The material described by KLiSb3O8 crystallizes in the triclinic P1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one K(3), one O(12), one O(13), one O(14), one O(18), one O(22), one O(3), and one O(9) atom. In the second K site, K(2) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(15), and one O(2) atom. In the third K site, K(3) is bonded in a 6-coordinate geometry to one K(1), one O(10), one O(12), one O(13), one O(23), and one O(7) atom. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted single-bond geometry to one O(20), one O(3), and one O(9) atom. In the second Li site, Li(2) is bonded in a 1-coordinate geometry to one Sb(4), one O(19), one O(23), and one O(24) atom. In the third Li site, Li(3) is bonded in a distorted single-bond geometry to one Sb(6), one O(15), one O(21), and one O(8) atom. There are nine inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(17), one O(20), and one O(4) atom. In the second Sb site, Sb(2) is bonded in a 4-coordinate geometry to one O(1), one O(18), one O(3), and one O(7) atom. In the third Sb site, Sb(3) is bonded in a 5-coordinate geometry to one O(16), one O(17), one O(2), one O(23), and one O(5) atom. In the fourth Sb site, Sb(4) is bonded in a 6-coordinate geometry to one Li(2), one O(19), one O(2), one O(22), one O(23), and one O(8) atom. In the fifth Sb site, Sb(5) is bonded in a 3-coordinate geometry to one O(14), one O(5), one O(6), and one O(9) atom. In the sixth Sb site, Sb(6) is bonded in a 5-coordinate geometry to one Li(3), one O(12), one O(14), one O(15), and one O(6) atom. In the seventh Sb site, Sb(7) is bonded in a 5-coordinate geometry to one Sb(8), one O(19), one O(20), one O(22), and one O(8) atom. In the eighth Sb site, Sb(8) is bonded in a distorted single-bond geometry to one Sb(7), one O(10), one O(12), and one O(20) atom. In the ninth Sb site, Sb(9) is bonded in a 4-coordinate geometry to one O(1), one O(17), one O(3), and one O(6) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one K(2), one Sb(2), and one Sb(9) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), one Sb(3), and one Sb(4) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), one Li(1), one Sb(2), and one Sb(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sb(3) and one Sb(5) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Sb(5), one Sb(6), and one Sb(9) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(3) and one Sb(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(3), one Sb(4), and one Sb(7) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one K(1), one Li(1), and one Sb(5) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one K(3) and one Sb(8) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one K(2) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one K(1), one K(3), one Sb(1), one Sb(6), and one Sb(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one K(1) and one K(3) atom. In the fourteenth O site, O(14) is bonded in a 1-coordinate geometry to one K(1), one Sb(5), and one Sb(6) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one K(2), one Li(3), one Sb(1), and one Sb(6) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Sb(3) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Sb(1), one Sb(3), and one Sb(9) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one K(1) and one Sb(2) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(2), one Sb(4), and one Sb(7) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Li(1), one Sb(1), one Sb(7), and one Sb(8) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Li(3) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one K(1), one Sb(4), and one Sb(7) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one K(3), one Li(2), one Sb(3), and one Sb(4) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one Li(2) atom. is represented by the CIF file [CIF]
