The crystal structure described by Tm4CrSe7 crystallizes in the monoclinic Cm space group. There are four inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 7-coordinate geometry to one Se(4), two equivalent Se(2), two equivalent Se(3), and two equivalent Se(5) atoms. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to one Se(3), two equivalent Se(1), two equivalent Se(4), and two equivalent Se(6) atoms. In the third Tm site, Tm(3) is bonded to one Se(5), one Se(6), two equivalent Se(3), and two equivalent Se(4) atoms to form TmSe6 octahedra that share  a cornercorner with one Tm(4)Se6 octahedra,  a cornercorner with one Cr(1)Se6 octahedra, and edges with two equivalent Tm(3)Se6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the fourth Tm site, Tm(4) is bonded to one Se(2), one Se(6), two equivalent Se(1), and two equivalent Se(7) atoms to form TmSe6 octahedra that share  a cornercorner with one Tm(3)Se6 octahedra, corners with two equivalent Cr(1)Se6 octahedra, edges with two equivalent Tm(4)Se6 octahedra, and edges with three equivalent Cr(1)Se6 octahedra. The corner-sharing octahedral tilt angles range from 2-50°. Cr(1) is bonded to one Se(1), one Se(5), two equivalent Se(2), and two equivalent Se(7) atoms to form CrSe6 octahedra that share  a cornercorner with one Tm(3)Se6 octahedra, corners with two equivalent Tm(4)Se6 octahedra, edges with two equivalent Cr(1)Se6 octahedra, and edges with three equivalent Tm(4)Se6 octahedra. The corner-sharing octahedral tilt angles range from 2-54°. There are seven inequivalent Se sites. In the first Se site, Se(1) is bonded to two equivalent Tm(2), two equivalent Tm(4), and one Cr(1) atom to form distorted SeTm4Cr trigonal bipyramids that share  a cornercorner with one Se(5)Tm3Cr tetrahedra, corners with four equivalent Se(6)Tm4 tetrahedra, corners with two equivalent Se(3)Tm5 trigonal bipyramids, corners with two equivalent Se(4)Tm5 trigonal bipyramids, edges with two equivalent Se(2)Tm3Cr2 square pyramids,  an edgeedge with one Se(6)Tm4 tetrahedra,  an edgeedge with one Se(4)Tm5 trigonal bipyramid, and edges with two equivalent Se(1)Tm4Cr trigonal bipyramids. In the second Se site, Se(2) is bonded to one Tm(4), two equivalent Tm(1), and two equivalent Cr(1) atoms to form SeTm3Cr2 square pyramids that share  a cornercorner with one Se(6)Tm4 tetrahedra, corners with four equivalent Se(5)Tm3Cr tetrahedra, corners with two equivalent Se(3)Tm5 trigonal bipyramids, corners with two equivalent Se(4)Tm5 trigonal bipyramids, edges with two equivalent Se(2)Tm3Cr2 square pyramids,  an edgeedge with one Se(5)Tm3Cr tetrahedra,  an edgeedge with one Se(3)Tm5 trigonal bipyramid, and edges with two equivalent Se(1)Tm4Cr trigonal bipyramids. In the third Se site, Se(3) is bonded to one Tm(2), two equivalent Tm(1), and two equivalent Tm(3) atoms to form distorted SeTm5 trigonal bipyramids that share corners with two equivalent Se(2)Tm3Cr2 square pyramids, corners with four equivalent Se(5)Tm3Cr tetrahedra, corners with two equivalent Se(1)Tm4Cr trigonal bipyramids, corners with two equivalent Se(4)Tm5 trigonal bipyramids,  an edgeedge with one Se(2)Tm3Cr2 square pyramid,  an edgeedge with one Se(5)Tm3Cr tetrahedra, edges with two equivalent Se(6)Tm4 tetrahedra, edges with two equivalent Se(3)Tm5 trigonal bipyramids, and edges with three equivalent Se(4)Tm5 trigonal bipyramids. In the fourth Se site, Se(4) is bonded to one Tm(1), two equivalent Tm(2), and two equivalent Tm(3) atoms to form distorted SeTm5 trigonal bipyramids that share corners with two equivalent Se(2)Tm3Cr2 square pyramids, corners with four equivalent Se(6)Tm4 tetrahedra, corners with two equivalent Se(1)Tm4Cr trigonal bipyramids, corners with two equivalent Se(3)Tm5 trigonal bipyramids,  an edgeedge with one Se(6)Tm4 tetrahedra, edges with two equivalent Se(5)Tm3Cr tetrahedra,  an edgeedge with one Se(1)Tm4Cr trigonal bipyramid, edges with two equivalent Se(4)Tm5 trigonal bipyramids, and edges with three equivalent Se(3)Tm5 trigonal bipyramids. In the fifth Se site, Se(5) is bonded to one