The material described by PHSF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PHSF2 clusters. P(1) is bonded in a 4-coordinate geometry to one H(1), one S(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. S(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PHSF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.504
_cell_length_b   8.675
_cell_length_c   9.403
_cell_angle_alpha   81.865
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   363.713
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.958  0.417  0.272  1.0
  P  P1  1  0.458  0.083  0.728  1.0
  P  P2  1  0.042  0.583  0.728  1.0
  P  P3  1  0.542  0.917  0.272  1.0
  H  H4  1  0.169  0.536  0.236  1.0
  H  H5  1  0.669  0.964  0.764  1.0
  H  H6  1  0.831  0.464  0.764  1.0
  H  H7  1  0.331  0.036  0.236  1.0
  S  S8  1  0.749  0.335  0.125  1.0
  S  S9  1  0.249  0.165  0.875  1.0
  S  S10  1  0.251  0.665  0.875  1.0
  S  S11  1  0.751  0.835  0.125  1.0
  F  F12  1  0.760  0.485  0.387  1.0
  F  F13  1  0.260  0.015  0.613  1.0
  F  F14  1  0.240  0.515  0.613  1.0
  F  F15  1  0.740  0.985  0.387  1.0
  F  F16  1  0.143  0.295  0.378  1.0
  F  F17  1  0.643  0.205  0.622  1.0
  F  F18  1  0.857  0.705  0.622  1.0
  F  F19  1  0.357  0.795  0.378  1.0
[/CIF]
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The material described by PHSF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PHSF2 clusters. P(1) is bonded in a 4-coordinate geometry to one H(1), one S(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. S(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PHSF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.504
_cell_length_b   8.675
_cell_length_c   9.403
_cell_angle_alpha   81.865
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   363.713
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.958  0.417  0.272  1.0
  P  P1  1  0.458  0.083  0.728  1.0
  P  P2  1  0.042  0.583  0.728  1.0
  P  P3  1  0.542  0.917  0.272  1.0
  H  H4  1  0.169  0.536  0.236  1.0
  H  H5  1  0.669  0.964  0.764  1.0
  H  H6  1  0.831  0.464  0.764  1.0
  H  H7  1  0.331  0.036  0.236  1.0
  S  S8  1  0.749  0.335  0.125  1.0
  S  S9  1  0.249  0.165  0.875  1.0
  S  S10  1  0.251  0.665  0.875  1.0
  S  S11  1  0.751  0.835  0.125  1.0
  F  F12  1  0.760  0.485  0.387  1.0
  F  F13  1  0.260  0.015  0.613  1.0
  F  F14  1  0.240  0.515  0.613  1.0
  F  F15  1  0.740  0.985  0.387  1.0
  F  F16  1  0.143  0.295  0.378  1.0
  F  F17  1  0.643  0.205  0.622  1.0
  F  F18  1  0.857  0.705  0.622  1.0
  F  F19  1  0.357  0.795  0.378  1.0
[/CIF]
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