The material structure described by CsNH2SO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 10-coordinate geometry to one N(1), one H(2), two equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cs(1), one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom. is represented by the CIF file [CIF]
data_CsH2SNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.654
_cell_length_b   8.323
_cell_length_c   8.723
_cell_angle_alpha   115.273
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   502.533
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.646  0.816  0.560  1.0
  Cs  Cs1  1  0.146  0.184  0.940  1.0
  Cs  Cs2  1  0.354  0.184  0.440  1.0
  Cs  Cs3  1  0.854  0.816  0.060  1.0
  H  H4  1  0.492  0.470  0.159  1.0
  H  H5  1  0.992  0.530  0.341  1.0
  H  H6  1  0.508  0.530  0.841  1.0
  H  H7  1  0.008  0.470  0.659  1.0
  H  H8  1  0.617  0.357  0.236  1.0
  H  H9  1  0.117  0.643  0.264  1.0
  H  H10  1  0.383  0.643  0.764  1.0
  H  H11  1  0.883  0.357  0.736  1.0
  S  S12  1  0.652  0.271  0.955  1.0
  S  S13  1  0.152  0.729  0.545  1.0
  S  S14  1  0.348  0.729  0.045  1.0
  S  S15  1  0.848  0.271  0.455  1.0
  N  N16  1  0.537  0.346  0.136  1.0
  N  N17  1  0.037  0.654  0.364  1.0
  N  N18  1  0.463  0.654  0.864  1.0
  N  N19  1  0.963  0.346  0.636  1.0
  O  O20  1  0.787  0.404  0.969  1.0
  O  O21  1  0.287  0.596  0.531  1.0
  O  O22  1  0.213  0.596  0.031  1.0
  O  O23  1  0.713  0.404  0.469  1.0
  O  O24  1  0.519  0.254  0.826  1.0
  O  O25  1  0.019  0.746  0.674  1.0
  O  O26  1  0.481  0.746  0.174  1.0
  O  O27  1  0.981  0.254  0.326  1.0
  O  O28  1  0.728  0.102  0.934  1.0
  O  O29  1  0.228  0.898  0.566  1.0
  O  O30  1  0.272  0.898  0.066  1.0
  O  O31  1  0.772  0.102  0.434  1.0
[/CIF]
.
The material structure described by CsNH2SO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 10-coordinate geometry to one N(1), one H(2), two equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cs(1), one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom. is represented by the CIF file [CIF]
data_CsH2SNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.654
_cell_length_b   8.323
_cell_length_c   8.723
_cell_angle_alpha   115.273
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   502.533
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.646  0.816  0.560  1.0
  Cs  Cs1  1  0.146  0.184  0.940  1.0
  Cs  Cs2  1  0.354  0.184  0.440  1.0
  Cs  Cs3  1  0.854  0.816  0.060  1.0
  H  H4  1  0.492  0.470  0.159  1.0
  H  H5  1  0.992  0.530  0.341  1.0
  H  H6  1  0.508  0.530  0.841  1.0
  H  H7  1  0.008  0.470  0.659  1.0
  H  H8  1  0.617  0.357  0.236  1.0
  H  H9  1  0.117  0.643  0.264  1.0
  H  H10  1  0.383  0.643  0.764  1.0
  H  H11  1  0.883  0.357  0.736  1.0
  S  S12  1  0.652  0.271  0.955  1.0
  S  S13  1  0.152  0.729  0.545  1.0
  S  S14  1  0.348  0.729  0.045  1.0
  S  S15  1  0.848  0.271  0.455  1.0
  N  N16  1  0.537  0.346  0.136  1.0
  N  N17  1  0.037  0.654  0.364  1.0
  N  N18  1  0.463  0.654  0.864  1.0
  N  N19  1  0.963  0.346  0.636  1.0
  O  O20  1  0.787  0.404  0.969  1.0
  O  O21  1  0.287  0.596  0.531  1.0
  O  O22  1  0.213  0.596  0.031  1.0
  O  O23  1  0.713  0.404  0.469  1.0
  O  O24  1  0.519  0.254  0.826  1.0
  O  O25  1  0.019  0.746  0.674  1.0
  O  O26  1  0.481  0.746  0.174  1.0
  O  O27  1  0.981  0.254  0.326  1.0
  O  O28  1  0.728  0.102  0.934  1.0
  O  O29  1  0.228  0.898  0.566  1.0
  O  O30  1  0.272  0.898  0.066  1.0
  O  O31  1  0.772  0.102  0.434  1.0
[/CIF]
.