The compound described by VSO8O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and four VSO8 clusters. In each VSO8 cluster, V(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one V(1)O5 trigonal bipyramid. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one V(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VSO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.720
_cell_length_b   7.206
_cell_length_c   15.415
_cell_angle_alpha   69.203
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1009.385
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.295  0.675  0.459  1.0
  V  V1  1  0.795  0.325  0.041  1.0
  V  V2  1  0.705  0.325  0.541  1.0
  V  V3  1  0.205  0.675  0.959  1.0
  S  S4  1  0.962  0.971  0.194  1.0
  S  S5  1  0.462  0.029  0.306  1.0
  S  S6  1  0.038  0.029  0.806  1.0
  S  S7  1  0.538  0.971  0.694  1.0
  O  O8  1  0.455  0.564  0.431  1.0
  O  O9  1  0.955  0.436  0.069  1.0
  O  O10  1  0.545  0.436  0.569  1.0
  O  O11  1  0.045  0.564  0.931  1.0
  O  O12  1  0.113  0.671  0.429  1.0
  O  O13  1  0.613  0.329  0.071  1.0
  O  O14  1  0.887  0.329  0.571  1.0
  O  O15  1  0.387  0.671  0.929  1.0
  O  O16  1  0.235  0.577  0.257  1.0
  O  O17  1  0.735  0.423  0.243  1.0
  O  O18  1  0.765  0.423  0.743  1.0
  O  O19  1  0.265  0.577  0.757  1.0
  O  O20  1  0.304  0.699  0.560  1.0
  O  O21  1  0.804  0.301  0.940  1.0
  O  O22  1  0.696  0.301  0.440  1.0
  O  O23  1  0.196  0.699  0.060  1.0
  O  O24  1  0.243  0.413  0.479  1.0
  O  O25  1  0.743  0.587  0.021  1.0
  O  O26  1  0.757  0.587  0.521  1.0
  O  O27  1  0.257  0.413  0.979  1.0
  O  O28  1  0.334  0.926  0.359  1.0
  O  O29  1  0.834  0.074  0.141  1.0
  O  O30  1  0.666  0.074  0.641  1.0
  O  O31  1  0.166  0.926  0.859  1.0
  O  O32  1  0.087  0.073  0.144  1.0
  O  O33  1  0.587  0.927  0.356  1.0
  O  O34  1  0.913  0.927  0.856  1.0
  O  O35  1  0.413  0.073  0.644  1.0
  O  O36  1  0.965  0.987  0.287  1.0
  O  O37  1  0.465  0.013  0.213  1.0
  O  O38  1  0.035  0.013  0.713  1.0
  O  O39  1  0.535  0.987  0.787  1.0
  O  O40  1  0.956  0.763  0.200  1.0
  O  O41  1  0.456  0.237  0.300  1.0
  O  O42  1  0.044  0.237  0.800  1.0
  O  O43  1  0.544  0.763  0.700  1.0
  O  O44  1  0.698  0.589  0.234  1.0
  O  O45  1  0.198  0.411  0.266  1.0
  O  O46  1  0.302  0.411  0.766  1.0
  O  O47  1  0.802  0.589  0.734  1.0
[/CIF]
.
The compound described by VSO8O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and four VSO8 clusters. In each VSO8 cluster, V(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one V(1)O5 trigonal bipyramid. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one V(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VSO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.720
_cell_length_b   7.206
_cell_length_c   15.415
_cell_angle_alpha   69.203
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1009.385
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.295  0.675  0.459  1.0
  V  V1  1  0.795  0.325  0.041  1.0
  V  V2  1  0.705  0.325  0.541  1.0
  V  V3  1  0.205  0.675  0.959  1.0
  S  S4  1  0.962  0.971  0.194  1.0
  S  S5  1  0.462  0.029  0.306  1.0
  S  S6  1  0.038  0.029  0.806  1.0
  S  S7  1  0.538  0.971  0.694  1.0
  O  O8  1  0.455  0.564  0.431  1.0
  O  O9  1  0.955  0.436  0.069  1.0
  O  O10  1  0.545  0.436  0.569  1.0
  O  O11  1  0.045  0.564  0.931  1.0
  O  O12  1  0.113  0.671  0.429  1.0
  O  O13  1  0.613  0.329  0.071  1.0
  O  O14  1  0.887  0.329  0.571  1.0
  O  O15  1  0.387  0.671  0.929  1.0
  O  O16  1  0.235  0.577  0.257  1.0
  O  O17  1  0.735  0.423  0.243  1.0
  O  O18  1  0.765  0.423  0.743  1.0
  O  O19  1  0.265  0.577  0.757  1.0
  O  O20  1  0.304  0.699  0.560  1.0
  O  O21  1  0.804  0.301  0.940  1.0
  O  O22  1  0.696  0.301  0.440  1.0
  O  O23  1  0.196  0.699  0.060  1.0
  O  O24  1  0.243  0.413  0.479  1.0
  O  O25  1  0.743  0.587  0.021  1.0
  O  O26  1  0.757  0.587  0.521  1.0
  O  O27  1  0.257  0.413  0.979  1.0
  O  O28  1  0.334  0.926  0.359  1.0
  O  O29  1  0.834  0.074  0.141  1.0
  O  O30  1  0.666  0.074  0.641  1.0
  O  O31  1  0.166  0.926  0.859  1.0
  O  O32  1  0.087  0.073  0.144  1.0
  O  O33  1  0.587  0.927  0.356  1.0
  O  O34  1  0.913  0.927  0.856  1.0
  O  O35  1  0.413  0.073  0.644  1.0
  O  O36  1  0.965  0.987  0.287  1.0
  O  O37  1  0.465  0.013  0.213  1.0
  O  O38  1  0.035  0.013  0.713  1.0
  O  O39  1  0.535  0.987  0.787  1.0
  O  O40  1  0.956  0.763  0.200  1.0
  O  O41  1  0.456  0.237  0.300  1.0
  O  O42  1  0.044  0.237  0.800  1.0
  O  O43  1  0.544  0.763  0.700  1.0
  O  O44  1  0.698  0.589  0.234  1.0
  O  O45  1  0.198  0.411  0.266  1.0
  O  O46  1  0.302  0.411  0.766  1.0
  O  O47  1  0.802  0.589  0.734  1.0
[/CIF]
.