The material structure described by LiRu2Cu(RhO4)2 is Spinel-derived structured and crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form LiO4 tetrahedra that share corners with six equivalent Ru(1)O6 octahedra and corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-64°. Ru(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form RuO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Cu(1)O4 tetrahedra, edges with two equivalent Ru(1)O6 octahedra, and edges with four equivalent Rh(1)O6 octahedra. Rh(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form RhO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Cu(1)O4 tetrahedra, edges with two equivalent Rh(1)O6 octahedra, and edges with four equivalent Ru(1)O6 octahedra. Cu(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form CuO4 tetrahedra that share corners with six equivalent Ru(1)O6 octahedra and corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-65°. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ru(1), one Rh(1), and one Cu(1) atom to form distorted OCuRu2Rh tetrahedra that share  a cornercorner with one O(1)CuRu2Rh tetrahedra, corners with two equivalent O(2)CuRuRh2 tetrahedra, corners with four equivalent O(4)LiRuRh2 trigonal pyramids,  an edgeedge with one O(1)CuRu2Rh tetrahedra, and edges with two equivalent O(2)CuRuRh2 tetrahedra. In the second O site, O(2) is bonded to one Ru(1), two equivalent Rh(1), and one Cu(1) atom to form distorted OCuRuRh2 tetrahedra that share  a cornercorner with one O(2)CuRuRh2 tetrahedra, corners with two equivalent O(1)CuRu2Rh tetrahedra, corners with five equivalent O(4)LiRuRh2 trigonal pyramids,  an edgeedge with one O(2)CuRuRh2 tetrahedra, and edges with two equivalent O(1)CuRu2Rh tetrahedra. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Ru(1), and one Rh(1) atom. In the fourth O site, O(4) is bonded to one Li(1), one Ru(1), and two equivalent Rh(1) atoms to form distorted OLiRuRh2 trigonal pyramids that share corners with four equivalent O(1)CuRu2Rh tetrahedra, corners with five equivalent O(2)CuRuRh2 tetrahedra,  a cornercorner with one O(4)LiRuRh2 trigonal pyramid, and  an edgeedge with one O(4)LiRuRh2 trigonal pyramid. is represented by the CIF card [CIF]
data_LiCuRu2(RhO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.146
_cell_length_b   6.146
_cell_length_c   6.146
_cell_angle_alpha   125.161
_cell_angle_beta   118.743
_cell_angle_gamma   86.746
_symmetry_Int_Tables_number   1
_cell_volume   158.356
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.380  0.380  0.000  1.0
  Cu  Cu1  1  0.132  0.632  0.500  1.0
  Ru  Ru2  1  0.750  0.027  0.277  1.0
  Ru  Ru3  1  0.750  0.473  0.723  1.0
  Rh  Rh4  1  0.752  0.999  0.753  1.0
  Rh  Rh5  1  0.246  0.999  0.247  1.0
  O  O6  1  0.983  0.766  0.216  1.0
  O  O7  1  0.550  0.766  0.784  1.0
  O  O8  1  0.978  0.739  0.761  1.0
  O  O9  1  0.978  0.218  0.239  1.0
  O  O10  1  0.482  0.231  0.251  1.0
  O  O11  1  0.980  0.231  0.749  1.0
  O  O12  1  0.520  0.250  0.731  1.0
  O  O13  1  0.520  0.789  0.269  1.0
[/CIF]
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The material structure described by LiRu2Cu(RhO4)2 is Spinel-derived structured and crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form LiO4 tetrahedra that share corners with six equivalent Ru(1)O6 octahedra and corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-64°. Ru(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form RuO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Cu(1)O4 tetrahedra, edges with two equivalent Ru(1)O6 octahedra, and edges with four equivalent Rh(1)O6 octahedra. Rh(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form RhO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Cu(1)O4 tetrahedra, edges with two equivalent Rh(1)O6 octahedra, and edges with four equivalent Ru(1)O6 octahedra. Cu(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form CuO4 tetrahedra that share corners with six equivalent Ru(1)O6 octahedra and corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-65°. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ru(1), one Rh(1), and one Cu(1) atom to form distorted OCuRu2Rh tetrahedra that share  a cornercorner with one O(1)CuRu2Rh tetrahedra, corners with two equivalent O(2)CuRuRh2 tetrahedra, corners with four equivalent O(4)LiRuRh2 trigonal pyramids,  an edgeedge with one O(1)CuRu2Rh tetrahedra, and edges with two equivalent O(2)CuRuRh2 tetrahedra. In the second O site, O(2) is bonded to one Ru(1), two equivalent Rh(1), and one Cu(1) atom to form distorted OCuRuRh2 tetrahedra that share  a cornercorner with one O(2)CuRuRh2 tetrahedra, corners with two equivalent O(1)CuRu2Rh tetrahedra, corners with five equivalent O(4)LiRuRh2 trigonal pyramids,  an edgeedge with one O(2)CuRuRh2 tetrahedra, and edges with two equivalent O(1)CuRu2Rh tetrahedra. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Ru(1), and one Rh(1) atom. In the fourth O site, O(4) is bonded to one Li(1), one Ru(1), and two equivalent Rh(1) atoms to form distorted OLiRuRh2 trigonal pyramids that share corners with four equivalent O(1)CuRu2Rh tetrahedra, corners with five equivalent O(2)CuRuRh2 tetrahedra,  a cornercorner with one O(4)LiRuRh2 trigonal pyramid, and  an edgeedge with one O(4)LiRuRh2 trigonal pyramid. is represented by the CIF card [CIF]
data_LiCuRu2(RhO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.146
_cell_length_b   6.146
_cell_length_c   6.146
_cell_angle_alpha   125.161
_cell_angle_beta   118.743
_cell_angle_gamma   86.746
_symmetry_Int_Tables_number   1
_cell_volume   158.356
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.380  0.380  0.000  1.0
  Cu  Cu1  1  0.132  0.632  0.500  1.0
  Ru  Ru2  1  0.750  0.027  0.277  1.0
  Ru  Ru3  1  0.750  0.473  0.723  1.0
  Rh  Rh4  1  0.752  0.999  0.753  1.0
  Rh  Rh5  1  0.246  0.999  0.247  1.0
  O  O6  1  0.983  0.766  0.216  1.0
  O  O7  1  0.550  0.766  0.784  1.0
  O  O8  1  0.978  0.739  0.761  1.0
  O  O9  1  0.978  0.218  0.239  1.0
  O  O10  1  0.482  0.231  0.251  1.0
  O  O11  1  0.980  0.231  0.749  1.0
  O  O12  1  0.520  0.250  0.731  1.0
  O  O13  1  0.520  0.789  0.269  1.0
[/CIF]
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