The compound described by Sr3LaCu2HgBiO10 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(5), one O(6), one O(7), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(6), one O(7), one O(8), two equivalent O(10), two equivalent O(4), and two equivalent O(9) atoms. La(1) is bonded in a 9-coordinate geometry to one O(5), one O(6), one O(7), two equivalent O(10), two equivalent O(2), and two equivalent O(9) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(2), one O(4), one O(9), and two equivalent O(6) atoms to form CuO6 octahedra that share  a cornercorner with one Bi(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, and corners with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the second Cu site, Cu(2) is bonded to one O(10), one O(2), one O(3), one O(4), and two equivalent O(7) atoms to form distorted CuO6 octahedra that share  a cornercorner with one Bi(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, and corners with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. Hg(1) is bonded in a linear geometry to one O(1) and one O(10) atom. Bi(1) is bonded to one O(3), one O(9), two equivalent O(5), and two equivalent O(8) atoms to form distorted BiO6 octahedra that share  a cornercorner with one Cu(1)O6 octahedra,  a cornercorner with one Cu(2)O6 octahedra, and edges with two equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Cu(1), and one Hg(1) atom to form distorted OSr4CuHg octahedra that share  a cornercorner with one O(9)Sr2La2CuBi octahedra, corners with two equivalent O(2)Sr2La2Cu2 octahedra, corners with two equivalent O(4)Sr4Cu2 octahedra, corners with four equivalent O(7)Sr3LaCu2 octahedra, corners with four equivalent O(3)Sr4CuBi octahedra, edges with two equivalent O(3)Sr4CuBi octahedra, edges with two equivalent O(1)Sr4CuHg octahedra,  a faceface with one O(2)Sr2La2Cu2 octahedra,  a faceface with one O(4)Sr4Cu2 octahedra, and faces with two equivalent O(6)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 4-52°. In the second O site, O(2) is bonded to two equivalent Sr(2), two equivalent La(1), one Cu(1), and one Cu(2) atom to form distorted OSr2La2Cu2 octahedra that share corners with two equivalent O(9)Sr2La2CuBi octahedra, corners with two equivalent O(4)Sr4Cu2 octahedra, corners with two equivalent O(3)Sr4CuBi octahedra, corners with two equivalent O(1)Sr4CuHg octahedra, edges with two equivalent O(2)Sr2La2Cu2 octahedra,  a faceface with one O(9)Sr2La2CuBi octahedra,  a faceface with one O(3)Sr4CuBi octahedra,  a faceface with one O(1)Sr4CuHg octahedra, faces with two equivalent O(6)Sr3LaCu2 octahedra, and faces with two equivalent O(7)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 2-54°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Cu(2), and one Bi(1) atom to form distorted OSr4CuBi octahedra that share  a cornercorner with one O(9)Sr2La2CuBi octahedra, corners with two equivalent O(2)Sr2La2Cu2 octahedra, corners with two equivalent O(4)Sr4Cu2 octahedra, corners with four equivalent O(6)Sr3LaCu2 octahedra, corners with four equivalent O(1)Sr4CuHg octahedra, edges with two equivalent O(3)Sr4CuBi octahedra, edges with two equivalent O(1)Sr4CuHg octahedra,  a faceface with one O(2)Sr2La2Cu2 octahedra,  a faceface with one O(4)Sr4Cu2 octahedra, and faces with two equivalent O(7)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 9-54°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Cu(1), and one Cu(2) atom to form OSr4Cu2 octahedra that share corners with two equivalent O(2)Sr2La2Cu2 octahedra, corners with two equivalent O(9)Sr2La2CuBi octahedra, corners with two equivalent O(3)Sr4CuBi octahedra, corners with two equivalent O(1)Sr4CuHg octahedra, edges with two equivalent O(4)Sr4Cu2 octahedra,  a faceface with one O(9)Sr2La2CuBi octahedra,  a faceface with one O(3)Sr4CuBi octahedra,  a faceface with one O(1)Sr4CuHg octahedra, faces with two equivalent O(6)Sr3LaCu2 octahedra, and faces with two equivalent O(7)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 2-53°. