The crystal structure described by SrCo3(P2O7)2 crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a distorted body-centered cubic geometry to two equivalent O(1), two equivalent O(2), two equivalent O(5), and two equivalent O(7) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent Co(2)O6 octahedra. In the second Co site, Co(2) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-60°. In the second P site, P(2) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-59°. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one Co(1), one Co(2), and one P(2) atom. In the second O site, O(6) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one P(1) atom. In the third O site, O(7) is bonded in a 3-coordinate geometry to one Sr(1), one Co(2), and one P(2) atom. In the fourth O site, O(1) is bonded in a 3-coordinate geometry to one Sr(1), one Co(2), and one P(2) atom. In the fifth O site, O(2) is bonded in a distorted trigonal planar geometry to one Sr(1), one Co(1), and one P(1) atom. In the sixth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Co(2) and one P(1) atom. is represented by the CIF card [CIF]
data_SrCo3(P2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.809
_cell_length_b   7.561
_cell_length_c   9.615
_cell_angle_alpha   68.030
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.458
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.000  0.500  1.0
  Sr  Sr1  1  0.000  0.000  0.000  1.0
  Co  Co2  1  0.500  0.500  0.500  1.0
  Co  Co3  1  0.000  0.500  0.000  1.0
  Co  Co4  1  0.625  0.314  0.028  1.0
  Co  Co5  1  0.125  0.686  0.472  1.0
  Co  Co6  1  0.375  0.686  0.972  1.0
  Co  Co7  1  0.875  0.314  0.528  1.0
  P  P8  1  0.204  0.388  0.306  1.0
  P  P9  1  0.704  0.612  0.194  1.0
  P  P10  1  0.796  0.612  0.694  1.0
  P  P11  1  0.296  0.388  0.806  1.0
  P  P12  1  0.558  0.104  0.798  1.0
  P  P13  1  0.058  0.896  0.702  1.0
  P  P14  1  0.442  0.896  0.202  1.0
  P  P15  1  0.942  0.104  0.298  1.0
  O  O16  1  0.180  0.877  0.585  1.0
  O  O17  1  0.680  0.123  0.915  1.0
  O  O18  1  0.820  0.123  0.415  1.0
  O  O19  1  0.320  0.877  0.085  1.0
  O  O20  1  0.624  0.657  0.612  1.0
  O  O21  1  0.124  0.343  0.888  1.0
  O  O22  1  0.376  0.343  0.388  1.0
  O  O23  1  0.876  0.657  0.112  1.0
  O  O24  1  0.372  0.182  0.822  1.0
  O  O25  1  0.872  0.818  0.678  1.0
  O  O26  1  0.628  0.818  0.178  1.0
  O  O27  1  0.128  0.182  0.322  1.0
  O  O28  1  0.578  0.527  0.113  1.0
  O  O29  1  0.078  0.473  0.387  1.0
  O  O30  1  0.422  0.473  0.887  1.0
  O  O31  1  0.922  0.527  0.613  1.0
  O  O32  1  0.615  0.228  0.635  1.0
  O  O33  1  0.115  0.772  0.865  1.0
  O  O34  1  0.385  0.772  0.365  1.0
  O  O35  1  0.885  0.228  0.135  1.0
  O  O36  1  0.212  0.498  0.135  1.0
  O  O37  1  0.712  0.502  0.365  1.0
  O  O38  1  0.788  0.502  0.865  1.0
  O  O39  1  0.288  0.498  0.635  1.0
  O  O40  1  0.518  0.902  0.807  1.0
  O  O41  1  0.018  0.098  0.693  1.0
  O  O42  1  0.482  0.098  0.193  1.0
  O  O43  1  0.982  0.902  0.307  1.0
[/CIF]
.
The crystal structure described by SrCo3(P2O7)2 crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a distorted body-centered cubic geometry to two equivalent O(1), two equivalent O(2), two equivalent O(5), and two equivalent O(7) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent Co(2)O6 octahedra. In the second Co site, Co(2) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-60°. In the second P site, P(2) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-59°. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one Co(1), one Co(2), and one P(2) atom. In the second O site, O(6) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one P(1) atom. In the third O site, O(7) is bonded in a 3-coordinate geometry to one Sr(1), one Co(2), and one P(2) atom. In the fourth O site, O(1) is bonded in a 3-coordinate geometry to one Sr(1), one Co(2), and one P(2) atom. In the fifth O site, O(2) is bonded in a distorted trigonal planar geometry to one Sr(1), one Co(1), and one P(1) atom. In the sixth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Co(2) and one P(1) atom. is represented by the CIF card [CIF]
data_SrCo3(P2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.809
_cell_length_b   7.561
_cell_length_c   9.615
_cell_angle_alpha   68.030
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.458
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.000  0.500  1.0
  Sr  Sr1  1  0.000  0.000  0.000  1.0
  Co  Co2  1  0.500  0.500  0.500  1.0
  Co  Co3  1  0.000  0.500  0.000  1.0
  Co  Co4  1  0.625  0.314  0.028  1.0
  Co  Co5  1  0.125  0.686  0.472  1.0
  Co  Co6  1  0.375  0.686  0.972  1.0
  Co  Co7  1  0.875  0.314  0.528  1.0
  P  P8  1  0.204  0.388  0.306  1.0
  P  P9  1  0.704  0.612  0.194  1.0
  P  P10  1  0.796  0.612  0.694  1.0
  P  P11  1  0.296  0.388  0.806  1.0
  P  P12  1  0.558  0.104  0.798  1.0
  P  P13  1  0.058  0.896  0.702  1.0
  P  P14  1  0.442  0.896  0.202  1.0
  P  P15  1  0.942  0.104  0.298  1.0
  O  O16  1  0.180  0.877  0.585  1.0
  O  O17  1  0.680  0.123  0.915  1.0
  O  O18  1  0.820  0.123  0.415  1.0
  O  O19  1  0.320  0.877  0.085  1.0
  O  O20  1  0.624  0.657  0.612  1.0
  O  O21  1  0.124  0.343  0.888  1.0
  O  O22  1  0.376  0.343  0.388  1.0
  O  O23  1  0.876  0.657  0.112  1.0
  O  O24  1  0.372  0.182  0.822  1.0
  O  O25  1  0.872  0.818  0.678  1.0
  O  O26  1  0.628  0.818  0.178  1.0
  O  O27  1  0.128  0.182  0.322  1.0
  O  O28  1  0.578  0.527  0.113  1.0
  O  O29  1  0.078  0.473  0.387  1.0
  O  O30  1  0.422  0.473  0.887  1.0
  O  O31  1  0.922  0.527  0.613  1.0
  O  O32  1  0.615  0.228  0.635  1.0
  O  O33  1  0.115  0.772  0.865  1.0
  O  O34  1  0.385  0.772  0.365  1.0
  O  O35  1  0.885  0.228  0.135  1.0
  O  O36  1  0.212  0.498  0.135  1.0
  O  O37  1  0.712  0.502  0.365  1.0
  O  O38  1  0.788  0.502  0.865  1.0
  O  O39  1  0.288  0.498  0.635  1.0
  O  O40  1  0.518  0.902  0.807  1.0
  O  O41  1  0.018  0.098  0.693  1.0
  O  O42  1  0.482  0.098  0.193  1.0
  O  O43  1  0.982  0.902  0.307  1.0
[/CIF]
.