The crystal structure described by MoOCl4C3S2Cl3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two 3,4,5-trichloro-3h-dithiole molecules and two MoOCl4 clusters. In each MoOCl4 cluster, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one Cl(1), one Cl(2), one Cl(4), and one Cl(7) atom. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoC3S2Cl7O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.331
_cell_length_b   8.379
_cell_length_c   9.001
_cell_angle_alpha   72.352
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   742.489
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.769  0.434  0.879  1.0
  Mo  Mo1  1  0.231  0.434  0.379  1.0
  C  C2  1  0.335  0.922  0.958  1.0
  C  C3  1  0.773  0.853  0.405  1.0
  C  C4  1  0.665  0.922  0.458  1.0
  C  C5  1  0.693  0.060  0.509  1.0
  C  C6  1  0.227  0.853  0.905  1.0
  C  C7  1  0.307  0.060  0.009  1.0
  S  S8  1  0.920  0.941  0.417  1.0
  S  S9  1  0.150  0.121  0.006  1.0
  S  S10  1  0.850  0.121  0.506  1.0
  S  S11  1  0.080  0.941  0.917  1.0
  Cl  Cl12  1  0.189  0.718  0.366  1.0
  Cl  Cl13  1  0.821  0.141  0.979  1.0
  Cl  Cl14  1  0.513  0.844  0.457  1.0
  Cl  Cl15  1  0.811  0.718  0.866  1.0
  Cl  Cl16  1  0.953  0.453  0.716  1.0
  Cl  Cl17  1  0.767  0.694  0.328  1.0
  Cl  Cl18  1  0.581  0.170  0.572  1.0
  Cl  Cl19  1  0.681  0.403  0.131  1.0
  Cl  Cl20  1  0.179  0.141  0.479  1.0
  Cl  Cl21  1  0.047  0.453  0.216  1.0
  Cl  Cl22  1  0.419  0.170  0.072  1.0
  Cl  Cl23  1  0.319  0.403  0.631  1.0
  Cl  Cl24  1  0.233  0.694  0.828  1.0
  Cl  Cl25  1  0.487  0.844  0.957  1.0
  O  O26  1  0.640  0.446  0.760  1.0
  O  O27  1  0.360  0.446  0.260  1.0
[/CIF]
.
The crystal structure described by MoOCl4C3S2Cl3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two 3,4,5-trichloro-3h-dithiole molecules and two MoOCl4 clusters. In each MoOCl4 cluster, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one Cl(1), one Cl(2), one Cl(4), and one Cl(7) atom. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoC3S2Cl7O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.331
_cell_length_b   8.379
_cell_length_c   9.001
_cell_angle_alpha   72.352
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   742.489
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.769  0.434  0.879  1.0
  Mo  Mo1  1  0.231  0.434  0.379  1.0
  C  C2  1  0.335  0.922  0.958  1.0
  C  C3  1  0.773  0.853  0.405  1.0
  C  C4  1  0.665  0.922  0.458  1.0
  C  C5  1  0.693  0.060  0.509  1.0
  C  C6  1  0.227  0.853  0.905  1.0
  C  C7  1  0.307  0.060  0.009  1.0
  S  S8  1  0.920  0.941  0.417  1.0
  S  S9  1  0.150  0.121  0.006  1.0
  S  S10  1  0.850  0.121  0.506  1.0
  S  S11  1  0.080  0.941  0.917  1.0
  Cl  Cl12  1  0.189  0.718  0.366  1.0
  Cl  Cl13  1  0.821  0.141  0.979  1.0
  Cl  Cl14  1  0.513  0.844  0.457  1.0
  Cl  Cl15  1  0.811  0.718  0.866  1.0
  Cl  Cl16  1  0.953  0.453  0.716  1.0
  Cl  Cl17  1  0.767  0.694  0.328  1.0
  Cl  Cl18  1  0.581  0.170  0.572  1.0
  Cl  Cl19  1  0.681  0.403  0.131  1.0
  Cl  Cl20  1  0.179  0.141  0.479  1.0
  Cl  Cl21  1  0.047  0.453  0.216  1.0
  Cl  Cl22  1  0.419  0.170  0.072  1.0
  Cl  Cl23  1  0.319  0.403  0.631  1.0
  Cl  Cl24  1  0.233  0.694  0.828  1.0
  Cl  Cl25  1  0.487  0.844  0.957  1.0
  O  O26  1  0.640  0.446  0.760  1.0
  O  O27  1  0.360  0.446  0.260  1.0
[/CIF]
.