The structure described by Li4Ti3Mn3(TeO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(8), and two equivalent O(11) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with three equivalent Te(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-72°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(4), one O(5), and two equivalent O(12) atoms. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(3), one O(6), and two equivalent O(9) atoms. In the fourth Li site, Li(4) is bonded to one O(1), one O(7), and two equivalent O(10) atoms to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Te(1)O6 octahedra, and corners with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-72°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(4), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TiO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form TiO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-56°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), two equivalent O(10), and two equivalent O(12) atoms to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second Mn site, Mn(2) is bonded to one O(11), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form distorted TeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-56°. In the second Te site, Te(2) is bonded to one O(5), one O(8), two equivalent O(11), and two equivalent O(12) atoms to form distorted TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-56°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent Ti(2), and one Te(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent Ti(2), and one Mn(1) atom. In the third O site, O(3) is bonded to one Li(3), two equivalent Ti(2), and one Mn(1) atom to form distorted corner-sharing OLiTi2Mn tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one Ti(1), and two equivalent Mn(2) atoms to form OLiTiMn2 tetrahedra that share corners with two equivalent O(8)LiMn2Te tetrahedra and corners with three equivalent O(7)LiTiMn2 trigonal pyramids. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(2), two equivalent Ti(2), and one Te(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Mn(2), and one Te(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), and two equivalent Mn(2) atoms to form distorted OLiTiMn2 trigonal pyramids that share corners with two equivalent O(10)LiTiMnTe tetrahedra, corners with three equivalent O(4)LiTiMn2 tetrahedra, and  an edgeedge with one O(8)LiMn2Te tetrahedra. In the eighth O site, O(8) is bonded to one Li(1), two equivalent Mn(2), and one Te(2) atom to form a mixture of distorted corner and edge-sharing OLiMn2Te tetrahedra. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Ti(1), one Mn(2), and one Te(1) atom. In the tenth O site, O(10) is bonded to one Li(4), one Ti(2), one Mn(1), and one Te(1) atom to form distorted OLiTiMnTe tetrahedra that share  a cornercorner with one O(10)LiTiMnTe tetrahedra, corners with two equivalent O(3)LiTi2Mn tetrahedra,  a cornercorner with one O(7)LiTiMn2 trigonal pyramid, and  an edgeedge with one O(10)LiTiMnTe tetrahedra. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Ti(1), one Mn(2), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one Mn(1), and one Te(2) atom. is represented by the CIF card [CIF]
data_Li4Ti3Mn3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.018
_cell_length_b   6.078
_cell_length_c   10.316
_cell_angle_alpha   89.920
_cell_angle_beta   89.999
_cell_angle_gamma   119.667
_symmetry_Int_Tables_number   1
_cell_volume   327.862
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.671  0.341  0.902  1.0
  Li  Li1  1  0.008  0.017  0.990  1.0
  Li  Li2  1  0.000  0.001  0.492  1.0
  Li  Li3  1  0.331  0.662  0.400  1.0
  Mn  Mn4  1  0.832  0.663  0.212  1.0
  Mn  Mn5  1  0.167  0.835  0.711  1.0
  Mn  Mn6  1  0.667  0.835  0.711  1.0
  O  O7  1  0.504  0.009  0.318  1.0
  O  O8  1  0.656  0.313  0.115  1.0
  O  O9  1  0.001  0.003  0.311  1.0
  O  O10  1  0.997  0.995  0.804  1.0
  O  O11  1  0.150  0.300  0.120  1.0
  O  O12  1  0.831  0.663  0.579  1.0
  O  O13  1  0.337  0.674  0.615  1.0
  O  O14  1  0.488  0.977  0.858  1.0
  O  O15  1  0.307  0.152  0.608  1.0
  O  O16  1  0.845  0.153  0.607  1.0
  O  O17  1  0.489  0.452  0.344  1.0
  O  O18  1  0.962  0.452  0.344  1.0
  O  O19  1  0.024  0.510  0.816  1.0
  O  O20  1  0.487  0.510  0.816  1.0
  O  O21  1  0.181  0.864  0.091  1.0
  O  O22  1  0.684  0.864  0.091  1.0
  Te  Te23  1  0.666  0.332  0.494  1.0
  Te  Te24  1  0.360  0.719  0.994  1.0
  Ti  Ti25  1  0.177  0.353  0.722  1.0
  Ti  Ti26  1  0.339  0.176  0.222  1.0
  Ti  Ti27  1  0.837  0.176  0.222  1.0
[/CIF]
.
