The compound described by Sr2La2MnZnO8 is (La,Ba)CuO4-derived structured and crystallizes in the orthorhombic Fmm2 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1,3) is bonded in a 9-coordinate geometry to one O(9), two equivalent O(13), two equivalent O(15), two equivalent O(5), and two equivalent O(7) atoms. In the second Sr site, Sr(2,4) is bonded in a 9-coordinate geometry to one O(10), two equivalent O(14), two equivalent O(16), two equivalent O(6), and two equivalent O(8) atoms. There are seven inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(17), two equivalent O(19), and four equivalent O(11) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(18), two equivalent O(20), and four equivalent O(12) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(17), two equivalent O(19), and four equivalent O(11) atoms. In the fourth La site, La(4,8) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(18), two equivalent O(20), and four equivalent O(12) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(18), two equivalent O(20), and four equivalent O(9) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(6), two equivalent O(17), two equivalent O(19), and four equivalent O(10) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(7), two equivalent O(18), two equivalent O(20), and four equivalent O(9) atoms. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(6), two equivalent O(14), and two equivalent O(16) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the second Mn site, Mn(2) is bonded to one O(3), one O(7), two equivalent O(13), and two equivalent O(15) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the third Mn site, Mn(3) is bonded to one O(1), one O(5), two equivalent O(13), and two equivalent O(15) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the fourth Mn site, Mn(4) is bonded to one O(4), one O(8), two equivalent O(14), and two equivalent O(16) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(10), one O(11), two equivalent O(17), and two equivalent O(19) atoms to form corner-sharing ZnO6 octahedra. The corner-sharing octahedra are not tilted. In the second Zn site, Zn(2) is bonded to one O(12), one O(9), two equivalent O(18), and two equivalent O(20) atoms to form corner-sharing ZnO6 octahedra. The corner-sharing octahedra are not tilted. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Sr(1,3); one La(1); and one Mn(3) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(5)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(1)Sr4LaMn octahedra, corners with four equivalent O(13)Sr4Mn2 octahedra, corners with four equivalent O(15)Sr4Mn2 octahedra, edges with four equivalent O(3)Sr4LaMn octahedra, edges with four equivalent O(11)SrLa4Zn octahedra, faces with two equivalent O(13)Sr4Mn2 octahedra, and faces with two equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the second O site, O(2) is bonded to four equivalent Sr(2,4); one La(2); and one Mn(1) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(6)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(14)Sr4Mn2 octahedra, corners with four equivalent O(16)Sr4Mn2 octahedra, edges with four equivalent O(4)Sr4LaMn octahedra, edges with four equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(14)Sr4Mn2 octahedra, and faces with two equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the third O site, O(3) is bonded to four equivalent Sr(1,3); one La(3); and one Mn(2) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(7)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(3)Sr4LaMn octahedra, corners with four equivalent O(13)Sr4Mn2 octahedra, corners with four equivalent O(15)Sr4Mn2 octahedra, edges with four equivalent O(1)Sr4LaMn octahedra, edges with four equivalent O(11)SrLa4Zn octahedra, faces with two equivalent O(13)Sr4Mn2 octahedra, and faces with two equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-52°. In the fourth O site, O(4) is bonded to four equivalent Sr(2,4); one La(4,8); and one Mn(4) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(8)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(14)Sr4Mn2 octahedra, corners with four equivalent O(16)Sr4Mn2 octahedra, edges with four equivalent O(2)Sr4LaMn octahedra, edges with four equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(14)Sr4Mn2 octahedra, and faces with two equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fifth O site, O(5) is bonded to four equivalent Sr(1,3); one La(5); and one Mn(3) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(1)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(5)Sr4LaMn octahedra, corners with four equivalent O(13)Sr4Mn2 octahedra, corners with four equivalent O(15)Sr4Mn2 octahedra, edges with four equivalent O(7)Sr4LaMn octahedra, edges with four equivalent O(9)SrLa4Zn octahedra, faces with two equivalent O(13)Sr4Mn2 octahedra, and faces with two equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the sixth O site, O(6) is bonded to four equivalent Sr(2,4); one La(6); and one Mn(1) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(2)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(6)Sr4LaMn