The compound described by RuC3H2(O2Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four RuC3H2(O2Cl)2 clusters. Ru(1) is bonded in an octahedral geometry to one C(1), one C(2), one C(3), one O(3), one Cl(1), and one Cl(2) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ru(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Ru(1) and one O(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one Ru(1), one H(1), and one H(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H2RuC3(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.430
_cell_length_b   6.329
_cell_length_c   12.817
_cell_angle_alpha   68.439
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   786.907
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.507  0.740  0.024  1.0
  H  H1  1  0.923  0.262  0.575  1.0
  H  H2  1  0.007  0.260  0.476  1.0
  H  H3  1  0.423  0.738  0.925  1.0
  H  H4  1  0.577  0.262  0.075  1.0
  H  H5  1  0.993  0.740  0.524  1.0
  H  H6  1  0.077  0.738  0.425  1.0
  H  H7  1  0.493  0.260  0.976  1.0
  Ru  Ru8  1  0.779  0.466  0.387  1.0
  Ru  Ru9  1  0.279  0.534  0.113  1.0
  Ru  Ru10  1  0.721  0.466  0.887  1.0
  Ru  Ru11  1  0.221  0.534  0.613  1.0
  C  C12  1  0.666  0.676  0.287  1.0
  C  C13  1  0.285  0.712  0.205  1.0
  C  C14  1  0.140  0.704  0.025  1.0
  C  C15  1  0.640  0.296  0.475  1.0
  C  C16  1  0.785  0.288  0.295  1.0
  C  C17  1  0.166  0.324  0.213  1.0
  C  C18  1  0.834  0.676  0.787  1.0
  C  C19  1  0.215  0.712  0.705  1.0
  C  C20  1  0.360  0.704  0.525  1.0
  C  C21  1  0.860  0.296  0.975  1.0
  C  C22  1  0.715  0.288  0.795  1.0
  C  C23  1  0.334  0.324  0.713  1.0
  Cl  Cl24  1  0.962  0.681  0.283  1.0
  Cl  Cl25  1  0.720  0.693  0.005  1.0
  Cl  Cl26  1  0.220  0.307  0.495  1.0
  Cl  Cl27  1  0.462  0.319  0.217  1.0
  Cl  Cl28  1  0.538  0.681  0.783  1.0
  Cl  Cl29  1  0.780  0.693  0.505  1.0
  Cl  Cl30  1  0.280  0.307  0.995  1.0
  Cl  Cl31  1  0.038  0.319  0.717  1.0
  O  O32  1  0.402  0.190  0.772  1.0
  O  O33  1  0.711  0.183  0.738  1.0
  O  O34  1  0.917  0.239  0.503  1.0
  O  O35  1  0.555  0.198  0.528  1.0
  O  O36  1  0.055  0.802  0.972  1.0
  O  O37  1  0.417  0.761  0.997  1.0
  O  O38  1  0.098  0.190  0.272  1.0
  O  O39  1  0.211  0.817  0.762  1.0
  O  O40  1  0.789  0.183  0.238  1.0
  O  O41  1  0.902  0.810  0.728  1.0
  O  O42  1  0.583  0.239  0.003  1.0
  O  O43  1  0.945  0.198  0.028  1.0
  O  O44  1  0.445  0.802  0.472  1.0
  O  O45  1  0.083  0.761  0.497  1.0
  O  O46  1  0.289  0.817  0.262  1.0
  O  O47  1  0.598  0.810  0.228  1.0
[/CIF]
.
The compound described by RuC3H2(O2Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four RuC3H2(O2Cl)2 clusters. Ru(1) is bonded in an octahedral geometry to one C(1), one C(2), one C(3), one O(3), one Cl(1), and one Cl(2) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ru(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Ru(1) and one O(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one Ru(1), one H(1), and one H(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H2RuC3(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.430
_cell_length_b   6.329
_cell_length_c   12.817
_cell_angle_alpha   68.439
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   786.907
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.507  0.740  0.024  1.0
  H  H1  1  0.923  0.262  0.575  1.0
  H  H2  1  0.007  0.260  0.476  1.0
  H  H3  1  0.423  0.738  0.925  1.0
  H  H4  1  0.577  0.262  0.075  1.0
  H  H5  1  0.993  0.740  0.524  1.0
  H  H6  1  0.077  0.738  0.425  1.0
  H  H7  1  0.493  0.260  0.976  1.0
  Ru  Ru8  1  0.779  0.466  0.387  1.0
  Ru  Ru9  1  0.279  0.534  0.113  1.0
  Ru  Ru10  1  0.721  0.466  0.887  1.0
  Ru  Ru11  1  0.221  0.534  0.613  1.0
  C  C12  1  0.666  0.676  0.287  1.0
  C  C13  1  0.285  0.712  0.205  1.0
  C  C14  1  0.140  0.704  0.025  1.0
  C  C15  1  0.640  0.296  0.475  1.0
  C  C16  1  0.785  0.288  0.295  1.0
  C  C17  1  0.166  0.324  0.213  1.0
  C  C18  1  0.834  0.676  0.787  1.0
  C  C19  1  0.215  0.712  0.705  1.0
  C  C20  1  0.360  0.704  0.525  1.0
  C  C21  1  0.860  0.296  0.975  1.0
  C  C22  1  0.715  0.288  0.795  1.0
  C  C23  1  0.334  0.324  0.713  1.0
  Cl  Cl24  1  0.962  0.681  0.283  1.0
  Cl  Cl25  1  0.720  0.693  0.005  1.0
  Cl  Cl26  1  0.220  0.307  0.495  1.0
  Cl  Cl27  1  0.462  0.319  0.217  1.0
  Cl  Cl28  1  0.538  0.681  0.783  1.0
  Cl  Cl29  1  0.780  0.693  0.505  1.0
  Cl  Cl30  1  0.280  0.307  0.995  1.0
  Cl  Cl31  1  0.038  0.319  0.717  1.0
  O  O32  1  0.402  0.190  0.772  1.0
  O  O33  1  0.711  0.183  0.738  1.0
  O  O34  1  0.917  0.239  0.503  1.0
  O  O35  1  0.555  0.198  0.528  1.0
  O  O36  1  0.055  0.802  0.972  1.0
  O  O37  1  0.417  0.761  0.997  1.0
  O  O38  1  0.098  0.190  0.272  1.0
  O  O39  1  0.211  0.817  0.762  1.0
  O  O40  1  0.789  0.183  0.238  1.0
  O  O41  1  0.902  0.810  0.728  1.0
  O  O42  1  0.583  0.239  0.003  1.0
  O  O43  1  0.945  0.198  0.028  1.0
  O  O44  1  0.445  0.802  0.472  1.0
  O  O45  1  0.083  0.761  0.497  1.0
  O  O46  1  0.289  0.817  0.262  1.0
  O  O47  1  0.598  0.810  0.228  1.0
[/CIF]
.