The crystal structure described by TiOF2 is alpha Rhenium trioxide-derived structured and crystallizes in the tetragonal P4_2/mmc space group. Ti(1) is bonded to two equivalent O(1), two equivalent F(1), and two equivalent F(2) atoms to form corner-sharing TiO2F4 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a linear geometry to two equivalent Ti(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Ti(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Ti(1) atoms. is represented by the CIF file [CIF]
data_TiOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.805
_cell_length_b   3.805
_cell_length_c   7.894
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   114.265
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.000  0.000  0.000  1.0
  Ti  Ti1  1  0.000  0.000  0.500  1.0
  O  O2  1  0.500  0.000  0.000  1.0
  O  O3  1  0.000  0.500  0.500  1.0
  F  F4  1  0.500  0.000  0.500  1.0
  F  F5  1  0.000  0.500  0.000  1.0
  F  F6  1  0.000  0.000  0.250  1.0
  F  F7  1  0.000  0.000  0.750  1.0
[/CIF]
.
The crystal structure described by TiOF2 is alpha Rhenium trioxide-derived structured and crystallizes in the tetragonal P4_2/mmc space group. Ti(1) is bonded to two equivalent O(1), two equivalent F(1), and two equivalent F(2) atoms to form corner-sharing TiO2F4 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a linear geometry to two equivalent Ti(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Ti(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Ti(1) atoms. is represented by the CIF file [CIF]
data_TiOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.805
_cell_length_b   3.805
_cell_length_c   7.894
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   114.265
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.000  0.000  0.000  1.0
  Ti  Ti1  1  0.000  0.000  0.500  1.0
  O  O2  1  0.500  0.000  0.000  1.0
  O  O3  1  0.000  0.500  0.500  1.0
  F  F4  1  0.500  0.000  0.500  1.0
  F  F5  1  0.000  0.500  0.000  1.0
  F  F6  1  0.000  0.000  0.250  1.0
  F  F7  1  0.000  0.000  0.750  1.0
[/CIF]
.