The structure described by Li5Co5(SnO6)2 is Caswellsilverite-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the second Co site, Co(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the third Co site, Co(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the fourth Co site, Co(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form SnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. In the second Sn site, Sn(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form SnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Co(2), one Co(4), and one Sn(1) atom to form OLi3Co2Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(2)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co3Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(5)Li3Co2Sn octahedra, edges with four equivalent O(1)Li3Co2Sn octahedra, and edges with four equivalent O(3)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Co(1), one Co(2), one Co(3), and one Sn(2) atom to form OLi2Co3Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra,  an edgeedge with one O(3)Li3Co2Sn octahedra,  an edgeedge with one O(5)Li3Co2Sn octahedra, edges with four equivalent O(2)Li2Co3Sn octahedra, and edges with four equivalent O(4)Li2Co3Sn octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Co(2), one Co(4), and one Sn(1) atom to form OLi3Co2Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(2)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co3Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra, edges with four equivalent O(3)Li3Co2Sn octahedra, and edges with four equivalent O(5)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Co(1), one Co(2), one Co(3), and one Sn(2) atom to form OLi2Co3Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(2)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra,  an edgeedge with one O(3)Li3Co2Sn octahedra,  an edgeedge with one O(5)Li3Co2Sn octahedra, edges with four equivalent O(4)Li2Co3Sn octahedra, and edges with four equivalent O(6)Li2Co3Sn octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Co(2), one Co(4), and one Sn(1) atom to form OLi3Co2Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(2)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co3Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(3)Li3Co2Sn octahedra, edges with four equivalent O(1)Li3Co2Sn octahedra, and edges with four equivalent O(5)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Co(1), one Co(2), one Co(3), and one Sn(2) atom to form OLi2Co3Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(4)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra,  an edgeedge with one O(3)Li3Co2Sn octahedra,  an edgeedge with one O(5)Li3Co2Sn octahedra, edges with four equivalent O(2)Li2Co3Sn octahedra, and edges with four equivalent O(6)Li2Co3Sn octahedra. The corner-sharing octahedral tilt angles range from 2-11°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5Co5(SnO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.272
_cell_length_b   5.272
_cell_length_c   10.053
_cell_angle_alpha   84.221
_cell_angle_beta   84.221
_cell_angle_gamma   120.813
_symmetry_Int_Tables_number   1
_cell_volume   234.883
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.812  0.682  0.251  1.0
  Li  Li1  1  0.670  0.813  0.743  1.0
  Li  Li2  1  0.318  0.188  0.749  1.0
  Li  Li3  1  0.187  0.330  0.257  1.0
  Li  Li4  1  0.086  0.914  0.500  1.0
  Co  Co5  1  0.916  0.084  0.000  1.0
  Co  Co6  1  1.000  0.503  0.747  1.0
  Co  Co7  1  0.497  0.000  0.253  1.0
  Co  Co8  1  0.582  0.418  0.000  1.0
  Co  Co9  1  0.419  0.581  0.500  1.0
  Sn  Sn10  1  0.749  0.251  0.500  1.0
  Sn  Sn11  1  0.249  0.751  0.000  1.0
  O  O12  1  0.055  0.238  0.617  1.0
  O  O13  1  0.762  0.945  0.383  1.0
  O  O14  1  0.871  0.374  0.124  1.0
  O  O15  1  0.626  0.129  0.876  1.0
  O  O16  1  0.687  0.528  0.615  1.0
  O  O17  1  0.472  0.313  0.385  1.0
  O  O18  1  0.536  0.713  0.119  1.0
  O  O19  1  0.287  0.464  0.881  1.0
  O  O20  1  0.383  0.845  0.614  1.0
  O  O21  1  0.155  0.617  0.386  1.0
  O  O22  1  0.212  0.031  0.124  1.0
  O  O23  1  0.969  0.788  0.876  1.0
[/CIF]
.
