The material described by Mg(H2O)6SiF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Mg(H2O)6 clusters and two SiF6 clusters. In each Mg(H2O)6 cluster, Mg(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(5), and one H(6) atom. In each SiF6 cluster, Si(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Si(1) atom. is represented by the CIF file [CIF]
data_MgSiH12(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.501
_cell_length_b   6.631
_cell_length_c   8.458
_cell_angle_alpha   79.406
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   523.803
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.000  0.500  1.0
  Mg  Mg1  1  0.000  0.000  0.000  1.0
  Si  Si2  1  0.000  0.500  0.500  1.0
  Si  Si3  1  0.500  0.500  0.000  1.0
  H  H4  1  0.436  0.957  0.820  1.0
  H  H5  1  0.064  0.957  0.320  1.0
  H  H6  1  0.976  0.808  0.740  1.0
  H  H7  1  0.672  0.754  0.705  1.0
  H  H8  1  0.524  0.808  0.240  1.0
  H  H9  1  0.732  0.749  0.531  1.0
  H  H10  1  0.276  0.734  0.522  1.0
  H  H11  1  0.828  0.754  0.205  1.0
  H  H12  1  0.397  0.631  0.639  1.0
  H  H13  1  0.768  0.749  0.031  1.0
  H  H14  1  0.224  0.734  0.022  1.0
  H  H15  1  0.103  0.631  0.139  1.0
  H  H16  1  0.897  0.369  0.861  1.0
  H  H17  1  0.776  0.266  0.978  1.0
  H  H18  1  0.232  0.251  0.969  1.0
  H  H19  1  0.603  0.369  0.361  1.0
  H  H20  1  0.172  0.246  0.795  1.0
  H  H21  1  0.724  0.266  0.478  1.0
  H  H22  1  0.268  0.251  0.469  1.0
  H  H23  1  0.476  0.192  0.760  1.0
  H  H24  1  0.328  0.246  0.295  1.0
  H  H25  1  0.024  0.192  0.260  1.0
  H  H26  1  0.936  0.043  0.680  1.0
  H  H27  1  0.564  0.043  0.180  1.0
  O  O28  1  0.961  0.939  0.774  1.0
  O  O29  1  0.539  0.939  0.274  1.0
  O  O30  1  0.671  0.826  0.593  1.0
  O  O31  1  0.376  0.740  0.547  1.0
  O  O32  1  0.829  0.826  0.093  1.0
  O  O33  1  0.124  0.740  0.047  1.0
  O  O34  1  0.876  0.260  0.953  1.0
  O  O35  1  0.171  0.174  0.907  1.0
  O  O36  1  0.624  0.260  0.453  1.0
  O  O37  1  0.329  0.174  0.407  1.0
  O  O38  1  0.461  0.061  0.726  1.0
  O  O39  1  0.039  0.061  0.226  1.0
  F  F40  1  0.407  0.728  0.968  1.0
  F  F41  1  0.093  0.728  0.468  1.0
  F  F42  1  0.647  0.625  0.911  1.0
  F  F43  1  0.853  0.625  0.411  1.0
  F  F44  1  0.946  0.547  0.684  1.0
  F  F45  1  0.446  0.453  0.816  1.0
  F  F46  1  0.554  0.547  0.184  1.0
  F  F47  1  0.054  0.453  0.316  1.0
  F  F48  1  0.147  0.375  0.589  1.0
  F  F49  1  0.353  0.375  0.088  1.0
  F  F50  1  0.907  0.272  0.532  1.0
  F  F51  1  0.593  0.272  0.032  1.0
[/CIF]
.
The material described by Mg(H2O)6SiF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Mg(H2O)6 clusters and two SiF6 clusters. In each Mg(H2O)6 cluster, Mg(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(5), and one H(6) atom. In each SiF6 cluster, Si(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Si(1) atom. is represented by the CIF file [CIF]
data_MgSiH12(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.501
_cell_length_b   6.631
_cell_length_c   8.458
_cell_angle_alpha   79.406
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   523.803
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.000  0.500  1.0
  Mg  Mg1  1  0.000  0.000  0.000  1.0
  Si  Si2  1  0.000  0.500  0.500  1.0
  Si  Si3  1  0.500  0.500  0.000  1.0
  H  H4  1  0.436  0.957  0.820  1.0
  H  H5  1  0.064  0.957  0.320  1.0
  H  H6  1  0.976  0.808  0.740  1.0
  H  H7  1  0.672  0.754  0.705  1.0
  H  H8  1  0.524  0.808  0.240  1.0
  H  H9  1  0.732  0.749  0.531  1.0
  H  H10  1  0.276  0.734  0.522  1.0
  H  H11  1  0.828  0.754  0.205  1.0
  H  H12  1  0.397  0.631  0.639  1.0
  H  H13  1  0.768  0.749  0.031  1.0
  H  H14  1  0.224  0.734  0.022  1.0
  H  H15  1  0.103  0.631  0.139  1.0
  H  H16  1  0.897  0.369  0.861  1.0
  H  H17  1  0.776  0.266  0.978  1.0
  H  H18  1  0.232  0.251  0.969  1.0
  H  H19  1  0.603  0.369  0.361  1.0
  H  H20  1  0.172  0.246  0.795  1.0
  H  H21  1  0.724  0.266  0.478  1.0
  H  H22  1  0.268  0.251  0.469  1.0
  H  H23  1  0.476  0.192  0.760  1.0
  H  H24  1  0.328  0.246  0.295  1.0
  H  H25  1  0.024  0.192  0.260  1.0
  H  H26  1  0.936  0.043  0.680  1.0
  H  H27  1  0.564  0.043  0.180  1.0
  O  O28  1  0.961  0.939  0.774  1.0
  O  O29  1  0.539  0.939  0.274  1.0
  O  O30  1  0.671  0.826  0.593  1.0
  O  O31  1  0.376  0.740  0.547  1.0
  O  O32  1  0.829  0.826  0.093  1.0
  O  O33  1  0.124  0.740  0.047  1.0
  O  O34  1  0.876  0.260  0.953  1.0
  O  O35  1  0.171  0.174  0.907  1.0
  O  O36  1  0.624  0.260  0.453  1.0
  O  O37  1  0.329  0.174  0.407  1.0
  O  O38  1  0.461  0.061  0.726  1.0
  O  O39  1  0.039  0.061  0.226  1.0
  F  F40  1  0.407  0.728  0.968  1.0
  F  F41  1  0.093  0.728  0.468  1.0
  F  F42  1  0.647  0.625  0.911  1.0
  F  F43  1  0.853  0.625  0.411  1.0
  F  F44  1  0.946  0.547  0.684  1.0
  F  F45  1  0.446  0.453  0.816  1.0
  F  F46  1  0.554  0.547  0.184  1.0
  F  F47  1  0.054  0.453  0.316  1.0
  F  F48  1  0.147  0.375  0.589  1.0
  F  F49  1  0.353  0.375  0.088  1.0
  F  F50  1  0.907  0.272  0.532  1.0
  F  F51  1  0.593  0.272  0.032  1.0
[/CIF]
.