The crystal structure described by K2LiGaAs2 crystallizes in the orthorhombic Cmce space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to two equivalent Ga(1), two equivalent As(2), and three equivalent As(1) atoms. In the second K site, K(2) is bonded in a 5-coordinate geometry to two equivalent As(1) and three equivalent As(2) atoms. Li(1) is bonded to two equivalent As(1) and two equivalent As(2) atoms to form distorted LiAs4 tetrahedra that share corners with two equivalent Li(1)As4 tetrahedra, corners with two equivalent Ga(1)K2As4 tetrahedra,  an edgeedge with one Li(1)As4 tetrahedra, and edges with three equivalent Ga(1)K2As4 tetrahedra. Ga(1) is bonded to two equivalent K(1), two equivalent As(1), and two equivalent As(2) atoms to form distorted GaK2As4 tetrahedra that share corners with two equivalent Li(1)As4 tetrahedra, edges with three equivalent Li(1)As4 tetrahedra, and edges with three equivalent Ga(1)K2As4 tetrahedra. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 9-coordinate geometry to two equivalent K(2), three equivalent K(1), two equivalent Li(1), and two equivalent Ga(1) atoms. In the second As site, As(2) is bonded in a 9-coordinate geometry to two equivalent K(1), three equivalent K(2), two equivalent Li(1), and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_K2LiGaAs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.008
_cell_length_b   10.008
_cell_length_c   6.285
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.049
_symmetry_Int_Tables_number   1
_cell_volume   615.637
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.078  0.422  0.750  1.0
  K  K1  1  0.671  0.329  0.780  1.0
  K  K2  1  0.329  0.671  0.220  1.0
  K  K3  1  0.578  0.922  0.750  1.0
  K  K4  1  0.422  0.078  0.250  1.0
  K  K5  1  0.922  0.578  0.250  1.0
  K  K6  1  0.829  0.171  0.280  1.0
  K  K7  1  0.171  0.829  0.720  1.0
  Li  Li8  1  0.120  0.120  0.500  1.0
  Li  Li9  1  0.880  0.880  0.500  1.0
  Li  Li10  1  0.380  0.380  0.000  1.0
  Li  Li11  1  0.620  0.620  0.000  1.0
  Ga  Ga12  1  0.868  0.868  0.000  1.0
  Ga  Ga13  1  0.368  0.368  0.500  1.0
  Ga  Ga14  1  0.632  0.632  0.500  1.0
  Ga  Ga15  1  0.132  0.132  0.000  1.0
  As  As16  1  0.843  0.657  0.750  1.0
  As  As17  1  0.093  0.907  0.213  1.0
  As  As18  1  0.407  0.593  0.713  1.0
  As  As19  1  0.593  0.407  0.287  1.0
  As  As20  1  0.657  0.843  0.250  1.0
  As  As21  1  0.157  0.343  0.250  1.0
  As  As22  1  0.343  0.157  0.750  1.0
  As  As23  1  0.907  0.093  0.787  1.0
[/CIF]
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The crystal structure described by K2LiGaAs2 crystallizes in the orthorhombic Cmce space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to two equivalent Ga(1), two equivalent As(2), and three equivalent As(1) atoms. In the second K site, K(2) is bonded in a 5-coordinate geometry to two equivalent As(1) and three equivalent As(2) atoms. Li(1) is bonded to two equivalent As(1) and two equivalent As(2) atoms to form distorted LiAs4 tetrahedra that share corners with two equivalent Li(1)As4 tetrahedra, corners with two equivalent Ga(1)K2As4 tetrahedra,  an edgeedge with one Li(1)As4 tetrahedra, and edges with three equivalent Ga(1)K2As4 tetrahedra. Ga(1) is bonded to two equivalent K(1), two equivalent As(1), and two equivalent As(2) atoms to form distorted GaK2As4 tetrahedra that share corners with two equivalent Li(1)As4 tetrahedra, edges with three equivalent Li(1)As4 tetrahedra, and edges with three equivalent Ga(1)K2As4 tetrahedra. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 9-coordinate geometry to two equivalent K(2), three equivalent K(1), two equivalent Li(1), and two equivalent Ga(1) atoms. In the second As site, As(2) is bonded in a 9-coordinate geometry to two equivalent K(1), three equivalent K(2), two equivalent Li(1), and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_K2LiGaAs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.008
_cell_length_b   10.008
_cell_length_c   6.285
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.049
_symmetry_Int_Tables_number   1
_cell_volume   615.637
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.078  0.422  0.750  1.0
  K  K1  1  0.671  0.329  0.780  1.0
  K  K2  1  0.329  0.671  0.220  1.0
  K  K3  1  0.578  0.922  0.750  1.0
  K  K4  1  0.422  0.078  0.250  1.0
  K  K5  1  0.922  0.578  0.250  1.0
  K  K6  1  0.829  0.171  0.280  1.0
  K  K7  1  0.171  0.829  0.720  1.0
  Li  Li8  1  0.120  0.120  0.500  1.0
  Li  Li9  1  0.880  0.880  0.500  1.0
  Li  Li10  1  0.380  0.380  0.000  1.0
  Li  Li11  1  0.620  0.620  0.000  1.0
  Ga  Ga12  1  0.868  0.868  0.000  1.0
  Ga  Ga13  1  0.368  0.368  0.500  1.0
  Ga  Ga14  1  0.632  0.632  0.500  1.0
  Ga  Ga15  1  0.132  0.132  0.000  1.0
  As  As16  1  0.843  0.657  0.750  1.0
  As  As17  1  0.093  0.907  0.213  1.0
  As  As18  1  0.407  0.593  0.713  1.0
  As  As19  1  0.593  0.407  0.287  1.0
  As  As20  1  0.657  0.843  0.250  1.0
  As  As21  1  0.157  0.343  0.250  1.0
  As  As22  1  0.343  0.157  0.750  1.0
  As  As23  1  0.907  0.093  0.787  1.0
[/CIF]
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