octahedra, corners with four equivalent O(14)Sr4Mn2 octahedra, corners with four equivalent O(16)Sr4Mn2 octahedra, edges with four equivalent O(8)Sr4LaMn octahedra, edges with four equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(14)Sr4Mn2 octahedra, and faces with two equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the seventh O site, O(7) is bonded to four equivalent Sr(1,3); one La(7); and one Mn(2) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(3)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(7)Sr4LaMn octahedra, corners with four equivalent O(13)Sr4Mn2 octahedra, corners with four equivalent O(15)Sr4Mn2 octahedra, edges with four equivalent O(5)Sr4LaMn octahedra, edges with four equivalent O(9)SrLa4Zn octahedra, faces with two equivalent O(13)Sr4Mn2 octahedra, and faces with two equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-52°. In the eighth O site, O(8) is bonded to four equivalent Sr(2,4); one La(4,8); and one Mn(4) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(4)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(8)Sr4LaMn octahedra, corners with four equivalent O(14)Sr4Mn2 octahedra, corners with four equivalent O(16)Sr4Mn2 octahedra, edges with four equivalent O(6)Sr4LaMn octahedra, edges with four equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(14)Sr4Mn2 octahedra, and faces with two equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the ninth O site, O(9) is bonded to one Sr(1,3); two equivalent La(5); two equivalent La(7); and one Zn(2) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(12)SrLa4Zn octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with four equivalent O(18)La4Zn2 octahedra, corners with four equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(5)Sr4LaMn octahedra, edges with two equivalent O(7)Sr4LaMn octahedra, edges with four equivalent O(9)SrLa4Zn octahedra, faces with two equivalent O(18)La4Zn2 octahedra, and faces with two equivalent O(20)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the tenth O site, O(10) is bonded to one Sr(2,4); two equivalent La(4,8); two equivalent La(6); and one Zn(1) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(11)SrLa4Zn octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with four equivalent O(17)La4Zn2 octahedra, corners with four equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(10)SrLa4Zn octahedra, edges with two equivalent O(6)Sr4LaMn octahedra, edges with two equivalent O(8)Sr4LaMn octahedra, edges with four equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(17)La4Zn2 octahedra, and faces with two equivalent O(19)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the eleventh O site, O(11) is bonded to one Sr(1,3); two equivalent La(1); two equivalent La(3); and one Zn(1) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(10)SrLa4Zn octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with four equivalent O(17)La4Zn2 octahedra, corners with four equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(11)SrLa4Zn octahedra, edges with two equivalent O(1)Sr4LaMn octahedra, edges with two equivalent O(3)Sr4LaMn octahedra, edges with four equivalent O(11)SrLa4Zn octahedra, faces with two equivalent O(17)La4Zn2 octahedra, and faces with two equivalent O(19)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the twelfth O site, O(12) is bonded to one Sr(2,4); two equivalent La(2); two equivalent La(4,8); and one Zn(2) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(9)SrLa4Zn octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with four equivalent O(18)La4Zn2 octahedra, corners with four equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(12)SrLa4Zn octahedra, edges with two equivalent O(2)Sr4LaMn octahedra, edges with two equivalent O(4)Sr4LaMn octahedra, edges with four equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(18)La4Zn2 octahedra, and faces with two equivalent O(20)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the thirteenth O site, O(13) is bonded to four equivalent Sr(1,3); one Mn(2); and one Mn(3) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(5)Sr4LaMn octahedra, corners with two equivalent O(7)Sr4LaMn octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(11)SrLa4Zn octahedra, corners with two equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(13)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4LaMn octahedra,  a faceface with one O(3)Sr4LaMn octahedra,  a faceface with one O(5)Sr4LaMn octahedra,  a faceface with one O(7)Sr4LaMn octahedra, and faces with four equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fourteenth O site, O(14) is bonded to four equivalent Sr(2,4); one Mn(1); and one Mn(4) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with two equivalent O(6)Sr4LaMn octahedra, corners with two equivalent O(8)Sr4LaMn octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(10)SrLa4Zn octahedra, corners with two equivalent O(12)SrLa4Zn octahedra, edges with two equivalent O(14)Sr4Mn2 octahedra,  a faceface with one O(2)Sr4LaMn