The structure described by Pr2MoTe4O14 crystallizes in the triclinic P-1 space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(2), one O(3), one O(7), and one O(8) atom. In the second Pr site, Pr(2) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(2), one O(6), one O(8), and two equivalent O(12) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(7), and one O(9) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(11), one O(13), and one O(8) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(1), one O(11), one O(12), and one O(2) atom. In the third Te site, Te(3) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(2), one O(4), and one O(5) atom. In the fourth Te site, Te(4) is bonded in a 4-coordinate geometry to one O(10), one O(14), one O(5), and one O(6) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Pr(1), one Pr(2), and one Te(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Pr(1), one Pr(2), one Te(2), and one Te(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Pr(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Te(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Te(3) and one Te(4) atom. In the sixth O site, O(6) is bonded in a linear geometry to one Pr(2) and one Te(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Pr(1), one Pr(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Mo(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Pr(1), one Pr(2), one Te(1), and one Te(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Pr(1), two equivalent Pr(2), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Pr(1), one Pr(2), and one Te(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Pr(2), one Te(3), and one Te(4) atom. is represented by the CIF file [CIF]
data_Pr2Te4MoO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.084
_cell_length_b   10.196
_cell_length_c   10.329
_cell_angle_alpha   90.098
_cell_angle_beta   107.244
_cell_angle_gamma   93.271
_symmetry_Int_Tables_number   1
_cell_volume   711.237
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.644  0.308  0.086  1.0
  Pr  Pr1  1  0.220  0.465  0.215  1.0
  Pr  Pr2  1  0.780  0.535  0.785  1.0
  Pr  Pr3  1  0.356  0.692  0.914  1.0
  Te  Te4  1  0.742  0.609  0.279  1.0
  Te  Te5  1  0.943  0.789  0.043  1.0
  Te  Te6  1  0.057  0.211  0.957  1.0
  Te  Te7  1  0.075  0.166  0.369  1.0
  Te  Te8  1  0.362  0.727  0.542  1.0
  Te  Te9  1  0.638  0.273  0.458  1.0
  Te  Te10  1  0.925  0.834  0.631  1.0
  Te  Te11  1  0.258  0.391  0.721  1.0
  Mo  Mo12  1  0.523  0.038  0.768  1.0
  Mo  Mo13  1  0.477  0.962  0.232  1.0
  O  O14  1  0.707  0.705  0.931  1.0
  O  O15  1  0.975  0.226  0.188  1.0
  O  O16  1  0.594  0.121  0.931  1.0
  O  O17  1  0.746  0.000  0.730  1.0
  O  O18  1  0.929  0.277  0.459  1.0
  O  O19  1  0.254  1.000  0.270  1.0
  O  O20  1  0.306  0.609  0.397  1.0
  O  O21  1  0.376  0.885  0.766  1.0
  O  O22  1  0.121  0.509  0.796  1.0
  O  O23  1  0.388  0.141  0.639  1.0
  O  O24  1  0.406  0.879  0.069  1.0
  O  O25  1  0.415  0.605  0.688  1.0
  O  O26  1  0.612  0.859  0.361  1.0
  O  O27  1  0.879  0.491  0.204  1.0
  O  O28  1  0.869  0.765  0.209  1.0
  O  O29  1  0.103  0.646  0.049  1.0
  O  O30  1  0.585  0.395  0.312  1.0
  O  O31  1  0.499  0.417  0.865  1.0
  O  O32  1  0.897  0.354  0.951  1.0
  O  O33  1  0.713  0.704  0.600  1.0
  O  O34  1  0.694  0.391  0.603  1.0
  O  O35  1  0.025  0.774  0.812  1.0
  O  O36  1  0.071  0.723  0.541  1.0
  O  O37  1  0.131  0.235  0.791  1.0
  O  O38  1  0.501  0.583  0.135  1.0
  O  O39  1  0.624  0.115  0.234  1.0
  O  O40  1  0.287  0.296  0.400  1.0
  O  O41  1  0.293  0.295  0.069  1.0
[/CIF]
.
