The structure described by CsSO2F crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 11-coordinate geometry to one S(1), six equivalent O(1), and four equivalent F(1) atoms. S(1) is bonded in a trigonal non-coplanar geometry to one Cs(1), two equivalent O(1), and one F(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one S(1) atom. is represented by the CIF file [CIF]
data_CsSO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.781
_cell_length_b   8.151
_cell_length_c   8.236
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   455.247
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.884  0.645  1.0
  Cs  Cs1  1  0.250  0.116  0.355  1.0
  Cs  Cs2  1  0.750  0.616  0.145  1.0
  Cs  Cs3  1  0.250  0.384  0.855  1.0
  S  S4  1  0.750  0.137  0.066  1.0
  S  S5  1  0.250  0.863  0.934  1.0
  S  S6  1  0.750  0.363  0.566  1.0
  S  S7  1  0.250  0.637  0.434  1.0
  O  O8  1  0.069  0.766  0.904  1.0
  O  O9  1  0.569  0.234  0.096  1.0
  O  O10  1  0.931  0.266  0.596  1.0
  O  O11  1  0.431  0.734  0.404  1.0
  O  O12  1  0.431  0.766  0.904  1.0
  O  O13  1  0.931  0.234  0.096  1.0
  O  O14  1  0.069  0.734  0.404  1.0
  O  O15  1  0.569  0.266  0.596  1.0
  F  F16  1  0.250  0.509  0.255  1.0
  F  F17  1  0.750  0.491  0.745  1.0
  F  F18  1  0.750  0.009  0.245  1.0
  F  F19  1  0.250  0.991  0.755  1.0
[/CIF]
.
The structure described by CsSO2F crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 11-coordinate geometry to one S(1), six equivalent O(1), and four equivalent F(1) atoms. S(1) is bonded in a trigonal non-coplanar geometry to one Cs(1), two equivalent O(1), and one F(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one S(1) atom. is represented by the CIF file [CIF]
data_CsSO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.781
_cell_length_b   8.151
_cell_length_c   8.236
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   455.247
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.884  0.645  1.0
  Cs  Cs1  1  0.250  0.116  0.355  1.0
  Cs  Cs2  1  0.750  0.616  0.145  1.0
  Cs  Cs3  1  0.250  0.384  0.855  1.0
  S  S4  1  0.750  0.137  0.066  1.0
  S  S5  1  0.250  0.863  0.934  1.0
  S  S6  1  0.750  0.363  0.566  1.0
  S  S7  1  0.250  0.637  0.434  1.0
  O  O8  1  0.069  0.766  0.904  1.0
  O  O9  1  0.569  0.234  0.096  1.0
  O  O10  1  0.931  0.266  0.596  1.0
  O  O11  1  0.431  0.734  0.404  1.0
  O  O12  1  0.431  0.766  0.904  1.0
  O  O13  1  0.931  0.234  0.096  1.0
  O  O14  1  0.069  0.734  0.404  1.0
  O  O15  1  0.569  0.266  0.596  1.0
  F  F16  1  0.250  0.509  0.255  1.0
  F  F17  1  0.750  0.491  0.745  1.0
  F  F18  1  0.750  0.009  0.245  1.0
  F  F19  1  0.250  0.991  0.755  1.0
[/CIF]
.