Tm(3), two equivalent Tm(1), and one Cr(1) atom to form distorted SeTm3Cr tetrahedra that share corners with four equivalent Se(2)Tm3Cr2 square pyramids,  a cornercorner with one Se(6)Tm4 tetrahedra, corners with two equivalent Se(5)Tm3Cr tetrahedra,  a cornercorner with one Se(1)Tm4Cr trigonal bipyramid, corners with four equivalent Se(3)Tm5 trigonal bipyramids,  an edgeedge with one Se(2)Tm3Cr2 square pyramid,  an edgeedge with one Se(3)Tm5 trigonal bipyramid, and edges with two equivalent Se(4)Tm5 trigonal bipyramids. In the sixth Se site, Se(6) is bonded to one Tm(3), one Tm(4), and two equivalent Tm(2) atoms to form SeTm4 tetrahedra that share  a cornercorner with one Se(2)Tm3Cr2 square pyramid,  a cornercorner with one Se(5)Tm3Cr tetrahedra, corners with two equivalent Se(6)Tm4 tetrahedra, corners with four equivalent Se(1)Tm4Cr trigonal bipyramids, corners with four equivalent Se(4)Tm5 trigonal bipyramids,  an edgeedge with one Se(1)Tm4Cr trigonal bipyramid,  an edgeedge with one Se(4)Tm5 trigonal bipyramid, and edges with two equivalent Se(3)Tm5 trigonal bipyramids. In the seventh Se site, Se(7) is bonded in a rectangular see-saw-like geometry to two equivalent Tm(4) and two equivalent Cr(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tm4CrSe7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.760
_cell_length_b   6.760
_cell_length_c   11.869
_cell_angle_alpha   75.273
_cell_angle_beta   75.273
_cell_angle_gamma   33.724
_symmetry_Int_Tables_number   1
_cell_volume   290.287
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.694  0.694  0.206  1.0
  Tm  Tm1  1  0.306  0.306  0.803  1.0
  Tm  Tm2  1  0.998  0.998  0.007  1.0
  Tm  Tm3  1  0.113  0.113  0.564  1.0
  Cr  Cr4  1  0.885  0.885  0.424  1.0
  Se  Se5  1  0.746  0.746  0.636  1.0
  Se  Se6  1  0.270  0.270  0.353  1.0
  Se  Se7  1  0.337  0.337  0.051  1.0
  Se  Se8  1  0.659  0.659  0.949  1.0
  Se  Se9  1  0.032  0.032  0.229  1.0
  Se  Se10  1  0.964  0.964  0.785  1.0
  Se  Se11  1  0.494  0.494  0.495  1.0
[/CIF]
.
The crystal structure described by Tm4CrSe7 crystallizes in the monoclinic Cm space group. There are four inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 7-coordinate geometry to one Se(4), two equivalent Se(2), two equivalent Se(3), and two equivalent Se(5) atoms. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to one Se(3), two equivalent Se(1), two equivalent Se(4), and two equivalent Se(6) atoms. In the third Tm site, Tm(3) is bonded to one Se(5), one Se(6), two equivalent Se(3), and two equivalent Se(4) atoms to form TmSe6 octahedra that share  a cornercorner with one Tm(4)Se6 octahedra,  a cornercorner with one Cr(1)Se6 octahedra, and edges with two equivalent Tm(3)Se6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the fourth Tm site, Tm(4) is bonded to one Se(2), one Se(6), two equivalent Se(1), and two equivalent Se(7) atoms to form TmSe6 octahedra that share  a cornercorner with one Tm(3)Se6 octahedra, corners with two equivalent Cr(1)Se6 octahedra, edges with two equivalent Tm(4)Se6 octahedra, and edges with three equivalent Cr(1)Se6 octahedra. The corner-sharing octahedral tilt angles range from 2-50°. Cr(1) is bonded to one Se(1), one Se(5), two equivalent Se(2), and two equivalent Se(7) atoms to form CrSe6 octahedra that share  a cornercorner with one Tm(3)Se6 octahedra, corners with two equivalent Tm(4)Se6 octahedra, edges with two equivalent Cr(1)Se6 octahedra, and edges with three equivalent Tm(4)Se6 octahedra. The corner-sharing octahedral tilt angles range from 2-54°. There are seven inequivalent Se sites. In the first Se site, Se(1) is bonded to two equivalent Tm(2), two equivalent Tm(4), and one Cr(1) atom to form distorted SeTm4Cr trigonal bipyramids that share  a cornercorner with one Se(5)Tm3Cr tetrahedra, corners with four equivalent Se(6)Tm4 tetrahedra, corners with two equivalent Se(3)Tm5 trigonal bipyramids, corners with two equivalent Se(4)Tm5 trigonal bipyramids, edges with two equivalent Se(2)Tm3Cr2 square pyramids,  an edgeedge with one Se(6)Tm4 