The structure described by KBiS(O2Cl)2 crystallizes in the orthorhombic P2_12_12_1 space group. K(1) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(3), two equivalent Cl(1), and two equivalent Cl(2) atoms. Bi(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), one Cl(1), and one Cl(2) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Bi(1), and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one S(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Bi(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1), one Bi(1), and one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to two equivalent K(1) and one Bi(1) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KBiS(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.433
_cell_length_b   7.502
_cell_length_c   15.559
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   750.907
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.029  0.798  0.156  1.0
  K  K1  1  0.529  0.702  0.844  1.0
  K  K2  1  0.971  0.298  0.344  1.0
  K  K3  1  0.471  0.202  0.656  1.0
  Bi  Bi4  1  0.486  0.364  0.117  1.0
  Bi  Bi5  1  0.986  0.136  0.883  1.0
  Bi  Bi6  1  0.514  0.864  0.383  1.0
  Bi  Bi7  1  0.014  0.636  0.617  1.0
  S  S8  1  0.006  0.816  0.388  1.0
  S  S9  1  0.506  0.684  0.612  1.0
  S  S10  1  0.994  0.316  0.112  1.0
  S  S11  1  0.494  0.184  0.888  1.0
  Cl  Cl12  1  0.398  0.506  0.266  1.0
  Cl  Cl13  1  0.898  0.994  0.734  1.0
  Cl  Cl14  1  0.602  0.006  0.234  1.0
  Cl  Cl15  1  0.102  0.494  0.766  1.0
  Cl  Cl16  1  0.570  0.665  0.052  1.0
  Cl  Cl17  1  0.070  0.835  0.948  1.0
  Cl  Cl18  1  0.430  0.165  0.448  1.0
  Cl  Cl19  1  0.930  0.335  0.552  1.0
  O  O20  1  0.619  0.328  0.849  1.0
  O  O21  1  0.119  0.172  0.151  1.0
  O  O22  1  0.381  0.828  0.651  1.0
  O  O23  1  0.881  0.672  0.349  1.0
  O  O24  1  0.369  0.247  0.963  1.0
  O  O25  1  0.869  0.253  0.037  1.0
  O  O26  1  0.631  0.747  0.537  1.0
  O  O27  1  0.131  0.753  0.463  1.0
  O  O28  1  0.343  0.106  0.824  1.0
  O  O29  1  0.843  0.394  0.176  1.0
  O  O30  1  0.657  0.606  0.676  1.0
  O  O31  1  0.157  0.894  0.324  1.0
  O  O32  1  0.642  0.038  0.915  1.0
  O  O33  1  0.142  0.462  0.085  1.0
  O  O34  1  0.358  0.538  0.585  1.0
  O  O35  1  0.858  0.962  0.415  1.0
[/CIF]
.
The structure described by KBiS(O2Cl)2 crystallizes in the orthorhombic P2_12_12_1 space group. K(1) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(3), two equivalent Cl(1), and two equivalent Cl(2) atoms. Bi(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), one Cl(1), and one Cl(2) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Bi(1), and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one S(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Bi(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1), one Bi(1), and one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to two equivalent K(1) and one Bi(1) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KBiS(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.433
_cell_length_b   7.502
_cell_length_c   15.559
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   750.907
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.029  0.798  0.156  1.0
  K  K1  1  0.529  0.702  0.844  1.0
  K  K2  1  0.971  0.298  0.344  1.0
  K  K3  1  0.471  0.202  0.656  1.0
  Bi  Bi4  1  0.486  0.364  0.117  1.0
  Bi  Bi5  1  0.986  0.136  0.883  1.0
  Bi  Bi6  1  0.514  0.864  0.383  1.0
  Bi  Bi7  1  0.014  0.636  0.617  1.0
  S  S8  1  0.006  0.816  0.388  1.0
  S  S9  1  0.506  0.684  0.612  1.0
  S  S10  1  0.994  0.316  0.112  1.0
  S  S11  1  0.494  0.184  0.888  1.0
  Cl  Cl12  1  0.398  0.506  0.266  1.0
  Cl  Cl13  1  0.898  0.994  0.734  1.0
  Cl  Cl14  1  0.602  0.006  0.234  1.0
  Cl  Cl15  1  0.102  0.494  0.766  1.0
  Cl  Cl16  1  0.570  0.665  0.052  1.0
  Cl  Cl17  1  0.070  0.835  0.948  1.0
  Cl  Cl18  1  0.430  0.165  0.448  1.0
  Cl  Cl19  1  0.930  0.335  0.552  1.0
  O  O20  1  0.619  0.328  0.849  1.0
  O  O21  1  0.119  0.172  0.151  1.0
  O  O22  1  0.381  0.828  0.651  1.0
  O  O23  1  0.881  0.672  0.349  1.0
  O  O24  1  0.369  0.247  0.963  1.0
  O  O25  1  0.869  0.253  0.037  1.0
  O  O26  1  0.631  0.747  0.537  1.0
  O  O27  1  0.131  0.753  0.463  1.0
  O  O28  1  0.343  0.106  0.824  1.0
  O  O29  1  0.843  0.394  0.176  1.0
  O  O30  1  0.657  0.606  0.676  1.0
  O  O31  1  0.157  0.894  0.324  1.0
  O  O32  1  0.642  0.038  0.915  1.0
  O  O33  1  0.142  0.462  0.085  1.0
  O  O34  1  0.358  0.538  0.585  1.0
  O  O35  1  0.858  0.962  0.415  1.0
[/CIF]
.