The crystal structure described by LiAgF2 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded to two equivalent F(2) and three equivalent F(1) atoms to form edge-sharing LiF5 square pyramids. Ag(1) is bonded in a distorted T-shaped geometry to one F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to three equivalent Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded to two equivalent Li(1) and two equivalent Ag(1) atoms to form distorted corner-sharing FLi2Ag2 trigonal pyramids. is represented by the CIF file [CIF]
data_LiAgF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.964
_cell_length_b   6.116
_cell_length_c   11.281
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   204.499
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.288  0.240  0.107  1.0
  Li  Li1  1  0.788  0.260  0.893  1.0
  Li  Li2  1  0.712  0.740  0.393  1.0
  Li  Li3  1  0.212  0.760  0.607  1.0
  Ag  Ag4  1  0.664  0.240  0.618  1.0
  Ag  Ag5  1  0.164  0.260  0.382  1.0
  Ag  Ag6  1  0.336  0.740  0.882  1.0
  Ag  Ag7  1  0.836  0.760  0.118  1.0
  F  F8  1  0.286  0.070  0.957  1.0
  F  F9  1  0.784  0.092  0.197  1.0
  F  F10  1  0.284  0.408  0.803  1.0
  F  F11  1  0.786  0.430  0.043  1.0
  F  F12  1  0.714  0.570  0.543  1.0
  F  F13  1  0.216  0.592  0.303  1.0
  F  F14  1  0.716  0.908  0.697  1.0
  F  F15  1  0.214  0.930  0.457  1.0
[/CIF]
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The crystal structure described by LiAgF2 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded to two equivalent F(2) and three equivalent F(1) atoms to form edge-sharing LiF5 square pyramids. Ag(1) is bonded in a distorted T-shaped geometry to one F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to three equivalent Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded to two equivalent Li(1) and two equivalent Ag(1) atoms to form distorted corner-sharing FLi2Ag2 trigonal pyramids. is represented by the CIF file [CIF]
data_LiAgF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.964
_cell_length_b   6.116
_cell_length_c   11.281
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   204.499
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.288  0.240  0.107  1.0
  Li  Li1  1  0.788  0.260  0.893  1.0
  Li  Li2  1  0.712  0.740  0.393  1.0
  Li  Li3  1  0.212  0.760  0.607  1.0
  Ag  Ag4  1  0.664  0.240  0.618  1.0
  Ag  Ag5  1  0.164  0.260  0.382  1.0
  Ag  Ag6  1  0.336  0.740  0.882  1.0
  Ag  Ag7  1  0.836  0.760  0.118  1.0
  F  F8  1  0.286  0.070  0.957  1.0
  F  F9  1  0.784  0.092  0.197  1.0
  F  F10  1  0.284  0.408  0.803  1.0
  F  F11  1  0.786  0.430  0.043  1.0
  F  F12  1  0.714  0.570  0.543  1.0
  F  F13  1  0.216  0.592  0.303  1.0
  F  F14  1  0.716  0.908  0.697  1.0
  F  F15  1  0.214  0.930  0.457  1.0
[/CIF]
.