The structure described by Li4Co3Cu3(WO8)2 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Cu(1)O6 octahedra,  a cornercorner with one Cu(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, and corners with three equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-66°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, corners with three equivalent W(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra, and  an edgeedge with one Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-70°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Cu(1)O6 octahedra,  a cornercorner with one Cu(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-69°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-68°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra, and  an edgeedge with one Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. In the second W site, W(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Cu(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 48°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Cu(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 47-48°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the second Cu site, Cu(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Co(2), and one Cu(3) atom. In the second O site, O(2) is bonded to one Li(4), one W(1), one Cu(1), and one Cu(2) atom to form distorted OLiCu2W tetrahedra that share  a cornercorner with one O(13)LiCo2Cu tetrahedra, corners with two equivalent O(4)LiCoCu2 tetrahedra, and  an edgeedge with one O(3)LiCoCu2 tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Co(1), one Cu(1), and one Cu(2) atom to form OLiCoCu2 tetrahedra that share  a cornercorner with one O(15)LiCo2W tetrahedra,  a cornercorner with one O(11)LiCoCuW tetrahedra,  a cornercorner with one O(12)LiCoCuW tetrahedra, corners with three equivalent O(4)LiCoCu2 tetrahedra, and  an edgeedge with one O(2)LiCu2W tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Co(1), one Cu(1), and one Cu(2) atom to form OLiCoCu2 tetrahedra that share corners with two equivalent O(2)LiCu2W tetrahedra and corners with three equivalent O(3)LiCoCu2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one Co(2), one Co(3), and one Cu(3) atom to form OLiCo2Cu tetrahedra that share corners with two equivalent O(15)LiCo2W tetrahedra, corners with two equivalent O(11)LiCoCuW tetrahedra, corners with two equivalent O(12)LiCoCuW tetrahedra, and corners with three equivalent O(13)LiCo2Cu tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Co(3), and one Cu(3) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(4), one W(1), one Co(1), and one Cu(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(4), one W(1), one Co(1), and one Cu(2) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one W(2), one Cu(1), and one Cu(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Co(2), and one Co(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one W(2), one Co(2), and one Cu(3) atom to form distorted OLiCoCuW tetrahedra that share  a cornercorner with one O(15)LiCo2W tetrahedra,  a cornercorner with one O(3)LiCoCu2 tetrahedra,  a cornercorner with one O(12)LiCoCuW tetrahedra, corners with two equivalent O(5)LiCo2Cu tetrahedra,  an edgeedge with one O(13)LiCo2Cu tetrahedra,  an edgeedge with one O(15)LiCo2W tetrahedra, and  an edgeedge with one O(12)LiCoCuW tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one W(2), one Co(3), and one Cu(3) atom to form distorted OLiCoCuW tetrahedra that share  a cornercorner with one O(15)LiCo2W tetrahedra,  a cornercorner with one O(3)LiCoCu2 tetrahedra,  a cornercorner with one O(11)LiCoCuW tetrahedra, corners with two equivalent O(5)LiCo2Cu tetrahedra,  an edgeedge with one O(13)LiCo2Cu tetrahedra,  an edgeedge with one O(15)LiCo2W tetrahedra, and  an edgeedge with one O(11)LiCoCuW tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(2), one Co(3), and one Cu(3) atom to form distorted OLiCo2Cu tetrahedra that share  a cornercorner with one O(2)LiCu2W tetrahedra, corners with three equivalent O(5)LiCo2Cu tetrahedra,  an edgeedge with one O(15)LiCo2W tetrahedra,  an edgeedge with one O(11)LiCoCuW tetrahedra, and  an edgeedge with one O(12)LiCoCuW tetrahedra. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one W(2), one Co(1), and one Cu(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one W(2), one Co(2), and one Co(3) atom to form distorted OLiCo2W tetrahedra that share  a cornercorner with one O(3)LiCoCu2 tetrahedra,  a cornercorner with one O(11)LiCoCuW tetrahedra,  a cornercorner with one O(12)LiCoCuW tetrahedra, corners with two equivalent O(5)LiCo2Cu tetrahedra,  an edgeedge with one O(13)LiCo2Cu tetrahedra,  an edgeedge with one O(11)LiCoCuW tetrahedra, and  an edgeedge with one O(12)LiCoCuW tetrahedra. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one W(2), one Co(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_Li4Co3Cu3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.907
_cell_length_b   5.770
_cell_length_c   9.593
_cell_angle_alpha   90.031
_cell_angle_beta   86.309
_cell_angle_gamma   119.327
_symmetry_Int_Tables_number   1
_cell_volume   284.252
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.342  0.671  0.905  1.0
  Li  Li1  1  0.990  0.995  0.990  1.0
  Li  Li2  1  0.988  0.994  0.488  1.0
  Li  Li3  1  0.688  0.344  0.410  1.0
  Co  Co4  1  0.659  0.829  0.217  1.0
  Co  Co5  1  0.826  0.660  0.713  1.0
  Co  Co6  1  0.826  0.167  0.713  1.0
  Cu  Cu7  1  0.162  0.824  0.214  1.0
  Cu  Cu8  1  0.162  0.338  0.214  1.0
  Cu  Cu9  1  0.333  0.166  0.715  1.0
  W  W10  1  0.353  0.677  0.492  1.0
  W  W11  1  0.661  0.330  0.985  1.0
  O  O12  1  0.160  0.825  0.587  1.0
  O  O13  1  0.059  0.530  0.357  1.0
  O  O14  1  0.349  0.674  0.123  1.0
  O  O15  1  0.983  0.991  0.295  1.0
  O  O16  1  0.983  0.992  0.801  1.0
  O  O17  1  0.158  0.336  0.587  1.0
  O  O18  1  0.524  0.976  0.356  1.0
  O  O19  1  0.524  0.549  0.357  1.0
  O  O20  1  0.321  0.160  0.075  1.0
  O  O21  1  0.658  0.828  0.608  1.0
  O  O22  1  0.533  0.495  0.844  1.0
  O  O23  1  0.534  0.037  0.844  1.0
  O  O24  1  0.676  0.338  0.618  1.0
  O  O25  1  0.796  0.646  0.085  1.0
  O  O26  1  0.957  0.479  0.830  1.0
  O  O27  1  0.795  0.149  0.085  1.0
[/CIF]
.
The structure described by Li4Co3Cu3(WO8)2 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Cu(1)O6 octahedra,  a cornercorner with one Cu(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, and corners with three equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-66°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, corners with three equivalent W(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra, and  an edgeedge with one Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-70°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Cu(1)O6 octahedra,  a cornercorner with one Cu(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-69°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-68°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra, and  an edgeedge with one Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. In the second W site, W(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Cu(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 48°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Cu(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 47-48°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the second Cu site, Cu(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Co(2), and one Cu(3) atom. In the second O site, O(2) is bonded to one Li(4), one W(1), one Cu(1), and one Cu(2) atom to form distorted OLiCu2W tetrahedra that share  a cornercorner with one O(13)LiCo2Cu tetrahedra, corners with two equivalent O(4)LiCoCu2 tetrahedra, and  an edgeedge with one O(3)LiCoCu2 tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Co(1), one Cu(1), and one Cu(2) atom to form OLiCoCu2 tetrahedra that share  a cornercorner with one O(15)LiCo2W tetrahedra,  a cornercorner with one O(11)LiCoCuW tetrahedra,  a cornercorner with one O(12)LiCoCuW tetrahedra, corners with three equivalent O(4)LiCoCu2 tetrahedra, and  an edgeedge with one O(2)LiCu2W tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Co(1), one Cu(1), and one Cu(2) atom to form OLiCoCu2 tetrahedra that share corners with two equivalent O(2)LiCu2W tetrahedra and corners with three equivalent