The structure described by LiCoH8(SO6)2 crystallizes in the monoclinic Pc space group. Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(5), one O(7), and one O(9) atom. Co(1) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one S(1)O4 tetrahedra and  a cornercorner with one S(2)O4 tetrahedra. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(4) and one O(5) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(5) and one O(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) and one O(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(10) atom. In the sixth H site, H(6) is bonded in a distorted linear geometry to one O(7) and one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(4), and one O(7) atom to form SO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 41°. In the second S site, S(2) is bonded to one O(11), one O(12), one O(6), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Co(1), one H(1), and one H(4) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one H(2) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Li(1), one Co(1), one H(2), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one S(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one H(6), and one S(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(6), and one H(7) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Li(1) and one S(2) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Li(1), one Co(1), one H(5), and one H(8) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one S(2) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Co(1) and one S(2) atom. is represented by the CIF card [CIF]
data_LiCoH8(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.117
_cell_length_b   5.501
_cell_length_c   10.962
_cell_angle_alpha   78.158
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   479.010
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.306  0.116  0.629  1.0
  Li  Li1  1  0.694  0.116  0.129  1.0
  Co  Co2  1  0.244  0.998  0.000  1.0
  Co  Co3  1  0.756  0.998  0.500  1.0
  H  H4  1  0.965  0.227  0.980  1.0
  H  H5  1  0.385  0.775  0.844  1.0
  H  H6  1  0.186  0.779  0.818  1.0
  H  H7  1  0.056  0.334  0.856  1.0
  H  H8  1  0.557  0.677  0.644  1.0
  H  H9  1  0.690  0.213  0.686  1.0
  H  H10  1  0.888  0.225  0.656  1.0
  H  H11  1  0.467  0.772  0.516  1.0
  H  H12  1  0.035  0.227  0.480  1.0
  H  H13  1  0.615  0.775  0.344  1.0
  H  H14  1  0.814  0.779  0.318  1.0
  H  H15  1  0.944  0.334  0.356  1.0
  H  H16  1  0.443  0.677  0.144  1.0
  H  H17  1  0.310  0.213  0.186  1.0
  H  H18  1  0.112  0.225  0.156  1.0
  H  H19  1  0.533  0.772  0.016  1.0
  S  S20  1  0.534  0.366  0.868  1.0
  S  S21  1  0.047  0.635  0.636  1.0
  S  S22  1  0.466  0.366  0.368  1.0
  S  S23  1  0.953  0.635  0.136  1.0
  O  O24  1  0.368  0.296  0.929  1.0
  O  O25  1  0.664  0.211  0.936  1.0
  O  O26  1  0.042  0.178  0.920  1.0
  O  O27  1  0.557  0.633  0.869  1.0
  O  O28  1  0.282  0.883  0.835  1.0
  O  O29  1  0.025  0.634  0.771  1.0
  O  O30  1  0.522  0.335  0.735  1.0
  O  O31  1  0.786  0.127  0.656  1.0
  O  O32  1  0.081  0.374  0.623  1.0
  O  O33  1  0.538  0.828  0.579  1.0
  O  O34  1  0.174  0.811  0.581  1.0
  O  O35  1  0.881  0.702  0.571  1.0
  O  O36  1  0.632  0.296  0.429  1.0
  O  O37  1  0.336  0.211  0.436  1.0
  O  O38  1  0.958  0.178  0.420  1.0
  O  O39  1  0.443  0.633  0.369  1.0
  O  O40  1  0.718  0.883  0.335  1.0
  O  O41  1  0.975  0.634  0.271  1.0
  O  O42  1  0.478  0.335  0.235  1.0
  O  O43  1  0.214  0.127  0.156  1.0
  O  O44  1  0.919  0.374  0.123  1.0
  O  O45  1  0.462  0.828  0.079  1.0
  O  O46  1  0.826  0.811  0.081  1.0
  O  O47  1  0.119  0.702  0.071  1.0
[/CIF]
.
