The structure described by NaTlO crystallizes in the hexagonal P6_3mc space group. Na(1) is bonded in a 3-coordinate geometry to one Tl(1) and three equivalent O(1) atoms. Tl(1) is bonded in a distorted rectangular see-saw-like geometry to one Na(1) and three equivalent O(1) atoms. O(1) is bonded to three equivalent Na(1) and three equivalent Tl(1) atoms to form edge-sharing ONa3Tl3 octahedra. is represented by the CIF file [CIF]
data_NaTlO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.484
_cell_length_b   3.484
_cell_length_c   11.395
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   119.807
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.333  0.667  0.394  1.0
  Na  Na1  1  0.667  0.333  0.894  1.0
  Tl  Tl2  1  0.667  0.333  0.616  1.0
  Tl  Tl3  1  0.333  0.667  0.116  1.0
  O  O4  1  0.000  0.000  0.490  1.0
  O  O5  1  0.000  0.000  0.990  1.0
[/CIF]
.
The structure described by NaTlO crystallizes in the hexagonal P6_3mc space group. Na(1) is bonded in a 3-coordinate geometry to one Tl(1) and three equivalent O(1) atoms. Tl(1) is bonded in a distorted rectangular see-saw-like geometry to one Na(1) and three equivalent O(1) atoms. O(1) is bonded to three equivalent Na(1) and three equivalent Tl(1) atoms to form edge-sharing ONa3Tl3 octahedra. is represented by the CIF file [CIF]
data_NaTlO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.484
_cell_length_b   3.484
_cell_length_c   11.395
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   119.807
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.333  0.667  0.394  1.0
  Na  Na1  1  0.667  0.333  0.894  1.0
  Tl  Tl2  1  0.667  0.333  0.616  1.0
  Tl  Tl3  1  0.333  0.667  0.116  1.0
  O  O4  1  0.000  0.000  0.490  1.0
  O  O5  1  0.000  0.000  0.990  1.0
[/CIF]
.