The crystal structure described by Sr3Ca5Mn3Fe5O24 is (Cubic) Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(13), one O(14), one O(17), one O(19), one O(2), one O(21), one O(23), one O(3), one O(4), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, corners with four equivalent Ca(4)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(3)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(18), one O(2), one O(20), one O(22), one O(24), one O(3), one O(4), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ca(1)O12 cuboctahedra, corners with four equivalent Ca(3)O12 cuboctahedra, corners with four equivalent Ca(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(10), one O(13), one O(14), one O(18), one O(20), one O(22), one O(24), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, corners with four equivalent Ca(4)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Ca(3)O12 cuboctahedra, faces with two equivalent Ca(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. There are five inequivalent Ca sites. In the first Ca site, Ca(1) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(17), one O(19), one O(2), one O(21), one O(23), one O(3), and one O(4) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Ca(3)O12 cuboctahedra, corners with four equivalent Ca(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Ca(4)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the second Ca site, Ca(2) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(18), one O(2), one O(20), one O(22), one O(24), one O(3), and one O(4) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Ca(4)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the third Ca site, Ca(3) is bonded to one O(10), one O(13), one O(14), one O(17), one O(19), one O(21), one O(23), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Ca(1)O12 cuboctahedra, corners with four equivalent Ca(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(4)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the fourth Ca site, Ca(4) is bonded to one O(11), one O(12), one O(15), one O(16), one O(17), one O(19), one O(21), one O(23), one O(5), one O(6), one O(7), and one O(8) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(3)O12 cuboctahedra, faces with two equivalent Ca(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the fifth Ca site, Ca(5) is bonded to one O(11), one O(12), one O(15), one O(16), one O(18), one O(20), one O(22), one O(24), one O(5), one O(6), one O(7), and one O(8) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Ca(1)O12 cuboctahedra, corners with four equivalent Ca(3)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Ca(4)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(19), one O(20), one O(4), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second Mn site, Mn(2) is bonded to one O(14), one O(16), one O(2), one O(21), one O(22), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Mn site, Mn(3) is bonded to one O(14), one O(16), one O(23), one O(24), one O(4), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are five inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(11), one O(17), one O(18), one O(5), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Fe site, Fe(2) is bonded to one O(10), one O(12), one O(17), one O(18), one O(2), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Fe site, Fe(3) is bonded to one O(11), one O(19), one O(20), one O(3), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth Fe site, Fe(4) is bonded to one O(1), one O(13), one O(15), one O(21), one O(22), and one O(5) atom to form FeO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth Fe site, Fe(5) is bonded to one O(13), one O(15), one O(23), one O(24), one O(3), and one O(7) atom