The material structure described by Li8VMn3(PO4)6 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(10), one O(2), and one O(21) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 trigonal pyramid, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 66-68°. In the second Li site, Li(2) is bonded to one O(24), one O(3), one O(5), and one O(6) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 62-65°. In the third Li site, Li(3) is bonded to one O(12), one O(20), one O(4), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 trigonal pyramid, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 69-70°. In the fourth Li site, Li(4) is bonded in a rectangular see-saw-like geometry to one O(14), one O(3), one O(6), and one O(7) atom. In the fifth Li site, Li(5) is bonded in a rectangular see-saw-like geometry to one O(11), one O(18), one O(19), and one O(22) atom. In the sixth Li site, Li(6) is bonded to one O(13), one O(16), one O(21), and one O(5) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 68-69°. In the seventh Li site, Li(7) is bonded to one O(1), one O(19), one O(20), and one O(22) atom to form LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 63-66°. In the eighth Li site, Li(8) is bonded to one O(15), one O(23), one O(24), and one O(4) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 65-67°. V(1) is bonded to one O(2), one O(20), one O(21), one O(24), one O(3), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 trigonal pyramid,  an edgeedge with one Li(1)O4 tetrahedra,  an edgeedge with one Li(3)O4 tetrahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(13), one O(15), one O(19), one O(7), and one O(8) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(7)O4 trigonal pyramid. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(14), one O(17), one O(18), and one O(6) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. In the third Mn site, Mn(3) is bonded to one O(1), one O(16), one O(22), one O(23), one O(4), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Li(6)O4 tetrahedra,  an edgeedge with one Li(8)O4 tetrahedra, and  an edgeedge with one Li(7)O4 trigonal pyramid. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(12), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  a cornercorner with one Li(7)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 32-52°. In the second P site, P(2) is bonded to one O(2), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 22-58°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 30-53°. In the fourth P site, P(4) is bonded to one O(14), one O(15), one O(16), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(7)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 29-53°. In the fifth P site, P(5) is bonded to one O(17), one O(19), one O(21), and one O(23) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(7)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 22-56°. In the sixth P site, P(6) is bonded to one O(13), one O(18), one O(22), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  a cornercorner with one Li(7)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 32-54°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(7), one Mn(3), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(4)Li2MnP tetrahedra,  a cornercorner with one O(21)Li2VP tetrahedra,  a cornercorner with one O(5)Li2MnP trigonal pyramid, and  a cornercorner with one O(20)Li2VP trigonal pyramid. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one P(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one Li(8), one Mn(3), and one P(2) atom to form distorted OLi2MnP tetrahedra that share  a cornercorner with one O(1)Li2MnP trigonal pyramid,  a cornercorner with one O(5)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2VP trigonal pyramid, and  a cornercorner with one O(24)Li2VP trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Li(6), one Mn(3), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(4)Li2MnP tetrahedra,  a cornercorner with one O(21)Li2VP tetrahedra,  a cornercorner with one O(1)Li2MnP trigonal pyramid, and  a cornercorner with one O(24)Li2VP trigonal pyramid. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Li(4), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(3), one V(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(2), and one P(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Li(5), one Mn(1), and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(2), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Li(6), one Mn(1), and one P(6) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(4), one Mn(2), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(8), one Mn(1), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(6), one Mn(3), and one P(4) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(5) atom. In the eighteenth O site, O(18) is bonded in a distorted T-shaped geometry to one Li(5), one Mn(2), and one P(6) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Mn(1), and one P(5) atom. In the twentieth O site, O(20) is bonded to one Li(3), one Li(7), one V(1), and one P(4) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(4)Li2MnP tetrahedra,  a cornercorner with one O(21)Li2VP tetrahedra,  a cornercorner with one O(1)Li2MnP trigonal pyramid, and  a cornercorner with one O(24)Li2VP trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(6), one V(1), and one P(5) atom to form OLi2VP tetrahedra that share  a cornercorner with one O(1)Li2MnP trigonal pyramid,  a cornercorner with one O(5)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2VP trigonal pyramid, and  a cornercorner with one O(24)Li2VP trigonal pyramid. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Mn(3), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Li(8), one Mn(3), and one P(5) atom. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(8), one V(1), and one P(6) atom to form OLi2VP trigonal pyramids that share  a cornercorner with one O(4)Li2MnP tetrahedra,  a cornercorner with one O(21)Li2VP tetrahedra,  a cornercorner with one O(5)Li2MnP trigonal pyramid, and  a cornercorner with one O(20)Li2VP trigonal pyramid. is represented by the CIF card [CIF]
