The material structure described by Li(CoO2)2 is Spinel structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(26), one O(27), one O(4), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, and  a cornercorner with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-65°. In the second Li site, Li(2) is bonded to one O(1), one O(14), one O(15), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. In the third Li site, Li(3) is bonded to one O(12), one O(16), one O(2), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra, and  a cornercorner with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the fourth Li site, Li(4) is bonded to one O(13), one O(22), one O(23), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. In the fifth Li site, Li(5) is bonded to one O(10), one O(11), one O(20), and one O(24) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. In the sixth Li site, Li(6) is bonded to one O(17), one O(21), one O(30), and one O(31) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. In the seventh Li site, Li(7) is bonded to one O(18), one O(19), one O(28), and one O(32) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the eighth Li site, Li(8) is bonded to one O(25), one O(29), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-64°. There are sixteen inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(30), one O(4), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(3), one O(31), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. In the third Co site, Co(3) is bonded to one O(1), one O(13), one O(2), one O(28), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(11), one O(3), one O(32), one O(5), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), one O(14), one O(17), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the sixth Co site, Co(6) is bonded to one O(10), one O(15), one O(16), one O(21), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the seventh Co site, Co(7) is bonded to one O(11), one O(12), one O(13), one O(14), one O(18), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the eighth Co site, Co(8) is bonded to one O(11), one O(13), one O(15), one O(16), one O(19), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(7)O6 octahedra. In the ninth Co site, Co(9) is bonded to one O(14), one O(17), one O(18), one O(20), one O(22), and one O(25) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(7)O6 octahedra. In the tenth Co site, Co(10) is bonded to one O(15), one O(19), one O(20), one O(21), one O(22), and one O(26) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the eleventh Co site, Co(11) is bonded to one O(12), one O(17), one O(18), one O(23), one O(24), and one O(29) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the twelfth Co site, Co(12) is bonded to one O(16), one O(19), one O(21), one O(23), one O(24), and one O(27) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the thirteenth Co site, Co(13) is bonded to one O(1), one O(22), one O(25), one O(26), one O(28), and one O(30) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the fourteenth Co site, Co(14) is bonded to one O(20), one O(25), one O(26), one O(31), one O(32), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the fifteenth Co site, Co(15) is bonded to one O(2), one O(23), one O(27), one O(28), one O(29), and one O(30) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. In the sixteenth Co site, Co(16) is bonded to one O(24), one O(27), one O(29), one O(3), one O(31), and one O(32) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Co(1), one Co(13), and one Co(3) atom to form distorted corner-sharing OLiCo3 trigonal pyramids. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(1), one Co(15), and one Co(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(16), one Co(2), and one Co(4) atom. In the fourth O site, O(4) is bonded to one Li(1), one Co(1), one Co(2), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(14), one Co(2), and one Co(4) atom. In the sixth O site, O(6) is bonded to one Li(8), one Co(1), one Co(2), and one Co(5) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Co(3), one Co(4), and one Co(7) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(3), one Co(4), and one Co(8) atom. In the ninth O site, O(9) is bonded to one Li(4), one Co(1), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the tenth O site, O(10) is bonded to one Li(5), one Co(2), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Co(4), one Co(7), and one Co(8) atom. In the twelfth O site, O(12) is bonded to one Li(3), one Co(11), one Co(5), and one Co(7) atom to form distorted corner-sharing OLiCo3 trigonal pyramids. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(3), one Co(7), and one Co(8) atom to form distorted corner-sharing OLiCo3 trigonal pyramids. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(5), one Co(7), and one Co(9) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(10), one Co(6), and one Co(8) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(12), one Co(6), and one Co(8) atom. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(11), one Co(5), and one Co(9) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Co(11), one Co(7), and one Co(9) atom. In the nineteenth O site, O(19) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Co(10), one Co(12), and one Co(8) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(5), one Co(10), one Co(14), and one Co(9) atom. In the twenty-first O site, O(21) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(10), one Co(12), and one Co(6) atom. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(10), one Co(13), and one Co(9) atom. In the twenty-third O site, O(23) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(11), one Co(12), and one Co(15) atom. In the twenty-fourth O site, O(24) is bonded to one Li(5), one Co(11), one Co(12), and one Co(16) atom to form distorted corner-sharing OLiCo3 trigonal pyramids. In the twenty-fifth O site, O(25) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Co(13), one Co(14), and one Co(9) atom. In the twenty-sixth O site, O(26) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(10), one Co(13), and one Co(14) atom. In the twenty-seventh O site, O(27) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(12), one Co(15), and one Co(16) atom. In the twenty-eighth O site, O(28) is bonded in a rectangular see-saw-like geometry to one Li(7), one Co(13), one Co(15), and one Co(3) atom. In the twenty-ninth O site, O(29) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Co(11), one Co(15), and one Co(16) atom. In the thirtieth O site, O(30) is bonded in a rectangular see-saw-like geometry to one Li(6), one Co(1), one Co(13), and one Co(15) atom. In the thirty-first O site, O(31) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(14), one Co(16), and one Co(2) atom. In the thirty-second O site, O(32) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Co(14), one Co(16), and one Co(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(CoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.791
_cell_length_b   5.803
_cell_length_c   5.827
_cell_angle_alpha   90.556
_cell_angle_beta   119.426
_cell_angle_gamma   119.737
_symmetry_Int_Tables_number   1
_cell_volume   139.548
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.746  0.123  0.374  1.0
  Co  Co1  1  0.251  0.626  0.375  1.0
  Co  Co2  1  0.752  0.626  0.376  1.0
  Co  Co3  1  0.250  0.623  0.874  1.0
  Li  Li4  1  0.003  0.000  0.006  1.0
  Li  Li5  1  0.497  0.251  0.745  1.0
  O  O6  1  0.218  0.384  0.599  1.0
  O  O7  1  0.780  0.394  0.165  1.0
  O  O8  1  0.278  0.864  0.148  1.0
  O  O9  1  0.722  0.857  0.586  1.0
  O  O10  1  0.734  0.862  0.151  1.0
  O  O11  1  0.283  0.416  0.152  1.0
  O  O12  1  0.765  0.388  0.600  1.0
  O  O13  1  0.220  0.835  0.600  1.0
[/CIF]
.
The material structure described by Li(CoO2)2 is Spinel structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(26), one O(27), one O(4), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, and  a cornercorner with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-65°. In the second Li site, Li(2) is bonded to one O(1), one O(14), one O(15), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. In the third Li site, Li(3) is bonded to one O(12), one O(16), one O(2), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra, and  a cornercorner with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the fourth Li site, Li(4) is bonded to one O(13), one O(22), one O(23), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. In the fifth Li site, Li(5) is bonded to one O(10), one O(11), one O(20), and one O(24) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. In the sixth Li site, Li(6) is bonded to one O(17), one O(21), one O(30), and one O(31) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. In the seventh Li site, Li(7) is bonded to one O(18), one O(19), one O(28), and one O(32) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the eighth Li site, Li(8) is bonded to one O(25), one O(29), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-64°. There are sixteen inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(30), one O(4), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(3), one O(31), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. In the third Co site, Co(3) is bonded to one O(1), one O(13), one O(2), one O(28), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(11), one O(3), one O(32), one O(5), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), one O(14), one O(17), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the sixth Co site, Co(6) is bonded to one O(10), one O(15), one O(16), one O(21), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the seventh Co site, Co(7) is bonded to one O(11), one O(12), one O(13), one O(14), one O(18), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the eighth Co site, Co(8) is bonded to one O(11), one O(13), one O(15), one O(16), one O(19), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(7)O6 octahedra. In the ninth Co site, Co(9) is bonded to one O(14), one O(17), one O(18), one O(20), one O(22), and one O(25) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(7)O6 octahedra. In the tenth Co site, Co(10) is bonded to one O(15), one O(19), one O(20), one O(21), one O(22), and one O(26) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the eleventh Co site, Co(11) is bonded