The crystal structure described by ZnZn(WF4)2 crystallizes in the triclinic P1 space group. The structure consists of one 7440-66-6 atom inside a Zn(WF4)2 framework. In the Zn(WF4)2 framework, there are two inequivalent W sites. In the first W site, W(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(5) atom. In the second W site, W(2) is bonded in a square co-planar geometry to one F(4), one F(6), one F(7), and one F(8) atom. Zn(2) is bonded in a 8-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), one F(6), one F(7), and one F(8) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one W(2) and one Zn(2) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to one W(2) and one Zn(2) atom. In the seventh F site, F(7) is bonded in a distorted single-bond geometry to one W(2) and one Zn(2) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to one W(2) and one Zn(2) atom. is represented by the CIF card [CIF]
data_ZnWF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.888
_cell_length_b   5.904
_cell_length_c   6.887
_cell_angle_alpha   115.579
_cell_angle_beta   115.252
_cell_angle_gamma   89.961
_symmetry_Int_Tables_number   1
_cell_volume   190.292
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.243  0.500  1.0
  Zn  Zn1  1  0.749  0.745  0.503  1.0
  W  W2  1  0.000  0.497  0.000  1.0
  W  W3  1  0.501  0.998  1.000  1.0
  F  F4  1  0.948  0.452  0.255  1.0
  F  F5  1  0.700  0.190  0.739  1.0
  F  F6  1  0.049  0.546  0.745  1.0
  F  F7  1  0.195  0.042  0.742  1.0
  F  F8  1  0.305  0.800  0.259  1.0
  F  F9  1  0.456  0.303  0.259  1.0
  F  F10  1  0.804  0.950  0.254  1.0
  F  F11  1  0.548  0.697  0.740  1.0
[/CIF]
.
The crystal structure described by ZnZn(WF4)2 crystallizes in the triclinic P1 space group. The structure consists of one 7440-66-6 atom inside a Zn(WF4)2 framework. In the Zn(WF4)2 framework, there are two inequivalent W sites. In the first W site, W(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(5) atom. In the second W site, W(2) is bonded in a square co-planar geometry to one F(4), one F(6), one F(7), and one F(8) atom. Zn(2) is bonded in a 8-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), one F(6), one F(7), and one F(8) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one W(2) and one Zn(2) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to one W(2) and one Zn(2) atom. In the seventh F site, F(7) is bonded in a distorted single-bond geometry to one W(2) and one Zn(2) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to one W(2) and one Zn(2) atom. is represented by the CIF card [CIF]
data_ZnWF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.888
_cell_length_b   5.904
_cell_length_c   6.887
_cell_angle_alpha   115.579
_cell_angle_beta   115.252
_cell_angle_gamma   89.961
_symmetry_Int_Tables_number   1
_cell_volume   190.292
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.243  0.500  1.0
  Zn  Zn1  1  0.749  0.745  0.503  1.0
  W  W2  1  0.000  0.497  0.000  1.0
  W  W3  1  0.501  0.998  1.000  1.0
  F  F4  1  0.948  0.452  0.255  1.0
  F  F5  1  0.700  0.190  0.739  1.0
  F  F6  1  0.049  0.546  0.745  1.0
  F  F7  1  0.195  0.042  0.742  1.0
  F  F8  1  0.305  0.800  0.259  1.0
  F  F9  1  0.456  0.303  0.259  1.0
  F  F10  1  0.804  0.950  0.254  1.0
  F  F11  1  0.548  0.697  0.740  1.0
[/CIF]
.