The crystal structure described by KLiSb3O8 crystallizes in the triclinic P1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(18), and one O(2) atom. In the second K site, K(2) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(14), one O(15), one O(17), one O(2), one O(22), one O(23), and one O(3) atom. In the third K site, K(3) is bonded in a 4-coordinate geometry to one O(12), one O(13), one O(22), and one O(7) atom. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(18), one O(19), one O(23), one O(24), and one O(9) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(2), one O(20), one O(24), one O(7), and one O(8) atom. In the third Li site, Li(3) is bonded in a 3-coordinate geometry to one O(13), one O(14), one O(21), one O(24), and one O(6) atom. There are nine inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(12), one O(14), one O(19), and one O(4) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the second Sb site, Sb(2) is bonded to one O(1), one O(17), one O(18), one O(2), one O(22), and one O(5) atom to form a mixture of distorted edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the third Sb site, Sb(3) is bonded to one O(1), one O(16), one O(2), one O(3), one O(6), and one O(7) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the fourth Sb site, Sb(4) is bonded to one O(23), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-51°. In the fifth Sb site, Sb(5) is bonded to one O(12), one O(14), one O(15), one O(21), one O(5), and one O(8) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the sixth Sb site, Sb(6) is bonded to one O(11), one O(13), one O(15), one O(5), one O(6), and one O(9) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the seventh Sb site, Sb(7) is bonded to one O(15), one O(16), one O(19), one O(20), one O(22), and one O(24) atom to form distorted corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 51-60°. In the eighth Sb site, Sb(8) is bonded to one O(10), one O(11), one O(13), one O(17), one O(20), and one O(4) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the ninth Sb site, Sb(9) is bonded to one O(16), one O(17), one O(18), one O(21), one O(23), and one O(3) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sb(1), one Sb(2), and one Sb(3) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one K(1), one K(2), one Li(2), one Sb(2), and one Sb(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(2), one Sb(3), one Sb(4), and one Sb(9) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Sb(1), one Sb(4), and one Sb(8) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Sb(2), one Sb(5), and one Sb(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Li(3), one Sb(3), and one Sb(6) atom. In the seventh O site, O(7) is bonded to one K(3), one Li(2), one Sb(3), and one Sb(4) atom to form distorted OKLiSb2 trigonal pyramids that share  a cornercorner with one O(22)K2Sb2 tetrahedra and  a cornercorner with one O(24)Li3Sb tetrahedra. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(2), one Sb(4), and one Sb(5) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(4), and one Sb(6) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one K(2), one Sb(1), and one Sb(8) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one K(2), one Sb(6), and one Sb(8) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one K(3), one Sb(1), and one Sb(5) atom. In the thirteenth O site, O(13) is bonded in a 5-coordinate geometry to one K(1), one K(3), one Li(3), one Sb(6), and one Sb(8) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one K(1), one K(2), one Li(3), one Sb(1), and one Sb(5) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one K(2), one Sb(5), one Sb(6), and one Sb(7) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Sb(3), one Sb(7), and one Sb(9) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one K(2), one Sb(2), one Sb(8), and one Sb(9) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one K(1), one Li(1), one Sb(2), and one Sb(9) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one Sb(7) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Li(2), one Sb(7), and one Sb(8) atom. In the twenty-first O site, O(21) is bonded in a trigonal planar geometry to one Li(3), one Sb(5), and one Sb(9) atom. In the twenty-second O site, O(22) is bonded to one K(2), one K(3), one Sb(2), and one Sb(7) atom to form distorted OK2Sb2 tetrahedra that share  a cornercorner with one O(24)Li3Sb tetrahedra and  a cornercorner with one O(7)KLiSb2 trigonal pyramid. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one K(2), one Li(1), one Sb(4), and one Sb(9) atom. In the twenty-fourth O site, O(24) is bonded to one Li(1), one Li(2), one Li(3), and one Sb(7) atom to form distorted OLi3Sb tetrahedra that share  a cornercorner with one O(22)K2Sb2 tetrahedra and  a cornercorner with one O(7)KLiSb2 trigonal pyramid. is represented by the CIF file [CIF]
