The crystal structure described by Th6OF24 crystallizes in the tetragonal I4/m space group. There are two inequivalent Th sites. In the first Th site, Th(1) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. In the second Th site, Th(2) is bonded in a 9-coordinate geometry to one O(1), four equivalent F(3), and four equivalent F(4) atoms. O(1) is bonded in a linear geometry to two equivalent Th(2) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to two equivalent Th(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Th(1) atoms. In the third F site, F(3) is bonded in a linear geometry to one Th(1) and one Th(2) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Th(1) and one Th(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th6OF24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.856
_cell_length_b   8.856
_cell_length_c   8.856
_cell_angle_alpha   115.831
_cell_angle_beta   115.831
_cell_angle_gamma   97.387
_symmetry_Int_Tables_number   1
_cell_volume   517.450
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.827  0.615  0.442  1.0
  Th  Th1  1  0.173  0.385  0.558  1.0
  Th  Th2  1  0.615  0.173  0.789  1.0
  Th  Th3  1  0.385  0.827  0.211  1.0
  Th  Th4  1  0.221  0.221  0.000  1.0
  Th  Th5  1  0.779  0.779  0.000  1.0
  O  O6  1  0.000  0.000  0.000  1.0
  F  F7  1  0.110  0.610  0.500  1.0
  F  F8  1  0.610  0.110  0.500  1.0
  F  F9  1  0.890  0.390  0.500  1.0
  F  F10  1  0.390  0.890  0.500  1.0
  F  F11  1  0.632  0.767  0.399  1.0
  F  F12  1  0.368  0.233  0.601  1.0
  F  F13  1  0.767  0.368  0.136  1.0
  F  F14  1  0.233  0.632  0.864  1.0
  F  F15  1  0.034  0.918  0.710  1.0
  F  F16  1  0.209  0.325  0.290  1.0
  F  F17  1  0.918  0.209  0.884  1.0
  F  F18  1  0.325  0.034  0.116  1.0
  F  F19  1  0.966  0.082  0.290  1.0
  F  F20  1  0.791  0.675  0.710  1.0
  F  F21  1  0.082  0.791  0.116  1.0
  F  F22  1  0.675  0.966  0.884  1.0
  F  F23  1  0.145  0.273  0.743  1.0
  F  F24  1  0.530  0.403  0.257  1.0
  F  F25  1  0.273  0.530  0.128  1.0
  F  F26  1  0.403  0.145  0.872  1.0
  F  F27  1  0.855  0.727  0.257  1.0
  F  F28  1  0.470  0.597  0.743  1.0
  F  F29  1  0.727  0.470  0.872  1.0
  F  F30  1  0.597  0.855  0.128  1.0
[/CIF]
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The crystal structure described by Th6OF24 crystallizes in the tetragonal I4/m space group. There are two inequivalent Th sites. In the first Th site, Th(1) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. In the second Th site, Th(2) is bonded in a 9-coordinate geometry to one O(1), four equivalent F(3), and four equivalent F(4) atoms. O(1) is bonded in a linear geometry to two equivalent Th(2) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to two equivalent Th(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Th(1) atoms. In the third F site, F(3) is bonded in a linear geometry to one Th(1) and one Th(2) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Th(1) and one Th(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th6OF24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.856
_cell_length_b   8.856
_cell_length_c   8.856
_cell_angle_alpha   115.831
_cell_angle_beta   115.831
_cell_angle_gamma   97.387
_symmetry_Int_Tables_number   1
_cell_volume   517.450
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.827  0.615  0.442  1.0
  Th  Th1  1  0.173  0.385  0.558  1.0
  Th  Th2  1  0.615  0.173  0.789  1.0
  Th  Th3  1  0.385  0.827  0.211  1.0
  Th  Th4  1  0.221  0.221  0.000  1.0
  Th  Th5  1  0.779  0.779  0.000  1.0
  O  O6  1  0.000  0.000  0.000  1.0
  F  F7  1  0.110  0.610  0.500  1.0
  F  F8  1  0.610  0.110  0.500  1.0
  F  F9  1  0.890  0.390  0.500  1.0
  F  F10  1  0.390  0.890  0.500  1.0
  F  F11  1  0.632  0.767  0.399  1.0
  F  F12  1  0.368  0.233  0.601  1.0
  F  F13  1  0.767  0.368  0.136  1.0
  F  F14  1  0.233  0.632  0.864  1.0
  F  F15  1  0.034  0.918  0.710  1.0
  F  F16  1  0.209  0.325  0.290  1.0
  F  F17  1  0.918  0.209  0.884  1.0
  F  F18  1  0.325  0.034  0.116  1.0
  F  F19  1  0.966  0.082  0.290  1.0
  F  F20  1  0.791  0.675  0.710  1.0
  F  F21  1  0.082  0.791  0.116  1.0
  F  F22  1  0.675  0.966  0.884  1.0
  F  F23  1  0.145  0.273  0.743  1.0
  F  F24  1  0.530  0.403  0.257  1.0
  F  F25  1  0.273  0.530  0.128  1.0
  F  F26  1  0.403  0.145  0.872  1.0
  F  F27  1  0.855  0.727  0.257  1.0
  F  F28  1  0.470  0.597  0.743  1.0
  F  F29  1  0.727  0.470  0.872  1.0
  F  F30  1  0.597  0.855  0.128  1.0
[/CIF]
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