The crystal structure described by LiSiBiO4 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. Si(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Bi(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one Si(1), and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1), one Si(1), and two equivalent Bi(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Si(1), and two equivalent Bi(1) atoms. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to two equivalent Li(1), one Si(1), and one Bi(1) atom. is represented by the CIF card [CIF]
data_LiSiBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.408
_cell_length_b   5.853
_cell_length_c   11.400
_cell_angle_alpha   64.365
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   385.478
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.368  0.582  0.563  1.0
  Li  Li1  1  0.868  0.418  0.937  1.0
  Li  Li2  1  0.132  0.582  0.063  1.0
  Li  Li3  1  0.632  0.418  0.437  1.0
  Si  Si4  1  0.699  0.808  0.633  1.0
  Si  Si5  1  0.801  0.808  0.133  1.0
  Si  Si6  1  0.199  0.192  0.867  1.0
  Si  Si7  1  0.301  0.192  0.367  1.0
  Bi  Bi8  1  0.665  0.968  0.858  1.0
  Bi  Bi9  1  0.835  0.968  0.358  1.0
  Bi  Bi10  1  0.165  0.032  0.642  1.0
  Bi  Bi11  1  0.335  0.032  0.142  1.0
  O  O12  1  0.297  0.909  0.971  1.0
  O  O13  1  0.203  0.909  0.471  1.0
  O  O14  1  0.853  0.711  0.760  1.0
  O  O15  1  0.470  0.827  0.692  1.0
  O  O16  1  0.687  0.652  0.541  1.0
  O  O17  1  0.647  0.711  0.260  1.0
  O  O18  1  0.030  0.827  0.192  1.0
  O  O19  1  0.187  0.348  0.959  1.0
  O  O20  1  0.813  0.652  0.041  1.0
  O  O21  1  0.970  0.173  0.808  1.0
  O  O22  1  0.353  0.289  0.740  1.0
  O  O23  1  0.313  0.348  0.459  1.0
  O  O24  1  0.530  0.173  0.308  1.0
  O  O25  1  0.147  0.289  0.240  1.0
  O  O26  1  0.797  0.091  0.529  1.0
  O  O27  1  0.703  0.091  0.029  1.0
[/CIF]
.
The crystal structure described by LiSiBiO4 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. Si(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Bi(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one Si(1), and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1), one Si(1), and two equivalent Bi(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Si(1), and two equivalent Bi(1) atoms. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to two equivalent Li(1), one Si(1), and one Bi(1) atom. is represented by the CIF card [CIF]
data_LiSiBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.408
_cell_length_b   5.853
_cell_length_c   11.400
_cell_angle_alpha   64.365
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   385.478
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.368  0.582  0.563  1.0
  Li  Li1  1  0.868  0.418  0.937  1.0
  Li  Li2  1  0.132  0.582  0.063  1.0
  Li  Li3  1  0.632  0.418  0.437  1.0
  Si  Si4  1  0.699  0.808  0.633  1.0
  Si  Si5  1  0.801  0.808  0.133  1.0
  Si  Si6  1  0.199  0.192  0.867  1.0
  Si  Si7  1  0.301  0.192  0.367  1.0
  Bi  Bi8  1  0.665  0.968  0.858  1.0
  Bi  Bi9  1  0.835  0.968  0.358  1.0
  Bi  Bi10  1  0.165  0.032  0.642  1.0
  Bi  Bi11  1  0.335  0.032  0.142  1.0
  O  O12  1  0.297  0.909  0.971  1.0
  O  O13  1  0.203  0.909  0.471  1.0
  O  O14  1  0.853  0.711  0.760  1.0
  O  O15  1  0.470  0.827  0.692  1.0
  O  O16  1  0.687  0.652  0.541  1.0
  O  O17  1  0.647  0.711  0.260  1.0
  O  O18  1  0.030  0.827  0.192  1.0
  O  O19  1  0.187  0.348  0.959  1.0
  O  O20  1  0.813  0.652  0.041  1.0
  O  O21  1  0.970  0.173  0.808  1.0
  O  O22  1  0.353  0.289  0.740  1.0
  O  O23  1  0.313  0.348  0.459  1.0
  O  O24  1  0.530  0.173  0.308  1.0
  O  O25  1  0.147  0.289  0.240  1.0
  O  O26  1  0.797  0.091  0.529  1.0
  O  O27  1  0.703  0.091  0.029  1.0
[/CIF]
.