The compound described by LiNaNbBiO6 crystallizes in the cubic F-43m space group. The structure consists of four 7439-93-2 atoms inside a NaNbBiO6 framework. In the NaNbBiO6 framework, Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with four equivalent Nb(1)O6 octahedra, and faces with four equivalent Bi(1)O6 octahedra. Nb(1) is bonded to six equivalent O(1) atoms to form NbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Nb(1)O6 octahedra and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent Na(1), one Nb(1), and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaLiNbBiO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.781
_cell_length_b   5.781
_cell_length_c   5.781
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   136.600
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.750  0.750  1.0
  Li  Li1  1  0.250  0.250  0.250  1.0
  Nb  Nb2  1  0.500  0.500  0.500  1.0
  Bi  Bi3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.744  0.256  0.256  1.0
  O  O5  1  0.256  0.744  0.744  1.0
  O  O6  1  0.744  0.256  0.744  1.0
  O  O7  1  0.256  0.744  0.256  1.0
  O  O8  1  0.744  0.744  0.256  1.0
  O  O9  1  0.256  0.256  0.744  1.0
[/CIF]
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The compound described by LiNaNbBiO6 crystallizes in the cubic F-43m space group. The structure consists of four 7439-93-2 atoms inside a NaNbBiO6 framework. In the NaNbBiO6 framework, Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with four equivalent Nb(1)O6 octahedra, and faces with four equivalent Bi(1)O6 octahedra. Nb(1) is bonded to six equivalent O(1) atoms to form NbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Nb(1)O6 octahedra and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent Na(1), one Nb(1), and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaLiNbBiO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.781
_cell_length_b   5.781
_cell_length_c   5.781
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   136.600
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.750  0.750  1.0
  Li  Li1  1  0.250  0.250  0.250  1.0
  Nb  Nb2  1  0.500  0.500  0.500  1.0
  Bi  Bi3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.744  0.256  0.256  1.0
  O  O5  1  0.256  0.744  0.744  1.0
  O  O6  1  0.744  0.256  0.744  1.0
  O  O7  1  0.256  0.744  0.256  1.0
  O  O8  1  0.744  0.744  0.256  1.0
  O  O9  1  0.256  0.256  0.744  1.0
[/CIF]
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