The material structure described by V3H5O8 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic Cm space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the second V site, V(2) is bonded to one O(3), one O(7), two equivalent O(5), and two equivalent O(8) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 1°. In the third V site, V(3) is bonded to one O(4), one O(8), two equivalent O(6), and two equivalent O(7) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 7°. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(6) atom. In the second H site, H(2) is bonded in a linear geometry to one O(1) and one O(2) atom. In the third H site, H(3) is bonded in a linear geometry to one O(2) and one O(5) atom. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(5) and one O(8) atom. In the fifth H site, H(5) is bonded in a distorted linear geometry to one O(6) and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded to two equivalent V(1), one H(1), and one H(2) atom to form distorted corner-sharing OV2H2 tetrahedra. In the second O site, O(2) is bonded in a distorted water-like geometry to two equivalent V(1), one H(2), and one H(3) atom. In the third O site, O(3) is bonded in a linear geometry to one V(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one V(1) and one V(3) atom. In the fifth O site, O(5) is bonded to two equivalent V(2), one H(3), and one H(4) atom to form distorted OV2H2 tetrahedra that share corners with two equivalent O(5)V2H2 tetrahedra, corners with two equivalent O(7)V3H tetrahedra, corners with three equivalent O(8)V3H tetrahedra, and  an edgeedge with one O(8)V3H tetrahedra. In the sixth O site, O(6) is bonded to two equivalent V(3), one H(1), and one H(5) atom to form distorted OV2H2 tetrahedra that share  a cornercorner with one O(1)V2H2 tetrahedra, corners with two equivalent O(6)V2H2 tetrahedra, corners with two equivalent O(8)V3H tetrahedra, corners with three equivalent O(7)V3H tetrahedra, and  an edgeedge with one O(7)V3H tetrahedra. In the seventh O site, O(7) is bonded to one V(2), two equivalent V(3), and one H(5) atom to form distorted OV3H tetrahedra that share corners with two equivalent O(5)V2H2 tetrahedra, corners with two equivalent O(7)V3H tetrahedra, corners with three equivalent O(6)V2H2 tetrahedra,  an edgeedge with one O(6)V2H2 tetrahedra, and edges with two equivalent O(8)V3H tetrahedra. In the eighth O site, O(8) is bonded to one V(3), two equivalent V(2), and one H(4) atom to form distorted OV3H tetrahedra that share corners with two equivalent O(6)V2H2 tetrahedra, corners with two equivalent O(8)V3H tetrahedra, corners with three equivalent O(5)V2H2 tetrahedra,  an edgeedge with one O(5)V2H2 tetrahedra, and edges with two equivalent O(7)V3H tetrahedra. is represented by the CIF card [CIF]
data_V3H5O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.703
_cell_length_b   9.703
_cell_length_c   4.717
_cell_angle_alpha   75.052
_cell_angle_beta   75.052
_cell_angle_gamma   17.994
_symmetry_Int_Tables_number   1
_cell_volume   132.421
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.001  0.001  0.484  1.0
  V  V1  1  0.820  0.820  0.384  1.0
  V  V2  1  0.179  0.179  0.614  1.0
  H  H3  1  0.585  0.585  0.092  1.0
  H  H4  1  0.495  0.495  0.957  1.0
  H  H5  1  0.411  0.411  0.914  1.0
  H  H6  1  0.312  0.312  0.926  1.0
  H  H7  1  0.689  0.689  0.065  1.0
  O  O8  1  0.531  0.531  0.203  1.0
  O  O9  1  0.468  0.468  0.796  1.0
  O  O10  1  0.907  0.907  0.427  1.0
  O  O11  1  0.091  0.091  0.575  1.0
  O  O12  1  0.341  0.341  0.079  1.0
  O  O13  1  0.661  0.661  0.910  1.0
  O  O14  1  0.718  0.718  0.351  1.0
  O  O15  1  0.282  0.282  0.644  1.0
[/CIF]
.
