The compound described by AgIn(MoO4)2 crystallizes in the monoclinic C2 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(11), two equivalent O(5), and two equivalent O(9) atoms to form distorted MoO6 octahedra that share corners with two equivalent Ag(3)O6 octahedra and corners with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the second Mo site, Mo(2) is bonded to two equivalent O(10), two equivalent O(12), and two equivalent O(6) atoms to form distorted MoO6 octahedra that share corners with two equivalent In(3)O6 octahedra, corners with four equivalent In(2)O6 octahedra, and edges with two equivalent Mo(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. In the third Mo site, Mo(3) is bonded to two equivalent O(3) and two equivalent O(7) atoms to form MoO4 tetrahedra that share corners with two equivalent Ag(3)O6 octahedra and corners with two equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. In the fourth Mo site, Mo(4) is bonded to two equivalent O(4) and two equivalent O(8) atoms to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent In(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(11), and two equivalent O(9) atoms. In the sixth Mo site, Mo(6) is bonded to two equivalent O(10), two equivalent O(12), and two equivalent O(2) atoms to form distorted MoO6 octahedra that share corners with two equivalent In(2)O6 octahedra, corners with four equivalent In(3)O6 octahedra, and edges with two equivalent Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(8) atoms. In the third Ag site, Ag(3) is bonded to two equivalent O(1), two equivalent O(11), and two equivalent O(3) atoms to form distorted AgO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra and corners with two equivalent Mo(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 57°. There are three inequivalent In sites. In the first In site, In(1) is bonded to two equivalent O(5), two equivalent O(8), and two equivalent O(9) atoms to form distorted InO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra and corners with two equivalent Mo(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second In site, In(2) is bonded to two equivalent O(10), two equivalent O(6), and two equivalent O(7) atoms to form InO6 octahedra that share corners with two equivalent Mo(6)O6 octahedra, corners with four equivalent Mo(2)O6 octahedra, and corners with two equivalent Mo(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-57°. In the third In site, In(3) is bonded to two equivalent O(12), two equivalent O(2), and two equivalent O(4) atoms to form InO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra, corners with four equivalent Mo(6)O6 octahedra, and corners with two equivalent Mo(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-55°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(5), one Ag(1), and one Ag(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mo(6) and one In(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one Ag(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(2), and one In(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(1) and one In(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one In(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mo(3), one Ag(1), and one In(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(2), and one In(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(5), and one In(1) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mo(2), one Mo(6), and one In(2) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mo(1), one Mo(5), and one Ag(3) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mo(2), one Mo(6), and one In(3) atom. is represented by the CIF file [CIF]
data_InAg(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.105
_cell_length_b   5.037
_cell_length_c   19.318
_cell_angle_alpha   82.608
_cell_angle_beta   82.507
_cell_angle_gamma   90.751
_symmetry_Int_Tables_number   1
_cell_volume   488.169
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.423  0.923  0.154  1.0
  In  In1  1  0.677  0.677  0.645  1.0
  In  In2  1  0.072  0.572  0.856  1.0
  Ag  Ag3  1  0.258  0.758  0.485  1.0
  Ag  Ag4  1  0.498  0.498  0.004  1.0
  Ag  Ag5  1  0.326  0.326  0.348  1.0
  Mo  Mo6  1  0.903  0.403  0.194  1.0
  Mo  Mo7  1  0.152  0.152  0.696  1.0
  Mo  Mo8  1  0.746  0.246  0.508  1.0
  Mo  Mo9  1  0.999  0.999  0.002  1.0
  Mo  Mo10  1  0.845  0.845  0.309  1.0
  Mo  Mo11  1  0.596  0.096  0.808  1.0
  O  O12  1  0.584  0.675  0.368  1.0
  O  O13  1  0.048  0.957  0.368  1.0
  O  O14  1  0.418  0.308  0.865  1.0
  O  O15  1  0.717  0.827  0.865  1.0
  O  O16  1  0.526  0.125  0.455  1.0
  O  O17  1  0.019  0.420  0.455  1.0
  O  O18  1  0.887  0.284  0.947  1.0
  O  O19  1  0.166  0.769  0.947  1.0
  O  O20  1  0.701  0.272  0.133  1.0
  O  O21  1  0.167  0.596  0.133  1.0
  O  O22  1  0.028  0.417  0.640  1.0
  O  O23  1  0.332  0.943  0.640  1.0
  O  O24  1  0.563  0.476  0.562  1.0
  O  O25  1  0.875  0.962  0.562  1.0
  O  O26  1  0.236  0.114  0.053  1.0
  O  O27  1  0.711  0.833  0.053  1.0
  O  O28  1  0.115  0.091  0.215  1.0
  O  O29  1  0.670  0.694  0.215  1.0
  O  O30  1  0.827  0.929  0.720  1.0
  O  O31  1  0.453  0.351  0.720  1.0
  O  O32  1  0.672  0.164  0.276  1.0
  O  O33  1  0.052  0.559  0.276  1.0
  O  O34  1  0.922  0.319  0.786  1.0
  O  O35  1  0.293  0.896  0.786  1.0
[/CIF]
.
