The crystal structure described by Li3V2(OF)3 is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one F(1), one F(3), and two equivalent F(4) atoms to form distorted LiOF4 trigonal bipyramids that share  a cornercorner with one Li(5)F4 tetrahedra, corners with two equivalent Li(6)F4 tetrahedra, corners with two equivalent Li(1)OF4 trigonal bipyramids,  an edgeedge with one V(2)O4F trigonal bipyramid, and edges with two equivalent V(4)O4F trigonal bipyramids. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(2), one F(2), one F(4), and two equivalent F(3) atoms. In the third Li site, Li(3) is bonded to one O(3), one F(5), and two equivalent F(6) atoms to form LiOF3 tetrahedra that share  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(5)F4 tetrahedra, corners with two equivalent Li(6)F4 tetrahedra, corners with two equivalent Li(3)OF3 tetrahedra, and corners with four equivalent Li(4)OF3 tetrahedra. The corner-sharing octahedral tilt angles range from 65-67°. In the fourth Li site, Li(4) is bonded to one O(4), one F(6), and two equivalent F(5) atoms to form LiOF3 tetrahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  a cornercorner with one Li(6)F4 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(4)OF3 tetrahedra, and corners with four equivalent Li(3)OF3 tetrahedra. The corner-sharing octahedral tilt angles range from 66-67°. In the fifth Li site, Li(5) is bonded to one F(1), one F(5), and two equivalent F(2) atoms to form LiF4 tetrahedra that share  a cornercorner with one Li(3)OF3 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(4)OF3 tetrahedra, corners with four equivalent Li(6)F4 tetrahedra, and  a cornercorner with one Li(1)OF4 trigonal bipyramid. In the sixth Li site, Li(6) is bonded to one F(2), one F(6), and two equivalent F(1) atoms to form LiF4 tetrahedra that share  a cornercorner with one Li(4)OF3 tetrahedra, corners with two equivalent Li(6)F4 tetrahedra, corners with two equivalent Li(3)OF3 tetrahedra, corners with four equivalent Li(5)F4 tetrahedra, and corners with two equivalent Li(1)OF4 trigonal bipyramids. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(4), one O(5), two equivalent O(3), and two equivalent O(6) atoms to form VO6 octahedra that share  a cornercorner with one Li(4)OF3 tetrahedra, corners with two equivalent Li(3)OF3 tetrahedra,  a cornercorner with one V(2)O4F trigonal bipyramid, corners with two equivalent V(4)O4F trigonal bipyramids, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent V(3)O6 octahedra. In the second V site, V(2) is bonded to one O(1), one O(5), two equivalent O(2), and one F(3) atom to form distorted VO4F trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent V(2)O4F trigonal bipyramids, corners with four equivalent V(4)O4F trigonal bipyramids, and  an edgeedge with one Li(1)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 58-59°. In the third V site, V(3) is bonded to one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms to form VO6 octahedra that share  a cornercorner with one Li(3)OF3 tetrahedra, corners with two equivalent Li(4)OF3 tetrahedra,  a cornercorner with one V(4)O4F trigonal bipyramid, corners with two equivalent V(2)O4F trigonal bipyramids, edges with two equivalent V(3)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. In the fourth V site, V(4) is bonded to one O(2), one O(6), two equivalent O(1), and one F(4) atom to form distorted VO4F trigonal bipyramids that share  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O4F trigonal bipyramids, corners with four equivalent V(2)O4F trigonal bipyramids, and edges with two equivalent Li(1)OF4 trigonal bipyramids. The corner-sharing octahedral tilt angles are 59°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one V(2), and two equivalent V(4) atoms to form distorted OLiV3 tetrahedra that share  a cornercorner with one F(1)Li4 tetrahedra, corners with two equivalent O(1)LiV3 tetrahedra, corners with four equivalent O(2)LiV3 tetrahedra,  a cornercorner with one O(5)V4 trigonal pyramid, corners with two equivalent