The structure described by Pr2MoTe4O14 crystallizes in the triclinic P-1 space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(2), one O(3), one O(7), and one O(8) atom. In the second Pr site, Pr(2) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(2), one O(6), one O(8), and two equivalent O(12) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(7), and one O(9) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(11), one O(13), and one O(8) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(1), one O(11), one O(12), and one O(2) atom. In the third Te site, Te(3) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(2), one O(4), and one O(5) atom. In the fourth Te site, Te(4) is bonded in a 4-coordinate geometry to one O(10), one O(14), one O(5), and one O(6) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Pr(1), one Pr(2), and one Te(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Pr(1), one Pr(2), one Te(2), and one Te(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Pr(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Te(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Te(3) and one Te(4) atom. In the sixth O site, O(6) is bonded in a linear geometry to one Pr(2) and one Te(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Pr(1), one Pr(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Mo(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Pr(1), one Pr(2), one Te(1), and one Te(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Pr(1), two equivalent Pr(2), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Pr(1), one Pr(2), and one Te(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Pr(2), one Te(3), and one Te(4) atom. is represented by the CIF file [CIF]
data_Pr2Te4MoO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.084
_cell_length_b   10.196
_cell_length_c   10.329
_cell_angle_alpha   90.098
_cell_angle_beta   107.244
_cell_angle_gamma   93.271
_symmetry_Int_Tables_number   1
_cell_volume   711.237
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.644  0.308  0.086  1.0
  Pr  Pr1  1  0.220  0.465  0.215  1.0
  Pr  Pr2  1  0.780  0.535  0.785  1.0
  Pr  Pr3  1  0.356  0.692  0.914  1.0
  Te  Te4  1  0.742  0.609  0.279  1.0
  Te  Te5  1  0.943  0.789  0.043  1.0
  Te  Te6  1  0.057  0.211  0.957  1.0
  Te  Te7  1  0.075  0.166  0.369  1.0
  Te  Te8  1  0.362  0.727  0.542  1.0
  Te  Te9  1  0.638  0.273  0.458  1.0
  Te  Te10  1  0.925  0.834  0.631  1.0
  Te  Te11  1  0.258  0.391  0.721  1.0
  Mo  Mo12  1  0.523  0.038  0.768  1.0
  Mo  Mo13  1  0.477  0.962  0.232  1.0
  O  O14  1  0.707  0.705  0.931  1.0
  O  O15  1  0.975  0.226  0.188  1.0
  O  O16  1  0.594  0.121  0.931  1.0
  O  O17  1  0.746  0.000  0.730  1.0
  O  O18  1  0.929  0.277  0.459  1.0
  O  O19  1  0.254  1.000  0.270  1.0
  O  O20  1  0.306  0.609  0.397  1.0
  O  O21  1  0.376  0.885  0.766  1.0
  O  O22  1  0.121  0.509  0.796  1.0
  O  O23  1  0.388  0.141  0.639  1.0
  O  O24  1  0.406  0.879  0.069  1.0
  O  O25  1  0.415  0.605  0.688  1.0
  O  O26  1  0.612  0.859  0.361  1.0
  O  O27  1  0.879  0.491  0.204  1.0
  O  O28  1  0.869  0.765  0.209  1.0
  O  O29  1  0.103  0.646  0.049  1.0
  O  O30  1  0.585  0.395  0.312  1.0
  O  O31  1  0.499  0.417  0.865  1.0
  O  O32  1  0.897  0.354  0.951  1.0
  O  O33  1  0.713  0.704  0.600  1.0
  O  O34  1  0.694  0.391  0.603  1.0
  O  O35  1  0.025  0.774  0.812  1.0
  O  O36  1  0.071  0.723  0.541  1.0
  O  O37  1  0.131  0.235  0.791  1.0
  O  O38  1  0.501  0.583  0.135  1.0
  O  O39  1  0.624  0.115  0.234  1.0
  O  O40  1  0.287  0.296  0.400  1.0
  O  O41  1  0.293  0.295  0.069  1.0
[/CIF]
.