The material structure described by Re3(TeI)7 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re3(TeI)7 cluster. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 9-coordinate geometry to two equivalent Re(2), two equivalent Re(3), one Te(1), one Te(4), one Te(5), one Te(6), and one Te(7) atom. In the second Re site, Re(2) is bonded in a 9-coordinate geometry to two equivalent Re(1), two equivalent Re(3), one Te(2), one Te(4), one Te(5), one Te(6), and one Te(7) atom. In the third Re site, Re(3) is bonded in a 9-coordinate geometry to two equivalent Re(1), two equivalent Re(2), one Te(3), one Te(4), one Te(5), one Te(6), and one Te(7) atom. There are seven inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted trigonal pyramidal geometry to one Re(1), one I(1), one I(2), and one I(3) atom. In the second Te site, Te(2) is bonded in a trigonal non-coplanar geometry to one Re(2), one I(4), and one I(7) atom. In the third Te site, Te(3) is bonded in a trigonal non-coplanar geometry to one Re(3), one I(5), and one I(6) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the fifth Te site, Te(5) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the sixth Te site, Te(6) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the seventh Te site, Te(7) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. There are seven inequivalent I sites. In the first I site, I(7) is bonded in a single-bond geometry to one Te(2) atom. In the second I site, I(1) is bonded in a single-bond geometry to one Te(1) atom. In the third I site, I(2) is bonded in a single-bond geometry to one Te(1) atom. In the fourth I site, I(3) is bonded in a single-bond geometry to one Te(1) atom. In the fifth I site, I(4) is bonded in a single-bond geometry to one Te(2) atom. In the sixth I site, I(5) is bonded in a single-bond geometry to one Te(3) atom. In the seventh I site, I(6) is bonded in a single-bond geometry to one Te(3) atom. is represented by the CIF file [CIF]
data_Re3(TeI)7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.025
_cell_length_b   11.055
_cell_length_c   12.356
_cell_angle_alpha   86.585
_cell_angle_beta   104.799
_cell_angle_gamma   118.171
_symmetry_Int_Tables_number   1
_cell_volume   1280.271
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.939  0.119  0.911  1.0
  Re  Re1  1  0.061  0.881  0.089  1.0
  Re  Re2  1  0.843  0.845  0.908  1.0
  Re  Re3  1  0.157  0.155  0.092  1.0
  Re  Re4  1  0.115  0.016  0.902  1.0
  Re  Re5  1  0.885  0.984  0.098  1.0
  Te  Te6  1  0.850  0.291  0.799  1.0
  Te  Te7  1  0.150  0.709  0.201  1.0
  Te  Te8  1  0.622  0.614  0.797  1.0
  Te  Te9  1  0.378  0.386  0.203  1.0
  Te  Te10  1  0.294  0.042  0.778  1.0
  Te  Te11  1  0.706  0.958  0.222  1.0
  Te  Te12  1  0.668  0.949  0.918  1.0
  Te  Te13  1  0.332  0.051  0.082  1.0
  Te  Te14  1  0.018  0.740  0.898  1.0
  Te  Te15  1  0.982  0.260  0.102  1.0
  Te  Te16  1  0.898  0.979  0.722  1.0
  Te  Te17  1  0.102  0.021  0.278  1.0
  Te  Te18  1  0.211  0.290  0.905  1.0
  Te  Te19  1  0.789  0.710  0.095  1.0
  I  I20  1  0.391  0.874  0.369  1.0
  I  I21  1  0.609  0.126  0.631  1.0
  I  I22  1  0.983  0.594  0.359  1.0
  I  I23  1  0.017  0.406  0.641  1.0
  I  I24  1  0.357  0.688  0.053  1.0
  I  I25  1  0.643  0.312  0.947  1.0
  I  I26  1  0.705  0.548  0.624  1.0
  I  I27  1  0.295  0.452  0.376  1.0
  I  I28  1  0.144  0.830  0.608  1.0
  I  I29  1  0.856  0.170  0.392  1.0
  I  I30  1  0.290  0.233  0.623  1.0
  I  I31  1  0.710  0.767  0.377  1.0
  I  I32  1  0.432  0.690  0.658  1.0
  I  I33  1  0.568  0.310  0.342  1.0
[/CIF]
.
