The material structure described by Li2PtO2 is Ilmenite-like structured and crystallizes in the orthorhombic Immm space group. Li(1) is bonded to four equivalent O(1) atoms to form a mixture of distorted corner and edge-sharing LiO4 trigonal pyramids. Pt(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to four equivalent Li(1) and two equivalent Pt(1) atoms to form a mixture of corner and edge-sharing OLi4Pt2 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. is represented by the CIF file [CIF]
data_Li2PtO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.162
_cell_length_b   5.162
_cell_length_c   5.162
_cell_angle_alpha   144.841
_cell_angle_beta   135.902
_cell_angle_gamma   57.608
_symmetry_Int_Tables_number   1
_cell_volume   54.679
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.689  0.689  0.000  1.0
  Li  Li1  1  0.311  0.311  0.000  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  O  O3  1  0.850  0.350  0.500  1.0
  O  O4  1  0.150  0.650  0.500  1.0
[/CIF]
.
The material structure described by Li2PtO2 is Ilmenite-like structured and crystallizes in the orthorhombic Immm space group. Li(1) is bonded to four equivalent O(1) atoms to form a mixture of distorted corner and edge-sharing LiO4 trigonal pyramids. Pt(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to four equivalent Li(1) and two equivalent Pt(1) atoms to form a mixture of corner and edge-sharing OLi4Pt2 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. is represented by the CIF file [CIF]
data_Li2PtO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.162
_cell_length_b   5.162
_cell_length_c   5.162
_cell_angle_alpha   144.841
_cell_angle_beta   135.902
_cell_angle_gamma   57.608
_symmetry_Int_Tables_number   1
_cell_volume   54.679
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.689  0.689  0.000  1.0
  Li  Li1  1  0.311  0.311  0.000  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  O  O3  1  0.850  0.350  0.500  1.0
  O  O4  1  0.150  0.650  0.500  1.0
[/CIF]
.