The compound described by Mn12O7F17 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(4), one O(7), one F(1), one F(13), one F(14), and one F(5) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(7)OF5 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(11)O2F4 octahedra,  an edgeedge with one Mn(5)O2F4 octahedra, and  an edgeedge with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the second Mn site, Mn(2) is bonded to one O(3), one F(1), one F(12), one F(14), one F(4), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(11)O2F4 octahedra, corners with four equivalent Mn(9)OF5 octahedra,  an edgeedge with one Mn(1)O2F4 octahedra, and  an edgeedge with one Mn(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-60°. In the third Mn site, Mn(3) is bonded to one O(2), one O(3), one O(6), one F(12), one F(15), and one F(3) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(8)O3F3 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(10)O2F4 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. In the fourth Mn site, Mn(4) is bonded in a 6-coordinate geometry to one O(1), one O(5), one F(11), one F(16), one F(17), and one F(2) atom. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(4), one F(13), one F(17), one F(6), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(11)O2F4 octahedra, corners with two equivalent Mn(12)OF5 octahedra, corners with four equivalent Mn(7)OF5 octahedra, and  an edgeedge with one Mn(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. In the sixth Mn site, Mn(6) is bonded to one O(2), one F(10), one F(15), one F(16), one F(2), and one F(7) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(12)OF5 octahedra, corners with four equivalent Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-64°. In the seventh Mn site, Mn(7) is bonded to one O(1), one F(11), one F(13), one F(5), one F(6), and one F(9) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with four equivalent Mn(5)O2F4 octahedra,  an edgeedge with one Mn(11)O2F4 octahedra, and  an edgeedge with one Mn(12)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In the eighth Mn site, Mn(8) is bonded to one O(2), one O(5), one O(6), one F(10), one F(16), and one F(7) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(3)O3F3 octahedra, corners with four equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(12)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-64°. In the ninth Mn site, Mn(9) is bonded to one O(7), one F(1), one F(12), one F(3), one F(4), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with two equivalent Mn(3)O3F3 octahedra, corners with four equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(11)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In the tenth Mn site, Mn(10) is bonded to one O(3), one O(6), one F(15), one F(3), one F(7), and one F(8) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with two equivalent Mn(6)OF5 octahedra, corners with four equivalent Mn(3)O3F3 octahedra,  an edgeedge with one Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. In the eleventh Mn site, Mn(11) is bonded to one O(4), one O(7), one F(14), one F(4), one F(5), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(5)O2F4 octahedra, corners with two equivalent Mn(2)OF5 octahedra, corners with four equivalent Mn(1)O2F4 octahedra,  an edgeedge with one Mn(7)OF5 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the twelfth Mn site, Mn(12) is bonded to one O(5), one F(10), one F(11), one F(17), one F(2), and one F(6) atom to form MnOF5 octahedra that share corners with two equivalent Mn(5)O2F4 octahedra, corners with two equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-51°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. There are seventeen inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the fifteenth F site, F(15) is bonded in a distorted T-shaped geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the sixteenth F site, F(16) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the seventeenth F site, F(17) is bonded in a 3-coordinate geometry to one Mn(12), one Mn(4), and one Mn(5) atom. is represented by the CIF card [CIF]
data_Mn12O7F17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.768
_cell_length_b   5.764
_cell_length_c   15.889
_cell_angle_alpha   89.800
_cell_angle_beta   89.473
_cell_angle_gamma   88.604
_symmetry_Int_Tables_number   1
_cell_volume   436.563
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.992  0.156  0.415  1.0
  Mn  Mn1  1  0.028  0.839  0.238  1.0
  Mn  Mn2  1  0.010  0.160  0.076  1.0
  Mn  Mn3  1  0.052  0.171  0.749  1.0
  Mn  Mn4  1  0.022  0.854  0.581  1.0
  Mn  Mn5  1  0.001  0.858  0.918  1.0
  Mn  Mn6  1  0.473  0.321  0.585  1.0
  Mn  Mn7  1  0.491  0.331  0.924  1.0
  Mn  Mn8  1  0.530  0.341  0.259  1.0
  Mn  Mn9  1  0.487  0.649  0.082  1.0
  Mn  Mn10  1  0.503  0.666  0.420  1.0
  Mn  Mn11  1  0.510  0.631  0.755  1.0
  O  O12  1  0.211  0.097  0.640  1.0
  O  O13  1  0.206  0.122  0.969  1.0
  O  O14  1  0.230  0.889  0.127  1.0
  O  O15  1  0.216  0.899  0.469  1.0
  O  O16  1  0.306  0.388  0.810  1.0
  O  O17  1  0.701  0.383  0.029  1.0
  O  O18  1  0.727  0.387  0.369  1.0
  F  F19  1  0.225  0.118  0.306  1.0
  F  F20  1  0.250  0.876  0.807  1.0
  F  F21  1  0.267  0.396  0.151  1.0
  F  F22  1  0.278  0.619  0.310  1.0
  F  F23  1  0.245  0.401  0.474  1.0
  F  F24  1  0.265  0.603  0.645  1.0
  F  F25  1  0.249  0.615  0.976  1.0
  F  F26  1  0.724  0.619  0.193  1.0
  F  F27  1  0.726  0.626  0.533  1.0
  F  F28  1  0.739  0.614  0.867  1.0
  F  F29  1  0.741  0.380  0.693  1.0
  F  F30  1  0.788  0.126  0.186  1.0
  F  F31  1  0.754  0.114  0.521  1.0
  F  F32  1  0.764  0.892  0.351  1.0
  F  F33  1  0.738  0.882  0.024  1.0
  F  F34  1  0.784  0.120  0.851  1.0
  F  F35  1  0.767  0.860  0.697  1.0
[/CIF]
.
