The crystal structure described by SO2Cl2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfuryl chloride molecules. S(1) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_S(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.510
_cell_length_b   5.904
_cell_length_c   8.208
_cell_angle_alpha   80.990
_cell_angle_beta   70.389
_cell_angle_gamma   62.187
_symmetry_Int_Tables_number   1
_cell_volume   222.490
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.249  0.500  0.500  1.0
  S  S1  1  0.999  0.000  0.000  1.0
  Cl  Cl2  1  0.396  0.762  0.405  1.0
  Cl  Cl3  1  0.052  0.262  0.095  1.0
  Cl  Cl4  1  0.409  0.738  0.905  1.0
  Cl  Cl5  1  0.564  0.238  0.595  1.0
  O  O6  1  0.998  0.612  0.641  1.0
  O  O7  1  0.889  0.112  0.859  1.0
  O  O8  1  0.251  0.388  0.359  1.0
  O  O9  1  0.860  0.888  0.141  1.0
[/CIF]
.
The crystal structure described by SO2Cl2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfuryl chloride molecules. S(1) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_S(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.510
_cell_length_b   5.904
_cell_length_c   8.208
_cell_angle_alpha   80.990
_cell_angle_beta   70.389
_cell_angle_gamma   62.187
_symmetry_Int_Tables_number   1
_cell_volume   222.490
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.249  0.500  0.500  1.0
  S  S1  1  0.999  0.000  0.000  1.0
  Cl  Cl2  1  0.396  0.762  0.405  1.0
  Cl  Cl3  1  0.052  0.262  0.095  1.0
  Cl  Cl4  1  0.409  0.738  0.905  1.0
  Cl  Cl5  1  0.564  0.238  0.595  1.0
  O  O6  1  0.998  0.612  0.641  1.0
  O  O7  1  0.889  0.112  0.859  1.0
  O  O8  1  0.251  0.388  0.359  1.0
  O  O9  1  0.860  0.888  0.141  1.0
[/CIF]
.