The compound described by TiAg is beta Cu3Ti-like structured and crystallizes in the tetragonal P4/nmm space group. Ti(1) is bonded to eight equivalent Ti(1) and four equivalent Ag(1) atoms to form distorted TiTi8Ag4 cuboctahedra that share corners with four equivalent Ti(1)Ti8Ag4 cuboctahedra, corners with eight equivalent Ag(1)Ti4Ag8 cuboctahedra, edges with eight equivalent Ti(1)Ti8Ag4 cuboctahedra, edges with sixteen equivalent Ag(1)Ti4Ag8 cuboctahedra, faces with six equivalent Ag(1)Ti4Ag8 cuboctahedra, and faces with twelve equivalent Ti(1)Ti8Ag4 cuboctahedra. Ag(1) is bonded to four equivalent Ti(1) and eight equivalent Ag(1) atoms to form AgTi4Ag8 cuboctahedra that share corners with four equivalent Ag(1)Ti4Ag8 cuboctahedra, corners with eight equivalent Ti(1)Ti8Ag4 cuboctahedra, edges with eight equivalent Ag(1)Ti4Ag8 cuboctahedra, edges with sixteen equivalent Ti(1)Ti8Ag4 cuboctahedra, faces with six equivalent Ti(1)Ti8Ag4 cuboctahedra, and faces with twelve equivalent Ag(1)Ti4Ag8 cuboctahedra. is represented by the CIF card [CIF]
data_TiAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.904
_cell_length_b   2.904
_cell_length_c   8.133
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   68.576
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.750  0.750  0.883  1.0
  Ti  Ti1  1  0.250  0.250  0.117  1.0
  Ag  Ag2  1  0.750  0.750  0.373  1.0
  Ag  Ag3  1  0.250  0.250  0.627  1.0
[/CIF]
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The compound described by TiAg is beta Cu3Ti-like structured and crystallizes in the tetragonal P4/nmm space group. Ti(1) is bonded to eight equivalent Ti(1) and four equivalent Ag(1) atoms to form distorted TiTi8Ag4 cuboctahedra that share corners with four equivalent Ti(1)Ti8Ag4 cuboctahedra, corners with eight equivalent Ag(1)Ti4Ag8 cuboctahedra, edges with eight equivalent Ti(1)Ti8Ag4 cuboctahedra, edges with sixteen equivalent Ag(1)Ti4Ag8 cuboctahedra, faces with six equivalent Ag(1)Ti4Ag8 cuboctahedra, and faces with twelve equivalent Ti(1)Ti8Ag4 cuboctahedra. Ag(1) is bonded to four equivalent Ti(1) and eight equivalent Ag(1) atoms to form AgTi4Ag8 cuboctahedra that share corners with four equivalent Ag(1)Ti4Ag8 cuboctahedra, corners with eight equivalent Ti(1)Ti8Ag4 cuboctahedra, edges with eight equivalent Ag(1)Ti4Ag8 cuboctahedra, edges with sixteen equivalent Ti(1)Ti8Ag4 cuboctahedra, faces with six equivalent Ti(1)Ti8Ag4 cuboctahedra, and faces with twelve equivalent Ag(1)Ti4Ag8 cuboctahedra. is represented by the CIF card [CIF]
data_TiAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.904
_cell_length_b   2.904
_cell_length_c   8.133
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   68.576
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.750  0.750  0.883  1.0
  Ti  Ti1  1  0.250  0.250  0.117  1.0
  Ag  Ag2  1  0.750  0.750  0.373  1.0
  Ag  Ag3  1  0.250  0.250  0.627  1.0
[/CIF]
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