The compound described by LiVWO6 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms to form edge-sharing LiO6 octahedra. In the second Li site, Li(2) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms to form edge-sharing LiO6 octahedra. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(6), and two equivalent O(3) atoms. W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent V(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1) and two equivalent W(1) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Li(1), one Li(2), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(2), and one V(1) atom. is represented by the CIF file [CIF]
data_LiVWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.130
_cell_length_b   6.818
_cell_length_c   7.353
_cell_angle_alpha   66.026
_cell_angle_beta   70.780
_cell_angle_gamma   79.156
_symmetry_Int_Tables_number   1
_cell_volume   221.436
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.500  0.000  0.500  1.0
  V  V2  1  0.046  0.354  0.228  1.0
  V  V3  1  0.954  0.646  0.772  1.0
  W  W4  1  0.451  0.640  0.267  1.0
  W  W5  1  0.549  0.360  0.733  1.0
  O  O6  1  0.171  0.720  0.152  1.0
  O  O7  1  0.315  0.308  0.337  1.0
  O  O8  1  0.757  0.562  0.063  1.0
  O  O9  1  0.258  0.565  0.566  1.0
  O  O10  1  0.561  0.891  0.224  1.0
  O  O11  1  0.048  0.883  0.722  1.0
  O  O12  1  0.952  0.117  0.278  1.0
  O  O13  1  0.439  0.109  0.776  1.0
  O  O14  1  0.243  0.438  0.937  1.0
  O  O15  1  0.742  0.435  0.434  1.0
  O  O16  1  0.685  0.692  0.663  1.0
  O  O17  1  0.829  0.280  0.848  1.0
[/CIF]
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The compound described by LiVWO6 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms to form edge-sharing LiO6 octahedra. In the second Li site, Li(2) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms to form edge-sharing LiO6 octahedra. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(6), and two equivalent O(3) atoms. W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent V(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1) and two equivalent W(1) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Li(1), one Li(2), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(2), and one V(1) atom. is represented by the CIF file [CIF]
data_LiVWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.130
_cell_length_b   6.818
_cell_length_c   7.353
_cell_angle_alpha   66.026
_cell_angle_beta   70.780
_cell_angle_gamma   79.156
_symmetry_Int_Tables_number   1
_cell_volume   221.436
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.500  0.000  0.500  1.0
  V  V2  1  0.046  0.354  0.228  1.0
  V  V3  1  0.954  0.646  0.772  1.0
  W  W4  1  0.451  0.640  0.267  1.0
  W  W5  1  0.549  0.360  0.733  1.0
  O  O6  1  0.171  0.720  0.152  1.0
  O  O7  1  0.315  0.308  0.337  1.0
  O  O8  1  0.757  0.562  0.063  1.0
  O  O9  1  0.258  0.565  0.566  1.0
  O  O10  1  0.561  0.891  0.224  1.0
  O  O11  1  0.048  0.883  0.722  1.0
  O  O12  1  0.952  0.117  0.278  1.0
  O  O13  1  0.439  0.109  0.776  1.0
  O  O14  1  0.243  0.438  0.937  1.0
  O  O15  1  0.742  0.435  0.434  1.0
  O  O16  1  0.685  0.692  0.663  1.0
  O  O17  1  0.829  0.280  0.848  1.0
[/CIF]
.