The compound described by Li2V3WO8 is Spinel-derived structured and crystallizes in the monoclinic C2 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form LiO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra, corners with three equivalent V(3)O6 octahedra, and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-60°. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(6), and one O(8) atom to form LiO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(3)O6 octahedra, corners with three equivalent V(4)O6 octahedra, and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-60°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. In the third V site, V(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. In the fourth V site, V(4) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form VO6 octahedra that share corners with six equivalent Li(2)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. W(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one V(3), and one W(1) atom. In the second O site, O(8) is bonded to one Li(2), one V(1), one V(4), and one W(1) atom to form distorted OLiV2W trigonal pyramids that share  a cornercorner with one O(8)LiV2W trigonal pyramid,  a cornercorner with one O(1)LiV3 trigonal pyramid, corners with two equivalent O(5)LiV2W trigonal pyramids, corners with two equivalent O(2)LiV3 trigonal pyramids, corners with three equivalent O(3)LiV2W trigonal pyramids,  an edgeedge with one O(4)LiV2W trigonal pyramid, and  an edgeedge with one O(2)LiV3 trigonal pyramid. In the third O site, O(1) is bonded to one Li(1), one V(1), one V(2), and one V(3) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(8)LiV2W trigonal pyramid,  a cornercorner with one O(1)LiV3 trigonal pyramid, corners with two equivalent O(5)LiV2W trigonal pyramids, corners with two equivalent O(2)LiV3 trigonal pyramids, corners with three equivalent O(4)LiV2W trigonal pyramids,  an edgeedge with one O(3)LiV2W trigonal pyramid, and  an edgeedge with one O(5)LiV2W trigonal pyramid. In the fourth O site, O(2) is bonded to one Li(2), one V(1), one V(3), and one V(4) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(5)LiV2W trigonal pyramid,  a cornercorner with one O(2)LiV3 trigonal pyramid, corners with two equivalent O(8)LiV2W trigonal pyramids, corners with two equivalent O(1)LiV3 trigonal pyramids, corners with three equivalent O(3)LiV2W trigonal pyramids,  an edgeedge with one O(4)LiV2W trigonal pyramid, and  an edgeedge with one O(8)LiV2W trigonal pyramid. In the fifth O site, O(3) is bonded to one Li(2), one V(1), one V(3), and one W(1) atom to form distorted OLiV2W trigonal pyramids that share corners with three equivalent O(4)LiV2W trigonal pyramids, corners with three equivalent O(8)LiV2W trigonal pyramids, corners with three equivalent O(2)LiV3 trigonal pyramids,  an edgeedge with one O(5)LiV2W trigonal pyramid, and  an edgeedge with one O(1)LiV3 trigonal pyramid. In the sixth O site, O(4) is bonded to one Li(1), one V(1), one V(3), and one W(1) atom to form distorted OLiV2W trigonal pyramids that share corners with three equivalent O(3)LiV2W trigonal pyramids, corners with three equivalent O(5)LiV2W trigonal pyramids, corners with three equivalent O(1)LiV3 trigonal pyramids,  an edgeedge with one O(8)LiV2W trigonal pyramid, and  an edgeedge with one O(2)LiV3 trigonal pyramid. In the seventh O site, O(5) is bonded to one Li(1), one V(1), one V(2), and one W(1) atom to form distorted OLiV2W trigonal pyramids that share  a cornercorner with one O(5)LiV2W trigonal pyramid,  a cornercorner with one O(2)LiV3 trigonal pyramid, corners with two equivalent O(8)LiV2W trigonal pyramids, corners with two equivalent O(1)LiV3 trigonal pyramids, corners with three equivalent O(4)LiV2W trigonal pyramids,  an edgeedge with one O(3)LiV2W trigonal pyramid, and  an edgeedge with one O(1)LiV3 trigonal pyramid. In the eighth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(3), one V(4), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V3WO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.047
_cell_length_b   6.067
_cell_length_c   6.107
_cell_angle_alpha   119.665
_cell_angle_beta   89.999
_cell_angle_gamma   119.893
_symmetry_Int_Tables_number   1
_cell_volume   159.475
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.131  0.261  0.389  1.0
  Li  Li1  1  0.869  0.739  0.611  1.0
  O  O2  1  0.266  0.533  0.795  1.0
  O  O3  1  0.734  0.467  0.205  1.0
  O  O4  1  0.263  0.527  0.244  1.0
  O  O5  1  0.266  0.984  0.251  1.0
  O  O6  1  0.718  0.985  0.251  1.0
  O  O7  1  0.282  0.016  0.749  1.0
  O  O8  1  0.733  0.015  0.749  1.0
  O  O9  1  0.737  0.473  0.756  1.0
  V  V10  1  0.000  0.500  0.999  1.0
  V  V11  1  0.501  0.500  0.001  1.0
  V  V12  1  0.500  0.000  0.000  1.0
  W  W13  1  0.500  1.000  0.500  1.0
[/CIF]
.
