The material structure described by Ba2MgAg2CuF14 crystallizes in the triclinic P-1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(13), one F(14), one F(4), one F(8), one F(9), two equivalent F(2), and two equivalent F(3) atoms. In the second Ba site, Ba(2) is bonded in a 10-coordinate geometry to one F(11), one F(12), one F(14), one F(5), one F(7), one F(8), two equivalent F(10), and two equivalent F(6) atoms. Mg(1) is bonded in a 6-coordinate geometry to one F(1), one F(11), one F(4), one F(5), one F(7), and one F(9) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one F(10), one F(12), one F(6), one F(7), one F(8), and one F(9) atom to form AgF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 51-66°. In the second Ag site, Ag(2) is bonded to one F(1), one F(11), one F(13), one F(14), one F(2), and one F(3) atom to form AgF6 octahedra that share corners with two equivalent Cu(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent F(12), two equivalent F(5), and two equivalent F(6) atoms to form distorted CuF6 octahedra that share corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 51-66°. In the second Cu site, Cu(2) is bonded to two equivalent F(13), two equivalent F(2), and two equivalent F(4) atoms to form distorted CuF6 octahedra that share corners with four equivalent Ag(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Mg(1), and one Ag(2) atom. In the second F site, F(2) is bonded to two equivalent Ba(1), one Ag(2), and one Cu(2) atom to form a mixture of distorted edge and corner-sharing FBa2CuAg tetrahedra. In the third F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Mg(1), and one Cu(2) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Ba(2), one Mg(1), and one Cu(1) atom. In the sixth F site, F(6) is bonded to two equivalent Ba(2), one Ag(1), and one Cu(1) atom to form a mixture of distorted edge and corner-sharing FBa2CuAg tetrahedra. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Ba(2), one Mg(1), and one Ag(1) atom. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Ba(1), one Ba(2), and one Ag(1) atom. In the ninth F site, F(9) is bonded in a 2-coordinate geometry to one Ba(1), one Mg(1), and one Ag(1) atom. In the tenth F site, F(10) is bonded in a 3-coordinate geometry to two equivalent Ba(2) and one Ag(1) atom. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Ba(2), one Mg(1), and one Ag(2) atom. In the twelfth F site, F(12) is bonded in a distorted bent 120 degrees geometry to one Ba(2), one Ag(1), and one Cu(1) atom. In the thirteenth F site, F(13) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(2), and one Cu(2) atom. In the fourteenth F site, F(14) is bonded in a 3-coordinate geometry to one Ba(1), one Ba(2), and one Ag(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba2MgCuAg2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.372
_cell_length_b   7.657
_cell_length_c   15.282
_cell_angle_alpha   91.525
_cell_angle_beta   89.622
_cell_angle_gamma   110.461
_symmetry_Int_Tables_number   1
_cell_volume   588.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.726  0.630  0.374  1.0
  Ba  Ba1  1  0.902  0.630  0.875  1.0
  Ba  Ba2  1  0.274  0.370  0.626  1.0
  Ba  Ba3  1  0.098  0.370  0.125  1.0
  Mg  Mg4  1  0.429  0.002  0.248  1.0
  Mg  Mg5  1  0.571  0.998  0.752  1.0
  Cu  Cu6  1  0.500  0.000  0.000  1.0
  Cu  Cu7  1  0.500  0.000  0.500  1.0
  Ag  Ag8  1  0.855  0.766  0.128  1.0
  Ag  Ag9  1  0.145  0.234  0.872  1.0
  Ag  Ag10  1  0.908  0.767  0.628  1.0
  Ag  Ag11  1  0.092  0.233  0.372  1.0
  F  F12  1  0.878  0.028  0.667  1.0
  F  F13  1  0.580  0.717  0.541  1.0
  F  F14  1  0.420  0.283  0.459  1.0
  F  F15  1  0.134  0.511  0.403  1.0
  F  F16  1  0.533  0.914  0.386  1.0
  F  F17  1  0.617  0.084  0.114  1.0
  F  F18  1  0.135  0.716  0.041  1.0
  F  F19  1  0.861  0.972  0.834  1.0
  F  F20  1  0.027  0.654  0.228  1.0
  F  F21  1  0.866  0.489  0.597  1.0
  F  F22  1  0.567  0.792  0.223  1.0
  F  F23  1  0.627  0.488  0.096  1.0
  F  F24  1  0.218  0.789  0.723  1.0
  F  F25  1  0.433  0.208  0.777  1.0
  F  F26  1  0.383  0.916  0.886  1.0
  F  F27  1  0.973  0.346  0.772  1.0
  F  F28  1  0.293  0.150  0.990  1.0
  F  F29  1  0.122  0.972  0.333  1.0
  F  F30  1  0.707  0.850  0.010  1.0
  F  F31  1  0.853  0.151  0.491  1.0
  F  F32  1  0.865  0.284  0.959  1.0
  F  F33  1  0.782  0.211  0.277  1.0
  F  F34  1  0.623  0.658  0.730  1.0
  F  F35  1  0.147  0.849  0.509  1.0
  F  F36  1  0.467  0.086  0.614  1.0
  F  F37  1  0.139  0.028  0.166  1.0
  F  F38  1  0.377  0.342  0.270  1.0
  F  F39  1  0.373  0.512  0.904  1.0
[/CIF]
.
