The crystal structure described by Mg3NF3 crystallizes in the cubic Pm-3m space group. Mg(1) is bonded to two equivalent N(1) and four equivalent F(1) atoms to form a mixture of corner and edge-sharing MgN2F4 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded to six equivalent Mg(1) atoms to form corner-sharing NMg6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a square co-planar geometry to four equivalent Mg(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg3NF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.201
_cell_length_b   4.201
_cell_length_c   4.201
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   74.149
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.000  0.500  1.0
  Mg  Mg1  1  0.500  0.500  0.000  1.0
  Mg  Mg2  1  0.000  0.500  0.500  1.0
  N  N3  1  0.500  0.500  0.500  1.0
  F  F4  1  0.000  0.500  0.000  1.0
  F  F5  1  0.000  0.000  0.500  1.0
  F  F6  1  0.500  0.000  0.000  1.0
[/CIF]
.
The crystal structure described by Mg3NF3 crystallizes in the cubic Pm-3m space group. Mg(1) is bonded to two equivalent N(1) and four equivalent F(1) atoms to form a mixture of corner and edge-sharing MgN2F4 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded to six equivalent Mg(1) atoms to form corner-sharing NMg6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a square co-planar geometry to four equivalent Mg(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg3NF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.201
_cell_length_b   4.201
_cell_length_c   4.201
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   74.149
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.000  0.500  1.0
  Mg  Mg1  1  0.500  0.500  0.000  1.0
  Mg  Mg2  1  0.000  0.500  0.500  1.0
  N  N3  1  0.500  0.500  0.500  1.0
  F  F4  1  0.000  0.500  0.000  1.0
  F  F5  1  0.000  0.000  0.500  1.0
  F  F6  1  0.500  0.000  0.000  1.0
[/CIF]
.