The compound described by InIn3(SnCl3)4 crystallizes in the orthorhombic Fmm2 space group. The structure consists of eight 7440-74-6 atoms inside a In3(SnCl3)4 framework. In the In3(SnCl3)4 framework, there are two inequivalent In sites. In the first In site, In(2) is bonded in a 2-coordinate geometry to one Cl(6) and one Cl(8) atom. In the second In site, In(3) is bonded in a 2-coordinate geometry to one Cl(7) and one Cl(9) atom. There are five inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 7-coordinate geometry to one Cl(6), two equivalent Cl(9), and four equivalent Cl(3) atoms. In the second Sn site, Sn(2) is bonded in a 7-coordinate geometry to one Cl(5), two equivalent Cl(9), and four equivalent Cl(4) atoms. In the third Sn site, Sn(3) is bonded in a 5-coordinate geometry to one Cl(7), two equivalent Cl(1), and two equivalent Cl(2) atoms. In the fourth Sn site, Sn(4) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. In the fifth Sn site, Sn(5) is bonded in a 4-coordinate geometry to one Cl(5), one Cl(8), and two equivalent Cl(2) atoms. There are nine inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to one Sn(3) and one Sn(4) atom. In the second Cl site, Cl(2) is bonded in a distorted T-shaped geometry to one Sn(3), one Sn(4), and one Sn(5) atom. In the third Cl site, Cl(3) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one Sn(4) atom. In the fourth Cl site, Cl(4) is bonded in a distorted linear geometry to one Sn(2) and one Sn(4) atom. In the fifth Cl site, Cl(5) is bonded in a distorted bent 150 degrees geometry to one Sn(2) and two equivalent Sn(5) atoms. In the sixth Cl site, Cl(6) is bonded in a T-shaped geometry to two equivalent In(2) and one Sn(1) atom. In the seventh Cl site, Cl(7) is bonded in a T-shaped geometry to two equivalent In(3) and one Sn(3) atom. In the eighth Cl site, Cl(8) is bonded in a distorted bent 150 degrees geometry to one In(2) and one Sn(5) atom. In the ninth Cl site, Cl(9) is bonded to two equivalent In(3), one Sn(1), and one Sn(2) atom to form distorted edge-sharing ClIn2Sn2 tetrahedra. is represented by the CIF file [CIF]
data_InSnCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.979
_cell_length_b   11.574
_cell_length_c   11.432
_cell_angle_alpha   62.753
_cell_angle_beta   59.202
_cell_angle_gamma   58.045
_symmetry_Int_Tables_number   1
_cell_volume   1116.478
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.501  0.499  1.0
  In  In1  1  0.501  0.000  1.000  1.0
  In  In2  1  0.651  0.018  0.349  1.0
  In  In3  1  0.477  0.523  0.854  1.0
  In  In4  1  0.146  0.853  0.523  1.0
  In  In5  1  0.018  0.651  0.982  1.0
  In  In6  1  0.523  0.477  0.147  1.0
  In  In7  1  0.853  0.146  0.477  1.0
  Sn  Sn8  1  0.650  0.650  0.350  1.0
  Sn  Sn9  1  0.369  0.369  0.631  1.0
  Sn  Sn10  1  0.146  0.842  0.158  1.0
  Sn  Sn11  1  0.842  0.146  0.854  1.0
  Sn  Sn12  1  0.750  0.750  0.750  1.0
  Sn  Sn13  1  0.250  0.250  0.250  1.0
  Sn  Sn14  1  0.992  0.330  0.008  1.0
  Sn  Sn15  1  0.330  0.992  0.670  1.0
  Cl  Cl16  1  0.930  0.833  0.435  1.0
  Cl  Cl17  1  0.810  0.433  0.844  1.0
  Cl  Cl18  1  0.420  0.939  0.349  1.0
  Cl  Cl19  1  0.292  0.335  0.938  1.0
  Cl  Cl20  1  0.651  0.708  0.580  1.0
  Cl  Cl21  1  0.062  0.566  0.708  1.0
  Cl  Cl22  1  0.565  0.197  0.070  1.0
  Cl  Cl23  1  0.156  0.087  0.190  1.0
  Cl  Cl24  1  0.087  0.156  0.567  1.0
  Cl  Cl25  1  0.197  0.565  0.167  1.0
  Cl  Cl26  1  0.566  0.062  0.665  1.0
  Cl  Cl27  1  0.708  0.651  0.061  1.0
  Cl  Cl28  1  0.335  0.292  0.434  1.0
  Cl  Cl29  1  0.939  0.420  0.292  1.0
  Cl  Cl30  1  0.433  0.810  0.913  1.0
  Cl  Cl31  1  0.833  0.930  0.803  1.0
  Cl  Cl32  1  0.186  0.186  0.814  1.0
  Cl  Cl33  1  0.810  0.810  0.190  1.0
  Cl  Cl34  1  0.695  0.310  0.690  1.0
  Cl  Cl35  1  0.310  0.695  0.305  1.0
  Cl  Cl36  1  0.879  0.142  0.121  1.0
  Cl  Cl37  1  0.386  0.610  0.614  1.0
  Cl  Cl38  1  0.142  0.879  0.858  1.0
  Cl  Cl39  1  0.610  0.386  0.390  1.0
[/CIF]
.
