The material structure described by MgMo2(WO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(11), one O(3), one O(5), and one O(7) atom to form WO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra and corners with four equivalent Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-40°. In the second W site, W(2) is bonded to one O(12), one O(2), one O(4), one O(6), one O(8), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra and corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-38°. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(8) atom to form MoO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-38°. In the second Mo site, Mo(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(7), and one O(9) atom to form MoO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-40°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mg(1), one W(1), and one Mo(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(2) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(1), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Mg(1), one W(2), and one Mo(1) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Mo(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(2), and one Mo(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one W(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Mg(1), one W(2), and one Mo(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(2) and one Mo(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one Mo(1) atom. In the eleventh O site, O(11) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Mo(1) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one W(2), and one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgMo2(WO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.213
_cell_length_b   5.493
_cell_length_c   7.569
_cell_angle_alpha   90.790
_cell_angle_beta   90.432
_cell_angle_gamma   89.753
_symmetry_Int_Tables_number   1
_cell_volume   216.699
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.478  0.432  0.752  1.0
  Mo  Mo1  1  0.510  0.983  0.998  1.0
  Mo  Mo2  1  0.980  0.500  0.497  1.0
  W  W3  1  0.487  0.983  0.494  1.0
  W  W4  1  0.001  0.489  0.006  1.0
  O  O5  1  0.719  0.290  0.453  1.0
  O  O6  1  0.798  0.802  0.045  1.0
  O  O7  1  0.310  0.700  0.562  1.0
  O  O8  1  0.214  0.218  0.949  1.0
  O  O9  1  0.237  0.233  0.557  1.0
  O  O10  1  0.306  0.684  0.931  1.0
  O  O11  1  0.799  0.810  0.459  1.0
  O  O12  1  0.707  0.302  0.044  1.0
  O  O13  1  0.091  0.504  0.245  1.0
  O  O14  1  0.397  0.978  0.255  1.0
  O  O15  1  0.586  0.048  0.747  1.0
  O  O16  1  0.869  0.518  0.756  1.0
[/CIF]
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The material structure described by MgMo2(WO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(11), one O(3), one O(5), and one O(7) atom to form WO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra and corners with four equivalent Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-40°. In the second W site, W(2) is bonded to one O(12), one O(2), one O(4), one O(6), one O(8), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra and corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-38°. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(8) atom to form MoO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-38°. In the second Mo site, Mo(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(7), and one O(9) atom to form MoO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-40°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mg(1), one W(1), and one Mo(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(2) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(1), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Mg(1), one W(2), and one Mo(1) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Mo(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(2), and one Mo(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one W(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Mg(1), one W(2), and one Mo(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(2) and one Mo(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one Mo(1) atom. In the eleventh O site, O(11) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Mo(1) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one W(2), and one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgMo2(WO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.213
_cell_length_b   5.493
_cell_length_c   7.569
_cell_angle_alpha   90.790
_cell_angle_beta   90.432
_cell_angle_gamma   89.753
_symmetry_Int_Tables_number   1
_cell_volume   216.699
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.478  0.432  0.752  1.0
  Mo  Mo1  1  0.510  0.983  0.998  1.0
  Mo  Mo2  1  0.980  0.500  0.497  1.0
  W  W3  1  0.487  0.983  0.494  1.0
  W  W4  1  0.001  0.489  0.006  1.0
  O  O5  1  0.719  0.290  0.453  1.0
  O  O6  1  0.798  0.802  0.045  1.0
  O  O7  1  0.310  0.700  0.562  1.0
  O  O8  1  0.214  0.218  0.949  1.0
  O  O9  1  0.237  0.233  0.557  1.0
  O  O10  1  0.306  0.684  0.931  1.0
  O  O11  1  0.799  0.810  0.459  1.0
  O  O12  1  0.707  0.302  0.044  1.0
  O  O13  1  0.091  0.504  0.245  1.0
  O  O14  1  0.397  0.978  0.255  1.0
  O  O15  1  0.586  0.048  0.747  1.0
  O  O16  1  0.869  0.518  0.756  1.0
[/CIF]
.