The structure described by LiVF4 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. V(1) is bonded to one F(1), one F(4), two equivalent F(2), and two equivalent F(3) atoms to form distorted edge-sharing VF6 octahedra. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Li(1) and two equivalent V(1) atoms. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Li(1) and two equivalent V(1) atoms. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiVF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.437
_cell_length_b   6.401
_cell_length_c   9.073
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   315.742
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.008  0.531  0.591  1.0
  Li  Li1  1  0.508  0.969  0.409  1.0
  Li  Li2  1  0.492  0.469  0.091  1.0
  Li  Li3  1  0.992  0.031  0.909  1.0
  V  V4  1  0.487  0.268  0.758  1.0
  V  V5  1  0.987  0.232  0.242  1.0
  V  V6  1  0.013  0.732  0.258  1.0
  V  V7  1  0.513  0.768  0.742  1.0
  F  F8  1  0.157  0.300  0.693  1.0
  F  F9  1  0.588  0.043  0.619  1.0
  F  F10  1  0.658  0.491  0.644  1.0
  F  F11  1  0.269  0.734  0.594  1.0
  F  F12  1  0.769  0.766  0.406  1.0
  F  F13  1  0.158  0.009  0.356  1.0
  F  F14  1  0.088  0.457  0.381  1.0
  F  F15  1  0.657  0.200  0.307  1.0
  F  F16  1  0.343  0.700  0.193  1.0
  F  F17  1  0.912  0.957  0.119  1.0
  F  F18  1  0.842  0.509  0.144  1.0
  F  F19  1  0.231  0.266  0.094  1.0
  F  F20  1  0.731  0.234  0.906  1.0
  F  F21  1  0.342  0.991  0.856  1.0
  F  F22  1  0.412  0.543  0.881  1.0
  F  F23  1  0.843  0.800  0.807  1.0
[/CIF]
.
The structure described by LiVF4 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. V(1) is bonded to one F(1), one F(4), two equivalent F(2), and two equivalent F(3) atoms to form distorted edge-sharing VF6 octahedra. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Li(1) and two equivalent V(1) atoms. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Li(1) and two equivalent V(1) atoms. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiVF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.437
_cell_length_b   6.401
_cell_length_c   9.073
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   315.742
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.008  0.531  0.591  1.0
  Li  Li1  1  0.508  0.969  0.409  1.0
  Li  Li2  1  0.492  0.469  0.091  1.0
  Li  Li3  1  0.992  0.031  0.909  1.0
  V  V4  1  0.487  0.268  0.758  1.0
  V  V5  1  0.987  0.232  0.242  1.0
  V  V6  1  0.013  0.732  0.258  1.0
  V  V7  1  0.513  0.768  0.742  1.0
  F  F8  1  0.157  0.300  0.693  1.0
  F  F9  1  0.588  0.043  0.619  1.0
  F  F10  1  0.658  0.491  0.644  1.0
  F  F11  1  0.269  0.734  0.594  1.0
  F  F12  1  0.769  0.766  0.406  1.0
  F  F13  1  0.158  0.009  0.356  1.0
  F  F14  1  0.088  0.457  0.381  1.0
  F  F15  1  0.657  0.200  0.307  1.0
  F  F16  1  0.343  0.700  0.193  1.0
  F  F17  1  0.912  0.957  0.119  1.0
  F  F18  1  0.842  0.509  0.144  1.0
  F  F19  1  0.231  0.266  0.094  1.0
  F  F20  1  0.731  0.234  0.906  1.0
  F  F21  1  0.342  0.991  0.856  1.0
  F  F22  1  0.412  0.543  0.881  1.0
  F  F23  1  0.843  0.800  0.807  1.0
[/CIF]
.