The compound described by Ag4TeSO4 crystallizes in the cubic P2_13 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to two equivalent Te(1), one O(1), and one O(2) atom. Te(1) is bonded in a 6-coordinate geometry to six equivalent Ag(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ag(2) and one S(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. is represented by the CIF file [CIF]
data_Ag4TeSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.973
_cell_length_b   8.973
_cell_length_c   8.973
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   722.463
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  1.000  0.500  1.0
  Ag  Ag1  1  1.000  0.500  0.500  1.0
  Ag  Ag2  1  0.500  0.500  1.000  1.0
  Ag  Ag3  1  0.000  0.000  0.000  1.0
  Ag  Ag4  1  0.205  0.990  0.613  1.0
  Ag  Ag5  1  0.387  0.705  0.510  1.0
  Ag  Ag6  1  0.490  0.887  0.795  1.0
  Ag  Ag7  1  0.705  0.510  0.387  1.0
  Ag  Ag8  1  0.887  0.795  0.490  1.0
  Ag  Ag9  1  0.990  0.613  0.205  1.0
  Ag  Ag10  1  0.795  0.490  0.887  1.0
  Ag  Ag11  1  0.613  0.205  0.990  1.0
  Ag  Ag12  1  0.510  0.387  0.705  1.0
  Ag  Ag13  1  0.295  0.010  0.113  1.0
  Ag  Ag14  1  0.113  0.295  0.010  1.0
  Ag  Ag15  1  0.010  0.113  0.295  1.0
  Te  Te16  1  0.844  0.344  0.156  1.0
  Te  Te17  1  0.344  0.156  0.844  1.0
  Te  Te18  1  0.156  0.844  0.344  1.0
  Te  Te19  1  0.656  0.656  0.656  1.0
  S  S20  1  0.143  0.643  0.857  1.0
  S  S21  1  0.643  0.857  0.143  1.0
  S  S22  1  0.857  0.143  0.643  1.0
  S  S23  1  0.357  0.357  0.357  1.0
  O  O24  1  0.070  0.736  0.975  1.0
  O  O25  1  0.025  0.570  0.764  1.0
  O  O26  1  0.236  0.525  0.930  1.0
  O  O27  1  0.570  0.764  0.025  1.0
  O  O28  1  0.525  0.930  0.236  1.0
  O  O29  1  0.736  0.975  0.070  1.0
  O  O30  1  0.930  0.236  0.525  1.0
  O  O31  1  0.975  0.070  0.736  1.0
  O  O32  1  0.764  0.025  0.570  1.0
  O  O33  1  0.430  0.264  0.475  1.0
  O  O34  1  0.475  0.430  0.264  1.0
  O  O35  1  0.264  0.475  0.430  1.0
  O  O36  1  0.239  0.739  0.761  1.0
  O  O37  1  0.739  0.761  0.239  1.0
  O  O38  1  0.761  0.239  0.739  1.0
  O  O39  1  0.261  0.261  0.261  1.0
[/CIF]
.
The compound described by Ag4TeSO4 crystallizes in the cubic P2_13 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to two equivalent Te(1), one O(1), and one O(2) atom. Te(1) is bonded in a 6-coordinate geometry to six equivalent Ag(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ag(2) and one S(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. is represented by the CIF file [CIF]
data_Ag4TeSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.973
_cell_length_b   8.973
_cell_length_c   8.973
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   722.463
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  1.000  0.500  1.0
  Ag  Ag1  1  1.000  0.500  0.500  1.0
  Ag  Ag2  1  0.500  0.500  1.000  1.0
  Ag  Ag3  1  0.000  0.000  0.000  1.0
  Ag  Ag4  1  0.205  0.990  0.613  1.0
  Ag  Ag5  1  0.387  0.705  0.510  1.0
  Ag  Ag6  1  0.490  0.887  0.795  1.0
  Ag  Ag7  1  0.705  0.510  0.387  1.0
  Ag  Ag8  1  0.887  0.795  0.490  1.0
  Ag  Ag9  1  0.990  0.613  0.205  1.0
  Ag  Ag10  1  0.795  0.490  0.887  1.0
  Ag  Ag11  1  0.613  0.205  0.990  1.0
  Ag  Ag12  1  0.510  0.387  0.705  1.0
  Ag  Ag13  1  0.295  0.010  0.113  1.0
  Ag  Ag14  1  0.113  0.295  0.010  1.0
  Ag  Ag15  1  0.010  0.113  0.295  1.0
  Te  Te16  1  0.844  0.344  0.156  1.0
  Te  Te17  1  0.344  0.156  0.844  1.0
  Te  Te18  1  0.156  0.844  0.344  1.0
  Te  Te19  1  0.656  0.656  0.656  1.0
  S  S20  1  0.143  0.643  0.857  1.0
  S  S21  1  0.643  0.857  0.143  1.0
  S  S22  1  0.857  0.143  0.643  1.0
  S  S23  1  0.357  0.357  0.357  1.0
  O  O24  1  0.070  0.736  0.975  1.0
  O  O25  1  0.025  0.570  0.764  1.0
  O  O26  1  0.236  0.525  0.930  1.0
  O  O27  1  0.570  0.764  0.025  1.0
  O  O28  1  0.525  0.930  0.236  1.0
  O  O29  1  0.736  0.975  0.070  1.0
  O  O30  1  0.930  0.236  0.525  1.0
  O  O31  1  0.975  0.070  0.736  1.0
  O  O32  1  0.764  0.025  0.570  1.0
  O  O33  1  0.430  0.264  0.475  1.0
  O  O34  1  0.475  0.430  0.264  1.0
  O  O35  1  0.264  0.475  0.430  1.0
  O  O36  1  0.239  0.739  0.761  1.0
  O  O37  1  0.739  0.761  0.239  1.0
  O  O38  1  0.761  0.239  0.739  1.0
  O  O39  1  0.261  0.261  0.261  1.0
[/CIF]
.