The structure described by N2S3O5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N2S3O5 clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded to one N(1), one O(1), one O(2), and one O(5) atom to form corner-sharing SNO3 tetrahedra. In the third S site, S(3) is bonded to one N(2), one O(2), one O(3), and one O(4) atom to form corner-sharing SNO3 tetrahedra. There are five inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one S(3) atom. is represented by the CIF file [CIF]
data_S3N2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.322
_cell_length_b   8.174
_cell_length_c   8.648
_cell_angle_alpha   68.101
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   676.951
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.176  0.769  0.749  1.0
  S  S1  1  0.676  0.731  0.251  1.0
  S  S2  1  0.824  0.231  0.251  1.0
  S  S3  1  0.324  0.269  0.749  1.0
  S  S4  1  0.959  0.576  0.708  1.0
  S  S5  1  0.459  0.924  0.292  1.0
  S  S6  1  0.041  0.424  0.292  1.0
  S  S7  1  0.541  0.076  0.708  1.0
  S  S8  1  0.925  0.892  0.787  1.0
  S  S9  1  0.425  0.608  0.213  1.0
  S  S10  1  0.075  0.108  0.213  1.0
  S  S11  1  0.575  0.392  0.787  1.0
  N  N12  1  0.116  0.610  0.718  1.0
  N  N13  1  0.616  0.890  0.282  1.0
  N  N14  1  0.884  0.390  0.282  1.0
  N  N15  1  0.384  0.110  0.718  1.0
  N  N16  1  0.085  0.901  0.786  1.0
  N  N17  1  0.585  0.599  0.214  1.0
  N  N18  1  0.915  0.099  0.214  1.0
  N  N19  1  0.415  0.401  0.786  1.0
  O  O20  1  0.932  0.395  0.804  1.0
  O  O21  1  0.432  0.105  0.196  1.0
  O  O22  1  0.068  0.605  0.196  1.0
  O  O23  1  0.568  0.895  0.804  1.0
  O  O24  1  0.603  0.180  0.824  1.0
  O  O25  1  0.103  0.320  0.176  1.0
  O  O26  1  0.397  0.820  0.176  1.0
  O  O27  1  0.897  0.680  0.824  1.0
  O  O28  1  0.622  0.412  0.934  1.0
  O  O29  1  0.122  0.088  0.066  1.0
  O  O30  1  0.378  0.588  0.066  1.0
  O  O31  1  0.878  0.912  0.934  1.0
  O  O32  1  0.622  0.498  0.625  1.0
  O  O33  1  0.122  0.002  0.375  1.0
  O  O34  1  0.378  0.502  0.375  1.0
  O  O35  1  0.878  0.998  0.625  1.0
  O  O36  1  0.583  0.160  0.539  1.0
  O  O37  1  0.083  0.340  0.461  1.0
  O  O38  1  0.417  0.840  0.461  1.0
  O  O39  1  0.917  0.660  0.539  1.0
[/CIF]
.
The structure described by N2S3O5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N2S3O5 clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded to one N(1), one O(1), one O(2), and one O(5) atom to form corner-sharing SNO3 tetrahedra. In the third S site, S(3) is bonded to one N(2), one O(2), one O(3), and one O(4) atom to form corner-sharing SNO3 tetrahedra. There are five inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one S(3) atom. is represented by the CIF file [CIF]
data_S3N2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.322
_cell_length_b   8.174
_cell_length_c   8.648
_cell_angle_alpha   68.101
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   676.951
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.176  0.769  0.749  1.0
  S  S1  1  0.676  0.731  0.251  1.0
  S  S2  1  0.824  0.231  0.251  1.0
  S  S3  1  0.324  0.269  0.749  1.0
  S  S4  1  0.959  0.576  0.708  1.0
  S  S5  1  0.459  0.924  0.292  1.0
  S  S6  1  0.041  0.424  0.292  1.0
  S  S7  1  0.541  0.076  0.708  1.0
  S  S8  1  0.925  0.892  0.787  1.0
  S  S9  1  0.425  0.608  0.213  1.0
  S  S10  1  0.075  0.108  0.213  1.0
  S  S11  1  0.575  0.392  0.787  1.0
  N  N12  1  0.116  0.610  0.718  1.0
  N  N13  1  0.616  0.890  0.282  1.0
  N  N14  1  0.884  0.390  0.282  1.0
  N  N15  1  0.384  0.110  0.718  1.0
  N  N16  1  0.085  0.901  0.786  1.0
  N  N17  1  0.585  0.599  0.214  1.0
  N  N18  1  0.915  0.099  0.214  1.0
  N  N19  1  0.415  0.401  0.786  1.0
  O  O20  1  0.932  0.395  0.804  1.0
  O  O21  1  0.432  0.105  0.196  1.0
  O  O22  1  0.068  0.605  0.196  1.0
  O  O23  1  0.568  0.895  0.804  1.0
  O  O24  1  0.603  0.180  0.824  1.0
  O  O25  1  0.103  0.320  0.176  1.0
  O  O26  1  0.397  0.820  0.176  1.0
  O  O27  1  0.897  0.680  0.824  1.0
  O  O28  1  0.622  0.412  0.934  1.0
  O  O29  1  0.122  0.088  0.066  1.0
  O  O30  1  0.378  0.588  0.066  1.0
  O  O31  1  0.878  0.912  0.934  1.0
  O  O32  1  0.622  0.498  0.625  1.0
  O  O33  1  0.122  0.002  0.375  1.0
  O  O34  1  0.378  0.502  0.375  1.0
  O  O35  1  0.878  0.998  0.625  1.0
  O  O36  1  0.583  0.160  0.539  1.0
  O  O37  1  0.083  0.340  0.461  1.0
  O  O38  1  0.417  0.840  0.461  1.0
  O  O39  1  0.917  0.660  0.539  1.0
[/CIF]
.