The compound described by Ag3C2(NO3)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one C(1), one O(1), one O(2), and one O(3) atom. C(1) is bonded in a distorted T-shaped geometry to one Ag(1), one Ag(2), and one C(1) atom. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one N(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ag(2) and one N(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ag(2) and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3C2(NO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.577
_cell_length_b   5.202
_cell_length_c   7.461
_cell_angle_alpha   54.401
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.931
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.500  0.000  0.500  1.0
  Ag  Ag2  1  0.397  0.602  0.169  1.0
  Ag  Ag3  1  0.603  0.398  0.831  1.0
  Ag  Ag4  1  0.897  0.398  0.331  1.0
  Ag  Ag5  1  0.103  0.602  0.669  1.0
  C  C6  1  0.987  0.574  0.040  1.0
  C  C7  1  0.013  0.426  0.960  1.0
  C  C8  1  0.487  0.426  0.460  1.0
  C  C9  1  0.513  0.574  0.540  1.0
  N  N10  1  0.674  0.691  0.065  1.0
  N  N11  1  0.326  0.309  0.935  1.0
  N  N12  1  0.174  0.309  0.435  1.0
  N  N13  1  0.826  0.691  0.565  1.0
  O  O14  1  0.903  0.865  0.439  1.0
  O  O15  1  0.097  0.135  0.561  1.0
  O  O16  1  0.403  0.135  0.061  1.0
  O  O17  1  0.597  0.865  0.939  1.0
  O  O18  1  0.686  0.417  0.107  1.0
  O  O19  1  0.314  0.583  0.893  1.0
  O  O20  1  0.186  0.583  0.393  1.0
  O  O21  1  0.814  0.417  0.607  1.0
  O  O22  1  0.735  0.789  0.145  1.0
  O  O23  1  0.265  0.211  0.855  1.0
  O  O24  1  0.235  0.211  0.355  1.0
  O  O25  1  0.765  0.789  0.645  1.0
[/CIF]
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The compound described by Ag3C2(NO3)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one C(1), one O(1), one O(2), and one O(3) atom. C(1) is bonded in a distorted T-shaped geometry to one Ag(1), one Ag(2), and one C(1) atom. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one N(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ag(2) and one N(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ag(2) and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3C2(NO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.577
_cell_length_b   5.202
_cell_length_c   7.461
_cell_angle_alpha   54.401
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.931
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.500  0.000  0.500  1.0
  Ag  Ag2  1  0.397  0.602  0.169  1.0
  Ag  Ag3  1  0.603  0.398  0.831  1.0
  Ag  Ag4  1  0.897  0.398  0.331  1.0
  Ag  Ag5  1  0.103  0.602  0.669  1.0
  C  C6  1  0.987  0.574  0.040  1.0
  C  C7  1  0.013  0.426  0.960  1.0
  C  C8  1  0.487  0.426  0.460  1.0
  C  C9  1  0.513  0.574  0.540  1.0
  N  N10  1  0.674  0.691  0.065  1.0
  N  N11  1  0.326  0.309  0.935  1.0
  N  N12  1  0.174  0.309  0.435  1.0
  N  N13  1  0.826  0.691  0.565  1.0
  O  O14  1  0.903  0.865  0.439  1.0
  O  O15  1  0.097  0.135  0.561  1.0
  O  O16  1  0.403  0.135  0.061  1.0
  O  O17  1  0.597  0.865  0.939  1.0
  O  O18  1  0.686  0.417  0.107  1.0
  O  O19  1  0.314  0.583  0.893  1.0
  O  O20  1  0.186  0.583  0.393  1.0
  O  O21  1  0.814  0.417  0.607  1.0
  O  O22  1  0.735  0.789  0.145  1.0
  O  O23  1  0.265  0.211  0.855  1.0
  O  O24  1  0.235  0.211  0.355  1.0
  O  O25  1  0.765  0.789  0.645  1.0
[/CIF]
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