to form FeO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Fe(1), and one Fe(4) atom to form distorted OSr2Ca2Fe2 octahedra that share corners with two equivalent O(20)Sr2Ca2MnFe octahedra, corners with two equivalent O(24)Sr2Ca2MnFe octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra, corners with two equivalent O(10)Sr3CaMnFe octahedra, edges with two equivalent O(3)Sr2Ca2Fe2 octahedra, edges with two equivalent O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(18)Sr2Ca2Fe2 octahedra,  a faceface with one O(22)Sr2Ca2MnFe octahedra,  a faceface with one O(13)Sr3CaFe2 octahedra,  a faceface with one O(9)Sr3CaFe2 octahedra, and  a faceface with one O(17)SrCa3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 59-62°. In the second O site, O(2) is bonded to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(2), and one Fe(2) atom to form distorted OSr2Ca2MnFe octahedra that share corners with two equivalent O(20)Sr2Ca2MnFe octahedra, corners with two equivalent O(24)Sr2Ca2MnFe octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(9)Sr3CaFe2 octahedra, corners with four equivalent O(3)Sr2Ca2Fe2 octahedra, edges with two equivalent O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(18)Sr2Ca2Fe2 octahedra,  a faceface with one O(22)Sr2Ca2MnFe octahedra,  a faceface with one O(14)Sr3CaMn2 octahedra,  a faceface with one O(10)Sr3CaMnFe octahedra, and  a faceface with one O(17)SrCa3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the third O site, O(3) is bonded to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Fe(3), and one Fe(5) atom to form distorted OSr2Ca2Fe2 octahedra that share corners with two equivalent O(18)Sr2Ca2Fe2 octahedra, corners with two equivalent O(22)Sr2Ca2MnFe octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra, corners with two equivalent O(10)Sr3CaMnFe octahedra, corners with two equivalent O(17)SrCa3Fe2 octahedra, corners with four equivalent O(2)Sr2Ca2MnFe octahedra, edges with two equivalent O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(20)Sr2Ca2MnFe octahedra,  a faceface with one O(24)Sr2Ca2MnFe octahedra,  a faceface with one O(13)Sr3CaFe2 octahedra, and  a faceface with one O(9)Sr3CaFe2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(1), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(3), one Ca(3), one Ca(4), one Ca(5), one Fe(1), and one Fe(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(3), one Ca(3), one Ca(4), one Ca(5), one Mn(2), and one Fe(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sr(3), one Ca(3), one Ca(4), one Ca(5), one Fe(3), and one Fe(5) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sr(3), one Ca(3), one Ca(4), one Ca(5), one Mn(1), and one Mn(3) atom. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(3), one Fe(1), and one Fe(3) atom to form distorted OSr3CaFe2 octahedra that share corners with two equivalent O(2)Sr2Ca2MnFe octahedra, corners with two equivalent O(22)Sr2Ca2MnFe octahedra, corners with two equivalent O(24)Sr2Ca2MnFe octahedra, corners with four equivalent O(14)Sr3CaMn2 octahedra, edges with two equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(10)Sr3CaMnFe octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(18)Sr2Ca2Fe2 octahedra,  a faceface with one O(3)Sr2Ca2Fe2 octahedra,  a faceface with one O(20)Sr2Ca2MnFe octahedra, and  a faceface with one O(17)SrCa3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the tenth O site, O(10) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(3), one Mn(1), and one Fe(2) atom to form distorted OSr3CaMnFe octahedra that share corners with two equivalent O(1)Sr2Ca2Fe2 octahedra, corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(22)Sr2Ca2MnFe octahedra, corners with two equivalent