The structure described by BaSrWCoO6 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Imm2 space group. Ba(1) is bonded to two equivalent O(2), two equivalent O(3), and eight equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Co(1)O6 octahedra. Sr(1) is bonded to two equivalent O(2), two equivalent O(3), and eight equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Co(1)O6 octahedra. W(1) is bonded to one O(2), one O(3), and four equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Co(1) is bonded to one O(2), one O(3), and four equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ba(1), two equivalent Sr(1), one W(1), and one Co(1) atom to form a mixture of distorted corner, face, and edge-sharing OBa2Sr2CoW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the second O site, O(2) is bonded to two equivalent Ba(1), two equivalent Sr(1), one W(1), and one Co(1) atom to form a mixture of distorted corner, face, and edge-sharing OBa2Sr2CoW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the third O site, O(3) is bonded to two equivalent Ba(1), two equivalent Sr(1), one W(1), and one Co(1) atom to form a mixture of distorted corner, face, and edge-sharing OBa2Sr2CoW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF file [CIF]
data_BaSrCoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.761
_cell_length_b   5.759
_cell_length_c   5.758
_cell_angle_alpha   59.946
_cell_angle_beta   59.970
_cell_angle_gamma   89.770
_symmetry_Int_Tables_number   1
_cell_volume   135.184
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.749  0.251  0.500  1.0
  Sr  Sr1  1  0.251  0.750  0.500  1.0
  Co  Co2  1  0.500  0.500  0.000  1.0
  W  W3  1  0.000  1.000  1.000  1.0
  O  O4  1  0.760  0.760  0.479  1.0
  O  O5  1  0.761  0.761  1.000  1.0
  O  O6  1  0.241  0.759  0.000  1.0
  O  O7  1  0.240  0.240  0.520  1.0
  O  O8  1  0.239  0.239  0.000  1.0
  O  O9  1  0.759  0.241  1.000  1.0
[/CIF]
.
The structure described by BaSrWCoO6 is (Cubic) Perovskite-derived structured and crystallizes in the orthorhombic Imm2 space group. Ba(1) is bonded to two equivalent O(2), two equivalent O(3), and eight equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Co(1)O6 octahedra. Sr(1) is bonded to two equivalent O(2), two equivalent O(3), and eight equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Co(1)O6 octahedra. W(1) is bonded to one O(2), one O(3), and four equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Co(1) is bonded to one O(2), one O(3), and four equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ba(1), two equivalent Sr(1), one W(1), and one Co(1) atom to form a mixture of distorted corner, face, and edge-sharing OBa2Sr2CoW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the second O site, O(2) is bonded to two equivalent Ba(1), two equivalent Sr(1), one W(1), and one Co(1) atom to form a mixture of distorted corner, face, and edge-sharing OBa2Sr2CoW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the third O site, O(3) is bonded to two equivalent Ba(1), two equivalent Sr(1), one W(1), and one Co(1) atom to form a mixture of distorted corner, face, and edge-sharing OBa2Sr2CoW octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF file [CIF]
data_BaSrCoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.761
_cell_length_b   5.759
_cell_length_c   5.758
_cell_angle_alpha   59.946
_cell_angle_beta   59.970
_cell_angle_gamma   89.770
_symmetry_Int_Tables_number   1
_cell_volume   135.184
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.749  0.251  0.500  1.0
  Sr  Sr1  1  0.251  0.750  0.500  1.0
  Co  Co2  1  0.500  0.500  0.000  1.0
  W  W3  1  0.000  1.000  1.000  1.0
  O  O4  1  0.760  0.760  0.479  1.0
  O  O5  1  0.761  0.761  1.000  1.0
  O  O6  1  0.241  0.759  0.000  1.0
  O  O7  1  0.240  0.240  0.520  1.0
  O  O8  1  0.239  0.239  0.000  1.0
  O  O9  1  0.759  0.241  1.000  1.0
[/CIF]
.