The crystal structure described by Li2SbSO4F3 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(4), and one F(1) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to two equivalent F(2) and two equivalent F(3) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one F(1), one F(2), and one F(3) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(2) and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li2SbSO4F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.134
_cell_length_b   8.740
_cell_length_c   13.018
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   584.126
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.959  0.493  0.721  1.0
  Li  Li1  1  0.004  0.289  0.446  1.0
  Li  Li2  1  0.496  0.711  0.946  1.0
  Li  Li3  1  0.541  0.507  0.221  1.0
  Li  Li4  1  0.459  0.007  0.279  1.0
  Li  Li5  1  0.504  0.211  0.554  1.0
  Li  Li6  1  0.996  0.789  0.054  1.0
  Li  Li7  1  0.041  0.993  0.779  1.0
  Sb  Sb8  1  0.057  0.942  0.526  1.0
  Sb  Sb9  1  0.443  0.058  0.026  1.0
  Sb  Sb10  1  0.557  0.558  0.474  1.0
  Sb  Sb11  1  0.943  0.442  0.974  1.0
  S  S12  1  0.973  0.204  0.178  1.0
  S  S13  1  0.527  0.796  0.678  1.0
  S  S14  1  0.473  0.296  0.822  1.0
  S  S15  1  0.027  0.704  0.322  1.0
  O  O16  1  0.024  0.119  0.076  1.0
  O  O17  1  0.156  0.853  0.354  1.0
  O  O18  1  0.207  0.613  0.259  1.0
  O  O19  1  0.225  0.230  0.229  1.0
  O  O20  1  0.275  0.770  0.729  1.0
  O  O21  1  0.293  0.387  0.759  1.0
  O  O22  1  0.344  0.147  0.854  1.0
  O  O23  1  0.476  0.881  0.576  1.0
  O  O24  1  0.524  0.381  0.924  1.0
  O  O25  1  0.656  0.647  0.646  1.0
  O  O26  1  0.707  0.887  0.741  1.0
  O  O27  1  0.725  0.270  0.771  1.0
  O  O28  1  0.775  0.730  0.271  1.0
  O  O29  1  0.793  0.113  0.241  1.0
  O  O30  1  0.844  0.353  0.146  1.0
  O  O31  1  0.976  0.619  0.424  1.0
  F  F32  1  0.110  0.087  0.646  1.0
  F  F33  1  0.208  0.611  0.020  1.0
  F  F34  1  0.275  0.102  0.455  1.0
  F  F35  1  0.225  0.898  0.955  1.0
  F  F36  1  0.292  0.389  0.520  1.0
  F  F37  1  0.390  0.913  0.146  1.0
  F  F38  1  0.610  0.413  0.354  1.0
  F  F39  1  0.708  0.889  0.980  1.0
  F  F40  1  0.775  0.398  0.545  1.0
  F  F41  1  0.725  0.602  0.045  1.0
  F  F42  1  0.792  0.111  0.480  1.0
  F  F43  1  0.890  0.587  0.854  1.0
[/CIF]
.
The crystal structure described by Li2SbSO4F3 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(4), and one F(1) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to two equivalent F(2) and two equivalent F(3) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one F(1), one F(2), and one F(3) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(2) and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li2SbSO4F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.134
_cell_length_b   8.740
_cell_length_c   13.018
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   584.126
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.959  0.493  0.721  1.0
  Li  Li1  1  0.004  0.289  0.446  1.0
  Li  Li2  1  0.496  0.711  0.946  1.0
  Li  Li3  1  0.541  0.507  0.221  1.0
  Li  Li4  1  0.459  0.007  0.279  1.0
  Li  Li5  1  0.504  0.211  0.554  1.0
  Li  Li6  1  0.996  0.789  0.054  1.0
  Li  Li7  1  0.041  0.993  0.779  1.0
  Sb  Sb8  1  0.057  0.942  0.526  1.0
  Sb  Sb9  1  0.443  0.058  0.026  1.0
  Sb  Sb10  1  0.557  0.558  0.474  1.0
  Sb  Sb11  1  0.943  0.442  0.974  1.0
  S  S12  1  0.973  0.204  0.178  1.0
  S  S13  1  0.527  0.796  0.678  1.0
  S  S14  1  0.473  0.296  0.822  1.0
  S  S15  1  0.027  0.704  0.322  1.0
  O  O16  1  0.024  0.119  0.076  1.0
  O  O17  1  0.156  0.853  0.354  1.0
  O  O18  1  0.207  0.613  0.259  1.0
  O  O19  1  0.225  0.230  0.229  1.0
  O  O20  1  0.275  0.770  0.729  1.0
  O  O21  1  0.293  0.387  0.759  1.0
  O  O22  1  0.344  0.147  0.854  1.0
  O  O23  1  0.476  0.881  0.576  1.0
  O  O24  1  0.524  0.381  0.924  1.0
  O  O25  1  0.656  0.647  0.646  1.0
  O  O26  1  0.707  0.887  0.741  1.0
  O  O27  1  0.725  0.270  0.771  1.0
  O  O28  1  0.775  0.730  0.271  1.0
  O  O29  1  0.793  0.113  0.241  1.0
  O  O30  1  0.844  0.353  0.146  1.0
  O  O31  1  0.976  0.619  0.424  1.0
  F  F32  1  0.110  0.087  0.646  1.0
  F  F33  1  0.208  0.611  0.020  1.0
  F  F34  1  0.275  0.102  0.455  1.0
  F  F35  1  0.225  0.898  0.955  1.0
  F  F36  1  0.292  0.389  0.520  1.0
  F  F37  1  0.390  0.913  0.146  1.0
  F  F38  1  0.610  0.413  0.354  1.0
  F  F39  1  0.708  0.889  0.980  1.0
  F  F40  1  0.775  0.398  0.545  1.0
  F  F41  1  0.725  0.602  0.045  1.0
  F  F42  1  0.792  0.111  0.480  1.0
  F  F43  1  0.890  0.587  0.854  1.0
[/CIF]
.