O(24)Sr2Ca2MnFe octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(9)Sr3CaFe2 octahedra, edges with two equivalent O(14)Sr3CaMn2 octahedra,  a faceface with one O(18)Sr2Ca2Fe2 octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(20)Sr2Ca2MnFe octahedra, and  a faceface with one O(17)SrCa3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one Ca(1), one Ca(2), one Ca(4), one Ca(5), one Fe(1), and one Fe(3) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Ca(1), one Ca(2), one Ca(4), one Ca(5), one Mn(1), and one Fe(2) atom. In the thirteenth O site, O(13) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(3), one Fe(4), and one Fe(5) atom to form distorted OSr3CaFe2 octahedra that share corners with two equivalent O(18)Sr2Ca2Fe2 octahedra, corners with two equivalent O(2)Sr2Ca2MnFe octahedra, corners with two equivalent O(20)Sr2Ca2MnFe octahedra, corners with two equivalent O(17)SrCa3Fe2 octahedra, corners with four equivalent O(10)Sr3CaMnFe octahedra, edges with two equivalent O(9)Sr3CaFe2 octahedra, edges with two equivalent O(14)Sr3CaMn2 octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(3)Sr2Ca2Fe2 octahedra,  a faceface with one O(22)Sr2Ca2MnFe octahedra, and  a faceface with one O(24)Sr2Ca2MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fourteenth O site, O(14) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(3), one Mn(2), and one Mn(3) atom to form distorted OSr3CaMn2 octahedra that share corners with two equivalent O(1)Sr2Ca2Fe2 octahedra, corners with two equivalent O(18)Sr2Ca2Fe2 octahedra, corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(20)Sr2Ca2MnFe octahedra, corners with two equivalent O(17)SrCa3Fe2 octahedra, corners with four equivalent O(9)Sr3CaFe2 octahedra, edges with two equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(10)Sr3CaMnFe octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(22)Sr2Ca2MnFe octahedra, and  a faceface with one O(24)Sr2Ca2MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the fifteenth O site, O(15) is bonded in a distorted linear geometry to one Ca(1), one Ca(2), one Ca(4), one Ca(5), one Fe(4), and one Fe(5) atom. In the sixteenth O site, O(16) is bonded in a distorted linear geometry to one Ca(1), one Ca(2), one Ca(4), one Ca(5), one Mn(2), and one Mn(3) atom. In the seventeenth O site, O(17) is bonded to one Sr(1), one Ca(1), one Ca(3), one Ca(4), one Fe(1), and one Fe(2) atom to form distorted OSrCa3Fe2 octahedra that share corners with two equivalent O(18)Sr2Ca2Fe2 octahedra, corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(9)Sr3CaFe2 octahedra, and  a faceface with one O(10)Sr3CaMnFe octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the eighteenth O site, O(18) is bonded to one Sr(2), one Sr(3), one Ca(2), one Ca(5), one Fe(1), and one Fe(2) atom to form distorted OSr2Ca2Fe2 octahedra that share corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra, corners with two equivalent O(17)SrCa3Fe2 octahedra, corners with four equivalent O(24)Sr2Ca2MnFe octahedra, edges with two equivalent O(20)Sr2Ca2MnFe octahedra, edges with two equivalent O(22)Sr2Ca2MnFe octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(9)Sr3CaFe2 octahedra, and  a faceface with one O(10)Sr3CaMnFe octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one Sr(1), one Ca(1), one Ca(3), one Ca(4), one Mn(1), and one Fe(3) atom. In the twentieth O site, O(20) is bonded to one Sr(2), one Sr(3), one Ca(2), one Ca(5), one Mn(1), and one Fe(3) atom to form distorted OSr2Ca2MnFe octahedra that share corners with two equivalent O(1)Sr2Ca2Fe2 octahedra, corners with two equivalent O(2)Sr2Ca2MnFe octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra, corners with four equivalent O(22)Sr2Ca2MnFe