The structure described by Li3Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-77°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(2), and one O(4) atom. In the third Li site, Li(3) is bonded to one O(13), one O(14), one O(5), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 66-75°. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(22), one O(23), and one O(24) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 63-79°. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(17), one O(18), one O(20), one O(25), and one O(27) atom. In the sixth Li site, Li(6) is bonded in a 4-coordinate geometry to one O(1), one O(21), one O(22), and one O(27) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(13), one O(15), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. In the second Mn site, Mn(2) is bonded to one O(10), one O(11), one O(17), one O(3), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(1)O5 trigonal bipyramid. In the third Mn site, Mn(3) is bonded to one O(12), one O(18), one O(19), one O(20), one O(23), and one O(26) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(16), one O(21), one O(22), one O(25), and one O(28) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(4)O5 trigonal bipyramid. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(24), and one O(4) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(2), one O(23), and one O(26) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(25), one O(28), and one O(5) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(16), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-53°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(18), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 43-51°. In the third P site, P(3) is bonded to one O(11), one O(15), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 40-50°. In the fourth P site, P(4) is bonded to one O(13), one O(17), one O(21), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 39-50°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(6), one Mn(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(2), and one C(3) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Mn(2) and one C(2) atom. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Mn(1), and one C(1) atom to form distorted edge-sharing OLi2MnC trigonal pyramids. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(3) and one C(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(3), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Li(2), one Mn(2), and one P(3) atom to form distorted edge-sharing OLi2MnP trigonal pyramids. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Mn(3), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(3), one Mn(1), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Li(3), one Mn(4), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(1), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(4), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Mn(2), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(5), one Mn(3), and one P(2) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(3) atom. In the twentieth O site, O(20) is bonded in a distorted T-shaped geometry to one Li(5), one Mn(3), and one P(3) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(6), one Mn(4), and one P(4) atom. In the twenty-second O site, O(22) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(6), one Mn(4), and one P(4) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Li(4), one Mn(3), and one C(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Li(4) and one C(1) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Li(5), one Mn(4), and one C(4) atom. In the twenty-sixth O site, O(26) is bonded in an L-shaped geometry to one Mn(3) and one C(3) atom. In the twenty-seventh O site, O(27) is bonded in a trigonal non-coplanar geometry to one Li(5), one Li(6), and one C(2) atom. In the twenty-eighth O site, O(28) is bonded in an L-shaped geometry to one Mn(4) and one C(4) atom. is represented by the CIF card [CIF]
data_Li3Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.479
_cell_length_b   8.297
_cell_length_c   10.101
_cell_angle_alpha   85.698
_cell_angle_beta   89.814
_cell_angle_gamma   89.525
_symmetry_Int_Tables_number   1
_cell_volume   541.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.022  0.739  0.874  1.0
  Li  Li1  1  0.479  0.744  0.874  1.0
  Li  Li2  1  0.053  0.725  0.381  1.0
  Li  Li3  1  0.970  0.270  0.633  1.0
  Li  Li4  1  0.534  0.263  0.115  1.0
  Li  Li5  1  0.741  0.098  0.384  1.0
  Mn  Mn6  1  0.744  0.671  0.598  1.0
  Mn  Mn7  1  0.750  0.668  0.104  1.0
  Mn  Mn8  1  0.246  0.330  0.899  1.0
  Mn  Mn9  1  0.252  0.329  0.397  1.0
  P  P10  1  0.243  0.580  0.637  1.0
  P  P11  1  0.252  0.578  0.134  1.0
  P  P12  1  0.752  0.420  0.862  1.0
  P  P13  1  0.752  0.420  0.360  1.0
  C  C14  1  0.758  0.957  0.645  1.0
  C  C15  1  0.749  0.949  0.149  1.0
  C  C16  1  0.247  0.046  0.857  1.0
  C  C17  1  0.246  0.046  0.353  1.0
  O  O18  1  0.751  0.914  0.523  1.0
  O  O19  1  0.247  0.899  0.835  1.0
  O  O20  1  0.744  0.901  0.029  1.0
  O  O21  1  0.744  0.830  0.734  1.0
  O  O22  1  0.227  0.903  0.328  1.0
  O  O23  1  0.773  0.827  0.240  1.0
  O  O24  1  0.060  0.692  0.591  1.0
  O  O25  1  0.438  0.674  0.598  1.0
  O  O26  1  0.062  0.675  0.078  1.0
  O  O27  1  0.437  0.686  0.090  1.0
  O  O28  1  0.745  0.590  0.922  1.0
  O  O29  1  0.236  0.546  0.794  1.0
  O  O30  1  0.771  0.581  0.426  1.0
  O  O31  1  0.232  0.543  0.288  1.0
  O  O32  1  0.764  0.458  0.708  1.0
  O  O33  1  0.224  0.416  0.575  1.0
  O  O34  1  0.743  0.460  0.207  1.0
  O  O35  1  0.273  0.412  0.075  1.0
  O  O36  1  0.940  0.319  0.909  1.0
  O  O37  1  0.562  0.321  0.908  1.0
  O  O38  1  0.564  0.315  0.403  1.0
  O  O39  1  0.932  0.303  0.402  1.0
  O  O40  1  0.231  0.165  0.764  1.0
  O  O41  1  0.777  0.097  0.677  1.0
  O  O42  1  0.272  0.167  0.262  1.0
  O  O43  1  0.263  0.100  0.975  1.0
  O  O44  1  0.728  0.091  0.181  1.0
  O  O45  1  0.241  0.098  0.473  1.0
[/CIF]
.
