The material described by MnOF crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. O(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.109
_cell_length_b   4.746
_cell_length_c   5.850
_cell_angle_alpha   90.001
_cell_angle_beta   93.126
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   141.632
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.227  0.477  0.660  1.0
  Mn  Mn1  1  0.227  0.023  0.160  1.0
  Mn  Mn2  1  0.773  0.977  0.840  1.0
  Mn  Mn3  1  0.773  0.523  0.340  1.0
  O  O4  1  0.075  0.212  0.897  1.0
  O  O5  1  0.075  0.288  0.397  1.0
  O  O6  1  0.925  0.712  0.603  1.0
  O  O7  1  0.925  0.788  0.103  1.0
  F  F8  1  0.434  0.753  0.868  1.0
  F  F9  1  0.434  0.747  0.368  1.0
  F  F10  1  0.566  0.253  0.632  1.0
  F  F11  1  0.566  0.247  0.132  1.0
[/CIF]
.
The material described by MnOF crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. O(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.109
_cell_length_b   4.746
_cell_length_c   5.850
_cell_angle_alpha   90.001
_cell_angle_beta   93.126
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   141.632
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.227  0.477  0.660  1.0
  Mn  Mn1  1  0.227  0.023  0.160  1.0
  Mn  Mn2  1  0.773  0.977  0.840  1.0
  Mn  Mn3  1  0.773  0.523  0.340  1.0
  O  O4  1  0.075  0.212  0.897  1.0
  O  O5  1  0.075  0.288  0.397  1.0
  O  O6  1  0.925  0.712  0.603  1.0
  O  O7  1  0.925  0.788  0.103  1.0
  F  F8  1  0.434  0.753  0.868  1.0
  F  F9  1  0.434  0.747  0.368  1.0
  F  F10  1  0.566  0.253  0.632  1.0
  F  F11  1  0.566  0.247  0.132  1.0
[/CIF]
.