The material described by CoN3H6O4ClNH4ClN3H12ClClO4 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ammoniumhydrochloride molecules, two hypochlorous acid;trihydrate molecules, two triazanium;hydrochloride molecules, and two CoN3H6O4Cl clusters. In each CoN3H6O4Cl cluster, Co(1) is bonded to one N(1), two equivalent N(2), and one O(6) atom to form CoN3O tetrahedra that share  a cornercorner with one Cl(4)O4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent H(3) atoms. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(4), and one H(5) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(2) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Cl(4) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Cl(4) atom. In the third O site, O(6) is bonded in a linear geometry to one Co(1) and one Cl(4) atom. Cl(4) is bonded to one O(3), one O(6), and two equivalent O(2) atoms to form ClO4 tetrahedra that share  a cornercorner with one Co(1)N3O tetrahedra. is represented by the CIF file [CIF]
data_CoH22N7(ClO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.877
_cell_length_b   7.877
_cell_length_c   10.301
_cell_angle_alpha   65.577
_cell_angle_beta   65.577
_cell_angle_gamma   55.267
_symmetry_Int_Tables_number   1
_cell_volume   464.503
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.054  0.054  0.824  1.0
  H  H1  1  0.476  0.624  0.425  1.0
  H  H2  1  0.624  0.476  0.425  1.0
  H  H3  1  0.335  0.550  0.535  1.0
  H  H4  1  0.550  0.335  0.535  1.0
  H  H5  1  0.989  0.762  0.851  1.0
  H  H6  1  0.421  0.770  0.831  1.0
  H  H7  1  0.770  0.421  0.831  1.0
  H  H8  1  0.976  0.390  0.855  1.0
  H  H9  1  0.762  0.989  0.851  1.0
  H  H10  1  0.390  0.976  0.855  1.0
  H  H11  1  0.213  0.508  0.070  1.0
  H  H12  1  0.209  0.713  0.084  1.0
  H  H13  1  0.981  0.713  0.109  1.0
  H  H14  1  0.119  0.558  0.242  1.0
  H  H15  1  0.508  0.213  0.070  1.0
  H  H16  1  0.205  0.205  0.068  1.0
  H  H17  1  0.713  0.209  0.084  1.0
  H  H18  1  0.978  0.211  0.100  1.0
  H  H19  1  0.211  0.978  0.100  1.0
  H  H20  1  0.713  0.981  0.109  1.0
  H  H21  1  0.558  0.119  0.242  1.0
  H  H22  1  0.096  0.096  0.242  1.0
  N  N23  1  0.908  0.908  0.873  1.0
  N  N24  1  0.316  0.886  0.890  1.0
  N  N25  1  0.886  0.316  0.890  1.0
  N  N26  1  0.495  0.495  0.532  1.0
  N  N27  1  0.129  0.623  0.132  1.0
  N  N28  1  0.623  0.129  0.132  1.0
  N  N29  1  0.120  0.120  0.131  1.0
  Cl  Cl30  1  0.835  0.835  0.533  1.0
  Cl  Cl31  1  0.620  0.620  0.202  1.0
  Cl  Cl32  1  0.356  0.356  0.909  1.0
  Cl  Cl33  1  0.177  0.177  0.441  1.0
  O  O34  1  0.889  0.889  0.372  1.0
  O  O35  1  0.310  0.984  0.386  1.0
  O  O36  1  0.294  0.294  0.389  1.0
  O  O37  1  0.984  0.310  0.386  1.0
  O  O38  1  0.718  0.718  0.590  1.0
  O  O39  1  0.031  0.705  0.586  1.0
  O  O40  1  0.705  0.031  0.586  1.0
  O  O41  1  0.121  0.121  0.601  1.0
[/CIF]
.
The material described by CoN3H6O4ClNH4ClN3H12ClClO4 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ammoniumhydrochloride molecules, two hypochlorous acid;trihydrate molecules, two triazanium;hydrochloride molecules, and two CoN3H6O4Cl clusters. In each CoN3H6O4Cl cluster, Co(1) is bonded to one N(1), two equivalent N(2), and one O(6) atom to form CoN3O tetrahedra that share  a cornercorner with one Cl(4)O4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent H(3) atoms. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(4), and one H(5) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(2) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Cl(4) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Cl(4) atom. In the third O site, O(6) is bonded in a linear geometry to one Co(1) and one Cl(4) atom. Cl(4) is bonded to one O(3), one O(6), and two equivalent O(2) atoms to form ClO4 tetrahedra that share  a cornercorner with one Co(1)N3O tetrahedra. is represented by the CIF file [CIF]
data_CoH22N7(ClO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.877
_cell_length_b   7.877
_cell_length_c   10.301
_cell_angle_alpha   65.577
_cell_angle_beta   65.577
_cell_angle_gamma   55.267
_symmetry_Int_Tables_number   1
_cell_volume   464.503
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.054  0.054  0.824  1.0
  H  H1  1  0.476  0.624  0.425  1.0
  H  H2  1  0.624  0.476  0.425  1.0
  H  H3  1  0.335  0.550  0.535  1.0
  H  H4  1  0.550  0.335  0.535  1.0
  H  H5  1  0.989  0.762  0.851  1.0
  H  H6  1  0.421  0.770  0.831  1.0
  H  H7  1  0.770  0.421  0.831  1.0
  H  H8  1  0.976  0.390  0.855  1.0
  H  H9  1  0.762  0.989  0.851  1.0
  H  H10  1  0.390  0.976  0.855  1.0
  H  H11  1  0.213  0.508  0.070  1.0
  H  H12  1  0.209  0.713  0.084  1.0
  H  H13  1  0.981  0.713  0.109  1.0
  H  H14  1  0.119  0.558  0.242  1.0
  H  H15  1  0.508  0.213  0.070  1.0
  H  H16  1  0.205  0.205  0.068  1.0
  H  H17  1  0.713  0.209  0.084  1.0
  H  H18  1  0.978  0.211  0.100  1.0
  H  H19  1  0.211  0.978  0.100  1.0
  H  H20  1  0.713  0.981  0.109  1.0
  H  H21  1  0.558  0.119  0.242  1.0
  H  H22  1  0.096  0.096  0.242  1.0
  N  N23  1  0.908  0.908  0.873  1.0
  N  N24  1  0.316  0.886  0.890  1.0
  N  N25  1  0.886  0.316  0.890  1.0
  N  N26  1  0.495  0.495  0.532  1.0
  N  N27  1  0.129  0.623  0.132  1.0
  N  N28  1  0.623  0.129  0.132  1.0
  N  N29  1  0.120  0.120  0.131  1.0
  Cl  Cl30  1  0.835  0.835  0.533  1.0
  Cl  Cl31  1  0.620  0.620  0.202  1.0
  Cl  Cl32  1  0.356  0.356  0.909  1.0
  Cl  Cl33  1  0.177  0.177  0.441  1.0
  O  O34  1  0.889  0.889  0.372  1.0
  O  O35  1  0.310  0.984  0.386  1.0
  O  O36  1  0.294  0.294  0.389  1.0
  O  O37  1  0.984  0.310  0.386  1.0
  O  O38  1  0.718  0.718  0.590  1.0
  O  O39  1  0.031  0.705  0.586  1.0
  O  O40  1  0.705  0.031  0.586  1.0
  O  O41  1  0.121  0.121  0.601  1.0
[/CIF]
.