The compound described by VMo5AgCu6O24 crystallizes in the triclinic P1 space group. V(1) is bonded to one O(1), one O(18), one O(3), one O(4), and one O(5) atom to form distorted VO5 tetrahedra that share  an edgeedge with one Mo(1)O7 pentagonal bipyramid. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(12), one O(18), one O(2), one O(4), and one O(8) atom to form distorted MoO7 pentagonal bipyramids that share  a cornercorner with one O(7)Cu2MoO tetrahedra and  an edgeedge with one V(1)O5 tetrahedra. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(19), one O(4), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(13), one O(16), one O(21), one O(5), and one O(6) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(14), one O(21), one O(22), one O(23), one O(24), and one O(7) atom. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(16), one O(19), one O(20), and one O(23) atom. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(20), one O(24), and one O(6) atom. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 3-coordinate geometry to one O(23), one O(8), and one O(9) atom. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(24), one O(3), and one O(7) atom. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to one O(14), one O(17), one O(3), and one O(5) atom. In the fourth Cu site, Cu(4) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(20) atom. In the fifth Cu site, Cu(5) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(19), and one O(22) atom. In the sixth Cu site, Cu(6) is bonded in a see-saw-like geometry to one O(15), one O(16), one O(2), and one O(7) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Mo(5), and one Ag(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Cu(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(2), and one Cu(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Mo(1), and one Mo(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one V(1), one Mo(3), one Cu(3), and one O(6) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one O(5) atom. In the seventh O site, O(7) is bonded to one Mo(4), one Cu(2), one Cu(6), and one O(8) atom to form distorted OCu2MoO tetrahedra that share  a cornercorner with one Mo(1)O7 pentagonal bipyramid and  a cornercorner with one O(16)CuMo2O tetrahedra. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cu(1), and one O(7) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Mo(1) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mo(1), one Cu(2), and one Cu(4) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Cu(4) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(5) atom. In the fourteenth O site, O(14) is bonded in a linear geometry to one Mo(4) and one Cu(3) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(6) atom. In the sixteenth O site, O(16) is bonded to one Mo(3), one Mo(5), one Cu(6), and one O(17) atom to form distorted corner-sharing OCuMo2O tetrahedra. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Cu(3), one Cu(5), and one O(16) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one V(1), one Mo(1), and one Cu(5) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(5), and one Cu(5) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one Mo(5), one Ag(1), and one Cu(4) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(4) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one Cu(5) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Mo(4), one Mo(5), and one Cu(1) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Mo(4), one Ag(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_VCu6AgMo5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.797
_cell_length_b   7.896
_cell_length_c   8.300
_cell_angle_alpha   105.718
_cell_angle_beta   115.561
_cell_angle_gamma   97.098
_symmetry_Int_Tables_number   1
_cell_volume   481.032
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.165  0.778  0.461  1.0
  Cu  Cu1  1  0.135  0.311  0.143  1.0
  Cu  Cu2  1  0.205  0.114  0.850  1.0
  Cu  Cu3  1  0.525  0.880  0.808  1.0
  Cu  Cu4  1  0.567  0.041  0.176  1.0
  Cu  Cu5  1  0.820  0.913  0.267  1.0
  Cu  Cu6  1  0.857  0.709  0.783  1.0
  Ag  Ag7  1  0.004  0.431  0.589  1.0
  Mo  Mo8  1  0.222  0.915  0.176  1.0
  Mo  Mo9  1  0.516  0.664  0.317  1.0
  Mo  Mo10  1  0.474  0.386  0.669  1.0
  Mo  Mo11  1  0.807  0.160  0.703  1.0
  Mo  Mo12  1  0.757  0.412  0.111  1.0
  O  O13  1  0.006  0.573  0.387  1.0
  O  O14  1  0.081  0.712  0.962  1.0
  O  O15  1  0.266  0.919  0.699  1.0
  O  O16  1  0.324  0.785  0.377  1.0
  O  O17  1  0.378  0.607  0.637  1.0
  O  O18  1  0.322  0.516  0.743  1.0
  O  O19  1  0.968  0.979  0.855  1.0
  O  O20  1  0.026  0.043  0.060  1.0
  O  O21  1  0.352  0.455  0.215  1.0
  O  O22  1  0.339  0.195  0.452  1.0
  O  O23  1  0.327  0.067  0.090  1.0
  O  O24  1  0.439  0.820  0.171  1.0
  O  O25  1  0.529  0.301  0.884  1.0
  O  O26  1  0.652  0.034  0.743  1.0
  O  O27  1  0.645  0.681  0.561  1.0
  O  O28  1  0.717  0.617  0.914  1.0
  O  O29  1  0.676  0.785  0.992  1.0
  O  O30  1  0.055  0.896  0.313  1.0
  O  O31  1  0.672  0.605  0.230  1.0
  O  O32  1  0.734  0.245  0.227  1.0
  O  O33  1  0.695  0.337  0.644  1.0
  O  O34  1  0.762  0.992  0.473  1.0
  O  O35  1  0.901  0.346  0.012  1.0
  O  O36  1  0.046  0.262  0.776  1.0
[/CIF]
.
