The compound described by Hg11P4(GaCl4)4 crystallizes in the monoclinic C2/m space group. The structure consists of eight GaCl4 clusters inside a Hg11P4 framework. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(4), one Cl(6), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. In the Hg11P4 framework, there are five inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a linear geometry to one Hg(1) and one P(1) atom. In the second Hg site, Hg(2) is bonded in a linear geometry to one Hg(3) and one P(2) atom. In the third Hg site, Hg(3) is bonded in a linear geometry to two equivalent Hg(2) atoms. In the fourth Hg site, Hg(4) is bonded in a linear geometry to one P(1) and one P(2) atom. In the fifth Hg site, Hg(5) is bonded in a linear geometry to one P(1) and one P(2) atom. There are two inequivalent P sites. In the first P site, P(2) is bonded to one Hg(2), one Hg(4), and two equivalent Hg(5) atoms to form corner-sharing PHg4 tetrahedra. In the second P site, P(1) is bonded to one Hg(1), one Hg(4), and two equivalent Hg(5) atoms to form corner-sharing PHg4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga4Hg11(PCl4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.663
_cell_length_b   7.663
_cell_length_c   22.576
_cell_angle_alpha   80.725
_cell_angle_beta   80.725
_cell_angle_gamma   59.942
_symmetry_Int_Tables_number   1
_cell_volume   1127.424
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.631  0.631  0.613  1.0
  Ga  Ga1  1  0.369  0.369  0.387  1.0
  Ga  Ga2  1  0.212  0.212  0.885  1.0
  Ga  Ga3  1  0.788  0.788  0.115  1.0
  Hg  Hg4  1  0.522  0.522  0.940  1.0
  Hg  Hg5  1  0.478  0.478  0.060  1.0
  Hg  Hg6  1  0.961  0.961  0.620  1.0
  Hg  Hg7  1  0.039  0.039  0.380  1.0
  Hg  Hg8  1  0.000  0.000  0.500  1.0
  Hg  Hg9  1  0.744  0.744  0.781  1.0
  Hg  Hg10  1  0.256  0.256  0.219  1.0
  Hg  Hg11  1  0.244  0.744  0.780  1.0
  Hg  Hg12  1  0.744  0.244  0.780  1.0
  Hg  Hg13  1  0.756  0.256  0.220  1.0
  Hg  Hg14  1  0.256  0.756  0.220  1.0
  P  P15  1  0.563  0.563  0.826  1.0
  P  P16  1  0.437  0.437  0.174  1.0
  P  P17  1  0.925  0.925  0.735  1.0
  P  P18  1  0.075  0.075  0.265  1.0
  Cl  Cl19  1  0.243  0.243  0.785  1.0
  Cl  Cl20  1  0.757  0.757  0.215  1.0
  Cl  Cl21  1  0.044  0.044  0.915  1.0
  Cl  Cl22  1  0.956  0.956  0.085  1.0
  Cl  Cl23  1  0.464  0.928  0.652  1.0
  Cl  Cl24  1  0.928  0.464  0.652  1.0
  Cl  Cl25  1  0.536  0.072  0.348  1.0
  Cl  Cl26  1  0.072  0.536  0.348  1.0
  Cl  Cl27  1  0.464  0.464  0.652  1.0
  Cl  Cl28  1  0.536  0.536  0.348  1.0
  Cl  Cl29  1  0.044  0.519  0.914  1.0
  Cl  Cl30  1  0.519  0.044  0.914  1.0
  Cl  Cl31  1  0.956  0.481  0.086  1.0
  Cl  Cl32  1  0.481  0.956  0.086  1.0
  Cl  Cl33  1  0.661  0.661  0.516  1.0
  Cl  Cl34  1  0.339  0.339  0.484  1.0
[/CIF]
.
The compound described by Hg11P4(GaCl4)4 crystallizes in the monoclinic C2/m space group. The structure consists of eight GaCl4 clusters inside a Hg11P4 framework. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(4), one Cl(6), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. In the Hg11P4 framework, there are five inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a linear geometry to one Hg(1) and one P(1) atom. In the second Hg site, Hg(2) is bonded in a linear geometry to one Hg(3) and one P(2) atom. In the third Hg site, Hg(3) is bonded in a linear geometry to two equivalent Hg(2) atoms. In the fourth Hg site, Hg(4) is bonded in a linear geometry to one P(1) and one P(2) atom. In the fifth Hg site, Hg(5) is bonded in a linear geometry to one P(1) and one P(2) atom. There are two inequivalent P sites. In the first P site, P(2) is bonded to one Hg(2), one Hg(4), and two equivalent Hg(5) atoms to form corner-sharing PHg4 tetrahedra. In the second P site, P(1) is bonded to one Hg(1), one Hg(4), and two equivalent Hg(5) atoms to form corner-sharing PHg4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga4Hg11(PCl4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.663
_cell_length_b   7.663
_cell_length_c   22.576
_cell_angle_alpha   80.725
_cell_angle_beta   80.725
_cell_angle_gamma   59.942
_symmetry_Int_Tables_number   1
_cell_volume   1127.424
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.631  0.631  0.613  1.0
  Ga  Ga1  1  0.369  0.369  0.387  1.0
  Ga  Ga2  1  0.212  0.212  0.885  1.0
  Ga  Ga3  1  0.788  0.788  0.115  1.0
  Hg  Hg4  1  0.522  0.522  0.940  1.0
  Hg  Hg5  1  0.478  0.478  0.060  1.0
  Hg  Hg6  1  0.961  0.961  0.620  1.0
  Hg  Hg7  1  0.039  0.039  0.380  1.0
  Hg  Hg8  1  0.000  0.000  0.500  1.0
  Hg  Hg9  1  0.744  0.744  0.781  1.0
  Hg  Hg10  1  0.256  0.256  0.219  1.0
  Hg  Hg11  1  0.244  0.744  0.780  1.0
  Hg  Hg12  1  0.744  0.244  0.780  1.0
  Hg  Hg13  1  0.756  0.256  0.220  1.0
  Hg  Hg14  1  0.256  0.756  0.220  1.0
  P  P15  1  0.563  0.563  0.826  1.0
  P  P16  1  0.437  0.437  0.174  1.0
  P  P17  1  0.925  0.925  0.735  1.0
  P  P18  1  0.075  0.075  0.265  1.0
  Cl  Cl19  1  0.243  0.243  0.785  1.0
  Cl  Cl20  1  0.757  0.757  0.215  1.0
  Cl  Cl21  1  0.044  0.044  0.915  1.0
  Cl  Cl22  1  0.956  0.956  0.085  1.0
  Cl  Cl23  1  0.464  0.928  0.652  1.0
  Cl  Cl24  1  0.928  0.464  0.652  1.0
  Cl  Cl25  1  0.536  0.072  0.348  1.0
  Cl  Cl26  1  0.072  0.536  0.348  1.0
  Cl  Cl27  1  0.464  0.464  0.652  1.0
  Cl  Cl28  1  0.536  0.536  0.348  1.0
  Cl  Cl29  1  0.044  0.519  0.914  1.0
  Cl  Cl30  1  0.519  0.044  0.914  1.0
  Cl  Cl31  1  0.956  0.481  0.086  1.0
  Cl  Cl32  1  0.481  0.956  0.086  1.0
  Cl  Cl33  1  0.661  0.661  0.516  1.0
  Cl  Cl34  1  0.339  0.339  0.484  1.0
[/CIF]
.