The compound described by MoAgAsO6 crystallizes in the orthorhombic P2_12_12_1 space group. Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted MoO6 octahedra that share corners with four equivalent As(1)O4 tetrahedra. Ag(1) is bonded in a 4-coordinate geometry to one O(4), one O(6), and two equivalent O(3) atoms. As(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form AsO4 tetrahedra that share corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-60°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one As(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one As(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one As(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Ag(1) atoms. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one Ag(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one As(1) atom. is represented by the CIF card [CIF]
data_AgMoAsO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.649
_cell_length_b   7.339
_cell_length_c   10.332
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   504.132
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.520  0.806  0.506  1.0
  Ag  Ag1  1  0.980  0.194  0.006  1.0
  Ag  Ag2  1  0.020  0.694  0.494  1.0
  Ag  Ag3  1  0.480  0.306  0.994  1.0
  Mo  Mo4  1  0.252  0.801  0.830  1.0
  Mo  Mo5  1  0.248  0.199  0.330  1.0
  Mo  Mo6  1  0.752  0.699  0.170  1.0
  Mo  Mo7  1  0.748  0.301  0.670  1.0
  As  As8  1  0.250  0.213  0.659  1.0
  As  As9  1  0.250  0.787  0.159  1.0
  As  As10  1  0.750  0.287  0.341  1.0
  As  As11  1  0.750  0.713  0.841  1.0
  O  O12  1  0.545  0.858  0.842  1.0
  O  O13  1  0.955  0.142  0.342  1.0
  O  O14  1  0.045  0.642  0.158  1.0
  O  O15  1  0.455  0.358  0.658  1.0
  O  O16  1  0.456  0.642  0.157  1.0
  O  O17  1  0.044  0.358  0.657  1.0
  O  O18  1  0.956  0.858  0.843  1.0
  O  O19  1  0.544  0.142  0.343  1.0
  O  O20  1  0.251  0.752  0.662  1.0
  O  O21  1  0.249  0.248  0.162  1.0
  O  O22  1  0.751  0.748  0.338  1.0
  O  O23  1  0.749  0.252  0.838  1.0
  O  O24  1  0.255  0.584  0.898  1.0
  O  O25  1  0.245  0.416  0.398  1.0
  O  O26  1  0.755  0.916  0.102  1.0
  O  O27  1  0.745  0.084  0.602  1.0
  O  O28  1  0.250  0.100  0.804  1.0
  O  O29  1  0.250  0.900  0.304  1.0
  O  O30  1  0.750  0.400  0.196  1.0
  O  O31  1  0.750  0.600  0.696  1.0
  O  O32  1  0.254  0.075  0.525  1.0
  O  O33  1  0.246  0.925  0.025  1.0
  O  O34  1  0.754  0.425  0.475  1.0
  O  O35  1  0.746  0.575  0.975  1.0
[/CIF]
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The compound described by MoAgAsO6 crystallizes in the orthorhombic P2_12_12_1 space group. Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted MoO6 octahedra that share corners with four equivalent As(1)O4 tetrahedra. Ag(1) is bonded in a 4-coordinate geometry to one O(4), one O(6), and two equivalent O(3) atoms. As(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form AsO4 tetrahedra that share corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-60°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one As(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one As(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one As(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Ag(1) atoms. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one Ag(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one As(1) atom. is represented by the CIF card [CIF]
data_AgMoAsO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.649
_cell_length_b   7.339
_cell_length_c   10.332
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   504.132
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.520  0.806  0.506  1.0
  Ag  Ag1  1  0.980  0.194  0.006  1.0
  Ag  Ag2  1  0.020  0.694  0.494  1.0
  Ag  Ag3  1  0.480  0.306  0.994  1.0
  Mo  Mo4  1  0.252  0.801  0.830  1.0
  Mo  Mo5  1  0.248  0.199  0.330  1.0
  Mo  Mo6  1  0.752  0.699  0.170  1.0
  Mo  Mo7  1  0.748  0.301  0.670  1.0
  As  As8  1  0.250  0.213  0.659  1.0
  As  As9  1  0.250  0.787  0.159  1.0
  As  As10  1  0.750  0.287  0.341  1.0
  As  As11  1  0.750  0.713  0.841  1.0
  O  O12  1  0.545  0.858  0.842  1.0
  O  O13  1  0.955  0.142  0.342  1.0
  O  O14  1  0.045  0.642  0.158  1.0
  O  O15  1  0.455  0.358  0.658  1.0
  O  O16  1  0.456  0.642  0.157  1.0
  O  O17  1  0.044  0.358  0.657  1.0
  O  O18  1  0.956  0.858  0.843  1.0
  O  O19  1  0.544  0.142  0.343  1.0
  O  O20  1  0.251  0.752  0.662  1.0
  O  O21  1  0.249  0.248  0.162  1.0
  O  O22  1  0.751  0.748  0.338  1.0
  O  O23  1  0.749  0.252  0.838  1.0
  O  O24  1  0.255  0.584  0.898  1.0
  O  O25  1  0.245  0.416  0.398  1.0
  O  O26  1  0.755  0.916  0.102  1.0
  O  O27  1  0.745  0.084  0.602  1.0
  O  O28  1  0.250  0.100  0.804  1.0
  O  O29  1  0.250  0.900  0.304  1.0
  O  O30  1  0.750  0.400  0.196  1.0
  O  O31  1  0.750  0.600  0.696  1.0
  O  O32  1  0.254  0.075  0.525  1.0
  O  O33  1  0.246  0.925  0.025  1.0
  O  O34  1  0.754  0.425  0.475  1.0
  O  O35  1  0.746  0.575  0.975  1.0
[/CIF]
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