The compound described by (OsO4)2ZnN4 is Silicon tetrafluoride-derived structured and crystallizes in the cubic F-43m space group. The structure is zero-dimensional and consists of four azanide;zinc molecules and eight OsO4 clusters. In each OsO4 cluster, Os(1,2) is bonded in a tetrahedral geometry to four equivalent O(1,2) atoms. O(1,2) is bonded in a single-bond geometry to one Os(1,2) atom. is represented by the CIF card [CIF]
data_ZnOs2(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.527
_cell_length_b   7.527
_cell_length_c   7.527
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   301.557
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.250  0.250  1.0
  Os  Os1  1  0.750  0.750  0.750  1.0
  Os  Os2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.361  0.361  0.361  1.0
  N  N4  1  0.361  0.361  0.916  1.0
  N  N5  1  0.361  0.916  0.361  1.0
  N  N6  1  0.916  0.361  0.361  1.0
  O  O7  1  0.094  0.094  0.094  1.0
  O  O8  1  0.094  0.094  0.719  1.0
  O  O9  1  0.094  0.719  0.094  1.0
  O  O10  1  0.719  0.094  0.094  1.0
  O  O11  1  0.656  0.656  0.656  1.0
  O  O12  1  0.656  0.656  0.031  1.0
  O  O13  1  0.656  0.031  0.656  1.0
  O  O14  1  0.031  0.656  0.656  1.0
[/CIF]
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The compound described by (OsO4)2ZnN4 is Silicon tetrafluoride-derived structured and crystallizes in the cubic F-43m space group. The structure is zero-dimensional and consists of four azanide;zinc molecules and eight OsO4 clusters. In each OsO4 cluster, Os(1,2) is bonded in a tetrahedral geometry to four equivalent O(1,2) atoms. O(1,2) is bonded in a single-bond geometry to one Os(1,2) atom. is represented by the CIF card [CIF]
data_ZnOs2(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.527
_cell_length_b   7.527
_cell_length_c   7.527
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   301.557
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.250  0.250  1.0
  Os  Os1  1  0.750  0.750  0.750  1.0
  Os  Os2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.361  0.361  0.361  1.0
  N  N4  1  0.361  0.361  0.916  1.0
  N  N5  1  0.361  0.916  0.361  1.0
  N  N6  1  0.916  0.361  0.361  1.0
  O  O7  1  0.094  0.094  0.094  1.0
  O  O8  1  0.094  0.094  0.719  1.0
  O  O9  1  0.094  0.719  0.094  1.0
  O  O10  1  0.719  0.094  0.094  1.0
  O  O11  1  0.656  0.656  0.656  1.0
  O  O12  1  0.656  0.656  0.031  1.0
  O  O13  1  0.656  0.031  0.656  1.0
  O  O14  1  0.031  0.656  0.656  1.0
[/CIF]
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