The material structure described by PdPb2Te2(O3Cl)2 crystallizes in the monoclinic P2_1/c space group. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent Cl(1) atoms. Pb(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(3) atoms. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Pb(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Pd(1), one Pb(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent Pb(1) and one Te(1) atom. Cl(1) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF card [CIF]
data_Te2PdPb2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.554
_cell_length_b   8.318
_cell_length_c   13.305
_cell_angle_alpha   56.050
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   509.876
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.014  0.778  0.991  1.0
  Te  Te1  1  0.514  0.222  0.509  1.0
  Te  Te2  1  0.986  0.222  0.009  1.0
  Te  Te3  1  0.486  0.778  0.491  1.0
  Pd  Pd4  1  0.500  0.500  0.000  1.0
  Pd  Pd5  1  0.000  0.500  0.500  1.0
  Pb  Pb6  1  0.541  0.152  0.803  1.0
  Pb  Pb7  1  0.041  0.848  0.697  1.0
  Pb  Pb8  1  0.459  0.848  0.197  1.0
  Pb  Pb9  1  0.959  0.152  0.303  1.0
  Cl  Cl10  1  0.079  0.454  0.685  1.0
  Cl  Cl11  1  0.579  0.546  0.815  1.0
  Cl  Cl12  1  0.921  0.546  0.315  1.0
  Cl  Cl13  1  0.421  0.454  0.185  1.0
  O  O14  1  0.856  0.932  0.838  1.0
  O  O15  1  0.356  0.068  0.662  1.0
  O  O16  1  0.144  0.068  0.162  1.0
  O  O17  1  0.644  0.932  0.338  1.0
  O  O18  1  0.204  0.670  0.922  1.0
  O  O19  1  0.704  0.330  0.578  1.0
  O  O20  1  0.796  0.330  0.078  1.0
  O  O21  1  0.296  0.670  0.422  1.0
  O  O22  1  0.248  0.956  0.978  1.0
  O  O23  1  0.748  0.044  0.522  1.0
  O  O24  1  0.752  0.044  0.022  1.0
  O  O25  1  0.252  0.956  0.478  1.0
[/CIF]
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The material structure described by PdPb2Te2(O3Cl)2 crystallizes in the monoclinic P2_1/c space group. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent Cl(1) atoms. Pb(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(3) atoms. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Pb(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Pd(1), one Pb(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent Pb(1) and one Te(1) atom. Cl(1) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF card [CIF]
data_Te2PdPb2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.554
_cell_length_b   8.318
_cell_length_c   13.305
_cell_angle_alpha   56.050
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   509.876
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.014  0.778  0.991  1.0
  Te  Te1  1  0.514  0.222  0.509  1.0
  Te  Te2  1  0.986  0.222  0.009  1.0
  Te  Te3  1  0.486  0.778  0.491  1.0
  Pd  Pd4  1  0.500  0.500  0.000  1.0
  Pd  Pd5  1  0.000  0.500  0.500  1.0
  Pb  Pb6  1  0.541  0.152  0.803  1.0
  Pb  Pb7  1  0.041  0.848  0.697  1.0
  Pb  Pb8  1  0.459  0.848  0.197  1.0
  Pb  Pb9  1  0.959  0.152  0.303  1.0
  Cl  Cl10  1  0.079  0.454  0.685  1.0
  Cl  Cl11  1  0.579  0.546  0.815  1.0
  Cl  Cl12  1  0.921  0.546  0.315  1.0
  Cl  Cl13  1  0.421  0.454  0.185  1.0
  O  O14  1  0.856  0.932  0.838  1.0
  O  O15  1  0.356  0.068  0.662  1.0
  O  O16  1  0.144  0.068  0.162  1.0
  O  O17  1  0.644  0.932  0.338  1.0
  O  O18  1  0.204  0.670  0.922  1.0
  O  O19  1  0.704  0.330  0.578  1.0
  O  O20  1  0.796  0.330  0.078  1.0
  O  O21  1  0.296  0.670  0.422  1.0
  O  O22  1  0.248  0.956  0.978  1.0
  O  O23  1  0.748  0.044  0.522  1.0
  O  O24  1  0.752  0.044  0.022  1.0
  O  O25  1  0.252  0.956  0.478  1.0
[/CIF]
.