The structure described by Li3MnCO3PO4 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent P(1)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 66-88°. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(2), one O(6), and two equivalent O(4) atoms. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form distorted MnO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra, corners with four equivalent Li(1)O5 trigonal bipyramids, and edges with two equivalent Li(1)O5 trigonal bipyramids. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(6) atom. P(1) is bonded to one O(3), one O(5), and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with four equivalent Mn(1)O6 octahedra and corners with six equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 47-64°. There are six inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one Mn(1), and one C(1) atom to form distorted OLi2MnC trigonal pyramids that share corners with three equivalent O(5)Li2MnP tetrahedra, corners with three equivalent O(6)Li3C tetrahedra,  a cornercorner with one O(3)Li2MnP trigonal pyramid, corners with four equivalent O(4)Li2MnP trigonal pyramids, and  an edgeedge with one O(3)Li2MnP trigonal pyramid. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Li(2), one Mn(1), and one C(1) atom. In the third O site, O(3) is bonded to two equivalent Li(1), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(6)Li3C tetrahedra, corners with four equivalent O(5)Li2MnP tetrahedra,  a cornercorner with one O(1)Li2MnC trigonal pyramid, corners with two equivalent O(4)Li2MnP trigonal pyramids,  an edgeedge with one O(1)Li2MnC trigonal pyramid, and edges with two equivalent O(4)Li2MnP trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(6)Li3C tetrahedra, corners with three equivalent O(5)Li2MnP tetrahedra,  a cornercorner with one O(3)Li2MnP trigonal pyramid,  a cornercorner with one O(4)Li2MnP trigonal pyramid, corners with two equivalent O(1)Li2MnC trigonal pyramids,  an edgeedge with one O(3)Li2MnP trigonal pyramid, and  an edgeedge with one O(4)Li2MnP trigonal pyramid. In the fifth O site, O(5) is bonded to two equivalent Li(1), one Mn(1), and one P(1) atom to form OLi2MnP tetrahedra that share corners with three equivalent O(1)Li2MnC trigonal pyramids, corners with four equivalent O(3)Li2MnP trigonal pyramids, corners with six equivalent O(4)Li2MnP trigonal pyramids, and  an edgeedge with one O(6)Li3C tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), two equivalent Li(1), and one C(1) atom to form OLi3C tetrahedra that share corners with two equivalent O(3)Li2MnP trigonal pyramids, corners with three equivalent O(1)Li2MnC trigonal pyramids, corners with four equivalent O(4)Li2MnP trigonal pyramids, and  an edgeedge with one O(5)Li2MnP tetrahedra. is represented by the CIF file [CIF]
data_Li3MnPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.021
_cell_length_b   6.581
_cell_length_c   8.638
_cell_angle_alpha   90.000
_cell_angle_beta   83.452
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   283.526
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.729  0.978  0.732  1.0
  Li  Li1  1  0.271  0.022  0.268  1.0
  Li  Li2  1  0.800  0.250  0.103  1.0
  Li  Li3  1  0.200  0.750  0.897  1.0
  Li  Li4  1  0.271  0.478  0.268  1.0
  Li  Li5  1  0.729  0.522  0.732  1.0
  Mn  Mn6  1  0.781  0.750  0.341  1.0
  Mn  Mn7  1  0.219  0.250  0.659  1.0
  P  P8  1  0.738  0.250  0.407  1.0
  P  P9  1  0.263  0.750  0.593  1.0
  C  C10  1  0.671  0.750  0.039  1.0
  C  C11  1  0.329  0.250  0.961  1.0
  O  O12  1  0.512  0.250  0.839  1.0
  O  O13  1  0.919  0.750  0.064  1.0
  O  O14  1  0.175  0.750  0.428  1.0
  O  O15  1  0.488  0.750  0.161  1.0
  O  O16  1  0.152  0.566  0.694  1.0
  O  O17  1  0.825  0.250  0.572  1.0
  O  O18  1  0.152  0.934  0.694  1.0
  O  O19  1  0.848  0.434  0.306  1.0
  O  O20  1  0.848  0.066  0.306  1.0
  O  O21  1  0.424  0.250  0.422  1.0
  O  O22  1  0.598  0.750  0.899  1.0
  O  O23  1  0.401  0.250  0.101  1.0
  O  O24  1  0.576  0.750  0.578  1.0
  O  O25  1  0.081  0.250  0.936  1.0
[/CIF]
.
