The structure described by RbRe3Br10 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Br(1), two equivalent Br(2), two equivalent Br(3), and two equivalent Br(7) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 7-coordinate geometry to one Re(1), one Re(2), one Br(1), one Br(4), one Br(6), and two equivalent Br(5) atoms. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to two equivalent Re(1), one Br(2), one Br(3), one Br(7), and two equivalent Br(4) atoms. There are seven inequivalent Br sites. In the first Br site, Br(1) is bonded in a bent 120 degrees geometry to one Rb(1) and one Re(1) atom. In the second Br site, Br(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Re(2) atom. In the third Br site, Br(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rb(1) and one Re(2) atom. In the fourth Br site, Br(4) is bonded in a 2-coordinate geometry to one Re(1) and one Re(2) atom. In the fifth Br site, Br(5) is bonded in a water-like geometry to two equivalent Re(1) atoms. In the sixth Br site, Br(6) is bonded in a 2-coordinate geometry to two equivalent Re(1) atoms. In the seventh Br site, Br(7) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Re(2) atom. is represented by the CIF file [CIF]
data_RbRe3Br10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.318
_cell_length_b   9.318
_cell_length_c   10.570
_cell_angle_alpha   88.346
_cell_angle_beta   88.351
_cell_angle_gamma   72.128
_symmetry_Int_Tables_number   1
_cell_volume   872.997
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.784  0.216  0.000  1.0
  Rb  Rb1  1  0.216  0.784  0.000  1.0
  Re  Re2  1  0.409  0.187  0.372  1.0
  Re  Re3  1  0.813  0.591  0.628  1.0
  Re  Re4  1  0.187  0.409  0.372  1.0
  Re  Re5  1  0.591  0.813  0.628  1.0
  Re  Re6  1  0.237  0.237  0.193  1.0
  Re  Re7  1  0.763  0.763  0.807  1.0
  Br  Br8  1  0.291  0.608  0.299  1.0
  Br  Br9  1  0.923  0.923  0.740  1.0
  Br  Br10  1  0.077  0.077  0.260  1.0
  Br  Br11  1  0.159  0.159  0.963  1.0
  Br  Br12  1  0.529  0.997  0.812  1.0
  Br  Br13  1  0.999  0.678  0.497  1.0
  Br  Br14  1  0.709  0.392  0.701  1.0
  Br  Br15  1  0.359  0.359  0.563  1.0
  Br  Br16  1  0.322  0.001  0.503  1.0
  Br  Br17  1  0.471  0.003  0.188  1.0
  Br  Br18  1  0.392  0.709  0.701  1.0
  Br  Br19  1  0.608  0.291  0.299  1.0
  Br  Br20  1  0.631  0.631  0.955  1.0
  Br  Br21  1  0.997  0.529  0.812  1.0
  Br  Br22  1  0.841  0.841  0.037  1.0
  Br  Br23  1  0.678  0.999  0.497  1.0
  Br  Br24  1  0.369  0.369  0.045  1.0
  Br  Br25  1  0.003  0.471  0.188  1.0
  Br  Br26  1  0.641  0.641  0.437  1.0
  Br  Br27  1  0.001  0.322  0.503  1.0
[/CIF]
.
The structure described by RbRe3Br10 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Br(1), two equivalent Br(2), two equivalent Br(3), and two equivalent Br(7) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 7-coordinate geometry to one Re(1), one Re(2), one Br(1), one Br(4), one Br(6), and two equivalent Br(5) atoms. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to two equivalent Re(1), one Br(2), one Br(3), one Br(7), and two equivalent Br(4) atoms. There are seven inequivalent Br sites. In the first Br site, Br(1) is bonded in a bent 120 degrees geometry to one Rb(1) and one Re(1) atom. In the second Br site, Br(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Re(2) atom. In the third Br site, Br(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rb(1) and one Re(2) atom. In the fourth Br site, Br(4) is bonded in a 2-coordinate geometry to one Re(1) and one Re(2) atom. In the fifth Br site, Br(5) is bonded in a water-like geometry to two equivalent Re(1) atoms. In the sixth Br site, Br(6) is bonded in a 2-coordinate geometry to two equivalent Re(1) atoms. In the seventh Br site, Br(7) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Re(2) atom. is represented by the CIF file [CIF]
data_RbRe3Br10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.318
_cell_length_b   9.318
_cell_length_c   10.570
_cell_angle_alpha   88.346
_cell_angle_beta   88.351
_cell_angle_gamma   72.128
_symmetry_Int_Tables_number   1
_cell_volume   872.997
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.784  0.216  0.000  1.0
  Rb  Rb1  1  0.216  0.784  0.000  1.0
  Re  Re2  1  0.409  0.187  0.372  1.0
  Re  Re3  1  0.813  0.591  0.628  1.0
  Re  Re4  1  0.187  0.409  0.372  1.0
  Re  Re5  1  0.591  0.813  0.628  1.0
  Re  Re6  1  0.237  0.237  0.193  1.0
  Re  Re7  1  0.763  0.763  0.807  1.0
  Br  Br8  1  0.291  0.608  0.299  1.0
  Br  Br9  1  0.923  0.923  0.740  1.0
  Br  Br10  1  0.077  0.077  0.260  1.0
  Br  Br11  1  0.159  0.159  0.963  1.0
  Br  Br12  1  0.529  0.997  0.812  1.0
  Br  Br13  1  0.999  0.678  0.497  1.0
  Br  Br14  1  0.709  0.392  0.701  1.0
  Br  Br15  1  0.359  0.359  0.563  1.0
  Br  Br16  1  0.322  0.001  0.503  1.0
  Br  Br17  1  0.471  0.003  0.188  1.0
  Br  Br18  1  0.392  0.709  0.701  1.0
  Br  Br19  1  0.608  0.291  0.299  1.0
  Br  Br20  1  0.631  0.631  0.955  1.0
  Br  Br21  1  0.997  0.529  0.812  1.0
  Br  Br22  1  0.841  0.841  0.037  1.0
  Br  Br23  1  0.678  0.999  0.497  1.0
  Br  Br24  1  0.369  0.369  0.045  1.0
  Br  Br25  1  0.003  0.471  0.188  1.0
  Br  Br26  1  0.641  0.641  0.437  1.0
  Br  Br27  1  0.001  0.322  0.503  1.0
[/CIF]
.