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to one Sr(1), one La(1), and two equivalent Bi(1) atoms. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(1), and two equivalent Cu(1) atoms to form distorted OSr3LaCu2 octahedra that share corners with two equivalent O(6)Sr3LaCu2 octahedra, corners with four equivalent O(3)Sr4CuBi octahedra, edges with two equivalent O(7)Sr3LaCu2 octahedra, faces with two equivalent O(2)Sr2La2Cu2 octahedra, faces with two equivalent O(9)Sr2La2CuBi octahedra, faces with two equivalent O(4)Sr4Cu2 octahedra, and faces with two equivalent O(1)Sr4CuHg octahedra. The corner-sharing octahedral tilt angles range from 4-53°. In the seventh O site, O(7) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(1), and two equivalent Cu(2) atoms to form distorted OSr3LaCu2 octahedra that share corners with two equivalent O(7)Sr3LaCu2 octahedra, corners with four equivalent O(9)Sr2La2CuBi octahedra, corners with four equivalent O(1)Sr4CuHg octahedra, edges with two equivalent O(6)Sr3LaCu2 octahedra, faces with two equivalent O(2)Sr2La2Cu2 octahedra, faces with two equivalent O(4)Sr4Cu2 octahedra, and faces with two equivalent O(3)Sr4CuBi octahedra. The corner-sharing octahedral tilt angles range from 5-52°. In the eighth O site, O(8) is bonded in a distorted see-saw-like geometry to one Sr(2), one Sr(3), and two equivalent Bi(1) atoms. In the ninth O site, O(9) is bonded to two equivalent Sr(3), two equivalent La(1), one Cu(1), and one Bi(1) atom to form distorted OSr2La2CuBi octahedra that share  a cornercorner with one O(3)Sr4CuBi octahedra,  a cornercorner with one O(1)Sr4CuHg octahedra, corners with two equivalent O(2)Sr2La2Cu2 octahedra, corners with two equivalent O(4)Sr4Cu2 octahedra, corners with four equivalent O(7)Sr3LaCu2 octahedra, edges with two equivalent O(9)Sr2La2CuBi octahedra,  a faceface with one O(2)Sr2La2Cu2 octahedra,  a faceface with one O(4)Sr4Cu2 octahedra, and faces with two equivalent O(6)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 4-53°. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to two equivalent Sr(3), two equivalent La(1), one Cu(2), and one Hg(1) atom. is represented by the CIF card [CIF]
data_Sr3LaCu2HgBiO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.828
_cell_length_b   7.740
_cell_length_c   9.592
_cell_angle_alpha   66.120
_cell_angle_beta   90.046
_cell_angle_gamma   89.802
_symmetry_Int_Tables_number   1
_cell_volume   259.897
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.497  0.104  0.298  1.0
  Sr  Sr1  1  0.498  0.601  0.294  1.0
  Sr  Sr2  1  0.497  0.898  0.698  1.0
  La  La3  1  0.500  0.402  0.698  1.0
  Cu  Cu4  1  0.998  0.246  0.508  1.0
  Cu  Cu5  1  0.998  0.755  0.494  1.0
  Hg  Hg6  1  0.995  0.497  0.004  1.0
  Bi  Bi7  1  0.958  0.997  1.000  1.0
  O  O8  1  0.004  0.394  0.236  1.0
  O  O9  1  0.997  0.493  0.516  1.0
  O  O10  1  0.001  0.875  0.246  1.0
  O  O11  1  0.996  0.003  0.494  1.0
  O  O12  1  0.534  0.193  0.989  1.0
  O  O13  1  0.498  0.252  0.510  1.0
  O  O14  1  0.498  0.743  0.502  1.0
  O  O15  1  0.524  0.819  0.995  1.0
  O  O16  1  0.003  0.133  0.749  1.0
  O  O17  1  0.005  0.595  0.771  1.0
[/CIF]
.
