The structure described by WAgZn2O6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with eight equivalent Zn(1)O4 tetrahedra. Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-67°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Ag(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Ag(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Ag(1), and two equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_Zn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.227
_cell_length_b   5.295
_cell_length_c   9.921
_cell_angle_alpha   60.763
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   239.623
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.483  0.217  0.759  1.0
  Zn  Zn1  1  0.983  0.783  0.741  1.0
  Zn  Zn2  1  0.517  0.783  0.241  1.0
  Zn  Zn3  1  0.017  0.217  0.259  1.0
  Ag  Ag4  1  0.500  0.000  0.500  1.0
  Ag  Ag5  1  0.000  0.000  0.000  1.0
  W  W6  1  0.500  0.500  0.000  1.0
  W  W7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.190  0.468  0.902  1.0
  O  O9  1  0.690  0.532  0.598  1.0
  O  O10  1  0.810  0.532  0.098  1.0
  O  O11  1  0.310  0.468  0.402  1.0
  O  O12  1  0.345  0.763  0.060  1.0
  O  O13  1  0.845  0.237  0.440  1.0
  O  O14  1  0.655  0.237  0.940  1.0
  O  O15  1  0.155  0.763  0.560  1.0
  O  O16  1  0.125  0.172  0.698  1.0
  O  O17  1  0.625  0.828  0.802  1.0
  O  O18  1  0.375  0.172  0.198  1.0
  O  O19  1  0.875  0.828  0.302  1.0
[/CIF]
.
The structure described by WAgZn2O6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with eight equivalent Zn(1)O4 tetrahedra. Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-67°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Ag(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Ag(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Ag(1), and two equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_Zn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.227
_cell_length_b   5.295
_cell_length_c   9.921
_cell_angle_alpha   60.763
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   239.623
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.483  0.217  0.759  1.0
  Zn  Zn1  1  0.983  0.783  0.741  1.0
  Zn  Zn2  1  0.517  0.783  0.241  1.0
  Zn  Zn3  1  0.017  0.217  0.259  1.0
  Ag  Ag4  1  0.500  0.000  0.500  1.0
  Ag  Ag5  1  0.000  0.000  0.000  1.0
  W  W6  1  0.500  0.500  0.000  1.0
  W  W7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.190  0.468  0.902  1.0
  O  O9  1  0.690  0.532  0.598  1.0
  O  O10  1  0.810  0.532  0.098  1.0
  O  O11  1  0.310  0.468  0.402  1.0
  O  O12  1  0.345  0.763  0.060  1.0
  O  O13  1  0.845  0.237  0.440  1.0
  O  O14  1  0.655  0.237  0.940  1.0
  O  O15  1  0.155  0.763  0.560  1.0
  O  O16  1  0.125  0.172  0.698  1.0
  O  O17  1  0.625  0.828  0.802  1.0
  O  O18  1  0.375  0.172  0.198  1.0
  O  O19  1  0.875  0.828  0.302  1.0
[/CIF]
.