The crystal structure described by Ti3P crystallizes in the tetragonal P4_2/n space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a distorted see-saw-like geometry to four equivalent P(1) atoms. In the second Ti site, Ti(2) is bonded in a 3-coordinate geometry to three equivalent P(1) atoms. In the third Ti site, Ti(3) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to two equivalent Ti(3), three equivalent Ti(2), and four equivalent Ti(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti3P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.975
_cell_length_b   9.939
_cell_length_c   9.939
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.435
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.532  0.110  0.222  1.0
  Ti  Ti1  1  0.032  0.778  0.610  1.0
  Ti  Ti2  1  0.032  0.722  0.890  1.0
  Ti  Ti3  1  0.532  0.390  0.278  1.0
  Ti  Ti4  1  0.468  0.890  0.778  1.0
  Ti  Ti5  1  0.968  0.222  0.390  1.0
  Ti  Ti6  1  0.968  0.278  0.110  1.0
  Ti  Ti7  1  0.468  0.610  0.722  1.0
  Ti  Ti8  1  0.260  0.534  0.069  1.0
  Ti  Ti9  1  0.760  0.931  0.034  1.0
  Ti  Ti10  1  0.760  0.569  0.466  1.0
  Ti  Ti11  1  0.260  0.966  0.431  1.0
  Ti  Ti12  1  0.740  0.466  0.931  1.0
  Ti  Ti13  1  0.240  0.069  0.966  1.0
  Ti  Ti14  1  0.240  0.431  0.534  1.0
  Ti  Ti15  1  0.740  0.034  0.569  1.0
  Ti  Ti16  1  0.785  0.643  0.167  1.0
  Ti  Ti17  1  0.285  0.833  0.143  1.0
  Ti  Ti18  1  0.285  0.667  0.357  1.0
  Ti  Ti19  1  0.785  0.857  0.333  1.0
  Ti  Ti20  1  0.215  0.357  0.833  1.0
  Ti  Ti21  1  0.715  0.167  0.857  1.0
  Ti  Ti22  1  0.715  0.333  0.643  1.0
  Ti  Ti23  1  0.215  0.143  0.667  1.0
  P  P24  1  0.964  0.543  0.709  1.0
  P  P25  1  0.464  0.291  0.043  1.0
  P  P26  1  0.464  0.209  0.457  1.0
  P  P27  1  0.964  0.957  0.791  1.0
  P  P28  1  0.036  0.457  0.291  1.0
  P  P29  1  0.536  0.709  0.957  1.0
  P  P30  1  0.536  0.791  0.543  1.0
  P  P31  1  0.036  0.043  0.209  1.0
[/CIF]
.
The crystal structure described by Ti3P crystallizes in the tetragonal P4_2/n space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a distorted see-saw-like geometry to four equivalent P(1) atoms. In the second Ti site, Ti(2) is bonded in a 3-coordinate geometry to three equivalent P(1) atoms. In the third Ti site, Ti(3) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to two equivalent Ti(3), three equivalent Ti(2), and four equivalent Ti(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti3P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.975
_cell_length_b   9.939
_cell_length_c   9.939
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.435
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.532  0.110  0.222  1.0
  Ti  Ti1  1  0.032  0.778  0.610  1.0
  Ti  Ti2  1  0.032  0.722  0.890  1.0
  Ti  Ti3  1  0.532  0.390  0.278  1.0
  Ti  Ti4  1  0.468  0.890  0.778  1.0
  Ti  Ti5  1  0.968  0.222  0.390  1.0
  Ti  Ti6  1  0.968  0.278  0.110  1.0
  Ti  Ti7  1  0.468  0.610  0.722  1.0
  Ti  Ti8  1  0.260  0.534  0.069  1.0
  Ti  Ti9  1  0.760  0.931  0.034  1.0
  Ti  Ti10  1  0.760  0.569  0.466  1.0
  Ti  Ti11  1  0.260  0.966  0.431  1.0
  Ti  Ti12  1  0.740  0.466  0.931  1.0
  Ti  Ti13  1  0.240  0.069  0.966  1.0
  Ti  Ti14  1  0.240  0.431  0.534  1.0
  Ti  Ti15  1  0.740  0.034  0.569  1.0
  Ti  Ti16  1  0.785  0.643  0.167  1.0
  Ti  Ti17  1  0.285  0.833  0.143  1.0
  Ti  Ti18  1  0.285  0.667  0.357  1.0
  Ti  Ti19  1  0.785  0.857  0.333  1.0
  Ti  Ti20  1  0.215  0.357  0.833  1.0
  Ti  Ti21  1  0.715  0.167  0.857  1.0
  Ti  Ti22  1  0.715  0.333  0.643  1.0
  Ti  Ti23  1  0.215  0.143  0.667  1.0
  P  P24  1  0.964  0.543  0.709  1.0
  P  P25  1  0.464  0.291  0.043  1.0
  P  P26  1  0.464  0.209  0.457  1.0
  P  P27  1  0.964  0.957  0.791  1.0
  P  P28  1  0.036  0.457  0.291  1.0
  P  P29  1  0.536  0.709  0.957  1.0
  P  P30  1  0.536  0.791  0.543  1.0
  P  P31  1  0.036  0.043  0.209  1.0
[/CIF]
.