The structure described by LaMn2CdO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. In the second Mn site, Mn(2) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 21-30°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 18-29°. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 3-coordinate geometry to one O(2), one O(4), and one O(6) atom. In the second Cd site, Cd(2) is bonded in a 3-coordinate geometry to one O(1), one O(3), one O(5), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(1), one Mn(4), and one Cd(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(2), one Mn(3), and one Cd(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(1), one Mn(4), and one Cd(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(2), one Mn(3), and one Cd(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(1), one Mn(4), and one Cd(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(2), one Mn(3), and one Cd(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(2), one Mn(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one La(1), one Mn(3), and one Mn(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one La(2), one Mn(1), one Mn(2), and one Cd(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(1), one Mn(3), and one Mn(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(2), one Mn(1), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(1), one Mn(3), and one Mn(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaMn2CdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.563
_cell_length_b   9.491
_cell_length_c   5.468
_cell_angle_alpha   72.021
_cell_angle_beta   59.736
_cell_angle_gamma   73.077
_symmetry_Int_Tables_number   1
_cell_volume   233.905
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.135  0.625  0.123  1.0
  La  La1  1  0.612  0.124  0.626  1.0
  Mn  Mn2  1  0.245  0.249  0.252  1.0
  Mn  Mn3  1  0.984  0.001  0.005  1.0
  Mn  Mn4  1  0.754  0.749  0.747  1.0
  Mn  Mn5  1  0.515  0.501  0.493  1.0
  Cd  Cd6  1  0.368  0.875  0.374  1.0
  Cd  Cd7  1  0.886  0.374  0.874  1.0
  O  O8  1  0.891  0.378  0.455  1.0
  O  O9  1  0.334  0.877  0.975  1.0
  O  O10  1  0.303  0.376  0.871  1.0
  O  O11  1  0.778  0.876  0.376  1.0
  O  O12  1  0.485  0.378  0.298  1.0
  O  O13  1  0.946  0.879  0.784  1.0
  O  O14  1  0.185  0.121  0.626  1.0
  O  O15  1  0.701  0.631  0.132  1.0
  O  O16  1  0.035  0.128  0.176  1.0
  O  O17  1  0.575  0.617  0.700  1.0
  O  O18  1  0.610  0.119  0.062  1.0
  O  O19  1  0.158  0.622  0.552  1.0
[/CIF]
.
The structure described by LaMn2CdO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. In the second Mn site, Mn(2) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 21-30°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 18-29°. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 3-coordinate geometry to one O(2), one O(4), and one O(6) atom. In the second Cd site, Cd(2) is bonded in a 3-coordinate geometry to one O(1), one O(3), one O(5), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(1), one Mn(4), and one Cd(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(2), one Mn(3), and one Cd(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(1), one Mn(4), and one Cd(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(2), one Mn(3), and one Cd(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(1), one Mn(4), and one Cd(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mn(2), one Mn(3), and one Cd(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(2), one Mn(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one La(1), one Mn(3), and one Mn(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one La(2), one Mn(1), one Mn(2), and one Cd(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(1), one Mn(3), and one Mn(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(2), one Mn(1), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(1), one Mn(3), and one Mn(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaMn2CdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.563
_cell_length_b   9.491
_cell_length_c   5.468
_cell_angle_alpha   72.021
_cell_angle_beta   59.736
_cell_angle_gamma   73.077
_symmetry_Int_Tables_number   1
_cell_volume   233.905
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.135  0.625  0.123  1.0
  La  La1  1  0.612  0.124  0.626  1.0
  Mn  Mn2  1  0.245  0.249  0.252  1.0
  Mn  Mn3  1  0.984  0.001  0.005  1.0
  Mn  Mn4  1  0.754  0.749  0.747  1.0
  Mn  Mn5  1  0.515  0.501  0.493  1.0
  Cd  Cd6  1  0.368  0.875  0.374  1.0
  Cd  Cd7  1  0.886  0.374  0.874  1.0
  O  O8  1  0.891  0.378  0.455  1.0
  O  O9  1  0.334  0.877  0.975  1.0
  O  O10  1  0.303  0.376  0.871  1.0
  O  O11  1  0.778  0.876  0.376  1.0
  O  O12  1  0.485  0.378  0.298  1.0
  O  O13  1  0.946  0.879  0.784  1.0
  O  O14  1  0.185  0.121  0.626  1.0
  O  O15  1  0.701  0.631  0.132  1.0
  O  O16  1  0.035  0.128  0.176  1.0
  O  O17  1  0.575  0.617  0.700  1.0
  O  O18  1  0.610  0.119  0.062  1.0
  O  O19  1  0.158  0.622  0.552  1.0
[/CIF]
.