The crystal structure described by Tm2Rh3Ge5 crystallizes in the monoclinic C2/c space group. Tm(1) is bonded in a 1-coordinate geometry to two equivalent Ge(4) and four equivalent Ge(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to one Ge(2), one Ge(4), and four equivalent Ge(1) atoms. In the second Rh site, Rh(1) is bonded in a 5-coordinate geometry to one Ge(1), one Ge(2), one Ge(4), and two equivalent Ge(3) atoms. There are four inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to four equivalent Tm(1), one Rh(1), two equivalent Rh(2), one Ge(2), and one Ge(4) atom. In the second Ge site, Ge(2) is bonded in a 3-coordinate geometry to one Rh(2), two equivalent Rh(1), two equivalent Ge(1), and two equivalent Ge(4) atoms. In the third Ge site, Ge(3) is bonded in a 4-coordinate geometry to four equivalent Rh(1) atoms. In the fourth Ge site, Ge(4) is bonded in a 11-coordinate geometry to four equivalent Tm(1), one Rh(2), two equivalent Rh(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. is represented by the CIF card [CIF]
data_Tm2Ge5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.336
_cell_length_b   8.336
_cell_length_c   5.901
_cell_angle_alpha   70.705
_cell_angle_beta   70.705
_cell_angle_gamma   92.601
_symmetry_Int_Tables_number   1
_cell_volume   359.733
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.866  0.591  0.767  1.0
  Tm  Tm1  1  0.409  0.134  0.733  1.0
  Tm  Tm2  1  0.134  0.409  0.233  1.0
  Tm  Tm3  1  0.591  0.866  0.267  1.0
  Ge  Ge4  1  0.072  0.263  0.833  1.0
  Ge  Ge5  1  0.737  0.928  0.667  1.0
  Ge  Ge6  1  0.928  0.737  0.167  1.0
  Ge  Ge7  1  0.263  0.072  0.333  1.0
  Ge  Ge8  1  0.212  0.788  0.750  1.0
  Ge  Ge9  1  0.788  0.212  0.250  1.0
  Ge  Ge10  1  0.508  0.492  0.750  1.0
  Ge  Ge11  1  0.492  0.508  0.250  1.0
  Ge  Ge12  1  0.778  0.222  0.750  1.0
  Ge  Ge13  1  0.222  0.778  0.250  1.0
  Rh  Rh14  1  0.253  0.540  0.618  1.0
  Rh  Rh15  1  0.460  0.747  0.882  1.0
  Rh  Rh16  1  0.747  0.460  0.382  1.0
  Rh  Rh17  1  0.540  0.253  0.118  1.0
  Rh  Rh18  1  0.002  0.998  0.750  1.0
  Rh  Rh19  1  0.998  0.002  0.250  1.0
[/CIF]
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The crystal structure described by Tm2Rh3Ge5 crystallizes in the monoclinic C2/c space group. Tm(1) is bonded in a 1-coordinate geometry to two equivalent Ge(4) and four equivalent Ge(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to one Ge(2), one Ge(4), and four equivalent Ge(1) atoms. In the second Rh site, Rh(1) is bonded in a 5-coordinate geometry to one Ge(1), one Ge(2), one Ge(4), and two equivalent Ge(3) atoms. There are four inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to four equivalent Tm(1), one Rh(1), two equivalent Rh(2), one Ge(2), and one Ge(4) atom. In the second Ge site, Ge(2) is bonded in a 3-coordinate geometry to one Rh(2), two equivalent Rh(1), two equivalent Ge(1), and two equivalent Ge(4) atoms. In the third Ge site, Ge(3) is bonded in a 4-coordinate geometry to four equivalent Rh(1) atoms. In the fourth Ge site, Ge(4) is bonded in a 11-coordinate geometry to four equivalent Tm(1), one Rh(2), two equivalent Rh(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. is represented by the CIF card [CIF]
data_Tm2Ge5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.336
_cell_length_b   8.336
_cell_length_c   5.901
_cell_angle_alpha   70.705
_cell_angle_beta   70.705
_cell_angle_gamma   92.601
_symmetry_Int_Tables_number   1
_cell_volume   359.733
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.866  0.591  0.767  1.0
  Tm  Tm1  1  0.409  0.134  0.733  1.0
  Tm  Tm2  1  0.134  0.409  0.233  1.0
  Tm  Tm3  1  0.591  0.866  0.267  1.0
  Ge  Ge4  1  0.072  0.263  0.833  1.0
  Ge  Ge5  1  0.737  0.928  0.667  1.0
  Ge  Ge6  1  0.928  0.737  0.167  1.0
  Ge  Ge7  1  0.263  0.072  0.333  1.0
  Ge  Ge8  1  0.212  0.788  0.750  1.0
  Ge  Ge9  1  0.788  0.212  0.250  1.0
  Ge  Ge10  1  0.508  0.492  0.750  1.0
  Ge  Ge11  1  0.492  0.508  0.250  1.0
  Ge  Ge12  1  0.778  0.222  0.750  1.0
  Ge  Ge13  1  0.222  0.778  0.250  1.0
  Rh  Rh14  1  0.253  0.540  0.618  1.0
  Rh  Rh15  1  0.460  0.747  0.882  1.0
  Rh  Rh16  1  0.747  0.460  0.382  1.0
  Rh  Rh17  1  0.540  0.253  0.118  1.0
  Rh  Rh18  1  0.002  0.998  0.750  1.0
  Rh  Rh19  1  0.998  0.002  0.250  1.0
[/CIF]
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