octahedra,  a faceface with one O(4)Sr4LaMn octahedra,  a faceface with one O(6)Sr4LaMn octahedra,  a faceface with one O(8)Sr4LaMn octahedra, and faces with four equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fifteenth O site, O(15) is bonded to four equivalent Sr(1,3); one Mn(2); and one Mn(3) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(5)Sr4LaMn octahedra, corners with two equivalent O(7)Sr4LaMn octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with two equivalent O(11)SrLa4Zn octahedra, corners with two equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(15)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4LaMn octahedra,  a faceface with one O(3)Sr4LaMn octahedra,  a faceface with one O(5)Sr4LaMn octahedra,  a faceface with one O(7)Sr4LaMn octahedra, and faces with four equivalent O(13)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the sixteenth O site, O(16) is bonded to four equivalent Sr(2,4); one Mn(1); and one Mn(4) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with two equivalent O(6)Sr4LaMn octahedra, corners with two equivalent O(8)Sr4LaMn octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(10)SrLa4Zn octahedra, corners with two equivalent O(12)SrLa4Zn octahedra, edges with two equivalent O(16)Sr4Mn2 octahedra,  a faceface with one O(2)Sr4LaMn octahedra,  a faceface with one O(4)Sr4LaMn octahedra,  a faceface with one O(6)Sr4LaMn octahedra,  a faceface with one O(8)Sr4LaMn octahedra, and faces with four equivalent O(14)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the seventeenth O site, O(17) is bonded to one La(1); one La(3); one La(4,8); one La(6); and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(1)Sr4LaMn octahedra,  a cornercorner with one O(3)Sr4LaMn octahedra,  a cornercorner with one O(6)Sr4LaMn octahedra,  a cornercorner with one O(8)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with four equivalent O(10)SrLa4Zn octahedra, corners with four equivalent O(11)SrLa4Zn octahedra, edges with two equivalent O(17)La4Zn2 octahedra, faces with two equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(11)SrLa4Zn octahedra, and faces with four equivalent O(19)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the eighteenth O site, O(18) is bonded to one La(2); one La(4,8); one La(5); one La(7); and two equivalent Zn(2) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(2)Sr4LaMn octahedra,  a cornercorner with one O(4)Sr4LaMn octahedra,  a cornercorner with one O(5)Sr4LaMn octahedra,  a cornercorner with one O(7)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with four equivalent O(12)SrLa4Zn octahedra, corners with four equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(18)La4Zn2 octahedra, faces with two equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(9)SrLa4Zn octahedra, and faces with four equivalent O(20)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the nineteenth O site, O(19) is bonded to one La(1); one La(3); one La(4,8); one La(6); and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(1)Sr4LaMn octahedra,  a cornercorner with one O(3)Sr4LaMn octahedra,  a cornercorner with one O(6)Sr4LaMn octahedra,  a cornercorner with one O(8)Sr4LaMn octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(10)SrLa4Zn octahedra, corners with four equivalent O(11)SrLa4Zn octahedra, edges with two equivalent O(19)La4Zn2 octahedra, faces with two equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(11)SrLa4Zn octahedra, and faces with four equivalent O(17)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the twentieth O site, O(20) is bonded to one La(2); one La(4,8); one La(5); one La(7); and two equivalent Zn(2) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(2)Sr4LaMn octahedra,  a cornercorner with one O(4)Sr4LaMn octahedra,  a cornercorner with one O(5)Sr4LaMn octahedra,  a cornercorner with one O(7)Sr4LaMn octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(12)SrLa4Zn octahedra, corners with four equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(20)La4Zn2 octahedra, faces with two equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(9)SrLa4Zn octahedra, and faces with four equivalent O(18)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. is represented by the CIF file [CIF]
data_Sr2La2MnZnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.875
_cell_length_b   3.905
_cell_length_c   12.642
_cell_angle_alpha   90.000
_cell_angle_beta   90.001
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   191.265
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.500  0.855  1.0
  La  La1  1  0.500  0.500  0.145  1.0
  Mn  Mn2  1  0.500  0.500  0.500  1.0
  O  O3  1  0.500  0.500  0.664  1.0
  O  O4  1  0.500  0.500  0.336  1.0
  O  O5  1  0.000  1.000  0.174  1.0
  O  O6  1  1.000  1.000  0.826  1.0
  O  O7  1  0.500  0.000  0.500  1.0
  O  O8  1  1.000  0.500  0.500  1.0
  O  O9  1  1.000  0.500  1.000  1.0
  O  O10  1  0.500  1.000  1.000  1.0
  Sr  Sr11  1  0.000  0.000  0.363  1.0
  Sr  Sr12  1  1.000  0.000  0.637  1.0
  Zn  Zn13  1  1.000  1.000  1.000  1.0
[/CIF]
.
