The compound described by Li3V8O11 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(2), one O(3), one O(6), and two equivalent O(1) atoms to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent V(7)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second Li site, Li(2) is bonded to one O(2), one O(4), one O(6), one O(9), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(6)O6 octahedra, edges with three equivalent V(3)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the third Li site, Li(3) is bonded to one O(10), one O(11), one O(7), one O(9), and two equivalent O(8) atoms to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(6)O6 octahedra, edges with two equivalent V(7)O6 octahedra, edges with three equivalent V(5)O6 octahedra, and edges with three equivalent V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), one O(2), and two equivalent O(3) atoms to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(8)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(2) atoms to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(8)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the third V site, V(3) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the fourth V site, V(4) is bonded to one O(5), one O(6), one O(7), one O(9), and two equivalent O(4) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-17°. In the fifth V site, V(5) is bonded to one O(11), one O(4), one O(8), one O(9), and two equivalent O(7) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(8)O6 octahedra, corners with two equivalent V(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with two equivalent V(8)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-18°. In the sixth V site, V(6) is bonded to one O(4), one O(5), one O(7), one O(8), and two equivalent O(9) atoms to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent V(4)O6 octahedra, and edges with three equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the seventh V site, V(7) is bonded to one O(1), one O(11), one O(3), one O(8), and two equivalent O(10) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent V(7)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the eighth V site, V(8) is bonded to one O(10), one O(3), one O(7), one O(8), and two equivalent O(11) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent V(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-13°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one V(1), one V(2), one V(3), and one V(7) atom to form OLi2V4 octahedra that share  a cornercorner with one O(10)Li2V4 octahedra,  a cornercorner with one O(6)Li2V4 octahedra,  a cornercorner with one O(8)Li2V4 octahedra,  a cornercorner with one O(4)LiV5 octahedra, corners with two equivalent O(1)Li2V4 octahedra,  an edgeedge with one O(5)Li2V4 octahedra,  an edgeedge with one O(11)LiV5 octahedra, edges with two equivalent O(10)Li2V4 octahedra, edges with two equivalent O(6)Li2V4 octahedra, edges with three equivalent O(2)Li2V4 octahedra, and edges with three equivalent O(3)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one V(1), one V(3), and two equivalent V(2) atoms to form OLi2V4 octahedra that share  a cornercorner with one O(5)Li2V4 octahedra,  a cornercorner with one O(9)Li2V4 octahedra,  a cornercorner with one O(11)LiV5 octahedra,  a cornercorner with one O(3)LiV5 octahedra, corners with two equivalent O(2)Li2V4 octahedra,  an edgeedge with one O(10)Li2V4 octahedra,  an edgeedge with one O(4)LiV5 octahedra, edges with two equivalent O(5)Li2V4 octahedra, edges with two equivalent O(3)LiV5 octahedra, edges with three equivalent O(1)Li2V4 octahedra, and edges with three equivalent O(6)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the third O site, O(3) is bonded to one Li(1), one V(2), one V(7), one V(8), and two equivalent V(1) atoms to form OLiV5 octahedra that share  a cornercorner with one O(2)Li2V4 octahedra,  a cornercorner with one O(5)Li2V4 octahedra,  a cornercorner with one O(11)LiV5 octahedra,  a cornercorner with one O(7)LiV5 octahedra, corners with two equivalent O(3)LiV5 octahedra,  an edgeedge with one O(6)Li2V4 octahedra,  an edgeedge with one O(8)Li2V4 octahedra, edges with two equivalent O(2)Li2V4 octahedra, edges with two equivalent O(11)LiV5 octahedra, edges with three equivalent O(1)Li2V4 octahedra, and edges with three equivalent O(10)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the fourth O site, O(4) is bonded