The material structure described by V6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(4), two equivalent O(1), one F(1), and two equivalent F(4) atoms to form VO3F3 octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(4)O4F2 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second V site, V(2) is bonded to one O(3), one O(5), two equivalent O(1), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with three equivalent V(1)O3F3 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the third V site, V(3) is bonded to one O(4), one O(5), two equivalent O(2), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent V(1)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the fourth V site, V(4) is bonded to one O(3), one O(5), two equivalent O(2), and two equivalent F(4) atoms to form distorted VO4F2 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(3)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the fifth V site, V(5) is bonded to two equivalent O(1), two equivalent O(2), one F(2), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra, corners with three equivalent V(3)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the sixth V site, V(6) is bonded to one O(3), one O(4), one F(2), one F(3), and two equivalent F(4) atoms to form VO2F4 octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with three equivalent V(1)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. is represented by the CIF card [CIF]
data_V6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.596
_cell_length_b   5.596
_cell_length_c   7.358
_cell_angle_alpha   73.432
_cell_angle_beta   73.432
_cell_angle_gamma   71.862
_symmetry_Int_Tables_number   1
_cell_volume   204.899
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.307  0.307  0.172  1.0
  V  V1  1  0.663  0.663  0.332  1.0
  V  V2  1  0.347  0.347  0.684  1.0
  V  V3  1  0.696  0.696  0.809  1.0
  V  V4  1  0.008  0.008  0.493  1.0
  V  V5  1  0.996  0.996  0.996  1.0
  O  O6  1  0.956  0.361  0.338  1.0
  O  O7  1  0.646  0.037  0.664  1.0
  O  O8  1  0.765  0.765  0.028  1.0
  O  O9  1  0.219  0.219  0.971  1.0
  O  O10  1  0.571  0.571  0.647  1.0
  O  O11  1  0.361  0.956  0.338  1.0
  O  O12  1  0.037  0.646  0.664  1.0
  F  F13  1  0.427  0.427  0.369  1.0
  F  F14  1  0.111  0.111  0.700  1.0
  F  F15  1  0.899  0.899  0.292  1.0
  F  F16  1  0.691  0.302  0.001  1.0
  F  F17  1  0.302  0.691  0.001  1.0
[/CIF]
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The material structure described by V6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(4), two equivalent O(1), one F(1), and two equivalent F(4) atoms to form VO3F3 octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(4)O4F2 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second V site, V(2) is bonded to one O(3), one O(5), two equivalent O(1), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with three equivalent V(1)O3F3 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the third V site, V(3) is bonded to one O(4), one O(5), two equivalent O(2), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent V(1)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the fourth V site, V(4) is bonded to one O(3), one O(5), two equivalent O(2), and two equivalent F(4) atoms to form distorted VO4F2 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(3)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the fifth V site, V(5) is bonded to two equivalent O(1), two equivalent O(2), one F(2), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra, corners with three equivalent V(3)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the sixth V site, V(6) is bonded to one O(3), one O(4), one F(2), one F(3), and two equivalent F(4) atoms to form VO2F4 octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with three equivalent V(1)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. is represented by the CIF card [CIF]
data_V6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.596
_cell_length_b   5.596
_cell_length_c   7.358
_cell_angle_alpha   73.432
_cell_angle_beta   73.432
_cell_angle_gamma   71.862
_symmetry_Int_Tables_number   1
_cell_volume   204.899
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.307  0.307  0.172  1.0
  V  V1  1  0.663  0.663  0.332  1.0
  V  V2  1  0.347  0.347  0.684  1.0
  V  V3  1  0.696  0.696  0.809  1.0
  V  V4  1  0.008  0.008  0.493  1.0
  V  V5  1  0.996  0.996  0.996  1.0
  O  O6  1  0.956  0.361  0.338  1.0
  O  O7  1  0.646  0.037  0.664  1.0
  O  O8  1  0.765  0.765  0.028  1.0
  O  O9  1  0.219  0.219  0.971  1.0
  O  O10  1  0.571  0.571  0.647  1.0
  O  O11  1  0.361  0.956  0.338  1.0
  O  O12  1  0.037  0.646  0.664  1.0
  F  F13  1  0.427  0.427  0.369  1.0
  F  F14  1  0.111  0.111  0.700  1.0
  F  F15  1  0.899  0.899  0.292  1.0
  F  F16  1  0.691  0.302  0.001  1.0
  F  F17  1  0.302  0.691  0.001  1.0
[/CIF]
.