The structure described by Mn(Ge2S5)2(N(CH3)4)2 crystallizes in the tetragonal I-4 space group. The structure consists of four tetramethylammonium molecules inside a Mn(Ge2S5)2 framework. In the Mn(Ge2S5)2 framework, Mn(1) is bonded to four equivalent S(1) atoms to form MnS4 tetrahedra that share corners with four equivalent Ge(1)S4 tetrahedra. Ge(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form GeS4 tetrahedra that share  a cornercorner with one Mn(1)S4 tetrahedra and corners with three equivalent Ge(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one Ge(1) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the third S site, S(3) is bonded in a water-like geometry to two equivalent Ge(1) atoms. is represented by the CIF card [CIF]
data_MnGe4H24C8(S5N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.000
_cell_length_b   10.000
_cell_length_c   10.000
_cell_angle_alpha   122.012
_cell_angle_beta   122.012
_cell_angle_gamma   86.550
_symmetry_Int_Tables_number   1
_cell_volume   684.254
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.250  0.750  0.500  1.0
  Ge  Ge1  1  0.480  0.586  0.244  1.0
  Ge  Ge2  1  0.343  0.237  0.756  1.0
  Ge  Ge3  1  0.763  0.520  0.106  1.0
  Ge  Ge4  1  0.414  0.657  0.894  1.0
  H  H5  1  0.002  0.396  0.694  1.0
  H  H6  1  0.702  0.307  0.306  1.0
  H  H7  1  0.693  0.998  0.394  1.0
  H  H8  1  0.604  0.298  0.606  1.0
  H  H9  1  0.894  0.440  0.804  1.0
  H  H10  1  0.636  0.090  0.196  1.0
  H  H11  1  0.910  0.106  0.546  1.0
  H  H12  1  0.560  0.364  0.454  1.0
  H  H13  1  0.852  0.504  0.650  1.0
  H  H14  1  0.854  0.202  0.350  1.0
  H  H15  1  0.798  0.148  0.652  1.0
  H  H16  1  0.496  0.146  0.348  1.0
  H  H17  1  0.844  0.755  0.807  1.0
  H  H18  1  0.947  0.037  0.193  1.0
  H  H19  1  0.963  0.156  0.911  1.0
  H  H20  1  0.245  0.053  0.089  1.0
  H  H21  1  0.025  0.808  0.037  1.0
  H  H22  1  0.771  0.988  0.963  1.0
  H  H23  1  0.012  0.975  0.783  1.0
  H  H24  1  0.192  0.229  0.217  1.0
  H  H25  1  0.046  0.776  0.855  1.0
  H  H26  1  0.921  0.191  0.145  1.0
  H  H27  1  0.809  0.954  0.729  1.0
  H  H28  1  0.224  0.079  0.271  1.0
  C  C29  1  0.885  0.410  0.676  1.0
  C  C30  1  0.734  0.209  0.324  1.0
  C  C31  1  0.791  0.115  0.525  1.0
  C  C32  1  0.590  0.266  0.475  1.0
  C  C33  1  0.977  0.820  0.918  1.0
  C  C34  1  0.902  0.059  0.082  1.0
  C  C35  1  0.941  0.023  0.843  1.0
  C  C36  1  0.180  0.098  0.157  1.0
  S  S37  1  0.486  0.672  0.499  1.0
  S  S38  1  0.173  0.987  0.501  1.0
  S  S39  1  0.013  0.514  0.186  1.0
  S  S40  1  0.328  0.827  0.814  1.0
  S  S41  1  0.750  0.613  0.359  1.0
  S  S42  1  0.255  0.392  0.641  1.0
  S  S43  1  0.608  0.250  0.863  1.0
  S  S44  1  0.387  0.745  0.137  1.0
  S  S45  1  0.319  0.319  0.000  1.0
  S  S46  1  0.681  0.681  0.000  1.0
  N  N47  1  0.750  0.250  0.500  1.0
  N  N48  1  0.000  0.000  0.000  1.0
[/CIF]
.
