The crystal structure described by Ag5BiO4 crystallizes in the monoclinic P2_1/c space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one O(2) and one O(3) atom. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. In the fourth Ag site, Ag(4) is bonded in a linear geometry to one O(1) and one O(4) atom. In the fifth Ag site, Ag(5) is bonded in a linear geometry to two equivalent O(4) atoms. In the sixth Ag site, Ag(6) is bonded in a linear geometry to one O(2) and one O(3) atom. Bi(1) is bonded to one O(1), one O(2), one O(4), and two equivalent O(3) atoms to form edge-sharing BiO5 square pyramids. There are four inequivalent O sites. In the first O site, O(4) is bonded to one Ag(3), one Ag(4), one Ag(5), and one Bi(1) atom to form OAg3Bi tetrahedra that share  a cornercorner with one O(4)Ag3Bi tetrahedra, corners with two equivalent O(3)Ag2Bi2 tetrahedra, corners with two equivalent O(2)Ag3Bi tetrahedra, and corners with three equivalent O(1)Ag3Bi tetrahedra. In the second O site, O(1) is bonded to one Ag(2), one Ag(3), one Ag(4), and one Bi(1) atom to form OAg3Bi tetrahedra that share  a cornercorner with one O(1)Ag3Bi tetrahedra, corners with two equivalent O(3)Ag2Bi2 tetrahedra, corners with two equivalent O(2)Ag3Bi tetrahedra, and corners with three equivalent O(4)Ag3Bi tetrahedra. In the third O site, O(2) is bonded to one Ag(1), one Ag(3), one Ag(6), and one Bi(1) atom to form OAg3Bi tetrahedra that share corners with two equivalent O(1)Ag3Bi tetrahedra, corners with two equivalent O(4)Ag3Bi tetrahedra, and corners with four equivalent O(3)Ag2Bi2 tetrahedra. In the fourth O site, O(3) is bonded to one Ag(1), one Ag(6), and two equivalent Bi(1) atoms to form OAg2Bi2 tetrahedra that share corners with two equivalent O(1)Ag3Bi tetrahedra, corners with two equivalent O(4)Ag3Bi tetrahedra, corners with four equivalent O(2)Ag3Bi tetrahedra, and  an edgeedge with one O(3)Ag2Bi2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag5BiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.899
_cell_length_b   5.905
_cell_length_c   13.730
_cell_angle_alpha   65.769
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   657.932
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.728  0.874  0.877  1.0
  Ag  Ag1  1  0.772  0.874  0.377  1.0
  Ag  Ag2  1  0.500  0.000  0.000  1.0
  Ag  Ag3  1  0.000  0.000  0.500  1.0
  Ag  Ag4  1  0.141  0.612  0.352  1.0
  Ag  Ag5  1  0.641  0.388  0.148  1.0
  Ag  Ag6  1  0.859  0.388  0.648  1.0
  Ag  Ag7  1  0.359  0.612  0.852  1.0
  Ag  Ag8  1  0.992  0.711  0.754  1.0
  Ag  Ag9  1  0.492  0.289  0.746  1.0
  Ag  Ag10  1  0.008  0.289  0.246  1.0
  Ag  Ag11  1  0.508  0.711  0.254  1.0
  Ag  Ag12  1  0.000  0.500  0.000  1.0
  Ag  Ag13  1  0.500  0.500  0.500  1.0
  Ag  Ag14  1  0.269  0.615  0.126  1.0
  Ag  Ag15  1  0.769  0.385  0.374  1.0
  Ag  Ag16  1  0.731  0.385  0.874  1.0
  Ag  Ag17  1  0.231  0.615  0.626  1.0
  Ag  Ag18  1  0.272  0.126  0.123  1.0
  Ag  Ag19  1  0.228  0.126  0.623  1.0
  Bi  Bi20  1  0.381  0.082  0.377  1.0
  Bi  Bi21  1  0.881  0.918  0.123  1.0
  Bi  Bi22  1  0.619  0.918  0.623  1.0
  Bi  Bi23  1  0.119  0.082  0.877  1.0
  O  O24  1  0.363  0.030  0.871  1.0
  O  O25  1  0.863  0.970  0.629  1.0
  O  O26  1  0.637  0.970  0.129  1.0
  O  O27  1  0.137  0.030  0.371  1.0
  O  O28  1  0.908  0.696  0.305  1.0
  O  O29  1  0.408  0.304  0.195  1.0
  O  O30  1  0.136  0.931  0.060  1.0
  O  O31  1  0.636  0.069  0.440  1.0
  O  O32  1  0.864  0.069  0.940  1.0
  O  O33  1  0.364  0.931  0.560  1.0
  O  O34  1  0.134  0.448  0.880  1.0
  O  O35  1  0.634  0.552  0.620  1.0
  O  O36  1  0.866  0.552  0.120  1.0
  O  O37  1  0.366  0.448  0.380  1.0
  O  O38  1  0.092  0.304  0.695  1.0
  O  O39  1  0.592  0.696  0.805  1.0
[/CIF]
.
