The material structure described by Li4Ti3V3Mn2O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-68°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-68°. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the second Ti site, Ti(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the third Ti site, Ti(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-57°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-57°. In the second Mn site, Mn(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one V(3), and one Mn(1) atom. In the second O site, O(2) is bonded to one Li(4), one Ti(1), one Ti(2), and one Mn(1) atom to form distorted OLiTi2Mn tetrahedra that share  a cornercorner with one O(7)LiTiMnV tetrahedra,  a cornercorner with one O(8)LiTiMnV tetrahedra, corners with two equivalent O(4)LiTi2V tetrahedra,  an edgeedge with one O(7)LiTiMnV tetrahedra, and  an edgeedge with one O(8)LiTiMnV tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Ti(1), one Ti(2), and one V(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one Ti(1), one Ti(2), and one V(1) atom to form distorted OLiTi2V tetrahedra that share corners with two equivalent O(2)LiTi2Mn tetrahedra, corners with two equivalent O(7)LiTiMnV tetrahedra, and corners with two equivalent O(8)LiTiMnV tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one Ti(3), one V(2), and one V(3) atom to form distorted OLiTiV2 tetrahedra that share corners with two equivalent O(15)LiMnV2 tetrahedra, corners with two equivalent O(11)LiTiMnV tetrahedra, and corners with two equivalent O(12)LiTiMnV tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one V(2), and one Mn(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), one V(1), and one Mn(1) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(2)LiTi2Mn tetrahedra,  a cornercorner with one O(8)LiTiMnV tetrahedra, corners with two equivalent O(4)LiTi2V tetrahedra,  an edgeedge with one O(2)LiTi2Mn tetrahedra, and  an edgeedge with one O(8)LiTiMnV tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Ti(2), one V(1), and one Mn(1) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(2)LiTi2Mn tetrahedra,  a cornercorner with one O(7)LiTiMnV tetrahedra, corners with two equivalent O(4)LiTi2V tetrahedra,  an edgeedge with one O(2)LiTi2Mn tetrahedra, and  an edgeedge with one O(7)LiTiMnV tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one Ti(2), and one Mn(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one V(3), and one Mn(1) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Ti(3), one V(3), and one Mn(2) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(15)LiMnV2 tetrahedra,  a cornercorner with one O(12)LiTiMnV tetrahedra, corners with two equivalent O(5)LiTiV2 tetrahedra,  an edgeedge with one O(15)LiMnV2 tetrahedra, and  an edgeedge with one O(12)LiTiMnV tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one Ti(3), one V(2), and one Mn(2) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(15)LiMnV2 tetrahedra,  a cornercorner with one O(11)LiTiMnV tetrahedra, corners with two equivalent O(5)LiTiV2 tetrahedra,  an edgeedge with one O(15)LiMnV2 tetrahedra, and  an edgeedge with one O(11)LiTiMnV tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Ti(3), one V(2), and one V(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one V(1), and one Mn(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one V(3), and one Mn(2) atom to form distorted OLiMnV2 tetrahedra that share  a cornercorner with one O(11)LiTiMnV tetrahedra,  a cornercorner with one O(12)LiTiMnV tetrahedra, corners with two equivalent O(5)LiTiV2 tetrahedra,  an edgeedge with one O(11)LiTiMnV tetrahedra, and  an edgeedge with one O(12)LiTiMnV tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one V(1), and one Mn(2) atom. is represented by the CIF card [CIF]
data_Li4Ti3Mn2V3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.945
_cell_length_b   5.953
_cell_length_c   9.935
_cell_angle_alpha   90.356
_cell_angle_beta   90.148
_cell_angle_gamma   119.937
_symmetry_Int_Tables_number   1
_cell_volume   304.681
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.668  0.329  0.107  1.0
  Li  Li1  1  0.997  0.003  0.003  1.0
  Li  Li2  1  0.996  0.998  0.501  1.0
  Li  Li3  1  0.332  0.664  0.607  1.0
  Ti  Ti4  1  0.338  0.166  0.781  1.0
  Ti  Ti5  1  0.833  0.662  0.783  1.0
  Ti  Ti6  1  0.173  0.830  0.281  1.0
  Mn  Mn7  1  0.672  0.337  0.503  1.0
  Mn  Mn8  1  0.338  0.673  0.003  1.0
  V  V9  1  0.835  0.171  0.789  1.0
  V  V10  1  0.663  0.822  0.285  1.0
  V  V11  1  0.167  0.332  0.288  1.0
  O  O12  1  0.310  0.167  0.392  1.0
  O  O13  1  0.511  0.482  0.676  1.0
  O  O14  1  0.662  0.337  0.895  1.0
  O  O15  1  1.000  0.001  0.685  1.0
  O  O16  1  0.002  0.996  0.186  1.0
  O  O17  1  0.850  0.688  0.392  1.0
  O  O18  1  0.522  0.036  0.677  1.0
  O  O19  1  0.967  0.488  0.673  1.0
  O  O20  1  0.156  0.849  0.892  1.0
  O  O21  1  0.835  0.143  0.389  1.0
  O  O22  1  0.037  0.504  0.176  1.0
  O  O23  1  0.477  0.967  0.173  1.0
  O  O24  1  0.332  0.669  0.395  1.0
  O  O25  1  0.143  0.312  0.891  1.0
  O  O26  1  0.498  0.527  0.175  1.0
  O  O27  1  0.688  0.846  0.892  1.0
[/CIF]
.
