The compound described by SiH14(OF)6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SiH14(OF)6 clusters. Si(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(1) and one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(2) atom. In the seventh H site, H(7) is bonded in a distorted single-bond geometry to one O(1) and one F(2) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a 2-coordinate geometry to one H(3), one H(4), and one H(6) atom. In the second O site, O(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(5) atom. In the third O site, O(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(4), and one H(7) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Si(1) and one H(7) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Si(1) atom. is represented by the CIF card [CIF]
data_SiH14(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.509
_cell_length_b   5.905
_cell_length_c   13.838
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.907
_symmetry_Int_Tables_number   1
_cell_volume   425.914
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Si  Si0  1  0.000  0.000  0.000  1.0
  Si  Si1  1  0.000  0.500  0.500  1.0
  H  H2  1  0.880  0.001  0.284  1.0
  H  H3  1  0.120  0.999  0.716  1.0
  H  H4  1  0.120  0.499  0.784  1.0
  H  H5  1  0.880  0.501  0.216  1.0
  H  H6  1  0.449  0.569  0.843  1.0
  H  H7  1  0.551  0.431  0.157  1.0
  H  H8  1  0.551  0.931  0.343  1.0
  H  H9  1  0.449  0.069  0.657  1.0
  H  H10  1  0.725  0.990  0.552  1.0
  H  H11  1  0.275  0.010  0.448  1.0
  H  H12  1  0.275  0.510  0.052  1.0
  H  H13  1  0.725  0.490  0.948  1.0
  H  H14  1  0.802  0.872  0.685  1.0
  H  H15  1  0.198  0.128  0.315  1.0
  H  H16  1  0.198  0.628  0.185  1.0
  H  H17  1  0.802  0.372  0.815  1.0
  H  H18  1  0.325  0.776  0.853  1.0
  H  H19  1  0.675  0.224  0.147  1.0
  H  H20  1  0.675  0.724  0.353  1.0
  H  H21  1  0.325  0.276  0.647  1.0
  H  H22  1  0.500  0.752  0.585  1.0
  H  H23  1  0.500  0.248  0.415  1.0
  H  H24  1  0.500  0.748  0.085  1.0
  H  H25  1  0.500  0.252  0.915  1.0
  H  H26  1  0.878  0.911  0.800  1.0
  H  H27  1  0.122  0.089  0.200  1.0
  H  H28  1  0.122  0.589  0.300  1.0
  H  H29  1  0.878  0.411  0.700  1.0
  O  O30  1  0.933  0.868  0.736  1.0
  O  O31  1  0.067  0.132  0.264  1.0
  O  O32  1  0.067  0.632  0.236  1.0
  O  O33  1  0.933  0.368  0.764  1.0
  O  O34  1  0.618  0.906  0.606  1.0
  O  O35  1  0.382  0.094  0.394  1.0
  O  O36  1  0.382  0.594  0.106  1.0
  O  O37  1  0.618  0.406  0.894  1.0
  O  O38  1  0.346  0.654  0.809  1.0
  O  O39  1  0.654  0.346  0.191  1.0
  O  O40  1  0.654  0.846  0.309  1.0
  O  O41  1  0.346  0.154  0.691  1.0
  F  F42  1  0.240  0.988  0.923  1.0
  F  F43  1  0.760  0.012  0.077  1.0
  F  F44  1  0.760  0.512  0.423  1.0
  F  F45  1  0.240  0.488  0.577  1.0
  F  F46  1  0.790  0.946  0.907  1.0
  F  F47  1  0.210  0.054  0.093  1.0
  F  F48  1  0.210  0.554  0.407  1.0
  F  F49  1  0.790  0.446  0.593  1.0
  F  F50  1  0.920  0.203  0.479  1.0
  F  F51  1  0.080  0.797  0.521  1.0
  F  F52  1  0.080  0.297  0.979  1.0
  F  F53  1  0.920  0.703  0.021  1.0
[/CIF]
.
