The crystal structure described by HoSbO4 crystallizes in the triclinic P-1 space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(5), one O(7), two equivalent O(6), and two equivalent O(8) atoms. In the second Ho site, Ho(2) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(6), one O(7), one O(8), and two equivalent O(5) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 40-48°. In the second Sb site, Sb(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 40-48°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ho(1), one Sb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ho(1), one Sb(1), and one Sb(2) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ho(2), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Ho(2), one Sb(1), and one Sb(2) atom. In the fifth O site, O(5) is bonded to one Ho(1), two equivalent Ho(2), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OHo3Sb tetrahedra. In the sixth O site, O(6) is bonded to one Ho(2), two equivalent Ho(1), and one Sb(2) atom to form a mixture of distorted edge and corner-sharing OHo3Sb tetrahedra. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ho(1), one Ho(2), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Ho(2), two equivalent Ho(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_HoSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.321
_cell_length_b   7.567
_cell_length_c   7.454
_cell_angle_alpha   81.159
_cell_angle_beta   90.342
_cell_angle_gamma   91.934
_symmetry_Int_Tables_number   1
_cell_volume   296.368
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.264  0.133  0.613  1.0
  Ho  Ho1  1  0.736  0.867  0.387  1.0
  Ho  Ho2  1  0.214  0.156  0.109  1.0
  Ho  Ho3  1  0.786  0.844  0.891  1.0
  Sb  Sb4  1  0.239  0.664  0.195  1.0
  Sb  Sb5  1  0.761  0.336  0.805  1.0
  Sb  Sb6  1  0.724  0.336  0.308  1.0
  Sb  Sb7  1  0.276  0.664  0.692  1.0
  O  O8  1  0.088  0.435  0.691  1.0
  O  O9  1  0.912  0.565  0.309  1.0
  O  O10  1  0.609  0.328  0.560  1.0
  O  O11  1  0.391  0.672  0.440  1.0
  O  O12  1  0.872  0.331  0.061  1.0
  O  O13  1  0.128  0.669  0.939  1.0
  O  O14  1  0.401  0.432  0.195  1.0
  O  O15  1  0.599  0.568  0.805  1.0
  O  O16  1  0.039  0.886  0.174  1.0
  O  O17  1  0.961  0.114  0.826  1.0
  O  O18  1  0.509  0.112  0.324  1.0
  O  O19  1  0.491  0.888  0.676  1.0
  O  O20  1  0.469  0.185  0.879  1.0
  O  O21  1  0.531  0.815  0.121  1.0
  O  O22  1  0.992  0.170  0.383  1.0
  O  O23  1  0.008  0.830  0.617  1.0
[/CIF]
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The crystal structure described by HoSbO4 crystallizes in the triclinic P-1 space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(5), one O(7), two equivalent O(6), and two equivalent O(8) atoms. In the second Ho site, Ho(2) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(6), one O(7), one O(8), and two equivalent O(5) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 40-48°. In the second Sb site, Sb(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 40-48°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ho(1), one Sb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ho(1), one Sb(1), and one Sb(2) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ho(2), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Ho(2), one Sb(1), and one Sb(2) atom. In the fifth O site, O(5) is bonded to one Ho(1), two equivalent Ho(2), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OHo3Sb tetrahedra. In the sixth O site, O(6) is bonded to one Ho(2), two equivalent Ho(1), and one Sb(2) atom to form a mixture of distorted edge and corner-sharing OHo3Sb tetrahedra. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ho(1), one Ho(2), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Ho(2), two equivalent Ho(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_HoSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.321
_cell_length_b   7.567
_cell_length_c   7.454
_cell_angle_alpha   81.159
_cell_angle_beta   90.342
_cell_angle_gamma   91.934
_symmetry_Int_Tables_number   1
_cell_volume   296.368
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.264  0.133  0.613  1.0
  Ho  Ho1  1  0.736  0.867  0.387  1.0
  Ho  Ho2  1  0.214  0.156  0.109  1.0
  Ho  Ho3  1  0.786  0.844  0.891  1.0
  Sb  Sb4  1  0.239  0.664  0.195  1.0
  Sb  Sb5  1  0.761  0.336  0.805  1.0
  Sb  Sb6  1  0.724  0.336  0.308  1.0
  Sb  Sb7  1  0.276  0.664  0.692  1.0
  O  O8  1  0.088  0.435  0.691  1.0
  O  O9  1  0.912  0.565  0.309  1.0
  O  O10  1  0.609  0.328  0.560  1.0
  O  O11  1  0.391  0.672  0.440  1.0
  O  O12  1  0.872  0.331  0.061  1.0
  O  O13  1  0.128  0.669  0.939  1.0
  O  O14  1  0.401  0.432  0.195  1.0
  O  O15  1  0.599  0.568  0.805  1.0
  O  O16  1  0.039  0.886  0.174  1.0
  O  O17  1  0.961  0.114  0.826  1.0
  O  O18  1  0.509  0.112  0.324  1.0
  O  O19  1  0.491  0.888  0.676  1.0
  O  O20  1  0.469  0.185  0.879  1.0
  O  O21  1  0.531  0.815  0.121  1.0
  O  O22  1  0.992  0.170  0.383  1.0
  O  O23  1  0.008  0.830  0.617  1.0
[/CIF]
.