The material structure described by Ag6HgNO11 crystallizes in the orthorhombic Fmm2 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted square co-planar geometry to one O(4), two equivalent O(1), and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. In the third Ag site, Ag(3) is bonded in a 6-coordinate geometry to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms. Hg(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. N(1) is bonded in a trigonal planar geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Hg(1) atom to form a mixture of corner and edge-sharing OAg3Hg tetrahedra. In the second O site, O(2) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Hg(1) atom to form a mixture of distorted corner and edge-sharing OAg3Hg tetrahedra. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(3) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Ag(1), two equivalent Ag(3), and one N(1) atom. is represented by the CIF file [CIF]
data_Ag6HgNO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.220
_cell_length_b   7.150
_cell_length_c   7.104
_cell_angle_alpha   60.866
_cell_angle_beta   59.881
_cell_angle_gamma   59.253
_symmetry_Int_Tables_number   1
_cell_volume   259.173
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.996  0.500  1.0
  Ag  Ag1  1  0.499  0.499  0.001  1.0
  Ag  Ag2  1  0.500  0.003  0.997  1.0
  Ag  Ag3  1  0.996  0.500  0.004  1.0
  Ag  Ag4  1  0.999  0.999  0.501  1.0
  Ag  Ag5  1  0.003  0.500  0.500  1.0
  Hg  Hg6  1  0.001  0.001  0.999  1.0
  N  N7  1  0.473  0.473  0.527  1.0
  O  O8  1  0.575  0.143  0.143  1.0
  O  O9  1  0.136  0.142  0.148  1.0
  O  O10  1  0.143  0.575  0.138  1.0
  O  O11  1  0.142  0.136  0.574  1.0
  O  O12  1  0.426  0.852  0.858  1.0
  O  O13  1  0.862  0.857  0.857  1.0
  O  O14  1  0.852  0.426  0.864  1.0
  O  O15  1  0.857  0.862  0.425  1.0
  O  O16  1  0.424  0.641  0.359  1.0
  O  O17  1  0.349  0.349  0.651  1.0
  O  O18  1  0.641  0.424  0.576  1.0
[/CIF]
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The material structure described by Ag6HgNO11 crystallizes in the orthorhombic Fmm2 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted square co-planar geometry to one O(4), two equivalent O(1), and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. In the third Ag site, Ag(3) is bonded in a 6-coordinate geometry to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms. Hg(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. N(1) is bonded in a trigonal planar geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Hg(1) atom to form a mixture of corner and edge-sharing OAg3Hg tetrahedra. In the second O site, O(2) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Hg(1) atom to form a mixture of distorted corner and edge-sharing OAg3Hg tetrahedra. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(3) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Ag(1), two equivalent Ag(3), and one N(1) atom. is represented by the CIF file [CIF]
data_Ag6HgNO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.220
_cell_length_b   7.150
_cell_length_c   7.104
_cell_angle_alpha   60.866
_cell_angle_beta   59.881
_cell_angle_gamma   59.253
_symmetry_Int_Tables_number   1
_cell_volume   259.173
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.996  0.500  1.0
  Ag  Ag1  1  0.499  0.499  0.001  1.0
  Ag  Ag2  1  0.500  0.003  0.997  1.0
  Ag  Ag3  1  0.996  0.500  0.004  1.0
  Ag  Ag4  1  0.999  0.999  0.501  1.0
  Ag  Ag5  1  0.003  0.500  0.500  1.0
  Hg  Hg6  1  0.001  0.001  0.999  1.0
  N  N7  1  0.473  0.473  0.527  1.0
  O  O8  1  0.575  0.143  0.143  1.0
  O  O9  1  0.136  0.142  0.148  1.0
  O  O10  1  0.143  0.575  0.138  1.0
  O  O11  1  0.142  0.136  0.574  1.0
  O  O12  1  0.426  0.852  0.858  1.0
  O  O13  1  0.862  0.857  0.857  1.0
  O  O14  1  0.852  0.426  0.864  1.0
  O  O15  1  0.857  0.862  0.425  1.0
  O  O16  1  0.424  0.641  0.359  1.0
  O  O17  1  0.349  0.349  0.651  1.0
  O  O18  1  0.641  0.424  0.576  1.0
[/CIF]
.