The material structure described by Zn(MoO2)2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(4), two equivalent O(2), and three equivalent O(3) atoms to form a mixture of edge and corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the second Mo site, Mo(2) is bonded to one O(2), two equivalent O(4), and three equivalent O(1) atoms to form a mixture of edge and corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. Zn(1) is bonded in a 7-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Mo(2) and two equivalent Zn(1) atoms to form distorted OZn2Mo3 trigonal bipyramids that share  a cornercorner with one O(2)ZnMo3 tetrahedra, corners with two equivalent O(3)Zn2Mo3 trigonal bipyramids, edges with two equivalent O(2)ZnMo3 tetrahedra,  an edgeedge with one O(3)Zn2Mo3 trigonal bipyramid, and edges with four equivalent O(1)Zn2Mo3 trigonal bipyramids. In the second O site, O(2) is bonded to one Mo(2), two equivalent Mo(1), and one Zn(1) atom to form OZnMo3 tetrahedra that share corners with two equivalent O(2)ZnMo3 tetrahedra,  a cornercorner with one O(1)Zn2Mo3 trigonal bipyramid, corners with six equivalent O(3)Zn2Mo3 trigonal bipyramids,  an edgeedge with one O(3)Zn2Mo3 trigonal bipyramid, and edges with two equivalent O(1)Zn2Mo3 trigonal bipyramids. In the third O site, O(3) is bonded to three equivalent Mo(1) and two equivalent Zn(1) atoms to form distorted OZn2Mo3 trigonal bipyramids that share corners with six equivalent O(2)ZnMo3 tetrahedra, corners with two equivalent O(1)Zn2Mo3 trigonal bipyramids,  an edgeedge with one O(2)ZnMo3 tetrahedra,  an edgeedge with one O(1)Zn2Mo3 trigonal bipyramid, and edges with four equivalent O(3)Zn2Mo3 trigonal bipyramids. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Mo(1), two equivalent Mo(2), and two equivalent Zn(1) atoms. is represented by the CIF card [CIF]
data_Zn(MoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.161
_cell_length_b   9.659
_cell_length_c   11.003
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   335.995
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.747  0.348  1.0
  Zn  Zn1  1  0.750  0.253  0.652  1.0
  Zn  Zn2  1  0.250  0.247  0.152  1.0
  Zn  Zn3  1  0.750  0.753  0.848  1.0
  Mo  Mo4  1  0.750  0.894  0.098  1.0
  Mo  Mo5  1  0.250  0.606  0.598  1.0
  Mo  Mo6  1  0.750  0.394  0.402  1.0
  Mo  Mo7  1  0.250  0.106  0.902  1.0
  Mo  Mo8  1  0.250  0.047  0.377  1.0
  Mo  Mo9  1  0.750  0.953  0.623  1.0
  Mo  Mo10  1  0.250  0.547  0.123  1.0
  Mo  Mo11  1  0.750  0.453  0.877  1.0
  O  O12  1  0.750  0.399  0.069  1.0
  O  O13  1  0.250  0.601  0.931  1.0
  O  O14  1  0.750  0.899  0.431  1.0
  O  O15  1  0.250  0.101  0.569  1.0
  O  O16  1  0.750  0.583  0.721  1.0
  O  O17  1  0.250  0.417  0.279  1.0
  O  O18  1  0.750  0.083  0.779  1.0
  O  O19  1  0.250  0.917  0.221  1.0
  O  O20  1  0.750  0.116  0.048  1.0
  O  O21  1  0.250  0.884  0.952  1.0
  O  O22  1  0.750  0.616  0.452  1.0
  O  O23  1  0.250  0.384  0.548  1.0
  O  O24  1  0.250  0.314  0.824  1.0
  O  O25  1  0.750  0.686  0.176  1.0
  O  O26  1  0.750  0.186  0.324  1.0
  O  O27  1  0.250  0.814  0.676  1.0
[/CIF]
