The material structure described by CsSO3F crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to two equivalent O(1), three equivalent O(2), three equivalent O(3), and one F(1) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. F(1) is bonded in a single-bond geometry to one Cs(1) and one S(1) atom. is represented by the CIF file [CIF]
data_CsSO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.284
_cell_length_b   7.908
_cell_length_c   8.213
_cell_angle_alpha   65.841
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   490.885
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.621  0.276  0.718  1.0
  Cs  Cs1  1  0.121  0.724  0.782  1.0
  Cs  Cs2  1  0.879  0.276  0.218  1.0
  Cs  Cs3  1  0.379  0.724  0.282  1.0
  S  S4  1  0.617  0.742  0.787  1.0
  S  S5  1  0.383  0.258  0.213  1.0
  S  S6  1  0.883  0.742  0.287  1.0
  S  S7  1  0.117  0.258  0.713  1.0
  O  O8  1  0.447  0.174  0.099  1.0
  O  O9  1  0.947  0.826  0.401  1.0
  O  O10  1  0.256  0.394  0.139  1.0
  O  O11  1  0.744  0.606  0.861  1.0
  O  O12  1  0.503  0.306  0.318  1.0
  O  O13  1  0.497  0.694  0.682  1.0
  O  O14  1  0.003  0.694  0.182  1.0
  O  O15  1  0.553  0.826  0.901  1.0
  O  O16  1  0.053  0.174  0.599  1.0
  O  O17  1  0.756  0.606  0.361  1.0
  O  O18  1  0.244  0.394  0.639  1.0
  O  O19  1  0.997  0.306  0.818  1.0
  F  F20  1  0.786  0.919  0.134  1.0
  F  F21  1  0.286  0.081  0.366  1.0
  F  F22  1  0.714  0.919  0.634  1.0
  F  F23  1  0.214  0.081  0.866  1.0
[/CIF]
.
The material structure described by CsSO3F crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to two equivalent O(1), three equivalent O(2), three equivalent O(3), and one F(1) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. F(1) is bonded in a single-bond geometry to one Cs(1) and one S(1) atom. is represented by the CIF file [CIF]
data_CsSO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.284
_cell_length_b   7.908
_cell_length_c   8.213
_cell_angle_alpha   65.841
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   490.885
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.621  0.276  0.718  1.0
  Cs  Cs1  1  0.121  0.724  0.782  1.0
  Cs  Cs2  1  0.879  0.276  0.218  1.0
  Cs  Cs3  1  0.379  0.724  0.282  1.0
  S  S4  1  0.617  0.742  0.787  1.0
  S  S5  1  0.383  0.258  0.213  1.0
  S  S6  1  0.883  0.742  0.287  1.0
  S  S7  1  0.117  0.258  0.713  1.0
  O  O8  1  0.447  0.174  0.099  1.0
  O  O9  1  0.947  0.826  0.401  1.0
  O  O10  1  0.256  0.394  0.139  1.0
  O  O11  1  0.744  0.606  0.861  1.0
  O  O12  1  0.503  0.306  0.318  1.0
  O  O13  1  0.497  0.694  0.682  1.0
  O  O14  1  0.003  0.694  0.182  1.0
  O  O15  1  0.553  0.826  0.901  1.0
  O  O16  1  0.053  0.174  0.599  1.0
  O  O17  1  0.756  0.606  0.361  1.0
  O  O18  1  0.244  0.394  0.639  1.0
  O  O19  1  0.997  0.306  0.818  1.0
  F  F20  1  0.786  0.919  0.134  1.0
  F  F21  1  0.286  0.081  0.366  1.0
  F  F22  1  0.714  0.919  0.634  1.0
  F  F23  1  0.214  0.081  0.866  1.0
[/CIF]
.