The material structure described by Ba2MgAg2CuF14 crystallizes in the triclinic P-1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(13), one F(14), one F(4), one F(8), one F(9), two equivalent F(2), and two equivalent F(3) atoms. In the second Ba site, Ba(2) is bonded in a 10-coordinate geometry to one F(11), one F(12), one F(14), one F(5), one F(7), one F(8), two equivalent F(10), and two equivalent F(6) atoms. Mg(1) is bonded in a 6-coordinate geometry to one F(1), one F(11), one F(4), one F(5), one F(7), and one F(9) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one F(10), one F(12), one F(6), one F(7), one F(8), and one F(9) atom to form AgF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 51-66°. In the second Ag site, Ag(2) is bonded to one F(1), one F(11), one F(13), one F(14), one F(2), and one F(3) atom to form AgF6 octahedra that share corners with two equivalent Cu(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent F(12), two equivalent F(5), and two equivalent F(6) atoms to form distorted CuF6 octahedra that share corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 51-66°. In the second Cu site, Cu(2) is bonded to two equivalent F(13), two equivalent F(2), and two equivalent F(4) atoms to form distorted CuF6 octahedra that share corners with four equivalent Ag(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Mg(1), and one Ag(2) atom. In the second F site, F(2) is bonded to two equivalent Ba(1), one Ag(2), and one Cu(2) atom to form a mixture of distorted edge and corner-sharing FBa2CuAg tetrahedra. In the third F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Mg(1), and one Cu(2) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Ba(2), one Mg(1), and one Cu(1) atom. In the sixth F site, F(6) is bonded to two equivalent Ba(2), one Ag(1), and one Cu(1) atom to form a mixture of distorted edge and corner-sharing FBa2CuAg tetrahedra. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Ba(2), one Mg(1), and one Ag(1) atom. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Ba(1), one Ba(2), and one Ag(1) atom. In the ninth F site, F(9) is bonded in a 2-coordinate geometry to one Ba(1), one Mg(1), and one Ag(1) atom. In the tenth F site, F(10) is bonded in a 3-coordinate geometry to two equivalent Ba(2) and one Ag(1) atom. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Ba(2), one Mg(1), and one Ag(2) atom. In the twelfth F site, F(12) is bonded in a distorted bent 120 degrees geometry to one Ba(2), one Ag(1), and one Cu(1) atom. In the thirteenth F site, F(13) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(2), and one Cu(2) atom. In the fourteenth F site, F(14) is bonded in a 3-coordinate geometry to one Ba(1), one Ba(2), and one Ag(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba2MgCuAg2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.372
_cell_length_b   7.657
_cell_length_c   15.282
_cell_angle_alpha   91.525
_cell_angle_beta   89.622
_cell_angle_gamma   110.461
_symmetry_Int_Tables_number   1
_cell_volume   588.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.726  0.630  0.374  1.0
  Ba  Ba1  1  0.902  0.630  0.875  1.0
  Ba  Ba2  1  0.274  0.370  0.626  1.0
  Ba  Ba3  1  0.098  0.370  0.125  1.0
  Mg  Mg4  1  0.429  0.002  0.248  1.0
  Mg  Mg5  1  0.571  0.998  0.752  1.0
  Cu  Cu6  1  0.500  0.000  0.000  1.0
  Cu  Cu7  1  0.500  0.000  0.500  1.0
  Ag  Ag8  1  0.855  0.766  0.128  1.0
  Ag  Ag9  1  0.145  0.234  0.872  1.0
  Ag  Ag10  1  0.908  0.767  0.628  1.0
  Ag  Ag11  1  0.092  0.233  0.372  1.0
  F  F12  1  0.878  0.028  0.667  1.0
  F  F13  1  0.580  0.717  0.541  1.0
  F  F14  1  0.420  0.283  0.459  1.0
  F  F15  1  0.134  0.511  0.403  1.0
  F  F16  1  0.533  0.914  0.386  1.0
  F  F17  1  0.617  0.084  0.114  1.0
  F  F18  1  0.135  0.716  0.041  1.0
  F  F19  1  0.861  0.972  0.834  1.0
  F  F20  1  0.027  0.654  0.228  1.0
  F  F21  1  0.866  0.489  0.597  1.0
  F  F22  1  0.567  0.792  0.223  1.0
  F  F23  1  0.627  0.488  0.096  1.0
  F  F24  1  0.218  0.789  0.723  1.0
  F  F25  1  0.433  0.208  0.777  1.0
  F  F26  1  0.383  0.916  0.886  1.0
  F  F27  1  0.973  0.346  0.772  1.0
  F  F28  1  0.293  0.150  0.990  1.0
  F  F29  1  0.122  0.972  0.333  1.0
  F  F30  1  0.707  0.850  0.010  1.0
  F  F31  1  0.853  0.151  0.491  1.0
  F  F32  1  0.865  0.284  0.959  1.0
  F  F33  1  0.782  0.211  0.277  1.0
  F  F34  1  0.623  0.658  0.730  1.0
  F  F35  1  0.147  0.849  0.509  1.0
  F  F36  1  0.467  0.086  0.614  1.0
  F  F37  1  0.139  0.028  0.166  1.0
  F  F38  1  0.377  0.342  0.270  1.0
  F  F39  1  0.373  0.512  0.904  1.0
[/CIF]
.