The material structure described by W3Re2C crystallizes in the cubic P4_132 space group. W(1) is bonded in a 2-coordinate geometry to six equivalent Re(1) and two equivalent C(1) atoms. Re(1) is bonded to nine equivalent W(1) and three equivalent Re(1) atoms to form ReRe3W9 cuboctahedra that share corners with fifteen equivalent Re(1)Re3W9 cuboctahedra, edges with three equivalent C(1)W6 octahedra, faces with ten equivalent Re(1)Re3W9 cuboctahedra, and faces with four equivalent C(1)W6 octahedra. C(1) is bonded to six equivalent W(1) atoms to form distorted CW6 octahedra that share corners with six equivalent C(1)W6 octahedra, edges with six equivalent Re(1)Re3W9 cuboctahedra, and faces with eight equivalent Re(1)Re3W9 cuboctahedra. The corner-sharing octahedral tilt angles are 23°. is represented by the CIF file [CIF]
data_Re2W3C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.957
_cell_length_b   6.957
_cell_length_c   6.957
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   336.750
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.682  0.682  0.682  1.0
  Re  Re1  1  0.932  0.568  0.432  1.0
  Re  Re2  1  0.568  0.432  0.932  1.0
  Re  Re3  1  0.432  0.932  0.568  1.0
  Re  Re4  1  0.182  0.818  0.318  1.0
  Re  Re5  1  0.818  0.318  0.182  1.0
  Re  Re6  1  0.318  0.182  0.818  1.0
  Re  Re7  1  0.068  0.068  0.068  1.0
  W  W8  1  0.625  0.295  0.545  1.0
  W  W9  1  0.705  0.045  0.875  1.0
  W  W10  1  0.545  0.625  0.295  1.0
  W  W11  1  0.955  0.375  0.795  1.0
  W  W12  1  0.125  0.205  0.455  1.0
  W  W13  1  0.375  0.795  0.955  1.0
  W  W14  1  0.875  0.705  0.045  1.0
  W  W15  1  0.205  0.455  0.125  1.0
  W  W16  1  0.795  0.955  0.375  1.0
  W  W17  1  0.045  0.875  0.705  1.0
  W  W18  1  0.455  0.125  0.205  1.0
  W  W19  1  0.295  0.545  0.625  1.0
  C  C20  1  0.875  0.125  0.625  1.0
  C  C21  1  0.125  0.625  0.875  1.0
  C  C22  1  0.625  0.875  0.125  1.0
  C  C23  1  0.375  0.375  0.375  1.0
[/CIF]
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The material structure described by W3Re2C crystallizes in the cubic P4_132 space group. W(1) is bonded in a 2-coordinate geometry to six equivalent Re(1) and two equivalent C(1) atoms. Re(1) is bonded to nine equivalent W(1) and three equivalent Re(1) atoms to form ReRe3W9 cuboctahedra that share corners with fifteen equivalent Re(1)Re3W9 cuboctahedra, edges with three equivalent C(1)W6 octahedra, faces with ten equivalent Re(1)Re3W9 cuboctahedra, and faces with four equivalent C(1)W6 octahedra. C(1) is bonded to six equivalent W(1) atoms to form distorted CW6 octahedra that share corners with six equivalent C(1)W6 octahedra, edges with six equivalent Re(1)Re3W9 cuboctahedra, and faces with eight equivalent Re(1)Re3W9 cuboctahedra. The corner-sharing octahedral tilt angles are 23°. is represented by the CIF file [CIF]
data_Re2W3C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.957
_cell_length_b   6.957
_cell_length_c   6.957
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   336.750
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.682  0.682  0.682  1.0
  Re  Re1  1  0.932  0.568  0.432  1.0
  Re  Re2  1  0.568  0.432  0.932  1.0
  Re  Re3  1  0.432  0.932  0.568  1.0
  Re  Re4  1  0.182  0.818  0.318  1.0
  Re  Re5  1  0.818  0.318  0.182  1.0
  Re  Re6  1  0.318  0.182  0.818  1.0
  Re  Re7  1  0.068  0.068  0.068  1.0
  W  W8  1  0.625  0.295  0.545  1.0
  W  W9  1  0.705  0.045  0.875  1.0
  W  W10  1  0.545  0.625  0.295  1.0
  W  W11  1  0.955  0.375  0.795  1.0
  W  W12  1  0.125  0.205  0.455  1.0
  W  W13  1  0.375  0.795  0.955  1.0
  W  W14  1  0.875  0.705  0.045  1.0
  W  W15  1  0.205  0.455  0.125  1.0
  W  W16  1  0.795  0.955  0.375  1.0
  W  W17  1  0.045  0.875  0.705  1.0
  W  W18  1  0.455  0.125  0.205  1.0
  W  W19  1  0.295  0.545  0.625  1.0
  C  C20  1  0.875  0.125  0.625  1.0
  C  C21  1  0.125  0.625  0.875  1.0
  C  C22  1  0.625  0.875  0.125  1.0
  C  C23  1  0.375  0.375  0.375  1.0
[/CIF]
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