The crystal structure described by Mn6OF11 is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one F(1), one F(10), one F(2), one F(9), and two equivalent F(5) atoms to form a mixture of corner and edge-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 51-56°. In the second Mn site, Mn(2) is bonded to one F(1), one F(11), one F(2), one F(4), one F(6), and one F(8) atom to form MnF6 octahedra that share corners with two equivalent Mn(4)F6 octahedra, corners with two equivalent Mn(5)O2F4 octahedra, corners with four equivalent Mn(6)F6 octahedra,  an edgeedge with one Mn(1)F6 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the third Mn site, Mn(3) is bonded to one O(1), one F(4), one F(6), one F(7), and two equivalent F(3) atoms to form distorted MnOF5 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with six equivalent Mn(5)O2F4 octahedra,  an edgeedge with one Mn(2)F6 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 41-62°. In the fourth Mn site, Mn(4) is bonded to one F(10), one F(2), one F(5), one F(8), and two equivalent F(9) atoms to form a mixture of corner and edge-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 51-56°. In the fifth Mn site, Mn(5) is bonded to two equivalent O(1), one F(11), one F(3), one F(4), and one F(7) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(2)F6 octahedra, corners with six equivalent Mn(3)OF5 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 41-62°. In the sixth Mn site, Mn(6) is bonded to one F(1), one F(10), one F(11), one F(6), one F(7), and one F(8) atom to form MnF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra, corners with two equivalent Mn(3)OF5 octahedra, corners with four equivalent Mn(2)F6 octahedra,  an edgeedge with one Mn(4)F6 octahedra, and  an edgeedge with one Mn(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-57°. O(1) is bonded in a distorted trigonal planar geometry to one Mn(3) and two equivalent Mn(5) atoms. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(5) and two equivalent Mn(3) atoms. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(4) and two equivalent Mn(1) atoms. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Mn(4) atoms. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.897
_cell_length_b   5.773
_cell_length_c   15.855
_cell_angle_alpha   90.797
_cell_angle_beta   90.160
_cell_angle_gamma   91.139
_symmetry_Int_Tables_number   1
_cell_volume   448.083
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.003  0.832  0.586  1.0
  Mn  Mn1  1  0.005  0.178  0.759  1.0
  Mn  Mn2  1  0.984  0.815  0.924  1.0
  Mn  Mn3  1  0.995  0.822  0.241  1.0
  Mn  Mn4  1  0.997  0.168  0.414  1.0
  Mn  Mn5  1  0.016  0.185  0.076  1.0
  Mn  Mn6  1  0.495  0.673  0.416  1.0
  Mn  Mn7  1  0.505  0.642  0.075  1.0
  Mn  Mn8  1  0.496  0.676  0.753  1.0
  Mn  Mn9  1  0.495  0.358  0.925  1.0
  Mn  Mn10  1  0.505  0.327  0.584  1.0
  Mn  Mn11  1  0.504  0.324  0.247  1.0
  O  O12  1  0.295  0.396  0.026  1.0
  O  O13  1  0.705  0.604  0.974  1.0
  F  F14  1  0.236  0.907  0.696  1.0
  F  F15  1  0.224  0.890  0.355  1.0
  F  F16  1  0.226  0.892  0.030  1.0
  F  F17  1  0.245  0.124  0.870  1.0
  F  F18  1  0.234  0.102  0.524  1.0
  F  F19  1  0.215  0.108  0.191  1.0
  F  F20  1  0.244  0.609  0.856  1.0
  F  F21  1  0.267  0.397  0.694  1.0
  F  F22  1  0.272  0.603  0.528  1.0
  F  F23  1  0.266  0.395  0.355  1.0
  F  F24  1  0.295  0.615  0.183  1.0
  F  F25  1  0.705  0.385  0.817  1.0
  F  F26  1  0.734  0.605  0.645  1.0
  F  F27  1  0.728  0.397  0.472  1.0
  F  F28  1  0.756  0.391  0.144  1.0
  F  F29  1  0.733  0.603  0.306  1.0
  F  F30  1  0.785  0.892  0.809  1.0
  F  F31  1  0.766  0.898  0.476  1.0
  F  F32  1  0.776  0.110  0.645  1.0
  F  F33  1  0.774  0.108  0.970  1.0
  F  F34  1  0.755  0.876  0.130  1.0
  F  F35  1  0.764  0.093  0.304  1.0
[/CIF]
