The material structure described by KZrPdF7 crystallizes in the orthorhombic Pnna space group. K(1) is bonded in a 10-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(4), and four equivalent F(3) atoms. Zr(1) is bonded to one F(2), two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form ZrF7 pentagonal bipyramids that share corners with four equivalent Pd(1)F6 octahedra and  an edgeedge with one Pd(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 37-48°. Pd(1) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form PdF6 octahedra that share corners with four equivalent Zr(1)F7 pentagonal bipyramids and  an edgeedge with one Zr(1)F7 pentagonal bipyramid. There are four inequivalent F sites. In the first F site, F(4) is bonded in a 3-coordinate geometry to one K(1), one Zr(1), and one Pd(1) atom. In the second F site, F(1) is bonded in a 2-coordinate geometry to one K(1), one Zr(1), and one Pd(1) atom. In the third F site, F(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Zr(1) atom. In the fourth F site, F(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Zr(1), and one Pd(1) atom. is represented by the CIF file [CIF]
data_KZrPdF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.532
_cell_length_b   8.136
_cell_length_c   11.608
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   616.891
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.268  0.000  0.250  1.0
  K  K1  1  0.732  0.000  0.750  1.0
  K  K2  1  0.232  0.500  0.250  1.0
  K  K3  1  0.768  0.500  0.750  1.0
  Zr  Zr4  1  0.750  0.250  0.092  1.0
  Zr  Zr5  1  0.250  0.250  0.592  1.0
  Zr  Zr6  1  0.250  0.750  0.908  1.0
  Zr  Zr7  1  0.750  0.750  0.408  1.0
  Pd  Pd8  1  0.750  0.750  0.099  1.0
  Pd  Pd9  1  0.250  0.250  0.901  1.0
  Pd  Pd10  1  0.250  0.750  0.599  1.0
  Pd  Pd11  1  0.750  0.250  0.401  1.0
  F  F12  1  0.948  0.181  0.546  1.0
  F  F13  1  0.948  0.819  0.954  1.0
  F  F14  1  0.552  0.681  0.954  1.0
  F  F15  1  0.552  0.319  0.546  1.0
  F  F16  1  0.052  0.819  0.454  1.0
  F  F17  1  0.052  0.181  0.046  1.0
  F  F18  1  0.448  0.319  0.046  1.0
  F  F19  1  0.448  0.681  0.454  1.0
  F  F20  1  0.250  0.750  0.082  1.0
  F  F21  1  0.250  0.250  0.418  1.0
  F  F22  1  0.750  0.250  0.918  1.0
  F  F23  1  0.750  0.750  0.582  1.0
  F  F24  1  0.933  0.794  0.255  1.0
  F  F25  1  0.933  0.206  0.245  1.0
  F  F26  1  0.567  0.294  0.245  1.0
  F  F27  1  0.567  0.706  0.255  1.0
  F  F28  1  0.067  0.206  0.745  1.0
  F  F29  1  0.067  0.794  0.755  1.0
  F  F30  1  0.433  0.706  0.755  1.0
  F  F31  1  0.433  0.294  0.745  1.0
  F  F32  1  0.648  0.011  0.105  1.0
  F  F33  1  0.648  0.989  0.395  1.0
  F  F34  1  0.852  0.511  0.395  1.0
  F  F35  1  0.852  0.489  0.105  1.0
  F  F36  1  0.352  0.989  0.895  1.0
  F  F37  1  0.352  0.011  0.605  1.0
  F  F38  1  0.148  0.489  0.605  1.0
  F  F39  1  0.148  0.511  0.895  1.0
[/CIF]
.
The material structure described by KZrPdF7 crystallizes in the orthorhombic Pnna space group. K(1) is bonded in a 10-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(4), and four equivalent F(3) atoms. Zr(1) is bonded to one F(2), two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form ZrF7 pentagonal bipyramids that share corners with four equivalent Pd(1)F6 octahedra and  an edgeedge with one Pd(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 37-48°. Pd(1) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form PdF6 octahedra that share corners with four equivalent Zr(1)F7 pentagonal bipyramids and  an edgeedge with one Zr(1)F7 pentagonal bipyramid. There are four inequivalent F sites. In the first F site, F(4) is bonded in a 3-coordinate geometry to one K(1), one Zr(1), and one Pd(1) atom. In the second F site, F(1) is bonded in a 2-coordinate geometry to one K(1), one Zr(1), and one Pd(1) atom. In the third F site, F(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Zr(1) atom. In the fourth F site, F(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Zr(1), and one Pd(1) atom. is represented by the CIF file [CIF]
data_KZrPdF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.532
_cell_length_b   8.136
_cell_length_c   11.608
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   616.891
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.268  0.000  0.250  1.0
  K  K1  1  0.732  0.000  0.750  1.0
  K  K2  1  0.232  0.500  0.250  1.0
  K  K3  1  0.768  0.500  0.750  1.0
  Zr  Zr4  1  0.750  0.250  0.092  1.0
  Zr  Zr5  1  0.250  0.250  0.592  1.0
  Zr  Zr6  1  0.250  0.750  0.908  1.0
  Zr  Zr7  1  0.750  0.750  0.408  1.0
  Pd  Pd8  1  0.750  0.750  0.099  1.0
  Pd  Pd9  1  0.250  0.250  0.901  1.0
  Pd  Pd10  1  0.250  0.750  0.599  1.0
  Pd  Pd11  1  0.750  0.250  0.401  1.0
  F  F12  1  0.948  0.181  0.546  1.0
  F  F13  1  0.948  0.819  0.954  1.0
  F  F14  1  0.552  0.681  0.954  1.0
  F  F15  1  0.552  0.319  0.546  1.0
  F  F16  1  0.052  0.819  0.454  1.0
  F  F17  1  0.052  0.181  0.046  1.0
  F  F18  1  0.448  0.319  0.046  1.0
  F  F19  1  0.448  0.681  0.454  1.0
  F  F20  1  0.250  0.750  0.082  1.0
  F  F21  1  0.250  0.250  0.418  1.0
  F  F22  1  0.750  0.250  0.918  1.0
  F  F23  1  0.750  0.750  0.582  1.0
  F  F24  1  0.933  0.794  0.255  1.0
  F  F25  1  0.933  0.206  0.245  1.0
  F  F26  1  0.567  0.294  0.245  1.0
  F  F27  1  0.567  0.706  0.255  1.0
  F  F28  1  0.067  0.206  0.745  1.0
  F  F29  1  0.067  0.794  0.755  1.0
  F  F30  1  0.433  0.706  0.755  1.0
  F  F31  1  0.433  0.294  0.745  1.0
  F  F32  1  0.648  0.011  0.105  1.0
  F  F33  1  0.648  0.989  0.395  1.0
  F  F34  1  0.852  0.511  0.395  1.0
  F  F35  1  0.852  0.489  0.105  1.0
  F  F36  1  0.352  0.989  0.895  1.0
  F  F37  1  0.352  0.011  0.605  1.0
  F  F38  1  0.148  0.489  0.605  1.0
  F  F39  1  0.148  0.511  0.895  1.0
[/CIF]
.