The material described by OsCl6(IrN3Cl2)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two hexachloro osmium molecules, and four IrN3Cl2 clusters. In each IrN3Cl2 cluster, Ir(1) is bonded in a tetrahedral geometry to one N(1), two equivalent N(2), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(5) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom. is represented by the CIF card [CIF]
data_Ir2Os(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.707
_cell_length_b   6.707
_cell_length_c   16.917
_cell_angle_alpha   76.332
_cell_angle_beta   76.332
_cell_angle_gamma   73.058
_symmetry_Int_Tables_number   1
_cell_volume   695.706
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.445  0.445  0.246  1.0
  Ir  Ir1  1  0.555  0.555  0.754  1.0
  Os  Os2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.264  0.264  0.237  1.0
  N  N4  1  0.736  0.736  0.763  1.0
  N  N5  1  0.689  0.326  0.194  1.0
  N  N6  1  0.326  0.689  0.194  1.0
  N  N7  1  0.311  0.674  0.806  1.0
  N  N8  1  0.674  0.311  0.806  1.0
  N  N9  1  0.234  0.094  0.528  1.0
  N  N10  1  0.094  0.234  0.528  1.0
  N  N11  1  0.766  0.906  0.472  1.0
  N  N12  1  0.906  0.766  0.472  1.0
  Cl  Cl13  1  0.925  0.925  0.144  1.0
  Cl  Cl14  1  0.075  0.075  0.856  1.0
  Cl  Cl15  1  0.461  0.461  0.377  1.0
  Cl  Cl16  1  0.539  0.539  0.623  1.0
  Cl  Cl17  1  0.210  0.210  0.005  1.0
  Cl  Cl18  1  0.790  0.790  0.995  1.0
  Cl  Cl19  1  0.713  0.287  0.000  1.0
  Cl  Cl20  1  0.287  0.713  0.000  1.0
  Cl  Cl21  1  0.147  0.147  0.327  1.0
  Cl  Cl22  1  0.853  0.853  0.673  1.0
[/CIF]
.
The material described by OsCl6(IrN3Cl2)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two hexachloro osmium molecules, and four IrN3Cl2 clusters. In each IrN3Cl2 cluster, Ir(1) is bonded in a tetrahedral geometry to one N(1), two equivalent N(2), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(5) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom. is represented by the CIF card [CIF]
data_Ir2Os(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.707
_cell_length_b   6.707
_cell_length_c   16.917
_cell_angle_alpha   76.332
_cell_angle_beta   76.332
_cell_angle_gamma   73.058
_symmetry_Int_Tables_number   1
_cell_volume   695.706
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.445  0.445  0.246  1.0
  Ir  Ir1  1  0.555  0.555  0.754  1.0
  Os  Os2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.264  0.264  0.237  1.0
  N  N4  1  0.736  0.736  0.763  1.0
  N  N5  1  0.689  0.326  0.194  1.0
  N  N6  1  0.326  0.689  0.194  1.0
  N  N7  1  0.311  0.674  0.806  1.0
  N  N8  1  0.674  0.311  0.806  1.0
  N  N9  1  0.234  0.094  0.528  1.0
  N  N10  1  0.094  0.234  0.528  1.0
  N  N11  1  0.766  0.906  0.472  1.0
  N  N12  1  0.906  0.766  0.472  1.0
  Cl  Cl13  1  0.925  0.925  0.144  1.0
  Cl  Cl14  1  0.075  0.075  0.856  1.0
  Cl  Cl15  1  0.461  0.461  0.377  1.0
  Cl  Cl16  1  0.539  0.539  0.623  1.0
  Cl  Cl17  1  0.210  0.210  0.005  1.0
  Cl  Cl18  1  0.790  0.790  0.995  1.0
  Cl  Cl19  1  0.713  0.287  0.000  1.0
  Cl  Cl20  1  0.287  0.713  0.000  1.0
  Cl  Cl21  1  0.147  0.147  0.327  1.0
  Cl  Cl22  1  0.853  0.853  0.673  1.0
[/CIF]
.