The structure described by Xe3Re4(O5F7)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Xe3Re4(O5F7)2 cluster. There are two inequivalent Xe sites. In the first Xe site, Xe(1) is bonded in a linear geometry to two equivalent O(4) atoms. In the second Xe site, Xe(2) is bonded in a linear geometry to one O(4) and one F(1) atom. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(1), one O(5), one F(1), one F(2), one F(3), and one F(4) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 21°. In the second Re site, Re(2) is bonded to one O(2), one O(3), one F(2), one F(5), one F(6), and one F(7) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 21°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Xe(1) and one Xe(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Re(1) atom. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Xe(2) and one Re(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Re(2) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Re(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Re(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re4Xe3(O5F7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.052
_cell_length_b   8.486
_cell_length_c   10.429
_cell_angle_alpha   88.128
_cell_angle_beta   110.960
_cell_angle_gamma   118.256
_symmetry_Int_Tables_number   1
_cell_volume   578.019
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.439  0.684  0.286  1.0
  Re  Re1  1  0.561  0.316  0.714  1.0
  Re  Re2  1  0.013  0.002  0.243  1.0
  Re  Re3  1  0.987  0.998  0.757  1.0
  Xe  Xe4  1  0.000  0.500  0.500  1.0
  Xe  Xe5  1  0.345  0.668  0.864  1.0
  Xe  Xe6  1  0.655  0.332  0.136  1.0
  O  O7  1  0.183  0.532  0.238  1.0
  O  O8  1  0.817  0.468  0.762  1.0
  O  O9  1  0.207  0.108  0.186  1.0
  O  O10  1  0.793  0.892  0.814  1.0
  O  O11  1  0.074  0.166  0.371  1.0
  O  O12  1  0.926  0.834  0.629  1.0
  O  O13  1  0.263  0.728  0.666  1.0
  O  O14  1  0.737  0.272  0.334  1.0
  O  O15  1  0.498  0.790  0.445  1.0
  O  O16  1  0.502  0.210  0.555  1.0
  F  F17  1  0.426  0.593  0.098  1.0
  F  F18  1  0.574  0.407  0.902  1.0
  F  F19  1  0.741  0.839  0.305  1.0
  F  F20  1  0.259  0.161  0.695  1.0
  F  F21  1  0.530  0.517  0.350  1.0
  F  F22  1  0.470  0.483  0.650  1.0
  F  F23  1  0.407  0.863  0.186  1.0
  F  F24  1  0.593  0.137  0.814  1.0
  F  F25  1  0.816  0.047  0.109  1.0
  F  F26  1  0.184  0.953  0.891  1.0
  F  F27  1  0.864  0.772  0.118  1.0
  F  F28  1  0.136  0.228  0.882  1.0
  F  F29  1  0.118  0.875  0.368  1.0
  F  F30  1  0.882  0.125  0.632  1.0
[/CIF]
.
The structure described by Xe3Re4(O5F7)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Xe3Re4(O5F7)2 cluster. There are two inequivalent Xe sites. In the first Xe site, Xe(1) is bonded in a linear geometry to two equivalent O(4) atoms. In the second Xe site, Xe(2) is bonded in a linear geometry to one O(4) and one F(1) atom. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(1), one O(5), one F(1), one F(2), one F(3), and one F(4) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 21°. In the second Re site, Re(2) is bonded to one O(2), one O(3), one F(2), one F(5), one F(6), and one F(7) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 21°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Xe(1) and one Xe(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Re(1) atom. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Xe(2) and one Re(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Re(2) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Re(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Re(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re4Xe3(O5F7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.052
_cell_length_b   8.486
_cell_length_c   10.429
_cell_angle_alpha   88.128
_cell_angle_beta   110.960
_cell_angle_gamma   118.256
_symmetry_Int_Tables_number   1
_cell_volume   578.019
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.439  0.684  0.286  1.0
  Re  Re1  1  0.561  0.316  0.714  1.0
  Re  Re2  1  0.013  0.002  0.243  1.0
  Re  Re3  1  0.987  0.998  0.757  1.0
  Xe  Xe4  1  0.000  0.500  0.500  1.0
  Xe  Xe5  1  0.345  0.668  0.864  1.0
  Xe  Xe6  1  0.655  0.332  0.136  1.0
  O  O7  1  0.183  0.532  0.238  1.0
  O  O8  1  0.817  0.468  0.762  1.0
  O  O9  1  0.207  0.108  0.186  1.0
  O  O10  1  0.793  0.892  0.814  1.0
  O  O11  1  0.074  0.166  0.371  1.0
  O  O12  1  0.926  0.834  0.629  1.0
  O  O13  1  0.263  0.728  0.666  1.0
  O  O14  1  0.737  0.272  0.334  1.0
  O  O15  1  0.498  0.790  0.445  1.0
  O  O16  1  0.502  0.210  0.555  1.0
  F  F17  1  0.426  0.593  0.098  1.0
  F  F18  1  0.574  0.407  0.902  1.0
  F  F19  1  0.741  0.839  0.305  1.0
  F  F20  1  0.259  0.161  0.695  1.0
  F  F21  1  0.530  0.517  0.350  1.0
  F  F22  1  0.470  0.483  0.650  1.0
  F  F23  1  0.407  0.863  0.186  1.0
  F  F24  1  0.593  0.137  0.814  1.0
  F  F25  1  0.816  0.047  0.109  1.0
  F  F26  1  0.184  0.953  0.891  1.0
  F  F27  1  0.864  0.772  0.118  1.0
  F  F28  1  0.136  0.228  0.882  1.0
  F  F29  1  0.118  0.875  0.368  1.0
  F  F30  1  0.882  0.125  0.632  1.0
[/CIF]
.