The material structure described by Os3Bi(CO)9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3Bi(CO)9 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), one C(3), and one Bi(1) atom. In the second Os site, Os(2) is bonded in a 3-coordinate geometry to one C(4), one C(5), one C(6), and one Bi(1) atom. In the third Os site, Os(3) is bonded in a 3-coordinate geometry to one C(7), one C(8), one C(9), and one Bi(1) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(1,4) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Os(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Os(2) and one O(1,4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Os(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Os(2) and one O(6) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Os(3) and one O(7) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Os(3) and one O(8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Os(3) and one O(9) atom. Bi(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. There are eight inequivalent O sites. In the first O site, O(1,4) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiOs3(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.612
_cell_length_b   9.675
_cell_length_c   13.277
_cell_angle_alpha   90.160
_cell_angle_beta   69.629
_cell_angle_gamma   63.716
_symmetry_Int_Tables_number   1
_cell_volume   913.530
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.506  0.782  0.413  1.0
  Bi  Bi1  1  0.494  0.218  0.587  1.0
  Os  Os2  1  0.694  0.784  0.192  1.0
  Os  Os3  1  0.306  0.216  0.808  1.0
  Os  Os4  1  0.482  0.568  0.282  1.0
  Os  Os5  1  0.518  0.432  0.718  1.0
  Os  Os6  1  0.338  0.857  0.239  1.0
  Os  Os7  1  0.662  0.143  0.761  1.0
  C  C8  1  0.909  0.648  0.220  1.0
  C  C9  1  0.091  0.352  0.780  1.0
  C  C10  1  0.801  0.738  0.034  1.0
  C  C11  1  0.199  0.262  0.966  1.0
  C  C12  1  0.739  0.953  0.205  1.0
  C  C13  1  0.261  0.047  0.795  1.0
  C  C14  1  0.689  0.411  0.307  1.0
  C  C15  1  0.311  0.589  0.693  1.0
  C  C16  1  0.323  0.510  0.388  1.0
  C  C17  1  0.677  0.490  0.612  1.0
  C  C18  1  0.487  0.457  0.159  1.0
  C  C19  1  0.513  0.543  0.841  1.0
  C  C20  1  0.110  0.873  0.344  1.0
  C  C21  1  0.890  0.127  0.656  1.0
  C  C22  1  0.240  0.896  0.129  1.0
  C  C23  1  0.760  0.104  0.871  1.0
  C  C24  1  0.295  0.067  0.268  1.0
  C  C25  1  0.705  0.933  0.732  1.0
  O  O26  1  0.039  0.564  0.238  1.0
  O  O27  1  0.961  0.436  0.762  1.0
  O  O28  1  0.887  0.709  0.940  1.0
  O  O29  1  0.113  0.291  0.060  1.0
  O  O30  1  0.752  0.067  0.216  1.0
  O  O31  1  0.248  0.933  0.784  1.0
  O  O32  1  0.815  0.315  0.324  1.0
  O  O33  1  0.185  0.685  0.676  1.0
  O  O34  1  0.216  0.482  0.455  1.0
  O  O35  1  0.784  0.518  0.545  1.0
  O  O36  1  0.492  0.376  0.092  1.0
  O  O37  1  0.508  0.624  0.908  1.0
  O  O38  1  0.969  0.893  0.413  1.0
  O  O39  1  0.031  0.107  0.587  1.0
  O  O40  1  0.180  0.920  0.060  1.0
  O  O41  1  0.820  0.080  0.940  1.0
  O  O42  1  0.261  0.194  0.297  1.0
  O  O43  1  0.739  0.806  0.703  1.0
[/CIF]
.
The material structure described by Os3Bi(CO)9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3Bi(CO)9 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), one C(3), and one Bi(1) atom. In the second Os site, Os(2) is bonded in a 3-coordinate geometry to one C(4), one C(5), one C(6), and one Bi(1) atom. In the third Os site, Os(3) is bonded in a 3-coordinate geometry to one C(7), one C(8), one C(9), and one Bi(1) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(1,4) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Os(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Os(2) and one O(1,4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Os(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Os(2) and one O(6) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Os(3) and one O(7) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Os(3) and one O(8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Os(3) and one O(9) atom. Bi(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. There are eight inequivalent O sites. In the first O site, O(1,4) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiOs3(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.612
_cell_length_b   9.675
_cell_length_c   13.277
_cell_angle_alpha   90.160
_cell_angle_beta   69.629
_cell_angle_gamma   63.716
_symmetry_Int_Tables_number   1
_cell_volume   913.530
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.506  0.782  0.413  1.0
  Bi  Bi1  1  0.494  0.218  0.587  1.0
  Os  Os2  1  0.694  0.784  0.192  1.0
  Os  Os3  1  0.306  0.216  0.808  1.0
  Os  Os4  1  0.482  0.568  0.282  1.0
  Os  Os5  1  0.518  0.432  0.718  1.0
  Os  Os6  1  0.338  0.857  0.239  1.0
  Os  Os7  1  0.662  0.143  0.761  1.0
  C  C8  1  0.909  0.648  0.220  1.0
  C  C9  1  0.091  0.352  0.780  1.0
  C  C10  1  0.801  0.738  0.034  1.0
  C  C11  1  0.199  0.262  0.966  1.0
  C  C12  1  0.739  0.953  0.205  1.0
  C  C13  1  0.261  0.047  0.795  1.0
  C  C14  1  0.689  0.411  0.307  1.0
  C  C15  1  0.311  0.589  0.693  1.0
  C  C16  1  0.323  0.510  0.388  1.0
  C  C17  1  0.677  0.490  0.612  1.0
  C  C18  1  0.487  0.457  0.159  1.0
  C  C19  1  0.513  0.543  0.841  1.0
  C  C20  1  0.110  0.873  0.344  1.0
  C  C21  1  0.890  0.127  0.656  1.0
  C  C22  1  0.240  0.896  0.129  1.0
  C  C23  1  0.760  0.104  0.871  1.0
  C  C24  1  0.295  0.067  0.268  1.0
  C  C25  1  0.705  0.933  0.732  1.0
  O  O26  1  0.039  0.564  0.238  1.0
  O  O27  1  0.961  0.436  0.762  1.0
  O  O28  1  0.887  0.709  0.940  1.0
  O  O29  1  0.113  0.291  0.060  1.0
  O  O30  1  0.752  0.067  0.216  1.0
  O  O31  1  0.248  0.933  0.784  1.0
  O  O32  1  0.815  0.315  0.324  1.0
  O  O33  1  0.185  0.685  0.676  1.0
  O  O34  1  0.216  0.482  0.455  1.0
  O  O35  1  0.784  0.518  0.545  1.0
  O  O36  1  0.492  0.376  0.092  1.0
  O  O37  1  0.508  0.624  0.908  1.0
  O  O38  1  0.969  0.893  0.413  1.0
  O  O39  1  0.031  0.107  0.587  1.0
  O  O40  1  0.180  0.920  0.060  1.0
  O  O41  1  0.820  0.080  0.940  1.0
  O  O42  1  0.261  0.194  0.297  1.0
  O  O43  1  0.739  0.806  0.703  1.0
[/CIF]
.