The crystal structure described by VSn2 is Khatyrkite-like structured and crystallizes in the orthorhombic Fddd space group. V(1) is bonded in a 10-coordinate geometry to two equivalent V(1), four equivalent Sn(1), and four equivalent Sn(2) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to four equivalent V(1) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to four equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VSn2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.455
_cell_length_b   5.455
_cell_length_c   9.723
_cell_angle_alpha   98.234
_cell_angle_beta   98.234
_cell_angle_gamma   119.305
_symmetry_Int_Tables_number   1
_cell_volume   241.948
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.253  0.003  0.006  1.0
  V  V1  1  0.997  0.747  0.494  1.0
  V  V2  1  0.747  0.997  0.994  1.0
  V  V3  1  0.003  0.253  0.506  1.0
  Sn  Sn4  1  0.959  0.041  0.750  1.0
  Sn  Sn5  1  0.291  0.709  0.750  1.0
  Sn  Sn6  1  0.041  0.959  0.250  1.0
  Sn  Sn7  1  0.709  0.291  0.250  1.0
  Sn  Sn8  1  0.541  0.291  0.582  1.0
  Sn  Sn9  1  0.709  0.459  0.918  1.0
  Sn  Sn10  1  0.459  0.709  0.418  1.0
  Sn  Sn11  1  0.291  0.541  0.082  1.0
[/CIF]
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The crystal structure described by VSn2 is Khatyrkite-like structured and crystallizes in the orthorhombic Fddd space group. V(1) is bonded in a 10-coordinate geometry to two equivalent V(1), four equivalent Sn(1), and four equivalent Sn(2) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to four equivalent V(1) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to four equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VSn2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.455
_cell_length_b   5.455
_cell_length_c   9.723
_cell_angle_alpha   98.234
_cell_angle_beta   98.234
_cell_angle_gamma   119.305
_symmetry_Int_Tables_number   1
_cell_volume   241.948
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.253  0.003  0.006  1.0
  V  V1  1  0.997  0.747  0.494  1.0
  V  V2  1  0.747  0.997  0.994  1.0
  V  V3  1  0.003  0.253  0.506  1.0
  Sn  Sn4  1  0.959  0.041  0.750  1.0
  Sn  Sn5  1  0.291  0.709  0.750  1.0
  Sn  Sn6  1  0.041  0.959  0.250  1.0
  Sn  Sn7  1  0.709  0.291  0.250  1.0
  Sn  Sn8  1  0.541  0.291  0.582  1.0
  Sn  Sn9  1  0.709  0.459  0.918  1.0
  Sn  Sn10  1  0.459  0.709  0.418  1.0
  Sn  Sn11  1  0.291  0.541  0.082  1.0
[/CIF]
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