The structure described by Co3OF5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one F(10), one F(2), one F(3), one F(6), and one F(9) atom to form CoOF5 octahedra that share corners with two equivalent Co(2)OF5 octahedra, corners with three equivalent Co(3)OF5 octahedra, corners with three equivalent Co(6)OF5 octahedra,  an edgeedge with one Co(5)F6 octahedra, and  an edgeedge with one Co(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. In the second Co site, Co(2) is bonded to one O(1), one F(1), one F(3), one F(4), one F(6), and one F(8) atom to form CoOF5 octahedra that share corners with two equivalent Co(1)OF5 octahedra, corners with three equivalent Co(5)F6 octahedra, corners with three equivalent Co(4)O2F4 octahedra,  an edgeedge with one Co(3)OF5 octahedra, and  an edgeedge with one Co(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. In the third Co site, Co(3) is bonded to one O(1), one F(2), one F(3), one F(5), one F(7), and one F(9) atom to form CoOF5 octahedra that share corners with two equivalent Co(4)O2F4 octahedra, corners with three equivalent Co(5)F6 octahedra, corners with three equivalent Co(1)OF5 octahedra,  an edgeedge with one Co(2)OF5 octahedra, and  an edgeedge with one Co(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one F(1), one F(10), one F(5), and one F(8) atom to form CoO2F4 octahedra that share corners with two equivalent Co(3)OF5 octahedra, corners with three equivalent Co(2)OF5 octahedra, corners with three equivalent Co(6)OF5 octahedra,  an edgeedge with one Co(5)F6 octahedra, and  an edgeedge with one Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the fifth Co site, Co(5) is bonded to one F(1), one F(2), one F(4), one F(7), one F(8), and one F(9) atom to form CoF6 octahedra that share corners with two equivalent Co(6)OF5 octahedra, corners with three equivalent Co(2)OF5 octahedra, corners with three equivalent Co(3)OF5 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and  an edgeedge with one Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the sixth Co site, Co(6) is bonded to one O(2), one F(10), one F(4), one F(5), one F(6), and one F(7) atom to form CoOF5 octahedra that share corners with two equivalent Co(5)F6 octahedra, corners with three equivalent Co(4)O2F4 octahedra, corners with three equivalent Co(1)OF5 octahedra,  an edgeedge with one Co(2)OF5 octahedra, and  an edgeedge with one Co(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Co(2), one Co(3), and one Co(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(4), and one Co(6) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Co(2), one Co(4), and one Co(5) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(5) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one Co(3) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Co(2), one Co(5), and one Co(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(4), and one Co(6) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(6) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Co(3), one Co(5), and one Co(6) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Co(2), one Co(4), and one Co(5) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(5) atom. In the tenth F site, F(10) is bonded in a distorted T-shaped geometry to one Co(1), one Co(4), and one Co(6) atom. is represented by the CIF card [CIF]
data_Co3OF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.660
_cell_length_b   5.679
_cell_length_c   7.417
_cell_angle_alpha   72.923
_cell_angle_beta   72.674
_cell_angle_gamma   71.970
_symmetry_Int_Tables_number   1
_cell_volume   211.034
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.331  0.350  0.161  1.0
  Co  Co1  1  0.343  0.344  0.673  1.0
  Co  Co2  1  0.660  0.673  0.347  1.0
  Co  Co3  1  0.647  0.656  0.824  1.0
  Co  Co4  1  0.999  0.005  0.502  1.0
  Co  Co5  1  0.025  0.968  0.998  1.0
  O  O6  1  0.567  0.573  0.628  1.0
  O  O7  1  0.298  0.695  0.997  1.0
  F  F8  1  0.026  0.639  0.672  1.0
  F  F9  1  0.361  0.984  0.328  1.0
  F  F10  1  0.436  0.438  0.369  1.0
  F  F11  1  0.100  0.106  0.705  1.0
  F  F12  1  0.763  0.761  0.037  1.0
  F  F13  1  0.227  0.227  0.967  1.0
  F  F14  1  0.903  0.900  0.295  1.0
  F  F15  1  0.634  0.028  0.671  1.0
  F  F16  1  0.970  0.367  0.331  1.0
  F  F17  1  0.709  0.286  0.995  1.0
[/CIF]
.
