The crystal structure described by Ba3Sr5Co3Cu5O24 is (Cubic) Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(17), one O(19), one O(2), one O(21), one O(23), one O(3), and one O(4) atom to form BaO12 cuboctahedra that share corners with four equivalent Ba(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(18), one O(2), one O(20), one O(22), one O(24), one O(3), and one O(4) atom to form BaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the third Ba site, Ba(3) is bonded to one O(11), one O(12), one O(15), one O(16), one O(18), one O(20), one O(22), one O(24), one O(5), one O(6), one O(7), and one O(8) atom to form BaO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(13), one O(14), one O(17), one O(19), one O(2), one O(21), one O(23), one O(3), one O(4), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(18), one O(2), one O(20), one O(22), one O(24), one O(3), one O(4), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent Ba(3)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(10), one O(13), one O(14), one O(17), one O(19), one O(21), one O(23), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent Ba(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(10), one O(13), one O(14), one O(18), one O(20), one O(22), one O(24), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(2)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the fifth Sr site, Sr(5) is bonded to one O(11), one O(12), one O(15), one O(16), one O(17), one O(19), one O(21), one O(23), one O(5), one O(6), one O(7), and one O(8) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(2)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(12), one O(19), one O(20), one O(4), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Co site, Co(2) is bonded to one O(14), one O(16), one O(2), one O(21), one O(22), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Cu(4)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third Co site, Co(3) is bonded to one O(14), one O(16), one O(23), one O(24), one O(4), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Cu(5)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are five inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(11), one O(17), one O(18), one O(5), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, corners with two equivalent Cu(4)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the second Cu site, Cu(2) is bonded to one O(10), one O(12), one O(17), one O(18), one O(2), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the third Cu site, Cu(3) is bonded to one O(11), one O(19), one O(20), one O(3), one O(7), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(5)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fourth Cu site, Cu(4) is bonded to one O(1), one O(13), one O(15), one O(21), one O(22), and one O(5) atom to form CuO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(5)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fifth Cu site, Cu(5) is bonded to one O(13), one O(15), one O(23), one O(24), one O(3), and one O(7) atom to form CuO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, corners with two equivalent Cu(4)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Ba(1), one Ba(2), one Sr(1), one Sr(2), one Cu(1), and one Cu(4) atom to form distorted OBa2Sr2Cu2 octahedra that share corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with four equivalent O(4)Ba2Sr2Co2 octahedra, edges with two equivalent O(2)Ba2Sr2CoCu octahedra, edges with two equivalent O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra,  a faceface with one O(17)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the second O site, O(2) is bonded to one Ba(1), one Ba(2), one Sr(1), one Sr(2), one Co(2), and one Cu(2) atom to form distorted OBa2Sr2CoCu octahedra that share corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(3)Ba2Sr2Cu2 octahedra, edges with two equivalent O(4)Ba2Sr2Co2 octahedra, edges with two equivalent O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra, and  a faceface with one O(17)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-65°. In the third O site, O(3) is bonded to one Ba(1), one Ba(2), one Sr(1), one Sr(2), one Cu(3), and one Cu(5) atom to form distorted OBa2Sr2Cu2 octahedra that share corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with four equivalent O(2)Ba2Sr2CoCu octahedra, edges with two equivalent O(4)Ba2Sr2Co2 