The material described by TbWFe6Co5 crystallizes in the orthorhombic Imm2 space group. Tb(1) is bonded in a 20-coordinate geometry to one W(1), two equivalent Fe(2), two equivalent Fe(3), eight equivalent Fe(1), one Co(2), two equivalent Co(1), and four equivalent Co(3) atoms. W(1) is bonded in a 14-coordinate geometry to one Tb(1), two equivalent Fe(2), four equivalent Fe(1), one Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Tb(1), one W(1), one Fe(2), one Fe(3), two equivalent Fe(1), one Co(2), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeTb2Fe4Co5W cuboctahedra that share corners with two equivalent Fe(2)Tb2Fe4Co4W2 cuboctahedra, corners with two equivalent Fe(3)Tb2Fe4Co6 cuboctahedra, corners with ten equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(2)Tb2Fe4Co4W2 cuboctahedra,  an edgeedge with one Fe(3)Tb2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Tb2Fe4Co5W cuboctahedra, faces with two equivalent Fe(2)Tb2Fe4Co4W2 cuboctahedra, faces with two equivalent Fe(3)Tb2Fe4Co6 cuboctahedra, and faces with six equivalent Fe(1)Tb2Fe4Co5W cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Tb(1), two equivalent W(1), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeTb2Fe4Co4W2 cuboctahedra that share corners with six equivalent Fe(3)Tb2Fe4Co6 cuboctahedra, corners with eight equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(3)Tb2Fe4Co6 cuboctahedra, edges with two equivalent Fe(2)Tb2Fe4Co4W2 cuboctahedra, edges with four equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  a faceface with one Fe(3)Tb2Fe4Co6 cuboctahedra, and faces with eight equivalent Fe(1)Tb2Fe4Co5W cuboctahedra. In the third Fe site, Fe(3) is bonded to two equivalent Tb(1), four equivalent Fe(1), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(3) atoms to form FeTb2Fe4Co6 cuboctahedra that share corners with six equivalent Fe(2)Tb2Fe4Co4W2 cuboctahedra, corners with eight equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(2)Tb2Fe4Co4W2 cuboctahedra, edges with two equivalent Fe(3)Tb2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  a faceface with one Fe(2)Tb2Fe4Co4W2 cuboctahedra, and faces with eight equivalent Fe(1)Tb2Fe4Co5W cuboctahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 14-coordinate geometry to one Tb(1), two equivalent W(1), one Fe(2), one Fe(3), four equivalent Fe(1), one Co(1), two equivalent Co(2), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to one Tb(1), one W(1), two equivalent Fe(3), four equivalent Fe(1), two equivalent Co(3), and four equivalent Co(1) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to two equivalent Tb(1), one W(1), one Fe(2), one Fe(3), four equivalent Fe(1), one Co(2), and two equivalent Co(1) atoms. is represented by the CIF file [CIF]
data_TbFe6Co5W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.626
_cell_length_b   6.326
_cell_length_c   6.326
_cell_angle_alpha   96.702
_cell_angle_beta   111.448
_cell_angle_gamma   68.552
_symmetry_Int_Tables_number   1
_cell_volume   160.336
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.000  0.006  0.006  1.0
  Fe  Fe1  1  0.498  0.004  0.502  1.0
  Fe  Fe2  1  0.000  0.004  0.502  1.0
  Fe  Fe3  1  0.502  0.502  0.004  1.0
  Fe  Fe4  1  1.000  0.502  0.004  1.0
  Fe  Fe5  1  0.500  0.774  0.774  1.0
  Fe  Fe6  1  0.500  0.231  0.231  1.0
  Co  Co7  1  0.645  0.353  0.643  1.0
  Co  Co8  1  0.355  0.643  0.353  1.0
  Co  Co9  1  0.000  0.353  0.353  1.0
  Co  Co10  1  0.713  0.786  0.212  1.0
  Co  Co11  1  0.287  0.212  0.786  1.0
  W  W12  1  0.000  0.632  0.632  1.0
[/CIF]