octahedra, edges with two equivalent O(18)Sr2Ca2Fe2 octahedra, edges with two equivalent O(24)Sr2Ca2MnFe octahedra,  a faceface with one O(3)Sr2Ca2Fe2 octahedra,  a faceface with one O(9)Sr3CaFe2 octahedra, and  a faceface with one O(10)Sr3CaMnFe octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Sr(1), one Ca(1), one Ca(3), one Ca(4), one Mn(2), and one Fe(4) atom. In the twenty-second O site, O(22) is bonded to one Sr(2), one Sr(3), one Ca(2), one Ca(5), one Mn(2), and one Fe(4) atom to form distorted OSr2Ca2MnFe octahedra that share corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(9)Sr3CaFe2 octahedra, corners with two equivalent O(10)Sr3CaMnFe octahedra, corners with four equivalent O(20)Sr2Ca2MnFe octahedra, edges with two equivalent O(18)Sr2Ca2Fe2 octahedra, edges with two equivalent O(24)Sr2Ca2MnFe octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(13)Sr3CaFe2 octahedra, and  a faceface with one O(14)Sr3CaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the twenty-third O site, O(23) is bonded in a distorted linear geometry to one Sr(1), one Ca(1), one Ca(3), one Ca(4), one Mn(3), and one Fe(5) atom. In the twenty-fourth O site, O(24) is bonded to one Sr(2), one Sr(3), one Ca(2), one Ca(5), one Mn(3), and one Fe(5) atom to form distorted OSr2Ca2MnFe octahedra that share corners with two equivalent O(1)Sr2Ca2Fe2 octahedra, corners with two equivalent O(2)Sr2Ca2MnFe octahedra, corners with two equivalent O(9)Sr3CaFe2 octahedra, corners with two equivalent O(10)Sr3CaMnFe octahedra, corners with four equivalent O(18)Sr2Ca2Fe2 octahedra, edges with two equivalent O(20)Sr2Ca2MnFe octahedra, edges with two equivalent O(22)Sr2Ca2MnFe octahedra,  a faceface with one O(3)Sr2Ca2Fe2 octahedra,  a faceface with one O(13)Sr3CaFe2 octahedra, and  a faceface with one O(14)Sr3CaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. is represented by the CIF card [CIF]
data_Sr3Ca5Mn3Fe5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.711
_cell_length_b   7.715
_cell_length_c   7.753
_cell_angle_alpha   90.030
_cell_angle_beta   90.034
_cell_angle_gamma   90.015
_symmetry_Int_Tables_number   1
_cell_volume   461.241
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.250  0.750  0.251  1.0
  Sr  Sr1  1  0.250  0.750  0.749  1.0
  Sr  Sr2  1  0.250  0.250  0.749  1.0
  Ca  Ca3  1  0.750  0.750  0.252  1.0
  Ca  Ca4  1  0.750  0.750  0.748  1.0
  Ca  Ca5  1  0.250  0.250  0.252  1.0
  Ca  Ca6  1  0.750  0.250  0.252  1.0
  Ca  Ca7  1  0.750  0.250  0.748  1.0
  Mn  Mn8  1  0.502  0.001  0.499  1.0
  Mn  Mn9  1  0.997  0.499  0.499  1.0
  Mn  Mn10  1  0.502  0.499  0.499  1.0
  Fe  Fe11  1  0.997  0.001  0.001  1.0
  Fe  Fe12  1  0.997  0.001  0.499  1.0
  Fe  Fe13  1  0.502  0.001  0.001  1.0
  Fe  Fe14  1  0.998  0.499  0.001  1.0
  Fe  Fe15  1  0.502  0.499  0.001  1.0
  O  O16  1  0.993  0.752  0.001  1.0
  O  O17  1  0.992  0.746  0.499  1.0
  O  O18  1  0.507  0.749  0.001  1.0
  O  O19  1  0.509  0.749  0.499  1.0
  O  O20  1  0.995  0.248  0.003  1.0
  O  O21  1  0.995  0.254  0.497  1.0
  O  O22  1  0.505  0.250  0.003  1.0
  O  O23  1  0.505  0.251  0.496  1.0
  O  O24  1  0.248  0.003  0.003  1.0
  O  O25  1  0.254  0.003  0.497  1.0
  O  O26  1  0.751  0.001  0.001  1.0
  O  O27  1  0.746  0.001  0.499  1.0
  O  O28  1  0.251  0.497  0.003  1.0
  O  O29  1  0.251  0.496  0.496  1.0
  O  O30  1  0.750  0.499  0.001  1.0
  O  O31  1  0.749  0.499  0.499  1.0
  O  O32  1  0.995  0.003  0.248  1.0
  O  O33  1  0.992  0.001  0.753  1.0
  O  O34  1  0.505  0.003  0.253  1.0
  O  O35  1  0.508  0.001  0.747  1.0
  O  O36  1  0.995  0.497  0.253  1.0
  O  O37  1  0.992  0.499  0.747  1.0
  O  O38  1  0.505  0.497  0.253  1.0
  O  O39  1  0.508  0.499  0.747  1.0
[/CIF]
.