octahedra, edges with two equivalent O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the fourth O site, O(4) is bonded to one Ba(1), one Ba(2), one Sr(1), one Sr(2), one Co(1), and one Co(3) atom to form distorted OBa2Sr2Co2 octahedra that share corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(1)Ba2Sr2Cu2 octahedra, edges with two equivalent O(2)Ba2Sr2CoCu octahedra, edges with two equivalent O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra, and  a faceface with one O(12)Ba3SrCoCu octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(5) is bonded to one Ba(3), one Sr(3), one Sr(4), one Sr(5), one Cu(1), and one Cu(4) atom to form distorted OBaSr3Cu2 octahedra that share corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, edges with two equivalent O(6)BaSr3CoCu octahedra, edges with two equivalent O(7)BaSr3Cu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra,  a faceface with one O(17)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 5-62°. In the sixth O site, O(6) is bonded to one Ba(3), one Sr(3), one Sr(4), one Sr(5), one Co(2), and one Cu(2) atom to form distorted OBaSr3CoCu octahedra that share corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(7)BaSr3Cu2 octahedra, edges with two equivalent O(5)BaSr3Cu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra, and  a faceface with one O(17)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-65°. In the seventh O site, O(7) is bonded to one Ba(3), one Sr(3), one Sr(4), one Sr(5), one Cu(3), and one Cu(5) atom to form distorted OBaSr3Cu2 octahedra that share corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with four equivalent O(6)BaSr3CoCu octahedra, edges with two equivalent O(5)BaSr3Cu2 octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Ba(3), one Sr(3), one Sr(4), one Sr(5), one Co(1), and one Co(3) atom. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Cu(1), and one Cu(3) atom to form distorted OSr4Cu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(17)BaSr3Cu2 octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(7)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Co(1), and one Cu(2) atom. In the eleventh O site, O(11) is bonded to one Ba(1), one Ba(2), one Ba(3), one Sr(5), one Cu(1), and one Cu(3) atom to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(16)Ba3SrCo2 octahedra, edges with two equivalent O(12)Ba3SrCoCu octahedra, edges with two equivalent O(15)Ba3SrCu2 octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(17)BaSr3Cu2 octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(7)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the twelfth O site, O(12) is bonded to one Ba(1), one Ba(2), one Ba(3), one Sr(5), one Co(1), and one Cu(2) atom to form distorted OBa3SrCoCu octahedra that share corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with four equivalent O(15)Ba3SrCu2 octahedra, edges with two equivalent O(16)Ba3SrCo2 octahedra, edges with two equivalent O(11)Ba3SrCu2 octahedra,  a faceface with one O(4)Ba2Sr2Co2 octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(6)BaSr3CoCu octahedra, and  a faceface with one O(17)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-64°. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Cu(4), and one Cu(5) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Co(2), and one Co(3) atom. In the fifteenth O site, O(15) is bonded to one Ba(1), one Ba(2), one Ba(3), one Sr(5), one Cu(4), and one Cu(5) atom to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with four equivalent O(12)Ba3SrCoCu octahedra, edges with two equivalent O(16)Ba3SrCo2 octahedra, edges with two equivalent O(11)Ba3SrCu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(7)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the sixteenth O site, O(16) is bonded to one Ba(1), one Ba(2), one Ba(3), one Sr(5), one Co(2), and one Co(3) atom to form distorted OBa3SrCo2 octahedra that share corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with four equivalent O(11)Ba3SrCu2 octahedra, edges with two equivalent O(12)Ba3SrCoCu octahedra, edges with two equivalent O(15)Ba3SrCu2 octahedra,  a faceface with one O(4)Ba2Sr2Co2 octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra, and  a faceface with one O(6)BaSr3CoCu octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the seventeenth O site, O(17) is bonded to one Ba(1), one Sr(1), one Sr(3), one Sr(5), one Cu(1), and one Cu(2) atom to form distorted OBaSr3Cu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(6)BaSr3CoCu octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 5-62°. In the eighteenth O site, O(18) is bonded to one Ba(2), one Ba(3), one Sr(2), one Sr(4), one Cu(1), and one Cu(2) atom to form distorted OBa2Sr2Cu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with four equivalent O(24)Ba2Sr2CoCu octahedra, edges with two equivalent O(20)Ba2Sr2CoCu octahedra, edges with two equivalent O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(6)BaSr3CoCu octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 3-62°. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one Ba(1), one Sr(1), one Sr(3), one Sr(5), one Co(1), and one Cu(3) atom. In the twentieth O site, O(20) is bonded to one Ba(2), one Ba(3), one Sr(2), one Sr(4), one Co(1), and one Cu(3) atom to form distorted OBa2Sr2CoCu octahedra that share corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with four equivalent O(22)Ba2Sr2CoCu octahedra, edges with two equivalent O(24)Ba2Sr2CoCu octahedra, edges with two equivalent O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(4)Ba2Sr2Co2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(7)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Ba(1), one Sr(1), one Sr(3), one Sr(5), one Co(2), and one Cu(4) atom. In the twenty-second O site, O(22) is bonded to one Ba(2), one Ba(3), one Sr(2), one Sr(4), one Co(2), and one Cu(4) atom to form distorted OBa2Sr2CoCu octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(20)Ba2Sr2CoCu octahedra, edges with two equivalent O(24)Ba2Sr2CoCu octahedra, edges with two equivalent O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra,  a faceface with one O(6)BaSr3CoCu octahedra, and  a faceface with one O(5)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the twenty-third O site, O(23) is bonded in a distorted linear geometry to one Ba(1), one Sr(1), one Sr(3), one Sr(5), one Co(3), and one Cu(5) atom. In the twenty-fourth O site, O(24) is bonded to one Ba(2), one Ba(3), one Sr(2), one Sr(4), one Co(3), and one Cu(5) atom to form distorted OBa2Sr2CoCu octahedra that share corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(18)Ba2Sr2Cu2 octahedra, edges with two equivalent O(20)Ba2Sr2CoCu octahedra, edges with two equivalent O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(4)Ba2Sr2Co2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra, and  a faceface with one O(7)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 3-65°. is represented by the CIF file [CIF]
data_Ba3Sr5Co3Cu5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.853
_cell_length_b   7.890
_cell_length_c   7.899
_cell_angle_alpha   89.911
_cell_angle_beta   89.857
_cell_angle_gamma   89.978
_symmetry_Int_Tables_number   1
_cell_volume   489.449
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.248  0.249  0.751  1.0
  Ba  Ba1  1  0.752  0.249  0.751  1.0
  Ba  Ba2  1  0.752  0.751  0.752  1.0
  Sr  Sr3  1  0.247  0.248  0.248  1.0
  Sr  Sr4  1  0.753  0.248  0.248  1.0
  Sr  Sr5  1  0.247  0.752  0.248  1.0
  Sr  Sr6  1  0.753  0.752  0.248  1.0
  Sr  Sr7  1  0.248  0.751  0.752  1.0
  Co  Co8  1  0.499  1.000  0.496  1.0
  Co  Co9  1  0.499  0.502  0.002  1.0
  Co  Co10  1  0.499  0.501  0.496  1.0
  Cu  Cu11  1  0.000  1.000  0.001  1.0
  Cu  Cu12  1  0.499  0.000  0.000  1.0
  Cu  Cu13  1  0.000  0.999  0.499  1.0
  Cu  Cu14  1  0.000  0.500  0.002  1.0
  Cu  Cu15  1  0.000  0.500  0.499  1.0
  O  O16  1  0.001  0.250  0.014  1.0
  O  O17  1  0.499  0.259  0.009  1.0
  O  O18  1  0.001  0.251  0.486  1.0
  O  O19  1  0.499  0.248  0.489  1.0
  O  O20  1  0.006  0.750  0.009  1.0
  O  O21  1  0.496  0.742  0.007  1.0
  O  O22  1  0.006  0.749  0.491  1.0
  O  O23  1  0.497  0.752  0.493  1.0
  O  O24  1  0.001  0.999  0.251  1.0
  O  O25  1  0.498  0.998  0.250  1.0
  O  O26  1  0.007  0.993  0.749  1.0
  O  O27  1  0.496  0.994  0.747  1.0
  O  O28  1  0.001  0.501  0.252  1.0
  O  O29  1  0.498  0.502  0.247  1.0
  O  O30  1  0.007  0.507  0.749  1.0
  O  O31  1  0.496  0.504  0.754  1.0
  O  O32  1  0.251  0.994  0.008  1.0
  O  O33  1  0.748  0.999  0.014  1.0
  O  O34  1  0.257  0.996  0.492  1.0
  O  O35  1  0.742  0.999  0.491  1.0
  O  O36  1  0.251  0.504  0.007  1.0
  O  O37  1  0.749  0.500  0.013  1.0
  O  O38  1  0.263  0.505  0.495  1.0
  O  O39  1  0.736  0.501  0.490  1.0
[/CIF]
.
