The crystal structure described by VOF is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(5), two equivalent O(4), one F(1), and two equivalent F(2) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the second V site, V(2) is bonded to one O(2), one O(3), one O(4), one F(2), one F(3), and one F(4) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the third V site, V(3) is bonded to one O(1), two equivalent O(3), one F(5), and two equivalent F(3) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. In the fourth V site, V(4) is bonded to one O(2), one O(3), one O(4), one F(1), one F(4), and one F(5) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the fifth V site, V(5) is bonded to one O(1), one O(2), one O(5), one F(2), one F(3), and one F(4) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(5) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(4) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(5) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(5) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.843
_cell_length_b   7.843
_cell_length_c   4.709
_cell_angle_alpha   89.789
_cell_angle_beta   89.789
_cell_angle_gamma   105.846
_symmetry_Int_Tables_number   1
_cell_volume   278.644
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.619  0.619  0.562  1.0
  V  V1  1  0.364  0.865  0.476  1.0
  V  V2  1  0.136  0.136  0.452  1.0
  V  V3  1  0.865  0.364  0.476  1.0
  V  V4  1  0.513  0.246  0.010  1.0
  V  V5  1  0.761  0.996  0.011  1.0
  V  V6  1  0.246  0.513  0.010  1.0
  V  V7  1  0.996  0.761  0.011  1.0
  O  O8  1  0.980  0.980  0.205  1.0
  O  O9  1  0.726  0.212  0.190  1.0
  O  O10  1  0.212  0.726  0.190  1.0
  O  O11  1  0.357  0.096  0.297  1.0
  O  O12  1  0.096  0.357  0.297  1.0
  O  O13  1  0.652  0.395  0.698  1.0
  O  O14  1  0.395  0.652  0.698  1.0
  O  O15  1  0.780  0.780  0.813  1.0
  F  F16  1  0.477  0.477  0.206  1.0
  F  F17  1  0.599  0.839  0.304  1.0
  F  F18  1  0.839  0.599  0.304  1.0
  F  F19  1  0.910  0.152  0.698  1.0
  F  F20  1  0.152  0.910  0.698  1.0
  F  F21  1  0.018  0.530  0.794  1.0
  F  F22  1  0.530  0.018  0.794  1.0
  F  F23  1  0.279  0.279  0.806  1.0
[/CIF]
.
The crystal structure described by VOF is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(5), two equivalent O(4), one F(1), and two equivalent F(2) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the second V site, V(2) is bonded to one O(2), one O(3), one O(4), one F(2), one F(3), and one F(4) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the third V site, V(3) is bonded to one O(1), two equivalent O(3), one F(5), and two equivalent F(3) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. In the fourth V site, V(4) is bonded to one O(2), one O(3), one O(4), one F(1), one F(4), and one F(5) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the fifth V site, V(5) is bonded to one O(1), one O(2), one O(5), one F(2), one F(3), and one F(4) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(5) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(4) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(5) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(5) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.843
_cell_length_b   7.843
_cell_length_c   4.709
_cell_angle_alpha   89.789
_cell_angle_beta   89.789
_cell_angle_gamma   105.846
_symmetry_Int_Tables_number   1
_cell_volume   278.644
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.619  0.619  0.562  1.0
  V  V1  1  0.364  0.865  0.476  1.0
  V  V2  1  0.136  0.136  0.452  1.0
  V  V3  1  0.865  0.364  0.476  1.0
  V  V4  1  0.513  0.246  0.010  1.0
  V  V5  1  0.761  0.996  0.011  1.0
  V  V6  1  0.246  0.513  0.010  1.0
  V  V7  1  0.996  0.761  0.011  1.0
  O  O8  1  0.980  0.980  0.205  1.0
  O  O9  1  0.726  0.212  0.190  1.0
  O  O10  1  0.212  0.726  0.190  1.0
  O  O11  1  0.357  0.096  0.297  1.0
  O  O12  1  0.096  0.357  0.297  1.0
  O  O13  1  0.652  0.395  0.698  1.0
  O  O14  1  0.395  0.652  0.698  1.0
  O  O15  1  0.780  0.780  0.813  1.0
  F  F16  1  0.477  0.477  0.206  1.0
  F  F17  1  0.599  0.839  0.304  1.0
  F  F18  1  0.839  0.599  0.304  1.0
  F  F19  1  0.910  0.152  0.698  1.0
  F  F20  1  0.152  0.910  0.698  1.0
  F  F21  1  0.018  0.530  0.794  1.0
  F  F22  1  0.530  0.018  0.794  1.0
  F  F23  1  0.279  0.279  0.806  1.0
[/CIF]
.