The structure described by Nd2N2S4O17 crystallizes in the triclinic P1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(16), one O(2), one O(4), one O(5), and one O(8) atom. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(11), one O(14), one O(15), one O(17), one O(3), one O(6), one O(7), and one O(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one S(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one N(2), one O(4), one O(5), and one O(6) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(10), one O(7), one O(8), and one O(9) atom. In the fourth S site, S(4) is bonded in a tetrahedral geometry to one O(11), one O(12), one O(13), and one O(14) atom. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Nd(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Nd(1) and one S(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Nd(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Nd(1) and one S(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one S(3) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Nd(1) and one S(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(4) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Nd(1) and one S(4) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Nd(1) and one S(4) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(4) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Nd(2) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Nd(1) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Nd(2) atom. is represented by the CIF card [CIF]
data_Nd2S4N2O17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.031
_cell_length_b   7.039
_cell_length_c   9.798
_cell_angle_alpha   99.304
_cell_angle_beta   108.236
_cell_angle_gamma   106.337
_symmetry_Int_Tables_number   1
_cell_volume   425.083
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.905  0.017  0.632  1.0
  Nd  Nd1  1  0.066  0.673  0.134  1.0
  S  S2  1  0.367  0.079  0.505  1.0
  S  S3  1  0.090  0.586  0.749  1.0
  S  S4  1  0.046  0.122  0.979  1.0
  S  S5  1  0.670  0.801  0.275  1.0
  N  N6  1  0.404  0.252  0.414  1.0
  N  N7  1  0.349  0.639  0.825  1.0
  O  O8  1  0.236  0.127  0.587  1.0
  O  O9  1  0.579  0.098  0.607  1.0
  O  O10  1  0.255  0.877  0.393  1.0
  O  O11  1  0.002  0.388  0.637  1.0
  O  O12  1  0.064  0.755  0.684  1.0
  O  O13  1  0.008  0.579  0.871  1.0
  O  O14  1  0.134  0.004  0.078  1.0
  O  O15  1  0.831  0.993  0.863  1.0
  O  O16  1  0.033  0.304  0.078  1.0
  O  O17  1  0.184  0.200  0.897  1.0
  O  O18  1  0.437  0.711  0.191  1.0
  O  O19  1  0.738  0.017  0.364  1.0
  O  O20  1  0.741  0.686  0.392  1.0
  O  O21  1  0.784  0.779  0.174  1.0
  O  O22  1  0.734  0.374  0.991  1.0
  O  O23  1  0.600  0.694  0.571  1.0
  O  O24  1  0.916  0.472  0.296  1.0
[/CIF]
.
The structure described by Nd2N2S4O17 crystallizes in the triclinic P1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(16), one O(2), one O(4), one O(5), and one O(8) atom. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(11), one O(14), one O(15), one O(17), one O(3), one O(6), one O(7), and one O(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one S(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one N(2), one O(4), one O(5), and one O(6) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(10), one O(7), one O(8), and one O(9) atom. In the fourth S site, S(4) is bonded in a tetrahedral geometry to one O(11), one O(12), one O(13), and one O(14) atom. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Nd(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Nd(1) and one S(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Nd(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Nd(1) and one S(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one S(3) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Nd(1) and one S(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(4) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Nd(1) and one S(4) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Nd(1) and one S(4) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(4) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Nd(2) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Nd(1) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Nd(2) atom. is represented by the CIF card [CIF]
data_Nd2S4N2O17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.031
_cell_length_b   7.039
_cell_length_c   9.798
_cell_angle_alpha   99.304
_cell_angle_beta   108.236
_cell_angle_gamma   106.337
_symmetry_Int_Tables_number   1
_cell_volume   425.083
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.905  0.017  0.632  1.0
  Nd  Nd1  1  0.066  0.673  0.134  1.0
  S  S2  1  0.367  0.079  0.505  1.0
  S  S3  1  0.090  0.586  0.749  1.0
  S  S4  1  0.046  0.122  0.979  1.0
  S  S5  1  0.670  0.801  0.275  1.0
  N  N6  1  0.404  0.252  0.414  1.0
  N  N7  1  0.349  0.639  0.825  1.0
  O  O8  1  0.236  0.127  0.587  1.0
  O  O9  1  0.579  0.098  0.607  1.0
  O  O10  1  0.255  0.877  0.393  1.0
  O  O11  1  0.002  0.388  0.637  1.0
  O  O12  1  0.064  0.755  0.684  1.0
  O  O13  1  0.008  0.579  0.871  1.0
  O  O14  1  0.134  0.004  0.078  1.0
  O  O15  1  0.831  0.993  0.863  1.0
  O  O16  1  0.033  0.304  0.078  1.0
  O  O17  1  0.184  0.200  0.897  1.0
  O  O18  1  0.437  0.711  0.191  1.0
  O  O19  1  0.738  0.017  0.364  1.0
  O  O20  1  0.741  0.686  0.392  1.0
  O  O21  1  0.784  0.779  0.174  1.0
  O  O22  1  0.734  0.374  0.991  1.0
  O  O23  1  0.600  0.694  0.571  1.0
  O  O24  1  0.916  0.472  0.296  1.0
[/CIF]
.