to one Li(2), one V(3), one V(5), one V(6), and two equivalent V(4) atoms to form OLiV5 octahedra that share  a cornercorner with one O(1)Li2V4 octahedra,  a cornercorner with one O(6)Li2V4 octahedra,  a cornercorner with one O(11)LiV5 octahedra,  a cornercorner with one O(7)LiV5 octahedra, corners with two equivalent O(4)LiV5 octahedra,  an edgeedge with one O(2)Li2V4 octahedra,  an edgeedge with one O(8)Li2V4 octahedra, edges with two equivalent O(6)Li2V4 octahedra, edges with two equivalent O(7)LiV5 octahedra, edges with three equivalent O(5)Li2V4 octahedra, and edges with three equivalent O(9)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 0-17°. In the fifth O site, O(5) is bonded to two equivalent Li(2), one V(2), one V(3), one V(4), and one V(6) atom to form OLi2V4 octahedra that share  a cornercorner with one O(2)Li2V4 octahedra,  a cornercorner with one O(8)Li2V4 octahedra,  a cornercorner with one O(9)Li2V4 octahedra,  a cornercorner with one O(3)LiV5 octahedra, corners with two equivalent O(5)Li2V4 octahedra,  an edgeedge with one O(1)Li2V4 octahedra,  an edgeedge with one O(7)LiV5 octahedra, edges with two equivalent O(2)Li2V4 octahedra, edges with two equivalent O(9)Li2V4 octahedra, edges with three equivalent O(6)Li2V4 octahedra, and edges with three equivalent O(4)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one V(2), one V(4), and two equivalent V(3) atoms to form OLi2V4 octahedra that share  a cornercorner with one O(1)Li2V4 octahedra,  a cornercorner with one O(10)Li2V4 octahedra,  a cornercorner with one O(4)LiV5 octahedra,  a cornercorner with one O(7)LiV5 octahedra, corners with two equivalent O(6)Li2V4 octahedra,  an edgeedge with one O(9)Li2V4 octahedra,  an edgeedge with one O(3)LiV5 octahedra, edges with two equivalent O(1)Li2V4 octahedra, edges with two equivalent O(4)LiV5 octahedra, edges with three equivalent O(2)Li2V4 octahedra, and edges with three equivalent O(5)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the seventh O site, O(7) is bonded to one Li(3), one V(4), one V(6), one V(8), and two equivalent V(5) atoms to form OLiV5 octahedra that share  a cornercorner with one O(6)Li2V4 octahedra,  a cornercorner with one O(11)LiV5 octahedra,  a cornercorner with one O(3)LiV5 octahedra,  a cornercorner with one O(4)LiV5 octahedra, corners with two equivalent O(7)LiV5 octahedra,  an edgeedge with one O(10)Li2V4 octahedra,  an edgeedge with one O(5)Li2V4 octahedra, edges with two equivalent O(11)LiV5 octahedra, edges with two equivalent O(4)LiV5 octahedra, edges with three equivalent O(8)Li2V4 octahedra, and edges with three equivalent O(9)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 2-18°. In the eighth O site, O(8) is bonded to two equivalent Li(3), one V(5), one V(6), one V(7), and one V(8) atom to form OLi2V4 octahedra that share  a cornercorner with one O(1)Li2V4 octahedra,  a cornercorner with one O(10)Li2V4 octahedra,  a cornercorner with one O(5)Li2V4 octahedra,  a cornercorner with one O(9)Li2V4 octahedra, corners with two equivalent O(8)Li2V4 octahedra,  an edgeedge with one O(3)LiV5 octahedra,  an edgeedge with one O(4)LiV5 octahedra, edges with two equivalent O(10)Li2V4 octahedra, edges with two equivalent O(9)Li2V4 octahedra, edges with three equivalent O(11)LiV5 octahedra, and edges with three equivalent O(7)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the ninth O site, O(9) is bonded to one Li(2), one Li(3), one V(4), one V(5), and two equivalent V(6) atoms to form OLi2V4 octahedra that share  a cornercorner with one O(10)Li2V4 octahedra,  a cornercorner with one O(2)Li2V4 octahedra,  a cornercorner with one O(5)Li2V4 octahedra,  a cornercorner with one O(8)Li2V4 octahedra, corners with two equivalent O(9)Li2V4 octahedra,  an edgeedge with one O(6)Li2V4 octahedra,  an edgeedge with one O(11)LiV5 octahedra, edges with two equivalent O(5)Li2V4 octahedra, edges with two equivalent O(8)Li2V4 octahedra, edges with three equivalent O(4)LiV5 octahedra, and edges with three equivalent O(7)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 1-15°. In the tenth O site, O(10) is bonded to one Li(1), one Li(3), one V(1), one V(8), and two equivalent V(7) atoms to form OLi2V4 octahedra that share  a cornercorner with one O(1)Li2V4 octahedra,  a cornercorner with one O(6)Li2V4 octahedra,  a cornercorner with one O(8)Li2V4 octahedra,  a cornercorner with one O(9)Li2V4 octahedra, corners with