The material described by K2PdH4(N2O5)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pd(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pd(1), one O(3), and one O(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one K(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to two equivalent K(1), one H(1), and one H(2) atom. is represented by the CIF file [CIF]
data_K2H4Pd(N2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.968
_cell_length_b   7.225
_cell_length_c   7.497
_cell_angle_alpha   116.749
_cell_angle_beta   104.817
_cell_angle_gamma   97.849
_symmetry_Int_Tables_number   1
_cell_volume   311.716
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.680  0.732  0.361  1.0
  K  K1  1  0.320  0.268  0.639  1.0
  H  H2  1  0.181  0.793  0.633  1.0
  H  H3  1  0.819  0.207  0.367  1.0
  H  H4  1  0.159  0.745  0.404  1.0
  H  H5  1  0.841  0.255  0.596  1.0
  Pd  Pd6  1  0.000  0.000  0.000  1.0
  N  N7  1  0.750  0.118  0.953  1.0
  N  N8  1  0.250  0.882  0.047  1.0
  N  N9  1  0.803  0.696  0.868  1.0
  N  N10  1  0.197  0.304  0.132  1.0
  O  O11  1  0.704  0.235  0.108  1.0
  O  O12  1  0.296  0.765  0.891  1.0
  O  O13  1  0.650  0.074  0.768  1.0
  O  O14  1  0.350  0.926  0.232  1.0
  O  O15  1  0.712  0.585  0.670  1.0
  O  O16  1  0.288  0.415  0.330  1.0
  O  O17  1  0.776  0.622  0.984  1.0
  O  O18  1  0.224  0.378  0.016  1.0
  O  O19  1  0.118  0.829  0.524  1.0
  O  O20  1  0.882  0.171  0.476  1.0
[/CIF]
.
The material described by K2PdH4(N2O5)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pd(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pd(1), one O(3), and one O(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one K(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to two equivalent K(1), one H(1), and one H(2) atom. is represented by the CIF file [CIF]
data_K2H4Pd(N2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.968
_cell_length_b   7.225
_cell_length_c   7.497
_cell_angle_alpha   116.749
_cell_angle_beta   104.817
_cell_angle_gamma   97.849
_symmetry_Int_Tables_number   1
_cell_volume   311.716
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.680  0.732  0.361  1.0
  K  K1  1  0.320  0.268  0.639  1.0
  H  H2  1  0.181  0.793  0.633  1.0
  H  H3  1  0.819  0.207  0.367  1.0
  H  H4  1  0.159  0.745  0.404  1.0
  H  H5  1  0.841  0.255  0.596  1.0
  Pd  Pd6  1  0.000  0.000  0.000  1.0
  N  N7  1  0.750  0.118  0.953  1.0
  N  N8  1  0.250  0.882  0.047  1.0
  N  N9  1  0.803  0.696  0.868  1.0
  N  N10  1  0.197  0.304  0.132  1.0
  O  O11  1  0.704  0.235  0.108  1.0
  O  O12  1  0.296  0.765  0.891  1.0
  O  O13  1  0.650  0.074  0.768  1.0
  O  O14  1  0.350  0.926  0.232  1.0
  O  O15  1  0.712  0.585  0.670  1.0
  O  O16  1  0.288  0.415  0.330  1.0
  O  O17  1  0.776  0.622  0.984  1.0
  O  O18  1  0.224  0.378  0.016  1.0
  O  O19  1  0.118  0.829  0.524  1.0
  O  O20  1  0.882  0.171  0.476  1.0
[/CIF]
.