The structure described by AsOCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AsOCl3 clusters. As(1) is bonded to two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing AsCl3O2 trigonal bipyramids. O(1) is bonded in a water-like geometry to two equivalent As(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one As(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one As(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsCl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.358
_cell_length_b   8.270
_cell_length_c   10.388
_cell_angle_alpha   113.034
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   502.697
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.555  0.342  0.008  1.0
  As  As1  1  0.055  0.658  0.492  1.0
  As  As2  1  0.445  0.658  0.992  1.0
  As  As3  1  0.945  0.342  0.508  1.0
  Cl  Cl4  1  0.037  0.345  0.706  1.0
  Cl  Cl5  1  0.537  0.655  0.794  1.0
  Cl  Cl6  1  0.963  0.655  0.294  1.0
  Cl  Cl7  1  0.463  0.345  0.206  1.0
  Cl  Cl8  1  0.074  0.126  0.335  1.0
  Cl  Cl9  1  0.574  0.874  0.165  1.0
  Cl  Cl10  1  0.926  0.874  0.665  1.0
  Cl  Cl11  1  0.426  0.126  0.835  1.0
  Cl  Cl12  1  0.643  0.209  0.502  1.0
  Cl  Cl13  1  0.143  0.791  0.998  1.0
  Cl  Cl14  1  0.357  0.791  0.498  1.0
  Cl  Cl15  1  0.857  0.209  0.002  1.0
  O  O16  1  0.684  0.520  0.993  1.0
  O  O17  1  0.184  0.480  0.507  1.0
  O  O18  1  0.316  0.480  0.007  1.0
  O  O19  1  0.816  0.520  0.493  1.0
[/CIF]
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The structure described by AsOCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AsOCl3 clusters. As(1) is bonded to two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing AsCl3O2 trigonal bipyramids. O(1) is bonded in a water-like geometry to two equivalent As(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one As(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one As(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsCl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.358
_cell_length_b   8.270
_cell_length_c   10.388
_cell_angle_alpha   113.034
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   502.697
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.555  0.342  0.008  1.0
  As  As1  1  0.055  0.658  0.492  1.0
  As  As2  1  0.445  0.658  0.992  1.0
  As  As3  1  0.945  0.342  0.508  1.0
  Cl  Cl4  1  0.037  0.345  0.706  1.0
  Cl  Cl5  1  0.537  0.655  0.794  1.0
  Cl  Cl6  1  0.963  0.655  0.294  1.0
  Cl  Cl7  1  0.463  0.345  0.206  1.0
  Cl  Cl8  1  0.074  0.126  0.335  1.0
  Cl  Cl9  1  0.574  0.874  0.165  1.0
  Cl  Cl10  1  0.926  0.874  0.665  1.0
  Cl  Cl11  1  0.426  0.126  0.835  1.0
  Cl  Cl12  1  0.643  0.209  0.502  1.0
  Cl  Cl13  1  0.143  0.791  0.998  1.0
  Cl  Cl14  1  0.357  0.791  0.498  1.0
  Cl  Cl15  1  0.857  0.209  0.002  1.0
  O  O16  1  0.684  0.520  0.993  1.0
  O  O17  1  0.184  0.480  0.507  1.0
  O  O18  1  0.316  0.480  0.007  1.0
  O  O19  1  0.816  0.520  0.493  1.0
[/CIF]
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