The compound described by PtC2(NO2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two cis-(oxalatodiammine)platinum(ii) molecules. Pt(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. N(1) is bonded in a single-bond geometry to one Pt(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_PtC2(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.613
_cell_length_b   3.792
_cell_length_c   6.587
_cell_angle_alpha   87.474
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   264.843
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.250  0.631  0.862  1.0
  Pt  Pt1  1  0.750  0.369  0.138  1.0
  C  C2  1  0.323  0.898  0.256  1.0
  C  C3  1  0.677  0.102  0.744  1.0
  C  C4  1  0.823  0.102  0.744  1.0
  C  C5  1  0.177  0.898  0.256  1.0
  N  N6  1  0.886  0.471  0.283  1.0
  N  N7  1  0.114  0.529  0.717  1.0
  N  N8  1  0.386  0.529  0.717  1.0
  N  N9  1  0.614  0.471  0.283  1.0
  O  O10  1  0.374  0.786  0.089  1.0
  O  O11  1  0.626  0.214  0.911  1.0
  O  O12  1  0.874  0.214  0.911  1.0
  O  O13  1  0.126  0.786  0.089  1.0
  O  O14  1  0.384  0.005  0.400  1.0
  O  O15  1  0.616  0.995  0.600  1.0
  O  O16  1  0.884  0.995  0.600  1.0
  O  O17  1  0.116  0.005  0.400  1.0
[/CIF]
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The compound described by PtC2(NO2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two cis-(oxalatodiammine)platinum(ii) molecules. Pt(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. N(1) is bonded in a single-bond geometry to one Pt(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_PtC2(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.613
_cell_length_b   3.792
_cell_length_c   6.587
_cell_angle_alpha   87.474
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   264.843
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.250  0.631  0.862  1.0
  Pt  Pt1  1  0.750  0.369  0.138  1.0
  C  C2  1  0.323  0.898  0.256  1.0
  C  C3  1  0.677  0.102  0.744  1.0
  C  C4  1  0.823  0.102  0.744  1.0
  C  C5  1  0.177  0.898  0.256  1.0
  N  N6  1  0.886  0.471  0.283  1.0
  N  N7  1  0.114  0.529  0.717  1.0
  N  N8  1  0.386  0.529  0.717  1.0
  N  N9  1  0.614  0.471  0.283  1.0
  O  O10  1  0.374  0.786  0.089  1.0
  O  O11  1  0.626  0.214  0.911  1.0
  O  O12  1  0.874  0.214  0.911  1.0
  O  O13  1  0.126  0.786  0.089  1.0
  O  O14  1  0.384  0.005  0.400  1.0
  O  O15  1  0.616  0.995  0.600  1.0
  O  O16  1  0.884  0.995  0.600  1.0
  O  O17  1  0.116  0.005  0.400  1.0
[/CIF]
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