The material structure described by Li4Sb2H2OF10(H2O)2 crystallizes in the monoclinic P2_1/m space group. The structure consists of four water molecules inside a Li4Sb2H2OF10 framework. In the Li4Sb2H2OF10 framework, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 7-coordinate geometry to one F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. In the second Li site, Li(2) is bonded to one O(3), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(2)OF5 octahedra and corners with five equivalent Sb(1)F5 square pyramids. The corner-sharing octahedral tilt angles are 14°. Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form distorted SbF5 square pyramids that share corners with five equivalent Li(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 12-39°. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(3) atom. O(3) is bonded in a water-like geometry to two equivalent Li(2), one H(3), and one H(4) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), and one Sb(1) atom. In the second F site, F(3) is bonded in a 4-coordinate geometry to one Li(2), two equivalent Li(1), and one Sb(1) atom. In the third F site, F(4) is bonded to one Li(2), two equivalent Li(1), and one Sb(1) atom to form distorted edge-sharing FLi3Sb tetrahedra. In the fourth F site, F(5) is bonded in a 4-coordinate geometry to one Li(2), two equivalent Li(1), and one Sb(1) atom. In the fifth F site, F(1) is bonded in a linear geometry to one Li(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li4Sb2H6O3F10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.676
_cell_length_b   5.675
_cell_length_c   5.685
_cell_angle_alpha   89.965
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   537.995
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.752  0.248  1.0
  Li  Li1  1  0.500  0.752  0.248  1.0
  Li  Li2  1  0.389  0.745  0.749  1.0
  Li  Li3  1  0.111  0.745  0.749  1.0
  Li  Li4  1  0.611  0.255  0.251  1.0
  Li  Li5  1  0.889  0.255  0.251  1.0
  Li  Li6  1  1.000  0.248  0.752  1.0
  Li  Li7  1  0.500  0.248  0.752  1.0
  Sb  Sb8  1  0.629  0.741  0.740  1.0
  Sb  Sb9  1  0.871  0.741  0.740  1.0
  Sb  Sb10  1  0.371  0.259  0.260  1.0
  Sb  Sb11  1  0.129  0.259  0.260  1.0
  H  H12  1  0.796  0.867  0.221  1.0
  H  H13  1  0.704  0.867  0.221  1.0
  H  H14  1  0.296  0.791  0.145  1.0
  H  H15  1  0.204  0.791  0.145  1.0
  H  H16  1  0.250  0.732  0.543  1.0
  H  H17  1  0.250  0.534  0.738  1.0
  H  H18  1  0.750  0.466  0.262  1.0
  H  H19  1  0.750  0.268  0.457  1.0
  H  H20  1  0.796  0.209  0.855  1.0
  H  H21  1  0.704  0.209  0.855  1.0
  H  H22  1  0.296  0.133  0.779  1.0
  H  H23  1  0.204  0.133  0.779  1.0
  O  O24  1  0.750  0.771  0.269  1.0
  O  O25  1  0.250  0.747  0.243  1.0
  O  O26  1  0.250  0.709  0.716  1.0
  O  O27  1  0.750  0.291  0.284  1.0
  O  O28  1  0.750  0.253  0.757  1.0
  O  O29  1  0.250  0.229  0.731  1.0
  F  F30  1  0.867  0.013  0.004  1.0
  F  F31  1  0.633  0.013  0.004  1.0
  F  F32  1  0.902  0.994  0.485  1.0
  F  F33  1  0.598  0.994  0.485  1.0
  F  F34  1  0.513  0.819  0.807  1.0
  F  F35  1  0.987  0.819  0.807  1.0
  F  F36  1  0.922  0.500  0.502  1.0
  F  F37  1  0.578  0.500  0.502  1.0
  F  F38  1  0.907  0.493  0.998  1.0
  F  F39  1  0.593  0.493  0.998  1.0
  F  F40  1  0.407  0.507  0.002  1.0
  F  F41  1  0.093  0.507  0.002  1.0
  F  F42  1  0.422  0.500  0.498  1.0
  F  F43  1  0.078  0.500  0.498  1.0
  F  F44  1  0.013  0.181  0.193  1.0
  F  F45  1  0.487  0.181  0.193  1.0
  F  F46  1  0.402  0.006  0.515  1.0
  F  F47  1  0.098  0.006  0.515  1.0
  F  F48  1  0.367  0.987  0.996  1.0
  F  F49  1  0.133  0.987  0.996  1.0
[/CIF]
.
