The material structure described by SrMgLa9Ga9O29 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 1-coordinate geometry to one O(1), one O(3), one O(4), one O(9), and two equivalent O(7) atoms. Mg(1) is bonded in a 5-coordinate geometry to one O(11), one O(3), one O(4), one O(7), and one O(9) atom. There are nine inequivalent La sites. In the first La site, La(1) is bonded in a 1-coordinate geometry to one O(2), one O(28), one O(29), one O(9), and two equivalent O(1) atoms. In the second La site, La(2) is bonded in a 1-coordinate geometry to one O(10), one O(13), and one O(3) atom. In the third La site, La(3) is bonded in a 1-coordinate geometry to one O(11), one O(15), one O(4), one O(7), and two equivalent O(3) atoms. In the fourth La site, La(4) is bonded in a 1-coordinate geometry to one O(14), one O(16), one O(19), one O(8), and two equivalent O(21) atoms. In the fifth La site, La(5) is bonded in a 1-coordinate geometry to one O(10), one O(13), and one O(21) atom. In the sixth La site, La(6) is bonded in a 1-coordinate geometry to one O(14), one O(22), one O(25), and two equivalent O(26) atoms. In the seventh La site, La(7) is bonded in a 1-coordinate geometry to one O(16), one O(19), one O(21), one O(26), and two equivalent O(14) atoms. In the eighth La site, La(8) is bonded in a 1-coordinate geometry to one O(1), one O(20), one O(28), and two equivalent O(29) atoms. In the ninth La site, La(9) is bonded in a 1-coordinate geometry to one O(22), one O(25), one O(26), and one O(29) atom. There are nine inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(5), one O(7), and one O(9) atom. In the second Ga site, Ga(2) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(15), one O(3), one O(4), and one O(6) atom. In the third Ga site, Ga(3) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(17), one O(19), one O(21), and one O(8) atom. In the fourth Ga site, Ga(4) is bonded in a 4-coordinate geometry to one O(10), one O(13), one O(17), and one O(6) atom. In the fifth Ga site, Ga(5) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(18), one O(23), one O(25), and one O(26) atom. In the sixth Ga site, Ga(6) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(16), one O(19), one O(21), and one O(23) atom. In the seventh Ga site, Ga(7) is bonded in a 6-coordinate geometry to one O(20), one O(22), one O(24), one O(27), one O(28), and one O(29) atom. In the eighth Ga site, Ga(8) is bonded in a 4-coordinate geometry to one O(18), one O(22), one O(25), one O(26), and one O(27) atom. In the ninth Ga site, Ga(9) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(24), one O(28), one O(29), and one O(5) atom. There are twenty-nine inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Sr(1), one La(8), two equivalent La(1), one Ga(1), and one Ga(9) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Ga(1), and one Ga(9) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), one Mg(1), one La(2), two equivalent La(3), and one Ga(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(3), and one Ga(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ga(1) and one Ga(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ga(2) and one Ga(4) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(3), and one Ga(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one La(4) and one Ga(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(1), and one Ga(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ga(3), and one Ga(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mg(1), one La(3), and one Ga(2) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one Ga(6) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ga(2), and one Ga(4) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one La(4), one