The crystal structure described by PbC6(N2S)6(ClO4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hypochlorous acid;trihydrate molecules and one PbC6(N2S)6 cluster. In the PbC6(N2S)6 cluster, Pb(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one N(5), one N(6), and one S(3) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one C(2) and one S(1) atom. In the fifth N site, N(5) is bonded in a 2-coordinate geometry to one C(3) and one N(6) atom. In the sixth N site, N(6) is bonded in a 2-coordinate geometry to one C(3) and one N(5) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Pb(1), one N(2), and one N(4) atom. In the second S site, S(2) is bonded in a single-bond geometry to one Pb(1) and one N(3) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to one Pb(1) and one C(3) atom. is represented by the CIF card [CIF]
data_PbC6S6N12(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.776
_cell_length_b   11.777
_cell_length_c   6.104
_cell_angle_alpha   102.827
_cell_angle_beta   100.828
_cell_angle_gamma   108.941
_symmetry_Int_Tables_number   1
_cell_volume   749.036
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.640  0.088  0.048  1.0
  C  C2  1  0.360  0.912  0.952  1.0
  C  C3  1  0.728  0.742  0.595  1.0
  C  C4  1  0.272  0.258  0.405  1.0
  C  C5  1  0.056  0.689  0.815  1.0
  C  C6  1  0.944  0.311  0.185  1.0
  S  S7  1  0.740  0.918  0.032  1.0
  S  S8  1  0.260  0.082  0.968  1.0
  S  S9  1  0.897  0.887  0.464  1.0
  S  S10  1  0.103  0.113  0.536  1.0
  S  S11  1  0.003  0.743  0.019  1.0
  S  S12  1  0.997  0.257  0.981  1.0
  N  N13  1  0.578  0.145  0.097  1.0
  N  N14  1  0.422  0.855  0.903  1.0
  N  N15  1  0.722  0.040  0.003  1.0
  N  N16  1  0.278  0.960  0.997  1.0
  N  N17  1  0.771  0.764  0.425  1.0
  N  N18  1  0.229  0.236  0.575  1.0
  N  N19  1  0.683  0.723  0.750  1.0
  N  N20  1  0.317  0.277  0.250  1.0
  N  N21  1  0.087  0.595  0.690  1.0
  N  N22  1  0.913  0.405  0.310  1.0
  N  N23  1  0.105  0.695  0.625  1.0
  N  N24  1  0.895  0.305  0.375  1.0
  Cl  Cl25  1  0.646  0.389  0.767  1.0
  Cl  Cl26  1  0.354  0.611  0.233  1.0
  O  O27  1  0.583  0.436  0.599  1.0
  O  O28  1  0.417  0.564  0.401  1.0
  O  O29  1  0.605  0.252  0.663  1.0
  O  O30  1  0.395  0.748  0.337  1.0
  O  O31  1  0.781  0.449  0.817  1.0
  O  O32  1  0.219  0.551  0.183  1.0
  O  O33  1  0.607  0.413  0.980  1.0
  O  O34  1  0.393  0.587  0.020  1.0
[/CIF]
.
The crystal structure described by PbC6(N2S)6(ClO4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hypochlorous acid;trihydrate molecules and one PbC6(N2S)6 cluster. In the PbC6(N2S)6 cluster, Pb(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one N(5), one N(6), and one S(3) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one C(2) and one S(1) atom. In the fifth N site, N(5) is bonded in a 2-coordinate geometry to one C(3) and one N(6) atom. In the sixth N site, N(6) is bonded in a 2-coordinate geometry to one C(3) and one N(5) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Pb(1), one N(2), and one N(4) atom. In the second S site, S(2) is bonded in a single-bond geometry to one Pb(1) and one N(3) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to one Pb(1) and one C(3) atom. is represented by the CIF card [CIF]
data_PbC6S6N12(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.776
_cell_length_b   11.777
_cell_length_c   6.104
_cell_angle_alpha   102.827
_cell_angle_beta   100.828
_cell_angle_gamma   108.941
_symmetry_Int_Tables_number   1
_cell_volume   749.036
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.640  0.088  0.048  1.0
  C  C2  1  0.360  0.912  0.952  1.0
  C  C3  1  0.728  0.742  0.595  1.0
  C  C4  1  0.272  0.258  0.405  1.0
  C  C5  1  0.056  0.689  0.815  1.0
  C  C6  1  0.944  0.311  0.185  1.0
  S  S7  1  0.740  0.918  0.032  1.0
  S  S8  1  0.260  0.082  0.968  1.0
  S  S9  1  0.897  0.887  0.464  1.0
  S  S10  1  0.103  0.113  0.536  1.0
  S  S11  1  0.003  0.743  0.019  1.0
  S  S12  1  0.997  0.257  0.981  1.0
  N  N13  1  0.578  0.145  0.097  1.0
  N  N14  1  0.422  0.855  0.903  1.0
  N  N15  1  0.722  0.040  0.003  1.0
  N  N16  1  0.278  0.960  0.997  1.0
  N  N17  1  0.771  0.764  0.425  1.0
  N  N18  1  0.229  0.236  0.575  1.0
  N  N19  1  0.683  0.723  0.750  1.0
  N  N20  1  0.317  0.277  0.250  1.0
  N  N21  1  0.087  0.595  0.690  1.0
  N  N22  1  0.913  0.405  0.310  1.0
  N  N23  1  0.105  0.695  0.625  1.0
  N  N24  1  0.895  0.305  0.375  1.0
  Cl  Cl25  1  0.646  0.389  0.767  1.0
  Cl  Cl26  1  0.354  0.611  0.233  1.0
  O  O27  1  0.583  0.436  0.599  1.0
  O  O28  1  0.417  0.564  0.401  1.0
  O  O29  1  0.605  0.252  0.663  1.0
  O  O30  1  0.395  0.748  0.337  1.0
  O  O31  1  0.781  0.449  0.817  1.0
  O  O32  1  0.219  0.551  0.183  1.0
  O  O33  1  0.607  0.413  0.980  1.0
  O  O34  1  0.393  0.587  0.020  1.0
[/CIF]
.