The compound described by Mn6OF11 is Hydrophilite-derived structured and crystallizes in the monoclinic Pc space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one F(1), one F(11), one F(4), one F(6), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(2)F6 octahedra, corners with two equivalent Mn(6)F6 octahedra, corners with four equivalent Mn(3)OF5 octahedra,  an edgeedge with one Mn(2)F6 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. In the second Mn site, Mn(2) is bonded to one F(4), one F(6), two equivalent F(1), and two equivalent F(7) atoms to form MnF6 octahedra that share corners with two equivalent Mn(1)OF5 octahedra, corners with two equivalent Mn(3)OF5 octahedra, corners with four equivalent Mn(2)F6 octahedra,  an edgeedge with one Mn(1)OF5 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the third Mn site, Mn(3) is bonded to one O(1), one F(3), one F(4), one F(6), one F(7), and one F(8) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(2)F6 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(1)OF5 octahedra,  an edgeedge with one Mn(2)F6 octahedra, and  an edgeedge with one Mn(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. In the fourth Mn site, Mn(4) is bonded to one F(2), one F(9), two equivalent F(10), and two equivalent F(5) atoms to form MnF6 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(4)F6 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the fifth Mn site, Mn(5) is bonded to one O(1), one F(10), one F(11), one F(2), one F(3), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(4)F6 octahedra, corners with two equivalent Mn(3)OF5 octahedra, corners with four equivalent Mn(6)F6 octahedra,  an edgeedge with one Mn(4)F6 octahedra, and  an edgeedge with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 49-61°. In the sixth Mn site, Mn(6) is bonded to one F(11), one F(2), one F(3), one F(5), one F(8), and one F(9) atom to form MnF6 octahedra that share corners with two equivalent Mn(4)F6 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with four equivalent Mn(5)OF5 octahedra,  an edgeedge with one Mn(4)F6 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(5) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Mn(2) atoms. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(6) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(6) and two equivalent Mn(4) atoms. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(3) and two equivalent Mn(2) atoms. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(6) atom. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Mn(5) and two equivalent Mn(4) atoms. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. is represented by the CIF file [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.221
_cell_length_b   4.964
_cell_length_c   7.655
_cell_angle_alpha   50.282
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   474.133
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.668  0.846  0.144  1.0
  Mn  Mn1  1  0.496  0.160  0.829  1.0
  Mn  Mn2  1  0.329  0.832  0.187  1.0
  Mn  Mn3  1  0.001  0.825  0.169  1.0
  Mn  Mn4  1  0.828  0.153  0.833  1.0
  Mn  Mn5  1  0.168  0.176  0.830  1.0
  Mn  Mn6  1  0.832  0.176  0.330  1.0
  Mn  Mn7  1  0.172  0.153  0.333  1.0
  Mn  Mn8  1  0.504  0.160  0.329  1.0
  Mn  Mn9  1  0.332  0.846  0.644  1.0
  Mn  Mn10  1  0.671  0.832  0.687  1.0
  Mn  Mn11  1  0.999  0.825  0.669  1.0
  O  O12  1  0.718  0.881  0.910  1.0
  O  O13  1  0.282  0.881  0.410  1.0
  F  F14  1  0.557  0.666  0.110  1.0
  F  F15  1  0.892  0.660  0.106  1.0
  F  F16  1  0.223  0.673  0.115  1.0
  F  F17  1  0.385  0.875  0.874  1.0
  F  F18  1  0.058  0.881  0.890  1.0
  F  F19  1  0.394  0.340  0.392  1.0
  F  F20  1  0.557  0.109  0.608  1.0
  F  F21  1  0.720  0.349  0.392  1.0
  F  F22  1  0.891  0.131  0.603  1.0
  F  F23  1  0.061  0.330  0.391  1.0
  F  F24  1  0.228  0.114  0.617  1.0
  F  F25  1  0.443  0.666  0.610  1.0
  F  F26  1  0.615  0.875  0.374  1.0
  F  F27  1  0.777  0.673  0.615  1.0
  F  F28  1  0.108  0.660  0.606  1.0
  F  F29  1  0.942  0.881  0.390  1.0
  F  F30  1  0.443  0.109  0.108  1.0
  F  F31  1  0.772  0.114  0.117  1.0
  F  F32  1  0.606  0.340  0.892  1.0
  F  F33  1  0.280  0.349  0.892  1.0
  F  F34  1  0.109  0.131  0.103  1.0
  F  F35  1  0.939  0.330  0.891  1.0
[/CIF]