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The material described by TbWFe6Co5 crystallizes in the orthorhombic Imm2 space group. Tb(1) is bonded in a 20-coordinate geometry to one W(1), two equivalent Fe(2), two equivalent Fe(3), eight equivalent Fe(1), one Co(2), two equivalent Co(1), and four equivalent Co(3) atoms. W(1) is bonded in a 14-coordinate geometry to one Tb(1), two equivalent Fe(2), four equivalent Fe(1), one Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Tb(1), one W(1), one Fe(2), one Fe(3), two equivalent Fe(1), one Co(2), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeTb2Fe4Co5W cuboctahedra that share corners with two equivalent Fe(2)Tb2Fe4Co4W2 cuboctahedra, corners with two equivalent Fe(3)Tb2Fe4Co6 cuboctahedra, corners with ten equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(2)Tb2Fe4Co4W2 cuboctahedra,  an edgeedge with one Fe(3)Tb2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Tb2Fe4Co5W cuboctahedra, faces with two equivalent Fe(2)Tb2Fe4Co4W2 cuboctahedra, faces with two equivalent Fe(3)Tb2Fe4Co6 cuboctahedra, and faces with six equivalent Fe(1)Tb2Fe4Co5W cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Tb(1), two equivalent W(1), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeTb2Fe4Co4W2 cuboctahedra that share corners with six equivalent Fe(3)Tb2Fe4Co6 cuboctahedra, corners with eight equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(3)Tb2Fe4Co6 cuboctahedra, edges with two equivalent Fe(2)Tb2Fe4Co4W2 cuboctahedra, edges with four equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  a faceface with one Fe(3)Tb2Fe4Co6 cuboctahedra, and faces with eight equivalent Fe(1)Tb2Fe4Co5W cuboctahedra. In the third Fe site, Fe(3) is bonded to two equivalent Tb(1), four equivalent Fe(1), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(3) atoms to form FeTb2Fe4Co6 cuboctahedra that share corners with six equivalent Fe(2)Tb2Fe4Co4W2 cuboctahedra, corners with eight equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(2)Tb2Fe4Co4W2 cuboctahedra, edges with two equivalent Fe(3)Tb2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Tb2Fe4Co5W cuboctahedra,  a faceface with one Fe(2)Tb2Fe4Co4W2 cuboctahedra, and faces with eight equivalent Fe(1)Tb2Fe4Co5W cuboctahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 14-coordinate geometry to one Tb(1), two equivalent W(1), one Fe(2), one Fe(3), four equivalent Fe(1), one Co(1), two equivalent Co(2), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to one Tb(1), one W(1), two equivalent Fe(3), four equivalent Fe(1), two equivalent Co(3), and four equivalent Co(1) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to two equivalent Tb(1), one W(1), one Fe(2), one Fe(3), four equivalent Fe(1), one Co(2), and two equivalent Co(1) atoms. is represented by the CIF file [CIF]
data_TbFe6Co5W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.626
_cell_length_b   6.326
_cell_length_c   6.326
_cell_angle_alpha   96.702
_cell_angle_beta   111.448
_cell_angle_gamma   68.552
_symmetry_Int_Tables_number   1
_cell_volume   160.336
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.000  0.006  0.006  1.0
  Fe  Fe1  1  0.498  0.004  0.502  1.0
  Fe  Fe2  1  0.000  0.004  0.502  1.0
  Fe  Fe3  1  0.502  0.502  0.004  1.0
  Fe  Fe4  1  1.000  0.502  0.004  1.0
  Fe  Fe5  1  0.500  0.774  0.774  1.0
  Fe  Fe6  1  0.500  0.231  0.231  1.0
  Co  Co7  1  0.645  0.353  0.643  1.0
  Co  Co8  1  0.355  0.643  0.353  1.0
  Co  Co9  1  0.000  0.353  0.353  1.0
  Co  Co10  1  0.713  0.786  0.212  1.0
  Co  Co11  1  0.287  0.212  0.786  1.0
  W  W12  1  0.000  0.632  0.632  1.0
[/CIF]
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