The compound described by Li3CoCPO7 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(28), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(10), one O(26), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(10), one O(11), one O(12), one O(2), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Co(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 66-93°. In the fourth Li site, Li(4) is bonded to one O(13), one O(14), one O(5), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(6)O6 octahedra, and edges with two equivalent Li(5)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 69-82°. In the fifth Li site, Li(5) is bonded to one O(13), one O(14), one O(5), one O(6), and one O(8) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(6)O6 octahedra, and edges with two equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 72-85°. In the sixth Li site, Li(6) is bonded to one O(1), one O(13), one O(15), one O(4), one O(7), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  a cornercorner with one Co(1)O5 trigonal bipyramid,  an edgeedge with one Li(4)O5 trigonal bipyramid, and  an edgeedge with one Li(5)O5 trigonal bipyramid. In the seventh Li site, Li(7) is bonded to one O(15), one O(16), one O(21), one O(23), and one O(24) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Li(8)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 69-85°. In the eighth Li site, Li(8) is bonded to one O(15), one O(16), one O(22), one O(23), and one O(24) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Li(7)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 69-88°. In the ninth Li site, Li(9) is bonded to one O(17), one O(18), one O(20), one O(25), and one O(27) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Li(10)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 65-87°. In the tenth Li site, Li(10) is bonded to one O(17), one O(18), one O(19), one O(25), and one O(27) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Li(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 64-86°. In the eleventh Li site, Li(11) is bonded in a 4-coordinate geometry to one O(19), one O(20), one O(24), and one O(3) atom. In the twelfth Li site, Li(12) is bonded in a 4-coordinate geometry to one O(1), one O(21), one O(22), and one O(27) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Li(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 60-89°. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(17), one O(3), one O(6), and one O(9) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid,  an edgeedge with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Co(1)O5 trigonal bipyramid. In the third Co site, Co(3) is bonded to one O(12), one O(18), one O(19), one O(20), one O(23), and one O(26) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  a cornercorner with one Co(1)O5 trigonal bipyramid,  an edgeedge with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one Li(9)O5 trigonal bipyramid. In the fourth Co site, Co(4) is bonded to one O(14), one O(16), one O(21), one O(22), one O(25), and one O(28) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid,  an edgeedge with one Li(7)O5 trigonal bipyramid, and  an edgeedge with one Li(8)O5 trigonal bipyramid. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(24), and one O(4) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(2), one O(23), and one O(26) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(25), one O(28), and one O(5) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(16), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 44-62°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(18), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 44-61°. In the third P site, P(3) is bonded to one O(11), one O(15), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-60°. In the fourth P site, P(4) is bonded to one O(13), one O(17), one O(21), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid, and  a cornercorner with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 46-63°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(12), one Li(6), and one C(1) atom. In the second O site, O(2) is bonded to one Li(1), one Li(3), one Co(1), and one C(3) atom to form distorted OLi2CoC tetrahedra that share  a cornercorner with one O(23)Li2CoC trigonal pyramid, corners with two equivalent O(11)LiCo2P trigonal pyramids, and  an edgeedge with one O(12)LiCo2P tetrahedra. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(11), one Co(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(3), one Li(6), one Co(1), and one C(1) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(4), one Li(5), and one C(4) atom to form OLi3C tetrahedra that share corners with two equivalent O(13)Li3P trigonal pyramids and  an edgeedge with one O(14)Li2CoP tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(5), one Co(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Li(4), one Li(6), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(5), one Li(6), and one P(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Li(2), one Co(1), one Co(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Co(2), and one P(2) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Co(1), one Co(2), and one P(3) atom to form distorted OLiCo2P trigonal pyramids that share  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra, corners with two equivalent O(2)Li2CoC tetrahedra, corners with two equivalent O(12)LiCo2P tetrahedra,  a cornercorner with one O(19)Li2CoP trigonal pyramid, and  a cornercorner with one O(20)Li2CoP trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(3), one Co(1), one Co(3), and one P(1) atom to form distorted OLiCo2P tetrahedra that share  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(16)Li2CoP trigonal pyramid,  a cornercorner with one O(18)Li2CoP trigonal pyramid,  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid, corners with two equivalent O(11)LiCo2P trigonal pyramids, and  an edgeedge with one O(2)Li2CoC tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(4), one Li(5), one Li(6), and one P(4) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra, corners with two equivalent O(14)Li2CoP tetrahedra, corners with two equivalent O(5)Li3C tetrahedra,  a cornercorner with one O(21)Li2CoP trigonal pyramid, and  a cornercorner with one O(22)Li2CoP trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(4), one Li(5), one Co(4), and one P(2) atom to form distorted OLi2CoP tetrahedra that share  a cornercorner with one O(16)Li2CoP trigonal pyramid,  a cornercorner with one O(18)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid, corners with two equivalent O(13)Li3P trigonal pyramids, and  an edgeedge with one O(5)Li3C tetrahedra. In the fifteenth O site, O(15) is bonded to one Li(6), one Li(7), one Li(8), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li3P trigonal pyramid,  a cornercorner with one O(11)LiCo2P trigonal pyramid, corners with two equivalent O(23)Li2CoC trigonal pyramids, corners with two equivalent O(16)Li2CoP trigonal pyramids, and  an edgeedge with one O(24)Li3C tetrahedra. In the sixteenth O site, O(16) is bonded to one Li(7), one Li(8), one Co(4), and one P(1) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(14)Li2CoP tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra, corners with two equivalent O(24)Li3C tetrahedra, corners with two equivalent O(15)Li3P tetrahedra,  an edgeedge with one O(23)Li2CoC trigonal pyramid,  an edgeedge with one O(21)Li2CoP trigonal pyramid, and  an edgeedge with one O(22)Li2CoP trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Li(10), one Li(9), one Co(2), and one P(4) atom to form OLi2CoP tetrahedra that share  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li3P trigonal pyramid,  a cornercorner with one O(11)LiCo2P trigonal pyramid, corners with two equivalent O(18)Li2CoP trigonal pyramids, and  an edgeedge with one O(27)Li3C tetrahedra. In the eighteenth O site, O(18) is bonded to one Li(10), one Li(9), one Co(3), and one P(2) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(14)Li2CoP tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra, corners with two equivalent O(17)Li2CoP tetrahedra, corners with two equivalent O(27)Li3C tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  an edgeedge with one O(19)Li2CoP trigonal pyramid, and  an edgeedge with one O(20)Li2CoP trigonal pyramid. In the nineteenth O site, O(19) is bonded to one Li(10), one Li(11), one Co(3), and one P(3) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(24)Li3C tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(11)LiCo2P trigonal pyramid,  an edgeedge with one O(18)Li2CoP trigonal pyramid, and  an edgeedge with one O(20)Li2CoP trigonal pyramid. In the twentieth O site, O(20) is bonded to one Li(11), one Li(9), one Co(3), and one P(3) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(24)Li3C tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(11)LiCo2P trigonal pyramid,  an edgeedge with one O(18)Li2CoP