The compound described by C2H9(O2Cl)3(H2O)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four water molecules and two C2H9(O2Cl)3 clusters. In each C2H9(O2Cl)3 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(2), one Cl(1), one Cl(2), and one Cl(3) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(1) and one O(4) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(4) and one O(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(5) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one O(7) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one O(1) and one O(7) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one C(2), one H(11), and one H(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one H(1), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(4), and one H(5) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one H(7) atom. In the sixth O site, O(7) is bonded in a water-like geometry to one H(10) and one H(11) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H13C2Cl3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.688
_cell_length_b   8.788
_cell_length_c   9.185
_cell_angle_alpha   88.646
_cell_angle_beta   62.311
_cell_angle_gamma   73.518
_symmetry_Int_Tables_number   1
_cell_volume   590.560
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.005  0.540  0.814  1.0
  H  H1  1  0.995  0.460  0.186  1.0
  H  H2  1  0.858  0.472  0.726  1.0
  H  H3  1  0.142  0.528  0.274  1.0
  H  H4  1  0.007  0.319  0.741  1.0
  H  H5  1  0.993  0.681  0.259  1.0
  H  H6  1  0.168  0.615  0.827  1.0
  H  H7  1  0.832  0.385  0.173  1.0
  H  H8  1  0.971  0.745  0.857  1.0
  H  H9  1  0.029  0.255  0.143  1.0
  H  H10  1  0.783  0.970  0.958  1.0
  H  H11  1  0.217  0.030  0.042  1.0
  H  H12  1  0.804  0.910  0.781  1.0
  H  H13  1  0.196  0.090  0.219  1.0
  H  H14  1  0.774  0.885  0.538  1.0
  H  H15  1  0.226  0.115  0.462  1.0
  H  H16  1  0.706  0.760  0.662  1.0
  H  H17  1  0.294  0.240  0.338  1.0
  H  H18  1  0.457  0.952  0.772  1.0
  H  H19  1  0.543  0.048  0.228  1.0
  H  H20  1  0.337  0.838  0.819  1.0
  H  H21  1  0.663  0.162  0.181  1.0
  H  H22  1  0.189  0.066  0.746  1.0
  H  H23  1  0.811  0.934  0.254  1.0
  H  H24  1  0.014  0.053  0.745  1.0
  H  H25  1  0.986  0.947  0.255  1.0
  C  C26  1  0.555  0.355  0.707  1.0
  C  C27  1  0.445  0.645  0.293  1.0
  C  C28  1  0.527  0.541  0.732  1.0
  C  C29  1  0.473  0.459  0.268  1.0
  Cl  Cl30  1  0.782  0.250  0.557  1.0
  Cl  Cl31  1  0.218  0.750  0.443  1.0
  Cl  Cl32  1  0.512  0.291  0.905  1.0
  Cl  Cl33  1  0.488  0.709  0.095  1.0
  Cl  Cl34  1  0.401  0.315  0.649  1.0
  Cl  Cl35  1  0.599  0.685  0.351  1.0
  O  O36  1  0.368  0.634  0.778  1.0
  O  O37  1  0.632  0.366  0.222  1.0
  O  O38  1  0.665  0.578  0.709  1.0
  O  O39  1  0.335  0.422  0.291  1.0
  O  O40  1  0.970  0.437  0.738  1.0
  O  O41  1  0.030  0.563  0.262  1.0
  O  O42  1  0.033  0.631  0.872  1.0
  O  O43  1  0.967  0.369  0.128  1.0
  O  O44  1  0.872  0.917  0.842  1.0
  O  O45  1  0.128  0.083  0.158  1.0
  O  O46  1  0.712  0.872  0.657  1.0
  O  O47  1  0.288  0.128  0.343  1.0
  O  O48  1  0.328  0.953  0.835  1.0
  O  O49  1  0.672  0.047  0.165  1.0
  O  O50  1  0.102  0.115  0.703  1.0
  O  O51  1  0.898  0.885  0.297  1.0
[/CIF]
.
