The compound described by AsF6OBrF2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four OBrF2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(11), one F(12), one F(5), one F(6), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(12) is bonded in a single-bond geometry to one As(1) atom. In each OBrF2 cluster, O(1) is bonded in a single-bond geometry to one Br(1,2) atom. Br(1,2) is bonded in a 3-coordinate geometry to one O(1), one F(13), and one F(14) atom. There are two inequivalent F sites. In the first F site, F(14) is bonded in a single-bond geometry to one Br(1,2) atom. In the second F site, F(13) is bonded in a single-bond geometry to one Br(1,2) atom. is represented by the CIF card [CIF]
data_AsBrOF8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.880
_cell_length_b   8.860
_cell_length_c   8.887
_cell_angle_alpha   89.604
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   699.162
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.635  0.886  0.636  1.0
  As  As1  1  0.865  0.615  0.135  1.0
  As  As2  1  0.365  0.385  0.865  1.0
  As  As3  1  0.135  0.114  0.364  1.0
  Br  Br4  1  0.780  0.454  0.696  1.0
  Br  Br5  1  0.196  0.970  0.796  1.0
  Br  Br6  1  0.696  0.030  0.204  1.0
  Br  Br7  1  0.280  0.546  0.304  1.0
  O  O8  1  0.715  0.381  0.547  1.0
  O  O9  1  0.047  0.035  0.869  1.0
  O  O10  1  0.547  0.965  0.131  1.0
  O  O11  1  0.215  0.619  0.453  1.0
  F  F12  1  0.641  0.681  0.621  1.0
  F  F13  1  0.881  0.614  0.934  1.0
  F  F14  1  0.570  0.370  0.859  1.0
  F  F15  1  0.361  0.179  0.878  1.0
  F  F16  1  0.122  0.110  0.569  1.0
  F  F17  1  0.435  0.869  0.638  1.0
  F  F18  1  0.861  0.821  0.122  1.0
  F  F19  1  0.622  0.890  0.431  1.0
  F  F20  1  0.935  0.131  0.362  1.0
  F  F21  1  0.141  0.319  0.379  1.0
  F  F22  1  0.381  0.386  0.066  1.0
  F  F23  1  0.070  0.630  0.141  1.0
  F  F24  1  0.622  0.083  0.639  1.0
  F  F25  1  0.862  0.629  0.331  1.0
  F  F26  1  0.169  0.388  0.878  1.0
  F  F27  1  0.379  0.582  0.859  1.0
  F  F28  1  0.140  0.129  0.168  1.0
  F  F29  1  0.831  0.889  0.621  1.0
  F  F30  1  0.879  0.418  0.141  1.0
  F  F31  1  0.640  0.871  0.832  1.0
  F  F32  1  0.331  0.111  0.379  1.0
  F  F33  1  0.122  0.917  0.361  1.0
  F  F34  1  0.362  0.371  0.669  1.0
  F  F35  1  0.669  0.612  0.122  1.0
  F  F36  1  0.955  0.531  0.636  1.0
  F  F37  1  0.873  0.300  0.785  1.0
  F  F38  1  0.284  0.876  0.950  1.0
  F  F39  1  0.136  0.795  0.720  1.0
  F  F40  1  0.784  0.124  0.050  1.0
  F  F41  1  0.636  0.205  0.280  1.0
  F  F42  1  0.455  0.469  0.364  1.0
  F  F43  1  0.373  0.700  0.215  1.0
[/CIF]
.
The compound described by AsF6OBrF2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four OBrF2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(11), one F(12), one F(5), one F(6), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(12) is bonded in a single-bond geometry to one As(1) atom. In each OBrF2 cluster, O(1) is bonded in a single-bond geometry to one Br(1,2) atom. Br(1,2) is bonded in a 3-coordinate geometry to one O(1), one F(13), and one F(14) atom. There are two inequivalent F sites. In the first F site, F(14) is bonded in a single-bond geometry to one Br(1,2) atom. In the second F site, F(13) is bonded in a single-bond geometry to one Br(1,2) atom. is represented by the CIF card [CIF]
data_AsBrOF8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.880
_cell_length_b   8.860
_cell_length_c   8.887
_cell_angle_alpha   89.604
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   699.162
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.635  0.886  0.636  1.0
  As  As1  1  0.865  0.615  0.135  1.0
  As  As2  1  0.365  0.385  0.865  1.0
  As  As3  1  0.135  0.114  0.364  1.0
  Br  Br4  1  0.780  0.454  0.696  1.0
  Br  Br5  1  0.196  0.970  0.796  1.0
  Br  Br6  1  0.696  0.030  0.204  1.0
  Br  Br7  1  0.280  0.546  0.304  1.0
  O  O8  1  0.715  0.381  0.547  1.0
  O  O9  1  0.047  0.035  0.869  1.0
  O  O10  1  0.547  0.965  0.131  1.0
  O  O11  1  0.215  0.619  0.453  1.0
  F  F12  1  0.641  0.681  0.621  1.0
  F  F13  1  0.881  0.614  0.934  1.0
  F  F14  1  0.570  0.370  0.859  1.0
  F  F15  1  0.361  0.179  0.878  1.0
  F  F16  1  0.122  0.110  0.569  1.0
  F  F17  1  0.435  0.869  0.638  1.0
  F  F18  1  0.861  0.821  0.122  1.0
  F  F19  1  0.622  0.890  0.431  1.0
  F  F20  1  0.935  0.131  0.362  1.0
  F  F21  1  0.141  0.319  0.379  1.0
  F  F22  1  0.381  0.386  0.066  1.0
  F  F23  1  0.070  0.630  0.141  1.0
  F  F24  1  0.622  0.083  0.639  1.0
  F  F25  1  0.862  0.629  0.331  1.0
  F  F26  1  0.169  0.388  0.878  1.0
  F  F27  1  0.379  0.582  0.859  1.0
  F  F28  1  0.140  0.129  0.168  1.0
  F  F29  1  0.831  0.889  0.621  1.0
  F  F30  1  0.879  0.418  0.141  1.0
  F  F31  1  0.640  0.871  0.832  1.0
  F  F32  1  0.331  0.111  0.379  1.0
  F  F33  1  0.122  0.917  0.361  1.0
  F  F34  1  0.362  0.371  0.669  1.0
  F  F35  1  0.669  0.612  0.122  1.0
  F  F36  1  0.955  0.531  0.636  1.0
  F  F37  1  0.873  0.300  0.785  1.0
  F  F38  1  0.284  0.876  0.950  1.0
  F  F39  1  0.136  0.795  0.720  1.0
  F  F40  1  0.784  0.124  0.050  1.0
  F  F41  1  0.636  0.205  0.280  1.0
  F  F42  1  0.455  0.469  0.364  1.0
  F  F43  1  0.373  0.700  0.215  1.0
[/CIF]
.