The structure described by Dy2Mn2O7 crystallizes in the cubic Fd-3m space group. Dy(1) is bonded to two equivalent O(2) and six equivalent O(1) atoms to form distorted DyO8 hexagonal bipyramids that share edges with six equivalent Dy(1)O8 hexagonal bipyramids and edges with six equivalent Mn(1)O6 octahedra. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with six equivalent Dy(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Dy(1) and two equivalent Mn(1) atoms to form distorted ODy2Mn2 tetrahedra that share corners with two equivalent O(2)Dy4 tetrahedra, corners with twelve equivalent O(1)Dy2Mn2 tetrahedra,  an edgeedge with one O(2)Dy4 tetrahedra, and edges with four equivalent O(1)Dy2Mn2 tetrahedra. In the second O site, O(2) is bonded to four equivalent Dy(1) atoms to form ODy4 tetrahedra that share corners with four equivalent O(2)Dy4 tetrahedra, corners with twelve equivalent O(1)Dy2Mn2 tetrahedra, and edges with six equivalent O(1)Dy2Mn2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy2Mn2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.999
_cell_length_b   6.999
_cell_length_c   6.999
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   242.396
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.125  0.625  0.125  1.0
  Dy  Dy1  1  0.125  0.125  0.625  1.0
  Dy  Dy2  1  0.625  0.125  0.125  1.0
  Dy  Dy3  1  0.125  0.125  0.125  1.0
  Mn  Mn4  1  0.625  0.625  0.625  1.0
  Mn  Mn5  1  0.125  0.625  0.625  1.0
  Mn  Mn6  1  0.625  0.625  0.125  1.0
  Mn  Mn7  1  0.625  0.125  0.625  1.0
  O  O8  1  0.297  0.703  0.703  1.0
  O  O9  1  0.547  0.953  0.953  1.0
  O  O10  1  0.703  0.703  0.297  1.0
  O  O11  1  0.297  0.297  0.703  1.0
  O  O12  1  0.000  0.000  0.000  1.0
  O  O13  1  0.703  0.297  0.703  1.0
  O  O14  1  0.297  0.703  0.297  1.0
  O  O15  1  0.953  0.547  0.953  1.0
  O  O16  1  0.547  0.547  0.953  1.0
  O  O17  1  0.953  0.953  0.547  1.0
  O  O18  1  0.250  0.250  0.250  1.0
  O  O19  1  0.547  0.953  0.547  1.0
  O  O20  1  0.703  0.297  0.297  1.0
  O  O21  1  0.953  0.547  0.547  1.0
[/CIF]
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The structure described by Dy2Mn2O7 crystallizes in the cubic Fd-3m space group. Dy(1) is bonded to two equivalent O(2) and six equivalent O(1) atoms to form distorted DyO8 hexagonal bipyramids that share edges with six equivalent Dy(1)O8 hexagonal bipyramids and edges with six equivalent Mn(1)O6 octahedra. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with six equivalent Dy(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Dy(1) and two equivalent Mn(1) atoms to form distorted ODy2Mn2 tetrahedra that share corners with two equivalent O(2)Dy4 tetrahedra, corners with twelve equivalent O(1)Dy2Mn2 tetrahedra,  an edgeedge with one O(2)Dy4 tetrahedra, and edges with four equivalent O(1)Dy2Mn2 tetrahedra. In the second O site, O(2) is bonded to four equivalent Dy(1) atoms to form ODy4 tetrahedra that share corners with four equivalent O(2)Dy4 tetrahedra, corners with twelve equivalent O(1)Dy2Mn2 tetrahedra, and edges with six equivalent O(1)Dy2Mn2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy2Mn2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.999
_cell_length_b   6.999
_cell_length_c   6.999
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   242.396
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.125  0.625  0.125  1.0
  Dy  Dy1  1  0.125  0.125  0.625  1.0
  Dy  Dy2  1  0.625  0.125  0.125  1.0
  Dy  Dy3  1  0.125  0.125  0.125  1.0
  Mn  Mn4  1  0.625  0.625  0.625  1.0
  Mn  Mn5  1  0.125  0.625  0.625  1.0
  Mn  Mn6  1  0.625  0.625  0.125  1.0
  Mn  Mn7  1  0.625  0.125  0.625  1.0
  O  O8  1  0.297  0.703  0.703  1.0
  O  O9  1  0.547  0.953  0.953  1.0
  O  O10  1  0.703  0.703  0.297  1.0
  O  O11  1  0.297  0.297  0.703  1.0
  O  O12  1  0.000  0.000  0.000  1.0
  O  O13  1  0.703  0.297  0.703  1.0
  O  O14  1  0.297  0.703  0.297  1.0
  O  O15  1  0.953  0.547  0.953  1.0
  O  O16  1  0.547  0.547  0.953  1.0
  O  O17  1  0.953  0.953  0.547  1.0
  O  O18  1  0.250  0.250  0.250  1.0
  O  O19  1  0.547  0.953  0.547  1.0
  O  O20  1  0.703  0.297  0.297  1.0
  O  O21  1  0.953  0.547  0.547  1.0
[/CIF]
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