The structure described by TbSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted corner and edge-sharing TbS4Br3 pentagonal bipyramids. S(1) is bonded to four equivalent Tb(1) atoms to form a mixture of corner and edge-sharing STb4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Tb(1) atoms. is represented by the CIF file [CIF]
data_TbSBr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.888
_cell_length_b   6.811
_cell_length_c   6.800
_cell_angle_alpha   80.404
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   314.581
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.964  0.792  0.321  1.0
  Tb  Tb1  1  0.036  0.208  0.679  1.0
  Tb  Tb2  1  0.464  0.708  0.679  1.0
  Tb  Tb3  1  0.536  0.292  0.321  1.0
  S  S4  1  0.740  0.992  0.555  1.0
  S  S5  1  0.260  0.008  0.445  1.0
  S  S6  1  0.240  0.508  0.445  1.0
  S  S7  1  0.760  0.492  0.555  1.0
  Br  Br8  1  0.624  0.705  0.080  1.0
  Br  Br9  1  0.376  0.295  0.920  1.0
  Br  Br10  1  0.124  0.795  0.920  1.0
  Br  Br11  1  0.876  0.205  0.080  1.0
[/CIF]
.
The structure described by TbSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted corner and edge-sharing TbS4Br3 pentagonal bipyramids. S(1) is bonded to four equivalent Tb(1) atoms to form a mixture of corner and edge-sharing STb4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Tb(1) atoms. is represented by the CIF file [CIF]
data_TbSBr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.888
_cell_length_b   6.811
_cell_length_c   6.800
_cell_angle_alpha   80.404
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   314.581
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.964  0.792  0.321  1.0
  Tb  Tb1  1  0.036  0.208  0.679  1.0
  Tb  Tb2  1  0.464  0.708  0.679  1.0
  Tb  Tb3  1  0.536  0.292  0.321  1.0
  S  S4  1  0.740  0.992  0.555  1.0
  S  S5  1  0.260  0.008  0.445  1.0
  S  S6  1  0.240  0.508  0.445  1.0
  S  S7  1  0.760  0.492  0.555  1.0
  Br  Br8  1  0.624  0.705  0.080  1.0
  Br  Br9  1  0.376  0.295  0.920  1.0
  Br  Br10  1  0.124  0.795  0.920  1.0
  Br  Br11  1  0.876  0.205  0.080  1.0
[/CIF]
.