The material structure described by Ba3(ZnB5O10)PO4 crystallizes in the orthorhombic Pmn2_1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 9-coordinate geometry to one O(4), one O(5), one O(6), one O(7), one O(8), two equivalent O(1), and two equivalent O(3) atoms. In the second Ba site, Ba(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. Zn(1) is bonded to one O(2), one O(5), one O(6), and two equivalent O(7) atoms to form ZnO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent B(2)O4 tetrahedra. There are three inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. In the second B site, B(2) is bonded to one O(2), one O(3), one O(8), and one O(9) atom to form BO4 tetrahedra that share  a cornercorner with one B(2)O4 tetrahedra and  a cornercorner with one Zn(1)O5 trigonal bipyramid. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(5) and two equivalent O(3) atoms. P(1) is bonded to one O(4), one O(6), and two equivalent O(1) atoms to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O5 trigonal bipyramid. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Zn(1), and one B(3) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ba(1), one Zn(1), and one P(1) atom. In the third O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ba(2), one Zn(1), and one B(1) atom. In the fourth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ba(2), one B(1), and one B(2) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one Ba(2), one B(1), and one B(2) atom. In the sixth O site, O(1) is bonded in a distorted single-bond geometry to one Ba(2), two equivalent Ba(1), and one P(1) atom. In the seventh O site, O(2) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent B(2) atoms. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent Ba(1), one B(2), and one B(3) atom. In the ninth O site, O(4) is bonded in a 4-coordinate geometry to one Ba(2), two equivalent Ba(1), and one P(1) atom. is represented by the CIF file [CIF]
data_Ba3ZnB5PO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.183
_cell_length_b   8.323
_cell_length_c   10.491
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   627.235
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.563  0.439  0.730  1.0
  Ba  Ba1  1  0.563  0.439  0.270  1.0
  Ba  Ba2  1  0.437  0.939  0.770  1.0
  Ba  Ba3  1  0.437  0.939  0.230  1.0
  Ba  Ba4  1  0.973  0.225  0.500  1.0
  Ba  Ba5  1  0.027  0.725  0.000  1.0
  Zn  Zn6  1  0.241  0.332  0.000  1.0
  Zn  Zn7  1  0.759  0.832  0.500  1.0
  B  B8  1  0.052  0.425  0.763  1.0
  B  B9  1  0.052  0.425  0.237  1.0
  B  B10  1  0.948  0.925  0.737  1.0
  B  B11  1  0.948  0.925  0.263  1.0
  B  B12  1  0.898  0.175  0.877  1.0
  B  B13  1  0.898  0.175  0.123  1.0
  B  B14  1  0.102  0.675  0.623  1.0
  B  B15  1  0.102  0.675  0.377  1.0
  B  B16  1  0.594  0.161  0.000  1.0
  B  B17  1  0.406  0.661  0.500  1.0
  P  P18  1  0.435  0.161  0.500  1.0
  P  P19  1  0.565  0.661  0.000  1.0
  O  O20  1  0.321  0.201  0.623  1.0
  O  O21  1  0.321  0.201  0.377  1.0
  O  O22  1  0.679  0.701  0.877  1.0
  O  O23  1  0.679  0.701  0.123  1.0
  O  O24  1  0.971  0.232  0.000  1.0
  O  O25  1  0.029  0.732  0.500  1.0
  O  O26  1  0.310  0.659  0.615  1.0
  O  O27  1  0.310  0.659  0.385  1.0
  O  O28  1  0.690  0.159  0.885  1.0
  O  O29  1  0.690  0.159  0.115  1.0
  O  O30  1  0.611  0.270  0.500  1.0
  O  O31  1  0.389  0.770  0.000  1.0
  O  O32  1  0.405  0.143  0.000  1.0
  O  O33  1  0.595  0.643  0.500  1.0
  O  O34  1  0.480  0.979  0.500  1.0
  O  O35  1  0.520  0.479  0.000  1.0
  O  O36  1  0.189  0.463  0.847  1.0
  O  O37  1  0.189  0.463  0.153  1.0
  O  O38  1  0.811  0.963  0.653  1.0
  O  O39  1  0.811  0.963  0.347  1.0
  O  O40  1  0.930  0.294  0.773  1.0
  O  O41  1  0.930  0.294  0.227  1.0
  O  O42  1  0.070  0.794  0.727  1.0
  O  O43  1  0.070  0.794  0.273  1.0
  O  O44  1  0.014  0.518  0.655  1.0
  O  O45  1  0.014  0.518  0.345  1.0
  O  O46  1  0.986  0.018  0.845  1.0
  O  O47  1  0.986  0.018  0.155  1.0
[/CIF]
.
