The crystal structure described by BaSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Ba(1) is bonded to six equivalent O(1) atoms to form BaO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Ba(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a distorted trigonal planar geometry to one Ba(1) and two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_Ba(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.328
_cell_length_b   5.328
_cell_length_c   5.816
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   142.980
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.667  0.333  0.500  1.0
  Sb  Sb2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.386  0.386  0.693  1.0
  O  O4  1  0.614  0.000  0.693  1.0
  O  O5  1  0.000  0.614  0.693  1.0
  O  O6  1  0.386  0.000  0.307  1.0
  O  O7  1  0.000  0.386  0.307  1.0
  O  O8  1  0.614  0.614  0.307  1.0
[/CIF]
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The crystal structure described by BaSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Ba(1) is bonded to six equivalent O(1) atoms to form BaO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Ba(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a distorted trigonal planar geometry to one Ba(1) and two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_Ba(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.328
_cell_length_b   5.328
_cell_length_c   5.816
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   142.980
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.667  0.333  0.500  1.0
  Sb  Sb2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.386  0.386  0.693  1.0
  O  O4  1  0.614  0.000  0.693  1.0
  O  O5  1  0.000  0.614  0.693  1.0
  O  O6  1  0.386  0.000  0.307  1.0
  O  O7  1  0.000  0.386  0.307  1.0
  O  O8  1  0.614  0.614  0.307  1.0
[/CIF]
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