The structure described by PrVO4 crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and three equivalent O(2) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Pr(1) and one V(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Pr(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one V(1) atom. is represented by the CIF file [CIF]
data_PrVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.669
_cell_length_b   6.989
_cell_length_c   7.220
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.193
_symmetry_Int_Tables_number   1
_cell_volume   324.760
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.400  0.222  0.655  1.0
  Pr  Pr1  1  0.900  0.722  0.845  1.0
  Pr  Pr2  1  0.600  0.778  0.345  1.0
  Pr  Pr3  1  0.100  0.278  0.155  1.0
  V  V4  1  0.885  0.200  0.665  1.0
  V  V5  1  0.385  0.700  0.835  1.0
  V  V6  1  0.115  0.800  0.335  1.0
  V  V7  1  0.615  0.300  0.165  1.0
  O  O8  1  0.076  0.252  0.496  1.0
  O  O9  1  0.576  0.752  0.004  1.0
  O  O10  1  0.924  0.748  0.504  1.0
  O  O11  1  0.424  0.248  0.996  1.0
  O  O12  1  1.000  0.112  0.847  1.0
  O  O13  1  0.500  0.612  0.653  1.0
  O  O14  1  0.000  0.888  0.153  1.0
  O  O15  1  0.500  0.388  0.347  1.0
  O  O16  1  0.671  0.018  0.605  1.0
  O  O17  1  0.171  0.518  0.895  1.0
  O  O18  1  0.329  0.982  0.395  1.0
  O  O19  1  0.829  0.482  0.105  1.0
  O  O20  1  0.772  0.385  0.720  1.0
  O  O21  1  0.272  0.885  0.780  1.0
  O  O22  1  0.228  0.615  0.280  1.0
  O  O23  1  0.728  0.115  0.220  1.0
[/CIF]
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The structure described by PrVO4 crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and three equivalent O(2) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Pr(1) and one V(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Pr(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one V(1) atom. is represented by the CIF file [CIF]
data_PrVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.669
_cell_length_b   6.989
_cell_length_c   7.220
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.193
_symmetry_Int_Tables_number   1
_cell_volume   324.760
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.400  0.222  0.655  1.0
  Pr  Pr1  1  0.900  0.722  0.845  1.0
  Pr  Pr2  1  0.600  0.778  0.345  1.0
  Pr  Pr3  1  0.100  0.278  0.155  1.0
  V  V4  1  0.885  0.200  0.665  1.0
  V  V5  1  0.385  0.700  0.835  1.0
  V  V6  1  0.115  0.800  0.335  1.0
  V  V7  1  0.615  0.300  0.165  1.0
  O  O8  1  0.076  0.252  0.496  1.0
  O  O9  1  0.576  0.752  0.004  1.0
  O  O10  1  0.924  0.748  0.504  1.0
  O  O11  1  0.424  0.248  0.996  1.0
  O  O12  1  1.000  0.112  0.847  1.0
  O  O13  1  0.500  0.612  0.653  1.0
  O  O14  1  0.000  0.888  0.153  1.0
  O  O15  1  0.500  0.388  0.347  1.0
  O  O16  1  0.671  0.018  0.605  1.0
  O  O17  1  0.171  0.518  0.895  1.0
  O  O18  1  0.329  0.982  0.395  1.0
  O  O19  1  0.829  0.482  0.105  1.0
  O  O20  1  0.772  0.385  0.720  1.0
  O  O21  1  0.272  0.885  0.780  1.0
  O  O22  1  0.228  0.615  0.280  1.0
  O  O23  1  0.728  0.115  0.220  1.0
[/CIF]
.