The crystal structure described by K3SbN3(O3F)3 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one O(2), one O(3), one O(5), two equivalent O(1), two equivalent O(4), one F(1), and two equivalent F(2) atoms. In the second K site, K(2) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(4), four equivalent O(3), and two equivalent F(2) atoms. Sb(1) is bonded in a 5-coordinate geometry to two equivalent O(2), one F(1), and two equivalent F(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(5) and two equivalent O(1) atoms. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one N(2) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one Sb(1), and one N(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one K(1), two equivalent K(2), and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the second F site, F(2) is bonded to one K(2), two equivalent K(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing FK3Sb tetrahedra. is represented by the CIF file [CIF]
data_K3SbN3(O3F)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.151
_cell_length_b   9.151
_cell_length_c   7.543
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.788
_symmetry_Int_Tables_number   1
_cell_volume   618.334
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.971  0.615  0.773  1.0
  K  K1  1  0.029  0.385  0.273  1.0
  K  K2  1  0.615  0.971  0.273  1.0
  K  K3  1  0.597  0.403  0.005  1.0
  K  K4  1  0.403  0.597  0.505  1.0
  K  K5  1  0.385  0.029  0.773  1.0
  Sb  Sb6  1  0.863  0.137  0.849  1.0
  Sb  Sb7  1  0.137  0.863  0.349  1.0
  N  N8  1  0.207  0.314  0.755  1.0
  N  N9  1  0.314  0.207  0.255  1.0
  N  N10  1  0.793  0.686  0.255  1.0
  N  N11  1  0.686  0.793  0.755  1.0
  N  N12  1  0.703  0.297  0.484  1.0
  N  N13  1  0.297  0.703  0.984  1.0
  O  O14  1  0.791  0.399  0.566  1.0
  O  O15  1  0.210  0.146  0.363  1.0
  O  O16  1  0.653  0.652  0.248  1.0
  O  O17  1  0.873  0.623  0.157  1.0
  O  O18  1  0.790  0.854  0.863  1.0
  O  O19  1  0.854  0.790  0.363  1.0
  O  O20  1  0.127  0.377  0.657  1.0
  O  O21  1  0.623  0.873  0.657  1.0
  O  O22  1  0.399  0.791  0.066  1.0
  O  O23  1  0.601  0.209  0.566  1.0
  O  O24  1  0.347  0.348  0.748  1.0
  O  O25  1  0.146  0.210  0.863  1.0
  O  O26  1  0.720  0.280  0.318  1.0
  O  O27  1  0.348  0.347  0.248  1.0
  O  O28  1  0.652  0.653  0.748  1.0
  O  O29  1  0.377  0.127  0.157  1.0
  O  O30  1  0.209  0.601  0.066  1.0
  O  O31  1  0.280  0.720  0.818  1.0
  F  F32  1  0.918  0.082  0.087  1.0
  F  F33  1  0.082  0.918  0.587  1.0
  F  F34  1  0.655  0.115  0.948  1.0
  F  F35  1  0.115  0.655  0.448  1.0
  F  F36  1  0.345  0.885  0.448  1.0
  F  F37  1  0.885  0.345  0.948  1.0
[/CIF]
.
The crystal structure described by K3SbN3(O3F)3 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one O(2), one O(3), one O(5), two equivalent O(1), two equivalent O(4), one F(1), and two equivalent F(2) atoms. In the second K site, K(2) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(4), four equivalent O(3), and two equivalent F(2) atoms. Sb(1) is bonded in a 5-coordinate geometry to two equivalent O(2), one F(1), and two equivalent F(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(5) and two equivalent O(1) atoms. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one N(2) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one Sb(1), and one N(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one K(1), two equivalent K(2), and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the second F site, F(2) is bonded to one K(2), two equivalent K(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing FK3Sb tetrahedra. is represented by the CIF file [CIF]
data_K3SbN3(O3F)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.151
_cell_length_b   9.151
_cell_length_c   7.543
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.788
_symmetry_Int_Tables_number   1
_cell_volume   618.334
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.971  0.615  0.773  1.0
  K  K1  1  0.029  0.385  0.273  1.0
  K  K2  1  0.615  0.971  0.273  1.0
  K  K3  1  0.597  0.403  0.005  1.0
  K  K4  1  0.403  0.597  0.505  1.0
  K  K5  1  0.385  0.029  0.773  1.0
  Sb  Sb6  1  0.863  0.137  0.849  1.0
  Sb  Sb7  1  0.137  0.863  0.349  1.0
  N  N8  1  0.207  0.314  0.755  1.0
  N  N9  1  0.314  0.207  0.255  1.0
  N  N10  1  0.793  0.686  0.255  1.0
  N  N11  1  0.686  0.793  0.755  1.0
  N  N12  1  0.703  0.297  0.484  1.0
  N  N13  1  0.297  0.703  0.984  1.0
  O  O14  1  0.791  0.399  0.566  1.0
  O  O15  1  0.210  0.146  0.363  1.0
  O  O16  1  0.653  0.652  0.248  1.0
  O  O17  1  0.873  0.623  0.157  1.0
  O  O18  1  0.790  0.854  0.863  1.0
  O  O19  1  0.854  0.790  0.363  1.0
  O  O20  1  0.127  0.377  0.657  1.0
  O  O21  1  0.623  0.873  0.657  1.0
  O  O22  1  0.399  0.791  0.066  1.0
  O  O23  1  0.601  0.209  0.566  1.0
  O  O24  1  0.347  0.348  0.748  1.0
  O  O25  1  0.146  0.210  0.863  1.0
  O  O26  1  0.720  0.280  0.318  1.0
  O  O27  1  0.348  0.347  0.248  1.0
  O  O28  1  0.652  0.653  0.748  1.0
  O  O29  1  0.377  0.127  0.157  1.0
  O  O30  1  0.209  0.601  0.066  1.0
  O  O31  1  0.280  0.720  0.818  1.0
  F  F32  1  0.918  0.082  0.087  1.0
  F  F33  1  0.082  0.918  0.587  1.0
  F  F34  1  0.655  0.115  0.948  1.0
  F  F35  1  0.115  0.655  0.448  1.0
  F  F36  1  0.345  0.885  0.448  1.0
  F  F37  1  0.885  0.345  0.948  1.0
[/CIF]
.