The material described by IF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-41-4 molecule, one IF5 cluster, and one IF7 cluster. In the IF5 cluster, I(1) is bonded in a distorted square pyramidal geometry to one F(10), one F(13), one F(2), one F(5), and one F(6) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one I(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one I(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one I(1) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one I(1) atom. In the fifth F site, F(13) is bonded in a single-bond geometry to one I(1) atom. In the IF7 cluster, I(2) is bonded in a 6-coordinate geometry to one F(11), one F(12), one F(14), one F(4), one F(7), and one F(9) atom. There are seven inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one I(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one I(2) atom. In the third F site, F(8) is bonded in a single-bond geometry to one F(9) atom. In the fourth F site, F(9) is bonded in a bent 150 degrees geometry to one I(2) and one F(8) atom. In the fifth F site, F(11) is bonded in a single-bond geometry to one I(2) atom. In the sixth F site, F(12) is bonded in a single-bond geometry to one I(2) atom. In the seventh F site, F(14) is bonded in a single-bond geometry to one I(2) atom. is represented by the CIF file [CIF]
data_IF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.218
_cell_length_b   6.362
_cell_length_c   6.622
_cell_angle_alpha   90.768
_cell_angle_beta   91.331
_cell_angle_gamma   110.327
_symmetry_Int_Tables_number   1
_cell_volume   245.527
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  I  I0  1  0.996  0.225  0.995  1.0
  I  I1  1  0.448  0.568  0.547  1.0
  F  F2  1  0.683  0.190  0.327  1.0
  F  F3  1  0.984  0.262  0.710  1.0
  F  F4  1  0.487  0.034  0.221  1.0
  F  F5  1  0.313  0.260  0.468  1.0
  F  F6  1  0.764  0.367  0.984  1.0
  F  F7  1  0.275  0.188  0.906  1.0
  F  F8  1  0.733  0.526  0.595  1.0
  F  F9  1  0.167  0.773  0.024  1.0
  F  F10  1  0.281  0.659  0.874  1.0
  F  F11  1  0.758  0.961  0.922  1.0
  F  F12  1  0.607  0.879  0.557  1.0
  F  F13  1  0.542  0.595  0.280  1.0
  F  F14  1  0.019  0.008  0.198  1.0
  F  F15  1  0.187  0.620  0.427  1.0
[/CIF]
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The material described by IF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-41-4 molecule, one IF5 cluster, and one IF7 cluster. In the IF5 cluster, I(1) is bonded in a distorted square pyramidal geometry to one F(10), one F(13), one F(2), one F(5), and one F(6) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one I(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one I(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one I(1) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one I(1) atom. In the fifth F site, F(13) is bonded in a single-bond geometry to one I(1) atom. In the IF7 cluster, I(2) is bonded in a 6-coordinate geometry to one F(11), one F(12), one F(14), one F(4), one F(7), and one F(9) atom. There are seven inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one I(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one I(2) atom. In the third F site, F(8) is bonded in a single-bond geometry to one F(9) atom. In the fourth F site, F(9) is bonded in a bent 150 degrees geometry to one I(2) and one F(8) atom. In the fifth F site, F(11) is bonded in a single-bond geometry to one I(2) atom. In the sixth F site, F(12) is bonded in a single-bond geometry to one I(2) atom. In the seventh F site, F(14) is bonded in a single-bond geometry to one I(2) atom. is represented by the CIF file [CIF]
data_IF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.218
_cell_length_b   6.362
_cell_length_c   6.622
_cell_angle_alpha   90.768
_cell_angle_beta   91.331
_cell_angle_gamma   110.327
_symmetry_Int_Tables_number   1
_cell_volume   245.527
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  I  I0  1  0.996  0.225  0.995  1.0
  I  I1  1  0.448  0.568  0.547  1.0
  F  F2  1  0.683  0.190  0.327  1.0
  F  F3  1  0.984  0.262  0.710  1.0
  F  F4  1  0.487  0.034  0.221  1.0
  F  F5  1  0.313  0.260  0.468  1.0
  F  F6  1  0.764  0.367  0.984  1.0
  F  F7  1  0.275  0.188  0.906  1.0
  F  F8  1  0.733  0.526  0.595  1.0
  F  F9  1  0.167  0.773  0.024  1.0
  F  F10  1  0.281  0.659  0.874  1.0
  F  F11  1  0.758  0.961  0.922  1.0
  F  F12  1  0.607  0.879  0.557  1.0
  F  F13  1  0.542  0.595  0.280  1.0
  F  F14  1  0.019  0.008  0.198  1.0
  F  F15  1  0.187  0.620  0.427  1.0
[/CIF]
.