The material structure described by N4S5O3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N4S5O3 clusters. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one S(1), one S(4), and one S(5) atom. In the third N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the fourth N site, N(3) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one N(1) and one N(4) atom. In the fifth S site, S(5) is bonded in a distorted tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(5) atom. is represented by the CIF card [CIF]
data_S5N4O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.962
_cell_length_b   7.444
_cell_length_c   12.826
_cell_angle_alpha   60.328
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   909.378
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.431  0.877  0.905  1.0
  S  S1  1  0.931  0.123  0.595  1.0
  S  S2  1  0.569  0.123  0.095  1.0
  S  S3  1  0.069  0.877  0.405  1.0
  S  S4  1  0.459  0.270  0.676  1.0
  S  S5  1  0.959  0.730  0.824  1.0
  S  S6  1  0.541  0.730  0.324  1.0
  S  S7  1  0.041  0.270  0.176  1.0
  S  S8  1  0.340  0.061  0.553  1.0
  S  S9  1  0.840  0.939  0.947  1.0
  S  S10  1  0.660  0.939  0.447  1.0
  S  S11  1  0.160  0.061  0.053  1.0
  S  S12  1  0.333  0.672  0.787  1.0
  S  S13  1  0.833  0.328  0.713  1.0
  S  S14  1  0.667  0.328  0.213  1.0
  S  S15  1  0.167  0.672  0.287  1.0
  S  S16  1  0.612  0.700  0.802  1.0
  S  S17  1  0.112  0.300  0.698  1.0
  S  S18  1  0.388  0.300  0.198  1.0
  S  S19  1  0.888  0.700  0.302  1.0
  N  N20  1  0.456  0.744  0.834  1.0
  N  N21  1  0.956  0.256  0.666  1.0
  N  N22  1  0.544  0.256  0.166  1.0
  N  N23  1  0.044  0.744  0.334  1.0
  N  N24  1  0.446  0.119  0.814  1.0
  N  N25  1  0.946  0.881  0.686  1.0
  N  N26  1  0.554  0.881  0.186  1.0
  N  N27  1  0.054  0.119  0.314  1.0
  N  N28  1  0.437  0.188  0.584  1.0
  N  N29  1  0.937  0.812  0.916  1.0
  N  N30  1  0.563  0.812  0.416  1.0
  N  N31  1  0.063  0.188  0.084  1.0
  N  N32  1  0.300  0.842  0.653  1.0
  N  N33  1  0.800  0.158  0.847  1.0
  N  N34  1  0.700  0.158  0.347  1.0
  N  N35  1  0.200  0.842  0.153  1.0
  O  O36  1  0.663  0.573  0.921  1.0
  O  O37  1  0.163  0.427  0.579  1.0
  O  O38  1  0.337  0.427  0.079  1.0
  O  O39  1  0.837  0.573  0.421  1.0
  O  O40  1  0.662  0.908  0.736  1.0
  O  O41  1  0.162  0.092  0.764  1.0
  O  O42  1  0.338  0.092  0.264  1.0
  O  O43  1  0.838  0.908  0.236  1.0
  O  O44  1  0.588  0.597  0.733  1.0
  O  O45  1  0.088  0.403  0.767  1.0
  O  O46  1  0.412  0.403  0.267  1.0
  O  O47  1  0.912  0.597  0.233  1.0
[/CIF]
.
The material structure described by N4S5O3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N4S5O3 clusters. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one S(1), one S(4), and one S(5) atom. In the third N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the fourth N site, N(3) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one N(1) and one N(4) atom. In the fifth S site, S(5) is bonded in a distorted tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(5) atom. is represented by the CIF card [CIF]
data_S5N4O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.962
_cell_length_b   7.444
_cell_length_c   12.826
_cell_angle_alpha   60.328
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   909.378
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.431  0.877  0.905  1.0
  S  S1  1  0.931  0.123  0.595  1.0
  S  S2  1  0.569  0.123  0.095  1.0
  S  S3  1  0.069  0.877  0.405  1.0
  S  S4  1  0.459  0.270  0.676  1.0
  S  S5  1  0.959  0.730  0.824  1.0
  S  S6  1  0.541  0.730  0.324  1.0
  S  S7  1  0.041  0.270  0.176  1.0
  S  S8  1  0.340  0.061  0.553  1.0
  S  S9  1  0.840  0.939  0.947  1.0
  S  S10  1  0.660  0.939  0.447  1.0
  S  S11  1  0.160  0.061  0.053  1.0
  S  S12  1  0.333  0.672  0.787  1.0
  S  S13  1  0.833  0.328  0.713  1.0
  S  S14  1  0.667  0.328  0.213  1.0
  S  S15  1  0.167  0.672  0.287  1.0
  S  S16  1  0.612  0.700  0.802  1.0
  S  S17  1  0.112  0.300  0.698  1.0
  S  S18  1  0.388  0.300  0.198  1.0
  S  S19  1  0.888  0.700  0.302  1.0
  N  N20  1  0.456  0.744  0.834  1.0
  N  N21  1  0.956  0.256  0.666  1.0
  N  N22  1  0.544  0.256  0.166  1.0
  N  N23  1  0.044  0.744  0.334  1.0
  N  N24  1  0.446  0.119  0.814  1.0
  N  N25  1  0.946  0.881  0.686  1.0
  N  N26  1  0.554  0.881  0.186  1.0
  N  N27  1  0.054  0.119  0.314  1.0
  N  N28  1  0.437  0.188  0.584  1.0
  N  N29  1  0.937  0.812  0.916  1.0
  N  N30  1  0.563  0.812  0.416  1.0
  N  N31  1  0.063  0.188  0.084  1.0
  N  N32  1  0.300  0.842  0.653  1.0
  N  N33  1  0.800  0.158  0.847  1.0
  N  N34  1  0.700  0.158  0.347  1.0
  N  N35  1  0.200  0.842  0.153  1.0
  O  O36  1  0.663  0.573  0.921  1.0
  O  O37  1  0.163  0.427  0.579  1.0
  O  O38  1  0.337  0.427  0.079  1.0
  O  O39  1  0.837  0.573  0.421  1.0
  O  O40  1  0.662  0.908  0.736  1.0
  O  O41  1  0.162  0.092  0.764  1.0
  O  O42  1  0.338  0.092  0.264  1.0
  O  O43  1  0.838  0.908  0.236  1.0
  O  O44  1  0.588  0.597  0.733  1.0
  O  O45  1  0.088  0.403  0.767  1.0
  O  O46  1  0.412  0.403  0.267  1.0
  O  O47  1  0.912  0.597  0.233  1.0
[/CIF]
.