The structure described by Li7Co5O12 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(11), one O(14), one O(15), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(7)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the second Li site, Li(2) is bonded to one O(12), one O(13), one O(16), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-11°. In the third Li site, Li(3) is bonded to one O(12), one O(21), one O(23), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, and edges with two equivalent Li(14)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-11°. In the fourth Li site, Li(4) is bonded to one O(10), one O(11), one O(22), one O(24), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, and edges with two equivalent Li(13)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the fifth Li site, Li(5) is bonded to one O(1), one O(13), one O(16), one O(17), one O(19), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, and edges with two equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the sixth Li site, Li(6) is bonded to one O(14), one O(15), one O(18), one O(2), one O(20), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Li(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the seventh Li site, Li(7) is bonded to one O(1), one O(11), one O(13), one O(17), one O(24), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(13)O6 octahedra, and edges with two equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the eighth Li site, Li(8) is bonded to one O(12), one O(14), one O(18), one O(2), one O(23), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(14)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the ninth Li site, Li(9) is bonded to one O(15), one O(2), one O(20), one O(21), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the tenth Li site, Li(10) is bonded to one O(1), one O(10), one O(16), one O(19), one O(22), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, and edges with two equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the eleventh Li site, Li(11) is bonded to one O(15), one O(20), one O(21), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Li(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the twelfth Li site, Li(12) is bonded to one O(10), one O(16), one O(19), one O(22), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the thirteenth Li site, Li(13) is bonded to one O(11), one O(13), one O(17), one O(24), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the fourteenth Li site, Li(14) is bonded to one O(12), one O(14), one O(18), one O(23), one O(3), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Co(10)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the second Co site, Co(2) is bonded to one O(13), one O(20), one O(24), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the third Co site, Co(3) is bonded to one O(12), one O(16), one O(18), one O(22), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the fourth Co site, Co(4) is bonded to one O(12), one O(16), one O(18), one O(2), one O(22), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. In the fifth Co site, Co(5) is bonded to one O(13), one O(2), one O(20), one O(24), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the sixth Co site, Co(6) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the seventh Co site, Co(7) is bonded to one O(10), one O(14), one O(19), one O(23), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Co(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the eighth Co site, Co(8) is bonded to one O(11), one O(15), one O(17), one O(21), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the ninth Co site, Co(9) is bonded to one O(1), one O(11), one O(15), one O(17), one O(21), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the tenth Co site, Co(10) is bonded to one O(1), one O(10), one O(14), one O(19), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(10), one Li(5), one Li(7), one Co(1), one Co(10), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(17)Li3Co3 octahedra, and edges with two equivalent O(19)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(6), one Li(8), one Li(9), one Co(4), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(18)Li3Co3 octahedra, and edges with two equivalent O(20)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(3) is bonded to one Li(11), one Li(14), one Li(3), one Co(1), one Co(10), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(21)Li3Co3 octahedra, and edges with two equivalent O(23)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fourth O site, O(4) is bonded to one Li(12), one Li(13), one Li(4), one Co(4), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with two equivalent O(22)Li3Co3 octahedra, and edges with two equivalent O(24)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fifth O site, O(5) is bonded to one Li(1), one Li(12), one Li(13), one Li(4), one Co(7), and one Co(8) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(10)Li4Co2 octahedra, and edges with two equivalent O(11)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the sixth O site, O(6) is bonded to one Li(11), one Li(14), one Li(2), one Li(3), one Co(2), and one Co(3) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(12)Li4Co2 octahedra, and edges with two equivalent O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the seventh O site, O(7) is bonded to one Li(1), one Li(6), one Li(8), one Li(9), one Co(7), and one Co(8) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with