The crystal structure described by NH2SF4AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two NH2SF4 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3,5) atoms. There are two inequivalent F sites. In the first F site, F(1,3,5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each NH2SF4 cluster, N(1) is bonded in a trigonal planar geometry to one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a trigonal bipyramidal geometry to one N(1), one F(10), one F(7), one F(8), and one F(9) atom. There are four inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(9) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_AsH2SNF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.646
_cell_length_b   6.898
_cell_length_c   10.738
_cell_angle_alpha   89.155
_cell_angle_beta   87.877
_cell_angle_gamma   75.355
_symmetry_Int_Tables_number   1
_cell_volume   404.328
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.000  0.000  0.500  1.0
  As  As1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.580  0.897  0.341  1.0
  H  H3  1  0.420  0.103  0.659  1.0
  H  H4  1  0.516  0.911  0.179  1.0
  H  H5  1  0.484  0.089  0.821  1.0
  S  S6  1  0.635  0.597  0.251  1.0
  S  S7  1  0.365  0.403  0.749  1.0
  N  N8  1  0.566  0.828  0.258  1.0
  N  N9  1  0.434  0.172  0.742  1.0
  F  F10  1  0.126  0.136  0.386  1.0
  F  F11  1  0.874  0.864  0.614  1.0
  F  F12  1  0.704  0.086  0.434  1.0
  F  F13  1  0.296  0.914  0.566  1.0
  F  F14  1  0.065  0.790  0.400  1.0
  F  F15  1  0.935  0.210  0.600  1.0
  F  F16  1  0.783  0.122  0.116  1.0
  F  F17  1  0.217  0.878  0.884  1.0
  F  F18  1  0.935  0.220  0.907  1.0
  F  F19  1  0.065  0.780  0.093  1.0
  F  F20  1  0.764  0.918  0.928  1.0
  F  F21  1  0.236  0.082  0.072  1.0
  F  F22  1  0.672  0.577  0.397  1.0
  F  F23  1  0.328  0.423  0.603  1.0
  F  F24  1  0.898  0.465  0.229  1.0
  F  F25  1  0.102  0.535  0.771  1.0
  F  F26  1  0.459  0.457  0.265  1.0
  F  F27  1  0.541  0.543  0.735  1.0
  F  F28  1  0.597  0.602  0.105  1.0
  F  F29  1  0.403  0.398  0.895  1.0
[/CIF]
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The crystal structure described by NH2SF4AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two NH2SF4 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3,5) atoms. There are two inequivalent F sites. In the first F site, F(1,3,5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each NH2SF4 cluster, N(1) is bonded in a trigonal planar geometry to one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a trigonal bipyramidal geometry to one N(1), one F(10), one F(7), one F(8), and one F(9) atom. There are four inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(9) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_AsH2SNF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.646
_cell_length_b   6.898
_cell_length_c   10.738
_cell_angle_alpha   89.155
_cell_angle_beta   87.877
_cell_angle_gamma   75.355
_symmetry_Int_Tables_number   1
_cell_volume   404.328
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.000  0.000  0.500  1.0
  As  As1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.580  0.897  0.341  1.0
  H  H3  1  0.420  0.103  0.659  1.0
  H  H4  1  0.516  0.911  0.179  1.0
  H  H5  1  0.484  0.089  0.821  1.0
  S  S6  1  0.635  0.597  0.251  1.0
  S  S7  1  0.365  0.403  0.749  1.0
  N  N8  1  0.566  0.828  0.258  1.0
  N  N9  1  0.434  0.172  0.742  1.0
  F  F10  1  0.126  0.136  0.386  1.0
  F  F11  1  0.874  0.864  0.614  1.0
  F  F12  1  0.704  0.086  0.434  1.0
  F  F13  1  0.296  0.914  0.566  1.0
  F  F14  1  0.065  0.790  0.400  1.0
  F  F15  1  0.935  0.210  0.600  1.0
  F  F16  1  0.783  0.122  0.116  1.0
  F  F17  1  0.217  0.878  0.884  1.0
  F  F18  1  0.935  0.220  0.907  1.0
  F  F19  1  0.065  0.780  0.093  1.0
  F  F20  1  0.764  0.918  0.928  1.0
  F  F21  1  0.236  0.082  0.072  1.0
  F  F22  1  0.672  0.577  0.397  1.0
  F  F23  1  0.328  0.423  0.603  1.0
  F  F24  1  0.898  0.465  0.229  1.0
  F  F25  1  0.102  0.535  0.771  1.0
  F  F26  1  0.459  0.457  0.265  1.0
  F  F27  1  0.541  0.543  0.735  1.0
  F  F28  1  0.597  0.602  0.105  1.0
  F  F29  1  0.403  0.398  0.895  1.0
[/CIF]
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