The compound described by Mn2OsN3 crystallizes in the orthorhombic Cmc2_1 space group. Mn(1) is bonded to one N(2) and three equivalent N(1) atoms to form distorted corner-sharing MnN4 trigonal pyramids. Os(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to three equivalent Mn(1) and one Os(1) atom. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Os(1) atoms to form corner-sharing NMn2Os2 trigonal pyramids. is represented by the CIF file [CIF]
data_Mn2OsN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.179
_cell_length_b   5.494
_cell_length_c   4.944
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   122.030
_symmetry_Int_Tables_number   1
_cell_volume   119.277
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.359  0.390  0.524  1.0
  Mn  Mn1  1  0.641  0.031  0.524  1.0
  Mn  Mn2  1  0.641  0.610  0.024  1.0
  Mn  Mn3  1  0.359  0.969  0.024  1.0
  Os  Os4  1  0.000  0.640  0.438  1.0
  Os  Os5  1  0.000  0.360  0.938  1.0
  N  N6  1  0.324  0.269  0.885  1.0
  N  N7  1  0.676  0.945  0.885  1.0
  N  N8  1  0.676  0.731  0.385  1.0
  N  N9  1  0.324  0.055  0.385  1.0
  N  N10  1  0.000  0.712  0.834  1.0
  N  N11  1  0.000  0.288  0.334  1.0
[/CIF]
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The compound described by Mn2OsN3 crystallizes in the orthorhombic Cmc2_1 space group. Mn(1) is bonded to one N(2) and three equivalent N(1) atoms to form distorted corner-sharing MnN4 trigonal pyramids. Os(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to three equivalent Mn(1) and one Os(1) atom. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Os(1) atoms to form corner-sharing NMn2Os2 trigonal pyramids. is represented by the CIF file [CIF]
data_Mn2OsN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.179
_cell_length_b   5.494
_cell_length_c   4.944
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   122.030
_symmetry_Int_Tables_number   1
_cell_volume   119.277
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.359  0.390  0.524  1.0
  Mn  Mn1  1  0.641  0.031  0.524  1.0
  Mn  Mn2  1  0.641  0.610  0.024  1.0
  Mn  Mn3  1  0.359  0.969  0.024  1.0
  Os  Os4  1  0.000  0.640  0.438  1.0
  Os  Os5  1  0.000  0.360  0.938  1.0
  N  N6  1  0.324  0.269  0.885  1.0
  N  N7  1  0.676  0.945  0.885  1.0
  N  N8  1  0.676  0.731  0.385  1.0
  N  N9  1  0.324  0.055  0.385  1.0
  N  N10  1  0.000  0.712  0.834  1.0
  N  N11  1  0.000  0.288  0.334  1.0
[/CIF]
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