The material described by VO2SO4O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and two VO2SO4 clusters. In each VO2SO4 cluster, V(1) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form VO4 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form SO4 tetrahedra that share corners with two equivalent V(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_VSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.724
_cell_length_b   7.423
_cell_length_c   11.904
_cell_angle_alpha   65.297
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   780.563
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.117  0.716  0.861  1.0
  V  V1  1  0.617  0.284  0.639  1.0
  V  V2  1  0.883  0.284  0.139  1.0
  V  V3  1  0.383  0.716  0.361  1.0
  S  S4  1  0.851  0.750  0.024  1.0
  S  S5  1  0.351  0.250  0.476  1.0
  S  S6  1  0.149  0.250  0.976  1.0
  S  S7  1  0.649  0.750  0.524  1.0
  O  O8  1  0.190  0.462  0.962  1.0
  O  O9  1  0.690  0.538  0.538  1.0
  O  O10  1  0.810  0.538  0.038  1.0
  O  O11  1  0.310  0.462  0.462  1.0
  O  O12  1  0.992  0.785  0.960  1.0
  O  O13  1  0.492  0.215  0.540  1.0
  O  O14  1  0.008  0.215  0.040  1.0
  O  O15  1  0.508  0.785  0.460  1.0
  O  O16  1  0.752  0.890  0.943  1.0
  O  O17  1  0.252  0.110  0.557  1.0
  O  O18  1  0.248  0.110  0.057  1.0
  O  O19  1  0.748  0.890  0.443  1.0
  O  O20  1  0.245  0.877  0.809  1.0
  O  O21  1  0.745  0.123  0.691  1.0
  O  O22  1  0.755  0.123  0.191  1.0
  O  O23  1  0.255  0.877  0.309  1.0
  O  O24  1  0.042  0.705  0.741  1.0
  O  O25  1  0.542  0.295  0.759  1.0
  O  O26  1  0.958  0.295  0.259  1.0
  O  O27  1  0.458  0.705  0.241  1.0
  O  O28  1  0.868  0.752  0.144  1.0
  O  O29  1  0.368  0.248  0.356  1.0
  O  O30  1  0.132  0.248  0.856  1.0
  O  O31  1  0.632  0.752  0.644  1.0
  O  O32  1  0.478  0.717  0.973  1.0
  O  O33  1  0.978  0.283  0.527  1.0
  O  O34  1  0.522  0.283  0.027  1.0
  O  O35  1  0.022  0.717  0.473  1.0
  O  O36  1  0.512  0.686  0.884  1.0
  O  O37  1  0.012  0.314  0.616  1.0
  O  O38  1  0.488  0.314  0.116  1.0
  O  O39  1  0.988  0.686  0.384  1.0
[/CIF]
.
The material described by VO2SO4O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and two VO2SO4 clusters. In each VO2SO4 cluster, V(1) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form VO4 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form SO4 tetrahedra that share corners with two equivalent V(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_VSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.724
_cell_length_b   7.423
_cell_length_c   11.904
_cell_angle_alpha   65.297
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   780.563
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.117  0.716  0.861  1.0
  V  V1  1  0.617  0.284  0.639  1.0
  V  V2  1  0.883  0.284  0.139  1.0
  V  V3  1  0.383  0.716  0.361  1.0
  S  S4  1  0.851  0.750  0.024  1.0
  S  S5  1  0.351  0.250  0.476  1.0
  S  S6  1  0.149  0.250  0.976  1.0
  S  S7  1  0.649  0.750  0.524  1.0
  O  O8  1  0.190  0.462  0.962  1.0
  O  O9  1  0.690  0.538  0.538  1.0
  O  O10  1  0.810  0.538  0.038  1.0
  O  O11  1  0.310  0.462  0.462  1.0
  O  O12  1  0.992  0.785  0.960  1.0
  O  O13  1  0.492  0.215  0.540  1.0
  O  O14  1  0.008  0.215  0.040  1.0
  O  O15  1  0.508  0.785  0.460  1.0
  O  O16  1  0.752  0.890  0.943  1.0
  O  O17  1  0.252  0.110  0.557  1.0
  O  O18  1  0.248  0.110  0.057  1.0
  O  O19  1  0.748  0.890  0.443  1.0
  O  O20  1  0.245  0.877  0.809  1.0
  O  O21  1  0.745  0.123  0.691  1.0
  O  O22  1  0.755  0.123  0.191  1.0
  O  O23  1  0.255  0.877  0.309  1.0
  O  O24  1  0.042  0.705  0.741  1.0
  O  O25  1  0.542  0.295  0.759  1.0
  O  O26  1  0.958  0.295  0.259  1.0
  O  O27  1  0.458  0.705  0.241  1.0
  O  O28  1  0.868  0.752  0.144  1.0
  O  O29  1  0.368  0.248  0.356  1.0
  O  O30  1  0.132  0.248  0.856  1.0
  O  O31  1  0.632  0.752  0.644  1.0
  O  O32  1  0.478  0.717  0.973  1.0
  O  O33  1  0.978  0.283  0.527  1.0
  O  O34  1  0.522  0.283  0.027  1.0
  O  O35  1  0.022  0.717  0.473  1.0
  O  O36  1  0.512  0.686  0.884  1.0
  O  O37  1  0.012  0.314  0.616  1.0
  O  O38  1  0.488  0.314  0.116  1.0
  O  O39  1  0.988  0.686  0.384  1.0
[/CIF]
.