The material structure described by Mn2TeSO8 crystallizes in the orthorhombic Pbcm space group. Mn(1) is bonded to one O(1), one O(2), one O(4), one O(6), and two equivalent O(5) atoms to form distorted MnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent S(1)O4 tetrahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 46°. Te(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(5) atoms. S(1) is bonded to one O(1), one O(3), and two equivalent O(6) atoms to form SO4 tetrahedra that share corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. There are six inequivalent O sites. In the first O site, O(5) is bonded in a trigonal planar geometry to two equivalent Mn(1) and one Te(1) atom. In the second O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a trigonal planar geometry to two equivalent Mn(1) and one Te(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_Mn2TeSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.390
_cell_length_b   8.604
_cell_length_c   9.927
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   631.241
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.319  0.050  0.087  1.0
  Mn  Mn1  1  0.681  0.550  0.913  1.0
  Mn  Mn2  1  0.319  0.950  0.413  1.0
  Mn  Mn3  1  0.681  0.450  0.587  1.0
  Mn  Mn4  1  0.681  0.950  0.913  1.0
  Mn  Mn5  1  0.319  0.450  0.087  1.0
  Mn  Mn6  1  0.681  0.050  0.587  1.0
  Mn  Mn7  1  0.319  0.550  0.413  1.0
  Te  Te8  1  0.648  0.250  0.281  1.0
  Te  Te9  1  0.352  0.750  0.719  1.0
  Te  Te10  1  0.648  0.750  0.219  1.0
  Te  Te11  1  0.352  0.250  0.781  1.0
  S  S12  1  0.946  0.250  0.969  1.0
  S  S13  1  0.054  0.750  0.031  1.0
  S  S14  1  0.946  0.750  0.531  1.0
  S  S15  1  0.054  0.250  0.469  1.0
  O  O16  1  0.126  0.250  0.042  1.0
  O  O17  1  0.874  0.750  0.958  1.0
  O  O18  1  0.126  0.750  0.458  1.0
  O  O19  1  0.874  0.250  0.542  1.0
  O  O20  1  0.443  0.250  0.163  1.0
  O  O21  1  0.557  0.750  0.837  1.0
  O  O22  1  0.443  0.750  0.337  1.0
  O  O23  1  0.557  0.250  0.663  1.0
  O  O24  1  0.981  0.250  0.826  1.0
  O  O25  1  0.019  0.750  0.174  1.0
  O  O26  1  0.981  0.750  0.674  1.0
  O  O27  1  0.019  0.250  0.326  1.0
  O  O28  1  0.223  0.000  0.250  1.0
  O  O29  1  0.777  0.500  0.750  1.0
  O  O30  1  0.777  0.000  0.750  1.0
  O  O31  1  0.223  0.500  0.250  1.0
  O  O32  1  0.568  0.085  0.398  1.0
  O  O33  1  0.432  0.585  0.602  1.0
  O  O34  1  0.568  0.915  0.102  1.0
  O  O35  1  0.432  0.415  0.898  1.0
  O  O36  1  0.432  0.915  0.602  1.0
  O  O37  1  0.568  0.415  0.398  1.0
  O  O38  1  0.432  0.085  0.898  1.0
  O  O39  1  0.568  0.585  0.102  1.0
  O  O40  1  0.158  0.890  0.983  1.0
  O  O41  1  0.842  0.390  0.017  1.0
  O  O42  1  0.158  0.110  0.517  1.0
  O  O43  1  0.842  0.610  0.483  1.0
  O  O44  1  0.842  0.110  0.017  1.0
  O  O45  1  0.158  0.610  0.983  1.0
  O  O46  1  0.842  0.890  0.483  1.0
  O  O47  1  0.158  0.390  0.517  1.0
[/CIF]
.
The material structure described by Mn2TeSO8 crystallizes in the orthorhombic Pbcm space group. Mn(1) is bonded to one O(1), one O(2), one O(4), one O(6), and two equivalent O(5) atoms to form distorted MnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent S(1)O4 tetrahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 46°. Te(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(5) atoms. S(1) is bonded to one O(1), one O(3), and two equivalent O(6) atoms to form SO4 tetrahedra that share corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. There are six inequivalent O sites. In the first O site, O(5) is bonded in a trigonal planar geometry to two equivalent Mn(1) and one Te(1) atom. In the second O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a trigonal planar geometry to two equivalent Mn(1) and one Te(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_Mn2TeSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.390
_cell_length_b   8.604
_cell_length_c   9.927
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   631.241
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.319  0.050  0.087  1.0
  Mn  Mn1  1  0.681  0.550  0.913  1.0
  Mn  Mn2  1  0.319  0.950  0.413  1.0
  Mn  Mn3  1  0.681  0.450  0.587  1.0
  Mn  Mn4  1  0.681  0.950  0.913  1.0
  Mn  Mn5  1  0.319  0.450  0.087  1.0
  Mn  Mn6  1  0.681  0.050  0.587  1.0
  Mn  Mn7  1  0.319  0.550  0.413  1.0
  Te  Te8  1  0.648  0.250  0.281  1.0
  Te  Te9  1  0.352  0.750  0.719  1.0
  Te  Te10  1  0.648  0.750  0.219  1.0
  Te  Te11  1  0.352  0.250  0.781  1.0
  S  S12  1  0.946  0.250  0.969  1.0
  S  S13  1  0.054  0.750  0.031  1.0
  S  S14  1  0.946  0.750  0.531  1.0
  S  S15  1  0.054  0.250  0.469  1.0
  O  O16  1  0.126  0.250  0.042  1.0
  O  O17  1  0.874  0.750  0.958  1.0
  O  O18  1  0.126  0.750  0.458  1.0
  O  O19  1  0.874  0.250  0.542  1.0
  O  O20  1  0.443  0.250  0.163  1.0
  O  O21  1  0.557  0.750  0.837  1.0
  O  O22  1  0.443  0.750  0.337  1.0
  O  O23  1  0.557  0.250  0.663  1.0
  O  O24  1  0.981  0.250  0.826  1.0
  O  O25  1  0.019  0.750  0.174  1.0
  O  O26  1  0.981  0.750  0.674  1.0
  O  O27  1  0.019  0.250  0.326  1.0
  O  O28  1  0.223  0.000  0.250  1.0
  O  O29  1  0.777  0.500  0.750  1.0
  O  O30  1  0.777  0.000  0.750  1.0
  O  O31  1  0.223  0.500  0.250  1.0
  O  O32  1  0.568  0.085  0.398  1.0
  O  O33  1  0.432  0.585  0.602  1.0
  O  O34  1  0.568  0.915  0.102  1.0
  O  O35  1  0.432  0.415  0.898  1.0
  O  O36  1  0.432  0.915  0.602  1.0
  O  O37  1  0.568  0.415  0.398  1.0
  O  O38  1  0.432  0.085  0.898  1.0
  O  O39  1  0.568  0.585  0.102  1.0
  O  O40  1  0.158  0.890  0.983  1.0
  O  O41  1  0.842  0.390  0.017  1.0
  O  O42  1  0.158  0.110  0.517  1.0
  O  O43  1  0.842  0.610  0.483  1.0
  O  O44  1  0.842  0.110  0.017  1.0
  O  O45  1  0.158  0.610  0.983  1.0
  O  O46  1  0.842  0.890  0.483  1.0
  O  O47  1  0.158  0.390  0.517  1.0
[/CIF]
.