The crystal structure described by Dy(O2Cl)3 crystallizes in the monoclinic P2/c space group. Dy(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Dy(1) and one O(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Dy(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to one Dy(1) and one O(1) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to two equivalent O(3) atoms. is represented by the CIF card [CIF]
data_Dy(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.525
_cell_length_b   7.838
_cell_length_c   7.858
_cell_angle_alpha   90.000
_cell_angle_beta   113.281
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   369.191
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.781  0.250  1.0
  Dy  Dy1  1  0.000  0.219  0.750  1.0
  Cl  Cl2  1  0.190  0.177  0.150  1.0
  Cl  Cl3  1  0.810  0.823  0.850  1.0
  Cl  Cl4  1  0.810  0.177  0.350  1.0
  Cl  Cl5  1  0.190  0.823  0.650  1.0
  Cl  Cl6  1  0.500  0.548  0.250  1.0
  Cl  Cl7  1  0.500  0.452  0.750  1.0
  O  O8  1  0.209  0.024  0.708  1.0
  O  O9  1  0.791  0.976  0.292  1.0
  O  O10  1  0.791  0.024  0.792  1.0
  O  O11  1  0.209  0.976  0.208  1.0
  O  O12  1  0.936  0.521  0.043  1.0
  O  O13  1  0.064  0.479  0.957  1.0
  O  O14  1  0.064  0.521  0.457  1.0
  O  O15  1  0.936  0.479  0.543  1.0
  O  O16  1  0.629  0.655  0.162  1.0
  O  O17  1  0.371  0.345  0.838  1.0
  O  O18  1  0.371  0.655  0.338  1.0
  O  O19  1  0.629  0.345  0.662  1.0
[/CIF]
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The crystal structure described by Dy(O2Cl)3 crystallizes in the monoclinic P2/c space group. Dy(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Dy(1) and one O(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Dy(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to one Dy(1) and one O(1) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to two equivalent O(3) atoms. is represented by the CIF card [CIF]
data_Dy(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.525
_cell_length_b   7.838
_cell_length_c   7.858
_cell_angle_alpha   90.000
_cell_angle_beta   113.281
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   369.191
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.781  0.250  1.0
  Dy  Dy1  1  0.000  0.219  0.750  1.0
  Cl  Cl2  1  0.190  0.177  0.150  1.0
  Cl  Cl3  1  0.810  0.823  0.850  1.0
  Cl  Cl4  1  0.810  0.177  0.350  1.0
  Cl  Cl5  1  0.190  0.823  0.650  1.0
  Cl  Cl6  1  0.500  0.548  0.250  1.0
  Cl  Cl7  1  0.500  0.452  0.750  1.0
  O  O8  1  0.209  0.024  0.708  1.0
  O  O9  1  0.791  0.976  0.292  1.0
  O  O10  1  0.791  0.024  0.792  1.0
  O  O11  1  0.209  0.976  0.208  1.0
  O  O12  1  0.936  0.521  0.043  1.0
  O  O13  1  0.064  0.479  0.957  1.0
  O  O14  1  0.064  0.521  0.457  1.0
  O  O15  1  0.936  0.479  0.543  1.0
  O  O16  1  0.629  0.655  0.162  1.0
  O  O17  1  0.371  0.345  0.838  1.0
  O  O18  1  0.371  0.655  0.338  1.0
  O  O19  1  0.629  0.345  0.662  1.0
[/CIF]
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