The material described by ONS2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ONS2 clusters. In two of the ONS2 clusters, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(2) atom. In the second S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one O(2) atom. O(2) is bonded in a single-bond geometry to one S(3) atom. In two of the ONS2 clusters, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the second S site, S(4) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one S(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S2NO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.494
_cell_length_b   8.164
_cell_length_c   10.820
_cell_angle_alpha   108.360
_cell_angle_beta   92.625
_cell_angle_gamma   103.493
_symmetry_Int_Tables_number   1
_cell_volume   363.265
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.270  0.985  0.648  1.0
  S  S1  1  0.999  0.190  0.276  1.0
  S  S2  1  0.001  0.810  0.724  1.0
  S  S3  1  0.720  0.655  0.319  1.0
  S  S4  1  0.108  0.746  0.964  1.0
  S  S5  1  0.892  0.254  0.036  1.0
  S  S6  1  0.280  0.345  0.681  1.0
  S  S7  1  0.730  0.015  0.352  1.0
  N  N8  1  0.205  0.850  0.868  1.0
  N  N9  1  0.163  0.173  0.715  1.0
  N  N10  1  0.837  0.827  0.285  1.0
  N  N11  1  0.795  0.150  0.132  1.0
  O  O12  1  0.816  0.604  0.925  1.0
  O  O13  1  0.505  0.657  0.418  1.0
  O  O14  1  0.184  0.396  0.075  1.0
  O  O15  1  0.495  0.343  0.582  1.0
[/CIF]
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The material described by ONS2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ONS2 clusters. In two of the ONS2 clusters, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(2) atom. In the second S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one O(2) atom. O(2) is bonded in a single-bond geometry to one S(3) atom. In two of the ONS2 clusters, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the second S site, S(4) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one S(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S2NO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.494
_cell_length_b   8.164
_cell_length_c   10.820
_cell_angle_alpha   108.360
_cell_angle_beta   92.625
_cell_angle_gamma   103.493
_symmetry_Int_Tables_number   1
_cell_volume   363.265
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.270  0.985  0.648  1.0
  S  S1  1  0.999  0.190  0.276  1.0
  S  S2  1  0.001  0.810  0.724  1.0
  S  S3  1  0.720  0.655  0.319  1.0
  S  S4  1  0.108  0.746  0.964  1.0
  S  S5  1  0.892  0.254  0.036  1.0
  S  S6  1  0.280  0.345  0.681  1.0
  S  S7  1  0.730  0.015  0.352  1.0
  N  N8  1  0.205  0.850  0.868  1.0
  N  N9  1  0.163  0.173  0.715  1.0
  N  N10  1  0.837  0.827  0.285  1.0
  N  N11  1  0.795  0.150  0.132  1.0
  O  O12  1  0.816  0.604  0.925  1.0
  O  O13  1  0.505  0.657  0.418  1.0
  O  O14  1  0.184  0.396  0.075  1.0
  O  O15  1  0.495  0.343  0.582  1.0
[/CIF]
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