The material described by C3V crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded in a 10-coordinate geometry to one C(10), one C(12), one C(13), one C(14), one C(17), one C(18), one C(2), one C(23), one C(6), and one C(9) atom. In the second V site, V(2) is bonded in a 7-coordinate geometry to one C(1), one C(11), one C(13), one C(19), one C(20), one C(23), and one C(9) atom. In the third V site, V(3) is bonded in a 5-coordinate geometry to one C(13), one C(16), one C(18), one C(23), one C(3), and one C(4) atom. In the fourth V site, V(4) is bonded in a 7-coordinate geometry to one C(10), one C(15), one C(17), one C(2), one C(3), one C(4), and one C(5) atom. In the fifth V site, V(5) is bonded in a 8-coordinate geometry to one C(1), one C(12), one C(13), one C(14), one C(17), one C(19), one C(22), and one C(24) atom. In the sixth V site, V(6) is bonded in a 8-coordinate geometry to one C(1), one C(14), one C(2), one C(20), one C(21), one C(23), one C(8), and one C(9) atom. In the seventh V site, V(7) is bonded in a 6-coordinate geometry to one C(13), one C(15), one C(17), one C(21), one C(3), one C(4), and one C(5) atom. In the eighth V site, V(8) is bonded in a 9-coordinate geometry to one C(10), one C(11), one C(15), one C(16), one C(18), one C(20), one C(24), one C(3), and one C(4) atom. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a 5-coordinate geometry to one V(2), one V(5), one V(6), one C(21), and one C(8) atom. In the second C site, C(2) is bonded in a 5-coordinate geometry to one V(1), one V(4), one V(6), one C(10), and one C(19) atom. In the third C site, C(3) is bonded in a 5-coordinate geometry to one V(3), one V(4), one V(7), one V(8), and one C(7) atom. In the fourth C site, C(4) is bonded in a 5-coordinate geometry to one V(3), one V(4), one V(7), one V(8), and one C(20) atom. In the fifth C site, C(5) is bonded in a 4-coordinate geometry to one V(4), one V(7), one C(16), and one C(21) atom. In the sixth C site, C(6) is bonded in a 4-coordinate geometry to one V(1), one C(10), one C(14), and one C(21) atom. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one C(22), one C(3), and one C(9) atom. In the eighth C site, C(8) is bonded in a 4-coordinate geometry to one V(6), one C(1), one C(12), and one C(23) atom. In the ninth C site, C(9) is bonded in a 5-coordinate geometry to one V(1), one V(2), one V(6), one C(13), and one C(7) atom. In the tenth C site, C(10) is bonded in a distorted pentagonal planar geometry to one V(1), one V(4), one V(8), one C(2), and one C(6) atom. In the eleventh C site, C(11) is bonded in a 5-coordinate geometry to one V(2), one V(8), one C(15), one C(19), and one C(20) atom. In the twelfth C site, C(12) is bonded in a distorted trigonal pyramidal geometry to one V(1), one V(5), one C(18), and one C(8) atom. In the thirteenth C site, C(13) is bonded in a 7-coordinate geometry to one V(1), one V(2), one V(3), one V(5), one V(7), one C(17), and one C(9) atom. In the fourteenth C site, C(14) is bonded in a 5-coordinate geometry to one V(1), one V(5), one V(6), one C(22), and one C(6) atom. In the fifteenth C site, C(15) is bonded in a 5-coordinate geometry to one V(4), one V(7), one V(8), one C(11), and one C(18) atom. In the sixteenth C site, C(16) is bonded in a 4-coordinate geometry to one V(3), one V(8), one C(24), and one C(5) atom. In the seventeenth C site, C(17) is bonded in a 6-coordinate geometry to one V(1), one V(4), one V(5), one V(7), one C(13), and one C(22) atom. In the eighteenth C site, C(18) is bonded in a 5-coordinate geometry to one V(1), one V(3), one V(8), one C(12), and one C(15) atom. In the nineteenth C site, C(19) is bonded in a 5-coordinate geometry to one V(2), one V(5), one C(11), one C(2), and one C(24) atom. In the twentieth C site, C(20) is bonded in a 5-coordinate geometry to one V(2), one V(6), one V(8), one C(11), and one C(4) atom. In the twenty-first C site, C(21) is bonded in a 5-coordinate geometry to one V(6), one V(7), one C(1), one C(5), and one C(6) atom. In the twenty-second C site, C(22) is bonded in a 4-coordinate geometry to one V(5), one C(14), one C(17), and one C(7) atom. In the twenty-third C site, C(23) is bonded in a 5-coordinate geometry to one V(1), one V(2), one V(3), one V(6), and one C(8) atom. In the twenty-fourth C site, C(24) is bonded in a 4-coordinate geometry to one V(5), one V(8), one C(16), and one C(19) atom. is represented by the CIF card [CIF]