trigonal pyramid, and  an edgeedge with one O(19)Li2CoP trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Li(12), one Li(7), one Co(4), and one P(4) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(14)Li2CoP tetrahedra,  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(24)Li3C tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li3P trigonal pyramid,  an edgeedge with one O(16)Li2CoP trigonal pyramid, and  an edgeedge with one O(22)Li2CoP trigonal pyramid. In the twenty-second O site, O(22) is bonded to one Li(12), one Li(8), one Co(4), and one P(4) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(14)Li2CoP tetrahedra,  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(24)Li3C tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li3P trigonal pyramid,  an edgeedge with one O(16)Li2CoP trigonal pyramid, and  an edgeedge with one O(21)Li2CoP trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Li(7), one Li(8), one Co(3), and one C(3) atom to form distorted OLi2CoC trigonal pyramids that share  a cornercorner with one O(2)Li2CoC tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra, corners with two equivalent O(24)Li3C tetrahedra, corners with two equivalent O(15)Li3P tetrahedra,  a cornercorner with one O(18)Li2CoP trigonal pyramid,  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid, and  an edgeedge with one O(16)Li2CoP trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Li(11), one Li(7), one Li(8), and one C(1) atom to form OLi3C tetrahedra that share  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid, corners with two equivalent O(23)Li2CoC trigonal pyramids, corners with two equivalent O(16)Li2CoP trigonal pyramids, and  an edgeedge with one O(15)Li3P tetrahedra. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one Li(10), one Li(9), one Co(4), and one C(4) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Li(2), one Co(3), and one C(3) atom. In the twenty-seventh O site, O(27) is bonded to one Li(10), one Li(12), one Li(9), and one C(2) atom to form a mixture of edge and corner-sharing OLi3C tetrahedra. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one Li(1), one Co(4), and one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3CoPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.441
_cell_length_b   8.467
_cell_length_c   9.934
_cell_angle_alpha   95.500
_cell_angle_beta   90.259
_cell_angle_gamma   90.446
_symmetry_Int_Tables_number   1
_cell_volume   539.201
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.742  0.894  0.393  1.0
  Li  Li1  1  0.745  0.899  0.881  1.0
  Li  Li2  1  0.509  0.724  0.137  1.0
  Li  Li3  1  0.998  0.727  0.614  1.0
  Li  Li4  1  0.511  0.724  0.610  1.0
  Li  Li5  1  0.252  0.651  0.398  1.0
  Li  Li6  1  0.473  0.282  0.375  1.0
  Li  Li7  1  0.028  0.284  0.376  1.0
  Li  Li8  1  0.476  0.277  0.871  1.0
  Li  Li9  1  0.019  0.275  0.871  1.0
  Li  Li10  1  0.251  0.100  0.115  1.0
  Li  Li11  1  0.250  0.103  0.610  1.0
  Co  Co12  1  0.996  0.730  0.144  1.0
  Co  Co13  1  0.253  0.667  0.894  1.0
  Co  Co14  1  0.751  0.331  0.103  1.0
  Co  Co15  1  0.751  0.332  0.604  1.0
  P  P16  1  0.753  0.590  0.362  1.0
  P  P17  1  0.751  0.586  0.865  1.0
  P  P18  1  0.249  0.409  0.141  1.0
  P  P19  1  0.251  0.416  0.639  1.0
  C  C20  1  0.242  0.963  0.348  1.0
  C  C21  1  0.247  0.961  0.848  1.0
  C  C22  1  0.751  0.038  0.151  1.0
  C  C23  1  0.749  0.038  0.651  1.0
  O  O24  1  0.250  0.931  0.470  1.0
  O  O25  1  0.756  0.893  0.189  1.0
  O  O26  1  0.253  0.929  0.973  1.0
  O  O27  1  0.237  0.847  0.248  1.0
  O  O28  1  0.746  0.893  0.681  1.0
  O  O29  1  0.240  0.842  0.755  1.0
  O  O30  1  0.942  0.694  0.411  1.0
  O  O31  1  0.560  0.690  0.405  1.0
  O  O32  1  0.939  0.691  0.927  1.0
  O  O33  1  0.565  0.691  0.917  1.0
  O  O34  1  0.247  0.578  0.089  1.0
  O  O35  1  0.763  0.568  0.201  1.0
  O  O36  1  0.254  0.579  0.587  1.0
  O  O37  1  0.761  0.568  0.709  1.0
  O  O38  1  0.249  0.428  0.296  1.0
  O  O39  1  0.750  0.423  0.412  1.0
  O  O40  1  0.250  0.434  0.798  1.0
  O  O41  1  0.749  0.420  0.916  1.0
  O  O42  1  0.062  0.305  0.083  1.0
  O  O43  1  0.438  0.312  0.083  1.0
  O  O44  1  0.438  0.309  0.589  1.0
  O  O45  1  0.064  0.309  0.586  1.0
  O  O46  1  0.741  0.158  0.243  1.0
  O  O47  1  0.246  0.108  0.315  1.0
  O  O48  1  0.752  0.156  0.746  1.0
  O  O49  1  0.754  0.065  0.026  1.0
  O  O50  1  0.249  0.106  0.815  1.0
  O  O51  1  0.748  0.073  0.527  1.0
[/CIF]
.
