The crystal structure described by OsO4FN(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Aem2 space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four OsO4F clusters. In each OsO4F cluster, Os(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), two equivalent O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. F(1) is bonded in a single-bond geometry to one Os(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H12OsC4NO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.452
_cell_length_b   8.452
_cell_length_c   7.572
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   93.061
_symmetry_Int_Tables_number   1
_cell_volume   540.138
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.009  0.093  0.312  1.0
  H  H1  1  0.093  0.009  0.688  1.0
  H  H2  1  0.509  0.593  0.688  1.0
  H  H3  1  0.593  0.509  0.312  1.0
  H  H4  1  0.927  0.175  0.509  1.0
  H  H5  1  0.175  0.927  0.491  1.0
  H  H6  1  0.427  0.675  0.491  1.0
  H  H7  1  0.675  0.427  0.509  1.0
  H  H8  1  0.799  0.082  0.345  1.0
  H  H9  1  0.082  0.799  0.655  1.0
  H  H10  1  0.299  0.582  0.655  1.0
  H  H11  1  0.582  0.299  0.345  1.0
  H  H12  1  0.002  0.806  0.271  1.0
  H  H13  1  0.806  0.002  0.729  1.0
  H  H14  1  0.502  0.306  0.729  1.0
  H  H15  1  0.306  0.502  0.271  1.0
  H  H16  1  0.792  0.800  0.300  1.0
  H  H17  1  0.800  0.792  0.700  1.0
  H  H18  1  0.292  0.300  0.700  1.0
  H  H19  1  0.300  0.292  0.300  1.0
  H  H20  1  0.913  0.679  0.438  1.0
  H  H21  1  0.679  0.913  0.562  1.0
  H  H22  1  0.413  0.179  0.562  1.0
  H  H23  1  0.179  0.413  0.438  1.0
  Os  Os24  1  0.948  0.448  0.942  1.0
  Os  Os25  1  0.448  0.948  0.058  1.0
  C  C26  1  0.914  0.081  0.410  1.0
  C  C27  1  0.081  0.914  0.590  1.0
  C  C28  1  0.414  0.581  0.590  1.0
  C  C29  1  0.581  0.414  0.410  1.0
  C  C30  1  0.906  0.791  0.367  1.0
  C  C31  1  0.791  0.906  0.633  1.0
  C  C32  1  0.406  0.291  0.633  1.0
  C  C33  1  0.291  0.406  0.367  1.0
  N  N34  1  0.923  0.923  0.500  1.0
  N  N35  1  0.423  0.423  0.500  1.0
  O  O36  1  0.960  0.460  0.172  1.0
  O  O37  1  0.460  0.960  0.828  1.0
  O  O38  1  0.799  0.299  0.917  1.0
  O  O39  1  0.299  0.799  0.083  1.0
  O  O40  1  0.894  0.641  0.899  1.0
  O  O41  1  0.641  0.894  0.101  1.0
  O  O42  1  0.394  0.141  0.101  1.0
  O  O43  1  0.141  0.394  0.899  1.0
  F  F44  1  0.944  0.444  0.659  1.0
  F  F45  1  0.444  0.944  0.341  1.0
[/CIF]
.
The crystal structure described by OsO4FN(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Aem2 space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four OsO4F clusters. In each OsO4F cluster, Os(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), two equivalent O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. F(1) is bonded in a single-bond geometry to one Os(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H12OsC4NO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.452
_cell_length_b   8.452
_cell_length_c   7.572
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   93.061
_symmetry_Int_Tables_number   1
_cell_volume   540.138
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.009  0.093  0.312  1.0
  H  H1  1  0.093  0.009  0.688  1.0
  H  H2  1  0.509  0.593  0.688  1.0
  H  H3  1  0.593  0.509  0.312  1.0
  H  H4  1  0.927  0.175  0.509  1.0
  H  H5  1  0.175  0.927  0.491  1.0
  H  H6  1  0.427  0.675  0.491  1.0
  H  H7  1  0.675  0.427  0.509  1.0
  H  H8  1  0.799  0.082  0.345  1.0
  H  H9  1  0.082  0.799  0.655  1.0
  H  H10  1  0.299  0.582  0.655  1.0
  H  H11  1  0.582  0.299  0.345  1.0
  H  H12  1  0.002  0.806  0.271  1.0
  H  H13  1  0.806  0.002  0.729  1.0
  H  H14  1  0.502  0.306  0.729  1.0
  H  H15  1  0.306  0.502  0.271  1.0
  H  H16  1  0.792  0.800  0.300  1.0
  H  H17  1  0.800  0.792  0.700  1.0
  H  H18  1  0.292  0.300  0.700  1.0
  H  H19  1  0.300  0.292  0.300  1.0
  H  H20  1  0.913  0.679  0.438  1.0
  H  H21  1  0.679  0.913  0.562  1.0
  H  H22  1  0.413  0.179  0.562  1.0
  H  H23  1  0.179  0.413  0.438  1.0
  Os  Os24  1  0.948  0.448  0.942  1.0
  Os  Os25  1  0.448  0.948  0.058  1.0
  C  C26  1  0.914  0.081  0.410  1.0
  C  C27  1  0.081  0.914  0.590  1.0
  C  C28  1  0.414  0.581  0.590  1.0
  C  C29  1  0.581  0.414  0.410  1.0
  C  C30  1  0.906  0.791  0.367  1.0
  C  C31  1  0.791  0.906  0.633  1.0
  C  C32  1  0.406  0.291  0.633  1.0
  C  C33  1  0.291  0.406  0.367  1.0
  N  N34  1  0.923  0.923  0.500  1.0
  N  N35  1  0.423  0.423  0.500  1.0
  O  O36  1  0.960  0.460  0.172  1.0
  O  O37  1  0.460  0.960  0.828  1.0
  O  O38  1  0.799  0.299  0.917  1.0
  O  O39  1  0.299  0.799  0.083  1.0
  O  O40  1  0.894  0.641  0.899  1.0
  O  O41  1  0.641  0.894  0.101  1.0
  O  O42  1  0.394  0.141  0.101  1.0
  O  O43  1  0.141  0.394  0.899  1.0
  F  F44  1  0.944  0.444  0.659  1.0
  F  F45  1  0.444  0.944  0.341  1.0
[/CIF]
.