The material structure described by RbCdC3(NS)3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to one C(2), one N(1), one N(2), one N(3), one S(2), two equivalent S(1), and two equivalent S(3) atoms. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent S(1) atoms. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent S(2), and two equivalent S(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Rb(1), one N(2), and one S(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Cd(2), and one C(2) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(1), and one C(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(2), and one C(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(2), and one C(3) atom. is represented by the CIF card [CIF]
data_RbCdC3(SN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.664
_cell_length_b   5.808
_cell_length_c   13.890
_cell_angle_alpha   68.491
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1025.506
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.285  0.090  0.287  1.0
  Rb  Rb1  1  0.785  0.910  0.213  1.0
  Rb  Rb2  1  0.715  0.910  0.713  1.0
  Rb  Rb3  1  0.215  0.090  0.787  1.0
  Cd  Cd4  1  0.000  0.000  0.000  1.0
  Cd  Cd5  1  0.500  0.000  0.500  1.0
  Cd  Cd6  1  0.000  0.500  0.500  1.0
  Cd  Cd7  1  0.500  0.500  0.000  1.0
  C  C8  1  0.128  0.510  0.990  1.0
  C  C9  1  0.628  0.490  0.510  1.0
  C  C10  1  0.872  0.490  0.010  1.0
  C  C11  1  0.372  0.510  0.490  1.0
  C  C12  1  0.405  0.929  0.090  1.0
  C  C13  1  0.905  0.071  0.410  1.0
  C  C14  1  0.595  0.071  0.910  1.0
  C  C15  1  0.095  0.929  0.590  1.0
  C  C16  1  0.056  0.649  0.244  1.0
  C  C17  1  0.556  0.351  0.256  1.0
  C  C18  1  0.944  0.351  0.756  1.0
  C  C19  1  0.444  0.649  0.744  1.0
  S  S20  1  0.170  0.228  0.029  1.0
  S  S21  1  0.670  0.772  0.471  1.0
  S  S22  1  0.830  0.772  0.971  1.0
  S  S23  1  0.330  0.228  0.529  1.0
  S  S24  1  0.350  0.689  0.081  1.0
  S  S25  1  0.850  0.311  0.419  1.0
  S  S26  1  0.650  0.311  0.919  1.0
  S  S27  1  0.150  0.689  0.581  1.0
  S  S28  1  0.130  0.521  0.341  1.0
  S  S29  1  0.630  0.479  0.159  1.0
  S  S30  1  0.870  0.479  0.659  1.0
  S  S31  1  0.370  0.521  0.841  1.0
  N  N32  1  0.401  0.718  0.459  1.0
  N  N33  1  0.901  0.282  0.041  1.0
  N  N34  1  0.599  0.282  0.541  1.0
  N  N35  1  0.099  0.718  0.959  1.0
  N  N36  1  0.442  0.107  0.098  1.0
  N  N37  1  0.942  0.893  0.402  1.0
  N  N38  1  0.558  0.893  0.902  1.0
  N  N39  1  0.058  0.107  0.598  1.0
  N  N40  1  0.002  0.744  0.174  1.0
  N  N41  1  0.502  0.256  0.326  1.0
  N  N42  1  0.998  0.256  0.826  1.0
  N  N43  1  0.498  0.744  0.674  1.0
[/CIF]
.
The material structure described by RbCdC3(NS)3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to one C(2), one N(1), one N(2), one N(3), one S(2), two equivalent S(1), and two equivalent S(3) atoms. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent S(1) atoms. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent S(2), and two equivalent S(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Rb(1), one N(2), and one S(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Cd(2), and one C(2) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(1), and one C(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(2), and one C(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(2), and one C(3) atom. is represented by the CIF card [CIF]
data_RbCdC3(SN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.664
_cell_length_b   5.808
_cell_length_c   13.890
_cell_angle_alpha   68.491
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1025.506
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.285  0.090  0.287  1.0
  Rb  Rb1  1  0.785  0.910  0.213  1.0
  Rb  Rb2  1  0.715  0.910  0.713  1.0
  Rb  Rb3  1  0.215  0.090  0.787  1.0
  Cd  Cd4  1  0.000  0.000  0.000  1.0
  Cd  Cd5  1  0.500  0.000  0.500  1.0
  Cd  Cd6  1  0.000  0.500  0.500  1.0
  Cd  Cd7  1  0.500  0.500  0.000  1.0
  C  C8  1  0.128  0.510  0.990  1.0
  C  C9  1  0.628  0.490  0.510  1.0
  C  C10  1  0.872  0.490  0.010  1.0
  C  C11  1  0.372  0.510  0.490  1.0
  C  C12  1  0.405  0.929  0.090  1.0
  C  C13  1  0.905  0.071  0.410  1.0
  C  C14  1  0.595  0.071  0.910  1.0
  C  C15  1  0.095  0.929  0.590  1.0
  C  C16  1  0.056  0.649  0.244  1.0
  C  C17  1  0.556  0.351  0.256  1.0
  C  C18  1  0.944  0.351  0.756  1.0
  C  C19  1  0.444  0.649  0.744  1.0
  S  S20  1  0.170  0.228  0.029  1.0
  S  S21  1  0.670  0.772  0.471  1.0
  S  S22  1  0.830  0.772  0.971  1.0
  S  S23  1  0.330  0.228  0.529  1.0
  S  S24  1  0.350  0.689  0.081  1.0
  S  S25  1  0.850  0.311  0.419  1.0
  S  S26  1  0.650  0.311  0.919  1.0
  S  S27  1  0.150  0.689  0.581  1.0
  S  S28  1  0.130  0.521  0.341  1.0
  S  S29  1  0.630  0.479  0.159  1.0
  S  S30  1  0.870  0.479  0.659  1.0
  S  S31  1  0.370  0.521  0.841  1.0
  N  N32  1  0.401  0.718  0.459  1.0
  N  N33  1  0.901  0.282  0.041  1.0
  N  N34  1  0.599  0.282  0.541  1.0
  N  N35  1  0.099  0.718  0.959  1.0
  N  N36  1  0.442  0.107  0.098  1.0
  N  N37  1  0.942  0.893  0.402  1.0
  N  N38  1  0.558  0.893  0.902  1.0
  N  N39  1  0.058  0.107  0.598  1.0
  N  N40  1  0.002  0.744  0.174  1.0
  N  N41  1  0.502  0.256  0.326  1.0
  N  N42  1  0.998  0.256  0.826  1.0
  N  N43  1  0.498  0.744  0.674  1.0
[/CIF]
.