The material structure described by KSm(MoO4)2 crystallizes in the orthorhombic Pbcn space group. K(1) is bonded in a 6-coordinate geometry to two equivalent O(4) and four equivalent O(1) atoms. Sm(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one Mo(1) atom. In the second O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Sm(1), and one Mo(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Mo(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_KSm(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.214
_cell_length_b   8.279
_cell_length_c   18.580
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   802.102
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.750  0.230  1.0
  K  K1  1  0.000  0.250  0.770  1.0
  K  K2  1  0.500  0.250  0.270  1.0
  K  K3  1  0.500  0.750  0.730  1.0
  Sm  Sm4  1  0.000  0.750  0.994  1.0
  Sm  Sm5  1  0.000  0.250  0.006  1.0
  Sm  Sm6  1  0.500  0.250  0.506  1.0
  Sm  Sm7  1  0.500  0.750  0.494  1.0
  Mo  Mo8  1  0.977  0.984  0.601  1.0
  Mo  Mo9  1  0.023  0.016  0.399  1.0
  Mo  Mo10  1  0.523  0.484  0.899  1.0
  Mo  Mo11  1  0.023  0.516  0.601  1.0
  Mo  Mo12  1  0.477  0.516  0.101  1.0
  Mo  Mo13  1  0.977  0.484  0.399  1.0
  Mo  Mo14  1  0.477  0.016  0.899  1.0
  Mo  Mo15  1  0.523  0.984  0.101  1.0
  O  O16  1  0.898  0.525  0.689  1.0
  O  O17  1  0.102  0.475  0.311  1.0
  O  O18  1  0.602  0.025  0.811  1.0
  O  O19  1  0.102  0.975  0.689  1.0
  O  O20  1  0.398  0.975  0.189  1.0
  O  O21  1  0.898  0.025  0.311  1.0
  O  O22  1  0.398  0.475  0.811  1.0
  O  O23  1  0.602  0.525  0.189  1.0
  O  O24  1  0.726  0.659  0.900  1.0
  O  O25  1  0.274  0.341  0.100  1.0
  O  O26  1  0.774  0.159  0.600  1.0
  O  O27  1  0.274  0.841  0.900  1.0
  O  O28  1  0.226  0.841  0.400  1.0
  O  O29  1  0.726  0.159  0.100  1.0
  O  O30  1  0.226  0.341  0.600  1.0
  O  O31  1  0.774  0.659  0.400  1.0
  O  O32  1  0.747  0.997  0.964  1.0
  O  O33  1  0.253  0.003  0.036  1.0
  O  O34  1  0.753  0.497  0.536  1.0
  O  O35  1  0.253  0.503  0.964  1.0
  O  O36  1  0.247  0.503  0.464  1.0
  O  O37  1  0.747  0.497  0.036  1.0
  O  O38  1  0.247  0.003  0.536  1.0
  O  O39  1  0.753  0.997  0.464  1.0
  O  O40  1  0.759  0.813  0.593  1.0
  O  O41  1  0.241  0.187  0.407  1.0
  O  O42  1  0.741  0.313  0.907  1.0
  O  O43  1  0.241  0.687  0.593  1.0
  O  O44  1  0.259  0.687  0.093  1.0
  O  O45  1  0.759  0.313  0.407  1.0
  O  O46  1  0.259  0.187  0.907  1.0
  O  O47  1  0.741  0.813  0.093  1.0
[/CIF]
.
The material structure described by KSm(MoO4)2 crystallizes in the orthorhombic Pbcn space group. K(1) is bonded in a 6-coordinate geometry to two equivalent O(4) and four equivalent O(1) atoms. Sm(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(4), and four equivalent O(3) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one Mo(1) atom. In the second O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Sm(1), and one Mo(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Mo(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_KSm(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.214
_cell_length_b   8.279
_cell_length_c   18.580
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   802.102
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.750  0.230  1.0
  K  K1  1  0.000  0.250  0.770  1.0
  K  K2  1  0.500  0.250  0.270  1.0
  K  K3  1  0.500  0.750  0.730  1.0
  Sm  Sm4  1  0.000  0.750  0.994  1.0
  Sm  Sm5  1  0.000  0.250  0.006  1.0
  Sm  Sm6  1  0.500  0.250  0.506  1.0
  Sm  Sm7  1  0.500  0.750  0.494  1.0
  Mo  Mo8  1  0.977  0.984  0.601  1.0
  Mo  Mo9  1  0.023  0.016  0.399  1.0
  Mo  Mo10  1  0.523  0.484  0.899  1.0
  Mo  Mo11  1  0.023  0.516  0.601  1.0
  Mo  Mo12  1  0.477  0.516  0.101  1.0
  Mo  Mo13  1  0.977  0.484  0.399  1.0
  Mo  Mo14  1  0.477  0.016  0.899  1.0
  Mo  Mo15  1  0.523  0.984  0.101  1.0
  O  O16  1  0.898  0.525  0.689  1.0
  O  O17  1  0.102  0.475  0.311  1.0
  O  O18  1  0.602  0.025  0.811  1.0
  O  O19  1  0.102  0.975  0.689  1.0
  O  O20  1  0.398  0.975  0.189  1.0
  O  O21  1  0.898  0.025  0.311  1.0
  O  O22  1  0.398  0.475  0.811  1.0
  O  O23  1  0.602  0.525  0.189  1.0
  O  O24  1  0.726  0.659  0.900  1.0
  O  O25  1  0.274  0.341  0.100  1.0
  O  O26  1  0.774  0.159  0.600  1.0
  O  O27  1  0.274  0.841  0.900  1.0
  O  O28  1  0.226  0.841  0.400  1.0
  O  O29  1  0.726  0.159  0.100  1.0
  O  O30  1  0.226  0.341  0.600  1.0
  O  O31  1  0.774  0.659  0.400  1.0
  O  O32  1  0.747  0.997  0.964  1.0
  O  O33  1  0.253  0.003  0.036  1.0
  O  O34  1  0.753  0.497  0.536  1.0
  O  O35  1  0.253  0.503  0.964  1.0
  O  O36  1  0.247  0.503  0.464  1.0
  O  O37  1  0.747  0.497  0.036  1.0
  O  O38  1  0.247  0.003  0.536  1.0
  O  O39  1  0.753  0.997  0.464  1.0
  O  O40  1  0.759  0.813  0.593  1.0
  O  O41  1  0.241  0.187  0.407  1.0
  O  O42  1  0.741  0.313  0.907  1.0
  O  O43  1  0.241  0.687  0.593  1.0
  O  O44  1  0.259  0.687  0.093  1.0
  O  O45  1  0.759  0.313  0.407  1.0
  O  O46  1  0.259  0.187  0.907  1.0
  O  O47  1  0.741  0.813  0.093  1.0
[/CIF]
.