The structure described by TlCl4NH4 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of four ammonium molecules and four TlCl4 clusters. In each TlCl4 cluster, Tl(1) is bonded in a tetrahedral geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one Tl(1) atom. is represented by the CIF card [CIF]
data_TlH4NCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.463
_cell_length_b   9.463
_cell_length_c   9.463
_cell_angle_alpha   135.263
_cell_angle_beta   135.263
_cell_angle_gamma   65.123
_symmetry_Int_Tables_number   1
_cell_volume   413.774
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.750  0.250  0.500  1.0
  Tl  Tl1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.568  0.425  0.917  1.0
  H  H3  1  0.400  0.818  0.643  1.0
  H  H4  1  0.175  0.757  0.357  1.0
  H  H5  1  0.507  0.650  0.083  1.0
  H  H6  1  0.182  0.825  0.583  1.0
  H  H7  1  0.350  0.432  0.857  1.0
  H  H8  1  0.575  0.493  0.143  1.0
  H  H9  1  0.243  0.600  0.417  1.0
  N  N10  1  0.500  0.500  0.000  1.0
  N  N11  1  0.250  0.750  0.500  1.0
  Cl  Cl12  1  0.509  0.405  0.587  1.0
  Cl  Cl13  1  0.241  0.845  0.913  1.0
  Cl  Cl14  1  0.931  0.328  0.087  1.0
  Cl  Cl15  1  0.078  0.491  0.896  1.0
  Cl  Cl16  1  0.155  0.069  0.396  1.0
  Cl  Cl17  1  0.672  0.759  0.604  1.0
  Cl  Cl18  1  0.819  0.922  0.413  1.0
  Cl  Cl19  1  0.595  0.181  0.104  1.0
[/CIF]
.
The structure described by TlCl4NH4 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of four ammonium molecules and four TlCl4 clusters. In each TlCl4 cluster, Tl(1) is bonded in a tetrahedral geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one Tl(1) atom. is represented by the CIF card [CIF]
data_TlH4NCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.463
_cell_length_b   9.463
_cell_length_c   9.463
_cell_angle_alpha   135.263
_cell_angle_beta   135.263
_cell_angle_gamma   65.123
_symmetry_Int_Tables_number   1
_cell_volume   413.774
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.750  0.250  0.500  1.0
  Tl  Tl1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.568  0.425  0.917  1.0
  H  H3  1  0.400  0.818  0.643  1.0
  H  H4  1  0.175  0.757  0.357  1.0
  H  H5  1  0.507  0.650  0.083  1.0
  H  H6  1  0.182  0.825  0.583  1.0
  H  H7  1  0.350  0.432  0.857  1.0
  H  H8  1  0.575  0.493  0.143  1.0
  H  H9  1  0.243  0.600  0.417  1.0
  N  N10  1  0.500  0.500  0.000  1.0
  N  N11  1  0.250  0.750  0.500  1.0
  Cl  Cl12  1  0.509  0.405  0.587  1.0
  Cl  Cl13  1  0.241  0.845  0.913  1.0
  Cl  Cl14  1  0.931  0.328  0.087  1.0
  Cl  Cl15  1  0.078  0.491  0.896  1.0
  Cl  Cl16  1  0.155  0.069  0.396  1.0
  Cl  Cl17  1  0.672  0.759  0.604  1.0
  Cl  Cl18  1  0.819  0.922  0.413  1.0
  Cl  Cl19  1  0.595  0.181  0.104  1.0
[/CIF]
.