The crystal structure described by KLa(PS3)2 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to one S(1), one S(6), two equivalent S(2), two equivalent S(3), and two equivalent S(5) atoms. La(1) is bonded in a 9-coordinate geometry to one S(2), one S(3), one S(5), two equivalent S(1), two equivalent S(4), and two equivalent S(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one P(2), one S(2), one S(4), and one S(6) atom to form distorted PPS3 tetrahedra that share  a cornercorner with one S(1)KLa2P trigonal pyramid. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one S(1), one S(3), and one S(5) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded to one K(1), two equivalent La(1), and one P(2) atom to form distorted SKLa2P trigonal pyramids that share  a cornercorner with one P(1)PS3 tetrahedra, corners with two equivalent S(2)K2LaP tetrahedra, corners with two equivalent S(1)KLa2P trigonal pyramids, and  an edgeedge with one S(2)K2LaP tetrahedra. In the second S site, S(2) is bonded to two equivalent K(1), one La(1), and one P(1) atom to form distorted SK2LaP tetrahedra that share corners with two equivalent S(2)K2LaP tetrahedra, corners with two equivalent S(1)KLa2P trigonal pyramids, and  an edgeedge with one S(1)KLa2P trigonal pyramid. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one La(1), and one P(2) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to two equivalent La(1) and one P(1) atom. In the fifth S site, S(5) is bonded in a distorted see-saw-like geometry to two equivalent K(1), one La(1), and one P(2) atom. In the sixth S site, S(6) is bonded in a 1-coordinate geometry to one K(1), two equivalent La(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KLa(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.662
_cell_length_b   11.487
_cell_length_c   12.189
_cell_angle_alpha   70.320
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1010.073
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.094  0.375  0.869  1.0
  K  K1  1  0.594  0.125  0.131  1.0
  K  K2  1  0.906  0.625  0.131  1.0
  K  K3  1  0.406  0.875  0.869  1.0
  La  La4  1  0.607  0.597  0.648  1.0
  La  La5  1  0.893  0.097  0.648  1.0
  La  La6  1  0.107  0.903  0.352  1.0
  La  La7  1  0.393  0.403  0.352  1.0
  P  P8  1  0.400  0.254  0.671  1.0
  P  P9  1  0.100  0.754  0.671  1.0
  P  P10  1  0.882  0.767  0.789  1.0
  P  P11  1  0.900  0.246  0.329  1.0
  P  P12  1  0.118  0.233  0.211  1.0
  P  P13  1  0.382  0.733  0.211  1.0
  P  P14  1  0.600  0.746  0.329  1.0
  P  P15  1  0.618  0.267  0.789  1.0
  S  S16  1  0.195  0.638  0.325  1.0
  S  S17  1  0.714  0.355  0.227  1.0
  S  S18  1  0.286  0.645  0.773  1.0
  S  S19  1  0.526  0.367  0.883  1.0
  S  S20  1  0.517  0.184  0.555  1.0
  S  S21  1  0.017  0.316  0.445  1.0
  S  S22  1  0.204  0.408  0.132  1.0
  S  S23  1  0.786  0.855  0.227  1.0
  S  S24  1  0.818  0.069  0.411  1.0
  S  S25  1  0.682  0.569  0.411  1.0
  S  S26  1  0.974  0.867  0.883  1.0
  S  S27  1  0.983  0.684  0.555  1.0
  S  S28  1  0.305  0.138  0.325  1.0
  S  S29  1  0.214  0.145  0.773  1.0
  S  S30  1  0.695  0.862  0.675  1.0
  S  S31  1  0.483  0.816  0.445  1.0
  S  S32  1  0.182  0.931  0.589  1.0
  S  S33  1  0.796  0.592  0.868  1.0
  S  S34  1  0.805  0.362  0.675  1.0
  S  S35  1  0.704  0.092  0.868  1.0
  S  S36  1  0.026  0.133  0.117  1.0
  S  S37  1  0.296  0.908  0.132  1.0
  S  S38  1  0.474  0.633  0.117  1.0
  S  S39  1  0.318  0.431  0.589  1.0
[/CIF]
.
