The crystal structure described by NaSbCl6 crystallizes in the tetragonal P4_2/m space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent Cl(1) and four equivalent Cl(2) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1) and four equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a water-like geometry to one Na(1) and one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Sb(1) atom. is represented by the CIF file [CIF]
data_NaSbCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.412
_cell_length_b   6.412
_cell_length_c   10.681
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   439.165
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.750  1.0
  Na  Na1  1  0.000  0.000  0.250  1.0
  Sb  Sb2  1  0.500  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  Cl  Cl4  1  0.786  0.194  0.000  1.0
  Cl  Cl5  1  0.806  0.786  0.500  1.0
  Cl  Cl6  1  0.194  0.214  0.500  1.0
  Cl  Cl7  1  0.214  0.806  0.000  1.0
  Cl  Cl8  1  0.217  0.349  0.158  1.0
  Cl  Cl9  1  0.651  0.217  0.658  1.0
  Cl  Cl10  1  0.349  0.783  0.658  1.0
  Cl  Cl11  1  0.783  0.651  0.158  1.0
  Cl  Cl12  1  0.783  0.651  0.842  1.0
  Cl  Cl13  1  0.349  0.783  0.342  1.0
  Cl  Cl14  1  0.651  0.217  0.342  1.0
  Cl  Cl15  1  0.217  0.349  0.842  1.0
[/CIF]
.
The crystal structure described by NaSbCl6 crystallizes in the tetragonal P4_2/m space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent Cl(1) and four equivalent Cl(2) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1) and four equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a water-like geometry to one Na(1) and one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Sb(1) atom. is represented by the CIF file [CIF]
data_NaSbCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.412
_cell_length_b   6.412
_cell_length_c   10.681
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   439.165
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.750  1.0
  Na  Na1  1  0.000  0.000  0.250  1.0
  Sb  Sb2  1  0.500  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  Cl  Cl4  1  0.786  0.194  0.000  1.0
  Cl  Cl5  1  0.806  0.786  0.500  1.0
  Cl  Cl6  1  0.194  0.214  0.500  1.0
  Cl  Cl7  1  0.214  0.806  0.000  1.0
  Cl  Cl8  1  0.217  0.349  0.158  1.0
  Cl  Cl9  1  0.651  0.217  0.658  1.0
  Cl  Cl10  1  0.349  0.783  0.658  1.0
  Cl  Cl11  1  0.783  0.651  0.158  1.0
  Cl  Cl12  1  0.783  0.651  0.842  1.0
  Cl  Cl13  1  0.349  0.783  0.342  1.0
  Cl  Cl14  1  0.651  0.217  0.342  1.0
  Cl  Cl15  1  0.217  0.349  0.842  1.0
[/CIF]
.