The compound described by RbYSeO3Cl2 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 6-coordinate geometry to one O(3), two equivalent Cl(2), and three equivalent Cl(1) atoms. Y(1) is bonded to one O(3), two equivalent O(1), two equivalent O(2), one Cl(1), and one Cl(2) atom to form edge-sharing YCl2O5 pentagonal bipyramids. Se(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Y(1) and one Se(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Y(1) and one Se(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Rb(1), one Y(1), and one Se(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted see-saw-like geometry to three equivalent Rb(1) and one Y(1) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rb(1) and one Y(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbYSeCl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.676
_cell_length_b   7.098
_cell_length_c   8.959
_cell_angle_alpha   98.605
_cell_angle_beta   105.289
_cell_angle_gamma   88.926
_symmetry_Int_Tables_number   1
_cell_volume   404.769
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.735  0.716  0.615  1.0
  Rb  Rb1  1  0.265  0.284  0.385  1.0
  Y  Y2  1  0.641  0.253  0.019  1.0
  Y  Y3  1  0.359  0.747  0.981  1.0
  Se  Se4  1  0.867  0.761  0.088  1.0
  Se  Se5  1  0.133  0.239  0.912  1.0
  Cl  Cl6  1  0.743  0.324  0.332  1.0
  Cl  Cl7  1  0.257  0.676  0.668  1.0
  Cl  Cl8  1  0.391  0.807  0.287  1.0
  Cl  Cl9  1  0.609  0.193  0.713  1.0
  O  O10  1  0.681  0.577  0.016  1.0
  O  O11  1  0.319  0.423  0.984  1.0
  O  O12  1  0.683  0.930  0.027  1.0
  O  O13  1  0.317  0.070  0.973  1.0
  O  O14  1  0.997  0.258  0.051  1.0
  O  O15  1  0.003  0.742  0.949  1.0
[/CIF]
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The compound described by RbYSeO3Cl2 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 6-coordinate geometry to one O(3), two equivalent Cl(2), and three equivalent Cl(1) atoms. Y(1) is bonded to one O(3), two equivalent O(1), two equivalent O(2), one Cl(1), and one Cl(2) atom to form edge-sharing YCl2O5 pentagonal bipyramids. Se(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Y(1) and one Se(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Y(1) and one Se(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Rb(1), one Y(1), and one Se(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted see-saw-like geometry to three equivalent Rb(1) and one Y(1) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rb(1) and one Y(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbYSeCl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.676
_cell_length_b   7.098
_cell_length_c   8.959
_cell_angle_alpha   98.605
_cell_angle_beta   105.289
_cell_angle_gamma   88.926
_symmetry_Int_Tables_number   1
_cell_volume   404.769
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.735  0.716  0.615  1.0
  Rb  Rb1  1  0.265  0.284  0.385  1.0
  Y  Y2  1  0.641  0.253  0.019  1.0
  Y  Y3  1  0.359  0.747  0.981  1.0
  Se  Se4  1  0.867  0.761  0.088  1.0
  Se  Se5  1  0.133  0.239  0.912  1.0
  Cl  Cl6  1  0.743  0.324  0.332  1.0
  Cl  Cl7  1  0.257  0.676  0.668  1.0
  Cl  Cl8  1  0.391  0.807  0.287  1.0
  Cl  Cl9  1  0.609  0.193  0.713  1.0
  O  O10  1  0.681  0.577  0.016  1.0
  O  O11  1  0.319  0.423  0.984  1.0
  O  O12  1  0.683  0.930  0.027  1.0
  O  O13  1  0.317  0.070  0.973  1.0
  O  O14  1  0.997  0.258  0.051  1.0
  O  O15  1  0.003  0.742  0.949  1.0
[/CIF]
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