The structure described by ReCl6(RuN5Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two 7782-50-5 molecules, two rhenium (iv) hexachloride molecules, and four RuN5Cl clusters. In each RuN5Cl cluster, Ru(1) is bonded in a distorted trigonal non-coplanar geometry to one N(3), two equivalent N(1), and two equivalent N(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one Ru(1) and one N(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Ru(1) and one Cl(5) atom. Cl(5) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_ReRu2(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.414
_cell_length_b   7.414
_cell_length_c   13.112
_cell_angle_alpha   79.543
_cell_angle_beta   79.543
_cell_angle_gamma   65.152
_symmetry_Int_Tables_number   1
_cell_volume   638.690
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.000  0.000  0.500  1.0
  Ru  Ru1  1  0.408  0.408  0.822  1.0
  Ru  Ru2  1  0.592  0.592  0.178  1.0
  N  N3  1  0.187  0.327  0.712  1.0
  N  N4  1  0.327  0.187  0.712  1.0
  N  N5  1  0.813  0.673  0.288  1.0
  N  N6  1  0.673  0.813  0.288  1.0
  N  N7  1  0.192  0.539  0.897  1.0
  N  N8  1  0.539  0.192  0.897  1.0
  N  N9  1  0.808  0.461  0.103  1.0
  N  N10  1  0.461  0.808  0.103  1.0
  N  N11  1  0.557  0.557  0.783  1.0
  N  N12  1  0.443  0.443  0.217  1.0
  Cl  Cl13  1  0.189  0.189  0.478  1.0
  Cl  Cl14  1  0.811  0.811  0.522  1.0
  Cl  Cl15  1  0.978  0.978  0.681  1.0
  Cl  Cl16  1  0.022  0.022  0.319  1.0
  Cl  Cl17  1  0.292  0.708  0.500  1.0
  Cl  Cl18  1  0.708  0.292  0.500  1.0
  Cl  Cl19  1  0.079  0.079  0.966  1.0
  Cl  Cl20  1  0.921  0.921  0.034  1.0
  Cl  Cl21  1  0.673  0.673  0.816  1.0
  Cl  Cl22  1  0.327  0.327  0.184  1.0
[/CIF]
.
The structure described by ReCl6(RuN5Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two 7782-50-5 molecules, two rhenium (iv) hexachloride molecules, and four RuN5Cl clusters. In each RuN5Cl cluster, Ru(1) is bonded in a distorted trigonal non-coplanar geometry to one N(3), two equivalent N(1), and two equivalent N(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one Ru(1) and one N(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Ru(1) and one Cl(5) atom. Cl(5) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_ReRu2(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.414
_cell_length_b   7.414
_cell_length_c   13.112
_cell_angle_alpha   79.543
_cell_angle_beta   79.543
_cell_angle_gamma   65.152
_symmetry_Int_Tables_number   1
_cell_volume   638.690
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.000  0.000  0.500  1.0
  Ru  Ru1  1  0.408  0.408  0.822  1.0
  Ru  Ru2  1  0.592  0.592  0.178  1.0
  N  N3  1  0.187  0.327  0.712  1.0
  N  N4  1  0.327  0.187  0.712  1.0
  N  N5  1  0.813  0.673  0.288  1.0
  N  N6  1  0.673  0.813  0.288  1.0
  N  N7  1  0.192  0.539  0.897  1.0
  N  N8  1  0.539  0.192  0.897  1.0
  N  N9  1  0.808  0.461  0.103  1.0
  N  N10  1  0.461  0.808  0.103  1.0
  N  N11  1  0.557  0.557  0.783  1.0
  N  N12  1  0.443  0.443  0.217  1.0
  Cl  Cl13  1  0.189  0.189  0.478  1.0
  Cl  Cl14  1  0.811  0.811  0.522  1.0
  Cl  Cl15  1  0.978  0.978  0.681  1.0
  Cl  Cl16  1  0.022  0.022  0.319  1.0
  Cl  Cl17  1  0.292  0.708  0.500  1.0
  Cl  Cl18  1  0.708  0.292  0.500  1.0
  Cl  Cl19  1  0.079  0.079  0.966  1.0
  Cl  Cl20  1  0.921  0.921  0.034  1.0
  Cl  Cl21  1  0.673  0.673  0.816  1.0
  Cl  Cl22  1  0.327  0.327  0.184  1.0
[/CIF]
.