two equivalent O(10)Li2V4 octahedra,  an edgeedge with one O(2)Li2V4 octahedra,  an edgeedge with one O(7)LiV5 octahedra, edges with two equivalent O(1)Li2V4 octahedra, edges with two equivalent O(8)Li2V4 octahedra, edges with three equivalent O(11)LiV5 octahedra, and edges with three equivalent O(3)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the eleventh O site, O(11) is bonded to one Li(3), one V(1), one V(5), one V(7), and two equivalent V(8) atoms to form OLiV5 octahedra that share  a cornercorner with one O(2)Li2V4 octahedra,  a cornercorner with one O(3)LiV5 octahedra,  a cornercorner with one O(4)LiV5 octahedra,  a cornercorner with one O(7)LiV5 octahedra, corners with two equivalent O(11)LiV5 octahedra,  an edgeedge with one O(1)Li2V4 octahedra,  an edgeedge with one O(9)Li2V4 octahedra, edges with two equivalent O(3)LiV5 octahedra, edges with two equivalent O(7)LiV5 octahedra, edges with three equivalent O(10)Li2V4 octahedra, and edges with three equivalent O(8)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. is represented by the CIF card [CIF]
data_Li3V8O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.879
_cell_length_b   4.144
_cell_length_c   5.026
_cell_angle_alpha   65.843
_cell_angle_beta   84.580
_cell_angle_gamma   101.307
_symmetry_Int_Tables_number   1
_cell_volume   198.826
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.096  0.361  0.369  1.0
  Li  Li1  1  0.361  0.453  0.450  1.0
  Li  Li2  1  0.730  0.908  0.911  1.0
  V  V3  1  0.991  0.982  0.012  1.0
  V  V4  1  0.186  0.737  0.708  1.0
  V  V5  1  0.273  0.080  0.112  1.0
  V  V6  1  0.467  0.819  0.824  1.0
  V  V7  1  0.623  0.522  0.584  1.0
  V  V8  1  0.544  0.196  0.140  1.0
  V  V9  1  0.914  0.634  0.641  1.0
  V  V10  1  0.829  0.293  0.257  1.0
  O  O11  1  0.094  0.866  0.357  1.0
  O  O12  1  0.179  0.211  0.752  1.0
  O  O13  1  0.012  0.499  0.001  1.0
  O  O14  1  0.440  0.312  0.807  1.0
  O  O15  1  0.370  0.952  0.457  1.0
  O  O16  1  0.278  0.603  0.070  1.0
  O  O17  1  0.643  0.062  0.521  1.0
  O  O18  1  0.728  0.407  0.910  1.0
  O  O19  1  0.550  0.673  0.194  1.0
  O  O20  1  0.911  0.136  0.633  1.0
  O  O21  1  0.809  0.763  0.290  1.0
[/CIF]
.
The compound described by Li3V8O11 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(2), one O(3), one O(6), and two equivalent O(1) atoms to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent V(7)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second Li site, Li(2) is bonded to one O(2), one O(4), one O(6), one O(9), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(6)O6 octahedra, edges with three equivalent V(3)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the third Li site, Li(3) is bonded to one O(10), one O(11), one O(7), one O(9), and two equivalent O(8) atoms to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(6)O6 octahedra, edges with two equivalent V(7)O6 octahedra, edges with three equivalent V(5)O6 octahedra, and edges with three equivalent V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), one O(2), and two equivalent O(3) atoms to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(8)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(2) atoms to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(8)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the third V site, V(3) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the fourth V site, V(4) is bonded to one O(5), one O(6), one O(7), one O(9), and two equivalent O(4) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-17°. In the fifth V site, V(5) is bonded to one O(11), one O(4), one O(8), one O(9), and two equivalent O(7) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(8)O6 octahedra, corners with two equivalent V(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with two equivalent V(8)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-18°. In the sixth V site, V(6) is bonded to one O(4), one O(5), one O(7), one O(8), and two equivalent O(9) atoms to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent V(4)O6 octahedra, and edges with three equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the seventh V site, V(7) is bonded to one O(1), one O(11), one O(3), one O(8), and two equivalent O(10) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent V(7)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the eighth V site, V(8) is bonded to one O(10), one