The crystal structure described by V2MnTeO7 crystallizes in the triclinic P-1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(3) atoms to form distorted VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent V(2)O5 trigonal bipyramids,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 37°. In the second V site, V(2) is bonded to one O(2), one O(3), one O(4), and two equivalent O(7) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-53°. Mn(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms to form distorted MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O5 trigonal bipyramids,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. Te(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Mn(1), and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one V(2) and one Mn(1) atom. In the third O site, O(3) is bonded to one V(2), two equivalent V(1), and one Te(1) atom to form distorted edge-sharing OV3Te trigonal pyramids. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(2), one Mn(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one Mn(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent Mn(1) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. is represented by the CIF file [CIF]
data_MnV2TeO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.793
_cell_length_b   7.014
_cell_length_c   8.025
_cell_angle_alpha   94.402
_cell_angle_beta   113.534
_cell_angle_gamma   114.593
_symmetry_Int_Tables_number   1
_cell_volume   304.951
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.439  0.064  0.176  1.0
  Mn  Mn1  1  0.561  0.936  0.824  1.0
  V  V2  1  0.026  0.887  0.667  1.0
  V  V3  1  0.508  0.567  0.328  1.0
  V  V4  1  0.492  0.433  0.672  1.0
  V  V5  1  0.974  0.113  0.333  1.0
  Te  Te6  1  0.058  0.693  0.290  1.0
  Te  Te7  1  0.942  0.307  0.710  1.0
  O  O8  1  0.146  0.984  0.255  1.0
  O  O9  1  0.449  0.366  0.155  1.0
  O  O10  1  0.177  0.182  0.631  1.0
  O  O11  1  0.343  0.741  0.253  1.0
  O  O12  1  0.215  0.779  0.560  1.0
  O  O13  1  0.657  0.259  0.747  1.0
  O  O14  1  0.823  0.818  0.369  1.0
  O  O15  1  0.749  0.094  0.119  1.0
  O  O16  1  0.854  0.016  0.745  1.0
  O  O17  1  0.265  0.409  0.415  1.0
  O  O18  1  0.551  0.634  0.845  1.0
  O  O19  1  0.785  0.221  0.440  1.0
  O  O20  1  0.251  0.906  0.881  1.0
  O  O21  1  0.735  0.591  0.585  1.0
[/CIF]
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The crystal structure described by V2MnTeO7 crystallizes in the triclinic P-1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(3) atoms to form distorted VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent V(2)O5 trigonal bipyramids,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 37°. In the second V site, V(2) is bonded to one O(2), one O(3), one O(4), and two equivalent O(7) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-53°. Mn(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms to form distorted MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O5 trigonal bipyramids,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. Te(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Mn(1), and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one V(2) and one Mn(1) atom. In the third O site, O(3) is bonded to one V(2), two equivalent V(1), and one Te(1) atom to form distorted edge-sharing OV3Te trigonal pyramids. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(2), one Mn(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one Mn(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent Mn(1) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. is represented by the CIF file [CIF]
data_MnV2TeO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.793
_cell_length_b   7.014
_cell_length_c   8.025
_cell_angle_alpha   94.402
_cell_angle_beta   113.534
_cell_angle_gamma   114.593
_symmetry_Int_Tables_number   1
_cell_volume   304.951
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.439  0.064  0.176  1.0
  Mn  Mn1  1  0.561  0.936  0.824  1.0
  V  V2  1  0.026  0.887  0.667  1.0
  V  V3  1  0.508  0.567  0.328  1.0
  V  V4  1  0.492  0.433  0.672  1.0
  V  V5  1  0.974  0.113  0.333  1.0
  Te  Te6  1  0.058  0.693  0.290  1.0
  Te  Te7  1  0.942  0.307  0.710  1.0
  O  O8  1  0.146  0.984  0.255  1.0
  O  O9  1  0.449  0.366  0.155  1.0
  O  O10  1  0.177  0.182  0.631  1.0
  O  O11  1  0.343  0.741  0.253  1.0
  O  O12  1  0.215  0.779  0.560  1.0
  O  O13  1  0.657  0.259  0.747  1.0
  O  O14  1  0.823  0.818  0.369  1.0
  O  O15  1  0.749  0.094  0.119  1.0
  O  O16  1  0.854  0.016  0.745  1.0
  O  O17  1  0.265  0.409  0.415  1.0
  O  O18  1  0.551  0.634  0.845  1.0
  O  O19  1  0.785  0.221  0.440  1.0
  O  O20  1  0.251  0.906  0.881  1.0
  O  O21  1  0.735  0.591  0.585  1.0
[/CIF]
.