The material structure described by Bi14SO24 crystallizes in the monoclinic Cm space group. There are nine inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(3) atoms. In the second Bi site, Bi(2) is bonded in a 5-coordinate geometry to one O(11), one O(3), one O(4), one O(5), and one O(8) atom. In the third Bi site, Bi(3) is bonded to one O(1), one O(10), one O(11), one O(6), and one O(8) atom to form a mixture of distorted corner and edge-sharing BiO5 square pyramids. In the fourth Bi site, Bi(4) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(5), and two equivalent O(9) atoms. In the fifth Bi site, Bi(5) is bonded in a distorted body-centered cubic geometry to one O(1), one O(10), one O(11), one O(2), one O(3), one O(4), one O(8), and one O(9) atom. In the sixth Bi site, Bi(6) is bonded in a 7-coordinate geometry to one O(12), two equivalent O(10), two equivalent O(3), and two equivalent O(5) atoms. In the seventh Bi site, Bi(7) is bonded to one O(1), one O(11), one O(2), one O(4), and one O(6) atom to form a mixture of distorted corner and edge-sharing BiO5 square pyramids. In the eighth Bi site, Bi(8) is bonded to one O(1), one O(4), one O(5), one O(8), and one O(9) atom to form distorted corner-sharing BiO5 square pyramids. In the ninth Bi site, Bi(9) is bonded in a 7-coordinate geometry to one O(13), two equivalent O(10), two equivalent O(6), and two equivalent O(9) atoms. S(1) is bonded in a tetrahedral geometry to one O(12), one O(13), and two equivalent O(7) atoms. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded to one Bi(3), one Bi(5), one Bi(7), and one Bi(8) atom to form a mixture of distorted corner and edge-sharing OBi4 tetrahedra. In the second O site, O(2) is bonded to one Bi(1), one Bi(4), one Bi(5), and one Bi(7) atom to form a mixture of corner and edge-sharing OBi4 tetrahedra. In the third O site, O(3) is bonded to one Bi(1), one Bi(2), one Bi(5), and one Bi(6) atom to form a mixture of corner and edge-sharing OBi4 tetrahedra. In the fourth O site, O(4) is bonded to one Bi(2), one Bi(5), one Bi(7), and one Bi(8) atom to form a mixture of distorted corner and edge-sharing OBi4 tetrahedra. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Bi(2), one Bi(4), one Bi(6), and one Bi(8) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Bi(3), one Bi(7), and one Bi(9) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Bi(2), one Bi(3), one Bi(5), and one Bi(8) atom. In the ninth O site, O(9) is bonded to one Bi(4), one Bi(5), one Bi(8), and one Bi(9) atom to form a mixture of corner and edge-sharing OBi4 tetrahedra. In the tenth O site, O(10) is bonded to one Bi(3), one Bi(5), one Bi(6), and one Bi(9) atom to form a mixture of corner and edge-sharing OBi4 tetrahedra. In the eleventh O site, O(11) is bonded to one Bi(2), one Bi(3), one Bi(5), and one Bi(7) atom to form a mixture of distorted corner and edge-sharing OBi4 tetrahedra. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Bi(6) and one S(1) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Bi(9) and one S(1) atom. is represented by the CIF file [CIF]
data_Bi14SO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.552
_cell_length_b   10.552
_cell_length_c   8.661
_cell_angle_alpha   65.810
_cell_angle_beta   65.810
