The structure described by Pd8Sb3 crystallizes in the trigonal R-3c space group. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to one Pd(3), four equivalent Pd(4), one Sb(2), and two equivalent Sb(1) atoms. In the second Pd site, Pd(2) is bonded in a 4-coordinate geometry to three equivalent Pd(4), one Sb(3), and three equivalent Sb(1) atoms. In the third Pd site, Pd(3) is bonded in a 11-coordinate geometry to one Pd(3), three equivalent Pd(1), three equivalent Pd(4), one Sb(2), and three equivalent Sb(1) atoms. In the fourth Pd site, Pd(4) is bonded in a 13-coordinate geometry to one Pd(2), one Pd(3), three equivalent Pd(4), four equivalent Pd(1), one Sb(1), one Sb(3), and two equivalent Sb(2) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 10-coordinate geometry to two equivalent Pd(2), two equivalent Pd(3), two equivalent Pd(4), and four equivalent Pd(1) atoms. In the second Sb site, Sb(2) is bonded in a distorted q6 geometry to one Pd(3), three equivalent Pd(1), and six equivalent Pd(4) atoms. In the third Sb site, Sb(3) is bonded in a body-centered cubic geometry to two equivalent Pd(2) and six equivalent Pd(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb3Pd8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.667
_cell_length_b   7.667
_cell_length_c   15.156
_cell_angle_alpha   75.349
_cell_angle_beta   75.349
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   737.828
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.801  0.120  0.595  1.0
  Sb  Sb1  1  0.120  0.483  0.595  1.0
  Sb  Sb2  1  0.483  0.801  0.595  1.0
  Sb  Sb3  1  0.301  0.983  0.095  1.0
  Sb  Sb4  1  0.983  0.620  0.095  1.0
  Sb  Sb5  1  0.620  0.301  0.095  1.0
  Sb  Sb6  1  0.394  0.394  0.818  1.0
  Sb  Sb7  1  0.894  0.894  0.318  1.0
  Sb  Sb8  1  0.052  0.052  0.845  1.0
  Sb  Sb9  1  0.552  0.552  0.345  1.0
  Sb  Sb10  1  0.709  0.709  0.873  1.0
  Sb  Sb11  1  0.209  0.209  0.373  1.0
  Pd  Pd12  1  0.168  0.908  0.502  1.0
  Pd  Pd13  1  0.908  0.423  0.502  1.0
  Pd  Pd14  1  0.423  0.168  0.502  1.0
  Pd  Pd15  1  0.668  0.923  0.002  1.0
  Pd  Pd16  1  0.923  0.408  0.002  1.0
  Pd  Pd17  1  0.408  0.668  0.002  1.0
  Pd  Pd18  1  0.490  0.490  0.530  1.0
  Pd  Pd19  1  0.990  0.990  0.030  1.0
  Pd  Pd20  1  0.833  0.833  0.501  1.0
  Pd  Pd21  1  0.333  0.333  0.001  1.0
  Pd  Pd22  1  0.181  0.696  0.689  1.0
  Pd  Pd23  1  0.696  0.435  0.689  1.0
  Pd  Pd24  1  0.435  0.181  0.689  1.0
  Pd  Pd25  1  0.681  0.935  0.189  1.0
  Pd  Pd26  1  0.935  0.196  0.189  1.0
  Pd  Pd27  1  0.196  0.681  0.189  1.0
  Pd  Pd28  1  0.113  0.113  0.661  1.0
  Pd  Pd29  1  0.613  0.613  0.161  1.0
  Pd  Pd30  1  0.770  0.770  0.690  1.0
  Pd  Pd31  1  0.270  0.270  0.190  1.0
  Pd  Pd32  1  0.759  0.040  0.793  1.0
  Pd  Pd33  1  0.040  0.408  0.793  1.0
  Pd  Pd34  1  0.408  0.759  0.793  1.0
  Pd  Pd35  1  0.259  0.908  0.293  1.0
  Pd  Pd36  1  0.908  0.540  0.293  1.0
  Pd  Pd37  1  0.540  0.259  0.293  1.0
  Pd  Pd38  1  0.063  0.695  0.898  1.0
  Pd  Pd39  1  0.695  0.344  0.898  1.0
  Pd  Pd40  1  0.344  0.063  0.898  1.0
  Pd  Pd41  1  0.563  0.844  0.398  1.0
  Pd  Pd42  1  0.844  0.195  0.398  1.0
  Pd  Pd43  1  0.195  0.563  0.398  1.0
[/CIF]
.
