The material structure described by SbSO2F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SbSO2F5 clusters. Sb(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one S(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbSO2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.743
_cell_length_b   5.956
_cell_length_c   10.778
_cell_angle_alpha   69.794
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   647.249
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.459  0.922  0.770  1.0
  Sb  Sb1  1  0.041  0.922  0.270  1.0
  Sb  Sb2  1  0.541  0.078  0.230  1.0
  Sb  Sb3  1  0.959  0.078  0.730  1.0
  S  S4  1  0.748  0.523  0.065  1.0
  S  S5  1  0.252  0.477  0.935  1.0
  S  S6  1  0.752  0.523  0.565  1.0
  S  S7  1  0.248  0.477  0.435  1.0
  O  O8  1  0.238  0.569  0.040  1.0
  O  O9  1  0.738  0.431  0.460  1.0
  O  O10  1  0.837  0.389  0.676  1.0
  O  O11  1  0.262  0.569  0.540  1.0
  O  O12  1  0.762  0.431  0.960  1.0
  O  O13  1  0.663  0.389  0.176  1.0
  O  O14  1  0.163  0.611  0.324  1.0
  O  O15  1  0.337  0.611  0.824  1.0
  F  F16  1  0.664  0.931  0.156  1.0
  F  F17  1  0.533  0.780  0.940  1.0
  F  F18  1  0.933  0.191  0.218  1.0
  F  F19  1  0.433  0.809  0.282  1.0
  F  F20  1  0.164  0.069  0.344  1.0
  F  F21  1  0.563  0.729  0.705  1.0
  F  F22  1  0.067  0.809  0.782  1.0
  F  F23  1  0.967  0.780  0.440  1.0
  F  F24  1  0.869  0.975  0.893  1.0
  F  F25  1  0.131  0.025  0.107  1.0
  F  F26  1  0.336  0.069  0.844  1.0
  F  F27  1  0.937  0.729  0.205  1.0
  F  F28  1  0.631  0.975  0.393  1.0
  F  F29  1  0.467  0.220  0.060  1.0
  F  F30  1  0.567  0.191  0.718  1.0
  F  F31  1  0.369  0.025  0.607  1.0
  F  F32  1  0.836  0.931  0.656  1.0
  F  F33  1  0.063  0.271  0.795  1.0
  F  F34  1  0.033  0.220  0.560  1.0
  F  F35  1  0.437  0.271  0.295  1.0
[/CIF]
.
The material structure described by SbSO2F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SbSO2F5 clusters. Sb(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one S(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbSO2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.743
_cell_length_b   5.956
_cell_length_c   10.778
_cell_angle_alpha   69.794
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   647.249
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.459  0.922  0.770  1.0
  Sb  Sb1  1  0.041  0.922  0.270  1.0
  Sb  Sb2  1  0.541  0.078  0.230  1.0
  Sb  Sb3  1  0.959  0.078  0.730  1.0
  S  S4  1  0.748  0.523  0.065  1.0
  S  S5  1  0.252  0.477  0.935  1.0
  S  S6  1  0.752  0.523  0.565  1.0
  S  S7  1  0.248  0.477  0.435  1.0
  O  O8  1  0.238  0.569  0.040  1.0
  O  O9  1  0.738  0.431  0.460  1.0
  O  O10  1  0.837  0.389  0.676  1.0
  O  O11  1  0.262  0.569  0.540  1.0
  O  O12  1  0.762  0.431  0.960  1.0
  O  O13  1  0.663  0.389  0.176  1.0
  O  O14  1  0.163  0.611  0.324  1.0
  O  O15  1  0.337  0.611  0.824  1.0
  F  F16  1  0.664  0.931  0.156  1.0
  F  F17  1  0.533  0.780  0.940  1.0
  F  F18  1  0.933  0.191  0.218  1.0
  F  F19  1  0.433  0.809  0.282  1.0
  F  F20  1  0.164  0.069  0.344  1.0
  F  F21  1  0.563  0.729  0.705  1.0
  F  F22  1  0.067  0.809  0.782  1.0
  F  F23  1  0.967  0.780  0.440  1.0
  F  F24  1  0.869  0.975  0.893  1.0
  F  F25  1  0.131  0.025  0.107  1.0
  F  F26  1  0.336  0.069  0.844  1.0
  F  F27  1  0.937  0.729  0.205  1.0
  F  F28  1  0.631  0.975  0.393  1.0
  F  F29  1  0.467  0.220  0.060  1.0
  F  F30  1  0.567  0.191  0.718  1.0
  F  F31  1  0.369  0.025  0.607  1.0
  F  F32  1  0.836  0.931  0.656  1.0
  F  F33  1  0.063  0.271  0.795  1.0
  F  F34  1  0.033  0.220  0.560  1.0
  F  F35  1  0.437  0.271  0.295  1.0
[/CIF]
.