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The crystal structure described by Mn6OF11 is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one F(1), one F(10), one F(2), one F(9), and two equivalent F(5) atoms to form a mixture of corner and edge-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 51-56°. In the second Mn site, Mn(2) is bonded to one F(1), one F(11), one F(2), one F(4), one F(6), and one F(8) atom to form MnF6 octahedra that share corners with two equivalent Mn(4)F6 octahedra, corners with two equivalent Mn(5)O2F4 octahedra, corners with four equivalent Mn(6)F6 octahedra,  an edgeedge with one Mn(1)F6 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the third Mn site, Mn(3) is bonded to one O(1), one F(4), one F(6), one F(7), and two equivalent F(3) atoms to form distorted MnOF5 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with six equivalent Mn(5)O2F4 octahedra,  an edgeedge with one Mn(2)F6 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 41-62°. In the fourth Mn site, Mn(4) is bonded to one F(10), one F(2), one F(5), one F(8), and two equivalent F(9) atoms to form a mixture of corner and edge-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 51-56°. In the fifth Mn site, Mn(5) is bonded to two equivalent O(1), one F(11), one F(3), one F(4), and one F(7) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(2)F6 octahedra, corners with six equivalent Mn(3)OF5 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 41-62°. In the sixth Mn site, Mn(6) is bonded to one F(1), one F(10), one F(11), one F(6), one F(7), and one F(8) atom to form MnF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra, corners with two equivalent Mn(3)OF5 octahedra, corners with four equivalent Mn(2)F6 octahedra,  an edgeedge with one Mn(4)F6 octahedra, and  an edgeedge with one Mn(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-57°. O(1) is bonded in a distorted trigonal planar geometry to one Mn(3) and two equivalent Mn(5) atoms. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(5) and two equivalent Mn(3) atoms. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(4) and two equivalent Mn(1) atoms. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Mn(4) atoms. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.897
_cell_length_b   5.773
_cell_length_c   15.855
_cell_angle_alpha   90.797
_cell_angle_beta   90.160
_cell_angle_gamma   91.139
_symmetry_Int_Tables_number   1
_cell_volume   448.083
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.003  0.832  0.586  1.0
  Mn  Mn1  1  0.005  0.178  0.759  1.0
  Mn  Mn2  1  0.984  0.815  0.924  1.0
  Mn  Mn3  1  0.995  0.822  0.241  1.0
  Mn  Mn4  1  0.997  0.168  0.414  1.0
  Mn  Mn5  1  0.016  0.185  0.076  1.0
  Mn  Mn6  1  0.495  0.673  0.416  1.0
  Mn  Mn7  1  0.505  0.642  0.075  1.0
  Mn  Mn8  1  0.496  0.676  0.753  1.0
  Mn  Mn9  1  0.495  0.358  0.925  1.0
  Mn  Mn10  1  0.505  0.327  0.584  1.0
  Mn  Mn11  1  0.504  0.324  0.247  1.0
  O  O12  1  0.295  0.396  0.026  1.0
  O  O13  1  0.705  0.604  0.974  1.0
  F  F14  1  0.236  0.907  0.696  1.0
  F  F15  1  0.224  0.890  0.355  1.0
  F  F16  1  0.226  0.892  0.030  1.0
  F  F17  1  0.245  0.124  0.870  1.0
  F  F18  1  0.234  0.102  0.524  1.0
  F  F19  1  0.215  0.108  0.191  1.0
  F  F20  1  0.244  0.609  0.856  1.0
  F  F21  1  0.267  0.397  0.694  1.0
  F  F22  1  0.272  0.603  0.528  1.0
  F  F23  1  0.266  0.395  0.355  1.0
  F  F24  1  0.295  0.615  0.183  1.0
  F  F25  1  0.705  0.385  0.817  1.0
  F  F26  1  0.734  0.605  0.645  1.0
  F  F27  1  0.728  0.397  0.472  1.0
  F  F28  1  0.756  0.391  0.144  1.0
  F  F29  1  0.733  0.603  0.306  1.0
  F  F30  1  0.785  0.892  0.809  1.0
  F  F31  1  0.766  0.898  0.476  1.0
  F  F32  1  0.776  0.110  0.645  1.0
  F  F33  1  0.774  0.108  0.970  1.0
  F  F34  1  0.755  0.876  0.130  1.0
  F  F35  1  0.764  0.093  0.304  1.0
[/CIF]
.