The structure described by LiAgF4 crystallizes in the monoclinic C2/m space group. Li(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form LiF6 octahedra that share corners with eight equivalent Ag(1)F6 octahedra and edges with two equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form distorted AgF6 octahedra that share corners with eight equivalent Li(1)F6 octahedra and edges with two equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiAgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.590
_cell_length_b   4.590
_cell_length_c   3.473
_cell_angle_alpha   84.158
_cell_angle_beta   84.158
_cell_angle_gamma   87.032
_symmetry_Int_Tables_number   1
_cell_volume   72.338
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.500  0.500  0.500  1.0
  F  F2  1  0.710  0.710  0.056  1.0
  F  F3  1  0.195  0.805  0.500  1.0
  F  F4  1  0.805  0.195  0.500  1.0
  F  F5  1  0.290  0.290  0.944  1.0
[/CIF]
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The structure described by LiAgF4 crystallizes in the monoclinic C2/m space group. Li(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form LiF6 octahedra that share corners with eight equivalent Ag(1)F6 octahedra and edges with two equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form distorted AgF6 octahedra that share corners with eight equivalent Li(1)F6 octahedra and edges with two equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiAgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.590
_cell_length_b   4.590
_cell_length_c   3.473
_cell_angle_alpha   84.158
_cell_angle_beta   84.158
_cell_angle_gamma   87.032
_symmetry_Int_Tables_number   1
_cell_volume   72.338
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.500  0.500  0.500  1.0
  F  F2  1  0.710  0.710  0.056  1.0
  F  F3  1  0.195  0.805  0.500  1.0
  F  F4  1  0.805  0.195  0.500  1.0
  F  F5  1  0.290  0.290  0.944  1.0
[/CIF]
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