The crystal structure described by Fe2WO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pbcn space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with six equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form FeO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with six equivalent W(1)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the second Fe site, Fe(2) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form FeO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1) and two equivalent Fe(2) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Fe(1), and one Fe(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Fe(1) atoms. is represented by the CIF file [CIF]
data_Fe2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.625
_cell_length_b   5.074
_cell_length_c   16.966
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   398.103
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.000  0.250  0.553  1.0
  Fe  Fe1  1  0.500  0.750  0.947  1.0
  Fe  Fe2  1  0.000  0.750  0.447  1.0
  Fe  Fe3  1  0.500  0.250  0.053  1.0
  Fe  Fe4  1  0.500  0.250  0.722  1.0
  Fe  Fe5  1  0.000  0.750  0.778  1.0
  Fe  Fe6  1  0.000  0.250  0.222  1.0
  Fe  Fe7  1  0.500  0.750  0.278  1.0
  W  W8  1  0.000  0.250  0.884  1.0
  W  W9  1  0.500  0.750  0.616  1.0
  W  W10  1  0.000  0.750  0.116  1.0
  W  W11  1  0.500  0.250  0.384  1.0
  O  O12  1  0.725  0.416  0.297  1.0
  O  O13  1  0.225  0.584  0.203  1.0
  O  O14  1  0.775  0.916  0.203  1.0
  O  O15  1  0.275  0.084  0.297  1.0
  O  O16  1  0.275  0.584  0.703  1.0
  O  O17  1  0.775  0.416  0.797  1.0
  O  O18  1  0.225  0.084  0.797  1.0
  O  O19  1  0.725  0.916  0.703  1.0
  O  O20  1  0.727  0.930  0.374  1.0
  O  O21  1  0.227  0.070  0.126  1.0
  O  O22  1  0.773  0.430  0.126  1.0
  O  O23  1  0.273  0.570  0.374  1.0
  O  O24  1  0.764  0.907  0.541  1.0
  O  O25  1  0.264  0.093  0.959  1.0
  O  O26  1  0.736  0.407  0.959  1.0
  O  O27  1  0.236  0.593  0.541  1.0
  O  O28  1  0.236  0.093  0.459  1.0
  O  O29  1  0.736  0.907  0.041  1.0
  O  O30  1  0.273  0.070  0.626  1.0
  O  O31  1  0.764  0.407  0.459  1.0
  O  O32  1  0.727  0.430  0.626  1.0
  O  O33  1  0.227  0.570  0.874  1.0
  O  O34  1  0.773  0.930  0.874  1.0
  O  O35  1  0.264  0.593  0.041  1.0
[/CIF]
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The crystal structure described by Fe2WO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pbcn space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with six equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form FeO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with six equivalent W(1)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the second Fe site, Fe(2) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form FeO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1) and two equivalent Fe(2) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Fe(1), and one Fe(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Fe(1) atoms. is represented by the CIF file [CIF]
data_Fe2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.625
_cell_length_b   5.074
_cell_length_c   16.966
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   398.103
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.000  0.250  0.553  1.0
  Fe  Fe1  1  0.500  0.750  0.947  1.0
  Fe  Fe2  1  0.000  0.750  0.447  1.0
  Fe  Fe3  1  0.500  0.250  0.053  1.0
  Fe  Fe4  1  0.500  0.250  0.722  1.0
  Fe  Fe5  1  0.000  0.750  0.778  1.0
  Fe  Fe6  1  0.000  0.250  0.222  1.0
  Fe  Fe7  1  0.500  0.750  0.278  1.0
  W  W8  1  0.000  0.250  0.884  1.0
  W  W9  1  0.500  0.750  0.616  1.0
  W  W10  1  0.000  0.750  0.116  1.0
  W  W11  1  0.500  0.250  0.384  1.0
  O  O12  1  0.725  0.416  0.297  1.0
  O  O13  1  0.225  0.584  0.203  1.0
  O  O14  1  0.775  0.916  0.203  1.0
  O  O15  1  0.275  0.084  0.297  1.0
  O  O16  1  0.275  0.584  0.703  1.0
  O  O17  1  0.775  0.416  0.797  1.0
  O  O18  1  0.225  0.084  0.797  1.0
  O  O19  1  0.725  0.916  0.703  1.0
  O  O20  1  0.727  0.930  0.374  1.0
  O  O21  1  0.227  0.070  0.126  1.0
  O  O22  1  0.773  0.430  0.126  1.0
  O  O23  1  0.273  0.570  0.374  1.0
  O  O24  1  0.764  0.907  0.541  1.0
  O  O25  1  0.264  0.093  0.959  1.0
  O  O26  1  0.736  0.407  0.959  1.0
  O  O27  1  0.236  0.593  0.541  1.0
  O  O28  1  0.236  0.093  0.459  1.0
  O  O29  1  0.736  0.907  0.041  1.0
  O  O30  1  0.273  0.070  0.626  1.0
  O  O31  1  0.764  0.407  0.459  1.0
  O  O32  1  0.727  0.430  0.626  1.0
  O  O33  1  0.227  0.570  0.874  1.0
  O  O34  1  0.773  0.930  0.874  1.0
  O  O35  1  0.264  0.593  0.041  1.0
[/CIF]
.