The structure described by KTh6F25 crystallizes in the trigonal R-3m space group. K(1) is bonded in a cuboctahedral geometry to six equivalent F(1) and six equivalent F(4) atoms. Th(1) is bonded in a 9-coordinate geometry to one F(2), one F(3), one F(6), two equivalent F(1), two equivalent F(4), and two equivalent F(5) atoms. There are six inequivalent F sites. In the first F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent Th(1) atoms. In the second F site, F(6) is bonded in a trigonal non-coplanar geometry to three equivalent Th(1) atoms. In the third F site, F(1) is bonded in a distorted trigonal planar geometry to one K(1) and two equivalent Th(1) atoms. In the fourth F site, F(2) is bonded in a trigonal non-coplanar geometry to three equivalent Th(1) atoms. In the fifth F site, F(3) is bonded in a linear geometry to two equivalent Th(1) atoms. In the sixth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one K(1) and two equivalent Th(1) atoms. is represented by the CIF card [CIF]
data_KTh6F25
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.706
_cell_length_b   9.706
_cell_length_c   9.706
_cell_angle_alpha   50.595
_cell_angle_beta   50.595
_cell_angle_gamma   50.595
_symmetry_Int_Tables_number   1
_cell_volume   503.142
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.000  1.0
  Th  Th1  1  0.909  0.408  0.408  1.0
  Th  Th2  1  0.408  0.909  0.408  1.0
  Th  Th3  1  0.592  0.091  0.592  1.0
  Th  Th4  1  0.592  0.592  0.091  1.0
  Th  Th5  1  0.091  0.592  0.592  1.0
  Th  Th6  1  0.408  0.408  0.909  1.0
  F  F7  1  0.252  0.252  0.689  1.0
  F  F8  1  0.689  0.252  0.252  1.0
  F  F9  1  0.252  0.689  0.252  1.0
  F  F10  1  0.748  0.311  0.748  1.0
  F  F11  1  0.748  0.748  0.311  1.0
  F  F12  1  0.311  0.748  0.748  1.0
  F  F13  1  0.550  0.550  0.550  1.0
  F  F14  1  0.500  0.500  0.000  1.0
  F  F15  1  0.500  0.000  0.500  1.0
  F  F16  1  0.000  0.500  0.500  1.0
  F  F17  1  0.554  0.127  0.127  1.0
  F  F18  1  0.127  0.127  0.554  1.0
  F  F19  1  0.127  0.554  0.127  1.0
  F  F20  1  0.873  0.446  0.873  1.0
  F  F21  1  0.446  0.873  0.873  1.0
  F  F22  1  0.873  0.873  0.446  1.0
  F  F23  1  0.176  0.824  0.500  1.0
  F  F24  1  0.824  0.500  0.176  1.0
  F  F25  1  0.500  0.176  0.824  1.0
  F  F26  1  0.824  0.176  0.500  1.0
  F  F27  1  0.176  0.500  0.824  1.0
  F  F28  1  0.500  0.824  0.176  1.0
  F  F29  1  0.210  0.210  0.210  1.0
  F  F30  1  0.790  0.790  0.790  1.0
  F  F31  1  0.450  0.450  0.450  1.0
[/CIF]
.
The structure described by KTh6F25 crystallizes in the trigonal R-3m space group. K(1) is bonded in a cuboctahedral geometry to six equivalent F(1) and six equivalent F(4) atoms. Th(1) is bonded in a 9-coordinate geometry to one F(2), one F(3), one F(6), two equivalent F(1), two equivalent F(4), and two equivalent F(5) atoms. There are six inequivalent F sites. In the first F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent Th(1) atoms. In the second F site, F(6) is bonded in a trigonal non-coplanar geometry to three equivalent Th(1) atoms. In the third F site, F(1) is bonded in a distorted trigonal planar geometry to one K(1) and two equivalent Th(1) atoms. In the fourth F site, F(2) is bonded in a trigonal non-coplanar geometry to three equivalent Th(1) atoms. In the fifth F site, F(3) is bonded in a linear geometry to two equivalent Th(1) atoms. In the sixth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one K(1) and two equivalent Th(1) atoms. is represented by the CIF card [CIF]
data_KTh6F25
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.706
_cell_length_b   9.706
_cell_length_c   9.706
_cell_angle_alpha   50.595
_cell_angle_beta   50.595
_cell_angle_gamma   50.595
_symmetry_Int_Tables_number   1
_cell_volume   503.142
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.000  1.0
  Th  Th1  1  0.909  0.408  0.408  1.0
  Th  Th2  1  0.408  0.909  0.408  1.0
  Th  Th3  1  0.592  0.091  0.592  1.0
  Th  Th4  1  0.592  0.592  0.091  1.0
  Th  Th5  1  0.091  0.592  0.592  1.0
  Th  Th6  1  0.408  0.408  0.909  1.0
  F  F7  1  0.252  0.252  0.689  1.0
  F  F8  1  0.689  0.252  0.252  1.0
  F  F9  1  0.252  0.689  0.252  1.0
  F  F10  1  0.748  0.311  0.748  1.0
  F  F11  1  0.748  0.748  0.311  1.0
  F  F12  1  0.311  0.748  0.748  1.0
  F  F13  1  0.550  0.550  0.550  1.0
  F  F14  1  0.500  0.500  0.000  1.0
  F  F15  1  0.500  0.000  0.500  1.0
  F  F16  1  0.000  0.500  0.500  1.0
  F  F17  1  0.554  0.127  0.127  1.0
  F  F18  1  0.127  0.127  0.554  1.0
  F  F19  1  0.127  0.554  0.127  1.0
  F  F20  1  0.873  0.446  0.873  1.0
  F  F21  1  0.446  0.873  0.873  1.0
  F  F22  1  0.873  0.873  0.446  1.0
  F  F23  1  0.176  0.824  0.500  1.0
  F  F24  1  0.824  0.500  0.176  1.0
  F  F25  1  0.500  0.176  0.824  1.0
  F  F26  1  0.824  0.176  0.500  1.0
  F  F27  1  0.176  0.500  0.824  1.0
  F  F28  1  0.500  0.824  0.176  1.0
  F  F29  1  0.210  0.210  0.210  1.0
  F  F30  1  0.790  0.790  0.790  1.0
  F  F31  1  0.450  0.450  0.450  1.0
[/CIF]
.