The material described by CaRhIn4 crystallizes in the orthorhombic Pmma space group. Ca(1) is bonded in a 13-coordinate geometry to one Rh(1), two equivalent In(1), two equivalent In(2), and eight equivalent In(3) atoms. Rh(1) is bonded in a 9-coordinate geometry to one Ca(1), two equivalent In(1), two equivalent In(2), and four equivalent In(3) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a linear geometry to two equivalent Ca(1) and two equivalent Rh(1) atoms. In the second In site, In(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Ca(1) and two equivalent Rh(1) atoms. In the third In site, In(3) is bonded in a 2-coordinate geometry to four equivalent Ca(1) and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_CaIn4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.278
_cell_length_b   7.447
_cell_length_c   8.707
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   277.423
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.000  0.400  0.250  1.0
  Ca  Ca1  1  0.000  0.600  0.750  1.0
  In  In2  1  0.000  0.000  0.000  1.0
  In  In3  1  0.000  0.000  0.500  1.0
  In  In4  1  0.500  0.066  0.250  1.0
  In  In5  1  0.500  0.934  0.750  1.0
  In  In6  1  0.500  0.687  0.065  1.0
  In  In7  1  0.500  0.313  0.935  1.0
  In  In8  1  0.500  0.687  0.435  1.0
  In  In9  1  0.500  0.313  0.565  1.0
  Rh  Rh10  1  0.000  0.807  0.250  1.0
  Rh  Rh11  1  0.000  0.193  0.750  1.0
[/CIF]
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The material described by CaRhIn4 crystallizes in the orthorhombic Pmma space group. Ca(1) is bonded in a 13-coordinate geometry to one Rh(1), two equivalent In(1), two equivalent In(2), and eight equivalent In(3) atoms. Rh(1) is bonded in a 9-coordinate geometry to one Ca(1), two equivalent In(1), two equivalent In(2), and four equivalent In(3) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a linear geometry to two equivalent Ca(1) and two equivalent Rh(1) atoms. In the second In site, In(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Ca(1) and two equivalent Rh(1) atoms. In the third In site, In(3) is bonded in a 2-coordinate geometry to four equivalent Ca(1) and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_CaIn4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.278
_cell_length_b   7.447
_cell_length_c   8.707
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   277.423
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.000  0.400  0.250  1.0
  Ca  Ca1  1  0.000  0.600  0.750  1.0
  In  In2  1  0.000  0.000  0.000  1.0
  In  In3  1  0.000  0.000  0.500  1.0
  In  In4  1  0.500  0.066  0.250  1.0
  In  In5  1  0.500  0.934  0.750  1.0
  In  In6  1  0.500  0.687  0.065  1.0
  In  In7  1  0.500  0.313  0.935  1.0
  In  In8  1  0.500  0.687  0.435  1.0
  In  In9  1  0.500  0.313  0.565  1.0
  Rh  Rh10  1  0.000  0.807  0.250  1.0
  Rh  Rh11  1  0.000  0.193  0.750  1.0
[/CIF]
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