The compound described by KVH4O7 crystallizes in the triclinic P1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(2), one O(6), one O(7), and one O(8) atom. In the second K site, K(2) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(13), one O(4), one O(5), one O(6), and one O(9) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(7), one O(8), and one O(9) atom. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(2), one O(3), and one O(7) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(9) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(3) and one O(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(10) and one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) and one O(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(14) and one O(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(6) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one K(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one V(2) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one V(2), one H(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one K(2), one H(3), and one H(4) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one K(2), one H(2), one H(5), and one H(6) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one K(1), one K(2), one H(7), and one H(8) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one K(1), one V(1), one V(2), and one O(8) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one K(1), one V(1), one H(5), and one O(7) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one K(2), one V(1), one H(1), and one O(10) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one K(1), one V(1), one H(3), and one O(9) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one K(2), one V(1), one V(2), and one O(12) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one K(1), one K(2), one V(2), and one O(11) atom. In the thirteenth O site, O(13) is bonded in a 1-coordinate geometry to one K(1), one K(2), one V(2), and one O(14) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one V(2), one H(6), and one O(13) atom. is represented by the CIF file [CIF]
data_KVH4O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.573
_cell_length_b   8.140
_cell_length_c   7.512
_cell_angle_alpha   106.618
_cell_angle_beta   96.129
_cell_angle_gamma   115.645
_symmetry_Int_Tables_number   1
_cell_volume   334.645
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.008  0.006  0.973  1.0
  K  K1  1  0.622  0.440  0.562  1.0
  V  V2  1  0.401  0.879  0.755  1.0
  V  V3  1  0.255  0.578  0.967  1.0
  H  H4  1  0.292  0.672  0.349  1.0
  H  H5  1  0.015  0.581  0.226  1.0
  H  H6  1  0.698  0.050  0.498  1.0
  H  H7  1  0.629  0.059  0.297  1.0
  H  H8  1  0.688  0.334  0.116  1.0
  H  H9  1  0.675  0.534  0.157  1.0
  H  H10  1  0.025  0.176  0.400  1.0
  H  H11  1  0.160  0.063  0.418  1.0
  O  O12  1  0.251  0.962  0.654  1.0
  O  O13  1  0.134  0.340  0.904  1.0
  O  O14  1  0.187  0.651  0.226  1.0
  O  O15  1  0.735  0.141  0.427  1.0
  O  O16  1  0.747  0.468  0.212  1.0
  O  O17  1  0.163  0.165  0.372  1.0
  O  O18  1  0.408  0.958  0.022  1.0
  O  O19  1  0.624  0.088  0.985  1.0
  O  O20  1  0.443  0.702  0.546  1.0
  O  O21  1  0.647  0.899  0.633  1.0
  O  O22  1  0.136  0.615  0.736  1.0
  O  O23  1  0.012  0.632  0.885  1.0
  O  O24  1  0.546  0.659  0.905  1.0
  O  O25  1  0.574  0.689  0.109  1.0
[/CIF]
.
The compound described by KVH4O7 crystallizes in the triclinic P1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(2), one O(6), one O(7), and one O(8) atom. In the second K site, K(2) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(13), one O(4), one O(5), one O(6), and one O(9) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(7), one O(8), and one O(9) atom. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(2), one O(3), and one O(7) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(9) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(3) and one O(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(10) and one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) and one O(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(14) and one O(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(6) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one K(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one V(2) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one V(2), one H(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one K(2), one H(3), and one H(4) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one K(2), one H(2), one H(5), and one H(6) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one K(1), one K(2), one H(7), and one H(8) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one K(1), one V(1), one V(2), and one O(8) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one K(1), one V(1), one H(5), and one O(7) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one K(2), one V(1), one H(1), and one O(10) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one K(1), one V(1), one H(3), and one O(9) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one K(2), one V(1), one V(2), and one O(12) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one K(1), one K(2), one V(2), and one O(11) atom. In the thirteenth O site, O(13) is bonded in a 1-coordinate geometry to one K(1), one K(2), one V(2), and one O(14) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one V(2), one H(6), and one O(13) atom. is represented by the CIF file [CIF]
data_KVH4O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.573
_cell_length_b   8.140
_cell_length_c   7.512
_cell_angle_alpha   106.618
_cell_angle_beta   96.129
_cell_angle_gamma   115.645
_symmetry_Int_Tables_number   1
_cell_volume   334.645
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.008  0.006  0.973  1.0
  K  K1  1  0.622  0.440  0.562  1.0
  V  V2  1  0.401  0.879  0.755  1.0
  V  V3  1  0.255  0.578  0.967  1.0
  H  H4  1  0.292  0.672  0.349  1.0
  H  H5  1  0.015  0.581  0.226  1.0
  H  H6  1  0.698  0.050  0.498  1.0
  H  H7  1  0.629  0.059  0.297  1.0
  H  H8  1  0.688  0.334  0.116  1.0
  H  H9  1  0.675  0.534  0.157  1.0
  H  H10  1  0.025  0.176  0.400  1.0
  H  H11  1  0.160  0.063  0.418  1.0
  O  O12  1  0.251  0.962  0.654  1.0
  O  O13  1  0.134  0.340  0.904  1.0
  O  O14  1  0.187  0.651  0.226  1.0
  O  O15  1  0.735  0.141  0.427  1.0
  O  O16  1  0.747  0.468  0.212  1.0
  O  O17  1  0.163  0.165  0.372  1.0
  O  O18  1  0.408  0.958  0.022  1.0
  O  O19  1  0.624  0.088  0.985  1.0
  O  O20  1  0.443  0.702  0.546  1.0
  O  O21  1  0.647  0.899  0.633  1.0
  O  O22  1  0.136  0.615  0.736  1.0
  O  O23  1  0.012  0.632  0.885  1.0
  O  O24  1  0.546  0.659  0.905  1.0
  O  O25  1  0.574  0.689  0.109  1.0
[/CIF]
.