The crystal structure described by Ag7NO6 crystallizes in the cubic F-43m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to twelve equivalent Ag(2) atoms to form AgAg12 cuboctahedra that share corners with twelve equivalent Ag(1)Ag12 cuboctahedra, faces with four equivalent O(1)Ag6 octahedra, and faces with four equivalent O(2)Ag6 octahedra. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1), one O(1), one O(2), and two equivalent O(3) atoms. N(1) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to six equivalent Ag(2) atoms to form OAg6 octahedra that share corners with six equivalent O(2)Ag6 octahedra and faces with four equivalent Ag(1)Ag12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded to six equivalent Ag(2) atoms to form OAg6 octahedra that share corners with six equivalent O(1)Ag6 octahedra and faces with four equivalent Ag(1)Ag12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(2) and one N(1) atom. is represented by the CIF card [CIF]
data_Ag7NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.666
_cell_length_b   6.666
_cell_length_c   6.666
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   209.426
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.004  0.496  0.496  1.0
  Ag  Ag2  1  0.496  0.004  0.496  1.0
  Ag  Ag3  1  0.004  0.004  0.496  1.0
  Ag  Ag4  1  0.496  0.004  0.004  1.0
  Ag  Ag5  1  0.004  0.496  0.004  1.0
  Ag  Ag6  1  0.496  0.496  0.004  1.0
  N  N7  1  0.000  0.000  0.000  1.0
  O  O8  1  0.750  0.750  0.750  1.0
  O  O9  1  0.250  0.250  0.250  1.0
  O  O10  1  0.915  0.915  0.254  1.0
  O  O11  1  0.915  0.915  0.915  1.0
  O  O12  1  0.254  0.915  0.915  1.0
  O  O13  1  0.915  0.254  0.915  1.0
[/CIF]
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The crystal structure described by Ag7NO6 crystallizes in the cubic F-43m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to twelve equivalent Ag(2) atoms to form AgAg12 cuboctahedra that share corners with twelve equivalent Ag(1)Ag12 cuboctahedra, faces with four equivalent O(1)Ag6 octahedra, and faces with four equivalent O(2)Ag6 octahedra. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1), one O(1), one O(2), and two equivalent O(3) atoms. N(1) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to six equivalent Ag(2) atoms to form OAg6 octahedra that share corners with six equivalent O(2)Ag6 octahedra and faces with four equivalent Ag(1)Ag12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded to six equivalent Ag(2) atoms to form OAg6 octahedra that share corners with six equivalent O(1)Ag6 octahedra and faces with four equivalent Ag(1)Ag12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(2) and one N(1) atom. is represented by the CIF card [CIF]
data_Ag7NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.666
_cell_length_b   6.666
_cell_length_c   6.666
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   209.426
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.004  0.496  0.496  1.0
  Ag  Ag2  1  0.496  0.004  0.496  1.0
  Ag  Ag3  1  0.004  0.004  0.496  1.0
  Ag  Ag4  1  0.496  0.004  0.004  1.0
  Ag  Ag5  1  0.004  0.496  0.004  1.0
  Ag  Ag6  1  0.496  0.496  0.004  1.0
  N  N7  1  0.000  0.000  0.000  1.0
  O  O8  1  0.750  0.750  0.750  1.0
  O  O9  1  0.250  0.250  0.250  1.0
  O  O10  1  0.915  0.915  0.254  1.0
  O  O11  1  0.915  0.915  0.915  1.0
  O  O12  1  0.254  0.915  0.915  1.0
  O  O13  1  0.915  0.254  0.915  1.0
[/CIF]
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