The structure described by Sr10Fe4Co(MoO6)5 crystallizes in the triclinic P-1 space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(11), one O(12), one O(13), one O(14), one O(5), one O(8), one O(9), two equivalent O(4), and two equivalent O(7) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with three equivalent Sr(4)O12 cuboctahedra, corners with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra,  a faceface with one Mo(1)O6 octahedra,  a faceface with one Mo(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with two equivalent Mo(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(10), one O(11), one O(12), one O(13), one O(14), one O(5), one O(8), one O(9), two equivalent O(6), and two equivalent O(7) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with three equivalent Sr(4)O12 cuboctahedra, corners with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra,  a faceface with one Mo(1)O6 octahedra,  a faceface with one Mo(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with two equivalent Mo(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(10), one O(4), one O(6), two equivalent O(2), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent Sr(4)O12 cuboctahedra, corners with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Mo(1)O6 octahedra, faces with two equivalent Mo(2)O6 octahedra, faces with two equivalent Fe(1)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(11), one O(12), one O(13), one O(14), one O(2), one O(3), one O(4), one O(5), two equivalent O(10), and two equivalent O(15) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Mo(3)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with two equivalent Mo(1)O6 octahedra, and faces with two equivalent Fe(1)O6 octahedra. In the fifth Sr site, Sr(5) is bonded to one O(11), one O(12), one O(13), one O(14), one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(15) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with three equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Mo(3)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with two equivalent Mo(1)O6 octahedra, and faces with two equivalent Fe(1)O6 octahedra. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(10), one O(11), one O(15), one O(2), and one O(8) atom to form MoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with three equivalent Fe(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-17°. In the second Mo site, Mo(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the third Mo site, Mo(3) is bonded to two equivalent O(12), two equivalent O(13), and two equivalent O(14) atoms to form MoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-16°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(10), one O(12), one O(15), one O(3), and one O(9) atom to form FeO6 octahedra that share  a cornercorner with one Mo(3)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with three equivalent Mo(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-17°. In the second Fe site, Fe(2) is bonded to one O(14), one O(2), one O(4), one O(6), one O(7), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Mo(3)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with three equivalent Mo(2)O6 octahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-16°. Co(1) is bonded to two equivalent O(11), two equivalent O(13), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Mo(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-15°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(3), two equivalent Sr(5), one Mo(1), and one Fe(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Sr(4), one Sr(5), two equivalent Sr(3), one Mo(1), and one Fe(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(4), one Sr(5), two equivalent Sr(3), one Mo(2), and one Fe(1) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(4), two equivalent Sr(1), one Mo(2), and one Fe(2) atom. