The compound described by EuNi5P3 crystallizes in the orthorhombic Cmcm space group. Eu(1) is bonded in a 15-coordinate geometry to four equivalent Ni(1), four equivalent Ni(2), three equivalent P(1), and four equivalent P(2) atoms. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to two equivalent Eu(1), two equivalent P(1), and two equivalent P(2) atoms. In the second Ni site, Ni(2) is bonded in a 4-coordinate geometry to two equivalent Eu(1), one P(1), and three equivalent P(2) atoms. In the third Ni site, Ni(3) is bonded in a 4-coordinate geometry to four equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent Eu(1), two equivalent Ni(2), and four equivalent Ni(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Eu(1), two equivalent Ni(1), two equivalent Ni(3), and three equivalent Ni(2) atoms. is represented by the CIF file [CIF]
data_EuNi5P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.077
_cell_length_b   6.077
_cell_length_c   11.425
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   145.800
_symmetry_Int_Tables_number   1
_cell_volume   237.174
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.161  0.839  0.250  1.0
  Eu  Eu1  1  0.839  0.161  0.750  1.0
  Ni  Ni2  1  0.449  0.551  0.145  1.0
  Ni  Ni3  1  0.449  0.551  0.355  1.0
  Ni  Ni4  1  0.198  0.802  0.932  1.0
  Ni  Ni5  1  0.551  0.449  0.855  1.0
  Ni  Ni6  1  0.802  0.198  0.432  1.0
  Ni  Ni7  1  0.551  0.449  0.645  1.0
  Ni  Ni8  1  0.198  0.802  0.568  1.0
  Ni  Ni9  1  0.000  0.000  0.000  1.0
  Ni  Ni10  1  0.000  0.000  0.500  1.0
  Ni  Ni11  1  0.802  0.198  0.068  1.0
  P  P12  1  0.117  0.883  0.750  1.0
  P  P13  1  0.381  0.619  0.961  1.0
  P  P14  1  0.381  0.619  0.539  1.0
  P  P15  1  0.619  0.381  0.461  1.0
  P  P16  1  0.619  0.381  0.039  1.0
  P  P17  1  0.883  0.117  0.250  1.0
[/CIF]
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The compound described by EuNi5P3 crystallizes in the orthorhombic Cmcm space group. Eu(1) is bonded in a 15-coordinate geometry to four equivalent Ni(1), four equivalent Ni(2), three equivalent P(1), and four equivalent P(2) atoms. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to two equivalent Eu(1), two equivalent P(1), and two equivalent P(2) atoms. In the second Ni site, Ni(2) is bonded in a 4-coordinate geometry to two equivalent Eu(1), one P(1), and three equivalent P(2) atoms. In the third Ni site, Ni(3) is bonded in a 4-coordinate geometry to four equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent Eu(1), two equivalent Ni(2), and four equivalent Ni(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Eu(1), two equivalent Ni(1), two equivalent Ni(3), and three equivalent Ni(2) atoms. is represented by the CIF file [CIF]
data_EuNi5P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.077
_cell_length_b   6.077
_cell_length_c   11.425
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   145.800
_symmetry_Int_Tables_number   1
_cell_volume   237.174
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.161  0.839  0.250  1.0
  Eu  Eu1  1  0.839  0.161  0.750  1.0
  Ni  Ni2  1  0.449  0.551  0.145  1.0
  Ni  Ni3  1  0.449  0.551  0.355  1.0
  Ni  Ni4  1  0.198  0.802  0.932  1.0
  Ni  Ni5  1  0.551  0.449  0.855  1.0
  Ni  Ni6  1  0.802  0.198  0.432  1.0
  Ni  Ni7  1  0.551  0.449  0.645  1.0
  Ni  Ni8  1  0.198  0.802  0.568  1.0
  Ni  Ni9  1  0.000  0.000  0.000  1.0
  Ni  Ni10  1  0.000  0.000  0.500  1.0
  Ni  Ni11  1  0.802  0.198  0.068  1.0
  P  P12  1  0.117  0.883  0.750  1.0
  P  P13  1  0.381  0.619  0.961  1.0
  P  P14  1  0.381  0.619  0.539  1.0
  P  P15  1  0.619  0.381  0.461  1.0
  P  P16  1  0.619  0.381  0.039  1.0
  P  P17  1  0.883  0.117  0.250  1.0
[/CIF]
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