The material structure described by RuN3OCl2NOCl is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four nitrosyl chloride molecules and four RuN3OCl2 clusters. In each RuN3OCl2 cluster, Ru(1) is bonded in a tetrahedral geometry to one N(2), one N(3), one N(4), and one O(2) atom. There are three inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one Ru(1) and one Cl(1) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Ru(1) atom. In the third N site, N(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one Cl(2) atom. O(2) is bonded in a single-bond geometry to one Ru(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one N(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF card [CIF]
data_RuN4Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.424
_cell_length_b   9.506
_cell_length_c   13.953
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   984.620
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.325  0.082  0.342  1.0
  Ru  Ru1  1  0.675  0.582  0.658  1.0
  Ru  Ru2  1  0.825  0.582  0.158  1.0
  Ru  Ru3  1  0.175  0.082  0.842  1.0
  N  N4  1  0.949  0.145  0.476  1.0
  N  N5  1  0.051  0.645  0.524  1.0
  N  N6  1  0.449  0.645  0.024  1.0
  N  N7  1  0.551  0.145  0.976  1.0
  N  N8  1  0.354  0.221  0.440  1.0
  N  N9  1  0.646  0.721  0.560  1.0
  N  N10  1  0.854  0.721  0.060  1.0
  N  N11  1  0.146  0.221  0.940  1.0
  N  N12  1  0.338  0.922  0.391  1.0
  N  N13  1  0.662  0.422  0.609  1.0
  N  N14  1  0.838  0.422  0.109  1.0
  N  N15  1  0.162  0.922  0.891  1.0
  N  N16  1  0.094  0.097  0.284  1.0
  N  N17  1  0.906  0.597  0.716  1.0
  N  N18  1  0.594  0.597  0.216  1.0
  N  N19  1  0.406  0.097  0.784  1.0
  Cl  Cl20  1  0.388  0.185  0.554  1.0
  Cl  Cl21  1  0.612  0.685  0.446  1.0
  Cl  Cl22  1  0.888  0.685  0.946  1.0
  Cl  Cl23  1  0.112  0.185  0.054  1.0
  Cl  Cl24  1  0.934  0.982  0.299  1.0
  Cl  Cl25  1  0.066  0.482  0.701  1.0
  Cl  Cl26  1  0.434  0.482  0.201  1.0
  Cl  Cl27  1  0.566  0.982  0.799  1.0
  Cl  Cl28  1  0.880  0.319  0.396  1.0
  Cl  Cl29  1  0.120  0.819  0.604  1.0
  Cl  Cl30  1  0.380  0.819  0.104  1.0
  Cl  Cl31  1  0.620  0.319  0.896  1.0
  O  O32  1  0.888  0.141  0.552  1.0
  O  O33  1  0.112  0.641  0.448  1.0
  O  O34  1  0.388  0.641  0.948  1.0
  O  O35  1  0.612  0.141  0.052  1.0
  O  O36  1  0.487  0.114  0.254  1.0
  O  O37  1  0.513  0.614  0.746  1.0
  O  O38  1  0.987  0.614  0.246  1.0
  O  O39  1  0.013  0.114  0.754  1.0
[/CIF]
.
The material structure described by RuN3OCl2NOCl is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four nitrosyl chloride molecules and four RuN3OCl2 clusters. In each RuN3OCl2 cluster, Ru(1) is bonded in a tetrahedral geometry to one N(2), one N(3), one N(4), and one O(2) atom. There are three inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one Ru(1) and one Cl(1) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Ru(1) atom. In the third N site, N(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one Cl(2) atom. O(2) is bonded in a single-bond geometry to one Ru(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one N(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF card [CIF]
data_RuN4Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.424
_cell_length_b   9.506
_cell_length_c   13.953
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   984.620
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.325  0.082  0.342  1.0
  Ru  Ru1  1  0.675  0.582  0.658  1.0
  Ru  Ru2  1  0.825  0.582  0.158  1.0
  Ru  Ru3  1  0.175  0.082  0.842  1.0
  N  N4  1  0.949  0.145  0.476  1.0
  N  N5  1  0.051  0.645  0.524  1.0
  N  N6  1  0.449  0.645  0.024  1.0
  N  N7  1  0.551  0.145  0.976  1.0
  N  N8  1  0.354  0.221  0.440  1.0
  N  N9  1  0.646  0.721  0.560  1.0
  N  N10  1  0.854  0.721  0.060  1.0
  N  N11  1  0.146  0.221  0.940  1.0
  N  N12  1  0.338  0.922  0.391  1.0
  N  N13  1  0.662  0.422  0.609  1.0
  N  N14  1  0.838  0.422  0.109  1.0
  N  N15  1  0.162  0.922  0.891  1.0
  N  N16  1  0.094  0.097  0.284  1.0
  N  N17  1  0.906  0.597  0.716  1.0
  N  N18  1  0.594  0.597  0.216  1.0
  N  N19  1  0.406  0.097  0.784  1.0
  Cl  Cl20  1  0.388  0.185  0.554  1.0
  Cl  Cl21  1  0.612  0.685  0.446  1.0
  Cl  Cl22  1  0.888  0.685  0.946  1.0
  Cl  Cl23  1  0.112  0.185  0.054  1.0
  Cl  Cl24  1  0.934  0.982  0.299  1.0
  Cl  Cl25  1  0.066  0.482  0.701  1.0
  Cl  Cl26  1  0.434  0.482  0.201  1.0
  Cl  Cl27  1  0.566  0.982  0.799  1.0
  Cl  Cl28  1  0.880  0.319  0.396  1.0
  Cl  Cl29  1  0.120  0.819  0.604  1.0
  Cl  Cl30  1  0.380  0.819  0.104  1.0
  Cl  Cl31  1  0.620  0.319  0.896  1.0
  O  O32  1  0.888  0.141  0.552  1.0
  O  O33  1  0.112  0.641  0.448  1.0
  O  O34  1  0.388  0.641  0.948  1.0
  O  O35  1  0.612  0.141  0.052  1.0
  O  O36  1  0.487  0.114  0.254  1.0
  O  O37  1  0.513  0.614  0.746  1.0
  O  O38  1  0.987  0.614  0.246  1.0
  O  O39  1  0.013  0.114  0.754  1.0
[/CIF]
.