The material described by RbVSO6 crystallizes in the orthorhombic P2_12_12_1 space group. Rb(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Rb(1), one V(1), and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one V(1), and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Rb(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Rb(1), one V(1), and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbVSO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.637
_cell_length_b   9.040
_cell_length_c   10.969
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   558.968
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.003  0.688  0.844  1.0
  Rb  Rb1  1  0.497  0.312  0.344  1.0
  Rb  Rb2  1  0.503  0.812  0.156  1.0
  Rb  Rb3  1  0.997  0.188  0.656  1.0
  V  V4  1  0.541  0.847  0.560  1.0
  V  V5  1  0.041  0.653  0.440  1.0
  V  V6  1  0.459  0.347  0.940  1.0
  V  V7  1  0.959  0.153  0.060  1.0
  S  S8  1  0.518  0.458  0.712  1.0
  S  S9  1  0.982  0.542  0.212  1.0
  S  S10  1  0.018  0.042  0.288  1.0
  S  S11  1  0.482  0.958  0.788  1.0
  O  O12  1  0.200  0.095  0.191  1.0
  O  O13  1  0.800  0.595  0.309  1.0
  O  O14  1  0.709  0.916  0.719  1.0
  O  O15  1  0.552  0.001  0.484  1.0
  O  O16  1  0.965  0.382  0.198  1.0
  O  O17  1  0.948  0.999  0.984  1.0
  O  O18  1  0.676  0.241  0.021  1.0
  O  O19  1  0.545  0.373  0.600  1.0
  O  O20  1  0.291  0.416  0.781  1.0
  O  O21  1  0.824  0.759  0.521  1.0
  O  O22  1  0.324  0.741  0.479  1.0
  O  O23  1  0.176  0.259  0.979  1.0
  O  O24  1  0.209  0.584  0.281  1.0
  O  O25  1  0.045  0.127  0.400  1.0
  O  O26  1  0.791  0.084  0.219  1.0
  O  O27  1  0.955  0.627  0.100  1.0
  O  O28  1  0.035  0.882  0.302  1.0
  O  O29  1  0.455  0.873  0.900  1.0
  O  O30  1  0.300  0.905  0.691  1.0
  O  O31  1  0.700  0.405  0.809  1.0
  O  O32  1  0.448  0.501  0.016  1.0
  O  O33  1  0.535  0.618  0.698  1.0
  O  O34  1  0.052  0.499  0.516  1.0
  O  O35  1  0.465  0.118  0.802  1.0
[/CIF]
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The material described by RbVSO6 crystallizes in the orthorhombic P2_12_12_1 space group. Rb(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Rb(1), one V(1), and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one V(1), and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Rb(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Rb(1), one V(1), and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbVSO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.637
_cell_length_b   9.040
_cell_length_c   10.969
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   558.968
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.003  0.688  0.844  1.0
  Rb  Rb1  1  0.497  0.312  0.344  1.0
  Rb  Rb2  1  0.503  0.812  0.156  1.0
  Rb  Rb3  1  0.997  0.188  0.656  1.0
  V  V4  1  0.541  0.847  0.560  1.0
  V  V5  1  0.041  0.653  0.440  1.0
  V  V6  1  0.459  0.347  0.940  1.0
  V  V7  1  0.959  0.153  0.060  1.0
  S  S8  1  0.518  0.458  0.712  1.0
  S  S9  1  0.982  0.542  0.212  1.0
  S  S10  1  0.018  0.042  0.288  1.0
  S  S11  1  0.482  0.958  0.788  1.0
  O  O12  1  0.200  0.095  0.191  1.0
  O  O13  1  0.800  0.595  0.309  1.0
  O  O14  1  0.709  0.916  0.719  1.0
  O  O15  1  0.552  0.001  0.484  1.0
  O  O16  1  0.965  0.382  0.198  1.0
  O  O17  1  0.948  0.999  0.984  1.0
  O  O18  1  0.676  0.241  0.021  1.0
  O  O19  1  0.545  0.373  0.600  1.0
  O  O20  1  0.291  0.416  0.781  1.0
  O  O21  1  0.824  0.759  0.521  1.0
  O  O22  1  0.324  0.741  0.479  1.0
  O  O23  1  0.176  0.259  0.979  1.0
  O  O24  1  0.209  0.584  0.281  1.0
  O  O25  1  0.045  0.127  0.400  1.0
  O  O26  1  0.791  0.084  0.219  1.0
  O  O27  1  0.955  0.627  0.100  1.0
  O  O28  1  0.035  0.882  0.302  1.0
  O  O29  1  0.455  0.873  0.900  1.0
  O  O30  1  0.300  0.905  0.691  1.0
  O  O31  1  0.700  0.405  0.809  1.0
  O  O32  1  0.448  0.501  0.016  1.0
  O  O33  1  0.535  0.618  0.698  1.0
  O  O34  1  0.052  0.499  0.516  1.0
  O  O35  1  0.465  0.118  0.802  1.0
[/CIF]
.