The material structure described by CsN3S2O4 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 11-coordinate geometry to one N(3), three equivalent N(2), one O(3), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one N(2) and one N(3) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one N(1) atom. In the third N site, N(3) is bonded in a distorted tetrahedral geometry to one Cs(1), one N(1), one S(1), and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted bent 120 degrees geometry to one N(3), one O(1), and one O(3) atom. In the second S site, S(2) is bonded in a distorted bent 120 degrees geometry to one N(3), one O(2), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cs(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsS2N3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.762
_cell_length_b   8.507
_cell_length_c   9.362
_cell_angle_alpha   70.314
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   807.068
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.077  0.899  0.796  1.0
  Cs  Cs1  1  0.577  0.601  0.204  1.0
  Cs  Cs2  1  0.923  0.101  0.204  1.0
  Cs  Cs3  1  0.423  0.399  0.796  1.0
  S  S4  1  0.735  0.733  0.549  1.0
  S  S5  1  0.235  0.767  0.451  1.0
  S  S6  1  0.506  0.066  0.275  1.0
  S  S7  1  0.006  0.434  0.725  1.0
  S  S8  1  0.265  0.267  0.451  1.0
  S  S9  1  0.994  0.566  0.275  1.0
  S  S10  1  0.765  0.233  0.549  1.0
  S  S11  1  0.494  0.934  0.725  1.0
  N  N12  1  0.282  0.979  0.136  1.0
  N  N13  1  0.281  0.572  0.046  1.0
  N  N14  1  0.218  0.479  0.136  1.0
  N  N15  1  0.150  0.386  0.231  1.0
  N  N16  1  0.650  0.114  0.769  1.0
  N  N17  1  0.719  0.428  0.954  1.0
  N  N18  1  0.782  0.521  0.864  1.0
  N  N19  1  0.219  0.072  0.046  1.0
  N  N20  1  0.850  0.614  0.769  1.0
  N  N21  1  0.718  0.021  0.864  1.0
  N  N22  1  0.350  0.886  0.231  1.0
  N  N23  1  0.781  0.928  0.954  1.0
  O  O24  1  0.644  0.599  0.564  1.0
  O  O25  1  0.114  0.512  0.769  1.0
  O  O26  1  0.356  0.401  0.436  1.0
  O  O27  1  0.666  0.244  0.439  1.0
  O  O28  1  0.964  0.277  0.837  1.0
  O  O29  1  0.144  0.901  0.436  1.0
  O  O30  1  0.834  0.744  0.439  1.0
  O  O31  1  0.886  0.488  0.231  1.0
  O  O32  1  0.464  0.223  0.163  1.0
  O  O33  1  0.856  0.099  0.564  1.0
  O  O34  1  0.334  0.756  0.561  1.0
  O  O35  1  0.166  0.256  0.561  1.0
  O  O36  1  0.036  0.723  0.163  1.0
  O  O37  1  0.386  0.012  0.769  1.0
  O  O38  1  0.536  0.777  0.837  1.0
  O  O39  1  0.614  0.988  0.231  1.0
[/CIF]
.
The material structure described by CsN3S2O4 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 11-coordinate geometry to one N(3), three equivalent N(2), one O(3), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one N(2) and one N(3) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one N(1) atom. In the third N site, N(3) is bonded in a distorted tetrahedral geometry to one Cs(1), one N(1), one S(1), and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted bent 120 degrees geometry to one N(3), one O(1), and one O(3) atom. In the second S site, S(2) is bonded in a distorted bent 120 degrees geometry to one N(3), one O(2), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cs(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsS2N3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.762
_cell_length_b   8.507
_cell_length_c   9.362
_cell_angle_alpha   70.314
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   807.068
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.077  0.899  0.796  1.0
  Cs  Cs1  1  0.577  0.601  0.204  1.0
  Cs  Cs2  1  0.923  0.101  0.204  1.0
  Cs  Cs3  1  0.423  0.399  0.796  1.0
  S  S4  1  0.735  0.733  0.549  1.0
  S  S5  1  0.235  0.767  0.451  1.0
  S  S6  1  0.506  0.066  0.275  1.0
  S  S7  1  0.006  0.434  0.725  1.0
  S  S8  1  0.265  0.267  0.451  1.0
  S  S9  1  0.994  0.566  0.275  1.0
  S  S10  1  0.765  0.233  0.549  1.0
  S  S11  1  0.494  0.934  0.725  1.0
  N  N12  1  0.282  0.979  0.136  1.0
  N  N13  1  0.281  0.572  0.046  1.0
  N  N14  1  0.218  0.479  0.136  1.0
  N  N15  1  0.150  0.386  0.231  1.0
  N  N16  1  0.650  0.114  0.769  1.0
  N  N17  1  0.719  0.428  0.954  1.0
  N  N18  1  0.782  0.521  0.864  1.0
  N  N19  1  0.219  0.072  0.046  1.0
  N  N20  1  0.850  0.614  0.769  1.0
  N  N21  1  0.718  0.021  0.864  1.0
  N  N22  1  0.350  0.886  0.231  1.0
  N  N23  1  0.781  0.928  0.954  1.0
  O  O24  1  0.644  0.599  0.564  1.0
  O  O25  1  0.114  0.512  0.769  1.0
  O  O26  1  0.356  0.401  0.436  1.0
  O  O27  1  0.666  0.244  0.439  1.0
  O  O28  1  0.964  0.277  0.837  1.0
  O  O29  1  0.144  0.901  0.436  1.0
  O  O30  1  0.834  0.744  0.439  1.0
  O  O31  1  0.886  0.488  0.231  1.0
  O  O32  1  0.464  0.223  0.163  1.0
  O  O33  1  0.856  0.099  0.564  1.0
  O  O34  1  0.334  0.756  0.561  1.0
  O  O35  1  0.166  0.256  0.561  1.0
  O  O36  1  0.036  0.723  0.163  1.0
  O  O37  1  0.386  0.012  0.769  1.0
  O  O38  1  0.536  0.777  0.837  1.0
  O  O39  1  0.614  0.988  0.231  1.0
[/CIF]
.