The material structure described by Tb2TeS2 is Corundum-derived structured and crystallizes in the orthorhombic Immm space group. Tb(1) is bonded to two equivalent Te(1) and four equivalent S(1) atoms to form a mixture of edge and corner-sharing TbTe2S4 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. Te(1) is bonded in a square co-planar geometry to four equivalent Tb(1) atoms. S(1) is bonded to four equivalent Tb(1) atoms to form a mixture of edge and corner-sharing STb4 trigonal pyramids. is represented by the CIF file [CIF]
data_Tb2TeS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.567
_cell_length_b   7.567
_cell_length_c   7.567
_cell_angle_alpha   147.690
_cell_angle_beta   138.440
_cell_angle_gamma   53.599
_symmetry_Int_Tables_number   1
_cell_volume   152.709
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.834  0.334  0.500  1.0
  Tb  Tb1  1  0.166  0.666  0.500  1.0
  Te  Te2  1  0.000  0.000  0.000  1.0
  S  S3  1  0.704  0.704  0.000  1.0
  S  S4  1  0.296  0.296  0.000  1.0
[/CIF]
.
The material structure described by Tb2TeS2 is Corundum-derived structured and crystallizes in the orthorhombic Immm space group. Tb(1) is bonded to two equivalent Te(1) and four equivalent S(1) atoms to form a mixture of edge and corner-sharing TbTe2S4 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. Te(1) is bonded in a square co-planar geometry to four equivalent Tb(1) atoms. S(1) is bonded to four equivalent Tb(1) atoms to form a mixture of edge and corner-sharing STb4 trigonal pyramids. is represented by the CIF file [CIF]
data_Tb2TeS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.567
_cell_length_b   7.567
_cell_length_c   7.567
_cell_angle_alpha   147.690
_cell_angle_beta   138.440
_cell_angle_gamma   53.599
_symmetry_Int_Tables_number   1
_cell_volume   152.709
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.834  0.334  0.500  1.0
  Tb  Tb1  1  0.166  0.666  0.500  1.0
  Te  Te2  1  0.000  0.000  0.000  1.0
  S  S3  1  0.704  0.704  0.000  1.0
  S  S4  1  0.296  0.296  0.000  1.0
[/CIF]
.