The compound described by Tb4Mn is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Tb4Mn clusters. Tb(1) is bonded in a single-bond geometry to one Mn(1) atom. Mn(1) is bonded in a tetrahedral geometry to four equivalent Tb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb4Mn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.447
_cell_length_b   7.447
_cell_length_c   7.447
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   292.088
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.386  0.386  0.386  1.0
  Tb  Tb1  1  0.386  0.386  0.842  1.0
  Tb  Tb2  1  0.386  0.842  0.386  1.0
  Tb  Tb3  1  0.864  0.864  0.408  1.0
  Tb  Tb4  1  0.864  0.864  0.864  1.0
  Tb  Tb5  1  0.842  0.386  0.386  1.0
  Tb  Tb6  1  0.864  0.408  0.864  1.0
  Tb  Tb7  1  0.408  0.864  0.864  1.0
  Mn  Mn8  1  0.000  0.000  0.000  1.0
  Mn  Mn9  1  0.250  0.250  0.250  1.0
[/CIF]
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The compound described by Tb4Mn is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Tb4Mn clusters. Tb(1) is bonded in a single-bond geometry to one Mn(1) atom. Mn(1) is bonded in a tetrahedral geometry to four equivalent Tb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb4Mn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.447
_cell_length_b   7.447
_cell_length_c   7.447
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   292.088
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.386  0.386  0.386  1.0
  Tb  Tb1  1  0.386  0.386  0.842  1.0
  Tb  Tb2  1  0.386  0.842  0.386  1.0
  Tb  Tb3  1  0.864  0.864  0.408  1.0
  Tb  Tb4  1  0.864  0.864  0.864  1.0
  Tb  Tb5  1  0.842  0.386  0.386  1.0
  Tb  Tb6  1  0.864  0.408  0.864  1.0
  Tb  Tb7  1  0.408  0.864  0.864  1.0
  Mn  Mn8  1  0.000  0.000  0.000  1.0
  Mn  Mn9  1  0.250  0.250  0.250  1.0
[/CIF]
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