The material structure described by Mo3AgP3O16 crystallizes in the triclinic P-1 space group. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(12), one O(13), one O(8), and one O(9) atom to form distorted MoO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. In the second Mo site, Mo(2) is bonded to one O(14), one O(15), one O(16), one O(6), and one O(7) atom to form MoO5 trigonal bipyramids that share  a cornercorner with one Mo(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. In the third Mo site, Mo(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form distorted MoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and  a cornercorner with one Mo(2)O5 trigonal bipyramid. Ag(1) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(13), one O(15), one O(16), and one O(5) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(13), one O(15), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(3)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, and  a cornercorner with one Mo(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 34-46°. In the second P site, P(2) is bonded to one O(10), one O(11), one O(2), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(3)O6 octahedra and corners with three equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-50°. In the third P site, P(3) is bonded to one O(1), one O(16), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mo(3)O6 octahedra and corners with two equivalent Mo(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 37-40°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(3) and one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mo(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(3) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(3) and one Ag(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one P(3) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one Mo(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(2) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Mo(1), one Ag(1), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Mo(1), one Ag(1), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(2) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(1), and one P(1) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Mo(2), one Ag(1), and one P(3) atom. is represented by the CIF card [CIF]
data_AgMo3P3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.516
_cell_length_b   7.902
_cell_length_c   13.025
_cell_angle_alpha   80.116
_cell_angle_beta   79.567
_cell_angle_gamma   82.606
_symmetry_Int_Tables_number   1
_cell_volume   646.521
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.407  0.624  0.670  1.0
  Ag  Ag1  1  0.593  0.376  0.330  1.0
  Mo  Mo2  1  0.802  0.785  0.458  1.0
  Mo  Mo3  1  0.198  0.215  0.542  1.0
  Mo  Mo4  1  0.939  0.789  0.858  1.0
  Mo  Mo5  1  0.061  0.211  0.142  1.0
  Mo  Mo6  1  0.598  0.233  0.835  1.0
  Mo  Mo7  1  0.402  0.767  0.165  1.0
  P  P8  1  0.935  0.512  0.685  1.0
  P  P9  1  0.065  0.488  0.315  1.0
  P  P10  1  0.694  0.144  0.577  1.0
  P  P11  1  0.306  0.856  0.423  1.0
  P  P12  1  0.424  0.834  0.900  1.0
  P  P13  1  0.576  0.166  0.100  1.0
  O  O14  1  0.424  0.029  0.896  1.0
  O  O15  1  0.576  0.971  0.104  1.0
  O  O16  1  0.637  0.150  0.695  1.0
  O  O17  1  0.363  0.850  0.305  1.0
  O  O18  1  0.837  0.383  0.778  1.0
  O  O19  1  0.163  0.617  0.222  1.0
  O  O20  1  0.628  0.257  0.986  1.0
  O  O21  1  0.372  0.743  0.014  1.0
  O  O22  1  0.398  0.393  0.817  1.0
  O  O23  1  0.602  0.607  0.183  1.0
  O  O24  1  0.640  0.756  0.844  1.0
  O  O25  1  0.360  0.244  0.156  1.0
  O  O26  1  0.866  0.011  0.861  1.0
  O  O27  1  0.134  0.989  0.139  1.0
  O  O28  1  0.190  0.058  0.650  1.0
  O  O29  1  0.810  0.942  0.350  1.0
  O  O30  1  0.892  0.234  0.526  1.0
  O  O31  1  0.108  0.766  0.474  1.0
  O  O32  1  0.516  0.249  0.520  1.0
  O  O33  1  0.484  0.751  0.480  1.0
  O  O34  1  0.280  0.048  0.435  1.0
  O  O35  1  0.720  0.952  0.565  1.0
  O  O36  1  0.137  0.425  0.623  1.0
  O  O37  1  0.863  0.575  0.377  1.0
  O  O38  1  0.220  0.405  0.390  1.0
  O  O39  1  0.780  0.595  0.610  1.0
  O  O40  1  0.084  0.308  0.014  1.0
  O  O41  1  0.916  0.692  0.986  1.0
  O  O42  1  0.985  0.345  0.265  1.0
  O  O43  1  0.015  0.655  0.735  1.0
  O  O44  1  0.745  0.203  0.163  1.0
  O  O45  1  0.255  0.797  0.837  1.0
[/CIF]
.
