The crystal structure described by K2SnHOF6 crystallizes in the orthorhombic Fdd2 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one F(3), one F(4), two equivalent F(1), two equivalent F(2), two equivalent F(5), and two equivalent F(6) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms. In the third K site, K(3) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent F(2), two equivalent F(4), and two equivalent F(5) atoms. Sn(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a single-bond geometry to one K(2), one K(3), and one H(1) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a 3-coordinate geometry to one K(3), two equivalent K(1), and one Sn(1) atom. In the second F site, F(6) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Sn(1) atom. In the third F site, F(1) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Sn(1) atom. In the fourth F site, F(2) is bonded in a 4-coordinate geometry to one K(3), two equivalent K(1), and one Sn(1) atom. In the fifth F site, F(3) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one Sn(1) atom. In the sixth F site, F(4) is bonded in a distorted T-shaped geometry to one K(1), one K(3), and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2SnHOF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.374
_cell_length_b   10.929
_cell_length_c   9.347
_cell_angle_alpha   67.725
_cell_angle_beta   62.767
_cell_angle_gamma   49.508
_symmetry_Int_Tables_number   1
_cell_volume   779.881
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.499  0.748  1.0
  K  K1  1  0.503  0.748  0.499  1.0
  K  K2  1  0.751  0.000  0.747  1.0
  K  K3  1  0.502  0.747  0.000  1.0
  K  K4  1  0.655  0.345  0.345  1.0
  K  K5  1  0.093  0.907  0.907  1.0
  K  K6  1  0.343  0.157  0.157  1.0
  K  K7  1  0.905  0.595  0.595  1.0
  Sn  Sn8  1  0.590  0.405  0.844  1.0
  Sn  Sn9  1  0.160  0.844  0.405  1.0
  Sn  Sn10  1  0.406  0.090  0.660  1.0
  Sn  Sn11  1  0.845  0.660  0.090  1.0
  H  H12  1  0.752  0.146  0.113  1.0
  H  H13  1  0.989  0.113  0.146  1.0
  H  H14  1  0.137  0.261  0.498  1.0
  H  H15  1  0.104  0.498  0.261  1.0
  O  O16  1  0.836  0.082  0.169  1.0
  O  O17  1  0.914  0.169  0.082  1.0
  O  O18  1  0.168  0.414  0.336  1.0
  O  O19  1  0.081  0.336  0.414  1.0
  F  F20  1  0.673  0.544  0.752  1.0
  F  F21  1  0.031  0.752  0.544  1.0
  F  F22  1  0.492  0.282  0.922  1.0
  F  F23  1  0.304  0.922  0.282  1.0
  F  F24  1  0.328  0.946  0.758  1.0
  F  F25  1  0.968  0.758  0.946  1.0
  F  F26  1  0.498  0.219  0.577  1.0
  F  F27  1  0.706  0.577  0.219  1.0
  F  F28  1  0.572  0.409  0.066  1.0
  F  F29  1  0.953  0.066  0.409  1.0
  F  F30  1  0.804  0.188  0.828  1.0
  F  F31  1  0.180  0.828  0.188  1.0
  F  F32  1  0.422  0.070  0.446  1.0
  F  F33  1  0.062  0.446  0.070  1.0
  F  F34  1  0.184  0.297  0.678  1.0
  F  F35  1  0.841  0.678  0.297  1.0
  F  F36  1  0.366  0.610  0.860  1.0
  F  F37  1  0.164  0.860  0.610  1.0
  F  F38  1  0.605  0.415  0.618  1.0
  F  F39  1  0.362  0.618  0.415  1.0
  F  F40  1  0.632  0.888  0.645  1.0
  F  F41  1  0.835  0.645  0.888  1.0
  F  F42  1  0.390  0.086  0.884  1.0
  F  F43  1  0.640  0.884  0.086  1.0
[/CIF]
.
The crystal structure described by K2SnHOF6 crystallizes in the orthorhombic Fdd2 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one F(3), one F(4), two equivalent F(1), two equivalent F(2), two equivalent F(5), and two equivalent F(6) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms. In the third K site, K(3) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent F(2), two equivalent F(4), and two equivalent F(5) atoms. Sn(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a single-bond geometry to one K(2), one K(3), and one H(1) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a 3-coordinate geometry to one K(3), two equivalent K(1), and one Sn(1) atom. In the second F site, F(6) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Sn(1) atom. In the third F site, F(1) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Sn(1) atom. In the fourth F site, F(2) is bonded in a 4-coordinate geometry to one K(3), two equivalent K(1), and one Sn(1) atom. In the fifth F site, F(3) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one Sn(1) atom. In the sixth F site, F(4) is bonded in a distorted T-shaped geometry to one K(1), one K(3), and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2SnHOF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.374
_cell_length_b   10.929
_cell_length_c   9.347
_cell_angle_alpha   67.725
_cell_angle_beta   62.767
_cell_angle_gamma   49.508
_symmetry_Int_Tables_number   1
_cell_volume   779.881
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.499  0.748  1.0
  K  K1  1  0.503  0.748  0.499  1.0
  K  K2  1  0.751  0.000  0.747  1.0
  K  K3  1  0.502  0.747  0.000  1.0
  K  K4  1  0.655  0.345  0.345  1.0
  K  K5  1  0.093  0.907  0.907  1.0
  K  K6  1  0.343  0.157  0.157  1.0
  K  K7  1  0.905  0.595  0.595  1.0
  Sn  Sn8  1  0.590  0.405  0.844  1.0
  Sn  Sn9  1  0.160  0.844  0.405  1.0
  Sn  Sn10  1  0.406  0.090  0.660  1.0
  Sn  Sn11  1  0.845  0.660  0.090  1.0
  H  H12  1  0.752  0.146  0.113  1.0
  H  H13  1  0.989  0.113  0.146  1.0
  H  H14  1  0.137  0.261  0.498  1.0
  H  H15  1  0.104  0.498  0.261  1.0
  O  O16  1  0.836  0.082  0.169  1.0
  O  O17  1  0.914  0.169  0.082  1.0
  O  O18  1  0.168  0.414  0.336  1.0
  O  O19  1  0.081  0.336  0.414  1.0
  F  F20  1  0.673  0.544  0.752  1.0
  F  F21  1  0.031  0.752  0.544  1.0
  F  F22  1  0.492  0.282  0.922  1.0
  F  F23  1  0.304  0.922  0.282  1.0
  F  F24  1  0.328  0.946  0.758  1.0
  F  F25  1  0.968  0.758  0.946  1.0
  F  F26  1  0.498  0.219  0.577  1.0
  F  F27  1  0.706  0.577  0.219  1.0
  F  F28  1  0.572  0.409  0.066  1.0
  F  F29  1  0.953  0.066  0.409  1.0
  F  F30  1  0.804  0.188  0.828  1.0
  F  F31  1  0.180  0.828  0.188  1.0
  F  F32  1  0.422  0.070  0.446  1.0
  F  F33  1  0.062  0.446  0.070  1.0
  F  F34  1  0.184  0.297  0.678  1.0
  F  F35  1  0.841  0.678  0.297  1.0
  F  F36  1  0.366  0.610  0.860  1.0
  F  F37  1  0.164  0.860  0.610  1.0
  F  F38  1  0.605  0.415  0.618  1.0
  F  F39  1  0.362  0.618  0.415  1.0
  F  F40  1  0.632  0.888  0.645  1.0
  F  F41  1  0.835  0.645  0.888  1.0
  F  F42  1  0.390  0.086  0.884  1.0
  F  F43  1  0.640  0.884  0.086  1.0
[/CIF]
.