The compound described by V2MnO10 crystallizes in the monoclinic Cc space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(9), and two equivalent O(6) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(6), and two equivalent O(9) atoms. Mn(1) is bonded in a distorted octahedral geometry to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(8) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(7) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the seventh O site, O(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(2) atom. In the ninth O site, O(9) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnV2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.978
_cell_length_b   8.395
_cell_length_c   8.395
_cell_angle_alpha   67.669
_cell_angle_beta   72.668
_cell_angle_gamma   72.668
_symmetry_Int_Tables_number   1
_cell_volume   424.594
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.303  0.893  0.365  1.0
  Mn  Mn1  1  0.803  0.365  0.893  1.0
  V  V2  1  0.094  0.524  0.456  1.0
  V  V3  1  0.594  0.456  0.524  1.0
  V  V4  1  0.973  0.327  0.256  1.0
  V  V5  1  0.473  0.256  0.327  1.0
  O  O6  1  0.441  0.048  0.428  1.0
  O  O7  1  0.941  0.428  0.048  1.0
  O  O8  1  0.475  0.017  0.954  1.0
  O  O9  1  0.975  0.954  0.017  1.0
  O  O10  1  0.126  0.733  0.355  1.0
  O  O11  1  0.626  0.355  0.733  1.0
  O  O12  1  0.016  0.898  0.662  1.0
  O  O13  1  0.516  0.662  0.898  1.0
  O  O14  1  0.474  0.669  0.501  1.0
  O  O15  1  0.974  0.501  0.669  1.0
  O  O16  1  0.360  0.394  0.499  1.0
  O  O17  1  0.860  0.499  0.394  1.0
  O  O18  1  0.840  0.884  0.677  1.0
  O  O19  1  0.340  0.677  0.884  1.0
  O  O20  1  0.014  0.094  0.905  1.0
  O  O21  1  0.514  0.905  0.094  1.0
  O  O22  1  0.208  0.387  0.283  1.0
  O  O23  1  0.708  0.283  0.387  1.0
  O  O24  1  0.097  0.115  0.271  1.0
  O  O25  1  0.597  0.271  0.115  1.0
[/CIF]
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The compound described by V2MnO10 crystallizes in the monoclinic Cc space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(9), and two equivalent O(6) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(6), and two equivalent O(9) atoms. Mn(1) is bonded in a distorted octahedral geometry to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(8) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(7) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the seventh O site, O(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(2) atom. In the ninth O site, O(9) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnV2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.978
_cell_length_b   8.395
_cell_length_c   8.395
_cell_angle_alpha   67.669
_cell_angle_beta   72.668
_cell_angle_gamma   72.668
_symmetry_Int_Tables_number   1
_cell_volume   424.594
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.303  0.893  0.365  1.0
  Mn  Mn1  1  0.803  0.365  0.893  1.0
  V  V2  1  0.094  0.524  0.456  1.0
  V  V3  1  0.594  0.456  0.524  1.0
  V  V4  1  0.973  0.327  0.256  1.0
  V  V5  1  0.473  0.256  0.327  1.0
  O  O6  1  0.441  0.048  0.428  1.0
  O  O7  1  0.941  0.428  0.048  1.0
  O  O8  1  0.475  0.017  0.954  1.0
  O  O9  1  0.975  0.954  0.017  1.0
  O  O10  1  0.126  0.733  0.355  1.0
  O  O11  1  0.626  0.355  0.733  1.0
  O  O12  1  0.016  0.898  0.662  1.0
  O  O13  1  0.516  0.662  0.898  1.0
  O  O14  1  0.474  0.669  0.501  1.0
  O  O15  1  0.974  0.501  0.669  1.0
  O  O16  1  0.360  0.394  0.499  1.0
  O  O17  1  0.860  0.499  0.394  1.0
  O  O18  1  0.840  0.884  0.677  1.0
  O  O19  1  0.340  0.677  0.884  1.0
  O  O20  1  0.014  0.094  0.905  1.0
  O  O21  1  0.514  0.905  0.094  1.0
  O  O22  1  0.208  0.387  0.283  1.0
  O  O23  1  0.708  0.283  0.387  1.0
  O  O24  1  0.097  0.115  0.271  1.0
  O  O25  1  0.597  0.271  0.115  1.0
[/CIF]
.