The material structure described by (WSbO6)2N2 crystallizes in the orthorhombic Imma space group. The structure consists of four ammonia atoms inside a WSbO6 framework. In the WSbO6 framework, W(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-40°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbWNO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.386
_cell_length_b   7.386
_cell_length_c   7.386
_cell_angle_alpha   120.572
_cell_angle_beta   119.686
_cell_angle_gamma   89.778
_symmetry_Int_Tables_number   1
_cell_volume   284.374
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.500  1.0
  Sb  Sb1  1  0.000  0.500  0.000  1.0
  W  W2  1  0.000  0.000  0.000  1.0
  W  W3  1  0.500  0.000  0.500  1.0
  N  N4  1  0.375  0.625  0.750  1.0
  N  N5  1  0.625  0.375  0.250  1.0
  O  O6  1  0.306  0.056  0.250  1.0
  O  O7  1  0.925  0.675  0.250  1.0
  O  O8  1  0.318  0.689  0.255  1.0
  O  O9  1  0.934  0.063  0.245  1.0
  O  O10  1  0.318  0.063  0.628  1.0
  O  O11  1  0.934  0.689  0.872  1.0
  O  O12  1  0.694  0.944  0.750  1.0
  O  O13  1  0.075  0.325  0.750  1.0
  O  O14  1  0.682  0.311  0.745  1.0
  O  O15  1  0.066  0.937  0.755  1.0
  O  O16  1  0.682  0.937  0.372  1.0
  O  O17  1  0.066  0.311  0.128  1.0
[/CIF]
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The material structure described by (WSbO6)2N2 crystallizes in the orthorhombic Imma space group. The structure consists of four ammonia atoms inside a WSbO6 framework. In the WSbO6 framework, W(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-40°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbWNO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.386
_cell_length_b   7.386
_cell_length_c   7.386
_cell_angle_alpha   120.572
_cell_angle_beta   119.686
_cell_angle_gamma   89.778
_symmetry_Int_Tables_number   1
_cell_volume   284.374
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.500  1.0
  Sb  Sb1  1  0.000  0.500  0.000  1.0
  W  W2  1  0.000  0.000  0.000  1.0
  W  W3  1  0.500  0.000  0.500  1.0
  N  N4  1  0.375  0.625  0.750  1.0
  N  N5  1  0.625  0.375  0.250  1.0
  O  O6  1  0.306  0.056  0.250  1.0
  O  O7  1  0.925  0.675  0.250  1.0
  O  O8  1  0.318  0.689  0.255  1.0
  O  O9  1  0.934  0.063  0.245  1.0
  O  O10  1  0.318  0.063  0.628  1.0
  O  O11  1  0.934  0.689  0.872  1.0
  O  O12  1  0.694  0.944  0.750  1.0
  O  O13  1  0.075  0.325  0.750  1.0
  O  O14  1  0.682  0.311  0.745  1.0
  O  O15  1  0.066  0.937  0.755  1.0
  O  O16  1  0.682  0.937  0.372  1.0
  O  O17  1  0.066  0.311  0.128  1.0
[/CIF]
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