The compound described by Ho5PdBi2 crystallizes in the orthorhombic Pnma space group. There are four inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 5-coordinate geometry to one Pd(1) and four equivalent Bi(1) atoms. In the second Ho site, Ho(2) is bonded to one Pd(1) and four equivalent Bi(1) atoms to form distorted edge-sharing HoBi4Pd square pyramids. In the third Ho site, Ho(3) is bonded in a 5-coordinate geometry to one Pd(1) and four equivalent Bi(1) atoms. In the fourth Ho site, Ho(4) is bonded in a 5-coordinate geometry to two equivalent Pd(1) and three equivalent Bi(1) atoms. Pd(1) is bonded in a 7-coordinate geometry to one Ho(1), one Ho(2), one Ho(3), and four equivalent Ho(4) atoms. Bi(1) is bonded in a 9-coordinate geometry to two equivalent Ho(1), two equivalent Ho(2), two equivalent Ho(3), and three equivalent Ho(4) atoms. is represented by the CIF file [CIF]
data_Ho5Bi2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.026
_cell_length_b   9.050
_cell_length_c   12.298
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   893.164
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.166  0.750  0.213  1.0
  Ho  Ho1  1  0.334  0.750  0.713  1.0
  Ho  Ho2  1  0.834  0.250  0.787  1.0
  Ho  Ho3  1  0.666  0.250  0.287  1.0
  Ho  Ho4  1  0.459  0.750  0.000  1.0
  Ho  Ho5  1  0.041  0.750  0.500  1.0
  Ho  Ho6  1  0.541  0.250  1.000  1.0
  Ho  Ho7  1  0.959  0.250  0.500  1.0
  Ho  Ho8  1  0.631  0.750  0.303  1.0
  Ho  Ho9  1  0.869  0.750  0.803  1.0
  Ho  Ho10  1  0.369  0.250  0.697  1.0
  Ho  Ho11  1  0.131  0.250  0.197  1.0
  Ho  Ho12  1  0.821  0.551  0.067  1.0
  Ho  Ho13  1  0.679  0.949  0.567  1.0
  Ho  Ho14  1  0.179  0.051  0.933  1.0
  Ho  Ho15  1  0.321  0.449  0.433  1.0
  Ho  Ho16  1  0.179  0.449  0.933  1.0
  Ho  Ho17  1  0.321  0.051  0.433  1.0
  Ho  Ho18  1  0.821  0.949  0.067  1.0
  Ho  Ho19  1  0.679  0.551  0.567  1.0
  Bi  Bi20  1  0.932  0.508  0.327  1.0
  Bi  Bi21  1  0.568  0.992  0.827  1.0
  Bi  Bi22  1  0.068  0.008  0.673  1.0
  Bi  Bi23  1  0.432  0.492  0.173  1.0
  Bi  Bi24  1  0.068  0.492  0.673  1.0
  Bi  Bi25  1  0.432  0.008  0.173  1.0
  Bi  Bi26  1  0.932  0.992  0.327  1.0
  Bi  Bi27  1  0.568  0.508  0.827  1.0
  Pd  Pd28  1  0.412  0.750  0.486  1.0
  Pd  Pd29  1  0.088  0.750  0.986  1.0
  Pd  Pd30  1  0.588  0.250  0.514  1.0
  Pd  Pd31  1  0.912  0.250  0.014  1.0
[/CIF]
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The compound described by Ho5PdBi2 crystallizes in the orthorhombic Pnma space group. There are four inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 5-coordinate geometry to one Pd(1) and four equivalent Bi(1) atoms. In the second Ho site, Ho(2) is bonded to one Pd(1) and four equivalent Bi(1) atoms to form distorted edge-sharing HoBi4Pd square pyramids. In the third Ho site, Ho(3) is bonded in a 5-coordinate geometry to one Pd(1) and four equivalent Bi(1) atoms. In the fourth Ho site, Ho(4) is bonded in a 5-coordinate geometry to two equivalent Pd(1) and three equivalent Bi(1) atoms. Pd(1) is bonded in a 7-coordinate geometry to one Ho(1), one Ho(2), one Ho(3), and four equivalent Ho(4) atoms. Bi(1) is bonded in a 9-coordinate geometry to two equivalent Ho(1), two equivalent Ho(2), two equivalent Ho(3), and three equivalent Ho(4) atoms. is represented by the CIF file [CIF]
data_Ho5Bi2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.026
_cell_length_b   9.050
_cell_length_c   12.298
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   893.164
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.166  0.750  0.213  1.0
  Ho  Ho1  1  0.334  0.750  0.713  1.0
  Ho  Ho2  1  0.834  0.250  0.787  1.0
  Ho  Ho3  1  0.666  0.250  0.287  1.0
  Ho  Ho4  1  0.459  0.750  0.000  1.0
  Ho  Ho5  1  0.041  0.750  0.500  1.0
  Ho  Ho6  1  0.541  0.250  1.000  1.0
  Ho  Ho7  1  0.959  0.250  0.500  1.0
  Ho  Ho8  1  0.631  0.750  0.303  1.0
  Ho  Ho9  1  0.869  0.750  0.803  1.0
  Ho  Ho10  1  0.369  0.250  0.697  1.0
  Ho  Ho11  1  0.131  0.250  0.197  1.0
  Ho  Ho12  1  0.821  0.551  0.067  1.0
  Ho  Ho13  1  0.679  0.949  0.567  1.0
  Ho  Ho14  1  0.179  0.051  0.933  1.0
  Ho  Ho15  1  0.321  0.449  0.433  1.0
  Ho  Ho16  1  0.179  0.449  0.933  1.0
  Ho  Ho17  1  0.321  0.051  0.433  1.0
  Ho  Ho18  1  0.821  0.949  0.067  1.0
  Ho  Ho19  1  0.679  0.551  0.567  1.0
  Bi  Bi20  1  0.932  0.508  0.327  1.0
  Bi  Bi21  1  0.568  0.992  0.827  1.0
  Bi  Bi22  1  0.068  0.008  0.673  1.0
  Bi  Bi23  1  0.432  0.492  0.173  1.0
  Bi  Bi24  1  0.068  0.492  0.673  1.0
  Bi  Bi25  1  0.432  0.008  0.173  1.0
  Bi  Bi26  1  0.932  0.992  0.327  1.0
  Bi  Bi27  1  0.568  0.508  0.827  1.0
  Pd  Pd28  1  0.412  0.750  0.486  1.0
  Pd  Pd29  1  0.088  0.750  0.986  1.0
  Pd  Pd30  1  0.588  0.250  0.514  1.0
  Pd  Pd31  1  0.912  0.250  0.014  1.0
[/CIF]
.