The material described by LiCoSiO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Co(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. Co(1) is bonded to four equivalent O(1) atoms to form CoO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. Si(1) is bonded to four equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Co(1)O4 tetrahedra. O(1) is bonded in a trigonal planar geometry to one Li(1), one Co(1), and one Si(1) atom. is represented by the CIF card [CIF]
data_LiCoSiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.485
_cell_length_b   4.486
_cell_length_c   5.322
_cell_angle_alpha   65.076
_cell_angle_beta   65.078
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   85.988
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.750  0.250  0.500  1.0
  Li  Li1  1  0.500  0.500  1.000  1.0
  O  O2  1  0.076  0.137  0.215  1.0
  O  O3  1  0.352  0.924  0.785  1.0
  O  O4  1  0.709  0.648  0.215  1.0
  O  O5  1  0.863  0.292  0.785  1.0
  Si  Si6  1  1.000  1.000  0.000  1.0
[/CIF]
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The material described by LiCoSiO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Co(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. Co(1) is bonded to four equivalent O(1) atoms to form CoO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. Si(1) is bonded to four equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Co(1)O4 tetrahedra. O(1) is bonded in a trigonal planar geometry to one Li(1), one Co(1), and one Si(1) atom. is represented by the CIF card [CIF]
data_LiCoSiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.485
_cell_length_b   4.486
_cell_length_c   5.322
_cell_angle_alpha   65.076
_cell_angle_beta   65.078
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   85.988
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.750  0.250  0.500  1.0
  Li  Li1  1  0.500  0.500  1.000  1.0
  O  O2  1  0.076  0.137  0.215  1.0
  O  O3  1  0.352  0.924  0.785  1.0
  O  O4  1  0.709  0.648  0.215  1.0
  O  O5  1  0.863  0.292  0.785  1.0
  Si  Si6  1  1.000  1.000  0.000  1.0
[/CIF]
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