The crystal structure described by Ag5BiO4 crystallizes in the monoclinic P2_1/c space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one O(2) and one O(3) atom. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. In the fourth Ag site, Ag(4) is bonded in a linear geometry to one O(1) and one O(4) atom. In the fifth Ag site, Ag(5) is bonded in a linear geometry to two equivalent O(4) atoms. In the sixth Ag site, Ag(6) is bonded in a linear geometry to one O(2) and one O(3) atom. Bi(1) is bonded to one O(1), one O(2), one O(4), and two equivalent O(3) atoms to form edge-sharing BiO5 square pyramids. There are four inequivalent O sites. In the first O site, O(4) is bonded to one Ag(3), one Ag(4), one Ag(5), and one Bi(1) atom to form OAg3Bi tetrahedra that share  a cornercorner with one O(4)Ag3Bi tetrahedra, corners with two equivalent O(3)Ag2Bi2 tetrahedra, corners with two equivalent O(2)Ag3Bi tetrahedra, and corners with three equivalent O(1)Ag3Bi tetrahedra. In the second O site, O(1) is bonded to one Ag(2), one Ag(3), one Ag(4), and one Bi(1) atom to form OAg3Bi tetrahedra that share  a cornercorner with one O(1)Ag3Bi tetrahedra, corners with two equivalent O(3)Ag2Bi2 tetrahedra, corners with two equivalent O(2)Ag3Bi tetrahedra, and corners with three equivalent O(4)Ag3Bi tetrahedra. In the third O site, O(2) is bonded to one Ag(1), one Ag(3), one Ag(6), and one Bi(1) atom to form OAg3Bi tetrahedra that share corners with two equivalent O(1)Ag3Bi tetrahedra, corners with two equivalent O(4)Ag3Bi tetrahedra, and corners with four equivalent O(3)Ag2Bi2 tetrahedra. In the fourth O site, O(3) is bonded to one Ag(1), one Ag(6), and two equivalent Bi(1) atoms to form OAg2Bi2 tetrahedra that share corners with two equivalent O(1)Ag3Bi tetrahedra, corners with two equivalent O(4)Ag3Bi tetrahedra, corners with four equivalent O(2)Ag3Bi tetrahedra, and  an edgeedge with one O(3)Ag2Bi2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag5BiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.899
_cell_length_b   5.905
_cell_length_c   13.730
_cell_angle_alpha   65.769
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   657.932
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.728  0.874  0.877  1.0
  Ag  Ag1  1  0.772  0.874  0.377  1.0
  Ag  Ag2  1  0.500  0.000  0.000  1.0
  Ag  Ag3  1  0.000  0.000  0.500  1.0
  Ag  Ag4  1  0.141  0.612  0.352  1.0
  Ag  Ag5  1  0.641  0.388  0.148  1.0
  Ag  Ag6  1  0.859  0.388  0.648  1.0
  Ag  Ag7  1  0.359  0.612  0.852  1.0
  Ag  Ag8  1  0.992  0.711  0.754  1.0
  Ag  Ag9  1  0.492  0.289  0.746  1.0
  Ag  Ag10  1  0.008  0.289  0.246  1.0
  Ag  Ag11  1  0.508  0.711  0.254  1.0
  Ag  Ag12  1  0.000  0.500  0.000  1.0
  Ag  Ag13  1  0.500  0.500  0.500  1.0
  Ag  Ag14  1  0.269  0.615  0.126  1.0
  Ag  Ag15  1  0.769  0.385  0.374  1.0
  Ag  Ag16  1  0.731  0.385  0.874  1.0
  Ag  Ag17  1  0.231  0.615  0.626  1.0
  Ag  Ag18  1  0.272  0.126  0.123  1.0
  Ag  Ag19  1  0.228  0.126  0.623  1.0
  Bi  Bi20  1  0.381  0.082  0.377  1.0
  Bi  Bi21  1  0.881  0.918  0.123  1.0
  Bi  Bi22  1  0.619  0.918  0.623  1.0
  Bi  Bi23  1  0.119  0.082  0.877  1.0
  O  O24  1  0.363  0.030  0.871  1.0
  O  O25  1  0.863  0.970  0.629  1.0
  O  O26  1  0.637  0.970  0.129  1.0
  O  O27  1  0.137  0.030  0.371  1.0
  O  O28  1  0.908  0.696  0.305  1.0
  O  O29  1  0.408  0.304  0.195  1.0
  O  O30  1  0.136  0.931  0.060  1.0
  O  O31  1  0.636  0.069  0.440  1.0
  O  O32  1  0.864  0.069  0.940  1.0
  O  O33  1  0.364  0.931  0.560  1.0
  O  O34  1  0.134  0.448  0.880  1.0
  O  O35  1  0.634  0.552  0.620  1.0
  O  O36  1  0.866  0.552  0.120  1.0
  O  O37  1  0.366  0.448  0.380  1.0
  O  O38  1  0.092  0.304  0.695  1.0
  O  O39  1  0.592  0.696  0.805  1.0
[/CIF]
.