The crystal structure described by Ba3Sr5Co3Cu5O24 is (Cubic) Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(17), one O(19), one O(2), one O(21), one O(23), one O(3), and one O(4) atom to form BaO12 cuboctahedra that share corners with four equivalent Ba(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(18), one O(2), one O(20), one O(22), one O(24), one O(3), and one O(4) atom to form BaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the third Ba site, Ba(3) is bonded to one O(11), one O(12), one O(15), one O(16), one O(18), one O(20), one O(22), one O(24), one O(5), one O(6), one O(7), and one O(8) atom to form BaO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(13), one O(14), one O(17), one O(19), one O(2), one O(21), one O(23), one O(3), one O(4), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(18), one O(2), one O(20), one O(22), one O(24), one O(3), one O(4), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent Ba(3)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ba(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(10), one O(13), one O(14), one O(17), one O(19), one O(21), one O(23), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent Ba(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(10), one O(13), one O(14), one O(18), one O(20), one O(22), one O(24), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(2)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. In the fifth Sr site, Sr(5) is bonded to one O(11), one O(12), one O(15), one O(16), one O(17), one O(19), one O(21), one O(23), one O(5), one O(6), one O(7), and one O(8) atom to form SrO12 cuboctahedra that share corners with four equivalent Ba(2)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Ba(3)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra,  a faceface with one Cu(2)O6 octahedra,  a faceface with one Cu(3)O6 octahedra,  a faceface with one Cu(4)O6 octahedra, and  a faceface with one Cu(5)O6 octahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(12), one O(19), one O(20), one O(4), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Co site, Co(2) is bonded to one O(14), one O(16), one O(2), one O(21), one O(22), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Cu(4)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third Co site, Co(3) is bonded to one O(14), one O(16), one O(23), one O(24), one O(4), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Cu(5)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are five inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(11), one O(17), one O(18), one O(5), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, corners with two equivalent Cu(4)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the second Cu site, Cu(2) is bonded to one O(10), one O(12), one O(17), one O(18), one O(2), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the third Cu site, Cu(3) is bonded to one O(11), one O(19), one O(20), one O(3), one O(7), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(5)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fourth Cu site, Cu(4) is bonded to one O(1), one O(13), one O(15), one O(21), one O(22), and one O(5) atom to form CuO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(5)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fifth Cu site, Cu(5) is bonded to one O(13), one O(15), one O(23), one O(24), one O(3), and one O(7) atom to form CuO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, corners with two equivalent Cu(4)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, and  a faceface with one Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-6°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Ba(1), one Ba(2), one Sr(1), one Sr(2), one Cu(1), and one Cu(4) atom to form distorted OBa2Sr2Cu2 octahedra that share corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with four equivalent O(4)Ba2Sr2Co2 octahedra, edges with two equivalent O(2)Ba2Sr2CoCu octahedra, edges with two equivalent O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra,  a faceface with one O(17)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the second O site, O(2) is bonded to one Ba(1), one Ba(2), one Sr(1), one Sr(2), one Co(2), and one Cu(2) atom to form distorted OBa2Sr2CoCu octahedra that share corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(3)Ba2Sr2Cu2 octahedra, edges with two equivalent O(4)Ba2Sr2Co2 octahedra, edges with two equivalent O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra, and  a faceface with one O(17)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-65°. In the third O site, O(3) is bonded to one Ba(1), one Ba(2), one Sr(1), one Sr(2), one Cu(3), and one Cu(5) atom to form distorted OBa2Sr2Cu2 octahedra that share corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with four equivalent O(2)Ba2Sr2CoCu octahedra, edges with two equivalent O(4)Ba2Sr2Co2 octahedra, edges with two equivalent O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the fourth O site, O(4) is bonded to one Ba(1), one Ba(2), one Sr(1), one Sr(2), one