The compound described by Li3CoCPO7 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(28), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(10), one O(26), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(10), one O(11), one O(12), one O(2), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Co(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 66-93°. In the fourth Li site, Li(4) is bonded to one O(13), one O(14), one O(5), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(6)O6 octahedra, and edges with two equivalent Li(5)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 69-82°. In the fifth Li site, Li(5) is bonded to one O(13), one O(14), one O(5), one O(6), and one O(8) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(6)O6 octahedra, and edges with two equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 72-85°. In the sixth Li site, Li(6) is bonded to one O(1), one O(13), one O(15), one O(4), one O(7), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  a cornercorner with one Co(1)O5 trigonal bipyramid,  an edgeedge with one Li(4)O5 trigonal bipyramid, and  an edgeedge with one Li(5)O5 trigonal bipyramid. In the seventh Li site, Li(7) is bonded to one O(15), one O(16), one O(21), one O(23), and one O(24) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Li(8)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 69-85°. In the eighth Li site, Li(8) is bonded to one O(15), one O(16), one O(22), one O(23), and one O(24) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Li(7)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 69-88°. In the ninth Li site, Li(9) is bonded to one O(17), one O(18), one O(20), one O(25), and one O(27) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Li(10)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 65-87°. In the tenth Li site, Li(10) is bonded to one O(17), one O(18), one O(19), one O(25), and one O(27) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Li(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 64-86°. In the eleventh Li site, Li(11) is bonded in a 4-coordinate geometry to one O(19), one O(20), one O(24), and one O(3) atom. In the twelfth Li site, Li(12) is bonded in a 4-coordinate geometry to one O(1), one O(21), one O(22), and one O(27) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Li(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 60-89°. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(17), one O(3), one O(6), and one O(9) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid,  an edgeedge with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Co(1)O5 trigonal bipyramid. In the third Co site, Co(3) is bonded to one O(12), one O(18), one O(19), one O(20), one O(23), and one O(26) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  a cornercorner with one Co(1)O5 trigonal bipyramid,  an edgeedge with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one Li(9)O5 trigonal bipyramid. In the fourth Co site, Co(4) is bonded to one O(14), one O(16), one O(21), one O(22), one O(25), and one O(28) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid,  an edgeedge with one Li(7)O5 trigonal bipyramid, and  an edgeedge with one Li(8)O5 trigonal bipyramid. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(24), and one O(4) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(2), one O(23), and one O(26) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(25), one O(28), and one O(5) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(16), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 44-62°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(18), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 44-61°. In the third P site, P(3) is bonded to one O(11), one O(15), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid,  a cornercorner with one Li(9)O5 trigonal bipyramid, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-60°. In the fourth P site, P(4) is bonded to one O(13), one O(17), one O(21), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  a cornercorner with one Li(8)O5 trigonal bipyramid, and  a cornercorner with one Li(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 46-63°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(12), one Li(6), and one C(1) atom. In the second O site, O(2) is bonded to one Li(1), one Li(3), one Co(1), and one C(3) atom to form distorted OLi2CoC tetrahedra that share  a cornercorner with one O(23)Li2CoC trigonal pyramid, corners with two equivalent O(11)LiCo2P trigonal pyramids, and  an edgeedge with one O(12)LiCo2P tetrahedra. