The structure described by PdSCl is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two PdSCl clusters. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a rectangular see-saw-like geometry to one S(2), one S(3), one Cl(3), and one Cl(4) atom. In the second Pd site, Pd(2) is bonded in a rectangular see-saw-like geometry to one S(2), one S(3), one Cl(1), and one Cl(2) atom. In the third Pd site, Pd(3) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent Cl(3) atoms. In the fourth Pd site, Pd(4) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent Cl(1) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Pd(3), one Pd(4), and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Pd(1), one Pd(2), and one S(1) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one Pd(1), one Pd(2), and one S(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted L-shaped geometry to one Pd(2) and one Pd(4) atom. In the second Cl site, Cl(2) is bonded in a distorted L-shaped geometry to two equivalent Pd(2) atoms. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one Pd(1) and one Pd(3) atom. In the fourth Cl site, Cl(4) is bonded in a distorted L-shaped geometry to two equivalent Pd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_PdSCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.803
_cell_length_b   9.397
_cell_length_c   11.993
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.954
_symmetry_Int_Tables_number   1
_cell_volume   826.631
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.888  0.898  0.371  1.0
  Pd  Pd1  1  0.112  0.102  0.871  1.0
  Pd  Pd2  1  0.112  0.102  0.629  1.0
  Pd  Pd3  1  0.888  0.898  0.129  1.0
  Pd  Pd4  1  0.590  0.557  0.373  1.0
  Pd  Pd5  1  0.410  0.443  0.873  1.0
  Pd  Pd6  1  0.410  0.443  0.627  1.0
  Pd  Pd7  1  0.590  0.557  0.127  1.0
  Pd  Pd8  1  0.144  0.790  0.250  1.0
  Pd  Pd9  1  0.856  0.210  0.750  1.0
  Pd  Pd10  1  0.843  0.449  0.250  1.0
  Pd  Pd11  1  0.157  0.551  0.750  1.0
  S  S12  1  0.037  0.601  0.123  1.0
  S  S13  1  0.147  0.320  0.533  1.0
  S  S14  1  0.853  0.680  0.033  1.0
  S  S15  1  0.963  0.399  0.623  1.0
  S  S16  1  0.853  0.680  0.467  1.0
  S  S17  1  0.037  0.601  0.377  1.0
  S  S18  1  0.963  0.399  0.877  1.0
  S  S19  1  0.583  0.794  0.339  1.0
  S  S20  1  0.417  0.206  0.839  1.0
  S  S21  1  0.417  0.206  0.661  1.0
  S  S22  1  0.583  0.794  0.161  1.0
  S  S23  1  0.147  0.320  0.967  1.0
  Cl  Cl24  1  0.638  0.321  0.395  1.0
  Cl  Cl25  1  0.638  0.321  0.105  1.0
  Cl  Cl26  1  0.362  0.679  0.605  1.0
  Cl  Cl27  1  0.335  0.450  0.250  1.0
  Cl  Cl28  1  0.665  0.550  0.750  1.0
  Cl  Cl29  1  0.787  0.025  0.895  1.0
  Cl  Cl30  1  0.095  0.895  0.750  1.0
  Cl  Cl31  1  0.213  0.975  0.105  1.0
  Cl  Cl32  1  0.787  0.025  0.605  1.0
  Cl  Cl33  1  0.905  0.105  0.250  1.0
  Cl  Cl34  1  0.362  0.679  0.895  1.0
  Cl  Cl35  1  0.213  0.975  0.395  1.0
[/CIF]
.
The structure described by PdSCl is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two PdSCl clusters. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a rectangular see-saw-like geometry to one S(2), one S(3), one Cl(3), and one Cl(4) atom. In the second Pd site, Pd(2) is bonded in a rectangular see-saw-like geometry to one S(2), one S(3), one Cl(1), and one Cl(2) atom. In the third Pd site, Pd(3) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent Cl(3) atoms. In the fourth Pd site, Pd(4) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent Cl(1) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Pd(3), one Pd(4), and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Pd(1), one Pd(2), and one S(1) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one Pd(1), one Pd(2), and one S(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted L-shaped geometry to one Pd(2) and one Pd(4) atom. In the second Cl site, Cl(2) is bonded in a distorted L-shaped geometry to two equivalent Pd(2) atoms. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one Pd(1) and one Pd(3) atom. In the fourth Cl site, Cl(4) is bonded in a distorted L-shaped geometry to two equivalent Pd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_PdSCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.803
_cell_length_b   9.397
_cell_length_c   11.993
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.954
_symmetry_Int_Tables_number   1
_cell_volume   826.631
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.888  0.898  0.371  1.0
  Pd  Pd1  1  0.112  0.102  0.871  1.0
  Pd  Pd2  1  0.112  0.102  0.629  1.0
  Pd  Pd3  1  0.888  0.898  0.129  1.0
  Pd  Pd4  1  0.590  0.557  0.373  1.0
  Pd  Pd5  1  0.410  0.443  0.873  1.0
  Pd  Pd6  1  0.410  0.443  0.627  1.0
  Pd  Pd7  1  0.590  0.557  0.127  1.0
  Pd  Pd8  1  0.144  0.790  0.250  1.0
  Pd  Pd9  1  0.856  0.210  0.750  1.0
  Pd  Pd10  1  0.843  0.449  0.250  1.0
  Pd  Pd11  1  0.157  0.551  0.750  1.0
  S  S12  1  0.037  0.601  0.123  1.0
  S  S13  1  0.147  0.320  0.533  1.0
  S  S14  1  0.853  0.680  0.033  1.0
  S  S15  1  0.963  0.399  0.623  1.0
  S  S16  1  0.853  0.680  0.467  1.0
  S  S17  1  0.037  0.601  0.377  1.0
  S  S18  1  0.963  0.399  0.877  1.0
  S  S19  1  0.583  0.794  0.339  1.0
  S  S20  1  0.417  0.206  0.839  1.0
  S  S21  1  0.417  0.206  0.661  1.0
  S  S22  1  0.583  0.794  0.161  1.0
  S  S23  1  0.147  0.320  0.967  1.0
  Cl  Cl24  1  0.638  0.321  0.395  1.0
  Cl  Cl25  1  0.638  0.321  0.105  1.0
  Cl  Cl26  1  0.362  0.679  0.605  1.0
  Cl  Cl27  1  0.335  0.450  0.250  1.0
  Cl  Cl28  1  0.665  0.550  0.750  1.0
  Cl  Cl29  1  0.787  0.025  0.895  1.0
  Cl  Cl30  1  0.095  0.895  0.750  1.0
  Cl  Cl31  1  0.213  0.975  0.105  1.0
  Cl  Cl32  1  0.787  0.025  0.605  1.0
  Cl  Cl33  1  0.905  0.105  0.250  1.0
  Cl  Cl34  1  0.362  0.679  0.895  1.0
  Cl  Cl35  1  0.213  0.975  0.395  1.0
[/CIF]
.