The crystal structure described by Na4RuN6O13 crystallizes in the monoclinic C2/c space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form distorted NaO6 pentagonal pyramids that share corners with two equivalent Na(2)O7 pentagonal bipyramids,  a cornercorner with one Na(1)O6 pentagonal pyramid, and edges with two equivalent Na(2)O7 pentagonal bipyramids. In the second Na site, Na(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and two equivalent O(6) atoms to form distorted NaO7 pentagonal bipyramids that share corners with two equivalent Na(1)O6 pentagonal pyramids,  an edgeedge with one Na(2)O7 pentagonal bipyramid, and edges with two equivalent Na(1)O6 pentagonal pyramids. Ru(1) is bonded to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms to form RuN6 octahedra that share corners with two equivalent O(6)Na3N trigonal pyramids. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ru(1), one O(2), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one O(4), and one O(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ru(1), one O(1), and one O(3) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted trigonal planar geometry to one Na(1), one Na(2), and one N(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Na(2) and one N(3) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to two equivalent Na(1) atoms. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(1) atom. In the fifth O site, O(3) is bonded in a distorted trigonal planar geometry to one Na(1), one Na(2), and one N(3) atom. In the sixth O site, O(4) is bonded in a trigonal planar geometry to one Na(1), one Na(2), and one N(2) atom. In the seventh O site, O(6) is bonded to one Na(1), two equivalent Na(2), and one N(1) atom to form distorted ONa3N trigonal pyramids that share  a cornercorner with one Ru(1)N6 octahedra and  an edgeedge with one O(6)Na3N trigonal pyramid. The corner-sharing octahedral tilt angles are 59°. is represented by the CIF card [CIF]
data_Na4RuN6O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.594
_cell_length_b   7.594
_cell_length_c   12.248
_cell_angle_alpha   87.626
_cell_angle_beta   87.626
_cell_angle_gamma   116.609
_symmetry_Int_Tables_number   1
_cell_volume   629.641
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.326  0.161  0.693  1.0
  Na  Na1  1  0.674  0.839  0.307  1.0
  Na  Na2  1  0.839  0.674  0.807  1.0
  Na  Na3  1  0.161  0.326  0.193  1.0
  Na  Na4  1  0.531  0.782  0.621  1.0
  Na  Na5  1  0.469  0.218  0.379  1.0
  Na  Na6  1  0.218  0.469  0.879  1.0
  Na  Na7  1  0.782  0.531  0.121  1.0
  Ru  Ru8  1  0.500  0.000  0.000  1.0
  Ru  Ru9  1  0.000  0.500  0.500  1.0
  N  N10  1  0.545  0.924  0.842  1.0
  N  N11  1  0.455  0.076  0.158  1.0
  N  N12  1  0.076  0.455  0.658  1.0
  N  N13  1  0.924  0.545  0.342  1.0
  N  N14  1  0.512  0.261  0.932  1.0
  N  N15  1  0.488  0.739  0.068  1.0
  N  N16  1  0.739  0.488  0.568  1.0
  N  N17  1  0.261  0.512  0.432  1.0
  N  N18  1  0.805  0.151  0.015  1.0
  N  N19  1  0.195  0.849  0.985  1.0
  N  N20  1  0.849  0.195  0.485  1.0
  N  N21  1  0.151  0.805  0.515  1.0
  O  O22  1  0.847  0.069  0.555  1.0
  O  O23  1  0.153  0.931  0.445  1.0
  O  O24  1  0.931  0.153  0.945  1.0
  O  O25  1  0.069  0.847  0.055  1.0
  O  O26  1  0.559  0.031  0.758  1.0
  O  O27  1  0.441  0.969  0.242  1.0
  O  O28  1  0.969  0.441  0.742  1.0
  O  O29  1  0.031  0.559  0.258  1.0
  O  O30  1  0.253  0.868  0.598  1.0
  O  O31  1  0.747  0.132  0.402  1.0
  O  O32  1  0.132  0.747  0.902  1.0
  O  O33  1  0.868  0.253  0.098  1.0
  O  O34  1  0.574  0.344  0.555  1.0
  O  O35  1  0.426  0.656  0.445  1.0
  O  O36  1  0.656  0.426  0.945  1.0
  O  O37  1  0.344  0.574  0.055  1.0
  O  O38  1  0.989  0.011  0.750  1.0
  O  O39  1  0.011  0.989  0.250  1.0
  O  O40  1  0.550  0.762  0.827  1.0
  O  O41  1  0.450  0.238  0.173  1.0
  O  O42  1  0.238  0.450  0.673  1.0
  O  O43  1  0.762  0.550  0.327  1.0
  O  O44  1  0.378  0.260  0.875  1.0
  O  O45  1  0.622  0.740  0.125  1.0
  O  O46  1  0.740  0.622  0.625  1.0
  O  O47  1  0.260  0.378  0.375  1.0
[/CIF]
.
