The structure described by PdCl2PdCl4(RhN5OCl2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two palladium(ii) chloride molecules, two tetrachloropalladium molecules, and four RhN5OCl2 clusters. In each RhN5OCl2 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. In the second N site, N(2) is bonded in an L-shaped geometry to one Rh(1) and one O(1) atom. In the third N site, N(3) is bonded in an L-shaped geometry to one Rh(1) and one O(1) atom. In the fourth N site, N(4) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(5) atom. O(1) is bonded in a water-like geometry to one N(2) and one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(4) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF card [CIF]
data_PdRhN5Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.030
_cell_length_b   11.704
_cell_length_c   14.539
_cell_angle_alpha   90.000
_cell_angle_beta   92.097
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1365.482
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.000  0.500  0.500  1.0
  Pd  Pd1  1  0.000  0.000  0.000  1.0
  Pd  Pd2  1  0.000  0.000  0.500  1.0
  Pd  Pd3  1  0.000  0.500  0.000  1.0
  Rh  Rh4  1  0.434  0.784  0.290  1.0
  Rh  Rh5  1  0.566  0.284  0.210  1.0
  Rh  Rh6  1  0.566  0.216  0.710  1.0
  Rh  Rh7  1  0.434  0.716  0.790  1.0
  N  N8  1  0.409  0.744  0.442  1.0
  N  N9  1  0.591  0.244  0.058  1.0
  N  N10  1  0.591  0.256  0.558  1.0
  N  N11  1  0.409  0.756  0.942  1.0
  N  N12  1  0.475  0.734  0.167  1.0
  N  N13  1  0.525  0.234  0.333  1.0
  N  N14  1  0.525  0.266  0.833  1.0
  N  N15  1  0.475  0.766  0.667  1.0
  N  N16  1  0.667  0.764  0.272  1.0
  N  N17  1  0.333  0.264  0.228  1.0
  N  N18  1  0.333  0.236  0.728  1.0
  N  N19  1  0.667  0.736  0.772  1.0
  N  N20  1  0.164  0.726  0.323  1.0
  N  N21  1  0.836  0.226  0.177  1.0
  N  N22  1  0.836  0.274  0.677  1.0
  N  N23  1  0.164  0.774  0.823  1.0
  N  N24  1  0.415  0.937  0.273  1.0
  N  N25  1  0.585  0.437  0.227  1.0
  N  N26  1  0.585  0.063  0.727  1.0
  N  N27  1  0.415  0.563  0.773  1.0
  Cl  Cl28  1  0.947  0.418  0.365  1.0
  Cl  Cl29  1  0.053  0.918  0.135  1.0
  Cl  Cl30  1  0.053  0.582  0.635  1.0
  Cl  Cl31  1  0.947  0.082  0.865  1.0
  Cl  Cl32  1  0.776  0.281  0.577  1.0
  Cl  Cl33  1  0.224  0.781  0.923  1.0
  Cl  Cl34  1  0.224  0.719  0.423  1.0
  Cl  Cl35  1  0.776  0.219  0.077  1.0
  Cl  Cl36  1  0.278  0.026  0.516  1.0
  Cl  Cl37  1  0.722  0.526  0.984  1.0
  Cl  Cl38  1  0.722  0.974  0.484  1.0
  Cl  Cl39  1  0.278  0.474  0.016  1.0
  Cl  Cl40  1  0.996  0.947  0.650  1.0
  Cl  Cl41  1  0.004  0.447  0.850  1.0
  Cl  Cl42  1  0.004  0.053  0.350  1.0
  Cl  Cl43  1  0.996  0.553  0.150  1.0
  Cl  Cl44  1  0.471  0.505  0.303  1.0
  Cl  Cl45  1  0.529  0.005  0.197  1.0
  Cl  Cl46  1  0.529  0.495  0.697  1.0
  Cl  Cl47  1  0.471  0.995  0.803  1.0
  O  O48  1  0.643  0.723  0.185  1.0
  O  O49  1  0.357  0.223  0.315  1.0
  O  O50  1  0.357  0.277  0.815  1.0
  O  O51  1  0.643  0.777  0.685  1.0
[/CIF]
.
