The structure described by Ba3Lu2Zn5O11 crystallizes in the cubic F-43m space group. Ba(1) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. Lu(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form LuO6 octahedra that share corners with three equivalent Zn(1)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra, and edges with three equivalent Lu(1)O6 octahedra. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with two equivalent Lu(1)O6 octahedra, corners with two equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 54°. In the second Zn site, Zn(2) is bonded to one O(4) and three equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with three equivalent Lu(1)O6 octahedra, corners with three equivalent Zn(1)O4 tetrahedra, and corners with three equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 54°. There are five inequivalent O sites. In the first O site, O(5) is bonded to six equivalent Ba(1) atoms to form corner-sharing OBa6 octahedra. In the second O site, O(1) is bonded to two equivalent Ba(1), one Lu(1), one Zn(1), and one Zn(2) atom to form distorted OBa2LuZn2 trigonal bipyramids that share corners with two equivalent O(5)Ba6 octahedra,  a cornercorner with one O(4)Zn4 tetrahedra, corners with three equivalent O(1)Ba2LuZn2 trigonal bipyramids, and edges with four equivalent O(1)Ba2LuZn2 trigonal bipyramids. The corner-sharing octahedral tilt angles are 52°. In the third O site, O(2) is bonded in a 3-coordinate geometry to three equivalent Ba(1) and three equivalent Lu(1) atoms. In the fourth O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ba(1) and three equivalent Zn(1) atoms. In the fifth O site, O(4) is bonded to four equivalent Zn(2) atoms to form corner-sharing OZn4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba3Lu2Zn5O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.629
_cell_length_b   9.629
_cell_length_c   9.629
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   631.356
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.544  0.544  0.956  1.0
  Ba  Ba1  1  0.956  0.544  0.956  1.0
  Ba  Ba2  1  0.544  0.956  0.544  1.0
  Ba  Ba3  1  0.956  0.956  0.544  1.0
  Ba  Ba4  1  0.544  0.956  0.956  1.0
  Ba  Ba5  1  0.956  0.544  0.544  1.0
  Lu  Lu6  1  0.743  0.086  0.086  1.0
  Lu  Lu7  1  0.086  0.743  0.086  1.0
  Lu  Lu8  1  0.086  0.086  0.086  1.0
  Lu  Lu9  1  0.086  0.086  0.743  1.0
  Zn  Zn10  1  0.668  0.332  0.668  1.0
  Zn  Zn11  1  0.999  0.334  0.334  1.0
  Zn  Zn12  1  0.668  0.668  0.332  1.0
  Zn  Zn13  1  0.334  0.334  0.999  1.0
  Zn  Zn14  1  0.332  0.668  0.668  1.0
  Zn  Zn15  1  0.334  0.334  0.334  1.0
  Zn  Zn16  1  0.332  0.332  0.668  1.0
  Zn  Zn17  1  0.334  0.999  0.334  1.0
  Zn  Zn18  1  0.332  0.668  0.332  1.0
  Zn  Zn19  1  0.668  0.332  0.332  1.0
  O  O20  1  0.584  0.248  0.248  1.0
  O  O21  1  0.584  0.248  0.920  1.0
  O  O22  1  0.237  0.921  0.921  1.0
  O  O23  1  0.224  0.592  0.592  1.0
  O  O24  1  0.920  0.248  0.584  1.0
  O  O25  1  0.584  0.920  0.248  1.0
  O  O26  1  0.592  0.592  0.224  1.0
  O  O27  1  0.248  0.248  0.584  1.0
  O  O28  1  0.248  0.584  0.248  1.0
  O  O29  1  0.248  0.920  0.248  1.0
  O  O30  1  0.592  0.224  0.592  1.0
  O  O31  1  0.250  0.250  0.250  1.0
  O  O32  1  0.921  0.921  0.921  1.0
  O  O33  1  0.248  0.248  0.920  1.0
  O  O34  1  0.921  0.921  0.237  1.0
  O  O35  1  0.921  0.237  0.921  1.0
  O  O36  1  0.920  0.584  0.248  1.0
  O  O37  1  0.248  0.584  0.920  1.0
  O  O38  1  0.592  0.592  0.592  1.0
  O  O39  1  0.248  0.920  0.584  1.0
  O  O40  1  0.750  0.750  0.750  1.0
  O  O41  1  0.920  0.248  0.248  1.0
[/CIF]
.
