The crystal structure described by RuH14S2(N2O3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two RuH14S2(N2O3)2 clusters. Ru(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent S(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(1), one H(2), and one H(6) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(4), one H(5), and one H(7) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a 3-coordinate geometry to one Ru(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one H(3) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H14RuS2(N2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.092
_cell_length_b   6.315
_cell_length_c   11.767
_cell_angle_alpha   65.591
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   479.881
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.117  0.706  0.230  1.0
  H  H1  1  0.888  0.684  0.230  1.0
  H  H2  1  0.539  0.777  0.088  1.0
  H  H3  1  0.717  0.339  0.523  1.0
  H  H4  1  0.607  0.184  0.656  1.0
  H  H5  1  0.023  0.545  0.167  1.0
  H  H6  1  0.523  0.455  0.333  1.0
  H  H7  1  0.303  0.913  0.882  1.0
  H  H8  1  0.803  0.087  0.618  1.0
  H  H9  1  0.039  0.223  0.412  1.0
  H  H10  1  0.388  0.316  0.270  1.0
  H  H11  1  0.107  0.816  0.844  1.0
  H  H12  1  0.617  0.294  0.270  1.0
  H  H13  1  0.217  0.661  0.977  1.0
  H  H14  1  0.783  0.339  0.023  1.0
  H  H15  1  0.383  0.706  0.730  1.0
  H  H16  1  0.893  0.184  0.156  1.0
  H  H17  1  0.612  0.684  0.730  1.0
  H  H18  1  0.961  0.777  0.588  1.0
  H  H19  1  0.197  0.913  0.382  1.0
  H  H20  1  0.697  0.087  0.118  1.0
  H  H21  1  0.477  0.545  0.667  1.0
  H  H22  1  0.977  0.455  0.833  1.0
  H  H23  1  0.393  0.816  0.344  1.0
  H  H24  1  0.283  0.661  0.477  1.0
  H  H25  1  0.461  0.223  0.912  1.0
  H  H26  1  0.112  0.316  0.770  1.0
  H  H27  1  0.883  0.294  0.770  1.0
  Ru  Ru28  1  0.000  0.000  0.000  1.0
  Ru  Ru29  1  0.500  0.000  0.500  1.0
  S  S30  1  0.744  0.861  0.937  1.0
  S  S31  1  0.244  0.139  0.563  1.0
  S  S32  1  0.756  0.861  0.437  1.0
  S  S33  1  0.256  0.139  0.063  1.0
  N  N34  1  0.006  0.699  0.176  1.0
  N  N35  1  0.680  0.173  0.583  1.0
  N  N36  1  0.506  0.301  0.324  1.0
  N  N37  1  0.180  0.827  0.917  1.0
  N  N38  1  0.820  0.173  0.083  1.0
  N  N39  1  0.494  0.699  0.676  1.0
  N  N40  1  0.320  0.827  0.417  1.0
  N  N41  1  0.994  0.301  0.824  1.0
  O  O42  1  0.286  0.293  0.628  1.0
  O  O43  1  0.601  0.044  0.864  1.0
  O  O44  1  0.621  0.681  0.058  1.0
  O  O45  1  0.121  0.319  0.442  1.0
  O  O46  1  0.101  0.956  0.636  1.0
  O  O47  1  0.786  0.707  0.872  1.0
  O  O48  1  0.214  0.293  0.128  1.0
  O  O49  1  0.899  0.044  0.364  1.0
  O  O50  1  0.879  0.681  0.558  1.0
  O  O51  1  0.379  0.319  0.942  1.0
  O  O52  1  0.399  0.956  0.136  1.0
  O  O53  1  0.714  0.707  0.372  1.0
[/CIF]
.
The crystal structure described by RuH14S2(N2O3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two RuH14S2(N2O3)2 clusters. Ru(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent S(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(1), one H(2), and one H(6) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(4), one H(5), and one H(7) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a 3-coordinate geometry to one Ru(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one H(3) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H14RuS2(N2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.092
_cell_length_b   6.315
_cell_length_c   11.767
_cell_angle_alpha   65.591
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   479.881
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.117  0.706  0.230  1.0
  H  H1  1  0.888  0.684  0.230  1.0
  H  H2  1  0.539  0.777  0.088  1.0
  H  H3  1  0.717  0.339  0.523  1.0
  H  H4  1  0.607  0.184  0.656  1.0
  H  H5  1  0.023  0.545  0.167  1.0
  H  H6  1  0.523  0.455  0.333  1.0
  H  H7  1  0.303  0.913  0.882  1.0
  H  H8  1  0.803  0.087  0.618  1.0
  H  H9  1  0.039  0.223  0.412  1.0
  H  H10  1  0.388  0.316  0.270  1.0
  H  H11  1  0.107  0.816  0.844  1.0
  H  H12  1  0.617  0.294  0.270  1.0
  H  H13  1  0.217  0.661  0.977  1.0
  H  H14  1  0.783  0.339  0.023  1.0
  H  H15  1  0.383  0.706  0.730  1.0
  H  H16  1  0.893  0.184  0.156  1.0
  H  H17  1  0.612  0.684  0.730  1.0
  H  H18  1  0.961  0.777  0.588  1.0
  H  H19  1  0.197  0.913  0.382  1.0
  H  H20  1  0.697  0.087  0.118  1.0
  H  H21  1  0.477  0.545  0.667  1.0
  H  H22  1  0.977  0.455  0.833  1.0
  H  H23  1  0.393  0.816  0.344  1.0
  H  H24  1  0.283  0.661  0.477  1.0
  H  H25  1  0.461  0.223  0.912  1.0
  H  H26  1  0.112  0.316  0.770  1.0
  H  H27  1  0.883  0.294  0.770  1.0
  Ru  Ru28  1  0.000  0.000  0.000  1.0
  Ru  Ru29  1  0.500  0.000  0.500  1.0
  S  S30  1  0.744  0.861  0.937  1.0
  S  S31  1  0.244  0.139  0.563  1.0
  S  S32  1  0.756  0.861  0.437  1.0
  S  S33  1  0.256  0.139  0.063  1.0
  N  N34  1  0.006  0.699  0.176  1.0
  N  N35  1  0.680  0.173  0.583  1.0
  N  N36  1  0.506  0.301  0.324  1.0
  N  N37  1  0.180  0.827  0.917  1.0
  N  N38  1  0.820  0.173  0.083  1.0
  N  N39  1  0.494  0.699  0.676  1.0
  N  N40  1  0.320  0.827  0.417  1.0
  N  N41  1  0.994  0.301  0.824  1.0
  O  O42  1  0.286  0.293  0.628  1.0
  O  O43  1  0.601  0.044  0.864  1.0
  O  O44  1  0.621  0.681  0.058  1.0
  O  O45  1  0.121  0.319  0.442  1.0
  O  O46  1  0.101  0.956  0.636  1.0
  O  O47  1  0.786  0.707  0.872  1.0
  O  O48  1  0.214  0.293  0.128  1.0
  O  O49  1  0.899  0.044  0.364  1.0
  O  O50  1  0.879  0.681  0.558  1.0
  O  O51  1  0.379  0.319  0.942  1.0
  O  O52  1  0.399  0.956  0.136  1.0
  O  O53  1  0.714  0.707  0.372  1.0
[/CIF]
.