The material structure described by AgCN3H6S is Cubic alpha N2-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight AgCN3H6S clusters. Ag(1) is bonded in a distorted trigonal planar geometry to one N(2), one N(3), and one S(1) atom. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one H(1), one H(2), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one H(4), one H(5), and one H(6) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. S(1) is bonded in a water-like geometry to one Ag(1) and one C(1) atom. is represented by the CIF file [CIF]
data_AgH6CSN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.274
_cell_length_b   7.707
_cell_length_c   13.337
_cell_angle_alpha   96.599
_cell_angle_beta   90.000
_cell_angle_gamma   118.160
_symmetry_Int_Tables_number   1
_cell_volume   653.608
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.964  0.891  0.850  1.0
  Ag  Ag1  1  0.073  0.109  0.650  1.0
  Ag  Ag2  1  0.036  0.109  0.150  1.0
  Ag  Ag3  1  0.927  0.891  0.350  1.0
  H  H4  1  0.132  0.625  0.828  1.0
  H  H5  1  0.507  0.375  0.672  1.0
  H  H6  1  0.868  0.375  0.172  1.0
  H  H7  1  0.493  0.625  0.328  1.0
  H  H8  1  0.931  0.530  0.900  1.0
  H  H9  1  0.402  0.470  0.600  1.0
  H  H10  1  0.069  0.470  0.100  1.0
  H  H11  1  0.598  0.530  0.400  1.0
  H  H12  1  0.162  0.709  0.950  1.0
  H  H13  1  0.453  0.291  0.550  1.0
  H  H14  1  0.838  0.291  0.050  1.0
  H  H15  1  0.547  0.709  0.450  1.0
  H  H16  1  0.529  0.676  0.865  1.0
  H  H17  1  0.853  0.324  0.635  1.0
  H  H18  1  0.471  0.324  0.135  1.0
  H  H19  1  0.147  0.676  0.365  1.0
  H  H20  1  0.563  0.787  0.762  1.0
  H  H21  1  0.777  0.213  0.738  1.0
  H  H22  1  0.437  0.213  0.238  1.0
  H  H23  1  0.223  0.787  0.262  1.0
  H  H24  1  0.599  0.917  0.874  1.0
  H  H25  1  0.682  0.083  0.626  1.0
  H  H26  1  0.401  0.083  0.126  1.0
  H  H27  1  0.318  0.917  0.374  1.0
  C  C28  1  0.457  0.231  0.891  1.0
  C  C29  1  0.226  0.769  0.609  1.0
  C  C30  1  0.543  0.769  0.109  1.0
  C  C31  1  0.774  0.231  0.391  1.0
  S  S32  1  0.240  0.247  0.883  1.0
  S  S33  1  0.993  0.753  0.617  1.0
  S  S34  1  0.760  0.753  0.117  1.0
  S  S35  1  0.007  0.247  0.383  1.0
  N  N36  1  0.618  0.227  0.898  1.0
  N  N37  1  0.391  0.773  0.602  1.0
  N  N38  1  0.382  0.773  0.102  1.0
  N  N39  1  0.609  0.227  0.398  1.0
  N  N40  1  0.060  0.658  0.887  1.0
  N  N41  1  0.402  0.342  0.613  1.0
  N  N42  1  0.940  0.342  0.113  1.0
  N  N43  1  0.598  0.658  0.387  1.0
  N  N44  1  0.617  0.804  0.835  1.0
  N  N45  1  0.813  0.196  0.665  1.0
  N  N46  1  0.383  0.196  0.165  1.0
  N  N47  1  0.187  0.804  0.335  1.0
[/CIF]
.
The material structure described by AgCN3H6S is Cubic alpha N2-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight AgCN3H6S clusters. Ag(1) is bonded in a distorted trigonal planar geometry to one N(2), one N(3), and one S(1) atom. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one H(1), one H(2), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one H(4), one H(5), and one H(6) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. S(1) is bonded in a water-like geometry to one Ag(1) and one C(1) atom. is represented by the CIF file [CIF]
data_AgH6CSN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.274
_cell_length_b   7.707
_cell_length_c   13.337
_cell_angle_alpha   96.599
_cell_angle_beta   90.000
_cell_angle_gamma   118.160
_symmetry_Int_Tables_number   1
_cell_volume   653.608
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.964  0.891  0.850  1.0
  Ag  Ag1  1  0.073  0.109  0.650  1.0
  Ag  Ag2  1  0.036  0.109  0.150  1.0
  Ag  Ag3  1  0.927  0.891  0.350  1.0
  H  H4  1  0.132  0.625  0.828  1.0
  H  H5  1  0.507  0.375  0.672  1.0
  H  H6  1  0.868  0.375  0.172  1.0
  H  H7  1  0.493  0.625  0.328  1.0
  H  H8  1  0.931  0.530  0.900  1.0
  H  H9  1  0.402  0.470  0.600  1.0
  H  H10  1  0.069  0.470  0.100  1.0
  H  H11  1  0.598  0.530  0.400  1.0
  H  H12  1  0.162  0.709  0.950  1.0
  H  H13  1  0.453  0.291  0.550  1.0
  H  H14  1  0.838  0.291  0.050  1.0
  H  H15  1  0.547  0.709  0.450  1.0
  H  H16  1  0.529  0.676  0.865  1.0
  H  H17  1  0.853  0.324  0.635  1.0
  H  H18  1  0.471  0.324  0.135  1.0
  H  H19  1  0.147  0.676  0.365  1.0
  H  H20  1  0.563  0.787  0.762  1.0
  H  H21  1  0.777  0.213  0.738  1.0
  H  H22  1  0.437  0.213  0.238  1.0
  H  H23  1  0.223  0.787  0.262  1.0
  H  H24  1  0.599  0.917  0.874  1.0
  H  H25  1  0.682  0.083  0.626  1.0
  H  H26  1  0.401  0.083  0.126  1.0
  H  H27  1  0.318  0.917  0.374  1.0
  C  C28  1  0.457  0.231  0.891  1.0
  C  C29  1  0.226  0.769  0.609  1.0
  C  C30  1  0.543  0.769  0.109  1.0
  C  C31  1  0.774  0.231  0.391  1.0
  S  S32  1  0.240  0.247  0.883  1.0
  S  S33  1  0.993  0.753  0.617  1.0
  S  S34  1  0.760  0.753  0.117  1.0
  S  S35  1  0.007  0.247  0.383  1.0
  N  N36  1  0.618  0.227  0.898  1.0
  N  N37  1  0.391  0.773  0.602  1.0
  N  N38  1  0.382  0.773  0.102  1.0
  N  N39  1  0.609  0.227  0.398  1.0
  N  N40  1  0.060  0.658  0.887  1.0
  N  N41  1  0.402  0.342  0.613  1.0
  N  N42  1  0.940  0.342  0.113  1.0
  N  N43  1  0.598  0.658  0.387  1.0
  N  N44  1  0.617  0.804  0.835  1.0
  N  N45  1  0.813  0.196  0.665  1.0
  N  N46  1  0.383  0.196  0.165  1.0
  N  N47  1  0.187  0.804  0.335  1.0
[/CIF]
.