two equivalent O(14)Li4Co2 octahedra, and edges with two equivalent O(15)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the eighth O site, O(8) is bonded to one Li(10), one Li(2), one Li(5), one Li(7), one Co(2), and one Co(3) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(13)Li4Co2 octahedra, and edges with two equivalent O(16)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the ninth O site, O(9) is bonded to one Li(11), one Li(2), one Li(3), one Li(9), one Co(2), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(20)Li3Co3 octahedra, and edges with two equivalent O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the tenth O site, O(10) is bonded to one Li(1), one Li(10), one Li(12), one Li(4), one Co(10), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(19)Li3Co3 octahedra, and edges with two equivalent O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(13), one Li(4), one Li(7), one Co(8), and one Co(9) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(17)Li3Co3 octahedra, and edges with two equivalent O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the twelfth O site, O(12) is bonded to one Li(14), one Li(2), one Li(3), one Li(8), one Co(3), and one Co(4) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(18)Li3Co3 octahedra, and edges with two equivalent O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the thirteenth O site, O(13) is bonded to one Li(13), one Li(2), one Li(5), one Li(7), one Co(2), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(24)Li3Co3 octahedra, and edges with two equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(14), one Li(6), one Li(8), one Co(10), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with two equivalent O(23)Li3Co3 octahedra, and edges with two equivalent O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(11), one Li(6), one Li(9), one Co(8), and one Co(9) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(21)Li3Co3 octahedra, and edges with two equivalent O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(12), one Li(2), one Li(5), one Co(3), and one Co(4) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with two equivalent O(22)Li3Co3 octahedra, and edges with two equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the seventeenth O site, O(17) is bonded to one Li(13), one Li(5), one Li(7), one Co(1), one Co(8), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(1)Li3Co3 octahedra, and edges with two equivalent O(11)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eighteenth O site, O(18) is bonded to one Li(14), one Li(6), one Li(8), one Co(3), one Co(4), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(2)Li3Co3 octahedra, and edges with two equivalent O(12)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the nineteenth O site, O(19) is bonded to one Li(10), one Li(12), one Li(5), one Co(1), one Co(10), and one Co(7) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(1)Li3Co3 octahedra, and edges with two equivalent O(10)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the twentieth O site, O(20) is bonded to one Li(11), one Li(6), one Li(9), one Co(2), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(2)Li3Co3 octahedra, and edges with two equivalent O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the twenty-first O site, O(21) is bonded to one Li(11), one Li(3), one Li(9), one Co(1), one Co(8), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(3)Li3Co3 octahedra, and edges with two equivalent O(15)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(12), one Li(4), one Co(3), one Co(4), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, and edges with two equivalent O(16)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the twenty-third O site, O(23) is bonded to one Li(14), one Li(3), one Li(8), one Co(1), one Co(10), and one Co(7) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(3)Li3Co3 octahedra, and edges with two equivalent O(14)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the twenty-fourth O site, O(24) is bonded to one Li(13), one Li(4), one Li(7), one Co(2), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, and edges with two equivalent O(13)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. is represented by the CIF card [CIF]
data_Li7Co5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.954
_cell_length_b   6.499
_cell_length_c   6.568
_cell_angle_alpha   83.841
_cell_angle_beta   81.900
_cell_angle_gamma   82.819
_symmetry_Int_Tables_number   1
_cell_volume   206.838
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.333  0.666  1.0
  Co  Co1  1  0.996  0.995  0.006  1.0
  Co  Co2  1  0.004  0.672  0.327  1.0
  Co  Co3  1  0.500  0.504  0.495  1.0
  Co  Co4  1  0.499  0.163  0.838  1.0
  Li  Li5  1  0.500  0.834  0.166  1.0
  Li  Li6  1  0.745  0.081  0.417  1.0
  Li  Li7  1  0.254  0.583  0.917  1.0
  Li  Li8  1  0.751  0.753  0.756  1.0
  Li  Li9  1  0.750  0.423  0.087  1.0
  Li  Li10  1  0.249  0.244  0.246  1.0
  Li  Li11  1  0.250  0.914  0.577  1.0
  O  O12  1  0.632  0.437  0.778  1.0
  O  O13  1  0.366  0.229  0.554  1.0
  O  O14  1  0.103  0.950  0.285  1.0
  O  O15  1  0.897  0.717  0.049  1.0
  O  O16  1  0.640  0.126  0.102  1.0
  O  O17  1  0.637  0.763  0.461  1.0
  O  O18  1  0.364  0.905  0.873  1.0
  O  O19  1  0.360  0.541  0.232  1.0
  O  O20  1  0.137  0.613  0.607  1.0
  O  O21  1  0.134  0.275  0.945  1.0
  O  O22  1  0.864  0.392  0.388  1.0
  O  O23  1  0.863  0.054  0.726  1.0
[/CIF]
.