to one O(12), one O(17), one O(18), one O(23), one O(24), and one O(29) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the twelfth Co site, Co(12) is bonded to one O(16), one O(19), one O(21), one O(23), one O(24), and one O(27) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the thirteenth Co site, Co(13) is bonded to one O(1), one O(22), one O(25), one O(26), one O(28), and one O(30) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the fourteenth Co site, Co(14) is bonded to one O(20), one O(25), one O(26), one O(31), one O(32), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the fifteenth Co site, Co(15) is bonded to one O(2), one O(23), one O(27), one O(28), one O(29), and one O(30) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. In the sixteenth Co site, Co(16) is bonded to one O(24), one O(27), one O(29), one O(3), one O(31), and one O(32) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Co(1), one Co(13), and one Co(3) atom to form distorted corner-sharing OLiCo3 trigonal pyramids. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(1), one Co(15), and one Co(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(16), one Co(2), and one Co(4) atom. In the fourth O site, O(4) is bonded to one Li(1), one Co(1), one Co(2), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(14), one Co(2), and one Co(4) atom. In the sixth O site, O(6) is bonded to one Li(8), one Co(1), one Co(2), and one Co(5) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Co(3), one Co(4), and one Co(7) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(3), one Co(4), and one Co(8) atom. In the ninth O site, O(9) is bonded to one Li(4), one Co(1), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the tenth O site, O(10) is bonded to one Li(5), one Co(2), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Co(4), one Co(7), and one Co(8) atom. In the twelfth O site, O(12) is bonded to one Li(3), one Co(11), one Co(5), and one Co(7) atom to form distorted corner-sharing OLiCo3 trigonal pyramids. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(3), one Co(7), and one Co(8) atom to form distorted corner-sharing OLiCo3 trigonal pyramids. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(5), one Co(7), and one Co(9) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(10), one Co(6), and one Co(8) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(12), one Co(6), and one Co(8) atom. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(11), one Co(5), and one Co(9) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Co(11), one Co(7), and one Co(9) atom. In the nineteenth O site, O(19) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Co(10), one Co(12), and one Co(8) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(5), one Co(10), one Co(14), and one Co(9) atom. In the twenty-first O site, O(21) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(10), one Co(12), and one Co(6) atom. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(10), one Co(13), and one Co(9) atom. In the twenty-third O site, O(23) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(11), one Co(12), and one Co(15) atom. In the twenty-fourth O site, O(24) is bonded to one Li(5), one Co(11), one Co(12), and one Co(16) atom to form distorted corner-sharing OLiCo3 trigonal pyramids. In the twenty-fifth O site, O(25) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Co(13), one Co(14), and one Co(9) atom. In the twenty-sixth O site, O(26) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(10), one Co(13), and one Co(14) atom. In the twenty-seventh O site, O(27) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(12), one Co(15), and one Co(16) atom. In the twenty-eighth O site, O(28) is bonded in a rectangular see-saw-like geometry to one Li(7), one Co(13), one Co(15), and one Co(3) atom. In the twenty-ninth O site, O(29) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Co(11), one Co(15), and one Co(16) atom. In the thirtieth O site, O(30) is bonded in a rectangular see-saw-like geometry to one Li(6), one Co(1), one Co(13), and one Co(15) atom. In the thirty-first O site, O(31) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(14), one Co(16), and one Co(2) atom. In the thirty-second O site, O(32) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Co(14), one Co(16), and one Co(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(CoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.791
_cell_length_b   5.803
_cell_length_c   5.827
_cell_angle_alpha   90.556
_cell_angle_beta   119.426
_cell_angle_gamma   119.737
_symmetry_Int_Tables_number   1
_cell_volume   139.548
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.746  0.123  0.374  1.0
  Co  Co1  1  0.251  0.626  0.375  1.0
  Co  Co2  1  0.752  0.626  0.376  1.0
  Co  Co3  1  0.250  0.623  0.874  1.0
  Li  Li4  1  0.003  0.000  0.006  1.0
  Li  Li5  1  0.497  0.251  0.745  1.0
  O  O6  1  0.218  0.384  0.599  1.0
  O  O7  1  0.780  0.394  0.165  1.0
  O  O8  1  0.278  0.864  0.148  1.0
  O  O9  1  0.722  0.857  0.586  1.0
  O  O10  1  0.734  0.862  0.151  1.0
  O  O11  1  0.283  0.416  0.152  1.0
  O  O12  1  0.765  0.388  0.600  1.0
  O  O13  1  0.220  0.835  0.600  1.0
[/CIF]
.