The compound described by GaZn2V3O11 crystallizes in the triclinic P-1 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), and one O(7) atom to form VO4 tetrahedra that share corners with two equivalent Ga(1)O6 octahedra, corners with two equivalent Zn(1)O5 trigonal bipyramids, and corners with three equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 59-66°. In the second V site, V(2) is bonded to one O(4), one O(5), one O(9), and two equivalent O(1) atoms to form distorted VO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with two equivalent Zn(2)O5 trigonal bipyramids, corners with three equivalent Zn(1)O5 trigonal bipyramids, and  an edgeedge with one V(2)O5 trigonal bipyramid. In the third V site, V(3) is bonded to one O(10), one O(6), one O(8), and one O(9) atom to form VO4 tetrahedra that share corners with four equivalent Ga(1)O6 octahedra,  a cornercorner with one V(2)O5 trigonal bipyramid, and  a cornercorner with one Zn(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 20-58°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), one O(5), one O(7), and one O(8) atom to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with three equivalent V(2)O5 trigonal bipyramids,  an edgeedge with one Ga(1)O6 octahedra, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. In the second Zn site, Zn(2) is bonded to one O(11), one O(2), one O(4), one O(5), and one O(7) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one Ga(1)O6 octahedra, corners with three equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O5 trigonal bipyramids, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 55°. Ga(1) is bonded to one O(11), one O(3), one O(6), one O(8), and two equivalent O(10) atoms to form GaO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with four equivalent V(3)O4 tetrahedra,  a cornercorner with one Zn(2)O5 trigonal bipyramid,  an edgeedge with one Ga(1)O6 octahedra, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a trigonal planar geometry to one V(1), one Zn(2), and one Ga(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(2) and one Zn(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(2) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one Zn(1), and one Ga(1) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one V(2) and one Zn(2) atom. In the sixth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one Zn(1), and one Zn(2) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one V(3) and one Ga(1) atom. In the eighth O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one Zn(1), and one Zn(2) atom. In the ninth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(3), one Zn(1), and one Ga(1) atom. In the tenth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the eleventh O site, O(10) is bonded in a 3-coordinate geometry to one V(3) and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_V3Zn2GaO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.569
_cell_length_b   6.932
_cell_length_c   10.019
_cell_angle_alpha   97.763
_cell_angle_beta   102.025
_cell_angle_gamma   101.319
_symmetry_Int_Tables_number   1
_cell_volume   430.144
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.173  0.486  0.290  1.0
  V  V1  1  0.827  0.514  0.710  1.0
  V  V2  1  0.803  0.926  0.384  1.0
  V  V3  1  0.197  0.074  0.616  1.0
  V  V4  1  0.745  0.823  0.025  1.0
  V  V5  1  0.255  0.177  0.975  1.0
  Zn  Zn6  1  0.283  0.004  0.279  1.0
  Zn  Zn7  1  0.717  0.996  0.721  1.0
  Zn  Zn8  1  0.675  0.376  0.335  1.0
  Zn  Zn9  1  0.325  0.624  0.665  1.0
  Ga  Ga10  1  0.190  0.675  0.004  1.0
  Ga  Ga11  1  0.810  0.325  0.996  1.0
  O  O12  1  0.886  0.994  0.578  1.0
  O  O13  1  0.114  0.006  0.422  1.0
  O  O14  1  0.195  0.570  0.457  1.0
  O  O15  1  0.805  0.430  0.543  1.0
  O  O16  1  0.243  0.700  0.214  1.0
  O  O17  1  0.757  0.300  0.786  1.0
  O  O18  1  0.691  0.683  0.357  1.0
  O  O19  1  0.309  0.317  0.643  1.0
  O  O20  1  0.607  0.064  0.349  1.0
  O  O21  1  0.393  0.936  0.651  1.0
  O  O22  1  0.481  0.714  0.997  1.0
  O  O23  1  0.519  0.286  0.003  1.0
  O  O24  1  0.345  0.318  0.279  1.0
  O  O25  1  0.655  0.682  0.721  1.0
  O  O26  1  0.216  0.969  0.061  1.0
  O  O27  1  0.784  0.031  0.939  1.0
  O  O28  1  0.851  0.925  0.195  1.0
  O  O29  1  0.149  0.075  0.805  1.0
  O  O30  1  0.876  0.623  0.987  1.0
  O  O31  1  0.124  0.377  0.013  1.0
  O  O32  1  0.109  0.628  0.789  1.0
  O  O33  1  0.891  0.372  0.211  1.0
[/CIF]
.
