The crystal structure described by KInH8(CO3)4 crystallizes in the tetragonal I4_1/a space group. K(1) is bonded in a distorted hexagonal bipyramidal geometry to four equivalent O(1) and four equivalent O(3) atoms. In(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one In(1) and one C(1) atom. In the second O site, O(3) is bonded in a water-like geometry to one K(1), one H(1), and one H(2) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one In(1), and one C(1) atom. is represented by the CIF card [CIF]
data_KInH8(CO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.161
_cell_length_b   9.161
_cell_length_c   9.161
_cell_angle_alpha   103.922
_cell_angle_beta   103.922
_cell_angle_gamma   121.251
_symmetry_Int_Tables_number   1
_cell_volume   572.818
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.000  1.0
  K  K1  1  0.750  0.250  0.500  1.0
  In  In2  1  0.000  0.000  0.000  1.0
  In  In3  1  0.250  0.750  0.500  1.0
  H  H4  1  0.115  0.195  0.583  1.0
  H  H5  1  0.612  0.532  0.417  1.0
  H  H6  1  0.782  0.865  0.420  1.0
  H  H7  1  0.445  0.362  0.580  1.0
  H  H8  1  0.135  0.555  0.917  1.0
  H  H9  1  0.638  0.218  0.083  1.0
  H  H10  1  0.468  0.885  0.080  1.0
  H  H11  1  0.805  0.388  0.920  1.0
  H  H12  1  0.845  0.992  0.325  1.0
  H  H13  1  0.667  0.520  0.675  1.0
  H  H14  1  0.770  0.595  0.352  1.0
  H  H15  1  0.242  0.417  0.648  1.0
  H  H16  1  0.405  0.758  0.175  1.0
  H  H17  1  0.583  0.230  0.825  1.0
  H  H18  1  0.480  0.155  0.148  1.0
  H  H19  1  0.008  0.333  0.852  1.0
  C  C20  1  0.022  0.797  0.230  1.0
  C  C21  1  0.567  0.792  0.770  1.0
  C  C22  1  0.042  0.772  0.725  1.0
  C  C23  1  0.047  0.317  0.275  1.0
  C  C24  1  0.228  0.953  0.270  1.0
  C  C25  1  0.683  0.958  0.730  1.0
  C  C26  1  0.208  0.978  0.775  1.0
  C  C27  1  0.203  0.433  0.225  1.0
  O  O28  1  0.894  0.785  0.124  1.0
  O  O29  1  0.661  0.770  0.876  1.0
  O  O30  1  0.020  0.644  0.609  1.0
  O  O31  1  0.035  0.411  0.391  1.0
  O  O32  1  0.356  0.965  0.376  1.0
  O  O33  1  0.589  0.980  0.624  1.0
  O  O34  1  0.230  0.106  0.891  1.0
  O  O35  1  0.215  0.339  0.109  1.0
  O  O36  1  0.995  0.693  0.306  1.0
  O  O37  1  0.387  0.689  0.694  1.0
  O  O38  1  0.939  0.745  0.802  1.0
  O  O39  1  0.943  0.137  0.198  1.0
  O  O40  1  0.255  0.057  0.194  1.0
  O  O41  1  0.863  0.061  0.806  1.0
  O  O42  1  0.311  0.005  0.698  1.0
  O  O43  1  0.307  0.613  0.302  1.0
  O  O44  1  0.248  0.313  0.646  1.0
  O  O45  1  0.667  0.602  0.354  1.0
  O  O46  1  0.852  0.998  0.435  1.0
  O  O47  1  0.563  0.417  0.565  1.0
  O  O48  1  0.002  0.437  0.854  1.0
  O  O49  1  0.583  0.148  0.146  1.0
  O  O50  1  0.398  0.752  0.065  1.0
  O  O51  1  0.687  0.333  0.935  1.0
[/CIF]
.
The crystal structure described by KInH8(CO3)4 crystallizes in the tetragonal I4_1/a space group. K(1) is bonded in a distorted hexagonal bipyramidal geometry to four equivalent O(1) and four equivalent O(3) atoms. In(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one In(1) and one C(1) atom. In the second O site, O(3) is bonded in a water-like geometry to one K(1), one H(1), and one H(2) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one In(1), and one C(1) atom. is represented by the CIF card [CIF]
data_KInH8(CO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.161
_cell_length_b   9.161
_cell_length_c   9.161
_cell_angle_alpha   103.922
_cell_angle_beta   103.922
_cell_angle_gamma   121.251
_symmetry_Int_Tables_number   1
_cell_volume   572.818
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.000  1.0
  K  K1  1  0.750  0.250  0.500  1.0
  In  In2  1  0.000  0.000  0.000  1.0
  In  In3  1  0.250  0.750  0.500  1.0
  H  H4  1  0.115  0.195  0.583  1.0
  H  H5  1  0.612  0.532  0.417  1.0
  H  H6  1  0.782  0.865  0.420  1.0
  H  H7  1  0.445  0.362  0.580  1.0
  H  H8  1  0.135  0.555  0.917  1.0
  H  H9  1  0.638  0.218  0.083  1.0
  H  H10  1  0.468  0.885  0.080  1.0
  H  H11  1  0.805  0.388  0.920  1.0
  H  H12  1  0.845  0.992  0.325  1.0
  H  H13  1  0.667  0.520  0.675  1.0
  H  H14  1  0.770  0.595  0.352  1.0
  H  H15  1  0.242  0.417  0.648  1.0
  H  H16  1  0.405  0.758  0.175  1.0
  H  H17  1  0.583  0.230  0.825  1.0
  H  H18  1  0.480  0.155  0.148  1.0
  H  H19  1  0.008  0.333  0.852  1.0
  C  C20  1  0.022  0.797  0.230  1.0
  C  C21  1  0.567  0.792  0.770  1.0
  C  C22  1  0.042  0.772  0.725  1.0
  C  C23  1  0.047  0.317  0.275  1.0
  C  C24  1  0.228  0.953  0.270  1.0
  C  C25  1  0.683  0.958  0.730  1.0
  C  C26  1  0.208  0.978  0.775  1.0
  C  C27  1  0.203  0.433  0.225  1.0
  O  O28  1  0.894  0.785  0.124  1.0
  O  O29  1  0.661  0.770  0.876  1.0
  O  O30  1  0.020  0.644  0.609  1.0
  O  O31  1  0.035  0.411  0.391  1.0
  O  O32  1  0.356  0.965  0.376  1.0
  O  O33  1  0.589  0.980  0.624  1.0
  O  O34  1  0.230  0.106  0.891  1.0
  O  O35  1  0.215  0.339  0.109  1.0
  O  O36  1  0.995  0.693  0.306  1.0
  O  O37  1  0.387  0.689  0.694  1.0
  O  O38  1  0.939  0.745  0.802  1.0
  O  O39  1  0.943  0.137  0.198  1.0
  O  O40  1  0.255  0.057  0.194  1.0
  O  O41  1  0.863  0.061  0.806  1.0
  O  O42  1  0.311  0.005  0.698  1.0
  O  O43  1  0.307  0.613  0.302  1.0
  O  O44  1  0.248  0.313  0.646  1.0
  O  O45  1  0.667  0.602  0.354  1.0
  O  O46  1  0.852  0.998  0.435  1.0
  O  O47  1  0.563  0.417  0.565  1.0
  O  O48  1  0.002  0.437  0.854  1.0
  O  O49  1  0.583  0.148  0.146  1.0
  O  O50  1  0.398  0.752  0.065  1.0
  O  O51  1  0.687  0.333  0.935  1.0
[/CIF]
.