The crystal structure described by CoC8(SF3)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoC8(SF3)4 cluster. Co(1) is bonded to one S(1), one S(2), one S(4), and two equivalent S(3) atoms to form distorted edge-sharing CoS5 trigonal bipyramids. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one S(2) atom. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(1), one F(1), one F(2), and one F(3) atom. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(2), one F(4), one F(5), and one F(6) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(6), one C(7), and one S(3) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(8), and one S(4) atom. In the seventh C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(5), one F(7), one F(8), and one F(9) atom. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(6), one F(10), one F(11), and one F(12) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Co(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Co(1) and one C(2) atom. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Co(1) and one C(5) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one Co(1) and one C(6) atom. There are twelve inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one C(8) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one C(8) atom. is represented by the CIF file [CIF]
data_CoC8(SF3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.134
_cell_length_b   10.057
_cell_length_c   10.318
_cell_angle_alpha   103.951
_cell_angle_beta   98.790
_cell_angle_gamma   100.511
_symmetry_Int_Tables_number   1
_cell_volume   788.064
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.369  0.402  0.527  1.0
  Co  Co1  1  0.631  0.598  0.473  1.0
  C  C2  1  0.084  0.139  0.367  1.0
  C  C3  1  0.916  0.861  0.633  1.0
  C  C4  1  0.234  0.094  0.350  1.0
  C  C5  1  0.766  0.906  0.650  1.0
  C  C6  1  0.902  0.051  0.303  1.0
  C  C7  1  0.098  0.949  0.697  1.0
  C  C8  1  0.241  0.946  0.269  1.0
  C  C9  1  0.759  0.054  0.731  1.0
  C  C10  1  0.634  0.571  0.794  1.0
  C  C11  1  0.366  0.429  0.206  1.0
  C  C12  1  0.483  0.613  0.816  1.0
  C  C13  1  0.517  0.387  0.184  1.0
  C  C14  1  0.805  0.619  0.895  1.0
  C  C15  1  0.195  0.381  0.105  1.0
  C  C16  1  0.468  0.720  0.945  1.0
  C  C17  1  0.532  0.280  0.055  1.0
  S  S18  1  0.099  0.304  0.465  1.0
  S  S19  1  0.901  0.696  0.535  1.0
  S  S20  1  0.425  0.206  0.425  1.0
  S  S21  1  0.575  0.794  0.575  1.0
  S  S22  1  0.632  0.463  0.637  1.0
  S  S23  1  0.368  0.537  0.363  1.0
  S  S24  1  0.304  0.553  0.692  1.0
  S  S25  1  0.696  0.447  0.308  1.0
  F  F26  1  0.870  0.025  0.165  1.0
  F  F27  1  0.130  0.975  0.835  1.0
  F  F28  1  0.876  0.924  0.331  1.0
  F  F29  1  0.124  0.076  0.669  1.0
  F  F30  1  0.783  0.117  0.350  1.0
  F  F31  1  0.217  0.883  0.650  1.0
  F  F32  1  0.151  0.913  0.139  1.0
  F  F33  1  0.849  0.087  0.861  1.0
  F  F34  1  0.175  0.845  0.327  1.0
  F  F35  1  0.825  0.155  0.673  1.0
  F  F36  1  0.404  0.935  0.262  1.0
  F  F37  1  0.596  0.065  0.738  1.0
  F  F38  1  0.921  0.548  0.847  1.0
  F  F39  1  0.079  0.452  0.153  1.0
  F  F40  1  0.796  0.598  0.019  1.0
  F  F41  1  0.204  0.402  0.981  1.0
  F  F42  1  0.873  0.759  0.915  1.0
  F  F43  1  0.127  0.241  0.085  1.0
  F  F44  1  0.516  0.681  0.060  1.0
  F  F45  1  0.484  0.319  0.940  1.0
  F  F46  1  0.569  0.849  0.959  1.0
  F  F47  1  0.431  0.151  0.041  1.0
  F  F48  1  0.306  0.735  0.941  1.0
  F  F49  1  0.694  0.265  0.059  1.0
[/CIF]
.
