The structure described by Tm5(ReO6)2 crystallizes in the monoclinic C2/m space group. There are three inequivalent Tm sites. In the first Tm site, Tm(1) is bonded to one O(3), two equivalent O(1), and four equivalent O(2) atoms to form distorted TmO7 pentagonal bipyramids that share corners with two equivalent Tm(3)O6 octahedra,  an edgeedge with one Tm(3)O6 octahedra, edges with two equivalent Re(1)O6 octahedra, and edges with two equivalent Tm(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 55°. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to one O(3), two equivalent O(2), and four equivalent O(1) atoms. In the third Tm site, Tm(3) is bonded to two equivalent O(4) and four equivalent O(2) atoms to form TmO6 octahedra that share corners with four equivalent Re(1)O6 octahedra, corners with four equivalent Tm(1)O7 pentagonal bipyramids, and edges with two equivalent Tm(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 38°. Re(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form ReO6 octahedra that share corners with two equivalent Tm(3)O6 octahedra, edges with two equivalent Re(1)O6 octahedra, and edges with two equivalent Tm(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 38°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Tm(1), two equivalent Tm(2), and one Re(1) atom to form distorted OTm3Re tetrahedra that share corners with four equivalent O(1)Tm3Re tetrahedra, corners with six equivalent O(2)Tm4 tetrahedra,  a cornercorner with one O(3)Tm2Re2 trigonal pyramid,  an edgeedge with one O(2)Tm4 tetrahedra, edges with two equivalent O(1)Tm3Re tetrahedra, and edges with two equivalent O(3)Tm2Re2 trigonal pyramids. In the second O site, O(2) is bonded to one Tm(2), one Tm(3), and two equivalent Tm(1) atoms to form OTm4 tetrahedra that share corners with four equivalent O(2)Tm4 tetrahedra, corners with six equivalent O(1)Tm3Re tetrahedra, corners with three equivalent O(3)Tm2Re2 trigonal pyramids,  an edgeedge with one O(1)Tm3Re tetrahedra, and edges with three equivalent O(2)Tm4 tetrahedra. In the third O site, O(3) is bonded to one Tm(1), one Tm(2), and two equivalent Re(1) atoms to form distorted OTm2Re2 trigonal pyramids that share corners with two equivalent O(1)Tm3Re tetrahedra, corners with six equivalent O(2)Tm4 tetrahedra, edges with four equivalent O(1)Tm3Re tetrahedra, and  an edgeedge with one O(3)Tm2Re2 trigonal pyramid. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Tm(3) and two equivalent Re(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tm5(ReO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.701
_cell_length_b   6.701
_cell_length_c   7.387
_cell_angle_alpha   73.728
_cell_angle_beta   73.728
_cell_angle_gamma   49.187
_symmetry_Int_Tables_number   1
_cell_volume   238.802
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.802  0.802  0.360  1.0
  Tm  Tm1  1  0.198  0.198  0.640  1.0
  Tm  Tm2  1  0.185  0.185  0.178  1.0
  Tm  Tm3  1  0.815  0.815  0.822  1.0
  Tm  Tm4  1  0.500  0.500  0.500  1.0
  Re  Re5  1  0.286  0.714  0.000  1.0
  Re  Re6  1  0.714  0.286  0.000  1.0
  O  O7  1  0.413  0.922  0.913  1.0
  O  O8  1  0.078  0.587  0.087  1.0
  O  O9  1  0.587  0.078  0.087  1.0
  O  O10  1  0.922  0.413  0.913  1.0
  O  O11  1  0.599  0.094  0.572  1.0
  O  O12  1  0.906  0.401  0.428  1.0
  O  O13  1  0.401  0.906  0.428  1.0
  O  O14  1  0.001  0.001  0.818  1.0
  O  O15  1  0.999  0.999  0.182  1.0
  O  O16  1  0.498  0.498  0.791  1.0
  O  O17  1  0.502  0.502  0.209  1.0
  O  O18  1  0.094  0.599  0.572  1.0
[/CIF]
