The material structure described by AuCl4C5S4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two tetrakis(methylthio)tetrathiafulvalene molecules and four AuCl4 clusters. In each AuCl4 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AuC5(SCl)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.516
_cell_length_b   9.516
_cell_length_c   8.137
_cell_angle_alpha   85.496
_cell_angle_beta   85.496
_cell_angle_gamma   74.127
_symmetry_Int_Tables_number   1
_cell_volume   705.332
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.857  0.857  0.114  1.0
  Au  Au1  1  0.143  0.143  0.886  1.0
  C  C2  1  0.346  0.466  0.673  1.0
  C  C3  1  0.479  0.479  0.926  1.0
  C  C4  1  0.919  0.355  0.397  1.0
  C  C5  1  0.466  0.346  0.673  1.0
  C  C6  1  0.355  0.919  0.397  1.0
  C  C7  1  0.521  0.521  0.074  1.0
  C  C8  1  0.645  0.081  0.603  1.0
  C  C9  1  0.081  0.645  0.603  1.0
  C  C10  1  0.534  0.654  0.327  1.0
  C  C11  1  0.654  0.534  0.327  1.0
  S  S12  1  0.211  0.510  0.523  1.0
  S  S13  1  0.677  0.421  0.166  1.0
  S  S14  1  0.579  0.323  0.834  1.0
  S  S15  1  0.789  0.490  0.477  1.0
  S  S16  1  0.490  0.789  0.477  1.0
  S  S17  1  0.510  0.211  0.523  1.0
  S  S18  1  0.421  0.677  0.166  1.0
  S  S19  1  0.323  0.579  0.834  1.0
  Cl  Cl20  1  0.967  0.967  0.291  1.0
  Cl  Cl21  1  0.949  0.353  0.874  1.0
  Cl  Cl22  1  0.051  0.647  0.126  1.0
  Cl  Cl23  1  0.748  0.748  0.930  1.0
  Cl  Cl24  1  0.353  0.949  0.874  1.0
  Cl  Cl25  1  0.033  0.033  0.709  1.0
  Cl  Cl26  1  0.647  0.051  0.126  1.0
  Cl  Cl27  1  0.252  0.252  0.070  1.0
[/CIF]
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The material structure described by AuCl4C5S4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two tetrakis(methylthio)tetrathiafulvalene molecules and four AuCl4 clusters. In each AuCl4 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AuC5(SCl)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.516
_cell_length_b   9.516
_cell_length_c   8.137
_cell_angle_alpha   85.496
_cell_angle_beta   85.496
_cell_angle_gamma   74.127
_symmetry_Int_Tables_number   1
_cell_volume   705.332
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.857  0.857  0.114  1.0
  Au  Au1  1  0.143  0.143  0.886  1.0
  C  C2  1  0.346  0.466  0.673  1.0
  C  C3  1  0.479  0.479  0.926  1.0
  C  C4  1  0.919  0.355  0.397  1.0
  C  C5  1  0.466  0.346  0.673  1.0
  C  C6  1  0.355  0.919  0.397  1.0
  C  C7  1  0.521  0.521  0.074  1.0
  C  C8  1  0.645  0.081  0.603  1.0
  C  C9  1  0.081  0.645  0.603  1.0
  C  C10  1  0.534  0.654  0.327  1.0
  C  C11  1  0.654  0.534  0.327  1.0
  S  S12  1  0.211  0.510  0.523  1.0
  S  S13  1  0.677  0.421  0.166  1.0
  S  S14  1  0.579  0.323  0.834  1.0
  S  S15  1  0.789  0.490  0.477  1.0
  S  S16  1  0.490  0.789  0.477  1.0
  S  S17  1  0.510  0.211  0.523  1.0
  S  S18  1  0.421  0.677  0.166  1.0
  S  S19  1  0.323  0.579  0.834  1.0
  Cl  Cl20  1  0.967  0.967  0.291  1.0
  Cl  Cl21  1  0.949  0.353  0.874  1.0
  Cl  Cl22  1  0.051  0.647  0.126  1.0
  Cl  Cl23  1  0.748  0.748  0.930  1.0
  Cl  Cl24  1  0.353  0.949  0.874  1.0
  Cl  Cl25  1  0.033  0.033  0.709  1.0
  Cl  Cl26  1  0.647  0.051  0.126  1.0
  Cl  Cl27  1  0.252  0.252  0.070  1.0
[/CIF]
.