The compound described by DyGdNi2 crystallizes in the monoclinic Pm space group. There are three inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 7-coordinate geometry to one Ni(3), two equivalent Ni(1), two equivalent Ni(2), and two equivalent Ni(6) atoms. In the second Dy site, Dy(2) is bonded in a 7-coordinate geometry to one Ni(4), two equivalent Ni(1), two equivalent Ni(2), and two equivalent Ni(5) atoms. In the third Dy site, Dy(3) is bonded in a 7-coordinate geometry to one Ni(1), two equivalent Ni(2), two equivalent Ni(4), and two equivalent Ni(5) atoms. There are three inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 7-coordinate geometry to one Ni(2), two equivalent Ni(1), two equivalent Ni(3), and two equivalent Ni(6) atoms. In the second Gd site, Gd(2) is bonded in a 7-coordinate geometry to one Ni(5), two equivalent Ni(3), two equivalent Ni(4), and two equivalent Ni(6) atoms. In the third Gd site, Gd(3) is bonded in a 7-coordinate geometry to one Ni(6), two equivalent Ni(3), two equivalent Ni(4), and two equivalent Ni(5) atoms. There are six inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 9-coordinate geometry to one Dy(3), two equivalent Dy(1), two equivalent Dy(2), two equivalent Gd(1), and two equivalent Ni(2) atoms. In the second Ni site, Ni(2) is bonded in a 9-coordinate geometry to two equivalent Dy(1), two equivalent Dy(2), two equivalent Dy(3), one Gd(1), and two equivalent Ni(1) atoms. In the third Ni site, Ni(3) is bonded in a 9-coordinate geometry to one Dy(1), two equivalent Gd(1), two equivalent Gd(2), two equivalent Gd(3), and two equivalent Ni(6) atoms. In the fourth Ni site, Ni(4) is bonded in a 9-coordinate geometry to one Dy(2), two equivalent Dy(3), two equivalent Gd(2), two equivalent Gd(3), and two equivalent Ni(5) atoms. In the fifth Ni site, Ni(5) is bonded in a 9-coordinate geometry to two equivalent Dy(2), two equivalent Dy(3), one Gd(2), two equivalent Gd(3), and two equivalent Ni(4) atoms. In the sixth Ni site, Ni(6) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Gd(3), two equivalent Gd(1), two equivalent Gd(2), and two equivalent Ni(3) atoms. is represented by the CIF card [CIF]
data_GdDyNi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.195
_cell_length_b   5.404
_cell_length_c   10.592
_cell_angle_alpha   97.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   238.288
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.750  0.415  0.211  1.0
  Gd  Gd1  1  0.250  0.744  0.455  1.0
  Gd  Gd2  1  0.750  0.256  0.548  1.0
  Dy  Dy3  1  0.250  0.894  0.119  1.0
  Dy  Dy4  1  0.750  0.106  0.880  1.0
  Dy  Dy5  1  0.250  0.585  0.789  1.0
  Ni  Ni6  1  0.250  0.381  0.022  1.0
  Ni  Ni7  1  0.750  0.620  0.974  1.0
  Ni  Ni8  1  0.250  0.210  0.357  1.0
  Ni  Ni9  1  0.750  0.789  0.646  1.0
  Ni  Ni10  1  0.250  0.053  0.694  1.0
  Ni  Ni11  1  0.750  0.945  0.307  1.0
[/CIF]
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The compound described by DyGdNi2 crystallizes in the monoclinic Pm space group. There are three inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 7-coordinate geometry to one Ni(3), two equivalent Ni(1), two equivalent Ni(2), and two equivalent Ni(6) atoms. In the second Dy site, Dy(2) is bonded in a 7-coordinate geometry to one Ni(4), two equivalent Ni(1), two equivalent Ni(2), and two equivalent Ni(5) atoms. In the third Dy site, Dy(3) is bonded in a 7-coordinate geometry to one Ni(1), two equivalent Ni(2), two equivalent Ni(4), and two equivalent Ni(5) atoms. There are three inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 7-coordinate geometry to one Ni(2), two equivalent Ni(1), two equivalent Ni(3), and two equivalent Ni(6) atoms. In the second Gd site, Gd(2) is bonded in a 7-coordinate geometry to one Ni(5), two equivalent Ni(3), two equivalent Ni(4), and two equivalent Ni(6) atoms. In the third Gd site, Gd(3) is bonded in a 7-coordinate geometry to one Ni(6), two equivalent Ni(3), two equivalent Ni(4), and two equivalent Ni(5) atoms. There are six inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 9-coordinate geometry to one Dy(3), two equivalent Dy(1), two equivalent Dy(2), two equivalent Gd(1), and two equivalent Ni(2) atoms. In the second Ni site, Ni(2) is bonded in a 9-coordinate geometry to two equivalent Dy(1), two equivalent Dy(2), two equivalent Dy(3), one Gd(1), and two equivalent Ni(1) atoms. In the third Ni site, Ni(3) is bonded in a 9-coordinate geometry to one Dy(1), two equivalent Gd(1), two equivalent Gd(2), two equivalent Gd(3), and two equivalent Ni(6) atoms. In the fourth Ni site, Ni(4) is bonded in a 9-coordinate geometry to one Dy(2), two equivalent Dy(3), two equivalent Gd(2), two equivalent Gd(3), and two equivalent Ni(5) atoms. In the fifth Ni site, Ni(5) is bonded in a 9-coordinate geometry to two equivalent Dy(2), two equivalent Dy(3), one Gd(2), two equivalent Gd(3), and two equivalent Ni(4) atoms. In the sixth Ni site, Ni(6) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Gd(3), two equivalent Gd(1), two equivalent Gd(2), and two equivalent Ni(3) atoms. is represented by the CIF card [CIF]
data_GdDyNi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.195
_cell_length_b   5.404
_cell_length_c   10.592
_cell_angle_alpha   97.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   238.288
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.750  0.415  0.211  1.0
  Gd  Gd1  1  0.250  0.744  0.455  1.0
  Gd  Gd2  1  0.750  0.256  0.548  1.0
  Dy  Dy3  1  0.250  0.894  0.119  1.0
  Dy  Dy4  1  0.750  0.106  0.880  1.0
  Dy  Dy5  1  0.250  0.585  0.789  1.0
  Ni  Ni6  1  0.250  0.381  0.022  1.0
  Ni  Ni7  1  0.750  0.620  0.974  1.0
  Ni  Ni8  1  0.250  0.210  0.357  1.0
  Ni  Ni9  1  0.750  0.789  0.646  1.0
  Ni  Ni10  1  0.250  0.053  0.694  1.0
  Ni  Ni11  1  0.750  0.945  0.307  1.0
[/CIF]
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