The material described by C4TeS4(N2F)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C4TeS4(N2F)4 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(1) and one F(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(2) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one C(1), one Te(1), and one F(2) atom. In the second S site, S(2) is bonded in a distorted water-like geometry to one N(3) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_TeC4S4(N2F)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.494
_cell_length_b   6.494
_cell_length_c   22.401
_cell_angle_alpha   81.292
_cell_angle_beta   81.292
_cell_angle_gamma   81.880
_symmetry_Int_Tables_number   1
_cell_volume   916.264
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.500  0.000  0.500  1.0
  Te  Te1  1  0.000  0.500  0.000  1.0
  C  C2  1  0.556  0.651  0.641  1.0
  C  C3  1  0.349  0.444  0.859  1.0
  C  C4  1  0.444  0.349  0.359  1.0
  C  C5  1  0.651  0.556  0.141  1.0
  C  C6  1  0.945  0.825  0.379  1.0
  C  C7  1  0.175  0.055  0.121  1.0
  C  C8  1  0.055  0.175  0.621  1.0
  C  C9  1  0.825  0.945  0.879  1.0
  S  S10  1  0.689  0.881  0.605  1.0
  S  S11  1  0.119  0.311  0.895  1.0
  S  S12  1  0.311  0.119  0.395  1.0
  S  S13  1  0.881  0.689  0.105  1.0
  S  S14  1  0.768  0.680  0.481  1.0
  S  S15  1  0.320  0.232  0.019  1.0
  S  S16  1  0.232  0.320  0.519  1.0
  S  S17  1  0.680  0.768  0.981  1.0
  N  N18  1  0.638  0.512  0.686  1.0
  N  N19  1  0.488  0.362  0.814  1.0
  N  N20  1  0.362  0.488  0.314  1.0
  N  N21  1  0.512  0.638  0.186  1.0
  N  N22  1  0.384  0.635  0.621  1.0
  N  N23  1  0.365  0.616  0.879  1.0
  N  N24  1  0.616  0.365  0.379  1.0
  N  N25  1  0.635  0.384  0.121  1.0
  N  N26  1  0.973  0.758  0.437  1.0
  N  N27  1  0.242  0.027  0.063  1.0
  N  N28  1  0.027  0.242  0.563  1.0
  N  N29  1  0.758  0.973  0.937  1.0
  N  N30  1  0.925  0.902  0.329  1.0
  N  N31  1  0.098  0.075  0.171  1.0
  N  N32  1  0.075  0.098  0.671  1.0
  N  N33  1  0.902  0.925  0.829  1.0
  F  F34  1  0.422  0.179  0.802  1.0
  F  F35  1  0.821  0.578  0.698  1.0
  F  F36  1  0.578  0.821  0.198  1.0
  F  F37  1  0.179  0.422  0.302  1.0
  F  F38  1  0.613  0.024  0.660  1.0
  F  F39  1  0.976  0.387  0.840  1.0
  F  F40  1  0.387  0.976  0.340  1.0
  F  F41  1  0.024  0.613  0.160  1.0
[/CIF]
.
The material described by C4TeS4(N2F)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C4TeS4(N2F)4 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(1) and one F(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(2) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one C(1), one Te(1), and one F(2) atom. In the second S site, S(2) is bonded in a distorted water-like geometry to one N(3) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_TeC4S4(N2F)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.494
_cell_length_b   6.494
_cell_length_c   22.401
_cell_angle_alpha   81.292
_cell_angle_beta   81.292
_cell_angle_gamma   81.880
_symmetry_Int_Tables_number   1
_cell_volume   916.264
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.500  0.000  0.500  1.0
  Te  Te1  1  0.000  0.500  0.000  1.0
  C  C2  1  0.556  0.651  0.641  1.0
  C  C3  1  0.349  0.444  0.859  1.0
  C  C4  1  0.444  0.349  0.359  1.0
  C  C5  1  0.651  0.556  0.141  1.0
  C  C6  1  0.945  0.825  0.379  1.0
  C  C7  1  0.175  0.055  0.121  1.0
  C  C8  1  0.055  0.175  0.621  1.0
  C  C9  1  0.825  0.945  0.879  1.0
  S  S10  1  0.689  0.881  0.605  1.0
  S  S11  1  0.119  0.311  0.895  1.0
  S  S12  1  0.311  0.119  0.395  1.0
  S  S13  1  0.881  0.689  0.105  1.0
  S  S14  1  0.768  0.680  0.481  1.0
  S  S15  1  0.320  0.232  0.019  1.0
  S  S16  1  0.232  0.320  0.519  1.0
  S  S17  1  0.680  0.768  0.981  1.0
  N  N18  1  0.638  0.512  0.686  1.0
  N  N19  1  0.488  0.362  0.814  1.0
  N  N20  1  0.362  0.488  0.314  1.0
  N  N21  1  0.512  0.638  0.186  1.0
  N  N22  1  0.384  0.635  0.621  1.0
  N  N23  1  0.365  0.616  0.879  1.0
  N  N24  1  0.616  0.365  0.379  1.0
  N  N25  1  0.635  0.384  0.121  1.0
  N  N26  1  0.973  0.758  0.437  1.0
  N  N27  1  0.242  0.027  0.063  1.0
  N  N28  1  0.027  0.242  0.563  1.0
  N  N29  1  0.758  0.973  0.937  1.0
  N  N30  1  0.925  0.902  0.329  1.0
  N  N31  1  0.098  0.075  0.171  1.0
  N  N32  1  0.075  0.098  0.671  1.0
  N  N33  1  0.902  0.925  0.829  1.0
  F  F34  1  0.422  0.179  0.802  1.0
  F  F35  1  0.821  0.578  0.698  1.0
  F  F36  1  0.578  0.821  0.198  1.0
  F  F37  1  0.179  0.422  0.302  1.0
  F  F38  1  0.613  0.024  0.660  1.0
  F  F39  1  0.976  0.387  0.840  1.0
  F  F40  1  0.387  0.976  0.340  1.0
  F  F41  1  0.024  0.613  0.160  1.0
[/CIF]
.