O(6)V4 trigonal pyramids,  an edgeedge with one F(3)Li3V tetrahedra, and edges with two equivalent F(4)Li3V tetrahedra. In the second O site, O(2) is bonded to one Li(2), one V(4), and two equivalent V(2) atoms to form distorted OLiV3 tetrahedra that share  a cornercorner with one F(2)Li4 tetrahedra, corners with two equivalent O(2)LiV3 tetrahedra, corners with four equivalent O(1)LiV3 tetrahedra,  a cornercorner with one O(6)V4 trigonal pyramid, corners with two equivalent O(5)V4 trigonal pyramids,  an edgeedge with one F(4)Li3V tetrahedra, and edges with two equivalent F(3)Li3V tetrahedra. In the third O site, O(3) is bonded to one Li(3), one V(3), and two equivalent V(1) atoms to form OLiV3 tetrahedra that share  a cornercorner with one F(5)Li4 tetrahedra, corners with two equivalent O(3)LiV3 tetrahedra, corners with two equivalent F(6)Li4 tetrahedra, corners with four equivalent O(4)LiV3 tetrahedra, corners with three equivalent O(6)V4 trigonal pyramids,  an edgeedge with one O(6)V4 trigonal pyramid, and edges with two equivalent O(5)V4 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(4), one V(1), and two equivalent V(3) atoms to form OLiV3 tetrahedra that share  a cornercorner with one F(6)Li4 tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra, corners with two equivalent F(5)Li4 tetrahedra, corners with four equivalent O(3)LiV3 tetrahedra, corners with three equivalent O(5)V4 trigonal pyramids,  an edgeedge with one O(5)V4 trigonal pyramid, and edges with two equivalent O(6)V4 trigonal pyramids. In the fifth O site, O(5) is bonded to one V(1), one V(2), and two equivalent V(3) atoms to form distorted OV4 trigonal pyramids that share  a cornercorner with one O(1)LiV3 tetrahedra,  a cornercorner with one F(3)Li3V tetrahedra, corners with two equivalent O(2)LiV3 tetrahedra, corners with three equivalent O(4)LiV3 tetrahedra, corners with two equivalent O(5)V4 trigonal pyramids, corners with four equivalent O(6)V4 trigonal pyramids,  an edgeedge with one O(4)LiV3 tetrahedra, and edges with two equivalent O(3)LiV3 tetrahedra. In the sixth O site, O(6) is bonded to one V(3), one V(4), and two equivalent V(1) atoms to form distorted OV4 trigonal pyramids that share  a cornercorner with one O(2)LiV3 tetrahedra,  a cornercorner with one F(4)Li3V tetrahedra, corners with two equivalent O(1)LiV3 tetrahedra, corners with three equivalent O(3)LiV3 tetrahedra, corners with two equivalent O(6)V4 trigonal pyramids, corners with four equivalent O(5)V4 trigonal pyramids,  an edgeedge with one O(3)LiV3 tetrahedra, and edges with two equivalent O(4)LiV3 tetrahedra. There are six inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(5), and two equivalent Li(6) atoms to form FLi4 tetrahedra that share  a cornercorner with one O(1)LiV3 tetrahedra,  a cornercorner with one F(3)Li3V tetrahedra,  a cornercorner with one F(5)Li4 tetrahedra, corners with two equivalent F(4)Li3V tetrahedra, corners with two equivalent F(1)Li4 tetrahedra, corners with two equivalent F(6)Li4 tetrahedra, and corners with four equivalent F(2)Li4 tetrahedra. In the second F site, F(2) is bonded to one Li(2), one Li(6), and two equivalent Li(5) atoms to form FLi4 tetrahedra that share  a cornercorner with one O(2)LiV3 tetrahedra,  a cornercorner with one F(4)Li3V tetrahedra,  a cornercorner with one F(6)Li4 tetrahedra, corners with two equivalent F(3)Li3V tetrahedra, corners with two equivalent F(2)Li4 tetrahedra, corners with two equivalent F(5)Li4 tetrahedra, and corners with four equivalent F(1)Li4 tetrahedra. In the third F site, F(3) is bonded to one Li(1), two equivalent Li(2), and one V(2) atom to form distorted FLi3V tetrahedra that share  a cornercorner with one F(1)Li4 tetrahedra, corners with two equivalent F(3)Li3V tetrahedra, corners with two equivalent F(2)Li4 tetrahedra, corners with four equivalent F(4)Li3V tetrahedra,  a cornercorner with one O(5)V4 trigonal pyramid,  an edgeedge with one O(1)LiV3 tetrahedra, and edges with two equivalent O(2)LiV3 tetrahedra. In the fourth F site, F(4) is bonded to