The material described by Eu2SmNbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the cubic Pn-3 space group. There are two inequivalent Eu sites. In the first Eu site, Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share faces with four equivalent Sm(1)O6 octahedra and faces with four equivalent Nb(1)O6 octahedra. In the second Eu site, Eu(2) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Sm(1) is bonded to six equivalent O(1) atoms to form SmO6 octahedra that share corners with six equivalent Nb(1)O6 octahedra and faces with two equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 28°. Nb(1) is bonded to six equivalent O(1) atoms to form NbO6 octahedra that share corners with six equivalent Sm(1)O6 octahedra and faces with two equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 28°. O(1) is bonded in a 3-coordinate geometry to one Eu(1), one Eu(2), one Sm(1), and one Nb(1) atom. is represented by the CIF card [CIF]
data_SmEu2NbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.328
_cell_length_b   8.328
_cell_length_c   8.328
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   577.622
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.250  0.250  0.250  1.0
  Sm  Sm1  1  0.250  0.750  0.750  1.0
  Sm  Sm2  1  0.750  0.250  0.750  1.0
  Sm  Sm3  1  0.750  0.750  0.250  1.0
  Eu  Eu4  1  0.500  0.500  0.500  1.0
  Eu  Eu5  1  0.000  0.000  0.000  1.0
  Eu  Eu6  1  0.000  0.000  0.500  1.0
  Eu  Eu7  1  0.000  0.500  0.000  1.0
  Eu  Eu8  1  0.500  0.000  0.000  1.0
  Eu  Eu9  1  0.500  0.500  0.000  1.0
  Eu  Eu10  1  0.500  0.000  0.500  1.0
  Eu  Eu11  1  0.000  0.500  0.500  1.0
  Nb  Nb12  1  0.750  0.750  0.750  1.0
  Nb  Nb13  1  0.750  0.250  0.250  1.0
  Nb  Nb14  1  0.250  0.750  0.250  1.0
  Nb  Nb15  1  0.250  0.250  0.750  1.0
  O  O16  1  0.211  0.298  0.518  1.0
  O  O17  1  0.211  0.702  0.482  1.0
  O  O18  1  0.789  0.298  0.482  1.0
  O  O19  1  0.789  0.702  0.518  1.0
  O  O20  1  0.298  0.518  0.211  1.0
  O  O21  1  0.702  0.482  0.211  1.0
  O  O22  1  0.298  0.482  0.789  1.0
  O  O23  1  0.702  0.518  0.789  1.0
  O  O24  1  0.518  0.211  0.298  1.0
  O  O25  1  0.482  0.211  0.702  1.0
  O  O26  1  0.482  0.789  0.298  1.0
  O  O27  1  0.518  0.789  0.702  1.0
  O  O28  1  0.289  0.202  0.982  1.0
  O  O29  1  0.289  0.798  0.018  1.0
  O  O30  1  0.711  0.202  0.018  1.0
  O  O31  1  0.711  0.798  0.982  1.0
  O  O32  1  0.202  0.982  0.289  1.0
  O  O33  1  0.798  0.018  0.289  1.0
  O  O34  1  0.202  0.018  0.711  1.0
  O  O35  1  0.798  0.982  0.711  1.0
  O  O36  1  0.982  0.289  0.202  1.0
  O  O37  1  0.018  0.289  0.798  1.0
  O  O38  1  0.018  0.711  0.202  1.0
  O  O39  1  0.982  0.711  0.798  1.0
[/CIF]
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The material described by Eu2SmNbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the cubic Pn-3 space group. There are two inequivalent Eu sites. In the first Eu site, Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share faces with four equivalent Sm(1)O6 octahedra and faces with four equivalent Nb(1)O6 octahedra. In the second Eu site, Eu(2) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Sm(1) is bonded to six equivalent O(1) atoms to form SmO6 octahedra that share corners with six equivalent Nb(1)O6 octahedra and faces with two equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 28°. Nb(1) is bonded to six equivalent O(1) atoms to form NbO6 octahedra that share corners with six equivalent Sm(1)O6 octahedra and faces with two equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 28°. O(1) is bonded in a 3-coordinate geometry to one Eu(1), one Eu(2), one Sm(1), and one Nb(1) atom. is represented by the CIF card [CIF]
data_SmEu2NbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.328
_cell_length_b   8.328
_cell_length_c   8.328
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   577.622
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.250  0.250  0.250  1.0
  Sm  Sm1  1  0.250  0.750  0.750  1.0
  Sm  Sm2  1  0.750  0.250  0.750  1.0
  Sm  Sm3  1  0.750  0.750  0.250  1.0
  Eu  Eu4  1  0.500  0.500  0.500  1.0
  Eu  Eu5  1  0.000  0.000  0.000  1.0
  Eu  Eu6  1  0.000  0.000  0.500  1.0
  Eu  Eu7  1  0.000  0.500  0.000  1.0
  Eu  Eu8  1  0.500  0.000  0.000  1.0
  Eu  Eu9  1  0.500  0.500  0.000  1.0
  Eu  Eu10  1  0.500  0.000  0.500  1.0
  Eu  Eu11  1  0.000  0.500  0.500  1.0
  Nb  Nb12  1  0.750  0.750  0.750  1.0
  Nb  Nb13  1  0.750  0.250  0.250  1.0
  Nb  Nb14  1  0.250  0.750  0.250  1.0
  Nb  Nb15  1  0.250  0.250  0.750  1.0
  O  O16  1  0.211  0.298  0.518  1.0
  O  O17  1  0.211  0.702  0.482  1.0
  O  O18  1  0.789  0.298  0.482  1.0
  O  O19  1  0.789  0.702  0.518  1.0
  O  O20  1  0.298  0.518  0.211  1.0
  O  O21  1  0.702  0.482  0.211  1.0
  O  O22  1  0.298  0.482  0.789  1.0
  O  O23  1  0.702  0.518  0.789  1.0
  O  O24  1  0.518  0.211  0.298  1.0
  O  O25  1  0.482  0.211  0.702  1.0
  O  O26  1  0.482  0.789  0.298  1.0
  O  O27  1  0.518  0.789  0.702  1.0
  O  O28  1  0.289  0.202  0.982  1.0
  O  O29  1  0.289  0.798  0.018  1.0
  O  O30  1  0.711  0.202  0.018  1.0
  O  O31  1  0.711  0.798  0.982  1.0
  O  O32  1  0.202  0.982  0.289  1.0
  O  O33  1  0.798  0.018  0.289  1.0
  O  O34  1  0.202  0.018  0.711  1.0
  O  O35  1  0.798  0.982  0.711  1.0
  O  O36  1  0.982  0.289  0.202  1.0
  O  O37  1  0.018  0.289  0.798  1.0
  O  O38  1  0.018  0.711  0.202  1.0
  O  O39  1  0.982  0.711  0.798  1.0
[/CIF]
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