The crystal structure described by Zn(AgO2)2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(4), two equivalent O(2), and three equivalent O(3) atoms to form a mixture of edge and corner-sharing AgO6 octahedra. The corner-sharing octahedral tilt angles range from 48-71°. In the second Ag site, Ag(2) is bonded to one O(2), two equivalent O(4), and three equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing AgO6 octahedra. The corner-sharing octahedral tilt angles range from 48-71°. Zn(1) is bonded in a 7-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ag(2) and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded to one Ag(2), two equivalent Ag(1), and one Zn(1) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(4)Zn2Ag3 trigonal bipyramids, corners with six equivalent O(3)Zn2Ag3 trigonal bipyramids, corners with two equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(3)Zn2Ag3 trigonal bipyramid, and edges with two equivalent O(4)Zn2Ag3 trigonal bipyramids. In the third O site, O(3) is bonded to three equivalent Ag(1) and two equivalent Zn(1) atoms to form distorted OZn2Ag3 trigonal bipyramids that share corners with five equivalent O(4)Zn2Ag3 trigonal bipyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(4)Zn2Ag3 trigonal bipyramid, edges with four equivalent O(3)Zn2Ag3 trigonal bipyramids, and  an edgeedge with one O(2)ZnAg3 trigonal pyramid. In the fourth O site, O(4) is bonded to one Ag(1), two equivalent Ag(2), and two equivalent Zn(1) atoms to form distorted OZn2Ag3 trigonal bipyramids that share corners with five equivalent O(3)Zn2Ag3 trigonal bipyramids, corners with two equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(3)Zn2Ag3 trigonal bipyramid, edges with two equivalent O(4)Zn2Ag3 trigonal bipyramids, and edges with two equivalent O(2)ZnAg3 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.111
_cell_length_b   9.744
_cell_length_c   11.014
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   333.899
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.262  0.341  1.0
  Zn  Zn1  1  0.750  0.738  0.659  1.0
  Zn  Zn2  1  0.250  0.762  0.159  1.0
  Zn  Zn3  1  0.750  0.238  0.841  1.0
  Ag  Ag4  1  0.750  0.415  0.107  1.0
  Ag  Ag5  1  0.250  0.085  0.607  1.0
  Ag  Ag6  1  0.750  0.915  0.393  1.0
  Ag  Ag7  1  0.250  0.585  0.893  1.0
  Ag  Ag8  1  0.250  0.569  0.387  1.0
  Ag  Ag9  1  0.750  0.431  0.613  1.0
  Ag  Ag10  1  0.250  0.069  0.113  1.0
  Ag  Ag11  1  0.750  0.931  0.887  1.0
  O  O12  1  0.750  0.872  0.072  1.0
  O  O13  1  0.250  0.128  0.928  1.0
  O  O14  1  0.750  0.372  0.428  1.0
  O  O15  1  0.250  0.628  0.572  1.0
  O  O16  1  0.750  0.025  0.722  1.0
  O  O17  1  0.250  0.975  0.278  1.0
  O  O18  1  0.750  0.525  0.778  1.0
  O  O19  1  0.250  0.475  0.222  1.0
  O  O20  1  0.750  0.618  0.033  1.0
  O  O21  1  0.250  0.382  0.967  1.0
  O  O22  1  0.750  0.118  0.467  1.0
  O  O23  1  0.250  0.882  0.533  1.0
  O  O24  1  0.250  0.772  0.792  1.0
  O  O25  1  0.750  0.228  0.208  1.0
  O  O26  1  0.750  0.728  0.292  1.0
  O  O27  1  0.250  0.272  0.708  1.0
[/CIF]
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The crystal structure described by Zn(AgO2)2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(4), two equivalent O(2), and three equivalent O(3) atoms to form a mixture of edge and corner-sharing AgO6 octahedra. The corner-sharing octahedral tilt angles range from 48-71°. In the second Ag site, Ag(2) is bonded to one O(2), two equivalent O(4), and three equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing AgO6 octahedra. The corner-sharing octahedral tilt angles range from 48-71°. Zn(1) is bonded in a 7-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ag(2) and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded to one Ag(2), two equivalent Ag(1), and one Zn(1) atom to form distorted OZnAg3 trigonal pyramids that share corners with two equivalent O(4)Zn2Ag3 trigonal bipyramids, corners with six equivalent O(3)Zn2Ag3 trigonal bipyramids, corners with two equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(3)Zn2Ag3 trigonal bipyramid, and edges with two equivalent O(4)Zn2Ag3 trigonal bipyramids. In the third O site, O(3) is bonded to three equivalent Ag(1) and two equivalent Zn(1) atoms to form distorted OZn2Ag3 trigonal bipyramids that share corners with five equivalent O(4)Zn2Ag3 trigonal bipyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(4)Zn2Ag3 trigonal bipyramid, edges with four equivalent O(3)Zn2Ag3 trigonal bipyramids, and  an edgeedge with one O(2)ZnAg3 trigonal pyramid. In the fourth O site, O(4) is bonded to one Ag(1), two equivalent Ag(2), and two equivalent Zn(1) atoms to form distorted OZn2Ag3 trigonal bipyramids that share corners with five equivalent O(3)Zn2Ag3 trigonal bipyramids, corners with two equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(3)Zn2Ag3 trigonal bipyramid, edges with two equivalent O(4)Zn2Ag3 trigonal bipyramids, and edges with two equivalent O(2)ZnAg3 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.111
_cell_length_b   9.744
_cell_length_c   11.014
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   333.899
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.262  0.341  1.0
  Zn  Zn1  1  0.750  0.738  0.659  1.0
  Zn  Zn2  1  0.250  0.762  0.159  1.0
  Zn  Zn3  1  0.750  0.238  0.841  1.0
  Ag  Ag4  1  0.750  0.415  0.107  1.0
  Ag  Ag5  1  0.250  0.085  0.607  1.0
  Ag  Ag6  1  0.750  0.915  0.393  1.0
  Ag  Ag7  1  0.250  0.585  0.893  1.0
  Ag  Ag8  1  0.250  0.569  0.387  1.0
  Ag  Ag9  1  0.750  0.431  0.613  1.0
  Ag  Ag10  1  0.250  0.069  0.113  1.0
  Ag  Ag11  1  0.750  0.931  0.887  1.0
  O  O12  1  0.750  0.872  0.072  1.0
  O  O13  1  0.250  0.128  0.928  1.0
  O  O14  1  0.750  0.372  0.428  1.0
  O  O15  1  0.250  0.628  0.572  1.0
  O  O16  1  0.750  0.025  0.722  1.0
  O  O17  1  0.250  0.975  0.278  1.0
  O  O18  1  0.750  0.525  0.778  1.0
  O  O19  1  0.250  0.475  0.222  1.0
  O  O20  1  0.750  0.618  0.033  1.0
  O  O21  1  0.250  0.382  0.967  1.0
  O  O22  1  0.750  0.118  0.467  1.0
  O  O23  1  0.250  0.882  0.533  1.0
  O  O24  1  0.250  0.772  0.792  1.0
  O  O25  1  0.750  0.228  0.208  1.0
  O  O26  1  0.750  0.728  0.292  1.0
  O  O27  1  0.250  0.272  0.708  1.0
[/CIF]
.