The material described by K2VAgS2 crystallizes in the orthorhombic Fddd space group. K(1) is bonded in a 12-coordinate geometry to three equivalent K(1), three equivalent V(1), two equivalent Ag(1), and four equivalent S(1) atoms. V(1) is bonded in a 4-coordinate geometry to six equivalent K(1) and four equivalent S(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent K(1) and two equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent K(1), two equivalent V(1), and one Ag(1) atom. is represented by the CIF file [CIF]
data_K2VAgS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.899
_cell_length_b   7.485
_cell_length_c   13.417
_cell_angle_alpha   69.364
_cell_angle_beta   63.678
_cell_angle_gamma   37.363
_symmetry_Int_Tables_number   1
_cell_volume   650.035
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.748  0.174  0.553  1.0
  K  K1  1  0.699  0.826  0.553  1.0
  K  K2  1  0.079  0.174  0.447  1.0
  K  K3  1  0.002  0.326  0.947  1.0
  K  K4  1  0.474  0.826  0.447  1.0
  K  K5  1  0.051  0.674  0.947  1.0
  K  K6  1  0.671  0.326  0.053  1.0
  K  K7  1  0.276  0.674  0.053  1.0
  V  V8  1  0.875  0.250  0.250  1.0
  V  V9  1  0.875  0.750  0.250  1.0
  V  V10  1  0.875  0.250  0.750  1.0
  V  V11  1  0.375  0.750  0.750  1.0
  Ag  Ag12  1  0.375  0.250  0.250  1.0
  Ag  Ag13  1  0.375  0.750  0.250  1.0
  Ag  Ag14  1  0.375  0.250  0.750  1.0
  Ag  Ag15  1  0.875  0.750  0.750  1.0
  S  S16  1  0.123  0.215  0.177  1.0
  S  S17  1  0.701  0.785  0.177  1.0
  S  S18  1  0.662  0.215  0.823  1.0
  S  S19  1  0.627  0.285  0.323  1.0
  S  S20  1  0.514  0.785  0.823  1.0
  S  S21  1  0.049  0.715  0.323  1.0
  S  S22  1  0.088  0.285  0.677  1.0
  S  S23  1  0.236  0.715  0.677  1.0
[/CIF]
.
The material described by K2VAgS2 crystallizes in the orthorhombic Fddd space group. K(1) is bonded in a 12-coordinate geometry to three equivalent K(1), three equivalent V(1), two equivalent Ag(1), and four equivalent S(1) atoms. V(1) is bonded in a 4-coordinate geometry to six equivalent K(1) and four equivalent S(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent K(1) and two equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent K(1), two equivalent V(1), and one Ag(1) atom. is represented by the CIF file [CIF]
data_K2VAgS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.899
_cell_length_b   7.485
_cell_length_c   13.417
_cell_angle_alpha   69.364
_cell_angle_beta   63.678
_cell_angle_gamma   37.363
_symmetry_Int_Tables_number   1
_cell_volume   650.035
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.748  0.174  0.553  1.0
  K  K1  1  0.699  0.826  0.553  1.0
  K  K2  1  0.079  0.174  0.447  1.0
  K  K3  1  0.002  0.326  0.947  1.0
  K  K4  1  0.474  0.826  0.447  1.0
  K  K5  1  0.051  0.674  0.947  1.0
  K  K6  1  0.671  0.326  0.053  1.0
  K  K7  1  0.276  0.674  0.053  1.0
  V  V8  1  0.875  0.250  0.250  1.0
  V  V9  1  0.875  0.750  0.250  1.0
  V  V10  1  0.875  0.250  0.750  1.0
  V  V11  1  0.375  0.750  0.750  1.0
  Ag  Ag12  1  0.375  0.250  0.250  1.0
  Ag  Ag13  1  0.375  0.750  0.250  1.0
  Ag  Ag14  1  0.375  0.250  0.750  1.0
  Ag  Ag15  1  0.875  0.750  0.750  1.0
  S  S16  1  0.123  0.215  0.177  1.0
  S  S17  1  0.701  0.785  0.177  1.0
  S  S18  1  0.662  0.215  0.823  1.0
  S  S19  1  0.627  0.285  0.323  1.0
  S  S20  1  0.514  0.785  0.823  1.0
  S  S21  1  0.049  0.715  0.323  1.0
  S  S22  1  0.088  0.285  0.677  1.0
  S  S23  1  0.236  0.715  0.677  1.0
[/CIF]
.