The structure described by VOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Ama2 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(3), two equivalent O(1), one F(2), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second V site, V(2) is bonded to one O(2), two equivalent O(1), one F(3), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the third V site, V(3) is bonded to one O(1), one O(2), one O(3), one F(1), one F(2), and one F(3) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(3) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.620
_cell_length_b   4.620
_cell_length_c   12.314
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.224
_symmetry_Int_Tables_number   1
_cell_volume   262.822
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.970  0.970  0.000  1.0
  V  V1  1  0.019  0.042  0.250  1.0
  V  V2  1  0.970  0.970  0.500  1.0
  V  V3  1  0.042  0.019  0.750  1.0
  V  V4  1  0.529  0.471  0.125  1.0
  V  V5  1  0.471  0.529  0.625  1.0
  V  V6  1  0.471  0.529  0.875  1.0
  V  V7  1  0.529  0.471  0.375  1.0
  O  O8  1  0.185  0.816  0.875  1.0
  O  O9  1  0.185  0.816  0.625  1.0
  O  O10  1  0.321  0.307  0.250  1.0
  O  O11  1  0.307  0.321  0.750  1.0
  O  O12  1  0.684  0.684  0.000  1.0
  O  O13  1  0.684  0.684  0.500  1.0
  O  O14  1  0.816  0.185  0.125  1.0
  O  O15  1  0.816  0.185  0.375  1.0
  F  F16  1  0.207  0.790  0.125  1.0
  F  F17  1  0.207  0.790  0.375  1.0
  F  F18  1  0.291  0.291  0.000  1.0
  F  F19  1  0.291  0.291  0.500  1.0
  F  F20  1  0.731  0.691  0.250  1.0
  F  F21  1  0.691  0.731  0.750  1.0
  F  F22  1  0.790  0.207  0.625  1.0
  F  F23  1  0.790  0.206  0.875  1.0
[/CIF]
.
The structure described by VOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Ama2 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(3), two equivalent O(1), one F(2), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second V site, V(2) is bonded to one O(2), two equivalent O(1), one F(3), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the third V site, V(3) is bonded to one O(1), one O(2), one O(3), one F(1), one F(2), and one F(3) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(3) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.620
_cell_length_b   4.620
_cell_length_c   12.314
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.224
_symmetry_Int_Tables_number   1
_cell_volume   262.822
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.970  0.970  0.000  1.0
  V  V1  1  0.019  0.042  0.250  1.0
  V  V2  1  0.970  0.970  0.500  1.0
  V  V3  1  0.042  0.019  0.750  1.0
  V  V4  1  0.529  0.471  0.125  1.0
  V  V5  1  0.471  0.529  0.625  1.0
  V  V6  1  0.471  0.529  0.875  1.0
  V  V7  1  0.529  0.471  0.375  1.0
  O  O8  1  0.185  0.816  0.875  1.0
  O  O9  1  0.185  0.816  0.625  1.0
  O  O10  1  0.321  0.307  0.250  1.0
  O  O11  1  0.307  0.321  0.750  1.0
  O  O12  1  0.684  0.684  0.000  1.0
  O  O13  1  0.684  0.684  0.500  1.0
  O  O14  1  0.816  0.185  0.125  1.0
  O  O15  1  0.816  0.185  0.375  1.0
  F  F16  1  0.207  0.790  0.125  1.0
  F  F17  1  0.207  0.790  0.375  1.0
  F  F18  1  0.291  0.291  0.000  1.0
  F  F19  1  0.291  0.291  0.500  1.0
  F  F20  1  0.731  0.691  0.250  1.0
  F  F21  1  0.691  0.731  0.750  1.0
  F  F22  1  0.790  0.207  0.625  1.0
  F  F23  1  0.790  0.206  0.875  1.0
[/CIF]
.