O(3), one O(7), one O(8), and two equivalent O(11) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent V(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-13°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one V(1), one V(2), one V(3), and one V(7) atom to form OLi2V4 octahedra that share  a cornercorner with one O(10)Li2V4 octahedra,  a cornercorner with one O(6)Li2V4 octahedra,  a cornercorner with one O(8)Li2V4 octahedra,  a cornercorner with one O(4)LiV5 octahedra, corners with two equivalent O(1)Li2V4 octahedra,  an edgeedge with one O(5)Li2V4 octahedra,  an edgeedge with one O(11)LiV5 octahedra, edges with two equivalent O(10)Li2V4 octahedra, edges with two equivalent O(6)Li2V4 octahedra, edges with three equivalent O(2)Li2V4 octahedra, and edges with three equivalent O(3)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one V(1), one V(3), and two equivalent V(2) atoms to form OLi2V4 octahedra that share  a cornercorner with one O(5)Li2V4 octahedra,  a cornercorner with one O(9)Li2V4 octahedra,  a cornercorner with one O(11)LiV5 octahedra,  a cornercorner with one O(3)LiV5 octahedra, corners with two equivalent O(2)Li2V4 octahedra,  an edgeedge with one O(10)Li2V4 octahedra,  an edgeedge with one O(4)LiV5 octahedra, edges with two equivalent O(5)Li2V4 octahedra, edges with two equivalent O(3)LiV5 octahedra, edges with three equivalent O(1)Li2V4 octahedra, and edges with three equivalent O(6)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the third O site, O(3) is bonded to one Li(1), one V(2), one V(7), one V(8), and two equivalent V(1) atoms to form OLiV5 octahedra that share  a cornercorner with one O(2)Li2V4 octahedra,  a cornercorner with one O(5)Li2V4 octahedra,  a cornercorner with one O(11)LiV5 octahedra,  a cornercorner with one O(7)LiV5 octahedra, corners with two equivalent O(3)LiV5 octahedra,  an edgeedge with one O(6)Li2V4 octahedra,  an edgeedge with one O(8)Li2V4 octahedra, edges with two equivalent O(2)Li2V4 octahedra, edges with two equivalent O(11)LiV5 octahedra, edges with three equivalent O(1)Li2V4 octahedra, and edges with three equivalent O(10)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the fourth O site, O(4) is bonded to one Li(2), one V(3), one V(5), one V(6), and two equivalent V(4) atoms to form OLiV5 octahedra that share  a cornercorner with one O(1)Li2V4 octahedra,  a cornercorner with one O(6)Li2V4 octahedra,  a cornercorner with one O(11)LiV5 octahedra,  a cornercorner with one O(7)LiV5 octahedra, corners with two equivalent O(4)LiV5 octahedra,  an edgeedge with one O(2)Li2V4 octahedra,  an edgeedge with one O(8)Li2V4 octahedra, edges with two equivalent O(6)Li2V4 octahedra, edges with two equivalent O(7)LiV5 octahedra, edges with three equivalent O(5)Li2V4 octahedra, and edges with three equivalent O(9)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 0-17°. In the fifth O site, O(5) is bonded to two equivalent Li(2), one V(2), one V(3), one V(4), and one V(6) atom to form OLi2V4 octahedra that share  a cornercorner with one O(2)Li2V4 octahedra,  a cornercorner with one O(8)Li2V4 octahedra,  a cornercorner with one O(9)Li2V4 octahedra,  a cornercorner with one O(3)LiV5 octahedra, corners with two equivalent O(5)Li2V4 octahedra,  an edgeedge with one O(1)Li2V4 octahedra,  an edgeedge with one O(7)LiV5 octahedra, edges with two equivalent O(2)Li2V4 octahedra, edges with two equivalent O(9)Li2V4 octahedra, edges with three equivalent O(6)Li2V4 octahedra, and edges with three equivalent O(4)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one V(2), one V(4), and two equivalent V(3) atoms to form OLi2V4 octahedra that share  a cornercorner with one O(1)Li2V4 octahedra,  a cornercorner with one O(10)Li2V4 octahedra,  a cornercorner with one O(4)LiV5 octahedra,  a cornercorner with one O(7)LiV5 octahedra, corners with two equivalent O(6)Li2V4 octahedra,  an edgeedge with one O(9)Li2V4 octahedra,  an edgeedge with one O(3)LiV5 octahedra, edges with two equivalent O(1)Li2V4 octahedra, edges with two equivalent O(4)LiV5 octahedra, edges with three equivalent O(2)Li2V4 octahedra, and edges with three equivalent O(5)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the seventh O site, O(7) is bonded to one Li(3), one V(4), one V(6), one V(8), and two equivalent V(5) atoms to form OLiV5 octahedra that share  a cornercorner with one O(6)Li2V4 octahedra,  a cornercorner with one O(11)LiV5 