The compound described by Ag3SBr crystallizes in the monoclinic Pm space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. S(1) is bonded to two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms to form distorted corner-sharing SAg6 pentagonal pyramids. Br(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms. is represented by the CIF card [CIF]
data_Ag3SBr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.922
_cell_length_b   4.981
_cell_length_c   4.825
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   93.277
_symmetry_Int_Tables_number   1
_cell_volume   118.091
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.510  0.633  0.000  1.0
  Ag  Ag1  1  0.395  0.983  0.500  1.0
  Ag  Ag2  1  0.985  0.393  0.500  1.0
  S  S3  1  0.496  0.490  0.500  1.0
  Br  Br4  1  0.999  0.001  0.000  1.0
[/CIF]
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The compound described by Ag3SBr crystallizes in the monoclinic Pm space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. S(1) is bonded to two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms to form distorted corner-sharing SAg6 pentagonal pyramids. Br(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms. is represented by the CIF card [CIF]
data_Ag3SBr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.922
_cell_length_b   4.981
_cell_length_c   4.825
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   93.277
_symmetry_Int_Tables_number   1
_cell_volume   118.091
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.510  0.633  0.000  1.0
  Ag  Ag1  1  0.395  0.983  0.500  1.0
  Ag  Ag2  1  0.985  0.393  0.500  1.0
  S  S3  1  0.496  0.490  0.500  1.0
  Br  Br4  1  0.999  0.001  0.000  1.0
[/CIF]
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