The compound described by Sr2La2MnZnO8 is (La,Ba)CuO4-derived structured and crystallizes in the orthorhombic Fmm2 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1,3) is bonded in a 9-coordinate geometry to one O(9), two equivalent O(13), two equivalent O(15), two equivalent O(5), and two equivalent O(7) atoms. In the second Sr site, Sr(2,4) is bonded in a 9-coordinate geometry to one O(10), two equivalent O(14), two equivalent O(16), two equivalent O(6), and two equivalent O(8) atoms. There are seven inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(17), two equivalent O(19), and four equivalent O(11) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(18), two equivalent O(20), and four equivalent O(12) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(17), two equivalent O(19), and four equivalent O(11) atoms. In the fourth La site, La(4,8) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(18), two equivalent O(20), and four equivalent O(12) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(18), two equivalent O(20), and four equivalent O(9) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(6), two equivalent O(17), two equivalent O(19), and four equivalent O(10) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(7), two equivalent O(18), two equivalent O(20), and four equivalent O(9) atoms. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(6), two equivalent O(14), and two equivalent O(16) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the second Mn site, Mn(2) is bonded to one O(3), one O(7), two equivalent O(13), and two equivalent O(15) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the third Mn site, Mn(3) is bonded to one O(1), one O(5), two equivalent O(13), and two equivalent O(15) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the fourth Mn site, Mn(4) is bonded to one O(4), one O(8), two equivalent O(14), and two equivalent O(16) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(10), one O(11), two equivalent O(17), and two equivalent O(19) atoms to form corner-sharing ZnO6 octahedra. The corner-sharing octahedra are not tilted. In the second Zn site, Zn(2) is bonded to one O(12), one O(9), two equivalent O(18), and two equivalent O(20) atoms to form corner-sharing ZnO6 octahedra. The corner-sharing octahedra are not tilted. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Sr(1,3); one La(1); and one Mn(3) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(5)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(1)Sr4LaMn octahedra, corners with four equivalent O(13)Sr4Mn2 octahedra, corners with four equivalent O(15)Sr4Mn2 octahedra, edges with four equivalent O(3)Sr4LaMn octahedra, edges with four equivalent O(11)SrLa4Zn octahedra, faces with two equivalent O(13)Sr4Mn2 octahedra, and faces with two equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the second O site, O(2) is bonded to four equivalent Sr(2,4); one La(2); and one Mn(1) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(6)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(14)Sr4Mn2 octahedra, corners with four equivalent O(16)Sr4Mn2 octahedra, edges with four equivalent O(4)Sr4LaMn octahedra, edges with four equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(14)Sr4Mn2 octahedra, and faces with two equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the third O site, O(3) is bonded to four equivalent Sr(1,3); one La(3); and one Mn(2) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(7)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(3)Sr4LaMn octahedra, corners with four equivalent O(13)Sr4Mn2 octahedra, corners with four equivalent O(15)Sr4Mn2 octahedra, edges with four equivalent O(1)Sr4LaMn octahedra, edges with four equivalent O(11)SrLa4Zn octahedra, faces with two equivalent O(13)Sr4Mn2 octahedra, and faces with two equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-52°. In the fourth O site, O(4) is bonded to four equivalent Sr(2,4); one La(4,8); and one Mn(4) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(8)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(14)Sr4Mn2 octahedra, corners with four equivalent O(16)Sr4Mn2 octahedra, edges with four equivalent O(2)Sr4LaMn octahedra, edges with four equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(14)Sr4Mn2 octahedra, and faces with two equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fifth O site, O(5) is bonded to four equivalent Sr(1,3); one La(5); and one Mn(3) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(1)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(5)Sr4LaMn octahedra, corners with four equivalent O(13)Sr4Mn2 octahedra, corners with four equivalent O(15)Sr4Mn2 octahedra, edges with four equivalent O(7)Sr4LaMn octahedra, edges with four equivalent O(9)SrLa4Zn octahedra, faces with two equivalent O(13)Sr4Mn2 octahedra, and faces with two equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the sixth O site, O(6) is bonded to four equivalent Sr(2,4); one La(6); and one Mn(1) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(2)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(6)Sr4LaMn octahedra, corners