The compound described by VO2 is Hydrophilite-like structured and crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(13), two equivalent O(14), and two equivalent O(3) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the second V site, V(2) is bonded to one O(14), one O(9), two equivalent O(13), and two equivalent O(4) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the third V site, V(3) is bonded to one O(2), one O(7), two equivalent O(10), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the fourth V site, V(4) is bonded to one O(4), one O(5), two equivalent O(12), and two equivalent O(6) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the fifth V site, V(5) is bonded to one O(12), one O(15), two equivalent O(1), and two equivalent O(16) atoms to form a mixture of distorted corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the sixth V site, V(6) is bonded to one O(11), one O(16), two equivalent O(15), and two equivalent O(2) atoms to form a mixture of distorted corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the seventh V site, V(7) is bonded to one O(1), one O(8), two equivalent O(7), and two equivalent O(9) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the eighth V site, V(8) is bonded to one O(3), one O(6), two equivalent O(11), and two equivalent O(5) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(5) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(6) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(8) and two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(4) and two equivalent V(2) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one V(4) and two equivalent V(8) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one V(8) and two equivalent V(4) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one V(3) and two equivalent V(7) atoms. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one V(7) and two equivalent V(3) atoms. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(7) atoms. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one V(6) and two equivalent V(8) atoms. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one V(5) and two equivalent V(4) atoms. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the fifteenth O site, O(15) is bonded in a trigonal non-coplanar geometry to one V(5) and two equivalent V(6) atoms. In the sixteenth O site, O(16) is bonded in a trigonal non-coplanar geometry to one V(6) and two equivalent V(5) atoms. is represented by the CIF card [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.033
_cell_length_b   8.773
_cell_length_c   10.537
_cell_angle_alpha   89.143
_cell_angle_beta   89.988
_cell_angle_gamma   90.048
_symmetry_Int_Tables_number   1
_cell_volume   280.320
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.253  0.929  0.894  1.0
  V  V1  1  0.754  0.070  0.105  1.0
  V  V2  1  0.763  0.065  0.609  1.0
  V  V3  1  0.252  0.430  0.107  1.0
  V  V4  1  0.700  0.564  0.385  1.0
  V  V5  1  0.199  0.436  0.615  1.0
  V  V6  1  0.263  0.936  0.391  1.0
  V  V7  1  0.752  0.570  0.893  1.0
  O  O8  1  0.275  0.716  0.359  1.0
  O  O9  1  0.775  0.285  0.642  1.0
  O  O10  1  0.753  0.791  0.863  1.0
  O  O11  1  0.254  0.209  0.136  1.0
  O  O12  1  0.253  0.611  0.017  1.0
  O  O13  1  0.752  0.389  0.983  1.0
  O  O14  1  0.766  0.889  0.516  1.0
  O  O15  1  0.267  0.112  0.484  1.0
  O  O16  1  0.763  0.986  0.280  1.0
  O  O17  1  0.262  0.015  0.721  1.0
  O  O18  1  0.251  0.522  0.784  1.0
  O  O19  1  0.752  0.477  0.217  1.0
  O  O20  1  0.254  0.923  0.070  1.0
  O  O21  1  0.755  0.076  0.930  1.0
  O  O22  1  0.717  0.567  0.574  1.0
  O  O23  1  0.216  0.433  0.426  1.0
[/CIF]
.
The compound described by VO2 is Hydrophilite-like structured and crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(13), two equivalent O(14), and two equivalent O(3) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the second V site, V(2) is bonded to one O(14), one O(9), two equivalent O(13), and two equivalent O(4) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the third V site, V(3) is bonded to one O(2), one O(7), two equivalent O(10), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the fourth V site, V(4) is bonded to one O(4), one O(5), two equivalent O(12), and two equivalent O(6) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the fifth V site, V(5) is bonded to one O(12), one O(15), two equivalent O(1), and two equivalent O(16) atoms to form a mixture of distorted corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the sixth V site, V(6) is bonded to one O(11), one O(16), two equivalent O(15), and two equivalent O(2) atoms to form a mixture of distorted corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the seventh V site, V(7) is bonded to one O(1), one O(8), two equivalent O(7), and two equivalent O(9) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the eighth V site, V(8) is bonded to one O(3), one O(6), two equivalent O(11), and two equivalent O(5) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(5) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(6) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(8) and two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(4) and two equivalent V(2) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one V(4) and two equivalent V(8) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one V(8) and two equivalent V(4) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one V(3) and two equivalent V(7) atoms. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one V(7) and two equivalent V(3) atoms. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(7) atoms. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one V(6) and two equivalent V(8) atoms. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one V(5) and two equivalent V(4) atoms. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the fifteenth O site, O(15) is bonded in a trigonal non-coplanar geometry to one V(5) and two equivalent V(6) atoms. In the sixteenth O site, O(16) is bonded in a trigonal non-coplanar geometry to one V(6) and two equivalent V(5) atoms. is represented by the CIF card [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.033
_cell_length_b   8.773
_cell_length_c   10.537
_cell_angle_alpha   89.143
_cell_angle_beta   89.988
_cell_angle_gamma   90.048
_symmetry_Int_Tables_number   1
_cell_volume   280.320
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.253  0.929  0.894  1.0
  V  V1  1  0.754  0.070  0.105  1.0
  V  V2  1  0.763  0.065  0.609  1.0
  V  V3  1  0.252  0.430  0.107  1.0
  V  V4  1  0.700  0.564  0.385  1.0
  V  V5  1  0.199  0.436  0.615  1.0
  V  V6  1  0.263  0.936  0.391  1.0
  V  V7  1  0.752  0.570  0.893  1.0
  O  O8  1  0.275  0.716  0.359  1.0
  O  O9  1  0.775  0.285  0.642  1.0
  O  O10  1  0.753  0.791  0.863  1.0
  O  O11  1  0.254  0.209  0.136  1.0
  O  O12  1  0.253  0.611  0.017  1.0
  O  O13  1  0.752  0.389  0.983  1.0
  O  O14  1  0.766  0.889  0.516  1.0
  O  O15  1  0.267  0.112  0.484  1.0
  O  O16  1  0.763  0.986  0.280  1.0
  O  O17  1  0.262  0.015  0.721  1.0
  O  O18  1  0.251  0.522  0.784  1.0
  O  O19  1  0.752  0.477  0.217  1.0
  O  O20  1  0.254  0.923  0.070  1.0
  O  O21  1  0.755  0.076  0.930  1.0
  O  O22  1  0.717  0.567  0.574  1.0
  O  O23  1  0.216  0.433  0.426  1.0
[/CIF]
.