The material structure described by Sb(WO3)5 crystallizes in the orthorhombic Cmme space group. There are three inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(4), one O(7), and two equivalent O(6) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 3-43°. In the second W site, W(2) is bonded to one O(1), one O(2), one O(5), one O(7), and two equivalent O(6) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 3-38°. In the third W site, W(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-43°. Sb(1) is bonded in a 2-coordinate geometry to two equivalent O(4) atoms. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a linear geometry to two equivalent W(3) atoms. In the second O site, O(4) is bonded in a trigonal planar geometry to one W(1), one W(3), and one Sb(1) atom. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one W(3) atom. In the fourth O site, O(6) is bonded in a linear geometry to one W(1) and one W(2) atom. In the fifth O site, O(7) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the sixth O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the seventh O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one W(2) atom. is represented by the CIF file [CIF]
data_Sb(WO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.122
_cell_length_b   11.122
_cell_length_c   7.538
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   139.402
_symmetry_Int_Tables_number   1
_cell_volume   606.760
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.750  0.426  1.0
  Sb  Sb1  1  0.750  0.250  0.574  1.0
  W  W2  1  0.410  0.590  0.250  1.0
  W  W3  1  0.910  0.090  0.254  1.0
  W  W4  1  0.590  0.410  0.750  1.0
  W  W5  1  0.090  0.910  0.746  1.0
  W  W6  1  0.590  0.410  0.254  1.0
  W  W7  1  0.090  0.910  0.250  1.0
  W  W8  1  0.410  0.590  0.746  1.0
  W  W9  1  0.910  0.090  0.750  1.0
  W  W10  1  0.750  0.250  0.018  1.0
  W  W11  1  0.250  0.750  0.982  1.0
  O  O12  1  0.425  0.575  0.000  1.0
  O  O13  1  0.925  0.075  1.000  1.0
  O  O14  1  0.575  0.425  1.000  1.0
  O  O15  1  0.075  0.925  0.000  1.0
  O  O16  1  0.379  0.621  0.499  1.0
  O  O17  1  0.879  0.121  0.501  1.0
  O  O18  1  0.621  0.379  0.501  1.0
  O  O19  1  0.121  0.879  0.499  1.0
  O  O20  1  0.000  0.500  0.000  1.0
  O  O21  1  0.500  0.000  0.000  1.0
  O  O22  1  0.311  0.689  0.202  1.0
  O  O23  1  0.816  0.184  0.182  1.0
  O  O24  1  0.689  0.311  0.798  1.0
  O  O25  1  0.184  0.816  0.818  1.0
  O  O26  1  0.684  0.316  0.182  1.0
  O  O27  1  0.189  0.811  0.202  1.0
  O  O28  1  0.316  0.684  0.818  1.0
  O  O29  1  0.811  0.189  0.798  1.0
  O  O30  1  0.657  0.842  0.254  1.0
  O  O31  1  0.158  0.343  0.254  1.0
  O  O32  1  0.842  0.657  0.746  1.0
  O  O33  1  0.343  0.158  0.746  1.0
  O  O34  1  0.843  0.658  0.254  1.0
  O  O35  1  0.342  0.157  0.254  1.0
  O  O36  1  0.658  0.843  0.746  1.0
  O  O37  1  0.157  0.342  0.746  1.0
  O  O38  1  0.500  0.500  0.304  1.0
  O  O39  1  0.000  1.000  0.304  1.0
  O  O40  1  0.500  0.500  0.696  1.0
  O  O41  1  1.000  0.000  0.696  1.0
[/CIF]
.
The material structure described by Sb(WO3)5 crystallizes in the orthorhombic Cmme space group. There are three inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(4), one O(7), and two equivalent O(6) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 3-43°. In the second W site, W(2) is bonded to one O(1), one O(2), one O(5), one O(7), and two equivalent O(6) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 3-38°. In the third W site, W(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-43°. Sb(1) is bonded in a 2-coordinate geometry to two equivalent O(4) atoms. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a linear geometry to two equivalent W(3) atoms. In the second O site, O(4) is bonded in a trigonal planar geometry to one W(1), one W(3), and one Sb(1) atom. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one W(3) atom. In the fourth O site, O(6) is bonded in a linear geometry to one W(1) and one W(2) atom. In the fifth O site, O(7) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the sixth O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the seventh O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one W(2) atom. is represented by the CIF file [CIF]
data_Sb(WO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.122
_cell_length_b   11.122
_cell_length_c   7.538
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   139.402
_symmetry_Int_Tables_number   1
_cell_volume   606.760
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.750  0.426  1.0
  Sb  Sb1  1  0.750  0.250  0.574  1.0
  W  W2  1  0.410  0.590  0.250  1.0
  W  W3  1  0.910  0.090  0.254  1.0
  W  W4  1  0.590  0.410  0.750  1.0
  W  W5  1  0.090  0.910  0.746  1.0
  W  W6  1  0.590  0.410  0.254  1.0
  W  W7  1  0.090  0.910  0.250  1.0
  W  W8  1  0.410  0.590  0.746  1.0
  W  W9  1  0.910  0.090  0.750  1.0
  W  W10  1  0.750  0.250  0.018  1.0
  W  W11  1  0.250  0.750  0.982  1.0
  O  O12  1  0.425  0.575  0.000  1.0
  O  O13  1  0.925  0.075  1.000  1.0
  O  O14  1  0.575  0.425  1.000  1.0
  O  O15  1  0.075  0.925  0.000  1.0
  O  O16  1  0.379  0.621  0.499  1.0
  O  O17  1  0.879  0.121  0.501  1.0
  O  O18  1  0.621  0.379  0.501  1.0
  O  O19  1  0.121  0.879  0.499  1.0
  O  O20  1  0.000  0.500  0.000  1.0
  O  O21  1  0.500  0.000  0.000  1.0
  O  O22  1  0.311  0.689  0.202  1.0
  O  O23  1  0.816  0.184  0.182  1.0
  O  O24  1  0.689  0.311  0.798  1.0
  O  O25  1  0.184  0.816  0.818  1.0
  O  O26  1  0.684  0.316  0.182  1.0
  O  O27  1  0.189  0.811  0.202  1.0
  O  O28  1  0.316  0.684  0.818  1.0
  O  O29  1  0.811  0.189  0.798  1.0
  O  O30  1  0.657  0.842  0.254  1.0
  O  O31  1  0.158  0.343  0.254  1.0
  O  O32  1  0.842  0.657  0.746  1.0
  O  O33  1  0.343  0.158  0.746  1.0
  O  O34  1  0.843  0.658  0.254  1.0
  O  O35  1  0.342  0.157  0.254  1.0
  O  O36  1  0.658  0.843  0.746  1.0
  O  O37  1  0.157  0.342  0.746  1.0
  O  O38  1  0.500  0.500  0.304  1.0
  O  O39  1  0.000  1.000  0.304  1.0
  O  O40  1  0.500  0.500  0.696  1.0
  O  O41  1  1.000  0.000  0.696  1.0
[/CIF]
.