The compound described by Mn12O7F17 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(4), one O(7), one F(1), one F(13), one F(14), and one F(5) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(7)OF5 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(11)O2F4 octahedra,  an edgeedge with one Mn(5)O2F4 octahedra, and  an edgeedge with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the second Mn site, Mn(2) is bonded to one O(3), one F(1), one F(12), one F(14), one F(4), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(11)O2F4 octahedra, corners with four equivalent Mn(9)OF5 octahedra,  an edgeedge with one Mn(1)O2F4 octahedra, and  an edgeedge with one Mn(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-60°. In the third Mn site, Mn(3) is bonded to one O(2), one O(3), one O(6), one F(12), one F(15), and one F(3) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(8)O3F3 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(10)O2F4 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. In the fourth Mn site, Mn(4) is bonded in a 6-coordinate geometry to one O(1), one O(5), one F(11), one F(16), one F(17), and one F(2) atom. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(4), one F(13), one F(17), one F(6), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(11)O2F4 octahedra, corners with two equivalent Mn(12)OF5 octahedra, corners with four equivalent Mn(7)OF5 octahedra, and  an edgeedge with one Mn(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. In the sixth Mn site, Mn(6) is bonded to one O(2), one F(10), one F(15), one F(16), one F(2), and one F(7) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(12)OF5 octahedra, corners with four equivalent Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-64°. In the seventh Mn site, Mn(7) is bonded to one O(1), one F(11), one F(13), one F(5), one F(6), and one F(9) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with four equivalent Mn(5)O2F4 octahedra,  an edgeedge with one Mn(11)O2F4 octahedra, and  an edgeedge with one Mn(12)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In the eighth Mn site, Mn(8) is bonded to one O(2), one O(5), one O(6), one F(10), one F(16), and one F(7) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(3)O3F3 octahedra, corners with four equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(12)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-64°. In the ninth Mn site, Mn(9) is bonded to one O(7), one F(1), one F(12), one F(3), one F(4), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with two equivalent Mn(3)O3F3 octahedra, corners with four equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(11)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In the tenth Mn site, Mn(10) is bonded to one O(3), one O(6), one F(15), one F(3), one F(7), and one F(8) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with two equivalent Mn(6)OF5 octahedra, corners with four equivalent Mn(3)O3F3 octahedra,  an edgeedge with one Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. In the eleventh Mn site, Mn(11) is bonded to one O(4), one O(7), one F(14), one F(4), one F(5), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(5)O2F4 octahedra, corners with two equivalent Mn(2)OF5 octahedra, corners with four equivalent Mn(1)O2F4 octahedra,  an edgeedge with one Mn(7)OF5 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the twelfth Mn site, Mn(12) is bonded to one O(5), one F(10), one F(11), one F(17), one F(2), and one F(6) atom to form MnOF5 octahedra that share corners with two equivalent Mn(5)O2F4 octahedra, corners with two equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-51°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. There are seventeen inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the fifteenth F site, F(15) is bonded in a distorted T-shaped geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the sixteenth F site, F(16) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the seventeenth F site, F(17) is bonded in a 3-coordinate geometry to one Mn(12), one Mn(4), and one Mn(5) atom. is represented by the CIF card [CIF]
data_Mn12O7F17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.768
_cell_length_b   5.764
_cell_length_c   15.889
_cell_angle_alpha   89.800
_cell_angle_beta   89.473
_cell_angle_gamma   88.604
_symmetry_Int_Tables_number   1
_cell_volume   436.563
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.992  0.156  0.415  1.0
  Mn  Mn1  1  0.028  0.839  0.238  1.0
  Mn  Mn2  1  0.010  0.160  0.076  1.0
  Mn  Mn3  1  0.052  0.171  0.749  1.0
  Mn  Mn4  1  0.022  0.854  0.581  1.0
  Mn  Mn5  1  0.001  0.858  0.918  1.0
  Mn  Mn6  1  0.473  0.321  0.585  1.0
  Mn  Mn7  1  0.491  0.331  0.924  1.0
  Mn  Mn8  1  0.530  0.341  0.259  1.0
  Mn  Mn9  1  0.487  0.649  0.082  1.0
  Mn  Mn10  1  0.503  0.666  0.420  1.0
  Mn  Mn11  1  0.510  0.631  0.755  1.0
  O  O12  1  0.211  0.097  0.640  1.0
  O  O13  1  0.206  0.122  0.969  1.0
  O  O14  1  0.230  0.889  0.127  1.0
  O  O15  1  0.216  0.899  0.469  1.0
  O  O16  1  0.306  0.388  0.810  1.0
  O  O17  1  0.701  0.383  0.029  1.0
  O  O18  1  0.727  0.387  0.369  1.0
  F  F19  1  0.225  0.118  0.306  1.0
  F  F20  1  0.250  0.876  0.807  1.0
  F  F21  1  0.267  0.396  0.151  1.0
  F  F22  1  0.278  0.619  0.310  1.0
  F  F23  1  0.245  0.401  0.474  1.0
  F  F24  1  0.265  0.603  0.645  1.0
  F  F25  1  0.249  0.615  0.976  1.0
  F  F26  1  0.724  0.619  0.193  1.0
  F  F27  1  0.726  0.626  0.533  1.0
  F  F28  1  0.739  0.614  0.867  1.0
  F  F29  1  0.741  0.380  0.693  1.0
  F  F30  1  0.788  0.126  0.186  1.0
  F  F31  1  0.754  0.114  0.521  1.0
  F  F32  1  0.764  0.892  0.351  1.0
  F  F33  1  0.738  0.882  0.024  1.0
  F  F34  1  0.784  0.120  0.851  1.0
  F  F35  1  0.767  0.860  0.697  1.0
[/CIF]
.