data_Li8Mn3V(PO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.418
_cell_length_b   8.475
_cell_length_c   9.283
_cell_angle_alpha   91.145
_cell_angle_beta   116.155
_cell_angle_gamma   119.359
_symmetry_Int_Tables_number   1
_cell_volume   493.937
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.197  0.265  0.865  1.0
  Li  Li1  1  0.636  0.944  0.904  1.0
  Li  Li2  1  0.928  0.661  0.853  1.0
  Li  Li3  1  0.329  0.797  0.591  1.0
  Li  Li4  1  0.670  0.202  0.408  1.0
  Li  Li5  1  0.073  0.340  0.148  1.0
  Li  Li6  1  0.366  0.056  0.098  1.0
  Li  Li7  1  0.803  0.734  0.132  1.0
  Mn  Mn8  1  0.284  0.148  0.438  1.0
  Mn  Mn9  1  0.712  0.850  0.562  1.0
  Mn  Mn10  1  0.689  0.350  0.031  1.0
  V  V11  1  0.311  0.649  0.967  1.0
  P  P12  1  0.215  0.949  0.754  1.0
  P  P13  1  0.495  0.551  0.752  1.0
  P  P14  1  0.808  0.256  0.762  1.0
  P  P15  1  0.191  0.746  0.238  1.0
  P  P16  1  0.506  0.451  0.244  1.0
  P  P17  1  0.784  0.048  0.248  1.0
  O  O18  1  0.360  0.148  0.895  1.0
  O  O19  1  0.341  0.505  0.820  1.0
  O  O20  1  0.319  0.832  0.818  1.0
  O  O21  1  0.697  0.565  0.896  1.0
  O  O22  1  0.746  0.213  0.904  1.0
  O  O23  1  0.568  0.751  0.726  1.0
  O  O24  1  0.207  0.967  0.589  1.0
  O  O25  1  0.382  0.398  0.591  1.0
  O  O26  1  0.986  0.471  0.822  1.0
  O  O27  1  0.892  0.133  0.756  1.0
  O  O28  1  0.618  0.209  0.593  1.0
  O  O29  1  1.000  0.853  0.744  1.0
  O  O30  1  0.997  0.145  0.254  1.0
  O  O31  1  0.383  0.793  0.408  1.0
  O  O32  1  0.107  0.868  0.247  1.0
  O  O33  1  0.014  0.529  0.178  1.0
  O  O34  1  0.621  0.606  0.404  1.0
  O  O35  1  0.800  0.029  0.417  1.0
  O  O36  1  0.425  0.251  0.267  1.0
  O  O37  1  0.255  0.789  0.099  1.0
  O  O38  1  0.307  0.445  0.100  1.0
  O  O39  1  0.677  0.161  0.189  1.0
  O  O40  1  0.664  0.495  0.180  1.0
  O  O41  1  0.638  0.848  0.107  1.0
[/CIF]
.
The material structure described by Li8VMn3(PO4)6 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(10), one O(2), and one O(21) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 trigonal pyramid, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 66-68°. In the second Li site, Li(2) is bonded to one O(24), one O(3), one O(5), and one O(6) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 62-65°. In the third Li site, Li(3) is bonded to one O(12), one O(20), one O(4), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 trigonal pyramid, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 69-70°. In the fourth Li site, Li(4) is bonded in a rectangular see-saw-like geometry to one O(14), one O(3), one O(6), and one O(7) atom. In the fifth Li site, Li(5) is bonded in a rectangular see-saw-like geometry to one O(11), one O(18), one O(19), and one O(22) atom. In the sixth Li site, Li(6) is bonded to one O(13), one O(16), one O(21), and one O(5) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 68-69°. In the seventh Li site, Li(7) is bonded to one O(1), one O(19), one O(20), and one O(22) atom to form LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 63-66°. In the eighth Li site, Li(8) is bonded to one O(15), one O(23), one O(24), and one O(4) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 65-67°. V(1) is bonded to one O(2), one O(20), one O(21), one O(24), one O(3), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 trigonal pyramid,  an edgeedge with one Li(1)O4 tetrahedra,  an edgeedge with one Li(3)O4 tetrahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(13), one O(15), one O(19), one O(7), and one O(8) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(7)O4 trigonal pyramid. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(14), one O(17), one O(18), and one O(6) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. In the third Mn site, Mn(3) is bonded to one O(1), one O(16), one O(22), one O(23), one O(4), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Li(6)O4 tetrahedra,  an edgeedge with one Li(8)O4 tetrahedra, and  an edgeedge with one Li(7)O4 trigonal pyramid. