The crystal structure described by TlS3 is Modderite-like structured and crystallizes in the hexagonal P6_3/mmc space group. Tl(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to two equivalent Tl(1) and four equivalent S(1) atoms. is represented by the CIF card [CIF]
data_TlS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.716
_cell_length_b   7.716
_cell_length_c   3.533
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   182.191
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.333  0.667  0.750  1.0
  Tl  Tl1  1  0.667  0.333  0.250  1.0
  S  S2  1  0.136  0.271  0.250  1.0
  S  S3  1  0.729  0.864  0.250  1.0
  S  S4  1  0.136  0.864  0.250  1.0
  S  S5  1  0.864  0.729  0.750  1.0
  S  S6  1  0.271  0.136  0.750  1.0
  S  S7  1  0.864  0.136  0.750  1.0
[/CIF]
.
The crystal structure described by TlS3 is Modderite-like structured and crystallizes in the hexagonal P6_3/mmc space group. Tl(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to two equivalent Tl(1) and four equivalent S(1) atoms. is represented by the CIF card [CIF]
data_TlS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.716
_cell_length_b   7.716
_cell_length_c   3.533
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   182.191
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.333  0.667  0.750  1.0
  Tl  Tl1  1  0.667  0.333  0.250  1.0
  S  S2  1  0.136  0.271  0.250  1.0
  S  S3  1  0.729  0.864  0.250  1.0
  S  S4  1  0.136  0.864  0.250  1.0
  S  S5  1  0.864  0.729  0.750  1.0
  S  S6  1  0.271  0.136  0.750  1.0
  S  S7  1  0.864  0.136  0.750  1.0
[/CIF]
.