The crystal structure described by KN3H8 crystallizes in the orthorhombic C222_1 space group. K(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent H(2), and two equivalent H(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to two equivalent K(1) and two equivalent H(3) atoms. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one K(1), one H(1), one H(2), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one K(1) and one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one K(1) and one N(2) atom. is represented by the CIF card [CIF]
data_KH8N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.962
_cell_length_b   5.962
_cell_length_c   6.579
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.638
_symmetry_Int_Tables_number   1
_cell_volume   220.246
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.062  0.938  0.750  1.0
  K  K1  1  0.938  0.062  0.250  1.0
  H  H2  1  0.479  0.789  0.524  1.0
  H  H3  1  0.505  0.071  0.555  1.0
  H  H4  1  0.416  0.409  0.621  1.0
  H  H5  1  0.590  0.921  0.735  1.0
  H  H6  1  0.079  0.410  0.765  1.0
  H  H7  1  0.591  0.584  0.879  1.0
  H  H8  1  0.929  0.495  0.945  1.0
  H  H9  1  0.211  0.521  0.976  1.0
  H  H10  1  0.521  0.211  0.024  1.0
  H  H11  1  0.495  0.929  0.055  1.0
  H  H12  1  0.584  0.591  0.121  1.0
  H  H13  1  0.410  0.079  0.235  1.0
  H  H14  1  0.921  0.590  0.265  1.0
  H  H15  1  0.409  0.416  0.379  1.0
  H  H16  1  0.071  0.505  0.445  1.0
  H  H17  1  0.789  0.479  0.476  1.0
  N  N18  1  0.318  0.318  0.500  1.0
  N  N19  1  0.588  0.948  0.581  1.0
  N  N20  1  0.052  0.412  0.919  1.0
  N  N21  1  0.682  0.682  0.000  1.0
  N  N22  1  0.412  0.052  0.081  1.0
  N  N23  1  0.948  0.588  0.419  1.0
[/CIF]
.
The crystal structure described by KN3H8 crystallizes in the orthorhombic C222_1 space group. K(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent H(2), and two equivalent H(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to two equivalent K(1) and two equivalent H(3) atoms. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one K(1), one H(1), one H(2), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one K(1) and one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one K(1) and one N(2) atom. is represented by the CIF card [CIF]
data_KH8N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.962
_cell_length_b   5.962
_cell_length_c   6.579
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.638
_symmetry_Int_Tables_number   1
_cell_volume   220.246
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.062  0.938  0.750  1.0
  K  K1  1  0.938  0.062  0.250  1.0
  H  H2  1  0.479  0.789  0.524  1.0
  H  H3  1  0.505  0.071  0.555  1.0
  H  H4  1  0.416  0.409  0.621  1.0
  H  H5  1  0.590  0.921  0.735  1.0
  H  H6  1  0.079  0.410  0.765  1.0
  H  H7  1  0.591  0.584  0.879  1.0
  H  H8  1  0.929  0.495  0.945  1.0
  H  H9  1  0.211  0.521  0.976  1.0
  H  H10  1  0.521  0.211  0.024  1.0
  H  H11  1  0.495  0.929  0.055  1.0
  H  H12  1  0.584  0.591  0.121  1.0
  H  H13  1  0.410  0.079  0.235  1.0
  H  H14  1  0.921  0.590  0.265  1.0
  H  H15  1  0.409  0.416  0.379  1.0
  H  H16  1  0.071  0.505  0.445  1.0
  H  H17  1  0.789  0.479  0.476  1.0
  N  N18  1  0.318  0.318  0.500  1.0
  N  N19  1  0.588  0.948  0.581  1.0
  N  N20  1  0.052  0.412  0.919  1.0
  N  N21  1  0.682  0.682  0.000  1.0
  N  N22  1  0.412  0.052  0.081  1.0
  N  N23  1  0.948  0.588  0.419  1.0
[/CIF]
.