The crystal structure described by Rb2LiVS4 crystallizes in the orthorhombic Fddd space group. Rb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Li(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 2-coordinate geometry to four equivalent Rb(1), one Li(1), and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2LiVS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.615
_cell_length_b   12.201
_cell_length_c   7.339
_cell_angle_alpha   84.436
_cell_angle_beta   63.118
_cell_angle_gamma   32.447
_symmetry_Int_Tables_number   1
_cell_volume   469.037
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.678  0.678  0.322  1.0
  Rb  Rb1  1  0.928  0.928  0.572  1.0
  Rb  Rb2  1  0.572  0.572  0.928  1.0
  Rb  Rb3  1  0.322  0.322  0.678  1.0
  Li  Li4  1  0.000  0.000  0.000  1.0
  Li  Li5  1  0.250  0.250  0.250  1.0
  V  V6  1  0.500  0.500  0.500  1.0
  V  V7  1  0.750  0.750  0.750  1.0
  S  S8  1  0.923  0.681  0.391  1.0
  S  S9  1  0.327  0.569  0.859  1.0
  S  S10  1  0.681  0.923  0.005  1.0
  S  S11  1  0.859  0.245  0.327  1.0
  S  S12  1  0.569  0.327  0.245  1.0
  S  S13  1  0.245  0.859  0.569  1.0
  S  S14  1  0.391  0.005  0.923  1.0
  S  S15  1  0.005  0.391  0.681  1.0
[/CIF]
.
The crystal structure described by Rb2LiVS4 crystallizes in the orthorhombic Fddd space group. Rb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Li(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 2-coordinate geometry to four equivalent Rb(1), one Li(1), and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2LiVS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.615
_cell_length_b   12.201
_cell_length_c   7.339
_cell_angle_alpha   84.436
_cell_angle_beta   63.118
_cell_angle_gamma   32.447
_symmetry_Int_Tables_number   1
_cell_volume   469.037
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.678  0.678  0.322  1.0
  Rb  Rb1  1  0.928  0.928  0.572  1.0
  Rb  Rb2  1  0.572  0.572  0.928  1.0
  Rb  Rb3  1  0.322  0.322  0.678  1.0
  Li  Li4  1  0.000  0.000  0.000  1.0
  Li  Li5  1  0.250  0.250  0.250  1.0
  V  V6  1  0.500  0.500  0.500  1.0
  V  V7  1  0.750  0.750  0.750  1.0
  S  S8  1  0.923  0.681  0.391  1.0
  S  S9  1  0.327  0.569  0.859  1.0
  S  S10  1  0.681  0.923  0.005  1.0
  S  S11  1  0.859  0.245  0.327  1.0
  S  S12  1  0.569  0.327  0.245  1.0
  S  S13  1  0.245  0.859  0.569  1.0
  S  S14  1  0.391  0.005  0.923  1.0
  S  S15  1  0.005  0.391  0.681  1.0
[/CIF]
.