The compound described by Cu(NO4)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and two Cu(NO4)2 clusters. In each Cu(NO4)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent O(6) and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one O(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one O(7) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(1) atom. is represented by the CIF file [CIF]
data_CuS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.227
_cell_length_b   6.823
_cell_length_c   8.805
_cell_angle_alpha   88.538
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   674.335
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.500  0.000  0.500  1.0
  Cu  Cu1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.608  0.237  0.057  1.0
  S  S3  1  0.108  0.763  0.443  1.0
  S  S4  1  0.392  0.763  0.943  1.0
  S  S5  1  0.892  0.237  0.557  1.0
  N  N6  1  0.847  0.778  0.184  1.0
  N  N7  1  0.347  0.222  0.316  1.0
  N  N8  1  0.153  0.222  0.816  1.0
  N  N9  1  0.653  0.778  0.684  1.0
  O  O10  1  0.845  0.372  0.074  1.0
  O  O11  1  0.345  0.628  0.426  1.0
  O  O12  1  0.155  0.628  0.926  1.0
  O  O13  1  0.655  0.372  0.574  1.0
  O  O14  1  0.597  0.324  0.908  1.0
  O  O15  1  0.097  0.676  0.592  1.0
  O  O16  1  0.403  0.676  0.092  1.0
  O  O17  1  0.903  0.324  0.408  1.0
  O  O18  1  0.593  0.354  0.189  1.0
  O  O19  1  0.093  0.646  0.311  1.0
  O  O20  1  0.407  0.646  0.811  1.0
  O  O21  1  0.907  0.354  0.689  1.0
  O  O22  1  0.630  0.030  0.076  1.0
  O  O23  1  0.130  0.970  0.424  1.0
  O  O24  1  0.370  0.970  0.924  1.0
  O  O25  1  0.870  0.030  0.576  1.0
  O  O26  1  0.777  0.758  0.288  1.0
  O  O27  1  0.277  0.242  0.212  1.0
  O  O28  1  0.223  0.242  0.712  1.0
  O  O29  1  0.723  0.758  0.788  1.0
  O  O30  1  0.607  0.954  0.659  1.0
  O  O31  1  0.107  0.046  0.841  1.0
  O  O32  1  0.393  0.046  0.341  1.0
  O  O33  1  0.893  0.954  0.159  1.0
  O  O34  1  0.438  0.683  0.487  1.0
  O  O35  1  0.938  0.317  0.013  1.0
  O  O36  1  0.562  0.317  0.513  1.0
  O  O37  1  0.062  0.683  0.987  1.0
[/CIF]
.
The compound described by Cu(NO4)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and two Cu(NO4)2 clusters. In each Cu(NO4)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent O(6) and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one O(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one O(7) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(1) atom. is represented by the CIF file [CIF]
data_CuS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.227
_cell_length_b   6.823
_cell_length_c   8.805
_cell_angle_alpha   88.538
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   674.335
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.500  0.000  0.500  1.0
  Cu  Cu1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.608  0.237  0.057  1.0
  S  S3  1  0.108  0.763  0.443  1.0
  S  S4  1  0.392  0.763  0.943  1.0
  S  S5  1  0.892  0.237  0.557  1.0
  N  N6  1  0.847  0.778  0.184  1.0
  N  N7  1  0.347  0.222  0.316  1.0
  N  N8  1  0.153  0.222  0.816  1.0
  N  N9  1  0.653  0.778  0.684  1.0
  O  O10  1  0.845  0.372  0.074  1.0
  O  O11  1  0.345  0.628  0.426  1.0
  O  O12  1  0.155  0.628  0.926  1.0
  O  O13  1  0.655  0.372  0.574  1.0
  O  O14  1  0.597  0.324  0.908  1.0
  O  O15  1  0.097  0.676  0.592  1.0
  O  O16  1  0.403  0.676  0.092  1.0
  O  O17  1  0.903  0.324  0.408  1.0
  O  O18  1  0.593  0.354  0.189  1.0
  O  O19  1  0.093  0.646  0.311  1.0
  O  O20  1  0.407  0.646  0.811  1.0
  O  O21  1  0.907  0.354  0.689  1.0
  O  O22  1  0.630  0.030  0.076  1.0
  O  O23  1  0.130  0.970  0.424  1.0
  O  O24  1  0.370  0.970  0.924  1.0
  O  O25  1  0.870  0.030  0.576  1.0
  O  O26  1  0.777  0.758  0.288  1.0
  O  O27  1  0.277  0.242  0.212  1.0
  O  O28  1  0.223  0.242  0.712  1.0
  O  O29  1  0.723  0.758  0.788  1.0
  O  O30  1  0.607  0.954  0.659  1.0
  O  O31  1  0.107  0.046  0.841  1.0
  O  O32  1  0.393  0.046  0.341  1.0
  O  O33  1  0.893  0.954  0.159  1.0
  O  O34  1  0.438  0.683  0.487  1.0
  O  O35  1  0.938  0.317  0.013  1.0
  O  O36  1  0.562  0.317  0.513  1.0
  O  O37  1  0.062  0.683  0.987  1.0
[/CIF]
.