The crystal structure described by Mg14LaY crystallizes in the hexagonal P-6m2 space group. There are six inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(4); four equivalent Mg(1); four Mg(3,3); and two equivalent Y(1) atoms to form MgY2Mg10 cuboctahedra that share corners with four equivalent La(1)Mg12 cuboctahedra; corners with six equivalent Mg(1)Y2Mg10 cuboctahedra; corners with eight equivalent Mg(2)La2Mg10 cuboctahedra; edges with two equivalent Y(1)Mg12 cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(1)Y2Mg10 cuboctahedra; edges with eight Mg(3,3)LaYMg10 cuboctahedra; faces with two equivalent Mg(2)La2Mg10 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Y(1)Mg12 cuboctahedra; faces with four equivalent Mg(1)Y2Mg10 cuboctahedra; and faces with ten Mg(3,3,3)LaYMg10 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(4); four equivalent Mg(2); four Mg(3,3); and two equivalent La(1) atoms to form distorted MgLa2Mg10 cuboctahedra that share corners with four equivalent Y(1)Mg12 cuboctahedra; corners with six equivalent Mg(2)La2Mg10 cuboctahedra; corners with eight equivalent Mg(1)Y2Mg10 cuboctahedra; edges with two equivalent La(1)Mg12 cuboctahedra; edges with four equivalent Mg(2)La2Mg10 cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra; edges with eight Mg(3,3)LaYMg10 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(1)Y2Mg10 cuboctahedra; faces with two equivalent La(1)Mg12 cuboctahedra; faces with four equivalent Mg(2)La2Mg10 cuboctahedra; and faces with ten Mg(3,3,3)LaYMg10 cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Mg(1); two equivalent Mg(2); two equivalent Mg(4); four Mg(3,3); one La(1); and one Y(1) atom to form distorted MgLaYMg10 cuboctahedra that share corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with fourteen Mg(3,3,3)LaYMg10 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent La(1)Mg12 cuboctahedra; edges with two equivalent Y(1)Mg12 cuboctahedra; edges with four equivalent Mg(2)La2Mg10 cuboctahedra; edges with four Mg(3,3)LaYMg10 cuboctahedra; edges with four equivalent Mg(1)Y2Mg10 cuboctahedra;  a faceface with one La(1)Mg12 cuboctahedra;  a faceface with one Y(1)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with five equivalent Mg(2)La2Mg10 cuboctahedra; faces with five equivalent Mg(1)Y2Mg10 cuboctahedra; and faces with six Mg(3,3,3)LaYMg10 cuboctahedra. In the fourth Mg site, Mg(3) is bonded to two equivalent Mg(1); two equivalent Mg(2); two equivalent Mg(4); four Mg(3,3); one La(1); and one Y(1) atom to form distorted MgLaYMg10 cuboctahedra that share corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with fourteen Mg(3,3,3)LaYMg10 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent La(1)Mg12 cuboctahedra; edges with two equivalent Y(1)Mg12 cuboctahedra; edges with four equivalent Mg(2)La2Mg10 cuboctahedra; edges with four Mg(3,3)LaYMg10 cuboctahedra; edges with four equivalent Mg(1)Y2Mg10 cuboctahedra;  a faceface with one La(1)Mg12 cuboctahedra;  a faceface with one Y(1)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with five equivalent Mg(2)La2Mg10 cuboctahedra; faces with five equivalent Mg(1)Y2Mg10 cuboctahedra; and faces with six Mg(3,3,3)LaYMg10 cuboctahedra. In the fifth Mg site, Mg(3) is bonded to two equivalent Mg(1); two equivalent Mg(2); two equivalent Mg(4); four