one Li(2), two equivalent Li(1), and one V(4) atom to form distorted FLi3V tetrahedra that share  a cornercorner with one F(2)Li4 tetrahedra, corners with two equivalent F(4)Li3V tetrahedra, corners with two equivalent F(1)Li4 tetrahedra, corners with four equivalent F(3)Li3V tetrahedra,  a cornercorner with one O(6)V4 trigonal pyramid,  an edgeedge with one O(2)LiV3 tetrahedra, and edges with two equivalent O(1)LiV3 tetrahedra. In the fifth F site, F(5) is bonded to one Li(3), one Li(5), and two equivalent Li(4) atoms to form FLi4 tetrahedra that share  a cornercorner with one O(3)LiV3 tetrahedra,  a cornercorner with one F(1)Li4 tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra, corners with two equivalent F(2)Li4 tetrahedra, corners with two equivalent F(5)Li4 tetrahedra, and corners with four equivalent F(6)Li4 tetrahedra. In the sixth F site, F(6) is bonded to one Li(4), one Li(6), and two equivalent Li(3) atoms to form FLi4 tetrahedra that share  a cornercorner with one O(4)LiV3 tetrahedra,  a cornercorner with one F(2)Li4 tetrahedra, corners with two equivalent O(3)LiV3 tetrahedra, corners with two equivalent F(1)Li4 tetrahedra, corners with two equivalent F(6)Li4 tetrahedra, and corners with four equivalent F(5)Li4 tetrahedra. is represented by the CIF file [CIF]
data_Li3V2(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.230
_cell_length_b   3.255
_cell_length_c   13.471
_cell_angle_alpha   83.394
_cell_angle_beta   83.271
_cell_angle_gamma   60.649
_symmetry_Int_Tables_number   1
_cell_volume   122.321
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.811  0.806  0.566  1.0
  F  F1  1  0.203  0.203  0.391  1.0
  F  F2  1  0.082  0.093  0.746  1.0
  Li  Li3  1  0.860  0.855  0.423  1.0
  Li  Li4  1  0.736  0.743  0.783  1.0
  Li  Li5  1  0.132  0.132  0.603  1.0
  O  O6  1  0.916  0.909  0.251  1.0
  O  O7  1  0.688  0.697  0.933  1.0
  O  O8  1  0.307  0.305  0.079  1.0
  V  V9  1  0.001  0.002  0.995  1.0
  V  V10  1  0.258  0.257  0.223  1.0
[/CIF]
.
The crystal structure described by Li3V2(OF)3 is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one F(1), one F(3), and two equivalent F(4) atoms to form distorted LiOF4 trigonal bipyramids that share  a cornercorner with one Li(5)F4 tetrahedra, corners with two equivalent Li(6)F4 tetrahedra, corners with two equivalent Li(1)OF4 trigonal bipyramids,  an edgeedge with one V(2)O4F trigonal bipyramid, and edges with two equivalent V(4)O4F trigonal bipyramids. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(2), one F(2), one F(4), and two equivalent F(3) atoms. In the third Li site, Li(3) is bonded to one O(3), one F(5), and two equivalent F(6) atoms to form LiOF3 tetrahedra that share  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(5)F4 tetrahedra, corners with two equivalent Li(6)F4 tetrahedra, corners with two equivalent Li(3)OF3 tetrahedra, and corners with four equivalent Li(4)OF3 tetrahedra. The corner-sharing octahedral tilt angles range from 65-67°. In the fourth Li site, Li(4) is bonded to one O(4), one F(6), and two equivalent F(5) atoms to form LiOF3 tetrahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  a cornercorner with one Li(6)F4 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(4)OF3 tetrahedra, and corners with four equivalent Li(3)OF3 tetrahedra. The corner-sharing octahedral tilt angles range from 66-67°. In the fifth Li site, Li(5) is bonded to one F(1), one F(5), and two equivalent F(2) atoms to form LiF4 tetrahedra that share  a cornercorner with one Li(3)OF3 tetrahedra, corners with two equivalent Li(5)F4 tetrahedra, corners with two equivalent Li(4)OF3 tetrahedra, corners with four equivalent Li(6)F4 tetrahedra, and  a cornercorner with one Li(1)OF4 trigonal bipyramid. In the sixth Li site, Li(6) is bonded to one F(2), one F(6), and two equivalent F(1) atoms to form LiF4 tetrahedra that share  a cornercorner with one Li(4)OF3 tetrahedra, corners with two equivalent Li(6)F4 tetrahedra, corners with two equivalent Li(3)OF3 tetrahedra, corners with four equivalent Li(5)F4 tetrahedra, and corners with two equivalent Li(1)OF4 trigonal bipyramids. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(4), one O(5), two equivalent O(3), and two equivalent O(6) atoms to form VO6 octahedra that share  a cornercorner with one Li(4)OF3 tetrahedra, corners with two equivalent Li(3)OF3 tetrahedra,  a cornercorner with one V(2)O4F trigonal bipyramid, corners with two equivalent V(4)O4F trigonal bipyramids, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent V(3)O6 octahedra. In the second V site, V(2) is bonded to one O(1), one O(5), two equivalent O(2), and one F(3) atom to form distorted VO4F trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent V(2)O4F trigonal bipyramids, corners with four equivalent V(4)O4F trigonal bipyramids, and  an edgeedge with one Li(1)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 58-59°. In the third V site, V(3) is bonded to one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms to form VO6 octahedra that share  a cornercorner with one Li(3)OF3 tetrahedra, corners with two equivalent Li(4)OF3 tetrahedra,  a cornercorner with one V(4)O4F trigonal bipyramid, corners with two equivalent V(2)O4F trigonal bipyramids, edges with two equivalent V(3)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. In the fourth V site, V(4) is bonded to one O(2), one O(6), two equivalent O(1), and one F(4) atom to form distorted VO4F trigonal bipyramids that share  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O4F trigonal bipyramids, corners with four equivalent V(2)O4F trigonal bipyramids, and edges with two equivalent Li(1)OF4 trigonal bipyramids. The corner-sharing octahedral tilt angles are 59°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one V(2), and two equivalent V(4) atoms to form distorted OLiV3 tetrahedra that share  a cornercorner with one F(1)Li4 tetrahedra, corners with two equivalent O(1)LiV3 tetrahedra, corners with four equivalent O(2)LiV3 tetrahedra,  a cornercorner with one O(5)V4 trigonal pyramid, corners with two equivalent O(6)V4 trigonal pyramids,  an edgeedge with one F(3)Li3V tetrahedra, and edges with two equivalent F(4)Li3V tetrahedra. In the second O site, O(2) is bonded to one Li(2), one V(4), and two equivalent V(2) atoms to form distorted OLiV3 tetrahedra that share  a cornercorner with one F(2)Li4 tetrahedra, corners with two equivalent O(2)LiV3 tetrahedra, corners with four equivalent O(1)LiV3 tetrahedra,  a cornercorner with one O(6)V4 trigonal pyramid, corners with two equivalent O(5)V4 trigonal pyramids,  an edgeedge with one F(4)Li3V tetrahedra, and edges with two equivalent F(3)Li3V tetrahedra. In the third O site, O(3) is bonded to one Li(3), one V(3), and two equivalent V(1) atoms to form OLiV3 tetrahedra that share  a cornercorner with one F(5)Li4 tetrahedra, corners with two equivalent O(3)LiV3 tetrahedra, corners with two equivalent F(6)Li4 tetrahedra, corners with four equivalent O(4)LiV3 tetrahedra, corners with three equivalent O(6)V4 trigonal pyramids,  an edgeedge with one O(6)V4 trigonal pyramid, and edges with two equivalent O(5)V4 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(4), one V(1), and two equivalent V(3) atoms to form OLiV3 tetrahedra that share  a cornercorner with one F(6)Li4 tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra, corners with two equivalent F(5)Li4 tetrahedra, corners with four equivalent O(3)LiV3 tetrahedra, corners with three equivalent O(5)V4 trigonal pyramids,  an edgeedge with one O(5)V4 trigonal pyramid, and edges with two equivalent O(6)V4 trigonal pyramids. In the fifth O site, O(5) is bonded to one V(1), one V(2), and two equivalent V(3) atoms to form distorted OV4 trigonal pyramids that share  a cornercorner with one O(1)LiV3 tetrahedra,  a cornercorner with one F(3)Li3V tetrahedra, corners with two equivalent O(2)LiV3 tetrahedra, corners with three equivalent O(4)LiV3 tetrahedra, corners with two equivalent O(5)V4 trigonal pyramids, corners with four equivalent O(6)V4 trigonal pyramids,  an edgeedge with one O(4)LiV3 