The crystal structure described by Ag3Sn2(GeP2)3 crystallizes in the cubic I-43m space group. Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Sn(1) and two equivalent P(1) atoms. Sn(1) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent P(1) atoms. Ge(1) is bonded to four equivalent P(1) atoms to form corner-sharing GeP4 tetrahedra. P(1) is bonded to one Ag(1), one Sn(1), and two equivalent Ge(1) atoms to form corner-sharing PAgSnGe2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3Sn2(GeP2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.203
_cell_length_b   9.203
_cell_length_c   9.203
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   599.975
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.196  0.196  0.000  1.0
  Ag  Ag1  1  0.804  0.804  0.000  1.0
  Ag  Ag2  1  0.000  0.196  0.196  1.0
  Ag  Ag3  1  0.000  0.804  0.804  1.0
  Ag  Ag4  1  0.804  0.000  0.804  1.0
  Ag  Ag5  1  0.196  0.000  0.196  1.0
  Sn  Sn6  1  0.412  0.412  0.412  1.0
  Sn  Sn7  1  0.588  0.000  0.000  1.0
  Sn  Sn8  1  0.000  0.000  0.588  1.0
  Sn  Sn9  1  0.000  0.588  0.000  1.0
  Ge  Ge10  1  0.250  0.750  0.500  1.0
  Ge  Ge11  1  0.750  0.250  0.500  1.0
  Ge  Ge12  1  0.750  0.500  0.250  1.0
  Ge  Ge13  1  0.500  0.750  0.250  1.0
  Ge  Ge14  1  0.250  0.500  0.750  1.0
  Ge  Ge15  1  0.500  0.250  0.750  1.0
  P  P16  1  0.509  0.509  0.749  1.0
  P  P17  1  0.000  0.491  0.240  1.0
  P  P18  1  0.491  0.000  0.240  1.0
  P  P19  1  0.509  0.749  0.509  1.0
  P  P20  1  0.240  0.491  0.000  1.0
  P  P21  1  0.491  0.240  0.000  1.0
  P  P22  1  0.760  0.760  0.251  1.0
  P  P23  1  0.760  0.251  0.760  1.0
  P  P24  1  0.749  0.509  0.509  1.0
  P  P25  1  0.240  0.000  0.491  1.0
  P  P26  1  0.000  0.240  0.491  1.0
  P  P27  1  0.251  0.760  0.760  1.0
[/CIF]
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The crystal structure described by Ag3Sn2(GeP2)3 crystallizes in the cubic I-43m space group. Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Sn(1) and two equivalent P(1) atoms. Sn(1) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent P(1) atoms. Ge(1) is bonded to four equivalent P(1) atoms to form corner-sharing GeP4 tetrahedra. P(1) is bonded to one Ag(1), one Sn(1), and two equivalent Ge(1) atoms to form corner-sharing PAgSnGe2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3Sn2(GeP2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.203
_cell_length_b   9.203
_cell_length_c   9.203
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   599.975
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.196  0.196  0.000  1.0
  Ag  Ag1  1  0.804  0.804  0.000  1.0
  Ag  Ag2  1  0.000  0.196  0.196  1.0
  Ag  Ag3  1  0.000  0.804  0.804  1.0
  Ag  Ag4  1  0.804  0.000  0.804  1.0
  Ag  Ag5  1  0.196  0.000  0.196  1.0
  Sn  Sn6  1  0.412  0.412  0.412  1.0
  Sn  Sn7  1  0.588  0.000  0.000  1.0
  Sn  Sn8  1  0.000  0.000  0.588  1.0
  Sn  Sn9  1  0.000  0.588  0.000  1.0
  Ge  Ge10  1  0.250  0.750  0.500  1.0
  Ge  Ge11  1  0.750  0.250  0.500  1.0
  Ge  Ge12  1  0.750  0.500  0.250  1.0
  Ge  Ge13  1  0.500  0.750  0.250  1.0
  Ge  Ge14  1  0.250  0.500  0.750  1.0
  Ge  Ge15  1  0.500  0.250  0.750  1.0
  P  P16  1  0.509  0.509  0.749  1.0
  P  P17  1  0.000  0.491  0.240  1.0
  P  P18  1  0.491  0.000  0.240  1.0
  P  P19  1  0.509  0.749  0.509  1.0
  P  P20  1  0.240  0.491  0.000  1.0
  P  P21  1  0.491  0.240  0.000  1.0
  P  P22  1  0.760  0.760  0.251  1.0
  P  P23  1  0.760  0.251  0.760  1.0
  P  P24  1  0.749  0.509  0.509  1.0
  P  P25  1  0.240  0.000  0.491  1.0
  P  P26  1  0.000  0.240  0.491  1.0
  P  P27  1  0.251  0.760  0.760  1.0
[/CIF]
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