The compound described by Ce2W4S3O14 crystallizes in the monoclinic C2/c space group. Ce(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and two equivalent O(7) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to one O(5), one O(6), and one O(7) atom. In the second W site, W(2) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(5) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ce(1), one W(2), and one S(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ce(1), one W(2), and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(2) atom. In the fourth O site, O(7) is bonded in a trigonal non-coplanar geometry to two equivalent Ce(1) and one W(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(1) and one S(2) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Ce(1), one W(1), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce2W4S3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.791
_cell_length_b   8.791
_cell_length_c   13.594
_cell_angle_alpha   82.902
_cell_angle_beta   82.902
_cell_angle_gamma   48.373
_symmetry_Int_Tables_number   1
_cell_volume   777.976
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.607  0.583  0.052  1.0
  Ce  Ce1  1  0.393  0.417  0.948  1.0
  Ce  Ce2  1  0.417  0.393  0.448  1.0
  Ce  Ce3  1  0.583  0.607  0.552  1.0
  W  W4  1  0.734  0.146  0.167  1.0
  W  W5  1  0.266  0.854  0.833  1.0
  W  W6  1  0.854  0.266  0.333  1.0
  W  W7  1  0.146  0.734  0.667  1.0
  W  W8  1  0.266  0.216  0.246  1.0
  W  W9  1  0.734  0.784  0.754  1.0
  W  W10  1  0.784  0.734  0.254  1.0
  W  W11  1  0.216  0.266  0.746  1.0
  S  S12  1  0.188  0.185  0.002  1.0
  S  S13  1  0.812  0.815  0.998  1.0
  S  S14  1  0.815  0.812  0.498  1.0
  S  S15  1  0.185  0.188  0.502  1.0
  S  S16  1  0.212  0.788  0.250  1.0
  S  S17  1  0.788  0.212  0.750  1.0
  O  O18  1  0.275  0.225  0.409  1.0
  O  O19  1  0.725  0.775  0.591  1.0
  O  O20  1  0.775  0.725  0.091  1.0
  O  O21  1  0.225  0.275  0.909  1.0
  O  O22  1  0.273  0.212  0.081  1.0
  O  O23  1  0.727  0.788  0.919  1.0
  O  O24  1  0.788  0.727  0.419  1.0
  O  O25  1  0.212  0.273  0.581  1.0
  O  O26  1  0.397  0.741  0.198  1.0
  O  O27  1  0.603  0.259  0.802  1.0
  O  O28  1  0.259  0.603  0.302  1.0
  O  O29  1  0.741  0.397  0.698  1.0
  O  O30  1  0.298  0.970  0.520  1.0
  O  O31  1  0.702  0.030  0.480  1.0
  O  O32  1  0.030  0.702  0.980  1.0
  O  O33  1  0.970  0.298  0.020  1.0
  O  O34  1  0.132  0.941  0.324  1.0
  O  O35  1  0.868  0.059  0.676  1.0
  O  O36  1  0.059  0.868  0.176  1.0
  O  O37  1  0.941  0.132  0.824  1.0
  O  O38  1  0.301  0.968  0.989  1.0
  O  O39  1  0.699  0.032  0.011  1.0
  O  O40  1  0.032  0.699  0.511  1.0
  O  O41  1  0.968  0.301  0.489  1.0
  O  O42  1  0.589  0.503  0.413  1.0
  O  O43  1  0.411  0.497  0.587  1.0
  O  O44  1  0.497  0.411  0.087  1.0
  O  O45  1  0.503  0.589  0.913  1.0
[/CIF]
.
The compound described by Ce2W4S3O14 crystallizes in the monoclinic C2/c space group. Ce(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and two equivalent O(7) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to one O(5), one O(6), and one O(7) atom. In the second W site, W(2) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(5) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ce(1), one W(2), and one S(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ce(1), one W(2), and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(2) atom. In the fourth O site, O(7) is bonded in a trigonal non-coplanar geometry to two equivalent Ce(1) and one W(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(1) and one S(2) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Ce(1), one W(1), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce2W4S3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.791
_cell_length_b   8.791
_cell_length_c   13.594
_cell_angle_alpha   82.902
_cell_angle_beta   82.902
_cell_angle_gamma   48.373
_symmetry_Int_Tables_number   1
_cell_volume   777.976
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.607  0.583  0.052  1.0
  Ce  Ce1  1  0.393  0.417  0.948  1.0
  Ce  Ce2  1  0.417  0.393  0.448  1.0
  Ce  Ce3  1  0.583  0.607  0.552  1.0
  W  W4  1  0.734  0.146  0.167  1.0
  W  W5  1  0.266  0.854  0.833  1.0
  W  W6  1  0.854  0.266  0.333  1.0
  W  W7  1  0.146  0.734  0.667  1.0
  W  W8  1  0.266  0.216  0.246  1.0
  W  W9  1  0.734  0.784  0.754  1.0
  W  W10  1  0.784  0.734  0.254  1.0
  W  W11  1  0.216  0.266  0.746  1.0
  S  S12  1  0.188  0.185  0.002  1.0
  S  S13  1  0.812  0.815  0.998  1.0
  S  S14  1  0.815  0.812  0.498  1.0
  S  S15  1  0.185  0.188  0.502  1.0
  S  S16  1  0.212  0.788  0.250  1.0
  S  S17  1  0.788  0.212  0.750  1.0
  O  O18  1  0.275  0.225  0.409  1.0
  O  O19  1  0.725  0.775  0.591  1.0
  O  O20  1  0.775  0.725  0.091  1.0
  O  O21  1  0.225  0.275  0.909  1.0
  O  O22  1  0.273  0.212  0.081  1.0
  O  O23  1  0.727  0.788  0.919  1.0
  O  O24  1  0.788  0.727  0.419  1.0
  O  O25  1  0.212  0.273  0.581  1.0
  O  O26  1  0.397  0.741  0.198  1.0
  O  O27  1  0.603  0.259  0.802  1.0
  O  O28  1  0.259  0.603  0.302  1.0
  O  O29  1  0.741  0.397  0.698  1.0
  O  O30  1  0.298  0.970  0.520  1.0
  O  O31  1  0.702  0.030  0.480  1.0
  O  O32  1  0.030  0.702  0.980  1.0
  O  O33  1  0.970  0.298  0.020  1.0
  O  O34  1  0.132  0.941  0.324  1.0
  O  O35  1  0.868  0.059  0.676  1.0
  O  O36  1  0.059  0.868  0.176  1.0
  O  O37  1  0.941  0.132  0.824  1.0
  O  O38  1  0.301  0.968  0.989  1.0
  O  O39  1  0.699  0.032  0.011  1.0
  O  O40  1  0.032  0.699  0.511  1.0
  O  O41  1  0.968  0.301  0.489  1.0
  O  O42  1  0.589  0.503  0.413  1.0
  O  O43  1  0.411  0.497  0.587  1.0
  O  O44  1  0.497  0.411  0.087  1.0
  O  O45  1  0.503  0.589  0.913  1.0
[/CIF]
.