The structure described by Pd8Sb3 crystallizes in the trigonal R-3c space group. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to one Pd(3), four equivalent Pd(4), one Sb(2), and two equivalent Sb(1) atoms. In the second Pd site, Pd(2) is bonded in a 4-coordinate geometry to three equivalent Pd(4), one Sb(3), and three equivalent Sb(1) atoms. In the third Pd site, Pd(3) is bonded in a 11-coordinate geometry to one Pd(3), three equivalent Pd(1), three equivalent Pd(4), one Sb(2), and three equivalent Sb(1) atoms. In the fourth Pd site, Pd(4) is bonded in a 13-coordinate geometry to one Pd(2), one Pd(3), three equivalent Pd(4), four equivalent Pd(1), one Sb(1), one Sb(3), and two equivalent Sb(2) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 10-coordinate geometry to two equivalent Pd(2), two equivalent Pd(3), two equivalent Pd(4), and four equivalent Pd(1) atoms. In the second Sb site, Sb(2) is bonded in a distorted q6 geometry to one Pd(3), three equivalent Pd(1), and six equivalent Pd(4) atoms. In the third Sb site, Sb(3) is bonded in a body-centered cubic geometry to two equivalent Pd(2) and six equivalent Pd(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb3Pd8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.667
_cell_length_b   7.667
_cell_length_c   15.156
_cell_angle_alpha   75.349
_cell_angle_beta   75.349
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   737.828
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.801  0.120  0.595  1.0
  Sb  Sb1  1  0.120  0.483  0.595  1.0
  Sb  Sb2  1  0.483  0.801  0.595  1.0
  Sb  Sb3  1  0.301  0.983  0.095  1.0
  Sb  Sb4  1  0.983  0.620  0.095  1.0
  Sb  Sb5  1  0.620  0.301  0.095  1.0
  Sb  Sb6  1  0.394  0.394  0.818  1.0
  Sb  Sb7  1  0.894  0.894  0.318  1.0
  Sb  Sb8  1  0.052  0.052  0.845  1.0
  Sb  Sb9  1  0.552  0.552  0.345  1.0
  Sb  Sb10  1  0.709  0.709  0.873  1.0
  Sb  Sb11  1  0.209  0.209  0.373  1.0
  Pd  Pd12  1  0.168  0.908  0.502  1.0
  Pd  Pd13  1  0.908  0.423  0.502  1.0
  Pd  Pd14  1  0.423  0.168  0.502  1.0
  Pd  Pd15  1  0.668  0.923  0.002  1.0
  Pd  Pd16  1  0.923  0.408  0.002  1.0
  Pd  Pd17  1  0.408  0.668  0.002  1.0
  Pd  Pd18  1  0.490  0.490  0.530  1.0
  Pd  Pd19  1  0.990  0.990  0.030  1.0
  Pd  Pd20  1  0.833  0.833  0.501  1.0
  Pd  Pd21  1  0.333  0.333  0.001  1.0
  Pd  Pd22  1  0.181  0.696  0.689  1.0
  Pd  Pd23  1  0.696  0.435  0.689  1.0
  Pd  Pd24  1  0.435  0.181  0.689  1.0
  Pd  Pd25  1  0.681  0.935  0.189  1.0
  Pd  Pd26  1  0.935  0.196  0.189  1.0
  Pd  Pd27  1  0.196  0.681  0.189  1.0
  Pd  Pd28  1  0.113  0.113  0.661  1.0
  Pd  Pd29  1  0.613  0.613  0.161  1.0
  Pd  Pd30  1  0.770  0.770  0.690  1.0
  Pd  Pd31  1  0.270  0.270  0.190  1.0
  Pd  Pd32  1  0.759  0.040  0.793  1.0
  Pd  Pd33  1  0.040  0.408  0.793  1.0
  Pd  Pd34  1  0.408  0.759  0.793  1.0
  Pd  Pd35  1  0.259  0.908  0.293  1.0
  Pd  Pd36  1  0.908  0.540  0.293  1.0
  Pd  Pd37  1  0.540  0.259  0.293  1.0
  Pd  Pd38  1  0.063  0.695  0.898  1.0
  Pd  Pd39  1  0.695  0.344  0.898  1.0
  Pd  Pd40  1  0.344  0.063  0.898  1.0
  Pd  Pd41  1  0.563  0.844  0.398  1.0
  Pd  Pd42  1  0.844  0.195  0.398  1.0
  Pd  Pd43  1  0.195  0.563  0.398  1.0
[/CIF]
.