The structure described by (CoAl2P3O14)2N2 crystallizes in the monoclinic C2/c space group. The structure consists of four ammonia atoms inside a CoAl2P3O14 framework. In the CoAl2P3O14 framework, Co(1) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(7) atoms to form distorted CoO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent Al(1)O5 trigonal bipyramids, and  an edgeedge with one P(2)O4 tetrahedra. Al(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form AlO5 trigonal bipyramids that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with three equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and corners with three equivalent Al(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 47°. In the second P site, P(2) is bonded to two equivalent O(4) and two equivalent O(5) atoms to form PO4 tetrahedra that share corners with four equivalent Al(1)O5 trigonal bipyramids and  an edgeedge with one Co(1)O6 octahedra. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Al(1) and one P(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Al(1) and one P(1) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to one Co(1), one Al(1), and one P(2) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Al(1) and one P(2) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(1) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Co(1) atom. In the seventh O site, O(1) is bonded in a bent 150 degrees geometry to one Al(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Al2CoP3NO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.332
_cell_length_b   8.332
_cell_length_c   8.935
_cell_angle_alpha   74.739
_cell_angle_beta   74.739
_cell_angle_gamma   76.862
_symmetry_Int_Tables_number   1
_cell_volume   568.920
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.247  0.401  0.575  1.0
  Al  Al1  1  0.599  0.753  0.925  1.0
  Al  Al2  1  0.753  0.599  0.425  1.0
  Al  Al3  1  0.401  0.247  0.075  1.0
  Co  Co4  1  0.215  0.785  0.750  1.0
  Co  Co5  1  0.785  0.215  0.250  1.0
  P  P6  1  0.340  0.081  0.832  1.0
  P  P7  1  0.919  0.660  0.668  1.0
  P  P8  1  0.660  0.919  0.168  1.0
  P  P9  1  0.081  0.340  0.332  1.0
  P  P10  1  0.491  0.509  0.750  1.0
  P  P11  1  0.509  0.491  0.250  1.0
  N  N12  1  0.139  0.861  0.250  1.0
  N  N13  1  0.861  0.139  0.750  1.0
  O  O14  1  0.362  0.211  0.673  1.0
  O  O15  1  0.789  0.638  0.827  1.0
  O  O16  1  0.638  0.789  0.327  1.0
  O  O17  1  0.211  0.362  0.173  1.0
  O  O18  1  0.508  0.962  0.841  1.0
  O  O19  1  0.038  0.492  0.659  1.0
  O  O20  1  0.492  0.038  0.159  1.0
  O  O21  1  0.962  0.508  0.341  1.0
  O  O22  1  0.275  0.168  0.972  1.0
  O  O23  1  0.832  0.725  0.528  1.0
  O  O24  1  0.725  0.832  0.028  1.0
  O  O25  1  0.168  0.275  0.472  1.0
  O  O26  1  0.321  0.533  0.697  1.0
  O  O27  1  0.467  0.679  0.803  1.0
  O  O28  1  0.679  0.467  0.303  1.0
  O  O29  1  0.533  0.321  0.197  1.0
  O  O30  1  0.640  0.487  0.610  1.0
  O  O31  1  0.513  0.360  0.890  1.0
  O  O32  1  0.360  0.513  0.390  1.0
  O  O33  1  0.487  0.640  0.110  1.0
  O  O34  1  0.203  0.978  0.831  1.0
  O  O35  1  0.022  0.797  0.669  1.0
  O  O36  1  0.797  0.022  0.169  1.0
  O  O37  1  0.978  0.203  0.331  1.0
  O  O38  1  0.305  0.894  0.538  1.0
  O  O39  1  0.106  0.695  0.962  1.0
  O  O40  1  0.695  0.106  0.462  1.0
  O  O41  1  0.894  0.305  0.038  1.0
[/CIF]
.
The structure described by (CoAl2P3O14)2N2 crystallizes in the monoclinic C2/c space group. The structure consists of four ammonia atoms inside a CoAl2P3O14 framework. In the CoAl2P3O14 framework, Co(1) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(7) atoms to form distorted CoO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent Al(1)O5 trigonal bipyramids, and  an edgeedge with one P(2)O4 tetrahedra. Al(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form AlO5 trigonal bipyramids that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with three equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and corners with three equivalent Al(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 47°. In the second P site, P(2) is bonded to two equivalent O(4) and two equivalent O(5) atoms to form PO4 tetrahedra that share corners with four equivalent Al(1)O5 trigonal bipyramids and  an edgeedge with one Co(1)O6 octahedra. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Al(1) and one P(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Al(1) and one P(1) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to one Co(1), one Al(1), and one P(2) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Al(1) and one P(2) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(1) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Co(1) atom. In the seventh O site, O(1) is bonded in a bent 150 degrees geometry to one Al(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Al2CoP3NO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.332
_cell_length_b   8.332
_cell_length_c   8.935
_cell_angle_alpha   74.739
_cell_angle_beta   74.739
_cell_angle_gamma   76.862
_symmetry_Int_Tables_number   1
_cell_volume   568.920
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.247  0.401  0.575  1.0
  Al  Al1  1  0.599  0.753  0.925  1.0
  Al  Al2  1  0.753  0.599  0.425  1.0
  Al  Al3  1  0.401  0.247  0.075  1.0
  Co  Co4  1  0.215  0.785  0.750  1.0
  Co  Co5  1  0.785  0.215  0.250  1.0
  P  P6  1  0.340  0.081  0.832  1.0
  P  P7  1  0.919  0.660  0.668  1.0
  P  P8  1  0.660  0.919  0.168  1.0
  P  P9  1  0.081  0.340  0.332  1.0
  P  P10  1  0.491  0.509  0.750  1.0
  P  P11  1  0.509  0.491  0.250  1.0
  N  N12  1  0.139  0.861  0.250  1.0
  N  N13  1  0.861  0.139  0.750  1.0
  O  O14  1  0.362  0.211  0.673  1.0
  O  O15  1  0.789  0.638  0.827  1.0
  O  O16  1  0.638  0.789  0.327  1.0
  O  O17  1  0.211  0.362  0.173  1.0
  O  O18  1  0.508  0.962  0.841  1.0
  O  O19  1  0.038  0.492  0.659  1.0
  O  O20  1  0.492  0.038  0.159  1.0
  O  O21  1  0.962  0.508  0.341  1.0
  O  O22  1  0.275  0.168  0.972  1.0
  O  O23  1  0.832  0.725  0.528  1.0
  O  O24  1  0.725  0.832  0.028  1.0
  O  O25  1  0.168  0.275  0.472  1.0
  O  O26  1  0.321  0.533  0.697  1.0
  O  O27  1  0.467  0.679  0.803  1.0
  O  O28  1  0.679  0.467  0.303  1.0
  O  O29  1  0.533  0.321  0.197  1.0
  O  O30  1  0.640  0.487  0.610  1.0
  O  O31  1  0.513  0.360  0.890  1.0
  O  O32  1  0.360  0.513  0.390  1.0
  O  O33  1  0.487  0.640  0.110  1.0
  O  O34  1  0.203  0.978  0.831  1.0
  O  O35  1  0.022  0.797  0.669  1.0
  O  O36  1  0.797  0.022  0.169  1.0
  O  O37  1  0.978  0.203  0.331  1.0
  O  O38  1  0.305  0.894  0.538  1.0
  O  O39  1  0.106  0.695  0.962  1.0
  O  O40  1  0.695  0.106  0.462  1.0
  O  O41  1  0.894  0.305  0.038  1.0
[/CIF]
.