The structure described by CsUSbO6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form distorted CsO6 octahedra that share corners with six equivalent U(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 66-75°. U(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form UO6 octahedra that share corners with two equivalent U(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-75°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent U(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-68°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cs(1) and two equivalent U(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one U(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsUSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.708
_cell_length_b   7.708
_cell_length_c   7.708
_cell_angle_alpha   122.489
_cell_angle_beta   117.826
_cell_angle_gamma   89.775
_symmetry_Int_Tables_number   1
_cell_volume   322.364
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.372  0.622  0.750  1.0
  Cs  Cs1  1  0.628  0.378  0.250  1.0
  U  U2  1  0.000  0.000  0.000  1.0
  U  U3  1  0.500  0.000  0.500  1.0
  Sb  Sb4  1  0.000  0.000  0.500  1.0
  Sb  Sb5  1  0.000  0.500  0.000  1.0
  O  O6  1  0.318  0.068  0.250  1.0
  O  O7  1  0.932  0.682  0.250  1.0
  O  O8  1  0.305  0.680  0.237  1.0
  O  O9  1  0.944  0.068  0.263  1.0
  O  O10  1  0.305  0.068  0.624  1.0
  O  O11  1  0.944  0.680  0.876  1.0
  O  O12  1  0.682  0.932  0.750  1.0
  O  O13  1  0.068  0.318  0.750  1.0
  O  O14  1  0.695  0.320  0.763  1.0
  O  O15  1  0.056  0.932  0.737  1.0
  O  O16  1  0.695  0.932  0.376  1.0
  O  O17  1  0.056  0.320  0.124  1.0
[/CIF]
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The structure described by CsUSbO6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form distorted CsO6 octahedra that share corners with six equivalent U(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 66-75°. U(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form UO6 octahedra that share corners with two equivalent U(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-75°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent U(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-68°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cs(1) and two equivalent U(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one U(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsUSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.708
_cell_length_b   7.708
_cell_length_c   7.708
_cell_angle_alpha   122.489
_cell_angle_beta   117.826
_cell_angle_gamma   89.775
_symmetry_Int_Tables_number   1
_cell_volume   322.364
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.372  0.622  0.750  1.0
  Cs  Cs1  1  0.628  0.378  0.250  1.0
  U  U2  1  0.000  0.000  0.000  1.0
  U  U3  1  0.500  0.000  0.500  1.0
  Sb  Sb4  1  0.000  0.000  0.500  1.0
  Sb  Sb5  1  0.000  0.500  0.000  1.0
  O  O6  1  0.318  0.068  0.250  1.0
  O  O7  1  0.932  0.682  0.250  1.0
  O  O8  1  0.305  0.680  0.237  1.0
  O  O9  1  0.944  0.068  0.263  1.0
  O  O10  1  0.305  0.068  0.624  1.0
  O  O11  1  0.944  0.680  0.876  1.0
  O  O12  1  0.682  0.932  0.750  1.0
  O  O13  1  0.068  0.318  0.750  1.0
  O  O14  1  0.695  0.320  0.763  1.0
  O  O15  1  0.056  0.932  0.737  1.0
  O  O16  1  0.695  0.932  0.376  1.0
  O  O17  1  0.056  0.320  0.124  1.0
[/CIF]
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