The crystal structure described by Li3V3Cr2O10 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with four equivalent Li(2)O6 octahedra, and edges with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the second Li site, Li(2) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with three equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-19°. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-16°. In the second V site, V(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form distorted VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with three equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-17°. Cr(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form CrO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-19°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one V(1), two equivalent V(2), and one Cr(1) atom to form OLiV3Cr square pyramids that share  a cornercorner with one O(1)LiV3Cr square pyramid, corners with two equivalent O(3)Li3Cr2 square pyramids, corners with three equivalent O(5)Li3VCr square pyramids,  an edgeedge with one O(3)Li3Cr2 square pyramid,  an edgeedge with one O(5)Li3VCr square pyramid,  an edgeedge with one O(1)LiV3Cr square pyramid, and edges with three equivalent O(4)Li2V2Cr square pyramids. In the second O site, O(2) is bonded in a see-saw-like geometry to one V(1), two equivalent V(2), and one Cr(1) atom. In the third O site, O(3) is bonded to one Li(1), two equivalent Li(2), and two equivalent Cr(1) atoms to form OLi3Cr2 square pyramids that share  a cornercorner with one O(3)Li3Cr2 square pyramid, corners with two equivalent O(4)Li2V2Cr square pyramids, corners with two equivalent O(5)Li3VCr square pyramids, corners with two equivalent O(1)LiV3Cr square pyramids,  an edgeedge with one O(1)LiV3Cr square pyramid, edges with two equivalent O(4)Li2V2Cr square pyramids, edges with two equivalent O(3)Li3Cr2 square pyramids, and edges with three equivalent O(5)Li3VCr square pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one V(1), one V(2), and one Cr(1) atom to form distorted OLi2V2Cr square pyramids that share corners with two equivalent O(4)Li2V2Cr square pyramids, corners with two equivalent O(3)Li3Cr2 square pyramids, corners with two equivalent O(5)Li3VCr square pyramids, edges with two equivalent O(3)Li3Cr2 square pyramids, edges with two equivalent O(5)Li3VCr square pyramids, and edges with three equivalent O(1)LiV3Cr square pyramids. In the fifth O site, O(5) is bonded to one Li(1), two equivalent Li(2), one V(2), and one Cr(1) atom to form OLi3VCr square pyramids that share  a cornercorner with one O(5)Li3VCr square pyramid, corners with two equivalent O(4)Li2V2Cr square pyramids, corners with two equivalent O(3)Li3Cr2 square pyramids, corners with three equivalent O(1)LiV3Cr square pyramids,  an edgeedge with one O(5)Li3VCr square pyramid,  an edgeedge with one O(1)LiV3Cr square pyramid, edges with two equivalent O(4)Li2V2Cr square pyramids, and edges with three equivalent O(3)Li3Cr2 square pyramids. is represented by the CIF card [CIF]
data_Li3V3Cr2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.115
_cell_length_b   5.168
_cell_length_c   7.829
_cell_angle_alpha   73.414
_cell_angle_beta   73.882
_cell_angle_gamma   79.195
_symmetry_Int_Tables_number   1
_cell_volume   189.228
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.012  0.895  0.691  1.0
  Cr  Cr1  1  0.988  0.105  0.309  1.0
  Li  Li2  1  1.000  0.500  0.500  1.0
  Li  Li3  1  0.508  0.789  0.427  1.0
  Li  Li4  1  0.492  0.211  0.573  1.0
  O  O5  1  0.234  0.969  0.863  1.0
  O  O6  1  0.766  0.031  0.137  1.0
  O  O7  1  0.802  0.674  0.940  1.0
  O  O8  1  0.198  0.326  0.060  1.0
  O  O9  1  0.779  0.885  0.532  1.0
  O  O10  1  0.221  0.115  0.468  1.0
  O  O11  1  0.247  0.776  0.221  1.0
  O  O12  1  0.753  0.224  0.779  1.0
  O  O13  1  0.206  0.528  0.672  1.0
  O  O14  1  0.794  0.472  0.328  1.0
  V  V15  1  0.500  0.000  1.000  1.0
  V  V16  1  0.994  0.318  0.882  1.0
  V  V17  1  0.006  0.682  0.118  1.0
[/CIF]
.