data_KLiSb3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.969
_cell_length_b   8.965
_cell_length_c   8.807
_cell_angle_alpha   108.197
_cell_angle_beta   107.504
_cell_angle_gamma   113.466
_symmetry_Int_Tables_number   1
_cell_volume   538.627
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.191  0.120  0.961  1.0
  K  K1  1  0.488  0.505  0.995  1.0
  K  K2  1  0.832  0.870  0.990  1.0
  Li  Li3  1  0.102  0.645  0.795  1.0
  Li  Li4  1  0.489  0.031  0.796  1.0
  Li  Li5  1  0.054  0.802  0.519  1.0
  Sb  Sb6  1  0.997  0.163  0.483  1.0
  Sb  Sb7  1  0.488  0.966  0.117  1.0
  Sb  Sb8  1  0.837  0.354  0.188  1.0
  Sb  Sb9  1  0.831  0.322  0.815  1.0
  Sb  Sb10  1  0.352  0.176  0.508  1.0
  Sb  Sb11  1  0.671  0.495  0.508  1.0
  Sb  Sb12  1  0.330  0.647  0.639  1.0
  Sb  Sb13  1  0.657  0.824  0.482  1.0
  Sb  Sb14  1  0.172  0.690  0.188  1.0
  O  O15  1  0.822  0.168  0.278  1.0
  O  O16  1  0.557  0.193  0.050  1.0
  O  O17  1  0.869  0.527  0.059  1.0
  O  O18  1  0.835  0.125  0.622  1.0
  O  O19  1  0.490  0.212  0.364  1.0
  O  O20  1  0.838  0.527  0.394  1.0
  O  O21  1  0.825  0.190  0.962  1.0
  O  O22  1  0.556  0.196  0.704  1.0
  O  O23  1  0.846  0.486  0.704  1.0
  O  O24  1  0.815  0.882  0.360  1.0
  O  O25  1  0.519  0.544  0.334  1.0
  O  O26  1  0.129  0.154  0.335  1.0
  O  O27  1  0.830  0.783  0.653  1.0
  O  O28  1  0.210  0.163  0.654  1.0
  O  O29  1  0.505  0.465  0.631  1.0
  O  O30  1  0.123  0.535  0.320  1.0
  O  O31  1  0.448  0.795  0.279  1.0
  O  O32  1  0.196  0.831  0.050  1.0
  O  O33  1  0.123  0.432  0.637  1.0
  O  O34  1  0.544  0.851  0.638  1.0
  O  O35  1  0.205  0.894  0.394  1.0
  O  O36  1  0.489  0.766  0.917  1.0
  O  O37  1  0.110  0.474  0.962  1.0
  O  O38  1  0.240  0.811  0.713  1.0
[/CIF]
.
The crystal structure described by KLiSb3O8 crystallizes in the triclinic P1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(18), and one O(2) atom. In the second K site, K(2) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(14), one O(15), one O(17), one O(2), one O(22), one O(23), and one O(3) atom. In the third K site, K(3) is bonded in a 4-coordinate geometry to one O(12), one O(13), one O(22), and one O(7) atom. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(18), one O(19), one O(23), one O(24), and one O(9) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(2), one O(20), one O(24), one O(7), and one O(8) atom. In the third Li site, Li(3) is bonded in a 3-coordinate geometry to one O(13), one O(14), one O(21), one O(24), and one O(6) atom. There are nine inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(12), one O(14), one O(19), and one O(4) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the second Sb site, Sb(2) is bonded to one O(1), one O(17), one O(18), one O(2), one O(22), and one O(5) atom to form a mixture of distorted edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the third Sb site, Sb(3) is bonded to one O(1), one O(16), one O(2), one O(3), one O(6), and one O(7) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the fourth Sb site, Sb(4) is bonded to one O(23), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-51°. In the fifth Sb site, Sb(5) is bonded to one O(12), one O(14), one O(15), one O(21), one O(5), and one O(8) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the sixth Sb site, Sb(6) is bonded to one O(11), one O(13), one O(15), one O(5), one O(6), and one O(9) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the seventh Sb site, Sb(7) is bonded to one O(15), one O(16), one O(19), one O(20), one O(22), and one O(24) atom to form distorted corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 51-60°. In the eighth Sb site, Sb(8) is bonded to one O(10), one O(11), one O(13), one O(17), one O(20), and one O(4) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-55°. In the ninth Sb site, Sb(9) is bonded to one O(16), one O(17), one O(18), one O(21), one O(23), and one O(3) atom to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sb(1), one