The structure described by Li3Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-77°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(2), and one O(4) atom. In the third Li site, Li(3) is bonded to one O(13), one O(14), one O(5), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 66-75°. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(22), one O(23), and one O(24) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 63-79°. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(17), one O(18), one O(20), one O(25), and one O(27) atom. In the sixth Li site, Li(6) is bonded in a 4-coordinate geometry to one O(1), one O(21), one O(22), and one O(27) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(13), one O(15), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. In the second Mn site, Mn(2) is bonded to one O(10), one O(11), one O(17), one O(3), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(1)O5 trigonal bipyramid. In the third Mn site, Mn(3) is bonded to one O(12), one O(18), one O(19), one O(20), one O(23), and one O(26) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(16), one O(21), one O(22), one O(25), and one O(28) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(4)O5 trigonal bipyramid. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(24), and one O(4) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(2), one O(23), and one O(26) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(25), one O(28), and one O(5) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(16), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-53°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(18), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 43-51°. In the third P site, P(3) is bonded to one O(11), one O(15), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 40-50°. In the fourth P site, P(4) is bonded to one O(13), one O(17), one O(21), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 39-50°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(6), one Mn(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(2), and one C(3) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Mn(2) and one C(2) atom. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Mn(1), and one C(1) atom to form distorted edge-sharing OLi2MnC trigonal pyramids. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(3) and one C(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(3), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Li(2), one Mn(2), and one P(3) atom to form distorted edge-sharing OLi2MnP trigonal pyramids. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Mn(3), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(3), one Mn(1), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Li(3), one Mn(4), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(1), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(4), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Mn(2), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(5), one Mn(3), and one P(2) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(3) atom. In the twentieth O site, O(20) is bonded in a distorted T-shaped geometry to one Li(5), one Mn(3), and one P(3) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(6), one Mn(4), and one P(4) atom. In the twenty-second O site, O(22) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(6), one Mn(4), and one P(4) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Li(4), one Mn(3), and one C(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Li(4) and one C(1) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Li(5), one Mn(4), and one C(4) atom. In the twenty-sixth O site, O(26) is bonded in an L-shaped geometry to one Mn(3) and one C(3) atom. In the twenty-seventh O site, O(27) is bonded in a trigonal non-coplanar geometry to one Li(5), one Li(6), and one C(2) atom. In the twenty-eighth O site, O(28) is bonded in an L-shaped geometry to one Mn(4) and one C(4) atom. is represented by the CIF card [CIF]
data_Li3Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.479
_cell_length_b   8.297
_cell_length_c   10.101
_cell_angle_alpha   85.698
_cell_angle_beta   89.814
_cell_angle_gamma   89.525
_symmetry_Int_Tables_number   1
_cell_volume   541.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.022  0.739  0.874  1.0
  Li  Li1  1  0.479  0.744  0.874  1.0
  Li  Li2  1  0.053  0.725  0.381  1.0
  Li  Li3  1  0.970  0.270  0.633  1.0
  Li  Li4  1  0.534  0.263  0.115  1.0
  Li  Li5  1  0.741  0.098  0.384  1.0
  Mn  Mn6  1  0.744  0.671  0.598  1.0
  Mn  Mn7  1  0.750  0.668  0.104  1.0
  Mn  Mn8  1  0.246  0.330  0.899  1.0
  Mn  Mn9  1  0.252  0.329  0.397  1.0
  P  P10  1  0.243  0.580  0.637  1.0
  P  P11  1  0.252  0.578  0.134  1.0
  P  P12  1  0.752  0.420  0.862  1.0
  P  P13  1  0.752  0.420  0.360  1.0
  C  C14  1  0.758  0.957  0.645  1.0
  C  C15  1  0.749  0.949  0.149  1.0
  C  C16  1  0.247  0.046  0.857  1.0
  C  C17  1  0.246  0.046  0.353  1.0
  O  O18  1  0.751  0.914  0.523  1.0
  O  O19  1  0.247  0.899  0.835  1.0
  O  O20  1  0.744  0.901  0.029  1.0
  O  O21  1  0.744  0.830  0.734  1.0
  O  O22  1  0.227  0.903  0.328  1.0
  O  O23  1  0.773  0.827  0.240  1.0
  O  O24  1  0.060  0.692  0.591  1.0
  O  O25  1  0.438  0.674  0.598  1.0
  O  O26  1  0.062  0.675  0.078  1.0
  O  O27  1  0.437  0.686  0.090  1.0
  O  O28  1  0.745  0.590  0.922  1.0
  O  O29  1  0.236  0.546  0.794  1.0
  O  O30  1  0.771  0.581  0.426  1.0
  O  O31  1  0.232  0.543  0.288  1.0
  O  O32  1  0.764  0.458  0.708  1.0
  O  O33  1  0.224  0.416  0.575  1.0
  O  O34  1  0.743  0.460  0.207  1.0
  O  O35  1  0.273  0.412  0.075  1.0
  O  O36  1  0.940  0.319  0.909  1.0
  O  O37  1  0.562  0.321  0.908  1.0
  O  O38  1  0.564  0.315  0.403  1.0
  O  O39  1  0.932  0.303  0.402  1.0
  O  O40  1  0.231  0.165  0.764  1.0
  O  O41  1  0.777  0.097  0.677  1.0
  O  O42  1  0.272  0.167  0.262  1.0
  O  O43  1  0.263  0.100  0.975  1.0
  O  O44  1  0.728  0.091  0.181  1.0
  O  O45  1  0.241  0.098  0.473  1.0
[/CIF]
.