The material structure described by ZnC2H10S3(N3O2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC2H10S3(N3O2)2 clusters. Zn(1) is bonded to one N(1), one N(3), one S(1), one S(2), and one O(1) atom to form distorted ZnS2N2O trigonal bipyramids that share  a cornercorner with one S(3)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(2), one N(5), and one S(1) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(4), one N(6), and one S(2) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Zn(1), one N(2), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one H(3) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one Zn(1), one N(4), one H(6), and one H(7) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(2), one N(3), and one H(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(5) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(2), one H(10), and one H(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(6) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Zn(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the third S site, S(3) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Zn(1)S2N2O trigonal bipyramid. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(3) atom. is represented by the CIF file [CIF]
data_ZnH10C2S3(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.612
_cell_length_b   7.307
_cell_length_c   12.482
_cell_angle_alpha   91.570
_cell_angle_beta   93.539
_cell_angle_gamma   100.376
_symmetry_Int_Tables_number   1
_cell_volume   591.599
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.158  0.291  0.726  1.0
  Zn  Zn1  1  0.842  0.709  0.274  1.0
  H  H2  1  0.405  0.098  0.852  1.0
  H  H3  1  0.595  0.902  0.148  1.0
  H  H4  1  0.505  0.326  0.853  1.0
  H  H5  1  0.495  0.674  0.147  1.0
  H  H6  1  0.384  0.243  0.025  1.0
  H  H7  1  0.616  0.757  0.975  1.0
  H  H8  1  0.132  0.302  0.127  1.0
  H  H9  1  0.868  0.698  0.873  1.0
  H  H10  1  0.872  0.260  0.076  1.0
  H  H11  1  0.128  0.740  0.924  1.0
  H  H12  1  0.405  0.085  0.625  1.0
  H  H13  1  0.595  0.915  0.375  1.0
  H  H14  1  0.517  0.310  0.634  1.0
  H  H15  1  0.483  0.690  0.366  1.0
  H  H16  1  0.412  0.221  0.448  1.0
  H  H17  1  0.588  0.779  0.552  1.0
  H  H18  1  0.188  0.292  0.321  1.0
  H  H19  1  0.812  0.708  0.679  1.0
  H  H20  1  0.935  0.302  0.349  1.0
  H  H21  1  0.065  0.698  0.651  1.0
  C  C22  1  0.085  0.250  0.965  1.0
  C  C23  1  0.915  0.750  0.035  1.0
  C  C24  1  0.119  0.254  0.478  1.0
  C  C25  1  0.881  0.746  0.522  1.0
  S  S26  1  0.912  0.215  0.855  1.0
  S  S27  1  0.088  0.785  0.145  1.0
  S  S28  1  0.934  0.249  0.568  1.0
  S  S29  1  0.066  0.751  0.432  1.0
  S  S30  1  0.445  0.710  0.766  1.0
  S  S31  1  0.555  0.290  0.234  1.0
  N  N32  1  0.371  0.230  0.857  1.0
  N  N33  1  0.629  0.770  0.143  1.0
  N  N34  1  0.290  0.258  0.957  1.0
  N  N35  1  0.710  0.742  0.043  1.0
  N  N36  1  0.381  0.220  0.615  1.0
  N  N37  1  0.619  0.780  0.385  1.0
  N  N38  1  0.318  0.246  0.507  1.0
  N  N39  1  0.682  0.754  0.493  1.0
  N  N40  1  0.024  0.269  0.064  1.0
  N  N41  1  0.976  0.731  0.936  1.0
  N  N42  1  0.072  0.266  0.374  1.0
  N  N43  1  0.928  0.734  0.626  1.0
  O  O44  1  0.246  0.577  0.737  1.0
  O  O45  1  0.754  0.423  0.263  1.0
  O  O46  1  0.477  0.848  0.680  1.0
  O  O47  1  0.523  0.152  0.320  1.0
  O  O48  1  0.426  0.805  0.872  1.0
  O  O49  1  0.574  0.195  0.128  1.0
  O  O50  1  0.618  0.603  0.774  1.0
  O  O51  1  0.382  0.397  0.226  1.0
[/CIF]
.