_cell_angle_gamma   109.010
_symmetry_Int_Tables_number   1
_cell_volume   645.983
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.215  0.215  0.232  1.0
  Bi  Bi1  1  0.468  0.127  0.815  1.0
  Bi  Bi2  1  0.723  0.061  0.404  1.0
  Bi  Bi3  1  0.450  0.450  0.338  1.0
  Bi  Bi4  1  0.662  0.343  0.994  1.0
  Bi  Bi5  1  0.558  0.558  0.652  1.0
  Bi  Bi6  1  0.944  0.278  0.596  1.0
  Bi  Bi7  1  0.874  0.537  0.189  1.0
  Bi  Bi8  1  0.793  0.793  0.765  1.0
  Bi  Bi9  1  0.127  0.468  0.815  1.0
  Bi  Bi10  1  0.061  0.723  0.404  1.0
  Bi  Bi11  1  0.343  0.662  0.994  1.0
  Bi  Bi12  1  0.278  0.944  0.596  1.0
  Bi  Bi13  1  0.537  0.874  0.189  1.0
  S  S14  1  0.966  0.966  0.006  1.0
  O  O15  1  0.496  0.008  0.328  1.0
  O  O16  1  0.398  0.242  0.305  1.0
  O  O17  1  0.453  0.296  0.945  1.0
  O  O18  1  0.673  0.184  0.829  1.0
  O  O19  1  0.622  0.379  0.500  1.0
  O  O20  1  0.878  0.120  0.504  1.0
  O  O21  1  0.970  0.111  0.995  1.0
  O  O22  1  0.826  0.336  0.171  1.0
  O  O23  1  0.706  0.550  0.056  1.0
  O  O24  1  0.762  0.603  0.690  1.0
  O  O25  1  0.008  0.496  0.328  1.0
  O  O26  1  0.992  0.505  0.676  1.0
  O  O27  1  0.242  0.398  0.305  1.0
  O  O28  1  0.800  0.800  0.214  1.0
  O  O29  1  0.296  0.453  0.945  1.0
  O  O30  1  0.184  0.673  0.829  1.0
  O  O31  1  0.981  0.981  0.820  1.0
  O  O32  1  0.120  0.878  0.504  1.0
  O  O33  1  0.379  0.622  0.500  1.0
  O  O34  1  0.111  0.970  0.995  1.0
  O  O35  1  0.336  0.826  0.171  1.0
  O  O36  1  0.550  0.706  0.056  1.0
  O  O37  1  0.603  0.762  0.690  1.0
  O  O38  1  0.505  0.992  0.676  1.0
[/CIF]
.
The material structure described by Bi14SO24 crystallizes in the monoclinic Cm space group. There are nine inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(3) atoms. In the second Bi site, Bi(2) is bonded in a 5-coordinate geometry to one O(11), one O(3), one O(4), one O(5), and one O(8) atom. In the third Bi site, Bi(3) is bonded to one O(1), one O(10), one O(11), one O(6), and one O(8) atom to form a mixture of distorted corner and edge-sharing BiO5 square pyramids. In the fourth Bi site, Bi(4) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(5), and two equivalent O(9) atoms. In the fifth Bi site, Bi(5) is bonded in a distorted body-centered cubic geometry to one O(1), one O(10), one O(11), one O(2), one O(3), one O(4), one O(8), and one O(9) atom. In the sixth Bi site, Bi(6) is bonded in a 7-coordinate geometry to one O(12), two equivalent O(10), two equivalent O(3), and two equivalent O(5) atoms. In the seventh Bi site, Bi(7) is bonded to one O(1), one O(11), one O(2), one O(4), and one O(6) atom to form a mixture of distorted corner and edge-sharing BiO5 square pyramids. In the eighth Bi site, Bi(8) is bonded to one O(1), one O(4), one O(5), one O(8), and one O(9) atom to form distorted corner-sharing BiO5 square pyramids. In the ninth Bi site, Bi(9) is bonded in a 7-coordinate geometry to one O(13), two equivalent O(10), two equivalent O(6), and two equivalent O(9) atoms. S(1) is bonded in a tetrahedral geometry to one O(12), one O(13), and two equivalent O(7) atoms. