The compound described by Rb6WN4 crystallizes in the tetragonal P4_2/nmc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted bent 150 degrees geometry to two equivalent N(1) atoms. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. W(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. N(1) is bonded in a 6-coordinate geometry to one Rb(1), four equivalent Rb(2), and one W(1) atom. is represented by the CIF card [CIF]
data_Rb6WN4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.557
_cell_length_b   8.557
_cell_length_c   7.216
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   528.347
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.500  0.703  1.0
  Rb  Rb1  1  0.500  0.000  0.797  1.0
  Rb  Rb2  1  0.500  0.000  0.297  1.0
  Rb  Rb3  1  0.000  0.500  0.203  1.0
  Rb  Rb4  1  0.204  0.204  0.500  1.0
  Rb  Rb5  1  0.796  0.796  0.500  1.0
  Rb  Rb6  1  0.704  0.704  0.000  1.0
  Rb  Rb7  1  0.296  0.296  0.000  1.0
  Rb  Rb8  1  0.796  0.204  0.500  1.0
  Rb  Rb9  1  0.204  0.796  0.500  1.0
  Rb  Rb10  1  0.296  0.704  0.000  1.0
  Rb  Rb11  1  0.704  0.296  0.000  1.0
  W  W12  1  0.500  0.500  0.500  1.0
  W  W13  1  0.000  0.000  0.000  1.0
  N  N14  1  0.311  0.500  0.355  1.0
  N  N15  1  0.689  0.500  0.355  1.0
  N  N16  1  0.811  0.000  0.145  1.0
  N  N17  1  0.189  0.000  0.145  1.0
  N  N18  1  0.500  0.311  0.645  1.0
  N  N19  1  0.500  0.689  0.645  1.0
  N  N20  1  0.000  0.811  0.855  1.0
  N  N21  1  0.000  0.189  0.855  1.0
[/CIF]
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The compound described by Rb6WN4 crystallizes in the tetragonal P4_2/nmc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted bent 150 degrees geometry to two equivalent N(1) atoms. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. W(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. N(1) is bonded in a 6-coordinate geometry to one Rb(1), four equivalent Rb(2), and one W(1) atom. is represented by the CIF card [CIF]
data_Rb6WN4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.557
_cell_length_b   8.557
_cell_length_c   7.216
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   528.347
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.500  0.703  1.0
  Rb  Rb1  1  0.500  0.000  0.797  1.0
  Rb  Rb2  1  0.500  0.000  0.297  1.0
  Rb  Rb3  1  0.000  0.500  0.203  1.0
  Rb  Rb4  1  0.204  0.204  0.500  1.0
  Rb  Rb5  1  0.796  0.796  0.500  1.0
  Rb  Rb6  1  0.704  0.704  0.000  1.0
  Rb  Rb7  1  0.296  0.296  0.000  1.0
  Rb  Rb8  1  0.796  0.204  0.500  1.0
  Rb  Rb9  1  0.204  0.796  0.500  1.0
  Rb  Rb10  1  0.296  0.704  0.000  1.0
  Rb  Rb11  1  0.704  0.296  0.000  1.0
  W  W12  1  0.500  0.500  0.500  1.0
  W  W13  1  0.000  0.000  0.000  1.0
  N  N14  1  0.311  0.500  0.355  1.0
  N  N15  1  0.689  0.500  0.355  1.0
  N  N16  1  0.811  0.000  0.145  1.0
  N  N17  1  0.189  0.000  0.145  1.0
  N  N18  1  0.500  0.311  0.645  1.0
  N  N19  1  0.500  0.689  0.645  1.0
  N  N20  1  0.000  0.811  0.855  1.0
  N  N21  1  0.000  0.189  0.855  1.0
[/CIF]
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