The compound described by CsMg14Cd crystallizes in the orthorhombic Amm2 space group. Cs(1) is bonded to two equivalent Mg(6), four equivalent Mg(3), four equivalent Mg(5), and two equivalent Cd(1) atoms to form CsMg10Cd2 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra, corners with six equivalent Cs(1)Mg10Cd2 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Cd(1)Cs2Mg10 cuboctahedra, edges with four equivalent Mg(6)CsMg11 cuboctahedra, edges with eight equivalent Mg(5)CsMg10Cd cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Cd(1)Cs2Mg10 cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, and faces with six equivalent Mg(7)Mg11Cd cuboctahedra. There are seven inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2), two equivalent Mg(6), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cd(1)Cs2Mg10 cuboctahedra, corners with six equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with four equivalent Mg(6)CsMg11 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with eight equivalent Mg(5)CsMg10Cd cuboctahedra, faces with two equivalent Cs(1)Mg10Cd2 cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, faces with four equivalent Mg(4)Mg12 cuboctahedra, and faces with six equivalent Mg(7)Mg11Cd cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1), two equivalent Mg(7), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg10Cd2 cuboctahedra, corners with six equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(7)Mg11Cd cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with eight equivalent Mg(5)CsMg10Cd cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Cd(1)Cs2Mg10 cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, faces with four equivalent Mg(4)Mg12 cuboctahedra, and faces with six equivalent Mg(6)CsMg11 cuboctahedra. In the third Mg site, Mg(3) is bonded in a 12-coordinate geometry to two equivalent Cs(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent Cd(1) atoms. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg10Cd2 cuboctahedra, corners with four equivalent Cd(1)Cs2Mg10 cuboctahedra, corners with six equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(5)CsMg10Cd cuboctahedra, edges with four equivalent Mg(6)CsMg11 cuboctahedra, edges with four equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, and faces with eight equivalent Mg(5)CsMg10Cd cuboctahedra. In the fifth Mg site, Mg(5) is bonded to one Cs(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one Cd(1) atom to form distorted MgCsMg10Cd cuboctahedra that share corners with four equivalent Mg(6)CsMg11 cuboctahedra, corners with four equivalent Mg(7)Mg11Cd cuboctahedra, corners with ten equivalent Mg(5)CsMg10Cd cuboctahedra, edges with two equivalent Cs(1)Mg10Cd2 cuboctahedra, edges with two equivalent Mg(5)CsMg10Cd cuboctahedra, edges with two equivalent Mg(6)CsMg11 cuboctahedra, edges with two equivalent Mg(7)Mg11Cd cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Cd(1)Cs2Mg10 cuboctahedra,  a faceface with one Cs(1)Mg10Cd2 cuboctahedra,  a faceface with one Mg(1)Mg12 cuboctahedra,  a faceface with one Mg(2)Mg12 cuboctahedra,  a faceface with one Cd(1)Cs2Mg10 cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the sixth Mg site, Mg(6) is bonded to one Cs(1), one Mg(1), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(7), and four equivalent Mg(5) atoms to form distorted MgCsMg11 cuboctahedra that share corners with four equivalent Mg(7)Mg11Cd cuboctahedra, corners with six equivalent Mg(6)CsMg11 cuboctahedra, corners with eight equivalent Mg(5)CsMg10Cd cuboctahedra, edges with two equivalent Cs(1)Mg10Cd2 cuboctahedra, edges with two equivalent Mg(7)Mg11Cd cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(5)CsMg10Cd cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra,  a faceface with one Cs(1)Mg10Cd2 cuboctahedra,  a faceface with one Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with three equivalent Mg(2)Mg12 cuboctahedra, faces with three equivalent Cd(1)Cs2Mg10 cuboctahedra, and faces with four equivalent Mg(5)CsMg10Cd cuboctahedra. In the seventh Mg site, Mg(7) is bonded to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), four equivalent Mg(5), and one Cd(1) atom to form distorted MgMg11Cd cuboctahedra that share corners with four equivalent Mg(6)CsMg11 cuboctahedra, corners with six equivalent Mg(7)Mg11Cd