The crystal structure described by K2CuCl4O2 crystallizes in the tetragonal I4/mmm space group. The structure consists of two hydrogen peroxide molecules inside a K2CuCl4 framework. In the K2CuCl4 framework, K(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Cu(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Cu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.688
_cell_length_b   6.688
_cell_length_c   6.688
_cell_angle_alpha   107.399
_cell_angle_beta   110.517
_cell_angle_gamma   110.517
_symmetry_Int_Tables_number   1
_cell_volume   230.014
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.750  0.250  1.0
  K  K1  1  0.500  0.250  0.750  1.0
  Cu  Cu2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.000  0.211  0.789  1.0
  Cl  Cl4  1  0.000  0.789  0.211  1.0
  Cl  Cl5  1  0.577  0.789  0.789  1.0
  Cl  Cl6  1  0.423  0.211  0.211  1.0
  O  O7  1  0.000  0.422  0.422  1.0
  O  O8  1  0.000  0.578  0.578  1.0
[/CIF]
.
The crystal structure described by K2CuCl4O2 crystallizes in the tetragonal I4/mmm space group. The structure consists of two hydrogen peroxide molecules inside a K2CuCl4 framework. In the K2CuCl4 framework, K(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Cu(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Cu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.688
_cell_length_b   6.688
_cell_length_c   6.688
_cell_angle_alpha   107.399
_cell_angle_beta   110.517
_cell_angle_gamma   110.517
_symmetry_Int_Tables_number   1
_cell_volume   230.014
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.750  0.250  1.0
  K  K1  1  0.500  0.250  0.750  1.0
  Cu  Cu2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.000  0.211  0.789  1.0
  Cl  Cl4  1  0.000  0.789  0.211  1.0
  Cl  Cl5  1  0.577  0.789  0.789  1.0
  Cl  Cl6  1  0.423  0.211  0.211  1.0
  O  O7  1  0.000  0.422  0.422  1.0
  O  O8  1  0.000  0.578  0.578  1.0
[/CIF]
.