The material structure described by KHo2Cu(MoO4)4 crystallizes in the triclinic P1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one O(10), one O(13), one O(16), one O(17), one O(19), one O(24), one O(26), one O(27), one O(28), and one O(6) atom. In the second K site, K(2) is bonded in a 10-coordinate geometry to one O(11), one O(20), one O(23), one O(3), one O(31), one O(32), one O(4), one O(5), one O(7), and one O(9) atom. There are four inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 8-coordinate geometry to one O(12), one O(15), one O(21), one O(25), one O(26), one O(28), one O(29), and one O(8) atom. In the second Ho site, Ho(2) is bonded in a 8-coordinate geometry to one O(1), one O(14), one O(17), one O(18), one O(2), one O(22), one O(24), and one O(30) atom. In the third Ho site, Ho(3) is bonded in a 8-coordinate geometry to one O(1), one O(14), one O(18), one O(2), one O(22), one O(30), one O(32), and one O(7) atom. In the fourth Ho site, Ho(4) is bonded in a 8-coordinate geometry to one O(12), one O(15), one O(20), one O(21), one O(25), one O(29), one O(4), and one O(8) atom. There are eight inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(2), one O(24), one O(30), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(15), one O(19), one O(26), and one O(27) atom. In the third Mo site, Mo(3) is bonded in a tetrahedral geometry to one O(11), one O(20), one O(25), and one O(29) atom. In the fourth Mo site, Mo(4) is bonded in a tetrahedral geometry to one O(10), one O(14), one O(16), and one O(17) atom. In the fifth Mo site, Mo(5) is bonded in a tetrahedral geometry to one O(1), one O(22), one O(3), and one O(7) atom. In the sixth Mo site, Mo(6) is bonded in a tetrahedral geometry to one O(31), one O(4), one O(8), and one O(9) atom. In the seventh Mo site, Mo(7) is bonded in a tetrahedral geometry to one O(12), one O(13), one O(21), and one O(28) atom. In the eighth Mo site, Mo(8) is bonded in a tetrahedral geometry to one O(18), one O(23), one O(32), and one O(5) atom. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one O(10), one O(13), one O(27), and one O(6) atom. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one O(11), one O(3), one O(5), and one O(9) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one K(2), one Mo(5), and one Cu(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(2), one Ho(4), and one Mo(6) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(2), one Mo(8), and one Cu(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one Mo(1), and one Cu(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one K(2), one Ho(3), and one Mo(5) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(6) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one K(2), one Mo(6), and one Cu(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one K(1), one Mo(4), and one Cu(1) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one K(2), one Mo(3), and one Cu(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(7) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one K(1), one Mo(7), and one Cu(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(2) atom. In the sixteenth O site, O(16) is bonded in a 1-coordinate geometry to one K(1) and one Mo(4) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one K(1), one Ho(2), and one Mo(4) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(8) atom. In the nineteenth O site, O(19) is bonded in a 1-coordinate geometry to one K(1) and one Mo(2) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one K(2), one Ho(4), and one Mo(3) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(7) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(5) atom. In the twenty-third O site, O(23) is bonded in a 1-coordinate geometry to one K(2) and one Mo(8) atom. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one K(1), one Ho(2), and one Mo(1) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(3) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one K(1), one Ho(1), and one Mo(2) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one K(1), one Mo(2), and one Cu(1) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one K(1), one Ho(1), and one Mo(7) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(3) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(1) atom. In the thirty-first O site, O(31) is bonded in a 1-coordinate geometry to one K(2) and one Mo(6) atom. In the thirty-second O site, O(32) is bonded in a distorted bent 120 degrees geometry to one K(2), one Ho(3), and one Mo(8) atom. is represented by the CIF file [CIF]
