The crystal structure described by NaInSn4 crystallizes in the tetragonal I422 space group. Na(1) is bonded in a distorted q6 geometry to two equivalent In(1) and eight equivalent Sn(1) atoms. In(1) is bonded in a 10-coordinate geometry to two equivalent Na(1) and eight equivalent Sn(1) atoms. Sn(1) is bonded in a 5-coordinate geometry to two equivalent Na(1), two equivalent In(1), and one Sn(1) atom. is represented by the CIF file [CIF]
data_NaInSn4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.061
_cell_length_b   6.061
_cell_length_c   6.061
_cell_angle_alpha   104.922
_cell_angle_beta   104.922
_cell_angle_gamma   119.012
_symmetry_Int_Tables_number   1
_cell_volume   167.814
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.000  1.0
  In  In1  1  0.000  0.000  0.000  1.0
  Sn  Sn2  1  0.601  0.101  0.202  1.0
  Sn  Sn3  1  0.899  0.399  0.798  1.0
  Sn  Sn4  1  0.399  0.601  0.500  1.0
  Sn  Sn5  1  0.101  0.899  0.500  1.0
[/CIF]
.
The crystal structure described by NaInSn4 crystallizes in the tetragonal I422 space group. Na(1) is bonded in a distorted q6 geometry to two equivalent In(1) and eight equivalent Sn(1) atoms. In(1) is bonded in a 10-coordinate geometry to two equivalent Na(1) and eight equivalent Sn(1) atoms. Sn(1) is bonded in a 5-coordinate geometry to two equivalent Na(1), two equivalent In(1), and one Sn(1) atom. is represented by the CIF file [CIF]
data_NaInSn4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.061
_cell_length_b   6.061
_cell_length_c   6.061
_cell_angle_alpha   104.922
_cell_angle_beta   104.922
_cell_angle_gamma   119.012
_symmetry_Int_Tables_number   1
_cell_volume   167.814
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.000  1.0
  In  In1  1  0.000  0.000  0.000  1.0
  Sn  Sn2  1  0.601  0.101  0.202  1.0
  Sn  Sn3  1  0.899  0.399  0.798  1.0
  Sn  Sn4  1  0.399  0.601  0.500  1.0
  Sn  Sn5  1  0.101  0.899  0.500  1.0
[/CIF]
.