The material structure described by Tb2Cu2O5 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of distorted corner and edge-sharing TbO6 octahedra. The corner-sharing octahedral tilt angles range from 23-65°. In the second Tb site, Tb(2) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form a mixture of distorted corner and edge-sharing TbO6 octahedra. The corner-sharing octahedral tilt angles range from 23-65°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded to two equivalent Tb(2), one Cu(1), and one Cu(2) atom to form distorted OTb2Cu2 trigonal pyramids that share corners with three equivalent O(1)Tb3Cu tetrahedra, corners with three equivalent O(3)Tb3Cu tetrahedra, corners with two equivalent O(5)Tb2Cu2 trigonal pyramids,  an edgeedge with one O(3)Tb3Cu tetrahedra, and  an edgeedge with one O(2)Tb2Cu2 trigonal pyramid. In the second O site, O(1) is bonded to one Tb(2), two equivalent Tb(1), and one Cu(1) atom to form OTb3Cu tetrahedra that share corners with two equivalent O(1)Tb3Cu tetrahedra, corners with four equivalent O(3)Tb3Cu tetrahedra, corners with three equivalent O(2)Tb2Cu2 trigonal pyramids, corners with three equivalent O(5)Tb2Cu2 trigonal pyramids, and  an edgeedge with one O(2)Tb2Cu2 trigonal pyramid. In the third O site, O(2) is bonded to two equivalent Tb(1), one Cu(1), and one Cu(2) atom to form distorted OTb2Cu2 trigonal pyramids that share corners with three equivalent O(1)Tb3Cu tetrahedra, corners with three equivalent O(3)Tb3Cu tetrahedra, corners with two equivalent O(2)Tb2Cu2 trigonal pyramids,  an edgeedge with one O(1)Tb3Cu tetrahedra, and  an edgeedge with one O(5)Tb2Cu2 trigonal pyramid. In the fourth O site, O(3) is bonded to one Tb(1), two equivalent Tb(2), and one Cu(2) atom to form OTb3Cu tetrahedra that share corners with two equivalent O(3)Tb3Cu tetrahedra, corners with four equivalent O(1)Tb3Cu tetrahedra, corners with three equivalent O(2)Tb2Cu2 trigonal pyramids, corners with three equivalent O(5)Tb2Cu2 trigonal pyramids, and  an edgeedge with one O(5)Tb2Cu2 trigonal pyramid. In the fifth O site, O(4) is bonded in a distorted see-saw-like geometry to one Tb(1), one Tb(2), one Cu(1), and one Cu(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb2Cu2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.555
_cell_length_b   10.899
_cell_length_c   12.588
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   487.762
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.779  0.958  0.235  1.0
  Tb  Tb1  1  0.221  0.042  0.735  1.0
  Tb  Tb2  1  0.721  0.458  0.235  1.0
  Tb  Tb3  1  0.279  0.542  0.735  1.0
  Tb  Tb4  1  0.781  0.792  0.563  1.0
  Tb  Tb5  1  0.219  0.208  0.063  1.0
  Tb  Tb6  1  0.719  0.292  0.563  1.0
  Tb  Tb7  1  0.281  0.708  0.063  1.0
  Cu  Cu8  1  0.845  0.761  0.848  1.0
  Cu  Cu9  1  0.155  0.239  0.348  1.0
  Cu  Cu10  1  0.655  0.261  0.848  1.0
  Cu  Cu11  1  0.345  0.739  0.348  1.0
  Cu  Cu12  1  0.658  0.989  0.951  1.0
  Cu  Cu13  1  0.342  0.011  0.451  1.0
  Cu  Cu14  1  0.842  0.489  0.951  1.0
  Cu  Cu15  1  0.158  0.511  0.451  1.0
  O  O16  1  0.776  0.674  0.710  1.0
  O  O17  1  0.224  0.326  0.210  1.0
  O  O18  1  0.724  0.174  0.710  1.0
  O  O19  1  0.276  0.826  0.210  1.0
  O  O20  1  0.723  0.927  0.802  1.0
  O  O21  1  0.277  0.073  0.302  1.0
  O  O22  1  0.777  0.427  0.802  1.0
  O  O23  1  0.223  0.573  0.302  1.0
  O  O24  1  0.274  0.923  0.590  1.0
  O  O25  1  0.726  0.077  0.090  1.0
  O  O26  1  0.226  0.423  0.590  1.0
  O  O27  1  0.774  0.577  0.090  1.0
  O  O28  1  0.653  0.875  0.400  1.0
  O  O29  1  0.347  0.125  0.900  1.0
  O  O30  1  0.847  0.375  0.400  1.0
  O  O31  1  0.153  0.625  0.900  1.0
  O  O32  1  0.780  0.823  0.997  1.0
  O  O33  1  0.220  0.177  0.497  1.0
  O  O34  1  0.720  0.323  0.997  1.0
  O  O35  1  0.280  0.677  0.497  1.0
[/CIF]
.
