The crystal structure described by Sr10Mn5Zn9(AsO)10 crystallizes in the triclinic P1 space group. There are ten inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 3-coordinate geometry to one As(3), one As(8), one O(2), one O(5), and one O(7) atom. In the second Sr site, Sr(2) is bonded in a distorted water-like geometry to one As(5), one As(8), one O(4), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a 2-coordinate geometry to one Zn(1), one As(1), one As(2), one As(4), one As(9), one O(4), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a 3-coordinate geometry to one As(2), one As(6), one As(7), one O(1), one O(6), and one O(9) atom. In the fifth Sr site, Sr(5) is bonded in a 3-coordinate geometry to one As(2), one As(6), one As(8), one O(1), one O(10), and one O(6) atom. In the sixth Sr site, Sr(6) is bonded in a 3-coordinate geometry to one As(4), one As(9), one O(10), one O(2), and one O(7) atom. In the seventh Sr site, Sr(7) is bonded in a 2-coordinate geometry to one Zn(4), one As(2), one As(3), one As(4), one As(5), one As(9), one O(3), and one O(8) atom. In the eighth Sr site, Sr(8) is bonded in a 3-coordinate geometry to one Zn(1), one As(5), one As(6), one O(4), one O(5), and one O(9) atom. In the ninth Sr site, Sr(9) is bonded in a 2-coordinate geometry to one As(5), one As(6), one As(7), one O(2), and one O(5) atom. In the tenth Sr site, Sr(10) is bonded in a 2-coordinate geometry to one Zn(4), one As(3), one As(6), one As(7), one O(2), and one O(7) atom. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 2-coordinate geometry to one As(2), one As(7), one O(1), and one O(3) atom. In the second Mn site, Mn(2) is bonded in a distorted T-shaped geometry to one As(1), one O(1), one O(10), and one O(2) atom. In the third Mn site, Mn(3) is bonded in a distorted water-like geometry to one Zn(4), one As(1), one O(4), and one O(7) atom. In the fourth Mn site, Mn(4) is bonded in a 3-coordinate geometry to one As(7), one O(5), one O(6), and one O(9) atom. In the fifth Mn site, Mn(5) is bonded in a distorted linear geometry to one As(3), one As(8), one As(9), one O(10), and one O(8) atom. There are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(8), one Zn(9), one As(2), one As(4), and one As(9) atom. In the second Zn site, Zn(2) is bonded in a distorted single-bond geometry to one As(10), one As(3), one As(6), and one O(5) atom. In the third Zn site, Zn(3) is bonded in a distorted single-bond geometry to one As(1), one As(10), and one O(8) atom. In the fourth Zn site, Zn(4) is bonded in a 7-coordinate geometry to one Sr(10), one Sr(7), one Mn(3), one Zn(8), one As(3), one As(5), and one As(8) atom. In the fifth Zn site, Zn(5) is bonded in a 3-coordinate geometry to one As(2), one As(4), one As(5), and one As(6) atom. In the sixth Zn site, Zn(6) is bonded in a distorted trigonal planar geometry to one As(5), one As(7), and one As(9) atom. In the seventh Zn site, Zn(7) is bonded in a distorted trigonal pyramidal geometry to one As(1), one As(10), one As(7), and one O(1) atom. In the eighth Zn site, Zn(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one As(1), one As(8), and one As(9) atom. In the ninth Zn site, Zn(9) is bonded in a distorted single-bond geometry to one Zn(1), one As(10), one As(7), and one O(3) atom. There are ten inequivalent As sites. In the first As site, As(1) is bonded in a 6-coordinate geometry to one Sr(3), one Mn(2), one Mn(3), one Zn(3), one Zn(7), and one Zn(8) atom. In the second As site, As(2) is bonded in a 8-coordinate geometry to one Sr(3), one Sr(4), one Sr(5), one Sr(7), one Mn(1), one Zn(1), one Zn(5), and one As(4) atom. In