The compound described by InIn3(SnCl3)4 crystallizes in the orthorhombic Fmm2 space group. The structure consists of eight 7440-74-6 atoms inside a In3(SnCl3)4 framework. In the In3(SnCl3)4 framework, there are two inequivalent In sites. In the first In site, In(2) is bonded in a 2-coordinate geometry to one Cl(6) and one Cl(8) atom. In the second In site, In(3) is bonded in a 2-coordinate geometry to one Cl(7) and one Cl(9) atom. There are five inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 7-coordinate geometry to one Cl(6), two equivalent Cl(9), and four equivalent Cl(3) atoms. In the second Sn site, Sn(2) is bonded in a 7-coordinate geometry to one Cl(5), two equivalent Cl(9), and four equivalent Cl(4) atoms. In the third Sn site, Sn(3) is bonded in a 5-coordinate geometry to one Cl(7), two equivalent Cl(1), and two equivalent Cl(2) atoms. In the fourth Sn site, Sn(4) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. In the fifth Sn site, Sn(5) is bonded in a 4-coordinate geometry to one Cl(5), one Cl(8), and two equivalent Cl(2) atoms. There are nine inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to one Sn(3) and one Sn(4) atom. In the second Cl site, Cl(2) is bonded in a distorted T-shaped geometry to one Sn(3), one Sn(4), and one Sn(5) atom. In the third Cl site, Cl(3) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one Sn(4) atom. In the fourth Cl site, Cl(4) is bonded in a distorted linear geometry to one Sn(2) and one Sn(4) atom. In the fifth Cl site, Cl(5) is bonded in a distorted bent 150 degrees geometry to one Sn(2) and two equivalent Sn(5) atoms. In the sixth Cl site, Cl(6) is bonded in a T-shaped geometry to two equivalent In(2) and one Sn(1) atom. In the seventh Cl site, Cl(7) is bonded in a T-shaped geometry to two equivalent In(3) and one Sn(3) atom. In the eighth Cl site, Cl(8) is bonded in a distorted bent 150 degrees geometry to one In(2) and one Sn(5) atom. In the ninth Cl site, Cl(9) is bonded to two equivalent In(3), one Sn(1), and one Sn(2) atom to form distorted edge-sharing ClIn2Sn2 tetrahedra. is represented by the CIF file [CIF]
data_InSnCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.979
_cell_length_b   11.574
_cell_length_c   11.432
_cell_angle_alpha   62.753
_cell_angle_beta   59.202
_cell_angle_gamma   58.045
_symmetry_Int_Tables_number   1
_cell_volume   1116.478
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.501  0.499  1.0
  In  In1  1  0.501  0.000  1.000  1.0
  In  In2  1  0.651  0.018  0.349  1.0
  In  In3  1  0.477  0.523  0.854  1.0
  In  In4  1  0.146  0.853  0.523  1.0
  In  In5  1  0.018  0.651  0.982  1.0
  In  In6  1  0.523  0.477  0.147  1.0
  In  In7  1  0.853  0.146  0.477  1.0
  Sn  Sn8  1  0.650  0.650  0.350  1.0
  Sn  Sn9  1  0.369  0.369  0.631  1.0
  Sn  Sn10  1  0.146  0.842  0.158  1.0
  Sn  Sn11  1  0.842  0.146  0.854  1.0
  Sn  Sn12  1  0.750  0.750  0.750  1.0
  Sn  Sn13  1  0.250  0.250  0.250  1.0
  Sn  Sn14  1  0.992  0.330  0.008  1.0
  Sn  Sn15  1  0.330  0.992  0.670  1.0
  Cl  Cl16  1  0.930  0.833  0.435  1.0
  Cl  Cl17  1  0.810  0.433  0.844  1.0
  Cl  Cl18  1  0.420  0.939  0.349  1.0
  Cl  Cl19  1  0.292  0.335  0.938  1.0
  Cl  Cl20  1  0.651  0.708  0.580  1.0
  Cl  Cl21  1  0.062  0.566  0.708  1.0
  Cl  Cl22  1  0.565  0.197  0.070  1.0
  Cl  Cl23  1  0.156  0.087  0.190  1.0
  Cl  Cl24  1  0.087  0.156  0.567  1.0
  Cl  Cl25  1  0.197  0.565  0.167  1.0
  Cl  Cl26  1  0.566  0.062  0.665  1.0
  Cl  Cl27  1  0.708  0.651  0.061  1.0
  Cl  Cl28  1  0.335  0.292  0.434  1.0
  Cl  Cl29  1  0.939  0.420  0.292  1.0
  Cl  Cl30  1  0.433  0.810  0.913  1.0
  Cl  Cl31  1  0.833  0.930  0.803  1.0
  Cl  Cl32  1  0.186  0.186  0.814  1.0
  Cl  Cl33  1  0.810  0.810  0.190  1.0
  Cl  Cl34  1  0.695  0.310  0.690  1.0
  Cl  Cl35  1  0.310  0.695  0.305  1.0
  Cl  Cl36  1  0.879  0.142  0.121  1.0
  Cl  Cl37  1  0.386  0.610  0.614  1.0
  Cl  Cl38  1  0.142  0.879  0.858  1.0
  Cl  Cl39  1  0.610  0.386  0.390  1.0
[/CIF]
.