data_KHo2Cu(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.284
_cell_length_b   6.871
_cell_length_c   19.696
_cell_angle_alpha   88.859
_cell_angle_beta   93.292
_cell_angle_gamma   112.600
_symmetry_Int_Tables_number   1
_cell_volume   659.140
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.973  0.943  0.752  1.0
  K  K1  1  0.027  0.061  0.252  1.0
  Ho  Ho2  1  0.851  0.706  0.531  1.0
  Ho  Ho3  1  0.855  0.706  0.969  1.0
  Ho  Ho4  1  0.146  0.296  0.032  1.0
  Ho  Ho5  1  0.150  0.296  0.468  1.0
  Cu  Cu6  1  0.690  0.382  0.750  1.0
  Cu  Cu7  1  0.309  0.618  0.249  1.0
  Mo  Mo8  1  0.546  0.124  0.909  1.0
  Mo  Mo9  1  0.268  0.518  0.646  1.0
  Mo  Mo10  1  0.421  0.878  0.409  1.0
  Mo  Mo11  1  0.251  0.520  0.854  1.0
  Mo  Mo12  1  0.454  0.877  0.092  1.0
  Mo  Mo13  1  0.732  0.484  0.353  1.0
  Mo  Mo14  1  0.580  0.125  0.591  1.0
  Mo  Mo15  1  0.750  0.484  0.147  1.0
  O  O16  1  0.216  0.962  0.037  1.0
  O  O17  1  0.507  0.339  0.959  1.0
  O  O18  1  0.303  0.820  0.172  1.0
  O  O19  1  0.907  0.304  0.369  1.0
  O  O20  1  0.931  0.405  0.215  1.0
  O  O21  1  0.696  0.180  0.828  1.0
  O  O22  1  0.777  0.097  0.101  1.0
  O  O23  1  0.582  0.521  0.434  1.0
  O  O24  1  0.471  0.404  0.286  1.0
  O  O25  1  0.068  0.597  0.787  1.0
  O  O26  1  0.512  0.815  0.329  1.0
  O  O27  1  0.840  0.340  0.542  1.0
  O  O28  1  0.487  0.183  0.671  1.0
  O  O29  1  0.060  0.479  0.934  1.0
  O  O30  1  0.423  0.477  0.567  1.0
  O  O31  1  0.270  0.281  0.828  1.0
  O  O32  1  0.604  0.701  0.871  1.0
  O  O33  1  0.943  0.524  0.067  1.0
  O  O34  1  0.016  0.278  0.673  1.0
  O  O35  1  0.321  0.098  0.399  1.0
  O  O36  1  0.259  0.040  0.536  1.0
  O  O37  1  0.495  0.662  0.042  1.0
  O  O38  1  0.733  0.723  0.173  1.0
  O  O39  1  0.223  0.904  0.900  1.0
  O  O40  1  0.745  0.962  0.462  1.0
  O  O41  1  0.093  0.698  0.630  1.0
  O  O42  1  0.529  0.600  0.714  1.0
  O  O43  1  0.680  0.904  0.599  1.0
  O  O44  1  0.167  0.662  0.458  1.0
  O  O45  1  0.784  0.040  0.963  1.0
  O  O46  1  0.986  0.726  0.329  1.0
  O  O47  1  0.396  0.303  0.130  1.0
[/CIF]
.
The material structure described by KHo2Cu(MoO4)4 crystallizes in the triclinic P1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one O(10), one O(13), one O(16), one O(17), one O(19), one O(24), one O(26), one O(27), one O(28), and one O(6) atom. In the second K site, K(2) is bonded in a 10-coordinate geometry to one O(11), one O(20), one O(23), one O(3), one O(31), one O(32), one O(4), one O(5), one O(7), and one O(9) atom. There are four inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 8-coordinate geometry to one O(12), one O(15), one O(21), one O(25), one O(26), one O(28), one O(29), and one O(8) atom. In the second Ho site, Ho(2) is bonded in a 8-coordinate geometry to one O(1), one O(14), one O(17), one O(18), one O(2), one O(22), one O(24), and one O(30) atom. In the third Ho site, Ho(3) is bonded in a 8-coordinate geometry to one O(1), one O(14), one O(18), one O(2), one O(22), one O(30), one O(32), and one O(7) atom. In the fourth Ho site, Ho(4) is bonded in a 8-coordinate geometry to one O(12), one O(15), one O(20), one O(21), one O(25), one O(29), one O(4), and one O(8) atom. There are eight inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(2), one O(24), one O(30), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(15), one O(19), one O(26), and one O(27) atom. In the third Mo site, Mo(3) is bonded in a tetrahedral geometry to one O(11), one O(20), one O(25), and one O(29) atom. In the fourth Mo site, Mo(4) is bonded in a tetrahedral geometry to one O(10), one O(14), one O(16), and one O(17) atom. In the fifth Mo site, Mo(5) is bonded in a tetrahedral geometry to one O(1), one O(22), one O(3), and one O(7) atom. In the sixth Mo site, Mo(6) is bonded in a tetrahedral geometry to one O(31), one O(4), one O(8), and one O(9) atom. In the seventh Mo site, Mo(7) is bonded in a tetrahedral geometry to one O(12), one O(13), one O(21), and one O(28) atom. In the eighth Mo site, Mo(8) is bonded in a tetrahedral geometry to one O(18), one O(23), one O(32), and one O(5) atom. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one O(10), one O(13), one O(27), and one O(6) atom. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one O(11), one O(3), one O(5), and one O(9) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one K(2), one Mo(5), and one Cu(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(2), one Ho(4), and one Mo(6) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(2), one Mo(8), and one Cu(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one Mo(1), and one Cu(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one K(2), one Ho(3), and one Mo(5) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(6) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one K(2), one Mo(6), and one Cu(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one K(1), one Mo(4), and one Cu(1) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one K(2), one Mo(3), and one Cu(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(7) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one K(1), one Mo(7), and one Cu(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(2) atom. In the sixteenth O site, O(16) is bonded in a 1-coordinate geometry to one K(1) and one Mo(4) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one K(1), one Ho(2), and one Mo(4) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(8) atom. In the nineteenth O site, O(19) is bonded in a 1-coordinate geometry to one K(1) and one Mo(2) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one K(2), one Ho(4), and one Mo(3) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(7) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(5) atom. In the twenty-third O site, O(23) is bonded in a 1-coordinate geometry to one K(2) and one Mo(8) atom. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one K(1), one Ho(2), and one Mo(1) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(3) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one K(1), one Ho(1), and one Mo(2) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one K(1), one Mo(2), and one Cu(1) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one K(1), one Ho(1), and one Mo(7) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Ho(1), one Ho(4), and one Mo(3) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Ho(2), one Ho(3), and one Mo(1) atom. In the thirty-first O site, O(31) is bonded in a 1-coordinate geometry to one K(2) and one Mo(6) atom. In the thirty-second O site, O(32) is bonded in a distorted bent 120 degrees geometry to one K(2), one Ho(3), and one Mo(8) atom. is represented by the CIF file [CIF]
data_KHo2Cu(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.284
_cell_length_b   6.871
_cell_length_c   19.696
_cell_angle_alpha   88.859
_cell_angle_beta   93.292
_cell_angle_gamma   112.600
_symmetry_Int_Tables_number   1
_cell_volume   659.140
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.973  0.943  0.752  1.0
  K  K1  1  0.027  0.061  0.252  1.0
  Ho  Ho2  1  0.851  0.706  0.531  1.0
  Ho  Ho3  1  0.855  0.706  0.969  1.0
  Ho  Ho4  1  0.146  0.296  0.032  1.0
  Ho  Ho5  1  0.150  0.296  0.468  1.0
  Cu  Cu6  1  0.690  0.382  0.750  1.0
  Cu  Cu7  1  0.309  0.618  0.249  1.0
  Mo  Mo8  1  0.546  0.124  0.909  1.0
  Mo  Mo9  1  0.268  0.518  0.646  1.0
  Mo  Mo10  1  0.421  0.878  0.409  1.0
  Mo  Mo11  1  0.251  0.520  0.854  1.0
  Mo  Mo12  1  0.454  0.877  0.092  1.0
  Mo  Mo13  1  0.732  0.484  0.353  1.0
  Mo  Mo14  1  0.580  0.125  0.591  1.0
  Mo  Mo15  1  0.750  0.484  0.147  1.0
  O  O16  1  0.216  0.962  0.037  1.0
  O  O17  1  0.507  0.339  0.959  1.0
  O  O18  1  0.303  0.820  0.172  1.0
  O  O19  1  0.907  0.304  0.369  1.0
  O  O20  1  0.931  0.405  0.215  1.0
  O  O21  1  0.696  0.180  0.828  1.0
  O  O22  1  0.777  0.097  0.101  1.0
  O  O23  1  0.582  0.521  0.434  1.0
  O  O24  1  0.471  0.404  0.286  1.0
  O  O25  1  0.068  0.597  0.787  1.0
  O  O26  1  0.512  0.815  0.329  1.0
  O  O27  1  0.840  0.340  0.542  1.0
  O  O28  1  0.487  0.183  0.671  1.0
  O  O29  1  0.060  0.479  0.934  1.0
  O  O30  1  0.423  0.477  0.567  1.0
  O  O31  1  0.270  0.281  0.828  1.0
  O  O32  1  0.604  0.701  0.871  1.0
  O  O33  1  0.943  0.524  0.067  1.0
  O  O34  1  0.016  0.278  0.673  1.0
  O  O35  1  0.321  0.098  0.399  1.0
  O  O36  1  0.259  0.040  0.536  1.0
  O  O37  1  0.495  0.662  0.042  1.0
  O  O38  1  0.733  0.723  0.173  1.0
  O  O39  1  0.223  0.904  0.900  1.0
  O  O40  1  0.745  0.962  0.462  1.0
  O  O41  1  0.093  0.698  0.630  1.0
  O  O42  1  0.529  0.600  0.714  1.0
  O  O43  1  0.680  0.904  0.599  1.0
  O  O44  1  0.167  0.662  0.458  1.0
  O  O45  1  0.784  0.040  0.963  1.0
  O  O46  1  0.986  0.726  0.329  1.0
  O  O47  1  0.396  0.303  0.130  1.0
[/CIF]
.