The structure described by Sn3(HO2)2 is Indium structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four Sn3(HO2)2 clusters. There are six inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(8) atom. In the second Sn site, Sn(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the third Sn site, Sn(3) is bonded in a distorted T-shaped geometry to one O(3), one O(6), and one O(7) atom. In the fourth Sn site, Sn(4) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(7), and one O(8) atom. In the fifth Sn site, Sn(5) is bonded in a distorted T-shaped geometry to one O(1), one O(5), and one O(7) atom. In the sixth Sn site, Sn(6) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Sn(1), one Sn(4), one Sn(5), and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sn(1), one Sn(2), one Sn(6), and one H(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sn(2), one Sn(3), and one H(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sn(4), one Sn(6), and one H(4) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(2), and one Sn(5) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Sn(2), one Sn(3), and one Sn(6) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Sn(3), one Sn(4), and one Sn(5) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(4), and one Sn(6) atom. is represented by the CIF card [CIF]
data_Sn3(HO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.382
_cell_length_b   8.382
_cell_length_c   9.635
_cell_angle_alpha   86.570
_cell_angle_beta   86.570
_cell_angle_gamma   91.085
_symmetry_Int_Tables_number   1
_cell_volume   674.313
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.611  0.706  0.513  1.0
  Sn  Sn1  1  0.867  0.226  0.033  1.0
  Sn  Sn2  1  0.352  0.250  0.451  1.0
  Sn  Sn3  1  0.116  0.786  0.996  1.0
  Sn  Sn4  1  0.226  0.867  0.533  1.0
  Sn  Sn5  1  0.706  0.611  0.013  1.0
  Sn  Sn6  1  0.786  0.116  0.496  1.0
  Sn  Sn7  1  0.250  0.352  0.951  1.0
  Sn  Sn8  1  0.547  0.972  0.232  1.0
  Sn  Sn9  1  0.995  0.506  0.266  1.0
  Sn  Sn10  1  0.506  0.995  0.766  1.0
  Sn  Sn11  1  0.972  0.547  0.732  1.0
  H  H12  1  0.823  0.823  0.255  1.0
  H  H13  1  0.673  0.340  0.249  1.0
  H  H14  1  0.247  0.025  0.276  1.0
  H  H15  1  0.293  0.569  0.137  1.0
  H  H16  1  0.340  0.673  0.749  1.0
  H  H17  1  0.823  0.823  0.755  1.0
  H  H18  1  0.569  0.293  0.637  1.0
  H  H19  1  0.025  0.247  0.776  1.0
  O  O20  1  0.751  0.874  0.325  1.0
  O  O21  1  0.748  0.403  0.182  1.0
  O  O22  1  0.205  0.076  0.359  1.0
  O  O23  1  0.217  0.647  0.170  1.0
  O  O24  1  0.403  0.748  0.682  1.0
  O  O25  1  0.874  0.751  0.825  1.0
  O  O26  1  0.647  0.217  0.670  1.0
  O  O27  1  0.076  0.205  0.859  1.0
  O  O28  1  0.435  0.828  0.403  1.0
  O  O29  1  0.070  0.341  0.114  1.0
  O  O30  1  0.579  0.168  0.366  1.0
  O  O31  1  0.909  0.691  0.119  1.0
  O  O32  1  0.341  0.070  0.614  1.0
  O  O33  1  0.828  0.435  0.903  1.0
  O  O34  1  0.691  0.909  0.619  1.0
  O  O35  1  0.168  0.579  0.866  1.0
[/CIF]
.
The structure described by Sn3(HO2)2 is Indium structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four Sn3(HO2)2 clusters. There are six inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(8) atom. In the second Sn site, Sn(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the third Sn site, Sn(3) is bonded in a distorted T-shaped geometry to one O(3), one O(6), and one O(7) atom. In the fourth Sn site, Sn(4) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(7), and one O(8) atom. In the fifth Sn site, Sn(5) is bonded in a distorted T-shaped geometry to one O(1), one O(5), and one O(7) atom. In the sixth Sn site, Sn(6) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Sn(1), one Sn(4), one Sn(5), and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sn(1), one Sn(2), one Sn(6), and one H(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sn(2), one Sn(3), and one H(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sn(4), one Sn(6), and one H(4) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(2), and one Sn(5) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Sn(2), one Sn(3), and one Sn(6) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Sn(3), one Sn(4), and one Sn(5) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(4), and one Sn(6) atom. is represented by the CIF card [CIF]
data_Sn3(HO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.382
_cell_length_b   8.382
_cell_length_c   9.635
_cell_angle_alpha   86.570
_cell_angle_beta   86.570
_cell_angle_gamma   91.085
_symmetry_Int_Tables_number   1
_cell_volume   674.313
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.611  0.706  0.513  1.0
  Sn  Sn1  1  0.867  0.226  0.033  1.0
  Sn  Sn2  1  0.352  0.250  0.451  1.0
  Sn  Sn3  1  0.116  0.786  0.996  1.0
  Sn  Sn4  1  0.226  0.867  0.533  1.0
  Sn  Sn5  1  0.706  0.611  0.013  1.0
  Sn  Sn6  1  0.786  0.116  0.496  1.0
  Sn  Sn7  1  0.250  0.352  0.951  1.0
  Sn  Sn8  1  0.547  0.972  0.232  1.0
  Sn  Sn9  1  0.995  0.506  0.266  1.0
  Sn  Sn10  1  0.506  0.995  0.766  1.0
  Sn  Sn11  1  0.972  0.547  0.732  1.0
  H  H12  1  0.823  0.823  0.255  1.0
  H  H13  1  0.673  0.340  0.249  1.0
  H  H14  1  0.247  0.025  0.276  1.0
  H  H15  1  0.293  0.569  0.137  1.0
  H  H16  1  0.340  0.673  0.749  1.0
  H  H17  1  0.823  0.823  0.755  1.0
  H  H18  1  0.569  0.293  0.637  1.0
  H  H19  1  0.025  0.247  0.776  1.0
  O  O20  1  0.751  0.874  0.325  1.0
  O  O21  1  0.748  0.403  0.182  1.0
  O  O22  1  0.205  0.076  0.359  1.0
  O  O23  1  0.217  0.647  0.170  1.0
  O  O24  1  0.403  0.748  0.682  1.0
  O  O25  1  0.874  0.751  0.825  1.0
  O  O26  1  0.647  0.217  0.670  1.0
  O  O27  1  0.076  0.205  0.859  1.0
  O  O28  1  0.435  0.828  0.403  1.0
  O  O29  1  0.070  0.341  0.114  1.0
  O  O30  1  0.579  0.168  0.366  1.0
  O  O31  1  0.909  0.691  0.119  1.0
  O  O32  1  0.341  0.070  0.614  1.0
  O  O33  1  0.828  0.435  0.903  1.0
  O  O34  1  0.691  0.909  0.619  1.0
  O  O35  1  0.168  0.579  0.866  1.0
[/CIF]
.