The material described by V2Cd(PO5)2 crystallizes in the orthorhombic Fdd2 space group. V(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. Cd(1) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-59°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Cd(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one Cd(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_V2Cd(PO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.977
_cell_length_b   8.894
_cell_length_c   6.848
_cell_angle_alpha   77.459
_cell_angle_beta   60.476
_cell_angle_gamma   42.064
_symmetry_Int_Tables_number   1
_cell_volume   342.529
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.635  0.625  0.094  1.0
  V  V1  1  0.156  0.604  0.615  1.0
  V  V2  1  0.646  0.094  0.625  1.0
  V  V3  1  0.625  0.615  0.604  1.0
  Cd  Cd4  1  0.001  0.999  0.999  1.0
  Cd  Cd5  1  0.251  0.249  0.249  1.0
  P  P6  1  0.797  0.786  0.202  1.0
  P  P7  1  0.048  0.035  0.453  1.0
  P  P8  1  0.215  0.202  0.786  1.0
  P  P9  1  0.464  0.453  0.035  1.0
  O  O10  1  0.868  0.599  0.344  1.0
  O  O11  1  0.390  0.639  0.891  1.0
  O  O12  1  0.359  0.170  0.860  1.0
  O  O13  1  0.974  0.333  0.997  1.0
  O  O14  1  0.335  0.965  0.690  1.0
  O  O15  1  0.917  0.276  0.554  1.0
  O  O16  1  0.673  0.659  0.823  1.0
  O  O17  1  0.651  0.382  0.061  1.0
  O  O18  1  0.844  0.823  0.659  1.0
  O  O19  1  0.696  0.997  0.333  1.0
  O  O20  1  0.253  0.554  0.276  1.0
  O  O21  1  0.591  0.577  0.406  1.0
  O  O22  1  0.189  0.344  0.599  1.0
  O  O23  1  0.906  0.061  0.382  1.0
  O  O24  1  0.560  0.241  0.915  1.0
  O  O25  1  0.427  0.406  0.577  1.0
  O  O26  1  0.080  0.891  0.639  1.0
  O  O27  1  0.009  0.690  0.965  1.0
  O  O28  1  0.611  0.860  0.170  1.0
  O  O29  1  0.285  0.915  0.241  1.0
[/CIF]
.
The material described by V2Cd(PO5)2 crystallizes in the orthorhombic Fdd2 space group. V(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. Cd(1) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-59°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Cd(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one Cd(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_V2Cd(PO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.977
_cell_length_b   8.894
_cell_length_c   6.848
_cell_angle_alpha   77.459
_cell_angle_beta   60.476
_cell_angle_gamma   42.064
_symmetry_Int_Tables_number   1
_cell_volume   342.529
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.635  0.625  0.094  1.0
  V  V1  1  0.156  0.604  0.615  1.0
  V  V2  1  0.646  0.094  0.625  1.0
  V  V3  1  0.625  0.615  0.604  1.0
  Cd  Cd4  1  0.001  0.999  0.999  1.0
  Cd  Cd5  1  0.251  0.249  0.249  1.0
  P  P6  1  0.797  0.786  0.202  1.0
  P  P7  1  0.048  0.035  0.453  1.0
  P  P8  1  0.215  0.202  0.786  1.0
  P  P9  1  0.464  0.453  0.035  1.0
  O  O10  1  0.868  0.599  0.344  1.0
  O  O11  1  0.390  0.639  0.891  1.0
  O  O12  1  0.359  0.170  0.860  1.0
  O  O13  1  0.974  0.333  0.997  1.0
  O  O14  1  0.335  0.965  0.690  1.0
  O  O15  1  0.917  0.276  0.554  1.0
  O  O16  1  0.673  0.659  0.823  1.0
  O  O17  1  0.651  0.382  0.061  1.0
  O  O18  1  0.844  0.823  0.659  1.0
  O  O19  1  0.696  0.997  0.333  1.0
  O  O20  1  0.253  0.554  0.276  1.0
  O  O21  1  0.591  0.577  0.406  1.0
  O  O22  1  0.189  0.344  0.599  1.0
  O  O23  1  0.906  0.061  0.382  1.0
  O  O24  1  0.560  0.241  0.915  1.0
  O  O25  1  0.427  0.406  0.577  1.0
  O  O26  1  0.080  0.891  0.639  1.0
  O  O27  1  0.009  0.690  0.965  1.0
  O  O28  1  0.611  0.860  0.170  1.0
  O  O29  1  0.285  0.915  0.241  1.0
[/CIF]
.