The crystal structure described by KTeOF3 crystallizes in the monoclinic P2_1 space group. K(1) is bonded to two equivalent O(1), one F(1), one F(2), and two equivalent F(3) atoms to form distorted corner-sharing KO2F4 pentagonal pyramids. Te(1) is bonded in a see-saw-like geometry to one O(1), one F(1), one F(2), and one F(3) atom. O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Te(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one K(1) and one Te(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one K(1) and one Te(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTeOF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.888
_cell_length_b   5.479
_cell_length_c   8.145
_cell_angle_alpha   71.758
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   249.540
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.598  0.323  0.309  1.0
  K  K1  1  0.098  0.677  0.691  1.0
  Te  Te2  1  0.118  0.859  0.206  1.0
  Te  Te3  1  0.618  0.141  0.794  1.0
  O  O4  1  0.212  0.587  0.384  1.0
  O  O5  1  0.712  0.413  0.616  1.0
  F  F6  1  0.152  0.656  0.037  1.0
  F  F7  1  0.293  0.208  0.815  1.0
  F  F8  1  0.793  0.792  0.185  1.0
  F  F9  1  0.494  0.960  0.627  1.0
  F  F10  1  0.994  0.040  0.373  1.0
  F  F11  1  0.652  0.344  0.963  1.0
[/CIF]
.
The crystal structure described by KTeOF3 crystallizes in the monoclinic P2_1 space group. K(1) is bonded to two equivalent O(1), one F(1), one F(2), and two equivalent F(3) atoms to form distorted corner-sharing KO2F4 pentagonal pyramids. Te(1) is bonded in a see-saw-like geometry to one O(1), one F(1), one F(2), and one F(3) atom. O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Te(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one K(1) and one Te(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one K(1) and one Te(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTeOF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.888
_cell_length_b   5.479
_cell_length_c   8.145
_cell_angle_alpha   71.758
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   249.540
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.598  0.323  0.309  1.0
  K  K1  1  0.098  0.677  0.691  1.0
  Te  Te2  1  0.118  0.859  0.206  1.0
  Te  Te3  1  0.618  0.141  0.794  1.0
  O  O4  1  0.212  0.587  0.384  1.0
  O  O5  1  0.712  0.413  0.616  1.0
  F  F6  1  0.152  0.656  0.037  1.0
  F  F7  1  0.293  0.208  0.815  1.0
  F  F8  1  0.793  0.792  0.185  1.0
  F  F9  1  0.494  0.960  0.627  1.0
  F  F10  1  0.994  0.040  0.373  1.0
  F  F11  1  0.652  0.344  0.963  1.0
[/CIF]
.