The material described by (UH12(O3Cl)2)2Cl2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two UH12(O3Cl)2 clusters. In each UH12(O3Cl)2 cluster, U(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one U(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one U(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one U(1), one H(5), and one H(6) atom. Cl(1) is bonded in a 4-coordinate geometry to one U(1) atom. is represented by the CIF card [CIF]
data_UH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.689
_cell_length_b   8.046
_cell_length_c   12.332
_cell_angle_alpha   52.442
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.143
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.150  0.000  0.250  1.0
  U  U1  1  0.850  0.000  0.750  1.0
  H  H2  1  0.255  0.478  0.033  1.0
  H  H3  1  0.255  0.522  0.467  1.0
  H  H4  1  0.745  0.522  0.967  1.0
  H  H5  1  0.745  0.478  0.533  1.0
  H  H6  1  0.333  0.378  0.964  1.0
  H  H7  1  0.333  0.622  0.536  1.0
  H  H8  1  0.667  0.622  0.036  1.0
  H  H9  1  0.667  0.378  0.464  1.0
  H  H10  1  0.555  0.974  0.386  1.0
  H  H11  1  0.555  0.026  0.114  1.0
  H  H12  1  0.445  0.026  0.614  1.0
  H  H13  1  0.445  0.974  0.886  1.0
  H  H14  1  0.479  0.204  0.318  1.0
  H  H15  1  0.479  0.796  0.182  1.0
  H  H16  1  0.521  0.796  0.682  1.0
  H  H17  1  0.521  0.204  0.818  1.0
  H  H18  1  0.090  0.751  0.132  1.0
  H  H19  1  0.090  0.249  0.368  1.0
  H  H20  1  0.910  0.249  0.868  1.0
  H  H21  1  0.910  0.751  0.632  1.0
  H  H22  1  0.087  0.668  0.737  1.0
  H  H23  1  0.087  0.332  0.763  1.0
  H  H24  1  0.913  0.332  0.263  1.0
  H  H25  1  0.913  0.668  0.237  1.0
  Cl  Cl26  1  0.824  0.795  0.447  1.0
  Cl  Cl27  1  0.824  0.205  0.053  1.0
  Cl  Cl28  1  0.176  0.205  0.553  1.0
  Cl  Cl29  1  0.176  0.795  0.947  1.0
  Cl  Cl30  1  0.368  0.500  0.750  1.0
  Cl  Cl31  1  0.632  0.500  0.250  1.0
  O  O32  1  0.295  0.342  0.053  1.0
  O  O33  1  0.295  0.658  0.447  1.0
  O  O34  1  0.705  0.658  0.947  1.0
  O  O35  1  0.705  0.342  0.553  1.0
  O  O36  1  0.433  0.062  0.354  1.0
  O  O37  1  0.433  0.938  0.146  1.0
  O  O38  1  0.567  0.938  0.646  1.0
  O  O39  1  0.567  0.062  0.854  1.0
  O  O40  1  0.045  0.736  0.214  1.0
  O  O41  1  0.045  0.264  0.286  1.0
  O  O42  1  0.955  0.264  0.786  1.0
  O  O43  1  0.955  0.736  0.714  1.0
[/CIF]
.
The material described by (UH12(O3Cl)2)2Cl2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two UH12(O3Cl)2 clusters. In each UH12(O3Cl)2 cluster, U(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one U(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one U(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one U(1), one H(5), and one H(6) atom. Cl(1) is bonded in a 4-coordinate geometry to one U(1) atom. is represented by the CIF card [CIF]
data_UH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.689
_cell_length_b   8.046
_cell_length_c   12.332
_cell_angle_alpha   52.442
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.143
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.150  0.000  0.250  1.0
  U  U1  1  0.850  0.000  0.750  1.0
  H  H2  1  0.255  0.478  0.033  1.0
  H  H3  1  0.255  0.522  0.467  1.0
  H  H4  1  0.745  0.522  0.967  1.0
  H  H5  1  0.745  0.478  0.533  1.0
  H  H6  1  0.333  0.378  0.964  1.0
  H  H7  1  0.333  0.622  0.536  1.0
  H  H8  1  0.667  0.622  0.036  1.0
  H  H9  1  0.667  0.378  0.464  1.0
  H  H10  1  0.555  0.974  0.386  1.0
  H  H11  1  0.555  0.026  0.114  1.0
  H  H12  1  0.445  0.026  0.614  1.0
  H  H13  1  0.445  0.974  0.886  1.0
  H  H14  1  0.479  0.204  0.318  1.0
  H  H15  1  0.479  0.796  0.182  1.0
  H  H16  1  0.521  0.796  0.682  1.0
  H  H17  1  0.521  0.204  0.818  1.0
  H  H18  1  0.090  0.751  0.132  1.0
  H  H19  1  0.090  0.249  0.368  1.0
  H  H20  1  0.910  0.249  0.868  1.0
  H  H21  1  0.910  0.751  0.632  1.0
  H  H22  1  0.087  0.668  0.737  1.0
  H  H23  1  0.087  0.332  0.763  1.0
  H  H24  1  0.913  0.332  0.263  1.0
  H  H25  1  0.913  0.668  0.237  1.0
  Cl  Cl26  1  0.824  0.795  0.447  1.0
  Cl  Cl27  1  0.824  0.205  0.053  1.0
  Cl  Cl28  1  0.176  0.205  0.553  1.0
  Cl  Cl29  1  0.176  0.795  0.947  1.0
  Cl  Cl30  1  0.368  0.500  0.750  1.0
  Cl  Cl31  1  0.632  0.500  0.250  1.0
  O  O32  1  0.295  0.342  0.053  1.0
  O  O33  1  0.295  0.658  0.447  1.0
  O  O34  1  0.705  0.658  0.947  1.0
  O  O35  1  0.705  0.342  0.553  1.0
  O  O36  1  0.433  0.062  0.354  1.0
  O  O37  1  0.433  0.938  0.146  1.0
  O  O38  1  0.567  0.938  0.646  1.0
  O  O39  1  0.567  0.062  0.854  1.0
  O  O40  1  0.045  0.736  0.214  1.0
  O  O41  1  0.045  0.264  0.286  1.0
  O  O42  1  0.955  0.264  0.786  1.0
  O  O43  1  0.955  0.736  0.714  1.0
[/CIF]
.