The material described by Mn5In3O12 crystallizes in the triclinic P1 space group. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 37-45°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 35-45°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(2), one O(4), one O(5), and one O(7) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 35-45°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(11), one O(3), one O(6), one O(8), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 37-45°. In the fifth Mn site, Mn(5) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(4), one O(5), one O(8), and one O(9) atom. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. In the second In site, In(2) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. In the third In site, In(3) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(4), one O(5), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(4), one Mn(5), and one In(3) atom to form distorted OMn3In trigonal pyramids that share  a cornercorner with one O(8)Mn3In tetrahedra, corners with three equivalent O(5)Mn3In tetrahedra,  a cornercorner with one O(7)Mn2In2 trigonal pyramid, corners with two equivalent O(3)Mn2In2 trigonal pyramids, corners with two equivalent O(4)Mn3In trigonal pyramids, and  an edgeedge with one O(8)Mn3In tetrahedra. In the second O site, O(2) is bonded to one Mn(2), one Mn(3), one In(1), and one In(2) atom to form distorted OMn2In2 trigonal pyramids that share  a cornercorner with one O(5)Mn3In tetrahedra,  a cornercorner with one O(8)Mn3In tetrahedra,  a cornercorner with one O(7)Mn2In2 trigonal pyramid, corners with two equivalent O(3)Mn2In2 trigonal pyramids, corners with two equivalent O(4)Mn3In trigonal pyramids, and  an edgeedge with one O(7)Mn2In2 trigonal pyramid. In the third O site, O(3) is bonded to one Mn(1), one Mn(4), one In(1), and one In(2) atom to form distorted OMn2In2 trigonal pyramids that share  a cornercorner with one O(5)Mn3In tetrahedra,  a cornercorner with one O(8)Mn3In tetrahedra, corners with two equivalent O(2)Mn2In2 trigonal pyramids, corners with two equivalent O(1)Mn3In trigonal pyramids, and corners with three equivalent O(7)Mn2In2 trigonal pyramids. In the fourth O site, O(4) is bonded to one Mn(2), one Mn(3), one Mn(5), and one In(3) atom to form distorted OMn3In trigonal pyramids that share  a cornercorner with one O(5)Mn3In tetrahedra, corners with three equivalent O(8)Mn3In tetrahedra,  a cornercorner with one O(7)Mn2In2 trigonal pyramid, corners with two equivalent O(2)Mn2In2 trigonal pyramids, corners with two equivalent O(1)Mn3In trigonal pyramids, and  an edgeedge with one O(5)Mn3In tetrahedra. In the fifth O site, O(5) is bonded to one Mn(1), one Mn(3), one Mn(5), and one In(3) atom to form distorted OMn3In tetrahedra that share corners with two equivalent O(8)Mn3In tetrahedra,  a cornercorner with one O(2)Mn2In2 trigonal pyramid,  a cornercorner with one O(3)Mn2In2 trigonal pyramid,  a cornercorner with one O(4)Mn3In trigonal pyramid, corners with two equivalent O(7)Mn2In2 trigonal pyramids, corners with three equivalent O(1)Mn3In trigonal pyramids, and  an edgeedge with one O(4)Mn3In trigonal pyramid. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Mn(2), one Mn(4), one In(1), and one In(2) atom. In the seventh O site, O(7) is bonded to one Mn(1), one Mn(3), one In(1), and one In(2) atom to form distorted OMn2In2 trigonal pyramids that share corners with two equivalent O(5)Mn3In tetrahedra,  a cornercorner with one O(2)Mn2In2 trigonal pyramid,  a cornercorner with one O(1)Mn3In trigonal pyramid,  a cornercorner with one O(4)Mn3In trigonal pyramid, corners with three equivalent O(3)Mn2In2 trigonal pyramids, and  an edgeedge with one O(2)Mn2In2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Mn(2), one Mn(4), one Mn(5), and one In(3) atom to form distorted OMn3In tetrahedra that share corners with two equivalent O(5)Mn3In tetrahedra,  a cornercorner with one O(2)Mn2In2 trigonal pyramid,  a cornercorner with one O(3)Mn2In2 trigonal pyramid,  a cornercorner with one O(1)Mn3In trigonal pyramid, corners with three equivalent O(4)Mn3In trigonal pyramids, and  an edgeedge with one O(1)Mn3In trigonal pyramid. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Mn(1), one Mn(4), one Mn(5), one In(1), and one In(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Mn(2), one Mn(3), one Mn(5), one In(1), and one In(3) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Mn(1), one Mn(4), one Mn(5), one In(2), and one In(3) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Mn(2), one Mn(3), one In(1), one In(2), and one In(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn5In3O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.211
_cell_length_b   5.404
_cell_length_c   7.939
_cell_angle_alpha   89.682
_cell_angle_beta   88.185
_cell_angle_gamma   89.493
_symmetry_Int_Tables_number   1
_cell_volume   223.427
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.998  0.500  0.997  1.0
  Mn  Mn1  1  0.502  1.000  0.503  1.0
  Mn  Mn2  1  1.000  0.501  0.504  1.0
  Mn  Mn3  1  0.501  0.001  0.995  1.0
  Mn  Mn4  1  0.518  0.447  0.764  1.0
  In  In5  1  0.022  0.060  0.262  1.0
  In  In6  1  0.478  0.559  0.235  1.0
  In  In7  1  0.981  0.942  0.739  1.0
  O  O8  1  0.803  0.191  0.920  1.0
  O  O9  1  0.302  0.300  0.417  1.0
  O  O10  1  0.201  0.805  0.082  1.0
  O  O11  1  0.696  0.701  0.585  1.0
  O  O12  1  0.127  0.565  0.767  1.0
  O  O13  1  0.628  0.935  0.268  1.0
  O  O14  1  0.872  0.437  0.233  1.0
  O  O15  1  0.373  0.068  0.732  1.0
  O  O16  1  0.305  0.302  0.058  1.0
  O  O17  1  0.814  0.191  0.551  1.0
  O  O18  1  0.686  0.691  0.945  1.0
  O  O19  1  0.195  0.802  0.444  1.0
[/CIF]
.
The material described by Mn5In3O12 crystallizes in the triclinic P1 space group. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 37-45°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 35-45°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(2), one O(4), one O(5), and one O(7) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 35-45°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(11), one O(3), one O(6), one O(8), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 37-45°. In the fifth Mn site, Mn(5) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(4), one O(5), one O(8), and one O(9) atom. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. In the second In site, In(2) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. In the third In site, In(3) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(4), one O(5), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(4), one Mn(5), and one In(3) atom to form distorted OMn3In trigonal pyramids that share  a cornercorner with one O(8)Mn3In tetrahedra, corners with three equivalent O(5)Mn3In tetrahedra,  a cornercorner with one O(7)Mn2In2 trigonal pyramid, corners with two equivalent O(3)Mn2In2 trigonal pyramids, corners with two equivalent O(4)Mn3In trigonal pyramids, and  an edgeedge with one O(8)Mn3In tetrahedra. In the second O site, O(2) is bonded to one Mn(2), one Mn(3), one In(1), and one In(2) atom to form distorted OMn2In2 trigonal pyramids that share  a cornercorner with one O(5)Mn3In tetrahedra,  a cornercorner with one O(8)Mn3In tetrahedra,  a cornercorner with one O(7)Mn2In2 trigonal pyramid, corners with two equivalent O(3)Mn2In2 trigonal pyramids, corners with two equivalent O(4)Mn3In trigonal pyramids, and  an edgeedge with one O(7)Mn2In2 trigonal pyramid. In the third O site, O(3) is bonded to one Mn(1), one Mn(4), one In(1), and one In(2) atom to form distorted OMn2In2 trigonal pyramids