The material structure described by MgP2N3H8O4NH4(PH6(NO)2)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ammonium molecule, one MgP2N3H8O4 cluster, and two PH6(NO)2 clusters. In the MgP2N3H8O4 cluster, Mg(1) is bonded in a water-like geometry to one O(1) and one O(3) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(5) atom. In the second P site, P(3) is bonded in a trigonal non-coplanar geometry to one N(3), one O(3), and one O(7) atom. There are three inequivalent N sites. In the first N site, N(5) is bonded in a tetrahedral geometry to one H(13), one H(17), one H(21), and one H(9) atom. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one P(1), one H(1), and one H(5) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one P(3), one H(3), and one H(7) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one N(5) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one N(5) and one O(5) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one N(5) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mg(1) and one P(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Mg(1) and one P(3) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one P(1) and one H(17) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one P(3) atom. In each PH6(NO)2 cluster, P(2) is bonded in a trigonal non-coplanar geometry to one N(2), one O(2), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(8) is bonded in a tetrahedral geometry to one H(12), one H(16), one H(20), and one H(24) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(2), and one H(6) atom. There are six inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(12) is bonded in a single-bond geometry to one N(8) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one N(8) and one O(2) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one N(8) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one N(8) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one P(2) and one H(16) atom. In the second O site, O(6) is bonded in a single-bond geometry to one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgP4H24(NO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.064
_cell_length_b   10.184
_cell_length_c   7.003
_cell_angle_alpha   81.432
_cell_angle_beta   116.347
_cell_angle_gamma   91.385
_symmetry_Int_Tables_number   1
_cell_volume   509.036
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.994  0.592  0.411  1.0
  P  P1  1  0.871  0.432  0.815  1.0
  P  P2  1  0.141  0.026  0.653  1.0
  P  P3  1  0.127  0.485  0.088  1.0
  P  P4  1  0.864  0.083  0.372  1.0
  H  H5  1  0.971  0.215  0.827  1.0
  H  H6  1  0.019  0.822  0.642  1.0
  H  H7  1  0.088  0.703  0.120  1.0
  H  H8  1  0.903  0.308  0.300  1.0
  H  H9  1  0.844  0.215  0.961  1.0
  H  H10  1  0.194  0.820  0.588  1.0
  H  H11  1  0.171  0.699  0.935  1.0
  H  H12  1  0.810  0.277  0.473  1.0
  H  H13  1  0.335  0.369  0.845  1.0
  H  H14  1  0.720  0.962  0.695  1.0
  H  H15  1  0.633  0.633  0.183  1.0
  H  H16  1  0.318  0.096  0.364  1.0
  H  H17  1  0.291  0.392  0.581  1.0
  H  H18  1  0.758  0.978  0.958  1.0
  H  H19  1  0.656  0.552  0.418  1.0
  H  H20  1  0.275  0.085  0.099  1.0
  H  H21  1  0.514  0.394  0.776  1.0
  H  H22  1  0.540  0.969  0.757  1.0
  H  H23  1  0.479  0.509  0.187  1.0
  H  H24  1  0.499  0.083  0.304  1.0
  H  H25  1  0.391  0.248  0.735  1.0
  H  H26  1  0.691  0.833  0.861  1.0
  H  H27  1  0.461  0.654  0.258  1.0
  H  H28  1  0.356  0.223  0.207  1.0
  N  N29  1  0.870  0.268  0.840  1.0
  N  N30  1  0.151  0.857  0.689  1.0
  N  N31  1  0.163  0.648  0.068  1.0
  N  N32  1  0.819  0.246  0.345  1.0
  N  N33  1  0.384  0.350  0.736  1.0
  N  N34  1  0.678  0.935  0.817  1.0
  N  N35  1  0.558  0.587  0.262  1.0
  N  N36  1  0.362  0.121  0.244  1.0
  O  O37  1  0.899  0.482  0.612  1.0
  O  O38  1  0.127  0.074  0.841  1.0
  O  O39  1  0.106  0.449  0.299  1.0
  O  O40  1  0.867  0.058  0.165  1.0
  O  O41  1  0.701  0.486  0.821  1.0
  O  O42  1  0.310  0.071  0.617  1.0
  O  O43  1  0.288  0.413  0.079  1.0
  O  O44  1  0.728  0.011  0.445  1.0
[/CIF]
.
