The structure described by Li2VMnP2(HO5)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), one O(2), and one O(9) atom to form distorted LiO5 square pyramids that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(2)O5 square pyramid, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the second Li site, Li(2) is bonded to one O(10), one O(13), one O(2), one O(3), and one O(9) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-65°. In the third Li site, Li(3) is bonded to one O(1), one O(6), one O(7), and two equivalent O(8) atoms to form distorted LiO5 square pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent P(3)O4 tetrahedra, edges with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(3)O5 square pyramid, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-63°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(14), one O(15), one O(3), one O(4), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(2)O5 square pyramid,  a cornercorner with one Li(3)O5 square pyramid, corners with two equivalent Li(1)O5 square pyramids, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(7), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and edges with four equivalent Li(3)O5 square pyramids. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(11), one O(12), one O(13), one O(2), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, edges with two equivalent Li(1)O5 square pyramids, and edges with two equivalent Li(2)O5 square pyramids. The corner-sharing octahedral tilt angles range from 51-53°. In the second Mn site, Mn(2) is bonded to two equivalent O(13), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Li(2)O5 square pyramids, corners with two equivalent Li(3)O5 square pyramids, and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid, and  an edgeedge with one Li(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 39-55°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(3), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 38-56°. In the third P site, P(3) is bonded to one O(12), one O(15), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 38-53°. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(11) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(13) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(3), one V(2), and one P(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(2), one V(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mn(2) and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(3), one Mn(2), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Li(3), one V(1), one V(2), and one H(1) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to two equivalent Li(3), one V(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(1), and one P(2) atom. In the tenth O site, O(10) is bonded in a T-shaped geometry to one Li(2), one Mn(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Mn(1), and one H(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(1), and one P(3) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Li(2), one Mn(1), one Mn(2), and one H(3) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(3) atom. is represented by the CIF card [CIF]
data_Li2MnVP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.435
_cell_length_b   10.101
_cell_length_c   10.350
_cell_angle_alpha   79.649
_cell_angle_beta   83.656
_cell_angle_gamma   79.309
_symmetry_Int_Tables_number   1
_cell_volume   547.487
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.207  0.192  0.363  1.0
  Li  Li1  1  0.127  0.475  0.301  1.0
  Li  Li2  1  0.464  0.144  0.967  1.0
  Li  Li3  1  0.536  0.856  0.033  1.0
  Li  Li4  1  0.873  0.525  0.699  1.0
  Li  Li5  1  0.793  0.808  0.637  1.0
  Mn  Mn6  1  0.333  0.666  0.665  1.0
  Mn  Mn7  1  0.667  0.334  0.335  1.0
  Mn  Mn8  1  0.500  0.500  0.000  1.0
  V  V9  1  0.171  0.831  0.333  1.0
  V  V10  1  0.829  0.169  0.667  1.0
  V  V11  1  0.000  0.000  0.000  1.0
  P  P12  1  0.066  0.305  0.070  1.0
  P  P13  1  0.269  0.364  0.595  1.0
  P  P14  1  0.612  0.031  0.262  1.0
  P  P15  1  0.388  0.969  0.738  1.0
  P  P16  1  0.731  0.636  0.405  1.0
  P  P17  1  0.934  0.695  0.930  1.0
  H  H18  1  0.173  0.765  0.105  1.0
  H  H19  1  0.165  0.898  0.563  1.0
  H  H20  1  0.501  0.563  0.232  1.0
  H  H21  1  0.499  0.437  0.768  1.0
  H  H22  1  0.835  0.102  0.437  1.0
  H  H23  1  0.827  0.235  0.895  1.0
  O  O24  1  0.117  0.148  0.073  1.0
  O  O25  1  0.021  0.337  0.212  1.0
  O  O26  1  0.023  0.322  0.667  1.0
  O  O27  1  0.160  0.035  0.656  1.0
  O  O28  1  0.157  0.631  0.015  1.0
  O  O29  1  0.320  0.348  0.001  1.0
  O  O30  1  0.194  0.854  0.129  1.0
  O  O31  1  0.335  0.000  0.882  1.0
  O  O32  1  0.313  0.330  0.455  1.0
  O  O33  1  0.225  0.522  0.590  1.0
  O  O34  1  0.140  0.810  0.540  1.0
  O  O35  1  0.564  0.188  0.258  1.0
  O  O36  1  0.477  0.474  0.210  1.0
  O  O37  1  0.499  0.299  0.678  1.0
  O  O38  1  0.365  0.986  0.329  1.0
  O  O39  1  0.635  0.014  0.671  1.0
  O  O40  1  0.501  0.701  0.322  1.0
  O  O41  1  0.523  0.526  0.790  1.0
  O  O42  1  0.436  0.812  0.742  1.0
  O  O43  1  0.860  0.190  0.460  1.0
  O  O44  1  0.775  0.478  0.410  1.0
  O  O45  1  0.687  0.670  0.545  1.0
  O  O46  1  0.665  1.000  0.118  1.0
  O  O47  1  0.806  0.146  0.871  1.0
  O  O48  1  0.680  0.652  0.999  1.0
  O  O49  1  0.843  0.369  0.985  1.0
  O  O50  1  0.840  0.965  0.344  1.0
  O  O51  1  0.977  0.678  0.333  1.0
  O  O52  1  0.979  0.663  0.788  1.0
  O  O53  1  0.883  0.852  0.927  1.0
[/CIF]
.
