The compound described by FeRhP crystallizes in the hexagonal P-62m space group. Fe(1) is bonded in a 11-coordinate geometry to six equivalent Rh(1), one P(2), and four equivalent P(1) atoms. Rh(1) is bonded in a 10-coordinate geometry to six equivalent Fe(1), two equivalent P(1), and two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to six equivalent Fe(1) and three equivalent Rh(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Fe(1) and six equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_FePRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.101
_cell_length_b   6.101
_cell_length_c   3.609
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   116.349
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.390  0.390  0.500  1.0
  Fe  Fe1  1  0.610  0.000  0.500  1.0
  Fe  Fe2  1  0.000  0.610  0.500  1.0
  P  P3  1  0.667  0.333  0.000  1.0
  P  P4  1  0.333  0.667  0.000  1.0
  P  P5  1  0.000  0.000  0.500  1.0
  Rh  Rh6  1  0.731  0.731  0.000  1.0
  Rh  Rh7  1  0.269  0.000  0.000  1.0
  Rh  Rh8  1  0.000  0.269  0.000  1.0
[/CIF]
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The compound described by FeRhP crystallizes in the hexagonal P-62m space group. Fe(1) is bonded in a 11-coordinate geometry to six equivalent Rh(1), one P(2), and four equivalent P(1) atoms. Rh(1) is bonded in a 10-coordinate geometry to six equivalent Fe(1), two equivalent P(1), and two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to six equivalent Fe(1) and three equivalent Rh(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Fe(1) and six equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_FePRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.101
_cell_length_b   6.101
_cell_length_c   3.609
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   116.349
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.390  0.390  0.500  1.0
  Fe  Fe1  1  0.610  0.000  0.500  1.0
  Fe  Fe2  1  0.000  0.610  0.500  1.0
  P  P3  1  0.667  0.333  0.000  1.0
  P  P4  1  0.333  0.667  0.000  1.0
  P  P5  1  0.000  0.000  0.500  1.0
  Rh  Rh6  1  0.731  0.731  0.000  1.0
  Rh  Rh7  1  0.269  0.000  0.000  1.0
  Rh  Rh8  1  0.000  0.269  0.000  1.0
[/CIF]
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