The material described by N3S3O2Cl is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight N3S3O2Cl clusters. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(1) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one N(2), one N(3), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. Cl(1) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_S3N3ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.740
_cell_length_b   9.740
_cell_length_c   12.516
_cell_angle_alpha   67.414
_cell_angle_beta   67.414
_cell_angle_gamma   42.165
_symmetry_Int_Tables_number   1
_cell_volume   726.371
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.911  0.284  0.798  1.0
  S  S1  1  0.499  0.838  0.444  1.0
  S  S2  1  0.716  0.089  0.702  1.0
  S  S3  1  0.162  0.501  0.056  1.0
  S  S4  1  0.090  0.226  0.419  1.0
  S  S5  1  0.774  0.910  0.081  1.0
  S  S6  1  0.838  0.499  0.944  1.0
  S  S7  1  0.501  0.162  0.556  1.0
  S  S8  1  0.910  0.774  0.581  1.0
  S  S9  1  0.089  0.716  0.202  1.0
  S  S10  1  0.284  0.911  0.298  1.0
  S  S11  1  0.226  0.090  0.919  1.0
  N  N12  1  0.757  0.468  0.868  1.0
  N  N13  1  0.243  0.532  0.132  1.0
  N  N14  1  0.331  0.080  0.428  1.0
  N  N15  1  0.101  0.139  0.320  1.0
  N  N16  1  0.899  0.861  0.680  1.0
  N  N17  1  0.669  0.920  0.572  1.0
  N  N18  1  0.468  0.757  0.368  1.0
  N  N19  1  0.139  0.101  0.820  1.0
  N  N20  1  0.532  0.243  0.632  1.0
  N  N21  1  0.080  0.331  0.928  1.0
  N  N22  1  0.861  0.899  0.180  1.0
  N  N23  1  0.920  0.669  0.072  1.0
  Cl  Cl24  1  0.436  0.705  0.614  1.0
  Cl  Cl25  1  0.705  0.436  0.114  1.0
  Cl  Cl26  1  0.295  0.564  0.886  1.0
  Cl  Cl27  1  0.564  0.295  0.386  1.0
  O  O28  1  0.995  0.569  0.633  1.0
  O  O29  1  0.804  0.016  0.972  1.0
  O  O30  1  0.196  0.984  0.028  1.0
  O  O31  1  0.431  0.005  0.867  1.0
  O  O32  1  0.984  0.196  0.528  1.0
  O  O33  1  0.016  0.804  0.472  1.0
  O  O34  1  0.569  0.995  0.133  1.0
  O  O35  1  0.005  0.431  0.367  1.0
[/CIF]
.
The material described by N3S3O2Cl is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight N3S3O2Cl clusters. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(1) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one N(2), one N(3), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. Cl(1) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_S3N3ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.740
_cell_length_b   9.740
_cell_length_c   12.516
_cell_angle_alpha   67.414
_cell_angle_beta   67.414
_cell_angle_gamma   42.165
_symmetry_Int_Tables_number   1
_cell_volume   726.371
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.911  0.284  0.798  1.0
  S  S1  1  0.499  0.838  0.444  1.0
  S  S2  1  0.716  0.089  0.702  1.0
  S  S3  1  0.162  0.501  0.056  1.0
  S  S4  1  0.090  0.226  0.419  1.0
  S  S5  1  0.774  0.910  0.081  1.0
  S  S6  1  0.838  0.499  0.944  1.0
  S  S7  1  0.501  0.162  0.556  1.0
  S  S8  1  0.910  0.774  0.581  1.0
  S  S9  1  0.089  0.716  0.202  1.0
  S  S10  1  0.284  0.911  0.298  1.0
  S  S11  1  0.226  0.090  0.919  1.0
  N  N12  1  0.757  0.468  0.868  1.0
  N  N13  1  0.243  0.532  0.132  1.0
  N  N14  1  0.331  0.080  0.428  1.0
  N  N15  1  0.101  0.139  0.320  1.0
  N  N16  1  0.899  0.861  0.680  1.0
  N  N17  1  0.669  0.920  0.572  1.0
  N  N18  1  0.468  0.757  0.368  1.0
  N  N19  1  0.139  0.101  0.820  1.0
  N  N20  1  0.532  0.243  0.632  1.0
  N  N21  1  0.080  0.331  0.928  1.0
  N  N22  1  0.861  0.899  0.180  1.0
  N  N23  1  0.920  0.669  0.072  1.0
  Cl  Cl24  1  0.436  0.705  0.614  1.0
  Cl  Cl25  1  0.705  0.436  0.114  1.0
  Cl  Cl26  1  0.295  0.564  0.886  1.0
  Cl  Cl27  1  0.564  0.295  0.386  1.0
  O  O28  1  0.995  0.569  0.633  1.0
  O  O29  1  0.804  0.016  0.972  1.0
  O  O30  1  0.196  0.984  0.028  1.0
  O  O31  1  0.431  0.005  0.867  1.0
  O  O32  1  0.984  0.196  0.528  1.0
  O  O33  1  0.016  0.804  0.472  1.0
  O  O34  1  0.569  0.995  0.133  1.0
  O  O35  1  0.005  0.431  0.367  1.0
[/CIF]
.