The structure described by BNCl is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four BNCl clusters. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to two equivalent N(2) and one Cl(1) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent B(2) atoms. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one B(2) atom. is represented by the CIF file [CIF]
data_BNCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.100
_cell_length_b   13.830
_cell_length_c   14.333
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   812.671
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.447  0.750  0.940  1.0
  B  B1  1  0.053  0.750  0.440  1.0
  B  B2  1  0.553  0.250  0.060  1.0
  B  B3  1  0.947  0.250  0.560  1.0
  B  B4  1  0.700  0.657  0.080  1.0
  B  B5  1  0.800  0.843  0.580  1.0
  B  B6  1  0.300  0.157  0.920  1.0
  B  B7  1  0.200  0.343  0.420  1.0
  B  B8  1  0.300  0.343  0.920  1.0
  B  B9  1  0.200  0.157  0.420  1.0
  B  B10  1  0.700  0.843  0.080  1.0
  B  B11  1  0.800  0.657  0.580  1.0
  N  N12  1  0.769  0.750  0.116  1.0
  N  N13  1  0.731  0.750  0.616  1.0
  N  N14  1  0.231  0.250  0.884  1.0
  N  N15  1  0.269  0.250  0.384  1.0
  N  N16  1  0.537  0.665  0.991  1.0
  N  N17  1  0.963  0.835  0.491  1.0
  N  N18  1  0.463  0.165  0.009  1.0
  N  N19  1  0.037  0.335  0.509  1.0
  N  N20  1  0.463  0.335  0.009  1.0
  N  N21  1  0.037  0.165  0.509  1.0
  N  N22  1  0.537  0.835  0.991  1.0
  N  N23  1  0.963  0.665  0.491  1.0
  Cl  Cl24  1  0.243  0.750  0.832  1.0
  Cl  Cl25  1  0.257  0.750  0.332  1.0
  Cl  Cl26  1  0.757  0.250  0.168  1.0
  Cl  Cl27  1  0.743  0.250  0.668  1.0
  Cl  Cl28  1  0.799  0.547  0.133  1.0
  Cl  Cl29  1  0.701  0.953  0.633  1.0
  Cl  Cl30  1  0.201  0.047  0.867  1.0
  Cl  Cl31  1  0.299  0.453  0.367  1.0
  Cl  Cl32  1  0.201  0.453  0.867  1.0
  Cl  Cl33  1  0.299  0.047  0.367  1.0
  Cl  Cl34  1  0.799  0.953  0.133  1.0
  Cl  Cl35  1  0.701  0.547  0.633  1.0
[/CIF]
.
The structure described by BNCl is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four BNCl clusters. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to two equivalent N(2) and one Cl(1) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent B(2) atoms. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one B(2) atom. is represented by the CIF file [CIF]
data_BNCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.100
_cell_length_b   13.830
_cell_length_c   14.333
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   812.671
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.447  0.750  0.940  1.0
  B  B1  1  0.053  0.750  0.440  1.0
  B  B2  1  0.553  0.250  0.060  1.0
  B  B3  1  0.947  0.250  0.560  1.0
  B  B4  1  0.700  0.657  0.080  1.0
  B  B5  1  0.800  0.843  0.580  1.0
  B  B6  1  0.300  0.157  0.920  1.0
  B  B7  1  0.200  0.343  0.420  1.0
  B  B8  1  0.300  0.343  0.920  1.0
  B  B9  1  0.200  0.157  0.420  1.0
  B  B10  1  0.700  0.843  0.080  1.0
  B  B11  1  0.800  0.657  0.580  1.0
  N  N12  1  0.769  0.750  0.116  1.0
  N  N13  1  0.731  0.750  0.616  1.0
  N  N14  1  0.231  0.250  0.884  1.0
  N  N15  1  0.269  0.250  0.384  1.0
  N  N16  1  0.537  0.665  0.991  1.0
  N  N17  1  0.963  0.835  0.491  1.0
  N  N18  1  0.463  0.165  0.009  1.0
  N  N19  1  0.037  0.335  0.509  1.0
  N  N20  1  0.463  0.335  0.009  1.0
  N  N21  1  0.037  0.165  0.509  1.0
  N  N22  1  0.537  0.835  0.991  1.0
  N  N23  1  0.963  0.665  0.491  1.0
  Cl  Cl24  1  0.243  0.750  0.832  1.0
  Cl  Cl25  1  0.257  0.750  0.332  1.0
  Cl  Cl26  1  0.757  0.250  0.168  1.0
  Cl  Cl27  1  0.743  0.250  0.668  1.0
  Cl  Cl28  1  0.799  0.547  0.133  1.0
  Cl  Cl29  1  0.701  0.953  0.633  1.0
  Cl  Cl30  1  0.201  0.047  0.867  1.0
  Cl  Cl31  1  0.299  0.453  0.367  1.0
  Cl  Cl32  1  0.201  0.453  0.867  1.0
  Cl  Cl33  1  0.299  0.047  0.367  1.0
  Cl  Cl34  1  0.799  0.953  0.133  1.0
  Cl  Cl35  1  0.701  0.547  0.633  1.0
[/CIF]
.