The material described by KGaCl4 is Zircon-like structured and crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. is represented by the CIF card [CIF]
data_KGaCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.296
_cell_length_b   7.294
_cell_length_c   11.528
_cell_angle_alpha   54.315
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   703.128
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.300  0.976  0.205  1.0
  K  K1  1  0.800  0.024  0.295  1.0
  K  K2  1  0.700  0.024  0.795  1.0
  K  K3  1  0.200  0.976  0.705  1.0
  Ga  Ga4  1  0.548  0.430  0.316  1.0
  Ga  Ga5  1  0.048  0.570  0.184  1.0
  Ga  Ga6  1  0.452  0.570  0.684  1.0
  Ga  Ga7  1  0.952  0.430  0.816  1.0
  Cl  Cl8  1  0.873  0.620  0.063  1.0
  Cl  Cl9  1  0.373  0.380  0.437  1.0
  Cl  Cl10  1  0.127  0.380  0.937  1.0
  Cl  Cl11  1  0.627  0.620  0.563  1.0
  Cl  Cl12  1  0.474  0.712  0.807  1.0
  Cl  Cl13  1  0.974  0.288  0.693  1.0
  Cl  Cl14  1  0.526  0.288  0.193  1.0
  Cl  Cl15  1  0.026  0.712  0.307  1.0
  Cl  Cl16  1  0.920  0.795  0.671  1.0
  Cl  Cl17  1  0.420  0.205  0.829  1.0
  Cl  Cl18  1  0.080  0.205  0.329  1.0
  Cl  Cl19  1  0.580  0.795  0.171  1.0
  Cl  Cl20  1  0.718  0.260  0.452  1.0
  Cl  Cl21  1  0.218  0.740  0.048  1.0
  Cl  Cl22  1  0.282  0.740  0.548  1.0
  Cl  Cl23  1  0.782  0.260  0.952  1.0
[/CIF]
.
The material described by KGaCl4 is Zircon-like structured and crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. is represented by the CIF card [CIF]
data_KGaCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.296
_cell_length_b   7.294
_cell_length_c   11.528
_cell_angle_alpha   54.315
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   703.128
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.300  0.976  0.205  1.0
  K  K1  1  0.800  0.024  0.295  1.0
  K  K2  1  0.700  0.024  0.795  1.0
  K  K3  1  0.200  0.976  0.705  1.0
  Ga  Ga4  1  0.548  0.430  0.316  1.0
  Ga  Ga5  1  0.048  0.570  0.184  1.0
  Ga  Ga6  1  0.452  0.570  0.684  1.0
  Ga  Ga7  1  0.952  0.430  0.816  1.0
  Cl  Cl8  1  0.873  0.620  0.063  1.0
  Cl  Cl9  1  0.373  0.380  0.437  1.0
  Cl  Cl10  1  0.127  0.380  0.937  1.0
  Cl  Cl11  1  0.627  0.620  0.563  1.0
  Cl  Cl12  1  0.474  0.712  0.807  1.0
  Cl  Cl13  1  0.974  0.288  0.693  1.0
  Cl  Cl14  1  0.526  0.288  0.193  1.0
  Cl  Cl15  1  0.026  0.712  0.307  1.0
  Cl  Cl16  1  0.920  0.795  0.671  1.0
  Cl  Cl17  1  0.420  0.205  0.829  1.0
  Cl  Cl18  1  0.080  0.205  0.329  1.0
  Cl  Cl19  1  0.580  0.795  0.171  1.0
  Cl  Cl20  1  0.718  0.260  0.452  1.0
  Cl  Cl21  1  0.218  0.740  0.048  1.0
  Cl  Cl22  1  0.282  0.740  0.548  1.0
  Cl  Cl23  1  0.782  0.260  0.952  1.0
[/CIF]
.