The material structure described by Ba3(ZnB5O10)PO4 crystallizes in the orthorhombic Pmn2_1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 9-coordinate geometry to one O(4), one O(5), one O(6), one O(7), one O(8), two equivalent O(1), and two equivalent O(3) atoms. In the second Ba site, Ba(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. Zn(1) is bonded to one O(2), one O(5), one O(6), and two equivalent O(7) atoms to form ZnO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent B(2)O4 tetrahedra. There are three inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. In the second B site, B(2) is bonded to one O(2), one O(3), one O(8), and one O(9) atom to form BO4 tetrahedra that share  a cornercorner with one B(2)O4 tetrahedra and  a cornercorner with one Zn(1)O5 trigonal bipyramid. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(5) and two equivalent O(3) atoms. P(1) is bonded to one O(4), one O(6), and two equivalent O(1) atoms to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O5 trigonal bipyramid. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Zn(1), and one B(3) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ba(1), one Zn(1), and one P(1) atom. In the third O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ba(2), one Zn(1), and one B(1) atom. In the fourth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ba(2), one B(1), and one B(2) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one Ba(2), one B(1), and one B(2) atom. In the sixth O site, O(1) is bonded in a distorted single-bond geometry to one Ba(2), two equivalent Ba(1), and one P(1) atom. In the seventh O site, O(2) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent B(2) atoms. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent Ba(1), one B(2), and one B(3) atom. In the ninth O site, O(4) is bonded in a 4-coordinate geometry to one Ba(2), two equivalent Ba(1), and one P(1) atom. is represented by the CIF file [CIF]
data_Ba3ZnB5PO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.183
_cell_length_b   8.323
_cell_length_c   10.491
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   627.235
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.563  0.439  0.730  1.0
  Ba  Ba1  1  0.563  0.439  0.270  1.0
  Ba  Ba2  1  0.437  0.939  0.770  1.0
  Ba  Ba3  1  0.437  0.939  0.230  1.0
  Ba  Ba4  1  0.973  0.225  0.500  1.0
  Ba  Ba5  1  0.027  0.725  0.000  1.0
  Zn  Zn6  1  0.241  0.332  0.000  1.0
  Zn  Zn7  1  0.759  0.832  0.500  1.0
  B  B8  1  0.052  0.425  0.763  1.0
  B  B9  1  0.052  0.425  0.237  1.0
  B  B10  1  0.948  0.925  0.737  1.0
  B  B11  1  0.948  0.925  0.263  1.0
  B  B12  1  0.898  0.175  0.877  1.0
  B  B13  1  0.898  0.175  0.123  1.0
  B  B14  1  0.102  0.675  0.623  1.0
  B  B15  1  0.102  0.675  0.377  1.0
  B  B16  1  0.594  0.161  0.000  1.0
  B  B17  1  0.406  0.661  0.500  1.0
  P  P18  1  0.435  0.161  0.500  1.0
  P  P19  1  0.565  0.661  0.000  1.0
  O  O20  1  0.321  0.201  0.623  1.0
  O  O21  1  0.321  0.201  0.377  1.0
  O  O22  1  0.679  0.701  0.877  1.0
  O  O23  1  0.679  0.701  0.123  1.0
  O  O24  1  0.971  0.232  0.000  1.0
  O  O25  1  0.029  0.732  0.500  1.0
  O  O26  1  0.310  0.659  0.615  1.0
  O  O27  1  0.310  0.659  0.385  1.0
  O  O28  1  0.690  0.159  0.885  1.0
  O  O29  1  0.690  0.159  0.115  1.0
  O  O30  1  0.611  0.270  0.500  1.0
  O  O31  1  0.389  0.770  0.000  1.0
  O  O32  1  0.405  0.143  0.000  1.0
  O  O33  1  0.595  0.643  0.500  1.0
  O  O34  1  0.480  0.979  0.500  1.0
  O  O35  1  0.520  0.479  0.000  1.0
  O  O36  1  0.189  0.463  0.847  1.0
  O  O37  1  0.189  0.463  0.153  1.0
  O  O38  1  0.811  0.963  0.653  1.0
  O  O39  1  0.811  0.963  0.347  1.0
  O  O40  1  0.930  0.294  0.773  1.0
  O  O41  1  0.930  0.294  0.227  1.0
  O  O42  1  0.070  0.794  0.727  1.0
  O  O43  1  0.070  0.794  0.273  1.0
  O  O44  1  0.014  0.518  0.655  1.0
  O  O45  1  0.014  0.518  0.345  1.0
  O  O46  1  0.986  0.018  0.845  1.0
  O  O47  1  0.986  0.018  0.155  1.0
[/CIF]
.