The crystal structure described by Sr5La5Mn9CuO30 crystallizes in the triclinic P1 space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(12), one O(13), one O(2), one O(27), one O(28), one O(3), two equivalent O(17), two equivalent O(22), and two equivalent O(7) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent La(1)O12 cuboctahedra, corners with six equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(5)O12 cuboctahedra, faces with three equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(8)O6 octahedra, faces with three equivalent Mn(3)O6 octahedra, and faces with three equivalent Mn(7)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(12), one O(14), one O(28), one O(29), one O(3), one O(4), two equivalent O(18), two equivalent O(23), and two equivalent O(8) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra, faces with three equivalent Mn(4)O6 octahedra, and faces with three equivalent Mn(8)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(11), one O(15), one O(26), one O(30), one O(5), two equivalent O(10), two equivalent O(20), and two equivalent O(25) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent La(1)O12 cuboctahedra, corners with six equivalent Sr(3)O12 cuboctahedra, faces with three equivalent Sr(4)O12 cuboctahedra,  a faceface with one Mn(5)O6 octahedra,  a faceface with one Mn(6)O6 octahedra, faces with three equivalent Mn(1)O6 octahedra, and faces with three equivalent Mn(9)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(10), one O(16), one O(20), one O(21), one O(25), one O(6), two equivalent O(1), two equivalent O(11), and two equivalent O(26) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(5)O12 cuboctahedra, corners with six equivalent Sr(4)O12 cuboctahedra, faces with three equivalent Sr(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(9)O6 octahedra, faces with three equivalent Mn(1)O6 octahedra, and faces with three equivalent Mn(6)O6 octahedra. In the fifth Sr site, Sr(5) is bonded to one O(16), one O(17), one O(21), one O(22), one O(6), one O(7), two equivalent O(13), two equivalent O(2), and two equivalent O(27) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(4)O12 cuboctahedra, corners with three equivalent La(3)O12 cuboctahedra, corners with six equivalent Sr(5)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Mn(6)O6 octahedra, faces with three equivalent Mn(2)O6 octahedra, and faces with three equivalent Mn(7)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(11), one O(13), one O(2), one O(26), one O(27), two equivalent O(16), two equivalent O(21), and two equivalent O(6) atoms to form distorted LaO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with six equivalent La(1)O12 cuboctahedra, faces with three equivalent Sr(4)O12 cuboctahedra, faces with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(7)O6 octahedra, faces with three equivalent Mn(2)O6 octahedra, and faces with three equivalent Mn(6)O6 octahedra. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(14), one O(15), one O(29), one O(30), one O(4), one O(5), two equivalent O(19), two equivalent O(24), and two equivalent O(9) atoms. In the third La site, La(3) is bonded to one O(17), one O(18), one O(22), one O(23), one O(7), one O(8), two equivalent O(12), two equivalent O(28), and two equivalent O(3) atoms to form distorted LaO12 cuboctahedra that share corners with three equivalent Sr(5)O12 cuboctahedra, corners with six equivalent La(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(7)O6 octahedra, faces with three equivalent Mn(3)O6 octahedra, and faces with three equivalent Mn(8)O6 octahedra. In the fourth La site, La(4) is bonded in a 12-coordinate geometry to one O(18), one O(19), one O(23), one O(24), one O(8), one O(9), two equivalent O(14), two equivalent O(29), and two equivalent O(4) atoms. In the fifth La site, La(5) is bonded in a 12-coordinate geometry to one O(10), one O(19), one O(20), one O(24), one O(25), one O(9), two equivalent O(15), two equivalent O(30), and two equivalent O(5) atoms. