The material structure described by La(ClO4)3 crystallizes in the trigonal R3c space group. La(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one La(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one La(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one La(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La(ClO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.850
_cell_length_b   9.850
_cell_length_c   9.850
_cell_angle_alpha   50.618
_cell_angle_beta   50.618
_cell_angle_gamma   50.618
_symmetry_Int_Tables_number   1
_cell_volume   526.161
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.060  0.060  0.060  1.0
  La  La1  1  0.560  0.560  0.560  1.0
  Cl  Cl2  1  0.845  0.471  0.185  1.0
  Cl  Cl3  1  0.471  0.185  0.845  1.0
  Cl  Cl4  1  0.971  0.345  0.685  1.0
  Cl  Cl5  1  0.185  0.845  0.471  1.0
  Cl  Cl6  1  0.685  0.971  0.345  1.0
  Cl  Cl7  1  0.345  0.685  0.971  1.0
  O  O8  1  0.743  0.081  0.139  1.0
  O  O9  1  0.081  0.139  0.743  1.0
  O  O10  1  0.882  0.294  0.200  1.0
  O  O11  1  0.571  0.000  0.948  1.0
  O  O12  1  0.893  0.422  0.328  1.0
  O  O13  1  0.500  0.071  0.448  1.0
  O  O14  1  0.794  0.382  0.700  1.0
  O  O15  1  0.139  0.743  0.081  1.0
  O  O16  1  0.948  0.571  0.000  1.0
  O  O17  1  0.581  0.243  0.639  1.0
  O  O18  1  0.294  0.200  0.882  1.0
  O  O19  1  0.422  0.328  0.893  1.0
  O  O20  1  0.639  0.581  0.243  1.0
  O  O21  1  0.448  0.500  0.071  1.0
  O  O22  1  0.700  0.794  0.382  1.0
  O  O23  1  0.382  0.700  0.794  1.0
  O  O24  1  0.071  0.448  0.500  1.0
  O  O25  1  0.243  0.639  0.581  1.0
  O  O26  1  0.922  0.393  0.828  1.0
  O  O27  1  0.328  0.893  0.422  1.0
  O  O28  1  0.200  0.882  0.294  1.0
  O  O29  1  0.000  0.948  0.571  1.0
  O  O30  1  0.828  0.922  0.393  1.0
  O  O31  1  0.393  0.828  0.922  1.0
[/CIF]
.
The material structure described by La(ClO4)3 crystallizes in the trigonal R3c space group. La(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one La(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one La(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one La(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La(ClO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.850
_cell_length_b   9.850
_cell_length_c   9.850
_cell_angle_alpha   50.618
_cell_angle_beta   50.618
_cell_angle_gamma   50.618
_symmetry_Int_Tables_number   1
_cell_volume   526.161
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.060  0.060  0.060  1.0
  La  La1  1  0.560  0.560  0.560  1.0
  Cl  Cl2  1  0.845  0.471  0.185  1.0
  Cl  Cl3  1  0.471  0.185  0.845  1.0
  Cl  Cl4  1  0.971  0.345  0.685  1.0
  Cl  Cl5  1  0.185  0.845  0.471  1.0
  Cl  Cl6  1  0.685  0.971  0.345  1.0
  Cl  Cl7  1  0.345  0.685  0.971  1.0
  O  O8  1  0.743  0.081  0.139  1.0
  O  O9  1  0.081  0.139  0.743  1.0
  O  O10  1  0.882  0.294  0.200  1.0
  O  O11  1  0.571  0.000  0.948  1.0
  O  O12  1  0.893  0.422  0.328  1.0
  O  O13  1  0.500  0.071  0.448  1.0
  O  O14  1  0.794  0.382  0.700  1.0
  O  O15  1  0.139  0.743  0.081  1.0
  O  O16  1  0.948  0.571  0.000  1.0
  O  O17  1  0.581  0.243  0.639  1.0
  O  O18  1  0.294  0.200  0.882  1.0
  O  O19  1  0.422  0.328  0.893  1.0
  O  O20  1  0.639  0.581  0.243  1.0
  O  O21  1  0.448  0.500  0.071  1.0
  O  O22  1  0.700  0.794  0.382  1.0
  O  O23  1  0.382  0.700  0.794  1.0
  O  O24  1  0.071  0.448  0.500  1.0
  O  O25  1  0.243  0.639  0.581  1.0
  O  O26  1  0.922  0.393  0.828  1.0
  O  O27  1  0.328  0.893  0.422  1.0
  O  O28  1  0.200  0.882  0.294  1.0
  O  O29  1  0.000  0.948  0.571  1.0
  O  O30  1  0.828  0.922  0.393  1.0
  O  O31  1  0.393  0.828  0.922  1.0
[/CIF]
.