Mg(3,3); one La(1); and one Y(1) atom to form distorted MgLaYMg10 cuboctahedra that share corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with fourteen Mg(3,3,3)LaYMg10 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent La(1)Mg12 cuboctahedra; edges with two equivalent Y(1)Mg12 cuboctahedra; edges with four equivalent Mg(2)La2Mg10 cuboctahedra; edges with four Mg(3,3)LaYMg10 cuboctahedra; edges with four equivalent Mg(1)Y2Mg10 cuboctahedra;  a faceface with one La(1)Mg12 cuboctahedra;  a faceface with one Y(1)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with five equivalent Mg(2)La2Mg10 cuboctahedra; faces with five equivalent Mg(1)Y2Mg10 cuboctahedra; and faces with six Mg(3,3,3)LaYMg10 cuboctahedra. In the sixth Mg site, Mg(4) is bonded to three equivalent Mg(1); three equivalent Mg(2); and six Mg(3,3,3) atoms to form MgMg12 cuboctahedra that share corners with six equivalent Mg(4)Mg12 cuboctahedra; corners with twelve Mg(3,3,3)LaYMg10 cuboctahedra; edges with six equivalent Mg(2)La2Mg10 cuboctahedra; edges with six Mg(3,3,3)LaYMg10 cuboctahedra; edges with six equivalent Mg(1)Y2Mg10 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with three equivalent Mg(2)La2Mg10 cuboctahedra; faces with three equivalent Mg(1)Y2Mg10 cuboctahedra; faces with three equivalent La(1)Mg12 cuboctahedra; faces with three equivalent Y(1)Mg12 cuboctahedra; and faces with six Mg(3,3,3)LaYMg10 cuboctahedra. La(1) is bonded to six equivalent Mg(2) and six Mg(3,3,3) atoms to form LaMg12 cuboctahedra that share corners with six equivalent La(1)Mg12 cuboctahedra; corners with twelve equivalent Mg(1)Y2Mg10 cuboctahedra; edges with six equivalent Mg(2)La2Mg10 cuboctahedra; edges with twelve Mg(3,3,3)LaYMg10 cuboctahedra; faces with two equivalent Y(1)Mg12 cuboctahedra; faces with six equivalent Mg(2)La2Mg10 cuboctahedra; faces with six Mg(3,3,3)LaYMg10 cuboctahedra; and faces with six equivalent Mg(4)Mg12 cuboctahedra. Y(1) is bonded to six equivalent Mg(1) and six Mg(3,3,3) atoms to form YMg12 cuboctahedra that share corners with six equivalent Y(1)Mg12 cuboctahedra; corners with twelve equivalent Mg(2)La2Mg10 cuboctahedra; edges with six equivalent Mg(1)Y2Mg10 cuboctahedra; edges with twelve Mg(3,3,3)LaYMg10 cuboctahedra; faces with two equivalent La(1)Mg12 cuboctahedra; faces with six Mg(3,3,3)LaYMg10 cuboctahedra; faces with six equivalent Mg(4)Mg12 cuboctahedra; and faces with six equivalent Mg(1)Y2Mg10 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaYMg14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.695
_cell_length_b   6.695
_cell_length_c   10.326
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   400.881
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.167  0.333  0.625  1.0
  Y  Y1  1  0.167  0.333  0.125  1.0
  Mg  Mg2  1  0.172  0.836  0.125  1.0
  Mg  Mg3  1  0.173  0.837  0.625  1.0
  Mg  Mg4  1  0.664  0.328  0.125  1.0
  Mg  Mg5  1  0.663  0.327  0.625  1.0
  Mg  Mg6  1  0.664  0.836  0.125  1.0
  Mg  Mg7  1  0.663  0.837  0.625  1.0
  Mg  Mg8  1  0.338  0.162  0.373  1.0
  Mg  Mg9  1  0.338  0.162  0.877  1.0
  Mg  Mg10  1  0.338  0.675  0.373  1.0
  Mg  Mg11  1  0.338  0.675  0.877  1.0
  Mg  Mg12  1  0.825  0.162  0.373  1.0
  Mg  Mg13  1  0.825  0.162  0.877  1.0
  Mg  Mg14  1  0.833  0.667  0.376  1.0
  Mg  Mg15  1  0.833  0.667  0.874  1.0
[/CIF]
.