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(11), one O(20), one O(25), and one O(26) atom to form MnO6 octahedra that share corners with three equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(9)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(3)O12 cuboctahedra, and faces with three equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-18°. In the second Mn site, Mn(2) is bonded to one O(13), one O(16), one O(2), one O(21), one O(27), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(7)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with three equivalent Sr(5)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the third Mn site, Mn(3) is bonded to one O(12), one O(17), one O(22), one O(28), one O(3), and one O(7) atom to form MnO6 octahedra that share corners with three equivalent Mn(7)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-18°. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(18), one O(23), one O(29), one O(4), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Mn(8)O6 octahedra, corners with three equivalent Cu(1)O6 octahedra,  a faceface with one La(3)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-22°. In the fifth Mn site, Mn(5) is bonded to one O(15), one O(19), one O(24), one O(30), one O(5), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Mn(9)O6 octahedra, corners with three equivalent Cu(1)O6 octahedra, and  a faceface with one Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-24°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(11), one O(16), one O(21), one O(26), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with three equivalent Sr(4)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the seventh Mn site, Mn(7) is bonded to one O(13), one O(17), one O(2), one O(22), one O(27), and one O(7) atom to form MnO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-17°. In the eighth Mn site, Mn(8) is bonded to one O(12), one O(18), one O(23), one O(28), one O(3), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Mn(3)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-20°. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(15), one O(20), one O(25), one O(30), and one O(5) atom to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a faceface with one Sr(4)O12 cuboctahedra, and faces with three equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-22°. Cu(1) is bonded to one O(14), one O(19), one O(24), one O(29), one O(4), and one O(9) atom to form CuO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra, and  a faceface with one Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-24°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded to one Sr(3), two equivalent Sr(4), one La(1), one Mn(1), and one Mn(6) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(16)Sr2La2Mn2 octahedra,  a cornercorner with one O(2)Sr3LaMn2 octahedra,  a cornercorner with one O(20)Sr3LaMn2 octahedra, corners with two equivalent O(1)Sr3LaMn2 octahedra, edges with two equivalent O(16)Sr2La2Mn2 octahedra, and edges with two equivalent O(20)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the second O site, O(2) is bonded to one Sr(1), two equivalent Sr(5), one La(1), one Mn(2), and one Mn(7) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(16)Sr2La2Mn2 octahedra,  a cornercorner with one O(1)Sr3LaMn2 octahedra,  a cornercorner with one O(17)Sr3LaMn2 octahedra, corners with two equivalent O(2)Sr3LaMn2 octahedra, edges with two equivalent O(16)Sr2La2Mn2 octahedra, and edges with two equivalent O(17)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(3), one Mn(3), and one Mn(8) atom. In the fourth O site, O(4) is bonded to one Sr(2), one La(2), two equivalent La(4), one Mn(4), and one Cu(1) atom to form distorted OSrLa3MnCu octahedra that share  a cornercorner with one O(19)La4MnCu octahedra, corners with two equivalent O(4)SrLa3MnCu octahedra, and edges with two equivalent O(19)La4MnCu octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(3), one La(2), two equivalent La(5), one Mn(5), and one Mn(9) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Sr(4), one Sr(5), two equivalent La(1), one Mn(2), and one Mn(6) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Sr(5), two