The crystal structure described by Sr3Ca5Mn3Fe5O24 is (Cubic) Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(13), one O(14), one O(17), one O(19), one O(2), one O(21), one O(23), one O(3), one O(4), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, corners with four equivalent Ca(4)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(3)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(18), one O(2), one O(20), one O(22), one O(24), one O(3), one O(4), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Ca(1)O12 cuboctahedra, corners with four equivalent Ca(3)O12 cuboctahedra, corners with four equivalent Ca(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(10), one O(13), one O(14), one O(18), one O(20), one O(22), one O(24), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, corners with four equivalent Ca(4)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Ca(3)O12 cuboctahedra, faces with two equivalent Ca(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. There are five inequivalent Ca sites. In the first Ca site, Ca(1) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(17), one O(19), one O(2), one O(21), one O(23), one O(3), and one O(4) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Ca(3)O12 cuboctahedra, corners with four equivalent Ca(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Ca(4)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the second Ca site, Ca(2) is bonded to one O(1), one O(11), one O(12), one O(15), one O(16), one O(18), one O(2), one O(20), one O(22), one O(24), one O(3), and one O(4) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Ca(4)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the third Ca site, Ca(3) is bonded to one O(10), one O(13), one O(14), one O(17), one O(19), one O(21), one O(23), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Ca(1)O12 cuboctahedra, corners with four equivalent Ca(5)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(4)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the fourth Ca site, Ca(4) is bonded to one O(11), one O(12), one O(15), one O(16), one O(17), one O(19), one O(21), one O(23), one O(5), one O(6), one O(7), and one O(8) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(3)O12 cuboctahedra, faces with two equivalent Ca(5)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. In the fifth Ca site, Ca(5) is bonded to one O(11), one O(12), one O(15), one O(16), one O(18), one O(20), one O(22), one O(24), one O(5), one O(6), one O(7), and one O(8) atom to form CaO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Ca(1)O12 cuboctahedra, corners with four equivalent Ca(3)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Ca(4)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Fe(4)O6 octahedra, and  a faceface with one Fe(5)O6 octahedra. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(19), one O(20), one O(4), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second Mn site, Mn(2) is bonded to one O(14), one O(16), one O(2), one O(21), one O(22), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Mn site, Mn(3) is bonded to one O(14), one O(16), one O(23), one O(24), one O(4), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are five inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(11), one O(17), one O(18), one O(5), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Fe site, Fe(2) is bonded to one O(10), one O(12), one O(17), one O(18), one O(2), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Fe site, Fe(3) is bonded to one O(11), one O(19), one O(20), one O(3), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth Fe site, Fe(4) is bonded to one O(1), one O(13), one O(15), one O(21), one O(22), and one O(5) atom to form FeO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth Fe site, Fe(5) is bonded to one O(13), one O(15), one O(23), one