The structure described by Li4Ti3Mn3(TeO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(8), and two equivalent O(11) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with three equivalent Te(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-72°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(4), one O(5), and two equivalent O(12) atoms. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(3), one O(6), and two equivalent O(9) atoms. In the fourth Li site, Li(4) is bonded to one O(1), one O(7), and two equivalent O(10) atoms to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Te(1)O6 octahedra, and corners with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-72°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(4), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TiO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form TiO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-56°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), two equivalent O(10), and two equivalent O(12) atoms to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second Mn site, Mn(2) is bonded to one O(11), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form distorted TeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-56°. In the second Te site, Te(2) is bonded to one O(5), one O(8), two equivalent O(11), and two equivalent O(12) atoms to form distorted TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-56°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent Ti(2), and one Te(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent Ti(2), and one Mn(1) atom. In the third O site, O(3) is bonded to one Li(3), two equivalent Ti(2), and one Mn(1) atom to form distorted corner-sharing OLiTi2Mn tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one Ti(1), and two equivalent Mn(2) atoms to form OLiTiMn2 tetrahedra that share corners with two equivalent O(8)LiMn2Te tetrahedra and corners with three equivalent O(7)LiTiMn2 trigonal pyramids. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(2), two equivalent Ti(2), and one Te(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Mn(2), and one Te(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), and two equivalent Mn(2) atoms to form distorted OLiTiMn2 trigonal pyramids that share corners with two equivalent O(10)LiTiMnTe tetrahedra, corners with three equivalent O(4)LiTiMn2 tetrahedra, and  an edgeedge with one O(8)LiMn2Te tetrahedra. In the eighth O site, O(8) is bonded to one Li(1), two equivalent Mn(2), and one Te(2) atom to form a mixture of distorted corner and edge-sharing OLiMn2Te tetrahedra. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Ti(1), one Mn(2), and one Te(1) atom. In the tenth O site, O(10) is bonded to one Li(4), one Ti(2), one Mn(1), and one Te(1) atom to form distorted OLiTiMnTe tetrahedra that share  a cornercorner with one O(10)LiTiMnTe tetrahedra, corners with two equivalent O(3)LiTi2Mn tetrahedra,  a cornercorner with one O(7)LiTiMn2 trigonal pyramid, and  an edgeedge with one O(10)LiTiMnTe tetrahedra. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Ti(1), one Mn(2), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one Mn(1), and one Te(2) atom. is represented by the CIF card [CIF]
data_Li4Ti3Mn3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.018
_cell_length_b   6.078
_cell_length_c   10.316
_cell_angle_alpha   89.920
_cell_angle_beta   89.999
_cell_angle_gamma   119.667
_symmetry_Int_Tables_number   1
_cell_volume   327.862
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.671  0.341  0.902  1.0
  Li  Li1  1  0.008  0.017  0.990  1.0
  Li  Li2  1  0.000  0.001  0.492  1.0
  Li  Li3  1  0.331  0.662  0.400  1.0
  Mn  Mn4  1  0.832  0.663  0.212  1.0
  Mn  Mn5  1  0.167  0.835  0.711  1.0
  Mn  Mn6  1  0.667  0.835  0.711  1.0
  O  O7  1  0.504  0.009  0.318  1.0
  O  O8  1  0.656  0.313  0.115  1.0
  O  O9  1  0.001  0.003  0.311  1.0
  O  O10  1  0.997  0.995  0.804  1.0
  O  O11  1  0.150  0.300  0.120  1.0
  O  O12  1  0.831  0.663  0.579  1.0
  O  O13  1  0.337  0.674  0.615  1.0
  O  O14  1  0.488  0.977  0.858  1.0
  O  O15  1  0.307  0.152  0.608  1.0
  O  O16  1  0.845  0.153  0.607  1.0
  O  O17  1  0.489  0.452  0.344  1.0
  O  O18  1  0.962  0.452  0.344  1.0
  O  O19  1  0.024  0.510  0.816  1.0
  O  O20  1  0.487  0.510  0.816  1.0
  O  O21  1  0.181  0.864  0.091  1.0
  O  O22  1  0.684  0.864  0.091  1.0
  Te  Te23  1  0.666  0.332  0.494  1.0
  Te  Te24  1  0.360  0.719  0.994  1.0
  Ti  Ti25  1  0.177  0.353  0.722  1.0
  Ti  Ti26  1  0.339  0.176  0.222  1.0
  Ti  Ti27  1  0.837  0.176  0.222  1.0
[/CIF]
.