The structure described by NaPH4SO8 crystallizes in the monoclinic P2_1 space group. Na(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(2) and one O(8) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(5) and one O(8) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(3) and one O(7) atom. S(1) is bonded in a tetrahedral geometry to one O(4), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Na(1), one P(1), and one H(2) atom. In the third O site, O(3) is bonded in a distorted tetrahedral geometry to one Na(1), one P(1), one H(1), and one H(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Na(1), one H(4), and one S(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one H(2), one H(3), and one S(1) atom. is represented by the CIF card [CIF]
data_NaPH4SO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.845
_cell_length_b   5.473
_cell_length_c   8.821
_cell_angle_alpha   84.578
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   328.980
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.860  0.987  0.446  1.0
  Na  Na1  1  0.360  0.013  0.554  1.0
  P  P2  1  0.120  0.882  0.878  1.0
  P  P3  1  0.620  0.118  0.122  1.0
  H  H4  1  0.504  0.913  0.931  1.0
  H  H5  1  0.420  0.846  0.249  1.0
  H  H6  1  0.914  0.572  0.861  1.0
  H  H7  1  0.390  0.548  0.778  1.0
  H  H8  1  0.890  0.452  0.222  1.0
  H  H9  1  0.414  0.428  0.139  1.0
  H  H10  1  0.920  0.154  0.751  1.0
  H  H11  1  0.004  0.087  0.069  1.0
  S  S12  1  0.136  0.541  0.361  1.0
  S  S13  1  0.636  0.459  0.639  1.0
  O  O14  1  0.628  0.948  0.990  1.0
  O  O15  1  0.512  0.986  0.266  1.0
  O  O16  1  0.327  0.824  0.832  1.0
  O  O17  1  0.634  0.715  0.578  1.0
  O  O18  1  0.004  0.645  0.936  1.0
  O  O19  1  0.139  0.720  0.474  1.0
  O  O20  1  0.934  0.597  0.277  1.0
  O  O21  1  0.295  0.595  0.247  1.0
  O  O22  1  0.795  0.405  0.753  1.0
  O  O23  1  0.434  0.403  0.723  1.0
  O  O24  1  0.639  0.280  0.526  1.0
  O  O25  1  0.504  0.355  0.064  1.0
  O  O26  1  0.134  0.285  0.422  1.0
  O  O27  1  0.827  0.176  0.168  1.0
  O  O28  1  0.012  0.014  0.734  1.0
  O  O29  1  0.128  0.052  0.010  1.0
[/CIF]
.
The structure described by NaPH4SO8 crystallizes in the monoclinic P2_1 space group. Na(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(2) and one O(8) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(5) and one O(8) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(3) and one O(7) atom. S(1) is bonded in a tetrahedral geometry to one O(4), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Na(1), one P(1), and one H(2) atom. In the third O site, O(3) is bonded in a distorted tetrahedral geometry to one Na(1), one P(1), one H(1), and one H(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Na(1), one H(4), and one S(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one H(2), one H(3), and one S(1) atom. is represented by the CIF card [CIF]
data_NaPH4SO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.845
_cell_length_b   5.473
_cell_length_c   8.821
_cell_angle_alpha   84.578
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   328.980
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.860  0.987  0.446  1.0
  Na  Na1  1  0.360  0.013  0.554  1.0
  P  P2  1  0.120  0.882  0.878  1.0
  P  P3  1  0.620  0.118  0.122  1.0
  H  H4  1  0.504  0.913  0.931  1.0
  H  H5  1  0.420  0.846  0.249  1.0
  H  H6  1  0.914  0.572  0.861  1.0
  H  H7  1  0.390  0.548  0.778  1.0
  H  H8  1  0.890  0.452  0.222  1.0
  H  H9  1  0.414  0.428  0.139  1.0
  H  H10  1  0.920  0.154  0.751  1.0
  H  H11  1  0.004  0.087  0.069  1.0
  S  S12  1  0.136  0.541  0.361  1.0
  S  S13  1  0.636  0.459  0.639  1.0
  O  O14  1  0.628  0.948  0.990  1.0
  O  O15  1  0.512  0.986  0.266  1.0
  O  O16  1  0.327  0.824  0.832  1.0
  O  O17  1  0.634  0.715  0.578  1.0
  O  O18  1  0.004  0.645  0.936  1.0
  O  O19  1  0.139  0.720  0.474  1.0
  O  O20  1  0.934  0.597  0.277  1.0
  O  O21  1  0.295  0.595  0.247  1.0
  O  O22  1  0.795  0.405  0.753  1.0
  O  O23  1  0.434  0.403  0.723  1.0
  O  O24  1  0.639  0.280  0.526  1.0
  O  O25  1  0.504  0.355  0.064  1.0
  O  O26  1  0.134  0.285  0.422  1.0
  O  O27  1  0.827  0.176  0.168  1.0
  O  O28  1  0.012  0.014  0.734  1.0
  O  O29  1  0.128  0.052  0.010  1.0
[/CIF]
.