The material described by Cd(NO3)2(O2)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of sixteen hydrogen peroxide molecules and eight Cd(NO3)2 clusters. In each Cd(NO3)2 cluster, Cd(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in an L-shaped geometry to one Cd(1) and one N(1) atom. In the third O site, O(2) is bonded in an L-shaped geometry to one Cd(1) and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cd(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.567
_cell_length_b   12.430
_cell_length_c   6.771
_cell_angle_alpha   84.442
_cell_angle_beta   65.773
_cell_angle_gamma   29.786
_symmetry_Int_Tables_number   1
_cell_volume   424.154
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.247  0.253  0.247  1.0
  Cd  Cd1  1  0.997  0.003  0.997  1.0
  N  N2  1  0.873  0.451  0.627  1.0
  N  N3  1  0.627  0.049  0.873  1.0
  N  N4  1  0.201  0.623  0.799  1.0
  N  N5  1  0.799  0.377  0.201  1.0
  O  O6  1  0.819  0.599  0.589  1.0
  O  O7  1  0.589  0.994  0.819  1.0
  O  O8  1  0.256  0.661  0.651  1.0
  O  O9  1  0.651  0.431  0.256  1.0
  O  O10  1  0.122  0.198  0.467  1.0
  O  O11  1  0.467  0.213  0.122  1.0
  O  O12  1  0.037  0.783  0.052  1.0
  O  O13  1  0.052  0.128  0.037  1.0
  O  O14  1  0.699  0.547  0.805  1.0
  O  O15  1  0.805  0.949  0.699  1.0
  O  O16  1  0.301  0.445  0.703  1.0
  O  O17  1  0.703  0.551  0.301  1.0
  O  O18  1  0.214  0.291  0.704  1.0
  O  O19  1  0.704  0.791  0.214  1.0
  O  O20  1  0.459  0.546  0.959  1.0
  O  O21  1  0.959  0.036  0.459  1.0
  O  O22  1  0.831  0.739  0.221  1.0
  O  O23  1  0.221  0.209  0.831  1.0
  O  O24  1  0.041  0.029  0.511  1.0
  O  O25  1  0.511  0.419  0.041  1.0
[/CIF]
.
The material described by Cd(NO3)2(O2)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of sixteen hydrogen peroxide molecules and eight Cd(NO3)2 clusters. In each Cd(NO3)2 cluster, Cd(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in an L-shaped geometry to one Cd(1) and one N(1) atom. In the third O site, O(2) is bonded in an L-shaped geometry to one Cd(1) and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cd(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.567
_cell_length_b   12.430
_cell_length_c   6.771
_cell_angle_alpha   84.442
_cell_angle_beta   65.773
_cell_angle_gamma   29.786
_symmetry_Int_Tables_number   1
_cell_volume   424.154
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.247  0.253  0.247  1.0
  Cd  Cd1  1  0.997  0.003  0.997  1.0
  N  N2  1  0.873  0.451  0.627  1.0
  N  N3  1  0.627  0.049  0.873  1.0
  N  N4  1  0.201  0.623  0.799  1.0
  N  N5  1  0.799  0.377  0.201  1.0
  O  O6  1  0.819  0.599  0.589  1.0
  O  O7  1  0.589  0.994  0.819  1.0
  O  O8  1  0.256  0.661  0.651  1.0
  O  O9  1  0.651  0.431  0.256  1.0
  O  O10  1  0.122  0.198  0.467  1.0
  O  O11  1  0.467  0.213  0.122  1.0
  O  O12  1  0.037  0.783  0.052  1.0
  O  O13  1  0.052  0.128  0.037  1.0
  O  O14  1  0.699  0.547  0.805  1.0
  O  O15  1  0.805  0.949  0.699  1.0
  O  O16  1  0.301  0.445  0.703  1.0
  O  O17  1  0.703  0.551  0.301  1.0
  O  O18  1  0.214  0.291  0.704  1.0
  O  O19  1  0.704  0.791  0.214  1.0
  O  O20  1  0.459  0.546  0.959  1.0
  O  O21  1  0.959  0.036  0.459  1.0
  O  O22  1  0.831  0.739  0.221  1.0
  O  O23  1  0.221  0.209  0.831  1.0
  O  O24  1  0.041  0.029  0.511  1.0
  O  O25  1  0.511  0.419  0.041  1.0
[/CIF]
.