Sb(2), and one Sb(3) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one K(1), one K(2), one Li(2), one Sb(2), and one Sb(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(2), one Sb(3), one Sb(4), and one Sb(9) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Sb(1), one Sb(4), and one Sb(8) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Sb(2), one Sb(5), and one Sb(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Li(3), one Sb(3), and one Sb(6) atom. In the seventh O site, O(7) is bonded to one K(3), one Li(2), one Sb(3), and one Sb(4) atom to form distorted OKLiSb2 trigonal pyramids that share  a cornercorner with one O(22)K2Sb2 tetrahedra and  a cornercorner with one O(24)Li3Sb tetrahedra. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(2), one Sb(4), and one Sb(5) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(4), and one Sb(6) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one K(2), one Sb(1), and one Sb(8) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one K(2), one Sb(6), and one Sb(8) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one K(3), one Sb(1), and one Sb(5) atom. In the thirteenth O site, O(13) is bonded in a 5-coordinate geometry to one K(1), one K(3), one Li(3), one Sb(6), and one Sb(8) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one K(1), one K(2), one Li(3), one Sb(1), and one Sb(5) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one K(2), one Sb(5), one Sb(6), and one Sb(7) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Sb(3), one Sb(7), and one Sb(9) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one K(2), one Sb(2), one Sb(8), and one Sb(9) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one K(1), one Li(1), one Sb(2), and one Sb(9) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one Sb(7) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Li(2), one Sb(7), and one Sb(8) atom. In the twenty-first O site, O(21) is bonded in a trigonal planar geometry to one Li(3), one Sb(5), and one Sb(9) atom. In the twenty-second O site, O(22) is bonded to one K(2), one K(3), one Sb(2), and one Sb(7) atom to form distorted OK2Sb2 tetrahedra that share  a cornercorner with one O(24)Li3Sb tetrahedra and  a cornercorner with one O(7)KLiSb2 trigonal pyramid. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one K(2), one Li(1), one Sb(4), and one Sb(9) atom. In the twenty-fourth O site, O(24) is bonded to one Li(1), one Li(2), one Li(3), and one Sb(7) atom to form distorted OLi3Sb tetrahedra that share  a cornercorner with one O(22)K2Sb2 tetrahedra and  a cornercorner with one O(7)KLiSb2 trigonal pyramid. is represented by the CIF file [CIF]
data_KLiSb3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.969
_cell_length_b   8.965
_cell_length_c   8.807
_cell_angle_alpha   108.197
_cell_angle_beta   107.504
_cell_angle_gamma   113.466
_symmetry_Int_Tables_number   1
_cell_volume   538.627
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.191  0.120  0.961  1.0
  K  K1  1  0.488  0.505  0.995  1.0
  K  K2  1  0.832  0.870  0.990  1.0
  Li  Li3  1  0.102  0.645  0.795  1.0
  Li  Li4  1  0.489  0.031  0.796  1.0
  Li  Li5  1  0.054  0.802  0.519  1.0
  Sb  Sb6  1  0.997  0.163  0.483  1.0
  Sb  Sb7  1  0.488  0.966  0.117  1.0
  Sb  Sb8  1  0.837  0.354  0.188  1.0
  Sb  Sb9  1  0.831  0.322  0.815  1.0
  Sb  Sb10  1  0.352  0.176  0.508  1.0
  Sb  Sb11  1  0.671  0.495  0.508  1.0
  Sb  Sb12  1  0.330  0.647  0.639  1.0
  Sb  Sb13  1  0.657  0.824  0.482  1.0
  Sb  Sb14  1  0.172  0.690  0.188  1.0
  O  O15  1  0.822  0.168  0.278  1.0
  O  O16  1  0.557  0.193  0.050  1.0
  O  O17  1  0.869  0.527  0.059  1.0
  O  O18  1  0.835  0.125  0.622  1.0
  O  O19  1  0.490  0.212  0.364  1.0
  O  O20  1  0.838  0.527  0.394  1.0
  O  O21  1  0.825  0.190  0.962  1.0
  O  O22  1  0.556  0.196  0.704  1.0
  O  O23  1  0.846  0.486  0.704  1.0
  O  O24  1  0.815  0.882  0.360  1.0
  O  O25  1  0.519  0.544  0.334  1.0
  O  O26  1  0.129  0.154  0.335  1.0
  O  O27  1  0.830  0.783  0.653  1.0
  O  O28  1  0.210  0.163  0.654  1.0
  O  O29  1  0.505  0.465  0.631  1.0
  O  O30  1  0.123  0.535  0.320  1.0
  O  O31  1  0.448  0.795  0.279  1.0
  O  O32  1  0.196  0.831  0.050  1.0
  O  O33  1  0.123  0.432  0.637  1.0
  O  O34  1  0.544  0.851  0.638  1.0
  O  O35  1  0.205  0.894  0.394  1.0
  O  O36  1  0.489  0.766  0.917  1.0
  O  O37  1  0.110  0.474  0.962  1.0
  O  O38  1  0.240  0.811  0.713  1.0
[/CIF]
.