The compound described by LiNd4Nb2In2O14 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(5), and two equivalent O(7) atoms. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(9), two equivalent O(3), and two equivalent O(7) atoms. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(5), one O(9), two equivalent O(4), and two equivalent O(8) atoms. In the third Nd site, Nd(3) is bonded in a 8-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. Nb(1) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form NbO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra, corners with two equivalent In(1)O6 octahedra, and corners with two equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 30-61°. There are two inequivalent In sites. In the first In site, In(1) is bonded to one O(2), one O(6), two equivalent O(4), and two equivalent O(8) atoms to form InO6 octahedra that share corners with two equivalent In(2)O6 octahedra and corners with four equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-60°. In the second In site, In(2) is bonded to one O(2), one O(6), two equivalent O(3), and two equivalent O(7) atoms to form distorted InO6 octahedra that share corners with two equivalent In(1)O6 octahedra and corners with four equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-61°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Nd(1), one Nd(2), and two equivalent Nb(1) atoms to form distorted ONd2Nb2 tetrahedra that share corners with two equivalent O(9)Nd4 tetrahedra, corners with four equivalent O(3)Nd2NbIn tetrahedra, edges with two equivalent O(8)Nd2NbIn tetrahedra, and  an edgeedge with one O(10)LiNd4 trigonal bipyramid. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Nd(3), one In(1), and one In(2) atom. In the third O site, O(3) is bonded to one Nd(1), one Nd(3), one Nb(1), and one In(2) atom to form distorted ONd2NbIn tetrahedra that share corners with two equivalent O(1)Nd2Nb2 tetrahedra, corners with two equivalent O(3)Nd2NbIn tetrahedra, corners with two equivalent O(9)Nd4 tetrahedra,  an edgeedge with one O(6)Nd2In2 tetrahedra,  an edgeedge with one O(8)Nd2NbIn tetrahedra, and  an edgeedge with one O(10)LiNd4 trigonal bipyramid. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Nd(2), one Nd(3), one Nb(1), and one In(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one Nd(2), and two equivalent Nb(1) atoms. In the sixth O site, O(6) is bonded to two equivalent Nd(3), one In(1), and one In(2) atom to form ONd2In2 tetrahedra that share corners with four equivalent O(8)Nd2NbIn tetrahedra, corners with two equivalent O(10)LiNd4 trigonal bipyramids,  an edgeedge with one O(9)Nd4 tetrahedra, and edges with two equivalent O(3)Nd2NbIn tetrahedra. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one Nd(1), one Nd(3), one Nb(1), and one In(2) atom. In the eighth O site, O(8) is bonded to one Nd(2), one Nd(3), one Nb(1), and one In(1) atom to form distorted ONd2NbIn tetrahedra that share corners with two equivalent O(6)Nd2In2 tetrahedra, corners with two equivalent O(8)Nd2NbIn tetrahedra, corners with two equivalent O(10)LiNd4 trigonal bipyramids,  an edgeedge with one O(1)Nd2Nb2 tetrahedra,  an edgeedge with one O(3)Nd2NbIn tetrahedra, and  an edgeedge with one O(9)Nd4 tetrahedra. In the ninth O site, O(9) is bonded to one Nd(1), one Nd(2), and two equivalent Nd(3) atoms to form ONd4 tetrahedra that share corners with two equivalent O(1)Nd2Nb2 tetrahedra, corners with four equivalent O(3)Nd2NbIn tetrahedra, corners with four equivalent