The structure described by ZrVMo crystallizes in the orthorhombic Imma space group. Zr(1) is bonded in a 12-coordinate geometry to six equivalent V(1) and six equivalent Mo(1) atoms. V(1) is bonded to six equivalent Zr(1), two equivalent V(1), and four equivalent Mo(1) atoms to form distorted VZr6V2Mo4 cuboctahedra that share corners with eight equivalent Mo(1)Zr6V4Mo2 cuboctahedra, corners with ten equivalent V(1)Zr6V2Mo4 cuboctahedra, edges with six equivalent V(1)Zr6V2Mo4 cuboctahedra, faces with six equivalent V(1)Zr6V2Mo4 cuboctahedra, and faces with twelve equivalent Mo(1)Zr6V4Mo2 cuboctahedra. Mo(1) is bonded to six equivalent Zr(1), four equivalent V(1), and two equivalent Mo(1) atoms to form distorted MoZr6V4Mo2 cuboctahedra that share corners with eight equivalent V(1)Zr6V2Mo4 cuboctahedra, corners with ten equivalent Mo(1)Zr6V4Mo2 cuboctahedra, edges with six equivalent Mo(1)Zr6V4Mo2 cuboctahedra, faces with six equivalent Mo(1)Zr6V4Mo2 cuboctahedra, and faces with twelve equivalent V(1)Zr6V2Mo4 cuboctahedra. is represented by the CIF file [CIF]
data_ZrVMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.276
_cell_length_b   5.276
_cell_length_c   5.276
_cell_angle_alpha   120.526
_cell_angle_beta   119.032
_cell_angle_gamma   90.388
_symmetry_Int_Tables_number   1
_cell_volume   104.164
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.375  0.125  0.250  1.0
  Zr  Zr1  1  0.625  0.875  0.750  1.0
  V  V2  1  0.500  0.500  0.000  1.0
  V  V3  1  0.000  0.500  0.500  1.0
  Mo  Mo4  1  0.000  0.500  0.000  1.0
  Mo  Mo5  1  0.000  0.000  0.500  1.0
[/CIF]
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The structure described by ZrVMo crystallizes in the orthorhombic Imma space group. Zr(1) is bonded in a 12-coordinate geometry to six equivalent V(1) and six equivalent Mo(1) atoms. V(1) is bonded to six equivalent Zr(1), two equivalent V(1), and four equivalent Mo(1) atoms to form distorted VZr6V2Mo4 cuboctahedra that share corners with eight equivalent Mo(1)Zr6V4Mo2 cuboctahedra, corners with ten equivalent V(1)Zr6V2Mo4 cuboctahedra, edges with six equivalent V(1)Zr6V2Mo4 cuboctahedra, faces with six equivalent V(1)Zr6V2Mo4 cuboctahedra, and faces with twelve equivalent Mo(1)Zr6V4Mo2 cuboctahedra. Mo(1) is bonded to six equivalent Zr(1), four equivalent V(1), and two equivalent Mo(1) atoms to form distorted MoZr6V4Mo2 cuboctahedra that share corners with eight equivalent V(1)Zr6V2Mo4 cuboctahedra, corners with ten equivalent Mo(1)Zr6V4Mo2 cuboctahedra, edges with six equivalent Mo(1)Zr6V4Mo2 cuboctahedra, faces with six equivalent Mo(1)Zr6V4Mo2 cuboctahedra, and faces with twelve equivalent V(1)Zr6V2Mo4 cuboctahedra. is represented by the CIF file [CIF]
data_ZrVMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.276
_cell_length_b   5.276
_cell_length_c   5.276
_cell_angle_alpha   120.526
_cell_angle_beta   119.032
_cell_angle_gamma   90.388
_symmetry_Int_Tables_number   1
_cell_volume   104.164
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.375  0.125  0.250  1.0
  Zr  Zr1  1  0.625  0.875  0.750  1.0
  V  V2  1  0.500  0.500  0.000  1.0
  V  V3  1  0.000  0.500  0.500  1.0
  Mo  Mo4  1  0.000  0.500  0.000  1.0
  Mo  Mo5  1  0.000  0.000  0.500  1.0
[/CIF]
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