The structure described by UMo2O8 crystallizes in the orthorhombic Pban space group. U(1) is bonded to two equivalent O(1) and four equivalent O(5) atoms to form a mixture of distorted corner and edge-sharing UO6 octahedra. The corner-sharing octahedral tilt angles are 4°. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the second O site, O(1) is bonded in a linear geometry to two equivalent U(1) atoms. In the third O site, O(2) is bonded in a linear geometry to two equivalent Mo(1) atoms. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(1) atoms. In the fifth O site, O(4) is bonded in a linear geometry to two equivalent Mo(1) atoms. In the sixth O site, O(5) is bonded in a trigonal planar geometry to two equivalent U(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_U(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.145
_cell_length_b   7.581
_cell_length_c   10.193
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   320.269
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.914  0.250  0.183  1.0
  Mo  Mo1  1  0.914  0.750  0.817  1.0
  Mo  Mo2  1  0.086  0.250  0.817  1.0
  Mo  Mo3  1  0.086  0.750  0.183  1.0
  O  O4  1  0.500  0.500  0.500  1.0
  O  O5  1  0.500  0.000  0.500  1.0
  O  O6  1  0.000  0.750  0.000  1.0
  O  O7  1  0.000  0.250  0.000  1.0
  O  O8  1  0.000  0.500  0.213  1.0
  O  O9  1  0.000  0.500  0.787  1.0
  O  O10  1  0.000  0.000  0.787  1.0
  O  O11  1  0.000  0.000  0.213  1.0
  O  O12  1  0.011  0.750  0.380  1.0
  O  O13  1  0.011  0.250  0.620  1.0
  O  O14  1  0.989  0.750  0.620  1.0
  O  O15  1  0.989  0.250  0.380  1.0
  O  O16  1  0.495  0.250  0.180  1.0
  O  O17  1  0.495  0.750  0.820  1.0
  O  O18  1  0.505  0.250  0.820  1.0
  O  O19  1  0.505  0.750  0.180  1.0
  U  U20  1  0.000  0.500  0.500  1.0
  U  U21  1  0.000  0.000  0.500  1.0
[/CIF]
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The structure described by UMo2O8 crystallizes in the orthorhombic Pban space group. U(1) is bonded to two equivalent O(1) and four equivalent O(5) atoms to form a mixture of distorted corner and edge-sharing UO6 octahedra. The corner-sharing octahedral tilt angles are 4°. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the second O site, O(1) is bonded in a linear geometry to two equivalent U(1) atoms. In the third O site, O(2) is bonded in a linear geometry to two equivalent Mo(1) atoms. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(1) atoms. In the fifth O site, O(4) is bonded in a linear geometry to two equivalent Mo(1) atoms. In the sixth O site, O(5) is bonded in a trigonal planar geometry to two equivalent U(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_U(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.145
_cell_length_b   7.581
_cell_length_c   10.193
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   320.269
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.914  0.250  0.183  1.0
  Mo  Mo1  1  0.914  0.750  0.817  1.0
  Mo  Mo2  1  0.086  0.250  0.817  1.0
  Mo  Mo3  1  0.086  0.750  0.183  1.0
  O  O4  1  0.500  0.500  0.500  1.0
  O  O5  1  0.500  0.000  0.500  1.0
  O  O6  1  0.000  0.750  0.000  1.0
  O  O7  1  0.000  0.250  0.000  1.0
  O  O8  1  0.000  0.500  0.213  1.0
  O  O9  1  0.000  0.500  0.787  1.0
  O  O10  1  0.000  0.000  0.787  1.0
  O  O11  1  0.000  0.000  0.213  1.0
  O  O12  1  0.011  0.750  0.380  1.0
  O  O13  1  0.011  0.250  0.620  1.0
  O  O14  1  0.989  0.750  0.620  1.0
  O  O15  1  0.989  0.250  0.380  1.0
  O  O16  1  0.495  0.250  0.180  1.0
  O  O17  1  0.495  0.750  0.820  1.0
  O  O18  1  0.505  0.250  0.820  1.0
  O  O19  1  0.505  0.750  0.180  1.0
  U  U20  1  0.000  0.500  0.500  1.0
  U  U21  1  0.000  0.000  0.500  1.0
[/CIF]
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