La(6), two equivalent La(7), one Ga(5), and one Ga(6) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one La(3) and one Ga(2) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one La(4), one La(7), one Ga(5), and one Ga(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one Ga(4) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one Ga(8) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one La(4), one La(7), one Ga(3), and one Ga(6) atom. In the twentieth O site, O(20) is bonded in a 1-coordinate geometry to one La(8) and one Ga(7) atom. In the twenty-first O site, O(21) is bonded in a 6-coordinate geometry to one La(5), one La(7), two equivalent La(4), one Ga(3), and one Ga(6) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one La(6), one La(9), one Ga(7), and one Ga(8) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one Ga(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Ga(7) and one Ga(9) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one La(6), one La(9), one Ga(5), and one Ga(8) atom. In the twenty-sixth O site, O(26) is bonded in a 6-coordinate geometry to one La(7), one La(9), two equivalent La(6), one Ga(5), and one Ga(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 150 degrees geometry to one Ga(7) and one Ga(8) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one La(1), one La(8), one Ga(7), and one Ga(9) atom. In the twenty-ninth O site, O(29) is bonded in a 6-coordinate geometry to one La(1), one La(9), two equivalent La(8), one Ga(7), and one Ga(9) atom. is represented by the CIF file [CIF]
data_SrLa9MgGa9O29
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.557
_cell_length_b   5.584
_cell_length_c   23.048
_cell_angle_alpha   96.582
_cell_angle_beta   90.173
_cell_angle_gamma   119.833
_symmetry_Int_Tables_number   1
_cell_volume   614.823
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.764  0.214  0.846  1.0
  La  La1  1  0.246  0.393  0.955  1.0
  La  La2  1  0.750  0.797  0.651  1.0
  La  La3  1  0.292  0.031  0.744  1.0
  La  La4  1  0.750  0.395  0.448  1.0
  La  La5  1  0.249  0.603  0.553  1.0
  La  La6  1  0.747  0.994  0.249  1.0
  La  La7  1  0.248  0.202  0.353  1.0
  La  La8  1  0.736  0.587  0.051  1.0
  La  La9  1  0.248  0.801  0.152  1.0
  Mg  Mg10  1  0.470  0.584  0.797  1.0
  Ga  Ga11  1  0.029  0.812  0.905  1.0
  Ga  Ga12  1  0.001  0.399  0.701  1.0
  Ga  Ga13  1  1.000  1.000  0.500  1.0
  Ga  Ga14  1  0.502  0.202  0.598  1.0
  Ga  Ga15  1  0.999  0.599  0.300  1.0
  Ga  Ga16  1  0.499  0.799  0.401  1.0
  Ga  Ga17  1  0.999  0.199  0.101  1.0
  Ga  Ga18  1  0.498  0.398  0.201  1.0
  Ga  Ga19  1  0.505  0.005  0.999  1.0
  O  O20  1  0.731  0.385  0.934  1.0
  O  O21  1  0.698  0.831  0.954  1.0
  O  O22  1  0.757  0.972  0.737  1.0
  O  O23  1  0.729  0.453  0.758  1.0
  O  O24  1  0.189  0.816  0.966  1.0
  O  O25  1  0.780  0.363  0.644  1.0
  O  O26  1  0.263  0.766  0.841  1.0
  O  O27  1  0.754  0.567  0.533  1.0
  O  O28  1  0.238  0.226  0.869  1.0
  O  O29  1  0.708  0.029  0.559  1.0
  O  O30  1  0.229  0.424  0.750  1.0
  O  O31  1  0.798  0.975  0.441  1.0
  O  O32  1  0.294  0.371  0.638  1.0
  O  O33  1  0.751  0.167  0.333  1.0
  O  O34  1  0.258  0.837  0.664  1.0
  O  O35  1  0.704  0.628  0.358  1.0
  O  O36  1  0.204  0.022  0.558  1.0
  O  O37  1  0.798  0.574  0.240  1.0
  O  O38  1  0.297  0.976  0.440  1.0
  O  O39  1  0.747  0.767  0.134  1.0
  O  O40  1  0.252  0.435  0.467  1.0
  O  O41  1  0.704  0.229  0.158  1.0
  O  O42  1  0.205  0.626  0.359  1.0
  O  O43  1  0.798  0.168  0.040  1.0
  O  O44  1  0.297  0.575  0.241  1.0
  O  O45  1  0.252  0.033  0.266  1.0
  O  O46  1  0.203  0.225  0.160  1.0
  O  O47  1  0.295  0.170  0.043  1.0
  O  O48  1  0.259  0.631  0.067  1.0
[/CIF]
.