The structure described by Li5Co5(SnO6)2 is Caswellsilverite-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the second Co site, Co(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the third Co site, Co(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the fourth Co site, Co(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form SnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. In the second Sn site, Sn(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form SnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Co(2), one Co(4), and one Sn(1) atom to form OLi3Co2Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(2)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co3Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(5)Li3Co2Sn octahedra, edges with four equivalent O(1)Li3Co2Sn octahedra, and edges with four equivalent O(3)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Co(1), one Co(2), one Co(3), and one Sn(2) atom to form OLi2Co3Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra,  an edgeedge with one O(3)Li3Co2Sn octahedra,  an edgeedge with one O(5)Li3Co2Sn octahedra, edges with four equivalent O(2)Li2Co3Sn octahedra, and edges with four equivalent O(4)Li2Co3Sn octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Co(2), one Co(4), and one Sn(1) atom to form OLi3Co2Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(2)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co3Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra, edges with four equivalent O(3)Li3Co2Sn octahedra, and edges with four equivalent O(5)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Co(1), one Co(2), one Co(3), and one Sn(2) atom to form OLi2Co3Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(2)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra,  an edgeedge with one O(3)Li3Co2Sn octahedra,  an edgeedge with one O(5)Li3Co2Sn octahedra, edges with four equivalent O(4)Li2Co3Sn octahedra, and edges with four equivalent O(6)Li2Co3Sn octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Co(2), one Co(4), and one Sn(1) atom to form OLi3Co2Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(2)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co3Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(3)Li3Co2Sn octahedra, edges with four equivalent O(1)Li3Co2Sn octahedra, and edges with four equivalent O(5)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Co(1), one Co(2), one Co(3), and one Sn(2) atom to form OLi2Co3Sn octahedra that share  a cornercorner with one O(2)Li2Co3Sn octahedra,  a cornercorner with one O(4)Li2Co3Sn octahedra,  a cornercorner with one O(6)Li2Co3Sn octahedra,  a cornercorner with one O(1)Li3Co2Sn octahedra,  a cornercorner with one O(3)Li3Co2Sn octahedra,  a cornercorner with one O(5)Li3Co2Sn octahedra,  an edgeedge with one O(4)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra,  an edgeedge with one O(3)Li3Co2Sn octahedra,  an edgeedge with one O(5)Li3Co2Sn octahedra, edges with four equivalent O(2)Li2Co3Sn octahedra, and edges with four equivalent O(6)Li2Co3Sn octahedra. The corner-sharing octahedral tilt angles range from 2-11°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5Co5(SnO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.272
_cell_length_b   5.272
_cell_length_c   10.053
_cell_angle_alpha   84.221
_cell_angle_beta   84.221
_cell_angle_gamma   120.813
_symmetry_Int_Tables_number   1
_cell_volume   234.883
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.812  0.682  0.251  1.0
  Li  Li1  1  0.670  0.813  0.743  1.0
  Li  Li2  1  0.318  0.188  0.749  1.0
  Li  Li3  1  0.187  0.330  0.257  1.0
  Li  Li4  1  0.086  0.914  0.500  1.0
  Co  Co5  1  0.916  0.084  0.000  1.0
  Co  Co6  1  1.000  0.503  0.747  1.0
  Co  Co7  1  0.497  0.000  0.253  1.0
  Co  Co8  1  0.582  0.418  0.000  1.0
  Co  Co9  1  0.419  0.581  0.500  1.0
  Sn  Sn10  1  0.749  0.251  0.500  1.0
  Sn  Sn11  1  0.249  0.751  0.000  1.0
  O  O12  1  0.055  0.238  0.617  1.0
  O  O13  1  0.762  0.945  0.383  1.0
  O  O14  1  0.871  0.374  0.124  1.0
  O  O15  1  0.626  0.129  0.876  1.0
  O  O16  1  0.687  0.528  0.615  1.0
  O  O17  1  0.472  0.313  0.385  1.0
  O  O18  1  0.536  0.713  0.119  1.0
  O  O19  1  0.287  0.464  0.881  1.0
  O  O20  1  0.383  0.845  0.614  1.0
  O  O21  1  0.155  0.617  0.386  1.0
  O  O22  1  0.212  0.031  0.124  1.0
  O  O23  1  0.969  0.788  0.876  1.0
[/CIF]
.