The structure described by (AuBr4)2(AuBr2)4(N2)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twelve ammonia atoms, eight AuBr2 clusters, and four AuBr4 clusters. In each AuBr2 cluster, Au(2) is bonded in a linear geometry to two equivalent Br(1,2) atoms. Br(1,2) is bonded in a single-bond geometry to one Au(2) atom. In each AuBr4 cluster, Au(1) is bonded in a square co-planar geometry to two equivalent Br(3) and two equivalent Br(4) atoms. There are two inequivalent Br sites. In the first Br site, Br(4) is bonded in a single-bond geometry to one Au(1) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Au3Br8N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.672
_cell_length_b   7.672
_cell_length_c   19.879
_cell_angle_alpha   82.684
_cell_angle_beta   82.684
_cell_angle_gamma   64.321
_symmetry_Int_Tables_number   1
_cell_volume   1042.404
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.000  0.000  0.000  1.0
  Au  Au1  1  0.000  0.000  0.500  1.0
  Au  Au2  1  0.610  0.620  0.192  1.0
  Au  Au3  1  0.390  0.380  0.808  1.0
  Au  Au4  1  0.380  0.390  0.308  1.0
  Au  Au5  1  0.620  0.610  0.692  1.0
  Br  Br6  1  0.338  0.751  0.126  1.0
  Br  Br7  1  0.662  0.249  0.874  1.0
  Br  Br8  1  0.249  0.662  0.374  1.0
  Br  Br9  1  0.751  0.338  0.626  1.0
  Br  Br10  1  0.496  0.107  0.247  1.0
  Br  Br11  1  0.504  0.893  0.753  1.0
  Br  Br12  1  0.893  0.504  0.253  1.0
  Br  Br13  1  0.107  0.496  0.747  1.0
  Br  Br14  1  0.794  0.853  0.063  1.0
  Br  Br15  1  0.206  0.147  0.937  1.0
  Br  Br16  1  0.147  0.206  0.437  1.0
  Br  Br17  1  0.853  0.794  0.563  1.0
  Br  Br18  1  0.717  0.159  0.431  1.0
  Br  Br19  1  0.283  0.841  0.569  1.0
  Br  Br20  1  0.841  0.283  0.069  1.0
  Br  Br21  1  0.159  0.717  0.931  1.0
  N  N22  1  0.676  0.688  0.414  1.0
  N  N23  1  0.324  0.312  0.586  1.0
  N  N24  1  0.312  0.324  0.086  1.0
  N  N25  1  0.688  0.676  0.914  1.0
  N  N26  1  0.986  0.014  0.250  1.0
  N  N27  1  0.014  0.986  0.750  1.0
[/CIF]
.
The structure described by (AuBr4)2(AuBr2)4(N2)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twelve ammonia atoms, eight AuBr2 clusters, and four AuBr4 clusters. In each AuBr2 cluster, Au(2) is bonded in a linear geometry to two equivalent Br(1,2) atoms. Br(1,2) is bonded in a single-bond geometry to one Au(2) atom. In each AuBr4 cluster, Au(1) is bonded in a square co-planar geometry to two equivalent Br(3) and two equivalent Br(4) atoms. There are two inequivalent Br sites. In the first Br site, Br(4) is bonded in a single-bond geometry to one Au(1) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Au3Br8N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.672
_cell_length_b   7.672
_cell_length_c   19.879
_cell_angle_alpha   82.684
_cell_angle_beta   82.684
_cell_angle_gamma   64.321
_symmetry_Int_Tables_number   1
_cell_volume   1042.404
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.000  0.000  0.000  1.0
  Au  Au1  1  0.000  0.000  0.500  1.0
  Au  Au2  1  0.610  0.620  0.192  1.0
  Au  Au3  1  0.390  0.380  0.808  1.0
  Au  Au4  1  0.380  0.390  0.308  1.0
  Au  Au5  1  0.620  0.610  0.692  1.0
  Br  Br6  1  0.338  0.751  0.126  1.0
  Br  Br7  1  0.662  0.249  0.874  1.0
  Br  Br8  1  0.249  0.662  0.374  1.0
  Br  Br9  1  0.751  0.338  0.626  1.0
  Br  Br10  1  0.496  0.107  0.247  1.0
  Br  Br11  1  0.504  0.893  0.753  1.0
  Br  Br12  1  0.893  0.504  0.253  1.0
  Br  Br13  1  0.107  0.496  0.747  1.0
  Br  Br14  1  0.794  0.853  0.063  1.0
  Br  Br15  1  0.206  0.147  0.937  1.0
  Br  Br16  1  0.147  0.206  0.437  1.0
  Br  Br17  1  0.853  0.794  0.563  1.0
  Br  Br18  1  0.717  0.159  0.431  1.0
  Br  Br19  1  0.283  0.841  0.569  1.0
  Br  Br20  1  0.841  0.283  0.069  1.0
  Br  Br21  1  0.159  0.717  0.931  1.0
  N  N22  1  0.676  0.688  0.414  1.0
  N  N23  1  0.324  0.312  0.586  1.0
  N  N24  1  0.312  0.324  0.086  1.0
  N  N25  1  0.688  0.676  0.914  1.0
  N  N26  1  0.986  0.014  0.250  1.0
  N  N27  1  0.014  0.986  0.750  1.0
[/CIF]
.