The crystal structure described by FeH3(CO2)3N(CH3)2 crystallizes in the triclinic P1 space group. The structure consists of two dimethylamine molecules inside a FeH3(CO2)3 framework. In the FeH3(CO2)3 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom. In the second Fe site, Fe(2) is bonded in an octahedral geometry to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom. There are six inequivalent C sites. In the first C site, C(5) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(10) atom. In the second C site, C(6) is bonded in a trigonal planar geometry to one H(2), one O(11), and one O(2) atom. In the third C site, C(7) is bonded in a trigonal planar geometry to one H(3), one O(12), and one O(3) atom. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one H(4), one O(4), and one O(7) atom. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one H(5), one O(5), and one O(8) atom. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one H(6), one O(6), and one O(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(6) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(8) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(10) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(8) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(9) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(10) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(6) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(7) atom. is represented by the CIF card [CIF]
data_FeH9C5NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.304
_cell_length_b   8.255
_cell_length_c   8.853
_cell_angle_alpha   90.337
_cell_angle_beta   117.913
_cell_angle_gamma   59.777
_symmetry_Int_Tables_number   1
_cell_volume   441.831
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  1.000  0.499  0.500  1.0
  Fe  Fe1  1  0.001  0.999  1.000  1.0
  H  H2  1  0.500  0.875  0.247  1.0
  H  H3  1  0.116  0.628  0.242  1.0
  H  H4  1  0.891  0.241  0.262  1.0
  H  H5  1  0.498  0.128  0.742  1.0
  H  H6  1  0.872  0.375  0.747  1.0
  H  H7  1  0.129  0.741  0.761  1.0
  H  H8  1  0.499  0.338  0.403  1.0
  H  H9  1  0.755  0.164  0.429  1.0
  H  H10  1  0.651  0.085  0.527  1.0
  H  H11  1  0.511  0.664  0.930  1.0
  H  H12  1  0.566  0.838  0.902  1.0
  H  H13  1  0.791  0.585  0.026  1.0
  H  H14  1  0.389  0.733  0.474  1.0
  H  H15  1  0.261  0.836  0.598  1.0
  H  H16  1  0.406  0.919  0.570  1.0
  H  H17  1  0.502  0.335  0.098  1.0
  H  H18  1  0.352  0.232  0.974  1.0
  H  H19  1  0.244  0.419  0.069  1.0
  C  C20  1  0.604  0.183  0.409  1.0
  C  C21  1  0.623  0.683  0.909  1.0
  C  C22  1  0.408  0.786  0.591  1.0
  C  C23  1  0.397  0.286  0.091  1.0
  C  C24  1  0.500  0.740  0.245  1.0
  C  C25  1  0.991  0.762  0.251  1.0
  C  C26  1  0.019  0.246  0.254  1.0
  C  C27  1  0.499  0.261  0.751  1.0
  C  C28  1  0.005  0.239  0.745  1.0
  C  C29  1  0.990  0.745  0.755  1.0
  N  N30  1  0.499  0.139  0.250  1.0
  N  N31  1  0.611  0.638  0.750  1.0
  O  O32  1  0.684  0.572  0.335  1.0
  O  O33  1  0.925  0.742  0.348  1.0
  O  O34  1  0.094  0.338  0.345  1.0
  O  O35  1  0.683  0.241  0.848  1.0
  O  O36  1  0.079  0.071  0.835  1.0
  O  O37  1  0.914  0.838  0.846  1.0
  O  O38  1  0.316  0.429  0.664  1.0
  O  O39  1  0.081  0.253  0.653  1.0
  O  O40  1  0.912  0.660  0.656  1.0
  O  O41  1  0.318  0.755  0.153  1.0
  O  O42  1  0.919  0.929  0.163  1.0
  O  O43  1  0.082  0.160  0.155  1.0
[/CIF]
.
The crystal structure described by FeH3(CO2)3N(CH3)2 crystallizes in the triclinic P1 space group. The structure consists of two dimethylamine molecules inside a FeH3(CO2)3 framework. In the FeH3(CO2)3 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom. In the second Fe site, Fe(2) is bonded in an octahedral geometry to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom. There are six inequivalent C sites. In the first C site, C(5) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(10) atom. In the second C site, C(6) is bonded in a trigonal planar geometry to one H(2), one O(11), and one O(2) atom. In the third C site, C(7) is bonded in a trigonal planar geometry to one H(3), one O(12), and one O(3) atom. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one H(4), one O(4), and one O(7) atom. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one H(5), one O(5), and one O(8) atom. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one H(6), one O(6), and one O(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(6) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(8) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(10) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(8) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(9) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(10) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(6) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(7) atom. is represented by the CIF card [CIF]
data_FeH9C5NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.304
_cell_length_b   8.255
_cell_length_c   8.853
_cell_angle_alpha   90.337
_cell_angle_beta   117.913
_cell_angle_gamma   59.777
_symmetry_Int_Tables_number   1
_cell_volume   441.831
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  1.000  0.499  0.500  1.0
  Fe  Fe1  1  0.001  0.999  1.000  1.0
  H  H2  1  0.500  0.875  0.247  1.0
  H  H3  1  0.116  0.628  0.242  1.0
  H  H4  1  0.891  0.241  0.262  1.0
  H  H5  1  0.498  0.128  0.742  1.0
  H  H6  1  0.872  0.375  0.747  1.0
  H  H7  1  0.129  0.741  0.761  1.0
  H  H8  1  0.499  0.338  0.403  1.0
  H  H9  1  0.755  0.164  0.429  1.0
  H  H10  1  0.651  0.085  0.527  1.0
  H  H11  1  0.511  0.664  0.930  1.0
  H  H12  1  0.566  0.838  0.902  1.0
  H  H13  1  0.791  0.585  0.026  1.0
  H  H14  1  0.389  0.733  0.474  1.0
  H  H15  1  0.261  0.836  0.598  1.0
  H  H16  1  0.406  0.919  0.570  1.0
  H  H17  1  0.502  0.335  0.098  1.0
  H  H18  1  0.352  0.232  0.974  1.0
  H  H19  1  0.244  0.419  0.069  1.0
  C  C20  1  0.604  0.183  0.409  1.0
  C  C21  1  0.623  0.683  0.909  1.0
  C  C22  1  0.408  0.786  0.591  1.0
  C  C23  1  0.397  0.286  0.091  1.0
  C  C24  1  0.500  0.740  0.245  1.0
  C  C25  1  0.991  0.762  0.251  1.0
  C  C26  1  0.019  0.246  0.254  1.0
  C  C27  1  0.499  0.261  0.751  1.0
  C  C28  1  0.005  0.239  0.745  1.0
  C  C29  1  0.990  0.745  0.755  1.0
  N  N30  1  0.499  0.139  0.250  1.0
  N  N31  1  0.611  0.638  0.750  1.0
  O  O32  1  0.684  0.572  0.335  1.0
  O  O33  1  0.925  0.742  0.348  1.0
  O  O34  1  0.094  0.338  0.345  1.0
  O  O35  1  0.683  0.241  0.848  1.0
  O  O36  1  0.079  0.071  0.835  1.0
  O  O37  1  0.914  0.838  0.846  1.0
  O  O38  1  0.316  0.429  0.664  1.0
  O  O39  1  0.081  0.253  0.653  1.0
  O  O40  1  0.912  0.660  0.656  1.0
  O  O41  1  0.318  0.755  0.153  1.0
  O  O42  1  0.919  0.929  0.163  1.0
  O  O43  1  0.082  0.160  0.155  1.0
[/CIF]
.