The structure described by WFe2C10(SeO5)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WFe2C10(SeO5)2 clusters. W(1) is bonded in a 8-coordinate geometry to one Fe(1), one Fe(2), one C(1), one C(3), one C(6), one C(7), one Se(1), and one Se(2) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 5-coordinate geometry to one W(1), one C(10), one C(4), one C(8), one Se(1), and one Se(2) atom. In the second Fe site, Fe(2) is bonded in a 3-coordinate geometry to one W(1), one C(2), one C(5), one C(9), one Se(1), and one Se(2) atom. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one W(1) and one O(5) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(2) and one O(3) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one W(1) and one O(2) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(1) and one O(6) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Fe(2) and one O(4) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one W(1) and one O(1) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one W(1) and one O(9) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Fe(1) and one O(7) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Fe(2) and one O(8) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Fe(1) and one O(10) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one W(1), one Fe(1), and one Fe(2) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to one W(1), one Fe(1), and one Fe(2) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. is represented by the CIF card [CIF]
data_Fe2WC10(SeO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.168
_cell_length_b   9.629
_cell_length_c   14.182
_cell_angle_alpha   82.612
_cell_angle_beta   82.524
_cell_angle_gamma   86.236
_symmetry_Int_Tables_number   1
_cell_volume   961.331
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.286  0.006  0.273  1.0
  Fe  Fe1  1  0.357  0.326  0.364  1.0
  Fe  Fe2  1  0.714  0.994  0.727  1.0
  Fe  Fe3  1  0.643  0.674  0.636  1.0
  W  W4  1  0.605  0.729  0.832  1.0
  W  W5  1  0.395  0.271  0.168  1.0
  C  C6  1  0.630  0.388  0.137  1.0
  C  C7  1  0.431  0.589  0.626  1.0
  C  C8  1  0.567  0.156  0.075  1.0
  C  C9  1  0.433  0.844  0.925  1.0
  C  C10  1  0.908  0.045  0.783  1.0
  C  C11  1  0.214  0.487  0.365  1.0
  C  C12  1  0.719  0.528  0.861  1.0
  C  C13  1  0.569  0.411  0.374  1.0
  C  C14  1  0.281  0.472  0.139  1.0
  C  C15  1  0.780  0.754  0.932  1.0
  C  C16  1  0.370  0.612  0.863  1.0
  C  C17  1  0.554  0.128  0.774  1.0
  C  C18  1  0.786  0.513  0.635  1.0
  C  C19  1  0.305  0.252  0.484  1.0
  C  C20  1  0.771  0.079  0.609  1.0
  C  C21  1  0.695  0.748  0.516  1.0
  C  C22  1  0.446  0.872  0.226  1.0
  C  C23  1  0.092  0.955  0.217  1.0
  C  C24  1  0.220  0.246  0.068  1.0
  C  C25  1  0.229  0.921  0.391  1.0
  Se  Se26  1  0.110  0.221  0.302  1.0
  Se  Se27  1  0.456  0.873  0.688  1.0
  Se  Se28  1  0.544  0.127  0.312  1.0
  Se  Se29  1  0.890  0.779  0.698  1.0
  O  O30  1  0.221  0.586  0.121  1.0
  O  O31  1  0.664  0.095  0.021  1.0
  O  O32  1  0.295  0.536  0.617  1.0
  O  O33  1  0.877  0.409  0.633  1.0
  O  O34  1  0.237  0.546  0.880  1.0
  O  O35  1  0.123  0.591  0.367  1.0
  O  O36  1  0.034  0.076  0.818  1.0
  O  O37  1  0.545  0.783  0.198  1.0
  O  O38  1  0.966  0.924  0.182  1.0
  O  O39  1  0.728  0.797  0.437  1.0
  O  O40  1  0.336  0.905  0.979  1.0
  O  O41  1  0.879  0.769  0.988  1.0
  O  O42  1  0.272  0.203  0.563  1.0
  O  O43  1  0.194  0.867  0.468  1.0
  O  O44  1  0.455  0.217  0.802  1.0
  O  O45  1  0.806  0.133  0.532  1.0
  O  O46  1  0.121  0.231  0.012  1.0
  O  O47  1  0.763  0.454  0.120  1.0
  O  O48  1  0.705  0.464  0.383  1.0
  O  O49  1  0.779  0.414  0.879  1.0
[/CIF]
.
