The material structure described by Li4Ti11O24 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(13), one O(14), one O(18), one O(8), and one O(9) atom to form distorted LiO6 octahedra that share corners with two equivalent Ti(10)O6 octahedra, corners with two equivalent Ti(9)O6 octahedra,  an edgeedge with one Ti(4)O6 octahedra,  an edgeedge with one Ti(5)O6 octahedra,  an edgeedge with one Ti(6)O6 octahedra, and  an edgeedge with one Ti(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(19), one O(21), one O(22), and one O(6) atom. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(13), one O(17), one O(18), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(18), and one O(8) atom. There are eleven inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(12), one O(20), one O(23), one O(24), one O(4), and one O(5) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the second Ti site, Ti(2) is bonded to one O(11), one O(19), one O(22), one O(24), one O(4), and one O(6) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the third Ti site, Ti(3) is bonded to one O(10), one O(21), one O(22), one O(23), one O(5), and one O(6) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the fourth Ti site, Ti(4) is bonded to one O(14), one O(15), one O(16), one O(2), one O(7), and one O(8) atom to form distorted TiO6 octahedra that share corners with two equivalent Ti(10)O6 octahedra, corners with two equivalent Ti(11)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(5)O6 octahedra,  an edgeedge with one Ti(7)O6 octahedra, and  an edgeedge with one Ti(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-51°. In the fifth Ti site, Ti(5) is bonded to one O(13), one O(15), one O(17), one O(3), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Ti(11)O6 octahedra, corners with two equivalent Ti(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(4)O6 octahedra,  an edgeedge with one Ti(6)O6 octahedra, and  an edgeedge with one Ti(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-53°. In the sixth Ti site, Ti(6) is bonded to one O(10), one O(11), one O(17), one O(18), one O(22), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(5)O6 octahedra,  an edgeedge with one Ti(7)O6 octahedra, and  an edgeedge with one Ti(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the seventh Ti site, Ti(7) is bonded to one O(10), one O(12), one O(16), one O(18), one O(23), and one O(8) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(4)O6 octahedra,  an edgeedge with one Ti(6)O6 octahedra, and  an edgeedge with one Ti(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the eighth Ti site, Ti(8) is bonded to one O(11), one O(12), one O(16), one O(17), one O(24), and one O(7) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 46-48°. In the ninth Ti site, Ti(9) is bonded to one O(1), one O(13), one O(19), one O(21), one O(3), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Ti(5)O6 octahedra,  an edgeedge with one Ti(10)O6 octahedra,  an edgeedge with one Ti(11)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. In the tenth Ti site, Ti(10) is bonded to one O(1), one O(14), one O(2), one O(20), one O(21), and one O(5) atom to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(11)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, and  an edgeedge with one Ti(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-58°. In the eleventh Ti site, Ti(11) is bonded to one O(15), one O(19), one O(2), one O(20), one O(3), and one O(4) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 44-49°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one Ti(10), and one Ti(9) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ti(10), one Ti(11), and one Ti(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ti(11), one Ti(5), and one Ti(9) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Ti(11), and one Ti(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Ti(10), and one Ti(3) atom. In the sixth O site, O(6) is bonded to one Li(2), one Ti(2), one Ti(3), and one Ti(9) atom to form a mixture of distorted corner and edge-sharing OLiTi3 tetrahedra. