The compound described by AgSbS2 crystallizes in the monoclinic C2/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. In the second Ag site, Ag(2) is bonded in a tetrahedral geometry to two equivalent S(1) and two equivalent S(2) atoms. Sb(1) is bonded in a distorted T-shaped geometry to one S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(1) atom. In the second S site, S(2) is bonded in a distorted rectangular see-saw-like geometry to one Ag(1), one Ag(2), and two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_AgSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.621
_cell_length_b   6.802
_cell_length_c   13.247
_cell_angle_alpha   97.949
_cell_angle_beta   90.000
_cell_angle_gamma   109.858
_symmetry_Int_Tables_number   1
_cell_volume   387.340
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.000  0.000  1.0
  Ag  Ag1  1  0.006  0.000  0.750  1.0
  Ag  Ag2  1  0.500  0.000  0.500  1.0
  Ag  Ag3  1  0.994  0.000  0.250  1.0
  Sb  Sb4  1  0.280  0.509  0.627  1.0
  Sb  Sb5  1  0.771  0.491  0.873  1.0
  Sb  Sb6  1  0.720  0.491  0.373  1.0
  Sb  Sb7  1  0.229  0.509  0.127  1.0
  S  S8  1  0.301  0.217  0.914  1.0
  S  S9  1  0.083  0.783  0.586  1.0
  S  S10  1  0.699  0.783  0.086  1.0
  S  S11  1  0.917  0.217  0.414  1.0
  S  S12  1  0.492  0.288  0.199  1.0
  S  S13  1  0.796  0.288  0.699  1.0
  S  S14  1  0.508  0.712  0.801  1.0
  S  S15  1  0.204  0.712  0.301  1.0
[/CIF]
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The compound described by AgSbS2 crystallizes in the monoclinic C2/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. In the second Ag site, Ag(2) is bonded in a tetrahedral geometry to two equivalent S(1) and two equivalent S(2) atoms. Sb(1) is bonded in a distorted T-shaped geometry to one S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(1) atom. In the second S site, S(2) is bonded in a distorted rectangular see-saw-like geometry to one Ag(1), one Ag(2), and two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_AgSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.621
_cell_length_b   6.802
_cell_length_c   13.247
_cell_angle_alpha   97.949
_cell_angle_beta   90.000
_cell_angle_gamma   109.858
_symmetry_Int_Tables_number   1
_cell_volume   387.340
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.000  0.000  1.0
  Ag  Ag1  1  0.006  0.000  0.750  1.0
  Ag  Ag2  1  0.500  0.000  0.500  1.0
  Ag  Ag3  1  0.994  0.000  0.250  1.0
  Sb  Sb4  1  0.280  0.509  0.627  1.0
  Sb  Sb5  1  0.771  0.491  0.873  1.0
  Sb  Sb6  1  0.720  0.491  0.373  1.0
  Sb  Sb7  1  0.229  0.509  0.127  1.0
  S  S8  1  0.301  0.217  0.914  1.0
  S  S9  1  0.083  0.783  0.586  1.0
  S  S10  1  0.699  0.783  0.086  1.0
  S  S11  1  0.917  0.217  0.414  1.0
  S  S12  1  0.492  0.288  0.199  1.0
  S  S13  1  0.796  0.288  0.699  1.0
  S  S14  1  0.508  0.712  0.801  1.0
  S  S15  1  0.204  0.712  0.301  1.0
[/CIF]
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