The compound described by CdV2O6 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(1), and three equivalent O(3) atoms. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form edge-sharing CdO6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Cd(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2CdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.027
_cell_length_b   5.027
_cell_length_c   6.979
_cell_angle_alpha   68.496
_cell_angle_beta   68.496
_cell_angle_gamma   41.387
_symmetry_Int_Tables_number   1
_cell_volume   107.273
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.183  0.183  0.365  1.0
  V  V1  1  0.817  0.817  0.635  1.0
  Cd  Cd2  1  0.000  0.000  0.000  1.0
  O  O3  1  0.025  0.025  0.306  1.0
  O  O4  1  0.975  0.975  0.694  1.0
  O  O5  1  0.333  0.333  0.130  1.0
  O  O6  1  0.667  0.667  0.870  1.0
  O  O7  1  0.306  0.306  0.562  1.0
  O  O8  1  0.694  0.694  0.438  1.0
[/CIF]
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The compound described by CdV2O6 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(1), and three equivalent O(3) atoms. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form edge-sharing CdO6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Cd(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2CdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.027
_cell_length_b   5.027
_cell_length_c   6.979
_cell_angle_alpha   68.496
_cell_angle_beta   68.496
_cell_angle_gamma   41.387
_symmetry_Int_Tables_number   1
_cell_volume   107.273
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.183  0.183  0.365  1.0
  V  V1  1  0.817  0.817  0.635  1.0
  Cd  Cd2  1  0.000  0.000  0.000  1.0
  O  O3  1  0.025  0.025  0.306  1.0
  O  O4  1  0.975  0.975  0.694  1.0
  O  O5  1  0.333  0.333  0.130  1.0
  O  O6  1  0.667  0.667  0.870  1.0
  O  O7  1  0.306  0.306  0.562  1.0
  O  O8  1  0.694  0.694  0.438  1.0
[/CIF]
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