The structure described by LiInSiO4 is Ilmenite-derived structured and crystallizes in the orthorhombic Pnma space group. Li(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with four equivalent In(1)O6 octahedra, corners with two equivalent Si(1)O4 tetrahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent In(1)O6 octahedra, and edges with two equivalent Si(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-65°. In(1) is bonded to one O(2), one O(3), and four equivalent O(1) atoms to form InO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, corners with four equivalent Si(1)O4 tetrahedra, edges with two equivalent Li(1)O6 octahedra, and  an edgeedge with one Si(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-65°. Si(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form SiO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra,  an edgeedge with one In(1)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent In(1), and one Si(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li(1), one In(1), and one Si(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1), one In(1), and one Si(1) atom. is represented by the CIF file [CIF]
data_LiInSiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.913
_cell_length_b   6.153
_cell_length_c   10.641
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   321.620
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.500  0.000  0.500  1.0
  Li  Li2  1  0.000  0.500  0.000  1.0
  Li  Li3  1  0.500  0.500  0.500  1.0
  In  In4  1  0.021  0.750  0.276  1.0
  In  In5  1  0.479  0.750  0.776  1.0
  In  In6  1  0.979  0.250  0.724  1.0
  In  In7  1  0.521  0.250  0.224  1.0
  Si  Si8  1  0.576  0.750  0.089  1.0
  Si  Si9  1  0.924  0.750  0.589  1.0
  Si  Si10  1  0.424  0.250  0.911  1.0
  Si  Si11  1  0.076  0.250  0.411  1.0
  O  O12  1  0.772  0.542  0.663  1.0
  O  O13  1  0.228  0.458  0.337  1.0
  O  O14  1  0.728  0.542  0.163  1.0
  O  O15  1  0.772  0.958  0.663  1.0
  O  O16  1  0.272  0.042  0.837  1.0
  O  O17  1  0.754  0.250  0.902  1.0
  O  O18  1  0.272  0.458  0.837  1.0
  O  O19  1  0.228  0.042  0.337  1.0
  O  O20  1  0.246  0.750  0.098  1.0
  O  O21  1  0.746  0.250  0.402  1.0
  O  O22  1  0.705  0.750  0.947  1.0
  O  O23  1  0.254  0.750  0.598  1.0
  O  O24  1  0.795  0.750  0.447  1.0
  O  O25  1  0.205  0.250  0.553  1.0
  O  O26  1  0.295  0.250  0.053  1.0
  O  O27  1  0.728  0.958  0.163  1.0
[/CIF]
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The structure described by LiInSiO4 is Ilmenite-derived structured and crystallizes in the orthorhombic Pnma space group. Li(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with four equivalent In(1)O6 octahedra, corners with two equivalent Si(1)O4 tetrahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent In(1)O6 octahedra, and edges with two equivalent Si(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-65°. In(1) is bonded to one O(2), one O(3), and four equivalent O(1) atoms to form InO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, corners with four equivalent Si(1)O4 tetrahedra, edges with two equivalent Li(1)O6 octahedra, and  an edgeedge with one Si(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-65°. Si(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form SiO4 tetrahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra,  an edgeedge with one In(1)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent In(1), and one Si(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li(1), one In(1), and one Si(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1), one In(1), and one Si(1) atom. is represented by the CIF file [CIF]
data_LiInSiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.913
_cell_length_b   6.153
_cell_length_c   10.641
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   321.620
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.500  0.000  0.500  1.0
  Li  Li2  1  0.000  0.500  0.000  1.0
  Li  Li3  1  0.500  0.500  0.500  1.0
  In  In4  1  0.021  0.750  0.276  1.0
  In  In5  1  0.479  0.750  0.776  1.0
  In  In6  1  0.979  0.250  0.724  1.0
  In  In7  1  0.521  0.250  0.224  1.0
  Si  Si8  1  0.576  0.750  0.089  1.0
  Si  Si9  1  0.924  0.750  0.589  1.0
  Si  Si10  1  0.424  0.250  0.911  1.0
  Si  Si11  1  0.076  0.250  0.411  1.0
  O  O12  1  0.772  0.542  0.663  1.0
  O  O13  1  0.228  0.458  0.337  1.0
  O  O14  1  0.728  0.542  0.163  1.0
  O  O15  1  0.772  0.958  0.663  1.0
  O  O16  1  0.272  0.042  0.837  1.0
  O  O17  1  0.754  0.250  0.902  1.0
  O  O18  1  0.272  0.458  0.837  1.0
  O  O19  1  0.228  0.042  0.337  1.0
  O  O20  1  0.246  0.750  0.098  1.0
  O  O21  1  0.746  0.250  0.402  1.0
  O  O22  1  0.705  0.750  0.947  1.0
  O  O23  1  0.254  0.750  0.598  1.0
  O  O24  1  0.795  0.750  0.447  1.0
  O  O25  1  0.205  0.250  0.553  1.0
  O  O26  1  0.295  0.250  0.053  1.0
  O  O27  1  0.728  0.958  0.163  1.0
[/CIF]
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