data_VC3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.143
_cell_length_b   6.212
_cell_length_c   8.021
_cell_angle_alpha   108.176
_cell_angle_beta   104.905
_cell_angle_gamma   88.253
_symmetry_Int_Tables_number   1
_cell_volume   280.639
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.048  0.170  0.582  1.0
  V  V1  1  0.535  0.465  0.494  1.0
  V  V2  1  0.495  0.527  0.927  1.0
  V  V3  1  0.972  0.042  0.038  1.0
  V  V4  1  0.552  0.023  0.536  1.0
  V  V5  1  0.022  0.497  0.455  1.0
  V  V6  1  0.932  0.434  0.966  1.0
  V  V7  1  0.591  0.003  0.076  1.0
  C  C8  1  0.302  0.674  0.430  1.0
  C  C9  1  0.107  0.188  0.320  1.0
  C  C10  1  0.735  0.743  0.917  1.0
  C  C11  1  0.744  0.328  0.090  1.0
  C  C12  1  0.155  0.697  0.112  1.0
  C  C13  1  0.949  0.851  0.358  1.0
  C  C14  1  0.821  0.713  0.762  1.0
  C  C15  1  0.305  0.759  0.625  1.0
  C  C16  1  0.867  0.485  0.659  1.0
  C  C17  1  0.904  0.040  0.286  1.0
  C  C18  1  0.419  0.288  0.206  1.0
  C  C19  1  0.333  0.010  0.699  1.0
  C  C20  1  0.750  0.304  0.695  1.0
  C  C21  1  0.841  0.823  0.487  1.0
  C  C22  1  0.267  0.204  0.025  1.0
  C  C23  1  0.368  0.773  0.111  1.0
  C  C24  1  0.861  0.125  0.772  1.0
  C  C25  1  0.358  0.186  0.870  1.0
  C  C26  1  0.351  0.166  0.332  1.0
  C  C27  1  0.649  0.362  0.239  1.0
  C  C28  1  0.125  0.713  0.291  1.0
  C  C29  1  0.845  0.886  0.678  1.0
  C  C30  1  0.322  0.568  0.692  1.0
  C  C31  1  0.475  0.952  0.271  1.0
[/CIF]
.
The material described by C3V crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded in a 10-coordinate geometry to one C(10), one C(12), one C(13), one C(14), one C(17), one C(18), one C(2), one C(23), one C(6), and one C(9) atom. In the second V site, V(2) is bonded in a 7-coordinate geometry to one C(1), one C(11), one C(13), one C(19), one C(20), one C(23), and one C(9) atom. In the third V site, V(3) is bonded in a 5-coordinate geometry to one C(13), one C(16), one C(18), one C(23), one C(3), and one C(4) atom. In the fourth V site, V(4) is bonded in a 7-coordinate geometry to one C(10), one C(15), one C(17), one C(2), one C(3), one C(4), and one C(5) atom. In the fifth V site, V(5) is bonded in a 8-coordinate geometry to one C(1), one C(12), one C(13), one C(14), one C(17), one C(19), one C(22), and one C(24) atom. In the sixth V site, V(6) is bonded in a 8-coordinate geometry to one C(1), one C(14), one C(2), one C(20), one C(21), one C(23), one C(8), and one C(9) atom. In the seventh V site, V(7) is bonded in a 6-coordinate geometry to one C(13), one C(15), one C(17), one C(21), one C(3), one C(4), and one C(5) atom. In the eighth V site, V(8) is bonded in a 9-coordinate geometry to one C(10), one C(11), one C(15), one C(16), one C(18), one C(20), one C(24), one C(3), and one C(4) atom. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a 5-coordinate geometry to one V(2), one V(5), one V(6), one C(21), and one C(8) atom. In the second C site, C(2) is bonded in a 5-coordinate geometry to one V(1), one V(4), one V(6), one C(10), and one C(19) atom. In the third C site, C(3) is bonded in a 5-coordinate geometry to one V(3), one V(4), one V(7), one V(8), and one C(7) atom. In the fourth C site, C(4) is bonded in a 5-coordinate geometry to one V(3), one V(4), one V(7), one V(8), and one C(20) atom. In the fifth C site, C(5) is bonded in a 4-coordinate geometry to one V(4), one V(7), one C(16), and one C(21) atom. In the sixth C site, C(6) is bonded in a 4-coordinate geometry to one V(1), one C(10), one C(14), and one C(21) atom. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one C(22), one C(3), and one C(9) atom. In the eighth C site, C(8) is bonded in a 4-coordinate geometry to one V(6), one C(1), one C(12), and one C(23) atom. In the ninth C site, C(9) is bonded in a 5-coordinate geometry to one V(1), one V(2), one V(6), one C(13), and one C(7) atom. In the tenth C site, C(10) is bonded in a distorted pentagonal planar geometry to one V(1), one V(4), one V(8), one C(2), and one C(6) atom. In the eleventh C site, C(11) is bonded in a 5-coordinate geometry to one V(2), one V(8), one C(15), one C(19), and one C(20) atom. In the twelfth C site, C(12) is bonded in a distorted trigonal pyramidal geometry to one V(1), one V(5), one C(18), and one C(8) atom. In the thirteenth C site, C(13) is bonded in a 7-coordinate geometry to one V(1), one V(2), one V(3), one V(5), one V(7), one C(17), and one C(9) atom. In the fourteenth C site, C(14) is bonded in a 5-coordinate geometry to one V(1), one V(5), one V(6), one C(22), and one C(6) atom. In the fifteenth C site, C(15) is bonded in a 5-coordinate geometry to one V(4), one V(7), one V(8), one C(11), and one C(18) atom. In the sixteenth C site, C(16) is bonded in a 4-coordinate geometry to one V(3), one V(8), one C(24), and one C(5) atom. In the seventeenth C site, C(17) is bonded in a 6-coordinate geometry to one V(1), one V(4), one V(5), one V(7), one C(13), and one C(22) atom. In the eighteenth C site, C(18) is bonded in a 5-coordinate geometry to one V(1), one V(3), one V(8), one C(12), and one C(15) atom. In the nineteenth C site, C(19) is bonded in a 5-coordinate geometry to one V(2), one V(5), one C(11), one C(2), and one C(24) atom. In the twentieth C site, C(20) is bonded in a 5-coordinate geometry to one V(2), one V(6), one V(8), one C(11), and one C(4) atom. In the twenty-first C site, C(21) is bonded in a 5-coordinate geometry to one V(6), one V(7), one C(1), one C(5), and one C(6) atom. In the twenty-second C site, C(22) is bonded in a 4-coordinate geometry to one V(5), one C(14), one C(17), and one C(7) atom. In the twenty-third C site, C(23) is bonded in a 5-coordinate geometry to one V(1), one V(2), one V(3), one V(6), and one C(8) atom. In the twenty-fourth C site, C(24) is bonded in a 4-coordinate geometry to one V(5), one V(8), one C(16), and one C(19) atom. is represented by the CIF card [CIF]
data_VC3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.143
_cell_length_b   6.212
_cell_length_c   8.021
_cell_angle_alpha   108.176
_cell_angle_beta   104.905
_cell_angle_gamma   88.253
_symmetry_Int_Tables_number   1
_cell_volume   280.639
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.048  0.170  0.582  1.0
  V  V1  1  0.535  0.465  0.494  1.0
  V  V2  1  0.495  0.527  0.927  1.0
  V  V3  1  0.972  0.042  0.038  1.0
  V  V4  1  0.552  0.023  0.536  1.0
  V  V5  1  0.022  0.497  0.455  1.0
  V  V6  1  0.932  0.434  0.966  1.0
  V  V7  1  0.591  0.003  0.076  1.0
  C  C8  1  0.302  0.674  0.430  1.0
  C  C9  1  0.107  0.188  0.320  1.0
  C  C10  1  0.735  0.743  0.917  1.0
  C  C11  1  0.744  0.328  0.090  1.0
  C  C12  1  0.155  0.697  0.112  1.0
  C  C13  1  0.949  0.851  0.358  1.0
  C  C14  1  0.821  0.713  0.762  1.0
  C  C15  1  0.305  0.759  0.625  1.0
  C  C16  1  0.867  0.485  0.659  1.0
  C  C17  1  0.904  0.040  0.286  1.0
  C  C18  1  0.419  0.288  0.206  1.0
  C  C19  1  0.333  0.010  0.699  1.0
  C  C20  1  0.750  0.304  0.695  1.0
  C  C21  1  0.841  0.823  0.487  1.0
  C  C22  1  0.267  0.204  0.025  1.0
  C  C23  1  0.368  0.773  0.111  1.0
  C  C24  1  0.861  0.125  0.772  1.0
  C  C25  1  0.358  0.186  0.870  1.0
  C  C26  1  0.351  0.166  0.332  1.0
  C  C27  1  0.649  0.362  0.239  1.0
  C  C28  1  0.125  0.713  0.291  1.0
  C  C29  1  0.845  0.886  0.678  1.0
  C  C30  1  0.322  0.568  0.692  1.0
  C  C31  1  0.475  0.952  0.271  1.0
[/CIF]
.