The structure described by Co3OF5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one F(10), one F(2), one F(3), one F(6), and one F(9) atom to form CoOF5 octahedra that share corners with two equivalent Co(2)OF5 octahedra, corners with three equivalent Co(3)OF5 octahedra, corners with three equivalent Co(6)OF5 octahedra,  an edgeedge with one Co(5)F6 octahedra, and  an edgeedge with one Co(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. In the second Co site, Co(2) is bonded to one O(1), one F(1), one F(3), one F(4), one F(6), and one F(8) atom to form CoOF5 octahedra that share corners with two equivalent Co(1)OF5 octahedra, corners with three equivalent Co(5)F6 octahedra, corners with three equivalent Co(4)O2F4 octahedra,  an edgeedge with one Co(3)OF5 octahedra, and  an edgeedge with one Co(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. In the third Co site, Co(3) is bonded to one O(1), one F(2), one F(3), one F(5), one F(7), and one F(9) atom to form CoOF5 octahedra that share corners with two equivalent Co(4)O2F4 octahedra, corners with three equivalent Co(5)F6 octahedra, corners with three equivalent Co(1)OF5 octahedra,  an edgeedge with one Co(2)OF5 octahedra, and  an edgeedge with one Co(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one F(1), one F(10), one F(5), and one F(8) atom to form CoO2F4 octahedra that share corners with two equivalent Co(3)OF5 octahedra, corners with three equivalent Co(2)OF5 octahedra, corners with three equivalent Co(6)OF5 octahedra,  an edgeedge with one Co(5)F6 octahedra, and  an edgeedge with one Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the fifth Co site, Co(5) is bonded to one F(1), one F(2), one F(4), one F(7), one F(8), and one F(9) atom to form CoF6 octahedra that share corners with two equivalent Co(6)OF5 octahedra, corners with three equivalent Co(2)OF5 octahedra, corners with three equivalent Co(3)OF5 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and  an edgeedge with one Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the sixth Co site, Co(6) is bonded to one O(2), one F(10), one F(4), one F(5), one F(6), and one F(7) atom to form CoOF5 octahedra that share corners with two equivalent Co(5)F6 octahedra, corners with three equivalent Co(4)O2F4 octahedra, corners with three equivalent Co(1)OF5 octahedra,  an edgeedge with one Co(2)OF5 octahedra, and  an edgeedge with one Co(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Co(2), one Co(3), and one Co(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(4), and one Co(6) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Co(2), one Co(4), and one Co(5) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(5) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one Co(3) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Co(2), one Co(5), and one Co(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(4), and one Co(6) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(6) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Co(3), one Co(5), and one Co(6) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Co(2), one Co(4), and one Co(5) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(5) atom. In the tenth F site, F(10) is bonded in a distorted T-shaped geometry to one Co(1), one Co(4), and one Co(6) atom. is represented by the CIF card [CIF]
data_Co3OF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.660
_cell_length_b   5.679
_cell_length_c   7.417
_cell_angle_alpha   72.923
_cell_angle_beta   72.674
_cell_angle_gamma   71.970
_symmetry_Int_Tables_number   1
_cell_volume   211.034
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.331  0.350  0.161  1.0
  Co  Co1  1  0.343  0.344  0.673  1.0
  Co  Co2  1  0.660  0.673  0.347  1.0
  Co  Co3  1  0.647  0.656  0.824  1.0
  Co  Co4  1  0.999  0.005  0.502  1.0
  Co  Co5  1  0.025  0.968  0.998  1.0
  O  O6  1  0.567  0.573  0.628  1.0
  O  O7  1  0.298  0.695  0.997  1.0
  F  F8  1  0.026  0.639  0.672  1.0
  F  F9  1  0.361  0.984  0.328  1.0
  F  F10  1  0.436  0.438  0.369  1.0
  F  F11  1  0.100  0.106  0.705  1.0
  F  F12  1  0.763  0.761  0.037  1.0
  F  F13  1  0.227  0.227  0.967  1.0
  F  F14  1  0.903  0.900  0.295  1.0
  F  F15  1  0.634  0.028  0.671  1.0
  F  F16  1  0.970  0.367  0.331  1.0
  F  F17  1  0.709  0.286  0.995  1.0
[/CIF]
.