The compound described by Li(SeO3)2 crystallizes in the monoclinic Pc space group. Li(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(3), and one O(5) atom. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(2), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(SeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.626
_cell_length_b   6.563
_cell_length_c   8.070
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.546
_symmetry_Int_Tables_number   1
_cell_volume   287.054
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.491  0.003  0.251  1.0
  Li  Li1  1  0.991  0.503  0.749  1.0
  Se  Se2  1  0.076  0.262  0.372  1.0
  Se  Se3  1  0.576  0.762  0.628  1.0
  Se  Se4  1  0.899  0.738  0.123  1.0
  Se  Se5  1  0.399  0.238  0.877  1.0
  O  O6  1  0.857  0.196  0.228  1.0
  O  O7  1  0.357  0.696  0.772  1.0
  O  O8  1  0.108  0.813  0.272  1.0
  O  O9  1  0.608  0.313  0.728  1.0
  O  O10  1  0.356  0.282  0.297  1.0
  O  O11  1  0.856  0.782  0.703  1.0
  O  O12  1  0.612  0.717  0.184  1.0
  O  O13  1  0.112  0.217  0.816  1.0
  O  O14  1  0.061  0.471  0.485  1.0
  O  O15  1  0.561  0.971  0.515  1.0
  O  O16  1  0.929  0.533  0.013  1.0
  O  O17  1  0.429  0.033  0.987  1.0
[/CIF]
.
The compound described by Li(SeO3)2 crystallizes in the monoclinic Pc space group. Li(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(3), and one O(5) atom. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(2), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one Se(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(SeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.626
_cell_length_b   6.563
_cell_length_c   8.070
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.546
_symmetry_Int_Tables_number   1
_cell_volume   287.054
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.491  0.003  0.251  1.0
  Li  Li1  1  0.991  0.503  0.749  1.0
  Se  Se2  1  0.076  0.262  0.372  1.0
  Se  Se3  1  0.576  0.762  0.628  1.0
  Se  Se4  1  0.899  0.738  0.123  1.0
  Se  Se5  1  0.399  0.238  0.877  1.0
  O  O6  1  0.857  0.196  0.228  1.0
  O  O7  1  0.357  0.696  0.772  1.0
  O  O8  1  0.108  0.813  0.272  1.0
  O  O9  1  0.608  0.313  0.728  1.0
  O  O10  1  0.356  0.282  0.297  1.0
  O  O11  1  0.856  0.782  0.703  1.0
  O  O12  1  0.612  0.717  0.184  1.0
  O  O13  1  0.112  0.217  0.816  1.0
  O  O14  1  0.061  0.471  0.485  1.0
  O  O15  1  0.561  0.971  0.515  1.0
  O  O16  1  0.929  0.533  0.013  1.0
  O  O17  1  0.429  0.033  0.987  1.0
[/CIF]
.