The material described by Yb(Bi3O5)4 crystallizes in the cubic I23 space group. Yb(1) is bonded in a distorted body-centered cubic geometry to four equivalent O(1) and four equivalent O(3) atoms. Bi(1) is bonded to one O(1), one O(3), and three equivalent O(2) atoms to form a mixture of distorted corner and edge-sharing BiO5 square pyramids. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Yb(1) and three equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OYbBi3 trigonal pyramids. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Bi(1) atoms. In the third O site, O(3) is bonded to one Yb(1) and three equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OYbBi3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Yb(Bi3O5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.906
_cell_length_b   8.906
_cell_length_c   8.906
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   543.839
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.000  0.000  0.000  1.0
  Bi  Bi1  1  0.855  0.174  0.685  1.0
  Bi  Bi2  1  0.318  0.145  0.830  1.0
  Bi  Bi3  1  0.682  0.512  0.826  1.0
  Bi  Bi4  1  0.826  0.682  0.512  1.0
  Bi  Bi5  1  0.830  0.318  0.145  1.0
  Bi  Bi6  1  0.488  0.170  0.315  1.0
  Bi  Bi7  1  0.512  0.826  0.682  1.0
  Bi  Bi8  1  0.170  0.315  0.488  1.0
  Bi  Bi9  1  0.174  0.685  0.855  1.0
  Bi  Bi10  1  0.685  0.855  0.174  1.0
  Bi  Bi11  1  0.315  0.488  0.170  1.0
  Bi  Bi12  1  0.145  0.830  0.318  1.0
  O  O13  1  0.000  0.327  0.000  1.0
  O  O14  1  0.624  0.249  0.889  1.0
  O  O15  1  0.000  0.740  0.000  1.0
  O  O16  1  0.751  0.375  0.641  1.0
  O  O17  1  0.734  0.111  0.359  1.0
  O  O18  1  0.740  0.000  0.000  1.0
  O  O19  1  0.000  0.000  0.740  1.0
  O  O20  1  0.376  0.266  0.625  1.0
  O  O21  1  0.673  0.673  0.673  1.0
  O  O22  1  0.375  0.641  0.751  1.0
  O  O23  1  0.111  0.359  0.734  1.0
  O  O24  1  0.889  0.624  0.249  1.0
  O  O25  1  0.625  0.376  0.266  1.0
  O  O26  1  0.327  0.000  0.000  1.0
  O  O27  1  0.000  0.000  0.327  1.0
  O  O28  1  0.641  0.751  0.375  1.0
  O  O29  1  0.260  0.260  0.260  1.0
  O  O30  1  0.266  0.625  0.376  1.0
  O  O31  1  0.249  0.889  0.624  1.0
  O  O32  1  0.359  0.734  0.111  1.0
[/CIF]
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The material described by Yb(Bi3O5)4 crystallizes in the cubic I23 space group. Yb(1) is bonded in a distorted body-centered cubic geometry to four equivalent O(1) and four equivalent O(3) atoms. Bi(1) is bonded to one O(1), one O(3), and three equivalent O(2) atoms to form a mixture of distorted corner and edge-sharing BiO5 square pyramids. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Yb(1) and three equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OYbBi3 trigonal pyramids. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Bi(1) atoms. In the third O site, O(3) is bonded to one Yb(1) and three equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OYbBi3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Yb(Bi3O5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.906
_cell_length_b   8.906
_cell_length_c   8.906
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   543.839
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.000  0.000  0.000  1.0
  Bi  Bi1  1  0.855  0.174  0.685  1.0
  Bi  Bi2  1  0.318  0.145  0.830  1.0
  Bi  Bi3  1  0.682  0.512  0.826  1.0
  Bi  Bi4  1  0.826  0.682  0.512  1.0
  Bi  Bi5  1  0.830  0.318  0.145  1.0
  Bi  Bi6  1  0.488  0.170  0.315  1.0
  Bi  Bi7  1  0.512  0.826  0.682  1.0
  Bi  Bi8  1  0.170  0.315  0.488  1.0
  Bi  Bi9  1  0.174  0.685  0.855  1.0
  Bi  Bi10  1  0.685  0.855  0.174  1.0
  Bi  Bi11  1  0.315  0.488  0.170  1.0
  Bi  Bi12  1  0.145  0.830  0.318  1.0
  O  O13  1  0.000  0.327  0.000  1.0
  O  O14  1  0.624  0.249  0.889  1.0
  O  O15  1  0.000  0.740  0.000  1.0
  O  O16  1  0.751  0.375  0.641  1.0
  O  O17  1  0.734  0.111  0.359  1.0
  O  O18  1  0.740  0.000  0.000  1.0
  O  O19  1  0.000  0.000  0.740  1.0
  O  O20  1  0.376  0.266  0.625  1.0
  O  O21  1  0.673  0.673  0.673  1.0
  O  O22  1  0.375  0.641  0.751  1.0
  O  O23  1  0.111  0.359  0.734  1.0
  O  O24  1  0.889  0.624  0.249  1.0
  O  O25  1  0.625  0.376  0.266  1.0
  O  O26  1  0.327  0.000  0.000  1.0
  O  O27  1  0.000  0.000  0.327  1.0
  O  O28  1  0.641  0.751  0.375  1.0
  O  O29  1  0.260  0.260  0.260  1.0
  O  O30  1  0.266  0.625  0.376  1.0
  O  O31  1  0.249  0.889  0.624  1.0
  O  O32  1  0.359  0.734  0.111  1.0
[/CIF]
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