The material described by LaWP3H3O9 crystallizes in the triclinic P-1 space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(5), one O(9), two equivalent O(6), and two equivalent O(8) atoms. W(1) is bonded in a 5-coordinate geometry to one H(2), one O(2), one O(3), one O(4), and one O(7) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted tetrahedral geometry to one H(3), one O(6), one O(7), and one O(8) atom. In the second P site, P(2) is bonded in a distorted tetrahedral geometry to one H(2), one O(4), one O(5), and one O(9) atom. In the third P site, P(3) is bonded in a distorted tetrahedral geometry to one H(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(3) atom. In the second H site, H(2) is bonded in a bent 120 degrees geometry to one W(1) and one P(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one P(1) atom. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a distorted linear geometry to one La(1) and one P(2) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one P(3) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one W(1), and one P(3) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(3) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one P(2) atom. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one La(1) and one P(2) atom. In the seventh O site, O(6) is bonded in a 1-coordinate geometry to two equivalent La(1) and one P(1) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one W(1) and one P(1) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to two equivalent La(1) and one P(1) atom. is represented by the CIF card [CIF]
data_LaP3H3WO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.626
_cell_length_b   9.432
_cell_length_c   8.588
_cell_angle_alpha   122.756
_cell_angle_beta   98.511
_cell_angle_gamma   99.530
_symmetry_Int_Tables_number   1
_cell_volume   490.874
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.295  0.636  0.136  1.0
  La  La1  1  0.705  0.364  0.864  1.0
  P  P2  1  0.152  0.259  0.713  1.0
  P  P3  1  0.848  0.741  0.287  1.0
  P  P4  1  0.527  0.119  0.316  1.0
  P  P5  1  0.473  0.880  0.684  1.0
  P  P6  1  0.009  0.306  0.199  1.0
  P  P7  1  0.991  0.695  0.801  1.0
  H  H8  1  0.071  0.458  0.390  1.0
  H  H9  1  0.929  0.542  0.610  1.0
  H  H10  1  0.696  0.132  0.257  1.0
  H  H11  1  0.304  0.868  0.743  1.0
  H  H12  1  0.133  0.225  0.530  1.0
  H  H13  1  0.867  0.775  0.470  1.0
  W  W14  1  0.767  0.918  0.069  1.0
  W  W15  1  0.233  0.082  0.931  1.0
  O  O16  1  0.824  0.295  0.093  1.0
  O  O17  1  0.175  0.705  0.907  1.0
  O  O18  1  0.171  0.323  0.112  1.0
  O  O19  1  0.829  0.677  0.888  1.0
  O  O20  1  0.998  0.145  0.210  1.0
  O  O21  1  0.002  0.855  0.790  1.0
  O  O22  1  0.404  0.157  0.193  1.0
  O  O23  1  0.596  0.843  0.807  1.0
  O  O24  1  0.593  0.267  0.530  1.0
  O  O25  1  0.407  0.733  0.470  1.0
  O  O26  1  0.990  0.645  0.196  1.0
  O  O27  1  0.010  0.355  0.804  1.0
  O  O28  1  0.126  0.082  0.688  1.0
  O  O29  1  0.874  0.918  0.312  1.0
  O  O30  1  0.649  0.615  0.153  1.0
  O  O31  1  0.351  0.385  0.847  1.0
  O  O32  1  0.462  0.933  0.262  1.0
  O  O33  1  0.538  0.067  0.738  1.0
[/CIF]
.
The material described by LaWP3H3O9 crystallizes in the triclinic P-1 space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(5), one O(9), two equivalent O(6), and two equivalent O(8) atoms. W(1) is bonded in a 5-coordinate geometry to one H(2), one O(2), one O(3), one O(4), and one O(7) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted tetrahedral geometry to one H(3), one O(6), one O(7), and one O(8) atom. In the second P site, P(2) is bonded in a distorted tetrahedral geometry to one H(2), one O(4), one O(5), and one O(9) atom. In the third P site, P(3) is bonded in a distorted tetrahedral geometry to one H(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(3) atom. In the second H site, H(2) is bonded in a bent 120 degrees geometry to one W(1) and one P(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one P(1) atom. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a distorted linear geometry to one La(1) and one P(2) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one P(3) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one W(1), and one P(3) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(3) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one P(2) atom. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one La(1) and one P(2) atom. In the seventh O site, O(6) is bonded in a 1-coordinate geometry to two equivalent La(1) and one P(1) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one W(1) and one P(1) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to two equivalent La(1) and one P(1) atom. is represented by the CIF card [CIF]
data_LaP3H3WO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.626
_cell_length_b   9.432
_cell_length_c   8.588
_cell_angle_alpha   122.756
_cell_angle_beta   98.511
_cell_angle_gamma   99.530
_symmetry_Int_Tables_number   1
_cell_volume   490.874
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.295  0.636  0.136  1.0
  La  La1  1  0.705  0.364  0.864  1.0
  P  P2  1  0.152  0.259  0.713  1.0
  P  P3  1  0.848  0.741  0.287  1.0
  P  P4  1  0.527  0.119  0.316  1.0
  P  P5  1  0.473  0.880  0.684  1.0
  P  P6  1  0.009  0.306  0.199  1.0
  P  P7  1  0.991  0.695  0.801  1.0
  H  H8  1  0.071  0.458  0.390  1.0
  H  H9  1  0.929  0.542  0.610  1.0
  H  H10  1  0.696  0.132  0.257  1.0
  H  H11  1  0.304  0.868  0.743  1.0
  H  H12  1  0.133  0.225  0.530  1.0
  H  H13  1  0.867  0.775  0.470  1.0
  W  W14  1  0.767  0.918  0.069  1.0
  W  W15  1  0.233  0.082  0.931  1.0
  O  O16  1  0.824  0.295  0.093  1.0
  O  O17  1  0.175  0.705  0.907  1.0
  O  O18  1  0.171  0.323  0.112  1.0
  O  O19  1  0.829  0.677  0.888  1.0
  O  O20  1  0.998  0.145  0.210  1.0
  O  O21  1  0.002  0.855  0.790  1.0
  O  O22  1  0.404  0.157  0.193  1.0
  O  O23  1  0.596  0.843  0.807  1.0
  O  O24  1  0.593  0.267  0.530  1.0
  O  O25  1  0.407  0.733  0.470  1.0
  O  O26  1  0.990  0.645  0.196  1.0
  O  O27  1  0.010  0.355  0.804  1.0
  O  O28  1  0.126  0.082  0.688  1.0
  O  O29  1  0.874  0.918  0.312  1.0
  O  O30  1  0.649  0.615  0.153  1.0
  O  O31  1  0.351  0.385  0.847  1.0
  O  O32  1  0.462  0.933  0.262  1.0
  O  O33  1  0.538  0.067  0.738  1.0
[/CIF]
.