Co(1), and one Co(3) atom to form distorted OBa2Sr2Co2 octahedra that share corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(1)Ba2Sr2Cu2 octahedra, edges with two equivalent O(2)Ba2Sr2CoCu octahedra, edges with two equivalent O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra, and  a faceface with one O(12)Ba3SrCoCu octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(5) is bonded to one Ba(3), one Sr(3), one Sr(4), one Sr(5), one Cu(1), and one Cu(4) atom to form distorted OBaSr3Cu2 octahedra that share corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, edges with two equivalent O(6)BaSr3CoCu octahedra, edges with two equivalent O(7)BaSr3Cu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra,  a faceface with one O(17)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 5-62°. In the sixth O site, O(6) is bonded to one Ba(3), one Sr(3), one Sr(4), one Sr(5), one Co(2), and one Cu(2) atom to form distorted OBaSr3CoCu octahedra that share corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(7)BaSr3Cu2 octahedra, edges with two equivalent O(5)BaSr3Cu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra, and  a faceface with one O(17)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-65°. In the seventh O site, O(7) is bonded to one Ba(3), one Sr(3), one Sr(4), one Sr(5), one Cu(3), and one Cu(5) atom to form distorted OBaSr3Cu2 octahedra that share corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with four equivalent O(6)BaSr3CoCu octahedra, edges with two equivalent O(5)BaSr3Cu2 octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Ba(3), one Sr(3), one Sr(4), one Sr(5), one Co(1), and one Co(3) atom. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Cu(1), and one Cu(3) atom to form distorted OSr4Cu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(17)BaSr3Cu2 octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(7)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Co(1), and one Cu(2) atom. In the eleventh O site, O(11) is bonded to one Ba(1), one Ba(2), one Ba(3), one Sr(5), one Cu(1), and one Cu(3) atom to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(16)Ba3SrCo2 octahedra, edges with two equivalent O(12)Ba3SrCoCu octahedra, edges with two equivalent O(15)Ba3SrCu2 octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(17)BaSr3Cu2 octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(7)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the twelfth O site, O(12) is bonded to one Ba(1), one Ba(2), one Ba(3), one Sr(5), one Co(1), and one Cu(2) atom to form distorted OBa3SrCoCu octahedra that share corners with two equivalent O(22)Ba2Sr2CoCu octahedra, corners with two equivalent O(24)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with four equivalent O(15)Ba3SrCu2 octahedra, edges with two equivalent O(16)Ba3SrCo2 octahedra, edges with two equivalent O(11)Ba3SrCu2 octahedra,  a faceface with one O(4)Ba2Sr2Co2 octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(20)Ba2Sr2CoCu octahedra,  a faceface with one O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(6)BaSr3CoCu octahedra, and  a faceface with one O(17)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-64°. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Cu(4), and one Cu(5) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Co(2), and one Co(3) atom. In the fifteenth O site, O(15) is bonded to one Ba(1), one Ba(2), one Ba(3), one Sr(5), one Cu(4), and one Cu(5) atom to form distorted OBa3SrCu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with four equivalent O(12)Ba3SrCoCu octahedra, edges with two equivalent O(16)Ba3SrCo2 octahedra, edges with two equivalent O(11)Ba3SrCu2 octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(7)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the sixteenth O site, O(16) is bonded to one Ba(1), one Ba(2), one Ba(3), one Sr(5), one Co(2), and one Co(3) atom to form distorted OBa3SrCo2 octahedra that share corners with two equivalent O(20)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with four equivalent O(11)Ba3SrCu2 octahedra, edges with two equivalent O(12)Ba3SrCoCu octahedra, edges with two equivalent O(15)Ba3SrCu2 octahedra,  a faceface with one O(4)Ba2Sr2Co2 octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(24)Ba2Sr2CoCu octahedra, and  a faceface with one O(6)BaSr3CoCu octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the seventeenth O site, O(17) is bonded to one Ba(1), one Sr(1), one Sr(3), one Sr(5), one Cu(1), and one Cu(2) atom to form distorted OBaSr3Cu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(18)Ba2Sr2Cu2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(6)BaSr3CoCu octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 5-62°. In the eighteenth O site, O(18) is bonded to one Ba(2), one Ba(3), one Sr(2), one Sr(4), one Cu(1), and one Cu(2) atom to form distorted OBa2Sr2Cu2 octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(17)BaSr3Cu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with four equivalent O(24)Ba2Sr2CoCu octahedra, edges with two equivalent O(20)Ba2Sr2CoCu octahedra, edges with two equivalent O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(6)BaSr3CoCu octahedra,  a faceface with one O(5)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 3-62°. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one Ba(1), one Sr(1), one Sr(3), one Sr(5), one Co(1), and one Cu(3) atom. In the twentieth O site, O(20) is bonded to one Ba(2), one Ba(3), one Sr(2), one Sr(4), one Co(1), and one Cu(3) atom to form distorted OBa2Sr2CoCu octahedra that share corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(16)Ba3SrCo2 octahedra, corners with two equivalent O(15)Ba3SrCu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with four equivalent O(22)Ba2Sr2CoCu octahedra, edges with two equivalent O(24)Ba2Sr2CoCu octahedra, edges with two equivalent O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(4)Ba2Sr2Co2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(12)Ba3SrCoCu octahedra,  a faceface with one O(11)Ba3SrCu2 octahedra,  a faceface with one O(7)BaSr3Cu2 octahedra, and  a faceface with one O(9)Sr4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Ba(1), one Sr(1), one Sr(3), one Sr(5), one Co(2), and one Cu(4) atom. In the twenty-second O site, O(22) is bonded to one Ba(2), one Ba(3), one Sr(2), one Sr(4), one Co(2), and one Cu(4) atom to form distorted OBa2Sr2CoCu octahedra that share corners with two equivalent O(4)Ba2Sr2Co2 octahedra, corners with two equivalent O(3)Ba2Sr2Cu2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(7)BaSr3Cu2 octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(20)Ba2Sr2CoCu octahedra, edges with two equivalent O(24)Ba2Sr2CoCu octahedra, edges with two equivalent O(18)Ba2Sr2Cu2 octahedra,  a faceface with one O(2)Ba2Sr2CoCu octahedra,  a faceface with one O(1)Ba2Sr2Cu2 octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra,  a faceface with one O(6)BaSr3CoCu octahedra, and  a faceface with one O(5)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the twenty-third O site, O(23) is bonded in a distorted linear geometry to one Ba(1), one Sr(1), one Sr(3), one Sr(5), one Co(3), and one Cu(5) atom. In the twenty-fourth O site, O(24) is bonded to one Ba(2), one Ba(3), one Sr(2), one Sr(4), one Co(3), and one Cu(5) atom to form distorted OBa2Sr2CoCu octahedra that share corners with two equivalent O(2)Ba2Sr2CoCu octahedra, corners with two equivalent O(1)Ba2Sr2Cu2 octahedra, corners with two equivalent O(12)Ba3SrCoCu octahedra, corners with two equivalent O(11)Ba3SrCu2 octahedra, corners with two equivalent O(6)BaSr3CoCu octahedra, corners with two equivalent O(5)BaSr3Cu2 octahedra, corners with two equivalent O(9)Sr4Cu2 octahedra, corners with four equivalent O(18)Ba2Sr2Cu2 octahedra, edges with two equivalent O(20)Ba2Sr2CoCu octahedra, edges with two equivalent O(22)Ba2Sr2CoCu octahedra,  a faceface with one O(4)Ba2Sr2Co2 octahedra,  a faceface with one O(3)Ba2Sr2Cu2 octahedra,  a faceface with one O(16)Ba3SrCo2 octahedra,  a faceface with one O(15)Ba3SrCu2 octahedra, and  a faceface with one O(7)BaSr3Cu2 octahedra. The corner-sharing octahedral tilt angles range from 3-65°. is represented by the CIF file [CIF]
data_Ba3Sr5Co3Cu5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.853
_cell_length_b   7.890
_cell_length_c   7.899
_cell_angle_alpha   89.911
_cell_angle_beta   89.857
_cell_angle_gamma   89.978
_symmetry_Int_Tables_number   1
_cell_volume   489.449
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.248  0.249  0.751  1.0
  Ba  Ba1  1  0.752  0.249  0.751  1.0
  Ba  Ba2  1  0.752  0.751  0.752  1.0
  Sr  Sr3  1  0.247  0.248  0.248  1.0
  Sr  Sr4  1  0.753  0.248  0.248  1.0
  Sr  Sr5  1  0.247  0.752  0.248  1.0
  Sr  Sr6  1  0.753  0.752  0.248  1.0
  Sr  Sr7  1  0.248  0.751  0.752  1.0
  Co  Co8  1  0.499  1.000  0.496  1.0
  Co  Co9  1  0.499  0.502  0.002  1.0
  Co  Co10  1  0.499  0.501  0.496  1.0
  Cu  Cu11  1  0.000  1.000  0.001  1.0
  Cu  Cu12  1  0.499  0.000  0.000  1.0
  Cu  Cu13  1  0.000  0.999  0.499  1.0
  Cu  Cu14  1  0.000  0.500  0.002  1.0
  Cu  Cu15  1  0.000  0.500  0.499  1.0
  O  O16  1  0.001  0.250  0.014  1.0
  O  O17  1  0.499  0.259  0.009  1.0
  O  O18  1  0.001  0.251  0.486  1.0
  O  O19  1  0.499  0.248  0.489  1.0
  O  O20  1  0.006  0.750  0.009  1.0
  O  O21  1  0.496  0.742  0.007  1.0
  O  O22  1  0.006  0.749  0.491  1.0
  O  O23  1  0.497  0.752  0.493  1.0
  O  O24  1  0.001  0.999  0.251  1.0
  O  O25  1  0.498  0.998  0.250  1.0
  O  O26  1  0.007  0.993  0.749  1.0
  O  O27  1  0.496  0.994  0.747  1.0
  O  O28  1  0.001  0.501  0.252  1.0
  O  O29  1  0.498  0.502  0.247  1.0
  O  O30  1  0.007  0.507  0.749  1.0
  O  O31  1  0.496  0.504  0.754  1.0
  O  O32  1  0.251  0.994  0.008  1.0
  O  O33  1  0.748  0.999  0.014  1.0
  O  O34  1  0.257  0.996  0.492  1.0
  O  O35  1  0.742  0.999  0.491  1.0
  O  O36  1  0.251  0.504  0.007  1.0
  O  O37  1  0.749  0.500  0.013  1.0
  O  O38  1  0.263  0.505  0.495  1.0
  O  O39  1  0.736  0.501  0.490  1.0
[/CIF]
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