equivalent Sr(1), one La(3), one Mn(3), and one Mn(7) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one La(3), one La(4), one Mn(4), and one Mn(8) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one La(4), one La(5), two equivalent La(2), one Mn(5), and one Cu(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Sr(4), two equivalent Sr(3), one La(5), one Mn(1), and one Mn(9) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Sr(3), two equivalent Sr(4), one La(1), one Mn(1), and one Mn(6) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(3), one Mn(3), and one Mn(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one Sr(1), two equivalent Sr(5), one La(1), one Mn(2), and one Mn(7) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Mn(4), and one Cu(1) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Sr(3), one La(2), two equivalent La(5), one Mn(5), and one Mn(9) atom. In the sixteenth O site, O(16) is bonded to one Sr(4), one Sr(5), two equivalent La(1), one Mn(2), and one Mn(6) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(1)Sr3LaMn2 octahedra,  a cornercorner with one O(17)Sr3LaMn2 octahedra,  a cornercorner with one O(2)Sr3LaMn2 octahedra,  a cornercorner with one O(20)Sr3LaMn2 octahedra, corners with two equivalent O(16)Sr2La2Mn2 octahedra, edges with two equivalent O(1)Sr3LaMn2 octahedra, and edges with two equivalent O(2)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the seventeenth O site, O(17) is bonded to one Sr(5), two equivalent Sr(1), one La(3), one Mn(3), and one Mn(7) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(16)Sr2La2Mn2 octahedra,  a cornercorner with one O(2)Sr3LaMn2 octahedra, corners with two equivalent O(17)Sr3LaMn2 octahedra, and edges with two equivalent O(2)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to two equivalent Sr(2), one La(3), one La(4), one Mn(4), and one Mn(8) atom. In the nineteenth O site, O(19) is bonded to one La(4), one La(5), two equivalent La(2), one Mn(5), and one Cu(1) atom to form distorted OLa4MnCu octahedra that share  a cornercorner with one O(20)Sr3LaMn2 octahedra,  a cornercorner with one O(4)SrLa3MnCu octahedra, corners with two equivalent O(19)La4MnCu octahedra, and edges with two equivalent O(4)SrLa3MnCu octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the twentieth O site, O(20) is bonded to one Sr(4), two equivalent Sr(3), one La(5), one Mn(1), and one Mn(9) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(19)La4MnCu octahedra,  a cornercorner with one O(16)Sr2La2Mn2 octahedra,  a cornercorner with one O(1)Sr3LaMn2 octahedra, corners with two equivalent O(20)Sr3LaMn2 octahedra, and edges with two equivalent O(1)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one Sr(4), one Sr(5), two equivalent La(1), one Mn(2), and one Mn(6) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Sr(5), two equivalent Sr(1), one La(3), one Mn(3), and one Mn(7) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one La(3), one La(4), one Mn(4), and one Mn(8) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one La(4), one La(5), two equivalent La(2), one Mn(5), and one Cu(1) atom. In the twenty-fifth O site, O(25) is bonded in a 2-coordinate geometry to one Sr(4), two equivalent Sr(3), one La(5), one Mn(1), and one Mn(9) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Sr(3), two equivalent Sr(4), one La(1), one Mn(1), and one Mn(6) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Sr(1), two equivalent Sr(5), one La(1), one Mn(2), and one Mn(7) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(3), one Mn(3), and one Mn(8) atom. In the twenty-ninth O site, O(29) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Mn(4), and one Cu(1) atom. In the thirtieth O site, O(30) is bonded in a 4-coordinate geometry to one Sr(3), one La(2), two equivalent La(5), one Mn(5), and one Mn(9) atom. is represented by the CIF card [CIF]
data_Sr5La5Mn9CuO30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.478
_cell_length_b   5.535
_cell_length_c   22.694
_cell_angle_alpha   83.939
_cell_angle_beta   83.130
_cell_angle_gamma   60.349
_symmetry_Int_Tables_number   1
