The material described by TmSb(PbO3)2 crystallizes in the trigonal R-3 space group. Tm(1) is bonded to six equivalent O(1) atoms to form TmO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 21°. Pb(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Tm(1)O6 octahedra. The corner-sharing octahedral tilt angles are 21°. O(1) is bonded in a 3-coordinate geometry to one Tm(1), one Pb(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_TmSb(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.870
_cell_length_b   5.870
_cell_length_c   5.870
_cell_angle_alpha   60.416
_cell_angle_beta   60.416
_cell_angle_gamma   60.416
_symmetry_Int_Tables_number   1
_cell_volume   144.338
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.500  0.500  0.500  1.0
  Pb  Pb2  1  0.250  0.250  0.250  1.0
  Pb  Pb3  1  0.750  0.750  0.750  1.0
  O  O4  1  0.674  0.802  0.265  1.0
  O  O5  1  0.265  0.674  0.802  1.0
  O  O6  1  0.802  0.265  0.674  1.0
  O  O7  1  0.326  0.198  0.735  1.0
  O  O8  1  0.735  0.326  0.198  1.0
  O  O9  1  0.198  0.735  0.326  1.0
[/CIF]
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The material described by TmSb(PbO3)2 crystallizes in the trigonal R-3 space group. Tm(1) is bonded to six equivalent O(1) atoms to form TmO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 21°. Pb(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Tm(1)O6 octahedra. The corner-sharing octahedral tilt angles are 21°. O(1) is bonded in a 3-coordinate geometry to one Tm(1), one Pb(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_TmSb(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.870
_cell_length_b   5.870
_cell_length_c   5.870
_cell_angle_alpha   60.416
_cell_angle_beta   60.416
_cell_angle_gamma   60.416
_symmetry_Int_Tables_number   1
_cell_volume   144.338
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.500  0.500  0.500  1.0
  Pb  Pb2  1  0.250  0.250  0.250  1.0
  Pb  Pb3  1  0.750  0.750  0.750  1.0
  O  O4  1  0.674  0.802  0.265  1.0
  O  O5  1  0.265  0.674  0.802  1.0
  O  O6  1  0.802  0.265  0.674  1.0
  O  O7  1  0.326  0.198  0.735  1.0
  O  O8  1  0.735  0.326  0.198  1.0
  O  O9  1  0.198  0.735  0.326  1.0
[/CIF]
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