The compound described by MgWMoZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with three equivalent W(1)O6 octahedra, corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent Mo(1)O6 octahedra,  a faceface with one W(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-47°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with six equivalent Mo(1)O6 octahedra, edges with three equivalent Zn(1)O6 octahedra, and  a faceface with one Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-55°. Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MoO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, corners with six equivalent W(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-55°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with three equivalent Mo(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra,  a faceface with one Mg(1)O6 octahedra, and  a faceface with one Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-48°. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), one W(1), one Mo(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), one W(1), one Mo(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), one W(1), one Mo(1), and one Zn(1) atom. is represented by the CIF file [CIF]
data_MgZn2MoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.064
_cell_length_b   6.061
_cell_length_c   8.091
_cell_angle_alpha   80.449
_cell_angle_beta   138.605
_cell_angle_gamma   127.599
_symmetry_Int_Tables_number   1
_cell_volume   129.424
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.004  0.307  0.162  1.0
  Zn  Zn1  1  0.004  0.634  0.326  1.0
  Zn  Zn2  1  0.005  0.478  0.748  1.0
  Mo  Mo3  1  0.004  0.994  0.506  1.0
  W  W4  1  0.004  0.944  0.980  1.0
  O  O5  1  0.279  0.112  0.379  1.0
  O  O6  1  0.634  0.779  0.557  1.0
  O  O7  1  0.359  0.467  0.105  1.0
  O  O8  1  0.375  0.837  0.750  1.0
  O  O9  1  0.685  0.148  0.238  1.0
  O  O10  1  0.690  0.467  0.927  1.0
[/CIF]
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The compound described by MgWMoZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with three equivalent W(1)O6 octahedra, corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent Mo(1)O6 octahedra,  a faceface with one W(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-47°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with six equivalent Mo(1)O6 octahedra, edges with three equivalent Zn(1)O6 octahedra, and  a faceface with one Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-55°. Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MoO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, corners with six equivalent W(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-55°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with three equivalent Mo(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra,  a faceface with one Mg(1)O6 octahedra, and  a faceface with one Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-48°. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), one W(1), one Mo(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), one W(1), one Mo(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), one W(1), one Mo(1), and one Zn(1) atom. is represented by the CIF file [CIF]
data_MgZn2MoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.064
_cell_length_b   6.061
_cell_length_c   8.091
_cell_angle_alpha   80.449
_cell_angle_beta   138.605
_cell_angle_gamma   127.599
_symmetry_Int_Tables_number   1
_cell_volume   129.424
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.004  0.307  0.162  1.0
  Zn  Zn1  1  0.004  0.634  0.326  1.0
  Zn  Zn2  1  0.005  0.478  0.748  1.0
  Mo  Mo3  1  0.004  0.994  0.506  1.0
  W  W4  1  0.004  0.944  0.980  1.0
  O  O5  1  0.279  0.112  0.379  1.0
  O  O6  1  0.634  0.779  0.557  1.0
  O  O7  1  0.359  0.467  0.105  1.0
  O  O8  1  0.375  0.837  0.750  1.0
  O  O9  1  0.685  0.148  0.238  1.0
  O  O10  1  0.690  0.467  0.927  1.0
[/CIF]
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