_cell_volume   592.855
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.549  0.550  0.349  1.0
  Sr  Sr1  1  0.149  0.150  0.550  1.0
  Sr  Sr2  1  0.347  0.350  0.953  1.0
  Sr  Sr3  1  0.652  0.650  0.050  1.0
  Sr  Sr4  1  0.252  0.250  0.250  1.0
  La  La5  1  0.955  0.950  0.151  1.0
  La  La6  1  0.752  0.751  0.749  1.0
  La  La7  1  0.846  0.851  0.448  1.0
  La  La8  1  0.454  0.450  0.649  1.0
  La  La9  1  0.046  0.049  0.852  1.0
  Mn  Mn10  1  1.000  0.999  0.001  1.0
  Mn  Mn11  1  0.600  0.600  0.201  1.0
  Mn  Mn12  1  0.200  0.201  0.399  1.0
  Mn  Mn13  1  0.804  0.801  0.599  1.0
  Mn  Mn14  1  0.397  0.399  0.801  1.0
  Mn  Mn15  1  0.300  0.300  0.100  1.0
  Mn  Mn16  1  0.900  0.900  0.300  1.0
  Mn  Mn17  1  0.498  0.501  0.499  1.0
  Mn  Mn18  1  0.701  0.698  0.902  1.0
  Cu  Cu19  1  0.101  0.100  0.699  1.0
  O  O20  1  0.148  0.653  0.052  1.0
  O  O21  1  0.754  0.246  0.248  1.0
  O  O22  1  0.348  0.849  0.451  1.0
  O  O23  1  0.936  0.467  0.650  1.0
  O  O24  1  0.552  0.043  0.848  1.0
  O  O25  1  0.933  0.420  0.144  1.0
  O  O26  1  0.535  0.030  0.345  1.0
  O  O27  1  0.120  0.636  0.539  1.0
  O  O28  1  0.709  0.224  0.742  1.0
  O  O29  1  0.327  0.835  0.941  1.0
  O  O30  1  0.190  0.130  0.045  1.0
  O  O31  1  0.409  0.317  0.444  1.0
  O  O32  1  0.796  0.737  0.242  1.0
  O  O33  1  0.018  0.903  0.642  1.0
  O  O34  1  0.615  0.521  0.841  1.0
  O  O35  1  0.455  0.949  0.150  1.0
  O  O36  1  0.046  0.556  0.353  1.0
  O  O37  1  0.646  0.154  0.550  1.0
  O  O38  1  0.259  0.738  0.752  1.0
  O  O39  1  0.852  0.345  0.947  1.0
  O  O40  1  0.397  0.480  0.156  1.0
  O  O41  1  0.005  0.063  0.359  1.0
  O  O42  1  0.597  0.665  0.558  1.0
  O  O43  1  0.181  0.282  0.762  1.0
  O  O44  1  0.806  0.873  0.955  1.0
  O  O45  1  0.674  0.163  0.059  1.0
  O  O46  1  0.265  0.770  0.255  1.0
  O  O47  1  0.867  0.382  0.457  1.0
  O  O48  1  0.488  0.982  0.657  1.0
  O  O49  1  0.072  0.585  0.857  1.0
[/CIF]
.
The crystal structure described by Sr5La5Mn9CuO30 crystallizes in the triclinic P1 space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(12), one O(13), one O(2), one O(27), one O(28), one O(3), two equivalent O(17), two equivalent O(22), and two equivalent O(7) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent La(1)O12 cuboctahedra, corners with six equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(5)O12 cuboctahedra, faces with three equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(8)O6 octahedra, faces with three equivalent Mn(3)O6 octahedra, and faces with three equivalent Mn(7)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(12), one O(14), one O(28), one O(29), one O(3), one O(4), two equivalent O(18), two equivalent O(23), and two equivalent O(8) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(3)O12 cuboctahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Cu(1)O6 octahedra, faces with three equivalent Mn(4)O6 octahedra, and faces with three equivalent Mn(8)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(11), one O(15), one O(26), one O(30), one O(5), two equivalent O(10), two equivalent O(20), and two equivalent O(25) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent La(1)O12 cuboctahedra, corners with six equivalent Sr(3)O12 cuboctahedra, faces with three equivalent Sr(4)O12 cuboctahedra,  a faceface with one Mn(5)O6 octahedra,  a faceface with one Mn(6)O6 octahedra, faces with three equivalent Mn(1)O6 octahedra, and faces with three equivalent Mn(9)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(10), one O(16), one O(20), one O(21), one O(25), one O(6), two equivalent O(1), two equivalent O(11), and two equivalent O(26) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(5)O12 cuboctahedra, corners with six equivalent Sr(4)O12 cuboctahedra, faces with three equivalent Sr(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(9)O6 octahedra, faces with three equivalent Mn(1)O6 octahedra, and faces with three equivalent Mn(6)O6 octahedra. In the fifth Sr site, Sr(5) is bonded to one O(16), one O(17), one O(21), one O(22), one O(6), one O(7), two