The compound described by TeO3BrF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four TeO3BrF5 clusters. Te(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Br(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Te(1) and one Br(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeBrO3F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.403
_cell_length_b   5.430
_cell_length_c   20.172
_cell_angle_alpha   89.699
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   701.417
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.718  0.248  0.091  1.0
  Te  Te1  1  0.218  0.752  0.409  1.0
  Te  Te2  1  0.782  0.248  0.591  1.0
  Te  Te3  1  0.282  0.752  0.909  1.0
  Br  Br4  1  0.170  0.754  0.741  1.0
  Br  Br5  1  0.330  0.754  0.241  1.0
  Br  Br6  1  0.830  0.246  0.259  1.0
  Br  Br7  1  0.670  0.246  0.759  1.0
  O  O8  1  0.181  0.605  0.190  1.0
  O  O9  1  0.687  0.383  0.178  1.0
  O  O10  1  0.727  0.953  0.758  1.0
  O  O11  1  0.319  0.605  0.690  1.0
  O  O12  1  0.819  0.395  0.810  1.0
  O  O13  1  0.681  0.395  0.310  1.0
  O  O14  1  0.227  0.047  0.742  1.0
  O  O15  1  0.773  0.953  0.258  1.0
  O  O16  1  0.187  0.617  0.322  1.0
  O  O17  1  0.273  0.047  0.242  1.0
  O  O18  1  0.813  0.383  0.678  1.0
  O  O19  1  0.313  0.617  0.822  1.0
  F  F20  1  0.757  0.115  0.506  1.0
  F  F21  1  0.524  0.105  0.614  1.0
  F  F22  1  0.083  0.047  0.384  1.0
  F  F23  1  0.855  0.531  0.060  1.0
  F  F24  1  0.645  0.531  0.560  1.0
  F  F25  1  0.583  0.953  0.116  1.0
  F  F26  1  0.917  0.953  0.616  1.0
  F  F27  1  0.024  0.895  0.886  1.0
  F  F28  1  0.743  0.115  0.006  1.0
  F  F29  1  0.145  0.469  0.940  1.0
  F  F30  1  0.476  0.895  0.386  1.0
  F  F31  1  0.243  0.885  0.494  1.0
  F  F32  1  0.541  0.616  0.932  1.0
  F  F33  1  0.976  0.105  0.114  1.0
  F  F34  1  0.459  0.384  0.068  1.0
  F  F35  1  0.417  0.047  0.884  1.0
  F  F36  1  0.355  0.469  0.440  1.0
  F  F37  1  0.041  0.384  0.568  1.0
  F  F38  1  0.959  0.616  0.432  1.0
  F  F39  1  0.257  0.885  0.994  1.0
[/CIF]
.
The compound described by TeO3BrF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four TeO3BrF5 clusters. Te(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Br(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Te(1) and one Br(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeBrO3F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.403
_cell_length_b   5.430
_cell_length_c   20.172
_cell_angle_alpha   89.699
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   701.417
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.718  0.248  0.091  1.0
  Te  Te1  1  0.218  0.752  0.409  1.0
  Te  Te2  1  0.782  0.248  0.591  1.0
  Te  Te3  1  0.282  0.752  0.909  1.0
  Br  Br4  1  0.170  0.754  0.741  1.0
  Br  Br5  1  0.330  0.754  0.241  1.0
  Br  Br6  1  0.830  0.246  0.259  1.0
  Br  Br7  1  0.670  0.246  0.759  1.0
  O  O8  1  0.181  0.605  0.190  1.0
  O  O9  1  0.687  0.383  0.178  1.0
  O  O10  1  0.727  0.953  0.758  1.0
  O  O11  1  0.319  0.605  0.690  1.0
  O  O12  1  0.819  0.395  0.810  1.0
  O  O13  1  0.681  0.395  0.310  1.0
  O  O14  1  0.227  0.047  0.742  1.0
  O  O15  1  0.773  0.953  0.258  1.0
  O  O16  1  0.187  0.617  0.322  1.0
  O  O17  1  0.273  0.047  0.242  1.0
  O  O18  1  0.813  0.383  0.678  1.0
  O  O19  1  0.313  0.617  0.822  1.0
  F  F20  1  0.757  0.115  0.506  1.0
  F  F21  1  0.524  0.105  0.614  1.0
  F  F22  1  0.083  0.047  0.384  1.0
  F  F23  1  0.855  0.531  0.060  1.0
  F  F24  1  0.645  0.531  0.560  1.0
  F  F25  1  0.583  0.953  0.116  1.0
  F  F26  1  0.917  0.953  0.616  1.0
  F  F27  1  0.024  0.895  0.886  1.0
  F  F28  1  0.743  0.115  0.006  1.0
  F  F29  1  0.145  0.469  0.940  1.0
  F  F30  1  0.476  0.895  0.386  1.0
  F  F31  1  0.243  0.885  0.494  1.0
  F  F32  1  0.541  0.616  0.932  1.0
  F  F33  1  0.976  0.105  0.114  1.0
  F  F34  1  0.459  0.384  0.068  1.0
  F  F35  1  0.417  0.047  0.884  1.0
  F  F36  1  0.355  0.469  0.440  1.0
  F  F37  1  0.041  0.384  0.568  1.0
  F  F38  1  0.959  0.616  0.432  1.0
  F  F39  1  0.257  0.885  0.994  1.0
[/CIF]
.