The structure described by Mn(Ge2S5)2(N(CH3)4)2 crystallizes in the tetragonal I-4 space group. The structure consists of four tetramethylammonium molecules inside a Mn(Ge2S5)2 framework. In the Mn(Ge2S5)2 framework, Mn(1) is bonded to four equivalent S(1) atoms to form MnS4 tetrahedra that share corners with four equivalent Ge(1)S4 tetrahedra. Ge(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form GeS4 tetrahedra that share  a cornercorner with one Mn(1)S4 tetrahedra and corners with three equivalent Ge(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one Ge(1) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the third S site, S(3) is bonded in a water-like geometry to two equivalent Ge(1) atoms. is represented by the CIF card [CIF]
data_MnGe4H24C8(S5N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.000
_cell_length_b   10.000
_cell_length_c   10.000
_cell_angle_alpha   122.012
_cell_angle_beta   122.012
_cell_angle_gamma   86.550
_symmetry_Int_Tables_number   1
_cell_volume   684.254
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.250  0.750  0.500  1.0
  Ge  Ge1  1  0.480  0.586  0.244  1.0
  Ge  Ge2  1  0.343  0.237  0.756  1.0
  Ge  Ge3  1  0.763  0.520  0.106  1.0
  Ge  Ge4  1  0.414  0.657  0.894  1.0
  H  H5  1  0.002  0.396  0.694  1.0
  H  H6  1  0.702  0.307  0.306  1.0
  H  H7  1  0.693  0.998  0.394  1.0
  H  H8  1  0.604  0.298  0.606  1.0
  H  H9  1  0.894  0.440  0.804  1.0
  H  H10  1  0.636  0.090  0.196  1.0
  H  H11  1  0.910  0.106  0.546  1.0
  H  H12  1  0.560  0.364  0.454  1.0
  H  H13  1  0.852  0.504  0.650  1.0
  H  H14  1  0.854  0.202  0.350  1.0
  H  H15  1  0.798  0.148  0.652  1.0
  H  H16  1  0.496  0.146  0.348  1.0
  H  H17  1  0.844  0.755  0.807  1.0
  H  H18  1  0.947  0.037  0.193  1.0
  H  H19  1  0.963  0.156  0.911  1.0
  H  H20  1  0.245  0.053  0.089  1.0
  H  H21  1  0.025  0.808  0.037  1.0
  H  H22  1  0.771  0.988  0.963  1.0
  H  H23  1  0.012  0.975  0.783  1.0
  H  H24  1  0.192  0.229  0.217  1.0
  H  H25  1  0.046  0.776  0.855  1.0
  H  H26  1  0.921  0.191  0.145  1.0
  H  H27  1  0.809  0.954  0.729  1.0
  H  H28  1  0.224  0.079  0.271  1.0
  C  C29  1  0.885  0.410  0.676  1.0
  C  C30  1  0.734  0.209  0.324  1.0
  C  C31  1  0.791  0.115  0.525  1.0
  C  C32  1  0.590  0.266  0.475  1.0
  C  C33  1  0.977  0.820  0.918  1.0
  C  C34  1  0.902  0.059  0.082  1.0
  C  C35  1  0.941  0.023  0.843  1.0
  C  C36  1  0.180  0.098  0.157  1.0
  S  S37  1  0.486  0.672  0.499  1.0
  S  S38  1  0.173  0.987  0.501  1.0
  S  S39  1  0.013  0.514  0.186  1.0
  S  S40  1  0.328  0.827  0.814  1.0
  S  S41  1  0.750  0.613  0.359  1.0
  S  S42  1  0.255  0.392  0.641  1.0
  S  S43  1  0.608  0.250  0.863  1.0
  S  S44  1  0.387  0.745  0.137  1.0
  S  S45  1  0.319  0.319  0.000  1.0
  S  S46  1  0.681  0.681  0.000  1.0
  N  N47  1  0.750  0.250  0.500  1.0
  N  N48  1  0.000  0.000  0.000  1.0
[/CIF]
.