The structure described by MgMn2Tl2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 3-coordinate geometry to one Tl(1), one O(4), one O(5), and one O(6) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted edge-sharing MnO6 octahedra. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form edge-sharing MnO6 octahedra. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 4-coordinate geometry to one Mg(1), one O(1), one O(2), and one O(3) atom. In the second Tl site, Tl(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Tl(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Tl(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Tl(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Mg(1), one Mn(1), one Mn(2), and one Tl(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Mg(1), one Mn(1), one Mn(2), and one Tl(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Mg(1), one Mn(1), one Mn(2), and one Tl(2) atom. is represented by the CIF card [CIF]
data_MgMn2Tl2O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.199
_cell_length_b   8.082
_cell_length_c   5.198
_cell_angle_alpha   108.831
_cell_angle_beta   120.006
_cell_angle_gamma   89.907
_symmetry_Int_Tables_number   1
_cell_volume   175.576
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.229  0.683  0.455  1.0
  Mn  Mn1  1  0.342  0.024  0.682  1.0
  Mn  Mn2  1  0.667  0.999  0.332  1.0
  Tl  Tl3  1  0.103  0.310  0.207  1.0
  Tl  Tl4  1  0.895  0.681  0.787  1.0
  O  O5  1  0.041  0.146  0.471  1.0
  O  O6  1  0.430  0.146  0.105  1.0
  O  O7  1  0.675  0.146  0.716  1.0
  O  O8  1  0.337  0.854  0.299  1.0
  O  O9  1  0.556  0.854  0.891  1.0
  O  O10  1  0.964  0.854  0.518  1.0
[/CIF]
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The structure described by MgMn2Tl2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 3-coordinate geometry to one Tl(1), one O(4), one O(5), and one O(6) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted edge-sharing MnO6 octahedra. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form edge-sharing MnO6 octahedra. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 4-coordinate geometry to one Mg(1), one O(1), one O(2), and one O(3) atom. In the second Tl site, Tl(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Tl(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Tl(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Tl(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Mg(1), one Mn(1), one Mn(2), and one Tl(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Mg(1), one Mn(1), one Mn(2), and one Tl(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Mg(1), one Mn(1), one Mn(2), and one Tl(2) atom. is represented by the CIF card [CIF]
data_MgMn2Tl2O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.199
_cell_length_b   8.082
_cell_length_c   5.198
_cell_angle_alpha   108.831
_cell_angle_beta   120.006
_cell_angle_gamma   89.907
_symmetry_Int_Tables_number   1
_cell_volume   175.576
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.229  0.683  0.455  1.0
  Mn  Mn1  1  0.342  0.024  0.682  1.0
  Mn  Mn2  1  0.667  0.999  0.332  1.0
  Tl  Tl3  1  0.103  0.310  0.207  1.0
  Tl  Tl4  1  0.895  0.681  0.787  1.0
  O  O5  1  0.041  0.146  0.471  1.0
  O  O6  1  0.430  0.146  0.105  1.0
  O  O7  1  0.675  0.146  0.716  1.0
  O  O8  1  0.337  0.854  0.299  1.0
  O  O9  1  0.556  0.854  0.891  1.0
  O  O10  1  0.964  0.854  0.518  1.0
[/CIF]
.