(1), and one W(2) atom. In the third O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Rb(1), two equivalent Lu(1), and one W(2) atom. In the fourth O site, O(8) is bonded in a 3-coordinate geometry to one Lu(1), one W(1), and one W(2) atom. In the fifth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Lu(1), one W(1), and one W(2) atom. In the sixth O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one W(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one Lu(1) and one W(1) atom. In the eighth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Lu(1), and one W(1) atom. is represented by the CIF file [CIF]
data_RbLu(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.008
_cell_length_b   9.037
_cell_length_c   10.316
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   99.215
_symmetry_Int_Tables_number   1
_cell_volume   736.904
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.073  0.512  0.213  1.0
  Rb  Rb1  1  0.927  0.488  0.787  1.0
  Rb  Rb2  1  0.427  0.488  0.713  1.0
  Rb  Rb3  1  0.573  0.512  0.287  1.0
  Lu  Lu4  1  0.022  0.060  0.777  1.0
  Lu  Lu5  1  0.978  0.940  0.223  1.0
  Lu  Lu6  1  0.478  0.940  0.277  1.0
  Lu  Lu7  1  0.522  0.060  0.723  1.0
  W  W8  1  0.286  0.219  0.010  1.0
  W  W9  1  0.714  0.781  0.990  1.0
  W  W10  1  0.214  0.781  0.510  1.0
  W  W11  1  0.786  0.219  0.490  1.0
  W  W12  1  0.179  0.162  0.489  1.0
  W  W13  1  0.821  0.838  0.511  1.0
  W  W14  1  0.321  0.838  0.989  1.0
  W  W15  1  0.679  0.162  0.011  1.0
  O  O16  1  0.258  0.008  0.389  1.0
  O  O17  1  0.742  0.992  0.611  1.0
  O  O18  1  0.242  0.992  0.889  1.0
  O  O19  1  0.758  0.008  0.111  1.0
  O  O20  1  0.350  0.395  0.087  1.0
  O  O21  1  0.650  0.605  0.913  1.0
  O  O22  1  0.150  0.605  0.587  1.0
  O  O23  1  0.850  0.395  0.413  1.0
  O  O24  1  0.112  0.132  0.116  1.0
  O  O25  1  0.888  0.868  0.884  1.0
  O  O26  1  0.388  0.868  0.616  1.0
  O  O27  1  0.612  0.132  0.384  1.0
  O  O28  1  0.337  0.733  0.369  1.0
  O  O29  1  0.663  0.267  0.631  1.0
  O  O30  1  0.163  0.267  0.869  1.0
  O  O31  1  0.837  0.733  0.131  1.0
  O  O32  1  0.268  0.330  0.412  1.0
  O  O33  1  0.732  0.670  0.588  1.0
  O  O34  1  0.232  0.670  0.912  1.0
  O  O35  1  0.768  0.330  0.088  1.0
  O  O36  1  0.003  0.224  0.605  1.0
  O  O37  1  0.997  0.776  0.395  1.0
  O  O38  1  0.497  0.776  0.105  1.0
  O  O39  1  0.503  0.224  0.895  1.0
  O  O40  1  0.307  0.153  0.638  1.0
  O  O41  1  0.693  0.847  0.362  1.0
  O  O42  1  0.193  0.847  0.138  1.0
  O  O43  1  0.807  0.153  0.862  1.0
  O  O44  1  0.452  0.089  0.103  1.0
  O  O45  1  0.548  0.911  0.897  1.0
  O  O46  1  0.048  0.911  0.603  1.0
  O  O47  1  0.952  0.089  0.397  1.0
[/CIF]
.
The compound described by RbLu(WO4)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(6), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. Lu(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), one O(6), one O(8), two equivalent O(1), and two equivalent O(7) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(1), one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one W(2) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Lu(1), one W(1), and one W(2) atom. In the third O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Rb(1), two equivalent Lu(1), and one W(2) atom. In the fourth O site, O(8) is bonded in a 3-coordinate geometry to one Lu(1), one W(1), and one W(2) atom. In the fifth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Lu(1), one W(1), and one W(2) atom. In the sixth O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one W(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one Lu(1) and one W(1) atom. In the eighth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Lu(1), and one W(1) atom. is represented by the CIF file [CIF]
data_RbLu(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.008
_cell_length_b   9.037
_cell_length_c   10.316
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   99.215
_symmetry_Int_Tables_number   1
_cell_volume   736.904
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.073  0.512  0.213  1.0
  Rb  Rb1  1  0.927  0.488  0.787  1.0
  Rb  Rb2  1  0.427  0.488  0.713  1.0
  Rb  Rb3  1  0.573  0.512  0.287  1.0
  Lu  Lu4  1  0.022  0.060  0.777  1.0
  Lu  Lu5  1  0.978  0.940  0.223  1.0
  Lu  Lu6  1  0.478  0.940  0.277  1.0
  Lu  Lu7  1  0.522  0.060  0.723  1.0
  W  W8  1  0.286  0.219  0.010  1.0
  W  W9  1  0.714  0.781  0.990  1.0
  W  W10  1  0.214  0.781  0.510  1.0
  W  W11  1  0.786  0.219  0.490  1.0
  W  W12  1  0.179  0.162  0.489  1.0
  W  W13  1  0.821  0.838  0.511  1.0
  W  W14  1  0.321  0.838  0.989  1.0
  W  W15  1  0.679  0.162  0.011  1.0
  O  O16  1  0.258  0.008  0.389  1.0
  O  O17  1  0.742  0.992  0.611  1.0
  O  O18  1  0.242  0.992  0.889  1.0
  O  O19  1  0.758  0.008  0.111  1.0
  O  O20  1  0.350  0.395  0.087  1.0
  O  O21  1  0.650  0.605  0.913  1.0
  O  O22  1  0.150  0.605  0.587  1.0
  O  O23  1  0.850  0.395  0.413  1.0
  O  O24  1  0.112  0.132  0.116  1.0
  O  O25  1  0.888  0.868  0.884  1.0
  O  O26  1  0.388  0.868  0.616  1.0
  O  O27  1  0.612  0.132  0.384  1.0
  O  O28  1  0.337  0.733  0.369  1.0
  O  O29  1  0.663  0.267  0.631  1.0
  O  O30  1  0.163  0.267  0.869  1.0
  O  O31  1  0.837  0.733  0.131  1.0
  O  O32  1  0.268  0.330  0.412  1.0
  O  O33  1  0.732  0.670  0.588  1.0
  O  O34  1  0.232  0.670  0.912  1.0
  O  O35  1  0.768  0.330  0.088  1.0
  O  O36  1  0.003  0.224  0.605  1.0
  O  O37  1  0.997  0.776  0.395  1.0
  O  O38  1  0.497  0.776  0.105  1.0
  O  O39  1  0.503  0.224  0.895  1.0
  O  O40  1  0.307  0.153  0.638  1.0
  O  O41  1  0.693  0.847  0.362  1.0
  O  O42  1  0.193  0.847  0.138  1.0
  O  O43  1  0.807  0.153  0.862  1.0
  O  O44  1  0.452  0.089  0.103  1.0
  O  O45  1  0.548  0.911  0.897  1.0
  O  O46  1  0.048  0.911  0.603  1.0
  O  O47  1  0.952  0.089  0.397  1.0
[/CIF]
.