The compound described by NaCuN crystallizes in the orthorhombic Amm2 space group. Na(1) is bonded to six equivalent Cu(1) and six equivalent N(1) atoms to form a mixture of distorted face and edge-sharing NaCu6N6 cuboctahedra. Cu(1) is bonded in a trigonal planar geometry to six equivalent Na(1) and three equivalent N(1) atoms. N(1) is bonded in a distorted trigonal planar geometry to six equivalent Na(1) and three equivalent Cu(1) atoms. is represented by the CIF file [CIF]
data_NaCuN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.353
_cell_length_b   3.276
_cell_length_c   4.230
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.781
_symmetry_Int_Tables_number   1
_cell_volume   39.926
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.455  0.910  0.000  1.0
  Cu  Cu1  1  0.108  0.216  0.500  1.0
  N  N2  1  0.770  0.541  0.500  1.0
[/CIF]
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The compound described by NaCuN crystallizes in the orthorhombic Amm2 space group. Na(1) is bonded to six equivalent Cu(1) and six equivalent N(1) atoms to form a mixture of distorted face and edge-sharing NaCu6N6 cuboctahedra. Cu(1) is bonded in a trigonal planar geometry to six equivalent Na(1) and three equivalent N(1) atoms. N(1) is bonded in a distorted trigonal planar geometry to six equivalent Na(1) and three equivalent Cu(1) atoms. is represented by the CIF file [CIF]
data_NaCuN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.353
_cell_length_b   3.276
_cell_length_c   4.230
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.781
_symmetry_Int_Tables_number   1
_cell_volume   39.926
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.455  0.910  0.000  1.0
  Cu  Cu1  1  0.108  0.216  0.500  1.0
  N  N2  1  0.770  0.541  0.500  1.0
[/CIF]
.