The structure described by Co(C2O5)2PdN4H12O2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four water atoms, two Co(C2O5)2 clusters, and two PdN4H12 clusters. In each Co(C2O5)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent O(3) and four equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Co(1) atom. In each PdN4H12 cluster, Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_CoH12PdC4(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.008
_cell_length_b   9.008
_cell_length_c   7.183
_cell_angle_alpha   66.787
_cell_angle_beta   66.787
_cell_angle_gamma   111.209
_symmetry_Int_Tables_number   1
_cell_volume   389.231
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.500  1.0
  H  H1  1  0.804  0.995  0.312  1.0
  H  H2  1  0.995  0.804  0.312  1.0
  H  H3  1  0.196  0.005  0.688  1.0
  H  H4  1  0.005  0.196  0.688  1.0
  H  H5  1  0.869  0.187  0.326  1.0
  H  H6  1  0.187  0.869  0.326  1.0
  H  H7  1  0.131  0.813  0.674  1.0
  H  H8  1  0.813  0.131  0.674  1.0
  H  H9  1  0.042  0.214  0.085  1.0
  H  H10  1  0.214  0.042  0.085  1.0
  H  H11  1  0.958  0.786  0.915  1.0
  H  H12  1  0.786  0.958  0.915  1.0
  Pd  Pd13  1  0.000  0.000  0.500  1.0
  C  C14  1  0.429  0.781  0.405  1.0
  C  C15  1  0.781  0.429  0.405  1.0
  C  C16  1  0.571  0.219  0.595  1.0
  C  C17  1  0.219  0.571  0.595  1.0
  N  N18  1  0.919  0.112  0.279  1.0
  N  N19  1  0.112  0.919  0.279  1.0
  N  N20  1  0.081  0.888  0.721  1.0
  N  N21  1  0.888  0.081  0.721  1.0
  O  O22  1  0.584  0.776  0.346  1.0
  O  O23  1  0.776  0.584  0.346  1.0
  O  O24  1  0.416  0.224  0.654  1.0
  O  O25  1  0.224  0.416  0.654  1.0
  O  O26  1  0.442  0.937  0.319  1.0
  O  O27  1  0.937  0.442  0.319  1.0
  O  O28  1  0.558  0.063  0.681  1.0
  O  O29  1  0.063  0.558  0.681  1.0
  O  O30  1  0.459  0.459  0.780  1.0
  O  O31  1  0.541  0.541  0.220  1.0
  O  O32  1  0.643  0.357  0.000  1.0
  O  O33  1  0.357  0.643  0.000  1.0
[/CIF]
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The structure described by Co(C2O5)2PdN4H12O2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four water atoms, two Co(C2O5)2 clusters, and two PdN4H12 clusters. In each Co(C2O5)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent O(3) and four equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Co(1) atom. In each PdN4H12 cluster, Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_CoH12PdC4(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.008
_cell_length_b   9.008
_cell_length_c   7.183
_cell_angle_alpha   66.787
_cell_angle_beta   66.787
_cell_angle_gamma   111.209
_symmetry_Int_Tables_number   1
_cell_volume   389.231
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.500  1.0
  H  H1  1  0.804  0.995  0.312  1.0
  H  H2  1  0.995  0.804  0.312  1.0
  H  H3  1  0.196  0.005  0.688  1.0
  H  H4  1  0.005  0.196  0.688  1.0
  H  H5  1  0.869  0.187  0.326  1.0
  H  H6  1  0.187  0.869  0.326  1.0
  H  H7  1  0.131  0.813  0.674  1.0
  H  H8  1  0.813  0.131  0.674  1.0
  H  H9  1  0.042  0.214  0.085  1.0
  H  H10  1  0.214  0.042  0.085  1.0
  H  H11  1  0.958  0.786  0.915  1.0
  H  H12  1  0.786  0.958  0.915  1.0
  Pd  Pd13  1  0.000  0.000  0.500  1.0
  C  C14  1  0.429  0.781  0.405  1.0
  C  C15  1  0.781  0.429  0.405  1.0
  C  C16  1  0.571  0.219  0.595  1.0
  C  C17  1  0.219  0.571  0.595  1.0
  N  N18  1  0.919  0.112  0.279  1.0
  N  N19  1  0.112  0.919  0.279  1.0
  N  N20  1  0.081  0.888  0.721  1.0
  N  N21  1  0.888  0.081  0.721  1.0
  O  O22  1  0.584  0.776  0.346  1.0
  O  O23  1  0.776  0.584  0.346  1.0
  O  O24  1  0.416  0.224  0.654  1.0
  O  O25  1  0.224  0.416  0.654  1.0
  O  O26  1  0.442  0.937  0.319  1.0
  O  O27  1  0.937  0.442  0.319  1.0
  O  O28  1  0.558  0.063  0.681  1.0
  O  O29  1  0.063  0.558  0.681  1.0
  O  O30  1  0.459  0.459  0.780  1.0
  O  O31  1  0.541  0.541  0.220  1.0
  O  O32  1  0.643  0.357  0.000  1.0
  O  O33  1  0.357  0.643  0.000  1.0
[/CIF]
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