The material structure described by (Ag(NH3)2)2SO4 crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two sulfuric acid molecules and four Ag(NH3)2 clusters. In each Ag(NH3)2 cluster, Ag(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_Ag2H12S(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.583
_cell_length_b   8.583
_cell_length_c   6.450
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   475.173
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.000  0.985  1.0
  Ag  Ag1  1  0.000  0.500  0.515  1.0
  Ag  Ag2  1  0.000  0.500  0.015  1.0
  Ag  Ag3  1  0.500  0.000  0.485  1.0
  H  H4  1  0.585  0.702  0.880  1.0
  H  H5  1  0.915  0.202  0.620  1.0
  H  H6  1  0.415  0.298  0.880  1.0
  H  H7  1  0.085  0.798  0.620  1.0
  H  H8  1  0.298  0.585  0.120  1.0
  H  H9  1  0.798  0.915  0.380  1.0
  H  H10  1  0.702  0.415  0.120  1.0
  H  H11  1  0.202  0.085  0.380  1.0
  H  H12  1  0.719  0.788  0.029  1.0
  H  H13  1  0.781  0.288  0.471  1.0
  H  H14  1  0.281  0.212  0.029  1.0
  H  H15  1  0.219  0.712  0.471  1.0
  H  H16  1  0.212  0.719  0.971  1.0
  H  H17  1  0.712  0.781  0.529  1.0
  H  H18  1  0.788  0.281  0.971  1.0
  H  H19  1  0.288  0.219  0.529  1.0
  H  H20  1  0.556  0.717  0.137  1.0
  H  H21  1  0.944  0.217  0.363  1.0
  H  H22  1  0.444  0.283  0.137  1.0
  H  H23  1  0.056  0.783  0.363  1.0
  H  H24  1  0.283  0.556  0.863  1.0
  H  H25  1  0.783  0.944  0.637  1.0
  H  H26  1  0.717  0.444  0.863  1.0
  H  H27  1  0.217  0.056  0.637  1.0
  S  S28  1  0.500  0.500  0.500  1.0
  S  S29  1  0.000  0.000  0.000  1.0
  N  N30  1  0.600  0.772  0.008  1.0
  N  N31  1  0.900  0.272  0.492  1.0
  N  N32  1  0.400  0.228  0.008  1.0
  N  N33  1  0.100  0.728  0.492  1.0
  N  N34  1  0.228  0.600  0.992  1.0
  N  N35  1  0.728  0.900  0.508  1.0
  N  N36  1  0.772  0.400  0.992  1.0
  N  N37  1  0.272  0.100  0.508  1.0
  O  O38  1  0.627  0.565  0.633  1.0
  O  O39  1  0.873  0.065  0.867  1.0
  O  O40  1  0.373  0.435  0.633  1.0
  O  O41  1  0.127  0.935  0.867  1.0
  O  O42  1  0.435  0.627  0.367  1.0
  O  O43  1  0.935  0.873  0.133  1.0
  O  O44  1  0.565  0.373  0.367  1.0
  O  O45  1  0.065  0.127  0.133  1.0
[/CIF]
.
The material structure described by (Ag(NH3)2)2SO4 crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two sulfuric acid molecules and four Ag(NH3)2 clusters. In each Ag(NH3)2 cluster, Ag(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_Ag2H12S(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.583
_cell_length_b   8.583
_cell_length_c   6.450
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   475.173
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.000  0.985  1.0
  Ag  Ag1  1  0.000  0.500  0.515  1.0
  Ag  Ag2  1  0.000  0.500  0.015  1.0
  Ag  Ag3  1  0.500  0.000  0.485  1.0
  H  H4  1  0.585  0.702  0.880  1.0
  H  H5  1  0.915  0.202  0.620  1.0
  H  H6  1  0.415  0.298  0.880  1.0
  H  H7  1  0.085  0.798  0.620  1.0
  H  H8  1  0.298  0.585  0.120  1.0
  H  H9  1  0.798  0.915  0.380  1.0
  H  H10  1  0.702  0.415  0.120  1.0
  H  H11  1  0.202  0.085  0.380  1.0
  H  H12  1  0.719  0.788  0.029  1.0
  H  H13  1  0.781  0.288  0.471  1.0
  H  H14  1  0.281  0.212  0.029  1.0
  H  H15  1  0.219  0.712  0.471  1.0
  H  H16  1  0.212  0.719  0.971  1.0
  H  H17  1  0.712  0.781  0.529  1.0
  H  H18  1  0.788  0.281  0.971  1.0
  H  H19  1  0.288  0.219  0.529  1.0
  H  H20  1  0.556  0.717  0.137  1.0
  H  H21  1  0.944  0.217  0.363  1.0
  H  H22  1  0.444  0.283  0.137  1.0
  H  H23  1  0.056  0.783  0.363  1.0
  H  H24  1  0.283  0.556  0.863  1.0
  H  H25  1  0.783  0.944  0.637  1.0
  H  H26  1  0.717  0.444  0.863  1.0
  H  H27  1  0.217  0.056  0.637  1.0
  S  S28  1  0.500  0.500  0.500  1.0
  S  S29  1  0.000  0.000  0.000  1.0
  N  N30  1  0.600  0.772  0.008  1.0
  N  N31  1  0.900  0.272  0.492  1.0
  N  N32  1  0.400  0.228  0.008  1.0
  N  N33  1  0.100  0.728  0.492  1.0
  N  N34  1  0.228  0.600  0.992  1.0
  N  N35  1  0.728  0.900  0.508  1.0
  N  N36  1  0.772  0.400  0.992  1.0
  N  N37  1  0.272  0.100  0.508  1.0
  O  O38  1  0.627  0.565  0.633  1.0
  O  O39  1  0.873  0.065  0.867  1.0
  O  O40  1  0.373  0.435  0.633  1.0
  O  O41  1  0.127  0.935  0.867  1.0
  O  O42  1  0.435  0.627  0.367  1.0
  O  O43  1  0.935  0.873  0.133  1.0
  O  O44  1  0.565  0.373  0.367  1.0
  O  O45  1  0.065  0.127  0.133  1.0
[/CIF]
.