the third As site, As(3) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(10), one Sr(7), one Mn(5), one Zn(2), and one Zn(4) atom. In the fourth As site, As(4) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(6), one Sr(7), one Zn(1), one Zn(5), and one As(2) atom. In the fifth As site, As(5) is bonded in a 7-coordinate geometry to one Sr(2), one Sr(7), one Sr(8), one Sr(9), one Zn(4), one Zn(5), and one Zn(6) atom. In the sixth As site, As(6) is bonded in a 7-coordinate geometry to one Sr(10), one Sr(4), one Sr(5), one Sr(8), one Sr(9), one Zn(2), and one Zn(5) atom. In the seventh As site, As(7) is bonded in a 8-coordinate geometry to one Sr(10), one Sr(4), one Sr(9), one Mn(1), one Mn(4), one Zn(6), one Zn(7), and one Zn(9) atom. In the eighth As site, As(8) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(5), one Mn(5), one Zn(4), and one Zn(8) atom. In the ninth As site, As(9) is bonded to one Sr(3), one Sr(6), one Sr(7), one Mn(5), one Zn(1), one Zn(6), and one Zn(8) atom to form distorted AsSr3MnZn3 pentagonal bipyramids that share  a cornercorner with one O(4)Sr3Mn tetrahedra,  a cornercorner with one O(9)Sr3Mn tetrahedra,  a cornercorner with one O(2)Sr4Mn trigonal bipyramid, and  an edgeedge with one O(8)Sr2MnZn trigonal pyramid. In the tenth As site, As(10) is bonded in a 4-coordinate geometry to one Zn(2), one Zn(3), one Zn(7), and one Zn(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Sr(4), one Sr(5), one Mn(1), one Mn(2), and one Zn(7) atom. In the second O site, O(2) is bonded to one Sr(1), one Sr(10), one Sr(6), one Sr(9), and one Mn(2) atom to form distorted OSr4Mn trigonal bipyramids that share  a cornercorner with one As(9)Sr3MnZn3 pentagonal bipyramid and  an edgeedge with one O(5)Sr3MnZn trigonal bipyramid. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sr(7), one Mn(1), and one Zn(9) atom. In the fourth O site, O(4) is bonded to one Sr(2), one Sr(3), one Sr(8), and one Mn(3) atom to form distorted OSr3Mn tetrahedra that share  a cornercorner with one As(9)Sr3MnZn3 pentagonal bipyramid,  a cornercorner with one O(5)Sr3MnZn trigonal bipyramid,  a cornercorner with one O(8)Sr2MnZn trigonal pyramid, and  an edgeedge with one O(9)Sr3Mn tetrahedra. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(8), one Sr(9), one Mn(4), and one Zn(2) atom to form distorted OSr3MnZn trigonal bipyramids that share  a cornercorner with one O(4)Sr3Mn tetrahedra,  an edgeedge with one O(9)Sr3Mn tetrahedra, and  an edgeedge with one O(2)Sr4Mn trigonal bipyramid. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Sr(4), one Sr(5), and one Mn(4) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(10), one Sr(6), and one Mn(3) atom. In the eighth O site, O(8) is bonded to one Sr(2), one Sr(7), one Mn(5), and one Zn(3) atom to form distorted OSr2MnZn trigonal pyramids that share  a cornercorner with one O(4)Sr3Mn tetrahedra and  an edgeedge with one As(9)Sr3MnZn3 pentagonal bipyramid. In the ninth O site, O(9) is bonded to one Sr(3), one Sr(4), one Sr(8), and one Mn(4) atom to form distorted OSr3Mn tetrahedra that share  a cornercorner with one As(9)Sr3MnZn3 pentagonal bipyramid,  an edgeedge with one O(4)Sr3Mn tetrahedra, and  an edgeedge with one O(5)Sr3MnZn trigonal bipyramid. In the tenth O site, O(10) is bonded in a distorted square co-planar geometry to one Sr(5), one Sr(6), one Mn(2), and one Mn(5) atom. is represented by the CIF file [CIF]
data_Sr10Mn5Zn9(AsO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   26.342
_cell_length_b   12.430
_cell_length_c   11.901
_cell_angle_alpha   43.641
_cell_angle_beta   32.971
_cell_angle_gamma   25.825
