The structure described by KP4N7 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 12-coordinate geometry to two equivalent N(1), two equivalent N(4), four equivalent N(2), and four equivalent N(3) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(2), one N(3), and two equivalent N(4) atoms to form corner-sharing PN4 tetrahedra. There are four inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to two equivalent K(1), one P(1), and one P(2) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one K(1), one P(1), and two equivalent P(2) atoms. In the third N site, N(1) is bonded in a 2-coordinate geometry to two equivalent K(1) and two equivalent P(1) atoms. In the fourth N site, N(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one P(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KP4N7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.663
_cell_length_b   9.843
_cell_length_c   12.247
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   562.159
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.260  0.151  0.750  1.0
  K  K1  1  0.760  0.349  0.250  1.0
  K  K2  1  0.740  0.849  0.250  1.0
  K  K3  1  0.240  0.651  0.750  1.0
  P  P4  1  0.788  0.412  0.869  1.0
  P  P5  1  0.288  0.088  0.131  1.0
  P  P6  1  0.212  0.588  0.369  1.0
  P  P7  1  0.712  0.912  0.631  1.0
  P  P8  1  0.212  0.588  0.131  1.0
  P  P9  1  0.712  0.912  0.869  1.0
  P  P10  1  0.788  0.412  0.631  1.0
  P  P11  1  0.288  0.088  0.369  1.0
  P  P12  1  0.781  0.157  1.000  1.0
  P  P13  1  0.281  0.343  0.000  1.0
  P  P14  1  0.219  0.843  0.500  1.0
  P  P15  1  0.719  0.657  0.500  1.0
  P  P16  1  0.219  0.843  0.000  1.0
  P  P17  1  0.719  0.657  1.000  1.0
  P  P18  1  0.781  0.157  0.500  1.0
  P  P19  1  0.281  0.343  0.500  1.0
  N  N20  1  0.703  0.367  0.750  1.0
  N  N21  1  0.203  0.133  0.250  1.0
  N  N22  1  0.297  0.633  0.250  1.0
  N  N23  1  0.797  0.867  0.750  1.0
  N  N24  1  0.121  0.387  0.893  1.0
  N  N25  1  0.621  0.113  0.107  1.0
  N  N26  1  0.879  0.613  0.393  1.0
  N  N27  1  0.379  0.887  0.607  1.0
  N  N28  1  0.879  0.613  0.107  1.0
  N  N29  1  0.379  0.887  0.893  1.0
  N  N30  1  0.121  0.387  0.607  1.0
  N  N31  1  0.621  0.113  0.393  1.0
  N  N32  1  0.818  0.061  0.897  1.0
  N  N33  1  0.318  0.439  0.103  1.0
  N  N34  1  0.182  0.939  0.397  1.0
  N  N35  1  0.682  0.561  0.603  1.0
  N  N36  1  0.182  0.939  0.103  1.0
  N  N37  1  0.682  0.561  0.897  1.0
  N  N38  1  0.818  0.061  0.603  1.0
  N  N39  1  0.318  0.439  0.397  1.0
  N  N40  1  0.619  0.301  0.958  1.0
  N  N41  1  0.119  0.199  0.042  1.0
  N  N42  1  0.381  0.699  0.458  1.0
  N  N43  1  0.881  0.801  0.542  1.0
  N  N44  1  0.381  0.699  0.042  1.0
  N  N45  1  0.881  0.801  0.958  1.0
  N  N46  1  0.619  0.301  0.542  1.0
  N  N47  1  0.119  0.199  0.458  1.0
[/CIF]
.
The structure described by KP4N7 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 12-coordinate geometry to two equivalent N(1), two equivalent N(4), four equivalent N(2), and four equivalent N(3) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(2), one N(3), and two equivalent N(4) atoms to form corner-sharing PN4 tetrahedra. There are four inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to two equivalent K(1), one P(1), and one P(2) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one K(1), one P(1), and two equivalent P(2) atoms. In the third N site, N(1) is bonded in a 2-coordinate geometry to two equivalent K(1) and two equivalent P(1) atoms. In the fourth N site, N(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one P(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KP4N7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.663
_cell_length_b   9.843
_cell_length_c   12.247
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   562.159
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.260  0.151  0.750  1.0
  K  K1  1  0.760  0.349  0.250  1.0
  K  K2  1  0.740  0.849  0.250  1.0
  K  K3  1  0.240  0.651  0.750  1.0
  P  P4  1  0.788  0.412  0.869  1.0
  P  P5  1  0.288  0.088  0.131  1.0
  P  P6  1  0.212  0.588  0.369  1.0
  P  P7  1  0.712  0.912  0.631  1.0
  P  P8  1  0.212  0.588  0.131  1.0
  P  P9  1  0.712  0.912  0.869  1.0
  P  P10  1  0.788  0.412  0.631  1.0
  P  P11  1  0.288  0.088  0.369  1.0
  P  P12  1  0.781  0.157  1.000  1.0
  P  P13  1  0.281  0.343  0.000  1.0
  P  P14  1  0.219  0.843  0.500  1.0
  P  P15  1  0.719  0.657  0.500  1.0
  P  P16  1  0.219  0.843  0.000  1.0
  P  P17  1  0.719  0.657  1.000  1.0
  P  P18  1  0.781  0.157  0.500  1.0
  P  P19  1  0.281  0.343  0.500  1.0
  N  N20  1  0.703  0.367  0.750  1.0
  N  N21  1  0.203  0.133  0.250  1.0
  N  N22  1  0.297  0.633  0.250  1.0
  N  N23  1  0.797  0.867  0.750  1.0
  N  N24  1  0.121  0.387  0.893  1.0
  N  N25  1  0.621  0.113  0.107  1.0
  N  N26  1  0.879  0.613  0.393  1.0
  N  N27  1  0.379  0.887  0.607  1.0
  N  N28  1  0.879  0.613  0.107  1.0
  N  N29  1  0.379  0.887  0.893  1.0
  N  N30  1  0.121  0.387  0.607  1.0
  N  N31  1  0.621  0.113  0.393  1.0
  N  N32  1  0.818  0.061  0.897  1.0
  N  N33  1  0.318  0.439  0.103  1.0
  N  N34  1  0.182  0.939  0.397  1.0
  N  N35  1  0.682  0.561  0.603  1.0
  N  N36  1  0.182  0.939  0.103  1.0
  N  N37  1  0.682  0.561  0.897  1.0
  N  N38  1  0.818  0.061  0.603  1.0
  N  N39  1  0.318  0.439  0.397  1.0
  N  N40  1  0.619  0.301  0.958  1.0
  N  N41  1  0.119  0.199  0.042  1.0
  N  N42  1  0.381  0.699  0.458  1.0
  N  N43  1  0.881  0.801  0.542  1.0
  N  N44  1  0.381  0.699  0.042  1.0
  N  N45  1  0.881  0.801  0.958  1.0
  N  N46  1  0.619  0.301  0.542  1.0
  N  N47  1  0.119  0.199  0.458  1.0
[/CIF]
.