The compound described by V6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(4), one O(5), one O(7), one F(2), and one F(5) atom to form VO4F2 octahedra that share corners with two equivalent V(3)O2F4 octahedra, corners with three equivalent V(6)O3F3 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(5)O3F3 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-56°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(5), one F(2), and one F(4) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with three equivalent V(5)O3F3 octahedra, corners with three equivalent V(1)O4F2 octahedra,  an edgeedge with one V(3)O2F4 octahedra, and  an edgeedge with one V(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-51°. In the third V site, V(3) is bonded to one O(3), one O(6), one F(1), one F(2), one F(3), and one F(5) atom to form VO2F4 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with three equivalent V(5)O3F3 octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(6)O3F3 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the fourth V site, V(4) is bonded to one O(2), one O(3), one O(4), one O(6), one O(7), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with three equivalent V(3)O2F4 octahedra, corners with three equivalent V(6)O3F3 octahedra,  an edgeedge with one V(5)O3F3 octahedra, and  an edgeedge with one V(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the fifth V site, V(5) is bonded to one O(1), one O(5), one O(6), one F(1), one F(3), and one F(4) atom to form VO3F3 octahedra that share corners with two equivalent V(6)O3F3 octahedra, corners with three equivalent V(3)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the sixth V site, V(6) is bonded to one O(2), one O(4), one O(7), one F(3), one F(4), and one F(5) atom to form VO3F3 octahedra that share corners with two equivalent V(5)O3F3 octahedra, corners with three equivalent V(1)O4F2 octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(3)O2F4 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-56°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.594
_cell_length_b   5.602
_cell_length_c   7.438
_cell_angle_alpha   71.783
_cell_angle_beta   72.230
_cell_angle_gamma   71.014
_symmetry_Int_Tables_number   1
_cell_volume   203.948
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.672  0.671  0.830  1.0
  V  V1  1  0.331  0.335  0.665  1.0
  V  V2  1  0.673  0.624  0.328  1.0
  V  V3  1  0.335  0.357  0.151  1.0
  V  V4  1  0.981  0.997  0.508  1.0
  V  V5  1  0.010  0.023  0.007  1.0
  O  O6  1  0.030  0.642  0.667  1.0
  O  O7  1  0.235  0.239  0.971  1.0
  O  O8  1  0.432  0.426  0.364  1.0
  O  O9  1  0.300  0.702  0.000  1.0
  O  O10  1  0.623  0.032  0.670  1.0
  O  O11  1  0.983  0.351  0.331  1.0
  O  O12  1  0.695  0.311  0.003  1.0
  F  F13  1  0.374  0.958  0.333  1.0
  F  F14  1  0.573  0.562  0.627  1.0
  F  F15  1  0.889  0.890  0.305  1.0
  F  F16  1  0.090  0.104  0.706  1.0
  F  F17  1  0.775  0.775  0.034  1.0
[/CIF]
.
The compound described by V6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(4), one O(5), one O(7), one F(2), and one F(5) atom to form VO4F2 octahedra that share corners with two equivalent V(3)O2F4 octahedra, corners with three equivalent V(6)O3F3 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(5)O3F3 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-56°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(5), one F(2), and one F(4) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with three equivalent V(5)O3F3 octahedra, corners with three equivalent V(1)O4F2 octahedra,  an edgeedge with one V(3)O2F4 octahedra, and  an edgeedge with one V(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-51°. In the third V site, V(3) is bonded to one O(3), one O(6), one F(1), one F(2), one F(3), and one F(5) atom to form VO2F4 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with three equivalent V(5)O3F3 octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(6)O3F3 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the fourth V site, V(4) is bonded to one O(2), one O(3), one O(4), one O(6), one O(7), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with three equivalent V(3)O2F4 octahedra, corners with three equivalent V(6)O3F3 octahedra,  an edgeedge with one V(5)O3F3 octahedra, and  an edgeedge with one V(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the fifth V site, V(5) is bonded to one O(1), one O(5), one O(6), one F(1), one F(3), and one F(4) atom to form VO3F3 octahedra that share corners with two equivalent V(6)O3F3 octahedra, corners with three equivalent V(3)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the sixth V site, V(6) is bonded to one O(2), one O(4), one O(7), one F(3), one F(4), and one F(5) atom to form VO3F3 octahedra that share corners with two equivalent V(5)O3F3 octahedra, corners with three equivalent V(1)O4F2 octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(3)O2F4 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-56°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.594
_cell_length_b   5.602
_cell_length_c   7.438
_cell_angle_alpha   71.783
_cell_angle_beta   72.230
_cell_angle_gamma   71.014
_symmetry_Int_Tables_number   1
_cell_volume   203.948
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.672  0.671  0.830  1.0
  V  V1  1  0.331  0.335  0.665  1.0
  V  V2  1  0.673  0.624  0.328  1.0
  V  V3  1  0.335  0.357  0.151  1.0
  V  V4  1  0.981  0.997  0.508  1.0
  V  V5  1  0.010  0.023  0.007  1.0
  O  O6  1  0.030  0.642  0.667  1.0
  O  O7  1  0.235  0.239  0.971  1.0
  O  O8  1  0.432  0.426  0.364  1.0
  O  O9  1  0.300  0.702  0.000  1.0
  O  O10  1  0.623  0.032  0.670  1.0
  O  O11  1  0.983  0.351  0.331  1.0
  O  O12  1  0.695  0.311  0.003  1.0
  F  F13  1  0.374  0.958  0.333  1.0
  F  F14  1  0.573  0.562  0.627  1.0
  F  F15  1  0.889  0.890  0.305  1.0
  F  F16  1  0.090  0.104  0.706  1.0
  F  F17  1  0.775  0.775  0.034  1.0
[/CIF]
.