The compound described by TiSi crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded in a 7-coordinate geometry to seven equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to seven equivalent Ti(1) and two equivalent Si(1) atoms. is represented by the CIF file [CIF]
data_TiSi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.632
_cell_length_b   4.993
_cell_length_c   6.512
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   118.100
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.250  0.372  0.676  1.0
  Ti  Ti1  1  0.750  0.628  0.324  1.0
  Ti  Ti2  1  0.750  0.872  0.824  1.0
  Ti  Ti3  1  0.250  0.128  0.176  1.0
  Si  Si4  1  0.250  0.855  0.544  1.0
  Si  Si5  1  0.750  0.145  0.456  1.0
  Si  Si6  1  0.750  0.355  0.956  1.0
  Si  Si7  1  0.250  0.645  0.044  1.0
[/CIF]
.
The compound described by TiSi crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded in a 7-coordinate geometry to seven equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to seven equivalent Ti(1) and two equivalent Si(1) atoms. is represented by the CIF file [CIF]
data_TiSi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.632
_cell_length_b   4.993
_cell_length_c   6.512
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   118.100
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.250  0.372  0.676  1.0
  Ti  Ti1  1  0.750  0.628  0.324  1.0
  Ti  Ti2  1  0.750  0.872  0.824  1.0
  Ti  Ti3  1  0.250  0.128  0.176  1.0
  Si  Si4  1  0.250  0.855  0.544  1.0
  Si  Si5  1  0.750  0.145  0.456  1.0
  Si  Si6  1  0.750  0.355  0.956  1.0
  Si  Si7  1  0.250  0.645  0.044  1.0
[/CIF]
.