The compound described by PbCO2Cl crystallizes in the monoclinic C2/m space group. Pb(1) is bonded in a 2-coordinate geometry to two equivalent O(1) and five equivalent Cl(1) atoms. C(1) is bonded in a bent 120 degrees geometry to two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one Pb(1) and one C(1) atom. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_PbCClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.244
_cell_length_b   4.244
_cell_length_c   9.517
_cell_angle_alpha   86.489
_cell_angle_beta   86.489
_cell_angle_gamma   89.387
_symmetry_Int_Tables_number   1
_cell_volume   170.775
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.229  0.229  0.223  1.0
  Pb  Pb1  1  0.771  0.771  0.777  1.0
  C  C2  1  0.370  0.630  0.500  1.0
  C  C3  1  0.630  0.370  0.500  1.0
  Cl  Cl4  1  0.273  0.273  0.884  1.0
  Cl  Cl5  1  0.727  0.727  0.116  1.0
  O  O6  1  0.671  0.214  0.391  1.0
  O  O7  1  0.786  0.329  0.609  1.0
  O  O8  1  0.214  0.671  0.391  1.0
  O  O9  1  0.329  0.786  0.609  1.0
[/CIF]
.
The compound described by PbCO2Cl crystallizes in the monoclinic C2/m space group. Pb(1) is bonded in a 2-coordinate geometry to two equivalent O(1) and five equivalent Cl(1) atoms. C(1) is bonded in a bent 120 degrees geometry to two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one Pb(1) and one C(1) atom. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_PbCClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.244
_cell_length_b   4.244
_cell_length_c   9.517
_cell_angle_alpha   86.489
_cell_angle_beta   86.489
_cell_angle_gamma   89.387
_symmetry_Int_Tables_number   1
_cell_volume   170.775
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.229  0.229  0.223  1.0
  Pb  Pb1  1  0.771  0.771  0.777  1.0
  C  C2  1  0.370  0.630  0.500  1.0
  C  C3  1  0.630  0.370  0.500  1.0
  Cl  Cl4  1  0.273  0.273  0.884  1.0
  Cl  Cl5  1  0.727  0.727  0.116  1.0
  O  O6  1  0.671  0.214  0.391  1.0
  O  O7  1  0.786  0.329  0.609  1.0
  O  O8  1  0.214  0.671  0.391  1.0
  O  O9  1  0.329  0.786  0.609  1.0
[/CIF]
.