The material structure described by SrMgLa9Ga9O29 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 1-coordinate geometry to one O(1), one O(3), one O(4), one O(9), and two equivalent O(7) atoms. Mg(1) is bonded in a 5-coordinate geometry to one O(11), one O(3), one O(4), one O(7), and one O(9) atom. There are nine inequivalent La sites. In the first La site, La(1) is bonded in a 1-coordinate geometry to one O(2), one O(28), one O(29), one O(9), and two equivalent O(1) atoms. In the second La site, La(2) is bonded in a 1-coordinate geometry to one O(10), one O(13), and one O(3) atom. In the third La site, La(3) is bonded in a 1-coordinate geometry to one O(11), one O(15), one O(4), one O(7), and two equivalent O(3) atoms. In the fourth La site, La(4) is bonded in a 1-coordinate geometry to one O(14), one O(16), one O(19), one O(8), and two equivalent O(21) atoms. In the fifth La site, La(5) is bonded in a 1-coordinate geometry to one O(10), one O(13), and one O(21) atom. In the sixth La site, La(6) is bonded in a 1-coordinate geometry to one O(14), one O(22), one O(25), and two equivalent O(26) atoms. In the seventh La site, La(7) is bonded in a 1-coordinate geometry to one O(16), one O(19), one O(21), one O(26), and two equivalent O(14) atoms. In the eighth La site, La(8) is bonded in a 1-coordinate geometry to one O(1), one O(20), one O(28), and two equivalent O(29) atoms. In the ninth La site, La(9) is bonded in a 1-coordinate geometry to one O(22), one O(25), one O(26), and one O(29) atom. There are nine inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(5), one O(7), and one O(9) atom. In the second Ga site, Ga(2) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(15), one O(3), one O(4), and one O(6) atom. In the third Ga site, Ga(3) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(17), one O(19), one O(21), and one O(8) atom. In the fourth Ga site, Ga(4) is bonded in a 4-coordinate geometry to one O(10), one O(13), one O(17), and one O(6) atom. In the fifth Ga site, Ga(5) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(18), one O(23), one O(25), and one O(26) atom. In the sixth Ga site, Ga(6) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(16), one O(19), one O(21), and one O(23) atom. In the seventh Ga site, Ga(7) is bonded in a 6-coordinate geometry to one O(20), one O(22), one O(24), one O(27), one O(28), and one O(29) atom. In the eighth Ga site, Ga(8) is bonded in a 4-coordinate geometry to one O(18), one O(22), one O(25), one O(26), and one O(27) atom. In the ninth Ga site, Ga(9) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(24), one O(28), one O(29), and one O(5) atom. There are twenty-nine inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Sr(1), one La(8), two equivalent La(1), one Ga(1), and one Ga(9) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Ga(1), and one Ga(9) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), one Mg(1), one La(2), two equivalent La(3), and one Ga(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(3), and one Ga(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ga(1) and one Ga(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ga(2) and one Ga(4) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(3), and one Ga(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one La(4) and one Ga(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(1), and one Ga(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ga(3), and one Ga(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mg(1), one La(3), and one Ga(2) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one Ga(6) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ga(2), and one Ga(4) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one La(4), one