The compound described by TlTlCl4 is Iron carbide-like structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four TlCl4 clusters. In each TlCl4 cluster, Tl(2) is bonded in a tetrahedral geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one Tl(2) atom. is represented by the CIF file [CIF]
data_TlCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.043
_cell_length_b   7.043
_cell_length_c   9.164
_cell_angle_alpha   112.600
_cell_angle_beta   112.600
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   381.628
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.625  0.875  0.250  1.0
  Tl  Tl1  1  0.375  0.125  0.750  1.0
  Tl  Tl2  1  0.125  0.375  0.250  1.0
  Tl  Tl3  1  0.875  0.625  0.750  1.0
  Cl  Cl4  1  0.280  0.453  0.075  1.0
  Cl  Cl5  1  0.622  0.780  0.575  1.0
  Cl  Cl6  1  0.953  0.296  0.575  1.0
  Cl  Cl7  1  0.796  0.122  0.075  1.0
  Cl  Cl8  1  0.204  0.878  0.925  1.0
  Cl  Cl9  1  0.047  0.704  0.425  1.0
  Cl  Cl10  1  0.378  0.220  0.425  1.0
  Cl  Cl11  1  0.720  0.547  0.925  1.0
[/CIF]
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The compound described by TlTlCl4 is Iron carbide-like structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four TlCl4 clusters. In each TlCl4 cluster, Tl(2) is bonded in a tetrahedral geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one Tl(2) atom. is represented by the CIF file [CIF]
data_TlCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.043
_cell_length_b   7.043
_cell_length_c   9.164
_cell_angle_alpha   112.600
_cell_angle_beta   112.600
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   381.628
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.625  0.875  0.250  1.0
  Tl  Tl1  1  0.375  0.125  0.750  1.0
  Tl  Tl2  1  0.125  0.375  0.250  1.0
  Tl  Tl3  1  0.875  0.625  0.750  1.0
  Cl  Cl4  1  0.280  0.453  0.075  1.0
  Cl  Cl5  1  0.622  0.780  0.575  1.0
  Cl  Cl6  1  0.953  0.296  0.575  1.0
  Cl  Cl7  1  0.796  0.122  0.075  1.0
  Cl  Cl8  1  0.204  0.878  0.925  1.0
  Cl  Cl9  1  0.047  0.704  0.425  1.0
  Cl  Cl10  1  0.378  0.220  0.425  1.0
  Cl  Cl11  1  0.720  0.547  0.925  1.0
[/CIF]
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