The structure described by PbN3H3S2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PbN3H3S2 clusters. Pb(1) is bonded in a 3-coordinate geometry to one N(2), one N(3), and one S(1) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal non-coplanar geometry to one Pb(1), one H(1), one H(2), and one H(3) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(1) and one S(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Pb(1) and one N(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. is represented by the CIF file [CIF]
data_H3PbS2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.723
_cell_length_b   5.897
_cell_length_c   6.240
_cell_angle_alpha   88.515
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   615.175
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.281  0.944  0.175  1.0
  H  H1  1  0.781  0.556  0.825  1.0
  H  H2  1  0.719  0.056  0.825  1.0
  H  H3  1  0.219  0.444  0.175  1.0
  H  H4  1  0.347  0.145  0.217  1.0
  H  H5  1  0.847  0.355  0.783  1.0
  H  H6  1  0.653  0.855  0.783  1.0
  H  H7  1  0.153  0.645  0.217  1.0
  H  H8  1  0.341  0.029  0.978  1.0
  H  H9  1  0.841  0.471  0.022  1.0
  H  H10  1  0.659  0.971  0.022  1.0
  H  H11  1  0.159  0.529  0.978  1.0
  Pb  Pb12  1  0.442  0.688  0.223  1.0
  Pb  Pb13  1  0.942  0.812  0.777  1.0
  Pb  Pb14  1  0.558  0.312  0.777  1.0
  Pb  Pb15  1  0.058  0.188  0.223  1.0
  S  S16  1  0.456  0.786  0.654  1.0
  S  S17  1  0.956  0.714  0.346  1.0
  S  S18  1  0.544  0.214  0.346  1.0
  S  S19  1  0.044  0.286  0.654  1.0
  S  S20  1  0.326  0.476  0.620  1.0
  S  S21  1  0.826  0.024  0.380  1.0
  S  S22  1  0.674  0.524  0.380  1.0
  S  S23  1  0.174  0.976  0.620  1.0
  N  N24  1  0.381  0.628  0.766  1.0
  N  N25  1  0.881  0.872  0.234  1.0
  N  N26  1  0.619  0.372  0.234  1.0
  N  N27  1  0.119  0.128  0.766  1.0
  N  N28  1  0.339  0.475  0.378  1.0
  N  N29  1  0.839  0.025  0.622  1.0
  N  N30  1  0.661  0.525  0.622  1.0
  N  N31  1  0.161  0.975  0.378  1.0
  N  N32  1  0.338  0.996  0.139  1.0
  N  N33  1  0.838  0.504  0.861  1.0
  N  N34  1  0.662  0.004  0.861  1.0
  N  N35  1  0.162  0.496  0.139  1.0
[/CIF]
.
The structure described by PbN3H3S2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PbN3H3S2 clusters. Pb(1) is bonded in a 3-coordinate geometry to one N(2), one N(3), and one S(1) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal non-coplanar geometry to one Pb(1), one H(1), one H(2), and one H(3) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(1) and one S(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Pb(1) and one N(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. is represented by the CIF file [CIF]
data_H3PbS2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.723
_cell_length_b   5.897
_cell_length_c   6.240
_cell_angle_alpha   88.515
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   615.175
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.281  0.944  0.175  1.0
  H  H1  1  0.781  0.556  0.825  1.0
  H  H2  1  0.719  0.056  0.825  1.0
  H  H3  1  0.219  0.444  0.175  1.0
  H  H4  1  0.347  0.145  0.217  1.0
  H  H5  1  0.847  0.355  0.783  1.0
  H  H6  1  0.653  0.855  0.783  1.0
  H  H7  1  0.153  0.645  0.217  1.0
  H  H8  1  0.341  0.029  0.978  1.0
  H  H9  1  0.841  0.471  0.022  1.0
  H  H10  1  0.659  0.971  0.022  1.0
  H  H11  1  0.159  0.529  0.978  1.0
  Pb  Pb12  1  0.442  0.688  0.223  1.0
  Pb  Pb13  1  0.942  0.812  0.777  1.0
  Pb  Pb14  1  0.558  0.312  0.777  1.0
  Pb  Pb15  1  0.058  0.188  0.223  1.0
  S  S16  1  0.456  0.786  0.654  1.0
  S  S17  1  0.956  0.714  0.346  1.0
  S  S18  1  0.544  0.214  0.346  1.0
  S  S19  1  0.044  0.286  0.654  1.0
  S  S20  1  0.326  0.476  0.620  1.0
  S  S21  1  0.826  0.024  0.380  1.0
  S  S22  1  0.674  0.524  0.380  1.0
  S  S23  1  0.174  0.976  0.620  1.0
  N  N24  1  0.381  0.628  0.766  1.0
  N  N25  1  0.881  0.872  0.234  1.0
  N  N26  1  0.619  0.372  0.234  1.0
  N  N27  1  0.119  0.128  0.766  1.0
  N  N28  1  0.339  0.475  0.378  1.0
  N  N29  1  0.839  0.025  0.622  1.0
  N  N30  1  0.661  0.525  0.622  1.0
  N  N31  1  0.161  0.975  0.378  1.0
  N  N32  1  0.338  0.996  0.139  1.0
  N  N33  1  0.838  0.504  0.861  1.0
  N  N34  1  0.662  0.004  0.861  1.0
  N  N35  1  0.162  0.496  0.139  1.0
[/CIF]
.