equivalent O(13), two equivalent O(2), and two equivalent O(27) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(4)O12 cuboctahedra, corners with three equivalent La(3)O12 cuboctahedra, corners with six equivalent Sr(5)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Mn(6)O6 octahedra, faces with three equivalent Mn(2)O6 octahedra, and faces with three equivalent Mn(7)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(11), one O(13), one O(2), one O(26), one O(27), two equivalent O(16), two equivalent O(21), and two equivalent O(6) atoms to form distorted LaO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with six equivalent La(1)O12 cuboctahedra, faces with three equivalent Sr(4)O12 cuboctahedra, faces with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(7)O6 octahedra, faces with three equivalent Mn(2)O6 octahedra, and faces with three equivalent Mn(6)O6 octahedra. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(14), one O(15), one O(29), one O(30), one O(4), one O(5), two equivalent O(19), two equivalent O(24), and two equivalent O(9) atoms. In the third La site, La(3) is bonded to one O(17), one O(18), one O(22), one O(23), one O(7), one O(8), two equivalent O(12), two equivalent O(28), and two equivalent O(3) atoms to form distorted LaO12 cuboctahedra that share corners with three equivalent Sr(5)O12 cuboctahedra, corners with six equivalent La(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(7)O6 octahedra, faces with three equivalent Mn(3)O6 octahedra, and faces with three equivalent Mn(8)O6 octahedra. In the fourth La site, La(4) is bonded in a 12-coordinate geometry to one O(18), one O(19), one O(23), one O(24), one O(8), one O(9), two equivalent O(14), two equivalent O(29), and two equivalent O(4) atoms. In the fifth La site, La(5) is bonded in a 12-coordinate geometry to one O(10), one O(19), one O(20), one O(24), one O(25), one O(9), two equivalent O(15), two equivalent O(30), and two equivalent O(5) atoms. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(11), one O(20), one O(25), and one O(26) atom to form MnO6 octahedra that share corners with three equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(9)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(3)O12 cuboctahedra, and faces with three equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-18°. In the second Mn site, Mn(2) is bonded to one O(13), one O(16), one O(2), one O(21), one O(27), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(7)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with three equivalent Sr(5)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the third Mn site, Mn(3) is bonded to one O(12), one O(17), one O(22), one O(28), one O(3), and one O(7) atom to form MnO6 octahedra that share corners with three equivalent Mn(7)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-18°. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(18), one O(23), one O(29), one O(4), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Mn(8)O6 octahedra, corners with three equivalent Cu(1)O6 octahedra,  a faceface with one La(3)O12 cuboctahedra, and faces with three equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-22°. In the fifth Mn site, Mn(5) is bonded to one O(15), one O(19), one O(24), one O(30), one O(5), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Mn(9)O6 octahedra, corners with three equivalent Cu(1)O6 octahedra, and  a faceface with one Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-24°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(11), one O(16), one O(21), one O(26), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with three equivalent Sr(4)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the seventh Mn site, Mn(7) is bonded to one O(13), one O(17), one O(2), one O(22), one O(27), and one O(7) atom to form MnO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-17°. In the eighth Mn site, Mn(8) is bonded to one O(12), one O(18), one O(23), one O(28), one O(3), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Mn(3)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-20°. