The structure described by LiW3P5O19 crystallizes in the monoclinic Cm space group. The structure consists of two 7439-93-2 atoms inside a W3P5O19 framework. In the W3P5O19 framework, there are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), two equivalent O(10), and two equivalent O(5) atoms to form WO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second W site, W(2) is bonded to one O(11), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 27°. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with two equivalent W(1)O6 octahedra and corners with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-43°. In the second P site, P(2) is bonded to one O(11), one O(5), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 19-50°. In the third P site, P(3) is bonded to one O(10), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 20-42°. There are eleven inequivalent O sites. In the first O site, O(9) is bonded in a bent 150 degrees geometry to two equivalent W(2) atoms. In the second O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one P(3) atom. In the third O site, O(11) is bonded in a distorted bent 120 degrees geometry to one W(2) and one P(2) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(1) atom. In the sixth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one W(2) and one P(3) atom. In the seventh O site, O(4) is bonded in a distorted bent 150 degrees geometry to one W(2) and one P(1) atom. In the eighth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. In the ninth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one W(2) and one P(3) atom. In the tenth O site, O(7) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the eleventh O site, O(8) is bonded in a bent 150 degrees geometry to one W(2) and one P(2) atom. is represented by the CIF card [CIF]
data_LiP5W3O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.778
_cell_length_b   8.778
_cell_length_c   6.557
_cell_angle_alpha   81.196
_cell_angle_beta   81.196
_cell_angle_gamma   113.758
_symmetry_Int_Tables_number   1
_cell_volume   443.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.095  0.095  0.466  1.0
  P  P1  1  0.677  0.677  0.696  1.0
  P  P2  1  0.607  0.310  0.272  1.0
  P  P3  1  0.310  0.607  0.272  1.0
  P  P4  1  0.812  0.185  0.004  1.0
  P  P5  1  0.185  0.812  0.004  1.0
  W  W6  1  0.762  0.762  0.159  1.0
  W  W7  1  0.494  0.242  0.820  1.0
  W  W8  1  0.242  0.494  0.820  1.0
  O  O9  1  0.782  0.782  0.840  1.0
  O  O10  1  0.781  0.781  0.464  1.0
  O  O11  1  0.322  0.987  0.883  1.0
  O  O12  1  0.987  0.322  0.883  1.0
  O  O13  1  0.676  0.499  0.734  1.0
  O  O14  1  0.499  0.676  0.734  1.0
  O  O15  1  0.505  0.706  0.224  1.0
  O  O16  1  0.706  0.505  0.224  1.0
  O  O17  1  0.684  0.163  0.864  1.0
  O  O18  1  0.163  0.684  0.864  1.0
  O  O19  1  0.244  0.750  0.211  1.0
  O  O20  1  0.750  0.244  0.211  1.0
  O  O21  1  0.523  0.225  0.505  1.0
  O  O22  1  0.225  0.523  0.505  1.0
  O  O23  1  0.325  0.325  0.805  1.0
  O  O24  1  0.022  0.825  0.096  1.0
  O  O25  1  0.825  0.022  0.096  1.0
  O  O26  1  0.469  0.245  0.146  1.0
  O  O27  1  0.245  0.469  0.146  1.0
[/CIF]
.
The structure described by LiW3P5O19 crystallizes in the monoclinic Cm space group. The structure consists of two 7439-93-2 atoms inside a W3P5O19 framework. In the W3P5O19 framework, there are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), two equivalent O(10), and two equivalent O(5) atoms to form WO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second W site, W(2) is bonded to one O(11), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 27°. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with two equivalent W(1)O6 octahedra and corners with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-43°. In the second P site, P(2) is bonded to one O(11), one O(5), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 19-50°. In the third P site, P(3) is bonded to one O(10), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 20-42°. There are eleven inequivalent O sites. In the first O site, O(9) is bonded in a bent 150 degrees geometry to two equivalent W(2) atoms. In the second O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one P(3) atom. In the third O site, O(11) is bonded in a distorted bent 120 degrees geometry to one W(2) and one P(2) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(1) atom. In the sixth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one W(2) and one P(3) atom. In the seventh O site, O(4) is bonded in a distorted bent 150 degrees geometry to one W(2) and one P(1) atom. In the eighth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. In the ninth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one W(2) and one P(3) atom. In the tenth O site, O(7) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the eleventh O site, O(8) is bonded in a bent 150 degrees geometry to one W(2) and one P(2) atom. is represented by the CIF card [CIF]
data_LiP5W3O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.778
_cell_length_b   8.778
_cell_length_c   6.557
_cell_angle_alpha   81.196
_cell_angle_beta   81.196
_cell_angle_gamma   113.758
_symmetry_Int_Tables_number   1
_cell_volume   443.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.095  0.095  0.466  1.0
  P  P1  1  0.677  0.677  0.696  1.0
  P  P2  1  0.607  0.310  0.272  1.0
  P  P3  1  0.310  0.607  0.272  1.0
  P  P4  1  0.812  0.185  0.004  1.0
  P  P5  1  0.185  0.812  0.004  1.0
  W  W6  1  0.762  0.762  0.159  1.0
  W  W7  1  0.494  0.242  0.820  1.0
  W  W8  1  0.242  0.494  0.820  1.0
  O  O9  1  0.782  0.782  0.840  1.0
  O  O10  1  0.781  0.781  0.464  1.0
  O  O11  1  0.322  0.987  0.883  1.0
  O  O12  1  0.987  0.322  0.883  1.0
  O  O13  1  0.676  0.499  0.734  1.0
  O  O14  1  0.499  0.676  0.734  1.0
  O  O15  1  0.505  0.706  0.224  1.0
  O  O16  1  0.706  0.505  0.224  1.0
  O  O17  1  0.684  0.163  0.864  1.0
  O  O18  1  0.163  0.684  0.864  1.0
  O  O19  1  0.244  0.750  0.211  1.0
  O  O20  1  0.750  0.244  0.211  1.0
  O  O21  1  0.523  0.225  0.505  1.0
  O  O22  1  0.225  0.523  0.505  1.0
  O  O23  1  0.325  0.325  0.805  1.0
  O  O24  1  0.022  0.825  0.096  1.0
  O  O25  1  0.825  0.022  0.096  1.0
  O  O26  1  0.469  0.245  0.146  1.0
  O  O27  1  0.245  0.469  0.146  1.0
[/CIF]
.