with four equivalent O(14)Sr4Mn2 octahedra, corners with four equivalent O(16)Sr4Mn2 octahedra, edges with four equivalent O(8)Sr4LaMn octahedra, edges with four equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(14)Sr4Mn2 octahedra, and faces with two equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the seventh O site, O(7) is bonded to four equivalent Sr(1,3); one La(7); and one Mn(2) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(3)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(7)Sr4LaMn octahedra, corners with four equivalent O(13)Sr4Mn2 octahedra, corners with four equivalent O(15)Sr4Mn2 octahedra, edges with four equivalent O(5)Sr4LaMn octahedra, edges with four equivalent O(9)SrLa4Zn octahedra, faces with two equivalent O(13)Sr4Mn2 octahedra, and faces with two equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-52°. In the eighth O site, O(8) is bonded to four equivalent Sr(2,4); one La(4,8); and one Mn(4) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(4)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(8)Sr4LaMn octahedra, corners with four equivalent O(14)Sr4Mn2 octahedra, corners with four equivalent O(16)Sr4Mn2 octahedra, edges with four equivalent O(6)Sr4LaMn octahedra, edges with four equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(14)Sr4Mn2 octahedra, and faces with two equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the ninth O site, O(9) is bonded to one Sr(1,3); two equivalent La(5); two equivalent La(7); and one Zn(2) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(12)SrLa4Zn octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with four equivalent O(18)La4Zn2 octahedra, corners with four equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(5)Sr4LaMn octahedra, edges with two equivalent O(7)Sr4LaMn octahedra, edges with four equivalent O(9)SrLa4Zn octahedra, faces with two equivalent O(18)La4Zn2 octahedra, and faces with two equivalent O(20)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the tenth O site, O(10) is bonded to one Sr(2,4); two equivalent La(4,8); two equivalent La(6); and one Zn(1) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(11)SrLa4Zn octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with four equivalent O(17)La4Zn2 octahedra, corners with four equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(10)SrLa4Zn octahedra, edges with two equivalent O(6)Sr4LaMn octahedra, edges with two equivalent O(8)Sr4LaMn octahedra, edges with four equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(17)La4Zn2 octahedra, and faces with two equivalent O(19)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the eleventh O site, O(11) is bonded to one Sr(1,3); two equivalent La(1); two equivalent La(3); and one Zn(1) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(10)SrLa4Zn octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with four equivalent O(17)La4Zn2 octahedra, corners with four equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(11)SrLa4Zn octahedra, edges with two equivalent O(1)Sr4LaMn octahedra, edges with two equivalent O(3)Sr4LaMn octahedra, edges with four equivalent O(11)SrLa4Zn octahedra, faces with two equivalent O(17)La4Zn2 octahedra, and faces with two equivalent O(19)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the twelfth O site, O(12) is bonded to one Sr(2,4); two equivalent La(2); two equivalent La(4,8); and one Zn(2) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(9)SrLa4Zn octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with four equivalent O(18)La4Zn2 octahedra, corners with four equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(12)SrLa4Zn octahedra, edges with two equivalent O(2)Sr4LaMn octahedra, edges with two equivalent O(4)Sr4LaMn octahedra, edges with four equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(18)La4Zn2 octahedra, and faces with two equivalent O(20)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the thirteenth O site, O(13) is bonded to four equivalent Sr(1,3); one Mn(2); and one Mn(3) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(5)Sr4LaMn octahedra, corners with two equivalent O(7)Sr4LaMn octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(11)SrLa4Zn octahedra, corners with two equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(13)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4LaMn octahedra,  a faceface with one O(3)Sr4LaMn octahedra,  a faceface with one O(5)Sr4LaMn octahedra,  a faceface with one O(7)Sr4LaMn octahedra, and faces with four equivalent O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fourteenth O site, O(14) is bonded to four equivalent Sr(2,4); one Mn(1); and one Mn(4) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with two equivalent O(6)Sr4LaMn octahedra, corners with two equivalent O(8)Sr4LaMn octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(10)SrLa4Zn octahedra, corners with two equivalent O(12)SrLa4Zn octahedra, edges with two equivalent O(14)Sr4Mn2 octahedra,  a faceface with one O(2)Sr4LaMn octahedra,  a faceface with one O(4)Sr4LaMn octahedra,  a faceface with one O(6)Sr4LaMn octahedra,  