The crystal structure described by CoC8(SF3)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoC8(SF3)4 cluster. Co(1) is bonded to one S(1), one S(2), one S(4), and two equivalent S(3) atoms to form distorted edge-sharing CoS5 trigonal bipyramids. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one S(2) atom. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(1), one F(1), one F(2), and one F(3) atom. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(2), one F(4), one F(5), and one F(6) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(6), one C(7), and one S(3) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(8), and one S(4) atom. In the seventh C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(5), one F(7), one F(8), and one F(9) atom. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(6), one F(10), one F(11), and one F(12) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Co(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Co(1) and one C(2) atom. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Co(1) and one C(5) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one Co(1) and one C(6) atom. There are twelve inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one C(8) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one C(8) atom. is represented by the CIF file [CIF]
data_CoC8(SF3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.134
_cell_length_b   10.057
_cell_length_c   10.318
_cell_angle_alpha   103.951
_cell_angle_beta   98.790
_cell_angle_gamma   100.511
_symmetry_Int_Tables_number   1
_cell_volume   788.064
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.369  0.402  0.527  1.0
  Co  Co1  1  0.631  0.598  0.473  1.0
  C  C2  1  0.084  0.139  0.367  1.0
  C  C3  1  0.916  0.861  0.633  1.0
  C  C4  1  0.234  0.094  0.350  1.0
  C  C5  1  0.766  0.906  0.650  1.0
  C  C6  1  0.902  0.051  0.303  1.0
  C  C7  1  0.098  0.949  0.697  1.0
  C  C8  1  0.241  0.946  0.269  1.0
  C  C9  1  0.759  0.054  0.731  1.0
  C  C10  1  0.634  0.571  0.794  1.0
  C  C11  1  0.366  0.429  0.206  1.0
  C  C12  1  0.483  0.613  0.816  1.0
  C  C13  1  0.517  0.387  0.184  1.0
  C  C14  1  0.805  0.619  0.895  1.0
  C  C15  1  0.195  0.381  0.105  1.0
  C  C16  1  0.468  0.720  0.945  1.0
  C  C17  1  0.532  0.280  0.055  1.0
  S  S18  1  0.099  0.304  0.465  1.0
  S  S19  1  0.901  0.696  0.535  1.0
  S  S20  1  0.425  0.206  0.425  1.0
  S  S21  1  0.575  0.794  0.575  1.0
  S  S22  1  0.632  0.463  0.637  1.0
  S  S23  1  0.368  0.537  0.363  1.0
  S  S24  1  0.304  0.553  0.692  1.0
  S  S25  1  0.696  0.447  0.308  1.0
  F  F26  1  0.870  0.025  0.165  1.0
  F  F27  1  0.130  0.975  0.835  1.0
  F  F28  1  0.876  0.924  0.331  1.0
  F  F29  1  0.124  0.076  0.669  1.0
  F  F30  1  0.783  0.117  0.350  1.0
  F  F31  1  0.217  0.883  0.650  1.0
  F  F32  1  0.151  0.913  0.139  1.0
  F  F33  1  0.849  0.087  0.861  1.0
  F  F34  1  0.175  0.845  0.327  1.0
  F  F35  1  0.825  0.155  0.673  1.0
  F  F36  1  0.404  0.935  0.262  1.0
  F  F37  1  0.596  0.065  0.738  1.0
  F  F38  1  0.921  0.548  0.847  1.0
  F  F39  1  0.079  0.452  0.153  1.0
  F  F40  1  0.796  0.598  0.019  1.0
  F  F41  1  0.204  0.402  0.981  1.0
  F  F42  1  0.873  0.759  0.915  1.0
  F  F43  1  0.127  0.241  0.085  1.0
  F  F44  1  0.516  0.681  0.060  1.0
  F  F45  1  0.484  0.319  0.940  1.0
  F  F46  1  0.569  0.849  0.959  1.0
  F  F47  1  0.431  0.151  0.041  1.0
  F  F48  1  0.306  0.735  0.941  1.0
  F  F49  1  0.694  0.265  0.059  1.0
[/CIF]
.