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(11), one Co(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(3), one Li(6), one Co(1), and one C(1) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(4), one Li(5), and one C(4) atom to form OLi3C tetrahedra that share corners with two equivalent O(13)Li3P trigonal pyramids and  an edgeedge with one O(14)Li2CoP tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(5), one Co(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Li(4), one Li(6), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(5), one Li(6), and one P(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Li(2), one Co(1), one Co(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Co(2), and one P(2) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Co(1), one Co(2), and one P(3) atom to form distorted OLiCo2P trigonal pyramids that share  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra, corners with two equivalent O(2)Li2CoC tetrahedra, corners with two equivalent O(12)LiCo2P tetrahedra,  a cornercorner with one O(19)Li2CoP trigonal pyramid, and  a cornercorner with one O(20)Li2CoP trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(3), one Co(1), one Co(3), and one P(1) atom to form distorted OLiCo2P tetrahedra that share  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(16)Li2CoP trigonal pyramid,  a cornercorner with one O(18)Li2CoP trigonal pyramid,  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid, corners with two equivalent O(11)LiCo2P trigonal pyramids, and  an edgeedge with one O(2)Li2CoC tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(4), one Li(5), one Li(6), and one P(4) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra, corners with two equivalent O(14)Li2CoP tetrahedra, corners with two equivalent O(5)Li3C tetrahedra,  a cornercorner with one O(21)Li2CoP trigonal pyramid, and  a cornercorner with one O(22)Li2CoP trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(4), one Li(5), one Co(4), and one P(2) atom to form distorted OLi2CoP tetrahedra that share  a cornercorner with one O(16)Li2CoP trigonal pyramid,  a cornercorner with one O(18)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid, corners with two equivalent O(13)Li3P trigonal pyramids, and  an edgeedge with one O(5)Li3C tetrahedra. In the fifteenth O site, O(15) is bonded to one Li(6), one Li(7), one Li(8), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li3P trigonal pyramid,  a cornercorner with one O(11)LiCo2P trigonal pyramid, corners with two equivalent O(23)Li2CoC trigonal pyramids, corners with two equivalent O(16)Li2CoP trigonal pyramids, and  an edgeedge with one O(24)Li3C tetrahedra. In the sixteenth O site, O(16) is bonded to one Li(7), one Li(8), one Co(4), and one P(1) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(14)Li2CoP tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra, corners with two equivalent O(24)Li3C tetrahedra, corners with two equivalent O(15)Li3P tetrahedra,  an edgeedge with one O(23)Li2CoC trigonal pyramid,  an edgeedge with one O(21)Li2CoP trigonal pyramid, and  an edgeedge with one O(22)Li2CoP trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Li(10), one Li(9), one Co(2), and one P(4) atom to form OLi2CoP tetrahedra that share  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li3P trigonal pyramid,  a cornercorner with one O(11)LiCo2P trigonal pyramid, corners with two equivalent O(18)Li2CoP trigonal pyramids, and  an edgeedge with one O(27)Li3C tetrahedra. In the eighteenth O site, O(18) is bonded to one Li(10), one Li(9), one Co(3), and one P(2) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(14)Li2CoP tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra, corners with two equivalent O(17)Li2CoP tetrahedra, corners with two equivalent O(27)Li3C tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  an edgeedge with one O(19)Li2CoP trigonal pyramid, and  an edgeedge with one O(20)Li2CoP trigonal pyramid. In the nineteenth O site, O(19) is bonded to one Li(10), one Li(11), one Co(3), and one P(3) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(24)Li3C tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(11)LiCo2P trigonal pyramid,  an edgeedge with one O(18)Li2CoP trigonal pyramid, and  an edgeedge with one O(20)Li2CoP trigonal pyramid. In the twentieth O site, O(20) is bonded to one Li(11), one Li(9), one Co(3), and one P(3) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(24)Li3C tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(11)LiCo2P trigonal pyramid,  an edgeedge with one O(18)Li2CoP trigonal pyramid, and  an edgeedge with one O(19)Li2CoP trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Li(12), one