The material structure described by MgP2N3H8O4NH4(PH6(NO)2)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ammonium molecule, one MgP2N3H8O4 cluster, and two PH6(NO)2 clusters. In the MgP2N3H8O4 cluster, Mg(1) is bonded in a water-like geometry to one O(1) and one O(3) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(5) atom. In the second P site, P(3) is bonded in a trigonal non-coplanar geometry to one N(3), one O(3), and one O(7) atom. There are three inequivalent N sites. In the first N site, N(5) is bonded in a tetrahedral geometry to one H(13), one H(17), one H(21), and one H(9) atom. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one P(1), one H(1), and one H(5) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one P(3), one H(3), and one H(7) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one N(5) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one N(5) and one O(5) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one N(5) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mg(1) and one P(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Mg(1) and one P(3) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one P(1) and one H(17) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one P(3) atom. In each PH6(NO)2 cluster, P(2) is bonded in a trigonal non-coplanar geometry to one N(2), one O(2), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(8) is bonded in a tetrahedral geometry to one H(12), one H(16), one H(20), and one H(24) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(2), and one H(6) atom. There are six inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(12) is bonded in a single-bond geometry to one N(8) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one N(8) and one O(2) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one N(8) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one N(8) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one P(2) and one H(16) atom. In the second O site, O(6) is bonded in a single-bond geometry to one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgP4H24(NO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.064
_cell_length_b   10.184
_cell_length_c   7.003
_cell_angle_alpha   81.432
_cell_angle_beta   116.347
_cell_angle_gamma   91.385
_symmetry_Int_Tables_number   1
_cell_volume   509.036
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.994  0.592  0.411  1.0
  P  P1  1  0.871  0.432  0.815  1.0
  P  P2  1  0.141  0.026  0.653  1.0
  P  P3  1  0.127  0.485  0.088  1.0
  P  P4  1  0.864  0.083  0.372  1.0
  H  H5  1  0.971  0.215  0.827  1.0
  H  H6  1  0.019  0.822  0.642  1.0
  H  H7  1  0.088  0.703  0.120  1.0
  H  H8  1  0.903  0.308  0.300  1.0
  H  H9  1  0.844  0.215  0.961  1.0
  H  H10  1  0.194  0.820  0.588  1.0
  H  H11  1  0.171  0.699  0.935  1.0
  H  H12  1  0.810  0.277  0.473  1.0
  H  H13  1  0.335  0.369  0.845  1.0
  H  H14  1  0.720  0.962  0.695  1.0
  H  H15  1  0.633  0.633  0.183  1.0
  H  H16  1  0.318  0.096  0.364  1.0
  H  H17  1  0.291  0.392  0.581  1.0
  H  H18  1  0.758  0.978  0.958  1.0
  H  H19  1  0.656  0.552  0.418  1.0
  H  H20  1  0.275  0.085  0.099  1.0
  H  H21  1  0.514  0.394  0.776  1.0
  H  H22  1  0.540  0.969  0.757  1.0
  H  H23  1  0.479  0.509  0.187  1.0
  H  H24  1  0.499  0.083  0.304  1.0
  H  H25  1  0.391  0.248  0.735  1.0
  H  H26  1  0.691  0.833  0.861  1.0
  H  H27  1  0.461  0.654  0.258  1.0
  H  H28  1  0.356  0.223  0.207  1.0
  N  N29  1  0.870  0.268  0.840  1.0
  N  N30  1  0.151  0.857  0.689  1.0
  N  N31  1  0.163  0.648  0.068  1.0
  N  N32  1  0.819  0.246  0.345  1.0
  N  N33  1  0.384  0.350  0.736  1.0
  N  N34  1  0.678  0.935  0.817  1.0
  N  N35  1  0.558  0.587  0.262  1.0
  N  N36  1  0.362  0.121  0.244  1.0
  O  O37  1  0.899  0.482  0.612  1.0
  O  O38  1  0.127  0.074  0.841  1.0
  O  O39  1  0.106  0.449  0.299  1.0
  O  O40  1  0.867  0.058  0.165  1.0
  O  O41  1  0.701  0.486  0.821  1.0
  O  O42  1  0.310  0.071  0.617  1.0
  O  O43  1  0.288  0.413  0.079  1.0
  O  O44  1  0.728  0.011  0.445  1.0
[/CIF]
.