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Ti(4), one Ti(5), and one Ti(8) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Ti(4), and one Ti(7) atom to form distorted OLi2Ti2 tetrahedra that share  a cornercorner with one O(18)Li3Ti2 square pyramid,  a cornercorner with one O(9)Li2Ti2 tetrahedra, and  an edgeedge with one O(18)Li3Ti2 square pyramid. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Ti(5), and one Ti(6) atom to form distorted OLi2Ti2 tetrahedra that share  a cornercorner with one O(18)Li3Ti2 square pyramid,  a cornercorner with one O(8)Li2Ti2 tetrahedra,  a cornercorner with one O(22)LiTi3 trigonal pyramid, and  an edgeedge with one O(18)Li3Ti2 square pyramid. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Ti(3), one Ti(6), and one Ti(7) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Ti(2), one Ti(6), and one Ti(8) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(7), and one Ti(8) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Ti(5), and one Ti(9) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(4), one Ti(10), and one Ti(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Ti(11), one Ti(4), and one Ti(5) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(4), one Ti(4), one Ti(7), and one Ti(8) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(5), one Ti(6), and one Ti(8) atom. In the eighteenth O site, O(18) is bonded to one Li(1), one Li(3), one Li(4), one Ti(6), and one Ti(7) atom to form OLi3Ti2 square pyramids that share  a cornercorner with one O(8)Li2Ti2 tetrahedra,  a cornercorner with one O(9)Li2Ti2 tetrahedra,  a cornercorner with one O(22)LiTi3 trigonal pyramid,  an edgeedge with one O(8)Li2Ti2 tetrahedra, and  an edgeedge with one O(9)Li2Ti2 tetrahedra. In the nineteenth O site, O(19) is bonded in a see-saw-like geometry to one Li(2), one Ti(11), one Ti(2), and one Ti(9) atom. In the twentieth O site, O(20) is bonded in a trigonal non-coplanar geometry to one Ti(1), one Ti(10), and one Ti(11) atom. In the twenty-first O site, O(21) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(10), one Ti(3), and one Ti(9) atom. In the twenty-second O site, O(22) is bonded to one Li(2), one Ti(2), one Ti(3), and one Ti(6) atom to form OLiTi3 trigonal pyramids that share  a cornercorner with one O(18)Li3Ti2 square pyramid,  a cornercorner with one O(9)Li2Ti2 tetrahedra,  a cornercorner with one O(6)LiTi3 tetrahedra, and  an edgeedge with one O(6)LiTi3 tetrahedra. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(3), and one Ti(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(2), and one Ti(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Ti11O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.057
_cell_length_b   8.916
_cell_length_c   9.646
_cell_angle_alpha   89.955
_cell_angle_beta   89.884
_cell_angle_gamma   89.958
_symmetry_Int_Tables_number   1
_cell_volume   434.892
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.524  0.083  0.648  1.0
  Li  Li1  1  0.437  0.252  0.035  1.0
  Li  Li2  1  0.066  0.251  0.539  1.0
  Li  Li3  1  0.066  0.915  0.539  1.0
  Ti  Ti4  1  0.977  0.750  0.137  1.0
  Ti  Ti5  1  0.974  0.419  0.141  1.0
  Ti  Ti6  1  0.987  0.079  0.140  1.0
  Ti  Ti7  1  0.534  0.756  0.644  1.0
  Ti  Ti8  1  0.523  0.412  0.642  1.0
  Ti  Ti9  1  0.493  0.246  0.370  1.0
  Ti  Ti10  1  0.493  0.917  0.365  1.0
  Ti  Ti11  1  0.471  0.585  0.364  1.0
  Ti  Ti12  1  0.006  0.247  0.851  1.0
  Ti  Ti13  1  0.033  0.921  0.858  1.0
  Ti  Ti14  1  0.042  0.583  0.863  1.0
  O  O15  1  0.831  0.081  0.780  1.0
  O  O16  1  0.813  0.749  0.778  1.0
  O  O17  1  0.804  0.418  0.779  1.0
  O  O18  1  0.815  0.581  0.041  1.0
  O  O19  1  0.816  0.919  0.041  1.0
  O  O20  1  0.804  0.249  0.040  1.0
  O  O21  1  0.674  0.583  0.537  1.0
  O  O22  1  0.698  0.907  0.531  1.0
  O  O23  1  0.700  0.259  0.534  1.0
  O  O24  1  0.697  0.085  0.277  1.0
  O  O25  1  0.682  0.419  0.275  1.0
  O  O26  1  0.679  0.747  0.275  1.0
  O  O27  1  0.278  0.267  0.715  1.0
  O  O28  1  0.283  0.901  0.715  1.0
  O  O29  1  0.312  0.583  0.725  1.0
  O  O30  1  0.299  0.756  0.459  1.0
  O  O31  1  0.297  0.410  0.460  1.0
  O  O32  1  0.291  0.085  0.450  1.0
  O  O33  1  0.195  0.413  0.963  1.0
  O  O34  1  0.193  0.748  0.963  1.0
  O  O35  1  0.204  0.089  0.961  1.0
  O  O36  1  0.205  0.252  0.210  1.0
  O  O37  1  0.185  0.915  0.223  1.0
  O  O38  1  0.180  0.583  0.228  1.0
[/CIF]
.