_symmetry_Int_Tables_number   1
_cell_volume   915.636
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.471  0.415  0.117  1.0
  Sr  Sr1  1  0.643  0.331  0.145  1.0
  Sr  Sr2  1  0.824  0.465  0.766  1.0
  Sr  Sr3  1  0.708  0.627  0.173  1.0
  Sr  Sr4  1  0.004  0.488  0.826  1.0
  Sr  Sr5  1  0.184  0.120  0.167  1.0
  Sr  Sr6  1  0.122  0.720  0.892  1.0
  Sr  Sr7  1  0.428  0.088  0.087  1.0
  Sr  Sr8  1  0.352  0.608  0.903  1.0
  Sr  Sr9  1  0.461  0.818  0.707  1.0
  Mn  Mn10  1  0.016  0.018  0.122  1.0
  Mn  Mn11  1  0.069  0.127  0.158  1.0
  Mn  Mn12  1  0.564  0.744  0.836  1.0
  Mn  Mn13  1  0.680  0.988  0.836  1.0
  Mn  Mn14  1  0.977  0.669  0.004  1.0
  Zn  Zn15  1  0.076  0.384  0.455  1.0
  Zn  Zn16  1  0.324  0.290  0.396  1.0
  Zn  Zn17  1  0.989  0.937  0.666  1.0
  Zn  Zn18  1  0.486  0.127  0.584  1.0
  Zn  Zn19  1  0.363  0.776  0.514  1.0
  Zn  Zn20  1  0.713  0.082  0.481  1.0
  Zn  Zn21  1  0.837  0.198  0.513  1.0
  Zn  Zn22  1  0.756  0.758  0.433  1.0
  Zn  Zn23  1  0.005  0.721  0.419  1.0
  As  As24  1  0.838  0.365  0.552  1.0
  As  As25  1  0.025  0.179  0.819  1.0
  As  As26  1  0.277  0.384  0.634  1.0
  As  As27  1  0.213  0.956  0.483  1.0
  As  As28  1  0.475  0.356  0.623  1.0
  As  As29  1  0.370  0.950  0.523  1.0
  As  As30  1  0.718  0.236  0.541  1.0
  As  As31  1  0.718  0.928  0.189  1.0
  As  As32  1  0.929  0.659  0.328  1.0
  As  As33  1  0.087  0.754  0.429  1.0
  O  O34  1  0.933  0.296  0.150  1.0
  O  O35  1  0.277  0.842  0.043  1.0
  O  O36  1  0.135  0.697  0.098  1.0
  O  O37  1  0.577  0.697  0.004  1.0
  O  O38  1  0.457  0.270  0.079  1.0
  O  O39  1  0.753  0.847  0.945  1.0
  O  O40  1  0.462  0.710  0.979  1.0
  O  O41  1  0.921  0.962  0.922  1.0
  O  O42  1  0.677  0.791  0.925  1.0
  O  O43  1  0.057  0.370  0.034  1.0
[/CIF]
.
The crystal structure described by Sr10Mn5Zn9(AsO)10 crystallizes in the triclinic P1 space group. There are ten inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 3-coordinate geometry to one As(3), one As(8), one O(2), one O(5), and one O(7) atom. In the second Sr site, Sr(2) is bonded in a distorted water-like geometry to one As(5), one As(8), one O(4), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a 2-coordinate geometry to one Zn(1), one As(1), one As(2), one As(4), one As(9), one O(4), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a 3-coordinate geometry to one As(2), one As(6), one As(7), one O(1), one O(6), and one O(9) atom. In the fifth Sr site, Sr(5) is bonded in a 3-coordinate geometry to one As(2), one As(6), one As(8), one O(1), one O(10), and one O(6) atom. In the sixth Sr site, Sr(6) is bonded in a 3-coordinate geometry to one As(4), one As(9), one O(10), one O(2), and one O(7) atom. In the seventh Sr site, Sr(7) is bonded in a 2-coordinate geometry to one Zn(4), one As(2), one As(3), one As(4), one As(5), one As(9), one O(3), and one O(8) atom. In the eighth Sr site, Sr(8) is bonded in a 3-coordinate geometry to one Zn(1), one As(5), one As(6), one O(4), one O(5), and one O(9) atom. In the ninth Sr site, Sr(9) is bonded in a 2-coordinate geometry to one As(5), one As(6), one As(7), one O(2), and one O(5) atom. In the tenth Sr site, Sr(10) is bonded in a 2-coordinate geometry to one Zn(4), one As(3), one As(6), one As(7), one O(2), and one O(7) atom. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 2-coordinate geometry to one As(2), one As(7), one O(1), and one O(3) atom. In the second Mn site, Mn(2) is bonded in a distorted T-shaped geometry to one As(1), one O(1), one O(10), and one O(2) atom. In the third Mn site, Mn(3) is bonded in a distorted water-like geometry to one Zn(4), one As(1), one O(4), and one O(7) atom. In the fourth Mn site, Mn(4) is bonded in a 3-coordinate geometry to one As(7), one O(5), one O(6), and one O(9) atom. In the fifth Mn site, Mn(5) is bonded in a distorted linear geometry to one As(3), one As(8), one As(9), one O(10), and one O(8) atom. There are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(8), one Zn(9), one As(2), one As(4), and one As(9) atom. In the second Zn site, Zn(2) is bonded in a distorted single-bond geometry to one As(10), one As(3), one As(6), and one O(5) atom. In the third Zn site, Zn(3) is bonded in a distorted single-bond geometry to one As(1), one As(10), and one O(8) atom. In the fourth Zn site, Zn(4) is bonded in a 7-coordinate geometry to one Sr(10), one Sr(7), one Mn(3), one Zn(8), one As(3), one As(5), and one As(8) atom. In the fifth Zn site, Zn(5) is bonded in a 3-coordinate geometry to one As(2), one As(4), one As(5), and one As(6) atom. In the sixth Zn site, Zn(6) is bonded in a distorted trigonal planar geometry to one As(5), one As(7), and one As(9) atom. In the seventh Zn site, Zn(7) is bonded in a distorted trigonal pyramidal geometry to one As(1), one As(10), one As(7), and one O(1) atom. In the eighth Zn site, Zn(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one As(1), one As(8), and one As(9) atom. In the ninth Zn site, Zn(9) is bonded in a distorted single-bond geometry to one Zn(1), one As(10), one As(7), and one O(3) atom. There are ten inequivalent As sites. In the first As site, As(1) is bonded in a 6-coordinate geometry to one Sr(3), one Mn(2), one Mn(3), one Zn(3), one Zn(7), and one Zn(8) atom. In the second As site, As(2) is bonded in a 8-coordinate geometry to one Sr(3), one Sr(4), one Sr(5), one Sr(7), one Mn(1), one Zn(1), one Zn(5), and one As(4) atom. In the third As site, As(3) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(10), one Sr(7), one Mn(5), one Zn(2), and one Zn(4) atom. In the fourth As site, As(4) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(6), one Sr(7), one Zn(1), one Zn(5), and one As(2) atom. In the fifth As site, As(5) is bonded in a 7-coordinate geometry to one Sr(2), one Sr(7), one Sr(8), one Sr(9), one Zn(4), one Zn(5), and one Zn(6) atom. In the sixth As site, As(6) is bonded in a 7-coordinate geometry to one Sr(10), one Sr(4), one Sr(5), one Sr(8), one Sr(9), one Zn(2), and one Zn(5) atom. In the seventh As site, As(7) is bonded in a 8-coordinate geometry to one Sr(10), one Sr(4), one Sr(9), one Mn(1), one Mn(4), one Zn(6), one Zn(7), and one Zn(9) atom. In the eighth As site, As(8) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(5), one Mn(5), one Zn(4), and one Zn(8) atom. In the ninth As site, As(9) is bonded to one Sr(3), one Sr(6), one Sr(7), one Mn(5), one Zn(1), one Zn(6), and one Zn(8) atom to form distorted AsSr3MnZn3 pentagonal bipyramids that share  a cornercorner with one O(4)Sr3Mn tetrahedra,  a cornercorner with one O(9)Sr3Mn tetrahedra,  a cornercorner with one O(2)Sr4Mn trigonal bipyramid, and  an edgeedge with one O(8)Sr2MnZn trigonal pyramid. In the tenth As site, As(10) is bonded in a 4-coordinate geometry to one Zn(2), one Zn(3), one Zn(7), and one Zn(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Sr(4), one Sr(5), one Mn(1), one Mn(2), and one Zn(7) atom. In the second O site, O(2) is bonded to one Sr(1), one Sr(10), one Sr(6), one Sr(9), and one Mn(2) atom to form distorted OSr4Mn trigonal bipyramids that share  a cornercorner with one As(9)Sr3MnZn3 pentagonal bipyramid and  an edgeedge with one O(5)Sr3MnZn trigonal bipyramid. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sr(7), one Mn(1), and one Zn(9) atom. In the fourth O site, O(4) is bonded to one Sr(2), one Sr(3), one Sr(8), and one Mn(3) atom to form distorted OSr3Mn tetrahedra that share  a cornercorner with one As(9)Sr3MnZn3 pentagonal bipyramid,  a cornercorner with one O(5)Sr3MnZn trigonal bipyramid,  a cornercorner with one O(8)Sr2MnZn trigonal pyramid, and  an edgeedge with one O(9)Sr3Mn tetrahedra. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(8), one Sr(9), one Mn(4), and one Zn(2) atom to form distorted OSr3MnZn trigonal bipyramids that share  a cornercorner with one O(4)Sr3Mn tetrahedra,  an edgeedge with one O(9)Sr3Mn tetrahedra, and  an edgeedge with one O(2)Sr4Mn trigonal bipyramid. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Sr(4), one Sr(5), and one Mn(4) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(10), one Sr(6), and one Mn(3) atom. In the eighth O site, O(8) is bonded to one Sr(2), one Sr(7), one Mn(5), and one Zn(3) atom to form distorted OSr2MnZn trigonal pyramids that share  a cornercorner with one O(4)Sr3Mn tetrahedra and  an edgeedge with one As(9)Sr3MnZn3 pentagonal bipyramid. In the ninth O site, O(9) is bonded to one Sr(3), one Sr(4), one Sr(8), and one Mn(4) atom to form distorted OSr3Mn tetrahedra that share  a cornercorner with one As(9)Sr3MnZn3 pentagonal bipyramid,  an edgeedge with one O(4)Sr3Mn tetrahedra, and  an edgeedge with one O(5)Sr3MnZn trigonal bipyramid. In the tenth O site, O(10) is bonded in a distorted square co-planar geometry to one Sr(5), one Sr(6), one Mn(2), and one Mn(5) atom. is represented by the CIF file [CIF]
data_Sr10Mn5Zn9(AsO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   26.342
_cell_length_b   12.430
_cell_length_c   11.901
_cell_angle_alpha   43.641
_cell_angle_beta   32.971
_cell_angle_gamma   25.825
_symmetry_Int_Tables_number   1
_cell_volume   915.636
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.471  0.415  0.117  1.0
  Sr  Sr1  1  0.643  0.331  0.145  1.0
  Sr  Sr2  1  0.824  0.465  0.766  1.0
  Sr  Sr3  1  0.708  0.627  0.173  1.0
  Sr  Sr4  1  0.004  0.488  0.826  1.0
  Sr  Sr5  1  0.184  0.120  0.167  1.0
  Sr  Sr6  1  0.122  0.720  0.892  1.0
  Sr  Sr7  1  0.428  0.088  0.087  1.0
  Sr  Sr8  1  0.352  0.608  0.903  1.0
  Sr  Sr9  1  0.461  0.818  0.707  1.0
  Mn  Mn10  1  0.016  0.018  0.122  1.0
  Mn  Mn11  1  0.069  0.127  0.158  1.0
  Mn  Mn12  1  0.564  0.744  0.836  1.0
  Mn  Mn13  1  0.680  0.988  0.836  1.0
  Mn  Mn14  1  0.977  0.669  0.004  1.0
  Zn  Zn15  1  0.076  0.384  0.455  1.0
  Zn  Zn16  1  0.324  0.290  0.396  1.0
  Zn  Zn17  1  0.989  0.937  0.666  1.0
  Zn  Zn18  1  0.486  0.127  0.584  1.0
  Zn  Zn19  1  0.363  0.776  0.514  1.0
  Zn  Zn20  1  0.713  0.082  0.481  1.0
  Zn  Zn21  1  0.837  0.198  0.513  1.0
  Zn  Zn22  1  0.756  0.758  0.433  1.0
  Zn  Zn23  1  0.005  0.721  0.419  1.0
  As  As24  1  0.838  0.365  0.552  1.0
  As  As25  1  0.025  0.179  0.819  1.0
  As  As26  1  0.277  0.384  0.634  1.0
  As  As27  1  0.213  0.956  0.483  1.0
  As  As28  1  0.475  0.356  0.623  1.0
  As  As29  1  0.370  0.950  0.523  1.0
  As  As30  1  0.718  0.236  0.541  1.0
  As  As31  1  0.718  0.928  0.189  1.0
  As  As32  1  0.929  0.659  0.328  1.0
  As  As33  1  0.087  0.754  0.429  1.0
  O  O34  1  0.933  0.296  0.150  1.0
  O  O35  1  0.277  0.842  0.043  1.0
  O  O36  1  0.135  0.697  0.098  1.0
  O  O37  1  0.577  0.697  0.004  1.0
  O  O38  1  0.457  0.270  0.079  1.0
  O  O39  1  0.753  0.847  0.945  1.0
  O  O40  1  0.462  0.710  0.979  1.0
  O  O41  1  0.921  0.962  0.922  1.0
  O  O42  1  0.677  0.791  0.925  1.0
  O  O43  1  0.057  0.370  0.034  1.0
[/CIF]
.