The compound described by VMo5AgCu6O24 crystallizes in the triclinic P1 space group. V(1) is bonded to one O(1), one O(18), one O(3), one O(4), and one O(5) atom to form distorted VO5 tetrahedra that share  an edgeedge with one Mo(1)O7 pentagonal bipyramid. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(12), one O(18), one O(2), one O(4), and one O(8) atom to form distorted MoO7 pentagonal bipyramids that share  a cornercorner with one O(7)Cu2MoO tetrahedra and  an edgeedge with one V(1)O5 tetrahedra. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(19), one O(4), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(13), one O(16), one O(21), one O(5), and one O(6) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(14), one O(21), one O(22), one O(23), one O(24), and one O(7) atom. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(16), one O(19), one O(20), and one O(23) atom. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(20), one O(24), and one O(6) atom. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 3-coordinate geometry to one O(23), one O(8), and one O(9) atom. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(24), one O(3), and one O(7) atom. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to one O(14), one O(17), one O(3), and one O(5) atom. In the fourth Cu site, Cu(4) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(20) atom. In the fifth Cu site, Cu(5) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(19), and one O(22) atom. In the sixth Cu site, Cu(6) is bonded in a see-saw-like geometry to one O(15), one O(16), one O(2), and one O(7) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Mo(5), and one Ag(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Cu(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(2), and one Cu(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Mo(1), and one Mo(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one V(1), one Mo(3), one Cu(3), and one O(6) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one O(5) atom. In the seventh O site, O(7) is bonded to one Mo(4), one Cu(2), one Cu(6), and one O(8) atom to form distorted OCu2MoO tetrahedra that share  a cornercorner with one Mo(1)O7 pentagonal bipyramid and  a cornercorner with one O(16)CuMo2O tetrahedra. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cu(1), and one O(7) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Mo(1) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mo(1), one Cu(2), and one Cu(4) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Cu(4) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(5) atom. In the fourteenth O site, O(14) is bonded in a linear geometry to one Mo(4) and one Cu(3) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(6) atom. In the sixteenth O site, O(16) is bonded to one Mo(3), one Mo(5), one Cu(6), and one O(17) atom to form distorted corner-sharing OCuMo2O tetrahedra. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Cu(3), one Cu(5), and one O(16) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one V(1), one Mo(1), and one Cu(5) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(5), and one Cu(5) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one Mo(5), one Ag(1), and one Cu(4) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(4) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one Cu(5) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Mo(4), one Mo(5), and one Cu(1) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Mo(4), one Ag(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_VCu6AgMo5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.797
_cell_length_b   7.896
_cell_length_c   8.300
_cell_angle_alpha   105.718
_cell_angle_beta   115.561
_cell_angle_gamma   97.098
_symmetry_Int_Tables_number   1
_cell_volume   481.032
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.165  0.778  0.461  1.0
  Cu  Cu1  1  0.135  0.311  0.143  1.0
  Cu  Cu2  1  0.205  0.114  0.850  1.0
  Cu  Cu3  1  0.525  0.880  0.808  1.0
  Cu  Cu4  1  0.567  0.041  0.176  1.0
  Cu  Cu5  1  0.820  0.913  0.267  1.0
  Cu  Cu6  1  0.857  0.709  0.783  1.0
  Ag  Ag7  1  0.004  0.431  0.589  1.0
  Mo  Mo8  1  0.222  0.915  0.176  1.0
  Mo  Mo9  1  0.516  0.664  0.317  1.0
  Mo  Mo10  1  0.474  0.386  0.669  1.0
  Mo  Mo11  1  0.807  0.160  0.703  1.0
  Mo  Mo12  1  0.757  0.412  0.111  1.0
  O  O13  1  0.006  0.573  0.387  1.0
  O  O14  1  0.081  0.712  0.962  1.0
  O  O15  1  0.266  0.919  0.699  1.0
  O  O16  1  0.324  0.785  0.377  1.0
  O  O17  1  0.378  0.607  0.637  1.0
  O  O18  1  0.322  0.516  0.743  1.0
  O  O19  1  0.968  0.979  0.855  1.0
  O  O20  1  0.026  0.043  0.060  1.0
  O  O21  1  0.352  0.455  0.215  1.0
  O  O22  1  0.339  0.195  0.452  1.0
  O  O23  1  0.327  0.067  0.090  1.0
  O  O24  1  0.439  0.820  0.171  1.0
  O  O25  1  0.529  0.301  0.884  1.0
  O  O26  1  0.652  0.034  0.743  1.0
  O  O27  1  0.645  0.681  0.561  1.0
  O  O28  1  0.717  0.617  0.914  1.0
  O  O29  1  0.676  0.785  0.992  1.0
  O  O30  1  0.055  0.896  0.313  1.0
  O  O31  1  0.672  0.605  0.230  1.0
  O  O32  1  0.734  0.245  0.227  1.0
  O  O33  1  0.695  0.337  0.644  1.0
  O  O34  1  0.762  0.992  0.473  1.0
  O  O35  1  0.901  0.346  0.012  1.0
  O  O36  1  0.046  0.262  0.776  1.0
[/CIF]
.