The material structure described by ZnMo8O10 crystallizes in the tetragonal I4_1/amd space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(2) and three equivalent O(3) atoms to form MoO5 square pyramids that share corners with two equivalent Zn(1)O4 tetrahedra and edges with four equivalent Mo(1)O5 square pyramids. In the second Mo site, Mo(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. Zn(1) is bonded to four equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with eight equivalent Mo(1)O5 square pyramids. There are three inequivalent O sites. In the first O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(2), two equivalent Mo(1), and one Zn(1) atom. In the second O site, O(1) is bonded in a square co-planar geometry to four equivalent Mo(2) atoms. In the third O site, O(3) is bonded in a see-saw-like geometry to one Mo(2) and three equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_Zn(Mo4O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.703
_cell_length_b   13.703
_cell_length_c   13.703
_cell_angle_alpha   152.794
_cell_angle_beta   152.794
_cell_angle_gamma   38.855
_symmetry_Int_Tables_number   1
_cell_volume   536.910
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.750  0.500  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  Mo  Mo2  1  0.792  0.549  0.757  1.0
  Mo  Mo3  1  0.299  0.042  0.257  1.0
  Mo  Mo4  1  0.786  0.042  0.743  1.0
  Mo  Mo5  1  0.792  0.036  0.243  1.0
  Mo  Mo6  1  0.958  0.701  0.743  1.0
  Mo  Mo7  1  0.451  0.208  0.243  1.0
  Mo  Mo8  1  0.964  0.208  0.757  1.0
  Mo  Mo9  1  0.958  0.214  0.257  1.0
  Mo  Mo10  1  0.124  0.390  0.266  1.0
  Mo  Mo11  1  0.140  0.374  0.766  1.0
  Mo  Mo12  1  0.607  0.374  0.234  1.0
  Mo  Mo13  1  0.124  0.857  0.734  1.0
  Mo  Mo14  1  0.626  0.393  0.766  1.0
  Mo  Mo15  1  0.143  0.876  0.266  1.0
  Mo  Mo16  1  0.610  0.876  0.734  1.0
  Mo  Mo17  1  0.626  0.860  0.234  1.0
  O  O18  1  0.375  0.625  0.250  1.0
  O  O19  1  0.206  0.972  0.766  1.0
  O  O20  1  0.040  0.823  0.783  1.0
  O  O21  1  0.573  0.290  0.283  1.0
  O  O22  1  0.008  0.290  0.717  1.0
  O  O23  1  0.040  0.258  0.217  1.0
  O  O24  1  0.710  0.427  0.717  1.0
  O  O25  1  0.177  0.960  0.217  1.0
  O  O26  1  0.742  0.960  0.783  1.0
  O  O27  1  0.710  0.992  0.283  1.0
  O  O28  1  0.722  0.456  0.266  1.0
  O  O29  1  0.559  0.794  0.766  1.0
  O  O30  1  0.028  0.794  0.234  1.0
  O  O31  1  0.544  0.278  0.734  1.0
  O  O32  1  0.206  0.441  0.234  1.0
  O  O33  1  0.191  0.456  0.734  1.0
  O  O34  1  0.375  0.125  0.750  1.0
  O  O35  1  0.875  0.625  0.250  1.0
  O  O36  1  0.375  0.625  0.750  1.0
  O  O37  1  0.544  0.809  0.266  1.0
[/CIF]
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The material structure described by ZnMo8O10 crystallizes in the tetragonal I4_1/amd space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(2) and three equivalent O(3) atoms to form MoO5 square pyramids that share corners with two equivalent Zn(1)O4 tetrahedra and edges with four equivalent Mo(1)O5 square pyramids. In the second Mo site, Mo(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. Zn(1) is bonded to four equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with eight equivalent Mo(1)O5 square pyramids. There are three inequivalent O sites. In the first O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(2), two equivalent Mo(1), and one Zn(1) atom. In the second O site, O(1) is bonded in a square co-planar geometry to four equivalent Mo(2) atoms. In the third O site, O(3) is bonded in a see-saw-like geometry to one Mo(2) and three equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_Zn(Mo4O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.703
_cell_length_b   13.703
_cell_length_c   13.703
_cell_angle_alpha   152.794
_cell_angle_beta   152.794
_cell_angle_gamma   38.855
_symmetry_Int_Tables_number   1
_cell_volume   536.910
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.750  0.500  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  Mo  Mo2  1  0.792  0.549  0.757  1.0
  Mo  Mo3  1  0.299  0.042  0.257  1.0
  Mo  Mo4  1  0.786  0.042  0.743  1.0
  Mo  Mo5  1  0.792  0.036  0.243  1.0
  Mo  Mo6  1  0.958  0.701  0.743  1.0
  Mo  Mo7  1  0.451  0.208  0.243  1.0
  Mo  Mo8  1  0.964  0.208  0.757  1.0
  Mo  Mo9  1  0.958  0.214  0.257  1.0
  Mo  Mo10  1  0.124  0.390  0.266  1.0
  Mo  Mo11  1  0.140  0.374  0.766  1.0
  Mo  Mo12  1  0.607  0.374  0.234  1.0
  Mo  Mo13  1  0.124  0.857  0.734  1.0
  Mo  Mo14  1  0.626  0.393  0.766  1.0
  Mo  Mo15  1  0.143  0.876  0.266  1.0
  Mo  Mo16  1  0.610  0.876  0.734  1.0
  Mo  Mo17  1  0.626  0.860  0.234  1.0
  O  O18  1  0.375  0.625  0.250  1.0
  O  O19  1  0.206  0.972  0.766  1.0
  O  O20  1  0.040  0.823  0.783  1.0
  O  O21  1  0.573  0.290  0.283  1.0
  O  O22  1  0.008  0.290  0.717  1.0
  O  O23  1  0.040  0.258  0.217  1.0
  O  O24  1  0.710  0.427  0.717  1.0
  O  O25  1  0.177  0.960  0.217  1.0
  O  O26  1  0.742  0.960  0.783  1.0
  O  O27  1  0.710  0.992  0.283  1.0
  O  O28  1  0.722  0.456  0.266  1.0
  O  O29  1  0.559  0.794  0.766  1.0
  O  O30  1  0.028  0.794  0.234  1.0
  O  O31  1  0.544  0.278  0.734  1.0
  O  O32  1  0.206  0.441  0.234  1.0
  O  O33  1  0.191  0.456  0.734  1.0
  O  O34  1  0.375  0.125  0.750  1.0
  O  O35  1  0.875  0.625  0.250  1.0
  O  O36  1  0.375  0.625  0.750  1.0
  O  O37  1  0.544  0.809  0.266  1.0
[/CIF]
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