The structure described by WFe2C10(SeO5)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WFe2C10(SeO5)2 clusters. W(1) is bonded in a 8-coordinate geometry to one Fe(1), one Fe(2), one C(1), one C(3), one C(6), one C(7), one Se(1), and one Se(2) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 5-coordinate geometry to one W(1), one C(10), one C(4), one C(8), one Se(1), and one Se(2) atom. In the second Fe site, Fe(2) is bonded in a 3-coordinate geometry to one W(1), one C(2), one C(5), one C(9), one Se(1), and one Se(2) atom. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one W(1) and one O(5) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(2) and one O(3) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one W(1) and one O(2) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(1) and one O(6) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Fe(2) and one O(4) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one W(1) and one O(1) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one W(1) and one O(9) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Fe(1) and one O(7) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Fe(2) and one O(8) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Fe(1) and one O(10) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one W(1), one Fe(1), and one Fe(2) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to one W(1), one Fe(1), and one Fe(2) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. is represented by the CIF card [CIF]
data_Fe2WC10(SeO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.168
_cell_length_b   9.629
_cell_length_c   14.182
_cell_angle_alpha   82.612
_cell_angle_beta   82.524
_cell_angle_gamma   86.236
_symmetry_Int_Tables_number   1
_cell_volume   961.331
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.286  0.006  0.273  1.0
  Fe  Fe1  1  0.357  0.326  0.364  1.0
  Fe  Fe2  1  0.714  0.994  0.727  1.0
  Fe  Fe3  1  0.643  0.674  0.636  1.0
  W  W4  1  0.605  0.729  0.832  1.0
  W  W5  1  0.395  0.271  0.168  1.0
  C  C6  1  0.630  0.388  0.137  1.0
  C  C7  1  0.431  0.589  0.626  1.0
  C  C8  1  0.567  0.156  0.075  1.0
  C  C9  1  0.433  0.844  0.925  1.0
  C  C10  1  0.908  0.045  0.783  1.0
  C  C11  1  0.214  0.487  0.365  1.0
  C  C12  1  0.719  0.528  0.861  1.0
  C  C13  1  0.569  0.411  0.374  1.0
  C  C14  1  0.281  0.472  0.139  1.0
  C  C15  1  0.780  0.754  0.932  1.0
  C  C16  1  0.370  0.612  0.863  1.0
  C  C17  1  0.554  0.128  0.774  1.0
  C  C18  1  0.786  0.513  0.635  1.0
  C  C19  1  0.305  0.252  0.484  1.0
  C  C20  1  0.771  0.079  0.609  1.0
  C  C21  1  0.695  0.748  0.516  1.0
  C  C22  1  0.446  0.872  0.226  1.0
  C  C23  1  0.092  0.955  0.217  1.0
  C  C24  1  0.220  0.246  0.068  1.0
  C  C25  1  0.229  0.921  0.391  1.0
  Se  Se26  1  0.110  0.221  0.302  1.0
  Se  Se27  1  0.456  0.873  0.688  1.0
  Se  Se28  1  0.544  0.127  0.312  1.0
  Se  Se29  1  0.890  0.779  0.698  1.0
  O  O30  1  0.221  0.586  0.121  1.0
  O  O31  1  0.664  0.095  0.021  1.0
  O  O32  1  0.295  0.536  0.617  1.0
  O  O33  1  0.877  0.409  0.633  1.0
  O  O34  1  0.237  0.546  0.880  1.0
  O  O35  1  0.123  0.591  0.367  1.0
  O  O36  1  0.034  0.076  0.818  1.0
  O  O37  1  0.545  0.783  0.198  1.0
  O  O38  1  0.966  0.924  0.182  1.0
  O  O39  1  0.728  0.797  0.437  1.0
  O  O40  1  0.336  0.905  0.979  1.0
  O  O41  1  0.879  0.769  0.988  1.0
  O  O42  1  0.272  0.203  0.563  1.0
  O  O43  1  0.194  0.867  0.468  1.0
  O  O44  1  0.455  0.217  0.802  1.0
  O  O45  1  0.806  0.133  0.532  1.0
  O  O46  1  0.121  0.231  0.012  1.0
  O  O47  1  0.763  0.454  0.120  1.0
  O  O48  1  0.705  0.464  0.383  1.0
  O  O49  1  0.779  0.414  0.879  1.0
[/CIF]
.