octahedra,  a cornercorner with one O(3)LiV5 octahedra,  a cornercorner with one O(4)LiV5 octahedra, corners with two equivalent O(7)LiV5 octahedra,  an edgeedge with one O(10)Li2V4 octahedra,  an edgeedge with one O(5)Li2V4 octahedra, edges with two equivalent O(11)LiV5 octahedra, edges with two equivalent O(4)LiV5 octahedra, edges with three equivalent O(8)Li2V4 octahedra, and edges with three equivalent O(9)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 2-18°. In the eighth O site, O(8) is bonded to two equivalent Li(3), one V(5), one V(6), one V(7), and one V(8) atom to form OLi2V4 octahedra that share  a cornercorner with one O(1)Li2V4 octahedra,  a cornercorner with one O(10)Li2V4 octahedra,  a cornercorner with one O(5)Li2V4 octahedra,  a cornercorner with one O(9)Li2V4 octahedra, corners with two equivalent O(8)Li2V4 octahedra,  an edgeedge with one O(3)LiV5 octahedra,  an edgeedge with one O(4)LiV5 octahedra, edges with two equivalent O(10)Li2V4 octahedra, edges with two equivalent O(9)Li2V4 octahedra, edges with three equivalent O(11)LiV5 octahedra, and edges with three equivalent O(7)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the ninth O site, O(9) is bonded to one Li(2), one Li(3), one V(4), one V(5), and two equivalent V(6) atoms to form OLi2V4 octahedra that share  a cornercorner with one O(10)Li2V4 octahedra,  a cornercorner with one O(2)Li2V4 octahedra,  a cornercorner with one O(5)Li2V4 octahedra,  a cornercorner with one O(8)Li2V4 octahedra, corners with two equivalent O(9)Li2V4 octahedra,  an edgeedge with one O(6)Li2V4 octahedra,  an edgeedge with one O(11)LiV5 octahedra, edges with two equivalent O(5)Li2V4 octahedra, edges with two equivalent O(8)Li2V4 octahedra, edges with three equivalent O(4)LiV5 octahedra, and edges with three equivalent O(7)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 1-15°. In the tenth O site, O(10) is bonded to one Li(1), one Li(3), one V(1), one V(8), and two equivalent V(7) atoms to form OLi2V4 octahedra that share  a cornercorner with one O(1)Li2V4 octahedra,  a cornercorner with one O(6)Li2V4 octahedra,  a cornercorner with one O(8)Li2V4 octahedra,  a cornercorner with one O(9)Li2V4 octahedra, corners with two equivalent O(10)Li2V4 octahedra,  an edgeedge with one O(2)Li2V4 octahedra,  an edgeedge with one O(7)LiV5 octahedra, edges with two equivalent O(1)Li2V4 octahedra, edges with two equivalent O(8)Li2V4 octahedra, edges with three equivalent O(11)LiV5 octahedra, and edges with three equivalent O(3)LiV5 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the eleventh O site, O(11) is bonded to one Li(3), one V(1), one V(5), one V(7), and two equivalent V(8) atoms to form OLiV5 octahedra that share  a cornercorner with one O(2)Li2V4 octahedra,  a cornercorner with one O(3)LiV5 octahedra,  a cornercorner with one O(4)LiV5 octahedra,  a cornercorner with one O(7)LiV5 octahedra, corners with two equivalent O(11)LiV5 octahedra,  an edgeedge with one O(1)Li2V4 octahedra,  an edgeedge with one O(9)Li2V4 octahedra, edges with two equivalent O(3)LiV5 octahedra, edges with two equivalent O(7)LiV5 octahedra, edges with three equivalent O(10)Li2V4 octahedra, and edges with three equivalent O(8)Li2V4 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. is represented by the CIF card [CIF]
data_Li3V8O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.879
_cell_length_b   4.144
_cell_length_c   5.026
_cell_angle_alpha   65.843
_cell_angle_beta   84.580
_cell_angle_gamma   101.307
_symmetry_Int_Tables_number   1
_cell_volume   198.826
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.096  0.361  0.369  1.0
  Li  Li1  1  0.361  0.453  0.450  1.0
  Li  Li2  1  0.730  0.908  0.911  1.0
  V  V3  1  0.991  0.982  0.012  1.0
  V  V4  1  0.186  0.737  0.708  1.0
  V  V5  1  0.273  0.080  0.112  1.0
  V  V6  1  0.467  0.819  0.824  1.0
  V  V7  1  0.623  0.522  0.584  1.0
  V  V8  1  0.544  0.196  0.140  1.0
  V  V9  1  0.914  0.634  0.641  1.0
  V  V10  1  0.829  0.293  0.257  1.0
  O  O11  1  0.094  0.866  0.357  1.0
  O  O12  1  0.179  0.211  0.752  1.0
  O  O13  1  0.012  0.499  0.001  1.0
  O  O14  1  0.440  0.312  0.807  1.0
  O  O15  1  0.370  0.952  0.457  1.0
  O  O16  1  0.278  0.603  0.070  1.0
  O  O17  1  0.643  0.062  0.521  1.0
  O  O18  1  0.728  0.407  0.910  1.0
  O  O19  1  0.550  0.673  0.194  1.0
  O  O20  1  0.911  0.136  0.633  1.0
  O  O21  1  0.809  0.763  0.290  1.0
[/CIF]
.