The crystal structure described by MgVSbO4 crystallizes in the orthorhombic Amm2 space group. Mg(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form distorted MgO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra, corners with two equivalent Mg(1)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-51°. V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with four equivalent Mg(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and  an edgeedge with one Mg(1)O4 tetrahedra. Sb(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to two equivalent Mg(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mg(1), one V(1), and two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_MgVSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.141
_cell_length_b   5.550
_cell_length_c   5.550
_cell_angle_alpha   106.803
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   92.626
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.290  0.710  1.0
  V  V1  1  0.000  0.976  0.024  1.0
  Sb  Sb2  1  0.500  0.594  0.406  1.0
  O  O3  1  0.500  0.151  0.849  1.0
  O  O4  1  0.500  0.835  0.165  1.0
  O  O5  1  0.000  0.280  0.336  1.0
  O  O6  1  0.000  0.664  0.720  1.0
[/CIF]
.
The crystal structure described by MgVSbO4 crystallizes in the orthorhombic Amm2 space group. Mg(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form distorted MgO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra, corners with two equivalent Mg(1)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-51°. V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with four equivalent Mg(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and  an edgeedge with one Mg(1)O4 tetrahedra. Sb(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to two equivalent Mg(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mg(1), one V(1), and two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_MgVSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.141
_cell_length_b   5.550
_cell_length_c   5.550
_cell_angle_alpha   106.803
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   92.626
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.290  0.710  1.0
  V  V1  1  0.000  0.976  0.024  1.0
  Sb  Sb2  1  0.500  0.594  0.406  1.0
  O  O3  1  0.500  0.151  0.849  1.0
  O  O4  1  0.500  0.835  0.165  1.0
  O  O5  1  0.000  0.280  0.336  1.0
  O  O6  1  0.000  0.664  0.720  1.0
[/CIF]
.