The structure described by ZnH2SO5 crystallizes in the monoclinic C2/c space group. Zn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ZnO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with four equivalent S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 56°. H(1) is bonded in a single-bond geometry to one O(2) and one O(3) atom. S(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form SO4 tetrahedra that share corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one H(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Zn(1) and two equivalent H(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH2SO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.199
_cell_length_b   5.199
_cell_length_c   7.622
_cell_angle_alpha   73.498
_cell_angle_beta   73.498
_cell_angle_gamma   96.819
_symmetry_Int_Tables_number   1
_cell_volume   184.903
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.500  1.0
  Zn  Zn1  1  0.500  0.000  0.000  1.0
  H  H2  1  0.629  0.546  0.796  1.0
  H  H3  1  0.454  0.371  0.704  1.0
  H  H4  1  0.371  0.454  0.204  1.0
  H  H5  1  0.546  0.629  0.296  1.0
  S  S6  1  0.094  0.906  0.750  1.0
  S  S7  1  0.906  0.094  0.250  1.0
  O  O8  1  0.226  0.818  0.899  1.0
  O  O9  1  0.182  0.774  0.601  1.0
  O  O10  1  0.774  0.182  0.101  1.0
  O  O11  1  0.818  0.226  0.399  1.0
  O  O12  1  0.178  0.212  0.658  1.0
  O  O13  1  0.788  0.822  0.842  1.0
  O  O14  1  0.822  0.788  0.342  1.0
  O  O15  1  0.212  0.178  0.158  1.0
  O  O16  1  0.616  0.384  0.750  1.0
  O  O17  1  0.384  0.616  0.250  1.0
[/CIF]
.
The structure described by ZnH2SO5 crystallizes in the monoclinic C2/c space group. Zn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ZnO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with four equivalent S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 56°. H(1) is bonded in a single-bond geometry to one O(2) and one O(3) atom. S(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form SO4 tetrahedra that share corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one H(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Zn(1) and two equivalent H(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH2SO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.199
_cell_length_b   5.199
_cell_length_c   7.622
_cell_angle_alpha   73.498
_cell_angle_beta   73.498
_cell_angle_gamma   96.819
_symmetry_Int_Tables_number   1
_cell_volume   184.903
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.500  1.0
  Zn  Zn1  1  0.500  0.000  0.000  1.0
  H  H2  1  0.629  0.546  0.796  1.0
  H  H3  1  0.454  0.371  0.704  1.0
  H  H4  1  0.371  0.454  0.204  1.0
  H  H5  1  0.546  0.629  0.296  1.0
  S  S6  1  0.094  0.906  0.750  1.0
  S  S7  1  0.906  0.094  0.250  1.0
  O  O8  1  0.226  0.818  0.899  1.0
  O  O9  1  0.182  0.774  0.601  1.0
  O  O10  1  0.774  0.182  0.101  1.0
  O  O11  1  0.818  0.226  0.399  1.0
  O  O12  1  0.178  0.212  0.658  1.0
  O  O13  1  0.788  0.822  0.842  1.0
  O  O14  1  0.822  0.788  0.342  1.0
  O  O15  1  0.212  0.178  0.158  1.0
  O  O16  1  0.616  0.384  0.750  1.0
  O  O17  1  0.384  0.616  0.250  1.0
[/CIF]
.