The material described by RbIn3O5 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 7-coordinate geometry to one O(3), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(3), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of distorted edge and corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 7-54°. In the second In site, In(2) is bonded to one O(4), two equivalent O(2), and three equivalent O(1) atoms to form a mixture of edge and corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles are 7°. In the third In site, In(3) is bonded to one O(2), one O(5), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of distorted edge and corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 7-54°. There are five inequivalent O sites. In the first O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Rb(1), one In(3), and two equivalent In(1) atoms. In the second O site, O(1) is bonded to one In(1), two equivalent In(3), and three equivalent In(2) atoms to form edge-sharing OIn6 octahedra. In the third O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Rb(1), one In(3), and two equivalent In(2) atoms. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one In(1), and two equivalent In(3) atoms. In the fifth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Rb(1), one In(2), and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_RbIn3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.320
_cell_length_b   9.858
_cell_length_c   16.751
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   548.239
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.470  0.372  1.0
  Rb  Rb1  1  0.250  0.530  0.628  1.0
  Rb  Rb2  1  0.250  0.030  0.872  1.0
  Rb  Rb3  1  0.750  0.970  0.128  1.0
  In  In4  1  0.750  0.818  0.316  1.0
  In  In5  1  0.250  0.182  0.684  1.0
  In  In6  1  0.250  0.682  0.816  1.0
  In  In7  1  0.750  0.318  0.184  1.0
  In  In8  1  0.750  0.652  0.986  1.0
  In  In9  1  0.250  0.348  0.014  1.0
  In  In10  1  0.250  0.848  0.486  1.0
  In  In11  1  0.750  0.152  0.514  1.0
  In  In12  1  0.750  0.886  0.658  1.0
  In  In13  1  0.250  0.114  0.342  1.0
  In  In14  1  0.250  0.614  0.158  1.0
  In  In15  1  0.750  0.386  0.842  1.0
  O  O16  1  0.750  0.979  0.424  1.0
  O  O17  1  0.250  0.021  0.576  1.0
  O  O18  1  0.250  0.521  0.924  1.0
  O  O19  1  0.750  0.479  0.076  1.0
  O  O20  1  0.750  0.767  0.552  1.0
  O  O21  1  0.250  0.233  0.448  1.0
  O  O22  1  0.250  0.733  0.052  1.0
  O  O23  1  0.750  0.267  0.948  1.0
  O  O24  1  0.750  0.706  0.210  1.0
  O  O25  1  0.250  0.294  0.790  1.0
  O  O26  1  0.250  0.794  0.710  1.0
  O  O27  1  0.750  0.206  0.290  1.0
  O  O28  1  0.750  0.776  0.883  1.0
  O  O29  1  0.250  0.224  0.117  1.0
  O  O30  1  0.250  0.724  0.383  1.0
  O  O31  1  0.750  0.276  0.617  1.0
  O  O32  1  0.750  0.561  0.772  1.0
  O  O33  1  0.250  0.439  0.228  1.0
  O  O34  1  0.250  0.939  0.272  1.0
  O  O35  1  0.750  0.061  0.728  1.0
[/CIF]
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The material described by RbIn3O5 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 7-coordinate geometry to one O(3), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(3), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of distorted edge and corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 7-54°. In the second In site, In(2) is bonded to one O(4), two equivalent O(2), and three equivalent O(1) atoms to form a mixture of edge and corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles are 7°. In the third In site, In(3) is bonded to one O(2), one O(5), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of distorted edge and corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 7-54°. There are five inequivalent O sites. In the first O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Rb(1), one In(3), and two equivalent In(1) atoms. In the second O site, O(1) is bonded to one In(1), two equivalent In(3), and three equivalent In(2) atoms to form edge-sharing OIn6 octahedra. In the third O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Rb(1), one In(3), and two equivalent In(2) atoms. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one In(1), and two equivalent In(3) atoms. In the fifth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Rb(1), one In(2), and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_RbIn3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.320
_cell_length_b   9.858
_cell_length_c   16.751
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   548.239
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.470  0.372  1.0
  Rb  Rb1  1  0.250  0.530  0.628  1.0
  Rb  Rb2  1  0.250  0.030  0.872  1.0
  Rb  Rb3  1  0.750  0.970  0.128  1.0
  In  In4  1  0.750  0.818  0.316  1.0
  In  In5  1  0.250  0.182  0.684  1.0
  In  In6  1  0.250  0.682  0.816  1.0
  In  In7  1  0.750  0.318  0.184  1.0
  In  In8  1  0.750  0.652  0.986  1.0
  In  In9  1  0.250  0.348  0.014  1.0
  In  In10  1  0.250  0.848  0.486  1.0
  In  In11  1  0.750  0.152  0.514  1.0
  In  In12  1  0.750  0.886  0.658  1.0
  In  In13  1  0.250  0.114  0.342  1.0
  In  In14  1  0.250  0.614  0.158  1.0
  In  In15  1  0.750  0.386  0.842  1.0
  O  O16  1  0.750  0.979  0.424  1.0
  O  O17  1  0.250  0.021  0.576  1.0
  O  O18  1  0.250  0.521  0.924  1.0
  O  O19  1  0.750  0.479  0.076  1.0
  O  O20  1  0.750  0.767  0.552  1.0
  O  O21  1  0.250  0.233  0.448  1.0
  O  O22  1  0.250  0.733  0.052  1.0
  O  O23  1  0.750  0.267  0.948  1.0
  O  O24  1  0.750  0.706  0.210  1.0
  O  O25  1  0.250  0.294  0.790  1.0
  O  O26  1  0.250  0.794  0.710  1.0
  O  O27  1  0.750  0.206  0.290  1.0
  O  O28  1  0.750  0.776  0.883  1.0
  O  O29  1  0.250  0.224  0.117  1.0
  O  O30  1  0.250  0.724  0.383  1.0
  O  O31  1  0.750  0.276  0.617  1.0
  O  O32  1  0.750  0.561  0.772  1.0
  O  O33  1  0.250  0.439  0.228  1.0
  O  O34  1  0.250  0.939  0.272  1.0
  O  O35  1  0.750  0.061  0.728  1.0
[/CIF]
.