The material structure described by Re3(TeI)7 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re3(TeI)7 cluster. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 9-coordinate geometry to two equivalent Re(2), two equivalent Re(3), one Te(1), one Te(4), one Te(5), one Te(6), and one Te(7) atom. In the second Re site, Re(2) is bonded in a 9-coordinate geometry to two equivalent Re(1), two equivalent Re(3), one Te(2), one Te(4), one Te(5), one Te(6), and one Te(7) atom. In the third Re site, Re(3) is bonded in a 9-coordinate geometry to two equivalent Re(1), two equivalent Re(2), one Te(3), one Te(4), one Te(5), one Te(6), and one Te(7) atom. There are seven inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted trigonal pyramidal geometry to one Re(1), one I(1), one I(2), and one I(3) atom. In the second Te site, Te(2) is bonded in a trigonal non-coplanar geometry to one Re(2), one I(4), and one I(7) atom. In the third Te site, Te(3) is bonded in a trigonal non-coplanar geometry to one Re(3), one I(5), and one I(6) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the fifth Te site, Te(5) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the sixth Te site, Te(6) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the seventh Te site, Te(7) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. There are seven inequivalent I sites. In the first I site, I(7) is bonded in a single-bond geometry to one Te(2) atom. In the second I site, I(1) is bonded in a single-bond geometry to one Te(1) atom. In the third I site, I(2) is bonded in a single-bond geometry to one Te(1) atom. In the fourth I site, I(3) is bonded in a single-bond geometry to one Te(1) atom. In the fifth I site, I(4) is bonded in a single-bond geometry to one Te(2) atom. In the sixth I site, I(5) is bonded in a single-bond geometry to one Te(3) atom. In the seventh I site, I(6) is bonded in a single-bond geometry to one Te(3) atom. is represented by the CIF file [CIF]
data_Re3(TeI)7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.025
_cell_length_b   11.055
_cell_length_c   12.356
_cell_angle_alpha   86.585
_cell_angle_beta   104.799
_cell_angle_gamma   118.171
_symmetry_Int_Tables_number   1
_cell_volume   1280.271
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.939  0.119  0.911  1.0
  Re  Re1  1  0.061  0.881  0.089  1.0
  Re  Re2  1  0.843  0.845  0.908  1.0
  Re  Re3  1  0.157  0.155  0.092  1.0
  Re  Re4  1  0.115  0.016  0.902  1.0
  Re  Re5  1  0.885  0.984  0.098  1.0
  Te  Te6  1  0.850  0.291  0.799  1.0
  Te  Te7  1  0.150  0.709  0.201  1.0
  Te  Te8  1  0.622  0.614  0.797  1.0
  Te  Te9  1  0.378  0.386  0.203  1.0
  Te  Te10  1  0.294  0.042  0.778  1.0
  Te  Te11  1  0.706  0.958  0.222  1.0
  Te  Te12  1  0.668  0.949  0.918  1.0
  Te  Te13  1  0.332  0.051  0.082  1.0
  Te  Te14  1  0.018  0.740  0.898  1.0
  Te  Te15  1  0.982  0.260  0.102  1.0
  Te  Te16  1  0.898  0.979  0.722  1.0
  Te  Te17  1  0.102  0.021  0.278  1.0
  Te  Te18  1  0.211  0.290  0.905  1.0
  Te  Te19  1  0.789  0.710  0.095  1.0
  I  I20  1  0.391  0.874  0.369  1.0
  I  I21  1  0.609  0.126  0.631  1.0
  I  I22  1  0.983  0.594  0.359  1.0
  I  I23  1  0.017  0.406  0.641  1.0
  I  I24  1  0.357  0.688  0.053  1.0
  I  I25  1  0.643  0.312  0.947  1.0
  I  I26  1  0.705  0.548  0.624  1.0
  I  I27  1  0.295  0.452  0.376  1.0
  I  I28  1  0.144  0.830  0.608  1.0
  I  I29  1  0.856  0.170  0.392  1.0
  I  I30  1  0.290  0.233  0.623  1.0
  I  I31  1  0.710  0.767  0.377  1.0
  I  I32  1  0.432  0.690  0.658  1.0
  I  I33  1  0.568  0.310  0.342  1.0
[/CIF]
.