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The material structure described by Zn(MoO2)2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(4), two equivalent O(2), and three equivalent O(3) atoms to form a mixture of edge and corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the second Mo site, Mo(2) is bonded to one O(2), two equivalent O(4), and three equivalent O(1) atoms to form a mixture of edge and corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. Zn(1) is bonded in a 7-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Mo(2) and two equivalent Zn(1) atoms to form distorted OZn2Mo3 trigonal bipyramids that share  a cornercorner with one O(2)ZnMo3 tetrahedra, corners with two equivalent O(3)Zn2Mo3 trigonal bipyramids, edges with two equivalent O(2)ZnMo3 tetrahedra,  an edgeedge with one O(3)Zn2Mo3 trigonal bipyramid, and edges with four equivalent O(1)Zn2Mo3 trigonal bipyramids. In the second O site, O(2) is bonded to one Mo(2), two equivalent Mo(1), and one Zn(1) atom to form OZnMo3 tetrahedra that share corners with two equivalent O(2)ZnMo3 tetrahedra,  a cornercorner with one O(1)Zn2Mo3 trigonal bipyramid, corners with six equivalent O(3)Zn2Mo3 trigonal bipyramids,  an edgeedge with one O(3)Zn2Mo3 trigonal bipyramid, and edges with two equivalent O(1)Zn2Mo3 trigonal bipyramids. In the third O site, O(3) is bonded to three equivalent Mo(1) and two equivalent Zn(1) atoms to form distorted OZn2Mo3 trigonal bipyramids that share corners with six equivalent O(2)ZnMo3 tetrahedra, corners with two equivalent O(1)Zn2Mo3 trigonal bipyramids,  an edgeedge with one O(2)ZnMo3 tetrahedra,  an edgeedge with one O(1)Zn2Mo3 trigonal bipyramid, and edges with four equivalent O(3)Zn2Mo3 trigonal bipyramids. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Mo(1), two equivalent Mo(2), and two equivalent Zn(1) atoms. is represented by the CIF card [CIF]
data_Zn(MoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.161
_cell_length_b   9.659
_cell_length_c   11.003
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   335.995
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.747  0.348  1.0
  Zn  Zn1  1  0.750  0.253  0.652  1.0
  Zn  Zn2  1  0.250  0.247  0.152  1.0
  Zn  Zn3  1  0.750  0.753  0.848  1.0
  Mo  Mo4  1  0.750  0.894  0.098  1.0
  Mo  Mo5  1  0.250  0.606  0.598  1.0
  Mo  Mo6  1  0.750  0.394  0.402  1.0
  Mo  Mo7  1  0.250  0.106  0.902  1.0
  Mo  Mo8  1  0.250  0.047  0.377  1.0
  Mo  Mo9  1  0.750  0.953  0.623  1.0
  Mo  Mo10  1  0.250  0.547  0.123  1.0
  Mo  Mo11  1  0.750  0.453  0.877  1.0
  O  O12  1  0.750  0.399  0.069  1.0
  O  O13  1  0.250  0.601  0.931  1.0
  O  O14  1  0.750  0.899  0.431  1.0
  O  O15  1  0.250  0.101  0.569  1.0
  O  O16  1  0.750  0.583  0.721  1.0
  O  O17  1  0.250  0.417  0.279  1.0
  O  O18  1  0.750  0.083  0.779  1.0
  O  O19  1  0.250  0.917  0.221  1.0
  O  O20  1  0.750  0.116  0.048  1.0
  O  O21  1  0.250  0.884  0.952  1.0
  O  O22  1  0.750  0.616  0.452  1.0
  O  O23  1  0.250  0.384  0.548  1.0
  O  O24  1  0.250  0.314  0.824  1.0
  O  O25  1  0.750  0.686  0.176  1.0
  O  O26  1  0.750  0.186  0.324  1.0
  O  O27  1  0.250  0.814  0.676  1.0
[/CIF]
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