The crystal structure described by BF4C4NH11Br is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trimethylchloromethylammonium bromate molecules and two BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(3), and two equivalent F(2) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. is represented by the CIF file [CIF]
data_BH11C4BrNF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.908
_cell_length_b   6.084
_cell_length_c   9.621
_cell_angle_alpha   75.999
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   449.169
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.250  0.943  0.764  1.0
  B  B1  1  0.750  0.057  0.236  1.0
  H  H2  1  0.750  0.641  0.963  1.0
  H  H3  1  0.983  0.508  0.209  1.0
  H  H4  1  0.864  0.817  0.816  1.0
  H  H5  1  0.911  0.252  0.754  1.0
  H  H6  1  0.250  0.359  0.037  1.0
  H  H7  1  0.103  0.695  0.070  1.0
  H  H8  1  0.517  0.508  0.209  1.0
  H  H9  1  0.865  0.738  0.588  1.0
  H  H10  1  0.411  0.748  0.246  1.0
  H  H11  1  0.089  0.748  0.246  1.0
  H  H12  1  0.135  0.262  0.412  1.0
  H  H13  1  0.603  0.305  0.930  1.0
  H  H14  1  0.483  0.492  0.791  1.0
  H  H15  1  0.364  0.183  0.184  1.0
  H  H16  1  0.136  0.183  0.184  1.0
  H  H17  1  0.897  0.305  0.930  1.0
  H  H18  1  0.636  0.817  0.816  1.0
  H  H19  1  0.365  0.262  0.412  1.0
  H  H20  1  0.635  0.738  0.588  1.0
  H  H21  1  0.017  0.492  0.791  1.0
  H  H22  1  0.397  0.695  0.070  1.0
  H  H23  1  0.589  0.252  0.754  1.0
  C  C24  1  0.406  0.617  0.185  1.0
  C  C25  1  0.750  0.715  0.848  1.0
  C  C26  1  0.750  0.636  0.613  1.0
  C  C27  1  0.906  0.383  0.815  1.0
  C  C28  1  0.250  0.285  0.152  1.0
  C  C29  1  0.094  0.617  0.185  1.0
  C  C30  1  0.594  0.383  0.815  1.0
  C  C31  1  0.250  0.364  0.387  1.0
  Br  Br32  1  0.750  0.420  0.495  1.0
  Br  Br33  1  0.250  0.580  0.505  1.0
  N  N34  1  0.250  0.476  0.228  1.0
  N  N35  1  0.750  0.524  0.772  1.0
  F  F36  1  0.250  0.083  0.862  1.0
  F  F37  1  0.397  0.983  0.677  1.0
  F  F38  1  0.250  0.710  0.843  1.0
  F  F39  1  0.750  0.290  0.157  1.0
  F  F40  1  0.750  0.917  0.138  1.0
  F  F41  1  0.603  0.017  0.323  1.0
  F  F42  1  0.897  0.017  0.323  1.0
  F  F43  1  0.103  0.983  0.677  1.0
[/CIF]
.
The crystal structure described by BF4C4NH11Br is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trimethylchloromethylammonium bromate molecules and two BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(3), and two equivalent F(2) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. is represented by the CIF file [CIF]
data_BH11C4BrNF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.908
_cell_length_b   6.084
_cell_length_c   9.621
_cell_angle_alpha   75.999
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   449.169
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.250  0.943  0.764  1.0
  B  B1  1  0.750  0.057  0.236  1.0
  H  H2  1  0.750  0.641  0.963  1.0
  H  H3  1  0.983  0.508  0.209  1.0
  H  H4  1  0.864  0.817  0.816  1.0
  H  H5  1  0.911  0.252  0.754  1.0
  H  H6  1  0.250  0.359  0.037  1.0
  H  H7  1  0.103  0.695  0.070  1.0
  H  H8  1  0.517  0.508  0.209  1.0
  H  H9  1  0.865  0.738  0.588  1.0
  H  H10  1  0.411  0.748  0.246  1.0
  H  H11  1  0.089  0.748  0.246  1.0
  H  H12  1  0.135  0.262  0.412  1.0
  H  H13  1  0.603  0.305  0.930  1.0
  H  H14  1  0.483  0.492  0.791  1.0
  H  H15  1  0.364  0.183  0.184  1.0
  H  H16  1  0.136  0.183  0.184  1.0
  H  H17  1  0.897  0.305  0.930  1.0
  H  H18  1  0.636  0.817  0.816  1.0
  H  H19  1  0.365  0.262  0.412  1.0
  H  H20  1  0.635  0.738  0.588  1.0
  H  H21  1  0.017  0.492  0.791  1.0
  H  H22  1  0.397  0.695  0.070  1.0
  H  H23  1  0.589  0.252  0.754  1.0
  C  C24  1  0.406  0.617  0.185  1.0
  C  C25  1  0.750  0.715  0.848  1.0
  C  C26  1  0.750  0.636  0.613  1.0
  C  C27  1  0.906  0.383  0.815  1.0
  C  C28  1  0.250  0.285  0.152  1.0
  C  C29  1  0.094  0.617  0.185  1.0
  C  C30  1  0.594  0.383  0.815  1.0
  C  C31  1  0.250  0.364  0.387  1.0
  Br  Br32  1  0.750  0.420  0.495  1.0
  Br  Br33  1  0.250  0.580  0.505  1.0
  N  N34  1  0.250  0.476  0.228  1.0
  N  N35  1  0.750  0.524  0.772  1.0
  F  F36  1  0.250  0.083  0.862  1.0
  F  F37  1  0.397  0.983  0.677  1.0
  F  F38  1  0.250  0.710  0.843  1.0
  F  F39  1  0.750  0.290  0.157  1.0
  F  F40  1  0.750  0.917  0.138  1.0
  F  F41  1  0.603  0.017  0.323  1.0
  F  F42  1  0.897  0.017  0.323  1.0
  F  F43  1  0.103  0.983  0.677  1.0
[/CIF]
.