The material described by Ba2Ca2Fe3Zn5O14 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. In the second Ba site, Ba(2) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(7), and one O(8) atom. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(12), and two equivalent O(6) atoms. In the second Ca site, Ca(2) is bonded in a 4-coordinate geometry to one O(14), one O(2), one O(3), and one O(7) atom. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(13), one O(3), and one O(6) atom to form distorted FeO4 tetrahedra that share  a cornercorner with one Fe(3)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, and corners with two equivalent Zn(5)O4 tetrahedra. In the second Fe site, Fe(2) is bonded to one O(4), one O(8), one O(9), and two equivalent O(5) atoms to form FeO5 trigonal bipyramids that share  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Fe(2)O5 trigonal bipyramids, and  an edgeedge with one Zn(4)O4 tetrahedra. In the third Fe site, Fe(3) is bonded to one O(10), one O(11), one O(13), and one O(2) atom to form FeO4 tetrahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(5)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, and  an edgeedge with one Zn(5)O4 tetrahedra. There are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(11), one O(12), one O(4), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Fe(3)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, and corners with two equivalent Fe(2)O5 trigonal bipyramids. In the second Zn site, Zn(2) is bonded to one O(1), one O(10), one O(12), and one O(2) atom to form distorted ZnO4 tetrahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Fe(3)O4 tetrahedra, and corners with three equivalent Zn(5)O4 tetrahedra. In the third Zn site, Zn(3) is bonded in a trigonal planar geometry to one O(14), one O(7), and one O(9) atom. In the fourth Zn site, Zn(4) is bonded to one O(14), one O(3), one O(5), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Fe(2)O5 trigonal bipyramid, and  an edgeedge with one Fe(2)O5 trigonal bipyramid. In the fifth Zn site, Zn(5) is bonded to one O(1), one O(10), one O(13), and one O(2) atom to form distorted ZnO4 tetrahedra that share  a cornercorner with one Fe(3)O4 tetrahedra, corners with two equivalent Fe(1)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra, and  an edgeedge with one Fe(3)O4 tetrahedra. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Ca(1), one Fe(1), one Zn(2), and one Zn(5) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Ca(2), one Fe(3), one Zn(2), and one Zn(5) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ba(1), one Ca(2), one Fe(1), and one Zn(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Ba(1), one Fe(2), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Ba(1), two equivalent Fe(2), and one Zn(4) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ba(1), two equivalent Ca(1), and one Fe(1) atom. In the seventh O site, O(7) is bonded to one Ba(1), one Ba(2), one Ca(2), and one Zn(3) atom to form distorted edge-sharing OBa2CaZn tetrahedra. In the eighth O site, O(8) is bonded to one Ba(1), one Ba(2), one Fe(2), and one Zn(1) atom to form distorted edge-sharing OBa2ZnFe tetrahedra. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Fe(2), one Zn(3), and one Zn(4) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Ba(1), one Ca(1), one Fe(3), one Zn(2), and one Zn(5) atom. In the eleventh O site, O(11) is bonded in a T-shaped geometry to one Ca(1), one Fe(3), and one Zn(1) atom. In the twelfth O site, O(12) is bonded in a distorted see-saw-like geometry to one Ba(1), one Ca(1), one Zn(1), and one Zn(2) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Ba(2), one Fe(1), one Fe(3), and one Zn(5) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Ba(2), one Ca(2), one Zn(3), and one Zn(4) atom. is represented by the CIF card [CIF]
data_Ba2Ca2Zn5Fe3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.407
_cell_length_b   8.732
_cell_length_c   12.752
_cell_angle_alpha   88.270
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   824.401
