The compound described by Sm(MoO4)2Tl crystallizes in the tetragonal P4/nnc space group. The structure consists of two 7440-28-0 atoms inside a Sm(MoO4)2 framework. In the Sm(MoO4)2 framework, Sm(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. Mo(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_SmTl(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.372
_cell_length_b   6.372
_cell_length_c   9.637
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   391.299
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.500  0.500  0.000  1.0
  Sm  Sm1  1  0.000  0.000  0.500  1.0
  Tl  Tl2  1  0.500  0.500  0.500  1.0
  Tl  Tl3  1  0.000  0.000  0.000  1.0
  Mo  Mo4  1  0.500  0.000  0.250  1.0
  Mo  Mo5  1  0.000  0.500  0.250  1.0
  Mo  Mo6  1  0.500  0.000  0.750  1.0
  Mo  Mo7  1  0.000  0.500  0.750  1.0
  O  O8  1  0.802  0.390  0.138  1.0
  O  O9  1  0.198  0.610  0.138  1.0
  O  O10  1  0.390  0.802  0.862  1.0
  O  O11  1  0.390  0.198  0.138  1.0
  O  O12  1  0.610  0.802  0.138  1.0
  O  O13  1  0.198  0.390  0.862  1.0
  O  O14  1  0.802  0.610  0.862  1.0
  O  O15  1  0.610  0.198  0.862  1.0
  O  O16  1  0.890  0.302  0.638  1.0
  O  O17  1  0.698  0.890  0.638  1.0
  O  O18  1  0.302  0.110  0.638  1.0
  O  O19  1  0.890  0.698  0.362  1.0
  O  O20  1  0.110  0.302  0.362  1.0
  O  O21  1  0.110  0.698  0.638  1.0
  O  O22  1  0.302  0.890  0.362  1.0
  O  O23  1  0.698  0.110  0.362  1.0
[/CIF]
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The compound described by Sm(MoO4)2Tl crystallizes in the tetragonal P4/nnc space group. The structure consists of two 7440-28-0 atoms inside a Sm(MoO4)2 framework. In the Sm(MoO4)2 framework, Sm(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. Mo(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_SmTl(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.372
_cell_length_b   6.372
_cell_length_c   9.637
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   391.299
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.500  0.500  0.000  1.0
  Sm  Sm1  1  0.000  0.000  0.500  1.0
  Tl  Tl2  1  0.500  0.500  0.500  1.0
  Tl  Tl3  1  0.000  0.000  0.000  1.0
  Mo  Mo4  1  0.500  0.000  0.250  1.0
  Mo  Mo5  1  0.000  0.500  0.250  1.0
  Mo  Mo6  1  0.500  0.000  0.750  1.0
  Mo  Mo7  1  0.000  0.500  0.750  1.0
  O  O8  1  0.802  0.390  0.138  1.0
  O  O9  1  0.198  0.610  0.138  1.0
  O  O10  1  0.390  0.802  0.862  1.0
  O  O11  1  0.390  0.198  0.138  1.0
  O  O12  1  0.610  0.802  0.138  1.0
  O  O13  1  0.198  0.390  0.862  1.0
  O  O14  1  0.802  0.610  0.862  1.0
  O  O15  1  0.610  0.198  0.862  1.0
  O  O16  1  0.890  0.302  0.638  1.0
  O  O17  1  0.698  0.890  0.638  1.0
  O  O18  1  0.302  0.110  0.638  1.0
  O  O19  1  0.890  0.698  0.362  1.0
  O  O20  1  0.110  0.302  0.362  1.0
  O  O21  1  0.110  0.698  0.638  1.0
  O  O22  1  0.302  0.890  0.362  1.0
  O  O23  1  0.698  0.110  0.362  1.0
[/CIF]
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