cuboctahedra, corners with eight equivalent Mg(5)CsMg10Cd cuboctahedra, edges with two equivalent Mg(6)CsMg11 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Cd(1)Cs2Mg10 cuboctahedra, edges with four equivalent Mg(5)CsMg10Cd cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra,  a faceface with one Mg(2)Mg12 cuboctahedra,  a faceface with one Cd(1)Cs2Mg10 cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with three equivalent Cs(1)Mg10Cd2 cuboctahedra, faces with three equivalent Mg(1)Mg12 cuboctahedra, and faces with four equivalent Mg(5)CsMg10Cd cuboctahedra. Cd(1) is bonded to two equivalent Cs(1), two equivalent Mg(7), four equivalent Mg(3), and four equivalent Mg(5) atoms to form CdCs2Mg10 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra, corners with six equivalent Cd(1)Cs2Mg10 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Cs(1)Mg10Cd2 cuboctahedra, edges with four equivalent Mg(7)Mg11Cd cuboctahedra, edges with eight equivalent Mg(5)CsMg10Cd cuboctahedra, faces with two equivalent Cs(1)Mg10Cd2 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, and faces with six equivalent Mg(6)CsMg11 cuboctahedra. is represented by the CIF card [CIF]
data_CsMg14Cd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.625
_cell_length_b   6.552
_cell_length_c   10.842
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.635
_symmetry_Int_Tables_number   1
_cell_volume   409.077
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.166  0.333  0.125  1.0
  Mg  Mg1  1  0.167  0.333  0.625  1.0
  Mg  Mg2  1  0.161  0.831  0.625  1.0
  Mg  Mg3  1  0.662  0.323  0.125  1.0
  Mg  Mg4  1  0.669  0.338  0.625  1.0
  Mg  Mg5  1  0.662  0.839  0.125  1.0
  Mg  Mg6  1  0.669  0.830  0.625  1.0
  Mg  Mg7  1  0.341  0.161  0.396  1.0
  Mg  Mg8  1  0.341  0.161  0.854  1.0
  Mg  Mg9  1  0.341  0.679  0.396  1.0
  Mg  Mg10  1  0.341  0.679  0.854  1.0
  Mg  Mg11  1  0.820  0.160  0.395  1.0
  Mg  Mg12  1  0.820  0.160  0.855  1.0
  Mg  Mg13  1  0.834  0.667  0.372  1.0
  Mg  Mg14  1  0.834  0.667  0.878  1.0
  Cd  Cd15  1  0.175  0.837  0.125  1.0
[/CIF]
.
The compound described by CsMg14Cd crystallizes in the orthorhombic Amm2 space group. Cs(1) is bonded to two equivalent Mg(6), four equivalent Mg(3), four equivalent Mg(5), and two equivalent Cd(1) atoms to form CsMg10Cd2 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra, corners with six equivalent Cs(1)Mg10Cd2 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Cd(1)Cs2Mg10 cuboctahedra, edges with four equivalent Mg(6)CsMg11 cuboctahedra, edges with eight equivalent Mg(5)CsMg10Cd cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Cd(1)Cs2Mg10 cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, and faces with six equivalent Mg(7)Mg11Cd cuboctahedra. There are seven inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2), two equivalent Mg(6), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cd(1)Cs2Mg10 cuboctahedra, corners with six equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with four equivalent Mg(6)CsMg11 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with eight equivalent Mg(5)CsMg10Cd cuboctahedra, faces with two equivalent Cs(1)Mg10Cd2 cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, faces with four equivalent Mg(4)Mg12 cuboctahedra, and faces with six equivalent Mg(7)Mg11Cd cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1), two equivalent Mg(7), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg10Cd2 cuboctahedra, corners with six equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(7)Mg11Cd cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with eight equivalent Mg(5)CsMg10Cd cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Cd(1)Cs2Mg10 cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, faces with four equivalent Mg(4)Mg12 cuboctahedra, and faces with six equivalent Mg(6)CsMg11 cuboctahedra. In the third Mg site, Mg(3) is bonded in a 12-coordinate geometry to two equivalent Cs(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent Cd(1) atoms. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg10Cd2 cuboctahedra, corners with four equivalent Cd(1)Cs2Mg10 cuboctahedra, corners with six equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(5)CsMg10Cd cuboctahedra, edges with four equivalent Mg(6)CsMg11 cuboctahedra, edges with four equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, and faces with eight equivalent Mg(5)CsMg10Cd cuboctahedra. In the fifth Mg site, Mg(5) is bonded to one Cs(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and one Cd(1) atom to form distorted MgCsMg10Cd cuboctahedra that share corners with four equivalent Mg(6)CsMg11 cuboctahedra, corners with four equivalent Mg(7)Mg11Cd cuboctahedra, corners with ten equivalent Mg(5)CsMg10Cd cuboctahedra, edges with two equivalent Cs(1)Mg10Cd2 cuboctahedra, edges with two equivalent Mg(5)CsMg10Cd cuboctahedra, edges with two equivalent Mg(6)CsMg11 cuboctahedra, edges with two equivalent Mg(7)Mg11Cd cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Cd(1)Cs2Mg10 cuboctahedra,  a faceface with one Cs(1)Mg10Cd2 cuboctahedra,  a faceface with one Mg(1)Mg12 cuboctahedra,  a faceface with one Mg(2)Mg12 cuboctahedra,  a faceface with one Cd(1)Cs2Mg10 cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the sixth Mg site, Mg(6) is bonded to one Cs(1), one Mg(1), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(7), and four equivalent Mg(5) atoms to form distorted MgCsMg11 cuboctahedra that share corners with four equivalent Mg(7)Mg11Cd cuboctahedra, corners with six equivalent Mg(6)CsMg11 cuboctahedra, corners with eight equivalent Mg(5)CsMg10Cd cuboctahedra, edges with two equivalent Cs(1)Mg10Cd2 cuboctahedra, edges with two equivalent Mg(7)Mg11Cd cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(5)CsMg10Cd cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra,  a faceface with one Cs(1)Mg10Cd2 cuboctahedra,  a faceface with one Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with three equivalent Mg(2)Mg12 cuboctahedra, faces with three equivalent Cd(1)Cs2Mg10 cuboctahedra, and faces with four equivalent Mg(5)CsMg10Cd cuboctahedra. In the seventh Mg site, Mg(7) is bonded to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), four equivalent Mg(5), and one Cd(1) atom to form distorted MgMg11Cd cuboctahedra that share corners with four equivalent Mg(6)CsMg11 cuboctahedra, corners with six equivalent Mg(7)Mg11Cd cuboctahedra, corners with eight equivalent Mg(5)CsMg10Cd cuboctahedra, edges with two equivalent Mg(6)CsMg11 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Cd(1)Cs2Mg10 cuboctahedra, edges with four equivalent Mg(5)CsMg10Cd cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra,  a faceface with one Mg(2)Mg12 cuboctahedra,  a faceface with one Cd(1)Cs2Mg10 cuboctahedra, faces with two equivalent Mg(6)CsMg11 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with three equivalent Cs(1)Mg10Cd2 cuboctahedra, faces with three equivalent Mg(1)Mg12 cuboctahedra, and faces with four equivalent Mg(5)CsMg10Cd cuboctahedra. Cd(1) is bonded to two equivalent Cs(1), two equivalent Mg(7), four equivalent Mg(3), and four equivalent Mg(5) atoms to form CdCs2Mg10 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra, corners with six equivalent Cd(1)Cs2Mg10 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Cs(1)Mg10Cd2 cuboctahedra, edges with four equivalent Mg(7)Mg11Cd cuboctahedra, edges with eight equivalent Mg(5)CsMg10Cd cuboctahedra, faces with two equivalent Cs(1)Mg10Cd2 cuboctahedra, faces with two equivalent Mg(7)Mg11Cd cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with four equivalent Mg(5)CsMg10Cd cuboctahedra, and faces with six equivalent Mg(6)CsMg11 cuboctahedra. is represented by the CIF card [CIF]
data_CsMg14Cd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.625
_cell_length_b   6.552
_cell_length_c   10.842
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.635
_symmetry_Int_Tables_number   1
_cell_volume   409.077
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.166  0.333  0.125  1.0
  Mg  Mg1  1  0.167  0.333  0.625  1.0
  Mg  Mg2  1  0.161  0.831  0.625  1.0
  Mg  Mg3  1  0.662  0.323  0.125  1.0
  Mg  Mg4  1  0.669  0.338  0.625  1.0
  Mg  Mg5  1  0.662  0.839  0.125  1.0
  Mg  Mg6  1  0.669  0.830  0.625  1.0
  Mg  Mg7  1  0.341  0.161  0.396  1.0
  Mg  Mg8  1  0.341  0.161  0.854  1.0
  Mg  Mg9  1  0.341  0.679  0.396  1.0
  Mg  Mg10  1  0.341  0.679  0.854  1.0
  Mg  Mg11  1  0.820  0.160  0.395  1.0
  Mg  Mg12  1  0.820  0.160  0.855  1.0
  Mg  Mg13  1  0.834  0.667  0.372  1.0
  Mg  Mg14  1  0.834  0.667  0.878  1.0
  Cd  Cd15  1  0.175  0.837  0.125  1.0
[/CIF]
.