The structure described by Li7Co5O12 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(11), one O(14), one O(15), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(7)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the second Li site, Li(2) is bonded to one O(12), one O(13), one O(16), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-11°. In the third Li site, Li(3) is bonded to one O(12), one O(21), one O(23), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, and edges with two equivalent Li(14)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-11°. In the fourth Li site, Li(4) is bonded to one O(10), one O(11), one O(22), one O(24), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, and edges with two equivalent Li(13)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the fifth Li site, Li(5) is bonded to one O(1), one O(13), one O(16), one O(17), one O(19), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, and edges with two equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the sixth Li site, Li(6) is bonded to one O(14), one O(15), one O(18), one O(2), one O(20), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Li(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the seventh Li site, Li(7) is bonded to one O(1), one O(11), one O(13), one O(17), one O(24), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(13)O6 octahedra, and edges with two equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the eighth Li site, Li(8) is bonded to one O(12), one O(14), one O(18), one O(2), one O(23), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(14)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the ninth Li site, Li(9) is bonded to one O(15), one O(2), one O(20), one O(21), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the tenth Li site, Li(10) is bonded to one O(1), one O(10), one O(16), one O(19), one O(22), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, and edges with two equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the eleventh Li site, Li(11) is bonded to one O(15), one O(20), one O(21), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Li(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the twelfth Li site, Li(12) is bonded to one O(10), one O(16), one O(19), one O(22), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the thirteenth Li site, Li(13) is bonded to one O(11), one O(13), one O(17), one O(24), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the fourteenth Li site, Li(14) is bonded to one O(12), one O(14), one O(18), one O(23), one O(3), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Co(10)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the second Co site, Co(2) is bonded to one O(13), one O(20), one O(24), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the third Co site, Co(3) is bonded to one O(12), one O(16), one O(18), one O(22), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the fourth Co site, Co(4) is bonded to one O(12), one O(16), one O(18), one O(2), one O(22), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. In the fifth Co site, Co(5) is bonded to one O(13), one O(2), one O(20), one O(24), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the sixth Co site, Co(6) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the seventh Co site, Co(7) is bonded to one O(10), one O(14), one O(19), one O(23), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Co(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the eighth Co site, Co(8) is bonded to one O(11), one O(15), one O(17), one O(21), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the ninth Co site, Co(9) is bonded to one O(1), one O(11), one O(15), one O(17), one O(21), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the tenth Co site, Co(10) is bonded to one O(1), one O(10), one O(14), one O(19), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(10), one Li(5), one Li(7), one Co(1), one Co(10), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(17)Li3Co3 octahedra, and edges with two equivalent O(19)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(6), one Li(8), one Li(9), one Co(4), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(18)Li3Co3 octahedra, and edges with two equivalent O(20)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(3) is bonded to one Li(11), one Li(14), one Li(3), one Co(1), one Co(10), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(21)Li3Co3 octahedra, and edges with two equivalent O(23)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fourth O site, O(4) is bonded to one Li(12), one Li(13), one Li(4), one Co(4), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with two equivalent O(22)Li3Co3 octahedra, and edges with two equivalent O(24)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fifth O site, O(5) is bonded to one Li(1), one Li(12), one Li(13), one Li(4), one Co(7), and one Co(8) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(10)Li4Co2 octahedra, and edges with two equivalent O(11)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the sixth O site, O(6) is bonded to one Li(11), one Li(14), one Li(2), one Li(3), one Co(2), and one Co(3) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(12)Li4Co2 octahedra, and edges with two equivalent O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the seventh O site, O(7) is bonded to one Li(1), one Li(6), one Li(8), one Li(9), one Co(7), and one Co(8) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with two equivalent O(14)Li4Co2 octahedra, and edges