The compound described by VO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.036
_cell_length_b   4.814
_cell_length_c   9.128
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   133.399
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.250  0.425  0.636  1.0
  V  V1  1  0.250  0.075  0.136  1.0
  V  V2  1  0.750  0.575  0.364  1.0
  V  V3  1  0.750  0.925  0.864  1.0
  O  O4  1  0.750  0.290  0.517  1.0
  O  O5  1  0.250  0.790  0.983  1.0
  O  O6  1  0.750  0.210  0.017  1.0
  O  O7  1  0.250  0.710  0.483  1.0
  O  O8  1  0.750  0.879  0.238  1.0
  O  O9  1  0.750  0.621  0.738  1.0
  O  O10  1  0.250  0.121  0.762  1.0
  O  O11  1  0.250  0.379  0.262  1.0
[/CIF]
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The compound described by VO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.036
_cell_length_b   4.814
_cell_length_c   9.128
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   133.399
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.250  0.425  0.636  1.0
  V  V1  1  0.250  0.075  0.136  1.0
  V  V2  1  0.750  0.575  0.364  1.0
  V  V3  1  0.750  0.925  0.864  1.0
  O  O4  1  0.750  0.290  0.517  1.0
  O  O5  1  0.250  0.790  0.983  1.0
  O  O6  1  0.750  0.210  0.017  1.0
  O  O7  1  0.250  0.710  0.483  1.0
  O  O8  1  0.750  0.879  0.238  1.0
  O  O9  1  0.750  0.621  0.738  1.0
  O  O10  1  0.250  0.121  0.762  1.0
  O  O11  1  0.250  0.379  0.262  1.0
[/CIF]
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