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(15), one O(20), one O(25), one O(30), and one O(5) atom to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a faceface with one Sr(4)O12 cuboctahedra, and faces with three equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-22°. Cu(1) is bonded to one O(14), one O(19), one O(24), one O(29), one O(4), and one O(9) atom to form CuO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra, and  a faceface with one Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-24°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded to one Sr(3), two equivalent Sr(4), one La(1), one Mn(1), and one Mn(6) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(16)Sr2La2Mn2 octahedra,  a cornercorner with one O(2)Sr3LaMn2 octahedra,  a cornercorner with one O(20)Sr3LaMn2 octahedra, corners with two equivalent O(1)Sr3LaMn2 octahedra, edges with two equivalent O(16)Sr2La2Mn2 octahedra, and edges with two equivalent O(20)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the second O site, O(2) is bonded to one Sr(1), two equivalent Sr(5), one La(1), one Mn(2), and one Mn(7) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(16)Sr2La2Mn2 octahedra,  a cornercorner with one O(1)Sr3LaMn2 octahedra,  a cornercorner with one O(17)Sr3LaMn2 octahedra, corners with two equivalent O(2)Sr3LaMn2 octahedra, edges with two equivalent O(16)Sr2La2Mn2 octahedra, and edges with two equivalent O(17)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(3), one Mn(3), and one Mn(8) atom. In the fourth O site, O(4) is bonded to one Sr(2), one La(2), two equivalent La(4), one Mn(4), and one Cu(1) atom to form distorted OSrLa3MnCu octahedra that share  a cornercorner with one O(19)La4MnCu octahedra, corners with two equivalent O(4)SrLa3MnCu octahedra, and edges with two equivalent O(19)La4MnCu octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(3), one La(2), two equivalent La(5), one Mn(5), and one Mn(9) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Sr(4), one Sr(5), two equivalent La(1), one Mn(2), and one Mn(6) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Sr(5), two equivalent Sr(1), one La(3), one Mn(3), and one Mn(7) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one La(3), one La(4), one Mn(4), and one Mn(8) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one La(4), one La(5), two equivalent La(2), one Mn(5), and one Cu(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Sr(4), two equivalent Sr(3), one La(5), one Mn(1), and one Mn(9) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Sr(3), two equivalent Sr(4), one La(1), one Mn(1), and one Mn(6) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(3), one Mn(3), and one Mn(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one Sr(1), two equivalent Sr(5), one La(1), one Mn(2), and one Mn(7) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Mn(4), and one Cu(1) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Sr(3), one La(2), two equivalent La(5), one Mn(5), and one Mn(9) atom. In the sixteenth O site, O(16) is bonded to one Sr(4), one Sr(5), two equivalent La(1), one Mn(2), and one Mn(6) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(1)Sr3LaMn2 octahedra,  a cornercorner with one O(17)Sr3LaMn2 octahedra,  a cornercorner with one O(2)Sr3LaMn2 octahedra,  a cornercorner with one O(20)Sr3LaMn2 octahedra, corners with two equivalent O(16)Sr2La2Mn2 octahedra, edges with two equivalent O(1)Sr3LaMn2 octahedra, and edges with two equivalent O(2)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the seventeenth O site, O(17) is bonded to one Sr(5), two equivalent Sr(1), one La(3), one Mn(3), and one Mn(7) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(16)Sr2La2Mn2 octahedra,  a cornercorner with one O(2)Sr3LaMn2 octahedra, corners with two equivalent O(17)Sr3LaMn2 octahedra, and edges with two equivalent O(2)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to two equivalent Sr(2), one La(3), one La(4), one Mn(4), and one Mn(8) atom. In the nineteenth O site, O(19) is bonded to one La(4), one La(5), two equivalent La(2), one Mn(5), and one Cu(1) atom to form distorted