The structure described by NaAgS2O3 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded to one O(3), two equivalent O(2), and three equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing NaO6 pentagonal pyramids. Ag(1) is bonded in a 4-coordinate geometry to three equivalent S(1) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(1) and one S(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one S(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to three equivalent Na(1) and one S(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Ag(1), and one S(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one S(2) atom. is represented by the CIF file [CIF]
data_NaAgS2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.241
_cell_length_b   8.573
_cell_length_c   9.421
_cell_angle_alpha   105.975
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   484.589
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.137  0.170  0.940  1.0
  Na  Na1  1  0.637  0.330  0.060  1.0
  Na  Na2  1  0.863  0.830  0.060  1.0
  Na  Na3  1  0.363  0.670  0.940  1.0
  Ag  Ag4  1  0.511  0.781  0.444  1.0
  Ag  Ag5  1  0.011  0.719  0.556  1.0
  Ag  Ag6  1  0.489  0.219  0.556  1.0
  Ag  Ag7  1  0.989  0.281  0.444  1.0
  S  S8  1  0.281  0.541  0.400  1.0
  S  S9  1  0.781  0.959  0.600  1.0
  S  S10  1  0.719  0.459  0.600  1.0
  S  S11  1  0.219  0.041  0.400  1.0
  S  S12  1  0.129  0.510  0.194  1.0
  S  S13  1  0.629  0.990  0.806  1.0
  S  S14  1  0.871  0.490  0.806  1.0
  S  S15  1  0.371  0.010  0.194  1.0
  O  O16  1  0.301  0.466  0.080  1.0
  O  O17  1  0.801  0.034  0.920  1.0
  O  O18  1  0.699  0.534  0.920  1.0
  O  O19  1  0.199  0.966  0.080  1.0
  O  O20  1  0.981  0.370  0.179  1.0
  O  O21  1  0.481  0.130  0.821  1.0
  O  O22  1  0.019  0.630  0.821  1.0
  O  O23  1  0.519  0.870  0.179  1.0
  O  O24  1  0.020  0.660  0.194  1.0
  O  O25  1  0.520  0.840  0.806  1.0
  O  O26  1  0.980  0.340  0.806  1.0
  O  O27  1  0.480  0.160  0.194  1.0
[/CIF]
.
The structure described by NaAgS2O3 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded to one O(3), two equivalent O(2), and three equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing NaO6 pentagonal pyramids. Ag(1) is bonded in a 4-coordinate geometry to three equivalent S(1) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(1) and one S(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one S(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to three equivalent Na(1) and one S(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Ag(1), and one S(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one S(2) atom. is represented by the CIF file [CIF]
data_NaAgS2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.241
_cell_length_b   8.573
_cell_length_c   9.421
_cell_angle_alpha   105.975
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   484.589
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.137  0.170  0.940  1.0
  Na  Na1  1  0.637  0.330  0.060  1.0
  Na  Na2  1  0.863  0.830  0.060  1.0
  Na  Na3  1  0.363  0.670  0.940  1.0
  Ag  Ag4  1  0.511  0.781  0.444  1.0
  Ag  Ag5  1  0.011  0.719  0.556  1.0
  Ag  Ag6  1  0.489  0.219  0.556  1.0
  Ag  Ag7  1  0.989  0.281  0.444  1.0
  S  S8  1  0.281  0.541  0.400  1.0
  S  S9  1  0.781  0.959  0.600  1.0
  S  S10  1  0.719  0.459  0.600  1.0
  S  S11  1  0.219  0.041  0.400  1.0
  S  S12  1  0.129  0.510  0.194  1.0
  S  S13  1  0.629  0.990  0.806  1.0
  S  S14  1  0.871  0.490  0.806  1.0
  S  S15  1  0.371  0.010  0.194  1.0
  O  O16  1  0.301  0.466  0.080  1.0
  O  O17  1  0.801  0.034  0.920  1.0
  O  O18  1  0.699  0.534  0.920  1.0
  O  O19  1  0.199  0.966  0.080  1.0
  O  O20  1  0.981  0.370  0.179  1.0
  O  O21  1  0.481  0.130  0.821  1.0
  O  O22  1  0.019  0.630  0.821  1.0
  O  O23  1  0.519  0.870  0.179  1.0
  O  O24  1  0.020  0.660  0.194  1.0
  O  O25  1  0.520  0.840  0.806  1.0
  O  O26  1  0.980  0.340  0.806  1.0
  O  O27  1  0.480  0.160  0.194  1.0
[/CIF]
.