The structure described by LiCoH8(SO6)2 crystallizes in the monoclinic Pc space group. Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(5), one O(7), and one O(9) atom. Co(1) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one S(1)O4 tetrahedra and  a cornercorner with one S(2)O4 tetrahedra. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(4) and one O(5) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(5) and one O(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) and one O(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(10) atom. In the sixth H site, H(6) is bonded in a distorted linear geometry to one O(7) and one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(4), and one O(7) atom to form SO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 41°. In the second S site, S(2) is bonded to one O(11), one O(12), one O(6), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Co(1), one H(1), and one H(4) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one H(2) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Li(1), one Co(1), one H(2), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one S(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one H(6), and one S(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(6), and one H(7) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Li(1) and one S(2) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Li(1), one Co(1), one H(5), and one H(8) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one S(2) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Co(1) and one S(2) atom. is represented by the CIF card [CIF]
data_LiCoH8(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.117
_cell_length_b   5.501
_cell_length_c   10.962
_cell_angle_alpha   78.158
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   479.010
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.306  0.116  0.629  1.0
  Li  Li1  1  0.694  0.116  0.129  1.0
  Co  Co2  1  0.244  0.998  0.000  1.0
  Co  Co3  1  0.756  0.998  0.500  1.0
  H  H4  1  0.965  0.227  0.980  1.0
  H  H5  1  0.385  0.775  0.844  1.0
  H  H6  1  0.186  0.779  0.818  1.0
  H  H7  1  0.056  0.334  0.856  1.0
  H  H8  1  0.557  0.677  0.644  1.0
  H  H9  1  0.690  0.213  0.686  1.0
  H  H10  1  0.888  0.225  0.656  1.0
  H  H11  1  0.467  0.772  0.516  1.0
  H  H12  1  0.035  0.227  0.480  1.0
  H  H13  1  0.615  0.775  0.344  1.0
  H  H14  1  0.814  0.779  0.318  1.0
  H  H15  1  0.944  0.334  0.356  1.0
  H  H16  1  0.443  0.677  0.144  1.0
  H  H17  1  0.310  0.213  0.186  1.0
  H  H18  1  0.112  0.225  0.156  1.0
  H  H19  1  0.533  0.772  0.016  1.0
  S  S20  1  0.534  0.366  0.868  1.0
  S  S21  1  0.047  0.635  0.636  1.0
  S  S22  1  0.466  0.366  0.368  1.0
  S  S23  1  0.953  0.635  0.136  1.0
  O  O24  1  0.368  0.296  0.929  1.0
  O  O25  1  0.664  0.211  0.936  1.0
  O  O26  1  0.042  0.178  0.920  1.0
  O  O27  1  0.557  0.633  0.869  1.0
  O  O28  1  0.282  0.883  0.835  1.0
  O  O29  1  0.025  0.634  0.771  1.0
  O  O30  1  0.522  0.335  0.735  1.0
  O  O31  1  0.786  0.127  0.656  1.0
  O  O32  1  0.081  0.374  0.623  1.0
  O  O33  1  0.538  0.828  0.579  1.0
  O  O34  1  0.174  0.811  0.581  1.0
  O  O35  1  0.881  0.702  0.571  1.0
  O  O36  1  0.632  0.296  0.429  1.0
  O  O37  1  0.336  0.211  0.436  1.0
  O  O38  1  0.958  0.178  0.420  1.0
  O  O39  1  0.443  0.633  0.369  1.0
  O  O40  1  0.718  0.883  0.335  1.0
  O  O41  1  0.975  0.634  0.271  1.0
  O  O42  1  0.478  0.335  0.235  1.0
  O  O43  1  0.214  0.127  0.156  1.0
  O  O44  1  0.919  0.374  0.123  1.0
  O  O45  1  0.462  0.828  0.079  1.0
  O  O46  1  0.826  0.811  0.081  1.0
  O  O47  1  0.119  0.702  0.071  1.0
[/CIF]
.