The crystal structure described by LiLa2TiCrO6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LaO6 octahedra that share corners with three equivalent Cr(1)O5 square pyramids and  an edgeedge with one Cr(1)O5 square pyramid. In the second La site, La(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Ti(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form distorted CrO5 square pyramids that share corners with three equivalent La(1)O6 octahedra and  an edgeedge with one La(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-66°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one La(1), one La(2), and one Ti(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal bipyramidal geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. is represented by the CIF card [CIF]
data_LiLa2TiCrO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.553
_cell_length_b   6.031
_cell_length_c   6.276
_cell_angle_alpha   55.565
_cell_angle_beta   51.276
_cell_angle_gamma   56.167
_symmetry_Int_Tables_number   1
_cell_volume   151.448
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.099  0.228  0.076  1.0
  La  La1  1  0.330  0.286  0.298  1.0
  La  La2  1  0.770  0.799  0.777  1.0
  Ti  Ti3  1  0.981  0.953  0.003  1.0
  Cr  Cr4  1  0.505  0.487  0.514  1.0
  O  O5  1  0.634  0.838  0.229  1.0
  O  O6  1  0.906  0.173  0.667  1.0
  O  O7  1  0.204  0.585  0.896  1.0
  O  O8  1  0.098  0.780  0.300  1.0
  O  O9  1  0.737  0.349  0.142  1.0
  O  O10  1  0.354  0.142  0.729  1.0
[/CIF]
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The crystal structure described by LiLa2TiCrO6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LaO6 octahedra that share corners with three equivalent Cr(1)O5 square pyramids and  an edgeedge with one Cr(1)O5 square pyramid. In the second La site, La(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Ti(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form distorted CrO5 square pyramids that share corners with three equivalent La(1)O6 octahedra and  an edgeedge with one La(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-66°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one La(1), one La(2), and one Ti(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal bipyramidal geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. is represented by the CIF card [CIF]
data_LiLa2TiCrO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.553
_cell_length_b   6.031
_cell_length_c   6.276
_cell_angle_alpha   55.565
_cell_angle_beta   51.276
_cell_angle_gamma   56.167
_symmetry_Int_Tables_number   1
_cell_volume   151.448
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.099  0.228  0.076  1.0
  La  La1  1  0.330  0.286  0.298  1.0
  La  La2  1  0.770  0.799  0.777  1.0
  Ti  Ti3  1  0.981  0.953  0.003  1.0
  Cr  Cr4  1  0.505  0.487  0.514  1.0
  O  O5  1  0.634  0.838  0.229  1.0
  O  O6  1  0.906  0.173  0.667  1.0
  O  O7  1  0.204  0.585  0.896  1.0
  O  O8  1  0.098  0.780  0.300  1.0
  O  O9  1  0.737  0.349  0.142  1.0
  O  O10  1  0.354  0.142  0.729  1.0
[/CIF]
.