The compound described by GaZn2V3O11 crystallizes in the triclinic P-1 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), and one O(7) atom to form VO4 tetrahedra that share corners with two equivalent Ga(1)O6 octahedra, corners with two equivalent Zn(1)O5 trigonal bipyramids, and corners with three equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 59-66°. In the second V site, V(2) is bonded to one O(4), one O(5), one O(9), and two equivalent O(1) atoms to form distorted VO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with two equivalent Zn(2)O5 trigonal bipyramids, corners with three equivalent Zn(1)O5 trigonal bipyramids, and  an edgeedge with one V(2)O5 trigonal bipyramid. In the third V site, V(3) is bonded to one O(10), one O(6), one O(8), and one O(9) atom to form VO4 tetrahedra that share corners with four equivalent Ga(1)O6 octahedra,  a cornercorner with one V(2)O5 trigonal bipyramid, and  a cornercorner with one Zn(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 20-58°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), one O(5), one O(7), and one O(8) atom to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with three equivalent V(2)O5 trigonal bipyramids,  an edgeedge with one Ga(1)O6 octahedra, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. In the second Zn site, Zn(2) is bonded to one O(11), one O(2), one O(4), one O(5), and one O(7) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one Ga(1)O6 octahedra, corners with three equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O5 trigonal bipyramids, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 55°. Ga(1) is bonded to one O(11), one O(3), one O(6), one O(8), and two equivalent O(10) atoms to form GaO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with four equivalent V(3)O4 tetrahedra,  a cornercorner with one Zn(2)O5 trigonal bipyramid,  an edgeedge with one Ga(1)O6 octahedra, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a trigonal planar geometry to one V(1), one Zn(2), and one Ga(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(2) and one Zn(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(2) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one Zn(1), and one Ga(1) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one V(2) and one Zn(2) atom. In the sixth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one Zn(1), and one Zn(2) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one V(3) and one Ga(1) atom. In the eighth O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one Zn(1), and one Zn(2) atom. In the ninth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(3), one Zn(1), and one Ga(1) atom. In the tenth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the eleventh O site, O(10) is bonded in a 3-coordinate geometry to one V(3) and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_V3Zn2GaO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.569
_cell_length_b   6.932
_cell_length_c   10.019
_cell_angle_alpha   97.763
_cell_angle_beta   102.025
_cell_angle_gamma   101.319
_symmetry_Int_Tables_number   1
_cell_volume   430.144
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.173  0.486  0.290  1.0
  V  V1  1  0.827  0.514  0.710  1.0
  V  V2  1  0.803  0.926  0.384  1.0
  V  V3  1  0.197  0.074  0.616  1.0
  V  V4  1  0.745  0.823  0.025  1.0
  V  V5  1  0.255  0.177  0.975  1.0
  Zn  Zn6  1  0.283  0.004  0.279  1.0
  Zn  Zn7  1  0.717  0.996  0.721  1.0
  Zn  Zn8  1  0.675  0.376  0.335  1.0
  Zn  Zn9  1  0.325  0.624  0.665  1.0
  Ga  Ga10  1  0.190  0.675  0.004  1.0
  Ga  Ga11  1  0.810  0.325  0.996  1.0
  O  O12  1  0.886  0.994  0.578  1.0
  O  O13  1  0.114  0.006  0.422  1.0
  O  O14  1  0.195  0.570  0.457  1.0
  O  O15  1  0.805  0.430  0.543  1.0
  O  O16  1  0.243  0.700  0.214  1.0
  O  O17  1  0.757  0.300  0.786  1.0
  O  O18  1  0.691  0.683  0.357  1.0
  O  O19  1  0.309  0.317  0.643  1.0
  O  O20  1  0.607  0.064  0.349  1.0
  O  O21  1  0.393  0.936  0.651  1.0
  O  O22  1  0.481  0.714  0.997  1.0
  O  O23  1  0.519  0.286  0.003  1.0
  O  O24  1  0.345  0.318  0.279  1.0
  O  O25  1  0.655  0.682  0.721  1.0
  O  O26  1  0.216  0.969  0.061  1.0
  O  O27  1  0.784  0.031  0.939  1.0
  O  O28  1  0.851  0.925  0.195  1.0
  O  O29  1  0.149  0.075  0.805  1.0
  O  O30  1  0.876  0.623  0.987  1.0
  O  O31  1  0.124  0.377  0.013  1.0
  O  O32  1  0.109  0.628  0.789  1.0
  O  O33  1  0.891  0.372  0.211  1.0
[/CIF]
.