The material described by Na2RuN5H5O12 crystallizes in the monoclinic C2/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(7) atoms. In the second Na site, Na(2) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form distorted NaO6 octahedra that share corners with two equivalent Ru(1)N5O octahedra and  an edgeedge with one Na(2)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. Ru(1) is bonded to one N(1), two equivalent N(2), two equivalent N(3), and one O(1) atom to form RuN5O octahedra that share corners with two equivalent Na(2)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one O(3), and one O(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ru(1), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a trigonal non-coplanar geometry to one Na(1), one Na(2), and one N(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(7) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Na(1) and one N(2) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Na(2), one Ru(1), and one H(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF card [CIF]
data_Na2H5RuN5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.875
_cell_length_b   9.875
_cell_length_c   7.523
_cell_angle_alpha   69.586
_cell_angle_beta   69.586
_cell_angle_gamma   97.110
_symmetry_Int_Tables_number   1
_cell_volume   618.704
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.500  0.500  1.0
  Na  Na1  1  0.500  0.000  0.500  1.0
  Na  Na2  1  0.891  0.109  0.500  1.0
  Na  Na3  1  0.109  0.891  0.500  1.0
  H  H4  1  0.044  0.044  0.143  1.0
  H  H5  1  0.956  0.956  0.857  1.0
  H  H6  1  0.797  0.217  0.813  1.0
  H  H7  1  0.217  0.797  0.813  1.0
  H  H8  1  0.203  0.783  0.187  1.0
  H  H9  1  0.783  0.203  0.187  1.0
  H  H10  1  0.678  0.243  0.726  1.0
  H  H11  1  0.243  0.678  0.726  1.0
  H  H12  1  0.322  0.757  0.274  1.0
  H  H13  1  0.757  0.322  0.274  1.0
  Ru  Ru14  1  0.263  0.263  0.997  1.0
  Ru  Ru15  1  0.737  0.737  0.003  1.0
  N  N16  1  0.420  0.420  0.811  1.0
  N  N17  1  0.580  0.580  0.189  1.0
  N  N18  1  0.130  0.332  0.829  1.0
  N  N19  1  0.332  0.130  0.829  1.0
  N  N20  1  0.870  0.668  0.171  1.0
  N  N21  1  0.668  0.870  0.171  1.0
  N  N22  1  0.181  0.387  0.173  1.0
  N  N23  1  0.387  0.181  0.173  1.0
  N  N24  1  0.819  0.613  0.827  1.0
  N  N25  1  0.613  0.819  0.827  1.0
  O  O26  1  0.089  0.089  0.214  1.0
  O  O27  1  0.911  0.911  0.786  1.0
  O  O28  1  0.523  0.523  0.689  1.0
  O  O29  1  0.477  0.477  0.311  1.0
  O  O30  1  0.018  0.238  0.860  1.0
  O  O31  1  0.238  0.018  0.860  1.0
  O  O32  1  0.982  0.762  0.140  1.0
  O  O33  1  0.762  0.982  0.140  1.0
  O  O34  1  0.168  0.465  0.697  1.0
  O  O35  1  0.465  0.168  0.697  1.0
  O  O36  1  0.832  0.535  0.303  1.0
  O  O37  1  0.535  0.832  0.303  1.0
  O  O38  1  0.100  0.322  0.366  1.0
  O  O39  1  0.322  0.100  0.366  1.0
  O  O40  1  0.900  0.678  0.634  1.0
  O  O41  1  0.678  0.900  0.634  1.0
  O  O42  1  0.215  0.527  0.081  1.0
  O  O43  1  0.527  0.215  0.081  1.0
  O  O44  1  0.785  0.473  0.919  1.0
  O  O45  1  0.473  0.785  0.919  1.0
  O  O46  1  0.785  0.248  0.683  1.0
  O  O47  1  0.248  0.785  0.683  1.0
  O  O48  1  0.215  0.752  0.317  1.0
  O  O49  1  0.752  0.215  0.317  1.0
[/CIF]
.
