The material described by CoCl2N3ON2NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four nitroxyl molecules, and four CoCl2N3O clusters. In each CoCl2N3O cluster, Co(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one N(6) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a bent 150 degrees geometry to one Co(1) and one O(2) atom. In the second N site, N(4) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cl(1), and one Cl(2) atom. In the third N site, N(6) is bonded in a single-bond geometry to one Co(1) atom. O(2) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one N(4) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF file [CIF]
data_CoN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.382
_cell_length_b   8.382
_cell_length_c   11.802
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   79.992
_symmetry_Int_Tables_number   1
_cell_volume   913.994
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.157  0.215  0.644  1.0
  Co  Co1  1  0.657  0.715  0.856  1.0
  Co  Co2  1  0.843  0.785  0.356  1.0
  Co  Co3  1  0.343  0.285  0.144  1.0
  N  N4  1  0.694  0.232  0.435  1.0
  N  N5  1  0.194  0.732  0.065  1.0
  N  N6  1  0.306  0.768  0.565  1.0
  N  N7  1  0.806  0.268  0.935  1.0
  N  N8  1  0.522  0.340  0.653  1.0
  N  N9  1  0.022  0.840  0.847  1.0
  N  N10  1  0.478  0.660  0.347  1.0
  N  N11  1  0.978  0.160  0.153  1.0
  N  N12  1  0.044  0.263  0.758  1.0
  N  N13  1  0.544  0.763  0.742  1.0
  N  N14  1  0.956  0.737  0.242  1.0
  N  N15  1  0.456  0.237  0.258  1.0
  N  N16  1  0.097  0.229  0.492  1.0
  N  N17  1  0.597  0.729  0.008  1.0
  N  N18  1  0.903  0.771  0.508  1.0
  N  N19  1  0.403  0.271  0.992  1.0
  N  N20  1  0.412  0.408  0.635  1.0
  N  N21  1  0.912  0.908  0.865  1.0
  N  N22  1  0.588  0.592  0.365  1.0
  N  N23  1  0.088  0.092  0.135  1.0
  N  N24  1  0.302  0.095  0.656  1.0
  N  N25  1  0.802  0.595  0.844  1.0
  N  N26  1  0.698  0.905  0.344  1.0
  N  N27  1  0.198  0.405  0.156  1.0
  Cl  Cl28  1  0.339  0.443  0.911  1.0
  Cl  Cl29  1  0.839  0.943  0.589  1.0
  Cl  Cl30  1  0.661  0.557  0.089  1.0
  Cl  Cl31  1  0.161  0.057  0.411  1.0
  Cl  Cl32  1  0.356  0.099  0.926  1.0
  Cl  Cl33  1  0.856  0.599  0.574  1.0
  Cl  Cl34  1  0.644  0.901  0.074  1.0
  Cl  Cl35  1  0.144  0.401  0.426  1.0
  O  O36  1  0.778  0.233  0.365  1.0
  O  O37  1  0.278  0.733  0.135  1.0
  O  O38  1  0.222  0.767  0.635  1.0
  O  O39  1  0.722  0.267  0.865  1.0
  O  O40  1  0.466  0.262  0.357  1.0
  O  O41  1  0.966  0.762  0.143  1.0
  O  O42  1  0.534  0.738  0.643  1.0
  O  O43  1  0.034  0.238  0.857  1.0
[/CIF]
.
The material described by CoCl2N3ON2NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four nitroxyl molecules, and four CoCl2N3O clusters. In each CoCl2N3O cluster, Co(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one N(6) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a bent 150 degrees geometry to one Co(1) and one O(2) atom. In the second N site, N(4) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cl(1), and one Cl(2) atom. In the third N site, N(6) is bonded in a single-bond geometry to one Co(1) atom. O(2) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one N(4) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF file [CIF]
data_CoN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.382
_cell_length_b   8.382
_cell_length_c   11.802
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   79.992
_symmetry_Int_Tables_number   1
_cell_volume   913.994
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.157  0.215  0.644  1.0
  Co  Co1  1  0.657  0.715  0.856  1.0
  Co  Co2  1  0.843  0.785  0.356  1.0
  Co  Co3  1  0.343  0.285  0.144  1.0
  N  N4  1  0.694  0.232  0.435  1.0
  N  N5  1  0.194  0.732  0.065  1.0
  N  N6  1  0.306  0.768  0.565  1.0
  N  N7  1  0.806  0.268  0.935  1.0
  N  N8  1  0.522  0.340  0.653  1.0
  N  N9  1  0.022  0.840  0.847  1.0
  N  N10  1  0.478  0.660  0.347  1.0
  N  N11  1  0.978  0.160  0.153  1.0
  N  N12  1  0.044  0.263  0.758  1.0
  N  N13  1  0.544  0.763  0.742  1.0
  N  N14  1  0.956  0.737  0.242  1.0
  N  N15  1  0.456  0.237  0.258  1.0
  N  N16  1  0.097  0.229  0.492  1.0
  N  N17  1  0.597  0.729  0.008  1.0
  N  N18  1  0.903  0.771  0.508  1.0
  N  N19  1  0.403  0.271  0.992  1.0
  N  N20  1  0.412  0.408  0.635  1.0
  N  N21  1  0.912  0.908  0.865  1.0
  N  N22  1  0.588  0.592  0.365  1.0
  N  N23  1  0.088  0.092  0.135  1.0
  N  N24  1  0.302  0.095  0.656  1.0
  N  N25  1  0.802  0.595  0.844  1.0
  N  N26  1  0.698  0.905  0.344  1.0
  N  N27  1  0.198  0.405  0.156  1.0
  Cl  Cl28  1  0.339  0.443  0.911  1.0
  Cl  Cl29  1  0.839  0.943  0.589  1.0
  Cl  Cl30  1  0.661  0.557  0.089  1.0
  Cl  Cl31  1  0.161  0.057  0.411  1.0
  Cl  Cl32  1  0.356  0.099  0.926  1.0
  Cl  Cl33  1  0.856  0.599  0.574  1.0
  Cl  Cl34  1  0.644  0.901  0.074  1.0
  Cl  Cl35  1  0.144  0.401  0.426  1.0
  O  O36  1  0.778  0.233  0.365  1.0
  O  O37  1  0.278  0.733  0.135  1.0
  O  O38  1  0.222  0.767  0.635  1.0
  O  O39  1  0.722  0.267  0.865  1.0
  O  O40  1  0.466  0.262  0.357  1.0
  O  O41  1  0.966  0.762  0.143  1.0
  O  O42  1  0.534  0.738  0.643  1.0
  O  O43  1  0.034  0.238  0.857  1.0
[/CIF]
.