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The compound described by Mn6OF11 is Hydrophilite-derived structured and crystallizes in the monoclinic Pc space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one F(1), one F(11), one F(4), one F(6), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(2)F6 octahedra, corners with two equivalent Mn(6)F6 octahedra, corners with four equivalent Mn(3)OF5 octahedra,  an edgeedge with one Mn(2)F6 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. In the second Mn site, Mn(2) is bonded to one F(4), one F(6), two equivalent F(1), and two equivalent F(7) atoms to form MnF6 octahedra that share corners with two equivalent Mn(1)OF5 octahedra, corners with two equivalent Mn(3)OF5 octahedra, corners with four equivalent Mn(2)F6 octahedra,  an edgeedge with one Mn(1)OF5 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the third Mn site, Mn(3) is bonded to one O(1), one F(3), one F(4), one F(6), one F(7), and one F(8) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(2)F6 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(1)OF5 octahedra,  an edgeedge with one Mn(2)F6 octahedra, and  an edgeedge with one Mn(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. In the fourth Mn site, Mn(4) is bonded to one F(2), one F(9), two equivalent F(10), and two equivalent F(5) atoms to form MnF6 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(4)F6 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the fifth Mn site, Mn(5) is bonded to one O(1), one F(10), one F(11), one F(2), one F(3), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(4)F6 octahedra, corners with two equivalent Mn(3)OF5 octahedra, corners with four equivalent Mn(6)F6 octahedra,  an edgeedge with one Mn(4)F6 octahedra, and  an edgeedge with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 49-61°. In the sixth Mn site, Mn(6) is bonded to one F(11), one F(2), one F(3), one F(5), one F(8), and one F(9) atom to form MnF6 octahedra that share corners with two equivalent Mn(4)F6 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with four equivalent Mn(5)OF5 octahedra,  an edgeedge with one Mn(4)F6 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(5) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Mn(2) atoms. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(6) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(6) and two equivalent Mn(4) atoms. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(3) and two equivalent Mn(2) atoms. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(6) atom. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Mn(5) and two equivalent Mn(4) atoms. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. is represented by the CIF file [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.221
_cell_length_b   4.964
_cell_length_c   7.655
_cell_angle_alpha   50.282
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   474.133
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.668  0.846  0.144  1.0
  Mn  Mn1  1  0.496  0.160  0.829  1.0
  Mn  Mn2  1  0.329  0.832  0.187  1.0
  Mn  Mn3  1  0.001  0.825  0.169  1.0
  Mn  Mn4  1  0.828  0.153  0.833  1.0
  Mn  Mn5  1  0.168  0.176  0.830  1.0
  Mn  Mn6  1  0.832  0.176  0.330  1.0
  Mn  Mn7  1  0.172  0.153  0.333  1.0
  Mn  Mn8  1  0.504  0.160  0.329  1.0
  Mn  Mn9  1  0.332  0.846  0.644  1.0
  Mn  Mn10  1  0.671  0.832  0.687  1.0
  Mn  Mn11  1  0.999  0.825  0.669  1.0
  O  O12  1  0.718  0.881  0.910  1.0
  O  O13  1  0.282  0.881  0.410  1.0
  F  F14  1  0.557  0.666  0.110  1.0
  F  F15  1  0.892  0.660  0.106  1.0
  F  F16  1  0.223  0.673  0.115  1.0
  F  F17  1  0.385  0.875  0.874  1.0
  F  F18  1  0.058  0.881  0.890  1.0
  F  F19  1  0.394  0.340  0.392  1.0
  F  F20  1  0.557  0.109  0.608  1.0
  F  F21  1  0.720  0.349  0.392  1.0
  F  F22  1  0.891  0.131  0.603  1.0
  F  F23  1  0.061  0.330  0.391  1.0
  F  F24  1  0.228  0.114  0.617  1.0
  F  F25  1  0.443  0.666  0.610  1.0
  F  F26  1  0.615  0.875  0.374  1.0
  F  F27  1  0.777  0.673  0.615  1.0
  F  F28  1  0.108  0.660  0.606  1.0
  F  F29  1  0.942  0.881  0.390  1.0
  F  F30  1  0.443  0.109  0.108  1.0
  F  F31  1  0.772  0.114  0.117  1.0
  F  F32  1  0.606  0.340  0.892  1.0
  F  F33  1  0.280  0.349  0.892  1.0
  F  F34  1  0.109  0.131  0.103  1.0
  F  F35  1  0.939  0.330  0.891  1.0
[/CIF]
.