The crystal structure described by Ba4Ti2PtO10 crystallizes in the orthorhombic Cmce space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 10-coordinate geometry to one O(2), two equivalent O(4), three equivalent O(1), and four equivalent O(3) atoms. In the second Ba site, Ba(2) is bonded in a 11-coordinate geometry to one O(1), two equivalent O(4), four equivalent O(2), and four equivalent O(3) atoms. Ti(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra and  a faceface with one Pt(1)O6 octahedra. The corner-sharing octahedral tilt angles are 9°. Pt(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form PtO6 octahedra that share faces with two equivalent Ti(1)O6 octahedra. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted linear geometry to two equivalent Ba(1), two equivalent Ba(2), and two equivalent Ti(1) atoms. In the second O site, O(1) is bonded to one Ba(2), three equivalent Ba(1), one Ti(1), and one Pt(1) atom to form a mixture of distorted corner and edge-sharing OBa4TiPt octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Ba(1), four equivalent Ba(2), and one Ti(1) atom. In the fourth O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent Ba(2), one Ti(1), and one Pt(1) atom. is represented by the CIF file [CIF]
data_Ba4Ti2PtO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.396
_cell_length_b   7.396
_cell_length_c   13.319
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   133.414
_symmetry_Int_Tables_number   1
_cell_volume   529.254
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.471  0.529  0.142  1.0
  Ba  Ba1  1  0.234  0.766  0.900  1.0
  Ba  Ba2  1  0.734  0.266  0.600  1.0
  Ba  Ba3  1  0.029  0.971  0.642  1.0
  Ba  Ba4  1  0.971  0.029  0.358  1.0
  Ba  Ba5  1  0.266  0.734  0.400  1.0
  Ba  Ba6  1  0.529  0.471  0.858  1.0
  Ba  Ba7  1  0.766  0.234  0.100  1.0
  Ti  Ti8  1  0.139  0.861  0.155  1.0
  Ti  Ti9  1  0.361  0.639  0.655  1.0
  Ti  Ti10  1  0.861  0.139  0.845  1.0
  Ti  Ti11  1  0.639  0.361  0.345  1.0
  Pt  Pt12  1  0.000  0.000  0.000  1.0
  Pt  Pt13  1  0.500  0.500  0.500  1.0
  O  O14  1  0.536  0.464  0.651  1.0
  O  O15  1  0.730  0.270  0.859  1.0
  O  O16  1  0.383  0.166  0.460  1.0
  O  O17  1  0.883  0.666  0.040  1.0
  O  O18  1  0.622  0.878  0.750  1.0
  O  O19  1  0.122  0.378  0.750  1.0
  O  O20  1  0.270  0.730  0.141  1.0
  O  O21  1  0.036  0.964  0.849  1.0
  O  O22  1  0.378  0.122  0.250  1.0
  O  O23  1  0.834  0.617  0.460  1.0
  O  O24  1  0.770  0.230  0.359  1.0
  O  O25  1  0.464  0.536  0.349  1.0
  O  O26  1  0.878  0.622  0.250  1.0
  O  O27  1  0.117  0.334  0.960  1.0
  O  O28  1  0.617  0.834  0.540  1.0
  O  O29  1  0.230  0.770  0.641  1.0
  O  O30  1  0.666  0.883  0.960  1.0
  O  O31  1  0.166  0.383  0.540  1.0
  O  O32  1  0.964  0.036  0.151  1.0
  O  O33  1  0.334  0.117  0.040  1.0
[/CIF]
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The crystal structure described by Ba4Ti2PtO10 crystallizes in the orthorhombic Cmce space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 10-coordinate geometry to one O(2), two equivalent O(4), three equivalent O(1), and four equivalent O(3) atoms. In the second Ba site, Ba(2) is bonded in a 11-coordinate geometry to one O(1), two equivalent O(4), four equivalent O(2), and four equivalent O(3) atoms. Ti(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra and  a faceface with one Pt(1)O6 octahedra. The corner-sharing octahedral tilt angles are 9°. Pt(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form PtO6 octahedra that share faces with two equivalent Ti(1)O6 octahedra. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted linear geometry to two equivalent Ba(1), two equivalent Ba(2), and two equivalent Ti(1) atoms. In the second O site, O(1) is bonded to one Ba(2), three equivalent Ba(1), one Ti(1), and one Pt(1) atom to form a mixture of distorted corner and edge-sharing OBa4TiPt octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Ba(1), four equivalent Ba(2), and one Ti(1) atom. In the fourth O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent Ba(2), one Ti(1), and one Pt(1) atom. is represented by the CIF file [CIF]
data_Ba4Ti2PtO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.396
_cell_length_b   7.396
_cell_length_c   13.319
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   133.414
_symmetry_Int_Tables_number   1
_cell_volume   529.254
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.471  0.529  0.142  1.0
  Ba  Ba1  1  0.234  0.766  0.900  1.0
  Ba  Ba2  1  0.734  0.266  0.600  1.0
  Ba  Ba3  1  0.029  0.971  0.642  1.0
  Ba  Ba4  1  0.971  0.029  0.358  1.0
  Ba  Ba5  1  0.266  0.734  0.400  1.0
  Ba  Ba6  1  0.529  0.471  0.858  1.0
  Ba  Ba7  1  0.766  0.234  0.100  1.0
  Ti  Ti8  1  0.139  0.861  0.155  1.0
  Ti  Ti9  1  0.361  0.639  0.655  1.0
  Ti  Ti10  1  0.861  0.139  0.845  1.0
  Ti  Ti11  1  0.639  0.361  0.345  1.0
  Pt  Pt12  1  0.000  0.000  0.000  1.0
  Pt  Pt13  1  0.500  0.500  0.500  1.0
  O  O14  1  0.536  0.464  0.651  1.0
  O  O15  1  0.730  0.270  0.859  1.0
  O  O16  1  0.383  0.166  0.460  1.0
  O  O17  1  0.883  0.666  0.040  1.0
  O  O18  1  0.622  0.878  0.750  1.0
  O  O19  1  0.122  0.378  0.750  1.0
  O  O20  1  0.270  0.730  0.141  1.0
  O  O21  1  0.036  0.964  0.849  1.0
  O  O22  1  0.378  0.122  0.250  1.0
  O  O23  1  0.834  0.617  0.460  1.0
  O  O24  1  0.770  0.230  0.359  1.0
  O  O25  1  0.464  0.536  0.349  1.0
  O  O26  1  0.878  0.622  0.250  1.0
  O  O27  1  0.117  0.334  0.960  1.0
  O  O28  1  0.617  0.834  0.540  1.0
  O  O29  1  0.230  0.770  0.641  1.0
  O  O30  1  0.666  0.883  0.960  1.0
  O  O31  1  0.166  0.383  0.540  1.0
  O  O32  1  0.964  0.036  0.151  1.0
  O  O33  1  0.334  0.117  0.040  1.0
[/CIF]
.