The compound described by LiCuO2 crystallizes in the orthorhombic Pnnm space group. Li(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing LiO6 octahedra. The corner-sharing octahedral tilt angles are 51°. Cu(1) is bonded in a 4-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent Cu(1) atoms. is represented by the CIF card [CIF]
data_LiCuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.756
_cell_length_b   5.149
_cell_length_c   5.338
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   75.762
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.500  1.0
  Li  Li1  1  0.500  0.500  0.000  1.0
  Cu  Cu2  1  0.500  0.000  0.000  1.0
  Cu  Cu3  1  0.000  0.500  0.500  1.0
  O  O4  1  0.000  0.196  0.856  1.0
  O  O5  1  0.500  0.696  0.644  1.0
  O  O6  1  0.000  0.804  0.144  1.0
  O  O7  1  0.500  0.304  0.356  1.0
[/CIF]
.
The compound described by LiCuO2 crystallizes in the orthorhombic Pnnm space group. Li(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing LiO6 octahedra. The corner-sharing octahedral tilt angles are 51°. Cu(1) is bonded in a 4-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent Cu(1) atoms. is represented by the CIF card [CIF]
data_LiCuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.756
_cell_length_b   5.149
_cell_length_c   5.338
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   75.762
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.500  1.0
  Li  Li1  1  0.500  0.500  0.000  1.0
  Cu  Cu2  1  0.500  0.000  0.000  1.0
  Cu  Cu3  1  0.000  0.500  0.500  1.0
  O  O4  1  0.000  0.196  0.856  1.0
  O  O5  1  0.500  0.696  0.644  1.0
  O  O6  1  0.000  0.804  0.144  1.0
  O  O7  1  0.500  0.304  0.356  1.0
[/CIF]
.