The compound described by Ag2PO2 crystallizes in the orthorhombic Fddd space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent P(1), and two equivalent O(1) atoms. P(1) is bonded in a linear geometry to four equivalent Ag(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Ag2PO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.625
_cell_length_b   6.532
_cell_length_c   10.078
_cell_angle_alpha   77.243
_cell_angle_beta   67.770
_cell_angle_gamma   54.291
_symmetry_Int_Tables_number   1
_cell_volume   377.281
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.503  0.743  0.322  1.0
  Ag  Ag1  1  0.175  0.257  0.322  1.0
  Ag  Ag2  1  0.754  0.743  0.678  1.0
  Ag  Ag3  1  0.247  0.757  0.178  1.0
  Ag  Ag4  1  0.568  0.257  0.678  1.0
  Ag  Ag5  1  0.575  0.243  0.178  1.0
  Ag  Ag6  1  0.996  0.757  0.822  1.0
  Ag  Ag7  1  0.182  0.243  0.822  1.0
  P  P8  1  0.875  0.250  0.250  1.0
  P  P9  1  0.875  0.750  0.250  1.0
  P  P10  1  0.875  0.250  0.750  1.0
  P  P11  1  0.375  0.750  0.750  1.0
  O  O12  1  0.013  0.232  0.091  1.0
  O  O13  1  0.896  0.768  0.091  1.0
  O  O14  1  0.755  0.232  0.909  1.0
  O  O15  1  0.737  0.268  0.409  1.0
  O  O16  1  0.336  0.768  0.909  1.0
  O  O17  1  0.854  0.732  0.409  1.0
  O  O18  1  0.995  0.268  0.591  1.0
  O  O19  1  0.414  0.732  0.591  1.0
[/CIF]
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The compound described by Ag2PO2 crystallizes in the orthorhombic Fddd space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent P(1), and two equivalent O(1) atoms. P(1) is bonded in a linear geometry to four equivalent Ag(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Ag2PO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.625
_cell_length_b   6.532
_cell_length_c   10.078
_cell_angle_alpha   77.243
_cell_angle_beta   67.770
_cell_angle_gamma   54.291
_symmetry_Int_Tables_number   1
_cell_volume   377.281
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.503  0.743  0.322  1.0
  Ag  Ag1  1  0.175  0.257  0.322  1.0
  Ag  Ag2  1  0.754  0.743  0.678  1.0
  Ag  Ag3  1  0.247  0.757  0.178  1.0
  Ag  Ag4  1  0.568  0.257  0.678  1.0
  Ag  Ag5  1  0.575  0.243  0.178  1.0
  Ag  Ag6  1  0.996  0.757  0.822  1.0
  Ag  Ag7  1  0.182  0.243  0.822  1.0
  P  P8  1  0.875  0.250  0.250  1.0
  P  P9  1  0.875  0.750  0.250  1.0
  P  P10  1  0.875  0.250  0.750  1.0
  P  P11  1  0.375  0.750  0.750  1.0
  O  O12  1  0.013  0.232  0.091  1.0
  O  O13  1  0.896  0.768  0.091  1.0
  O  O14  1  0.755  0.232  0.909  1.0
  O  O15  1  0.737  0.268  0.409  1.0
  O  O16  1  0.336  0.768  0.909  1.0
  O  O17  1  0.854  0.732  0.409  1.0
  O  O18  1  0.995  0.268  0.591  1.0
  O  O19  1  0.414  0.732  0.591  1.0
[/CIF]
.