The compound described by Sr3LaCu2HgBiO10 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(5), one O(6), one O(7), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(6), one O(7), one O(8), two equivalent O(10), two equivalent O(4), and two equivalent O(9) atoms. La(1) is bonded in a 9-coordinate geometry to one O(5), one O(6), one O(7), two equivalent O(10), two equivalent O(2), and two equivalent O(9) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(2), one O(4), one O(9), and two equivalent O(6) atoms to form CuO6 octahedra that share  a cornercorner with one Bi(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, and corners with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the second Cu site, Cu(2) is bonded to one O(10), one O(2), one O(3), one O(4), and two equivalent O(7) atoms to form distorted CuO6 octahedra that share  a cornercorner with one Bi(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, and corners with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. Hg(1) is bonded in a linear geometry to one O(1) and one O(10) atom. Bi(1) is bonded to one O(3), one O(9), two equivalent O(5), and two equivalent O(8) atoms to form distorted BiO6 octahedra that share  a cornercorner with one Cu(1)O6 octahedra,  a cornercorner with one Cu(2)O6 octahedra, and edges with two equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Cu(1), and one Hg(1) atom to form distorted OSr4CuHg octahedra that share  a cornercorner with one O(9)Sr2La2CuBi octahedra, corners with two equivalent O(2)Sr2La2Cu2 octahedra, corners with two equivalent O(4)Sr4Cu2 octahedra, corners with four equivalent O(7)Sr3LaCu2 octahedra, corners with four equivalent O(3)Sr4CuBi octahedra, edges with two equivalent O(3)Sr4CuBi octahedra, edges with two equivalent O(1)Sr4CuHg octahedra,  a faceface with one O(2)Sr2La2Cu2 octahedra,  a faceface with one O(4)Sr4Cu2 octahedra, and faces with two equivalent O(6)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 4-52°. In the second O site, O(2) is bonded to two equivalent Sr(2), two equivalent La(1), one Cu(1), and one Cu(2) atom to form distorted OSr2La2Cu2 octahedra that share corners with two equivalent O(9)Sr2La2CuBi octahedra, corners with two equivalent O(4)Sr4Cu2 octahedra, corners with two equivalent O(3)Sr4CuBi octahedra, corners with two equivalent O(1)Sr4CuHg octahedra, edges with two equivalent O(2)Sr2La2Cu2 octahedra,  a faceface with one O(9)Sr2La2CuBi octahedra,  a faceface with one O(3)Sr4CuBi octahedra,  a faceface with one O(1)Sr4CuHg octahedra, faces with two equivalent O(6)Sr3LaCu2 octahedra, and faces with two equivalent O(7)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 2-54°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Cu(2), and one Bi(1) atom to form distorted OSr4CuBi octahedra that share  a cornercorner with one O(9)Sr2La2CuBi octahedra, corners with two equivalent O(2)Sr2La2Cu2 octahedra, corners with two equivalent O(4)Sr4Cu2 octahedra, corners with four equivalent O(6)Sr3LaCu2 octahedra, corners with four equivalent O(1)Sr4CuHg octahedra, edges with two equivalent O(3)Sr4CuBi octahedra, edges with two equivalent O(1)Sr4CuHg octahedra,  a faceface with one O(2)Sr2La2Cu2 octahedra,  a faceface with one O(4)Sr4Cu2 octahedra, and faces with two equivalent O(7)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 9-54°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Cu(1), and one Cu(2) atom to form OSr4Cu2 octahedra that share corners with two equivalent O(2)Sr2La2Cu2 octahedra, corners with two equivalent O(9)Sr2La2CuBi octahedra, corners with two equivalent O(3)Sr4CuBi octahedra, corners with two equivalent O(1)Sr4CuHg octahedra, edges with two equivalent O(4)Sr4Cu2 octahedra,  a faceface with one O(9)Sr2La2CuBi octahedra,  a faceface with one O(3)Sr4CuBi octahedra,  a faceface with one O(1)Sr4CuHg octahedra, faces with two equivalent O(6)Sr3LaCu2 octahedra, and faces with two equivalent O(7)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 2-53°. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to one Sr(1), one La(1), and two equivalent Bi(1) atoms. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(1), and two equivalent Cu(1) atoms to form distorted OSr3LaCu2 octahedra that share corners with two equivalent O(6)Sr3LaCu2 octahedra, corners with four equivalent O(3)Sr4CuBi octahedra, edges with two equivalent O(7)Sr3LaCu2 octahedra, faces with two equivalent O(2)Sr2La2Cu2 octahedra, faces with two equivalent O(9)Sr2La2CuBi octahedra, faces with two equivalent O(4)Sr4Cu2 octahedra, and faces with two equivalent O(1)Sr4CuHg octahedra. The corner-sharing octahedral tilt angles range from 4-53°. In the seventh O site, O(7) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(1), and two equivalent Cu(2) atoms to form distorted OSr3LaCu2 octahedra that share corners with two equivalent O(7)Sr3LaCu2 octahedra, corners with four equivalent O(9)Sr2La2CuBi octahedra, corners with four equivalent O(1)Sr4CuHg octahedra, edges with two equivalent O(6)Sr3LaCu2 octahedra, faces with two equivalent O(2)Sr2La2Cu2 octahedra, faces with two equivalent O(4)Sr4Cu2 octahedra, and faces with two equivalent O(3)Sr4CuBi octahedra. The corner-sharing octahedral tilt angles range from 5-52°. In the eighth O site, O(8) is bonded in a distorted see-saw-like geometry to one Sr(2), one Sr(3), and two equivalent Bi(1) atoms. In the ninth O site, O(9) is bonded to two equivalent Sr(3), two equivalent La(1), one Cu(1), and one Bi(1) atom to form distorted OSr2La2CuBi octahedra that share  a cornercorner with one O(3)Sr4CuBi octahedra,  a cornercorner with one O(1)Sr4CuHg octahedra, corners with two equivalent O(2)Sr2La2Cu2 octahedra, corners with two equivalent O(4)Sr4Cu2 octahedra, corners with four equivalent O(7)Sr3LaCu2 octahedra, edges with two equivalent O(9)Sr2La2CuBi octahedra,  a faceface with one O(2)Sr2La2Cu2 octahedra,  a faceface with one O(4)Sr4Cu2 octahedra, and faces with two equivalent O(6)Sr3LaCu2 octahedra. The corner-sharing octahedral tilt angles range from 4-53°. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to two equivalent Sr(3), two equivalent La(1), one Cu(2), and one Hg(1) atom. is represented by the CIF card [CIF]
data_Sr3LaCu2HgBiO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.828
_cell_length_b   7.740
_cell_length_c   9.592
_cell_angle_alpha   66.120
_cell_angle_beta   90.046
_cell_angle_gamma   89.802
_symmetry_Int_Tables_number   1
_cell_volume   259.897
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.497  0.104  0.298  1.0
  Sr  Sr1  1  0.498  0.601  0.294  1.0
  Sr  Sr2  1  0.497  0.898  0.698  1.0
  La  La3  1  0.500  0.402  0.698  1.0
  Cu  Cu4  1  0.998  0.246  0.508  1.0
  Cu  Cu5  1  0.998  0.755  0.494  1.0
  Hg  Hg6  1  0.995  0.497  0.004  1.0
  Bi  Bi7  1  0.958  0.997  1.000  1.0
  O  O8  1  0.004  0.394  0.236  1.0
  O  O9  1  0.997  0.493  0.516  1.0
  O  O10  1  0.001  0.875  0.246  1.0
  O  O11  1  0.996  0.003  0.494  1.0
  O  O12  1  0.534  0.193  0.989  1.0
  O  O13  1  0.498  0.252  0.510  1.0
  O  O14  1  0.498  0.743  0.502  1.0
  O  O15  1  0.524  0.819  0.995  1.0
  O  O16  1  0.003  0.133  0.749  1.0
  O  O17  1  0.005  0.595  0.771  1.0
[/CIF]
.