The material structure described by Fe10OF19 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one F(12), one F(13), one F(16), one F(5), and one F(8) atom to form FeOF5 octahedra that share corners with two equivalent Fe(7)F6 octahedra, corners with two equivalent Fe(8)OF5 octahedra, corners with four equivalent Fe(10)OF5 octahedra,  an edgeedge with one Fe(3)F6 octahedra, and  an edgeedge with one Fe(5)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. In the second Fe site, Fe(2) is bonded to one F(10), one F(14), one F(18), one F(4), one F(6), and one F(9) atom to form FeF6 octahedra that share corners with two equivalent Fe(9)F6 octahedra, corners with two equivalent Fe(8)OF5 octahedra, corners with four equivalent Fe(6)F6 octahedra,  an edgeedge with one Fe(3)F6 octahedra, and  an edgeedge with one Fe(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the third Fe site, Fe(3) is bonded to one F(1), one F(10), one F(12), one F(15), one F(5), and one F(9) atom to form FeF6 octahedra that share corners with two equivalent Fe(6)F6 octahedra, corners with two equivalent Fe(10)OF5 octahedra, corners with four equivalent Fe(8)OF5 octahedra,  an edgeedge with one Fe(2)F6 octahedra, and  an edgeedge with one Fe(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 40-54°. In the fourth Fe site, Fe(4) is bonded to one F(11), one F(14), one F(17), one F(3), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing FeF6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the fifth Fe site, Fe(5) is bonded to one F(11), one F(13), one F(19), one F(2), one F(7), and one F(8) atom to form FeF6 octahedra that share corners with two equivalent Fe(9)F6 octahedra, corners with two equivalent Fe(10)OF5 octahedra, corners with four equivalent Fe(7)F6 octahedra,  an edgeedge with one Fe(4)F6 octahedra, and  an edgeedge with one Fe(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the sixth Fe site, Fe(6) is bonded to one F(1), one F(10), one F(17), one F(18), one F(4), and one F(6) atom to form FeF6 octahedra that share corners with two equivalent Fe(3)F6 octahedra, corners with two equivalent Fe(4)F6 octahedra, corners with four equivalent Fe(2)F6 octahedra,  an edgeedge with one Fe(9)F6 octahedra, and  an edgeedge with one Fe(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. In the seventh Fe site, Fe(7) is bonded to one F(11), one F(16), one F(19), one F(2), one F(3), and one F(8) atom to form FeF6 octahedra that share corners with two equivalent Fe(4)F6 octahedra, corners with two equivalent Fe(1)OF5 octahedra, corners with four equivalent Fe(5)F6 octahedra,  an edgeedge with one Fe(9)F6 octahedra, and  an edgeedge with one Fe(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the eighth Fe site, Fe(8) is bonded to one O(1), one F(1), one F(12), one F(15), one F(18), and one F(9) atom to form FeOF5 octahedra that share corners with two equivalent Fe(2)F6 octahedra, corners with two equivalent Fe(1)OF5 octahedra, corners with four equivalent Fe(3)F6 octahedra,  an edgeedge with one Fe(6)F6 octahedra, and  an edgeedge with one Fe(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. In the ninth Fe site, Fe(9) is bonded to one F(14), one F(17), one F(19), one F(3), one F(4), and one F(7) atom to form a mixture of edge and corner-sharing FeF6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the tenth Fe site, Fe(10) is bonded to one O(1), one F(13), one F(15), one F(16), one F(2), and one F(5) atom to form FeOF5 octahedra that share corners with two equivalent Fe(3)F6 octahedra, corners with two equivalent Fe(5)F6 octahedra, corners with four equivalent Fe(1)OF5 octahedra,  an edgeedge with one Fe(7)F6 octahedra, and  an edgeedge with one Fe(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 40-55°. O(1) is bonded in a trigonal planar geometry to one Fe(1), one Fe(10), and one Fe(8) atom. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Fe(3), one Fe(6), and one Fe(8) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Fe(10), one Fe(5), and one Fe(7) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Fe(4), one Fe(7), and one Fe(9) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Fe(2), one Fe(6), and one Fe(9) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(10), and one Fe(3) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Fe(2), one Fe(4), and one Fe(6) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Fe(4), one Fe(5), and one Fe(9) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(5), and one Fe(7) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Fe(2), one Fe(3), and one Fe(8) atom. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Fe(2), one Fe(3), and one Fe(6) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Fe(4), one Fe(5), and one Fe(7) atom. In the twelfth F site, F(12) is bonded in a trigonal planar geometry to one Fe(1), one Fe(3), and one Fe(8) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(10), and one Fe(5) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Fe(2), one Fe(4), and one Fe(9) atom. In the fifteenth F site, F(15) is bonded in a distorted T-shaped geometry to one Fe(10), one Fe(3), and one Fe(8) atom. In the sixteenth F site, F(16) is bonded in a trigonal planar geometry to one Fe(1), one Fe(10), and one Fe(7) atom. In the seventeenth F site, F(17) is bonded in a trigonal planar geometry to one Fe(4), one Fe(6), and one Fe(9) atom. In the eighteenth F site, F(18) is bonded in a trigonal planar geometry to one Fe(2), one Fe(6), and one Fe(8) atom. In the nineteenth F site, F(19) is bonded in a trigonal planar geometry to one Fe(5), one Fe(7), and one Fe(9) atom. is represented by the CIF file [CIF]
data_Fe10OF19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.810
_cell_length_b   5.830
_cell_length_c   13.816
_cell_angle_alpha   80.208
_cell_angle_beta   89.788
_cell_angle_gamma   89.810
_symmetry_Int_Tables_number   1
_cell_volume   381.755
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.516  0.491  0.997  1.0
  Fe  Fe1  1  0.496  0.301  0.602  1.0
  Fe  Fe2  1  0.503  0.896  0.801  1.0
  Fe  Fe3  1  0.501  0.699  0.399  1.0
  Fe  Fe4  1  0.498  0.102  0.199  1.0
  Fe  Fe5  1  0.999  0.798  0.602  1.0
  Fe  Fe6  1  0.005  0.603  0.195  1.0
  Fe  Fe7  1  0.988  0.397  0.808  1.0
  Fe  Fe8  1  0.999  0.201  0.400  1.0
  Fe  Fe9  1  0.985  0.023  0.996  1.0
  O  O10  1  0.810  0.300  0.946  1.0
  F  F11  1  0.799  0.719  0.741  1.0
  F  F12  1  0.805  0.931  0.132  1.0
  F  F13  1  0.802  0.524  0.337  1.0
  F  F14  1  0.796  0.121  0.539  1.0
  F  F15  1  0.713  0.819  0.942  1.0
  F  F16  1  0.699  0.620  0.540  1.0
  F  F17  1  0.703  0.020  0.337  1.0
  F  F18  1  0.692  0.428  0.142  1.0
  F  F19  1  0.702  0.215  0.740  1.0
  F  F20  1  0.298  0.977  0.661  1.0
  F  F21  1  0.303  0.780  0.257  1.0
  F  F22  1  0.305  0.578  0.860  1.0
  F  F23  1  0.291  0.177  0.062  1.0
  F  F24  1  0.298  0.380  0.460  1.0
  F  F25  1  0.204  0.061  0.868  1.0
  F  F26  1  0.199  0.703  0.053  1.0
  F  F27  1  0.199  0.878  0.460  1.0
  F  F28  1  0.196  0.476  0.665  1.0
  F  F29  1  0.197  0.281  0.258  1.0
[/CIF]
.
The material structure described by Fe10OF19 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one F(12), one F(13), one F(16), one F(5), and one F(8) atom to form FeOF5 octahedra that share corners with two equivalent Fe(7)F6 octahedra, corners with two equivalent Fe(8)OF5 octahedra, corners with four equivalent Fe(10)OF5 octahedra,  an edgeedge with one Fe(3)F6 octahedra, and  an edgeedge with one Fe(5)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. In the second Fe site, Fe(2) is bonded to one F(10), one F(14), one F(18), one F(4), one F(6), and one F(9) atom to form FeF6 octahedra that share corners with two equivalent Fe(9)F6 octahedra, corners with two equivalent Fe(8)OF5 octahedra, corners with four equivalent Fe(6)F6 octahedra,  an edgeedge with one Fe(3)F6 octahedra, and  an edgeedge with one Fe(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the third Fe site, Fe(3) is bonded to one F(1), one F(10), one F(12), one F(15), one F(5), and one F(9) atom to form FeF6 octahedra that share corners with two equivalent Fe(6)F6 octahedra, corners with two equivalent Fe(10)OF5 octahedra, corners with four equivalent Fe(8)OF5 octahedra,  an edgeedge with one Fe(2)F6 octahedra, and  an edgeedge with one Fe(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 40-54°. In the fourth Fe site, Fe(4) is bonded to one F(11), one F(14), one F(17), one F(3), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing FeF6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the fifth Fe site, Fe(5) is bonded to one F(11), one F(13), one F(19), one F(2), one F(7), and one F(8) atom to form FeF6 octahedra that share corners with two equivalent Fe(9)F6 octahedra, corners with two equivalent Fe(10)OF5 octahedra, corners with four equivalent Fe(7)F6 octahedra,  an edgeedge with one Fe(4)F6 octahedra, and  an edgeedge with one Fe(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the sixth Fe site, Fe(6) is bonded to one F(1), one F(10), one F(17), one F(18), one F(4), and one F(6) atom to form FeF6 octahedra that share corners with two equivalent Fe(3)F6 octahedra, corners with two equivalent Fe(4)F6 octahedra, corners with four equivalent Fe(2)F6 octahedra,  an edgeedge with one Fe(9)F6 octahedra, and  an edgeedge with one Fe(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. In the seventh Fe site, Fe(7) is bonded to one F(11), one