The crystal structure described by CdSO3 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form a mixture of distorted edge and corner-sharing CdO6 pentagonal pyramids. S(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one S(1) atom. is represented by the CIF card [CIF]
data_CdSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.026
_cell_length_b   4.573
_cell_length_c   7.283
_cell_angle_alpha   88.930
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   300.594
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.711  0.785  0.473  1.0
  Cd  Cd1  1  0.211  0.215  0.027  1.0
  Cd  Cd2  1  0.289  0.215  0.527  1.0
  Cd  Cd3  1  0.789  0.785  0.973  1.0
  S  S4  1  0.572  0.258  0.212  1.0
  S  S5  1  0.072  0.742  0.288  1.0
  S  S6  1  0.428  0.742  0.788  1.0
  S  S7  1  0.928  0.258  0.712  1.0
  O  O8  1  0.902  0.735  0.255  1.0
  O  O9  1  0.402  0.265  0.245  1.0
  O  O10  1  0.098  0.265  0.745  1.0
  O  O11  1  0.598  0.735  0.755  1.0
  O  O12  1  0.610  0.930  0.184  1.0
  O  O13  1  0.110  0.070  0.316  1.0
  O  O14  1  0.390  0.070  0.816  1.0
  O  O15  1  0.890  0.930  0.684  1.0
  O  O16  1  0.861  0.306  0.906  1.0
  O  O17  1  0.361  0.694  0.594  1.0
  O  O18  1  0.139  0.694  0.094  1.0
  O  O19  1  0.639  0.306  0.406  1.0
[/CIF]
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The crystal structure described by CdSO3 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form a mixture of distorted edge and corner-sharing CdO6 pentagonal pyramids. S(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one S(1) atom. is represented by the CIF card [CIF]
data_CdSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.026
_cell_length_b   4.573
_cell_length_c   7.283
_cell_angle_alpha   88.930
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   300.594
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.711  0.785  0.473  1.0
  Cd  Cd1  1  0.211  0.215  0.027  1.0
  Cd  Cd2  1  0.289  0.215  0.527  1.0
  Cd  Cd3  1  0.789  0.785  0.973  1.0
  S  S4  1  0.572  0.258  0.212  1.0
  S  S5  1  0.072  0.742  0.288  1.0
  S  S6  1  0.428  0.742  0.788  1.0
  S  S7  1  0.928  0.258  0.712  1.0
  O  O8  1  0.902  0.735  0.255  1.0
  O  O9  1  0.402  0.265  0.245  1.0
  O  O10  1  0.098  0.265  0.745  1.0
  O  O11  1  0.598  0.735  0.755  1.0
  O  O12  1  0.610  0.930  0.184  1.0
  O  O13  1  0.110  0.070  0.316  1.0
  O  O14  1  0.390  0.070  0.816  1.0
  O  O15  1  0.890  0.930  0.684  1.0
  O  O16  1  0.861  0.306  0.906  1.0
  O  O17  1  0.361  0.694  0.594  1.0
  O  O18  1  0.139  0.694  0.094  1.0
  O  O19  1  0.639  0.306  0.406  1.0
[/CIF]
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