The compound described by Rb2V2Mn(O3Cl)2 crystallizes in the triclinic P1 space group. There are four inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 3-coordinate geometry to one O(6) and two equivalent O(5) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(9), and two equivalent Cl(3) atoms. In the third Rb site, Rb(3) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(8), two equivalent O(11), and one Cl(3) atom. In the fourth Rb site, Rb(4) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(8), one Cl(2), and two equivalent Cl(1) atoms. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), one O(7), and one Cl(4) atom to form distorted corner-sharing VClO3 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(12), one O(9), one Cl(2), and one Cl(3) atom to form a mixture of distorted edge and corner-sharing VCl2O3 trigonal bipyramids. In the third V site, V(3) is bonded to one O(1), one O(12), one O(2), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one V(1)ClO3 tetrahedra,  a cornercorner with one V(2)Cl2O3 trigonal bipyramid, and  an edgeedge with one V(2)Cl2O3 trigonal bipyramid. In the fourth V site, V(4) is bonded to one O(10), one O(5), one O(6), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one V(1)ClO3 tetrahedra and  a cornercorner with one Mn(1)O4 tetrahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(11), one O(3), and one O(8) atom to form MnO4 tetrahedra that share  a cornercorner with one V(4)O4 tetrahedra. In the second Mn site, Mn(2) is bonded in a 5-coordinate geometry to one O(10), one O(6), one O(7), one O(8), and one Cl(1) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Rb(3), one Rb(4), one V(2), and one V(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Rb(2) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one V(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one V(4) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1), one V(4), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a T-shaped geometry to one V(1), one V(4), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Rb(3), one Rb(4), one Mn(1), and one Mn(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Rb(2), one V(2), and one V(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one V(4), one Mn(1), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Rb(4), two equivalent Rb(3), and one Mn(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Rb(4), one V(2), and one V(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to two equivalent Rb(4) and one Mn(2) atom. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to one Rb(4) and one V(2) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to one Rb(3), two equivalent Rb(2), and one V(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_Rb2MnV2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.515
_cell_length_b   9.857
_cell_length_c   10.978
_cell_angle_alpha   95.272
_cell_angle_beta   97.494
_cell_angle_gamma   95.482
_symmetry_Int_Tables_number   1
_cell_volume   585.697
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.445  0.786  0.912  1.0
  Rb  Rb1  1  0.917  0.582  0.618  1.0
  Rb  Rb2  1  0.399  0.287  0.449  1.0
  Rb  Rb3  1  0.692  0.066  0.220  1.0
  Mn  Mn4  1  0.803  0.435  0.263  1.0
  Mn  Mn5  1  0.247  0.322  0.067  1.0
  V  V6  1  0.189  0.291  0.770  1.0
  V  V7  1  0.319  0.854  0.456  1.0
  V  V8  1  0.956  0.002  0.549  1.0
  V  V9  1  0.859  0.498  0.974  1.0
  Cl  Cl10  1  0.079  0.082  0.039  1.0
  Cl  Cl11  1  0.286  0.809  0.243  1.0
  Cl  Cl12  1  0.400  0.636  0.509  1.0
  Cl  Cl13  1  0.487  0.163  0.844  1.0
  O  O14  1  0.107  0.025  0.423  1.0
  O  O15  1  0.007  0.148  0.656  1.0
  O  O16  1  0.773  0.583  0.335  1.0
  O  O17  1  0.299  0.401  0.680  1.0
  O  O18  1  0.964  0.651  0.934  1.0
  O  O19  1  0.550  0.488  0.955  1.0
  O  O20  1  0.008  0.364  0.887  1.0
  O  O21  1  0.525  0.334  0.200  1.0
  O  O22  1  0.111  0.863  0.595  1.0
  O  O23  1  0.979  0.455  0.128  1.0
  O  O24  1  0.928  0.330  0.362  1.0
  O  O25  1  0.637  0.956  0.503  1.0
[/CIF]
.
