The material structure described by Ti(GeN)4 crystallizes in the triclinic P-1 space group. Ti(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent N(2) atoms. In the second Ge site, Ge(2) is bonded in a distorted water-like geometry to one N(2) and one N(3) atom. In the third Ge site, Ge(3) is bonded in a 3-coordinate geometry to one N(4) and two equivalent N(1) atoms. In the fourth Ge site, Ge(4) is bonded in a 3-coordinate geometry to one N(3) and two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted see-saw-like geometry to one Ti(1), one Ge(1), and two equivalent Ge(3) atoms. In the second N site, N(2) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Ge(2), and two equivalent Ge(1) atoms. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ge(2), and one Ge(4) atom. In the fourth N site, N(4) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Ge(3), and two equivalent Ge(4) atoms. is represented by the CIF file [CIF]
data_Ti(GeN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.234
_cell_length_b   7.022
_cell_length_c   7.802
_cell_angle_alpha   78.161
_cell_angle_beta   84.376
_cell_angle_gamma   63.627
_symmetry_Int_Tables_number   1
_cell_volume   251.414
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.790  0.881  0.758  1.0
  Ti  Ti1  1  0.210  0.119  0.242  1.0
  Ge  Ge2  1  0.796  0.559  0.140  1.0
  Ge  Ge3  1  0.204  0.441  0.860  1.0
  Ge  Ge4  1  0.726  0.197  0.945  1.0
  Ge  Ge5  1  0.274  0.803  0.055  1.0
  Ge  Ge6  1  0.702  0.543  0.551  1.0
  Ge  Ge7  1  0.298  0.457  0.449  1.0
  Ge  Ge8  1  0.258  0.995  0.627  1.0
  Ge  Ge9  1  0.742  0.005  0.373  1.0
  N  N10  1  0.013  0.602  0.642  1.0
  N  N11  1  0.987  0.398  0.358  1.0
  N  N12  1  0.033  0.687  0.984  1.0
  N  N13  1  0.967  0.313  0.016  1.0
  N  N14  1  0.481  0.826  0.839  1.0
  N  N15  1  0.519  0.174  0.161  1.0
  N  N16  1  0.498  0.848  0.422  1.0
  N  N17  1  0.502  0.152  0.578  1.0
[/CIF]
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The material structure described by Ti(GeN)4 crystallizes in the triclinic P-1 space group. Ti(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent N(2) atoms. In the second Ge site, Ge(2) is bonded in a distorted water-like geometry to one N(2) and one N(3) atom. In the third Ge site, Ge(3) is bonded in a 3-coordinate geometry to one N(4) and two equivalent N(1) atoms. In the fourth Ge site, Ge(4) is bonded in a 3-coordinate geometry to one N(3) and two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted see-saw-like geometry to one Ti(1), one Ge(1), and two equivalent Ge(3) atoms. In the second N site, N(2) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Ge(2), and two equivalent Ge(1) atoms. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ge(2), and one Ge(4) atom. In the fourth N site, N(4) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Ge(3), and two equivalent Ge(4) atoms. is represented by the CIF file [CIF]
data_Ti(GeN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.234
_cell_length_b   7.022
_cell_length_c   7.802
_cell_angle_alpha   78.161
_cell_angle_beta   84.376
_cell_angle_gamma   63.627
_symmetry_Int_Tables_number   1
_cell_volume   251.414
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.790  0.881  0.758  1.0
  Ti  Ti1  1  0.210  0.119  0.242  1.0
  Ge  Ge2  1  0.796  0.559  0.140  1.0
  Ge  Ge3  1  0.204  0.441  0.860  1.0
  Ge  Ge4  1  0.726  0.197  0.945  1.0
  Ge  Ge5  1  0.274  0.803  0.055  1.0
  Ge  Ge6  1  0.702  0.543  0.551  1.0
  Ge  Ge7  1  0.298  0.457  0.449  1.0
  Ge  Ge8  1  0.258  0.995  0.627  1.0
  Ge  Ge9  1  0.742  0.005  0.373  1.0
  N  N10  1  0.013  0.602  0.642  1.0
  N  N11  1  0.987  0.398  0.358  1.0
  N  N12  1  0.033  0.687  0.984  1.0
  N  N13  1  0.967  0.313  0.016  1.0
  N  N14  1  0.481  0.826  0.839  1.0
  N  N15  1  0.519  0.174  0.161  1.0
  N  N16  1  0.498  0.848  0.422  1.0
  N  N17  1  0.502  0.152  0.578  1.0
[/CIF]
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