The material structure described by Tb2Cu2O5 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of distorted corner and edge-sharing TbO6 octahedra. The corner-sharing octahedral tilt angles range from 23-65°. In the second Tb site, Tb(2) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form a mixture of distorted corner and edge-sharing TbO6 octahedra. The corner-sharing octahedral tilt angles range from 23-65°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded to two equivalent Tb(2), one Cu(1), and one Cu(2) atom to form distorted OTb2Cu2 trigonal pyramids that share corners with three equivalent O(1)Tb3Cu tetrahedra, corners with three equivalent O(3)Tb3Cu tetrahedra, corners with two equivalent O(5)Tb2Cu2 trigonal pyramids,  an edgeedge with one O(3)Tb3Cu tetrahedra, and  an edgeedge with one O(2)Tb2Cu2 trigonal pyramid. In the second O site, O(1) is bonded to one Tb(2), two equivalent Tb(1), and one Cu(1) atom to form OTb3Cu tetrahedra that share corners with two equivalent O(1)Tb3Cu tetrahedra, corners with four equivalent O(3)Tb3Cu tetrahedra, corners with three equivalent O(2)Tb2Cu2 trigonal pyramids, corners with three equivalent O(5)Tb2Cu2 trigonal pyramids, and  an edgeedge with one O(2)Tb2Cu2 trigonal pyramid. In the third O site, O(2) is bonded to two equivalent Tb(1), one Cu(1), and one Cu(2) atom to form distorted OTb2Cu2 trigonal pyramids that share corners with three equivalent O(1)Tb3Cu tetrahedra, corners with three equivalent O(3)Tb3Cu tetrahedra, corners with two equivalent O(2)Tb2Cu2 trigonal pyramids,  an edgeedge with one O(1)Tb3Cu tetrahedra, and  an edgeedge with one O(5)Tb2Cu2 trigonal pyramid. In the fourth O site, O(3) is bonded to one Tb(1), two equivalent Tb(2), and one Cu(2) atom to form OTb3Cu tetrahedra that share corners with two equivalent O(3)Tb3Cu tetrahedra, corners with four equivalent O(1)Tb3Cu tetrahedra, corners with three equivalent O(2)Tb2Cu2 trigonal pyramids, corners with three equivalent O(5)Tb2Cu2 trigonal pyramids, and  an edgeedge with one O(5)Tb2Cu2 trigonal pyramid. In the fifth O site, O(4) is bonded in a distorted see-saw-like geometry to one Tb(1), one Tb(2), one Cu(1), and one Cu(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb2Cu2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.555
_cell_length_b   10.899
_cell_length_c   12.588
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   487.762
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.779  0.958  0.235  1.0
  Tb  Tb1  1  0.221  0.042  0.735  1.0
  Tb  Tb2  1  0.721  0.458  0.235  1.0
  Tb  Tb3  1  0.279  0.542  0.735  1.0
  Tb  Tb4  1  0.781  0.792  0.563  1.0
  Tb  Tb5  1  0.219  0.208  0.063  1.0
  Tb  Tb6  1  0.719  0.292  0.563  1.0
  Tb  Tb7  1  0.281  0.708  0.063  1.0
  Cu  Cu8  1  0.845  0.761  0.848  1.0
  Cu  Cu9  1  0.155  0.239  0.348  1.0
  Cu  Cu10  1  0.655  0.261  0.848  1.0
  Cu  Cu11  1  0.345  0.739  0.348  1.0
  Cu  Cu12  1  0.658  0.989  0.951  1.0
  Cu  Cu13  1  0.342  0.011  0.451  1.0
  Cu  Cu14  1  0.842  0.489  0.951  1.0
  Cu  Cu15  1  0.158  0.511  0.451  1.0
  O  O16  1  0.776  0.674  0.710  1.0
  O  O17  1  0.224  0.326  0.210  1.0
  O  O18  1  0.724  0.174  0.710  1.0
  O  O19  1  0.276  0.826  0.210  1.0
  O  O20  1  0.723  0.927  0.802  1.0
  O  O21  1  0.277  0.073  0.302  1.0
  O  O22  1  0.777  0.427  0.802  1.0
  O  O23  1  0.223  0.573  0.302  1.0
  O  O24  1  0.274  0.923  0.590  1.0
  O  O25  1  0.726  0.077  0.090  1.0
  O  O26  1  0.226  0.423  0.590  1.0
  O  O27  1  0.774  0.577  0.090  1.0
  O  O28  1  0.653  0.875  0.400  1.0
  O  O29  1  0.347  0.125  0.900  1.0
  O  O30  1  0.847  0.375  0.400  1.0
  O  O31  1  0.153  0.625  0.900  1.0
  O  O32  1  0.780  0.823  0.997  1.0
  O  O33  1  0.220  0.177  0.497  1.0
  O  O34  1  0.720  0.323  0.997  1.0
  O  O35  1  0.280  0.677  0.497  1.0
[/CIF]
.