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The structure described by Tm5(ReO6)2 crystallizes in the monoclinic C2/m space group. There are three inequivalent Tm sites. In the first Tm site, Tm(1) is bonded to one O(3), two equivalent O(1), and four equivalent O(2) atoms to form distorted TmO7 pentagonal bipyramids that share corners with two equivalent Tm(3)O6 octahedra,  an edgeedge with one Tm(3)O6 octahedra, edges with two equivalent Re(1)O6 octahedra, and edges with two equivalent Tm(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 55°. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to one O(3), two equivalent O(2), and four equivalent O(1) atoms. In the third Tm site, Tm(3) is bonded to two equivalent O(4) and four equivalent O(2) atoms to form TmO6 octahedra that share corners with four equivalent Re(1)O6 octahedra, corners with four equivalent Tm(1)O7 pentagonal bipyramids, and edges with two equivalent Tm(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 38°. Re(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form ReO6 octahedra that share corners with two equivalent Tm(3)O6 octahedra, edges with two equivalent Re(1)O6 octahedra, and edges with two equivalent Tm(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 38°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Tm(1), two equivalent Tm(2), and one Re(1) atom to form distorted OTm3Re tetrahedra that share corners with four equivalent O(1)Tm3Re tetrahedra, corners with six equivalent O(2)Tm4 tetrahedra,  a cornercorner with one O(3)Tm2Re2 trigonal pyramid,  an edgeedge with one O(2)Tm4 tetrahedra, edges with two equivalent O(1)Tm3Re tetrahedra, and edges with two equivalent O(3)Tm2Re2 trigonal pyramids. In the second O site, O(2) is bonded to one Tm(2), one Tm(3), and two equivalent Tm(1) atoms to form OTm4 tetrahedra that share corners with four equivalent O(2)Tm4 tetrahedra, corners with six equivalent O(1)Tm3Re tetrahedra, corners with three equivalent O(3)Tm2Re2 trigonal pyramids,  an edgeedge with one O(1)Tm3Re tetrahedra, and edges with three equivalent O(2)Tm4 tetrahedra. In the third O site, O(3) is bonded to one Tm(1), one Tm(2), and two equivalent Re(1) atoms to form distorted OTm2Re2 trigonal pyramids that share corners with two equivalent O(1)Tm3Re tetrahedra, corners with six equivalent O(2)Tm4 tetrahedra, edges with four equivalent O(1)Tm3Re tetrahedra, and  an edgeedge with one O(3)Tm2Re2 trigonal pyramid. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Tm(3) and two equivalent Re(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tm5(ReO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.701
_cell_length_b   6.701
_cell_length_c   7.387
_cell_angle_alpha   73.728
_cell_angle_beta   73.728
_cell_angle_gamma   49.187
_symmetry_Int_Tables_number   1
_cell_volume   238.802
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.802  0.802  0.360  1.0
  Tm  Tm1  1  0.198  0.198  0.640  1.0
  Tm  Tm2  1  0.185  0.185  0.178  1.0
  Tm  Tm3  1  0.815  0.815  0.822  1.0
  Tm  Tm4  1  0.500  0.500  0.500  1.0
  Re  Re5  1  0.286  0.714  0.000  1.0
  Re  Re6  1  0.714  0.286  0.000  1.0
  O  O7  1  0.413  0.922  0.913  1.0
  O  O8  1  0.078  0.587  0.087  1.0
  O  O9  1  0.587  0.078  0.087  1.0
  O  O10  1  0.922  0.413  0.913  1.0
  O  O11  1  0.599  0.094  0.572  1.0
  O  O12  1  0.906  0.401  0.428  1.0
  O  O13  1  0.401  0.906  0.428  1.0
  O  O14  1  0.001  0.001  0.818  1.0
  O  O15  1  0.999  0.999  0.182  1.0
  O  O16  1  0.498  0.498  0.791  1.0
  O  O17  1  0.502  0.502  0.209  1.0
  O  O18  1  0.094  0.599  0.572  1.0
[/CIF]
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