The compound described by V3Al is Tungsten-derived structured and crystallizes in the orthorhombic Cmmm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to two equivalent V(2), four equivalent V(1), and two equivalent Al(1) atoms. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to four equivalent V(1) and four equivalent V(2) atoms. Al(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(1) and four equivalent Al(1) atoms. is represented by the CIF card [CIF]
data_AlV3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.642
_cell_length_b   2.642
_cell_length_c   8.471
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.496
_symmetry_Int_Tables_number   1
_cell_volume   56.059
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.500  0.258  1.0
  V  V2  1  0.000  0.000  0.500  1.0
  V  V3  1  0.500  0.500  0.742  1.0
[/CIF]
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The compound described by V3Al is Tungsten-derived structured and crystallizes in the orthorhombic Cmmm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to two equivalent V(2), four equivalent V(1), and two equivalent Al(1) atoms. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to four equivalent V(1) and four equivalent V(2) atoms. Al(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(1) and four equivalent Al(1) atoms. is represented by the CIF card [CIF]
data_AlV3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.642
_cell_length_b   2.642
_cell_length_c   8.471
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.496
_symmetry_Int_Tables_number   1
_cell_volume   56.059
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.500  0.258  1.0
  V  V2  1  0.000  0.000  0.500  1.0
  V  V3  1  0.500  0.500  0.742  1.0
[/CIF]
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