The material structure described by Th(GeO)2 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Th(GeO)2 clusters. Th(1) is bonded in a linear geometry to two equivalent O(1) atoms. Ge(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a bent 150 degrees geometry to one Th(1) and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th(GeO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.860
_cell_length_b   9.860
_cell_length_c   9.860
_cell_angle_alpha   122.684
_cell_angle_beta   122.684
_cell_angle_gamma   85.411
_symmetry_Int_Tables_number   1
_cell_volume   647.981
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.875  0.125  0.750  1.0
  Th  Th1  1  0.375  0.125  0.250  1.0
  Th  Th2  1  0.875  0.625  0.750  1.0
  Th  Th3  1  0.875  0.125  0.250  1.0
  Ge  Ge4  1  0.665  0.382  0.283  1.0
  Ge  Ge5  1  0.100  0.382  0.717  1.0
  Ge  Ge6  1  0.132  0.350  0.217  1.0
  Ge  Ge7  1  0.650  0.868  0.783  1.0
  Ge  Ge8  1  0.085  0.868  0.217  1.0
  Ge  Ge9  1  0.132  0.915  0.783  1.0
  Ge  Ge10  1  0.618  0.900  0.283  1.0
  Ge  Ge11  1  0.618  0.335  0.717  1.0
  O  O12  1  0.468  0.269  0.200  1.0
  O  O13  1  0.069  0.269  0.800  1.0
  O  O14  1  0.019  0.319  0.300  1.0
  O  O15  1  0.681  0.981  0.700  1.0
  O  O16  1  0.282  0.981  0.300  1.0
  O  O17  1  0.019  0.718  0.700  1.0
  O  O18  1  0.731  0.931  0.200  1.0
  O  O19  1  0.731  0.532  0.800  1.0
[/CIF]
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The material structure described by Th(GeO)2 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Th(GeO)2 clusters. Th(1) is bonded in a linear geometry to two equivalent O(1) atoms. Ge(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a bent 150 degrees geometry to one Th(1) and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th(GeO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.860
_cell_length_b   9.860
_cell_length_c   9.860
_cell_angle_alpha   122.684
_cell_angle_beta   122.684
_cell_angle_gamma   85.411
_symmetry_Int_Tables_number   1
_cell_volume   647.981
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.875  0.125  0.750  1.0
  Th  Th1  1  0.375  0.125  0.250  1.0
  Th  Th2  1  0.875  0.625  0.750  1.0
  Th  Th3  1  0.875  0.125  0.250  1.0
  Ge  Ge4  1  0.665  0.382  0.283  1.0
  Ge  Ge5  1  0.100  0.382  0.717  1.0
  Ge  Ge6  1  0.132  0.350  0.217  1.0
  Ge  Ge7  1  0.650  0.868  0.783  1.0
  Ge  Ge8  1  0.085  0.868  0.217  1.0
  Ge  Ge9  1  0.132  0.915  0.783  1.0
  Ge  Ge10  1  0.618  0.900  0.283  1.0
  Ge  Ge11  1  0.618  0.335  0.717  1.0
  O  O12  1  0.468  0.269  0.200  1.0
  O  O13  1  0.069  0.269  0.800  1.0
  O  O14  1  0.019  0.319  0.300  1.0
  O  O15  1  0.681  0.981  0.700  1.0
  O  O16  1  0.282  0.981  0.300  1.0
  O  O17  1  0.019  0.718  0.700  1.0
  O  O18  1  0.731  0.931  0.200  1.0
  O  O19  1  0.731  0.532  0.800  1.0
[/CIF]
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