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(2), and one Co(1) atom to form distorted OSr4CoMo octahedra that share  a cornercorner with one O(5)Sr4CoMo octahedra, corners with two equivalent O(15)Sr4FeMo octahedra, corners with three equivalent O(9)Sr4FeMo octahedra,  an edgeedge with one O(15)Sr4FeMo octahedra,  an edgeedge with one O(8)Sr4FeMo octahedra, and edges with two equivalent O(14)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(5), two equivalent Sr(2), one Mo(2), and one Fe(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Mo(2), and one Fe(2) atom. In the eighth O site, O(8) is bonded to one Sr(1), one Sr(2), two equivalent Sr(3), one Mo(1), and one Fe(2) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(15)Sr4FeMo octahedra, corners with two equivalent O(9)Sr4FeMo octahedra, corners with three equivalent O(14)Sr4FeMo octahedra,  an edgeedge with one O(5)Sr4CoMo octahedra,  an edgeedge with one O(8)Sr4FeMo octahedra, and edges with two equivalent O(9)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(2), two equivalent Sr(3), one Mo(2), and one Fe(1) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(15)Sr4FeMo octahedra, corners with two equivalent O(8)Sr4FeMo octahedra, corners with three equivalent O(5)Sr4CoMo octahedra,  an edgeedge with one O(14)Sr4FeMo octahedra,  an edgeedge with one O(9)Sr4FeMo octahedra, and edges with two equivalent O(8)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), two equivalent Sr(4), one Mo(1), and one Fe(1) atom. In the eleventh O site, O(11) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(1), and one Co(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(3), and one Fe(1) atom. In the thirteenth O site, O(13) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(3), and one Co(1) atom. In the fourteenth O site, O(14) is bonded to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(3), and one Fe(2) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(14)Sr4FeMo octahedra, corners with two equivalent O(15)Sr4FeMo octahedra, corners with three equivalent O(8)Sr4FeMo octahedra,  an edgeedge with one O(15)Sr4FeMo octahedra,  an edgeedge with one O(9)Sr4FeMo octahedra, and edges with two equivalent O(5)Sr4CoMo octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifteenth O site, O(15) is bonded to two equivalent Sr(4), two equivalent Sr(5), one Mo(1), and one Fe(1) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(8)Sr4FeMo octahedra,  a cornercorner with one O(9)Sr4FeMo octahedra, corners with two equivalent O(5)Sr4CoMo octahedra, corners with two equivalent O(14)Sr4FeMo octahedra,  an edgeedge with one O(5)Sr4CoMo octahedra,  an edgeedge with one O(14)Sr4FeMo octahedra, and edges with two equivalent O(15)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 1-2°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr10Fe4Co(MoO6)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.978
_cell_length_b   9.737
_cell_length_c   9.845
_cell_angle_alpha   81.406
_cell_angle_beta   113.861
_cell_angle_gamma   114.118
_symmetry_Int_Tables_number   1
_cell_volume   638.175
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.051  0.397  0.199  1.0
  Sr  Sr1  1  0.546  0.397  0.200  1.0
  Sr  Sr2  1  0.244  0.999  0.999  1.0
  Sr  Sr3  1  0.756  0.001  0.001  1.0
  Sr  Sr4  1  0.454  0.603  0.800  1.0
  Sr  Sr5  1  0.949  0.603  0.801  1.0
  Sr  Sr6  1  0.647  0.196  0.598  1.0
  Sr  Sr7  1  0.147  0.195  0.599  1.0
  Sr  Sr8  1  0.853  0.805  0.401  1.0
  Sr  Sr9  1  0.353  0.804  0.402  1.0
  Fe  Fe10  1  0.700  0.097  0.301  1.0
  Fe  Fe11  1  0.901  0.700  0.103  1.0
  Fe  Fe12  1  0.099  0.300  0.897  1.0
  Fe  Fe13  1  0.300  0.903  0.699  1.0
  Co  Co14  1  0.500  0.500  0.500  1.0
  Mo  Mo15  1  0.200  0.101  0.298  1.0
  Mo  Mo16  1  0.399  0.698  0.099  1.0
  Mo  Mo17  1  0.601  0.302  0.901  1.0
  Mo  Mo18  1  0.800  0.899  0.702  1.0
  Mo  Mo19  1  0.000  0.500  0.500  1.0
  O  O20  1  0.926  0.073  0.285  1.0
  O  O21  1  0.088  0.906  0.206  1.0
  O  O22  1  0.511  0.897  0.195  1.0
  O  O23  1  0.140  0.673  0.087  1.0
  O  O24  1  0.448  0.605  0.292  1.0
  O  O25  1  0.661  0.727  0.114  1.0
  O  O26  1  0.288  0.507  0.001  1.0
  O  O27  1  0.149  0.200  0.101  1.0
  O  O28  1  0.712  0.493  0.999  1.0
  O  O29  1  0.339  0.273  0.886  1.0
  O  O30  1  0.649  0.202  0.096  1.0
  O  O31  1  0.860  0.327  0.913  1.0
  O  O32  1  0.489  0.103  0.805  1.0
  O  O33  1  0.351  0.798  0.904  1.0
  O  O34  1  0.912  0.094  0.794  1.0
  O  O35  1  0.526  0.870  0.687  1.0
  O  O36  1  0.851  0.800  0.899  1.0
  O  O37  1  0.074  0.927  0.715  1.0
  O  O38  1  0.688  0.707  0.602  1.0
  O  O39  1  0.552  0.395  0.708  1.0
  O  O40  1  0.113  0.696  0.600  1.0
  O  O41  1  0.738  0.473  0.487  1.0
  O  O42  1  0.048  0.404  0.691  1.0
  O  O43  1  0.262  0.527  0.513  1.0
  O  O44  1  0.887  0.304  0.400  1.0
  O  O45  1  0.749  0.000  0.498  1.0
  O  O46  1  0.312  0.293  0.398  1.0
  O  O47  1  0.251  1.000  0.502  1.0
  O  O48  1  0.474  0.130  0.313  1.0
  O  O49  1  0.952  0.596  0.309  1.0
[/CIF]
.
