The material described by AsF6FN2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of ten 2-fluorohydrazine molecules and ten AsF6 clusters. In each AsF6 cluster, As(1,2,3,4,5) is bonded in an octahedral geometry to two equivalent F(1,4,6,9) and four equivalent F(2,3,7,8) atoms. There are two inequivalent F sites. In the first F site, F(1,4,6,9) is bonded in a single-bond geometry to one As(1,2,3,4,5) atom. In the second F site, F(2,3,7,8) is bonded in a single-bond geometry to one As(1,2,3,4,5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsN2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.338
_cell_length_b   5.338
_cell_length_c   26.266
_cell_angle_alpha   89.371
_cell_angle_beta   89.371
_cell_angle_gamma   65.943
_symmetry_Int_Tables_number   1
_cell_volume   683.333
_cell_formula_units_Z   5
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  1.000  1.000  0.900  1.0
  As  As1  1  1.000  1.000  0.700  1.0
  As  As2  1  1.000  1.000  0.500  1.0
  As  As3  1  1.000  1.000  0.300  1.0
  As  As4  1  1.000  1.000  0.100  1.0
  N  N5  1  0.624  0.624  0.985  1.0
  N  N6  1  0.376  0.376  0.815  1.0
  N  N7  1  0.495  0.495  0.802  1.0
  N  N8  1  0.505  0.505  0.599  1.0
  N  N9  1  0.624  0.624  0.585  1.0
  N  N10  1  0.505  0.505  0.399  1.0
  N  N11  1  0.624  0.624  0.385  1.0
  N  N12  1  0.505  0.505  0.199  1.0
  N  N13  1  0.624  0.624  0.185  1.0
  N  N14  1  0.505  0.505  0.999  1.0
  F  F15  1  0.132  0.132  0.950  1.0
  F  F16  1  0.679  0.114  0.933  1.0
  F  F17  1  0.114  0.679  0.933  1.0
  F  F18  1  0.886  0.321  0.867  1.0
  F  F19  1  0.321  0.886  0.867  1.0
  F  F20  1  0.868  0.868  0.850  1.0
  F  F21  1  0.627  0.627  0.785  1.0
  F  F22  1  0.132  0.132  0.750  1.0
  F  F23  1  0.679  0.114  0.733  1.0
  F  F24  1  0.114  0.679  0.733  1.0
  F  F25  1  0.886  0.321  0.667  1.0
  F  F26  1  0.321  0.886  0.667  1.0
  F  F27  1  0.868  0.868  0.650  1.0
  F  F28  1  0.373  0.373  0.615  1.0
  F  F29  1  0.132  0.132  0.550  1.0
  F  F30  1  0.678  0.114  0.533  1.0
  F  F31  1  0.114  0.678  0.533  1.0
  F  F32  1  0.886  0.320  0.467  1.0
  F  F33  1  0.320  0.886  0.467  1.0
  F  F34  1  0.868  0.868  0.450  1.0
  F  F35  1  0.373  0.373  0.415  1.0
  F  F36  1  0.132  0.132  0.350  1.0
  F  F37  1  0.678  0.114  0.333  1.0
  F  F38  1  0.114  0.678  0.333  1.0
  F  F39  1  0.886  0.320  0.267  1.0
  F  F40  1  0.320  0.886  0.267  1.0
  F  F41  1  0.868  0.868  0.250  1.0
  F  F42  1  0.373  0.373  0.215  1.0
  F  F43  1  0.132  0.132  0.150  1.0
  F  F44  1  0.678  0.114  0.133  1.0
  F  F45  1  0.114  0.678  0.133  1.0
  F  F46  1  0.886  0.320  0.067  1.0
  F  F47  1  0.320  0.886  0.067  1.0
  F  F48  1  0.868  0.868  0.050  1.0
  F  F49  1  0.373  0.373  0.015  1.0
[/CIF]
.
The material described by AsF6FN2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of ten 2-fluorohydrazine molecules and ten AsF6 clusters. In each AsF6 cluster, As(1,2,3,4,5) is bonded in an octahedral geometry to two equivalent F(1,4,6,9) and four equivalent F(2,3,7,8) atoms. There are two inequivalent F sites. In the first F site, F(1,4,6,9) is bonded in a single-bond geometry to one As(1,2,3,4,5) atom. In the second F site, F(2,3,7,8) is bonded in a single-bond geometry to one As(1,2,3,4,5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsN2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.338
_cell_length_b   5.338
_cell_length_c   26.266
_cell_angle_alpha   89.371
_cell_angle_beta   89.371
_cell_angle_gamma   65.943
_symmetry_Int_Tables_number   1
_cell_volume   683.333
_cell_formula_units_Z   5
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  1.000  1.000  0.900  1.0
  As  As1  1  1.000  1.000  0.700  1.0
  As  As2  1  1.000  1.000  0.500  1.0
  As  As3  1  1.000  1.000  0.300  1.0
  As  As4  1  1.000  1.000  0.100  1.0
  N  N5  1  0.624  0.624  0.985  1.0
  N  N6  1  0.376  0.376  0.815  1.0
  N  N7  1  0.495  0.495  0.802  1.0
  N  N8  1  0.505  0.505  0.599  1.0
  N  N9  1  0.624  0.624  0.585  1.0
  N  N10  1  0.505  0.505  0.399  1.0
  N  N11  1  0.624  0.624  0.385  1.0
  N  N12  1  0.505  0.505  0.199  1.0
  N  N13  1  0.624  0.624  0.185  1.0
  N  N14  1  0.505  0.505  0.999  1.0
  F  F15  1  0.132  0.132  0.950  1.0
  F  F16  1  0.679  0.114  0.933  1.0
  F  F17  1  0.114  0.679  0.933  1.0
  F  F18  1  0.886  0.321  0.867  1.0
  F  F19  1  0.321  0.886  0.867  1.0
  F  F20  1  0.868  0.868  0.850  1.0
  F  F21  1  0.627  0.627  0.785  1.0
  F  F22  1  0.132  0.132  0.750  1.0
  F  F23  1  0.679  0.114  0.733  1.0
  F  F24  1  0.114  0.679  0.733  1.0
  F  F25  1  0.886  0.321  0.667  1.0
  F  F26  1  0.321  0.886  0.667  1.0
  F  F27  1  0.868  0.868  0.650  1.0
  F  F28  1  0.373  0.373  0.615  1.0
  F  F29  1  0.132  0.132  0.550  1.0
  F  F30  1  0.678  0.114  0.533  1.0
  F  F31  1  0.114  0.678  0.533  1.0
  F  F32  1  0.886  0.320  0.467  1.0
  F  F33  1  0.320  0.886  0.467  1.0
  F  F34  1  0.868  0.868  0.450  1.0
  F  F35  1  0.373  0.373  0.415  1.0
  F  F36  1  0.132  0.132  0.350  1.0
  F  F37  1  0.678  0.114  0.333  1.0
  F  F38  1  0.114  0.678  0.333  1.0
  F  F39  1  0.886  0.320  0.267  1.0
  F  F40  1  0.320  0.886  0.267  1.0
  F  F41  1  0.868  0.868  0.250  1.0
  F  F42  1  0.373  0.373  0.215  1.0
  F  F43  1  0.132  0.132  0.150  1.0
  F  F44  1  0.678  0.114  0.133  1.0
  F  F45  1  0.114  0.678  0.133  1.0
  F  F46  1  0.886  0.320  0.067  1.0
  F  F47  1  0.320  0.886  0.067  1.0
  F  F48  1  0.868  0.868  0.050  1.0
  F  F49  1  0.373  0.373  0.015  1.0
[/CIF]
.