The compound described by V2O3F is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(5), one O(6), one O(8), and one F(1) atom to form distorted VO5F octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with two equivalent V(7)O4F2 octahedra, corners with two equivalent V(8)O4F2 octahedra, and corners with two equivalent V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-54°. In the second V site, V(2) is bonded to one O(12), one O(3), one O(4), one O(7), one O(9), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with two equivalent V(7)O4F2 octahedra, corners with two equivalent V(8)O4F2 octahedra, corners with two equivalent V(6)O5F octahedra, and edges with two equivalent V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-59°. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(5), one O(6), one O(8), and one F(4) atom. In the fourth V site, V(4) is bonded to one O(2), one O(4), one O(7), one O(9), one F(2), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with two equivalent V(7)O4F2 octahedra, corners with two equivalent V(8)O4F2 octahedra, corners with two equivalent V(6)O5F octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the fifth V site, V(5) is bonded to one O(1), one O(12), one O(7), one O(8), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O5F octahedra, and edges with two equivalent V(8)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the sixth V site, V(6) is bonded to one O(11), one O(2), one O(3), one O(6), one O(9), and one F(4) atom to form VO5F octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O5F octahedra, and edges with two equivalent V(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the seventh V site, V(7) is bonded to one O(11), one O(2), one O(3), one O(5), one F(2), and one F(4) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O5F octahedra, and edges with two equivalent V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-52°. In the eighth V site, V(8) is bonded to one O(1), one O(10), one O(12), one O(4), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O5F octahedra, and edges with two equivalent V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(8) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(4), one V(6), and one V(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2), one V(6), and one V(7) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(8) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(7) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(5) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(5) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(8) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one V(1), one V(6), and one V(7) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(8) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one V(1), one V(5), and one V(8) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(4), one V(5), and one V(8) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one V(3), one V(6), and one V(7) atom. is represented by the CIF file [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.689
_cell_length_b   6.055
_cell_length_c   9.851
_cell_angle_alpha   107.650
_cell_angle_beta   92.102
_cell_angle_gamma   89.818
_symmetry_Int_Tables_number   1
_cell_volume   266.336
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.553  0.860  0.228  1.0
  V  V1  1  0.501  0.127  0.743  1.0
  V  V2  1  0.454  0.394  0.276  1.0
  V  V3  1  0.463  0.612  0.754  1.0
  V  V4  1  0.983  0.245  0.499  1.0
  V  V5  1  0.013  0.499  0.995  1.0
  V  V6  1  0.057  0.003  0.002  1.0
  V  V7  1  0.989  0.760  0.506  1.0
  O  O8  1  0.186  0.455  0.401  1.0
  O  O9  1  0.202  0.709  0.905  1.0
  O  O10  1  0.196  0.189  0.898  1.0
  O  O11  1  0.313  0.810  0.656  1.0
  O  O12  1  0.305  0.077  0.154  1.0
  O  O13  1  0.316  0.575  0.152  1.0
  O  O14  1  0.285  0.333  0.648  1.0
  O  O15  1  0.685  0.173  0.344  1.0
  O  O16  1  0.689  0.442  0.847  1.0
  O  O17  1  0.693  0.672  0.345  1.0
  O  O18  1  0.813  0.807  0.097  1.0
  O  O19  1  0.799  0.048  0.599  1.0
  F  F20  1  0.198  0.949  0.397  1.0
  F  F21  1  0.710  0.921  0.855  1.0
  F  F22  1  0.784  0.549  0.602  1.0
  F  F23  1  0.814  0.291  0.095  1.0
[/CIF]
.
The compound described by V2O3F is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(5), one O(6), one O(8), and one F(1) atom to form distorted VO5F octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with two equivalent V(7)O4F2 octahedra, corners with two equivalent V(8)O4F2 octahedra, and corners with two equivalent V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-54°. In the second V site, V(2) is bonded to one O(12), one O(3), one O(4), one O(7), one O(9), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with two equivalent V(7)O4F2 octahedra, corners with two equivalent V(8)O4F2 octahedra, corners with two equivalent V(6)O5F octahedra, and edges with two equivalent V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-59°. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(5), one O(6), one O(8), and one F(4) atom. In the fourth V site, V(4) is bonded to one O(2), one O(4), one O(7), one O(9), one F(2), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with two equivalent V(7)O4F2 octahedra, corners with two equivalent V(8)O4F2 octahedra, corners with two equivalent V(6)O5F octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the fifth V site, V(5) is bonded to one O(1), one O(12), one O(7), one O(8), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O5F octahedra, and edges with two equivalent V(8)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the sixth V site, V(6) is bonded to one O(11), one O(2), one O(3), one O(6), one O(9), and one F(4) atom to form VO5F octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O5F octahedra, and edges with two equivalent V(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the seventh V site, V(7) is bonded to one O(11), one O(2), one O(3), one O(5), one F(2), and one F(4) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O5F octahedra, and edges with two equivalent V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-52°. In the eighth V site, V(8) is bonded to one O(1), one O(10), one O(12), one O(4), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O5F octahedra, and edges with two equivalent V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(8) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(4), one V(6), and one V(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2), one V(6), and one V(7) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(8) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(7) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(5) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(5) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(8) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one V(1), one V(6), and one V(7) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(8) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one V(1), one V(5), and one V(8) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(4), one V(5), and one V(8) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one V(3), one V(6), and one V(7) atom. is represented by the CIF file [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.689
_cell_length_b   6.055
_cell_length_c   9.851
_cell_angle_alpha   107.650
_cell_angle_beta   92.102
_cell_angle_gamma   89.818
_symmetry_Int_Tables_number   1
_cell_volume   266.336
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.553  0.860  0.228  1.0
  V  V1  1  0.501  0.127  0.743  1.0
  V  V2  1  0.454  0.394  0.276  1.0
  V  V3  1  0.463  0.612  0.754  1.0
  V  V4  1  0.983  0.245  0.499  1.0
  V  V5  1  0.013  0.499  0.995  1.0
  V  V6  1  0.057  0.003  0.002  1.0
  V  V7  1  0.989  0.760  0.506  1.0
  O  O8  1  0.186  0.455  0.401  1.0
  O  O9  1  0.202  0.709  0.905  1.0
  O  O10  1  0.196  0.189  0.898  1.0
  O  O11  1  0.313  0.810  0.656  1.0
  O  O12  1  0.305  0.077  0.154  1.0
  O  O13  1  0.316  0.575  0.152  1.0
  O  O14  1  0.285  0.333  0.648  1.0
  O  O15  1  0.685  0.173  0.344  1.0
  O  O16  1  0.689  0.442  0.847  1.0
  O  O17  1  0.693  0.672  0.345  1.0
  O  O18  1  0.813  0.807  0.097  1.0
  O  O19  1  0.799  0.048  0.599  1.0
  F  F20  1  0.198  0.949  0.397  1.0
  F  F21  1  0.710  0.921  0.855  1.0
  F  F22  1  0.784  0.549  0.602  1.0
  F  F23  1  0.814  0.291  0.095  1.0
[/CIF]
.