The crystal structure described by BH(PbO2)2 crystallizes in the monoclinic C2/m space group. B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 3-coordinate geometry to one O(3) and two equivalent O(4) atoms. In the second Pb site, Pb(2) is bonded in a distorted T-shaped geometry to one O(1) and two equivalent O(4) atoms. H(1) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one B(1), one Pb(2), and one H(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one B(1) and one H(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one B(1) and one Pb(1) atom. In the fourth O site, O(4) is bonded to two equivalent Pb(1) and two equivalent Pb(2) atoms to form edge-sharing OPb4 tetrahedra. is represented by the CIF card [CIF]
data_BH(PbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.211
_cell_length_b   7.211
_cell_length_c   7.631
_cell_angle_alpha   65.848
_cell_angle_beta   65.848
_cell_angle_gamma   47.870
_symmetry_Int_Tables_number   1
_cell_volume   263.150
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.330  0.330  0.662  1.0
  B  B1  1  0.670  0.670  0.338  1.0
  H  H2  1  0.454  0.454  0.391  1.0
  H  H3  1  0.546  0.546  0.609  1.0
  Pb  Pb4  1  0.059  0.059  0.739  1.0
  Pb  Pb5  1  0.941  0.941  0.261  1.0
  Pb  Pb6  1  0.652  0.652  0.937  1.0
  Pb  Pb7  1  0.348  0.348  0.063  1.0
  O  O8  1  0.410  0.410  0.732  1.0
  O  O9  1  0.590  0.590  0.268  1.0
  O  O10  1  0.368  0.368  0.457  1.0
  O  O11  1  0.632  0.632  0.543  1.0
  O  O12  1  0.216  0.216  0.787  1.0
  O  O13  1  0.784  0.784  0.213  1.0
  O  O14  1  0.747  0.253  0.000  1.0
  O  O15  1  0.253  0.747  0.000  1.0
[/CIF]
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The crystal structure described by BH(PbO2)2 crystallizes in the monoclinic C2/m space group. B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 3-coordinate geometry to one O(3) and two equivalent O(4) atoms. In the second Pb site, Pb(2) is bonded in a distorted T-shaped geometry to one O(1) and two equivalent O(4) atoms. H(1) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one B(1), one Pb(2), and one H(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one B(1) and one H(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one B(1) and one Pb(1) atom. In the fourth O site, O(4) is bonded to two equivalent Pb(1) and two equivalent Pb(2) atoms to form edge-sharing OPb4 tetrahedra. is represented by the CIF card [CIF]
data_BH(PbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.211
_cell_length_b   7.211
_cell_length_c   7.631
_cell_angle_alpha   65.848
_cell_angle_beta   65.848
_cell_angle_gamma   47.870
_symmetry_Int_Tables_number   1
_cell_volume   263.150
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.330  0.330  0.662  1.0
  B  B1  1  0.670  0.670  0.338  1.0
  H  H2  1  0.454  0.454  0.391  1.0
  H  H3  1  0.546  0.546  0.609  1.0
  Pb  Pb4  1  0.059  0.059  0.739  1.0
  Pb  Pb5  1  0.941  0.941  0.261  1.0
  Pb  Pb6  1  0.652  0.652  0.937  1.0
  Pb  Pb7  1  0.348  0.348  0.063  1.0
  O  O8  1  0.410  0.410  0.732  1.0
  O  O9  1  0.590  0.590  0.268  1.0
  O  O10  1  0.368  0.368  0.457  1.0
  O  O11  1  0.632  0.632  0.543  1.0
  O  O12  1  0.216  0.216  0.787  1.0
  O  O13  1  0.784  0.784  0.213  1.0
  O  O14  1  0.747  0.253  0.000  1.0
  O  O15  1  0.253  0.747  0.000  1.0
[/CIF]
.