The material structure described by Li4Ti11O24 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(13), one O(14), one O(18), one O(8), and one O(9) atom to form distorted LiO6 octahedra that share corners with two equivalent Ti(10)O6 octahedra, corners with two equivalent Ti(9)O6 octahedra,  an edgeedge with one Ti(4)O6 octahedra,  an edgeedge with one Ti(5)O6 octahedra,  an edgeedge with one Ti(6)O6 octahedra, and  an edgeedge with one Ti(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(19), one O(21), one O(22), and one O(6) atom. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(13), one O(17), one O(18), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(18), and one O(8) atom. There are eleven inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(12), one O(20), one O(23), one O(24), one O(4), and one O(5) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the second Ti site, Ti(2) is bonded to one O(11), one O(19), one O(22), one O(24), one O(4), and one O(6) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the third Ti site, Ti(3) is bonded to one O(10), one O(21), one O(22), one O(23), one O(5), and one O(6) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the fourth Ti site, Ti(4) is bonded to one O(14), one O(15), one O(16), one O(2), one O(7), and one O(8) atom to form distorted TiO6 octahedra that share corners with two equivalent Ti(10)O6 octahedra, corners with two equivalent Ti(11)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(5)O6 octahedra,  an edgeedge with one Ti(7)O6 octahedra, and  an edgeedge with one Ti(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-51°. In the fifth Ti site, Ti(5) is bonded to one O(13), one O(15), one O(17), one O(3), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Ti(11)O6 octahedra, corners with two equivalent Ti(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(4)O6 octahedra,  an edgeedge with one Ti(6)O6 octahedra, and  an edgeedge with one Ti(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-53°. In the sixth Ti site, Ti(6) is bonded to one O(10), one O(11), one O(17), one O(18), one O(22), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(5)O6 octahedra,  an edgeedge with one Ti(7)O6 octahedra, and  an edgeedge with one Ti(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the seventh Ti site, Ti(7) is bonded to one O(10), one O(12), one O(16), one O(18), one O(23), and one O(8) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(4)O6 octahedra,  an edgeedge with one Ti(6)O6 octahedra, and  an edgeedge with one Ti(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the eighth Ti site, Ti(8) is bonded to one O(11), one O(12), one O(16), one O(17), one O(24), and one O(7) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 46-48°. In the ninth Ti site, Ti(9) is bonded to one O(1), one O(13), one O(19), one O(21), one O(3), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Ti(5)O6 octahedra,  an edgeedge with one Ti(10)O6 octahedra,  an edgeedge with one Ti(11)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. In the tenth Ti site, Ti(10) is bonded to one O(1), one O(14), one O(2), one O(20), one O(21), and one O(5) atom to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(11)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, and  an edgeedge with one Ti(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-58°. In the eleventh Ti site, Ti(11) is bonded to one O(15), one O(19), one O(2), one O(20), one O(3), and one O(4) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 44-49°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one Ti(10), and one Ti(9) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ti(10), one Ti(11), and one Ti(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ti(11), one Ti(5), and one Ti(9) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Ti(11), and one Ti(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Ti(10), and one Ti(3) atom. In the sixth O site, O(6) is bonded to one Li(2), one Ti(2), one Ti(3), and one Ti(9) atom to form a mixture of distorted corner and edge-sharing OLiTi3 tetrahedra. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Ti(4), one Ti(5), and one Ti(8) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Ti(4), and one Ti(7) atom to form distorted OLi2Ti2 tetrahedra that share  a cornercorner with one O(18)Li3Ti2 square pyramid,  a cornercorner with one O(9)Li2Ti2 tetrahedra, and  an edgeedge with one O(18)Li3Ti2 square pyramid. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Ti(5), and one Ti(6) atom to form distorted OLi2Ti2 tetrahedra that share  a cornercorner with one O(18)Li3Ti2 square pyramid,  a cornercorner with one O(8)Li2Ti2 tetrahedra,  a cornercorner with one O(22)LiTi3 trigonal pyramid, and  an edgeedge with one O(18)Li3Ti2 square pyramid. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Ti(3), one Ti(6), and one Ti(7) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Ti(2), one Ti(6), and one Ti(8) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(7), and one Ti(8) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Ti(5), and one Ti(9) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(4), one Ti(10), and one Ti(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Ti(11), one Ti(4), and one Ti(5) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(4), one Ti(4), one Ti(7), and one Ti(8) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(5), one Ti(6), and one Ti(8) atom. In the eighteenth O site, O(18) is bonded to one Li(1), one Li(3), one Li(4), one Ti(6), and one Ti(7) atom to form OLi3Ti2 square pyramids that share  a cornercorner with one O(8)Li2Ti2 tetrahedra,  a cornercorner with one O(9)Li2Ti2 tetrahedra,  a cornercorner with one O(22)LiTi3 trigonal pyramid,  an edgeedge with one O(8)Li2Ti2 tetrahedra, and  an edgeedge with one O(9)Li2Ti2 tetrahedra. In the nineteenth O site, O(19) is bonded in a see-saw-like geometry to one Li(2), one Ti(11), one Ti(2), and one Ti(9) atom. In the twentieth O site, O(20) is bonded in a trigonal non-coplanar geometry to one Ti(1), one Ti(10), and one Ti(11) atom. In the twenty-first O site, O(21) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(10), one Ti(3), and one Ti(9) atom. In the twenty-second O site, O(22) is bonded to one Li(2), one Ti(2), one Ti(3), and one Ti(6) atom to form OLiTi3 trigonal pyramids that share  a cornercorner with one O(18)Li3Ti2 square pyramid,  a cornercorner with one O(9)Li2Ti2 tetrahedra,  a cornercorner with one O(6)LiTi3 tetrahedra, and  an edgeedge with one O(6)LiTi3 tetrahedra. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(3), and one Ti(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(2), and one Ti(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Ti11O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.057
_cell_length_b   8.916
_cell_length_c   9.646
_cell_angle_alpha   89.955
_cell_angle_beta   89.884
_cell_angle_gamma   89.958
_symmetry_Int_Tables_number   1
_cell_volume   434.892
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.524  0.083  0.648  1.0
  Li  Li1  1  0.437  0.252  0.035  1.0
  Li  Li2  1  0.066  0.251  0.539  1.0
  Li  Li3  1  0.066  0.915  0.539  1.0
  Ti  Ti4  1  0.977  0.750  0.137  1.0
  Ti  Ti5  1  0.974  0.419  0.141  1.0
  Ti  Ti6  1  0.987  0.079  0.140  1.0
  Ti  Ti7  1  0.534  0.756  0.644  1.0
  Ti  Ti8  1  0.523  0.412  0.642  1.0
  Ti  Ti9  1  0.493  0.246  0.370  1.0
  Ti  Ti10  1  0.493  0.917  0.365  1.0
  Ti  Ti11  1  0.471  0.585  0.364  1.0
  Ti  Ti12  1  0.006  0.247  0.851  1.0
  Ti  Ti13  1  0.033  0.921  0.858  1.0
  Ti  Ti14  1  0.042  0.583  0.863  1.0
  O  O15  1  0.831  0.081  0.780  1.0
  O  O16  1  0.813  0.749  0.778  1.0
  O  O17  1  0.804  0.418  0.779  1.0
  O  O18  1  0.815  0.581  0.041  1.0
  O  O19  1  0.816  0.919  0.041  1.0
  O  O20  1  0.804  0.249  0.040  1.0
  O  O21  1  0.674  0.583  0.537  1.0
  O  O22  1  0.698  0.907  0.531  1.0
  O  O23  1  0.700  0.259  0.534  1.0
  O  O24  1  0.697  0.085  0.277  1.0
  O  O25  1  0.682  0.419  0.275  1.0
  O  O26  1  0.679  0.747  0.275  1.0
  O  O27  1  0.278  0.267  0.715  1.0
  O  O28  1  0.283  0.901  0.715  1.0
  O  O29  1  0.312  0.583  0.725  1.0
  O  O30  1  0.299  0.756  0.459  1.0
  O  O31  1  0.297  0.410  0.460  1.0
  O  O32  1  0.291  0.085  0.450  1.0
  O  O33  1  0.195  0.413  0.963  1.0
  O  O34  1  0.193  0.748  0.963  1.0
  O  O35  1  0.204  0.089  0.961  1.0
  O  O36  1  0.205  0.252  0.210  1.0
  O  O37  1  0.185  0.915  0.223  1.0
  O  O38  1  0.180  0.583  0.228  1.0
[/CIF]
.