The structure described by Dy3SOF5 crystallizes in the monoclinic Pm space group. There are six inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(1), one O(2), one F(1), two equivalent F(6), and two equivalent F(9) atoms. In the second Dy site, Dy(2) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(2), one F(2), one F(7), two equivalent F(10), and two equivalent F(4) atoms. In the third Dy site, Dy(3) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(1), one F(3), one F(7), two equivalent F(5), and two equivalent F(8) atoms. In the fourth Dy site, Dy(4) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent O(2), one F(4), one F(8), one F(9), and two equivalent F(3) atoms. In the fifth Dy site, Dy(5) is bonded in a 9-coordinate geometry to two equivalent S(1), one F(10), one F(5), one F(9), two equivalent F(1), and two equivalent F(7) atoms. In the sixth Dy site, Dy(6) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent O(1), one F(10), one F(6), one F(8), and two equivalent F(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Dy(4), two equivalent Dy(5), and two equivalent Dy(6) atoms to form distorted SDy6 pentagonal pyramids that share corners with two equivalent O(1)Dy4 tetrahedra, corners with two equivalent O(2)Dy4 tetrahedra, corners with two equivalent F(7)Dy4 tetrahedra,  an edgeedge with one O(1)Dy4 tetrahedra,  an edgeedge with one O(2)Dy4 tetrahedra,  an edgeedge with one F(7)Dy4 tetrahedra, edges with two equivalent F(10)Dy4 tetrahedra, edges with two equivalent F(8)Dy4 tetrahedra, edges with two equivalent F(9)Dy4 tetrahedra, and faces with two equivalent S(1)Dy6 pentagonal pyramids. In the second S site, S(2) is bonded to two equivalent Dy(1), two equivalent Dy(2), and two equivalent Dy(3) atoms to form distorted SDy6 pentagonal pyramids that share corners with two equivalent F(10)Dy4 tetrahedra, corners with two equivalent F(8)Dy4 tetrahedra, corners with two equivalent F(9)Dy4 tetrahedra,  an edgeedge with one F(10)Dy4 tetrahedra,  an edgeedge with one F(8)Dy4 tetrahedra,  an edgeedge with one F(9)Dy4 tetrahedra, edges with two equivalent O(1)Dy4 tetrahedra, edges with two equivalent O(2)Dy4 tetrahedra, edges with two equivalent F(7)Dy4 tetrahedra, and faces with two equivalent S(2)Dy6 pentagonal pyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Dy(1), one Dy(3), and two equivalent Dy(6) atoms to form ODy4 tetrahedra that share corners with two equivalent S(1)Dy6 pentagonal pyramids,  a cornercorner with one O(2)Dy4 tetrahedra,  a cornercorner with one F(7)Dy4 tetrahedra, corners with two equivalent O(1)Dy4 tetrahedra, corners with two equivalent F(10)Dy4 tetrahedra, corners with two equivalent F(9)Dy4 tetrahedra,  an edgeedge with one S(1)Dy6 pentagonal pyramid, edges with two equivalent S(2)Dy6 pentagonal pyramids, and edges with two equivalent F(8)Dy4 tetrahedra. In the second O site, O(2) is bonded to one Dy(1), one Dy(2), and two equivalent Dy(4) atoms to form ODy4 tetrahedra that share corners with two equivalent S(1)Dy6 pentagonal pyramids,  a cornercorner with one O(1)Dy4 tetrahedra,  a cornercorner with one F(7)Dy4 tetrahedra, corners with two equivalent O(2)Dy4 tetrahedra, corners with two equivalent F(10)Dy4 tetrahedra, corners with two equivalent F(8)Dy4 tetrahedra,  an edgeedge with one S(1)Dy6 pentagonal pyramid, edges with two equivalent S(2)Dy6 pentagonal pyramids, and edges with two equivalent F(9)Dy4 tetrahedra. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a trigonal non-coplanar geometry to one Dy(1) and two equivalent Dy(5) atoms. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Dy(2) and two equivalent Dy(6) atoms. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Dy(3) and two equivalent Dy(4) atoms. In the fourth F site, F(4) is bonded in a trigonal non-coplanar geometry to one Dy(4) and two equivalent Dy(2) atoms. In the fifth F site, F(5) is bonded in a trigonal non-coplanar geometry to one Dy(5) and two equivalent Dy(3) atoms. In the sixth F site, F(6) is bonded in a trigonal non-coplanar geometry to one Dy(6) and two equivalent Dy(1) atoms. In the seventh F site, F(7) is bonded to one Dy(2), one Dy(3), and two equivalent Dy(5) atoms to form FDy4 tetrahedra that share corners with two equivalent S(1)Dy6 pentagonal pyramids,  a cornercorner with one O(1)Dy4 tetrahedra,  a cornercorner with one O(2)Dy4 tetrahedra, corners with two equivalent F(7)Dy4 tetrahedra, corners with two equivalent F(8)Dy4 tetrahedra, corners with two equivalent F(9)Dy4 tetrahedra,  an edgeedge with one S(1)Dy6 pentagonal pyramid, edges with two equivalent S(2)Dy6 pentagonal pyramids, and edges with two equivalent F(10)Dy4 tetrahedra. In the eighth F site, F(8) is bonded to one Dy(4), one Dy(6), and two equivalent Dy(3) atoms to form FDy4 tetrahedra that share corners with two equivalent S(2)Dy6 pentagonal pyramids,  a cornercorner with one F(10)Dy4 tetrahedra,  a cornercorner with one F(9)Dy4 tetrahedra, corners with two equivalent O(2)Dy4 tetrahedra, corners with two equivalent F(7)Dy4 tetrahedra, corners with two equivalent F(8)Dy4 tetrahedra,  an edgeedge with one S(2)Dy6 pentagonal pyramid, edges with two equivalent S(1)Dy6 pentagonal pyramids, and edges with two equivalent O(1)Dy4 tetrahedra. In the ninth F site, F(9) is bonded to one Dy(4), one Dy(5), and two equivalent Dy(1) atoms to form FDy4 tetrahedra that share corners with two equivalent S(2)Dy6 pentagonal pyramids,  a cornercorner with one F(10)Dy4 tetrahedra,  a cornercorner with one F(8)Dy4 tetrahedra, corners with two equivalent O(1)Dy4 tetrahedra, corners with two equivalent F(7)Dy4 tetrahedra, corners with two equivalent F(9)Dy4 tetrahedra,  an edgeedge with one S(2)Dy6 pentagonal pyramid, edges with two equivalent S(1)Dy6 pentagonal pyramids, and edges with two equivalent O(2)Dy4 tetrahedra. In the tenth F site, F(10) is bonded to one Dy(5), one Dy(6), and two equivalent Dy(2) atoms to form FDy4 tetrahedra that share corners with two equivalent S(2)Dy6 pentagonal pyramids,  a cornercorner with one F(8)Dy4 tetrahedra,  a cornercorner with one F(9)Dy4 tetrahedra, corners with two equivalent O(1)Dy4 tetrahedra, corners with two equivalent O(2)Dy4 tetrahedra, corners with two equivalent F(10)Dy4 tetrahedra,  an edgeedge with one S(2)Dy6 pentagonal pyramid, edges with two equivalent S(1)Dy6 pentagonal pyramids, and edges with two equivalent F(7)Dy4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy3SOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.671
_cell_length_b   9.390
_cell_length_c   9.451
_cell_angle_alpha   60.451
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   283.376
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.583  0.134  1.0
  Dy  Dy1  1  0.000  0.133  0.271  1.0
  Dy  Dy2  1  0.000  0.299  0.586  1.0
  Dy  Dy3  1  0.500  0.405  0.897  1.0
  Dy  Dy4  1  0.500  0.876  0.715  1.0
  Dy  Dy5  1  0.500  0.704  0.402  1.0
  S  S6  1  0.000  0.671  0.667  1.0
  S  S7  1  0.500  0.326  0.339  1.0
  O  O8  1  0.000  0.564  0.387  1.0
  O  O9  1  0.000  0.384  0.052  1.0
  F  F10  1  0.000  0.841  0.880  1.0
  F  F11  1  0.000  0.888  0.273  1.0
  F  F12  1  0.000  0.275  0.837  1.0
  F  F13  1  0.500  0.145  0.117  1.0
  F  F14  1  0.500  0.122  0.714  1.0
  F  F15  1  0.500  0.728  0.149  1.0
  F  F16  1  0.000  0.048  0.567  1.0
  F  F17  1  0.500  0.431  0.626  1.0
  F  F18  1  0.500  0.622  0.953  1.0
  F  F19  1  0.500  0.956  0.433  1.0
[/CIF]
.
