The material structure described by Zn3Pb3SbAs2O14 crystallizes in the trigonal P321 space group. Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with two equivalent As(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 62°. Pb(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra. As(1) is bonded to one O(3) and three equivalent O(2) atoms to form AsO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Pb(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1), one Pb(1), and one As(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_Zn3SbAs2Pb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.677
_cell_length_b   8.677
_cell_length_c   5.380
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   350.787
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.237  0.000  0.500  1.0
  Zn  Zn1  1  0.000  0.237  0.500  1.0
  Zn  Zn2  1  0.763  0.763  0.500  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  As  As4  1  0.333  0.667  0.538  1.0
  As  As5  1  0.667  0.333  0.462  1.0
  Pb  Pb6  1  0.605  0.000  0.000  1.0
  Pb  Pb7  1  0.000  0.605  0.000  1.0
  Pb  Pb8  1  0.395  0.395  0.000  1.0
  O  O9  1  0.125  0.217  0.214  1.0
  O  O10  1  0.783  0.908  0.214  1.0
  O  O11  1  0.217  0.125  0.786  1.0
  O  O12  1  0.092  0.875  0.214  1.0
  O  O13  1  0.908  0.783  0.786  1.0
  O  O14  1  0.875  0.092  0.786  1.0
  O  O15  1  0.459  0.196  0.333  1.0
  O  O16  1  0.804  0.262  0.333  1.0
  O  O17  1  0.196  0.459  0.667  1.0
  O  O18  1  0.738  0.541  0.333  1.0
  O  O19  1  0.262  0.804  0.667  1.0
  O  O20  1  0.541  0.738  0.667  1.0
  O  O21  1  0.333  0.667  0.219  1.0
  O  O22  1  0.667  0.333  0.781  1.0
[/CIF]
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The material structure described by Zn3Pb3SbAs2O14 crystallizes in the trigonal P321 space group. Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with two equivalent As(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 62°. Pb(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra. As(1) is bonded to one O(3) and three equivalent O(2) atoms to form AsO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Pb(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1), one Pb(1), and one As(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_Zn3SbAs2Pb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.677
_cell_length_b   8.677
_cell_length_c   5.380
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   350.787
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.237  0.000  0.500  1.0
  Zn  Zn1  1  0.000  0.237  0.500  1.0
  Zn  Zn2  1  0.763  0.763  0.500  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  As  As4  1  0.333  0.667  0.538  1.0
  As  As5  1  0.667  0.333  0.462  1.0
  Pb  Pb6  1  0.605  0.000  0.000  1.0
  Pb  Pb7  1  0.000  0.605  0.000  1.0
  Pb  Pb8  1  0.395  0.395  0.000  1.0
  O  O9  1  0.125  0.217  0.214  1.0
  O  O10  1  0.783  0.908  0.214  1.0
  O  O11  1  0.217  0.125  0.786  1.0
  O  O12  1  0.092  0.875  0.214  1.0
  O  O13  1  0.908  0.783  0.786  1.0
  O  O14  1  0.875  0.092  0.786  1.0
  O  O15  1  0.459  0.196  0.333  1.0
  O  O16  1  0.804  0.262  0.333  1.0
  O  O17  1  0.196  0.459  0.667  1.0
  O  O18  1  0.738  0.541  0.333  1.0
  O  O19  1  0.262  0.804  0.667  1.0
  O  O20  1  0.541  0.738  0.667  1.0
  O  O21  1  0.333  0.667  0.219  1.0
  O  O22  1  0.667  0.333  0.781  1.0
[/CIF]
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