The crystal structure described by LiMn(PO3)4 crystallizes in the monoclinic Cc space group. Li(1) is bonded in a 3-coordinate geometry to one O(10), one O(4), and one O(6) atom. Mn(1) is bonded to one O(12), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. In the second P site, P(2) is bonded to one O(1), one O(12), one O(5), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-54°. In the third P site, P(3) is bonded to one O(2), one O(3), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-50°. In the fourth P site, P(4) is bonded to one O(1), one O(10), one O(11), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. There are twelve inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(4) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the third O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(10) is bonded in a bent 150 degrees geometry to one Li(1) and one P(4) atom. In the fifth O site, O(11) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the sixth O site, O(12) is bonded in a 1-coordinate geometry to one Mn(1) and one P(2) atom. In the seventh O site, O(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(3) atom. In the ninth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the tenth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the eleventh O site, O(5) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the twelfth O site, O(6) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. is represented by the CIF file [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.264
_cell_length_b   8.264
_cell_length_c   7.756
_cell_angle_alpha   84.923
_cell_angle_beta   84.923
_cell_angle_gamma   110.555
_symmetry_Int_Tables_number   1
_cell_volume   489.949
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.204  0.505  0.717  1.0
  Li  Li1  1  0.505  0.204  0.217  1.0
  Mn  Mn2  1  0.861  0.131  0.756  1.0
  Mn  Mn3  1  0.131  0.861  0.256  1.0
  P  P4  1  0.754  0.436  0.868  1.0
  P  P5  1  0.060  0.210  0.336  1.0
  P  P6  1  0.210  0.060  0.836  1.0
  P  P7  1  0.945  0.792  0.679  1.0
  P  P8  1  0.792  0.945  0.179  1.0
  P  P9  1  0.239  0.560  0.113  1.0
  P  P10  1  0.436  0.754  0.368  1.0
  P  P11  1  0.560  0.239  0.613  1.0
  O  O12  1  0.162  0.354  0.175  1.0
  O  O13  1  0.354  0.162  0.675  1.0
  O  O14  1  0.984  0.720  0.517  1.0
  O  O15  1  0.919  0.851  0.163  1.0
  O  O16  1  0.368  0.900  0.311  1.0
  O  O17  1  0.121  0.877  0.765  1.0
  O  O18  1  0.662  0.378  0.046  1.0
  O  O19  1  0.851  0.919  0.663  1.0
  O  O20  1  0.900  0.368  0.811  1.0
  O  O21  1  0.107  0.638  0.182  1.0
  O  O22  1  0.838  0.643  0.837  1.0
  O  O23  1  0.082  0.156  0.843  1.0
  O  O24  1  0.583  0.295  0.424  1.0
  O  O25  1  0.643  0.838  0.337  1.0
  O  O26  1  0.720  0.984  0.017  1.0
  O  O27  1  0.877  0.121  0.265  1.0
  O  O28  1  0.378  0.662  0.546  1.0
  O  O29  1  0.402  0.621  0.222  1.0
  O  O30  1  0.156  0.082  0.343  1.0
  O  O31  1  0.638  0.107  0.682  1.0
  O  O32  1  0.621  0.402  0.722  1.0
  O  O33  1  0.036  0.285  0.500  1.0
  O  O34  1  0.295  0.583  0.924  1.0
  O  O35  1  0.285  0.036  1.000  1.0
[/CIF]
.
The crystal structure described by LiMn(PO3)4 crystallizes in the monoclinic Cc space group. Li(1) is bonded in a 3-coordinate geometry to one O(10), one O(4), and one O(6) atom. Mn(1) is bonded to one O(12), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. In the second P site, P(2) is bonded to one O(1), one O(12), one O(5), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-54°. In the third P site, P(3) is bonded to one O(2), one O(3), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-50°. In the fourth P site, P(4) is bonded to one O(1), one O(10), one O(11), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. There are twelve inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(4) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the third O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(10) is bonded in a bent 150 degrees geometry to one Li(1) and one P(4) atom. In the fifth O site, O(11) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the sixth O site, O(12) is bonded in a 1-coordinate geometry to one Mn(1) and one P(2) atom. In the seventh O site, O(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(3) atom. In the ninth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the tenth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the eleventh O site, O(5) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the twelfth O site, O(6) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. is represented by the CIF file [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.264
_cell_length_b   8.264
_cell_length_c   7.756
_cell_angle_alpha   84.923
_cell_angle_beta   84.923
_cell_angle_gamma   110.555
_symmetry_Int_Tables_number   1
_cell_volume   489.949
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.204  0.505  0.717  1.0
  Li  Li1  1  0.505  0.204  0.217  1.0
  Mn  Mn2  1  0.861  0.131  0.756  1.0
  Mn  Mn3  1  0.131  0.861  0.256  1.0
  P  P4  1  0.754  0.436  0.868  1.0
  P  P5  1  0.060  0.210  0.336  1.0
  P  P6  1  0.210  0.060  0.836  1.0
  P  P7  1  0.945  0.792  0.679  1.0
  P  P8  1  0.792  0.945  0.179  1.0
  P  P9  1  0.239  0.560  0.113  1.0
  P  P10  1  0.436  0.754  0.368  1.0
  P  P11  1  0.560  0.239  0.613  1.0
  O  O12  1  0.162  0.354  0.175  1.0
  O  O13  1  0.354  0.162  0.675  1.0
  O  O14  1  0.984  0.720  0.517  1.0
  O  O15  1  0.919  0.851  0.163  1.0
  O  O16  1  0.368  0.900  0.311  1.0
  O  O17  1  0.121  0.877  0.765  1.0
  O  O18  1  0.662  0.378  0.046  1.0
  O  O19  1  0.851  0.919  0.663  1.0
  O  O20  1  0.900  0.368  0.811  1.0
  O  O21  1  0.107  0.638  0.182  1.0
  O  O22  1  0.838  0.643  0.837  1.0
  O  O23  1  0.082  0.156  0.843  1.0
  O  O24  1  0.583  0.295  0.424  1.0
  O  O25  1  0.643  0.838  0.337  1.0
  O  O26  1  0.720  0.984  0.017  1.0
  O  O27  1  0.877  0.121  0.265  1.0
  O  O28  1  0.378  0.662  0.546  1.0
  O  O29  1  0.402  0.621  0.222  1.0
  O  O30  1  0.156  0.082  0.343  1.0
  O  O31  1  0.638  0.107  0.682  1.0
  O  O32  1  0.621  0.402  0.722  1.0
  O  O33  1  0.036  0.285  0.500  1.0
  O  O34  1  0.295  0.583  0.924  1.0
  O  O35  1  0.285  0.036  1.000  1.0
[/CIF]
.