The structure described by Nd4Rh4Ge3 crystallizes in the monoclinic C2/c space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 11-coordinate geometry to two equivalent Rh(1), five equivalent Rh(2), one Ge(1), and three equivalent Ge(2) atoms. In the second Nd site, Nd(2) is bonded in a 10-coordinate geometry to one Rh(2), four equivalent Rh(1), two equivalent Ge(2), and three equivalent Ge(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one Ge(2), and two equivalent Ge(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one Nd(2), five equivalent Nd(1), and three equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to two equivalent Nd(1), six equivalent Nd(2), and four equivalent Rh(1) atoms to form a mixture of distorted edge and face-sharing GeNd8Rh4 cuboctahedra. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Nd(2), three equivalent Nd(1), one Rh(1), and three equivalent Rh(2) atoms. is represented by the CIF file [CIF]
data_Nd4Ge3Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.938
_cell_length_b   10.938
_cell_length_c   8.005
_cell_angle_alpha   70.677
_cell_angle_beta   70.677
_cell_angle_gamma   30.188
_symmetry_Int_Tables_number   1
_cell_volume   452.463
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.215  0.444  0.399  1.0
  Nd  Nd1  1  0.556  0.785  0.101  1.0
  Nd  Nd2  1  0.444  0.215  0.899  1.0
  Nd  Nd3  1  0.920  0.215  0.331  1.0
  Nd  Nd4  1  0.785  0.080  0.169  1.0
  Nd  Nd5  1  0.080  0.785  0.669  1.0
  Nd  Nd6  1  0.215  0.920  0.831  1.0
  Nd  Nd7  1  0.785  0.556  0.601  1.0
  Ge  Ge8  1  0.643  0.357  0.750  1.0
  Ge  Ge9  1  0.357  0.643  0.250  1.0
  Ge  Ge10  1  0.292  0.053  0.440  1.0
  Ge  Ge11  1  0.947  0.708  0.060  1.0
  Ge  Ge12  1  0.708  0.947  0.560  1.0
  Ge  Ge13  1  0.053  0.292  0.940  1.0
  Rh  Rh14  1  0.303  0.573  0.017  1.0
  Rh  Rh15  1  0.573  0.303  0.517  1.0
  Rh  Rh16  1  0.697  0.427  0.983  1.0
  Rh  Rh17  1  0.071  0.370  0.184  1.0
  Rh  Rh18  1  0.630  0.929  0.316  1.0
  Rh  Rh19  1  0.427  0.697  0.483  1.0
  Rh  Rh20  1  0.929  0.630  0.816  1.0
  Rh  Rh21  1  0.370  0.071  0.684  1.0
[/CIF]
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The structure described by Nd4Rh4Ge3 crystallizes in the monoclinic C2/c space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 11-coordinate geometry to two equivalent Rh(1), five equivalent Rh(2), one Ge(1), and three equivalent Ge(2) atoms. In the second Nd site, Nd(2) is bonded in a 10-coordinate geometry to one Rh(2), four equivalent Rh(1), two equivalent Ge(2), and three equivalent Ge(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one Ge(2), and two equivalent Ge(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one Nd(2), five equivalent Nd(1), and three equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to two equivalent Nd(1), six equivalent Nd(2), and four equivalent Rh(1) atoms to form a mixture of distorted edge and face-sharing GeNd8Rh4 cuboctahedra. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Nd(2), three equivalent Nd(1), one Rh(1), and three equivalent Rh(2) atoms. is represented by the CIF file [CIF]
data_Nd4Ge3Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.938
_cell_length_b   10.938
_cell_length_c   8.005
_cell_angle_alpha   70.677
_cell_angle_beta   70.677
_cell_angle_gamma   30.188
_symmetry_Int_Tables_number   1
_cell_volume   452.463
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.215  0.444  0.399  1.0
  Nd  Nd1  1  0.556  0.785  0.101  1.0
  Nd  Nd2  1  0.444  0.215  0.899  1.0
  Nd  Nd3  1  0.920  0.215  0.331  1.0
  Nd  Nd4  1  0.785  0.080  0.169  1.0
  Nd  Nd5  1  0.080  0.785  0.669  1.0
  Nd  Nd6  1  0.215  0.920  0.831  1.0
  Nd  Nd7  1  0.785  0.556  0.601  1.0
  Ge  Ge8  1  0.643  0.357  0.750  1.0
  Ge  Ge9  1  0.357  0.643  0.250  1.0
  Ge  Ge10  1  0.292  0.053  0.440  1.0
  Ge  Ge11  1  0.947  0.708  0.060  1.0
  Ge  Ge12  1  0.708  0.947  0.560  1.0
  Ge  Ge13  1  0.053  0.292  0.940  1.0
  Rh  Rh14  1  0.303  0.573  0.017  1.0
  Rh  Rh15  1  0.573  0.303  0.517  1.0
  Rh  Rh16  1  0.697  0.427  0.983  1.0
  Rh  Rh17  1  0.071  0.370  0.184  1.0
  Rh  Rh18  1  0.630  0.929  0.316  1.0
  Rh  Rh19  1  0.427  0.697  0.483  1.0
  Rh  Rh20  1  0.929  0.630  0.816  1.0
  Rh  Rh21  1  0.370  0.071  0.684  1.0
[/CIF]
.