The material described by AgVO3 crystallizes in the triclinic P-1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(10), one O(2), one O(3), and one O(7) atom. In the second V site, V(2) is bonded to one O(1), one O(4), one O(8), and one O(9) atom to form corner-sharing VO4 tetrahedra. In the third V site, V(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(7), and two equivalent O(6) atoms. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(9), and two equivalent O(5) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(2)O4 tetrahedra and  an edgeedge with one V(4)O5 trigonal bipyramid. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to one O(1), one O(11), one O(12), and one O(2) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(10), one O(7), and one O(8) atom. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(4), and one O(9) atom. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted tetrahedral geometry to one V(2), one V(4), one Ag(1), and one Ag(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one Ag(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Ag(3) atom. In the fifth O site, O(5) is bonded in a water-like geometry to two equivalent V(4) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent V(3) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one Ag(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(2) and one Ag(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one V(2), one V(4), and one Ag(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(3), and one Ag(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one V(3), one Ag(1), and one Ag(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one V(4), one Ag(1), and one Ag(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAgO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.327
_cell_length_b   14.884
_cell_length_c   9.377
_cell_angle_alpha   55.471
_cell_angle_beta   91.978
_cell_angle_gamma   86.889
_symmetry_Int_Tables_number   1
_cell_volume   609.662
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.139  0.476  0.250  1.0
  V  V1  1  0.049  0.936  0.256  1.0
  V  V2  1  0.198  0.411  0.641  1.0
  V  V3  1  0.487  0.958  0.676  1.0
  V  V4  1  0.513  0.042  0.324  1.0
  V  V5  1  0.802  0.589  0.359  1.0
  V  V6  1  0.951  0.064  0.744  1.0
  V  V7  1  0.861  0.524  0.750  1.0
  Ag  Ag8  1  0.969  0.226  0.033  1.0
  Ag  Ag9  1  0.031  0.774  0.967  1.0
  Ag  Ag10  1  0.324  0.684  0.566  1.0
  Ag  Ag11  1  0.451  0.119  0.898  1.0
  Ag  Ag12  1  0.536  0.644  0.909  1.0
  Ag  Ag13  1  0.464  0.356  0.091  1.0
  Ag  Ag14  1  0.549  0.881  0.102  1.0
  Ag  Ag15  1  0.676  0.316  0.434  1.0
  O  O16  1  0.228  0.056  0.177  1.0
  O  O17  1  0.237  0.597  0.083  1.0
  O  O18  1  0.149  0.384  0.199  1.0
  O  O19  1  0.124  0.882  0.143  1.0
  O  O20  1  0.295  0.048  0.467  1.0
  O  O21  1  0.116  0.592  0.385  1.0
  O  O22  1  0.329  0.405  0.463  1.0
  O  O23  1  0.168  0.846  0.464  1.0
  O  O24  1  0.289  0.033  0.760  1.0
  O  O25  1  0.192  0.501  0.727  1.0
  O  O26  1  0.300  0.289  0.826  1.0
  O  O27  1  0.376  0.834  0.793  1.0
  O  O28  1  0.624  0.166  0.207  1.0
  O  O29  1  0.700  0.711  0.174  1.0
  O  O30  1  0.808  0.499  0.273  1.0
  O  O31  1  0.711  0.967  0.240  1.0
  O  O32  1  0.832  0.154  0.536  1.0
  O  O33  1  0.671  0.595  0.537  1.0
  O  O34  1  0.884  0.408  0.615  1.0
  O  O35  1  0.705  0.952  0.533  1.0
  O  O36  1  0.876  0.118  0.857  1.0
  O  O37  1  0.851  0.616  0.801  1.0
  O  O38  1  0.763  0.403  0.917  1.0
  O  O39  1  0.772  0.944  0.823  1.0
[/CIF]
.
The material described by AgVO3 crystallizes in the triclinic P-1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(10), one O(2), one O(3), and one O(7) atom. In the second V site, V(2) is bonded to one O(1), one O(4), one O(8), and one O(9) atom to form corner-sharing VO4 tetrahedra. In the third V site, V(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(7), and two equivalent O(6) atoms. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(9), and two equivalent O(5) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(2)O4 tetrahedra and  an edgeedge with one V(4)O5 trigonal bipyramid. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to one O(1), one O(11), one O(12), and one O(2) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(10), one O(7), and one O(8) atom. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(4), and one O(9) atom. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted tetrahedral geometry to one V(2), one V(4), one Ag(1), and one Ag(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one Ag(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Ag(3) atom. In the fifth O site, O(5) is bonded in a water-like geometry to two equivalent V(4) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent V(3) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one Ag(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(2) and one Ag(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one V(2), one V(4), and one Ag(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(3), and one Ag(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one V(3), one Ag(1), and one Ag(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one V(4), one Ag(1), and one Ag(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAgO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.327
_cell_length_b   14.884
_cell_length_c   9.377
_cell_angle_alpha   55.471
_cell_angle_beta   91.978
_cell_angle_gamma   86.889
_symmetry_Int_Tables_number   1
_cell_volume   609.662
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.139  0.476  0.250  1.0
  V  V1  1  0.049  0.936  0.256  1.0
  V  V2  1  0.198  0.411  0.641  1.0
  V  V3  1  0.487  0.958  0.676  1.0
  V  V4  1  0.513  0.042  0.324  1.0
  V  V5  1  0.802  0.589  0.359  1.0
  V  V6  1  0.951  0.064  0.744  1.0
  V  V7  1  0.861  0.524  0.750  1.0
  Ag  Ag8  1  0.969  0.226  0.033  1.0
  Ag  Ag9  1  0.031  0.774  0.967  1.0
  Ag  Ag10  1  0.324  0.684  0.566  1.0
  Ag  Ag11  1  0.451  0.119  0.898  1.0
  Ag  Ag12  1  0.536  0.644  0.909  1.0
  Ag  Ag13  1  0.464  0.356  0.091  1.0
  Ag  Ag14  1  0.549  0.881  0.102  1.0
  Ag  Ag15  1  0.676  0.316  0.434  1.0
  O  O16  1  0.228  0.056  0.177  1.0
  O  O17  1  0.237  0.597  0.083  1.0
  O  O18  1  0.149  0.384  0.199  1.0
  O  O19  1  0.124  0.882  0.143  1.0
  O  O20  1  0.295  0.048  0.467  1.0
  O  O21  1  0.116  0.592  0.385  1.0
  O  O22  1  0.329  0.405  0.463  1.0
  O  O23  1  0.168  0.846  0.464  1.0
  O  O24  1  0.289  0.033  0.760  1.0
  O  O25  1  0.192  0.501  0.727  1.0
  O  O26  1  0.300  0.289  0.826  1.0
  O  O27  1  0.376  0.834  0.793  1.0
  O  O28  1  0.624  0.166  0.207  1.0
  O  O29  1  0.700  0.711  0.174  1.0
  O  O30  1  0.808  0.499  0.273  1.0
  O  O31  1  0.711  0.967  0.240  1.0
  O  O32  1  0.832  0.154  0.536  1.0
  O  O33  1  0.671  0.595  0.537  1.0
  O  O34  1  0.884  0.408  0.615  1.0
  O  O35  1  0.705  0.952  0.533  1.0
  O  O36  1  0.876  0.118  0.857  1.0
  O  O37  1  0.851  0.616  0.801  1.0
  O  O38  1  0.763  0.403  0.917  1.0
  O  O39  1  0.772  0.944  0.823  1.0
[/CIF]
.