tetrahedra, and edges with two equivalent O(3)LiV3 tetrahedra. In the sixth O site, O(6) is bonded to one V(3), one V(4), and two equivalent V(1) atoms to form distorted OV4 trigonal pyramids that share  a cornercorner with one O(2)LiV3 tetrahedra,  a cornercorner with one F(4)Li3V tetrahedra, corners with two equivalent O(1)LiV3 tetrahedra, corners with three equivalent O(3)LiV3 tetrahedra, corners with two equivalent O(6)V4 trigonal pyramids, corners with four equivalent O(5)V4 trigonal pyramids,  an edgeedge with one O(3)LiV3 tetrahedra, and edges with two equivalent O(4)LiV3 tetrahedra. There are six inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(5), and two equivalent Li(6) atoms to form FLi4 tetrahedra that share  a cornercorner with one O(1)LiV3 tetrahedra,  a cornercorner with one F(3)Li3V tetrahedra,  a cornercorner with one F(5)Li4 tetrahedra, corners with two equivalent F(4)Li3V tetrahedra, corners with two equivalent F(1)Li4 tetrahedra, corners with two equivalent F(6)Li4 tetrahedra, and corners with four equivalent F(2)Li4 tetrahedra. In the second F site, F(2) is bonded to one Li(2), one Li(6), and two equivalent Li(5) atoms to form FLi4 tetrahedra that share  a cornercorner with one O(2)LiV3 tetrahedra,  a cornercorner with one F(4)Li3V tetrahedra,  a cornercorner with one F(6)Li4 tetrahedra, corners with two equivalent F(3)Li3V tetrahedra, corners with two equivalent F(2)Li4 tetrahedra, corners with two equivalent F(5)Li4 tetrahedra, and corners with four equivalent F(1)Li4 tetrahedra. In the third F site, F(3) is bonded to one Li(1), two equivalent Li(2), and one V(2) atom to form distorted FLi3V tetrahedra that share  a cornercorner with one F(1)Li4 tetrahedra, corners with two equivalent F(3)Li3V tetrahedra, corners with two equivalent F(2)Li4 tetrahedra, corners with four equivalent F(4)Li3V tetrahedra,  a cornercorner with one O(5)V4 trigonal pyramid,  an edgeedge with one O(1)LiV3 tetrahedra, and edges with two equivalent O(2)LiV3 tetrahedra. In the fourth F site, F(4) is bonded to one Li(2), two equivalent Li(1), and one V(4) atom to form distorted FLi3V tetrahedra that share  a cornercorner with one F(2)Li4 tetrahedra, corners with two equivalent F(4)Li3V tetrahedra, corners with two equivalent F(1)Li4 tetrahedra, corners with four equivalent F(3)Li3V tetrahedra,  a cornercorner with one O(6)V4 trigonal pyramid,  an edgeedge with one O(2)LiV3 tetrahedra, and edges with two equivalent O(1)LiV3 tetrahedra. In the fifth F site, F(5) is bonded to one Li(3), one Li(5), and two equivalent Li(4) atoms to form FLi4 tetrahedra that share  a cornercorner with one O(3)LiV3 tetrahedra,  a cornercorner with one F(1)Li4 tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra, corners with two equivalent F(2)Li4 tetrahedra, corners with two equivalent F(5)Li4 tetrahedra, and corners with four equivalent F(6)Li4 tetrahedra. In the sixth F site, F(6) is bonded to one Li(4), one Li(6), and two equivalent Li(3) atoms to form FLi4 tetrahedra that share  a cornercorner with one O(4)LiV3 tetrahedra,  a cornercorner with one F(2)Li4 tetrahedra, corners with two equivalent O(3)LiV3 tetrahedra, corners with two equivalent F(1)Li4 tetrahedra, corners with two equivalent F(6)Li4 tetrahedra, and corners with four equivalent F(5)Li4 tetrahedra. is represented by the CIF file [CIF]
data_Li3V2(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.230
_cell_length_b   3.255
_cell_length_c   13.471
_cell_angle_alpha   83.394
_cell_angle_beta   83.271
_cell_angle_gamma   60.649
_symmetry_Int_Tables_number   1
_cell_volume   122.321
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.811  0.806  0.566  1.0
  F  F1  1  0.203  0.203  0.391  1.0
  F  F2  1  0.082  0.093  0.746  1.0
  Li  Li3  1  0.860  0.855  0.423  1.0
  Li  Li4  1  0.736  0.743  0.783  1.0
  Li  Li5  1  0.132  0.132  0.603  1.0
  O  O6  1  0.916  0.909  0.251  1.0
  O  O7  1  0.688  0.697  0.933  1.0
  O  O8  1  0.307  0.305  0.079  1.0
  V  V9  1  0.001  0.002  0.995  1.0
  V  V10  1  0.258  0.257  0.223  1.0
[/CIF]
.