The compound described by WOsB4 crystallizes in the hexagonal P-6m2 space group. W(1) is bonded in a 8-coordinate geometry to two equivalent B(2) and six equivalent B(1) atoms. Os(1) is bonded in a 8-coordinate geometry to two equivalent B(1) and six equivalent B(2) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 7-coordinate geometry to three equivalent W(1), one Os(1), and three equivalent B(2) atoms. In the second B site, B(2) is bonded in a 7-coordinate geometry to one W(1), three equivalent Os(1), and three equivalent B(1) atoms. is represented by the CIF file [CIF]
data_B4OsW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.920
_cell_length_b   2.920
_cell_length_c   7.524
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   55.570
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.333  0.667  0.707  1.0
  B  B1  1  1.000  0.000  0.799  1.0
  B  B2  1  1.000  0.000  0.201  1.0
  B  B3  1  0.333  0.667  0.293  1.0
  Os  Os4  1  0.333  0.667  0.000  1.0
  W  W5  1  1.000  0.000  0.500  1.0
[/CIF]
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The compound described by WOsB4 crystallizes in the hexagonal P-6m2 space group. W(1) is bonded in a 8-coordinate geometry to two equivalent B(2) and six equivalent B(1) atoms. Os(1) is bonded in a 8-coordinate geometry to two equivalent B(1) and six equivalent B(2) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 7-coordinate geometry to three equivalent W(1), one Os(1), and three equivalent B(2) atoms. In the second B site, B(2) is bonded in a 7-coordinate geometry to one W(1), three equivalent Os(1), and three equivalent B(1) atoms. is represented by the CIF file [CIF]
data_B4OsW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.920
_cell_length_b   2.920
_cell_length_c   7.524
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   55.570
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.333  0.667  0.707  1.0
  B  B1  1  1.000  0.000  0.799  1.0
  B  B2  1  1.000  0.000  0.201  1.0
  B  B3  1  0.333  0.667  0.293  1.0
  Os  Os4  1  0.333  0.667  0.000  1.0
  W  W5  1  1.000  0.000  0.500  1.0
[/CIF]
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