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded to one Bi(3), one Bi(5), one Bi(7), and one Bi(8) atom to form a mixture of distorted corner and edge-sharing OBi4 tetrahedra. In the second O site, O(2) is bonded to one Bi(1), one Bi(4), one Bi(5), and one Bi(7) atom to form a mixture of corner and edge-sharing OBi4 tetrahedra. In the third O site, O(3) is bonded to one Bi(1), one Bi(2), one Bi(5), and one Bi(6) atom to form a mixture of corner and edge-sharing OBi4 tetrahedra. In the fourth O site, O(4) is bonded to one Bi(2), one Bi(5), one Bi(7), and one Bi(8) atom to form a mixture of distorted corner and edge-sharing OBi4 tetrahedra. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Bi(2), one Bi(4), one Bi(6), and one Bi(8) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Bi(3), one Bi(7), and one Bi(9) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Bi(2), one Bi(3), one Bi(5), and one Bi(8) atom. In the ninth O site, O(9) is bonded to one Bi(4), one Bi(5), one Bi(8), and one Bi(9) atom to form a mixture of corner and edge-sharing OBi4 tetrahedra. In the tenth O site, O(10) is bonded to one Bi(3), one Bi(5), one Bi(6), and one Bi(9) atom to form a mixture of corner and edge-sharing OBi4 tetrahedra. In the eleventh O site, O(11) is bonded to one Bi(2), one Bi(3), one Bi(5), and one Bi(7) atom to form a mixture of distorted corner and edge-sharing OBi4 tetrahedra. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Bi(6) and one S(1) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Bi(9) and one S(1) atom. is represented by the CIF file [CIF]
data_Bi14SO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.552
_cell_length_b   10.552
_cell_length_c   8.661
_cell_angle_alpha   65.810
_cell_angle_beta   65.810
_cell_angle_gamma   109.010
_symmetry_Int_Tables_number   1
_cell_volume   645.983
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.215  0.215  0.232  1.0
  Bi  Bi1  1  0.468  0.127  0.815  1.0
  Bi  Bi2  1  0.723  0.061  0.404  1.0
  Bi  Bi3  1  0.450  0.450  0.338  1.0
  Bi  Bi4  1  0.662  0.343  0.994  1.0
  Bi  Bi5  1  0.558  0.558  0.652  1.0
  Bi  Bi6  1  0.944  0.278  0.596  1.0
  Bi  Bi7  1  0.874  0.537  0.189  1.0
  Bi  Bi8  1  0.793  0.793  0.765  1.0
  Bi  Bi9  1  0.127  0.468  0.815  1.0
  Bi  Bi10  1  0.061  0.723  0.404  1.0
  Bi  Bi11  1  0.343  0.662  0.994  1.0
  Bi  Bi12  1  0.278  0.944  0.596  1.0
  Bi  Bi13  1  0.537  0.874  0.189  1.0
  S  S14  1  0.966  0.966  0.006  1.0
  O  O15  1  0.496  0.008  0.328  1.0
  O  O16  1  0.398  0.242  0.305  1.0
  O  O17  1  0.453  0.296  0.945  1.0
  O  O18  1  0.673  0.184  0.829  1.0
  O  O19  1  0.622  0.379  0.500  1.0
  O  O20  1  0.878  0.120  0.504  1.0
  O  O21  1  0.970  0.111  0.995  1.0
  O  O22  1  0.826  0.336  0.171  1.0
  O  O23  1  0.706  0.550  0.056  1.0
  O  O24  1  0.762  0.603  0.690  1.0
  O  O25  1  0.008  0.496  0.328  1.0
  O  O26  1  0.992  0.505  0.676  1.0
  O  O27  1  0.242  0.398  0.305  1.0
  O  O28  1  0.800  0.800  0.214  1.0
  O  O29  1  0.296  0.453  0.945  1.0
  O  O30  1  0.184  0.673  0.829  1.0
  O  O31  1  0.981  0.981  0.820  1.0
  O  O32  1  0.120  0.878  0.504  1.0
  O  O33  1  0.379  0.622  0.500  1.0
  O  O34  1  0.111  0.970  0.995  1.0
  O  O35  1  0.336  0.826  0.171  1.0
  O  O36  1  0.550  0.706  0.056  1.0
  O  O37  1  0.603  0.762  0.690  1.0
  O  O38  1  0.505  0.992  0.676  1.0
[/CIF]
.