The material structure described by RbPuP2S7 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one S(4), one S(5), two equivalent S(2), two equivalent S(6), and two equivalent S(7) atoms. Pu(1) is bonded in a 8-coordinate geometry to one S(2), one S(5), one S(6), one S(7), two equivalent S(1), and two equivalent S(3) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one S(4), and one S(7) atom to form corner-sharing PS4 tetrahedra. In the second P site, P(2) is bonded to one S(3), one S(4), one S(5), and one S(6) atom to form corner-sharing PS4 tetrahedra. There are seven inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Pu(1) and one P(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Pu(1), and one P(1) atom. In the third S site, S(3) is bonded in a distorted T-shaped geometry to two equivalent Pu(1) and one P(2) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Rb(1), one P(1), and one P(2) atom. In the fifth S site, S(5) is bonded in a 3-coordinate geometry to one Rb(1), one Pu(1), and one P(2) atom. In the sixth S site, S(6) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Pu(1), and one P(2) atom. In the seventh S site, S(7) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Pu(1), and one P(1) atom. is represented by the CIF card [CIF]
data_RbPuP2S7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.489
_cell_length_b   9.070
_cell_length_c   9.957
_cell_angle_alpha   89.253
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1127.870
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.196  0.633  0.899  1.0
  Rb  Rb1  1  0.804  0.367  0.101  1.0
  Rb  Rb2  1  0.304  0.133  0.899  1.0
  Rb  Rb3  1  0.696  0.867  0.101  1.0
  Pu  Pu4  1  0.641  0.108  0.638  1.0
  Pu  Pu5  1  0.141  0.392  0.362  1.0
  Pu  Pu6  1  0.359  0.892  0.362  1.0
  Pu  Pu7  1  0.859  0.608  0.638  1.0
  P  P8  1  0.464  0.803  0.684  1.0
  P  P9  1  0.964  0.697  0.316  1.0
  P  P10  1  0.103  0.023  0.234  1.0
  P  P11  1  0.536  0.197  0.316  1.0
  P  P12  1  0.397  0.523  0.234  1.0
  P  P13  1  0.897  0.977  0.766  1.0
  P  P14  1  0.603  0.477  0.766  1.0
  P  P15  1  0.036  0.303  0.684  1.0
  S  S16  1  0.943  0.323  0.518  1.0
  S  S17  1  0.191  0.352  0.647  1.0
  S  S18  1  0.309  0.852  0.647  1.0
  S  S19  1  0.332  0.572  0.414  1.0
  S  S20  1  0.168  0.072  0.414  1.0
  S  S21  1  0.050  0.079  0.747  1.0
  S  S22  1  0.559  0.290  0.859  1.0
  S  S23  1  0.292  0.390  0.142  1.0
  S  S24  1  0.525  0.930  0.829  1.0
  S  S25  1  0.057  0.677  0.482  1.0
  S  S26  1  0.941  0.790  0.859  1.0
  S  S27  1  0.441  0.710  0.141  1.0
  S  S28  1  0.557  0.823  0.518  1.0
  S  S29  1  0.792  0.110  0.858  1.0
  S  S30  1  0.550  0.421  0.253  1.0
  S  S31  1  0.059  0.210  0.141  1.0
  S  S32  1  0.809  0.648  0.353  1.0
  S  S33  1  0.208  0.890  0.142  1.0
  S  S34  1  0.668  0.428  0.586  1.0
  S  S35  1  0.708  0.610  0.858  1.0
  S  S36  1  0.832  0.928  0.586  1.0
  S  S37  1  0.691  0.148  0.353  1.0
  S  S38  1  0.025  0.570  0.171  1.0
  S  S39  1  0.450  0.579  0.747  1.0
  S  S40  1  0.475  0.070  0.171  1.0
  S  S41  1  0.443  0.177  0.482  1.0
  S  S42  1  0.950  0.921  0.253  1.0
  S  S43  1  0.975  0.430  0.829  1.0
[/CIF]
.
