The material described by KAg(NO3)2 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 10-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the second O site, O(6) is bonded in a 1-coordinate geometry to two equivalent K(1), one Ag(1), and one N(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one Ag(1), and one N(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the fifth O site, O(3) is bonded in a 1-coordinate geometry to one K(1), two equivalent Ag(1), and one N(2) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1), one Ag(1), and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KAg(NO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.035
_cell_length_b   8.447
_cell_length_c   14.450
_cell_angle_alpha   80.276
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   605.724
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.548  0.736  0.568  1.0
  K  K1  1  0.048  0.264  0.932  1.0
  K  K2  1  0.452  0.264  0.432  1.0
  K  K3  1  0.952  0.736  0.068  1.0
  Ag  Ag4  1  0.086  0.807  0.785  1.0
  Ag  Ag5  1  0.586  0.193  0.715  1.0
  Ag  Ag6  1  0.914  0.193  0.215  1.0
  Ag  Ag7  1  0.414  0.807  0.285  1.0
  N  N8  1  0.142  0.438  0.665  1.0
  N  N9  1  0.642  0.562  0.835  1.0
  N  N10  1  0.858  0.562  0.335  1.0
  N  N11  1  0.358  0.438  0.165  1.0
  N  N12  1  0.054  0.062  0.600  1.0
  N  N13  1  0.554  0.938  0.900  1.0
  N  N14  1  0.946  0.938  0.400  1.0
  N  N15  1  0.446  0.062  0.100  1.0
  O  O16  1  0.458  0.324  0.222  1.0
  O  O17  1  0.958  0.676  0.278  1.0
  O  O18  1  0.542  0.676  0.778  1.0
  O  O19  1  0.042  0.324  0.722  1.0
  O  O20  1  0.474  0.570  0.142  1.0
  O  O21  1  0.974  0.430  0.358  1.0
  O  O22  1  0.526  0.430  0.858  1.0
  O  O23  1  0.026  0.570  0.642  1.0
  O  O24  1  0.612  0.990  0.161  1.0
  O  O25  1  0.112  0.010  0.339  1.0
  O  O26  1  0.388  0.010  0.839  1.0
  O  O27  1  0.888  0.990  0.661  1.0
  O  O28  1  0.205  0.020  0.105  1.0
  O  O29  1  0.705  0.980  0.395  1.0
  O  O30  1  0.795  0.980  0.895  1.0
  O  O31  1  0.295  0.020  0.605  1.0
  O  O32  1  0.527  0.173  0.037  1.0
  O  O33  1  0.027  0.827  0.463  1.0
  O  O34  1  0.473  0.827  0.963  1.0
  O  O35  1  0.973  0.173  0.537  1.0
  O  O36  1  0.128  0.418  0.129  1.0
  O  O37  1  0.628  0.582  0.371  1.0
  O  O38  1  0.872  0.582  0.871  1.0
  O  O39  1  0.372  0.418  0.629  1.0
[/CIF]
.
The material described by KAg(NO3)2 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 10-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the second O site, O(6) is bonded in a 1-coordinate geometry to two equivalent K(1), one Ag(1), and one N(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one Ag(1), and one N(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the fifth O site, O(3) is bonded in a 1-coordinate geometry to one K(1), two equivalent Ag(1), and one N(2) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1), one Ag(1), and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KAg(NO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.035
_cell_length_b   8.447
_cell_length_c   14.450
_cell_angle_alpha   80.276
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   605.724
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.548  0.736  0.568  1.0
  K  K1  1  0.048  0.264  0.932  1.0
  K  K2  1  0.452  0.264  0.432  1.0
  K  K3  1  0.952  0.736  0.068  1.0
  Ag  Ag4  1  0.086  0.807  0.785  1.0
  Ag  Ag5  1  0.586  0.193  0.715  1.0
  Ag  Ag6  1  0.914  0.193  0.215  1.0
  Ag  Ag7  1  0.414  0.807  0.285  1.0
  N  N8  1  0.142  0.438  0.665  1.0
  N  N9  1  0.642  0.562  0.835  1.0
  N  N10  1  0.858  0.562  0.335  1.0
  N  N11  1  0.358  0.438  0.165  1.0
  N  N12  1  0.054  0.062  0.600  1.0
  N  N13  1  0.554  0.938  0.900  1.0
  N  N14  1  0.946  0.938  0.400  1.0
  N  N15  1  0.446  0.062  0.100  1.0
  O  O16  1  0.458  0.324  0.222  1.0
  O  O17  1  0.958  0.676  0.278  1.0
  O  O18  1  0.542  0.676  0.778  1.0
  O  O19  1  0.042  0.324  0.722  1.0
  O  O20  1  0.474  0.570  0.142  1.0
  O  O21  1  0.974  0.430  0.358  1.0
  O  O22  1  0.526  0.430  0.858  1.0
  O  O23  1  0.026  0.570  0.642  1.0
  O  O24  1  0.612  0.990  0.161  1.0
  O  O25  1  0.112  0.010  0.339  1.0
  O  O26  1  0.388  0.010  0.839  1.0
  O  O27  1  0.888  0.990  0.661  1.0
  O  O28  1  0.205  0.020  0.105  1.0
  O  O29  1  0.705  0.980  0.395  1.0
  O  O30  1  0.795  0.980  0.895  1.0
  O  O31  1  0.295  0.020  0.605  1.0
  O  O32  1  0.527  0.173  0.037  1.0
  O  O33  1  0.027  0.827  0.463  1.0
  O  O34  1  0.473  0.827  0.963  1.0
  O  O35  1  0.973  0.173  0.537  1.0
  O  O36  1  0.128  0.418  0.129  1.0
  O  O37  1  0.628  0.582  0.371  1.0
  O  O38  1  0.872  0.582  0.871  1.0
  O  O39  1  0.372  0.418  0.629  1.0
[/CIF]
.