The crystal structure described by (FeO2)12Cl2 is Hydrophilite-derived structured and crystallizes in the tetragonal I4/m space group. The structure consists of two 7782-50-5 molecules inside a FeO2 framework. In the FeO2 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of corner and edge-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. In the second Fe site, Fe(2) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of corner and edge-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal planar geometry to one Fe(1) and two equivalent Fe(2) atoms. In the second O site, O(4) is bonded in a distorted trigonal planar geometry to one Fe(1) and two equivalent Fe(2) atoms. In the third O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Fe(1) and two equivalent Fe(2) atoms. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Fe(1) and two equivalent Fe(2) atoms. is represented by the CIF file [CIF]
data_Fe6ClO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.566
_cell_length_b   8.566
_cell_length_c   8.566
_cell_angle_alpha   105.217
_cell_angle_beta   105.217
_cell_angle_gamma   118.363
_symmetry_Int_Tables_number   1
_cell_volume   475.014
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.168  0.353  0.521  1.0
  Fe  Fe1  1  0.833  0.018  0.516  1.0
  Fe  Fe2  1  0.498  0.683  0.516  1.0
  Fe  Fe3  1  0.167  0.982  0.484  1.0
  Fe  Fe4  1  0.832  0.647  0.479  1.0
  Fe  Fe5  1  0.502  0.317  0.484  1.0
  Fe  Fe6  1  0.353  0.832  0.184  1.0
  Fe  Fe7  1  0.683  0.167  0.185  1.0
  Fe  Fe8  1  0.018  0.502  0.185  1.0
  Fe  Fe9  1  0.647  0.168  0.816  1.0
  Fe  Fe10  1  0.982  0.498  0.815  1.0
  Fe  Fe11  1  0.317  0.833  0.815  1.0
  Cl  Cl12  1  0.888  0.888  0.000  1.0
  Cl  Cl13  1  0.112  0.112  0.000  1.0
  O  O14  1  0.483  0.117  0.936  1.0
  O  O15  1  0.154  0.782  0.936  1.0
  O  O16  1  0.818  0.453  0.936  1.0
  O  O17  1  0.846  0.218  0.064  1.0
  O  O18  1  0.517  0.883  0.064  1.0
  O  O19  1  0.182  0.547  0.064  1.0
  O  O20  1  0.497  0.880  0.707  1.0
  O  O21  1  0.166  0.545  0.710  1.0
  O  O22  1  0.827  0.211  0.707  1.0
  O  O23  1  0.834  0.455  0.290  1.0
  O  O24  1  0.503  0.120  0.293  1.0
  O  O25  1  0.173  0.789  0.293  1.0
  O  O26  1  0.883  0.818  0.365  1.0
  O  O27  1  0.547  0.483  0.365  1.0
  O  O28  1  0.218  0.154  0.372  1.0
  O  O29  1  0.453  0.517  0.635  1.0
  O  O30  1  0.117  0.182  0.635  1.0
  O  O31  1  0.782  0.846  0.628  1.0
  O  O32  1  0.120  0.827  0.617  1.0
  O  O33  1  0.789  0.497  0.617  1.0
  O  O34  1  0.455  0.166  0.621  1.0
  O  O35  1  0.211  0.503  0.383  1.0
  O  O36  1  0.880  0.173  0.383  1.0
  O  O37  1  0.545  0.834  0.379  1.0
[/CIF]
.
The crystal structure described by (FeO2)12Cl2 is Hydrophilite-derived structured and crystallizes in the tetragonal I4/m space group. The structure consists of two 7782-50-5 molecules inside a FeO2 framework. In the FeO2 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of corner and edge-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. In the second Fe site, Fe(2) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of corner and edge-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal planar geometry to one Fe(1) and two equivalent Fe(2) atoms. In the second O site, O(4) is bonded in a distorted trigonal planar geometry to one Fe(1) and two equivalent Fe(2) atoms. In the third O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Fe(1) and two equivalent Fe(2) atoms. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Fe(1) and two equivalent Fe(2) atoms. is represented by the CIF file [CIF]
data_Fe6ClO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.566
_cell_length_b   8.566
_cell_length_c   8.566
_cell_angle_alpha   105.217
_cell_angle_beta   105.217
_cell_angle_gamma   118.363
_symmetry_Int_Tables_number   1
_cell_volume   475.014
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.168  0.353  0.521  1.0
  Fe  Fe1  1  0.833  0.018  0.516  1.0
  Fe  Fe2  1  0.498  0.683  0.516  1.0
  Fe  Fe3  1  0.167  0.982  0.484  1.0
  Fe  Fe4  1  0.832  0.647  0.479  1.0
  Fe  Fe5  1  0.502  0.317  0.484  1.0
  Fe  Fe6  1  0.353  0.832  0.184  1.0
  Fe  Fe7  1  0.683  0.167  0.185  1.0
  Fe  Fe8  1  0.018  0.502  0.185  1.0
  Fe  Fe9  1  0.647  0.168  0.816  1.0
  Fe  Fe10  1  0.982  0.498  0.815  1.0
  Fe  Fe11  1  0.317  0.833  0.815  1.0
  Cl  Cl12  1  0.888  0.888  0.000  1.0
  Cl  Cl13  1  0.112  0.112  0.000  1.0
  O  O14  1  0.483  0.117  0.936  1.0
  O  O15  1  0.154  0.782  0.936  1.0
  O  O16  1  0.818  0.453  0.936  1.0
  O  O17  1  0.846  0.218  0.064  1.0
  O  O18  1  0.517  0.883  0.064  1.0
  O  O19  1  0.182  0.547  0.064  1.0
  O  O20  1  0.497  0.880  0.707  1.0
  O  O21  1  0.166  0.545  0.710  1.0
  O  O22  1  0.827  0.211  0.707  1.0
  O  O23  1  0.834  0.455  0.290  1.0
  O  O24  1  0.503  0.120  0.293  1.0
  O  O25  1  0.173  0.789  0.293  1.0
  O  O26  1  0.883  0.818  0.365  1.0
  O  O27  1  0.547  0.483  0.365  1.0
  O  O28  1  0.218  0.154  0.372  1.0
  O  O29  1  0.453  0.517  0.635  1.0
  O  O30  1  0.117  0.182  0.635  1.0
  O  O31  1  0.782  0.846  0.628  1.0
  O  O32  1  0.120  0.827  0.617  1.0
  O  O33  1  0.789  0.497  0.617  1.0
  O  O34  1  0.455  0.166  0.621  1.0
  O  O35  1  0.211  0.503  0.383  1.0
  O  O36  1  0.880  0.173  0.383  1.0
  O  O37  1  0.545  0.834  0.379  1.0
[/CIF]
.