The material structure described by VO is Halite, Rock Salt structured and crystallizes in the monoclinic C2/m space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent O sites. In the first O site, O(1) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing OV6 octahedra. The corner-sharing octahedral tilt angles are 2°. In the second O site, O(2) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing OV6 octahedra. The corner-sharing octahedral tilt angles are 2°. is represented by the Crystallographic Information File (CIF) [CIF]
data_VO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.962
_cell_length_b   2.962
_cell_length_c   2.964
_cell_angle_alpha   63.599
_cell_angle_beta   63.599
_cell_angle_gamma   63.742
_symmetry_Int_Tables_number   1
_cell_volume   19.868
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.500  0.500  0.500  1.0
  V  V1  1  1.000  1.000  0.000  1.0
[/CIF]
.
The material structure described by VO is Halite, Rock Salt structured and crystallizes in the monoclinic C2/m space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent O sites. In the first O site, O(1) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing OV6 octahedra. The corner-sharing octahedral tilt angles are 2°. In the second O site, O(2) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing OV6 octahedra. The corner-sharing octahedral tilt angles are 2°. is represented by the Crystallographic Information File (CIF) [CIF]
data_VO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.962
_cell_length_b   2.962
_cell_length_c   2.964
_cell_angle_alpha   63.599
_cell_angle_beta   63.599
_cell_angle_gamma   63.742
_symmetry_Int_Tables_number   1
_cell_volume   19.868
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.500  0.500  0.500  1.0
  V  V1  1  1.000  1.000  0.000  1.0
[/CIF]
.