The material structure described by Pt(NBr)2Pt(NBr2)2 is Protactinium structured and crystallizes in the orthorhombic Pmmn space group. The structure is zero-dimensional and consists of two Pt(NBr)2 clusters and two Pt(NBr2)2 clusters. In each Pt(NBr)2 cluster, Pt(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(2) and two equivalent Br(2) atoms. N(2) is bonded in a single-bond geometry to one Pt(1) atom. Br(2) is bonded in a single-bond geometry to one Pt(1) atom. In each Pt(NBr2)2 cluster, Pt(2) is bonded in an octahedral geometry to two equivalent N(1), one Br(3), one Br(4), and two equivalent Br(1) atoms. N(1) is bonded in a single-bond geometry to one Pt(2) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Pt(2) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Pt(2) atom. In the third Br site, Br(4) is bonded in a single-bond geometry to one Pt(2) atom. is represented by the CIF card [CIF]
data_PtBr3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.717
_cell_length_b   8.837
_cell_length_c   13.580
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1046.125
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.500  0.375  1.0
  Pt  Pt1  1  0.000  0.000  0.625  1.0
  Pt  Pt2  1  0.500  0.500  0.876  1.0
  Pt  Pt3  1  0.000  0.000  0.124  1.0
  Br  Br4  1  0.783  0.500  0.875  1.0
  Br  Br5  1  0.283  0.000  0.125  1.0
  Br  Br6  1  0.717  0.000  0.125  1.0
  Br  Br7  1  0.217  0.500  0.875  1.0
  Br  Br8  1  0.786  0.500  0.375  1.0
  Br  Br9  1  0.286  0.000  0.625  1.0
  Br  Br10  1  0.714  0.000  0.625  1.0
  Br  Br11  1  0.214  0.500  0.375  1.0
  Br  Br12  1  0.500  0.500  0.694  1.0
  Br  Br13  1  0.000  0.000  0.306  1.0
  Br  Br14  1  0.500  0.500  0.057  1.0
  Br  Br15  1  0.000  0.000  0.943  1.0
  N  N16  1  0.500  0.270  0.873  1.0
  N  N17  1  0.500  0.730  0.873  1.0
  N  N18  1  0.000  0.770  0.127  1.0
  N  N19  1  0.000  0.230  0.127  1.0
  N  N20  1  0.500  0.297  0.375  1.0
  N  N21  1  0.500  0.703  0.375  1.0
  N  N22  1  0.000  0.797  0.625  1.0
  N  N23  1  0.000  0.203  0.625  1.0
[/CIF]
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The material structure described by Pt(NBr)2Pt(NBr2)2 is Protactinium structured and crystallizes in the orthorhombic Pmmn space group. The structure is zero-dimensional and consists of two Pt(NBr)2 clusters and two Pt(NBr2)2 clusters. In each Pt(NBr)2 cluster, Pt(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(2) and two equivalent Br(2) atoms. N(2) is bonded in a single-bond geometry to one Pt(1) atom. Br(2) is bonded in a single-bond geometry to one Pt(1) atom. In each Pt(NBr2)2 cluster, Pt(2) is bonded in an octahedral geometry to two equivalent N(1), one Br(3), one Br(4), and two equivalent Br(1) atoms. N(1) is bonded in a single-bond geometry to one Pt(2) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Pt(2) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Pt(2) atom. In the third Br site, Br(4) is bonded in a single-bond geometry to one Pt(2) atom. is represented by the CIF card [CIF]
data_PtBr3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.717
_cell_length_b   8.837
_cell_length_c   13.580
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1046.125
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.500  0.375  1.0
  Pt  Pt1  1  0.000  0.000  0.625  1.0
  Pt  Pt2  1  0.500  0.500  0.876  1.0
  Pt  Pt3  1  0.000  0.000  0.124  1.0
  Br  Br4  1  0.783  0.500  0.875  1.0
  Br  Br5  1  0.283  0.000  0.125  1.0
  Br  Br6  1  0.717  0.000  0.125  1.0
  Br  Br7  1  0.217  0.500  0.875  1.0
  Br  Br8  1  0.786  0.500  0.375  1.0
  Br  Br9  1  0.286  0.000  0.625  1.0
  Br  Br10  1  0.714  0.000  0.625  1.0
  Br  Br11  1  0.214  0.500  0.375  1.0
  Br  Br12  1  0.500  0.500  0.694  1.0
  Br  Br13  1  0.000  0.000  0.306  1.0
  Br  Br14  1  0.500  0.500  0.057  1.0
  Br  Br15  1  0.000  0.000  0.943  1.0
  N  N16  1  0.500  0.270  0.873  1.0
  N  N17  1  0.500  0.730  0.873  1.0
  N  N18  1  0.000  0.770  0.127  1.0
  N  N19  1  0.000  0.230  0.127  1.0
  N  N20  1  0.500  0.297  0.375  1.0
  N  N21  1  0.500  0.703  0.375  1.0
  N  N22  1  0.000  0.797  0.625  1.0
  N  N23  1  0.000  0.203  0.625  1.0
[/CIF]
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