O(24), one O(3), and one O(7) atom to form FeO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Fe(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Ca(1)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra,  a faceface with one Ca(3)O12 cuboctahedra,  a faceface with one Ca(4)O12 cuboctahedra, and  a faceface with one Ca(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Fe(1), and one Fe(4) atom to form distorted OSr2Ca2Fe2 octahedra that share corners with two equivalent O(20)Sr2Ca2MnFe octahedra, corners with two equivalent O(24)Sr2Ca2MnFe octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra, corners with two equivalent O(10)Sr3CaMnFe octahedra, edges with two equivalent O(3)Sr2Ca2Fe2 octahedra, edges with two equivalent O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(18)Sr2Ca2Fe2 octahedra,  a faceface with one O(22)Sr2Ca2MnFe octahedra,  a faceface with one O(13)Sr3CaFe2 octahedra,  a faceface with one O(9)Sr3CaFe2 octahedra, and  a faceface with one O(17)SrCa3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 59-62°. In the second O site, O(2) is bonded to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(2), and one Fe(2) atom to form distorted OSr2Ca2MnFe octahedra that share corners with two equivalent O(20)Sr2Ca2MnFe octahedra, corners with two equivalent O(24)Sr2Ca2MnFe octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(9)Sr3CaFe2 octahedra, corners with four equivalent O(3)Sr2Ca2Fe2 octahedra, edges with two equivalent O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(18)Sr2Ca2Fe2 octahedra,  a faceface with one O(22)Sr2Ca2MnFe octahedra,  a faceface with one O(14)Sr3CaMn2 octahedra,  a faceface with one O(10)Sr3CaMnFe octahedra, and  a faceface with one O(17)SrCa3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the third O site, O(3) is bonded to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Fe(3), and one Fe(5) atom to form distorted OSr2Ca2Fe2 octahedra that share corners with two equivalent O(18)Sr2Ca2Fe2 octahedra, corners with two equivalent O(22)Sr2Ca2MnFe octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra, corners with two equivalent O(10)Sr3CaMnFe octahedra, corners with two equivalent O(17)SrCa3Fe2 octahedra, corners with four equivalent O(2)Sr2Ca2MnFe octahedra, edges with two equivalent O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(20)Sr2Ca2MnFe octahedra,  a faceface with one O(24)Sr2Ca2MnFe octahedra,  a faceface with one O(13)Sr3CaFe2 octahedra, and  a faceface with one O(9)Sr3CaFe2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(1), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(3), one Ca(3), one Ca(4), one Ca(5), one Fe(1), and one Fe(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(3), one Ca(3), one Ca(4), one Ca(5), one Mn(2), and one Fe(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sr(3), one Ca(3), one Ca(4), one Ca(5), one Fe(3), and one Fe(5) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sr(3), one Ca(3), one Ca(4), one Ca(5), one Mn(1), and one Mn(3) atom. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(3), one Fe(1), and one Fe(3) atom to form distorted OSr3CaFe2 octahedra that share corners with two equivalent O(2)Sr2Ca2MnFe octahedra, corners with two equivalent O(22)Sr2Ca2MnFe octahedra, corners with two equivalent O(24)Sr2Ca2MnFe octahedra, corners with four equivalent O(14)Sr3CaMn2 octahedra, edges with two equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(10)Sr3CaMnFe octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(18)Sr2Ca2Fe2 octahedra,  a faceface with one O(3)Sr2Ca2Fe2 octahedra,  a faceface with one O(20)Sr2Ca2MnFe octahedra, and  a faceface with one O(17)SrCa3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the tenth O site, O(10) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(3), one Mn(1), and one Fe(2) atom to form distorted