The material structure described by Li4Sb2H2OF10(H2O)2 crystallizes in the monoclinic P2_1/m space group. The structure consists of four water molecules inside a Li4Sb2H2OF10 framework. In the Li4Sb2H2OF10 framework, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 7-coordinate geometry to one F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. In the second Li site, Li(2) is bonded to one O(3), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form distorted LiOF5 octahedra that share  a cornercorner with one Li(2)OF5 octahedra and corners with five equivalent Sb(1)F5 square pyramids. The corner-sharing octahedral tilt angles are 14°. Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form distorted SbF5 square pyramids that share corners with five equivalent Li(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 12-39°. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(3) atom. O(3) is bonded in a water-like geometry to two equivalent Li(2), one H(3), and one H(4) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), and one Sb(1) atom. In the second F site, F(3) is bonded in a 4-coordinate geometry to one Li(2), two equivalent Li(1), and one Sb(1) atom. In the third F site, F(4) is bonded to one Li(2), two equivalent Li(1), and one Sb(1) atom to form distorted edge-sharing FLi3Sb tetrahedra. In the fourth F site, F(5) is bonded in a 4-coordinate geometry to one Li(2), two equivalent Li(1), and one Sb(1) atom. In the fifth F site, F(1) is bonded in a linear geometry to one Li(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li4Sb2H6O3F10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.676
_cell_length_b   5.675
_cell_length_c   5.685
_cell_angle_alpha   89.965
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   537.995
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.752  0.248  1.0
  Li  Li1  1  0.500  0.752  0.248  1.0
  Li  Li2  1  0.389  0.745  0.749  1.0
  Li  Li3  1  0.111  0.745  0.749  1.0
  Li  Li4  1  0.611  0.255  0.251  1.0
  Li  Li5  1  0.889  0.255  0.251  1.0
  Li  Li6  1  1.000  0.248  0.752  1.0
  Li  Li7  1  0.500  0.248  0.752  1.0
  Sb  Sb8  1  0.629  0.741  0.740  1.0
  Sb  Sb9  1  0.871  0.741  0.740  1.0
  Sb  Sb10  1  0.371  0.259  0.260  1.0
  Sb  Sb11  1  0.129  0.259  0.260  1.0
  H  H12  1  0.796  0.867  0.221  1.0
  H  H13  1  0.704  0.867  0.221  1.0
  H  H14  1  0.296  0.791  0.145  1.0
  H  H15  1  0.204  0.791  0.145  1.0
  H  H16  1  0.250  0.732  0.543  1.0
  H  H17  1  0.250  0.534  0.738  1.0
  H  H18  1  0.750  0.466  0.262  1.0
  H  H19  1  0.750  0.268  0.457  1.0
  H  H20  1  0.796  0.209  0.855  1.0
  H  H21  1  0.704  0.209  0.855  1.0
  H  H22  1  0.296  0.133  0.779  1.0
  H  H23  1  0.204  0.133  0.779  1.0
  O  O24  1  0.750  0.771  0.269  1.0
  O  O25  1  0.250  0.747  0.243  1.0
  O  O26  1  0.250  0.709  0.716  1.0
  O  O27  1  0.750  0.291  0.284  1.0
  O  O28  1  0.750  0.253  0.757  1.0
  O  O29  1  0.250  0.229  0.731  1.0
  F  F30  1  0.867  0.013  0.004  1.0
  F  F31  1  0.633  0.013  0.004  1.0
  F  F32  1  0.902  0.994  0.485  1.0
  F  F33  1  0.598  0.994  0.485  1.0
  F  F34  1  0.513  0.819  0.807  1.0
  F  F35  1  0.987  0.819  0.807  1.0
  F  F36  1  0.922  0.500  0.502  1.0
  F  F37  1  0.578  0.500  0.502  1.0
  F  F38  1  0.907  0.493  0.998  1.0
  F  F39  1  0.593  0.493  0.998  1.0
  F  F40  1  0.407  0.507  0.002  1.0
  F  F41  1  0.093  0.507  0.002  1.0
  F  F42  1  0.422  0.500  0.498  1.0
  F  F43  1  0.078  0.500  0.498  1.0
  F  F44  1  0.013  0.181  0.193  1.0
  F  F45  1  0.487  0.181  0.193  1.0
  F  F46  1  0.402  0.006  0.515  1.0
  F  F47  1  0.098  0.006  0.515  1.0
  F  F48  1  0.367  0.987  0.996  1.0
  F  F49  1  0.133  0.987  0.996  1.0
[/CIF]
.