The material described by Na3Co(Mo3O16)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(13), one O(16), two equivalent O(14), and two equivalent O(7) atoms. In the second Na site, Na(2) is bonded in a distorted octahedral geometry to two equivalent O(11), two equivalent O(12), and two equivalent O(8) atoms. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(6), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Mo(1), one Mo(2), and one Co(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Co(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one Mo(3), and one Co(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to two equivalent Na(1) and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Na(2) and one Mo(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Mo(2) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Mo(2) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one Na(2) and one Mo(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Na(2) and one Mo(3) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Na(1) and one O(15) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one O(14) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one O(13) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Na(1) atom. is represented by the CIF card [CIF]
data_Na3Co(Mo3O16)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.897
_cell_length_b   10.974
_cell_length_c   11.371
_cell_angle_alpha   113.272
_cell_angle_beta   107.518
_cell_angle_gamma   93.764
_symmetry_Int_Tables_number   1
_cell_volume   736.944
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.643  0.592  0.451  1.0
  Na  Na1  1  0.357  0.408  0.549  1.0
  Na  Na2  1  0.500  0.500  0.000  1.0
  Co  Co3  1  0.000  0.000  0.000  1.0
  Mo  Mo4  1  0.623  0.719  0.821  1.0
  Mo  Mo5  1  0.377  0.281  0.179  1.0
  Mo  Mo6  1  0.561  0.985  0.739  1.0
  Mo  Mo7  1  0.439  0.015  0.261  1.0
  Mo  Mo8  1  0.938  0.264  0.914  1.0
  Mo  Mo9  1  0.062  0.736  0.086  1.0
  O  O10  1  0.879  0.902  0.821  1.0
  O  O11  1  0.121  0.098  0.179  1.0
  O  O12  1  0.835  0.867  0.019  1.0
  O  O13  1  0.165  0.133  0.981  1.0
  O  O14  1  0.790  0.089  0.952  1.0
  O  O15  1  0.210  0.911  0.048  1.0
  O  O16  1  0.480  0.857  0.809  1.0
  O  O17  1  0.520  0.143  0.191  1.0
  O  O18  1  0.900  0.678  0.888  1.0
  O  O19  1  0.100  0.322  0.112  1.0
  O  O20  1  0.781  0.110  0.743  1.0
  O  O21  1  0.219  0.890  0.257  1.0
  O  O22  1  0.585  0.619  0.646  1.0
  O  O23  1  0.415  0.381  0.354  1.0
  O  O24  1  0.467  0.620  0.859  1.0
  O  O25  1  0.533  0.380  0.141  1.0
  O  O26  1  0.488  0.866  0.567  1.0
  O  O27  1  0.512  0.134  0.433  1.0
  O  O28  1  0.367  0.075  0.751  1.0
  O  O29  1  0.633  0.925  0.249  1.0
  O  O30  1  0.757  0.367  0.934  1.0
  O  O31  1  0.243  0.633  0.066  1.0
  O  O32  1  0.116  0.338  0.868  1.0
  O  O33  1  0.884  0.662  0.132  1.0
  O  O34  1  0.010  0.218  0.450  1.0
  O  O35  1  0.990  0.782  0.550  1.0
  O  O36  1  0.988  0.479  0.542  1.0
  O  O37  1  0.012  0.521  0.458  1.0
  O  O38  1  0.003  0.853  0.491  1.0
  O  O39  1  0.997  0.147  0.509  1.0
  O  O40  1  0.514  0.746  0.371  1.0
  O  O41  1  0.486  0.254  0.629  1.0
[/CIF]
.
The material described by Na3Co(Mo3O16)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(13), one O(16), two equivalent O(14), and two equivalent O(7) atoms. In the second Na site, Na(2) is bonded in a distorted octahedral geometry to two equivalent O(11), two equivalent O(12), and two equivalent O(8) atoms. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(6), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Mo(1), one Mo(2), and one Co(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Co(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one Mo(3), and one Co(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to two equivalent Na(1) and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Na(2) and one Mo(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Mo(2) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Mo(2) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one Na(2) and one Mo(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Na(2) and one Mo(3) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Na(1) and one O(15) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one O(14) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one O(13) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Na(1) atom. is represented by the CIF card [CIF]
data_Na3Co(Mo3O16)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.897
_cell_length_b   10.974
_cell_length_c   11.371
_cell_angle_alpha   113.272
_cell_angle_beta   107.518
_cell_angle_gamma   93.764
_symmetry_Int_Tables_number   1
_cell_volume   736.944
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.643  0.592  0.451  1.0
  Na  Na1  1  0.357  0.408  0.549  1.0
  Na  Na2  1  0.500  0.500  0.000  1.0
  Co  Co3  1  0.000  0.000  0.000  1.0
  Mo  Mo4  1  0.623  0.719  0.821  1.0
  Mo  Mo5  1  0.377  0.281  0.179  1.0
  Mo  Mo6  1  0.561  0.985  0.739  1.0
  Mo  Mo7  1  0.439  0.015  0.261  1.0
  Mo  Mo8  1  0.938  0.264  0.914  1.0
  Mo  Mo9  1  0.062  0.736  0.086  1.0
  O  O10  1  0.879  0.902  0.821  1.0
  O  O11  1  0.121  0.098  0.179  1.0
  O  O12  1  0.835  0.867  0.019  1.0
  O  O13  1  0.165  0.133  0.981  1.0
  O  O14  1  0.790  0.089  0.952  1.0
  O  O15  1  0.210  0.911  0.048  1.0
  O  O16  1  0.480  0.857  0.809  1.0
  O  O17  1  0.520  0.143  0.191  1.0
  O  O18  1  0.900  0.678  0.888  1.0
  O  O19  1  0.100  0.322  0.112  1.0
  O  O20  1  0.781  0.110  0.743  1.0
  O  O21  1  0.219  0.890  0.257  1.0
  O  O22  1  0.585  0.619  0.646  1.0
  O  O23  1  0.415  0.381  0.354  1.0
  O  O24  1  0.467  0.620  0.859  1.0
  O  O25  1  0.533  0.380  0.141  1.0
  O  O26  1  0.488  0.866  0.567  1.0
  O  O27  1  0.512  0.134  0.433  1.0
  O  O28  1  0.367  0.075  0.751  1.0
  O  O29  1  0.633  0.925  0.249  1.0
  O  O30  1  0.757  0.367  0.934  1.0
  O  O31  1  0.243  0.633  0.066  1.0
  O  O32  1  0.116  0.338  0.868  1.0
  O  O33  1  0.884  0.662  0.132  1.0
  O  O34  1  0.010  0.218  0.450  1.0
  O  O35  1  0.990  0.782  0.550  1.0
  O  O36  1  0.988  0.479  0.542  1.0
  O  O37  1  0.012  0.521  0.458  1.0
  O  O38  1  0.003  0.853  0.491  1.0
  O  O39  1  0.997  0.147  0.509  1.0
  O  O40  1  0.514  0.746  0.371  1.0
  O  O41  1  0.486  0.254  0.629  1.0
[/CIF]
.