The structure described by V3O5F is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(5), two equivalent O(1), two equivalent O(7), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with three equivalent V(2)O5F octahedra, corners with three equivalent V(6)O5F octahedra,  an edgeedge with one V(5)O5F octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(6), two equivalent O(1), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(4)O6 octahedra, corners with three equivalent V(1)O5F octahedra, corners with three equivalent V(5)O5F octahedra,  an edgeedge with one V(3)O4F2 octahedra, and  an edgeedge with one V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 42-54°. In the third V site, V(3) is bonded to one O(5), one O(6), two equivalent O(2), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent V(1)O5F octahedra, corners with three equivalent V(5)O5F octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(2)O5F octahedra, and  an edgeedge with one V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the fourth V site, V(4) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent V(2)O5F octahedra, corners with three equivalent V(3)O4F2 octahedra, corners with three equivalent V(6)O5F octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 42-53°. In the fifth V site, V(5) is bonded to one O(4), two equivalent O(1), two equivalent O(2), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(6)O5F octahedra, corners with three equivalent V(3)O4F2 octahedra, corners with three equivalent V(2)O5F octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-49°. In the sixth V site, V(6) is bonded to one O(3), one O(4), one O(5), two equivalent O(7), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(5)O5F octahedra, corners with three equivalent V(1)O5F octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(3)O4F2 octahedra, and  an edgeedge with one V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 42-54°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(2), one V(5), and one V(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3O5F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.521
_cell_length_b   5.521
_cell_length_c   7.330
_cell_angle_alpha   70.123
_cell_angle_beta   70.123
_cell_angle_gamma   71.837
_symmetry_Int_Tables_number   1
_cell_volume   192.663
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.674  0.674  0.847  1.0
  V  V1  1  0.319  0.319  0.671  1.0
  V  V2  1  0.656  0.656  0.318  1.0
  V  V3  1  0.338  0.338  0.160  1.0
  V  V4  1  1.000  1.000  0.515  1.0
  V  V5  1  0.012  0.012  0.987  1.0
  O  O6  1  0.638  0.040  0.659  1.0
  O  O7  1  0.961  0.369  0.334  1.0
  O  O8  1  0.238  0.238  0.965  1.0
  O  O9  1  0.097  0.097  0.697  1.0
  O  O10  1  0.772  0.772  0.038  1.0
  O  O11  1  0.433  0.433  0.369  1.0
  O  O12  1  0.697  0.294  0.007  1.0
  O  O13  1  0.040  0.638  0.659  1.0
  O  O14  1  0.369  0.961  0.334  1.0
  O  O15  1  0.294  0.697  0.007  1.0
  F  F16  1  0.564  0.564  0.633  1.0
  F  F17  1  0.899  0.899  0.300  1.0
[/CIF]
.
The structure described by V3O5F is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(5), two equivalent O(1), two equivalent O(7), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with three equivalent V(2)O5F octahedra, corners with three equivalent V(6)O5F octahedra,  an edgeedge with one V(5)O5F octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(6), two equivalent O(1), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(4)O6 octahedra, corners with three equivalent V(1)O5F octahedra, corners with three equivalent V(5)O5F octahedra,  an edgeedge with one V(3)O4F2 octahedra, and  an edgeedge with one V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 42-54°. In the third V site, V(3) is bonded to one O(5), one O(6), two equivalent O(2), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent V(1)O5F octahedra, corners with three equivalent V(5)O5F octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(2)O5F octahedra, and  an edgeedge with one V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the fourth V site, V(4) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent V(2)O5F octahedra, corners with three equivalent V(3)O4F2 octahedra, corners with three equivalent V(6)O5F octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 42-53°. In the fifth V site, V(5) is bonded to one O(4), two equivalent O(1), two equivalent O(2), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(6)O5F octahedra, corners with three equivalent V(3)O4F2 octahedra, corners with three equivalent V(2)O5F octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-49°. In the sixth V site, V(6) is bonded to one O(3), one O(4), one O(5), two equivalent O(7), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(5)O5F octahedra, corners with three equivalent V(1)O5F octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(3)O4F2 octahedra, and  an edgeedge with one V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 42-54°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(2), one V(5), and one V(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3O5F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.521
_cell_length_b   5.521
_cell_length_c   7.330
_cell_angle_alpha   70.123
_cell_angle_beta   70.123
_cell_angle_gamma   71.837
_symmetry_Int_Tables_number   1
_cell_volume   192.663
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.674  0.674  0.847  1.0
  V  V1  1  0.319  0.319  0.671  1.0
  V  V2  1  0.656  0.656  0.318  1.0
  V  V3  1  0.338  0.338  0.160  1.0
  V  V4  1  1.000  1.000  0.515  1.0
  V  V5  1  0.012  0.012  0.987  1.0
  O  O6  1  0.638  0.040  0.659  1.0
  O  O7  1  0.961  0.369  0.334  1.0
  O  O8  1  0.238  0.238  0.965  1.0
  O  O9  1  0.097  0.097  0.697  1.0
  O  O10  1  0.772  0.772  0.038  1.0
  O  O11  1  0.433  0.433  0.369  1.0
  O  O12  1  0.697  0.294  0.007  1.0
  O  O13  1  0.040  0.638  0.659  1.0
  O  O14  1  0.369  0.961  0.334  1.0
  O  O15  1  0.294  0.697  0.007  1.0
  F  F16  1  0.564  0.564  0.633  1.0
  F  F17  1  0.899  0.899  0.300  1.0
[/CIF]
.