The material described by Rb2P3 crystallizes in the orthorhombic Fmmm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to four equivalent P(1) and four equivalent P(2) atoms. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to two equivalent P(1) and eight equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 8-coordinate geometry to two equivalent Rb(2), four equivalent Rb(1), and two equivalent P(2) atoms. In the second P site, P(2) is bonded in a 8-coordinate geometry to two equivalent Rb(1), four equivalent Rb(2), one P(1), and one P(2) atom. is represented by the CIF card [CIF]
data_Rb2P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.619
_cell_length_b   6.619
_cell_length_c   8.617
_cell_angle_alpha   110.794
_cell_angle_beta   110.794
_cell_angle_gamma   94.338
_symmetry_Int_Tables_number   1
_cell_volume   321.046
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.750  0.500  1.0
  Rb  Rb1  1  0.750  0.250  0.500  1.0
  Rb  Rb2  1  0.280  0.720  0.000  1.0
  Rb  Rb3  1  0.720  0.280  0.000  1.0
  P  P4  1  0.853  0.853  0.706  1.0
  P  P5  1  0.147  0.147  0.294  1.0
  P  P6  1  0.133  0.133  0.854  1.0
  P  P7  1  0.280  0.280  0.146  1.0
  P  P8  1  0.867  0.867  0.146  1.0
  P  P9  1  0.720  0.720  0.854  1.0
[/CIF]
.
The material described by Rb2P3 crystallizes in the orthorhombic Fmmm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to four equivalent P(1) and four equivalent P(2) atoms. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to two equivalent P(1) and eight equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 8-coordinate geometry to two equivalent Rb(2), four equivalent Rb(1), and two equivalent P(2) atoms. In the second P site, P(2) is bonded in a 8-coordinate geometry to two equivalent Rb(1), four equivalent Rb(2), one P(1), and one P(2) atom. is represented by the CIF card [CIF]
data_Rb2P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.619
_cell_length_b   6.619
_cell_length_c   8.617
_cell_angle_alpha   110.794
_cell_angle_beta   110.794
_cell_angle_gamma   94.338
_symmetry_Int_Tables_number   1
_cell_volume   321.046
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.750  0.500  1.0
  Rb  Rb1  1  0.750  0.250  0.500  1.0
  Rb  Rb2  1  0.280  0.720  0.000  1.0
  Rb  Rb3  1  0.720  0.280  0.000  1.0
  P  P4  1  0.853  0.853  0.706  1.0
  P  P5  1  0.147  0.147  0.294  1.0
  P  P6  1  0.133  0.133  0.854  1.0
  P  P7  1  0.280  0.280  0.146  1.0
  P  P8  1  0.867  0.867  0.146  1.0
  P  P9  1  0.720  0.720  0.854  1.0
[/CIF]
.