data_KLiSb3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.804
_cell_length_b   8.807
_cell_length_c   8.965
_cell_angle_alpha   108.197
_cell_angle_beta   107.473
_cell_angle_gamma   112.082
_symmetry_Int_Tables_number   1
_cell_volume   538.627
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.951  0.912  0.929  1.0
  K  K1  1  0.478  0.473  0.017  1.0
  K  K2  1  0.091  0.081  0.039  1.0
  Li  Li3  1  0.812  0.608  0.543  1.0
  Li  Li4  1  0.428  0.223  0.542  1.0
  Li  Li5  1  0.451  0.970  0.747  1.0
  Sb  Sb6  1  0.671  0.153  0.166  1.0
  Sb  Sb7  1  0.556  0.673  0.478  1.0
  Sb  Sb8  1  0.129  0.317  0.517  1.0
  Sb  Sb9  1  0.186  0.001  0.492  1.0
  Sb  Sb10  1  0.000  0.509  0.824  1.0
  Sb  Sb11  1  0.682  0.190  0.824  1.0
  Sb  Sb12  1  0.035  0.674  0.318  1.0
  Sb  Sb13  1  0.010  0.492  0.166  1.0
  Sb  Sb14  1  0.792  0.980  0.518  1.0
  O  O15  1  0.485  0.763  0.347  1.0
  O  O16  1  0.172  0.222  0.635  1.0
  O  O17  1  0.816  0.875  0.657  1.0
  O  O18  1  0.585  0.207  0.290  1.0
  O  O19  1  0.066  0.430  0.722  1.0
  O  O20  1  0.784  0.178  0.689  1.0
  O  O21  1  0.446  0.407  0.365  1.0
  O  O22  1  0.164  0.869  0.640  1.0
  O  O23  1  0.874  0.578  0.640  1.0
  O  O24  1  0.051  0.410  0.067  1.0
  O  O25  1  0.432  0.766  0.025  1.0
  O  O26  1  0.821  0.156  0.025  1.0
  O  O27  1  0.264  0.917  0.953  1.0
  O  O28  1  0.883  0.537  0.954  1.0
  O  O29  1  0.575  0.206  0.960  1.0
  O  O30  1  0.053  0.373  0.412  1.0
  O  O31  1  0.857  0.135  0.348  1.0
  O  O32  1  0.533  0.583  0.635  1.0
  O  O33  1  0.259  0.896  0.309  1.0
  O  O34  1  0.842  0.480  0.307  1.0
  O  O35  1  0.417  0.812  0.689  1.0
  O  O36  1  0.958  0.874  0.277  1.0
  O  O37  1  0.161  0.123  0.365  1.0
  O  O38  1  0.618  0.331  0.571  1.0
[/CIF]
.
The material described by KLiSb3O8 crystallizes in the triclinic P1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one K(3), one O(12), one O(13), one O(14), one O(18), one O(22), one O(3), and one O(9) atom. In the second K site, K(2) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(15), and one O(2) atom. In the third K site, K(3) is bonded in a 6-coordinate geometry to one K(1), one O(10), one O(12), one O(13), one O(23), and one O(7) atom. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted single-bond geometry to one O(20), one O(3), and one O(9) atom. In the second Li site, Li(2) is bonded in a 1-coordinate geometry to one Sb(4), one O(19), one O(23), and one O(24) atom. In the third Li site, Li(3) is bonded in a distorted single-bond geometry to one Sb(6), one O(15), one O(21), and one O(8) atom. There are nine inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(17), one O(20), and one O(4) atom. In the second Sb site, Sb(2) is bonded in a 4-coordinate geometry to one O(1), one O(18), one O(3), and one O(7) atom. In the third Sb site, Sb(3) is bonded in a 5-coordinate geometry to one O(16), one O(17), one O(2), one O(23), and one O(5) atom. In the fourth Sb site, Sb(4) is bonded in a 6-coordinate geometry to one Li(2), one O(19), one O(2), one O(22), one O(23), and one O(8) atom. In the fifth Sb site, Sb(5) is bonded in a 3-coordinate geometry to one O(14), one O(5), one O(6), and one O(9) atom. In the sixth Sb site, Sb(6) is bonded in a 5-coordinate geometry to one Li(3), one O(12), one O(14), one O(15), and one O(6) atom. In the seventh Sb site, Sb(7) is bonded in a 5-coordinate geometry to one Sb(8), one O(19), one O(20), one O(22), and one O(8) atom. In the eighth Sb site, Sb(8) is bonded in a distorted single-bond geometry to one Sb(7), one O(10), one O(12), and one O(20) atom. In the ninth Sb site, Sb(9) is bonded in a 4-coordinate