The material structure described by ZnC2H10S3(N3O2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC2H10S3(N3O2)2 clusters. Zn(1) is bonded to one N(1), one N(3), one S(1), one S(2), and one O(1) atom to form distorted ZnS2N2O trigonal bipyramids that share  a cornercorner with one S(3)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(2), one N(5), and one S(1) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(4), one N(6), and one S(2) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Zn(1), one N(2), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one H(3) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one Zn(1), one N(4), one H(6), and one H(7) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(2), one N(3), and one H(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(5) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(2), one H(10), and one H(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(6) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Zn(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the third S site, S(3) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Zn(1)S2N2O trigonal bipyramid. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(3) atom. is represented by the CIF file [CIF]
data_ZnH10C2S3(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.612
_cell_length_b   7.307
_cell_length_c   12.482
_cell_angle_alpha   91.570
_cell_angle_beta   93.539
_cell_angle_gamma   100.376
_symmetry_Int_Tables_number   1
_cell_volume   591.599
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.158  0.291  0.726  1.0
  Zn  Zn1  1  0.842  0.709  0.274  1.0
  H  H2  1  0.405  0.098  0.852  1.0
  H  H3  1  0.595  0.902  0.148  1.0
  H  H4  1  0.505  0.326  0.853  1.0
  H  H5  1  0.495  0.674  0.147  1.0
  H  H6  1  0.384  0.243  0.025  1.0
  H  H7  1  0.616  0.757  0.975  1.0
  H  H8  1  0.132  0.302  0.127  1.0
  H  H9  1  0.868  0.698  0.873  1.0
  H  H10  1  0.872  0.260  0.076  1.0
  H  H11  1  0.128  0.740  0.924  1.0
  H  H12  1  0.405  0.085  0.625  1.0
  H  H13  1  0.595  0.915  0.375  1.0
  H  H14  1  0.517  0.310  0.634  1.0
  H  H15  1  0.483  0.690  0.366  1.0
  H  H16  1  0.412  0.221  0.448  1.0
  H  H17  1  0.588  0.779  0.552  1.0
  H  H18  1  0.188  0.292  0.321  1.0
  H  H19  1  0.812  0.708  0.679  1.0
  H  H20  1  0.935  0.302  0.349  1.0
  H  H21  1  0.065  0.698  0.651  1.0
  C  C22  1  0.085  0.250  0.965  1.0
  C  C23  1  0.915  0.750  0.035  1.0
  C  C24  1  0.119  0.254  0.478  1.0
  C  C25  1  0.881  0.746  0.522  1.0
  S  S26  1  0.912  0.215  0.855  1.0
  S  S27  1  0.088  0.785  0.145  1.0
  S  S28  1  0.934  0.249  0.568  1.0
  S  S29  1  0.066  0.751  0.432  1.0
  S  S30  1  0.445  0.710  0.766  1.0
  S  S31  1  0.555  0.290  0.234  1.0
  N  N32  1  0.371  0.230  0.857  1.0
  N  N33  1  0.629  0.770  0.143  1.0
  N  N34  1  0.290  0.258  0.957  1.0
  N  N35  1  0.710  0.742  0.043  1.0
  N  N36  1  0.381  0.220  0.615  1.0
  N  N37  1  0.619  0.780  0.385  1.0
  N  N38  1  0.318  0.246  0.507  1.0
  N  N39  1  0.682  0.754  0.493  1.0
  N  N40  1  0.024  0.269  0.064  1.0
  N  N41  1  0.976  0.731  0.936  1.0
  N  N42  1  0.072  0.266  0.374  1.0
  N  N43  1  0.928  0.734  0.626  1.0
  O  O44  1  0.246  0.577  0.737  1.0
  O  O45  1  0.754  0.423  0.263  1.0
  O  O46  1  0.477  0.848  0.680  1.0
  O  O47  1  0.523  0.152  0.320  1.0
  O  O48  1  0.426  0.805  0.872  1.0
  O  O49  1  0.574  0.195  0.128  1.0
  O  O50  1  0.618  0.603  0.774  1.0
  O  O51  1  0.382  0.397  0.226  1.0
[/CIF]
.