The crystal structure described by Mg14LaY crystallizes in the hexagonal P-6m2 space group. There are six inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(4); four equivalent Mg(1); four Mg(3,3); and two equivalent Y(1) atoms to form MgY2Mg10 cuboctahedra that share corners with four equivalent La(1)Mg12 cuboctahedra; corners with six equivalent Mg(1)Y2Mg10 cuboctahedra; corners with eight equivalent Mg(2)La2Mg10 cuboctahedra; edges with two equivalent Y(1)Mg12 cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra; edges with four equivalent Mg(1)Y2Mg10 cuboctahedra; edges with eight Mg(3,3)LaYMg10 cuboctahedra; faces with two equivalent Mg(2)La2Mg10 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Y(1)Mg12 cuboctahedra; faces with four equivalent Mg(1)Y2Mg10 cuboctahedra; and faces with ten Mg(3,3,3)LaYMg10 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(4); four equivalent Mg(2); four Mg(3,3); and two equivalent La(1) atoms to form distorted MgLa2Mg10 cuboctahedra that share corners with four equivalent Y(1)Mg12 cuboctahedra; corners with six equivalent Mg(2)La2Mg10 cuboctahedra; corners with eight equivalent Mg(1)Y2Mg10 cuboctahedra; edges with two equivalent La(1)Mg12 cuboctahedra; edges with four equivalent Mg(2)La2Mg10 cuboctahedra; edges with four equivalent Mg(4)Mg12 cuboctahedra; edges with eight Mg(3,3)LaYMg10 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with two equivalent Mg(1)Y2Mg10 cuboctahedra; faces with two equivalent La(1)Mg12 cuboctahedra; faces with four equivalent Mg(2)La2Mg10 cuboctahedra; and faces with ten Mg(3,3,3)LaYMg10 cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Mg(1); two equivalent Mg(2); two equivalent Mg(4); four Mg(3,3); one La(1); and one Y(1) atom to form distorted MgLaYMg10 cuboctahedra that share corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with fourteen Mg(3,3,3)LaYMg10 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent La(1)Mg12 cuboctahedra; edges with two equivalent Y(1)Mg12 cuboctahedra; edges with four equivalent Mg(2)La2Mg10 cuboctahedra; edges with four Mg(3,3)LaYMg10 cuboctahedra; edges with four equivalent Mg(1)Y2Mg10 cuboctahedra;  a faceface with one La(1)Mg12 cuboctahedra;  a faceface with one Y(1)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with five equivalent Mg(2)La2Mg10 cuboctahedra; faces with five equivalent Mg(1)Y2Mg10 cuboctahedra; and faces with six Mg(3,3,3)LaYMg10 cuboctahedra. In the fourth Mg site, Mg(3) is bonded to two equivalent Mg(1); two equivalent Mg(2); two equivalent Mg(4); four Mg(3,3); one La(1); and one Y(1) atom to form distorted MgLaYMg10 cuboctahedra that share corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with fourteen Mg(3,3,3)LaYMg10 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent La(1)Mg12 cuboctahedra; edges with two equivalent Y(1)Mg12 cuboctahedra; edges with four equivalent Mg(2)La2Mg10 cuboctahedra; edges with four Mg(3,3)LaYMg10 cuboctahedra; edges with four equivalent Mg(1)Y2Mg10 cuboctahedra;  a faceface with one La(1)Mg12 cuboctahedra;  a faceface with one Y(1)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with five equivalent Mg(2)La2Mg10 cuboctahedra; faces with five equivalent Mg(1)Y2Mg10 cuboctahedra; and faces with six Mg(3,3,3)LaYMg10 cuboctahedra. In the fifth Mg site, Mg(3) is bonded to two equivalent Mg(1); two equivalent Mg(2); two equivalent Mg(4); four