OSr3CaMnFe octahedra that share corners with two equivalent O(1)Sr2Ca2Fe2 octahedra, corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(22)Sr2Ca2MnFe octahedra, corners with two equivalent O(24)Sr2Ca2MnFe octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(9)Sr3CaFe2 octahedra, edges with two equivalent O(14)Sr3CaMn2 octahedra,  a faceface with one O(18)Sr2Ca2Fe2 octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(20)Sr2Ca2MnFe octahedra, and  a faceface with one O(17)SrCa3Fe2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one Ca(1), one Ca(2), one Ca(4), one Ca(5), one Fe(1), and one Fe(3) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Ca(1), one Ca(2), one Ca(4), one Ca(5), one Mn(1), and one Fe(2) atom. In the thirteenth O site, O(13) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(3), one Fe(4), and one Fe(5) atom to form distorted OSr3CaFe2 octahedra that share corners with two equivalent O(18)Sr2Ca2Fe2 octahedra, corners with two equivalent O(2)Sr2Ca2MnFe octahedra, corners with two equivalent O(20)Sr2Ca2MnFe octahedra, corners with two equivalent O(17)SrCa3Fe2 octahedra, corners with four equivalent O(10)Sr3CaMnFe octahedra, edges with two equivalent O(9)Sr3CaFe2 octahedra, edges with two equivalent O(14)Sr3CaMn2 octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(3)Sr2Ca2Fe2 octahedra,  a faceface with one O(22)Sr2Ca2MnFe octahedra, and  a faceface with one O(24)Sr2Ca2MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fourteenth O site, O(14) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(3), one Mn(2), and one Mn(3) atom to form distorted OSr3CaMn2 octahedra that share corners with two equivalent O(1)Sr2Ca2Fe2 octahedra, corners with two equivalent O(18)Sr2Ca2Fe2 octahedra, corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(20)Sr2Ca2MnFe octahedra, corners with two equivalent O(17)SrCa3Fe2 octahedra, corners with four equivalent O(9)Sr3CaFe2 octahedra, edges with two equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(10)Sr3CaMnFe octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(22)Sr2Ca2MnFe octahedra, and  a faceface with one O(24)Sr2Ca2MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the fifteenth O site, O(15) is bonded in a distorted linear geometry to one Ca(1), one Ca(2), one Ca(4), one Ca(5), one Fe(4), and one Fe(5) atom. In the sixteenth O site, O(16) is bonded in a distorted linear geometry to one Ca(1), one Ca(2), one Ca(4), one Ca(5), one Mn(2), and one Mn(3) atom. In the seventeenth O site, O(17) is bonded to one Sr(1), one Ca(1), one Ca(3), one Ca(4), one Fe(1), and one Fe(2) atom to form distorted OSrCa3Fe2 octahedra that share corners with two equivalent O(18)Sr2Ca2Fe2 octahedra, corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(9)Sr3CaFe2 octahedra, and  a faceface with one O(10)Sr3CaMnFe octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the eighteenth O site, O(18) is bonded to one Sr(2), one Sr(3), one Ca(2), one Ca(5), one Fe(1), and one Fe(2) atom to form distorted OSr2Ca2Fe2 octahedra that share corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra, corners with two equivalent O(17)SrCa3Fe2 octahedra, corners with four equivalent O(24)Sr2Ca2MnFe octahedra, edges with two equivalent O(20)Sr2Ca2MnFe octahedra, edges with two equivalent O(22)Sr2Ca2MnFe octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(9)Sr3CaFe2 octahedra, and  a faceface with one O(10)Sr3CaMnFe octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one Sr(1), one Ca(1), one Ca(3), one Ca(4), one Mn(1), and one Fe(3) atom. In the twentieth O site, O(20) is bonded to one Sr(2), one Sr(3), one Ca(2), one Ca(5), one Mn(1), and one Fe(3) atom to form distorted OSr2Ca2MnFe octahedra that share corners with two equivalent O(1)Sr2Ca2Fe2 octahedra, corners with two equivalent O(2)Sr2Ca2MnFe octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(14)Sr3CaMn2 