The material structure described by Li4Ti3V3Mn2O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-68°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-68°. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the second Ti site, Ti(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the third Ti site, Ti(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-57°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-57°. In the second Mn site, Mn(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one V(3), and one Mn(1) atom. In the second O site, O(2) is bonded to one Li(4), one Ti(1), one Ti(2), and one Mn(1) atom to form distorted OLiTi2Mn tetrahedra that share  a cornercorner with one O(7)LiTiMnV tetrahedra,  a cornercorner with one O(8)LiTiMnV tetrahedra, corners with two equivalent O(4)LiTi2V tetrahedra,  an edgeedge with one O(7)LiTiMnV tetrahedra, and  an edgeedge with one O(8)LiTiMnV tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Ti(1), one Ti(2), and one V(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one Ti(1), one Ti(2), and one V(1) atom to form distorted OLiTi2V tetrahedra that share corners with two equivalent O(2)LiTi2Mn tetrahedra, corners with two equivalent O(7)LiTiMnV tetrahedra, and corners with two equivalent O(8)LiTiMnV tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one Ti(3), one V(2), and one V(3) atom to form distorted OLiTiV2 tetrahedra that share corners with two equivalent O(15)LiMnV2 tetrahedra, corners with two equivalent O(11)LiTiMnV tetrahedra, and corners with two equivalent O(12)LiTiMnV tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one V(2), and one Mn(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), one V(1), and one Mn(1) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(2)LiTi2Mn tetrahedra,  a cornercorner with one O(8)LiTiMnV tetrahedra, corners with two equivalent O(4)LiTi2V tetrahedra,  an edgeedge with one O(2)LiTi2Mn tetrahedra, and  an edgeedge with one O(8)LiTiMnV tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Ti(2), one V(1), and one Mn(1) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(2)LiTi2Mn tetrahedra,  a cornercorner with one O(7)LiTiMnV tetrahedra, corners with two equivalent O(4)LiTi2V tetrahedra,  an edgeedge with one O(2)LiTi2Mn tetrahedra, and  an edgeedge with one O(7)LiTiMnV tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one Ti(2), and one Mn(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one V(3), and one Mn(1) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Ti(3), one V(3), and one Mn(2) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(15)LiMnV2 tetrahedra,  a cornercorner with one O(12)LiTiMnV tetrahedra, corners with two equivalent O(5)LiTiV2 tetrahedra,  an edgeedge with one O(15)LiMnV2 tetrahedra, and  an edgeedge with one O(12)LiTiMnV tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one Ti(3), one V(2), and one Mn(2) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(15)LiMnV2 tetrahedra,  a cornercorner with one O(11)LiTiMnV tetrahedra, corners with two equivalent O(5)LiTiV2 tetrahedra,  an edgeedge with one O(15)LiMnV2 tetrahedra, and  an edgeedge with one O(11)LiTiMnV tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Ti(3), one V(2), and one V(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one V(1), and one Mn(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one V(3), and one Mn(2) atom to form distorted OLiMnV2 tetrahedra that share  a cornercorner with one O(11)LiTiMnV tetrahedra,  a cornercorner with one O(12)LiTiMnV tetrahedra, corners with two equivalent O(5)LiTiV2 tetrahedra,  an edgeedge with one O(11)LiTiMnV tetrahedra, and  an edgeedge with one O(12)LiTiMnV tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one V(1), and one Mn(2) atom. is represented by the CIF card [CIF]
data_Li4Ti3Mn2V3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.945
_cell_length_b   5.953
_cell_length_c   9.935
_cell_angle_alpha   90.356
_cell_angle_beta   90.148
_cell_angle_gamma   119.937
_symmetry_Int_Tables_number   1
_cell_volume   304.681
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.668  0.329  0.107  1.0
  Li  Li1  1  0.997  0.003  0.003  1.0
  Li  Li2  1  0.996  0.998  0.501  1.0
  Li  Li3  1  0.332  0.664  0.607  1.0
  Ti  Ti4  1  0.338  0.166  0.781  1.0
  Ti  Ti5  1  0.833  0.662  0.783  1.0
  Ti  Ti6  1  0.173  0.830  0.281  1.0
  Mn  Mn7  1  0.672  0.337  0.503  1.0
  Mn  Mn8  1  0.338  0.673  0.003  1.0
  V  V9  1  0.835  0.171  0.789  1.0
  V  V10  1  0.663  0.822  0.285  1.0
  V  V11  1  0.167  0.332  0.288  1.0
  O  O12  1  0.310  0.167  0.392  1.0
  O  O13  1  0.511  0.482  0.676  1.0
  O  O14  1  0.662  0.337  0.895  1.0
  O  O15  1  1.000  0.001  0.685  1.0
  O  O16  1  0.002  0.996  0.186  1.0
  O  O17  1  0.850  0.688  0.392  1.0
  O  O18  1  0.522  0.036  0.677  1.0
  O  O19  1  0.967  0.488  0.673  1.0
  O  O20  1  0.156  0.849  0.892  1.0
  O  O21  1  0.835  0.143  0.389  1.0
  O  O22  1  0.037  0.504  0.176  1.0
  O  O23  1  0.477  0.967  0.173  1.0
  O  O24  1  0.332  0.669  0.395  1.0
  O  O25  1  0.143  0.312  0.891  1.0
  O  O26  1  0.498  0.527  0.175  1.0
  O  O27  1  0.688  0.846  0.892  1.0
[/CIF]
.