Mg(3,3); one La(1); and one Y(1) atom to form distorted MgLaYMg10 cuboctahedra that share corners with four equivalent Mg(4)Mg12 cuboctahedra; corners with fourteen Mg(3,3,3)LaYMg10 cuboctahedra; edges with two equivalent Mg(4)Mg12 cuboctahedra; edges with two equivalent La(1)Mg12 cuboctahedra; edges with two equivalent Y(1)Mg12 cuboctahedra; edges with four equivalent Mg(2)La2Mg10 cuboctahedra; edges with four Mg(3,3)LaYMg10 cuboctahedra; edges with four equivalent Mg(1)Y2Mg10 cuboctahedra;  a faceface with one La(1)Mg12 cuboctahedra;  a faceface with one Y(1)Mg12 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with five equivalent Mg(2)La2Mg10 cuboctahedra; faces with five equivalent Mg(1)Y2Mg10 cuboctahedra; and faces with six Mg(3,3,3)LaYMg10 cuboctahedra. In the sixth Mg site, Mg(4) is bonded to three equivalent Mg(1); three equivalent Mg(2); and six Mg(3,3,3) atoms to form MgMg12 cuboctahedra that share corners with six equivalent Mg(4)Mg12 cuboctahedra; corners with twelve Mg(3,3,3)LaYMg10 cuboctahedra; edges with six equivalent Mg(2)La2Mg10 cuboctahedra; edges with six Mg(3,3,3)LaYMg10 cuboctahedra; edges with six equivalent Mg(1)Y2Mg10 cuboctahedra; faces with two equivalent Mg(4)Mg12 cuboctahedra; faces with three equivalent Mg(2)La2Mg10 cuboctahedra; faces with three equivalent Mg(1)Y2Mg10 cuboctahedra; faces with three equivalent La(1)Mg12 cuboctahedra; faces with three equivalent Y(1)Mg12 cuboctahedra; and faces with six Mg(3,3,3)LaYMg10 cuboctahedra. La(1) is bonded to six equivalent Mg(2) and six Mg(3,3,3) atoms to form LaMg12 cuboctahedra that share corners with six equivalent La(1)Mg12 cuboctahedra; corners with twelve equivalent Mg(1)Y2Mg10 cuboctahedra; edges with six equivalent Mg(2)La2Mg10 cuboctahedra; edges with twelve Mg(3,3,3)LaYMg10 cuboctahedra; faces with two equivalent Y(1)Mg12 cuboctahedra; faces with six equivalent Mg(2)La2Mg10 cuboctahedra; faces with six Mg(3,3,3)LaYMg10 cuboctahedra; and faces with six equivalent Mg(4)Mg12 cuboctahedra. Y(1) is bonded to six equivalent Mg(1) and six Mg(3,3,3) atoms to form YMg12 cuboctahedra that share corners with six equivalent Y(1)Mg12 cuboctahedra; corners with twelve equivalent Mg(2)La2Mg10 cuboctahedra; edges with six equivalent Mg(1)Y2Mg10 cuboctahedra; edges with twelve Mg(3,3,3)LaYMg10 cuboctahedra; faces with two equivalent La(1)Mg12 cuboctahedra; faces with six Mg(3,3,3)LaYMg10 cuboctahedra; faces with six equivalent Mg(4)Mg12 cuboctahedra; and faces with six equivalent Mg(1)Y2Mg10 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaYMg14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.695
_cell_length_b   6.695
_cell_length_c   10.326
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   400.881
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.167  0.333  0.625  1.0
  Y  Y1  1  0.167  0.333  0.125  1.0
  Mg  Mg2  1  0.172  0.836  0.125  1.0
  Mg  Mg3  1  0.173  0.837  0.625  1.0
  Mg  Mg4  1  0.664  0.328  0.125  1.0
  Mg  Mg5  1  0.663  0.327  0.625  1.0
  Mg  Mg6  1  0.664  0.836  0.125  1.0
  Mg  Mg7  1  0.663  0.837  0.625  1.0
  Mg  Mg8  1  0.338  0.162  0.373  1.0
  Mg  Mg9  1  0.338  0.162  0.877  1.0
  Mg  Mg10  1  0.338  0.675  0.373  1.0
  Mg  Mg11  1  0.338  0.675  0.877  1.0
  Mg  Mg12  1  0.825  0.162  0.373  1.0
  Mg  Mg13  1  0.825  0.162  0.877  1.0
  Mg  Mg14  1  0.833  0.667  0.376  1.0
  Mg  Mg15  1  0.833  0.667  0.874  1.0
[/CIF]
.