The compound described by NiPb2(NO2)6 crystallizes in the cubic Fm-3m space group. Ni(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. Pb(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. N(1) is bonded to one Ni(1) and four equivalent O(1) atoms to form a mixture of corner and edge-sharing NNiO4 square pyramids. O(1) is bonded in a 5-coordinate geometry to two equivalent Pb(1), two equivalent N(1), and one O(1) atom. is represented by the CIF card [CIF]
data_NiPb2(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.084
_cell_length_b   7.084
_cell_length_c   7.084
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   251.322
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  Pb  Pb1  1  0.750  0.750  0.750  1.0
  Pb  Pb2  1  0.250  0.250  0.250  1.0
  N  N3  1  0.797  0.797  0.203  1.0
  N  N4  1  0.203  0.797  0.203  1.0
  N  N5  1  0.797  0.203  0.203  1.0
  N  N6  1  0.203  0.203  0.797  1.0
  N  N7  1  0.797  0.203  0.797  1.0
  N  N8  1  0.203  0.797  0.797  1.0
  O  O9  1  0.000  0.000  0.370  1.0
  O  O10  1  0.630  0.000  0.370  1.0
  O  O11  1  0.000  0.630  0.370  1.0
  O  O12  1  0.630  0.370  0.000  1.0
  O  O13  1  0.000  0.370  0.000  1.0
  O  O14  1  0.000  0.370  0.630  1.0
  O  O15  1  0.370  0.630  0.000  1.0
  O  O16  1  0.370  0.000  0.630  1.0
  O  O17  1  0.370  0.000  0.000  1.0
  O  O18  1  0.000  0.000  0.630  1.0
  O  O19  1  0.000  0.630  0.000  1.0
  O  O20  1  0.630  0.000  0.000  1.0
[/CIF]
.
The compound described by NiPb2(NO2)6 crystallizes in the cubic Fm-3m space group. Ni(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. Pb(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. N(1) is bonded to one Ni(1) and four equivalent O(1) atoms to form a mixture of corner and edge-sharing NNiO4 square pyramids. O(1) is bonded in a 5-coordinate geometry to two equivalent Pb(1), two equivalent N(1), and one O(1) atom. is represented by the CIF card [CIF]
data_NiPb2(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.084
_cell_length_b   7.084
_cell_length_c   7.084
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   251.322
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  Pb  Pb1  1  0.750  0.750  0.750  1.0
  Pb  Pb2  1  0.250  0.250  0.250  1.0
  N  N3  1  0.797  0.797  0.203  1.0
  N  N4  1  0.203  0.797  0.203  1.0
  N  N5  1  0.797  0.203  0.203  1.0
  N  N6  1  0.203  0.203  0.797  1.0
  N  N7  1  0.797  0.203  0.797  1.0
  N  N8  1  0.203  0.797  0.797  1.0
  O  O9  1  0.000  0.000  0.370  1.0
  O  O10  1  0.630  0.000  0.370  1.0
  O  O11  1  0.000  0.630  0.370  1.0
  O  O12  1  0.630  0.370  0.000  1.0
  O  O13  1  0.000  0.370  0.000  1.0
  O  O14  1  0.000  0.370  0.630  1.0
  O  O15  1  0.370  0.630  0.000  1.0
  O  O16  1  0.370  0.000  0.630  1.0
  O  O17  1  0.370  0.000  0.000  1.0
  O  O18  1  0.000  0.000  0.630  1.0
  O  O19  1  0.000  0.630  0.000  1.0
  O  O20  1  0.630  0.000  0.000  1.0
[/CIF]
.