The compound described by SiH14(OF)6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SiH14(OF)6 clusters. Si(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(1) and one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(2) atom. In the seventh H site, H(7) is bonded in a distorted single-bond geometry to one O(1) and one F(2) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a 2-coordinate geometry to one H(3), one H(4), and one H(6) atom. In the second O site, O(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(5) atom. In the third O site, O(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(4), and one H(7) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Si(1) and one H(7) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Si(1) atom. is represented by the CIF card [CIF]
data_SiH14(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.509
_cell_length_b   5.905
_cell_length_c   13.838
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.907
_symmetry_Int_Tables_number   1
_cell_volume   425.914
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Si  Si0  1  0.000  0.000  0.000  1.0
  Si  Si1  1  0.000  0.500  0.500  1.0
  H  H2  1  0.880  0.001  0.284  1.0
  H  H3  1  0.120  0.999  0.716  1.0
  H  H4  1  0.120  0.499  0.784  1.0
  H  H5  1  0.880  0.501  0.216  1.0
  H  H6  1  0.449  0.569  0.843  1.0
  H  H7  1  0.551  0.431  0.157  1.0
  H  H8  1  0.551  0.931  0.343  1.0
  H  H9  1  0.449  0.069  0.657  1.0
  H  H10  1  0.725  0.990  0.552  1.0
  H  H11  1  0.275  0.010  0.448  1.0
  H  H12  1  0.275  0.510  0.052  1.0
  H  H13  1  0.725  0.490  0.948  1.0
  H  H14  1  0.802  0.872  0.685  1.0
  H  H15  1  0.198  0.128  0.315  1.0
  H  H16  1  0.198  0.628  0.185  1.0
  H  H17  1  0.802  0.372  0.815  1.0
  H  H18  1  0.325  0.776  0.853  1.0
  H  H19  1  0.675  0.224  0.147  1.0
  H  H20  1  0.675  0.724  0.353  1.0
  H  H21  1  0.325  0.276  0.647  1.0
  H  H22  1  0.500  0.752  0.585  1.0
  H  H23  1  0.500  0.248  0.415  1.0
  H  H24  1  0.500  0.748  0.085  1.0
  H  H25  1  0.500  0.252  0.915  1.0
  H  H26  1  0.878  0.911  0.800  1.0
  H  H27  1  0.122  0.089  0.200  1.0
  H  H28  1  0.122  0.589  0.300  1.0
  H  H29  1  0.878  0.411  0.700  1.0
  O  O30  1  0.933  0.868  0.736  1.0
  O  O31  1  0.067  0.132  0.264  1.0
  O  O32  1  0.067  0.632  0.236  1.0
  O  O33  1  0.933  0.368  0.764  1.0
  O  O34  1  0.618  0.906  0.606  1.0
  O  O35  1  0.382  0.094  0.394  1.0
  O  O36  1  0.382  0.594  0.106  1.0
  O  O37  1  0.618  0.406  0.894  1.0
  O  O38  1  0.346  0.654  0.809  1.0
  O  O39  1  0.654  0.346  0.191  1.0
  O  O40  1  0.654  0.846  0.309  1.0
  O  O41  1  0.346  0.154  0.691  1.0
  F  F42  1  0.240  0.988  0.923  1.0
  F  F43  1  0.760  0.012  0.077  1.0
  F  F44  1  0.760  0.512  0.423  1.0
  F  F45  1  0.240  0.488  0.577  1.0
  F  F46  1  0.790  0.946  0.907  1.0
  F  F47  1  0.210  0.054  0.093  1.0
  F  F48  1  0.210  0.554  0.407  1.0
  F  F49  1  0.790  0.446  0.593  1.0
  F  F50  1  0.920  0.203  0.479  1.0
  F  F51  1  0.080  0.797  0.521  1.0
  F  F52  1  0.080  0.297  0.979  1.0
  F  F53  1  0.920  0.703  0.021  1.0
[/CIF]
.