The compound described by CPH3S3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CPH3S3 clusters. C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(2) atom. P(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form edge-sharing PS4 tetrahedra. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to two equivalent P(1) atoms. is represented by the CIF file [CIF]
data_PH3CS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.440
_cell_length_b   8.604
_cell_length_c   8.907
_cell_angle_alpha   69.334
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   605.180
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.579  0.058  0.343  1.0
  P  P1  1  0.921  0.558  0.343  1.0
  P  P2  1  0.421  0.942  0.657  1.0
  P  P3  1  0.079  0.442  0.657  1.0
  H  H4  1  0.289  0.683  0.285  1.0
  H  H5  1  0.212  0.976  0.281  1.0
  H  H6  1  0.789  0.817  0.715  1.0
  H  H7  1  0.211  0.183  0.285  1.0
  H  H8  1  0.662  0.352  0.897  1.0
  H  H9  1  0.838  0.852  0.897  1.0
  H  H10  1  0.338  0.648  0.103  1.0
  H  H11  1  0.288  0.476  0.281  1.0
  H  H12  1  0.788  0.024  0.719  1.0
  H  H13  1  0.711  0.317  0.715  1.0
  H  H14  1  0.162  0.148  0.103  1.0
  H  H15  1  0.712  0.524  0.719  1.0
  C  C16  1  0.264  0.607  0.212  1.0
  C  C17  1  0.764  0.893  0.788  1.0
  C  C18  1  0.736  0.393  0.788  1.0
  C  C19  1  0.236  0.107  0.212  1.0
  S  S20  1  0.702  0.581  0.276  1.0
  S  S21  1  0.798  0.081  0.276  1.0
  S  S22  1  0.438  0.135  0.138  1.0
  S  S23  1  0.938  0.365  0.862  1.0
  S  S24  1  0.202  0.919  0.724  1.0
  S  S25  1  0.501  0.181  0.501  1.0
  S  S26  1  0.562  0.865  0.862  1.0
  S  S27  1  0.999  0.681  0.501  1.0
  S  S28  1  0.499  0.819  0.499  1.0
  S  S29  1  0.001  0.319  0.499  1.0
  S  S30  1  0.062  0.635  0.138  1.0
  S  S31  1  0.298  0.419  0.724  1.0
[/CIF]
.
The compound described by CPH3S3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CPH3S3 clusters. C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(2) atom. P(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form edge-sharing PS4 tetrahedra. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to two equivalent P(1) atoms. is represented by the CIF file [CIF]
data_PH3CS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.440
_cell_length_b   8.604
_cell_length_c   8.907
_cell_angle_alpha   69.334
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   605.180
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.579  0.058  0.343  1.0
  P  P1  1  0.921  0.558  0.343  1.0
  P  P2  1  0.421  0.942  0.657  1.0
  P  P3  1  0.079  0.442  0.657  1.0
  H  H4  1  0.289  0.683  0.285  1.0
  H  H5  1  0.212  0.976  0.281  1.0
  H  H6  1  0.789  0.817  0.715  1.0
  H  H7  1  0.211  0.183  0.285  1.0
  H  H8  1  0.662  0.352  0.897  1.0
  H  H9  1  0.838  0.852  0.897  1.0
  H  H10  1  0.338  0.648  0.103  1.0
  H  H11  1  0.288  0.476  0.281  1.0
  H  H12  1  0.788  0.024  0.719  1.0
  H  H13  1  0.711  0.317  0.715  1.0
  H  H14  1  0.162  0.148  0.103  1.0
  H  H15  1  0.712  0.524  0.719  1.0
  C  C16  1  0.264  0.607  0.212  1.0
  C  C17  1  0.764  0.893  0.788  1.0
  C  C18  1  0.736  0.393  0.788  1.0
  C  C19  1  0.236  0.107  0.212  1.0
  S  S20  1  0.702  0.581  0.276  1.0
  S  S21  1  0.798  0.081  0.276  1.0
  S  S22  1  0.438  0.135  0.138  1.0
  S  S23  1  0.938  0.365  0.862  1.0
  S  S24  1  0.202  0.919  0.724  1.0
  S  S25  1  0.501  0.181  0.501  1.0
  S  S26  1  0.562  0.865  0.862  1.0
  S  S27  1  0.999  0.681  0.501  1.0
  S  S28  1  0.499  0.819  0.499  1.0
  S  S29  1  0.001  0.319  0.499  1.0
  S  S30  1  0.062  0.635  0.138  1.0
  S  S31  1  0.298  0.419  0.724  1.0
[/CIF]
.