The material structure described by K3RhC5N5HO crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. In the second K site, K(2) is bonded in a 11-coordinate geometry to one C(1), one C(3), one C(5), one N(3), one N(5), two equivalent N(1), two equivalent N(2), one H(1), and one O(1) atom. In the third K site, K(3) is bonded in a 1-coordinate geometry to one N(1) atom. Rh(1) is bonded in an octahedral geometry to one C(1), one C(3), one C(4), one C(5), one N(4), and one H(1) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one K(2), one Rh(1), and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(4) and one O(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one K(2), one Rh(1), and one N(1) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Rh(1) and one N(3) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one K(2), one Rh(1), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one K(1), one K(3), two equivalent K(2), and one C(3) atom. In the second N site, N(2) is bonded in a 1-coordinate geometry to one K(1), two equivalent K(2), and one C(1) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(4) atom. In the fourth N site, N(4) is bonded in a 1-coordinate geometry to one K(1), one Rh(1), and one C(2) atom. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(5) atom. H(1) is bonded in a distorted bent 120 degrees geometry to one K(2) and one Rh(1) atom. O(1) is bonded in a single-bond geometry to one K(2) and one C(2) atom. is represented by the CIF file [CIF]
data_K3HRhC5N5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.681
_cell_length_b   8.408
_cell_length_c   8.998
_cell_angle_alpha   89.860
_cell_angle_beta   100.344
_cell_angle_gamma   100.548
_symmetry_Int_Tables_number   1
_cell_volume   561.787
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.680  0.377  0.823  1.0
  K  K1  1  0.320  0.623  0.177  1.0
  K  K2  1  0.305  0.084  0.182  1.0
  K  K3  1  0.695  0.916  0.818  1.0
  K  K4  1  0.132  0.316  0.710  1.0
  K  K5  1  0.868  0.684  0.290  1.0
  H  H6  1  0.997  0.077  0.327  1.0
  H  H7  1  0.003  0.923  0.673  1.0
  Rh  Rh8  1  0.856  0.192  0.271  1.0
  Rh  Rh9  1  0.144  0.808  0.729  1.0
  C  C10  1  0.690  0.998  0.199  1.0
  C  C11  1  0.310  0.002  0.801  1.0
  C  C12  1  0.207  0.366  0.408  1.0
  C  C13  1  0.793  0.634  0.592  1.0
  C  C14  1  0.940  0.209  0.075  1.0
  C  C15  1  0.060  0.791  0.925  1.0
  C  C16  1  0.789  0.170  0.477  1.0
  C  C17  1  0.211  0.830  0.523  1.0
  C  C18  1  0.667  0.337  0.205  1.0
  C  C19  1  0.333  0.663  0.795  1.0
  N  N20  1  0.992  0.223  0.961  1.0
  N  N21  1  0.008  0.777  0.039  1.0
  N  N22  1  0.591  0.879  0.150  1.0
  N  N23  1  0.409  0.121  0.850  1.0
  N  N24  1  0.756  0.160  0.599  1.0
  N  N25  1  0.244  0.840  0.401  1.0
  N  N26  1  0.069  0.404  0.347  1.0
  N  N27  1  0.931  0.596  0.653  1.0
  N  N28  1  0.555  0.413  0.170  1.0
  N  N29  1  0.445  0.587  0.830  1.0
  O  O30  1  0.345  0.331  0.473  1.0
  O  O31  1  0.655  0.669  0.527  1.0
[/CIF]
.
The material structure described by K3RhC5N5HO crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. In the second K site, K(2) is bonded in a 11-coordinate geometry to one C(1), one C(3), one C(5), one N(3), one N(5), two equivalent N(1), two equivalent N(2), one H(1), and one O(1) atom. In the third K site, K(3) is bonded in a 1-coordinate geometry to one N(1) atom. Rh(1) is bonded in an octahedral geometry to one C(1), one C(3), one C(4), one C(5), one N(4), and one H(1) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one K(2), one Rh(1), and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(4) and one O(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one K(2), one Rh(1), and one N(1) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Rh(1) and one N(3) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one K(2), one Rh(1), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one K(1), one K(3), two equivalent K(2), and one C(3) atom. In the second N site, N(2) is bonded in a 1-coordinate geometry to one K(1), two equivalent K(2), and one C(1) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(4) atom. In the fourth N site, N(4) is bonded in a 1-coordinate geometry to one K(1), one Rh(1), and one C(2) atom. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(5) atom. H(1) is bonded in a distorted bent 120 degrees geometry to one K(2) and one Rh(1) atom. O(1) is bonded in a single-bond geometry to one K(2) and one C(2) atom. is represented by the CIF file [CIF]
data_K3HRhC5N5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.681
_cell_length_b   8.408
_cell_length_c   8.998
_cell_angle_alpha   89.860
_cell_angle_beta   100.344
_cell_angle_gamma   100.548
_symmetry_Int_Tables_number   1
_cell_volume   561.787
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.680  0.377  0.823  1.0
  K  K1  1  0.320  0.623  0.177  1.0
  K  K2  1  0.305  0.084  0.182  1.0
  K  K3  1  0.695  0.916  0.818  1.0
  K  K4  1  0.132  0.316  0.710  1.0
  K  K5  1  0.868  0.684  0.290  1.0
  H  H6  1  0.997  0.077  0.327  1.0
  H  H7  1  0.003  0.923  0.673  1.0
  Rh  Rh8  1  0.856  0.192  0.271  1.0
  Rh  Rh9  1  0.144  0.808  0.729  1.0
  C  C10  1  0.690  0.998  0.199  1.0
  C  C11  1  0.310  0.002  0.801  1.0
  C  C12  1  0.207  0.366  0.408  1.0
  C  C13  1  0.793  0.634  0.592  1.0
  C  C14  1  0.940  0.209  0.075  1.0
  C  C15  1  0.060  0.791  0.925  1.0
  C  C16  1  0.789  0.170  0.477  1.0
  C  C17  1  0.211  0.830  0.523  1.0
  C  C18  1  0.667  0.337  0.205  1.0
  C  C19  1  0.333  0.663  0.795  1.0
  N  N20  1  0.992  0.223  0.961  1.0
  N  N21  1  0.008  0.777  0.039  1.0
  N  N22  1  0.591  0.879  0.150  1.0
  N  N23  1  0.409  0.121  0.850  1.0
  N  N24  1  0.756  0.160  0.599  1.0
  N  N25  1  0.244  0.840  0.401  1.0
  N  N26  1  0.069  0.404  0.347  1.0
  N  N27  1  0.931  0.596  0.653  1.0
  N  N28  1  0.555  0.413  0.170  1.0
  N  N29  1  0.445  0.587  0.830  1.0
  O  O30  1  0.345  0.331  0.473  1.0
  O  O31  1  0.655  0.669  0.527  1.0
[/CIF]
.