The crystal structure described by CdH8(NO5)2 is gamma plutonium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two CdH8(NO5)2 clusters. Cd(1) is bonded in a 8-coordinate geometry to one O(1), one O(15), one O(16), one O(17), one O(18), one O(2), one O(5), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(16) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(15) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(16) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one O(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one O(18) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one O(17) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one O(18) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(15) is bonded in a distorted water-like geometry to one Cd(1), one H(3), and one H(7) atom. In the eighth O site, O(16) is bonded in a distorted water-like geometry to one Cd(1), one H(4), and one H(8) atom. In the ninth O site, O(17) is bonded in a water-like geometry to one Cd(1), one H(13), and one H(9) atom. In the tenth O site, O(18) is bonded in a water-like geometry to one Cd(1), one H(10), and one H(14) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdH8(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.201
_cell_length_b   14.007
_cell_length_c   6.261
_cell_angle_alpha   69.629
_cell_angle_beta   84.054
_cell_angle_gamma   26.377
_symmetry_Int_Tables_number   1
_cell_volume   417.558
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.257  0.242  0.247  1.0
  Cd  Cd1  1  0.006  0.995  0.998  1.0
  H  H2  1  0.491  0.624  0.991  1.0
  H  H3  1  0.887  0.999  0.622  1.0
  H  H4  1  0.249  0.367  0.754  1.0
  H  H5  1  0.631  0.754  0.359  1.0
  H  H6  1  0.495  0.500  0.060  1.0
  H  H7  1  0.946  0.059  0.501  1.0
  H  H8  1  0.195  0.301  0.754  1.0
  H  H9  1  0.753  0.752  0.301  1.0
  H  H10  1  0.150  0.179  0.637  1.0
  H  H11  1  0.032  0.638  0.178  1.0
  H  H12  1  0.614  0.215  0.105  1.0
  H  H13  1  0.073  0.099  0.222  1.0
  H  H14  1  0.435  0.962  0.772  1.0
  H  H15  1  0.830  0.770  0.965  1.0
  H  H16  1  0.480  0.417  0.819  1.0
  H  H17  1  0.287  0.815  0.423  1.0
  N  N18  1  0.829  0.491  0.016  1.0
  N  N19  1  0.667  0.013  0.495  1.0
  N  N20  1  0.235  0.584  0.423  1.0
  N  N21  1  0.759  0.421  0.587  1.0
  O  O22  1  0.782  0.621  0.005  1.0
  O  O23  1  0.594  0.002  0.624  1.0
  O  O24  1  0.246  0.659  0.466  1.0
  O  O25  1  0.628  0.469  0.660  1.0
  O  O26  1  0.068  0.240  0.150  1.0
  O  O27  1  0.548  0.142  0.245  1.0
  O  O28  1  0.107  0.701  0.186  1.0
  O  O29  1  0.009  0.182  0.709  1.0
  O  O30  1  0.644  0.607  0.897  1.0
  O  O31  1  0.851  0.898  0.611  1.0
  O  O32  1  0.351  0.400  0.611  1.0
  O  O33  1  0.644  0.605  0.401  1.0
  O  O34  1  0.434  0.612  0.079  1.0
  O  O35  1  0.877  0.078  0.615  1.0
  O  O36  1  0.173  0.373  0.817  1.0
  O  O37  1  0.639  0.815  0.371  1.0
  O  O38  1  0.248  0.155  0.639  1.0
  O  O39  1  0.959  0.637  0.157  1.0
  O  O40  1  0.612  0.291  0.007  1.0
  O  O41  1  0.095  0.003  0.296  1.0
[/CIF]
.
The crystal structure described by CdH8(NO5)2 is gamma plutonium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two CdH8(NO5)2 clusters. Cd(1) is bonded in a 8-coordinate geometry to one O(1), one O(15), one O(16), one O(17), one O(18), one O(2), one O(5), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(16) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(15) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(16) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one O(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one O(18) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one O(17) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one O(18) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(15) is bonded in a distorted water-like geometry to one Cd(1), one H(3), and one H(7) atom. In the eighth O site, O(16) is bonded in a distorted water-like geometry to one Cd(1), one H(4), and one H(8) atom. In the ninth O site, O(17) is bonded in a water-like geometry to one Cd(1), one H(13), and one H(9) atom. In the tenth O site, O(18) is bonded in a water-like geometry to one Cd(1), one H(10), and one H(14) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdH8(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.201
_cell_length_b   14.007
_cell_length_c   6.261
_cell_angle_alpha   69.629
_cell_angle_beta   84.054
_cell_angle_gamma   26.377
_symmetry_Int_Tables_number   1
_cell_volume   417.558
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.257  0.242  0.247  1.0
  Cd  Cd1  1  0.006  0.995  0.998  1.0
  H  H2  1  0.491  0.624  0.991  1.0
  H  H3  1  0.887  0.999  0.622  1.0
  H  H4  1  0.249  0.367  0.754  1.0
  H  H5  1  0.631  0.754  0.359  1.0
  H  H6  1  0.495  0.500  0.060  1.0
  H  H7  1  0.946  0.059  0.501  1.0
  H  H8  1  0.195  0.301  0.754  1.0
  H  H9  1  0.753  0.752  0.301  1.0
  H  H10  1  0.150  0.179  0.637  1.0
  H  H11  1  0.032  0.638  0.178  1.0
  H  H12  1  0.614  0.215  0.105  1.0
  H  H13  1  0.073  0.099  0.222  1.0
  H  H14  1  0.435  0.962  0.772  1.0
  H  H15  1  0.830  0.770  0.965  1.0
  H  H16  1  0.480  0.417  0.819  1.0
  H  H17  1  0.287  0.815  0.423  1.0
  N  N18  1  0.829  0.491  0.016  1.0
  N  N19  1  0.667  0.013  0.495  1.0
  N  N20  1  0.235  0.584  0.423  1.0
  N  N21  1  0.759  0.421  0.587  1.0
  O  O22  1  0.782  0.621  0.005  1.0
  O  O23  1  0.594  0.002  0.624  1.0
  O  O24  1  0.246  0.659  0.466  1.0
  O  O25  1  0.628  0.469  0.660  1.0
  O  O26  1  0.068  0.240  0.150  1.0
  O  O27  1  0.548  0.142  0.245  1.0
  O  O28  1  0.107  0.701  0.186  1.0
  O  O29  1  0.009  0.182  0.709  1.0
  O  O30  1  0.644  0.607  0.897  1.0
  O  O31  1  0.851  0.898  0.611  1.0
  O  O32  1  0.351  0.400  0.611  1.0
  O  O33  1  0.644  0.605  0.401  1.0
  O  O34  1  0.434  0.612  0.079  1.0
  O  O35  1  0.877  0.078  0.615  1.0
  O  O36  1  0.173  0.373  0.817  1.0
  O  O37  1  0.639  0.815  0.371  1.0
  O  O38  1  0.248  0.155  0.639  1.0
  O  O39  1  0.959  0.637  0.157  1.0
  O  O40  1  0.612  0.291  0.007  1.0
  O  O41  1  0.095  0.003  0.296  1.0
[/CIF]
.