O(3)LiCoCu2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one Co(2), one Co(3), and one Cu(3) atom to form OLiCo2Cu tetrahedra that share corners with two equivalent O(15)LiCo2W tetrahedra, corners with two equivalent O(11)LiCoCuW tetrahedra, corners with two equivalent O(12)LiCoCuW tetrahedra, and corners with three equivalent O(13)LiCo2Cu tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Co(3), and one Cu(3) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(4), one W(1), one Co(1), and one Cu(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(4), one W(1), one Co(1), and one Cu(2) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one W(2), one Cu(1), and one Cu(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Co(2), and one Co(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one W(2), one Co(2), and one Cu(3) atom to form distorted OLiCoCuW tetrahedra that share  a cornercorner with one O(15)LiCo2W tetrahedra,  a cornercorner with one O(3)LiCoCu2 tetrahedra,  a cornercorner with one O(12)LiCoCuW tetrahedra, corners with two equivalent O(5)LiCo2Cu tetrahedra,  an edgeedge with one O(13)LiCo2Cu tetrahedra,  an edgeedge with one O(15)LiCo2W tetrahedra, and  an edgeedge with one O(12)LiCoCuW tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one W(2), one Co(3), and one Cu(3) atom to form distorted OLiCoCuW tetrahedra that share  a cornercorner with one O(15)LiCo2W tetrahedra,  a cornercorner with one O(3)LiCoCu2 tetrahedra,  a cornercorner with one O(11)LiCoCuW tetrahedra, corners with two equivalent O(5)LiCo2Cu tetrahedra,  an edgeedge with one O(13)LiCo2Cu tetrahedra,  an edgeedge with one O(15)LiCo2W tetrahedra, and  an edgeedge with one O(11)LiCoCuW tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(2), one Co(3), and one Cu(3) atom to form distorted OLiCo2Cu tetrahedra that share  a cornercorner with one O(2)LiCu2W tetrahedra, corners with three equivalent O(5)LiCo2Cu tetrahedra,  an edgeedge with one O(15)LiCo2W tetrahedra,  an edgeedge with one O(11)LiCoCuW tetrahedra, and  an edgeedge with one O(12)LiCoCuW tetrahedra. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one W(2), one Co(1), and one Cu(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one W(2), one Co(2), and one Co(3) atom to form distorted OLiCo2W tetrahedra that share  a cornercorner with one O(3)LiCoCu2 tetrahedra,  a cornercorner with one O(11)LiCoCuW tetrahedra,  a cornercorner with one O(12)LiCoCuW tetrahedra, corners with two equivalent O(5)LiCo2Cu tetrahedra,  an edgeedge with one O(13)LiCo2Cu tetrahedra,  an edgeedge with one O(11)LiCoCuW tetrahedra, and  an edgeedge with one O(12)LiCoCuW tetrahedra. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one W(2), one Co(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_Li4Co3Cu3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.907
_cell_length_b   5.770
_cell_length_c   9.593
_cell_angle_alpha   90.031
_cell_angle_beta   86.309
_cell_angle_gamma   119.327
_symmetry_Int_Tables_number   1
_cell_volume   284.252
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.342  0.671  0.905  1.0
  Li  Li1  1  0.990  0.995  0.990  1.0
  Li  Li2  1  0.988  0.994  0.488  1.0
  Li  Li3  1  0.688  0.344  0.410  1.0
  Co  Co4  1  0.659  0.829  0.217  1.0
  Co  Co5  1  0.826  0.660  0.713  1.0
  Co  Co6  1  0.826  0.167  0.713  1.0
  Cu  Cu7  1  0.162  0.824  0.214  1.0
  Cu  Cu8  1  0.162  0.338  0.214  1.0
  Cu  Cu9  1  0.333  0.166  0.715  1.0
  W  W10  1  0.353  0.677  0.492  1.0
  W  W11  1  0.661  0.330  0.985  1.0
  O  O12  1  0.160  0.825  0.587  1.0
  O  O13  1  0.059  0.530  0.357  1.0
  O  O14  1  0.349  0.674  0.123  1.0
  O  O15  1  0.983  0.991  0.295  1.0
  O  O16  1  0.983  0.992  0.801  1.0
  O  O17  1  0.158  0.336  0.587  1.0
  O  O18  1  0.524  0.976  0.356  1.0
  O  O19  1  0.524  0.549  0.357  1.0
  O  O20  1  0.321  0.160  0.075  1.0
  O  O21  1  0.658  0.828  0.608  1.0
  O  O22  1  0.533  0.495  0.844  1.0
  O  O23  1  0.534  0.037  0.844  1.0
  O  O24  1  0.676  0.338  0.618  1.0
  O  O25  1  0.796  0.646  0.085  1.0
  O  O26  1  0.957  0.479  0.830  1.0
  O  O27  1  0.795  0.149  0.085  1.0
[/CIF]
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