The compound described by CsSm(MoO4)2 crystallizes in the monoclinic P2/c space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(1) atoms. Sm(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1), one Sm(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Sm(1), and one Mo(1) atom. is represented by the CIF card [CIF]
data_CsSm(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.141
_cell_length_b   8.426
_cell_length_c   9.887
_cell_angle_alpha   88.248
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   428.125
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.468  0.750  0.500  1.0
  Cs  Cs1  1  0.532  0.250  0.500  1.0
  Sm  Sm2  1  0.503  0.750  0.000  1.0
  Sm  Sm3  1  0.497  0.250  0.000  1.0
  Mo  Mo4  1  0.977  0.492  0.192  1.0
  Mo  Mo5  1  0.023  0.508  0.808  1.0
  Mo  Mo6  1  0.977  0.008  0.808  1.0
  Mo  Mo7  1  0.023  0.992  0.192  1.0
  O  O8  1  0.889  0.984  0.356  1.0
  O  O9  1  0.111  0.016  0.644  1.0
  O  O10  1  0.889  0.516  0.644  1.0
  O  O11  1  0.111  0.484  0.356  1.0
  O  O12  1  0.764  0.322  0.181  1.0
  O  O13  1  0.236  0.678  0.819  1.0
  O  O14  1  0.764  0.178  0.819  1.0
  O  O15  1  0.236  0.822  0.181  1.0
  O  O16  1  0.751  0.997  0.068  1.0
  O  O17  1  0.249  0.003  0.932  1.0
  O  O18  1  0.751  0.503  0.932  1.0
  O  O19  1  0.249  0.497  0.068  1.0
  O  O20  1  0.764  0.663  0.183  1.0
  O  O21  1  0.236  0.337  0.817  1.0
  O  O22  1  0.764  0.837  0.817  1.0
  O  O23  1  0.236  0.163  0.183  1.0
[/CIF]
.
The compound described by CsSm(MoO4)2 crystallizes in the monoclinic P2/c space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(1) atoms. Sm(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1), one Sm(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Sm(1), and one Mo(1) atom. is represented by the CIF card [CIF]
data_CsSm(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.141
_cell_length_b   8.426
_cell_length_c   9.887
_cell_angle_alpha   88.248
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   428.125
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.468  0.750  0.500  1.0
  Cs  Cs1  1  0.532  0.250  0.500  1.0
  Sm  Sm2  1  0.503  0.750  0.000  1.0
  Sm  Sm3  1  0.497  0.250  0.000  1.0
  Mo  Mo4  1  0.977  0.492  0.192  1.0
  Mo  Mo5  1  0.023  0.508  0.808  1.0
  Mo  Mo6  1  0.977  0.008  0.808  1.0
  Mo  Mo7  1  0.023  0.992  0.192  1.0
  O  O8  1  0.889  0.984  0.356  1.0
  O  O9  1  0.111  0.016  0.644  1.0
  O  O10  1  0.889  0.516  0.644  1.0
  O  O11  1  0.111  0.484  0.356  1.0
  O  O12  1  0.764  0.322  0.181  1.0
  O  O13  1  0.236  0.678  0.819  1.0
  O  O14  1  0.764  0.178  0.819  1.0
  O  O15  1  0.236  0.822  0.181  1.0
  O  O16  1  0.751  0.997  0.068  1.0
  O  O17  1  0.249  0.003  0.932  1.0
  O  O18  1  0.751  0.503  0.932  1.0
  O  O19  1  0.249  0.497  0.068  1.0
  O  O20  1  0.764  0.663  0.183  1.0
  O  O21  1  0.236  0.337  0.817  1.0
  O  O22  1  0.764  0.837  0.817  1.0
  O  O23  1  0.236  0.163  0.183  1.0
[/CIF]
.