The structure described by Li3MnCO3PO4 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent P(1)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 66-88°. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(2), one O(6), and two equivalent O(4) atoms. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form distorted MnO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra, corners with four equivalent Li(1)O5 trigonal bipyramids, and edges with two equivalent Li(1)O5 trigonal bipyramids. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(6) atom. P(1) is bonded to one O(3), one O(5), and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with four equivalent Mn(1)O6 octahedra and corners with six equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 47-64°. There are six inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one Mn(1), and one C(1) atom to form distorted OLi2MnC trigonal pyramids that share corners with three equivalent O(5)Li2MnP tetrahedra, corners with three equivalent O(6)Li3C tetrahedra,  a cornercorner with one O(3)Li2MnP trigonal pyramid, corners with four equivalent O(4)Li2MnP trigonal pyramids, and  an edgeedge with one O(3)Li2MnP trigonal pyramid. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Li(2), one Mn(1), and one C(1) atom. In the third O site, O(3) is bonded to two equivalent Li(1), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(6)Li3C tetrahedra, corners with four equivalent O(5)Li2MnP tetrahedra,  a cornercorner with one O(1)Li2MnC trigonal pyramid, corners with two equivalent O(4)Li2MnP trigonal pyramids,  an edgeedge with one O(1)Li2MnC trigonal pyramid, and edges with two equivalent O(4)Li2MnP trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(6)Li3C tetrahedra, corners with three equivalent O(5)Li2MnP tetrahedra,  a cornercorner with one O(3)Li2MnP trigonal pyramid,  a cornercorner with one O(4)Li2MnP trigonal pyramid, corners with two equivalent O(1)Li2MnC trigonal pyramids,  an edgeedge with one O(3)Li2MnP trigonal pyramid, and  an edgeedge with one O(4)Li2MnP trigonal pyramid. In the fifth O site, O(5) is bonded to two equivalent Li(1), one Mn(1), and one P(1) atom to form OLi2MnP tetrahedra that share corners with three equivalent O(1)Li2MnC trigonal pyramids, corners with four equivalent O(3)Li2MnP trigonal pyramids, corners with six equivalent O(4)Li2MnP trigonal pyramids, and  an edgeedge with one O(6)Li3C tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), two equivalent Li(1), and one C(1) atom to form OLi3C tetrahedra that share corners with two equivalent O(3)Li2MnP trigonal pyramids, corners with three equivalent O(1)Li2MnC trigonal pyramids, corners with four equivalent O(4)Li2MnP trigonal pyramids, and  an edgeedge with one O(5)Li2MnP tetrahedra. is represented by the CIF file [CIF]
data_Li3MnPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.021
_cell_length_b   6.581
_cell_length_c   8.638
_cell_angle_alpha   90.000
_cell_angle_beta   83.452
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   283.526
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.729  0.978  0.732  1.0
  Li  Li1  1  0.271  0.022  0.268  1.0
  Li  Li2  1  0.800  0.250  0.103  1.0
  Li  Li3  1  0.200  0.750  0.897  1.0
  Li  Li4  1  0.271  0.478  0.268  1.0
  Li  Li5  1  0.729  0.522  0.732  1.0
  Mn  Mn6  1  0.781  0.750  0.341  1.0
  Mn  Mn7  1  0.219  0.250  0.659  1.0
  P  P8  1  0.738  0.250  0.407  1.0
  P  P9  1  0.263  0.750  0.593  1.0
  C  C10  1  0.671  0.750  0.039  1.0
  C  C11  1  0.329  0.250  0.961  1.0
  O  O12  1  0.512  0.250  0.839  1.0
  O  O13  1  0.919  0.750  0.064  1.0
  O  O14  1  0.175  0.750  0.428  1.0
  O  O15  1  0.488  0.750  0.161  1.0
  O  O16  1  0.152  0.566  0.694  1.0
  O  O17  1  0.825  0.250  0.572  1.0
  O  O18  1  0.152  0.934  0.694  1.0
  O  O19  1  0.848  0.434  0.306  1.0
  O  O20  1  0.848  0.066  0.306  1.0
  O  O21  1  0.424  0.250  0.422  1.0
  O  O22  1  0.598  0.750  0.899  1.0
  O  O23  1  0.401  0.250  0.101  1.0
  O  O24  1  0.576  0.750  0.578  1.0
  O  O25  1  0.081  0.250  0.936  1.0
[/CIF]
.