The compound described by Li7(SbS)2 crystallizes in the orthorhombic Pnma space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to one Li(2), one Li(3), one Li(4), two equivalent Li(1), two equivalent Li(5), and one Sb(2) atom. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to one Li(2), one Li(3), one Li(4), two equivalent Li(1), two equivalent Li(5), and one Sb(1) atom. S(1) is bonded to one Li(2), one Li(3), one Li(4), two equivalent Li(1), and two equivalent Li(5) atoms to form a mixture of distorted corner and edge-sharing SLi7 pentagonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li7(SbS)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.517
_cell_length_b   8.700
_cell_length_c   13.191
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   862.646
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.169  0.508  0.544  1.0
  Li  Li1  1  0.169  0.992  0.544  1.0
  Li  Li2  1  0.758  0.250  0.585  1.0
  Li  Li3  1  0.811  0.750  0.613  1.0
  Li  Li4  1  0.051  0.250  0.685  1.0
  Li  Li5  1  0.585  0.472  0.708  1.0
  Li  Li6  1  0.585  0.028  0.708  1.0
  Li  Li7  1  0.085  0.528  0.792  1.0
  Li  Li8  1  0.085  0.972  0.792  1.0
  Li  Li9  1  0.551  0.750  0.815  1.0
  Li  Li10  1  0.311  0.250  0.887  1.0
  Li  Li11  1  0.258  0.750  0.915  1.0
  Li  Li12  1  0.669  0.492  0.956  1.0
  Li  Li13  1  0.669  0.008  0.956  1.0
  Li  Li14  1  0.331  0.508  0.044  1.0
  Li  Li15  1  0.331  0.992  0.044  1.0
  Li  Li16  1  0.742  0.250  0.085  1.0
  Li  Li17  1  0.689  0.750  0.113  1.0
  Li  Li18  1  0.449  0.250  0.185  1.0
  Li  Li19  1  0.915  0.472  0.208  1.0
  Li  Li20  1  0.915  0.028  0.208  1.0
  Li  Li21  1  0.415  0.528  0.292  1.0
  Li  Li22  1  0.415  0.972  0.292  1.0
  Li  Li23  1  0.949  0.750  0.315  1.0
  Li  Li24  1  0.189  0.250  0.387  1.0
  Li  Li25  1  0.242  0.750  0.415  1.0
  Li  Li26  1  0.831  0.492  0.456  1.0
  Li  Li27  1  0.831  0.008  0.456  1.0
  Sb  Sb28  1  0.427  0.750  0.599  1.0
  Sb  Sb29  1  0.396  0.250  0.586  1.0
  Sb  Sb30  1  0.896  0.750  0.914  1.0
  Sb  Sb31  1  0.927  0.250  0.901  1.0
  Sb  Sb32  1  0.073  0.750  0.099  1.0
  Sb  Sb33  1  0.104  0.250  0.086  1.0
  Sb  Sb34  1  0.604  0.750  0.414  1.0
  Sb  Sb35  1  0.573  0.250  0.401  1.0
  S  S36  1  0.899  0.018  0.640  1.0
  S  S37  1  0.899  0.482  0.640  1.0
  S  S38  1  0.399  0.982  0.860  1.0
  S  S39  1  0.399  0.518  0.860  1.0
  S  S40  1  0.601  0.018  0.140  1.0
  S  S41  1  0.601  0.482  0.140  1.0
  S  S42  1  0.101  0.982  0.360  1.0
  S  S43  1  0.101  0.518  0.360  1.0
[/CIF]
.
The compound described by Li7(SbS)2 crystallizes in the orthorhombic Pnma space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one Sb(1), one Sb(2), and two equivalent S(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to one Li(2), one Li(3), one Li(4), two equivalent Li(1), two equivalent Li(5), and one Sb(2) atom. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to one Li(2), one Li(3), one Li(4), two equivalent Li(1), two equivalent Li(5), and one Sb(1) atom. S(1) is bonded to one Li(2), one Li(3), one Li(4), two equivalent Li(1), and two equivalent Li(5) atoms to form a mixture of distorted corner and edge-sharing SLi7 pentagonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li7(SbS)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.517
_cell_length_b   8.700
_cell_length_c   13.191
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   862.646
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.169  0.508  0.544  1.0
  Li  Li1  1  0.169  0.992  0.544  1.0
  Li  Li2  1  0.758  0.250  0.585  1.0
  Li  Li3  1  0.811  0.750  0.613  1.0
  Li  Li4  1  0.051  0.250  0.685  1.0
  Li  Li5  1  0.585  0.472  0.708  1.0
  Li  Li6  1  0.585  0.028  0.708  1.0
  Li  Li7  1  0.085  0.528  0.792  1.0
  Li  Li8  1  0.085  0.972  0.792  1.0
  Li  Li9  1  0.551  0.750  0.815  1.0
  Li  Li10  1  0.311  0.250  0.887  1.0
  Li  Li11  1  0.258  0.750  0.915  1.0
  Li  Li12  1  0.669  0.492  0.956  1.0
  Li  Li13  1  0.669  0.008  0.956  1.0
  Li  Li14  1  0.331  0.508  0.044  1.0
  Li  Li15  1  0.331  0.992  0.044  1.0
  Li  Li16  1  0.742  0.250  0.085  1.0
  Li  Li17  1  0.689  0.750  0.113  1.0
  Li  Li18  1  0.449  0.250  0.185  1.0
  Li  Li19  1  0.915  0.472  0.208  1.0
  Li  Li20  1  0.915  0.028  0.208  1.0
  Li  Li21  1  0.415  0.528  0.292  1.0
  Li  Li22  1  0.415  0.972  0.292  1.0
  Li  Li23  1  0.949  0.750  0.315  1.0
  Li  Li24  1  0.189  0.250  0.387  1.0
  Li  Li25  1  0.242  0.750  0.415  1.0
  Li  Li26  1  0.831  0.492  0.456  1.0
  Li  Li27  1  0.831  0.008  0.456  1.0
  Sb  Sb28  1  0.427  0.750  0.599  1.0
  Sb  Sb29  1  0.396  0.250  0.586  1.0
  Sb  Sb30  1  0.896  0.750  0.914  1.0
  Sb  Sb31  1  0.927  0.250  0.901  1.0
  Sb  Sb32  1  0.073  0.750  0.099  1.0
  Sb  Sb33  1  0.104  0.250  0.086  1.0
  Sb  Sb34  1  0.604  0.750  0.414  1.0
  Sb  Sb35  1  0.573  0.250  0.401  1.0
  S  S36  1  0.899  0.018  0.640  1.0
  S  S37  1  0.899  0.482  0.640  1.0
  S  S38  1  0.399  0.982  0.860  1.0
  S  S39  1  0.399  0.518  0.860  1.0
  S  S40  1  0.601  0.018  0.140  1.0
  S  S41  1  0.601  0.482  0.140  1.0
  S  S42  1  0.101  0.982  0.360  1.0
  S  S43  1  0.101  0.518  0.360  1.0
[/CIF]
.