The structure described by Sr10Fe4Co(MoO6)5 crystallizes in the triclinic P-1 space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(11), one O(12), one O(13), one O(14), one O(5), one O(8), one O(9), two equivalent O(4), and two equivalent O(7) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with three equivalent Sr(4)O12 cuboctahedra, corners with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra,  a faceface with one Mo(1)O6 octahedra,  a faceface with one Mo(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with two equivalent Mo(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(10), one O(11), one O(12), one O(13), one O(14), one O(5), one O(8), one O(9), two equivalent O(6), and two equivalent O(7) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with three equivalent Sr(4)O12 cuboctahedra, corners with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra,  a faceface with one Mo(1)O6 octahedra,  a faceface with one Mo(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with two equivalent Mo(2)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(10), one O(4), one O(6), two equivalent O(2), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent Sr(4)O12 cuboctahedra, corners with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Mo(1)O6 octahedra, faces with two equivalent Mo(2)O6 octahedra, faces with two equivalent Fe(1)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(11), one O(12), one O(13), one O(14), one O(2), one O(3), one O(4), one O(5), two equivalent O(10), and two equivalent O(15) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with three equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Mo(3)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with two equivalent Mo(1)O6 octahedra, and faces with two equivalent Fe(1)O6 octahedra. In the fifth Sr site, Sr(5) is bonded to one O(11), one O(12), one O(13), one O(14), one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(15) atoms to form distorted SrO12 cuboctahedra that share corners with three equivalent Sr(1)O12 cuboctahedra, corners with three equivalent Sr(2)O12 cuboctahedra, corners with three equivalent Sr(3)O12 cuboctahedra, corners with three equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Mo(3)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with two equivalent Mo(1)O6 octahedra, and faces with two equivalent Fe(1)O6 octahedra. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(10), one O(11), one O(15), one O(2), and one O(8) atom to form MoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with three equivalent Fe(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-17°. In the second Mo site, Mo(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the third Mo site, Mo(3) is bonded to two equivalent O(12), two equivalent O(13), and two equivalent O(14) atoms to form MoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-16°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(10), one O(12), one O(15), one O(3), and one O(9) atom to form FeO6 octahedra that share  a cornercorner with one Mo(3)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with three equivalent Mo(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-17°. In the second Fe site, Fe(2) is bonded to one O(14), one O(2), one O(4), one O(6), one O(7), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Mo(3)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with three equivalent Mo(2)O6 octahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-16°. Co(1) is bonded to two equivalent O(11), two equivalent O(13), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Mo(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-15°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(3), two equivalent Sr(5), one Mo(1), and one Fe(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Sr(4), one Sr(5), two equivalent Sr(3), one Mo(1), and one Fe(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(4), one Sr(5), two equivalent Sr(3), one Mo(2), and one Fe(1) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(4), two equivalent Sr(1), one Mo(2), and one Fe(2) atom. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(2), and one Co(1) atom to form distorted OSr4CoMo octahedra that share  a cornercorner with one O(5)Sr4CoMo octahedra, corners with two equivalent O(15)Sr4FeMo octahedra, corners with three equivalent O(9)Sr4FeMo octahedra,  an edgeedge with one O(15)Sr4FeMo octahedra,  an edgeedge with one O(8)Sr4FeMo octahedra, and edges with two equivalent O(14)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(5), two equivalent Sr(2), one Mo(2), and one Fe(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Mo(2), and one Fe(2) atom. In the eighth O site, O(8) is bonded to one Sr(1), one Sr(2), two equivalent Sr(3), one Mo(1), and one Fe(2) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(15)Sr4FeMo octahedra, corners with two equivalent O(9)Sr4FeMo octahedra, corners with three equivalent O(14)Sr4FeMo octahedra,  an edgeedge with one O(5)Sr4CoMo octahedra,  an edgeedge with one O(8)Sr4FeMo octahedra, and edges with two equivalent O(9)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(2), two equivalent Sr(3), one Mo(2), and one Fe(1) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(15)Sr4FeMo octahedra, corners with two equivalent O(8)Sr4FeMo octahedra, corners with three equivalent O(5)Sr4CoMo octahedra,  an edgeedge with one O(14)Sr4FeMo octahedra,  an edgeedge with one O(9)Sr4FeMo octahedra, and edges with two equivalent O(8)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), two equivalent Sr(4), one Mo(1), and one Fe(1) atom. In the eleventh O site, O(11) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(1), and one Co(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(3), and one Fe(1) atom. In the thirteenth O site, O(13) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(3), and one Co(1) atom. In the fourteenth O site, O(14) is bonded to one Sr(1), one Sr(2), one Sr(4), one Sr(5), one Mo(3), and one Fe(2) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(14)Sr4FeMo octahedra, corners with two equivalent O(15)Sr4FeMo octahedra, corners with three equivalent O(8)Sr4FeMo octahedra,  an edgeedge with one O(15)Sr4FeMo octahedra,  an edgeedge with one O(9)Sr4FeMo octahedra, and edges with two equivalent O(5)Sr4CoMo octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifteenth O site, O(15) is bonded to two equivalent Sr(4), two equivalent Sr(5), one Mo(1), and one Fe(1) atom to form distorted OSr4FeMo octahedra that share  a cornercorner with one O(8)Sr4FeMo octahedra,  a cornercorner with one O(9)Sr4FeMo octahedra, corners with two equivalent O(5)Sr4CoMo octahedra, corners with two equivalent O(14)Sr4FeMo octahedra,  an edgeedge with one O(5)Sr4CoMo octahedra,  an edgeedge with one O(14)Sr4FeMo octahedra, and edges with two equivalent O(15)Sr4FeMo octahedra. The corner-sharing octahedral tilt angles range from 1-2°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr10Fe4Co(MoO6)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.978
_cell_length_b   9.737
_cell_length_c   9.845
_cell_angle_alpha   81.406
_cell_angle_beta   113.861
_cell_angle_gamma   114.118
_symmetry_Int_Tables_number   1
_cell_volume   638.175
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.051  0.397  0.199  1.0
  Sr  Sr1  1  0.546  0.397  0.200  1.0
  Sr  Sr2  1  0.244  0.999  0.999  1.0
  Sr  Sr3  1  0.756  0.001  0.001  1.0
  Sr  Sr4  1  0.454  0.603  0.800  1.0
  Sr  Sr5  1  0.949  0.603  0.801  1.0
  Sr  Sr6  1  0.647  0.196  0.598  1.0
  Sr  Sr7  1  0.147  0.195  0.599  1.0
  Sr  Sr8  1  0.853  0.805  0.401  1.0
  Sr  Sr9  1  0.353  0.804  0.402  1.0
  Fe  Fe10  1  0.700  0.097  0.301  1.0
  Fe  Fe11  1  0.901  0.700  0.103  1.0
  Fe  Fe12  1  0.099  0.300  0.897  1.0
  Fe  Fe13  1  0.300  0.903  0.699  1.0
  Co  Co14  1  0.500  0.500  0.500  1.0
  Mo  Mo15  1  0.200  0.101  0.298  1.0
  Mo  Mo16  1  0.399  0.698  0.099  1.0
  Mo  Mo17  1  0.601  0.302  0.901  1.0
  Mo  Mo18  1  0.800  0.899  0.702  1.0
  Mo  Mo19  1  0.000  0.500  0.500  1.0
  O  O20  1  0.926  0.073  0.285  1.0
  O  O21  1  0.088  0.906  0.206  1.0
  O  O22  1  0.511  0.897  0.195  1.0
  O  O23  1  0.140  0.673  0.087  1.0
  O  O24  1  0.448  0.605  0.292  1.0
  O  O25  1  0.661  0.727  0.114  1.0
  O  O26  1  0.288  0.507  0.001  1.0
  O  O27  1  0.149  0.200  0.101  1.0
  O  O28  1  0.712  0.493  0.999  1.0
  O  O29  1  0.339  0.273  0.886  1.0
  O  O30  1  0.649  0.202  0.096  1.0
  O  O31  1  0.860  0.327  0.913  1.0
  O  O32  1  0.489  0.103  0.805  1.0
  O  O33  1  0.351  0.798  0.904  1.0
  O  O34  1  0.912  0.094  0.794  1.0
  O  O35  1  0.526  0.870  0.687  1.0
  O  O36  1  0.851  0.800  0.899  1.0
  O  O37  1  0.074  0.927  0.715  1.0
  O  O38  1  0.688  0.707  0.602  1.0
  O  O39  1  0.552  0.395  0.708  1.0
  O  O40  1  0.113  0.696  0.600  1.0
  O  O41  1  0.738  0.473  0.487  1.0
  O  O42  1  0.048  0.404  0.691  1.0
  O  O43  1  0.262  0.527  0.513  1.0
  O  O44  1  0.887  0.304  0.400  1.0
  O  O45  1  0.749  0.000  0.498  1.0
  O  O46  1  0.312  0.293  0.398  1.0
  O  O47  1  0.251  1.000  0.502  1.0
  O  O48  1  0.474  0.130  0.313  1.0
  O  O49  1  0.952  0.596  0.309  1.0
[/CIF]
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