with two equivalent O(15)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the eighth O site, O(8) is bonded to one Li(10), one Li(2), one Li(5), one Li(7), one Co(2), and one Co(3) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(13)Li4Co2 octahedra, and edges with two equivalent O(16)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the ninth O site, O(9) is bonded to one Li(11), one Li(2), one Li(3), one Li(9), one Co(2), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(20)Li3Co3 octahedra, and edges with two equivalent O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the tenth O site, O(10) is bonded to one Li(1), one Li(10), one Li(12), one Li(4), one Co(10), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(19)Li3Co3 octahedra, and edges with two equivalent O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(13), one Li(4), one Li(7), one Co(8), and one Co(9) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(17)Li3Co3 octahedra, and edges with two equivalent O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the twelfth O site, O(12) is bonded to one Li(14), one Li(2), one Li(3), one Li(8), one Co(3), and one Co(4) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(18)Li3Co3 octahedra, and edges with two equivalent O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the thirteenth O site, O(13) is bonded to one Li(13), one Li(2), one Li(5), one Li(7), one Co(2), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(24)Li3Co3 octahedra, and edges with two equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(14), one Li(6), one Li(8), one Co(10), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with two equivalent O(23)Li3Co3 octahedra, and edges with two equivalent O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(11), one Li(6), one Li(9), one Co(8), and one Co(9) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(21)Li3Co3 octahedra, and edges with two equivalent O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(12), one Li(2), one Li(5), one Co(3), and one Co(4) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with two equivalent O(22)Li3Co3 octahedra, and edges with two equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the seventeenth O site, O(17) is bonded to one Li(13), one Li(5), one Li(7), one Co(1), one Co(8), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(1)Li3Co3 octahedra, and edges with two equivalent O(11)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eighteenth O site, O(18) is bonded to one Li(14), one Li(6), one Li(8), one Co(3), one Co(4), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(2)Li3Co3 octahedra, and edges with two equivalent O(12)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the nineteenth O site, O(19) is bonded to one Li(10), one Li(12), one Li(5), one Co(1), one Co(10), and one Co(7) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(1)Li3Co3 octahedra, and edges with two equivalent O(10)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the twentieth O site, O(20) is bonded to one Li(11), one Li(6), one Li(9), one Co(2), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(2)Li3Co3 octahedra, and edges with two equivalent O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the twenty-first O site, O(21) is bonded to one Li(11), one Li(3), one Li(9), one Co(1), one Co(8), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(3)Li3Co3 octahedra, and edges with two equivalent O(15)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(12), one Li(4), one Co(3), one Co(4), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, and edges with two equivalent O(16)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the twenty-third O site, O(23) is bonded to one Li(14), one Li(3), one Li(8), one Co(1), one Co(10), and one Co(7) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with two equivalent O(3)Li3Co3 octahedra, and edges with two equivalent O(14)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the twenty-fourth O site, O(24) is bonded to one Li(13), one Li(4), one Li(7), one Co(2), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra,  an edgeedge with one O(9)Li4Co2 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, and edges with two equivalent O(13)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. is represented by the CIF card [CIF]
data_Li7Co5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.954
_cell_length_b   6.499
_cell_length_c   6.568
_cell_angle_alpha   83.841
_cell_angle_beta   81.900
_cell_angle_gamma   82.819
_symmetry_Int_Tables_number   1
_cell_volume   206.838
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.333  0.666  1.0
  Co  Co1  1  0.996  0.995  0.006  1.0
  Co  Co2  1  0.004  0.672  0.327  1.0
  Co  Co3  1  0.500  0.504  0.495  1.0
  Co  Co4  1  0.499  0.163  0.838  1.0
  Li  Li5  1  0.500  0.834  0.166  1.0
  Li  Li6  1  0.745  0.081  0.417  1.0
  Li  Li7  1  0.254  0.583  0.917  1.0
  Li  Li8  1  0.751  0.753  0.756  1.0
  Li  Li9  1  0.750  0.423  0.087  1.0
  Li  Li10  1  0.249  0.244  0.246  1.0
  Li  Li11  1  0.250  0.914  0.577  1.0
  O  O12  1  0.632  0.437  0.778  1.0
  O  O13  1  0.366  0.229  0.554  1.0
  O  O14  1  0.103  0.950  0.285  1.0
  O  O15  1  0.897  0.717  0.049  1.0
  O  O16  1  0.640  0.126  0.102  1.0
  O  O17  1  0.637  0.763  0.461  1.0
  O  O18  1  0.364  0.905  0.873  1.0
  O  O19  1  0.360  0.541  0.232  1.0
  O  O20  1  0.137  0.613  0.607  1.0
  O  O21  1  0.134  0.275  0.945  1.0
  O  O22  1  0.864  0.392  0.388  1.0
  O  O23  1  0.863  0.054  0.726  1.0
[/CIF]
.