F(16), one F(19), one F(2), one F(3), and one F(8) atom to form FeF6 octahedra that share corners with two equivalent Fe(4)F6 octahedra, corners with two equivalent Fe(1)OF5 octahedra, corners with four equivalent Fe(5)F6 octahedra,  an edgeedge with one Fe(9)F6 octahedra, and  an edgeedge with one Fe(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the eighth Fe site, Fe(8) is bonded to one O(1), one F(1), one F(12), one F(15), one F(18), and one F(9) atom to form FeOF5 octahedra that share corners with two equivalent Fe(2)F6 octahedra, corners with two equivalent Fe(1)OF5 octahedra, corners with four equivalent Fe(3)F6 octahedra,  an edgeedge with one Fe(6)F6 octahedra, and  an edgeedge with one Fe(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. In the ninth Fe site, Fe(9) is bonded to one F(14), one F(17), one F(19), one F(3), one F(4), and one F(7) atom to form a mixture of edge and corner-sharing FeF6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the tenth Fe site, Fe(10) is bonded to one O(1), one F(13), one F(15), one F(16), one F(2), and one F(5) atom to form FeOF5 octahedra that share corners with two equivalent Fe(3)F6 octahedra, corners with two equivalent Fe(5)F6 octahedra, corners with four equivalent Fe(1)OF5 octahedra,  an edgeedge with one Fe(7)F6 octahedra, and  an edgeedge with one Fe(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 40-55°. O(1) is bonded in a trigonal planar geometry to one Fe(1), one Fe(10), and one Fe(8) atom. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Fe(3), one Fe(6), and one Fe(8) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Fe(10), one Fe(5), and one Fe(7) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Fe(4), one Fe(7), and one Fe(9) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Fe(2), one Fe(6), and one Fe(9) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(10), and one Fe(3) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Fe(2), one Fe(4), and one Fe(6) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Fe(4), one Fe(5), and one Fe(9) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(5), and one Fe(7) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Fe(2), one Fe(3), and one Fe(8) atom. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Fe(2), one Fe(3), and one Fe(6) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Fe(4), one Fe(5), and one Fe(7) atom. In the twelfth F site, F(12) is bonded in a trigonal planar geometry to one Fe(1), one Fe(3), and one Fe(8) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(10), and one Fe(5) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Fe(2), one Fe(4), and one Fe(9) atom. In the fifteenth F site, F(15) is bonded in a distorted T-shaped geometry to one Fe(10), one Fe(3), and one Fe(8) atom. In the sixteenth F site, F(16) is bonded in a trigonal planar geometry to one Fe(1), one Fe(10), and one Fe(7) atom. In the seventeenth F site, F(17) is bonded in a trigonal planar geometry to one Fe(4), one Fe(6), and one Fe(9) atom. In the eighteenth F site, F(18) is bonded in a trigonal planar geometry to one Fe(2), one Fe(6), and one Fe(8) atom. In the nineteenth F site, F(19) is bonded in a trigonal planar geometry to one Fe(5), one Fe(7), and one Fe(9) atom. is represented by the CIF file [CIF]
data_Fe10OF19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.810
_cell_length_b   5.830
_cell_length_c   13.816
_cell_angle_alpha   80.208
_cell_angle_beta   89.788
_cell_angle_gamma   89.810
_symmetry_Int_Tables_number   1
_cell_volume   381.755
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.516  0.491  0.997  1.0
  Fe  Fe1  1  0.496  0.301  0.602  1.0
  Fe  Fe2  1  0.503  0.896  0.801  1.0
  Fe  Fe3  1  0.501  0.699  0.399  1.0
  Fe  Fe4  1  0.498  0.102  0.199  1.0
  Fe  Fe5  1  0.999  0.798  0.602  1.0
  Fe  Fe6  1  0.005  0.603  0.195  1.0
  Fe  Fe7  1  0.988  0.397  0.808  1.0
  Fe  Fe8  1  0.999  0.201  0.400  1.0
  Fe  Fe9  1  0.985  0.023  0.996  1.0
  O  O10  1  0.810  0.300  0.946  1.0
  F  F11  1  0.799  0.719  0.741  1.0
  F  F12  1  0.805  0.931  0.132  1.0
  F  F13  1  0.802  0.524  0.337  1.0
  F  F14  1  0.796  0.121  0.539  1.0
  F  F15  1  0.713  0.819  0.942  1.0
  F  F16  1  0.699  0.620  0.540  1.0
  F  F17  1  0.703  0.020  0.337  1.0
  F  F18  1  0.692  0.428  0.142  1.0
  F  F19  1  0.702  0.215  0.740  1.0
  F  F20  1  0.298  0.977  0.661  1.0
  F  F21  1  0.303  0.780  0.257  1.0
  F  F22  1  0.305  0.578  0.860  1.0
  F  F23  1  0.291  0.177  0.062  1.0
  F  F24  1  0.298  0.380  0.460  1.0
  F  F25  1  0.204  0.061  0.868  1.0
  F  F26  1  0.199  0.703  0.053  1.0
  F  F27  1  0.199  0.878  0.460  1.0
  F  F28  1  0.196  0.476  0.665  1.0
  F  F29  1  0.197  0.281  0.258  1.0
[/CIF]
.