The material structure described by WCoP2O8 crystallizes in the monoclinic P2_1/m space group. W(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(6) atoms to form WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-53°. Co(1) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted CoO6 octahedra that share corners with four equivalent W(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), and two equivalent O(5) atoms to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the second P site, P(2) is bonded to one O(3), one O(4), and two equivalent O(6) atoms to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with three equivalent Co(1)O6 octahedra, and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-59°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one P(2) atom. is represented by the CIF file [CIF]
data_CoP2WO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.956
_cell_length_b   10.185
_cell_length_c   5.980
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   92.469
_symmetry_Int_Tables_number   1
_cell_volume   301.564
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.934  0.282  0.250  1.0
  Co  Co1  1  0.066  0.718  0.750  1.0
  P  P2  1  0.402  0.092  0.250  1.0
  P  P3  1  0.598  0.908  0.750  1.0
  P  P4  1  0.892  0.407  0.750  1.0
  P  P5  1  0.108  0.593  0.250  1.0
  W  W6  1  0.444  0.220  0.750  1.0
  W  W7  1  0.556  0.780  0.250  1.0
  O  O8  1  0.685  0.054  0.750  1.0
  O  O9  1  0.315  0.946  0.250  1.0
  O  O10  1  0.705  0.115  0.250  1.0
  O  O11  1  0.295  0.885  0.750  1.0
  O  O12  1  0.191  0.378  0.750  1.0
  O  O13  1  0.809  0.622  0.250  1.0
  O  O14  1  0.155  0.448  0.250  1.0
  O  O15  1  0.845  0.552  0.750  1.0
  O  O16  1  0.265  0.165  0.045  1.0
  O  O17  1  0.265  0.165  0.455  1.0
  O  O18  1  0.735  0.835  0.545  1.0
  O  O19  1  0.735  0.835  0.955  1.0
  O  O20  1  0.735  0.330  0.553  1.0
  O  O21  1  0.735  0.330  0.947  1.0
  O  O22  1  0.265  0.670  0.053  1.0
  O  O23  1  0.265  0.670  0.447  1.0
[/CIF]
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The material structure described by WCoP2O8 crystallizes in the monoclinic P2_1/m space group. W(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(6) atoms to form WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-53°. Co(1) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted CoO6 octahedra that share corners with four equivalent W(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), and two equivalent O(5) atoms to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the second P site, P(2) is bonded to one O(3), one O(4), and two equivalent O(6) atoms to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with three equivalent Co(1)O6 octahedra, and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-59°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one P(2) atom. is represented by the CIF file [CIF]
data_CoP2WO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.956
_cell_length_b   10.185
_cell_length_c   5.980
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   92.469
_symmetry_Int_Tables_number   1
_cell_volume   301.564
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.934  0.282  0.250  1.0
  Co  Co1  1  0.066  0.718  0.750  1.0
  P  P2  1  0.402  0.092  0.250  1.0
  P  P3  1  0.598  0.908  0.750  1.0
  P  P4  1  0.892  0.407  0.750  1.0
  P  P5  1  0.108  0.593  0.250  1.0
  W  W6  1  0.444  0.220  0.750  1.0
  W  W7  1  0.556  0.780  0.250  1.0
  O  O8  1  0.685  0.054  0.750  1.0
  O  O9  1  0.315  0.946  0.250  1.0
  O  O10  1  0.705  0.115  0.250  1.0
  O  O11  1  0.295  0.885  0.750  1.0
  O  O12  1  0.191  0.378  0.750  1.0
  O  O13  1  0.809  0.622  0.250  1.0
  O  O14  1  0.155  0.448  0.250  1.0
  O  O15  1  0.845  0.552  0.750  1.0
  O  O16  1  0.265  0.165  0.045  1.0
  O  O17  1  0.265  0.165  0.455  1.0
  O  O18  1  0.735  0.835  0.545  1.0
  O  O19  1  0.735  0.835  0.955  1.0
  O  O20  1  0.735  0.330  0.553  1.0
  O  O21  1  0.735  0.330  0.947  1.0
  O  O22  1  0.265  0.670  0.053  1.0
  O  O23  1  0.265  0.670  0.447  1.0
[/CIF]
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