geometry to one O(1), one O(17), one O(3), and one O(6) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one K(2), one Sb(2), and one Sb(9) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), one Sb(3), and one Sb(4) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), one Li(1), one Sb(2), and one Sb(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sb(3) and one Sb(5) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Sb(5), one Sb(6), and one Sb(9) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(3) and one Sb(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(3), one Sb(4), and one Sb(7) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one K(1), one Li(1), and one Sb(5) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one K(3) and one Sb(8) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one K(2) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one K(1), one K(3), one Sb(1), one Sb(6), and one Sb(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one K(1) and one K(3) atom. In the fourteenth O site, O(14) is bonded in a 1-coordinate geometry to one K(1), one Sb(5), and one Sb(6) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one K(2), one Li(3), one Sb(1), and one Sb(6) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Sb(3) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Sb(1), one Sb(3), and one Sb(9) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one K(1) and one Sb(2) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(2), one Sb(4), and one Sb(7) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Li(1), one Sb(1), one Sb(7), and one Sb(8) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Li(3) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one K(1), one Sb(4), and one Sb(7) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one K(3), one Li(2), one Sb(3), and one Sb(4) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one Li(2) atom. is represented by the CIF file [CIF]
data_KLiSb3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.804
_cell_length_b   8.807
_cell_length_c   8.965
_cell_angle_alpha   108.197
_cell_angle_beta   107.473
_cell_angle_gamma   112.082
_symmetry_Int_Tables_number   1
_cell_volume   538.627
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.951  0.912  0.929  1.0
  K  K1  1  0.478  0.473  0.017  1.0
  K  K2  1  0.091  0.081  0.039  1.0
  Li  Li3  1  0.812  0.608  0.543  1.0
  Li  Li4  1  0.428  0.223  0.542  1.0
  Li  Li5  1  0.451  0.970  0.747  1.0
  Sb  Sb6  1  0.671  0.153  0.166  1.0
  Sb  Sb7  1  0.556  0.673  0.478  1.0
  Sb  Sb8  1  0.129  0.317  0.517  1.0
  Sb  Sb9  1  0.186  0.001  0.492  1.0
  Sb  Sb10  1  0.000  0.509  0.824  1.0
  Sb  Sb11  1  0.682  0.190  0.824  1.0
  Sb  Sb12  1  0.035  0.674  0.318  1.0
  Sb  Sb13  1  0.010  0.492  0.166  1.0
  Sb  Sb14  1  0.792  0.980  0.518  1.0
  O  O15  1  0.485  0.763  0.347  1.0
  O  O16  1  0.172  0.222  0.635  1.0
  O  O17  1  0.816  0.875  0.657  1.0
  O  O18  1  0.585  0.207  0.290  1.0
  O  O19  1  0.066  0.430  0.722  1.0
  O  O20  1  0.784  0.178  0.689  1.0
  O  O21  1  0.446  0.407  0.365  1.0
  O  O22  1  0.164  0.869  0.640  1.0
  O  O23  1  0.874  0.578  0.640  1.0
  O  O24  1  0.051  0.410  0.067  1.0
  O  O25  1  0.432  0.766  0.025  1.0
  O  O26  1  0.821  0.156  0.025  1.0
  O  O27  1  0.264  0.917  0.953  1.0
  O  O28  1  0.883  0.537  0.954  1.0
  O  O29  1  0.575  0.206  0.960  1.0
  O  O30  1  0.053  0.373  0.412  1.0
  O  O31  1  0.857  0.135  0.348  1.0
  O  O32  1  0.533  0.583  0.635  1.0
  O  O33  1  0.259  0.896  0.309  1.0
  O  O34  1  0.842  0.480  0.307  1.0
  O  O35  1  0.417  0.812  0.689  1.0
  O  O36  1  0.958  0.874  0.277  1.0
  O  O37  1  0.161  0.123  0.365  1.0
  O  O38  1  0.618  0.331  0.571  1.0
[/CIF]
.