The structure described by K2S3 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one S(2) and six equivalent S(1) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to two equivalent S(2) and six equivalent S(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 7-coordinate geometry to three equivalent K(1), three equivalent K(2), and one S(2) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to one K(1), two equivalent K(2), and two equivalent S(1) atoms. is represented by the CIF card [CIF]
data_K2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.222
_cell_length_b   6.222
_cell_length_c   7.415
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.390
_symmetry_Int_Tables_number   1
_cell_volume   272.407
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.419  0.581  0.657  1.0
  K  K1  1  0.581  0.419  0.157  1.0
  K  K2  1  0.894  0.106  0.387  1.0
  K  K3  1  0.106  0.894  0.887  1.0
  S  S4  1  0.387  0.072  0.501  1.0
  S  S5  1  0.613  0.928  0.001  1.0
  S  S6  1  0.928  0.613  0.501  1.0
  S  S7  1  0.072  0.387  0.001  1.0
  S  S8  1  0.799  0.201  0.844  1.0
  S  S9  1  0.201  0.799  0.344  1.0
[/CIF]
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The structure described by K2S3 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one S(2) and six equivalent S(1) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to two equivalent S(2) and six equivalent S(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 7-coordinate geometry to three equivalent K(1), three equivalent K(2), and one S(2) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to one K(1), two equivalent K(2), and two equivalent S(1) atoms. is represented by the CIF card [CIF]
data_K2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.222
_cell_length_b   6.222
_cell_length_c   7.415
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.390
_symmetry_Int_Tables_number   1
_cell_volume   272.407
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.419  0.581  0.657  1.0
  K  K1  1  0.581  0.419  0.157  1.0
  K  K2  1  0.894  0.106  0.387  1.0
  K  K3  1  0.106  0.894  0.887  1.0
  S  S4  1  0.387  0.072  0.501  1.0
  S  S5  1  0.613  0.928  0.001  1.0
  S  S6  1  0.928  0.613  0.501  1.0
  S  S7  1  0.072  0.387  0.001  1.0
  S  S8  1  0.799  0.201  0.844  1.0
  S  S9  1  0.201  0.799  0.344  1.0
[/CIF]
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