The compound described by Li2V3WO8 is Spinel-derived structured and crystallizes in the monoclinic C2 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form LiO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra, corners with three equivalent V(3)O6 octahedra, and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-60°. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(6), and one O(8) atom to form LiO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(3)O6 octahedra, corners with three equivalent V(4)O6 octahedra, and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-60°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. In the third V site, V(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. In the fourth V site, V(4) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form VO6 octahedra that share corners with six equivalent Li(2)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. W(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one V(3), and one W(1) atom. In the second O site, O(8) is bonded to one Li(2), one V(1), one V(4), and one W(1) atom to form distorted OLiV2W trigonal pyramids that share  a cornercorner with one O(8)LiV2W trigonal pyramid,  a cornercorner with one O(1)LiV3 trigonal pyramid, corners with two equivalent O(5)LiV2W trigonal pyramids, corners with two equivalent O(2)LiV3 trigonal pyramids, corners with three equivalent O(3)LiV2W trigonal pyramids,  an edgeedge with one O(4)LiV2W trigonal pyramid, and  an edgeedge with one O(2)LiV3 trigonal pyramid. In the third O site, O(1) is bonded to one Li(1), one V(1), one V(2), and one V(3) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(8)LiV2W trigonal pyramid,  a cornercorner with one O(1)LiV3 trigonal pyramid, corners with two equivalent O(5)LiV2W trigonal pyramids, corners with two equivalent O(2)LiV3 trigonal pyramids, corners with three equivalent O(4)LiV2W trigonal pyramids,  an edgeedge with one O(3)LiV2W trigonal pyramid, and  an edgeedge with one O(5)LiV2W trigonal pyramid. In the fourth O site, O(2) is bonded to one Li(2), one V(1), one V(3), and one V(4) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(5)LiV2W trigonal pyramid,  a cornercorner with one O(2)LiV3 trigonal pyramid, corners with two equivalent O(8)LiV2W trigonal pyramids, corners with two equivalent O(1)LiV3 trigonal pyramids, corners with three equivalent O(3)LiV2W trigonal pyramids,  an edgeedge with one O(4)LiV2W trigonal pyramid, and  an edgeedge with one O(8)LiV2W trigonal pyramid. In the fifth O site, O(3) is bonded to one Li(2), one V(1), one V(3), and one W(1) atom to form distorted OLiV2W trigonal pyramids that share corners with three equivalent O(4)LiV2W trigonal pyramids, corners with three equivalent O(8)LiV2W trigonal pyramids, corners with three equivalent O(2)LiV3 trigonal pyramids,  an edgeedge with one O(5)LiV2W trigonal pyramid, and  an edgeedge with one O(1)LiV3 trigonal pyramid. In the sixth O site, O(4) is bonded to one Li(1), one V(1), one V(3), and one W(1) atom to form distorted OLiV2W trigonal pyramids that share corners with three equivalent O(3)LiV2W trigonal pyramids, corners with three equivalent O(5)LiV2W trigonal pyramids, corners with three equivalent O(1)LiV3 trigonal pyramids,  an edgeedge with one O(8)LiV2W trigonal pyramid, and  an edgeedge with one O(2)LiV3 trigonal pyramid. In the seventh O site, O(5) is bonded to one Li(1), one V(1), one V(2), and one W(1) atom to form distorted OLiV2W trigonal pyramids that share  a cornercorner with one O(5)LiV2W trigonal pyramid,  a cornercorner with one O(2)LiV3 trigonal pyramid, corners with two equivalent O(8)LiV2W trigonal pyramids, corners with two equivalent O(1)LiV3 trigonal pyramids, corners with three equivalent O(4)LiV2W trigonal pyramids,  an edgeedge with one O(3)LiV2W trigonal pyramid, and  an edgeedge with one O(1)LiV3 trigonal pyramid. In the eighth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(3), one V(4), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V3WO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.047
_cell_length_b   6.067
_cell_length_c   6.107
_cell_angle_alpha   119.665
_cell_angle_beta   89.999
_cell_angle_gamma   119.893
_symmetry_Int_Tables_number   1
_cell_volume   159.475
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.131  0.261  0.389  1.0
  Li  Li1  1  0.869  0.739  0.611  1.0
  O  O2  1  0.266  0.533  0.795  1.0
  O  O3  1  0.734  0.467  0.205  1.0
  O  O4  1  0.263  0.527  0.244  1.0
  O  O5  1  0.266  0.984  0.251  1.0
  O  O6  1  0.718  0.985  0.251  1.0
  O  O7  1  0.282  0.016  0.749  1.0
  O  O8  1  0.733  0.015  0.749  1.0
  O  O9  1  0.737  0.473  0.756  1.0
  V  V10  1  0.000  0.500  0.999  1.0
  V  V11  1  0.501  0.500  0.001  1.0
  V  V12  1  0.500  0.000  0.000  1.0
  W  W13  1  0.500  1.000  0.500  1.0
[/CIF]
.