The compound described by AgIn(MoO4)2 crystallizes in the monoclinic C2 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(11), two equivalent O(5), and two equivalent O(9) atoms to form distorted MoO6 octahedra that share corners with two equivalent Ag(3)O6 octahedra and corners with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the second Mo site, Mo(2) is bonded to two equivalent O(10), two equivalent O(12), and two equivalent O(6) atoms to form distorted MoO6 octahedra that share corners with two equivalent In(3)O6 octahedra, corners with four equivalent In(2)O6 octahedra, and edges with two equivalent Mo(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. In the third Mo site, Mo(3) is bonded to two equivalent O(3) and two equivalent O(7) atoms to form MoO4 tetrahedra that share corners with two equivalent Ag(3)O6 octahedra and corners with two equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. In the fourth Mo site, Mo(4) is bonded to two equivalent O(4) and two equivalent O(8) atoms to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent In(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(11), and two equivalent O(9) atoms. In the sixth Mo site, Mo(6) is bonded to two equivalent O(10), two equivalent O(12), and two equivalent O(2) atoms to form distorted MoO6 octahedra that share corners with two equivalent In(2)O6 octahedra, corners with four equivalent In(3)O6 octahedra, and edges with two equivalent Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(8) atoms. In the third Ag site, Ag(3) is bonded to two equivalent O(1), two equivalent O(11), and two equivalent O(3) atoms to form distorted AgO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra and corners with two equivalent Mo(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 57°. There are three inequivalent In sites. In the first In site, In(1) is bonded to two equivalent O(5), two equivalent O(8), and two equivalent O(9) atoms to form distorted InO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra and corners with two equivalent Mo(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second In site, In(2) is bonded to two equivalent O(10), two equivalent O(6), and two equivalent O(7) atoms to form InO6 octahedra that share corners with two equivalent Mo(6)O6 octahedra, corners with four equivalent Mo(2)O6 octahedra, and corners with two equivalent Mo(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-57°. In the third In site, In(3) is bonded to two equivalent O(12), two equivalent O(2), and two equivalent O(4) atoms to form InO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra, corners with four equivalent Mo(6)O6 octahedra, and corners with two equivalent Mo(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-55°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(5), one Ag(1), and one Ag(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mo(6) and one In(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one Ag(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(2), and one In(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(1) and one In(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one In(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mo(3), one Ag(1), and one In(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(2), and one In(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(5), and one In(1) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mo(2), one Mo(6), and one In(2) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mo(1), one Mo(5), and one Ag(3) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mo(2), one Mo(6), and one In(3) atom. is represented by the CIF file [CIF]
data_InAg(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.105
_cell_length_b   5.037
_cell_length_c   19.318
_cell_angle_alpha   82.608
_cell_angle_beta   82.507
_cell_angle_gamma   90.751
_symmetry_Int_Tables_number   1
_cell_volume   488.169
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.423  0.923  0.154  1.0
  In  In1  1  0.677  0.677  0.645  1.0
  In  In2  1  0.072  0.572  0.856  1.0
  Ag  Ag3  1  0.258  0.758  0.485  1.0
  Ag  Ag4  1  0.498  0.498  0.004  1.0
  Ag  Ag5  1  0.326  0.326  0.348  1.0
  Mo  Mo6  1  0.903  0.403  0.194  1.0
  Mo  Mo7  1  0.152  0.152  0.696  1.0
  Mo  Mo8  1  0.746  0.246  0.508  1.0
  Mo  Mo9  1  0.999  0.999  0.002  1.0
  Mo  Mo10  1  0.845  0.845  0.309  1.0
  Mo  Mo11  1  0.596  0.096  0.808  1.0
  O  O12  1  0.584  0.675  0.368  1.0
  O  O13  1  0.048  0.957  0.368  1.0
  O  O14  1  0.418  0.308  0.865  1.0
  O  O15  1  0.717  0.827  0.865  1.0
  O  O16  1  0.526  0.125  0.455  1.0
  O  O17  1  0.019  0.420  0.455  1.0
  O  O18  1  0.887  0.284  0.947  1.0
  O  O19  1  0.166  0.769  0.947  1.0
  O  O20  1  0.701  0.272  0.133  1.0
  O  O21  1  0.167  0.596  0.133  1.0
  O  O22  1  0.028  0.417  0.640  1.0
  O  O23  1  0.332  0.943  0.640  1.0
  O  O24  1  0.563  0.476  0.562  1.0
  O  O25  1  0.875  0.962  0.562  1.0
  O  O26  1  0.236  0.114  0.053  1.0
  O  O27  1  0.711  0.833  0.053  1.0
  O  O28  1  0.115  0.091  0.215  1.0
  O  O29  1  0.670  0.694  0.215  1.0
  O  O30  1  0.827  0.929  0.720  1.0
  O  O31  1  0.453  0.351  0.720  1.0
  O  O32  1  0.672  0.164  0.276  1.0
  O  O33  1  0.052  0.559  0.276  1.0
  O  O34  1  0.922  0.319  0.786  1.0
  O  O35  1  0.293  0.896  0.786  1.0
[/CIF]
.