The material structure described by P2Te(N2O7)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one P2Te(N2O7)2 cluster. P(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one O(2) and one O(5) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one O(4) and one O(7) atom. Te(1) is bonded in an octahedral geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one P(1) and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one Te(1) atom. is represented by the CIF file [CIF]
data_TeP2(N2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.383
_cell_length_b   6.966
_cell_length_c   9.029
_cell_angle_alpha   97.242
_cell_angle_beta   99.090
_cell_angle_gamma   116.535
_symmetry_Int_Tables_number   1
_cell_volume   345.715
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.455  0.008  0.249  1.0
  P  P2  1  0.545  0.992  0.751  1.0
  N  N3  1  0.790  0.573  0.149  1.0
  N  N4  1  0.210  0.427  0.851  1.0
  N  N5  1  0.095  0.328  0.349  1.0
  N  N6  1  0.905  0.672  0.651  1.0
  O  O7  1  0.379  0.774  0.196  1.0
  O  O8  1  0.621  0.226  0.804  1.0
  O  O9  1  0.894  0.682  0.277  1.0
  O  O10  1  0.106  0.318  0.723  1.0
  O  O11  1  0.607  0.162  0.396  1.0
  O  O12  1  0.393  0.838  0.604  1.0
  O  O13  1  0.294  0.425  0.354  1.0
  O  O14  1  0.706  0.575  0.646  1.0
  O  O15  1  0.186  0.345  0.974  1.0
  O  O16  1  0.814  0.655  0.026  1.0
  O  O17  1  0.338  0.109  0.140  1.0
  O  O18  1  0.662  0.891  0.860  1.0
  O  O19  1  0.915  0.123  0.174  1.0
  O  O20  1  0.085  0.877  0.826  1.0
[/CIF]
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The material structure described by P2Te(N2O7)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one P2Te(N2O7)2 cluster. P(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one O(2) and one O(5) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one O(4) and one O(7) atom. Te(1) is bonded in an octahedral geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one P(1) and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one Te(1) atom. is represented by the CIF file [CIF]
data_TeP2(N2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.383
_cell_length_b   6.966
_cell_length_c   9.029
_cell_angle_alpha   97.242
_cell_angle_beta   99.090
_cell_angle_gamma   116.535
_symmetry_Int_Tables_number   1
_cell_volume   345.715
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.455  0.008  0.249  1.0
  P  P2  1  0.545  0.992  0.751  1.0
  N  N3  1  0.790  0.573  0.149  1.0
  N  N4  1  0.210  0.427  0.851  1.0
  N  N5  1  0.095  0.328  0.349  1.0
  N  N6  1  0.905  0.672  0.651  1.0
  O  O7  1  0.379  0.774  0.196  1.0
  O  O8  1  0.621  0.226  0.804  1.0
  O  O9  1  0.894  0.682  0.277  1.0
  O  O10  1  0.106  0.318  0.723  1.0
  O  O11  1  0.607  0.162  0.396  1.0
  O  O12  1  0.393  0.838  0.604  1.0
  O  O13  1  0.294  0.425  0.354  1.0
  O  O14  1  0.706  0.575  0.646  1.0
  O  O15  1  0.186  0.345  0.974  1.0
  O  O16  1  0.814  0.655  0.026  1.0
  O  O17  1  0.338  0.109  0.140  1.0
  O  O18  1  0.662  0.891  0.860  1.0
  O  O19  1  0.915  0.123  0.174  1.0
  O  O20  1  0.085  0.877  0.826  1.0
[/CIF]
.