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.866  0.428  0.747  1.0
  Ba  Ba1  1  0.499  0.119  0.679  1.0
  Ba  Ba2  1  0.999  0.881  0.321  1.0
  Ba  Ba3  1  0.366  0.572  0.253  1.0
  Ca  Ca4  1  0.385  0.496  0.941  1.0
  Ca  Ca5  1  0.522  0.069  0.288  1.0
  Ca  Ca6  1  0.022  0.931  0.712  1.0
  Ca  Ca7  1  0.885  0.504  0.059  1.0
  Zn  Zn8  1  0.316  0.519  0.705  1.0
  Zn  Zn9  1  0.149  0.198  0.903  1.0
  Zn  Zn10  1  0.907  0.135  0.540  1.0
  Zn  Zn11  1  0.281  0.249  0.415  1.0
  Zn  Zn12  1  0.631  0.118  0.968  1.0
  Zn  Zn13  1  0.407  0.865  0.460  1.0
  Zn  Zn14  1  0.781  0.751  0.585  1.0
  Zn  Zn15  1  0.649  0.802  0.097  1.0
  Zn  Zn16  1  0.816  0.481  0.295  1.0
  Zn  Zn17  1  0.131  0.882  0.032  1.0
  Fe  Fe18  1  0.761  0.751  0.880  1.0
  Fe  Fe19  1  0.557  0.501  0.513  1.0
  Fe  Fe20  1  0.057  0.499  0.487  1.0
  Fe  Fe21  1  0.882  0.151  0.115  1.0
  Fe  Fe22  1  0.382  0.849  0.885  1.0
  Fe  Fe23  1  0.261  0.249  0.120  1.0
  O  O24  1  0.913  0.773  0.002  1.0
  O  O25  1  0.413  0.227  0.998  1.0
  O  O26  1  0.184  0.987  0.862  1.0
  O  O27  1  0.839  0.743  0.741  1.0
  O  O28  1  0.112  0.576  0.617  1.0
  O  O29  1  0.811  0.529  0.541  1.0
  O  O30  1  0.311  0.471  0.459  1.0
  O  O31  1  0.689  0.552  0.919  1.0
  O  O32  1  0.839  0.138  0.683  1.0
  O  O33  1  0.520  0.406  0.647  1.0
  O  O34  1  0.026  0.279  0.455  1.0
  O  O35  1  0.879  0.220  0.969  1.0
  O  O36  1  0.857  0.314  0.198  1.0
  O  O37  1  0.210  0.369  0.815  1.0
  O  O38  1  0.115  0.054  0.127  1.0
  O  O39  1  0.935  0.914  0.523  1.0
  O  O40  1  0.435  0.086  0.477  1.0
  O  O41  1  0.615  0.946  0.873  1.0
  O  O42  1  0.710  0.631  0.185  1.0
  O  O43  1  0.357  0.686  0.802  1.0
  O  O44  1  0.379  0.780  0.031  1.0
  O  O45  1  0.526  0.721  0.545  1.0
  O  O46  1  0.020  0.594  0.353  1.0
  O  O47  1  0.339  0.862  0.317  1.0
  O  O48  1  0.189  0.448  0.081  1.0
  O  O49  1  0.612  0.424  0.383  1.0
  O  O50  1  0.339  0.257  0.259  1.0
  O  O51  1  0.684  0.013  0.138  1.0
[/CIF]
.
The material described by Ba2Ca2Fe3Zn5O14 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. In the second Ba site, Ba(2) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(7), and one O(8) atom. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(12), and two equivalent O(6) atoms. In the second Ca site, Ca(2) is bonded in a 4-coordinate geometry to one O(14), one O(2), one O(3), and one O(7) atom. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(13), one O(3), and one O(6) atom to form distorted FeO4 tetrahedra that share  a cornercorner with one Fe(3)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, and corners with two equivalent Zn(5)O4 tetrahedra. In the second Fe site, Fe(2) is bonded to one O(4), one O(8), one O(9), and two equivalent O(5) atoms to form FeO5 trigonal bipyramids that share  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Fe(2)O5 trigonal bipyramids, and  an edgeedge with one Zn(4)O4 tetrahedra. In the third Fe site, Fe(3) is bonded to one O(10), one O(11), one O(13), and one O(2) atom to form FeO4 tetrahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(5)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, and  an edgeedge with one Zn(5)O4 tetrahedra. There are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(11), one O(12), one O(4), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Fe(3)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, and corners with two equivalent Fe(2)O5 trigonal bipyramids. In the second Zn site, Zn(2) is bonded to one O(1), one O(10), one O(12), and one O(2) atom to form distorted ZnO4 tetrahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Fe(3)O4 tetrahedra, and corners with three equivalent Zn(5)O4 tetrahedra. In the third Zn site, Zn(3) is bonded in a trigonal planar geometry to one O(14), one O(7), and one O(9) atom. In the fourth Zn site, Zn(4) is bonded to one O(14), one O(3), one O(5), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Fe(2)O5 trigonal bipyramid, and  an edgeedge with one Fe(2)O5 trigonal bipyramid. In the fifth Zn site, Zn(5) is bonded to one O(1), one O(10), one O(13), and one O(2) atom to form distorted ZnO4 tetrahedra that share  a cornercorner with one Fe(3)O4 tetrahedra, corners with two equivalent Fe(1)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra, and  an edgeedge with one Fe(3)O4 tetrahedra. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Ca(1), one Fe(1), one Zn(2), and one Zn(5) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Ca(2), one Fe(3), one Zn(2), and one Zn(5) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ba(1), one Ca(2), one Fe(1), and one Zn(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Ba(1), one Fe(2), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Ba(1), two equivalent Fe(2), and one Zn(4) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ba(1), two equivalent Ca(1), and one Fe(1) atom. In the seventh O site, O(7) is bonded to one Ba(1), one Ba(2), one Ca(2), and one Zn(3) atom to form distorted edge-sharing OBa2CaZn tetrahedra. In the eighth O site, O(8) is bonded to one Ba(1), one Ba(2), one Fe(2), and one Zn(1) atom to form distorted edge-sharing OBa2ZnFe tetrahedra. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Fe(2), one Zn(3), and one Zn(4) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Ba(1), one Ca(1), one Fe(3), one Zn(2), and one Zn(5) atom. In the eleventh O site, O(11) is bonded in a T-shaped geometry to one Ca(1), one Fe(3), and one Zn(1) atom. In the twelfth O site, O(12) is bonded in a distorted see-saw-like geometry to one Ba(1), one Ca(1), one Zn(1), and one Zn(2) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Ba(2), one Fe(1), one Fe(3), and one Zn(5) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Ba(2), one Ca(2), one Zn(3), and one Zn(4) atom. is represented by the CIF card [CIF]
data_Ba2Ca2Zn5Fe3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.407
_cell_length_b   8.732
_cell_length_c   12.752
_cell_angle_alpha   88.270
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   824.401
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.866  0.428  0.747  1.0
  Ba  Ba1  1  0.499  0.119  0.679  1.0
  Ba  Ba2  1  0.999  0.881  0.321  1.0
  Ba  Ba3  1  0.366  0.572  0.253  1.0
  Ca  Ca4  1  0.385  0.496  0.941  1.0
  Ca  Ca5  1  0.522  0.069  0.288  1.0
  Ca  Ca6  1  0.022  0.931  0.712  1.0
  Ca  Ca7  1  0.885  0.504  0.059  1.0
  Zn  Zn8  1  0.316  0.519  0.705  1.0
  Zn  Zn9  1  0.149  0.198  0.903  1.0
  Zn  Zn10  1  0.907  0.135  0.540  1.0
  Zn  Zn11  1  0.281  0.249  0.415  1.0
  Zn  Zn12  1  0.631  0.118  0.968  1.0
  Zn  Zn13  1  0.407  0.865  0.460  1.0
  Zn  Zn14  1  0.781  0.751  0.585  1.0
  Zn  Zn15  1  0.649  0.802  0.097  1.0
  Zn  Zn16  1  0.816  0.481  0.295  1.0
  Zn  Zn17  1  0.131  0.882  0.032  1.0
  Fe  Fe18  1  0.761  0.751  0.880  1.0
  Fe  Fe19  1  0.557  0.501  0.513  1.0
  Fe  Fe20  1  0.057  0.499  0.487  1.0
  Fe  Fe21  1  0.882  0.151  0.115  1.0
  Fe  Fe22  1  0.382  0.849  0.885  1.0
  Fe  Fe23  1  0.261  0.249  0.120  1.0
  O  O24  1  0.913  0.773  0.002  1.0
  O  O25  1  0.413  0.227  0.998  1.0
  O  O26  1  0.184  0.987  0.862  1.0
  O  O27  1  0.839  0.743  0.741  1.0
  O  O28  1  0.112  0.576  0.617  1.0
  O  O29  1  0.811  0.529  0.541  1.0
  O  O30  1  0.311  0.471  0.459  1.0
  O  O31  1  0.689  0.552  0.919  1.0
  O  O32  1  0.839  0.138  0.683  1.0
  O  O33  1  0.520  0.406  0.647  1.0
  O  O34  1  0.026  0.279  0.455  1.0
  O  O35  1  0.879  0.220  0.969  1.0
  O  O36  1  0.857  0.314  0.198  1.0
  O  O37  1  0.210  0.369  0.815  1.0
  O  O38  1  0.115  0.054  0.127  1.0
  O  O39  1  0.935  0.914  0.523  1.0
  O  O40  1  0.435  0.086  0.477  1.0
  O  O41  1  0.615  0.946  0.873  1.0
  O  O42  1  0.710  0.631  0.185  1.0
  O  O43  1  0.357  0.686  0.802  1.0
  O  O44  1  0.379  0.780  0.031  1.0
  O  O45  1  0.526  0.721  0.545  1.0
  O  O46  1  0.020  0.594  0.353  1.0
  O  O47  1  0.339  0.862  0.317  1.0
  O  O48  1  0.189  0.448  0.081  1.0
  O  O49  1  0.612  0.424  0.383  1.0
  O  O50  1  0.339  0.257  0.259  1.0
  O  O51  1  0.684  0.013  0.138  1.0
[/CIF]
.