OLa4MnCu octahedra that share  a cornercorner with one O(20)Sr3LaMn2 octahedra,  a cornercorner with one O(4)SrLa3MnCu octahedra, corners with two equivalent O(19)La4MnCu octahedra, and edges with two equivalent O(4)SrLa3MnCu octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the twentieth O site, O(20) is bonded to one Sr(4), two equivalent Sr(3), one La(5), one Mn(1), and one Mn(9) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(19)La4MnCu octahedra,  a cornercorner with one O(16)Sr2La2Mn2 octahedra,  a cornercorner with one O(1)Sr3LaMn2 octahedra, corners with two equivalent O(20)Sr3LaMn2 octahedra, and edges with two equivalent O(1)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one Sr(4), one Sr(5), two equivalent La(1), one Mn(2), and one Mn(6) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Sr(5), two equivalent Sr(1), one La(3), one Mn(3), and one Mn(7) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one La(3), one La(4), one Mn(4), and one Mn(8) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one La(4), one La(5), two equivalent La(2), one Mn(5), and one Cu(1) atom. In the twenty-fifth O site, O(25) is bonded in a 2-coordinate geometry to one Sr(4), two equivalent Sr(3), one La(5), one Mn(1), and one Mn(9) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Sr(3), two equivalent Sr(4), one La(1), one Mn(1), and one Mn(6) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Sr(1), two equivalent Sr(5), one La(1), one Mn(2), and one Mn(7) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(3), one Mn(3), and one Mn(8) atom. In the twenty-ninth O site, O(29) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), two equivalent La(4), one Mn(4), and one Cu(1) atom. In the thirtieth O site, O(30) is bonded in a 4-coordinate geometry to one Sr(3), one La(2), two equivalent La(5), one Mn(5), and one Mn(9) atom. is represented by the CIF card [CIF]
data_Sr5La5Mn9CuO30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.478
_cell_length_b   5.535
_cell_length_c   22.694
_cell_angle_alpha   83.939
_cell_angle_beta   83.130
_cell_angle_gamma   60.349
_symmetry_Int_Tables_number   1
_cell_volume   592.855
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.549  0.550  0.349  1.0
  Sr  Sr1  1  0.149  0.150  0.550  1.0
  Sr  Sr2  1  0.347  0.350  0.953  1.0
  Sr  Sr3  1  0.652  0.650  0.050  1.0
  Sr  Sr4  1  0.252  0.250  0.250  1.0
  La  La5  1  0.955  0.950  0.151  1.0
  La  La6  1  0.752  0.751  0.749  1.0
  La  La7  1  0.846  0.851  0.448  1.0
  La  La8  1  0.454  0.450  0.649  1.0
  La  La9  1  0.046  0.049  0.852  1.0
  Mn  Mn10  1  1.000  0.999  0.001  1.0
  Mn  Mn11  1  0.600  0.600  0.201  1.0
  Mn  Mn12  1  0.200  0.201  0.399  1.0
  Mn  Mn13  1  0.804  0.801  0.599  1.0
  Mn  Mn14  1  0.397  0.399  0.801  1.0
  Mn  Mn15  1  0.300  0.300  0.100  1.0
  Mn  Mn16  1  0.900  0.900  0.300  1.0
  Mn  Mn17  1  0.498  0.501  0.499  1.0
  Mn  Mn18  1  0.701  0.698  0.902  1.0
  Cu  Cu19  1  0.101  0.100  0.699  1.0
  O  O20  1  0.148  0.653  0.052  1.0
  O  O21  1  0.754  0.246  0.248  1.0
  O  O22  1  0.348  0.849  0.451  1.0
  O  O23  1  0.936  0.467  0.650  1.0
  O  O24  1  0.552  0.043  0.848  1.0
  O  O25  1  0.933  0.420  0.144  1.0
  O  O26  1  0.535  0.030  0.345  1.0
  O  O27  1  0.120  0.636  0.539  1.0
  O  O28  1  0.709  0.224  0.742  1.0
  O  O29  1  0.327  0.835  0.941  1.0
  O  O30  1  0.190  0.130  0.045  1.0
  O  O31  1  0.409  0.317  0.444  1.0
  O  O32  1  0.796  0.737  0.242  1.0
  O  O33  1  0.018  0.903  0.642  1.0
  O  O34  1  0.615  0.521  0.841  1.0
  O  O35  1  0.455  0.949  0.150  1.0
  O  O36  1  0.046  0.556  0.353  1.0
  O  O37  1  0.646  0.154  0.550  1.0
  O  O38  1  0.259  0.738  0.752  1.0
  O  O39  1  0.852  0.345  0.947  1.0
  O  O40  1  0.397  0.480  0.156  1.0
  O  O41  1  0.005  0.063  0.359  1.0
  O  O42  1  0.597  0.665  0.558  1.0
  O  O43  1  0.181  0.282  0.762  1.0
  O  O44  1  0.806  0.873  0.955  1.0
  O  O45  1  0.674  0.163  0.059  1.0
  O  O46  1  0.265  0.770  0.255  1.0
  O  O47  1  0.867  0.382  0.457  1.0
  O  O48  1  0.488  0.982  0.657  1.0
  O  O49  1  0.072  0.585  0.857  1.0
[/CIF]
.