The crystal structure described by KLa(PS3)2 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to one S(1), one S(6), two equivalent S(2), two equivalent S(3), and two equivalent S(5) atoms. La(1) is bonded in a 9-coordinate geometry to one S(2), one S(3), one S(5), two equivalent S(1), two equivalent S(4), and two equivalent S(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one P(2), one S(2), one S(4), and one S(6) atom to form distorted PPS3 tetrahedra that share  a cornercorner with one S(1)KLa2P trigonal pyramid. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one S(1), one S(3), and one S(5) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded to one K(1), two equivalent La(1), and one P(2) atom to form distorted SKLa2P trigonal pyramids that share  a cornercorner with one P(1)PS3 tetrahedra, corners with two equivalent S(2)K2LaP tetrahedra, corners with two equivalent S(1)KLa2P trigonal pyramids, and  an edgeedge with one S(2)K2LaP tetrahedra. In the second S site, S(2) is bonded to two equivalent K(1), one La(1), and one P(1) atom to form distorted SK2LaP tetrahedra that share corners with two equivalent S(2)K2LaP tetrahedra, corners with two equivalent S(1)KLa2P trigonal pyramids, and  an edgeedge with one S(1)KLa2P trigonal pyramid. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one La(1), and one P(2) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to two equivalent La(1) and one P(1) atom. In the fifth S site, S(5) is bonded in a distorted see-saw-like geometry to two equivalent K(1), one La(1), and one P(2) atom. In the sixth S site, S(6) is bonded in a 1-coordinate geometry to one K(1), two equivalent La(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KLa(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.662
_cell_length_b   11.487
_cell_length_c   12.189
_cell_angle_alpha   70.320
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1010.073
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.094  0.375  0.869  1.0
  K  K1  1  0.594  0.125  0.131  1.0
  K  K2  1  0.906  0.625  0.131  1.0
  K  K3  1  0.406  0.875  0.869  1.0
  La  La4  1  0.607  0.597  0.648  1.0
  La  La5  1  0.893  0.097  0.648  1.0
  La  La6  1  0.107  0.903  0.352  1.0
  La  La7  1  0.393  0.403  0.352  1.0
  P  P8  1  0.400  0.254  0.671  1.0
  P  P9  1  0.100  0.754  0.671  1.0
  P  P10  1  0.882  0.767  0.789  1.0
  P  P11  1  0.900  0.246  0.329  1.0
  P  P12  1  0.118  0.233  0.211  1.0
  P  P13  1  0.382  0.733  0.211  1.0
  P  P14  1  0.600  0.746  0.329  1.0
  P  P15  1  0.618  0.267  0.789  1.0
  S  S16  1  0.195  0.638  0.325  1.0
  S  S17  1  0.714  0.355  0.227  1.0
  S  S18  1  0.286  0.645  0.773  1.0
  S  S19  1  0.526  0.367  0.883  1.0
  S  S20  1  0.517  0.184  0.555  1.0
  S  S21  1  0.017  0.316  0.445  1.0
  S  S22  1  0.204  0.408  0.132  1.0
  S  S23  1  0.786  0.855  0.227  1.0
  S  S24  1  0.818  0.069  0.411  1.0
  S  S25  1  0.682  0.569  0.411  1.0
  S  S26  1  0.974  0.867  0.883  1.0
  S  S27  1  0.983  0.684  0.555  1.0
  S  S28  1  0.305  0.138  0.325  1.0
  S  S29  1  0.214  0.145  0.773  1.0
  S  S30  1  0.695  0.862  0.675  1.0
  S  S31  1  0.483  0.816  0.445  1.0
  S  S32  1  0.182  0.931  0.589  1.0
  S  S33  1  0.796  0.592  0.868  1.0
  S  S34  1  0.805  0.362  0.675  1.0
  S  S35  1  0.704  0.092  0.868  1.0
  S  S36  1  0.026  0.133  0.117  1.0
  S  S37  1  0.296  0.908  0.132  1.0
  S  S38  1  0.474  0.633  0.117  1.0
  S  S39  1  0.318  0.431  0.589  1.0
[/CIF]
.