The material structure described by LiLa4Ga2(FeO6)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one Fe(1), one O(4), one O(5), one O(8), and one O(9) atom. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(9) atom. In the second La site, La(2) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(8) atom. In the third La site, La(3) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(6), one O(7), and one O(9) atom. In the fourth La site, La(4) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 7-coordinate geometry to one Li(1), one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom. In the second Fe site, Fe(2) is bonded to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share corners with two equivalent Ga(2)O6 octahedra and corners with four equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-27°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form GaO6 octahedra that share corners with four equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-25°. In the second Ga site, Ga(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form GaO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles are 27°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Fe(2), and one Ga(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Fe(1), and one Ga(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), one La(3), one La(4), one Fe(1), and one Ga(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Fe(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one La(1), one La(2), one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal bipyramidal geometry to one Li(1), one La(2), one La(4), one Fe(1), and one Ga(2) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(3), one Fe(1), and one Ga(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eleventh O site, O(11) is bonded in a 6-coordinate geometry to one La(1), one La(2), one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Fe(1), and one Ga(2) atom. is represented by the CIF card [CIF]
data_LiLa4Ga2(FeO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.704
_cell_length_b   5.628
_cell_length_c   8.200
_cell_angle_alpha   90.517
_cell_angle_beta   86.880
_cell_angle_gamma   89.296
_symmetry_Int_Tables_number   1
_cell_volume   262.831
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.714  0.537  0.420  1.0
  La  La1  1  0.471  0.482  0.743  1.0
  La  La2  1  0.966  0.007  0.740  1.0
  La  La3  1  0.430  0.482  0.189  1.0
  La  La4  1  0.955  0.011  0.235  1.0
  Ga  Ga5  1  0.970  0.506  0.994  1.0
  Ga  Ga6  1  0.515  0.995  0.499  1.0
  Fe  Fe7  1  0.067  0.500  0.515  1.0
  Fe  Fe8  1  0.484  0.990  0.989  1.0
  O  O9  1  0.518  0.908  0.753  1.0
  O  O10  1  0.034  0.582  0.763  1.0
  O  O11  1  0.519  0.079  0.255  1.0
  O  O12  1  0.978  0.434  0.245  1.0
  O  O13  1  0.730  0.273  0.558  1.0
  O  O14  1  0.239  0.256  0.970  1.0
  O  O15  1  0.219  0.768  0.044  1.0
  O  O16  1  0.854  0.817  0.480  1.0
  O  O17  1  0.395  0.670  0.457  1.0
  O  O18  1  0.725  0.745  0.043  1.0
  O  O19  1  0.730  0.258  0.956  1.0
  O  O20  1  0.238  0.187  0.552  1.0
[/CIF]
.
The material structure described by LiLa4Ga2(FeO6)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one Fe(1), one O(4), one O(5), one O(8), and one O(9) atom. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(9) atom. In the second La site, La(2) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(8) atom. In the third La site, La(3) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(6), one O(7), and one O(9) atom. In the fourth La site, La(4) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 7-coordinate geometry to one Li(1), one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom. In the second Fe site, Fe(2) is bonded to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share corners with two equivalent Ga(2)O6 octahedra and corners with four equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-27°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form GaO6 octahedra that share corners with four equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-25°. In the second Ga site, Ga(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form GaO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles are 27°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Fe(2), and one Ga(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Fe(1), and one Ga(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), one La(3), one La(4), one Fe(1), and one Ga(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Fe(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one La(1), one La(2), one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal bipyramidal geometry to one Li(1), one La(2), one La(4), one Fe(1), and one Ga(2) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(3), one Fe(1), and one Ga(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eleventh O site, O(11) is bonded in a 6-coordinate geometry to one La(1), one La(2), one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Fe(1), and one Ga(2) atom. is represented by the CIF card [CIF]
data_LiLa4Ga2(FeO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.704
_cell_length_b   5.628
_cell_length_c   8.200
_cell_angle_alpha   90.517
_cell_angle_beta   86.880
_cell_angle_gamma   89.296
_symmetry_Int_Tables_number   1
_cell_volume   262.831
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.714  0.537  0.420  1.0
  La  La1  1  0.471  0.482  0.743  1.0
  La  La2  1  0.966  0.007  0.740  1.0
  La  La3  1  0.430  0.482  0.189  1.0
  La  La4  1  0.955  0.011  0.235  1.0
  Ga  Ga5  1  0.970  0.506  0.994  1.0
  Ga  Ga6  1  0.515  0.995  0.499  1.0
  Fe  Fe7  1  0.067  0.500  0.515  1.0
  Fe  Fe8  1  0.484  0.990  0.989  1.0
  O  O9  1  0.518  0.908  0.753  1.0
  O  O10  1  0.034  0.582  0.763  1.0
  O  O11  1  0.519  0.079  0.255  1.0
  O  O12  1  0.978  0.434  0.245  1.0
  O  O13  1  0.730  0.273  0.558  1.0
  O  O14  1  0.239  0.256  0.970  1.0
  O  O15  1  0.219  0.768  0.044  1.0
  O  O16  1  0.854  0.817  0.480  1.0
  O  O17  1  0.395  0.670  0.457  1.0
  O  O18  1  0.725  0.745  0.043  1.0
  O  O19  1  0.730  0.258  0.956  1.0
  O  O20  1  0.238  0.187  0.552  1.0
[/CIF]
.