The structure described by MnH3(CO2)3(CH3)2NH2 crystallizes in the monoclinic Cc space group. The structure consists of four dimethylazanium molecules inside a MnH3(CO2)3 framework. In the MnH3(CO2)3 framework, Mn(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(3), one O(1), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(4), one O(2), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one H(5), one O(4), and one O(5) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Mn(1) and one C(2) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Mn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(2) atom. is represented by the CIF file [CIF]
data_MnH11C5NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.295
_cell_length_b   8.295
_cell_length_c   8.831
_cell_angle_alpha   63.708
_cell_angle_beta   63.708
_cell_angle_gamma   60.347
_symmetry_Int_Tables_number   1
_cell_volume   453.513
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.322  0.828  0.605  1.0
  Mn  Mn1  1  0.828  0.322  0.105  1.0
  H  H2  1  0.186  0.692  0.355  1.0
  H  H3  1  0.692  0.186  0.855  1.0
  H  H4  1  0.959  0.820  0.325  1.0
  H  H5  1  0.820  0.959  0.825  1.0
  H  H6  1  0.482  0.169  0.351  1.0
  H  H7  1  0.169  0.482  0.851  1.0
  H  H8  1  0.561  0.651  0.871  1.0
  H  H9  1  0.651  0.561  0.371  1.0
  H  H10  1  0.022  0.159  0.776  1.0
  H  H11  1  0.159  0.022  0.276  1.0
  H  H12  1  0.952  0.597  0.616  1.0
  H  H13  1  0.597  0.952  0.116  1.0
  H  H14  1  0.121  0.402  0.519  1.0
  H  H15  1  0.402  0.121  0.019  1.0
  H  H16  1  0.884  0.529  0.493  1.0
  H  H17  1  0.529  0.884  0.993  1.0
  H  H18  1  0.182  0.735  0.066  1.0
  H  H19  1  0.735  0.182  0.566  1.0
  H  H20  1  0.016  0.610  0.175  1.0
  H  H21  1  0.610  0.016  0.675  1.0
  H  H22  1  0.259  0.486  0.191  1.0
  H  H23  1  0.486  0.259  0.691  1.0
  C  C24  1  0.612  0.034  0.355  1.0
  C  C25  1  0.034  0.612  0.855  1.0
  C  C26  1  0.577  0.523  0.848  1.0
  C  C27  1  0.523  0.577  0.348  1.0
  C  C28  1  0.135  0.087  0.844  1.0
  C  C29  1  0.087  0.135  0.344  1.0
  C  C30  1  0.002  0.543  0.504  1.0
  C  C31  1  0.543  0.002  0.004  1.0
  C  C32  1  0.136  0.625  0.181  1.0
  C  C33  1  0.625  0.136  0.681  1.0
  N  N34  1  0.071  0.682  0.341  1.0
  N  N35  1  0.682  0.071  0.841  1.0
  O  O36  1  0.590  0.874  0.441  1.0
  O  O37  1  0.874  0.590  0.941  1.0
  O  O38  1  0.358  0.685  0.425  1.0
  O  O39  1  0.685  0.358  0.925  1.0
  O  O40  1  0.777  0.051  0.270  1.0
  O  O41  1  0.051  0.777  0.770  1.0
  O  O42  1  0.142  0.101  0.472  1.0
  O  O43  1  0.101  0.142  0.972  1.0
  O  O44  1  0.289  0.954  0.788  1.0
  O  O45  1  0.954  0.289  0.288  1.0
  O  O46  1  0.489  0.547  0.749  1.0
  O  O47  1  0.547  0.489  0.249  1.0
[/CIF]
.
The structure described by MnH3(CO2)3(CH3)2NH2 crystallizes in the monoclinic Cc space group. The structure consists of four dimethylazanium molecules inside a MnH3(CO2)3 framework. In the MnH3(CO2)3 framework, Mn(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(3), one O(1), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(4), one O(2), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one H(5), one O(4), and one O(5) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Mn(1) and one C(2) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Mn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(2) atom. is represented by the CIF file [CIF]
data_MnH11C5NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.295
_cell_length_b   8.295
_cell_length_c   8.831
_cell_angle_alpha   63.708
_cell_angle_beta   63.708
_cell_angle_gamma   60.347
_symmetry_Int_Tables_number   1
_cell_volume   453.513
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.322  0.828  0.605  1.0
  Mn  Mn1  1  0.828  0.322  0.105  1.0
  H  H2  1  0.186  0.692  0.355  1.0
  H  H3  1  0.692  0.186  0.855  1.0
  H  H4  1  0.959  0.820  0.325  1.0
  H  H5  1  0.820  0.959  0.825  1.0
  H  H6  1  0.482  0.169  0.351  1.0
  H  H7  1  0.169  0.482  0.851  1.0
  H  H8  1  0.561  0.651  0.871  1.0
  H  H9  1  0.651  0.561  0.371  1.0
  H  H10  1  0.022  0.159  0.776  1.0
  H  H11  1  0.159  0.022  0.276  1.0
  H  H12  1  0.952  0.597  0.616  1.0
  H  H13  1  0.597  0.952  0.116  1.0
  H  H14  1  0.121  0.402  0.519  1.0
  H  H15  1  0.402  0.121  0.019  1.0
  H  H16  1  0.884  0.529  0.493  1.0
  H  H17  1  0.529  0.884  0.993  1.0
  H  H18  1  0.182  0.735  0.066  1.0
  H  H19  1  0.735  0.182  0.566  1.0
  H  H20  1  0.016  0.610  0.175  1.0
  H  H21  1  0.610  0.016  0.675  1.0
  H  H22  1  0.259  0.486  0.191  1.0
  H  H23  1  0.486  0.259  0.691  1.0
  C  C24  1  0.612  0.034  0.355  1.0
  C  C25  1  0.034  0.612  0.855  1.0
  C  C26  1  0.577  0.523  0.848  1.0
  C  C27  1  0.523  0.577  0.348  1.0
  C  C28  1  0.135  0.087  0.844  1.0
  C  C29  1  0.087  0.135  0.344  1.0
  C  C30  1  0.002  0.543  0.504  1.0
  C  C31  1  0.543  0.002  0.004  1.0
  C  C32  1  0.136  0.625  0.181  1.0
  C  C33  1  0.625  0.136  0.681  1.0
  N  N34  1  0.071  0.682  0.341  1.0
  N  N35  1  0.682  0.071  0.841  1.0
  O  O36  1  0.590  0.874  0.441  1.0
  O  O37  1  0.874  0.590  0.941  1.0
  O  O38  1  0.358  0.685  0.425  1.0
  O  O39  1  0.685  0.358  0.925  1.0
  O  O40  1  0.777  0.051  0.270  1.0
  O  O41  1  0.051  0.777  0.770  1.0
  O  O42  1  0.142  0.101  0.472  1.0
  O  O43  1  0.101  0.142  0.972  1.0
  O  O44  1  0.289  0.954  0.788  1.0
  O  O45  1  0.954  0.289  0.288  1.0
  O  O46  1  0.489  0.547  0.749  1.0
  O  O47  1  0.547  0.489  0.249  1.0
[/CIF]
.