The crystal structure described by K5Pb24 crystallizes in the cubic I-43m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 12-coordinate geometry to one K(2), three equivalent Pb(2), and nine equivalent Pb(1) atoms. In the second K site, K(2) is bonded in a 16-coordinate geometry to four equivalent K(1) and twelve equivalent Pb(1) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(2) is bonded in a distorted single-bond geometry to one K(1) and five equivalent Pb(1) atoms. In the second Pb site, Pb(1) is bonded in a 12-coordinate geometry to one K(2), three equivalent K(1), three equivalent Pb(1), and five equivalent Pb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_K5Pb24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.787
_cell_length_b   10.787
_cell_length_c   10.787
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   966.180
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.363  1.0
  K  K1  1  0.000  0.363  0.000  1.0
  K  K2  1  0.363  0.000  0.000  1.0
  K  K3  1  0.637  0.637  0.637  1.0
  K  K4  1  0.000  0.000  0.000  1.0
  Pb  Pb5  1  0.200  0.809  0.200  1.0
  Pb  Pb6  1  0.800  0.000  0.609  1.0
  Pb  Pb7  1  0.609  0.000  0.800  1.0
  Pb  Pb8  1  0.000  0.609  0.800  1.0
  Pb  Pb9  1  0.191  0.391  0.391  1.0
  Pb  Pb10  1  0.391  0.191  0.391  1.0
  Pb  Pb11  1  0.200  0.200  0.809  1.0
  Pb  Pb12  1  0.401  0.721  0.401  1.0
  Pb  Pb13  1  0.279  0.680  0.680  1.0
  Pb  Pb14  1  0.000  0.599  0.320  1.0
  Pb  Pb15  1  0.320  0.000  0.599  1.0
  Pb  Pb16  1  0.599  0.000  0.320  1.0
  Pb  Pb17  1  0.320  0.599  0.000  1.0
  Pb  Pb18  1  0.680  0.680  0.279  1.0
  Pb  Pb19  1  0.000  0.320  0.599  1.0
  Pb  Pb20  1  0.599  0.320  0.000  1.0
  Pb  Pb21  1  0.401  0.401  0.721  1.0
  Pb  Pb22  1  0.721  0.401  0.401  1.0
  Pb  Pb23  1  0.680  0.279  0.680  1.0
  Pb  Pb24  1  0.809  0.200  0.200  1.0
  Pb  Pb25  1  0.000  0.800  0.609  1.0
  Pb  Pb26  1  0.800  0.609  0.000  1.0
  Pb  Pb27  1  0.609  0.800  0.000  1.0
  Pb  Pb28  1  0.391  0.391  0.191  1.0
[/CIF]
.
The crystal structure described by K5Pb24 crystallizes in the cubic I-43m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 12-coordinate geometry to one K(2), three equivalent Pb(2), and nine equivalent Pb(1) atoms. In the second K site, K(2) is bonded in a 16-coordinate geometry to four equivalent K(1) and twelve equivalent Pb(1) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(2) is bonded in a distorted single-bond geometry to one K(1) and five equivalent Pb(1) atoms. In the second Pb site, Pb(1) is bonded in a 12-coordinate geometry to one K(2), three equivalent K(1), three equivalent Pb(1), and five equivalent Pb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_K5Pb24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.787
_cell_length_b   10.787
_cell_length_c   10.787
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   966.180
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.363  1.0
  K  K1  1  0.000  0.363  0.000  1.0
  K  K2  1  0.363  0.000  0.000  1.0
  K  K3  1  0.637  0.637  0.637  1.0
  K  K4  1  0.000  0.000  0.000  1.0
  Pb  Pb5  1  0.200  0.809  0.200  1.0
  Pb  Pb6  1  0.800  0.000  0.609  1.0
  Pb  Pb7  1  0.609  0.000  0.800  1.0
  Pb  Pb8  1  0.000  0.609  0.800  1.0
  Pb  Pb9  1  0.191  0.391  0.391  1.0
  Pb  Pb10  1  0.391  0.191  0.391  1.0
  Pb  Pb11  1  0.200  0.200  0.809  1.0
  Pb  Pb12  1  0.401  0.721  0.401  1.0
  Pb  Pb13  1  0.279  0.680  0.680  1.0
  Pb  Pb14  1  0.000  0.599  0.320  1.0
  Pb  Pb15  1  0.320  0.000  0.599  1.0
  Pb  Pb16  1  0.599  0.000  0.320  1.0
  Pb  Pb17  1  0.320  0.599  0.000  1.0
  Pb  Pb18  1  0.680  0.680  0.279  1.0
  Pb  Pb19  1  0.000  0.320  0.599  1.0
  Pb  Pb20  1  0.599  0.320  0.000  1.0
  Pb  Pb21  1  0.401  0.401  0.721  1.0
  Pb  Pb22  1  0.721  0.401  0.401  1.0
  Pb  Pb23  1  0.680  0.279  0.680  1.0
  Pb  Pb24  1  0.809  0.200  0.200  1.0
  Pb  Pb25  1  0.000  0.800  0.609  1.0
  Pb  Pb26  1  0.800  0.609  0.000  1.0
  Pb  Pb27  1  0.609  0.800  0.000  1.0
  Pb  Pb28  1  0.391  0.391  0.191  1.0
[/CIF]
.