The structure described by P3N5 crystallizes in the orthorhombic Imm2 space group. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent N(2) and three equivalent N(1) atoms to form PN5 square pyramids that share corners with four equivalent P(1)N5 square pyramids, corners with two equivalent P(2)N4 tetrahedra, and edges with two equivalent P(1)N5 square pyramids. In the second P site, P(2) is bonded to two equivalent N(2) and two equivalent N(3) atoms to form PN4 tetrahedra that share corners with four equivalent P(1)N5 square pyramids and corners with two equivalent P(2)N4 tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to three equivalent P(1) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one P(2) and two equivalent P(1) atoms. In the third N site, N(3) is bonded in a bent 120 degrees geometry to two equivalent P(2) atoms. is represented by the CIF card [CIF]
data_P3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.629
_cell_length_b   4.490
_cell_length_c   7.028
_cell_angle_alpha   108.629
_cell_angle_beta   100.780
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   77.071
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.817  0.276  0.634  1.0
  P  P1  1  0.183  0.641  0.366  1.0
  P  P2  1  0.500  0.798  0.000  1.0
  N  N3  1  0.726  0.462  0.453  1.0
  N  N4  1  0.274  0.009  0.547  1.0
  N  N5  1  0.396  0.474  0.792  1.0
  N  N6  1  0.000  0.994  0.000  1.0
  N  N7  1  0.604  0.681  0.208  1.0
[/CIF]
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The structure described by P3N5 crystallizes in the orthorhombic Imm2 space group. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent N(2) and three equivalent N(1) atoms to form PN5 square pyramids that share corners with four equivalent P(1)N5 square pyramids, corners with two equivalent P(2)N4 tetrahedra, and edges with two equivalent P(1)N5 square pyramids. In the second P site, P(2) is bonded to two equivalent N(2) and two equivalent N(3) atoms to form PN4 tetrahedra that share corners with four equivalent P(1)N5 square pyramids and corners with two equivalent P(2)N4 tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to three equivalent P(1) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one P(2) and two equivalent P(1) atoms. In the third N site, N(3) is bonded in a bent 120 degrees geometry to two equivalent P(2) atoms. is represented by the CIF card [CIF]
data_P3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.629
_cell_length_b   4.490
_cell_length_c   7.028
_cell_angle_alpha   108.629
_cell_angle_beta   100.780
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   77.071
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.817  0.276  0.634  1.0
  P  P1  1  0.183  0.641  0.366  1.0
  P  P2  1  0.500  0.798  0.000  1.0
  N  N3  1  0.726  0.462  0.453  1.0
  N  N4  1  0.274  0.009  0.547  1.0
  N  N5  1  0.396  0.474  0.792  1.0
  N  N6  1  0.000  0.994  0.000  1.0
  N  N7  1  0.604  0.681  0.208  1.0
[/CIF]
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