The crystal structure described by Li3V3Cr2O10 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with four equivalent Li(2)O6 octahedra, and edges with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the second Li site, Li(2) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with three equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-19°. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-16°. In the second V site, V(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form distorted VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with three equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-17°. Cr(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form CrO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-19°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one V(1), two equivalent V(2), and one Cr(1) atom to form OLiV3Cr square pyramids that share  a cornercorner with one O(1)LiV3Cr square pyramid, corners with two equivalent O(3)Li3Cr2 square pyramids, corners with three equivalent O(5)Li3VCr square pyramids,  an edgeedge with one O(3)Li3Cr2 square pyramid,  an edgeedge with one O(5)Li3VCr square pyramid,  an edgeedge with one O(1)LiV3Cr square pyramid, and edges with three equivalent O(4)Li2V2Cr square pyramids. In the second O site, O(2) is bonded in a see-saw-like geometry to one V(1), two equivalent V(2), and one Cr(1) atom. In the third O site, O(3) is bonded to one Li(1), two equivalent Li(2), and two equivalent Cr(1) atoms to form OLi3Cr2 square pyramids that share  a cornercorner with one O(3)Li3Cr2 square pyramid, corners with two equivalent O(4)Li2V2Cr square pyramids, corners with two equivalent O(5)Li3VCr square pyramids, corners with two equivalent O(1)LiV3Cr square pyramids,  an edgeedge with one O(1)LiV3Cr square pyramid, edges with two equivalent O(4)Li2V2Cr square pyramids, edges with two equivalent O(3)Li3Cr2 square pyramids, and edges with three equivalent O(5)Li3VCr square pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one V(1), one V(2), and one Cr(1) atom to form distorted OLi2V2Cr square pyramids that share corners with two equivalent O(4)Li2V2Cr square pyramids, corners with two equivalent O(3)Li3Cr2 square pyramids, corners with two equivalent O(5)Li3VCr square pyramids, edges with two equivalent O(3)Li3Cr2 square pyramids, edges with two equivalent O(5)Li3VCr square pyramids, and edges with three equivalent O(1)LiV3Cr square pyramids. In the fifth O site, O(5) is bonded to one Li(1), two equivalent Li(2), one V(2), and one Cr(1) atom to form OLi3VCr square pyramids that share  a cornercorner with one O(5)Li3VCr square pyramid, corners with two equivalent O(4)Li2V2Cr square pyramids, corners with two equivalent O(3)Li3Cr2 square pyramids, corners with three equivalent O(1)LiV3Cr square pyramids,  an edgeedge with one O(5)Li3VCr square pyramid,  an edgeedge with one O(1)LiV3Cr square pyramid, edges with two equivalent O(4)Li2V2Cr square pyramids, and edges with three equivalent O(3)Li3Cr2 square pyramids. is represented by the CIF card [CIF]
data_Li3V3Cr2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.115
_cell_length_b   5.168
_cell_length_c   7.829
_cell_angle_alpha   73.414
_cell_angle_beta   73.882
_cell_angle_gamma   79.195
_symmetry_Int_Tables_number   1
_cell_volume   189.228
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.012  0.895  0.691  1.0
  Cr  Cr1  1  0.988  0.105  0.309  1.0
  Li  Li2  1  1.000  0.500  0.500  1.0
  Li  Li3  1  0.508  0.789  0.427  1.0
  Li  Li4  1  0.492  0.211  0.573  1.0
  O  O5  1  0.234  0.969  0.863  1.0
  O  O6  1  0.766  0.031  0.137  1.0
  O  O7  1  0.802  0.674  0.940  1.0
  O  O8  1  0.198  0.326  0.060  1.0
  O  O9  1  0.779  0.885  0.532  1.0
  O  O10  1  0.221  0.115  0.468  1.0
  O  O11  1  0.247  0.776  0.221  1.0
  O  O12  1  0.753  0.224  0.779  1.0
  O  O13  1  0.206  0.528  0.672  1.0
  O  O14  1  0.794  0.472  0.328  1.0
  V  V15  1  0.500  0.000  1.000  1.0
  V  V16  1  0.994  0.318  0.882  1.0
  V  V17  1  0.006  0.682  0.118  1.0
[/CIF]
.