The material structure described by LaCl3N2Cl2 crystallizes in the orthorhombic Pnma space group. The structure consists of four 7727-37-9 molecules and four 7782-50-5 molecules inside a LaCl3 framework. In the LaCl3 framework, La(1) is bonded in a 6-coordinate geometry to two equivalent Cl(4) and four equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a water-like geometry to two equivalent La(1) atoms. In the second Cl site, Cl(4) is bonded in a linear geometry to two equivalent La(1) atoms. is represented by the CIF file [CIF]
data_LaN2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.042
_cell_length_b   8.831
_cell_length_c   12.443
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   883.689
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.250  0.490  0.906  1.0
  La  La1  1  0.750  0.510  0.094  1.0
  La  La2  1  0.750  0.010  0.406  1.0
  La  La3  1  0.250  0.990  0.594  1.0
  N  N4  1  0.547  0.994  0.032  1.0
  N  N5  1  0.453  0.006  0.968  1.0
  N  N6  1  0.453  0.506  0.532  1.0
  N  N7  1  0.047  0.006  0.968  1.0
  N  N8  1  0.547  0.494  0.468  1.0
  N  N9  1  0.953  0.994  0.032  1.0
  N  N10  1  0.953  0.494  0.468  1.0
  N  N11  1  0.047  0.506  0.532  1.0
  Cl  Cl12  1  0.250  0.726  0.174  1.0
  Cl  Cl13  1  0.750  0.274  0.826  1.0
  Cl  Cl14  1  0.750  0.774  0.674  1.0
  Cl  Cl15  1  0.250  0.226  0.326  1.0
  Cl  Cl16  1  0.544  0.653  0.936  1.0
  Cl  Cl17  1  0.456  0.347  0.064  1.0
  Cl  Cl18  1  0.456  0.847  0.436  1.0
  Cl  Cl19  1  0.044  0.347  0.064  1.0
  Cl  Cl20  1  0.544  0.153  0.564  1.0
  Cl  Cl21  1  0.956  0.653  0.936  1.0
  Cl  Cl22  1  0.956  0.153  0.564  1.0
  Cl  Cl23  1  0.044  0.847  0.436  1.0
  Cl  Cl24  1  0.250  0.448  0.301  1.0
  Cl  Cl25  1  0.750  0.552  0.699  1.0
  Cl  Cl26  1  0.750  0.052  0.801  1.0
  Cl  Cl27  1  0.250  0.948  0.199  1.0
  Cl  Cl28  1  0.250  0.751  0.734  1.0
  Cl  Cl29  1  0.750  0.249  0.266  1.0
  Cl  Cl30  1  0.750  0.749  0.234  1.0
  Cl  Cl31  1  0.250  0.251  0.766  1.0
[/CIF]
.
The material structure described by LaCl3N2Cl2 crystallizes in the orthorhombic Pnma space group. The structure consists of four 7727-37-9 molecules and four 7782-50-5 molecules inside a LaCl3 framework. In the LaCl3 framework, La(1) is bonded in a 6-coordinate geometry to two equivalent Cl(4) and four equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a water-like geometry to two equivalent La(1) atoms. In the second Cl site, Cl(4) is bonded in a linear geometry to two equivalent La(1) atoms. is represented by the CIF file [CIF]
data_LaN2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.042
_cell_length_b   8.831
_cell_length_c   12.443
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   883.689
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.250  0.490  0.906  1.0
  La  La1  1  0.750  0.510  0.094  1.0
  La  La2  1  0.750  0.010  0.406  1.0
  La  La3  1  0.250  0.990  0.594  1.0
  N  N4  1  0.547  0.994  0.032  1.0
  N  N5  1  0.453  0.006  0.968  1.0
  N  N6  1  0.453  0.506  0.532  1.0
  N  N7  1  0.047  0.006  0.968  1.0
  N  N8  1  0.547  0.494  0.468  1.0
  N  N9  1  0.953  0.994  0.032  1.0
  N  N10  1  0.953  0.494  0.468  1.0
  N  N11  1  0.047  0.506  0.532  1.0
  Cl  Cl12  1  0.250  0.726  0.174  1.0
  Cl  Cl13  1  0.750  0.274  0.826  1.0
  Cl  Cl14  1  0.750  0.774  0.674  1.0
  Cl  Cl15  1  0.250  0.226  0.326  1.0
  Cl  Cl16  1  0.544  0.653  0.936  1.0
  Cl  Cl17  1  0.456  0.347  0.064  1.0
  Cl  Cl18  1  0.456  0.847  0.436  1.0
  Cl  Cl19  1  0.044  0.347  0.064  1.0
  Cl  Cl20  1  0.544  0.153  0.564  1.0
  Cl  Cl21  1  0.956  0.653  0.936  1.0
  Cl  Cl22  1  0.956  0.153  0.564  1.0
  Cl  Cl23  1  0.044  0.847  0.436  1.0
  Cl  Cl24  1  0.250  0.448  0.301  1.0
  Cl  Cl25  1  0.750  0.552  0.699  1.0
  Cl  Cl26  1  0.750  0.052  0.801  1.0
  Cl  Cl27  1  0.250  0.948  0.199  1.0
  Cl  Cl28  1  0.250  0.751  0.734  1.0
  Cl  Cl29  1  0.750  0.249  0.266  1.0
  Cl  Cl30  1  0.750  0.749  0.234  1.0
  Cl  Cl31  1  0.250  0.251  0.766  1.0
[/CIF]
.