The compound described by Rb3Pd crystallizes in the cubic Im-3 space group. The structure consists of a Rb3Pd framework. Rb(1) is bonded in a distorted single-bond geometry to one Pd(1) and one Pd(2) atom. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a cuboctahedral geometry to twelve equivalent Rb(1) atoms. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to four equivalent Rb(1) atoms. is represented by the CIF card [CIF]
data_Rb3Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.376
_cell_length_b   10.376
_cell_length_c   10.376
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   859.885
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.301  0.116  0.815  1.0
  Rb  Rb1  1  0.699  0.884  0.185  1.0
  Rb  Rb2  1  0.301  0.486  0.185  1.0
  Rb  Rb3  1  0.699  0.514  0.815  1.0
  Rb  Rb4  1  0.815  0.301  0.116  1.0
  Rb  Rb5  1  0.185  0.699  0.884  1.0
  Rb  Rb6  1  0.185  0.301  0.486  1.0
  Rb  Rb7  1  0.815  0.699  0.514  1.0
  Rb  Rb8  1  0.116  0.815  0.301  1.0
  Rb  Rb9  1  0.884  0.185  0.699  1.0
  Rb  Rb10  1  0.486  0.185  0.301  1.0
  Rb  Rb11  1  0.514  0.815  0.699  1.0
  Pd  Pd12  1  0.000  0.000  0.000  1.0
  Pd  Pd13  1  0.500  0.000  0.500  1.0
  Pd  Pd14  1  0.500  0.500  0.000  1.0
  Pd  Pd15  1  0.000  0.500  0.500  1.0
[/CIF]
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The compound described by Rb3Pd crystallizes in the cubic Im-3 space group. The structure consists of a Rb3Pd framework. Rb(1) is bonded in a distorted single-bond geometry to one Pd(1) and one Pd(2) atom. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a cuboctahedral geometry to twelve equivalent Rb(1) atoms. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to four equivalent Rb(1) atoms. is represented by the CIF card [CIF]
data_Rb3Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.376
_cell_length_b   10.376
_cell_length_c   10.376
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   859.885
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.301  0.116  0.815  1.0
  Rb  Rb1  1  0.699  0.884  0.185  1.0
  Rb  Rb2  1  0.301  0.486  0.185  1.0
  Rb  Rb3  1  0.699  0.514  0.815  1.0
  Rb  Rb4  1  0.815  0.301  0.116  1.0
  Rb  Rb5  1  0.185  0.699  0.884  1.0
  Rb  Rb6  1  0.185  0.301  0.486  1.0
  Rb  Rb7  1  0.815  0.699  0.514  1.0
  Rb  Rb8  1  0.116  0.815  0.301  1.0
  Rb  Rb9  1  0.884  0.185  0.699  1.0
  Rb  Rb10  1  0.486  0.185  0.301  1.0
  Rb  Rb11  1  0.514  0.815  0.699  1.0
  Pd  Pd12  1  0.000  0.000  0.000  1.0
  Pd  Pd13  1  0.500  0.000  0.500  1.0
  Pd  Pd14  1  0.500  0.500  0.000  1.0
  Pd  Pd15  1  0.000  0.500  0.500  1.0
[/CIF]
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