The compound described by Mn2CoN2 crystallizes in the orthorhombic Pmmn space group. Mn(1) is bonded to five equivalent N(1) atoms to form a mixture of corner and edge-sharing MnN5 square pyramids. Co(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to five equivalent Mn(1) and one Co(1) atom to form a mixture of corner and edge-sharing NMn5Co octahedra. The corner-sharing octahedral tilt angles range from 0-7°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2CoN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.866
_cell_length_b   2.870
_cell_length_c   6.093
_cell_angle_alpha   76.381
_cell_angle_beta   76.398
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   47.256
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  1.000  1.000  0.500  1.0
  Mn  Mn1  1  0.348  0.348  0.803  1.0
  Mn  Mn2  1  0.652  0.652  0.197  1.0
  N  N3  1  0.837  0.837  0.825  1.0
  N  N4  1  0.163  0.163  0.175  1.0
[/CIF]
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The compound described by Mn2CoN2 crystallizes in the orthorhombic Pmmn space group. Mn(1) is bonded to five equivalent N(1) atoms to form a mixture of corner and edge-sharing MnN5 square pyramids. Co(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to five equivalent Mn(1) and one Co(1) atom to form a mixture of corner and edge-sharing NMn5Co octahedra. The corner-sharing octahedral tilt angles range from 0-7°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2CoN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.866
_cell_length_b   2.870
_cell_length_c   6.093
_cell_angle_alpha   76.381
_cell_angle_beta   76.398
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   47.256
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  1.000  1.000  0.500  1.0
  Mn  Mn1  1  0.348  0.348  0.803  1.0
  Mn  Mn2  1  0.652  0.652  0.197  1.0
  N  N3  1  0.837  0.837  0.825  1.0
  N  N4  1  0.163  0.163  0.175  1.0
[/CIF]
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