The crystal structure described by LiRe2N3 crystallizes in the orthorhombic Cmc2_1 space group. Li(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form distorted LiN4 tetrahedra that share corners with two equivalent Li(1)N4 tetrahedra, corners with six equivalent Re(1)N4 trigonal pyramids, and edges with two equivalent Re(1)N4 trigonal pyramids. Re(1) is bonded to one N(2) and three equivalent N(1) atoms to form distorted ReN4 trigonal pyramids that share corners with three equivalent Li(1)N4 tetrahedra, corners with seven equivalent Re(1)N4 trigonal pyramids, and  an edgeedge with one Li(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(2) is bonded to two equivalent Li(1) and two equivalent Re(1) atoms to form NLi2Re2 trigonal pyramids that share corners with six equivalent N(1)LiRe3 tetrahedra, corners with two equivalent N(2)Li2Re2 trigonal pyramids, and edges with two equivalent N(1)LiRe3 tetrahedra. In the second N site, N(1) is bonded to one Li(1) and three equivalent Re(1) atoms to form distorted NLiRe3 tetrahedra that share corners with seven equivalent N(1)LiRe3 tetrahedra, corners with three equivalent N(2)Li2Re2 trigonal pyramids, and  an edgeedge with one N(2)Li2Re2 trigonal pyramid. is represented by the CIF card [CIF]
data_LiRe2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.474
_cell_length_b   4.875
_cell_length_c   6.598
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   116.442
_symmetry_Int_Tables_number   1
_cell_volume   157.679
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.617  0.334  1.0
  Li  Li1  1  0.000  0.383  0.834  1.0
  Re  Re2  1  0.377  0.344  0.532  1.0
  Re  Re3  1  0.623  0.967  0.532  1.0
  Re  Re4  1  0.623  0.656  0.032  1.0
  Re  Re5  1  0.377  0.033  0.032  1.0
  N  N6  1  0.392  0.361  0.837  1.0
  N  N7  1  0.608  0.969  0.837  1.0
  N  N8  1  0.608  0.639  0.337  1.0
  N  N9  1  0.392  0.031  0.337  1.0
  N  N10  1  0.000  0.776  0.017  1.0
  N  N11  1  0.000  0.224  0.517  1.0
[/CIF]
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The crystal structure described by LiRe2N3 crystallizes in the orthorhombic Cmc2_1 space group. Li(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form distorted LiN4 tetrahedra that share corners with two equivalent Li(1)N4 tetrahedra, corners with six equivalent Re(1)N4 trigonal pyramids, and edges with two equivalent Re(1)N4 trigonal pyramids. Re(1) is bonded to one N(2) and three equivalent N(1) atoms to form distorted ReN4 trigonal pyramids that share corners with three equivalent Li(1)N4 tetrahedra, corners with seven equivalent Re(1)N4 trigonal pyramids, and  an edgeedge with one Li(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(2) is bonded to two equivalent Li(1) and two equivalent Re(1) atoms to form NLi2Re2 trigonal pyramids that share corners with six equivalent N(1)LiRe3 tetrahedra, corners with two equivalent N(2)Li2Re2 trigonal pyramids, and edges with two equivalent N(1)LiRe3 tetrahedra. In the second N site, N(1) is bonded to one Li(1) and three equivalent Re(1) atoms to form distorted NLiRe3 tetrahedra that share corners with seven equivalent N(1)LiRe3 tetrahedra, corners with three equivalent N(2)Li2Re2 trigonal pyramids, and  an edgeedge with one N(2)Li2Re2 trigonal pyramid. is represented by the CIF card [CIF]
data_LiRe2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.474
_cell_length_b   4.875
_cell_length_c   6.598
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   116.442
_symmetry_Int_Tables_number   1
_cell_volume   157.679
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.617  0.334  1.0
  Li  Li1  1  0.000  0.383  0.834  1.0
  Re  Re2  1  0.377  0.344  0.532  1.0
  Re  Re3  1  0.623  0.967  0.532  1.0
  Re  Re4  1  0.623  0.656  0.032  1.0
  Re  Re5  1  0.377  0.033  0.032  1.0
  N  N6  1  0.392  0.361  0.837  1.0
  N  N7  1  0.608  0.969  0.837  1.0
  N  N8  1  0.608  0.639  0.337  1.0
  N  N9  1  0.392  0.031  0.337  1.0
  N  N10  1  0.000  0.776  0.017  1.0
  N  N11  1  0.000  0.224  0.517  1.0
[/CIF]
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