The structure described by Cs2Sn3(SbS5)2 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to one S(2), two equivalent S(1), two equivalent S(3), two equivalent S(4), and two equivalent S(5) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms to form edge-sharing SnS6 octahedra. In the second Sn site, Sn(2) is bonded to one S(2), one S(3), one S(4), and two equivalent S(5) atoms to form distorted SnS5 trigonal bipyramids that share  an edgeedge with one Sn(1)S6 octahedra and  an edgeedge with one Sn(2)S5 trigonal bipyramid. Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(4) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Cs(1), one Sn(1), and one Sb(1) atom to form distorted corner-sharing SCs2SnSb trigonal pyramids. In the second S site, S(2) is bonded in a distorted rectangular see-saw-like geometry to one Cs(1), one Sn(1), one Sn(2), and one Sb(1) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one Sn(1), and one Sn(2) atom. In the fourth S site, S(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Cs(1), one Sn(2), and one Sb(1) atom. In the fifth S site, S(5) is bonded in a 4-coordinate geometry to two equivalent Cs(1) and two equivalent Sn(2) atoms. is represented by the CIF file [CIF]
data_Cs2Sn3(SbS5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.795
_cell_length_b   7.194
_cell_length_c   12.301
_cell_angle_alpha   59.247
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1049.149
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.335  0.461  0.155  1.0
  Cs  Cs1  1  0.165  0.461  0.655  1.0
  Cs  Cs2  1  0.665  0.539  0.845  1.0
  Cs  Cs3  1  0.835  0.539  0.345  1.0
  Sn  Sn4  1  0.000  0.500  0.000  1.0
  Sn  Sn5  1  0.500  0.500  0.500  1.0
  Sn  Sn6  1  0.053  0.107  0.348  1.0
  Sn  Sn7  1  0.447  0.107  0.848  1.0
  Sn  Sn8  1  0.947  0.893  0.652  1.0
  Sn  Sn9  1  0.553  0.893  0.152  1.0
  Sb  Sb10  1  0.142  0.009  0.097  1.0
  Sb  Sb11  1  0.358  0.009  0.597  1.0
  Sb  Sb12  1  0.858  0.991  0.903  1.0
  Sb  Sb13  1  0.642  0.991  0.403  1.0
  S  S14  1  0.170  0.401  0.962  1.0
  S  S15  1  0.330  0.401  0.462  1.0
  S  S16  1  0.830  0.599  0.038  1.0
  S  S17  1  0.670  0.599  0.538  1.0
  S  S18  1  0.971  0.078  0.131  1.0
  S  S19  1  0.529  0.078  0.631  1.0
  S  S20  1  0.029  0.922  0.869  1.0
  S  S21  1  0.471  0.922  0.369  1.0
  S  S22  1  0.940  0.507  0.797  1.0
  S  S23  1  0.560  0.507  0.297  1.0
  S  S24  1  0.060  0.493  0.203  1.0
  S  S25  1  0.440  0.493  0.703  1.0
  S  S26  1  0.191  0.929  0.316  1.0
  S  S27  1  0.309  0.929  0.816  1.0
  S  S28  1  0.809  0.071  0.684  1.0
  S  S29  1  0.691  0.071  0.184  1.0
  S  S30  1  0.898  0.932  0.443  1.0
  S  S31  1  0.602  0.932  0.943  1.0
  S  S32  1  0.102  0.068  0.557  1.0
  S  S33  1  0.398  0.068  0.057  1.0
[/CIF]
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The structure described by Cs2Sn3(SbS5)2 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to one S(2), two equivalent S(1), two equivalent S(3), two equivalent S(4), and two equivalent S(5) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms to form edge-sharing SnS6 octahedra. In the second Sn site, Sn(2) is bonded to one S(2), one S(3), one S(4), and two equivalent S(5) atoms to form distorted SnS5 trigonal bipyramids that share  an edgeedge with one Sn(1)S6 octahedra and  an edgeedge with one Sn(2)S5 trigonal bipyramid. Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(4) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Cs(1), one Sn(1), and one Sb(1) atom to form distorted corner-sharing SCs2SnSb trigonal pyramids. In the second S site, S(2) is bonded in a distorted rectangular see-saw-like geometry to one Cs(1), one Sn(1), one Sn(2), and one Sb(1) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one Sn(1), and one Sn(2) atom. In the fourth S site, S(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Cs(1), one Sn(2), and one Sb(1) atom. In the fifth S site, S(5) is bonded in a 4-coordinate geometry to two equivalent Cs(1) and two equivalent Sn(2) atoms. is represented by the CIF file [CIF]
data_Cs2Sn3(SbS5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.795
_cell_length_b   7.194
_cell_length_c   12.301
_cell_angle_alpha   59.247
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1049.149
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.335  0.461  0.155  1.0
  Cs  Cs1  1  0.165  0.461  0.655  1.0
  Cs  Cs2  1  0.665  0.539  0.845  1.0
  Cs  Cs3  1  0.835  0.539  0.345  1.0
  Sn  Sn4  1  0.000  0.500  0.000  1.0
  Sn  Sn5  1  0.500  0.500  0.500  1.0
  Sn  Sn6  1  0.053  0.107  0.348  1.0
  Sn  Sn7  1  0.447  0.107  0.848  1.0
  Sn  Sn8  1  0.947  0.893  0.652  1.0
  Sn  Sn9  1  0.553  0.893  0.152  1.0
  Sb  Sb10  1  0.142  0.009  0.097  1.0
  Sb  Sb11  1  0.358  0.009  0.597  1.0
  Sb  Sb12  1  0.858  0.991  0.903  1.0
  Sb  Sb13  1  0.642  0.991  0.403  1.0
  S  S14  1  0.170  0.401  0.962  1.0
  S  S15  1  0.330  0.401  0.462  1.0
  S  S16  1  0.830  0.599  0.038  1.0
  S  S17  1  0.670  0.599  0.538  1.0
  S  S18  1  0.971  0.078  0.131  1.0
  S  S19  1  0.529  0.078  0.631  1.0
  S  S20  1  0.029  0.922  0.869  1.0
  S  S21  1  0.471  0.922  0.369  1.0
  S  S22  1  0.940  0.507  0.797  1.0
  S  S23  1  0.560  0.507  0.297  1.0
  S  S24  1  0.060  0.493  0.203  1.0
  S  S25  1  0.440  0.493  0.703  1.0
  S  S26  1  0.191  0.929  0.316  1.0
  S  S27  1  0.309  0.929  0.816  1.0
  S  S28  1  0.809  0.071  0.684  1.0
  S  S29  1  0.691  0.071  0.184  1.0
  S  S30  1  0.898  0.932  0.443  1.0
  S  S31  1  0.602  0.932  0.943  1.0
  S  S32  1  0.102  0.068  0.557  1.0
  S  S33  1  0.398  0.068  0.057  1.0
[/CIF]
.