The crystal structure described by CsYb(MoO4)2 crystallizes in the monoclinic P2/c space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(1) atoms. Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Yb(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Yb(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Yb(1), and one Mo(1) atom. is represented by the CIF card [CIF]
data_CsYb(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.056
_cell_length_b   8.233
_cell_length_c   9.931
_cell_angle_alpha   87.981
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   413.182
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.466  0.750  0.500  1.0
  Cs  Cs1  1  0.534  0.250  0.500  1.0
  Yb  Yb2  1  0.501  0.750  0.000  1.0
  Yb  Yb3  1  0.499  0.250  0.000  1.0
  Mo  Mo4  1  0.985  0.492  0.193  1.0
  Mo  Mo5  1  0.015  0.508  0.807  1.0
  Mo  Mo6  1  0.985  0.008  0.807  1.0
  Mo  Mo7  1  0.015  0.992  0.193  1.0
  O  O8  1  0.878  0.983  0.356  1.0
  O  O9  1  0.122  0.017  0.644  1.0
  O  O10  1  0.878  0.517  0.644  1.0
  O  O11  1  0.122  0.483  0.356  1.0
  O  O12  1  0.765  0.318  0.184  1.0
  O  O13  1  0.235  0.682  0.816  1.0
  O  O14  1  0.765  0.182  0.816  1.0
  O  O15  1  0.235  0.818  0.184  1.0
  O  O16  1  0.752  0.998  0.065  1.0
  O  O17  1  0.248  0.002  0.935  1.0
  O  O18  1  0.752  0.502  0.935  1.0
  O  O19  1  0.248  0.498  0.065  1.0
  O  O20  1  0.766  0.667  0.185  1.0
  O  O21  1  0.234  0.333  0.815  1.0
  O  O22  1  0.766  0.833  0.815  1.0
  O  O23  1  0.234  0.167  0.185  1.0
[/CIF]
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The crystal structure described by CsYb(MoO4)2 crystallizes in the monoclinic P2/c space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(1) atoms. Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Yb(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Yb(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Yb(1), and one Mo(1) atom. is represented by the CIF card [CIF]
data_CsYb(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.056
_cell_length_b   8.233
_cell_length_c   9.931
_cell_angle_alpha   87.981
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   413.182
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.466  0.750  0.500  1.0
  Cs  Cs1  1  0.534  0.250  0.500  1.0
  Yb  Yb2  1  0.501  0.750  0.000  1.0
  Yb  Yb3  1  0.499  0.250  0.000  1.0
  Mo  Mo4  1  0.985  0.492  0.193  1.0
  Mo  Mo5  1  0.015  0.508  0.807  1.0
  Mo  Mo6  1  0.985  0.008  0.807  1.0
  Mo  Mo7  1  0.015  0.992  0.193  1.0
  O  O8  1  0.878  0.983  0.356  1.0
  O  O9  1  0.122  0.017  0.644  1.0
  O  O10  1  0.878  0.517  0.644  1.0
  O  O11  1  0.122  0.483  0.356  1.0
  O  O12  1  0.765  0.318  0.184  1.0
  O  O13  1  0.235  0.682  0.816  1.0
  O  O14  1  0.765  0.182  0.816  1.0
  O  O15  1  0.235  0.818  0.184  1.0
  O  O16  1  0.752  0.998  0.065  1.0
  O  O17  1  0.248  0.002  0.935  1.0
  O  O18  1  0.752  0.502  0.935  1.0
  O  O19  1  0.248  0.498  0.065  1.0
  O  O20  1  0.766  0.667  0.185  1.0
  O  O21  1  0.234  0.333  0.815  1.0
  O  O22  1  0.766  0.833  0.815  1.0
  O  O23  1  0.234  0.167  0.185  1.0
[/CIF]
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