The material described by GdCPH3O6H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a GdCPH3O6 framework. In the GdCPH3O6 framework, Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(5), one O(6), one O(7), two equivalent O(3), and two equivalent O(4) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(6) atom. P(1) is bonded in a distorted tetrahedral geometry to one H(5), one O(3), one O(4), and one O(7) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one P(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one C(1) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the fourth O site, O(5) is bonded in a distorted water-like geometry to one Gd(1), one H(2), and one H(4) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one Gd(1) and one C(1) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GdPH5CO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.608
_cell_length_b   7.000
_cell_length_c   7.838
_cell_angle_alpha   111.671
_cell_angle_beta   96.282
_cell_angle_gamma   90.379
_symmetry_Int_Tables_number   1
_cell_volume   334.478
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.127  0.222  0.934  1.0
  Gd  Gd1  1  0.873  0.778  0.066  1.0
  P  P2  1  0.673  0.251  0.019  1.0
  P  P3  1  0.327  0.749  0.981  1.0
  H  H4  1  0.483  0.881  0.592  1.0
  H  H5  1  0.720  0.673  0.648  1.0
  H  H6  1  0.525  0.742  0.393  1.0
  H  H7  1  0.517  0.119  0.408  1.0
  H  H8  1  0.280  0.327  0.352  1.0
  H  H9  1  0.835  0.479  0.678  1.0
  H  H10  1  0.475  0.258  0.607  1.0
  H  H11  1  0.628  0.292  0.200  1.0
  H  H12  1  0.165  0.521  0.322  1.0
  H  H13  1  0.372  0.708  0.800  1.0
  C  C14  1  0.940  0.093  0.498  1.0
  C  C15  1  0.060  0.907  0.502  1.0
  O  O16  1  0.155  0.920  0.655  1.0
  O  O17  1  0.588  0.800  0.522  1.0
  O  O18  1  0.803  0.058  0.962  1.0
  O  O19  1  0.412  0.200  0.478  1.0
  O  O20  1  0.181  0.572  0.975  1.0
  O  O21  1  0.215  0.382  0.260  1.0
  O  O22  1  0.819  0.428  0.025  1.0
  O  O23  1  0.053  0.754  0.350  1.0
  O  O24  1  0.472  0.223  0.894  1.0
  O  O25  1  0.528  0.777  0.106  1.0
  O  O26  1  0.197  0.942  0.038  1.0
  O  O27  1  0.785  0.618  0.740  1.0
  O  O28  1  0.947  0.246  0.650  1.0
  O  O29  1  0.845  0.080  0.345  1.0
[/CIF]
.
The material described by GdCPH3O6H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a GdCPH3O6 framework. In the GdCPH3O6 framework, Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(5), one O(6), one O(7), two equivalent O(3), and two equivalent O(4) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(6) atom. P(1) is bonded in a distorted tetrahedral geometry to one H(5), one O(3), one O(4), and one O(7) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one P(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one C(1) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the fourth O site, O(5) is bonded in a distorted water-like geometry to one Gd(1), one H(2), and one H(4) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one Gd(1) and one C(1) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GdPH5CO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.608
_cell_length_b   7.000
_cell_length_c   7.838
_cell_angle_alpha   111.671
_cell_angle_beta   96.282
_cell_angle_gamma   90.379
_symmetry_Int_Tables_number   1
_cell_volume   334.478
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.127  0.222  0.934  1.0
  Gd  Gd1  1  0.873  0.778  0.066  1.0
  P  P2  1  0.673  0.251  0.019  1.0
  P  P3  1  0.327  0.749  0.981  1.0
  H  H4  1  0.483  0.881  0.592  1.0
  H  H5  1  0.720  0.673  0.648  1.0
  H  H6  1  0.525  0.742  0.393  1.0
  H  H7  1  0.517  0.119  0.408  1.0
  H  H8  1  0.280  0.327  0.352  1.0
  H  H9  1  0.835  0.479  0.678  1.0
  H  H10  1  0.475  0.258  0.607  1.0
  H  H11  1  0.628  0.292  0.200  1.0
  H  H12  1  0.165  0.521  0.322  1.0
  H  H13  1  0.372  0.708  0.800  1.0
  C  C14  1  0.940  0.093  0.498  1.0
  C  C15  1  0.060  0.907  0.502  1.0
  O  O16  1  0.155  0.920  0.655  1.0
  O  O17  1  0.588  0.800  0.522  1.0
  O  O18  1  0.803  0.058  0.962  1.0
  O  O19  1  0.412  0.200  0.478  1.0
  O  O20  1  0.181  0.572  0.975  1.0
  O  O21  1  0.215  0.382  0.260  1.0
  O  O22  1  0.819  0.428  0.025  1.0
  O  O23  1  0.053  0.754  0.350  1.0
  O  O24  1  0.472  0.223  0.894  1.0
  O  O25  1  0.528  0.777  0.106  1.0
  O  O26  1  0.197  0.942  0.038  1.0
  O  O27  1  0.785  0.618  0.740  1.0
  O  O28  1  0.947  0.246  0.650  1.0
  O  O29  1  0.845  0.080  0.345  1.0
[/CIF]
.