The material structure described by AsO2(CF3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and one AsO2 cluster. In the AsO2 cluster, As(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(1) is bonded in an L-shaped geometry to two equivalent As(1) atoms. is represented by the CIF card [CIF]
data_AsC2(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.735
_cell_length_b   7.221
_cell_length_c   9.844
_cell_angle_alpha   102.732
_cell_angle_beta   101.855
_cell_angle_gamma   109.337
_symmetry_Int_Tables_number   1
_cell_volume   357.651
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.818  0.929  0.867  1.0
  As  As1  1  0.182  0.071  0.133  1.0
  C  C2  1  0.879  0.761  0.632  1.0
  C  C3  1  0.121  0.239  0.368  1.0
  C  C4  1  0.820  0.184  0.801  1.0
  C  C5  1  0.180  0.816  0.199  1.0
  O  O6  1  0.857  0.057  0.062  1.0
  O  O7  1  0.143  0.943  0.938  1.0
  O  O8  1  0.552  0.713  0.801  1.0
  O  O9  1  0.448  0.287  0.199  1.0
  F  F10  1  0.906  0.589  0.643  1.0
  F  F11  1  0.094  0.411  0.357  1.0
  F  F12  1  0.099  0.898  0.626  1.0
  F  F13  1  0.901  0.102  0.374  1.0
  F  F14  1  0.680  0.723  0.518  1.0
  F  F15  1  0.320  0.277  0.482  1.0
  F  F16  1  0.762  0.139  0.654  1.0
  F  F17  1  0.238  0.861  0.346  1.0
  F  F18  1  0.641  0.241  0.845  1.0
  F  F19  1  0.359  0.759  0.155  1.0
  F  F20  1  0.056  0.339  0.864  1.0
  F  F21  1  0.944  0.661  0.136  1.0
[/CIF]
.
The material structure described by AsO2(CF3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and one AsO2 cluster. In the AsO2 cluster, As(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(1) is bonded in an L-shaped geometry to two equivalent As(1) atoms. is represented by the CIF card [CIF]
data_AsC2(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.735
_cell_length_b   7.221
_cell_length_c   9.844
_cell_angle_alpha   102.732
_cell_angle_beta   101.855
_cell_angle_gamma   109.337
_symmetry_Int_Tables_number   1
_cell_volume   357.651
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.818  0.929  0.867  1.0
  As  As1  1  0.182  0.071  0.133  1.0
  C  C2  1  0.879  0.761  0.632  1.0
  C  C3  1  0.121  0.239  0.368  1.0
  C  C4  1  0.820  0.184  0.801  1.0
  C  C5  1  0.180  0.816  0.199  1.0
  O  O6  1  0.857  0.057  0.062  1.0
  O  O7  1  0.143  0.943  0.938  1.0
  O  O8  1  0.552  0.713  0.801  1.0
  O  O9  1  0.448  0.287  0.199  1.0
  F  F10  1  0.906  0.589  0.643  1.0
  F  F11  1  0.094  0.411  0.357  1.0
  F  F12  1  0.099  0.898  0.626  1.0
  F  F13  1  0.901  0.102  0.374  1.0
  F  F14  1  0.680  0.723  0.518  1.0
  F  F15  1  0.320  0.277  0.482  1.0
  F  F16  1  0.762  0.139  0.654  1.0
  F  F17  1  0.238  0.861  0.346  1.0
  F  F18  1  0.641  0.241  0.845  1.0
  F  F19  1  0.359  0.759  0.155  1.0
  F  F20  1  0.056  0.339  0.864  1.0
  F  F21  1  0.944  0.661  0.136  1.0
[/CIF]
.