Li(7), one Co(4), and one P(4) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(14)Li2CoP tetrahedra,  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(24)Li3C tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li3P trigonal pyramid,  an edgeedge with one O(16)Li2CoP trigonal pyramid, and  an edgeedge with one O(22)Li2CoP trigonal pyramid. In the twenty-second O site, O(22) is bonded to one Li(12), one Li(8), one Co(4), and one P(4) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(14)Li2CoP tetrahedra,  a cornercorner with one O(17)Li2CoP tetrahedra,  a cornercorner with one O(24)Li3C tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(23)Li2CoC trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(13)Li3P trigonal pyramid,  an edgeedge with one O(16)Li2CoP trigonal pyramid, and  an edgeedge with one O(21)Li2CoP trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Li(7), one Li(8), one Co(3), and one C(3) atom to form distorted OLi2CoC trigonal pyramids that share  a cornercorner with one O(2)Li2CoC tetrahedra,  a cornercorner with one O(12)LiCo2P tetrahedra, corners with two equivalent O(24)Li3C tetrahedra, corners with two equivalent O(15)Li3P tetrahedra,  a cornercorner with one O(18)Li2CoP trigonal pyramid,  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid, and  an edgeedge with one O(16)Li2CoP trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Li(11), one Li(7), one Li(8), and one C(1) atom to form OLi3C tetrahedra that share  a cornercorner with one O(19)Li2CoP trigonal pyramid,  a cornercorner with one O(20)Li2CoP trigonal pyramid,  a cornercorner with one O(21)Li2CoP trigonal pyramid,  a cornercorner with one O(22)Li2CoP trigonal pyramid, corners with two equivalent O(23)Li2CoC trigonal pyramids, corners with two equivalent O(16)Li2CoP trigonal pyramids, and  an edgeedge with one O(15)Li3P tetrahedra. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one Li(10), one Li(9), one Co(4), and one C(4) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Li(2), one Co(3), and one C(3) atom. In the twenty-seventh O site, O(27) is bonded to one Li(10), one Li(12), one Li(9), and one C(2) atom to form a mixture of edge and corner-sharing OLi3C tetrahedra. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one Li(1), one Co(4), and one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3CoPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.441
_cell_length_b   8.467
_cell_length_c   9.934
_cell_angle_alpha   95.500
_cell_angle_beta   90.259
_cell_angle_gamma   90.446
_symmetry_Int_Tables_number   1
_cell_volume   539.201
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.742  0.894  0.393  1.0
  Li  Li1  1  0.745  0.899  0.881  1.0
  Li  Li2  1  0.509  0.724  0.137  1.0
  Li  Li3  1  0.998  0.727  0.614  1.0
  Li  Li4  1  0.511  0.724  0.610  1.0
  Li  Li5  1  0.252  0.651  0.398  1.0
  Li  Li6  1  0.473  0.282  0.375  1.0
  Li  Li7  1  0.028  0.284  0.376  1.0
  Li  Li8  1  0.476  0.277  0.871  1.0
  Li  Li9  1  0.019  0.275  0.871  1.0
  Li  Li10  1  0.251  0.100  0.115  1.0
  Li  Li11  1  0.250  0.103  0.610  1.0
  Co  Co12  1  0.996  0.730  0.144  1.0
  Co  Co13  1  0.253  0.667  0.894  1.0
  Co  Co14  1  0.751  0.331  0.103  1.0
  Co  Co15  1  0.751  0.332  0.604  1.0
  P  P16  1  0.753  0.590  0.362  1.0
  P  P17  1  0.751  0.586  0.865  1.0
  P  P18  1  0.249  0.409  0.141  1.0
  P  P19  1  0.251  0.416  0.639  1.0
  C  C20  1  0.242  0.963  0.348  1.0
  C  C21  1  0.247  0.961  0.848  1.0
  C  C22  1  0.751  0.038  0.151  1.0
  C  C23  1  0.749  0.038  0.651  1.0
  O  O24  1  0.250  0.931  0.470  1.0
  O  O25  1  0.756  0.893  0.189  1.0
  O  O26  1  0.253  0.929  0.973  1.0
  O  O27  1  0.237  0.847  0.248  1.0
  O  O28  1  0.746  0.893  0.681  1.0
  O  O29  1  0.240  0.842  0.755  1.0
  O  O30  1  0.942  0.694  0.411  1.0
  O  O31  1  0.560  0.690  0.405  1.0
  O  O32  1  0.939  0.691  0.927  1.0
  O  O33  1  0.565  0.691  0.917  1.0
  O  O34  1  0.247  0.578  0.089  1.0
  O  O35  1  0.763  0.568  0.201  1.0
  O  O36  1  0.254  0.579  0.587  1.0
  O  O37  1  0.761  0.568  0.709  1.0
  O  O38  1  0.249  0.428  0.296  1.0
  O  O39  1  0.750  0.423  0.412  1.0
  O  O40  1  0.250  0.434  0.798  1.0
  O  O41  1  0.749  0.420  0.916  1.0
  O  O42  1  0.062  0.305  0.083  1.0
  O  O43  1  0.438  0.312  0.083  1.0
  O  O44  1  0.438  0.309  0.589  1.0
  O  O45  1  0.064  0.309  0.586  1.0
  O  O46  1  0.741  0.158  0.243  1.0
  O  O47  1  0.246  0.108  0.315  1.0
  O  O48  1  0.752  0.156  0.746  1.0
  O  O49  1  0.754  0.065  0.026  1.0
  O  O50  1  0.249  0.106  0.815  1.0
  O  O51  1  0.748  0.073  0.527  1.0
[/CIF]
.