The structure described by Ba3Lu2Zn5O11 crystallizes in the cubic F-43m space group. Ba(1) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. Lu(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form LuO6 octahedra that share corners with three equivalent Zn(1)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra, and edges with three equivalent Lu(1)O6 octahedra. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with two equivalent Lu(1)O6 octahedra, corners with two equivalent Zn(2)O4 tetrahedra, and corners with four equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 54°. In the second Zn site, Zn(2) is bonded to one O(4) and three equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with three equivalent Lu(1)O6 octahedra, corners with three equivalent Zn(1)O4 tetrahedra, and corners with three equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 54°. There are five inequivalent O sites. In the first O site, O(5) is bonded to six equivalent Ba(1) atoms to form corner-sharing OBa6 octahedra. In the second O site, O(1) is bonded to two equivalent Ba(1), one Lu(1), one Zn(1), and one Zn(2) atom to form distorted OBa2LuZn2 trigonal bipyramids that share corners with two equivalent O(5)Ba6 octahedra,  a cornercorner with one O(4)Zn4 tetrahedra, corners with three equivalent O(1)Ba2LuZn2 trigonal bipyramids, and edges with four equivalent O(1)Ba2LuZn2 trigonal bipyramids. The corner-sharing octahedral tilt angles are 52°. In the third O site, O(2) is bonded in a 3-coordinate geometry to three equivalent Ba(1) and three equivalent Lu(1) atoms. In the fourth O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ba(1) and three equivalent Zn(1) atoms. In the fifth O site, O(4) is bonded to four equivalent Zn(2) atoms to form corner-sharing OZn4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba3Lu2Zn5O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.629
_cell_length_b   9.629
_cell_length_c   9.629
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   631.356
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.544  0.544  0.956  1.0
  Ba  Ba1  1  0.956  0.544  0.956  1.0
  Ba  Ba2  1  0.544  0.956  0.544  1.0
  Ba  Ba3  1  0.956  0.956  0.544  1.0
  Ba  Ba4  1  0.544  0.956  0.956  1.0
  Ba  Ba5  1  0.956  0.544  0.544  1.0
  Lu  Lu6  1  0.743  0.086  0.086  1.0
  Lu  Lu7  1  0.086  0.743  0.086  1.0
  Lu  Lu8  1  0.086  0.086  0.086  1.0
  Lu  Lu9  1  0.086  0.086  0.743  1.0
  Zn  Zn10  1  0.668  0.332  0.668  1.0
  Zn  Zn11  1  0.999  0.334  0.334  1.0
  Zn  Zn12  1  0.668  0.668  0.332  1.0
  Zn  Zn13  1  0.334  0.334  0.999  1.0
  Zn  Zn14  1  0.332  0.668  0.668  1.0
  Zn  Zn15  1  0.334  0.334  0.334  1.0
  Zn  Zn16  1  0.332  0.332  0.668  1.0
  Zn  Zn17  1  0.334  0.999  0.334  1.0
  Zn  Zn18  1  0.332  0.668  0.332  1.0
  Zn  Zn19  1  0.668  0.332  0.332  1.0
  O  O20  1  0.584  0.248  0.248  1.0
  O  O21  1  0.584  0.248  0.920  1.0
  O  O22  1  0.237  0.921  0.921  1.0
  O  O23  1  0.224  0.592  0.592  1.0
  O  O24  1  0.920  0.248  0.584  1.0
  O  O25  1  0.584  0.920  0.248  1.0
  O  O26  1  0.592  0.592  0.224  1.0
  O  O27  1  0.248  0.248  0.584  1.0
  O  O28  1  0.248  0.584  0.248  1.0
  O  O29  1  0.248  0.920  0.248  1.0
  O  O30  1  0.592  0.224  0.592  1.0
  O  O31  1  0.250  0.250  0.250  1.0
  O  O32  1  0.921  0.921  0.921  1.0
  O  O33  1  0.248  0.248  0.920  1.0
  O  O34  1  0.921  0.921  0.237  1.0
  O  O35  1  0.921  0.237  0.921  1.0
  O  O36  1  0.920  0.584  0.248  1.0
  O  O37  1  0.248  0.584  0.920  1.0
  O  O38  1  0.592  0.592  0.592  1.0
  O  O39  1  0.248  0.920  0.584  1.0
  O  O40  1  0.750  0.750  0.750  1.0
  O  O41  1  0.920  0.248  0.248  1.0
[/CIF]
.