The structure described by CoZnF5 crystallizes in the monoclinic P2_1/c space group. Co(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing CoF6 octahedra. The corner-sharing octahedral tilt angles are 40°. Zn(1) is bonded in a 7-coordinate geometry to one F(3), one F(4), one F(5), two equivalent F(1), and two equivalent F(2) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent Zn(1) atoms. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and two equivalent Zn(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Co(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Co(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one Zn(1) atom. is represented by the CIF card [CIF]
data_ZnCoF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.664
_cell_length_b   5.220
_cell_length_c   7.433
_cell_angle_alpha   69.608
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   351.451
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.011  0.521  0.743  1.0
  Zn  Zn1  1  0.511  0.479  0.757  1.0
  Zn  Zn2  1  0.989  0.479  0.257  1.0
  Zn  Zn3  1  0.489  0.521  0.243  1.0
  Co  Co4  1  0.753  0.099  0.602  1.0
  Co  Co5  1  0.253  0.901  0.898  1.0
  Co  Co6  1  0.247  0.901  0.398  1.0
  Co  Co7  1  0.747  0.099  0.102  1.0
  F  F8  1  0.886  0.395  0.567  1.0
  F  F9  1  0.386  0.605  0.933  1.0
  F  F10  1  0.114  0.605  0.433  1.0
  F  F11  1  0.614  0.395  0.067  1.0
  F  F12  1  0.610  0.353  0.494  1.0
  F  F13  1  0.110  0.647  0.006  1.0
  F  F14  1  0.390  0.647  0.506  1.0
  F  F15  1  0.890  0.353  0.994  1.0
  F  F16  1  0.399  0.144  0.801  1.0
  F  F17  1  0.899  0.856  0.699  1.0
  F  F18  1  0.601  0.856  0.199  1.0
  F  F19  1  0.101  0.144  0.301  1.0
  F  F20  1  0.135  0.210  0.850  1.0
  F  F21  1  0.635  0.790  0.650  1.0
  F  F22  1  0.865  0.790  0.150  1.0
  F  F23  1  0.365  0.210  0.350  1.0
  F  F24  1  0.686  0.157  0.837  1.0
  F  F25  1  0.186  0.843  0.663  1.0
  F  F26  1  0.314  0.843  0.163  1.0
  F  F27  1  0.814  0.157  0.337  1.0
[/CIF]
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The structure described by CoZnF5 crystallizes in the monoclinic P2_1/c space group. Co(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing CoF6 octahedra. The corner-sharing octahedral tilt angles are 40°. Zn(1) is bonded in a 7-coordinate geometry to one F(3), one F(4), one F(5), two equivalent F(1), and two equivalent F(2) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent Zn(1) atoms. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and two equivalent Zn(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Co(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Co(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one Zn(1) atom. is represented by the CIF card [CIF]
data_ZnCoF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.664
_cell_length_b   5.220
_cell_length_c   7.433
_cell_angle_alpha   69.608
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   351.451
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.011  0.521  0.743  1.0
  Zn  Zn1  1  0.511  0.479  0.757  1.0
  Zn  Zn2  1  0.989  0.479  0.257  1.0
  Zn  Zn3  1  0.489  0.521  0.243  1.0
  Co  Co4  1  0.753  0.099  0.602  1.0
  Co  Co5  1  0.253  0.901  0.898  1.0
  Co  Co6  1  0.247  0.901  0.398  1.0
  Co  Co7  1  0.747  0.099  0.102  1.0
  F  F8  1  0.886  0.395  0.567  1.0
  F  F9  1  0.386  0.605  0.933  1.0
  F  F10  1  0.114  0.605  0.433  1.0
  F  F11  1  0.614  0.395  0.067  1.0
  F  F12  1  0.610  0.353  0.494  1.0
  F  F13  1  0.110  0.647  0.006  1.0
  F  F14  1  0.390  0.647  0.506  1.0
  F  F15  1  0.890  0.353  0.994  1.0
  F  F16  1  0.399  0.144  0.801  1.0
  F  F17  1  0.899  0.856  0.699  1.0
  F  F18  1  0.601  0.856  0.199  1.0
  F  F19  1  0.101  0.144  0.301  1.0
  F  F20  1  0.135  0.210  0.850  1.0
  F  F21  1  0.635  0.790  0.650  1.0
  F  F22  1  0.865  0.790  0.150  1.0
  F  F23  1  0.365  0.210  0.350  1.0
  F  F24  1  0.686  0.157  0.837  1.0
  F  F25  1  0.186  0.843  0.663  1.0
  F  F26  1  0.314  0.843  0.163  1.0
  F  F27  1  0.814  0.157  0.337  1.0
[/CIF]
.