The crystal structure described by (BiN3O11)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trioxidane molecules and two BiN3O11 clusters. In each BiN3O11 cluster, Bi(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(12), one O(13), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one Bi(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Bi(1) and one N(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(4) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(2) atom. In the sixth O site, O(5) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(2) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the eighth O site, O(7) is bonded in a distorted single-bond geometry to one Bi(1) and one N(3) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one Bi(1) and one N(3) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the eleventh O site, O(12) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the CIF file [CIF]
data_BiN3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.568
_cell_length_b   8.736
_cell_length_c   9.966
_cell_angle_alpha   79.310
_cell_angle_beta   85.225
_cell_angle_gamma   77.589
_symmetry_Int_Tables_number   1
_cell_volume   548.152
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.111  0.711  0.198  1.0
  Bi  Bi1  1  0.889  0.289  0.802  1.0
  N  N2  1  0.106  0.338  0.180  1.0
  N  N3  1  0.894  0.662  0.820  1.0
  N  N4  1  0.839  0.836  0.403  1.0
  N  N5  1  0.161  0.164  0.597  1.0
  N  N6  1  0.339  0.850  0.947  1.0
  N  N7  1  0.661  0.150  0.053  1.0
  O  O8  1  0.177  0.392  0.060  1.0
  O  O9  1  0.823  0.608  0.940  1.0
  O  O10  1  0.101  0.427  0.271  1.0
  O  O11  1  0.899  0.573  0.729  1.0
  O  O12  1  0.047  0.212  0.209  1.0
  O  O13  1  0.953  0.788  0.791  1.0
  O  O14  1  0.868  0.686  0.392  1.0
  O  O15  1  0.132  0.314  0.608  1.0
  O  O16  1  0.944  0.921  0.312  1.0
  O  O17  1  0.056  0.079  0.688  1.0
  O  O18  1  0.724  0.892  0.491  1.0
  O  O19  1  0.276  0.108  0.509  1.0
  O  O20  1  0.346  0.700  0.983  1.0
  O  O21  1  0.654  0.300  0.017  1.0
  O  O22  1  0.225  0.939  0.028  1.0
  O  O23  1  0.775  0.061  0.972  1.0
  O  O24  1  0.432  0.906  0.845  1.0
  O  O25  1  0.568  0.094  0.155  1.0
  O  O26  1  0.594  0.399  0.300  1.0
  O  O27  1  0.406  0.601  0.700  1.0
  O  O28  1  0.277  0.643  0.498  1.0
  O  O29  1  0.723  0.357  0.502  1.0
  O  O30  1  0.400  0.702  0.297  1.0
  O  O31  1  0.600  0.298  0.703  1.0
  O  O32  1  0.803  0.779  0.084  1.0
  O  O33  1  0.197  0.221  0.916  1.0
  O  O34  1  0.606  0.314  0.419  1.0
  O  O35  1  0.394  0.686  0.581  1.0
[/CIF]
.
The crystal structure described by (BiN3O11)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trioxidane molecules and two BiN3O11 clusters. In each BiN3O11 cluster, Bi(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(12), one O(13), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one Bi(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Bi(1) and one N(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(4) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(2) atom. In the sixth O site, O(5) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(2) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the eighth O site, O(7) is bonded in a distorted single-bond geometry to one Bi(1) and one N(3) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one Bi(1) and one N(3) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the eleventh O site, O(12) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the CIF file [CIF]
data_BiN3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.568
_cell_length_b   8.736
_cell_length_c   9.966
_cell_angle_alpha   79.310
_cell_angle_beta   85.225
_cell_angle_gamma   77.589
_symmetry_Int_Tables_number   1
_cell_volume   548.152
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.111  0.711  0.198  1.0
  Bi  Bi1  1  0.889  0.289  0.802  1.0
  N  N2  1  0.106  0.338  0.180  1.0
  N  N3  1  0.894  0.662  0.820  1.0
  N  N4  1  0.839  0.836  0.403  1.0
  N  N5  1  0.161  0.164  0.597  1.0
  N  N6  1  0.339  0.850  0.947  1.0
  N  N7  1  0.661  0.150  0.053  1.0
  O  O8  1  0.177  0.392  0.060  1.0
  O  O9  1  0.823  0.608  0.940  1.0
  O  O10  1  0.101  0.427  0.271  1.0
  O  O11  1  0.899  0.573  0.729  1.0
  O  O12  1  0.047  0.212  0.209  1.0
  O  O13  1  0.953  0.788  0.791  1.0
  O  O14  1  0.868  0.686  0.392  1.0
  O  O15  1  0.132  0.314  0.608  1.0
  O  O16  1  0.944  0.921  0.312  1.0
  O  O17  1  0.056  0.079  0.688  1.0
  O  O18  1  0.724  0.892  0.491  1.0
  O  O19  1  0.276  0.108  0.509  1.0
  O  O20  1  0.346  0.700  0.983  1.0
  O  O21  1  0.654  0.300  0.017  1.0
  O  O22  1  0.225  0.939  0.028  1.0
  O  O23  1  0.775  0.061  0.972  1.0
  O  O24  1  0.432  0.906  0.845  1.0
  O  O25  1  0.568  0.094  0.155  1.0
  O  O26  1  0.594  0.399  0.300  1.0
  O  O27  1  0.406  0.601  0.700  1.0
  O  O28  1  0.277  0.643  0.498  1.0
  O  O29  1  0.723  0.357  0.502  1.0
  O  O30  1  0.400  0.702  0.297  1.0
  O  O31  1  0.600  0.298  0.703  1.0
  O  O32  1  0.803  0.779  0.084  1.0
  O  O33  1  0.197  0.221  0.916  1.0
  O  O34  1  0.606  0.314  0.419  1.0
  O  O35  1  0.394  0.686  0.581  1.0
[/CIF]
.