a faceface with one O(8)Sr4LaMn octahedra, and faces with four equivalent O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fifteenth O site, O(15) is bonded to four equivalent Sr(1,3); one Mn(2); and one Mn(3) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(5)Sr4LaMn octahedra, corners with two equivalent O(7)Sr4LaMn octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with two equivalent O(11)SrLa4Zn octahedra, corners with two equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(15)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4LaMn octahedra,  a faceface with one O(3)Sr4LaMn octahedra,  a faceface with one O(5)Sr4LaMn octahedra,  a faceface with one O(7)Sr4LaMn octahedra, and faces with four equivalent O(13)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the sixteenth O site, O(16) is bonded to four equivalent Sr(2,4); one Mn(1); and one Mn(4) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with two equivalent O(6)Sr4LaMn octahedra, corners with two equivalent O(8)Sr4LaMn octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(10)SrLa4Zn octahedra, corners with two equivalent O(12)SrLa4Zn octahedra, edges with two equivalent O(16)Sr4Mn2 octahedra,  a faceface with one O(2)Sr4LaMn octahedra,  a faceface with one O(4)Sr4LaMn octahedra,  a faceface with one O(6)Sr4LaMn octahedra,  a faceface with one O(8)Sr4LaMn octahedra, and faces with four equivalent O(14)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the seventeenth O site, O(17) is bonded to one La(1); one La(3); one La(4,8); one La(6); and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(1)Sr4LaMn octahedra,  a cornercorner with one O(3)Sr4LaMn octahedra,  a cornercorner with one O(6)Sr4LaMn octahedra,  a cornercorner with one O(8)Sr4LaMn octahedra, corners with two equivalent O(17)La4Zn2 octahedra, corners with four equivalent O(10)SrLa4Zn octahedra, corners with four equivalent O(11)SrLa4Zn octahedra, edges with two equivalent O(17)La4Zn2 octahedra, faces with two equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(11)SrLa4Zn octahedra, and faces with four equivalent O(19)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the eighteenth O site, O(18) is bonded to one La(2); one La(4,8); one La(5); one La(7); and two equivalent Zn(2) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(2)Sr4LaMn octahedra,  a cornercorner with one O(4)Sr4LaMn octahedra,  a cornercorner with one O(5)Sr4LaMn octahedra,  a cornercorner with one O(7)Sr4LaMn octahedra, corners with two equivalent O(18)La4Zn2 octahedra, corners with four equivalent O(12)SrLa4Zn octahedra, corners with four equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(18)La4Zn2 octahedra, faces with two equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(9)SrLa4Zn octahedra, and faces with four equivalent O(20)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the nineteenth O site, O(19) is bonded to one La(1); one La(3); one La(4,8); one La(6); and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(1)Sr4LaMn octahedra,  a cornercorner with one O(3)Sr4LaMn octahedra,  a cornercorner with one O(6)Sr4LaMn octahedra,  a cornercorner with one O(8)Sr4LaMn octahedra, corners with two equivalent O(19)La4Zn2 octahedra, corners with four equivalent O(10)SrLa4Zn octahedra, corners with four equivalent O(11)SrLa4Zn octahedra, edges with two equivalent O(19)La4Zn2 octahedra, faces with two equivalent O(10)SrLa4Zn octahedra, faces with two equivalent O(11)SrLa4Zn octahedra, and faces with four equivalent O(17)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the twentieth O site, O(20) is bonded to one La(2); one La(4,8); one La(5); one La(7); and two equivalent Zn(2) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(2)Sr4LaMn octahedra,  a cornercorner with one O(4)Sr4LaMn octahedra,  a cornercorner with one O(5)Sr4LaMn octahedra,  a cornercorner with one O(7)Sr4LaMn octahedra, corners with two equivalent O(20)La4Zn2 octahedra, corners with four equivalent O(12)SrLa4Zn octahedra, corners with four equivalent O(9)SrLa4Zn octahedra, edges with two equivalent O(20)La4Zn2 octahedra, faces with two equivalent O(12)SrLa4Zn octahedra, faces with two equivalent O(9)SrLa4Zn octahedra, and faces with four equivalent O(18)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. is represented by the CIF file [CIF]
data_Sr2La2MnZnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.875
_cell_length_b   3.905
_cell_length_c   12.642
_cell_angle_alpha   90.000
_cell_angle_beta   90.001
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   191.265
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.500  0.855  1.0
  La  La1  1  0.500  0.500  0.145  1.0
  Mn  Mn2  1  0.500  0.500  0.500  1.0
  O  O3  1  0.500  0.500  0.664  1.0
  O  O4  1  0.500  0.500  0.336  1.0
  O  O5  1  0.000  1.000  0.174  1.0
  O  O6  1  1.000  1.000  0.826  1.0
  O  O7  1  0.500  0.000  0.500  1.0
  O  O8  1  1.000  0.500  0.500  1.0
  O  O9  1  1.000  0.500  1.000  1.0
  O  O10  1  0.500  1.000  1.000  1.0
  Sr  Sr11  1  0.000  0.000  0.363  1.0
  Sr  Sr12  1  1.000  0.000  0.637  1.0
  Zn  Zn13  1  1.000  1.000  1.000  1.0
[/CIF]
.