The structure described by Li2VBO4 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted LiO4 tetrahedra that share corners with two equivalent B(1)O4 tetrahedra, corners with four equivalent Li(2)O4 tetrahedra, corners with four equivalent V(1)O4 tetrahedra, and  an edgeedge with one B(1)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form LiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra, corners with four equivalent V(1)O4 tetrahedra, and corners with four equivalent B(1)O4 tetrahedra. V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra, corners with four equivalent Li(2)O4 tetrahedra, and corners with four equivalent B(1)O4 tetrahedra. B(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form BO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with four equivalent Li(2)O4 tetrahedra, corners with four equivalent V(1)O4 tetrahedra, and  an edgeedge with one Li(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one V(1), and one B(1) atom to form a mixture of distorted edge and corner-sharing OLi2VB trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one Li(2), one V(1), and one B(1) atom to form a mixture of edge and corner-sharing OLi2VB trigonal pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(2), one V(1), and one B(1) atom to form distorted corner-sharing OLi2VB tetrahedra. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one V(1), and one B(1) atom to form corner-sharing OLi2VB tetrahedra. is represented by the CIF file [CIF]
data_Li2VBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.908
_cell_length_b   6.218
_cell_length_c   10.244
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   312.627
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.695  0.867  0.077  1.0
  Li  Li1  1  0.186  0.116  0.157  1.0
  Li  Li2  1  0.686  0.616  0.343  1.0
  Li  Li3  1  0.195  0.367  0.423  1.0
  Li  Li4  1  0.805  0.867  0.577  1.0
  Li  Li5  1  0.314  0.116  0.657  1.0
  Li  Li6  1  0.814  0.616  0.843  1.0
  Li  Li7  1  0.305  0.367  0.923  1.0
  V  V8  1  0.181  0.626  0.164  1.0
  V  V9  1  0.681  0.126  0.336  1.0
  V  V10  1  0.319  0.626  0.664  1.0
  V  V11  1  0.819  0.126  0.836  1.0
  B  B12  1  0.676  0.366  0.091  1.0
  B  B13  1  0.176  0.866  0.409  1.0
  B  B14  1  0.824  0.366  0.591  1.0
  B  B15  1  0.324  0.866  0.909  1.0
  O  O16  1  0.267  0.863  0.053  1.0
  O  O17  1  0.374  0.372  0.110  1.0
  O  O18  1  0.793  0.566  0.152  1.0
  O  O19  1  0.787  0.166  0.154  1.0
  O  O20  1  0.287  0.666  0.346  1.0
  O  O21  1  0.293  0.066  0.348  1.0
  O  O22  1  0.874  0.872  0.390  1.0
  O  O23  1  0.767  0.363  0.447  1.0
  O  O24  1  0.233  0.863  0.553  1.0
  O  O25  1  0.126  0.372  0.610  1.0
  O  O26  1  0.707  0.566  0.652  1.0
  O  O27  1  0.713  0.166  0.654  1.0
  O  O28  1  0.213  0.666  0.846  1.0
  O  O29  1  0.207  0.066  0.848  1.0
  O  O30  1  0.626  0.872  0.890  1.0
  O  O31  1  0.733  0.363  0.947  1.0
[/CIF]
.
The structure described by Li2VBO4 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted LiO4 tetrahedra that share corners with two equivalent B(1)O4 tetrahedra, corners with four equivalent Li(2)O4 tetrahedra, corners with four equivalent V(1)O4 tetrahedra, and  an edgeedge with one B(1)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form LiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra, corners with four equivalent V(1)O4 tetrahedra, and corners with four equivalent B(1)O4 tetrahedra. V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra, corners with four equivalent Li(2)O4 tetrahedra, and corners with four equivalent B(1)O4 tetrahedra. B(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form BO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with four equivalent Li(2)O4 tetrahedra, corners with four equivalent V(1)O4 tetrahedra, and  an edgeedge with one Li(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one V(1), and one B(1) atom to form a mixture of distorted edge and corner-sharing OLi2VB trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one Li(2), one V(1), and one B(1) atom to form a mixture of edge and corner-sharing OLi2VB trigonal pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(2), one V(1), and one B(1) atom to form distorted corner-sharing OLi2VB tetrahedra. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one V(1), and one B(1) atom to form corner-sharing OLi2VB tetrahedra. is represented by the CIF file [CIF]
data_Li2VBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.908
_cell_length_b   6.218
_cell_length_c   10.244
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   312.627
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.695  0.867  0.077  1.0
  Li  Li1  1  0.186  0.116  0.157  1.0
  Li  Li2  1  0.686  0.616  0.343  1.0
  Li  Li3  1  0.195  0.367  0.423  1.0
  Li  Li4  1  0.805  0.867  0.577  1.0
  Li  Li5  1  0.314  0.116  0.657  1.0
  Li  Li6  1  0.814  0.616  0.843  1.0
  Li  Li7  1  0.305  0.367  0.923  1.0
  V  V8  1  0.181  0.626  0.164  1.0
  V  V9  1  0.681  0.126  0.336  1.0
  V  V10  1  0.319  0.626  0.664  1.0
  V  V11  1  0.819  0.126  0.836  1.0
  B  B12  1  0.676  0.366  0.091  1.0
  B  B13  1  0.176  0.866  0.409  1.0
  B  B14  1  0.824  0.366  0.591  1.0
  B  B15  1  0.324  0.866  0.909  1.0
  O  O16  1  0.267  0.863  0.053  1.0
  O  O17  1  0.374  0.372  0.110  1.0
  O  O18  1  0.793  0.566  0.152  1.0
  O  O19  1  0.787  0.166  0.154  1.0
  O  O20  1  0.287  0.666  0.346  1.0
  O  O21  1  0.293  0.066  0.348  1.0
  O  O22  1  0.874  0.872  0.390  1.0
  O  O23  1  0.767  0.363  0.447  1.0
  O  O24  1  0.233  0.863  0.553  1.0
  O  O25  1  0.126  0.372  0.610  1.0
  O  O26  1  0.707  0.566  0.652  1.0
  O  O27  1  0.713  0.166  0.654  1.0
  O  O28  1  0.213  0.666  0.846  1.0
  O  O29  1  0.207  0.066  0.848  1.0
  O  O30  1  0.626  0.872  0.890  1.0
  O  O31  1  0.733  0.363  0.947  1.0
[/CIF]
.