The crystal structure described by LiVTeO5 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form LiO4 trigonal pyramids that share corners with three equivalent V(1)O4 tetrahedra. V(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form VO4 tetrahedra that share corners with three equivalent Li(1)O4 trigonal pyramids. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_LiVTeO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.009
_cell_length_b   8.281
_cell_length_c   10.556
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.260
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.154  0.080  0.944  1.0
  Li  Li1  1  0.846  0.580  0.556  1.0
  Li  Li2  1  0.654  0.420  0.056  1.0
  Li  Li3  1  0.346  0.920  0.444  1.0
  V  V4  1  0.956  0.985  0.645  1.0
  V  V5  1  0.456  0.515  0.355  1.0
  V  V6  1  0.044  0.485  0.855  1.0
  V  V7  1  0.544  0.015  0.145  1.0
  Te  Te8  1  0.872  0.144  0.363  1.0
  Te  Te9  1  0.628  0.856  0.863  1.0
  Te  Te10  1  0.128  0.644  0.137  1.0
  Te  Te11  1  0.372  0.356  0.637  1.0
  O  O12  1  0.431  0.022  0.860  1.0
  O  O13  1  0.271  0.007  0.116  1.0
  O  O14  1  0.150  0.310  0.900  1.0
  O  O15  1  0.229  0.993  0.616  1.0
  O  O16  1  0.650  0.190  0.100  1.0
  O  O17  1  0.069  0.978  0.360  1.0
  O  O18  1  0.771  0.493  0.884  1.0
  O  O19  1  0.850  0.810  0.600  1.0
  O  O20  1  0.729  0.507  0.384  1.0
  O  O21  1  0.107  0.492  0.681  1.0
  O  O22  1  0.680  0.852  0.047  1.0
  O  O23  1  0.893  0.992  0.819  1.0
  O  O24  1  0.320  0.352  0.453  1.0
  O  O25  1  0.180  0.648  0.953  1.0
  O  O26  1  0.569  0.522  0.640  1.0
  O  O27  1  0.607  0.008  0.319  1.0
  O  O28  1  0.393  0.508  0.181  1.0
  O  O29  1  0.931  0.478  0.140  1.0
  O  O30  1  0.820  0.148  0.547  1.0
  O  O31  1  0.350  0.690  0.400  1.0
[/CIF]
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The crystal structure described by LiVTeO5 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form LiO4 trigonal pyramids that share corners with three equivalent V(1)O4 tetrahedra. V(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form VO4 tetrahedra that share corners with three equivalent Li(1)O4 trigonal pyramids. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_LiVTeO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.009
_cell_length_b   8.281
_cell_length_c   10.556
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.260
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.154  0.080  0.944  1.0
  Li  Li1  1  0.846  0.580  0.556  1.0
  Li  Li2  1  0.654  0.420  0.056  1.0
  Li  Li3  1  0.346  0.920  0.444  1.0
  V  V4  1  0.956  0.985  0.645  1.0
  V  V5  1  0.456  0.515  0.355  1.0
  V  V6  1  0.044  0.485  0.855  1.0
  V  V7  1  0.544  0.015  0.145  1.0
  Te  Te8  1  0.872  0.144  0.363  1.0
  Te  Te9  1  0.628  0.856  0.863  1.0
  Te  Te10  1  0.128  0.644  0.137  1.0
  Te  Te11  1  0.372  0.356  0.637  1.0
  O  O12  1  0.431  0.022  0.860  1.0
  O  O13  1  0.271  0.007  0.116  1.0
  O  O14  1  0.150  0.310  0.900  1.0
  O  O15  1  0.229  0.993  0.616  1.0
  O  O16  1  0.650  0.190  0.100  1.0
  O  O17  1  0.069  0.978  0.360  1.0
  O  O18  1  0.771  0.493  0.884  1.0
  O  O19  1  0.850  0.810  0.600  1.0
  O  O20  1  0.729  0.507  0.384  1.0
  O  O21  1  0.107  0.492  0.681  1.0
  O  O22  1  0.680  0.852  0.047  1.0
  O  O23  1  0.893  0.992  0.819  1.0
  O  O24  1  0.320  0.352  0.453  1.0
  O  O25  1  0.180  0.648  0.953  1.0
  O  O26  1  0.569  0.522  0.640  1.0
  O  O27  1  0.607  0.008  0.319  1.0
  O  O28  1  0.393  0.508  0.181  1.0
  O  O29  1  0.931  0.478  0.140  1.0
  O  O30  1  0.820  0.148  0.547  1.0
  O  O31  1  0.350  0.690  0.400  1.0
[/CIF]
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