The crystal structure described by MgMn2Te2(MoO6)2 crystallizes in the orthorhombic Cmm2 space group. Mg(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms to form MgO6 octahedra that share  an edgeedge with one Mo(2)O6 octahedra and  an edgeedge with one Te(1)O6 octahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted MoO6 octahedra that share corners with four equivalent Mo(2)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-55°. In the second Mo site, Mo(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form distorted MoO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles are 26°. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TeO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra, and  an edgeedge with one Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Te(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mo(1), two equivalent Mn(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mg(1), one Mo(2), and one Te(2) atom. In the fifth O site, O(5) is bonded to one Mg(1), two equivalent Mn(1), and one Te(1) atom to form a mixture of corner and edge-sharing OMgMn2Te tetrahedra. In the sixth O site, O(6) is bonded to one Mg(1), two equivalent Mn(1), and one Te(2) atom to form a mixture of distorted corner and edge-sharing OMgMn2Te trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgMn2Te2(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.122
_cell_length_b   5.122
_cell_length_c   9.323
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.261
_symmetry_Int_Tables_number   1
_cell_volume   244.569
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.500  0.097  1.0
  Mn  Mn1  1  0.000  0.000  0.952  1.0
  Mn  Mn2  1  0.500  0.500  0.952  1.0
  Te  Te3  1  0.000  0.500  0.735  1.0
  Te  Te4  1  0.500  0.000  0.237  1.0
  Mo  Mo5  1  0.500  0.000  0.616  1.0
  Mo  Mo6  1  0.000  0.500  0.405  1.0
  O  O7  1  0.249  0.749  0.568  1.0
  O  O8  1  0.250  0.250  0.453  1.0
  O  O9  1  0.751  0.251  0.568  1.0
  O  O10  1  0.750  0.750  0.453  1.0
  O  O11  1  0.297  0.203  0.766  1.0
  O  O12  1  0.194  0.694  0.247  1.0
  O  O13  1  0.703  0.797  0.766  1.0
  O  O14  1  0.806  0.306  0.247  1.0
  O  O15  1  0.830  0.330  0.905  1.0
  O  O16  1  0.696  0.804  0.089  1.0
  O  O17  1  0.170  0.670  0.905  1.0
  O  O18  1  0.304  0.196  0.089  1.0
[/CIF]
.
The crystal structure described by MgMn2Te2(MoO6)2 crystallizes in the orthorhombic Cmm2 space group. Mg(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms to form MgO6 octahedra that share  an edgeedge with one Mo(2)O6 octahedra and  an edgeedge with one Te(1)O6 octahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted MoO6 octahedra that share corners with four equivalent Mo(2)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-55°. In the second Mo site, Mo(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form distorted MoO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles are 26°. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TeO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra, and  an edgeedge with one Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Te(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mo(1), two equivalent Mn(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mg(1), one Mo(2), and one Te(2) atom. In the fifth O site, O(5) is bonded to one Mg(1), two equivalent Mn(1), and one Te(1) atom to form a mixture of corner and edge-sharing OMgMn2Te tetrahedra. In the sixth O site, O(6) is bonded to one Mg(1), two equivalent Mn(1), and one Te(2) atom to form a mixture of distorted corner and edge-sharing OMgMn2Te trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgMn2Te2(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.122
_cell_length_b   5.122
_cell_length_c   9.323
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.261
_symmetry_Int_Tables_number   1
_cell_volume   244.569
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.500  0.097  1.0
  Mn  Mn1  1  0.000  0.000  0.952  1.0
  Mn  Mn2  1  0.500  0.500  0.952  1.0
  Te  Te3  1  0.000  0.500  0.735  1.0
  Te  Te4  1  0.500  0.000  0.237  1.0
  Mo  Mo5  1  0.500  0.000  0.616  1.0
  Mo  Mo6  1  0.000  0.500  0.405  1.0
  O  O7  1  0.249  0.749  0.568  1.0
  O  O8  1  0.250  0.250  0.453  1.0
  O  O9  1  0.751  0.251  0.568  1.0
  O  O10  1  0.750  0.750  0.453  1.0
  O  O11  1  0.297  0.203  0.766  1.0
  O  O12  1  0.194  0.694  0.247  1.0
  O  O13  1  0.703  0.797  0.766  1.0
  O  O14  1  0.806  0.306  0.247  1.0
  O  O15  1  0.830  0.330  0.905  1.0
  O  O16  1  0.696  0.804  0.089  1.0
  O  O17  1  0.170  0.670  0.905  1.0
  O  O18  1  0.304  0.196  0.089  1.0
[/CIF]
.