The structure described by LiV4OF11 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(10), one F(3), one F(6), and one F(9) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one F(1), one F(10), one F(11), one F(2), one F(5), and one F(8) atom to form VF6 octahedra that share corners with two equivalent V(4)OF5 octahedra and corners with four equivalent V(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 34-42°. In the second V site, V(2) is bonded to one F(10), one F(2), one F(5), one F(6), one F(7), and one F(8) atom to form VF6 octahedra that share corners with two equivalent V(3)OF5 octahedra and corners with four equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 31-42°. In the third V site, V(3) is bonded to one O(1), one F(3), one F(4), one F(6), one F(7), and one F(9) atom to form VOF5 octahedra that share corners with two equivalent V(2)F6 octahedra and corners with four equivalent V(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-41°. In the fourth V site, V(4) is bonded to one O(1), one F(1), one F(11), one F(3), one F(4), and one F(9) atom to form VOF5 octahedra that share corners with two equivalent V(1)F6 octahedra and corners with four equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-37°. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one V(3), and one V(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one V(4) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the third F site, F(3) is bonded in a T-shaped geometry to one Li(1), one V(3), and one V(4) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one V(3) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the ninth F site, F(9) is bonded in a T-shaped geometry to one Li(1), one V(3), and one V(4) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one V(2) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiV4OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.214
_cell_length_b   5.501
_cell_length_c   7.633
_cell_angle_alpha   94.415
_cell_angle_beta   90.343
_cell_angle_gamma   90.796
_symmetry_Int_Tables_number   1
_cell_volume   218.275
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.006  0.578  0.190  1.0
  V  V1  1  0.002  0.002  0.504  1.0
  V  V2  1  0.504  0.499  0.500  1.0
  V  V3  1  0.484  0.485  0.997  1.0
  V  V4  1  0.008  0.022  0.001  1.0
  O  O5  1  0.196  0.308  0.055  1.0
  F  F6  1  0.893  0.993  0.258  1.0
  F  F7  1  0.814  0.312  0.555  1.0
  F  F8  1  0.804  0.694  0.970  1.0
  F  F9  1  0.695  0.187  0.937  1.0
  F  F10  1  0.692  0.808  0.551  1.0
  F  F11  1  0.632  0.498  0.253  1.0
  F  F12  1  0.395  0.507  0.743  1.0
  F  F13  1  0.309  0.194  0.445  1.0
  F  F14  1  0.279  0.790  0.068  1.0
  F  F15  1  0.187  0.683  0.429  1.0
  F  F16  1  0.114  0.987  0.743  1.0
[/CIF]
.
The structure described by LiV4OF11 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(10), one F(3), one F(6), and one F(9) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one F(1), one F(10), one F(11), one F(2), one F(5), and one F(8) atom to form VF6 octahedra that share corners with two equivalent V(4)OF5 octahedra and corners with four equivalent V(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 34-42°. In the second V site, V(2) is bonded to one F(10), one F(2), one F(5), one F(6), one F(7), and one F(8) atom to form VF6 octahedra that share corners with two equivalent V(3)OF5 octahedra and corners with four equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 31-42°. In the third V site, V(3) is bonded to one O(1), one F(3), one F(4), one F(6), one F(7), and one F(9) atom to form VOF5 octahedra that share corners with two equivalent V(2)F6 octahedra and corners with four equivalent V(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-41°. In the fourth V site, V(4) is bonded to one O(1), one F(1), one F(11), one F(3), one F(4), and one F(9) atom to form VOF5 octahedra that share corners with two equivalent V(1)F6 octahedra and corners with four equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-37°. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one V(3), and one V(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one V(4) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the third F site, F(3) is bonded in a T-shaped geometry to one Li(1), one V(3), and one V(4) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one V(3) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the ninth F site, F(9) is bonded in a T-shaped geometry to one Li(1), one V(3), and one V(4) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one V(2) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiV4OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.214
_cell_length_b   5.501
_cell_length_c   7.633
_cell_angle_alpha   94.415
_cell_angle_beta   90.343
_cell_angle_gamma   90.796
_symmetry_Int_Tables_number   1
_cell_volume   218.275
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.006  0.578  0.190  1.0
  V  V1  1  0.002  0.002  0.504  1.0
  V  V2  1  0.504  0.499  0.500  1.0
  V  V3  1  0.484  0.485  0.997  1.0
  V  V4  1  0.008  0.022  0.001  1.0
  O  O5  1  0.196  0.308  0.055  1.0
  F  F6  1  0.893  0.993  0.258  1.0
  F  F7  1  0.814  0.312  0.555  1.0
  F  F8  1  0.804  0.694  0.970  1.0
  F  F9  1  0.695  0.187  0.937  1.0
  F  F10  1  0.692  0.808  0.551  1.0
  F  F11  1  0.632  0.498  0.253  1.0
  F  F12  1  0.395  0.507  0.743  1.0
  F  F13  1  0.309  0.194  0.445  1.0
  F  F14  1  0.279  0.790  0.068  1.0
  F  F15  1  0.187  0.683  0.429  1.0
  F  F16  1  0.114  0.987  0.743  1.0
[/CIF]
.