The material structure described by Mg(MoO3)4 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(7), and one O(9) atom. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(4), and one O(9) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(3), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Mo(3) and one Mo(4) atom. In the second O site, O(2) is bonded in a linear geometry to one Mo(3) and one Mo(4) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Mo(2) and one Mo(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Mo(1) and one Mo(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(3) and one Mo(4) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(3) and one Mo(4) atom. In the seventh O site, O(7) is bonded in a linear geometry to one Mg(1) and one Mo(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(4) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Mg(1), one Mo(1), and one Mo(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Mg(1), one Mo(1), and one Mo(2) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Mg(1), one Mo(1), and one Mo(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Mg(1), one Mo(1), and one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg(MoO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.388
_cell_length_b   5.390
_cell_length_c   9.744
_cell_angle_alpha   73.968
_cell_angle_beta   90.407
_cell_angle_gamma   89.321
_symmetry_Int_Tables_number   1
_cell_volume   271.957
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.512  0.921  0.093  1.0
  Mo  Mo1  1  0.009  0.004  0.931  1.0
  Mo  Mo2  1  0.501  0.502  0.930  1.0
  Mo  Mo3  1  0.499  0.696  0.493  1.0
  Mo  Mo4  1  0.984  0.195  0.491  1.0
  O  O5  1  0.230  0.941  0.516  1.0
  O  O6  1  0.272  0.444  0.511  1.0
  O  O7  1  0.483  0.590  0.745  1.0
  O  O8  1  0.020  0.099  0.747  1.0
  O  O9  1  0.777  0.483  0.531  1.0
  O  O10  1  0.719  0.978  0.533  1.0
  O  O11  1  0.519  0.810  0.305  1.0
  O  O12  1  0.965  0.301  0.309  1.0
  O  O13  1  0.265  0.722  0.008  1.0
  O  O14  1  0.268  0.206  0.003  1.0
  O  O15  1  0.744  0.734  0.991  1.0
  O  O16  1  0.747  0.210  0.001  1.0
[/CIF]
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The material structure described by Mg(MoO3)4 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(7), and one O(9) atom. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(4), and one O(9) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(3), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Mo(3) and one Mo(4) atom. In the second O site, O(2) is bonded in a linear geometry to one Mo(3) and one Mo(4) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Mo(2) and one Mo(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Mo(1) and one Mo(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(3) and one Mo(4) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(3) and one Mo(4) atom. In the seventh O site, O(7) is bonded in a linear geometry to one Mg(1) and one Mo(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(4) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Mg(1), one Mo(1), and one Mo(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Mg(1), one Mo(1), and one Mo(2) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Mg(1), one Mo(1), and one Mo(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Mg(1), one Mo(1), and one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg(MoO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.388
_cell_length_b   5.390
_cell_length_c   9.744
_cell_angle_alpha   73.968
_cell_angle_beta   90.407
_cell_angle_gamma   89.321
_symmetry_Int_Tables_number   1
_cell_volume   271.957
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.512  0.921  0.093  1.0
  Mo  Mo1  1  0.009  0.004  0.931  1.0
  Mo  Mo2  1  0.501  0.502  0.930  1.0
  Mo  Mo3  1  0.499  0.696  0.493  1.0
  Mo  Mo4  1  0.984  0.195  0.491  1.0
  O  O5  1  0.230  0.941  0.516  1.0
  O  O6  1  0.272  0.444  0.511  1.0
  O  O7  1  0.483  0.590  0.745  1.0
  O  O8  1  0.020  0.099  0.747  1.0
  O  O9  1  0.777  0.483  0.531  1.0
  O  O10  1  0.719  0.978  0.533  1.0
  O  O11  1  0.519  0.810  0.305  1.0
  O  O12  1  0.965  0.301  0.309  1.0
  O  O13  1  0.265  0.722  0.008  1.0
  O  O14  1  0.268  0.206  0.003  1.0
  O  O15  1  0.744  0.734  0.991  1.0
  O  O16  1  0.747  0.210  0.001  1.0
[/CIF]
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