The material structure described by KSbClF3 crystallizes in the orthorhombic Pbca space group. K(1) is bonded in a 8-coordinate geometry to three equivalent Cl(1), one F(1), two equivalent F(2), and two equivalent F(3) atoms. Sb(1) is bonded in a 3-coordinate geometry to two equivalent Cl(1), one F(1), one F(2), and one F(3) atom. Cl(1) is bonded to three equivalent K(1) and two equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing ClK3Sb2 square pyramids. There are three inequivalent F sites. In the first F site, F(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Sb(1) atom. In the second F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Sb(1) atom. In the third F site, F(1) is bonded in a bent 120 degrees geometry to one K(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KSbClF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.033
_cell_length_b   8.259
_cell_length_c   15.099
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1001.674
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.682  0.196  0.057  1.0
  K  K1  1  0.182  0.304  0.943  1.0
  K  K2  1  0.318  0.696  0.443  1.0
  K  K3  1  0.818  0.804  0.557  1.0
  K  K4  1  0.182  0.196  0.443  1.0
  K  K5  1  0.818  0.696  0.057  1.0
  K  K6  1  0.682  0.304  0.557  1.0
  K  K7  1  0.318  0.804  0.943  1.0
  Sb  Sb8  1  0.630  0.005  0.325  1.0
  Sb  Sb9  1  0.130  0.495  0.675  1.0
  Sb  Sb10  1  0.370  0.505  0.175  1.0
  Sb  Sb11  1  0.870  0.995  0.825  1.0
  Sb  Sb12  1  0.370  0.995  0.675  1.0
  Sb  Sb13  1  0.870  0.505  0.325  1.0
  Sb  Sb14  1  0.630  0.495  0.825  1.0
  Sb  Sb15  1  0.130  0.005  0.175  1.0
  Cl  Cl16  1  0.018  0.377  0.151  1.0
  Cl  Cl17  1  0.018  0.123  0.651  1.0
  Cl  Cl18  1  0.482  0.877  0.151  1.0
  Cl  Cl19  1  0.982  0.623  0.849  1.0
  Cl  Cl20  1  0.482  0.623  0.651  1.0
  Cl  Cl21  1  0.982  0.877  0.349  1.0
  Cl  Cl22  1  0.518  0.123  0.849  1.0
  Cl  Cl23  1  0.518  0.377  0.349  1.0
  F  F24  1  0.893  0.271  0.354  1.0
  F  F25  1  0.393  0.229  0.646  1.0
  F  F26  1  0.107  0.771  0.146  1.0
  F  F27  1  0.607  0.729  0.854  1.0
  F  F28  1  0.107  0.729  0.646  1.0
  F  F29  1  0.607  0.771  0.354  1.0
  F  F30  1  0.893  0.229  0.854  1.0
  F  F31  1  0.393  0.271  0.146  1.0
  F  F32  1  0.615  0.505  0.151  1.0
  F  F33  1  0.115  0.995  0.849  1.0
  F  F34  1  0.385  0.005  0.349  1.0
  F  F35  1  0.885  0.495  0.651  1.0
  F  F36  1  0.385  0.495  0.849  1.0
  F  F37  1  0.885  0.005  0.151  1.0
  F  F38  1  0.615  0.995  0.651  1.0
  F  F39  1  0.164  0.039  0.046  1.0
  F  F40  1  0.664  0.039  0.454  1.0
  F  F41  1  0.164  0.461  0.546  1.0
  F  F42  1  0.336  0.539  0.046  1.0
  F  F43  1  0.836  0.961  0.954  1.0
  F  F44  1  0.336  0.961  0.546  1.0
  F  F45  1  0.836  0.539  0.454  1.0
  F  F46  1  0.664  0.461  0.954  1.0
  F  F47  1  0.115  0.505  0.349  1.0
[/CIF]
.
The material structure described by KSbClF3 crystallizes in the orthorhombic Pbca space group. K(1) is bonded in a 8-coordinate geometry to three equivalent Cl(1), one F(1), two equivalent F(2), and two equivalent F(3) atoms. Sb(1) is bonded in a 3-coordinate geometry to two equivalent Cl(1), one F(1), one F(2), and one F(3) atom. Cl(1) is bonded to three equivalent K(1) and two equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing ClK3Sb2 square pyramids. There are three inequivalent F sites. In the first F site, F(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Sb(1) atom. In the second F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Sb(1) atom. In the third F site, F(1) is bonded in a bent 120 degrees geometry to one K(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KSbClF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.033
_cell_length_b   8.259
_cell_length_c   15.099
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1001.674
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.682  0.196  0.057  1.0
  K  K1  1  0.182  0.304  0.943  1.0
  K  K2  1  0.318  0.696  0.443  1.0
  K  K3  1  0.818  0.804  0.557  1.0
  K  K4  1  0.182  0.196  0.443  1.0
  K  K5  1  0.818  0.696  0.057  1.0
  K  K6  1  0.682  0.304  0.557  1.0
  K  K7  1  0.318  0.804  0.943  1.0
  Sb  Sb8  1  0.630  0.005  0.325  1.0
  Sb  Sb9  1  0.130  0.495  0.675  1.0
  Sb  Sb10  1  0.370  0.505  0.175  1.0
  Sb  Sb11  1  0.870  0.995  0.825  1.0
  Sb  Sb12  1  0.370  0.995  0.675  1.0
  Sb  Sb13  1  0.870  0.505  0.325  1.0
  Sb  Sb14  1  0.630  0.495  0.825  1.0
  Sb  Sb15  1  0.130  0.005  0.175  1.0
  Cl  Cl16  1  0.018  0.377  0.151  1.0
  Cl  Cl17  1  0.018  0.123  0.651  1.0
  Cl  Cl18  1  0.482  0.877  0.151  1.0
  Cl  Cl19  1  0.982  0.623  0.849  1.0
  Cl  Cl20  1  0.482  0.623  0.651  1.0
  Cl  Cl21  1  0.982  0.877  0.349  1.0
  Cl  Cl22  1  0.518  0.123  0.849  1.0
  Cl  Cl23  1  0.518  0.377  0.349  1.0
  F  F24  1  0.893  0.271  0.354  1.0
  F  F25  1  0.393  0.229  0.646  1.0
  F  F26  1  0.107  0.771  0.146  1.0
  F  F27  1  0.607  0.729  0.854  1.0
  F  F28  1  0.107  0.729  0.646  1.0
  F  F29  1  0.607  0.771  0.354  1.0
  F  F30  1  0.893  0.229  0.854  1.0
  F  F31  1  0.393  0.271  0.146  1.0
  F  F32  1  0.615  0.505  0.151  1.0
  F  F33  1  0.115  0.995  0.849  1.0
  F  F34  1  0.385  0.005  0.349  1.0
  F  F35  1  0.885  0.495  0.651  1.0
  F  F36  1  0.385  0.495  0.849  1.0
  F  F37  1  0.885  0.005  0.151  1.0
  F  F38  1  0.615  0.995  0.651  1.0
  F  F39  1  0.164  0.039  0.046  1.0
  F  F40  1  0.664  0.039  0.454  1.0
  F  F41  1  0.164  0.461  0.546  1.0
  F  F42  1  0.336  0.539  0.046  1.0
  F  F43  1  0.836  0.961  0.954  1.0
  F  F44  1  0.336  0.961  0.546  1.0
  F  F45  1  0.836  0.539  0.454  1.0
  F  F46  1  0.664  0.461  0.954  1.0
  F  F47  1  0.115  0.505  0.349  1.0
[/CIF]
.