The material structure described by IO6 is alpha La structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four IO6 clusters. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one I(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one I(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one I(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_IO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.036
_cell_length_b   19.330
_cell_length_c   5.659
_cell_angle_alpha   90.000
_cell_angle_beta   115.284
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   498.123
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  I  I0  1  0.140  0.123  0.677  1.0
  I  I1  1  0.140  0.377  0.177  1.0
  I  I2  1  0.860  0.877  0.323  1.0
  I  I3  1  0.860  0.623  0.823  1.0
  O  O4  1  0.424  0.053  0.724  1.0
  O  O5  1  0.424  0.447  0.224  1.0
  O  O6  1  0.576  0.947  0.276  1.0
  O  O7  1  0.576  0.553  0.776  1.0
  O  O8  1  0.802  0.086  0.403  1.0
  O  O9  1  0.802  0.414  0.903  1.0
  O  O10  1  0.198  0.914  0.597  1.0
  O  O11  1  0.198  0.586  0.097  1.0
  O  O12  1  0.083  0.061  0.909  1.0
  O  O13  1  0.083  0.439  0.409  1.0
  O  O14  1  0.917  0.939  0.091  1.0
  O  O15  1  0.917  0.561  0.591  1.0
  O  O16  1  0.859  0.194  0.630  1.0
  O  O17  1  0.859  0.306  0.130  1.0
  O  O18  1  0.141  0.806  0.370  1.0
  O  O19  1  0.141  0.694  0.870  1.0
  O  O20  1  0.479  0.162  0.946  1.0
  O  O21  1  0.479  0.338  0.446  1.0
  O  O22  1  0.521  0.838  0.054  1.0
  O  O23  1  0.521  0.662  0.554  1.0
  O  O24  1  0.217  0.186  0.460  1.0
  O  O25  1  0.217  0.314  0.960  1.0
  O  O26  1  0.783  0.814  0.540  1.0
  O  O27  1  0.783  0.686  0.040  1.0
[/CIF]
.
The material structure described by IO6 is alpha La structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four IO6 clusters. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one I(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one I(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one I(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_IO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.036
_cell_length_b   19.330
_cell_length_c   5.659
_cell_angle_alpha   90.000
_cell_angle_beta   115.284
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   498.123
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  I  I0  1  0.140  0.123  0.677  1.0
  I  I1  1  0.140  0.377  0.177  1.0
  I  I2  1  0.860  0.877  0.323  1.0
  I  I3  1  0.860  0.623  0.823  1.0
  O  O4  1  0.424  0.053  0.724  1.0
  O  O5  1  0.424  0.447  0.224  1.0
  O  O6  1  0.576  0.947  0.276  1.0
  O  O7  1  0.576  0.553  0.776  1.0
  O  O8  1  0.802  0.086  0.403  1.0
  O  O9  1  0.802  0.414  0.903  1.0
  O  O10  1  0.198  0.914  0.597  1.0
  O  O11  1  0.198  0.586  0.097  1.0
  O  O12  1  0.083  0.061  0.909  1.0
  O  O13  1  0.083  0.439  0.409  1.0
  O  O14  1  0.917  0.939  0.091  1.0
  O  O15  1  0.917  0.561  0.591  1.0
  O  O16  1  0.859  0.194  0.630  1.0
  O  O17  1  0.859  0.306  0.130  1.0
  O  O18  1  0.141  0.806  0.370  1.0
  O  O19  1  0.141  0.694  0.870  1.0
  O  O20  1  0.479  0.162  0.946  1.0
  O  O21  1  0.479  0.338  0.446  1.0
  O  O22  1  0.521  0.838  0.054  1.0
  O  O23  1  0.521  0.662  0.554  1.0
  O  O24  1  0.217  0.186  0.460  1.0
  O  O25  1  0.217  0.314  0.960  1.0
  O  O26  1  0.783  0.814  0.540  1.0
  O  O27  1  0.783  0.686  0.040  1.0
[/CIF]
.