The material described by Na2RuN5H5O12 crystallizes in the monoclinic C2/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(7) atoms. In the second Na site, Na(2) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form distorted NaO6 octahedra that share corners with two equivalent Ru(1)N5O octahedra and  an edgeedge with one Na(2)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. Ru(1) is bonded to one N(1), two equivalent N(2), two equivalent N(3), and one O(1) atom to form RuN5O octahedra that share corners with two equivalent Na(2)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one O(3), and one O(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ru(1), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a trigonal non-coplanar geometry to one Na(1), one Na(2), and one N(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(7) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Na(1) and one N(2) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Na(2), one Ru(1), and one H(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF card [CIF]
data_Na2H5RuN5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.875
_cell_length_b   9.875
_cell_length_c   7.523
_cell_angle_alpha   69.586
_cell_angle_beta   69.586
_cell_angle_gamma   97.110
_symmetry_Int_Tables_number   1
_cell_volume   618.704
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.500  0.500  1.0
  Na  Na1  1  0.500  0.000  0.500  1.0
  Na  Na2  1  0.891  0.109  0.500  1.0
  Na  Na3  1  0.109  0.891  0.500  1.0
  H  H4  1  0.044  0.044  0.143  1.0
  H  H5  1  0.956  0.956  0.857  1.0
  H  H6  1  0.797  0.217  0.813  1.0
  H  H7  1  0.217  0.797  0.813  1.0
  H  H8  1  0.203  0.783  0.187  1.0
  H  H9  1  0.783  0.203  0.187  1.0
  H  H10  1  0.678  0.243  0.726  1.0
  H  H11  1  0.243  0.678  0.726  1.0
  H  H12  1  0.322  0.757  0.274  1.0
  H  H13  1  0.757  0.322  0.274  1.0
  Ru  Ru14  1  0.263  0.263  0.997  1.0
  Ru  Ru15  1  0.737  0.737  0.003  1.0
  N  N16  1  0.420  0.420  0.811  1.0
  N  N17  1  0.580  0.580  0.189  1.0
  N  N18  1  0.130  0.332  0.829  1.0
  N  N19  1  0.332  0.130  0.829  1.0
  N  N20  1  0.870  0.668  0.171  1.0
  N  N21  1  0.668  0.870  0.171  1.0
  N  N22  1  0.181  0.387  0.173  1.0
  N  N23  1  0.387  0.181  0.173  1.0
  N  N24  1  0.819  0.613  0.827  1.0
  N  N25  1  0.613  0.819  0.827  1.0
  O  O26  1  0.089  0.089  0.214  1.0
  O  O27  1  0.911  0.911  0.786  1.0
  O  O28  1  0.523  0.523  0.689  1.0
  O  O29  1  0.477  0.477  0.311  1.0
  O  O30  1  0.018  0.238  0.860  1.0
  O  O31  1  0.238  0.018  0.860  1.0
  O  O32  1  0.982  0.762  0.140  1.0
  O  O33  1  0.762  0.982  0.140  1.0
  O  O34  1  0.168  0.465  0.697  1.0
  O  O35  1  0.465  0.168  0.697  1.0
  O  O36  1  0.832  0.535  0.303  1.0
  O  O37  1  0.535  0.832  0.303  1.0
  O  O38  1  0.100  0.322  0.366  1.0
  O  O39  1  0.322  0.100  0.366  1.0
  O  O40  1  0.900  0.678  0.634  1.0
  O  O41  1  0.678  0.900  0.634  1.0
  O  O42  1  0.215  0.527  0.081  1.0
  O  O43  1  0.527  0.215  0.081  1.0
  O  O44  1  0.785  0.473  0.919  1.0
  O  O45  1  0.473  0.785  0.919  1.0
  O  O46  1  0.785  0.248  0.683  1.0
  O  O47  1  0.248  0.785  0.683  1.0
  O  O48  1  0.215  0.752  0.317  1.0
  O  O49  1  0.752  0.215  0.317  1.0
[/CIF]
.