The structure described by Dy3SOF5 crystallizes in the monoclinic Pm space group. There are six inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(1), one O(2), one F(1), two equivalent F(6), and two equivalent F(9) atoms. In the second Dy site, Dy(2) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(2), one F(2), one F(7), two equivalent F(10), and two equivalent F(4) atoms. In the third Dy site, Dy(3) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(1), one F(3), one F(7), two equivalent F(5), and two equivalent F(8) atoms. In the fourth Dy site, Dy(4) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent O(2), one F(4), one F(8), one F(9), and two equivalent F(3) atoms. In the fifth Dy site, Dy(5) is bonded in a 9-coordinate geometry to two equivalent S(1), one F(10), one F(5), one F(9), two equivalent F(1), and two equivalent F(7) atoms. In the sixth Dy site, Dy(6) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent O(1), one F(10), one F(6), one F(8), and two equivalent F(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Dy(4), two equivalent Dy(5), and two equivalent Dy(6) atoms to form distorted SDy6 pentagonal pyramids that share corners with two equivalent O(1)Dy4 tetrahedra, corners with two equivalent O(2)Dy4 tetrahedra, corners with two equivalent F(7)Dy4 tetrahedra,  an edgeedge with one O(1)Dy4 tetrahedra,  an edgeedge with one O(2)Dy4 tetrahedra,  an edgeedge with one F(7)Dy4 tetrahedra, edges with two equivalent F(10)Dy4 tetrahedra, edges with two equivalent F(8)Dy4 tetrahedra, edges with two equivalent F(9)Dy4 tetrahedra, and faces with two equivalent S(1)Dy6 pentagonal pyramids. In the second S site, S(2) is bonded to two equivalent Dy(1), two equivalent Dy(2), and two equivalent Dy(3) atoms to form distorted SDy6 pentagonal pyramids that share corners with two equivalent F(10)Dy4 tetrahedra, corners with two equivalent F(8)Dy4 tetrahedra, corners with two equivalent F(9)Dy4 tetrahedra,  an edgeedge with one F(10)Dy4 tetrahedra,  an edgeedge with one F(8)Dy4 tetrahedra,  an edgeedge with one F(9)Dy4 tetrahedra, edges with two equivalent O(1)Dy4 tetrahedra, edges with two equivalent O(2)Dy4 tetrahedra, edges with two equivalent F(7)Dy4 tetrahedra, and faces with two equivalent S(2)Dy6 pentagonal pyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Dy(1), one Dy(3), and two equivalent Dy(6) atoms to form ODy4 tetrahedra that share corners with two equivalent S(1)Dy6 pentagonal pyramids,  a cornercorner with one O(2)Dy4 tetrahedra,  a cornercorner with one F(7)Dy4 tetrahedra, corners with two equivalent O(1)Dy4 tetrahedra, corners with two equivalent F(10)Dy4 tetrahedra, corners with two equivalent F(9)Dy4 tetrahedra,  an edgeedge with one S(1)Dy6 pentagonal pyramid, edges with two equivalent S(2)Dy6 pentagonal pyramids, and edges with two equivalent F(8)Dy4 tetrahedra. In the second O site, O(2) is bonded to one Dy(1), one Dy(2), and two equivalent Dy(4) atoms to form ODy4 tetrahedra that share corners with two equivalent S(1)Dy6 pentagonal pyramids,  a cornercorner with one O(1)Dy4 tetrahedra,  a cornercorner with one F(7)Dy4 tetrahedra, corners with two equivalent O(2)Dy4 tetrahedra, corners with two equivalent F(10)Dy4 tetrahedra, corners with two equivalent F(8)Dy4 tetrahedra,  an edgeedge with one S(1)Dy6 pentagonal pyramid, edges with two equivalent S(2)Dy6 pentagonal pyramids, and edges with two equivalent F(9)Dy4 tetrahedra. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a trigonal non-coplanar geometry to one Dy(1) and two equivalent Dy(5) atoms. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Dy(2) and two equivalent Dy(6) atoms. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Dy(3) and two equivalent Dy(4) atoms. In the fourth F site, F(4) is bonded in a trigonal non-coplanar geometry to one Dy(4) and two equivalent Dy(2) atoms. In the fifth F site, F(5) is bonded in a trigonal non-coplanar geometry to one Dy(5) and two equivalent Dy(3) atoms. In the sixth F site, F(6) is bonded in a trigonal non-coplanar geometry to one Dy(6) and two equivalent Dy(1) atoms. In the seventh F site, F(7) is bonded to one Dy(2), one Dy(3), and two equivalent Dy(5) atoms to form FDy4 tetrahedra that share corners with two equivalent S(1)Dy6 pentagonal pyramids,  a cornercorner with one O(1)Dy4 tetrahedra,  a cornercorner with one O(2)Dy4 tetrahedra, corners with two equivalent F(7)Dy4 tetrahedra, corners with two equivalent F(8)Dy4 tetrahedra, corners with two equivalent F(9)Dy4 tetrahedra,  an edgeedge with one S(1)Dy6 pentagonal pyramid, edges with two equivalent S(2)Dy6 pentagonal pyramids, and edges with two equivalent F(10)Dy4 tetrahedra. In the eighth F site, F(8) is bonded to one Dy(4), one Dy(6), and two equivalent Dy(3) atoms to form FDy4 tetrahedra that share corners with two equivalent S(2)Dy6 pentagonal pyramids,  a cornercorner with one F(10)Dy4 tetrahedra,  a cornercorner with one F(9)Dy4 tetrahedra, corners with two equivalent O(2)Dy4 tetrahedra, corners with two equivalent F(7)Dy4 tetrahedra, corners with two equivalent F(8)Dy4 tetrahedra,  an edgeedge with one S(2)Dy6 pentagonal pyramid, edges with two equivalent S(1)Dy6 pentagonal pyramids, and edges with two equivalent O(1)Dy4 tetrahedra. In the ninth F site, F(9) is bonded to one Dy(4), one Dy(5), and two equivalent Dy(1) atoms to form FDy4 tetrahedra that share corners with two equivalent S(2)Dy6 pentagonal pyramids,  a cornercorner with one F(10)Dy4 tetrahedra,  a cornercorner with one F(8)Dy4 tetrahedra, corners with two equivalent O(1)Dy4 tetrahedra, corners with two equivalent F(7)Dy4 tetrahedra, corners with two equivalent F(9)Dy4 tetrahedra,  an edgeedge with one S(2)Dy6 pentagonal pyramid, edges with two equivalent S(1)Dy6 pentagonal pyramids, and edges with two equivalent O(2)Dy4 tetrahedra. In the tenth F site, F(10) is bonded to one Dy(5), one Dy(6), and two equivalent Dy(2) atoms to form FDy4 tetrahedra that share corners with two equivalent S(2)Dy6 pentagonal pyramids,  a cornercorner with one F(8)Dy4 tetrahedra,  a cornercorner with one F(9)Dy4 tetrahedra, corners with two equivalent O(1)Dy4 tetrahedra, corners with two equivalent O(2)Dy4 tetrahedra, corners with two equivalent F(10)Dy4 tetrahedra,  an edgeedge with one S(2)Dy6 pentagonal pyramid, edges with two equivalent S(1)Dy6 pentagonal pyramids, and edges with two equivalent F(7)Dy4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy3SOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.671
_cell_length_b   9.390
_cell_length_c   9.451
_cell_angle_alpha   60.451
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   283.376
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.583  0.134  1.0
  Dy  Dy1  1  0.000  0.133  0.271  1.0
  Dy  Dy2  1  0.000  0.299  0.586  1.0
  Dy  Dy3  1  0.500  0.405  0.897  1.0
  Dy  Dy4  1  0.500  0.876  0.715  1.0
  Dy  Dy5  1  0.500  0.704  0.402  1.0
  S  S6  1  0.000  0.671  0.667  1.0
  S  S7  1  0.500  0.326  0.339  1.0
  O  O8  1  0.000  0.564  0.387  1.0
  O  O9  1  0.000  0.384  0.052  1.0
  F  F10  1  0.000  0.841  0.880  1.0
  F  F11  1  0.000  0.888  0.273  1.0
  F  F12  1  0.000  0.275  0.837  1.0
  F  F13  1  0.500  0.145  0.117  1.0
  F  F14  1  0.500  0.122  0.714  1.0
  F  F15  1  0.500  0.728  0.149  1.0
  F  F16  1  0.000  0.048  0.567  1.0
  F  F17  1  0.500  0.431  0.626  1.0
  F  F18  1  0.500  0.622  0.953  1.0
  F  F19  1  0.500  0.956  0.433  1.0
[/CIF]
.