La(6), two equivalent La(7), one Ga(5), and one Ga(6) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one La(3) and one Ga(2) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one La(4), one La(7), one Ga(5), and one Ga(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one Ga(4) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one Ga(8) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one La(4), one La(7), one Ga(3), and one Ga(6) atom. In the twentieth O site, O(20) is bonded in a 1-coordinate geometry to one La(8) and one Ga(7) atom. In the twenty-first O site, O(21) is bonded in a 6-coordinate geometry to one La(5), one La(7), two equivalent La(4), one Ga(3), and one Ga(6) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one La(6), one La(9), one Ga(7), and one Ga(8) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one Ga(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Ga(7) and one Ga(9) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one La(6), one La(9), one Ga(5), and one Ga(8) atom. In the twenty-sixth O site, O(26) is bonded in a 6-coordinate geometry to one La(7), one La(9), two equivalent La(6), one Ga(5), and one Ga(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 150 degrees geometry to one Ga(7) and one Ga(8) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one La(1), one La(8), one Ga(7), and one Ga(9) atom. In the twenty-ninth O site, O(29) is bonded in a 6-coordinate geometry to one La(1), one La(9), two equivalent La(8), one Ga(7), and one Ga(9) atom. is represented by the CIF file [CIF]
data_SrLa9MgGa9O29
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.557
_cell_length_b   5.584
_cell_length_c   23.048
_cell_angle_alpha   96.582
_cell_angle_beta   90.173
_cell_angle_gamma   119.833
_symmetry_Int_Tables_number   1
_cell_volume   614.823
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.764  0.214  0.846  1.0
  La  La1  1  0.246  0.393  0.955  1.0
  La  La2  1  0.750  0.797  0.651  1.0
  La  La3  1  0.292  0.031  0.744  1.0
  La  La4  1  0.750  0.395  0.448  1.0
  La  La5  1  0.249  0.603  0.553  1.0
  La  La6  1  0.747  0.994  0.249  1.0
  La  La7  1  0.248  0.202  0.353  1.0
  La  La8  1  0.736  0.587  0.051  1.0
  La  La9  1  0.248  0.801  0.152  1.0
  Mg  Mg10  1  0.470  0.584  0.797  1.0
  Ga  Ga11  1  0.029  0.812  0.905  1.0
  Ga  Ga12  1  0.001  0.399  0.701  1.0
  Ga  Ga13  1  1.000  1.000  0.500  1.0
  Ga  Ga14  1  0.502  0.202  0.598  1.0
  Ga  Ga15  1  0.999  0.599  0.300  1.0
  Ga  Ga16  1  0.499  0.799  0.401  1.0
  Ga  Ga17  1  0.999  0.199  0.101  1.0
  Ga  Ga18  1  0.498  0.398  0.201  1.0
  Ga  Ga19  1  0.505  0.005  0.999  1.0
  O  O20  1  0.731  0.385  0.934  1.0
  O  O21  1  0.698  0.831  0.954  1.0
  O  O22  1  0.757  0.972  0.737  1.0
  O  O23  1  0.729  0.453  0.758  1.0
  O  O24  1  0.189  0.816  0.966  1.0
  O  O25  1  0.780  0.363  0.644  1.0
  O  O26  1  0.263  0.766  0.841  1.0
  O  O27  1  0.754  0.567  0.533  1.0
  O  O28  1  0.238  0.226  0.869  1.0
  O  O29  1  0.708  0.029  0.559  1.0
  O  O30  1  0.229  0.424  0.750  1.0
  O  O31  1  0.798  0.975  0.441  1.0
  O  O32  1  0.294  0.371  0.638  1.0
  O  O33  1  0.751  0.167  0.333  1.0
  O  O34  1  0.258  0.837  0.664  1.0
  O  O35  1  0.704  0.628  0.358  1.0
  O  O36  1  0.204  0.022  0.558  1.0
  O  O37  1  0.798  0.574  0.240  1.0
  O  O38  1  0.297  0.976  0.440  1.0
  O  O39  1  0.747  0.767  0.134  1.0
  O  O40  1  0.252  0.435  0.467  1.0
  O  O41  1  0.704  0.229  0.158  1.0
  O  O42  1  0.205  0.626  0.359  1.0
  O  O43  1  0.798  0.168  0.040  1.0
  O  O44  1  0.297  0.575  0.241  1.0
  O  O45  1  0.252  0.033  0.266  1.0
  O  O46  1  0.203  0.225  0.160  1.0
  O  O47  1  0.295  0.170  0.043  1.0
  O  O48  1  0.259  0.631  0.067  1.0
[/CIF]
.