The structure described by LiFePbO3 crystallizes in the trigonal R3m space group. Li(1) is bonded in a 3-coordinate geometry to one Pb(1) and three equivalent O(1) atoms. Fe(1) is bonded to six equivalent O(1) atoms to form distorted corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles are 1°. Pb(1) is bonded in a 4-coordinate geometry to one Li(1) and three equivalent O(1) atoms. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Fe(1), and one Pb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiFePbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.214
_cell_length_b   4.214
_cell_length_c   4.219
_cell_angle_alpha   95.383
_cell_angle_beta   84.616
_cell_angle_gamma   95.329
_symmetry_Int_Tables_number   1
_cell_volume   74.004
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.233  0.767  0.236  1.0
  Fe  Fe1  1  0.531  0.469  0.534  1.0
  Pb  Pb2  1  0.906  0.094  0.908  1.0
  O  O3  1  0.527  0.473  0.029  1.0
  O  O4  1  0.527  0.974  0.530  1.0
  O  O5  1  0.026  0.473  0.530  1.0
[/CIF]
.
The structure described by LiFePbO3 crystallizes in the trigonal R3m space group. Li(1) is bonded in a 3-coordinate geometry to one Pb(1) and three equivalent O(1) atoms. Fe(1) is bonded to six equivalent O(1) atoms to form distorted corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles are 1°. Pb(1) is bonded in a 4-coordinate geometry to one Li(1) and three equivalent O(1) atoms. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Fe(1), and one Pb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiFePbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.214
_cell_length_b   4.214
_cell_length_c   4.219
_cell_angle_alpha   95.383
_cell_angle_beta   84.616
_cell_angle_gamma   95.329
_symmetry_Int_Tables_number   1
_cell_volume   74.004
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.233  0.767  0.236  1.0
  Fe  Fe1  1  0.531  0.469  0.534  1.0
  Pb  Pb2  1  0.906  0.094  0.908  1.0
  O  O3  1  0.527  0.473  0.029  1.0
  O  O4  1  0.527  0.974  0.530  1.0
  O  O5  1  0.026  0.473  0.530  1.0
[/CIF]
.