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(12), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  a cornercorner with one Li(7)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 32-52°. In the second P site, P(2) is bonded to one O(2), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 22-58°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 30-53°. In the fourth P site, P(4) is bonded to one O(14), one O(15), one O(16), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(7)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 29-53°. In the fifth P site, P(5) is bonded to one O(17), one O(19), one O(21), and one O(23) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(7)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 22-56°. In the sixth P site, P(6) is bonded to one O(13), one O(18), one O(22), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  a cornercorner with one Li(7)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 32-54°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(7), one Mn(3), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(4)Li2MnP tetrahedra,  a cornercorner with one O(21)Li2VP tetrahedra,  a cornercorner with one O(5)Li2MnP trigonal pyramid, and  a cornercorner with one O(20)Li2VP trigonal pyramid. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one P(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one Li(8), one Mn(3), and one P(2) atom to form distorted OLi2MnP tetrahedra that share  a cornercorner with one O(1)Li2MnP trigonal pyramid,  a cornercorner with one O(5)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2VP trigonal pyramid, and  a cornercorner with one O(24)Li2VP trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Li(6), one Mn(3), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(4)Li2MnP tetrahedra,  a cornercorner with one O(21)Li2VP tetrahedra,  a cornercorner with one O(1)Li2MnP trigonal pyramid, and  a cornercorner with one O(24)Li2VP trigonal pyramid. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Li(4), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(3), one V(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(2), and one P(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Li(5), one Mn(1), and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(2), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Li(6), one Mn(1), and one P(6) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(4), one Mn(2), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(8), one Mn(1), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(6), one Mn(3), and one P(4) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(5) atom. In the eighteenth O site, O(18) is bonded in a distorted T-shaped geometry to one Li(5), one Mn(2), and one P(6) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Mn(1), and one P(5) atom. In the twentieth O site, O(20) is bonded to one Li(3), one Li(7), one V(1), and one P(4) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(4)Li2MnP tetrahedra,  a cornercorner with one O(21)Li2VP tetrahedra,  a cornercorner with one O(1)Li2MnP trigonal pyramid, and  a cornercorner with one O(24)Li2VP trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(6), one V(1), and one P(5) atom to form OLi2VP tetrahedra that share  a cornercorner with one O(1)Li2MnP trigonal pyramid,  a cornercorner with one O(5)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2VP trigonal pyramid, and  a cornercorner with one O(24)Li2VP trigonal pyramid. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Mn(3), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Li(8), one Mn(3), and one P(5) atom. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(8), one V(1), and one P(6) atom to form OLi2VP trigonal pyramids that share  a cornercorner with one O(4)Li2MnP tetrahedra,  a cornercorner with one O(21)Li2VP tetrahedra,  a cornercorner with one O(5)Li2MnP trigonal pyramid, and  a cornercorner with one O(20)Li2VP trigonal pyramid. is represented by the CIF card [CIF]
data_Li8Mn3V(PO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.418
_cell_length_b   8.475
_cell_length_c   9.283
_cell_angle_alpha   91.145
_cell_angle_beta   116.155
_cell_angle_gamma   119.359
_symmetry_Int_Tables_number   1
_cell_volume   493.937
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.197  0.265  0.865  1.0
  Li  Li1  1  0.636  0.944  0.904  1.0
  Li  Li2  1  0.928  0.661  0.853  1.0
  Li  Li3  1  0.329  0.797  0.591  1.0
  Li  Li4  1  0.670  0.202  0.408  1.0
  Li  Li5  1  0.073  0.340  0.148  1.0
  Li  Li6  1  0.366  0.056  0.098  1.0
  Li  Li7  1  0.803  0.734  0.132  1.0
  Mn  Mn8  1  0.284  0.148  0.438  1.0
  Mn  Mn9  1  0.712  0.850  0.562  1.0
  Mn  Mn10  1  0.689  0.350  0.031  1.0
  V  V11  1  0.311  0.649  0.967  1.0
  P  P12  1  0.215  0.949  0.754  1.0
  P  P13  1  0.495  0.551  0.752  1.0
  P  P14  1  0.808  0.256  0.762  1.0
  P  P15  1  0.191  0.746  0.238  1.0
  P  P16  1  0.506  0.451  0.244  1.0
  P  P17  1  0.784  0.048  0.248  1.0
  O  O18  1  0.360  0.148  0.895  1.0
  O  O19  1  0.341  0.505  0.820  1.0
  O  O20  1  0.319  0.832  0.818  1.0
  O  O21  1  0.697  0.565  0.896  1.0
  O  O22  1  0.746  0.213  0.904  1.0
  O  O23  1  0.568  0.751  0.726  1.0
  O  O24  1  0.207  0.967  0.589  1.0
  O  O25  1  0.382  0.398  0.591  1.0
  O  O26  1  0.986  0.471  0.822  1.0
  O  O27  1  0.892  0.133  0.756  1.0
  O  O28  1  0.618  0.209  0.593  1.0
  O  O29  1  1.000  0.853  0.744  1.0
  O  O30  1  0.997  0.145  0.254  1.0
  O  O31  1  0.383  0.793  0.408  1.0
  O  O32  1  0.107  0.868  0.247  1.0
  O  O33  1  0.014  0.529  0.178  1.0
  O  O34  1  0.621  0.606  0.404  1.0
  O  O35  1  0.800  0.029  0.417  1.0
  O  O36  1  0.425  0.251  0.267  1.0
  O  O37  1  0.255  0.789  0.099  1.0
  O  O38  1  0.307  0.445  0.100  1.0
  O  O39  1  0.677  0.161  0.189  1.0
  O  O40  1  0.664  0.495  0.180  1.0
  O  O41  1  0.638  0.848  0.107  1.0
[/CIF]
.