The compound described by Rb2V2Mn(O3Cl)2 crystallizes in the triclinic P1 space group. There are four inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 3-coordinate geometry to one O(6) and two equivalent O(5) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(9), and two equivalent Cl(3) atoms. In the third Rb site, Rb(3) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(8), two equivalent O(11), and one Cl(3) atom. In the fourth Rb site, Rb(4) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(8), one Cl(2), and two equivalent Cl(1) atoms. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), one O(7), and one Cl(4) atom to form distorted corner-sharing VClO3 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(12), one O(9), one Cl(2), and one Cl(3) atom to form a mixture of distorted edge and corner-sharing VCl2O3 trigonal bipyramids. In the third V site, V(3) is bonded to one O(1), one O(12), one O(2), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one V(1)ClO3 tetrahedra,  a cornercorner with one V(2)Cl2O3 trigonal bipyramid, and  an edgeedge with one V(2)Cl2O3 trigonal bipyramid. In the fourth V site, V(4) is bonded to one O(10), one O(5), one O(6), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one V(1)ClO3 tetrahedra and  a cornercorner with one Mn(1)O4 tetrahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(11), one O(3), and one O(8) atom to form MnO4 tetrahedra that share  a cornercorner with one V(4)O4 tetrahedra. In the second Mn site, Mn(2) is bonded in a 5-coordinate geometry to one O(10), one O(6), one O(7), one O(8), and one Cl(1) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Rb(3), one Rb(4), one V(2), and one V(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Rb(2) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one V(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one V(4) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1), one V(4), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a T-shaped geometry to one V(1), one V(4), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Rb(3), one Rb(4), one Mn(1), and one Mn(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Rb(2), one V(2), and one V(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one V(4), one Mn(1), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Rb(4), two equivalent Rb(3), and one Mn(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Rb(4), one V(2), and one V(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to two equivalent Rb(4) and one Mn(2) atom. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to one Rb(4) and one V(2) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to one Rb(3), two equivalent Rb(2), and one V(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_Rb2MnV2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.515
_cell_length_b   9.857
_cell_length_c   10.978
_cell_angle_alpha   95.272
_cell_angle_beta   97.494
_cell_angle_gamma   95.482
_symmetry_Int_Tables_number   1
_cell_volume   585.697
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.445  0.786  0.912  1.0
  Rb  Rb1  1  0.917  0.582  0.618  1.0
  Rb  Rb2  1  0.399  0.287  0.449  1.0
  Rb  Rb3  1  0.692  0.066  0.220  1.0
  Mn  Mn4  1  0.803  0.435  0.263  1.0
  Mn  Mn5  1  0.247  0.322  0.067  1.0
  V  V6  1  0.189  0.291  0.770  1.0
  V  V7  1  0.319  0.854  0.456  1.0
  V  V8  1  0.956  0.002  0.549  1.0
  V  V9  1  0.859  0.498  0.974  1.0
  Cl  Cl10  1  0.079  0.082  0.039  1.0
  Cl  Cl11  1  0.286  0.809  0.243  1.0
  Cl  Cl12  1  0.400  0.636  0.509  1.0
  Cl  Cl13  1  0.487  0.163  0.844  1.0
  O  O14  1  0.107  0.025  0.423  1.0
  O  O15  1  0.007  0.148  0.656  1.0
  O  O16  1  0.773  0.583  0.335  1.0
  O  O17  1  0.299  0.401  0.680  1.0
  O  O18  1  0.964  0.651  0.934  1.0
  O  O19  1  0.550  0.488  0.955  1.0
  O  O20  1  0.008  0.364  0.887  1.0
  O  O21  1  0.525  0.334  0.200  1.0
  O  O22  1  0.111  0.863  0.595  1.0
  O  O23  1  0.979  0.455  0.128  1.0
  O  O24  1  0.928  0.330  0.362  1.0
  O  O25  1  0.637  0.956  0.503  1.0
[/CIF]
.