The crystal structure described by CsPO3 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. is represented by the CIF file [CIF]
data_CsPO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.581
_cell_length_b   6.503
_cell_length_c   13.321
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.857
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.234  0.250  0.597  1.0
  Cs  Cs1  1  0.766  0.750  0.403  1.0
  Cs  Cs2  1  0.266  0.750  0.097  1.0
  Cs  Cs3  1  0.734  0.250  0.903  1.0
  P  P4  1  0.313  0.250  0.322  1.0
  P  P5  1  0.687  0.750  0.678  1.0
  P  P6  1  0.187  0.750  0.822  1.0
  P  P7  1  0.813  0.250  0.178  1.0
  O  O8  1  0.259  0.053  0.375  1.0
  O  O9  1  0.741  0.947  0.625  1.0
  O  O10  1  0.241  0.947  0.875  1.0
  O  O11  1  0.741  0.553  0.625  1.0
  O  O12  1  0.759  0.053  0.125  1.0
  O  O13  1  0.259  0.447  0.375  1.0
  O  O14  1  0.759  0.447  0.125  1.0
  O  O15  1  0.241  0.553  0.875  1.0
  O  O16  1  0.150  0.250  0.215  1.0
  O  O17  1  0.850  0.750  0.785  1.0
  O  O18  1  0.350  0.750  0.715  1.0
  O  O19  1  0.650  0.250  0.285  1.0
[/CIF]
.
The crystal structure described by CsPO3 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. is represented by the CIF file [CIF]
data_CsPO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.581
_cell_length_b   6.503
_cell_length_c   13.321
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.857
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.234  0.250  0.597  1.0
  Cs  Cs1  1  0.766  0.750  0.403  1.0
  Cs  Cs2  1  0.266  0.750  0.097  1.0
  Cs  Cs3  1  0.734  0.250  0.903  1.0
  P  P4  1  0.313  0.250  0.322  1.0
  P  P5  1  0.687  0.750  0.678  1.0
  P  P6  1  0.187  0.750  0.822  1.0
  P  P7  1  0.813  0.250  0.178  1.0
  O  O8  1  0.259  0.053  0.375  1.0
  O  O9  1  0.741  0.947  0.625  1.0
  O  O10  1  0.241  0.947  0.875  1.0
  O  O11  1  0.741  0.553  0.625  1.0
  O  O12  1  0.759  0.053  0.125  1.0
  O  O13  1  0.259  0.447  0.375  1.0
  O  O14  1  0.759  0.447  0.125  1.0
  O  O15  1  0.241  0.553  0.875  1.0
  O  O16  1  0.150  0.250  0.215  1.0
  O  O17  1  0.850  0.750  0.785  1.0
  O  O18  1  0.350  0.750  0.715  1.0
  O  O19  1  0.650  0.250  0.285  1.0
[/CIF]
.