The structure described by Li2VMnP2(HO5)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), one O(2), and one O(9) atom to form distorted LiO5 square pyramids that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(2)O5 square pyramid, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the second Li site, Li(2) is bonded to one O(10), one O(13), one O(2), one O(3), and one O(9) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-65°. In the third Li site, Li(3) is bonded to one O(1), one O(6), one O(7), and two equivalent O(8) atoms to form distorted LiO5 square pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent P(3)O4 tetrahedra, edges with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(3)O5 square pyramid, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-63°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(14), one O(15), one O(3), one O(4), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(2)O5 square pyramid,  a cornercorner with one Li(3)O5 square pyramid, corners with two equivalent Li(1)O5 square pyramids, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(7), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and edges with four equivalent Li(3)O5 square pyramids. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(11), one O(12), one O(13), one O(2), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, edges with two equivalent Li(1)O5 square pyramids, and edges with two equivalent Li(2)O5 square pyramids. The corner-sharing octahedral tilt angles range from 51-53°. In the second Mn site, Mn(2) is bonded to two equivalent O(13), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Li(2)O5 square pyramids, corners with two equivalent Li(3)O5 square pyramids, and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid, and  an edgeedge with one Li(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 39-55°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(3), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 38-56°. In the third P site, P(3) is bonded to one O(12), one O(15), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 38-53°. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(11) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(13) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(3), one V(2), and one P(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(2), one V(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mn(2) and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(3), one Mn(2), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Li(3), one V(1), one V(2), and one H(1) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to two equivalent Li(3), one V(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(1), and one P(2) atom. In the tenth O site, O(10) is bonded in a T-shaped geometry to one Li(2), one Mn(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Mn(1), and one H(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(1), and one P(3) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Li(2), one Mn(1), one Mn(2), and one H(3) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(3) atom. is represented by the CIF card [CIF]
data_Li2MnVP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.435
_cell_length_b   10.101
_cell_length_c   10.350
_cell_angle_alpha   79.649
_cell_angle_beta   83.656
_cell_angle_gamma   79.309
_symmetry_Int_Tables_number   1
_cell_volume   547.487
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.207  0.192  0.363  1.0
  Li  Li1  1  0.127  0.475  0.301  1.0
  Li  Li2  1  0.464  0.144  0.967  1.0
  Li  Li3  1  0.536  0.856  0.033  1.0
  Li  Li4  1  0.873  0.525  0.699  1.0
  Li  Li5  1  0.793  0.808  0.637  1.0
  Mn  Mn6  1  0.333  0.666  0.665  1.0
  Mn  Mn7  1  0.667  0.334  0.335  1.0
  Mn  Mn8  1  0.500  0.500  0.000  1.0
  V  V9  1  0.171  0.831  0.333  1.0
  V  V10  1  0.829  0.169  0.667  1.0
  V  V11  1  0.000  0.000  0.000  1.0
  P  P12  1  0.066  0.305  0.070  1.0
  P  P13  1  0.269  0.364  0.595  1.0
  P  P14  1  0.612  0.031  0.262  1.0
  P  P15  1  0.388  0.969  0.738  1.0
  P  P16  1  0.731  0.636  0.405  1.0
  P  P17  1  0.934  0.695  0.930  1.0
  H  H18  1  0.173  0.765  0.105  1.0
  H  H19  1  0.165  0.898  0.563  1.0
  H  H20  1  0.501  0.563  0.232  1.0
  H  H21  1  0.499  0.437  0.768  1.0
  H  H22  1  0.835  0.102  0.437  1.0
  H  H23  1  0.827  0.235  0.895  1.0
  O  O24  1  0.117  0.148  0.073  1.0
  O  O25  1  0.021  0.337  0.212  1.0
  O  O26  1  0.023  0.322  0.667  1.0
  O  O27  1  0.160  0.035  0.656  1.0
  O  O28  1  0.157  0.631  0.015  1.0
  O  O29  1  0.320  0.348  0.001  1.0
  O  O30  1  0.194  0.854  0.129  1.0
  O  O31  1  0.335  0.000  0.882  1.0
  O  O32  1  0.313  0.330  0.455  1.0
  O  O33  1  0.225  0.522  0.590  1.0
  O  O34  1  0.140  0.810  0.540  1.0
  O  O35  1  0.564  0.188  0.258  1.0
  O  O36  1  0.477  0.474  0.210  1.0
  O  O37  1  0.499  0.299  0.678  1.0
  O  O38  1  0.365  0.986  0.329  1.0
  O  O39  1  0.635  0.014  0.671  1.0
  O  O40  1  0.501  0.701  0.322  1.0
  O  O41  1  0.523  0.526  0.790  1.0
  O  O42  1  0.436  0.812  0.742  1.0
  O  O43  1  0.860  0.190  0.460  1.0
  O  O44  1  0.775  0.478  0.410  1.0
  O  O45  1  0.687  0.670  0.545  1.0
  O  O46  1  0.665  1.000  0.118  1.0
  O  O47  1  0.806  0.146  0.871  1.0
  O  O48  1  0.680  0.652  0.999  1.0
  O  O49  1  0.843  0.369  0.985  1.0
  O  O50  1  0.840  0.965  0.344  1.0
  O  O51  1  0.977  0.678  0.333  1.0
  O  O52  1  0.979  0.663  0.788  1.0
  O  O53  1  0.883  0.852  0.927  1.0
[/CIF]
.