The compound described by FN2 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of eight molecular nitrogen;hydrofluoride molecules. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one N(3) atom. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one F(1) atom. F(1) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF card [CIF]
data_N2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.381
_cell_length_b   7.847
_cell_length_c   12.348
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   424.489
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  N  N0  1  0.133  0.491  0.435  1.0
  N  N1  1  0.367  0.509  0.935  1.0
  N  N2  1  0.867  0.991  0.065  1.0
  N  N3  1  0.633  0.009  0.565  1.0
  N  N4  1  0.232  0.681  0.203  1.0
  N  N5  1  0.268  0.319  0.703  1.0
  N  N6  1  0.768  0.181  0.297  1.0
  N  N7  1  0.732  0.819  0.797  1.0
  N  N8  1  0.094  0.055  0.070  1.0
  N  N9  1  0.406  0.945  0.570  1.0
  N  N10  1  0.906  0.555  0.430  1.0
  N  N11  1  0.594  0.445  0.930  1.0
  N  N12  1  0.196  0.201  0.746  1.0
  N  N13  1  0.304  0.799  0.246  1.0
  N  N14  1  0.804  0.701  0.754  1.0
  N  N15  1  0.696  0.299  0.254  1.0
  F  F16  1  0.202  0.295  0.106  1.0
  F  F17  1  0.298  0.705  0.606  1.0
  F  F18  1  0.798  0.795  0.394  1.0
  F  F19  1  0.702  0.205  0.894  1.0
  F  F20  1  0.135  0.128  0.387  1.0
  F  F21  1  0.365  0.872  0.887  1.0
  F  F22  1  0.865  0.628  0.113  1.0
  F  F23  1  0.635  0.372  0.613  1.0
[/CIF]
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The compound described by FN2 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of eight molecular nitrogen;hydrofluoride molecules. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one N(3) atom. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one F(1) atom. F(1) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF card [CIF]
data_N2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.381
_cell_length_b   7.847
_cell_length_c   12.348
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   424.489
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  N  N0  1  0.133  0.491  0.435  1.0
  N  N1  1  0.367  0.509  0.935  1.0
  N  N2  1  0.867  0.991  0.065  1.0
  N  N3  1  0.633  0.009  0.565  1.0
  N  N4  1  0.232  0.681  0.203  1.0
  N  N5  1  0.268  0.319  0.703  1.0
  N  N6  1  0.768  0.181  0.297  1.0
  N  N7  1  0.732  0.819  0.797  1.0
  N  N8  1  0.094  0.055  0.070  1.0
  N  N9  1  0.406  0.945  0.570  1.0
  N  N10  1  0.906  0.555  0.430  1.0
  N  N11  1  0.594  0.445  0.930  1.0
  N  N12  1  0.196  0.201  0.746  1.0
  N  N13  1  0.304  0.799  0.246  1.0
  N  N14  1  0.804  0.701  0.754  1.0
  N  N15  1  0.696  0.299  0.254  1.0
  F  F16  1  0.202  0.295  0.106  1.0
  F  F17  1  0.298  0.705  0.606  1.0
  F  F18  1  0.798  0.795  0.394  1.0
  F  F19  1  0.702  0.205  0.894  1.0
  F  F20  1  0.135  0.128  0.387  1.0
  F  F21  1  0.365  0.872  0.887  1.0
  F  F22  1  0.865  0.628  0.113  1.0
  F  F23  1  0.635  0.372  0.613  1.0
[/CIF]
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