The crystal structure described by WOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two WOF4 clusters. W(1) is bonded in a 6-coordinate geometry to one O(1), one F(2), one F(3), one F(4), and two equivalent F(1) atoms. O(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted water-like geometry to two equivalent W(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   8.099
_cell_length_c   10.276
_cell_angle_alpha   70.377
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   392.282
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.453  0.763  0.547  1.0
  W  W1  1  0.047  0.763  0.047  1.0
  W  W2  1  0.953  0.237  0.953  1.0
  W  W3  1  0.547  0.237  0.453  1.0
  O  O4  1  0.241  0.615  0.517  1.0
  O  O5  1  0.741  0.385  0.983  1.0
  O  O6  1  0.259  0.615  0.017  1.0
  O  O7  1  0.759  0.385  0.483  1.0
  F  F8  1  0.210  0.988  0.933  1.0
  F  F9  1  0.801  0.802  0.901  1.0
  F  F10  1  0.290  0.988  0.433  1.0
  F  F11  1  0.280  0.804  0.696  1.0
  F  F12  1  0.699  0.802  0.401  1.0
  F  F13  1  0.704  0.621  0.669  1.0
  F  F14  1  0.220  0.804  0.196  1.0
  F  F15  1  0.204  0.379  0.831  1.0
  F  F16  1  0.796  0.621  0.169  1.0
  F  F17  1  0.780  0.196  0.804  1.0
  F  F18  1  0.296  0.379  0.331  1.0
  F  F19  1  0.301  0.198  0.599  1.0
  F  F20  1  0.720  0.196  0.304  1.0
  F  F21  1  0.710  0.012  0.567  1.0
  F  F22  1  0.199  0.198  0.099  1.0
  F  F23  1  0.790  0.012  0.067  1.0
[/CIF]
.
The crystal structure described by WOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two WOF4 clusters. W(1) is bonded in a 6-coordinate geometry to one O(1), one F(2), one F(3), one F(4), and two equivalent F(1) atoms. O(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted water-like geometry to two equivalent W(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   8.099
_cell_length_c   10.276
_cell_angle_alpha   70.377
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   392.282
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.453  0.763  0.547  1.0
  W  W1  1  0.047  0.763  0.047  1.0
  W  W2  1  0.953  0.237  0.953  1.0
  W  W3  1  0.547  0.237  0.453  1.0
  O  O4  1  0.241  0.615  0.517  1.0
  O  O5  1  0.741  0.385  0.983  1.0
  O  O6  1  0.259  0.615  0.017  1.0
  O  O7  1  0.759  0.385  0.483  1.0
  F  F8  1  0.210  0.988  0.933  1.0
  F  F9  1  0.801  0.802  0.901  1.0
  F  F10  1  0.290  0.988  0.433  1.0
  F  F11  1  0.280  0.804  0.696  1.0
  F  F12  1  0.699  0.802  0.401  1.0
  F  F13  1  0.704  0.621  0.669  1.0
  F  F14  1  0.220  0.804  0.196  1.0
  F  F15  1  0.204  0.379  0.831  1.0
  F  F16  1  0.796  0.621  0.169  1.0
  F  F17  1  0.780  0.196  0.804  1.0
  F  F18  1  0.296  0.379  0.331  1.0
  F  F19  1  0.301  0.198  0.599  1.0
  F  F20  1  0.720  0.196  0.304  1.0
  F  F21  1  0.710  0.012  0.567  1.0
  F  F22  1  0.199  0.198  0.099  1.0
  F  F23  1  0.790  0.012  0.067  1.0
[/CIF]
.