The compound described by ReNS8O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and one ReNS8 cluster. In the ReNS8 cluster, Re(1) is bonded to one S(3), one S(4), one S(6), one S(8), and two equivalent S(5) atoms to form distorted edge-sharing ReS6 octahedra. N(1) is bonded in a single-bond geometry to one S(5) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one S(3) and one S(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(7) atom. In the third S site, S(3) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one S(1) atom. In the fourth S site, S(4) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one S(2) atom. In the fifth S site, S(5) is bonded in a 3-coordinate geometry to two equivalent Re(1) and one N(1) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one Re(1) and one S(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(2) and one S(6) atom. In the eighth S site, S(8) is bonded in a bent 120 degrees geometry to one Re(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ReS8NO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.860
_cell_length_b   8.746
_cell_length_c   10.207
_cell_angle_alpha   83.876
_cell_angle_beta   77.616
_cell_angle_gamma   78.209
_symmetry_Int_Tables_number   1
_cell_volume   669.495
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.105  0.908  0.887  1.0
  Re  Re1  1  0.895  0.092  0.113  1.0
  S  S2  1  0.119  0.709  0.240  1.0
  S  S3  1  0.881  0.291  0.760  1.0
  S  S4  1  0.441  0.606  0.714  1.0
  S  S5  1  0.559  0.394  0.286  1.0
  S  S6  1  0.990  0.933  0.283  1.0
  S  S7  1  0.010  0.067  0.717  1.0
  S  S8  1  0.399  0.802  0.821  1.0
  S  S9  1  0.601  0.198  0.179  1.0
  S  S10  1  0.190  0.093  0.981  1.0
  S  S11  1  0.810  0.907  0.019  1.0
  S  S12  1  0.017  0.700  0.780  1.0
  S  S13  1  0.983  0.300  0.220  1.0
  S  S14  1  0.222  0.642  0.625  1.0
  S  S15  1  0.778  0.358  0.375  1.0
  S  S16  1  0.136  0.660  0.051  1.0
  S  S17  1  0.864  0.340  0.949  1.0
  N  N18  1  0.326  0.193  0.970  1.0
  N  N19  1  0.674  0.807  0.030  1.0
  O  O20  1  0.576  0.077  0.617  1.0
  O  O21  1  0.424  0.923  0.383  1.0
  O  O22  1  0.457  0.193  0.613  1.0
  O  O23  1  0.543  0.807  0.387  1.0
[/CIF]
.
The compound described by ReNS8O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and one ReNS8 cluster. In the ReNS8 cluster, Re(1) is bonded to one S(3), one S(4), one S(6), one S(8), and two equivalent S(5) atoms to form distorted edge-sharing ReS6 octahedra. N(1) is bonded in a single-bond geometry to one S(5) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one S(3) and one S(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(7) atom. In the third S site, S(3) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one S(1) atom. In the fourth S site, S(4) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one S(2) atom. In the fifth S site, S(5) is bonded in a 3-coordinate geometry to two equivalent Re(1) and one N(1) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one Re(1) and one S(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(2) and one S(6) atom. In the eighth S site, S(8) is bonded in a bent 120 degrees geometry to one Re(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ReS8NO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.860
_cell_length_b   8.746
_cell_length_c   10.207
_cell_angle_alpha   83.876
_cell_angle_beta   77.616
_cell_angle_gamma   78.209
_symmetry_Int_Tables_number   1
_cell_volume   669.495
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.105  0.908  0.887  1.0
  Re  Re1  1  0.895  0.092  0.113  1.0
  S  S2  1  0.119  0.709  0.240  1.0
  S  S3  1  0.881  0.291  0.760  1.0
  S  S4  1  0.441  0.606  0.714  1.0
  S  S5  1  0.559  0.394  0.286  1.0
  S  S6  1  0.990  0.933  0.283  1.0
  S  S7  1  0.010  0.067  0.717  1.0
  S  S8  1  0.399  0.802  0.821  1.0
  S  S9  1  0.601  0.198  0.179  1.0
  S  S10  1  0.190  0.093  0.981  1.0
  S  S11  1  0.810  0.907  0.019  1.0
  S  S12  1  0.017  0.700  0.780  1.0
  S  S13  1  0.983  0.300  0.220  1.0
  S  S14  1  0.222  0.642  0.625  1.0
  S  S15  1  0.778  0.358  0.375  1.0
  S  S16  1  0.136  0.660  0.051  1.0
  S  S17  1  0.864  0.340  0.949  1.0
  N  N18  1  0.326  0.193  0.970  1.0
  N  N19  1  0.674  0.807  0.030  1.0
  O  O20  1  0.576  0.077  0.617  1.0
  O  O21  1  0.424  0.923  0.383  1.0
  O  O22  1  0.457  0.193  0.613  1.0
  O  O23  1  0.543  0.807  0.387  1.0
[/CIF]
.