The structure described by (GdH12(O3Cl)2)2Cl2 crystallizes in the monoclinic P2/c space group. The structure consists of two hydrochloric acid atoms inside a GdH12(O3Cl)2 framework. In the GdH12(O3Cl)2 framework, Gd(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one Cl(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) and one Cl(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) and one Cl(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Gd(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Gd(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Gd(1), one H(5), and one H(6) atom. Cl(1) is bonded in a 4-coordinate geometry to one Gd(1), one H(1), one H(3), and one H(5) atom. is represented by the CIF card [CIF]
data_GdH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.599
_cell_length_b   7.920
_cell_length_c   12.181
_cell_angle_alpha   52.554
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   505.400
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.153  0.000  0.250  1.0
  Gd  Gd1  1  0.847  0.000  0.750  1.0
  H  H2  1  0.248  0.473  0.035  1.0
  H  H3  1  0.248  0.527  0.465  1.0
  H  H4  1  0.752  0.527  0.965  1.0
  H  H5  1  0.752  0.473  0.535  1.0
  H  H6  1  0.329  0.371  0.967  1.0
  H  H7  1  0.329  0.629  0.533  1.0
  H  H8  1  0.671  0.629  0.033  1.0
  H  H9  1  0.671  0.371  0.467  1.0
  H  H10  1  0.552  0.968  0.385  1.0
  H  H11  1  0.552  0.032  0.115  1.0
  H  H12  1  0.448  0.032  0.615  1.0
  H  H13  1  0.448  0.968  0.885  1.0
  H  H14  1  0.475  0.200  0.318  1.0
  H  H15  1  0.475  0.800  0.182  1.0
  H  H16  1  0.525  0.800  0.682  1.0
  H  H17  1  0.525  0.200  0.818  1.0
  H  H18  1  0.095  0.760  0.130  1.0
  H  H19  1  0.095  0.240  0.370  1.0
  H  H20  1  0.905  0.240  0.870  1.0
  H  H21  1  0.905  0.760  0.630  1.0
  H  H22  1  0.085  0.677  0.735  1.0
  H  H23  1  0.085  0.323  0.765  1.0
  H  H24  1  0.915  0.323  0.265  1.0
  H  H25  1  0.915  0.677  0.235  1.0
  Cl  Cl26  1  0.832  0.799  0.443  1.0
  Cl  Cl27  1  0.832  0.201  0.057  1.0
  Cl  Cl28  1  0.168  0.201  0.557  1.0
  Cl  Cl29  1  0.168  0.799  0.943  1.0
  Cl  Cl30  1  0.366  0.500  0.750  1.0
  Cl  Cl31  1  0.634  0.500  0.250  1.0
  O  O32  1  0.294  0.336  0.057  1.0
  O  O33  1  0.294  0.664  0.443  1.0
  O  O34  1  0.706  0.664  0.943  1.0
  O  O35  1  0.706  0.336  0.557  1.0
  O  O36  1  0.428  0.056  0.354  1.0
  O  O37  1  0.428  0.944  0.146  1.0
  O  O38  1  0.572  0.944  0.646  1.0
  O  O39  1  0.572  0.056  0.854  1.0
  O  O40  1  0.051  0.742  0.214  1.0
  O  O41  1  0.051  0.258  0.286  1.0
  O  O42  1  0.949  0.258  0.786  1.0
  O  O43  1  0.949  0.742  0.714  1.0
[/CIF]
.
The structure described by (GdH12(O3Cl)2)2Cl2 crystallizes in the monoclinic P2/c space group. The structure consists of two hydrochloric acid atoms inside a GdH12(O3Cl)2 framework. In the GdH12(O3Cl)2 framework, Gd(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one Cl(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) and one Cl(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) and one Cl(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Gd(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Gd(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Gd(1), one H(5), and one H(6) atom. Cl(1) is bonded in a 4-coordinate geometry to one Gd(1), one H(1), one H(3), and one H(5) atom. is represented by the CIF card [CIF]
data_GdH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.599
_cell_length_b   7.920
_cell_length_c   12.181
_cell_angle_alpha   52.554
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   505.400
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.153  0.000  0.250  1.0
  Gd  Gd1  1  0.847  0.000  0.750  1.0
  H  H2  1  0.248  0.473  0.035  1.0
  H  H3  1  0.248  0.527  0.465  1.0
  H  H4  1  0.752  0.527  0.965  1.0
  H  H5  1  0.752  0.473  0.535  1.0
  H  H6  1  0.329  0.371  0.967  1.0
  H  H7  1  0.329  0.629  0.533  1.0
  H  H8  1  0.671  0.629  0.033  1.0
  H  H9  1  0.671  0.371  0.467  1.0
  H  H10  1  0.552  0.968  0.385  1.0
  H  H11  1  0.552  0.032  0.115  1.0
  H  H12  1  0.448  0.032  0.615  1.0
  H  H13  1  0.448  0.968  0.885  1.0
  H  H14  1  0.475  0.200  0.318  1.0
  H  H15  1  0.475  0.800  0.182  1.0
  H  H16  1  0.525  0.800  0.682  1.0
  H  H17  1  0.525  0.200  0.818  1.0
  H  H18  1  0.095  0.760  0.130  1.0
  H  H19  1  0.095  0.240  0.370  1.0
  H  H20  1  0.905  0.240  0.870  1.0
  H  H21  1  0.905  0.760  0.630  1.0
  H  H22  1  0.085  0.677  0.735  1.0
  H  H23  1  0.085  0.323  0.765  1.0
  H  H24  1  0.915  0.323  0.265  1.0
  H  H25  1  0.915  0.677  0.235  1.0
  Cl  Cl26  1  0.832  0.799  0.443  1.0
  Cl  Cl27  1  0.832  0.201  0.057  1.0
  Cl  Cl28  1  0.168  0.201  0.557  1.0
  Cl  Cl29  1  0.168  0.799  0.943  1.0
  Cl  Cl30  1  0.366  0.500  0.750  1.0
  Cl  Cl31  1  0.634  0.500  0.250  1.0
  O  O32  1  0.294  0.336  0.057  1.0
  O  O33  1  0.294  0.664  0.443  1.0
  O  O34  1  0.706  0.664  0.943  1.0
  O  O35  1  0.706  0.336  0.557  1.0
  O  O36  1  0.428  0.056  0.354  1.0
  O  O37  1  0.428  0.944  0.146  1.0
  O  O38  1  0.572  0.944  0.646  1.0
  O  O39  1  0.572  0.056  0.854  1.0
  O  O40  1  0.051  0.742  0.214  1.0
  O  O41  1  0.051  0.258  0.286  1.0
  O  O42  1  0.949  0.258  0.786  1.0
  O  O43  1  0.949  0.742  0.714  1.0
[/CIF]
.