The compound described by V2O3 is Corundum structured and crystallizes in the monoclinic C2/c space group. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form a mixture of corner, face, and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OV4 trigonal pyramids. In the second O site, O(2) is bonded to four equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OV4 trigonal pyramids. is represented by the CIF file [CIF]
data_V2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.017
_cell_length_b   5.017
_cell_length_c   5.465
_cell_angle_alpha   63.435
_cell_angle_beta   90.234
_cell_angle_gamma   121.151
_symmetry_Int_Tables_number   1
_cell_volume   100.558
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.848  0.702  0.456  1.0
  V  V1  1  0.659  0.307  0.040  1.0
  V  V2  1  0.156  0.305  0.540  1.0
  V  V3  1  0.345  0.700  0.956  1.0
  O  O4  1  0.440  0.192  0.748  1.0
  O  O5  1  0.564  0.816  0.248  1.0
  O  O6  1  0.252  0.195  0.242  1.0
  O  O7  1  0.752  0.813  0.754  1.0
  O  O8  1  0.067  0.510  0.742  1.0
  O  O9  1  0.937  0.498  0.254  1.0
[/CIF]
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The compound described by V2O3 is Corundum structured and crystallizes in the monoclinic C2/c space group. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form a mixture of corner, face, and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OV4 trigonal pyramids. In the second O site, O(2) is bonded to four equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OV4 trigonal pyramids. is represented by the CIF file [CIF]
data_V2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.017
_cell_length_b   5.017
_cell_length_c   5.465
_cell_angle_alpha   63.435
_cell_angle_beta   90.234
_cell_angle_gamma   121.151
_symmetry_Int_Tables_number   1
_cell_volume   100.558
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.848  0.702  0.456  1.0
  V  V1  1  0.659  0.307  0.040  1.0
  V  V2  1  0.156  0.305  0.540  1.0
  V  V3  1  0.345  0.700  0.956  1.0
  O  O4  1  0.440  0.192  0.748  1.0
  O  O5  1  0.564  0.816  0.248  1.0
  O  O6  1  0.252  0.195  0.242  1.0
  O  O7  1  0.752  0.813  0.754  1.0
  O  O8  1  0.067  0.510  0.742  1.0
  O  O9  1  0.937  0.498  0.254  1.0
[/CIF]
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