The structure described by PdCl2PdCl4(RhN5OCl2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two palladium(ii) chloride molecules, two tetrachloropalladium molecules, and four RhN5OCl2 clusters. In each RhN5OCl2 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. In the second N site, N(2) is bonded in an L-shaped geometry to one Rh(1) and one O(1) atom. In the third N site, N(3) is bonded in an L-shaped geometry to one Rh(1) and one O(1) atom. In the fourth N site, N(4) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(5) atom. O(1) is bonded in a water-like geometry to one N(2) and one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(4) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF card [CIF]
data_PdRhN5Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.030
_cell_length_b   11.704
_cell_length_c   14.539
_cell_angle_alpha   90.000
_cell_angle_beta   92.097
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1365.482
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.000  0.500  0.500  1.0
  Pd  Pd1  1  0.000  0.000  0.000  1.0
  Pd  Pd2  1  0.000  0.000  0.500  1.0
  Pd  Pd3  1  0.000  0.500  0.000  1.0
  Rh  Rh4  1  0.434  0.784  0.290  1.0
  Rh  Rh5  1  0.566  0.284  0.210  1.0
  Rh  Rh6  1  0.566  0.216  0.710  1.0
  Rh  Rh7  1  0.434  0.716  0.790  1.0
  N  N8  1  0.409  0.744  0.442  1.0
  N  N9  1  0.591  0.244  0.058  1.0
  N  N10  1  0.591  0.256  0.558  1.0
  N  N11  1  0.409  0.756  0.942  1.0
  N  N12  1  0.475  0.734  0.167  1.0
  N  N13  1  0.525  0.234  0.333  1.0
  N  N14  1  0.525  0.266  0.833  1.0
  N  N15  1  0.475  0.766  0.667  1.0
  N  N16  1  0.667  0.764  0.272  1.0
  N  N17  1  0.333  0.264  0.228  1.0
  N  N18  1  0.333  0.236  0.728  1.0
  N  N19  1  0.667  0.736  0.772  1.0
  N  N20  1  0.164  0.726  0.323  1.0
  N  N21  1  0.836  0.226  0.177  1.0
  N  N22  1  0.836  0.274  0.677  1.0
  N  N23  1  0.164  0.774  0.823  1.0
  N  N24  1  0.415  0.937  0.273  1.0
  N  N25  1  0.585  0.437  0.227  1.0
  N  N26  1  0.585  0.063  0.727  1.0
  N  N27  1  0.415  0.563  0.773  1.0
  Cl  Cl28  1  0.947  0.418  0.365  1.0
  Cl  Cl29  1  0.053  0.918  0.135  1.0
  Cl  Cl30  1  0.053  0.582  0.635  1.0
  Cl  Cl31  1  0.947  0.082  0.865  1.0
  Cl  Cl32  1  0.776  0.281  0.577  1.0
  Cl  Cl33  1  0.224  0.781  0.923  1.0
  Cl  Cl34  1  0.224  0.719  0.423  1.0
  Cl  Cl35  1  0.776  0.219  0.077  1.0
  Cl  Cl36  1  0.278  0.026  0.516  1.0
  Cl  Cl37  1  0.722  0.526  0.984  1.0
  Cl  Cl38  1  0.722  0.974  0.484  1.0
  Cl  Cl39  1  0.278  0.474  0.016  1.0
  Cl  Cl40  1  0.996  0.947  0.650  1.0
  Cl  Cl41  1  0.004  0.447  0.850  1.0
  Cl  Cl42  1  0.004  0.053  0.350  1.0
  Cl  Cl43  1  0.996  0.553  0.150  1.0
  Cl  Cl44  1  0.471  0.505  0.303  1.0
  Cl  Cl45  1  0.529  0.005  0.197  1.0
  Cl  Cl46  1  0.529  0.495  0.697  1.0
  Cl  Cl47  1  0.471  0.995  0.803  1.0
  O  O48  1  0.643  0.723  0.185  1.0
  O  O49  1  0.357  0.223  0.315  1.0
  O  O50  1  0.357  0.277  0.815  1.0
  O  O51  1  0.643  0.777  0.685  1.0
[/CIF]
.