The structure described by UPO6Cl crystallizes in the tetragonal I-4 space group. U(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one Cl(1) atom to form distorted UClO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent U(1)ClO6 octahedra. The corner-sharing octahedral tilt angles range from 14-36°. There are six inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one U(1) and one P(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one U(1) and one P(1) atom. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one U(1) and one P(1) atom. In the fourth O site, O(6) is bonded in a distorted linear geometry to one U(1) and one P(1) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one U(1) atom. Cl(1) is bonded in a single-bond geometry to one U(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_UPClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.417
_cell_length_b   10.417
_cell_length_c   10.417
_cell_angle_alpha   96.415
_cell_angle_beta   96.415
_cell_angle_gamma   140.944
_symmetry_Int_Tables_number   1
_cell_volume   671.319
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.366  0.172  0.559  1.0
  U  U1  1  0.613  0.807  0.441  1.0
  U  U2  1  0.193  0.634  0.806  1.0
  U  U3  1  0.828  0.387  0.194  1.0
  P  P4  1  0.656  0.197  0.828  1.0
  P  P5  1  0.368  0.827  0.172  1.0
  P  P6  1  0.173  0.344  0.541  1.0
  P  P7  1  0.803  0.632  0.459  1.0
  Cl  Cl8  1  0.240  0.141  0.822  1.0
  Cl  Cl9  1  0.319  0.418  0.178  1.0
  Cl  Cl10  1  0.859  0.681  0.099  1.0
  Cl  Cl11  1  0.582  0.760  0.901  1.0
  O  O12  1  0.406  0.048  0.452  1.0
  O  O13  1  0.596  0.954  0.548  1.0
  O  O14  1  0.046  0.594  0.642  1.0
  O  O15  1  0.952  0.404  0.358  1.0
  O  O16  1  0.237  0.102  0.373  1.0
  O  O17  1  0.729  0.864  0.627  1.0
  O  O18  1  0.136  0.763  0.866  1.0
  O  O19  1  0.898  0.271  0.134  1.0
  O  O20  1  0.041  0.842  0.541  1.0
  O  O21  1  0.301  0.501  0.459  1.0
  O  O22  1  0.874  0.323  0.820  1.0
  O  O23  1  0.503  0.054  0.180  1.0
  O  O24  1  0.946  0.126  0.448  1.0
  O  O25  1  0.677  0.497  0.552  1.0
  O  O26  1  0.158  0.699  0.200  1.0
  O  O27  1  0.499  0.959  0.800  1.0
  O  O28  1  0.293  0.319  0.605  1.0
  O  O29  1  0.714  0.688  0.395  1.0
  O  O30  1  0.312  0.707  0.026  1.0
  O  O31  1  0.681  0.286  0.974  1.0
  O  O32  1  0.561  0.222  0.726  1.0
  O  O33  1  0.496  0.835  0.274  1.0
  O  O34  1  0.165  0.439  0.661  1.0
  O  O35  1  0.778  0.504  0.339  1.0
[/CIF]
.
The structure described by UPO6Cl crystallizes in the tetragonal I-4 space group. U(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one Cl(1) atom to form distorted UClO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent U(1)ClO6 octahedra. The corner-sharing octahedral tilt angles range from 14-36°. There are six inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one U(1) and one P(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one U(1) and one P(1) atom. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one U(1) and one P(1) atom. In the fourth O site, O(6) is bonded in a distorted linear geometry to one U(1) and one P(1) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one U(1) atom. Cl(1) is bonded in a single-bond geometry to one U(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_UPClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.417
_cell_length_b   10.417
_cell_length_c   10.417
_cell_angle_alpha   96.415
_cell_angle_beta   96.415
_cell_angle_gamma   140.944
_symmetry_Int_Tables_number   1
_cell_volume   671.319
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.366  0.172  0.559  1.0
  U  U1  1  0.613  0.807  0.441  1.0
  U  U2  1  0.193  0.634  0.806  1.0
  U  U3  1  0.828  0.387  0.194  1.0
  P  P4  1  0.656  0.197  0.828  1.0
  P  P5  1  0.368  0.827  0.172  1.0
  P  P6  1  0.173  0.344  0.541  1.0
  P  P7  1  0.803  0.632  0.459  1.0
  Cl  Cl8  1  0.240  0.141  0.822  1.0
  Cl  Cl9  1  0.319  0.418  0.178  1.0
  Cl  Cl10  1  0.859  0.681  0.099  1.0
  Cl  Cl11  1  0.582  0.760  0.901  1.0
  O  O12  1  0.406  0.048  0.452  1.0
  O  O13  1  0.596  0.954  0.548  1.0
  O  O14  1  0.046  0.594  0.642  1.0
  O  O15  1  0.952  0.404  0.358  1.0
  O  O16  1  0.237  0.102  0.373  1.0
  O  O17  1  0.729  0.864  0.627  1.0
  O  O18  1  0.136  0.763  0.866  1.0
  O  O19  1  0.898  0.271  0.134  1.0
  O  O20  1  0.041  0.842  0.541  1.0
  O  O21  1  0.301  0.501  0.459  1.0
  O  O22  1  0.874  0.323  0.820  1.0
  O  O23  1  0.503  0.054  0.180  1.0
  O  O24  1  0.946  0.126  0.448  1.0
  O  O25  1  0.677  0.497  0.552  1.0
  O  O26  1  0.158  0.699  0.200  1.0
  O  O27  1  0.499  0.959  0.800  1.0
  O  O28  1  0.293  0.319  0.605  1.0
  O  O29  1  0.714  0.688  0.395  1.0
  O  O30  1  0.312  0.707  0.026  1.0
  O  O31  1  0.681  0.286  0.974  1.0
  O  O32  1  0.561  0.222  0.726  1.0
  O  O33  1  0.496  0.835  0.274  1.0
  O  O34  1  0.165  0.439  0.661  1.0
  O  O35  1  0.778  0.504  0.339  1.0
[/CIF]
.