The compound described by LiAg2F6 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(4), and two equivalent F(3) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one F(2), one F(5), two equivalent F(1), and two equivalent F(6) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one F(1), one F(3), one F(5), one F(6), and two equivalent F(4) atoms. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ag(2), and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Ag(2) atoms. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Ag(2) and two equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_LiAg2F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.487
_cell_length_b   5.610
_cell_length_c   16.085
_cell_angle_alpha   86.187
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   493.994
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.462  0.157  0.067  1.0
  Li  Li1  1  0.038  0.157  0.567  1.0
  Li  Li2  1  0.962  0.843  0.433  1.0
  Li  Li3  1  0.538  0.843  0.933  1.0
  Ag  Ag4  1  0.986  0.242  0.245  1.0
  Ag  Ag5  1  0.528  0.299  0.423  1.0
  Ag  Ag6  1  0.514  0.242  0.745  1.0
  Ag  Ag7  1  0.972  0.299  0.923  1.0
  Ag  Ag8  1  0.028  0.701  0.077  1.0
  Ag  Ag9  1  0.486  0.758  0.255  1.0
  Ag  Ag10  1  0.472  0.701  0.577  1.0
  Ag  Ag11  1  0.014  0.758  0.755  1.0
  F  F12  1  0.147  0.009  0.173  1.0
  F  F13  1  0.353  0.009  0.673  1.0
  F  F14  1  0.143  0.076  0.345  1.0
  F  F15  1  0.763  0.080  0.494  1.0
  F  F16  1  0.357  0.076  0.845  1.0
  F  F17  1  0.737  0.080  0.994  1.0
  F  F18  1  0.239  0.394  0.022  1.0
  F  F19  1  0.829  0.424  0.147  1.0
  F  F20  1  0.261  0.394  0.522  1.0
  F  F21  1  0.825  0.469  0.317  1.0
  F  F22  1  0.671  0.424  0.647  1.0
  F  F23  1  0.325  0.531  0.183  1.0
  F  F24  1  0.675  0.469  0.817  1.0
  F  F25  1  0.329  0.576  0.353  1.0
  F  F26  1  0.175  0.531  0.683  1.0
  F  F27  1  0.739  0.606  0.478  1.0
  F  F28  1  0.171  0.576  0.853  1.0
  F  F29  1  0.761  0.606  0.978  1.0
  F  F30  1  0.263  0.920  0.006  1.0
  F  F31  1  0.643  0.924  0.155  1.0
  F  F32  1  0.237  0.920  0.506  1.0
  F  F33  1  0.857  0.924  0.655  1.0
  F  F34  1  0.647  0.991  0.327  1.0
  F  F35  1  0.853  0.991  0.827  1.0
[/CIF]
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The compound described by LiAg2F6 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(4), and two equivalent F(3) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one F(2), one F(5), two equivalent F(1), and two equivalent F(6) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one F(1), one F(3), one F(5), one F(6), and two equivalent F(4) atoms. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ag(2), and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Ag(2) atoms. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Ag(2) and two equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_LiAg2F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.487
_cell_length_b   5.610
_cell_length_c   16.085
_cell_angle_alpha   86.187
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   493.994
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.462  0.157  0.067  1.0
  Li  Li1  1  0.038  0.157  0.567  1.0
  Li  Li2  1  0.962  0.843  0.433  1.0
  Li  Li3  1  0.538  0.843  0.933  1.0
  Ag  Ag4  1  0.986  0.242  0.245  1.0
  Ag  Ag5  1  0.528  0.299  0.423  1.0
  Ag  Ag6  1  0.514  0.242  0.745  1.0
  Ag  Ag7  1  0.972  0.299  0.923  1.0
  Ag  Ag8  1  0.028  0.701  0.077  1.0
  Ag  Ag9  1  0.486  0.758  0.255  1.0
  Ag  Ag10  1  0.472  0.701  0.577  1.0
  Ag  Ag11  1  0.014  0.758  0.755  1.0
  F  F12  1  0.147  0.009  0.173  1.0
  F  F13  1  0.353  0.009  0.673  1.0
  F  F14  1  0.143  0.076  0.345  1.0
  F  F15  1  0.763  0.080  0.494  1.0
  F  F16  1  0.357  0.076  0.845  1.0
  F  F17  1  0.737  0.080  0.994  1.0
  F  F18  1  0.239  0.394  0.022  1.0
  F  F19  1  0.829  0.424  0.147  1.0
  F  F20  1  0.261  0.394  0.522  1.0
  F  F21  1  0.825  0.469  0.317  1.0
  F  F22  1  0.671  0.424  0.647  1.0
  F  F23  1  0.325  0.531  0.183  1.0
  F  F24  1  0.675  0.469  0.817  1.0
  F  F25  1  0.329  0.576  0.353  1.0
  F  F26  1  0.175  0.531  0.683  1.0
  F  F27  1  0.739  0.606  0.478  1.0
  F  F28  1  0.171  0.576  0.853  1.0
  F  F29  1  0.761  0.606  0.978  1.0
  F  F30  1  0.263  0.920  0.006  1.0
  F  F31  1  0.643  0.924  0.155  1.0
  F  F32  1  0.237  0.920  0.506  1.0
  F  F33  1  0.857  0.924  0.655  1.0
  F  F34  1  0.647  0.991  0.327  1.0
  F  F35  1  0.853  0.991  0.827  1.0
[/CIF]
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