The material structure described by ((CH3)2NH2)2SnH6(CCl2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethylazanium molecules and one SnH6(CCl2)2 cluster. In the SnH6(CCl2)2 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent C(3), two equivalent Cl(1), and two equivalent Cl(2) atoms. C(3) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(4), one H(5), and one H(6) atom. There are three inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnH22C6(NCl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.600
_cell_length_b   7.423
_cell_length_c   8.482
_cell_angle_alpha   108.856
_cell_angle_beta   97.501
_cell_angle_gamma   94.205
_symmetry_Int_Tables_number   1
_cell_volume   386.902
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.500  0.500  0.500  1.0
  H  H1  1  0.253  0.707  0.210  1.0
  H  H2  1  0.747  0.293  0.790  1.0
  H  H3  1  0.931  0.822  0.138  1.0
  H  H4  1  0.069  0.178  0.862  1.0
  H  H5  1  0.063  0.063  0.221  1.0
  H  H6  1  0.937  0.937  0.779  1.0
  H  H7  1  0.114  0.375  0.531  1.0
  H  H8  1  0.886  0.625  0.469  1.0
  H  H9  1  0.279  0.457  0.733  1.0
  H  H10  1  0.721  0.543  0.267  1.0
  H  H11  1  0.295  0.225  0.585  1.0
  H  H12  1  0.705  0.775  0.415  1.0
  H  H13  1  0.169  0.729  0.929  1.0
  H  H14  1  0.831  0.271  0.071  1.0
  H  H15  1  0.039  0.925  0.359  1.0
  H  H16  1  0.961  0.075  0.641  1.0
  H  H17  1  0.441  0.761  0.005  1.0
  H  H18  1  0.559  0.239  0.995  1.0
  H  H19  1  0.308  0.965  0.010  1.0
  H  H20  1  0.692  0.035  0.990  1.0
  H  H21  1  0.376  0.934  0.283  1.0
  H  H22  1  0.624  0.066  0.717  1.0
  C  C23  1  0.057  0.919  0.231  1.0
  C  C24  1  0.943  0.081  0.769  1.0
  C  C25  1  0.296  0.823  0.022  1.0
  C  C26  1  0.704  0.177  0.978  1.0
  C  C27  1  0.266  0.373  0.600  1.0
  C  C28  1  0.734  0.627  0.400  1.0
  N  N29  1  0.255  0.842  0.195  1.0
  N  N30  1  0.745  0.158  0.805  1.0
  Cl  Cl31  1  0.255  0.411  0.200  1.0
  Cl  Cl32  1  0.745  0.589  0.800  1.0
  Cl  Cl33  1  0.649  0.166  0.396  1.0
  Cl  Cl34  1  0.351  0.834  0.604  1.0
[/CIF]
.
The material structure described by ((CH3)2NH2)2SnH6(CCl2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethylazanium molecules and one SnH6(CCl2)2 cluster. In the SnH6(CCl2)2 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent C(3), two equivalent Cl(1), and two equivalent Cl(2) atoms. C(3) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(4), one H(5), and one H(6) atom. There are three inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnH22C6(NCl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.600
_cell_length_b   7.423
_cell_length_c   8.482
_cell_angle_alpha   108.856
_cell_angle_beta   97.501
_cell_angle_gamma   94.205
_symmetry_Int_Tables_number   1
_cell_volume   386.902
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.500  0.500  0.500  1.0
  H  H1  1  0.253  0.707  0.210  1.0
  H  H2  1  0.747  0.293  0.790  1.0
  H  H3  1  0.931  0.822  0.138  1.0
  H  H4  1  0.069  0.178  0.862  1.0
  H  H5  1  0.063  0.063  0.221  1.0
  H  H6  1  0.937  0.937  0.779  1.0
  H  H7  1  0.114  0.375  0.531  1.0
  H  H8  1  0.886  0.625  0.469  1.0
  H  H9  1  0.279  0.457  0.733  1.0
  H  H10  1  0.721  0.543  0.267  1.0
  H  H11  1  0.295  0.225  0.585  1.0
  H  H12  1  0.705  0.775  0.415  1.0
  H  H13  1  0.169  0.729  0.929  1.0
  H  H14  1  0.831  0.271  0.071  1.0
  H  H15  1  0.039  0.925  0.359  1.0
  H  H16  1  0.961  0.075  0.641  1.0
  H  H17  1  0.441  0.761  0.005  1.0
  H  H18  1  0.559  0.239  0.995  1.0
  H  H19  1  0.308  0.965  0.010  1.0
  H  H20  1  0.692  0.035  0.990  1.0
  H  H21  1  0.376  0.934  0.283  1.0
  H  H22  1  0.624  0.066  0.717  1.0
  C  C23  1  0.057  0.919  0.231  1.0
  C  C24  1  0.943  0.081  0.769  1.0
  C  C25  1  0.296  0.823  0.022  1.0
  C  C26  1  0.704  0.177  0.978  1.0
  C  C27  1  0.266  0.373  0.600  1.0
  C  C28  1  0.734  0.627  0.400  1.0
  N  N29  1  0.255  0.842  0.195  1.0
  N  N30  1  0.745  0.158  0.805  1.0
  Cl  Cl31  1  0.255  0.411  0.200  1.0
  Cl  Cl32  1  0.745  0.589  0.800  1.0
  Cl  Cl33  1  0.649  0.166  0.396  1.0
  Cl  Cl34  1  0.351  0.834  0.604  1.0
[/CIF]
.