The crystal structure described by Mn3SnO8 is beta Vanadium nitride-derived structured and crystallizes in the hexagonal P6_3mc space group. Mn(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form MnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. Sn(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SnO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one Sn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Mn(1) and one Sn(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to three equivalent Mn(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3SnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.826
_cell_length_b   5.826
_cell_length_c   9.431
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   277.256
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.168  0.832  0.213  1.0
  Mn  Mn1  1  0.168  0.335  0.213  1.0
  Mn  Mn2  1  0.665  0.832  0.213  1.0
  Mn  Mn3  1  0.335  0.168  0.713  1.0
  Mn  Mn4  1  0.832  0.665  0.713  1.0
  Mn  Mn5  1  0.832  0.168  0.713  1.0
  Sn  Sn6  1  0.333  0.667  0.493  1.0
  Sn  Sn7  1  0.667  0.333  0.993  1.0
  O  O8  1  0.159  0.841  0.604  1.0
  O  O9  1  0.034  0.517  0.330  1.0
  O  O10  1  0.333  0.667  0.109  1.0
  O  O11  1  0.000  0.000  0.314  1.0
  O  O12  1  0.000  0.000  0.814  1.0
  O  O13  1  0.159  0.317  0.604  1.0
  O  O14  1  0.483  0.966  0.330  1.0
  O  O15  1  0.483  0.517  0.330  1.0
  O  O16  1  0.317  0.159  0.104  1.0
  O  O17  1  0.683  0.841  0.604  1.0
  O  O18  1  0.517  0.483  0.830  1.0
  O  O19  1  0.517  0.034  0.830  1.0
  O  O20  1  0.667  0.333  0.609  1.0
  O  O21  1  0.841  0.683  0.104  1.0
  O  O22  1  0.966  0.483  0.830  1.0
  O  O23  1  0.841  0.159  0.104  1.0
[/CIF]
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The crystal structure described by Mn3SnO8 is beta Vanadium nitride-derived structured and crystallizes in the hexagonal P6_3mc space group. Mn(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form MnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. Sn(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SnO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one Sn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Mn(1) and one Sn(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to three equivalent Mn(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3SnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.826
_cell_length_b   5.826
_cell_length_c   9.431
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   277.256
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.168  0.832  0.213  1.0
  Mn  Mn1  1  0.168  0.335  0.213  1.0
  Mn  Mn2  1  0.665  0.832  0.213  1.0
  Mn  Mn3  1  0.335  0.168  0.713  1.0
  Mn  Mn4  1  0.832  0.665  0.713  1.0
  Mn  Mn5  1  0.832  0.168  0.713  1.0
  Sn  Sn6  1  0.333  0.667  0.493  1.0
  Sn  Sn7  1  0.667  0.333  0.993  1.0
  O  O8  1  0.159  0.841  0.604  1.0
  O  O9  1  0.034  0.517  0.330  1.0
  O  O10  1  0.333  0.667  0.109  1.0
  O  O11  1  0.000  0.000  0.314  1.0
  O  O12  1  0.000  0.000  0.814  1.0
  O  O13  1  0.159  0.317  0.604  1.0
  O  O14  1  0.483  0.966  0.330  1.0
  O  O15  1  0.483  0.517  0.330  1.0
  O  O16  1  0.317  0.159  0.104  1.0
  O  O17  1  0.683  0.841  0.604  1.0
  O  O18  1  0.517  0.483  0.830  1.0
  O  O19  1  0.517  0.034  0.830  1.0
  O  O20  1  0.667  0.333  0.609  1.0
  O  O21  1  0.841  0.683  0.104  1.0
  O  O22  1  0.966  0.483  0.830  1.0
  O  O23  1  0.841  0.159  0.104  1.0
[/CIF]
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