The material described by AlPH8(CCl)3 is alpha U structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two AlPH8(CCl)3 clusters. Al(1) is bonded to one P(1), one Cl(1), one Cl(2), and one Cl(3) atom to form AlPCl3 tetrahedra that share  a cornercorner with one C(1)PH3 tetrahedra and  a cornercorner with one C(2)PH3 tetrahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded to one P(1), one H(1), one H(3), and one H(5) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one Al(1)PCl3 tetrahedra and  a cornercorner with one C(2)PH3 tetrahedra. In the second C site, C(2) is bonded to one P(1), one H(2), one H(4), and one H(6) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one Al(1)PCl3 tetrahedra and  a cornercorner with one C(1)PH3 tetrahedra. In the third C site, C(3) is bonded in a trigonal planar geometry to one P(1), one H(7), and one H(8) atom. P(1) is bonded in a tetrahedral geometry to one Al(1), one C(1), one C(2), and one C(3) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF card [CIF]
data_AlPH8(CCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.845
_cell_length_b   7.994
_cell_length_c   10.833
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   113.276
_symmetry_Int_Tables_number   1
_cell_volume   544.502
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.403  0.923  0.750  1.0
  Al  Al1  1  0.597  0.077  0.250  1.0
  P  P2  1  0.425  0.235  0.749  1.0
  P  P3  1  0.575  0.765  0.249  1.0
  H  H4  1  0.367  0.256  0.531  1.0
  H  H5  1  0.633  0.744  0.031  1.0
  H  H6  1  0.629  0.742  0.468  1.0
  H  H7  1  0.371  0.258  0.968  1.0
  H  H8  1  0.122  0.193  0.615  1.0
  H  H9  1  0.878  0.807  0.115  1.0
  H  H10  1  0.870  0.803  0.383  1.0
  H  H11  1  0.130  0.197  0.883  1.0
  H  H12  1  0.315  0.425  0.618  1.0
  H  H13  1  0.685  0.575  0.118  1.0
  H  H14  1  0.682  0.572  0.382  1.0
  H  H15  1  0.318  0.428  0.882  1.0
  H  H16  1  0.721  0.543  0.766  1.0
  H  H17  1  0.279  0.457  0.266  1.0
  H  H18  1  0.802  0.379  0.677  1.0
  H  H19  1  0.198  0.621  0.177  1.0
  C  C20  1  0.293  0.281  0.615  1.0
  C  C21  1  0.707  0.719  0.115  1.0
  C  C22  1  0.700  0.715  0.384  1.0
  C  C23  1  0.300  0.285  0.884  1.0
  C  C24  1  0.686  0.404  0.735  1.0
  C  C25  1  0.314  0.596  0.235  1.0
  Cl  Cl26  1  0.719  0.926  0.750  1.0
  Cl  Cl27  1  0.281  0.074  0.250  1.0
  Cl  Cl28  1  0.231  0.793  0.587  1.0
  Cl  Cl29  1  0.769  0.207  0.087  1.0
  Cl  Cl30  1  0.769  0.206  0.413  1.0
  Cl  Cl31  1  0.231  0.794  0.913  1.0
[/CIF]
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The material described by AlPH8(CCl)3 is alpha U structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two AlPH8(CCl)3 clusters. Al(1) is bonded to one P(1), one Cl(1), one Cl(2), and one Cl(3) atom to form AlPCl3 tetrahedra that share  a cornercorner with one C(1)PH3 tetrahedra and  a cornercorner with one C(2)PH3 tetrahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded to one P(1), one H(1), one H(3), and one H(5) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one Al(1)PCl3 tetrahedra and  a cornercorner with one C(2)PH3 tetrahedra. In the second C site, C(2) is bonded to one P(1), one H(2), one H(4), and one H(6) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one Al(1)PCl3 tetrahedra and  a cornercorner with one C(1)PH3 tetrahedra. In the third C site, C(3) is bonded in a trigonal planar geometry to one P(1), one H(7), and one H(8) atom. P(1) is bonded in a tetrahedral geometry to one Al(1), one C(1), one C(2), and one C(3) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF card [CIF]
data_AlPH8(CCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.845
_cell_length_b   7.994
_cell_length_c   10.833
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   113.276
_symmetry_Int_Tables_number   1
_cell_volume   544.502
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.403  0.923  0.750  1.0
  Al  Al1  1  0.597  0.077  0.250  1.0
  P  P2  1  0.425  0.235  0.749  1.0
  P  P3  1  0.575  0.765  0.249  1.0
  H  H4  1  0.367  0.256  0.531  1.0
  H  H5  1  0.633  0.744  0.031  1.0
  H  H6  1  0.629  0.742  0.468  1.0
  H  H7  1  0.371  0.258  0.968  1.0
  H  H8  1  0.122  0.193  0.615  1.0
  H  H9  1  0.878  0.807  0.115  1.0
  H  H10  1  0.870  0.803  0.383  1.0
  H  H11  1  0.130  0.197  0.883  1.0
  H  H12  1  0.315  0.425  0.618  1.0
  H  H13  1  0.685  0.575  0.118  1.0
  H  H14  1  0.682  0.572  0.382  1.0
  H  H15  1  0.318  0.428  0.882  1.0
  H  H16  1  0.721  0.543  0.766  1.0
  H  H17  1  0.279  0.457  0.266  1.0
  H  H18  1  0.802  0.379  0.677  1.0
  H  H19  1  0.198  0.621  0.177  1.0
  C  C20  1  0.293  0.281  0.615  1.0
  C  C21  1  0.707  0.719  0.115  1.0
  C  C22  1  0.700  0.715  0.384  1.0
  C  C23  1  0.300  0.285  0.884  1.0
  C  C24  1  0.686  0.404  0.735  1.0
  C  C25  1  0.314  0.596  0.235  1.0
  Cl  Cl26  1  0.719  0.926  0.750  1.0
  Cl  Cl27  1  0.281  0.074  0.250  1.0
  Cl  Cl28  1  0.231  0.793  0.587  1.0
  Cl  Cl29  1  0.769  0.207  0.087  1.0
  Cl  Cl30  1  0.769  0.206  0.413  1.0
  Cl  Cl31  1  0.231  0.794  0.913  1.0
[/CIF]
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