The material described by CrO2Cl2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two CrO2Cl2 clusters. Cr(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one Cl(1), and one Cl(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.413
_cell_length_b   6.984
_cell_length_c   7.737
_cell_angle_alpha   73.966
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   281.126
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.824  0.336  0.275  1.0
  Cr  Cr1  1  0.324  0.664  0.725  1.0
  Cl  Cl2  1  0.945  0.155  0.112  1.0
  Cl  Cl3  1  0.445  0.845  0.888  1.0
  Cl  Cl4  1  0.936  0.223  0.548  1.0
  Cl  Cl5  1  0.436  0.777  0.452  1.0
  O  O6  1  0.935  0.554  0.199  1.0
  O  O7  1  0.435  0.446  0.801  1.0
  O  O8  1  0.531  0.347  0.268  1.0
  O  O9  1  0.031  0.653  0.732  1.0
[/CIF]
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The material described by CrO2Cl2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two CrO2Cl2 clusters. Cr(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one Cl(1), and one Cl(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.413
_cell_length_b   6.984
_cell_length_c   7.737
_cell_angle_alpha   73.966
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   281.126
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.824  0.336  0.275  1.0
  Cr  Cr1  1  0.324  0.664  0.725  1.0
  Cl  Cl2  1  0.945  0.155  0.112  1.0
  Cl  Cl3  1  0.445  0.845  0.888  1.0
  Cl  Cl4  1  0.936  0.223  0.548  1.0
  Cl  Cl5  1  0.436  0.777  0.452  1.0
  O  O6  1  0.935  0.554  0.199  1.0
  O  O7  1  0.435  0.446  0.801  1.0
  O  O8  1  0.531  0.347  0.268  1.0
  O  O9  1  0.031  0.653  0.732  1.0
[/CIF]
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