The material described by VAgOF4 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. O(1) is bonded in a distorted single-bond geometry to one V(1) and one Ag(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one V(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one V(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAgOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.185
_cell_length_b   5.735
_cell_length_c   14.096
_cell_angle_alpha   80.383
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   413.213
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.944  0.177  0.143  1.0
  V  V1  1  0.444  0.823  0.357  1.0
  V  V2  1  0.056  0.823  0.857  1.0
  V  V3  1  0.556  0.177  0.643  1.0
  Ag  Ag4  1  0.434  0.654  0.112  1.0
  Ag  Ag5  1  0.934  0.346  0.388  1.0
  Ag  Ag6  1  0.566  0.346  0.888  1.0
  Ag  Ag7  1  0.066  0.654  0.612  1.0
  O  O8  1  0.154  0.351  0.082  1.0
  O  O9  1  0.654  0.649  0.418  1.0
  O  O10  1  0.846  0.649  0.918  1.0
  O  O11  1  0.346  0.351  0.582  1.0
  F  F12  1  0.034  0.886  0.116  1.0
  F  F13  1  0.534  0.114  0.384  1.0
  F  F14  1  0.966  0.114  0.884  1.0
  F  F15  1  0.466  0.886  0.616  1.0
  F  F16  1  0.754  0.392  0.199  1.0
  F  F17  1  0.254  0.608  0.301  1.0
  F  F18  1  0.246  0.608  0.801  1.0
  F  F19  1  0.746  0.392  0.699  1.0
  F  F20  1  0.673  0.180  0.058  1.0
  F  F21  1  0.173  0.820  0.442  1.0
  F  F22  1  0.327  0.820  0.942  1.0
  F  F23  1  0.827  0.180  0.558  1.0
  F  F24  1  0.106  0.099  0.262  1.0
  F  F25  1  0.606  0.901  0.238  1.0
  F  F26  1  0.894  0.901  0.738  1.0
  F  F27  1  0.394  0.099  0.762  1.0
[/CIF]
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The material described by VAgOF4 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. O(1) is bonded in a distorted single-bond geometry to one V(1) and one Ag(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one V(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one V(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAgOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.185
_cell_length_b   5.735
_cell_length_c   14.096
_cell_angle_alpha   80.383
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   413.213
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.944  0.177  0.143  1.0
  V  V1  1  0.444  0.823  0.357  1.0
  V  V2  1  0.056  0.823  0.857  1.0
  V  V3  1  0.556  0.177  0.643  1.0
  Ag  Ag4  1  0.434  0.654  0.112  1.0
  Ag  Ag5  1  0.934  0.346  0.388  1.0
  Ag  Ag6  1  0.566  0.346  0.888  1.0
  Ag  Ag7  1  0.066  0.654  0.612  1.0
  O  O8  1  0.154  0.351  0.082  1.0
  O  O9  1  0.654  0.649  0.418  1.0
  O  O10  1  0.846  0.649  0.918  1.0
  O  O11  1  0.346  0.351  0.582  1.0
  F  F12  1  0.034  0.886  0.116  1.0
  F  F13  1  0.534  0.114  0.384  1.0
  F  F14  1  0.966  0.114  0.884  1.0
  F  F15  1  0.466  0.886  0.616  1.0
  F  F16  1  0.754  0.392  0.199  1.0
  F  F17  1  0.254  0.608  0.301  1.0
  F  F18  1  0.246  0.608  0.801  1.0
  F  F19  1  0.746  0.392  0.699  1.0
  F  F20  1  0.673  0.180  0.058  1.0
  F  F21  1  0.173  0.820  0.442  1.0
  F  F22  1  0.327  0.820  0.942  1.0
  F  F23  1  0.827  0.180  0.558  1.0
  F  F24  1  0.106  0.099  0.262  1.0
  F  F25  1  0.606  0.901  0.238  1.0
  F  F26  1  0.894  0.901  0.738  1.0
  F  F27  1  0.394  0.099  0.762  1.0
[/CIF]
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