The compound described by RhF3 is Upper Bainite-like structured and crystallizes in the trigonal R-3c space group. Rh(1) is bonded to six equivalent F(1) atoms to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 49°. F(1) is bonded in a bent 120 degrees geometry to two equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.332
_cell_length_b   5.332
_cell_length_c   5.332
_cell_angle_alpha   54.420
_cell_angle_beta   54.420
_cell_angle_gamma   54.420
_symmetry_Int_Tables_number   1
_cell_volume   93.242
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.500  0.500  0.500  1.0
  Rh  Rh1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.418  0.750  0.082  1.0
  F  F3  1  0.750  0.082  0.418  1.0
  F  F4  1  0.918  0.582  0.250  1.0
  F  F5  1  0.250  0.918  0.582  1.0
  F  F6  1  0.582  0.250  0.918  1.0
  F  F7  1  0.082  0.418  0.750  1.0
[/CIF]
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The compound described by RhF3 is Upper Bainite-like structured and crystallizes in the trigonal R-3c space group. Rh(1) is bonded to six equivalent F(1) atoms to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 49°. F(1) is bonded in a bent 120 degrees geometry to two equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.332
_cell_length_b   5.332
_cell_length_c   5.332
_cell_angle_alpha   54.420
_cell_angle_beta   54.420
_cell_angle_gamma   54.420
_symmetry_Int_Tables_number   1
_cell_volume   93.242
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.500  0.500  0.500  1.0
  Rh  Rh1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.418  0.750  0.082  1.0
  F  F3  1  0.750  0.082  0.418  1.0
  F  F4  1  0.918  0.582  0.250  1.0
  F  F5  1  0.250  0.918  0.582  1.0
  F  F6  1  0.582  0.250  0.918  1.0
  F  F7  1  0.082  0.418  0.750  1.0
[/CIF]
.