The compound described by PtCl6N2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of eight ammonia atoms and four PtCl6 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to six equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt(NCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.805
_cell_length_b   6.805
_cell_length_c   6.805
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   222.833
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.750  0.750  0.750  1.0
  N  N2  1  0.250  0.250  0.250  1.0
  Cl  Cl3  1  0.759  0.759  0.241  1.0
  Cl  Cl4  1  0.241  0.759  0.241  1.0
  Cl  Cl5  1  0.759  0.241  0.241  1.0
  Cl  Cl6  1  0.241  0.241  0.759  1.0
  Cl  Cl7  1  0.759  0.241  0.759  1.0
  Cl  Cl8  1  0.241  0.759  0.759  1.0
[/CIF]
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The compound described by PtCl6N2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of eight ammonia atoms and four PtCl6 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to six equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt(NCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.805
_cell_length_b   6.805
_cell_length_c   6.805
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   222.833
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.750  0.750  0.750  1.0
  N  N2  1  0.250  0.250  0.250  1.0
  Cl  Cl3  1  0.759  0.759  0.241  1.0
  Cl  Cl4  1  0.241  0.759  0.241  1.0
  Cl  Cl5  1  0.759  0.241  0.241  1.0
  Cl  Cl6  1  0.241  0.241  0.759  1.0
  Cl  Cl7  1  0.759  0.241  0.759  1.0
  Cl  Cl8  1  0.241  0.759  0.759  1.0
[/CIF]
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