The material described by AgIn(WO4)2 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Ag(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. Ag(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form distorted AgO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-56°. In(1) is bonded to two equivalent O(1) and four equivalent O(4) atoms to form distorted InO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one In(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent W(1) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent In(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_InAg(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.838
_cell_length_b   5.060
_cell_length_c   10.257
_cell_angle_alpha   89.166
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   302.949
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.315  0.250  0.500  1.0
  In  In1  1  0.685  0.750  0.500  1.0
  Ag  Ag2  1  0.316  0.250  0.000  1.0
  Ag  Ag3  1  0.684  0.750  0.000  1.0
  W  W4  1  0.177  0.744  0.259  1.0
  W  W5  1  0.177  0.756  0.741  1.0
  W  W6  1  0.823  0.256  0.741  1.0
  W  W7  1  0.823  0.244  0.259  1.0
  O  O8  1  0.896  0.951  0.631  1.0
  O  O9  1  0.369  0.879  0.146  1.0
  O  O10  1  0.104  0.049  0.369  1.0
  O  O11  1  0.096  0.065  0.830  1.0
  O  O12  1  0.623  0.396  0.615  1.0
  O  O13  1  0.904  0.935  0.170  1.0
  O  O14  1  0.096  0.435  0.170  1.0
  O  O15  1  0.904  0.565  0.830  1.0
  O  O16  1  0.896  0.549  0.369  1.0
  O  O17  1  0.104  0.451  0.631  1.0
  O  O18  1  0.631  0.379  0.146  1.0
  O  O19  1  0.377  0.896  0.615  1.0
  O  O20  1  0.377  0.604  0.385  1.0
  O  O21  1  0.623  0.104  0.385  1.0
  O  O22  1  0.631  0.121  0.854  1.0
  O  O23  1  0.369  0.621  0.854  1.0
[/CIF]
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The material described by AgIn(WO4)2 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Ag(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. Ag(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form distorted AgO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-56°. In(1) is bonded to two equivalent O(1) and four equivalent O(4) atoms to form distorted InO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one In(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent W(1) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent In(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_InAg(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.838
_cell_length_b   5.060
_cell_length_c   10.257
_cell_angle_alpha   89.166
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   302.949
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.315  0.250  0.500  1.0
  In  In1  1  0.685  0.750  0.500  1.0
  Ag  Ag2  1  0.316  0.250  0.000  1.0
  Ag  Ag3  1  0.684  0.750  0.000  1.0
  W  W4  1  0.177  0.744  0.259  1.0
  W  W5  1  0.177  0.756  0.741  1.0
  W  W6  1  0.823  0.256  0.741  1.0
  W  W7  1  0.823  0.244  0.259  1.0
  O  O8  1  0.896  0.951  0.631  1.0
  O  O9  1  0.369  0.879  0.146  1.0
  O  O10  1  0.104  0.049  0.369  1.0
  O  O11  1  0.096  0.065  0.830  1.0
  O  O12  1  0.623  0.396  0.615  1.0
  O  O13  1  0.904  0.935  0.170  1.0
  O  O14  1  0.096  0.435  0.170  1.0
  O  O15  1  0.904  0.565  0.830  1.0
  O  O16  1  0.896  0.549  0.369  1.0
  O  O17  1  0.104  0.451  0.631  1.0
  O  O18  1  0.631  0.379  0.146  1.0
  O  O19  1  0.377  0.896  0.615  1.0
  O  O20  1  0.377  0.604  0.385  1.0
  O  O21  1  0.623  0.104  0.385  1.0
  O  O22  1  0.631  0.121  0.854  1.0
  O  O23  1  0.369  0.621  0.854  1.0
[/CIF]
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