The material structure described by V3H5O8 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic Cm space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the second V site, V(2) is bonded to one O(3), one O(7), two equivalent O(5), and two equivalent O(8) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 1°. In the third V site, V(3) is bonded to one O(4), one O(8), two equivalent O(6), and two equivalent O(7) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 7°. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(6) atom. In the second H site, H(2) is bonded in a linear geometry to one O(1) and one O(2) atom. In the third H site, H(3) is bonded in a linear geometry to one O(2) and one O(5) atom. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(5) and one O(8) atom. In the fifth H site, H(5) is bonded in a distorted linear geometry to one O(6) and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded to two equivalent V(1), one H(1), and one H(2) atom to form distorted corner-sharing OV2H2 tetrahedra. In the second O site, O(2) is bonded in a distorted water-like geometry to two equivalent V(1), one H(2), and one H(3) atom. In the third O site, O(3) is bonded in a linear geometry to one V(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one V(1) and one V(3) atom. In the fifth O site, O(5) is bonded to two equivalent V(2), one H(3), and one H(4) atom to form distorted OV2H2 tetrahedra that share corners with two equivalent O(5)V2H2 tetrahedra, corners with two equivalent O(7)V3H tetrahedra, corners with three equivalent O(8)V3H tetrahedra, and  an edgeedge with one O(8)V3H tetrahedra. In the sixth O site, O(6) is bonded to two equivalent V(3), one H(1), and one H(5) atom to form distorted OV2H2 tetrahedra that share  a cornercorner with one O(1)V2H2 tetrahedra, corners with two equivalent O(6)V2H2 tetrahedra, corners with two equivalent O(8)V3H tetrahedra, corners with three equivalent O(7)V3H tetrahedra, and  an edgeedge with one O(7)V3H tetrahedra. In the seventh O site, O(7) is bonded to one V(2), two equivalent V(3), and one H(5) atom to form distorted OV3H tetrahedra that share corners with two equivalent O(5)V2H2 tetrahedra, corners with two equivalent O(7)V3H tetrahedra, corners with three equivalent O(6)V2H2 tetrahedra,  an edgeedge with one O(6)V2H2 tetrahedra, and edges with two equivalent O(8)V3H tetrahedra. In the eighth O site, O(8) is bonded to one V(3), two equivalent V(2), and one H(4) atom to form distorted OV3H tetrahedra that share corners with two equivalent O(6)V2H2 tetrahedra, corners with two equivalent O(8)V3H tetrahedra, corners with three equivalent O(5)V2H2 tetrahedra,  an edgeedge with one O(5)V2H2 tetrahedra, and edges with two equivalent O(7)V3H tetrahedra. is represented by the CIF card [CIF]
data_V3H5O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.703
_cell_length_b   9.703
_cell_length_c   4.717
_cell_angle_alpha   75.052
_cell_angle_beta   75.052
_cell_angle_gamma   17.994
_symmetry_Int_Tables_number   1
_cell_volume   132.421
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.001  0.001  0.484  1.0
  V  V1  1  0.820  0.820  0.384  1.0
  V  V2  1  0.179  0.179  0.614  1.0
  H  H3  1  0.585  0.585  0.092  1.0
  H  H4  1  0.495  0.495  0.957  1.0
  H  H5  1  0.411  0.411  0.914  1.0
  H  H6  1  0.312  0.312  0.926  1.0
  H  H7  1  0.689  0.689  0.065  1.0
  O  O8  1  0.531  0.531  0.203  1.0
  O  O9  1  0.468  0.468  0.796  1.0
  O  O10  1  0.907  0.907  0.427  1.0
  O  O11  1  0.091  0.091  0.575  1.0
  O  O12  1  0.341  0.341  0.079  1.0
  O  O13  1  0.661  0.661  0.910  1.0
  O  O14  1  0.718  0.718  0.351  1.0
  O  O15  1  0.282  0.282  0.644  1.0
[/CIF]
.