The compound described by C2H9(O2Cl)3(H2O)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four water molecules and two C2H9(O2Cl)3 clusters. In each C2H9(O2Cl)3 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(2), one Cl(1), one Cl(2), and one Cl(3) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(1) and one O(4) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(4) and one O(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(5) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one O(7) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one O(1) and one O(7) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one C(2), one H(11), and one H(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one H(1), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(4), and one H(5) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one H(7) atom. In the sixth O site, O(7) is bonded in a water-like geometry to one H(10) and one H(11) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H13C2Cl3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.688
_cell_length_b   8.788
_cell_length_c   9.185
_cell_angle_alpha   88.646
_cell_angle_beta   62.311
_cell_angle_gamma   73.518
_symmetry_Int_Tables_number   1
_cell_volume   590.560
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.005  0.540  0.814  1.0
  H  H1  1  0.995  0.460  0.186  1.0
  H  H2  1  0.858  0.472  0.726  1.0
  H  H3  1  0.142  0.528  0.274  1.0
  H  H4  1  0.007  0.319  0.741  1.0
  H  H5  1  0.993  0.681  0.259  1.0
  H  H6  1  0.168  0.615  0.827  1.0
  H  H7  1  0.832  0.385  0.173  1.0
  H  H8  1  0.971  0.745  0.857  1.0
  H  H9  1  0.029  0.255  0.143  1.0
  H  H10  1  0.783  0.970  0.958  1.0
  H  H11  1  0.217  0.030  0.042  1.0
  H  H12  1  0.804  0.910  0.781  1.0
  H  H13  1  0.196  0.090  0.219  1.0
  H  H14  1  0.774  0.885  0.538  1.0
  H  H15  1  0.226  0.115  0.462  1.0
  H  H16  1  0.706  0.760  0.662  1.0
  H  H17  1  0.294  0.240  0.338  1.0
  H  H18  1  0.457  0.952  0.772  1.0
  H  H19  1  0.543  0.048  0.228  1.0
  H  H20  1  0.337  0.838  0.819  1.0
  H  H21  1  0.663  0.162  0.181  1.0
  H  H22  1  0.189  0.066  0.746  1.0
  H  H23  1  0.811  0.934  0.254  1.0
  H  H24  1  0.014  0.053  0.745  1.0
  H  H25  1  0.986  0.947  0.255  1.0
  C  C26  1  0.555  0.355  0.707  1.0
  C  C27  1  0.445  0.645  0.293  1.0
  C  C28  1  0.527  0.541  0.732  1.0
  C  C29  1  0.473  0.459  0.268  1.0
  Cl  Cl30  1  0.782  0.250  0.557  1.0
  Cl  Cl31  1  0.218  0.750  0.443  1.0
  Cl  Cl32  1  0.512  0.291  0.905  1.0
  Cl  Cl33  1  0.488  0.709  0.095  1.0
  Cl  Cl34  1  0.401  0.315  0.649  1.0
  Cl  Cl35  1  0.599  0.685  0.351  1.0
  O  O36  1  0.368  0.634  0.778  1.0
  O  O37  1  0.632  0.366  0.222  1.0
  O  O38  1  0.665  0.578  0.709  1.0
  O  O39  1  0.335  0.422  0.291  1.0
  O  O40  1  0.970  0.437  0.738  1.0
  O  O41  1  0.030  0.563  0.262  1.0
  O  O42  1  0.033  0.631  0.872  1.0
  O  O43  1  0.967  0.369  0.128  1.0
  O  O44  1  0.872  0.917  0.842  1.0
  O  O45  1  0.128  0.083  0.158  1.0
  O  O46  1  0.712  0.872  0.657  1.0
  O  O47  1  0.288  0.128  0.343  1.0
  O  O48  1  0.328  0.953  0.835  1.0
  O  O49  1  0.672  0.047  0.165  1.0
  O  O50  1  0.102  0.115  0.703  1.0
  O  O51  1  0.898  0.885  0.297  1.0
[/CIF]
.