that share  a cornercorner with one O(5)Mn3In tetrahedra,  a cornercorner with one O(8)Mn3In tetrahedra, corners with two equivalent O(2)Mn2In2 trigonal pyramids, corners with two equivalent O(1)Mn3In trigonal pyramids, and corners with three equivalent O(7)Mn2In2 trigonal pyramids. In the fourth O site, O(4) is bonded to one Mn(2), one Mn(3), one Mn(5), and one In(3) atom to form distorted OMn3In trigonal pyramids that share  a cornercorner with one O(5)Mn3In tetrahedra, corners with three equivalent O(8)Mn3In tetrahedra,  a cornercorner with one O(7)Mn2In2 trigonal pyramid, corners with two equivalent O(2)Mn2In2 trigonal pyramids, corners with two equivalent O(1)Mn3In trigonal pyramids, and  an edgeedge with one O(5)Mn3In tetrahedra. In the fifth O site, O(5) is bonded to one Mn(1), one Mn(3), one Mn(5), and one In(3) atom to form distorted OMn3In tetrahedra that share corners with two equivalent O(8)Mn3In tetrahedra,  a cornercorner with one O(2)Mn2In2 trigonal pyramid,  a cornercorner with one O(3)Mn2In2 trigonal pyramid,  a cornercorner with one O(4)Mn3In trigonal pyramid, corners with two equivalent O(7)Mn2In2 trigonal pyramids, corners with three equivalent O(1)Mn3In trigonal pyramids, and  an edgeedge with one O(4)Mn3In trigonal pyramid. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Mn(2), one Mn(4), one In(1), and one In(2) atom. In the seventh O site, O(7) is bonded to one Mn(1), one Mn(3), one In(1), and one In(2) atom to form distorted OMn2In2 trigonal pyramids that share corners with two equivalent O(5)Mn3In tetrahedra,  a cornercorner with one O(2)Mn2In2 trigonal pyramid,  a cornercorner with one O(1)Mn3In trigonal pyramid,  a cornercorner with one O(4)Mn3In trigonal pyramid, corners with three equivalent O(3)Mn2In2 trigonal pyramids, and  an edgeedge with one O(2)Mn2In2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Mn(2), one Mn(4), one Mn(5), and one In(3) atom to form distorted OMn3In tetrahedra that share corners with two equivalent O(5)Mn3In tetrahedra,  a cornercorner with one O(2)Mn2In2 trigonal pyramid,  a cornercorner with one O(3)Mn2In2 trigonal pyramid,  a cornercorner with one O(1)Mn3In trigonal pyramid, corners with three equivalent O(4)Mn3In trigonal pyramids, and  an edgeedge with one O(1)Mn3In trigonal pyramid. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Mn(1), one Mn(4), one Mn(5), one In(1), and one In(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Mn(2), one Mn(3), one Mn(5), one In(1), and one In(3) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Mn(1), one Mn(4), one Mn(5), one In(2), and one In(3) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Mn(2), one Mn(3), one In(1), one In(2), and one In(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn5In3O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.211
_cell_length_b   5.404
_cell_length_c   7.939
_cell_angle_alpha   89.682
_cell_angle_beta   88.185
_cell_angle_gamma   89.493
_symmetry_Int_Tables_number   1
_cell_volume   223.427
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.998  0.500  0.997  1.0
  Mn  Mn1  1  0.502  1.000  0.503  1.0
  Mn  Mn2  1  1.000  0.501  0.504  1.0
  Mn  Mn3  1  0.501  0.001  0.995  1.0
  Mn  Mn4  1  0.518  0.447  0.764  1.0
  In  In5  1  0.022  0.060  0.262  1.0
  In  In6  1  0.478  0.559  0.235  1.0
  In  In7  1  0.981  0.942  0.739  1.0
  O  O8  1  0.803  0.191  0.920  1.0
  O  O9  1  0.302  0.300  0.417  1.0
  O  O10  1  0.201  0.805  0.082  1.0
  O  O11  1  0.696  0.701  0.585  1.0
  O  O12  1  0.127  0.565  0.767  1.0
  O  O13  1  0.628  0.935  0.268  1.0
  O  O14  1  0.872  0.437  0.233  1.0
  O  O15  1  0.373  0.068  0.732  1.0
  O  O16  1  0.305  0.302  0.058  1.0
  O  O17  1  0.814  0.191  0.551  1.0
  O  O18  1  0.686  0.691  0.945  1.0
  O  O19  1  0.195  0.802  0.444  1.0
[/CIF]
.