The material structure described by V(OH)2 crystallizes in the orthorhombic Pnnm space group. V(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 51°. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent V(1) and one H(1) atom. is represented by the CIF card [CIF]
data_V(HO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.324
_cell_length_b   4.925
_cell_length_c   5.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   88.587
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.000  0.500  1.0
  V  V1  1  0.000  0.500  0.000  1.0
  H  H2  1  0.500  0.494  0.666  1.0
  H  H3  1  0.500  0.506  0.334  1.0
  H  H4  1  0.000  0.006  0.166  1.0
  H  H5  1  0.000  0.994  0.834  1.0
  O  O6  1  0.500  0.342  0.231  1.0
  O  O7  1  0.000  0.158  0.731  1.0
  O  O8  1  0.000  0.842  0.269  1.0
  O  O9  1  0.500  0.658  0.769  1.0
[/CIF]
.
The material structure described by V(OH)2 crystallizes in the orthorhombic Pnnm space group. V(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 51°. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent V(1) and one H(1) atom. is represented by the CIF card [CIF]
data_V(HO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.324
_cell_length_b   4.925
_cell_length_c   5.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   88.587
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.000  0.500  1.0
  V  V1  1  0.000  0.500  0.000  1.0
  H  H2  1  0.500  0.494  0.666  1.0
  H  H3  1  0.500  0.506  0.334  1.0
  H  H4  1  0.000  0.006  0.166  1.0
  H  H5  1  0.000  0.994  0.834  1.0
  O  O6  1  0.500  0.342  0.231  1.0
  O  O7  1  0.000  0.158  0.731  1.0
  O  O8  1  0.000  0.842  0.269  1.0
  O  O9  1  0.500  0.658  0.769  1.0
[/CIF]
.