The crystal structure described by PF5 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two phosphorus pentafluoride molecules. P(1) is bonded in a trigonal bipyramidal geometry to two equivalent F(2) and three equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.447
_cell_length_b   5.447
_cell_length_c   6.025
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   154.789
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.667  0.333  0.750  1.0
  P  P1  1  0.333  0.667  0.250  1.0
  F  F2  1  0.830  0.659  0.750  1.0
  F  F3  1  0.170  0.830  0.250  1.0
  F  F4  1  0.333  0.667  0.515  1.0
  F  F5  1  0.667  0.333  0.015  1.0
  F  F6  1  0.667  0.333  0.485  1.0
  F  F7  1  0.333  0.667  0.985  1.0
  F  F8  1  0.170  0.341  0.250  1.0
  F  F9  1  0.830  0.170  0.750  1.0
  F  F10  1  0.341  0.170  0.750  1.0
  F  F11  1  0.659  0.830  0.250  1.0
[/CIF]
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The crystal structure described by PF5 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two phosphorus pentafluoride molecules. P(1) is bonded in a trigonal bipyramidal geometry to two equivalent F(2) and three equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.447
_cell_length_b   5.447
_cell_length_c   6.025
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   154.789
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.667  0.333  0.750  1.0
  P  P1  1  0.333  0.667  0.250  1.0
  F  F2  1  0.830  0.659  0.750  1.0
  F  F3  1  0.170  0.830  0.250  1.0
  F  F4  1  0.333  0.667  0.515  1.0
  F  F5  1  0.667  0.333  0.015  1.0
  F  F6  1  0.667  0.333  0.485  1.0
  F  F7  1  0.333  0.667  0.985  1.0
  F  F8  1  0.170  0.341  0.250  1.0
  F  F9  1  0.830  0.170  0.750  1.0
  F  F10  1  0.341  0.170  0.750  1.0
  F  F11  1  0.659  0.830  0.250  1.0
[/CIF]
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