The crystal structure described by Pt5P2 crystallizes in the monoclinic C2/c space group. There are three inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a distorted water-like geometry to four equivalent Pt(2) and two equivalent P(1) atoms. In the second Pt site, Pt(2) is bonded in a 10-coordinate geometry to one Pt(2), two equivalent Pt(3), four equivalent Pt(1), and three equivalent P(1) atoms. In the third Pt site, Pt(3) is bonded in a distorted L-shaped geometry to four equivalent Pt(2) and two equivalent P(1) atoms. P(1) is bonded in a 6-coordinate geometry to one Pt(3), two equivalent Pt(1), and three equivalent Pt(2) atoms. is represented by the CIF card [CIF]
data_P2Pt5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.412
_cell_length_b   6.074
_cell_length_c   7.468
_cell_angle_alpha   98.622
_cell_angle_beta   90.000
_cell_angle_gamma   116.459
_symmetry_Int_Tables_number   1
_cell_volume   216.675
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.436  0.683  0.224  1.0
  P  P1  1  0.753  0.317  0.276  1.0
  P  P2  1  0.564  0.317  0.776  1.0
  P  P3  1  0.247  0.683  0.724  1.0
  Pt  Pt4  1  0.844  0.238  0.969  1.0
  Pt  Pt5  1  0.606  0.762  0.531  1.0
  Pt  Pt6  1  0.920  0.289  0.596  1.0
  Pt  Pt7  1  0.631  0.711  0.904  1.0
  Pt  Pt8  1  0.080  0.711  0.404  1.0
  Pt  Pt9  1  0.369  0.289  0.096  1.0
  Pt  Pt10  1  0.394  0.238  0.469  1.0
  Pt  Pt11  1  0.156  0.762  0.031  1.0
  Pt  Pt12  1  0.111  0.000  0.750  1.0
  Pt  Pt13  1  0.889  0.000  0.250  1.0
[/CIF]
.
The crystal structure described by Pt5P2 crystallizes in the monoclinic C2/c space group. There are three inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a distorted water-like geometry to four equivalent Pt(2) and two equivalent P(1) atoms. In the second Pt site, Pt(2) is bonded in a 10-coordinate geometry to one Pt(2), two equivalent Pt(3), four equivalent Pt(1), and three equivalent P(1) atoms. In the third Pt site, Pt(3) is bonded in a distorted L-shaped geometry to four equivalent Pt(2) and two equivalent P(1) atoms. P(1) is bonded in a 6-coordinate geometry to one Pt(3), two equivalent Pt(1), and three equivalent Pt(2) atoms. is represented by the CIF card [CIF]
data_P2Pt5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.412
_cell_length_b   6.074
_cell_length_c   7.468
_cell_angle_alpha   98.622
_cell_angle_beta   90.000
_cell_angle_gamma   116.459
_symmetry_Int_Tables_number   1
_cell_volume   216.675
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.436  0.683  0.224  1.0
  P  P1  1  0.753  0.317  0.276  1.0
  P  P2  1  0.564  0.317  0.776  1.0
  P  P3  1  0.247  0.683  0.724  1.0
  Pt  Pt4  1  0.844  0.238  0.969  1.0
  Pt  Pt5  1  0.606  0.762  0.531  1.0
  Pt  Pt6  1  0.920  0.289  0.596  1.0
  Pt  Pt7  1  0.631  0.711  0.904  1.0
  Pt  Pt8  1  0.080  0.711  0.404  1.0
  Pt  Pt9  1  0.369  0.289  0.096  1.0
  Pt  Pt10  1  0.394  0.238  0.469  1.0
  Pt  Pt11  1  0.156  0.762  0.031  1.0
  Pt  Pt12  1  0.111  0.000  0.750  1.0
  Pt  Pt13  1  0.889  0.000  0.250  1.0
[/CIF]
.