The material described by K2LiBaCo(NO2)6 crystallizes in the triclinic P1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(9) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(6), and one O(9) atom. Ba(1) is bonded in a distorted cuboctahedral geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one O(3), and one O(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one O(1), and one O(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one O(10), and one O(11) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one O(6), and one O(9) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one O(12), and one O(5) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(1), one O(7), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Ba(1), and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Li(1), one Ba(1), and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(5) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one K(2), one Li(1), one Ba(1), and one N(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(6) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(2), one Ba(1), and one N(6) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one K(1), one Li(1), one Ba(1), and one N(4) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(3) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one K(2), one Ba(1), and one N(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one K(1), one Ba(1), and one N(5) atom. is represented by the CIF file [CIF]
data_K2BaLiCo(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.752
_cell_length_b   7.930
_cell_length_c   7.845
_cell_angle_alpha   122.953
_cell_angle_beta   118.161
_cell_angle_gamma   88.814
_symmetry_Int_Tables_number   1
_cell_volume   338.122
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.195  0.716  0.492  1.0
  K  K1  1  0.771  0.312  0.490  1.0
  Ba  Ba2  1  0.498  0.488  0.981  1.0
  Li  Li3  1  0.574  0.923  0.483  1.0
  Co  Co4  1  0.006  0.997  0.998  1.0
  N  N5  1  0.198  0.809  0.999  1.0
  N  N6  1  0.813  0.187  0.996  1.0
  N  N7  1  0.188  0.196  0.379  1.0
  N  N8  1  0.824  0.802  0.624  1.0
  N  N9  1  0.202  0.196  0.002  1.0
  N  N10  1  0.811  0.809  0.005  1.0
  O  O11  1  0.659  0.153  0.802  1.0
  O  O12  1  0.844  0.351  0.191  1.0
  O  O13  1  0.169  0.646  0.803  1.0
  O  O14  1  0.349  0.842  0.192  1.0
  O  O15  1  0.346  0.144  0.970  1.0
  O  O16  1  0.636  0.688  0.513  1.0
  O  O17  1  0.834  0.635  0.971  1.0
  O  O18  1  0.671  0.864  0.042  1.0
  O  O19  1  0.839  0.866  0.509  1.0
  O  O20  1  0.358  0.338  0.498  1.0
  O  O21  1  0.149  0.168  0.502  1.0
  O  O22  1  0.182  0.370  0.042  1.0
[/CIF]
.
The material described by K2LiBaCo(NO2)6 crystallizes in the triclinic P1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(9) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(6), and one O(9) atom. Ba(1) is bonded in a distorted cuboctahedral geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one O(3), and one O(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one O(1), and one O(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one O(10), and one O(11) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one O(6), and one O(9) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one O(12), and one O(5) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(1), one O(7), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Ba(1), and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Li(1), one Ba(1), and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(5) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one K(2), one Li(1), one Ba(1), and one N(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(6) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(2), one Ba(1), and one N(6) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one K(1), one Li(1), one Ba(1), and one N(4) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one K(1), one K(2), one Ba(1), and one N(3) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one K(2), one Ba(1), and one N(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one K(1), one Ba(1), and one N(5) atom. is represented by the CIF file [CIF]
data_K2BaLiCo(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.752
_cell_length_b   7.930
_cell_length_c   7.845
_cell_angle_alpha   122.953
_cell_angle_beta   118.161
_cell_angle_gamma   88.814
_symmetry_Int_Tables_number   1
_cell_volume   338.122
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.195  0.716  0.492  1.0
  K  K1  1  0.771  0.312  0.490  1.0
  Ba  Ba2  1  0.498  0.488  0.981  1.0
  Li  Li3  1  0.574  0.923  0.483  1.0
  Co  Co4  1  0.006  0.997  0.998  1.0
  N  N5  1  0.198  0.809  0.999  1.0
  N  N6  1  0.813  0.187  0.996  1.0
  N  N7  1  0.188  0.196  0.379  1.0
  N  N8  1  0.824  0.802  0.624  1.0
  N  N9  1  0.202  0.196  0.002  1.0
  N  N10  1  0.811  0.809  0.005  1.0
  O  O11  1  0.659  0.153  0.802  1.0
  O  O12  1  0.844  0.351  0.191  1.0
  O  O13  1  0.169  0.646  0.803  1.0
  O  O14  1  0.349  0.842  0.192  1.0
  O  O15  1  0.346  0.144  0.970  1.0
  O  O16  1  0.636  0.688  0.513  1.0
  O  O17  1  0.834  0.635  0.971  1.0
  O  O18  1  0.671  0.864  0.042  1.0
  O  O19  1  0.839  0.866  0.509  1.0
  O  O20  1  0.358  0.338  0.498  1.0
  O  O21  1  0.149  0.168  0.502  1.0
  O  O22  1  0.182  0.370  0.042  1.0
[/CIF]
.