The material structure described by RbPuP2S7 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one S(4), one S(5), two equivalent S(2), two equivalent S(6), and two equivalent S(7) atoms. Pu(1) is bonded in a 8-coordinate geometry to one S(2), one S(5), one S(6), one S(7), two equivalent S(1), and two equivalent S(3) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one S(4), and one S(7) atom to form corner-sharing PS4 tetrahedra. In the second P site, P(2) is bonded to one S(3), one S(4), one S(5), and one S(6) atom to form corner-sharing PS4 tetrahedra. There are seven inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Pu(1) and one P(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Pu(1), and one P(1) atom. In the third S site, S(3) is bonded in a distorted T-shaped geometry to two equivalent Pu(1) and one P(2) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Rb(1), one P(1), and one P(2) atom. In the fifth S site, S(5) is bonded in a 3-coordinate geometry to one Rb(1), one Pu(1), and one P(2) atom. In the sixth S site, S(6) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Pu(1), and one P(2) atom. In the seventh S site, S(7) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Pu(1), and one P(1) atom. is represented by the CIF card [CIF]
data_RbPuP2S7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.489
_cell_length_b   9.070
_cell_length_c   9.957
_cell_angle_alpha   89.253
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1127.870
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.196  0.633  0.899  1.0
  Rb  Rb1  1  0.804  0.367  0.101  1.0
  Rb  Rb2  1  0.304  0.133  0.899  1.0
  Rb  Rb3  1  0.696  0.867  0.101  1.0
  Pu  Pu4  1  0.641  0.108  0.638  1.0
  Pu  Pu5  1  0.141  0.392  0.362  1.0
  Pu  Pu6  1  0.359  0.892  0.362  1.0
  Pu  Pu7  1  0.859  0.608  0.638  1.0
  P  P8  1  0.464  0.803  0.684  1.0
  P  P9  1  0.964  0.697  0.316  1.0
  P  P10  1  0.103  0.023  0.234  1.0
  P  P11  1  0.536  0.197  0.316  1.0
  P  P12  1  0.397  0.523  0.234  1.0
  P  P13  1  0.897  0.977  0.766  1.0
  P  P14  1  0.603  0.477  0.766  1.0
  P  P15  1  0.036  0.303  0.684  1.0
  S  S16  1  0.943  0.323  0.518  1.0
  S  S17  1  0.191  0.352  0.647  1.0
  S  S18  1  0.309  0.852  0.647  1.0
  S  S19  1  0.332  0.572  0.414  1.0
  S  S20  1  0.168  0.072  0.414  1.0
  S  S21  1  0.050  0.079  0.747  1.0
  S  S22  1  0.559  0.290  0.859  1.0
  S  S23  1  0.292  0.390  0.142  1.0
  S  S24  1  0.525  0.930  0.829  1.0
  S  S25  1  0.057  0.677  0.482  1.0
  S  S26  1  0.941  0.790  0.859  1.0
  S  S27  1  0.441  0.710  0.141  1.0
  S  S28  1  0.557  0.823  0.518  1.0
  S  S29  1  0.792  0.110  0.858  1.0
  S  S30  1  0.550  0.421  0.253  1.0
  S  S31  1  0.059  0.210  0.141  1.0
  S  S32  1  0.809  0.648  0.353  1.0
  S  S33  1  0.208  0.890  0.142  1.0
  S  S34  1  0.668  0.428  0.586  1.0
  S  S35  1  0.708  0.610  0.858  1.0
  S  S36  1  0.832  0.928  0.586  1.0
  S  S37  1  0.691  0.148  0.353  1.0
  S  S38  1  0.025  0.570  0.171  1.0
  S  S39  1  0.450  0.579  0.747  1.0
  S  S40  1  0.475  0.070  0.171  1.0
  S  S41  1  0.443  0.177  0.482  1.0
  S  S42  1  0.950  0.921  0.253  1.0
  S  S43  1  0.975  0.430  0.829  1.0
[/CIF]
.