The crystal structure described by Na4RuN6O13 crystallizes in the monoclinic C2/c space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form distorted NaO6 pentagonal pyramids that share corners with two equivalent Na(2)O7 pentagonal bipyramids,  a cornercorner with one Na(1)O6 pentagonal pyramid, and edges with two equivalent Na(2)O7 pentagonal bipyramids. In the second Na site, Na(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and two equivalent O(6) atoms to form distorted NaO7 pentagonal bipyramids that share corners with two equivalent Na(1)O6 pentagonal pyramids,  an edgeedge with one Na(2)O7 pentagonal bipyramid, and edges with two equivalent Na(1)O6 pentagonal pyramids. Ru(1) is bonded to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms to form RuN6 octahedra that share corners with two equivalent O(6)Na3N trigonal pyramids. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ru(1), one O(2), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one O(4), and one O(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ru(1), one O(1), and one O(3) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted trigonal planar geometry to one Na(1), one Na(2), and one N(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Na(2) and one N(3) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to two equivalent Na(1) atoms. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(1) atom. In the fifth O site, O(3) is bonded in a distorted trigonal planar geometry to one Na(1), one Na(2), and one N(3) atom. In the sixth O site, O(4) is bonded in a trigonal planar geometry to one Na(1), one Na(2), and one N(2) atom. In the seventh O site, O(6) is bonded to one Na(1), two equivalent Na(2), and one N(1) atom to form distorted ONa3N trigonal pyramids that share  a cornercorner with one Ru(1)N6 octahedra and  an edgeedge with one O(6)Na3N trigonal pyramid. The corner-sharing octahedral tilt angles are 59°. is represented by the CIF card [CIF]
data_Na4RuN6O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.594
_cell_length_b   7.594
_cell_length_c   12.248
_cell_angle_alpha   87.626
_cell_angle_beta   87.626
_cell_angle_gamma   116.609
_symmetry_Int_Tables_number   1
_cell_volume   629.641
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.326  0.161  0.693  1.0
  Na  Na1  1  0.674  0.839  0.307  1.0
  Na  Na2  1  0.839  0.674  0.807  1.0
  Na  Na3  1  0.161  0.326  0.193  1.0
  Na  Na4  1  0.531  0.782  0.621  1.0
  Na  Na5  1  0.469  0.218  0.379  1.0
  Na  Na6  1  0.218  0.469  0.879  1.0
  Na  Na7  1  0.782  0.531  0.121  1.0
  Ru  Ru8  1  0.500  0.000  0.000  1.0
  Ru  Ru9  1  0.000  0.500  0.500  1.0
  N  N10  1  0.545  0.924  0.842  1.0
  N  N11  1  0.455  0.076  0.158  1.0
  N  N12  1  0.076  0.455  0.658  1.0
  N  N13  1  0.924  0.545  0.342  1.0
  N  N14  1  0.512  0.261  0.932  1.0
  N  N15  1  0.488  0.739  0.068  1.0
  N  N16  1  0.739  0.488  0.568  1.0
  N  N17  1  0.261  0.512  0.432  1.0
  N  N18  1  0.805  0.151  0.015  1.0
  N  N19  1  0.195  0.849  0.985  1.0
  N  N20  1  0.849  0.195  0.485  1.0
  N  N21  1  0.151  0.805  0.515  1.0
  O  O22  1  0.847  0.069  0.555  1.0
  O  O23  1  0.153  0.931  0.445  1.0
  O  O24  1  0.931  0.153  0.945  1.0
  O  O25  1  0.069  0.847  0.055  1.0
  O  O26  1  0.559  0.031  0.758  1.0
  O  O27  1  0.441  0.969  0.242  1.0
  O  O28  1  0.969  0.441  0.742  1.0
  O  O29  1  0.031  0.559  0.258  1.0
  O  O30  1  0.253  0.868  0.598  1.0
  O  O31  1  0.747  0.132  0.402  1.0
  O  O32  1  0.132  0.747  0.902  1.0
  O  O33  1  0.868  0.253  0.098  1.0
  O  O34  1  0.574  0.344  0.555  1.0
  O  O35  1  0.426  0.656  0.445  1.0
  O  O36  1  0.656  0.426  0.945  1.0
  O  O37  1  0.344  0.574  0.055  1.0
  O  O38  1  0.989  0.011  0.750  1.0
  O  O39  1  0.011  0.989  0.250  1.0
  O  O40  1  0.550  0.762  0.827  1.0
  O  O41  1  0.450  0.238  0.173  1.0
  O  O42  1  0.238  0.450  0.673  1.0
  O  O43  1  0.762  0.550  0.327  1.0
  O  O44  1  0.378  0.260  0.875  1.0
  O  O45  1  0.622  0.740  0.125  1.0
  O  O46  1  0.740  0.622  0.625  1.0
  O  O47  1  0.260  0.378  0.375  1.0
[/CIF]
.