The material structure described by MnSbO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic P2_1 space group. Mn(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form distorted MnO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra and edges with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 28°. Sb(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted SbO6 octahedra that share corners with four equivalent Sb(1)O6 octahedra and edges with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-29°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent Mn(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Mn(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1) and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Mn(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.646
_cell_length_b   5.668
_cell_length_c   5.648
_cell_angle_alpha   119.997
_cell_angle_beta   89.995
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   156.524
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.968  0.984  1.0
  Mn  Mn1  1  0.500  0.032  0.516  1.0
  O  O2  1  0.727  0.100  0.300  1.0
  O  O3  1  0.274  0.101  0.802  1.0
  O  O4  1  0.774  0.899  0.698  1.0
  O  O5  1  0.227  0.900  0.200  1.0
  O  O6  1  0.000  0.396  0.199  1.0
  O  O7  1  0.499  0.434  0.715  1.0
  O  O8  1  0.500  0.604  0.301  1.0
  O  O9  1  0.999  0.566  0.785  1.0
  Sb  Sb10  1  0.750  0.500  0.490  1.0
  Sb  Sb11  1  0.250  0.500  0.010  1.0
[/CIF]
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The material structure described by MnSbO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic P2_1 space group. Mn(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form distorted MnO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra and edges with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 28°. Sb(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted SbO6 octahedra that share corners with four equivalent Sb(1)O6 octahedra and edges with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-29°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent Mn(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Mn(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1) and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Mn(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.646
_cell_length_b   5.668
_cell_length_c   5.648
_cell_angle_alpha   119.997
_cell_angle_beta   89.995
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   156.524
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.968  0.984  1.0
  Mn  Mn1  1  0.500  0.032  0.516  1.0
  O  O2  1  0.727  0.100  0.300  1.0
  O  O3  1  0.274  0.101  0.802  1.0
  O  O4  1  0.774  0.899  0.698  1.0
  O  O5  1  0.227  0.900  0.200  1.0
  O  O6  1  0.000  0.396  0.199  1.0
  O  O7  1  0.499  0.434  0.715  1.0
  O  O8  1  0.500  0.604  0.301  1.0
  O  O9  1  0.999  0.566  0.785  1.0
  Sb  Sb10  1  0.750  0.500  0.490  1.0
  Sb  Sb11  1  0.250  0.500  0.010  1.0
[/CIF]
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