tetrahedra,  an edgeedge with one Se(4)Tm5 trigonal bipyramid, and edges with two equivalent Se(1)Tm4Cr trigonal bipyramids. In the second Se site, Se(2) is bonded to one Tm(4), two equivalent Tm(1), and two equivalent Cr(1) atoms to form SeTm3Cr2 square pyramids that share  a cornercorner with one Se(6)Tm4 tetrahedra, corners with four equivalent Se(5)Tm3Cr tetrahedra, corners with two equivalent Se(3)Tm5 trigonal bipyramids, corners with two equivalent Se(4)Tm5 trigonal bipyramids, edges with two equivalent Se(2)Tm3Cr2 square pyramids,  an edgeedge with one Se(5)Tm3Cr tetrahedra,  an edgeedge with one Se(3)Tm5 trigonal bipyramid, and edges with two equivalent Se(1)Tm4Cr trigonal bipyramids. In the third Se site, Se(3) is bonded to one Tm(2), two equivalent Tm(1), and two equivalent Tm(3) atoms to form distorted SeTm5 trigonal bipyramids that share corners with two equivalent Se(2)Tm3Cr2 square pyramids, corners with four equivalent Se(5)Tm3Cr tetrahedra, corners with two equivalent Se(1)Tm4Cr trigonal bipyramids, corners with two equivalent Se(4)Tm5 trigonal bipyramids,  an edgeedge with one Se(2)Tm3Cr2 square pyramid,  an edgeedge with one Se(5)Tm3Cr tetrahedra, edges with two equivalent Se(6)Tm4 tetrahedra, edges with two equivalent Se(3)Tm5 trigonal bipyramids, and edges with three equivalent Se(4)Tm5 trigonal bipyramids. In the fourth Se site, Se(4) is bonded to one Tm(1), two equivalent Tm(2), and two equivalent Tm(3) atoms to form distorted SeTm5 trigonal bipyramids that share corners with two equivalent Se(2)Tm3Cr2 square pyramids, corners with four equivalent Se(6)Tm4 tetrahedra, corners with two equivalent Se(1)Tm4Cr trigonal bipyramids, corners with two equivalent Se(3)Tm5 trigonal bipyramids,  an edgeedge with one Se(6)Tm4 tetrahedra, edges with two equivalent Se(5)Tm3Cr tetrahedra,  an edgeedge with one Se(1)Tm4Cr trigonal bipyramid, edges with two equivalent Se(4)Tm5 trigonal bipyramids, and edges with three equivalent Se(3)Tm5 trigonal bipyramids. In the fifth Se site, Se(5) is bonded to one Tm(3), two equivalent Tm(1), and one Cr(1) atom to form distorted SeTm3Cr tetrahedra that share corners with four equivalent Se(2)Tm3Cr2 square pyramids,  a cornercorner with one Se(6)Tm4 tetrahedra, corners with two equivalent Se(5)Tm3Cr tetrahedra,  a cornercorner with one Se(1)Tm4Cr trigonal bipyramid, corners with four equivalent Se(3)Tm5 trigonal bipyramids,  an edgeedge with one Se(2)Tm3Cr2 square pyramid,  an edgeedge with one Se(3)Tm5 trigonal bipyramid, and edges with two equivalent Se(4)Tm5 trigonal bipyramids. In the sixth Se site, Se(6) is bonded to one Tm(3), one Tm(4), and two equivalent Tm(2) atoms to form SeTm4 tetrahedra that share  a cornercorner with one Se(2)Tm3Cr2 square pyramid,  a cornercorner with one Se(5)Tm3Cr tetrahedra, corners with two equivalent Se(6)Tm4 tetrahedra, corners with four equivalent Se(1)Tm4Cr trigonal bipyramids, corners with four equivalent Se(4)Tm5 trigonal bipyramids,  an edgeedge with one Se(1)Tm4Cr trigonal bipyramid,  an edgeedge with one Se(4)Tm5 trigonal bipyramid, and edges with two equivalent Se(3)Tm5 trigonal bipyramids. In the seventh Se site, Se(7) is bonded in a rectangular see-saw-like geometry to two equivalent Tm(4) and two equivalent Cr(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tm4CrSe7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.760
_cell_length_b   6.760
_cell_length_c   11.869
_cell_angle_alpha   75.273
_cell_angle_beta   75.273
_cell_angle_gamma   33.724
_symmetry_Int_Tables_number   1
_cell_volume   290.287
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.694  0.694  0.206  1.0
  Tm  Tm1  1  0.306  0.306  0.803  1.0
  Tm  Tm2  1  0.998  0.998  0.007  1.0
  Tm  Tm3  1  0.113  0.113  0.564  1.0
  Cr  Cr4  1  0.885  0.885  0.424  1.0
  Se  Se5  1  0.746  0.746  0.636  1.0
  Se  Se6  1  0.270  0.270  0.353  1.0
  Se  Se7  1  0.337  0.337  0.051  1.0
  Se  Se8  1  0.659  0.659  0.949  1.0
  Se  Se9  1  0.032  0.032  0.229  1.0
  Se  Se10  1  0.964  0.964  0.785  1.0
  Se  Se11  1  0.494  0.494  0.495  1.0
[/CIF]
.