O(10)LiNd4 trigonal bipyramids,  an edgeedge with one O(6)Nd2In2 tetrahedra, and edges with two equivalent O(8)Nd2NbIn tetrahedra. In the tenth O site, O(10) is bonded to one Li(1), one Nd(1), one Nd(2), and two equivalent Nd(3) atoms to form distorted OLiNd4 trigonal bipyramids that share corners with two equivalent O(6)Nd2In2 tetrahedra, corners with four equivalent O(8)Nd2NbIn tetrahedra, corners with four equivalent O(9)Nd4 tetrahedra,  an edgeedge with one O(1)Nd2Nb2 tetrahedra, and edges with two equivalent O(3)Nd2NbIn tetrahedra. is represented by the CIF card [CIF]
data_LiNd4Nb2In2O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.714
_cell_length_b   7.609
_cell_length_c   7.598
_cell_angle_alpha   90.000
_cell_angle_beta   60.495
_cell_angle_gamma   120.609
_symmetry_Int_Tables_number   1
_cell_volume   314.789
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.958  0.224  0.771  1.0
  Nd  Nd1  1  0.519  0.995  0.491  1.0
  Nd  Nd2  1  0.506  0.502  0.497  1.0
  Nd  Nd3  1  0.997  0.521  0.006  1.0
  Nd  Nd4  1  0.997  0.521  0.497  1.0
  Nb  Nb5  1  0.012  0.006  0.481  1.0
  Nb  Nb6  1  0.012  0.006  0.008  1.0
  In  In7  1  0.511  0.510  0.994  1.0
  In  In8  1  0.487  0.999  0.007  1.0
  O  O9  1  0.821  0.918  0.340  1.0
  O  O10  1  0.701  0.349  0.899  1.0
  O  O11  1  0.254  0.923  0.889  1.0
  O  O12  1  0.260  0.324  0.336  1.0
  O  O13  1  0.260  0.324  0.904  1.0
  O  O14  1  0.254  0.923  0.358  1.0
  O  O15  1  0.108  0.073  0.696  1.0
  O  O16  1  0.301  0.653  0.100  1.0
  O  O17  1  0.771  0.090  0.077  1.0
  O  O18  1  0.763  0.676  0.641  1.0
  O  O19  1  0.763  0.676  0.096  1.0
  O  O20  1  0.771  0.090  0.652  1.0
  O  O21  1  0.736  0.364  0.382  1.0
  O  O22  1  0.238  0.601  0.631  1.0
[/CIF]
.
The compound described by LiNd4Nb2In2O14 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(5), and two equivalent O(7) atoms. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(9), two equivalent O(3), and two equivalent O(7) atoms. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(5), one O(9), two equivalent O(4), and two equivalent O(8) atoms. In the third Nd site, Nd(3) is bonded in a 8-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. Nb(1) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form NbO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra, corners with two equivalent In(1)O6 octahedra, and corners with two equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 30-61°. There are two inequivalent In sites. In the first In site, In(1) is bonded to one O(2), one O(6), two equivalent O(4), and two equivalent O(8) atoms to form InO6 octahedra that share corners with two equivalent In(2)O6 octahedra and corners with four equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-60°. In the second In site, In(2) is bonded to one O(2), one O(6), two equivalent O(3), and two equivalent O(7) atoms to form distorted InO6 octahedra that share corners with two equivalent In(1)O6 octahedra and corners with four equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-61°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Nd(1), one Nd(2), and two equivalent Nb(1) atoms to form distorted ONd2Nb2 tetrahedra that share corners with two equivalent O(9)Nd4 tetrahedra, corners with four equivalent O(3)Nd2NbIn tetrahedra, edges with two equivalent O(8)Nd2NbIn tetrahedra, and  an edgeedge with one O(10)LiNd4 trigonal bipyramid. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Nd(3), one In(1), and one In(2) atom. In the third O site, O(3) is bonded to one Nd(1), one Nd(3), one Nb(1), and one In(2) atom to form distorted ONd2NbIn tetrahedra that share corners with two equivalent O(1)Nd2Nb2 tetrahedra, corners with two equivalent O(3)Nd2NbIn tetrahedra, corners with two equivalent O(9)Nd4 tetrahedra,  an edgeedge with one O(6)Nd2In2 tetrahedra,  an edgeedge with one O(8)Nd2NbIn tetrahedra, and  an edgeedge with one O(10)LiNd4 trigonal bipyramid. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Nd(2), one Nd(3), one Nb(1), and one In(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one Nd(2), and two equivalent Nb(1) atoms. In the sixth O site, O(6) is bonded to two equivalent Nd(3), one In(1), and one In(2) atom to form ONd2In2 tetrahedra that share corners with four equivalent O(8)Nd2NbIn tetrahedra, corners with two equivalent O(10)LiNd4 trigonal bipyramids,  an edgeedge with one O(9)Nd4 tetrahedra, and edges with two equivalent O(3)Nd2NbIn tetrahedra. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one Nd(1), one Nd(3), one Nb(1), and one In(2) atom. In the eighth O site, O(8) is bonded to one Nd(2), one Nd(3), one Nb(1), and one In(1) atom to form distorted ONd2NbIn tetrahedra that share corners with two equivalent O(6)Nd2In2 tetrahedra, corners with two equivalent O(8)Nd2NbIn tetrahedra, corners with two equivalent O(10)LiNd4 trigonal bipyramids,  an edgeedge with one O(1)Nd2Nb2 tetrahedra,  an edgeedge with one O(3)Nd2NbIn tetrahedra, and  an edgeedge with one O(9)Nd4 tetrahedra. In the ninth O site, O(9) is bonded to one Nd(1), one Nd(2), and two equivalent Nd(3) atoms to form ONd4 tetrahedra that share corners with two equivalent O(1)Nd2Nb2 tetrahedra, corners with four equivalent O(3)Nd2NbIn tetrahedra, corners with four equivalent O(10)LiNd4 trigonal bipyramids,  an edgeedge with one O(6)Nd2In2 tetrahedra, and edges with two equivalent O(8)Nd2NbIn tetrahedra. In the tenth O site, O(10) is bonded to one Li(1), one Nd(1), one Nd(2), and two equivalent Nd(3) atoms to form distorted OLiNd4 trigonal bipyramids that share corners with two equivalent O(6)Nd2In2 tetrahedra, corners with four equivalent O(8)Nd2NbIn tetrahedra, corners with four equivalent O(9)Nd4 tetrahedra,  an edgeedge with one O(1)Nd2Nb2 tetrahedra, and edges with two equivalent O(3)Nd2NbIn tetrahedra. is represented by the CIF card [CIF]
data_LiNd4Nb2In2O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.714
_cell_length_b   7.609
_cell_length_c   7.598
_cell_angle_alpha   90.000
_cell_angle_beta   60.495
_cell_angle_gamma   120.609
_symmetry_Int_Tables_number   1
_cell_volume   314.789
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.958  0.224  0.771  1.0
  Nd  Nd1  1  0.519  0.995  0.491  1.0
  Nd  Nd2  1  0.506  0.502  0.497  1.0
  Nd  Nd3  1  0.997  0.521  0.006  1.0
  Nd  Nd4  1  0.997  0.521  0.497  1.0
  Nb  Nb5  1  0.012  0.006  0.481  1.0
  Nb  Nb6  1  0.012  0.006  0.008  1.0
  In  In7  1  0.511  0.510  0.994  1.0
  In  In8  1  0.487  0.999  0.007  1.0
  O  O9  1  0.821  0.918  0.340  1.0
  O  O10  1  0.701  0.349  0.899  1.0
  O  O11  1  0.254  0.923  0.889  1.0
  O  O12  1  0.260  0.324  0.336  1.0
  O  O13  1  0.260  0.324  0.904  1.0
  O  O14  1  0.254  0.923  0.358  1.0
  O  O15  1  0.108  0.073  0.696  1.0
  O  O16  1  0.301  0.653  0.100  1.0
  O  O17  1  0.771  0.090  0.077  1.0
  O  O18  1  0.763  0.676  0.641  1.0
  O  O19  1  0.763  0.676  0.096  1.0
  O  O20  1  0.771  0.090  0.652  1.0
  O  O21  1  0.736  0.364  0.382  1.0
  O  O22  1  0.238  0.601  0.631  1.0
[/CIF]
.