The structure described by PrMn5Co7 crystallizes in the orthorhombic Imm2 space group. Pr(1) is bonded in a 20-coordinate geometry to two equivalent Mn(2), eight equivalent Mn(1), one Co(1), one Co(2), two equivalent Co(3), two equivalent Co(4), and four equivalent Co(5) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 12-coordinate geometry to two equivalent Pr(1), one Mn(2), two equivalent Mn(1), one Co(1), one Co(2), one Co(4), two equivalent Co(3), and two equivalent Co(5) atoms. In the second Mn site, Mn(2) is bonded in a 12-coordinate geometry to two equivalent Pr(1), four equivalent Mn(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(5) atoms. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 14-coordinate geometry to one Pr(1), four equivalent Mn(1), one Co(2), two equivalent Co(4), two equivalent Co(5), and four equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a 14-coordinate geometry to one Pr(1), two equivalent Mn(2), four equivalent Mn(1), one Co(1), two equivalent Co(5), and four equivalent Co(3) atoms. In the third Co site, Co(3) is bonded in a 14-coordinate geometry to one Pr(1), one Mn(2), four equivalent Mn(1), one Co(3), one Co(4), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(5) atoms. In the fourth Co site, Co(4) is bonded in a 12-coordinate geometry to two equivalent Pr(1), four equivalent Mn(1), two equivalent Co(1), two equivalent Co(3), and two equivalent Co(5) atoms. In the fifth Co site, Co(5) is bonded in a 12-coordinate geometry to two equivalent Pr(1), one Mn(2), four equivalent Mn(1), one Co(1), one Co(2), one Co(4), and two equivalent Co(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_PrMn5Co7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.589
_cell_length_b   6.386
_cell_length_c   6.386
_cell_angle_alpha   97.176
_cell_angle_beta   111.058
_cell_angle_gamma   68.942
_symmetry_Int_Tables_number   1
_cell_volume   162.961
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.997  0.003  0.997  1.0
  Mn  Mn1  1  0.497  0.002  0.501  1.0
  Mn  Mn2  1  0.002  0.002  0.501  1.0
  Mn  Mn3  1  0.497  0.499  0.998  1.0
  Mn  Mn4  1  0.002  0.499  0.998  1.0
  Mn  Mn5  1  0.731  0.769  0.231  1.0
  Co  Co6  1  0.642  0.358  0.642  1.0
  Co  Co7  1  0.361  0.639  0.361  1.0
  Co  Co8  1  0.998  0.362  0.357  1.0
  Co  Co9  1  0.998  0.643  0.638  1.0
  Co  Co10  1  0.271  0.229  0.771  1.0
  Co  Co11  1  0.502  0.764  0.768  1.0
  Co  Co12  1  0.502  0.232  0.236  1.0
[/CIF]
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The structure described by PrMn5Co7 crystallizes in the orthorhombic Imm2 space group. Pr(1) is bonded in a 20-coordinate geometry to two equivalent Mn(2), eight equivalent Mn(1), one Co(1), one Co(2), two equivalent Co(3), two equivalent Co(4), and four equivalent Co(5) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 12-coordinate geometry to two equivalent Pr(1), one Mn(2), two equivalent Mn(1), one Co(1), one Co(2), one Co(4), two equivalent Co(3), and two equivalent Co(5) atoms. In the second Mn site, Mn(2) is bonded in a 12-coordinate geometry to two equivalent Pr(1), four equivalent Mn(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(5) atoms. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 14-coordinate geometry to one Pr(1), four equivalent Mn(1), one Co(2), two equivalent Co(4), two equivalent Co(5), and four equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a 14-coordinate geometry to one Pr(1), two equivalent Mn(2), four equivalent Mn(1), one Co(1), two equivalent Co(5), and four equivalent Co(3) atoms. In the third Co site, Co(3) is bonded in a 14-coordinate geometry to one Pr(1), one Mn(2), four equivalent Mn(1), one Co(3), one Co(4), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(5) atoms. In the fourth Co site, Co(4) is bonded in a 12-coordinate geometry to two equivalent Pr(1), four equivalent Mn(1), two equivalent Co(1), two equivalent Co(3), and two equivalent Co(5) atoms. In the fifth Co site, Co(5) is bonded in a 12-coordinate geometry to two equivalent Pr(1), one Mn(2), four equivalent Mn(1), one Co(1), one Co(2), one Co(4), and two equivalent Co(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_PrMn5Co7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.589
_cell_length_b   6.386
_cell_length_c   6.386
_cell_angle_alpha   97.176
_cell_angle_beta   111.058
_cell_angle_gamma   68.942
_symmetry_Int_Tables_number   1
_cell_volume   162.961
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.997  0.003  0.997  1.0
  Mn  Mn1  1  0.497  0.002  0.501  1.0
  Mn  Mn2  1  0.002  0.002  0.501  1.0
  Mn  Mn3  1  0.497  0.499  0.998  1.0
  Mn  Mn4  1  0.002  0.499  0.998  1.0
  Mn  Mn5  1  0.731  0.769  0.231  1.0
  Co  Co6  1  0.642  0.358  0.642  1.0
  Co  Co7  1  0.361  0.639  0.361  1.0
  Co  Co8  1  0.998  0.362  0.357  1.0
  Co  Co9  1  0.998  0.643  0.638  1.0
  Co  Co10  1  0.271  0.229  0.771  1.0
  Co  Co11  1  0.502  0.764  0.768  1.0
  Co  Co12  1  0.502  0.232  0.236  1.0
[/CIF]
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