The material structure described by NaTaZnP2SO12 crystallizes in the monoclinic Cc space group. Na(1) is bonded in a distorted hexagonal planar geometry to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom. Ta(1) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom to form TaO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. Zn(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form ZnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(2), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Ta(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-38°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Ta(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. S(1) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent Ta(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-37°. There are twelve inequivalent O sites. In the first O site, O(6) is bonded in a bent 150 degrees geometry to one Ta(1) and one S(1) atom. In the second O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one P(2) atom. In the third O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one P(1) atom. In the fourth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one S(1) atom. In the fifth O site, O(10) is bonded in a 3-coordinate geometry to one Na(1), one Ta(1), and one S(1) atom. In the sixth O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Na(1), one Ta(1), and one P(1) atom. In the seventh O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one Ta(1), and one P(2) atom. In the eighth O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the ninth O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the tenth O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(2) atom. In the eleventh O site, O(4) is bonded in a bent 150 degrees geometry to one Ta(1) and one P(2) atom. In the twelfth O site, O(5) is bonded in a bent 150 degrees geometry to one Ta(1) and one P(1) atom. is represented by the CIF card [CIF]
data_NaTaZnP2SO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.736
_cell_length_b   8.736
_cell_length_c   9.080
_cell_angle_alpha   90.324
_cell_angle_beta   118.581
_cell_angle_gamma   119.796
_symmetry_Int_Tables_number   1
_cell_volume   500.442
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.034  0.518  0.529  1.0
  Na  Na1  1  0.010  0.995  0.029  1.0
  O  O2  1  0.369  0.486  0.088  1.0
  O  O3  1  0.602  0.877  0.082  1.0
  O  O4  1  0.200  0.709  0.079  1.0
  O  O5  1  0.206  0.980  0.582  1.0
  O  O6  1  0.603  0.220  0.588  1.0
  O  O7  1  0.370  0.378  0.579  1.0
  O  O8  1  0.636  0.502  0.913  1.0
  O  O9  1  0.411  0.133  0.913  1.0
  O  O10  1  0.782  0.275  0.909  1.0
  O  O11  1  0.780  0.002  0.413  1.0
  O  O12  1  0.411  0.777  0.413  1.0
  O  O13  1  0.634  0.627  0.409  1.0
  O  O14  1  0.352  0.569  0.770  1.0
  O  O15  1  0.181  0.775  0.766  1.0
  O  O16  1  0.983  0.404  0.773  1.0
  O  O17  1  0.991  0.085  0.266  1.0
  O  O18  1  0.201  0.918  0.270  1.0
  O  O19  1  0.369  0.290  0.273  1.0
  O  O20  1  0.660  0.448  0.235  1.0
  O  O21  1  0.782  0.218  0.227  1.0
  O  O22  1  0.008  0.570  0.226  1.0
  O  O23  1  0.009  0.945  0.727  1.0
  O  O24  1  0.787  0.075  0.735  1.0
  O  O25  1  0.657  0.718  0.726  1.0
  P  P26  1  0.789  0.040  0.244  1.0
  P  P27  1  0.207  0.751  0.242  1.0
  P  P28  1  0.205  0.955  0.744  1.0
  P  P29  1  0.491  0.535  0.742  1.0
  S  S30  1  0.495  0.458  0.246  1.0
  S  S31  1  0.788  0.251  0.746  1.0
  Ta  Ta32  1  0.706  0.356  0.062  1.0
  Ta  Ta33  1  0.707  0.856  0.562  1.0
  Zn  Zn34  1  0.308  0.669  0.945  1.0
  Zn  Zn35  1  0.276  0.137  0.445  1.0
[/CIF]
.
The material structure described by NaTaZnP2SO12 crystallizes in the monoclinic Cc space group. Na(1) is bonded in a distorted hexagonal planar geometry to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom. Ta(1) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom to form TaO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. Zn(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form ZnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(2), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Ta(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-38°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Ta(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. S(1) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent Ta(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-37°. There are twelve inequivalent O sites. In the first O site, O(6) is bonded in a bent 150 degrees geometry to one Ta(1) and one S(1) atom. In the second O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one P(2) atom. In the third O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one P(1) atom. In the fourth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one S(1) atom. In the fifth O site, O(10) is bonded in a 3-coordinate geometry to one Na(1), one Ta(1), and one S(1) atom. In the sixth O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Na(1), one Ta(1), and one P(1) atom. In the seventh O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one Ta(1), and one P(2) atom. In the eighth O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the ninth O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the tenth O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(2) atom. In the eleventh O site, O(4) is bonded in a bent 150 degrees geometry to one Ta(1) and one P(2) atom. In the twelfth O site, O(5) is bonded in a bent 150 degrees geometry to one Ta(1) and one P(1) atom. is represented by the CIF card [CIF]
data_NaTaZnP2SO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.736
_cell_length_b   8.736
_cell_length_c   9.080
_cell_angle_alpha   90.324
_cell_angle_beta   118.581
_cell_angle_gamma   119.796
_symmetry_Int_Tables_number   1
_cell_volume   500.442
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.034  0.518  0.529  1.0
  Na  Na1  1  0.010  0.995  0.029  1.0
  O  O2  1  0.369  0.486  0.088  1.0
  O  O3  1  0.602  0.877  0.082  1.0
  O  O4  1  0.200  0.709  0.079  1.0
  O  O5  1  0.206  0.980  0.582  1.0
  O  O6  1  0.603  0.220  0.588  1.0
  O  O7  1  0.370  0.378  0.579  1.0
  O  O8  1  0.636  0.502  0.913  1.0
  O  O9  1  0.411  0.133  0.913  1.0
  O  O10  1  0.782  0.275  0.909  1.0
  O  O11  1  0.780  0.002  0.413  1.0
  O  O12  1  0.411  0.777  0.413  1.0
  O  O13  1  0.634  0.627  0.409  1.0
  O  O14  1  0.352  0.569  0.770  1.0
  O  O15  1  0.181  0.775  0.766  1.0
  O  O16  1  0.983  0.404  0.773  1.0
  O  O17  1  0.991  0.085  0.266  1.0
  O  O18  1  0.201  0.918  0.270  1.0
  O  O19  1  0.369  0.290  0.273  1.0
  O  O20  1  0.660  0.448  0.235  1.0
  O  O21  1  0.782  0.218  0.227  1.0
  O  O22  1  0.008  0.570  0.226  1.0
  O  O23  1  0.009  0.945  0.727  1.0
  O  O24  1  0.787  0.075  0.735  1.0
  O  O25  1  0.657  0.718  0.726  1.0
  P  P26  1  0.789  0.040  0.244  1.0
  P  P27  1  0.207  0.751  0.242  1.0
  P  P28  1  0.205  0.955  0.744  1.0
  P  P29  1  0.491  0.535  0.742  1.0
  S  S30  1  0.495  0.458  0.246  1.0
  S  S31  1  0.788  0.251  0.746  1.0
  Ta  Ta32  1  0.706  0.356  0.062  1.0
  Ta  Ta33  1  0.707  0.856  0.562  1.0
  Zn  Zn34  1  0.308  0.669  0.945  1.0
  Zn  Zn35  1  0.276  0.137  0.445  1.0
[/CIF]
.