The material structure described by Mo3AgP3O16 crystallizes in the triclinic P-1 space group. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(12), one O(13), one O(8), and one O(9) atom to form distorted MoO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. In the second Mo site, Mo(2) is bonded to one O(14), one O(15), one O(16), one O(6), and one O(7) atom to form MoO5 trigonal bipyramids that share  a cornercorner with one Mo(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. In the third Mo site, Mo(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form distorted MoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and  a cornercorner with one Mo(2)O5 trigonal bipyramid. Ag(1) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(13), one O(15), one O(16), and one O(5) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(13), one O(15), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(3)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, and  a cornercorner with one Mo(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 34-46°. In the second P site, P(2) is bonded to one O(10), one O(11), one O(2), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(3)O6 octahedra and corners with three equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-50°. In the third P site, P(3) is bonded to one O(1), one O(16), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mo(3)O6 octahedra and corners with two equivalent Mo(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 37-40°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(3) and one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mo(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(3) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(3) and one Ag(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one P(3) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one Mo(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(2) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Mo(1), one Ag(1), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Mo(1), one Ag(1), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(2) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(1), and one P(1) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Mo(2), one Ag(1), and one P(3) atom. is represented by the CIF card [CIF]
data_AgMo3P3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.516
_cell_length_b   7.902
_cell_length_c   13.025
_cell_angle_alpha   80.116
_cell_angle_beta   79.567
_cell_angle_gamma   82.606
_symmetry_Int_Tables_number   1
_cell_volume   646.521
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.407  0.624  0.670  1.0
  Ag  Ag1  1  0.593  0.376  0.330  1.0
  Mo  Mo2  1  0.802  0.785  0.458  1.0
  Mo  Mo3  1  0.198  0.215  0.542  1.0
  Mo  Mo4  1  0.939  0.789  0.858  1.0
  Mo  Mo5  1  0.061  0.211  0.142  1.0
  Mo  Mo6  1  0.598  0.233  0.835  1.0
  Mo  Mo7  1  0.402  0.767  0.165  1.0
  P  P8  1  0.935  0.512  0.685  1.0
  P  P9  1  0.065  0.488  0.315  1.0
  P  P10  1  0.694  0.144  0.577  1.0
  P  P11  1  0.306  0.856  0.423  1.0
  P  P12  1  0.424  0.834  0.900  1.0
  P  P13  1  0.576  0.166  0.100  1.0
  O  O14  1  0.424  0.029  0.896  1.0
  O  O15  1  0.576  0.971  0.104  1.0
  O  O16  1  0.637  0.150  0.695  1.0
  O  O17  1  0.363  0.850  0.305  1.0
  O  O18  1  0.837  0.383  0.778  1.0
  O  O19  1  0.163  0.617  0.222  1.0
  O  O20  1  0.628  0.257  0.986  1.0
  O  O21  1  0.372  0.743  0.014  1.0
  O  O22  1  0.398  0.393  0.817  1.0
  O  O23  1  0.602  0.607  0.183  1.0
  O  O24  1  0.640  0.756  0.844  1.0
  O  O25  1  0.360  0.244  0.156  1.0
  O  O26  1  0.866  0.011  0.861  1.0
  O  O27  1  0.134  0.989  0.139  1.0
  O  O28  1  0.190  0.058  0.650  1.0
  O  O29  1  0.810  0.942  0.350  1.0
  O  O30  1  0.892  0.234  0.526  1.0
  O  O31  1  0.108  0.766  0.474  1.0
  O  O32  1  0.516  0.249  0.520  1.0
  O  O33  1  0.484  0.751  0.480  1.0
  O  O34  1  0.280  0.048  0.435  1.0
  O  O35  1  0.720  0.952  0.565  1.0
  O  O36  1  0.137  0.425  0.623  1.0
  O  O37  1  0.863  0.575  0.377  1.0
  O  O38  1  0.220  0.405  0.390  1.0
  O  O39  1  0.780  0.595  0.610  1.0
  O  O40  1  0.084  0.308  0.014  1.0
  O  O41  1  0.916  0.692  0.986  1.0
  O  O42  1  0.985  0.345  0.265  1.0
  O  O43  1  0.015  0.655  0.735  1.0
  O  O44  1  0.745  0.203  0.163  1.0
  O  O45  1  0.255  0.797  0.837  1.0
[/CIF]
.