The structure described by Rb2LiCo(CN)6 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 4-coordinate geometry to one N(2), one N(3), and two equivalent N(1) atoms. Li(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one N(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(1), one Li(1), and one C(3) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Rb(1), one Li(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Li(1), and one C(1) atom. is represented by the CIF file [CIF]
data_Rb2LiCo(CN)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.492
_cell_length_b   7.212
_cell_length_c   12.576
_cell_angle_alpha   55.180
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   557.829
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.554  0.738  0.249  1.0
  Rb  Rb1  1  0.054  0.262  0.251  1.0
  Rb  Rb2  1  0.446  0.262  0.751  1.0
  Rb  Rb3  1  0.946  0.738  0.749  1.0
  Li  Li4  1  0.000  0.500  0.500  1.0
  Li  Li5  1  0.500  0.500  0.000  1.0
  Co  Co6  1  0.500  0.000  0.500  1.0
  Co  Co7  1  0.000  0.000  0.000  1.0
  C  C8  1  0.857  0.766  0.023  1.0
  C  C9  1  0.643  0.766  0.523  1.0
  C  C10  1  0.143  0.234  0.977  1.0
  C  C11  1  0.357  0.234  0.477  1.0
  C  C12  1  0.294  0.830  0.527  1.0
  C  C13  1  0.794  0.170  0.973  1.0
  C  C14  1  0.010  0.130  0.822  1.0
  C  C15  1  0.510  0.870  0.678  1.0
  C  C16  1  0.990  0.870  0.178  1.0
  C  C17  1  0.490  0.130  0.322  1.0
  C  C18  1  0.206  0.830  0.027  1.0
  C  C19  1  0.706  0.170  0.473  1.0
  N  N20  1  0.982  0.786  0.290  1.0
  N  N21  1  0.482  0.214  0.210  1.0
  N  N22  1  0.165  0.723  0.544  1.0
  N  N23  1  0.335  0.723  0.044  1.0
  N  N24  1  0.835  0.277  0.456  1.0
  N  N25  1  0.665  0.277  0.956  1.0
  N  N26  1  0.235  0.379  0.962  1.0
  N  N27  1  0.735  0.621  0.538  1.0
  N  N28  1  0.765  0.621  0.038  1.0
  N  N29  1  0.265  0.379  0.462  1.0
  N  N30  1  0.018  0.214  0.710  1.0
  N  N31  1  0.518  0.786  0.790  1.0
[/CIF]
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The structure described by Rb2LiCo(CN)6 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 4-coordinate geometry to one N(2), one N(3), and two equivalent N(1) atoms. Li(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one N(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(1), one Li(1), and one C(3) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Rb(1), one Li(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Li(1), and one C(1) atom. is represented by the CIF file [CIF]
data_Rb2LiCo(CN)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.492
_cell_length_b   7.212
_cell_length_c   12.576
_cell_angle_alpha   55.180
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   557.829
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.554  0.738  0.249  1.0
  Rb  Rb1  1  0.054  0.262  0.251  1.0
  Rb  Rb2  1  0.446  0.262  0.751  1.0
  Rb  Rb3  1  0.946  0.738  0.749  1.0
  Li  Li4  1  0.000  0.500  0.500  1.0
  Li  Li5  1  0.500  0.500  0.000  1.0
  Co  Co6  1  0.500  0.000  0.500  1.0
  Co  Co7  1  0.000  0.000  0.000  1.0
  C  C8  1  0.857  0.766  0.023  1.0
  C  C9  1  0.643  0.766  0.523  1.0
  C  C10  1  0.143  0.234  0.977  1.0
  C  C11  1  0.357  0.234  0.477  1.0
  C  C12  1  0.294  0.830  0.527  1.0
  C  C13  1  0.794  0.170  0.973  1.0
  C  C14  1  0.010  0.130  0.822  1.0
  C  C15  1  0.510  0.870  0.678  1.0
  C  C16  1  0.990  0.870  0.178  1.0
  C  C17  1  0.490  0.130  0.322  1.0
  C  C18  1  0.206  0.830  0.027  1.0
  C  C19  1  0.706  0.170  0.473  1.0
  N  N20  1  0.982  0.786  0.290  1.0
  N  N21  1  0.482  0.214  0.210  1.0
  N  N22  1  0.165  0.723  0.544  1.0
  N  N23  1  0.335  0.723  0.044  1.0
  N  N24  1  0.835  0.277  0.456  1.0
  N  N25  1  0.665  0.277  0.956  1.0
  N  N26  1  0.235  0.379  0.962  1.0
  N  N27  1  0.735  0.621  0.538  1.0
  N  N28  1  0.765  0.621  0.038  1.0
  N  N29  1  0.265  0.379  0.462  1.0
  N  N30  1  0.018  0.214  0.710  1.0
  N  N31  1  0.518  0.786  0.790  1.0
[/CIF]
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