octahedra, corners with four equivalent O(22)Sr2Ca2MnFe octahedra, edges with two equivalent O(18)Sr2Ca2Fe2 octahedra, edges with two equivalent O(24)Sr2Ca2MnFe octahedra,  a faceface with one O(3)Sr2Ca2Fe2 octahedra,  a faceface with one O(9)Sr3CaFe2 octahedra, and  a faceface with one O(10)Sr3CaMnFe octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Sr(1), one Ca(1), one Ca(3), one Ca(4), one Mn(2), and one Fe(4) atom. In the twenty-second O site, O(22) is bonded to one Sr(2), one Sr(3), one Ca(2), one Ca(5), one Mn(2), and one Fe(4) atom to form distorted OSr2Ca2MnFe octahedra that share corners with two equivalent O(3)Sr2Ca2Fe2 octahedra, corners with two equivalent O(9)Sr3CaFe2 octahedra, corners with two equivalent O(10)Sr3CaMnFe octahedra, corners with four equivalent O(20)Sr2Ca2MnFe octahedra, edges with two equivalent O(18)Sr2Ca2Fe2 octahedra, edges with two equivalent O(24)Sr2Ca2MnFe octahedra,  a faceface with one O(1)Sr2Ca2Fe2 octahedra,  a faceface with one O(2)Sr2Ca2MnFe octahedra,  a faceface with one O(13)Sr3CaFe2 octahedra, and  a faceface with one O(14)Sr3CaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the twenty-third O site, O(23) is bonded in a distorted linear geometry to one Sr(1), one Ca(1), one Ca(3), one Ca(4), one Mn(3), and one Fe(5) atom. In the twenty-fourth O site, O(24) is bonded to one Sr(2), one Sr(3), one Ca(2), one Ca(5), one Mn(3), and one Fe(5) atom to form distorted OSr2Ca2MnFe octahedra that share corners with two equivalent O(1)Sr2Ca2Fe2 octahedra, corners with two equivalent O(2)Sr2Ca2MnFe octahedra, corners with two equivalent O(9)Sr3CaFe2 octahedra, corners with two equivalent O(10)Sr3CaMnFe octahedra, corners with four equivalent O(18)Sr2Ca2Fe2 octahedra, edges with two equivalent O(20)Sr2Ca2MnFe octahedra, edges with two equivalent O(22)Sr2Ca2MnFe octahedra,  a faceface with one O(3)Sr2Ca2Fe2 octahedra,  a faceface with one O(13)Sr3CaFe2 octahedra, and  a faceface with one O(14)Sr3CaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. is represented by the CIF card [CIF]
data_Sr3Ca5Mn3Fe5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.711
_cell_length_b   7.715
_cell_length_c   7.753
_cell_angle_alpha   90.030
_cell_angle_beta   90.034
_cell_angle_gamma   90.015
_symmetry_Int_Tables_number   1
_cell_volume   461.241
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.250  0.750  0.251  1.0
  Sr  Sr1  1  0.250  0.750  0.749  1.0
  Sr  Sr2  1  0.250  0.250  0.749  1.0
  Ca  Ca3  1  0.750  0.750  0.252  1.0
  Ca  Ca4  1  0.750  0.750  0.748  1.0
  Ca  Ca5  1  0.250  0.250  0.252  1.0
  Ca  Ca6  1  0.750  0.250  0.252  1.0
  Ca  Ca7  1  0.750  0.250  0.748  1.0
  Mn  Mn8  1  0.502  0.001  0.499  1.0
  Mn  Mn9  1  0.997  0.499  0.499  1.0
  Mn  Mn10  1  0.502  0.499  0.499  1.0
  Fe  Fe11  1  0.997  0.001  0.001  1.0
  Fe  Fe12  1  0.997  0.001  0.499  1.0
  Fe  Fe13  1  0.502  0.001  0.001  1.0
  Fe  Fe14  1  0.998  0.499  0.001  1.0
  Fe  Fe15  1  0.502  0.499  0.001  1.0
  O  O16  1  0.993  0.752  0.001  1.0
  O  O17  1  0.992  0.746  0.499  1.0
  O  O18  1  0.507  0.749  0.001  1.0
  O  O19  1  0.509  0.749  0.499  1.0
  O  O20  1  0.995  0.248  0.003  1.0
  O  O21  1  0.995  0.254  0.497  1.0
  O  O22  1  0.505  0.250  0.003  1.0
  O  O23  1  0.505  0.251  0.496  1.0
  O  O24  1  0.248  0.003  0.003  1.0
  O  O25  1  0.254  0.003  0.497  1.0
  O  O26  1  0.751  0.001  0.001  1.0
  O  O27  1  0.746  0.001  0.499  1.0
  O  O28  1  0.251  0.497  0.003  1.0
  O  O29  1  0.251  0.496  0.496  1.0
  O  O30  1  0.750  0.499  0.001  1.0
  O  O31  1  0.749  0.499  0.499  1.0
  O  O32  1  0.995  0.003  0.248  1.0
  O  O33  1  0.992  0.001  0.753  1.0
  O  O34  1  0.505  0.003  0.253  1.0
  O  O35  1  0.508  0.001  0.747  1.0
  O  O36  1  0.995  0.497  0.253  1.0
  O  O37  1  0.992  0.499  0.747  1.0
  O  O38  1  0.505  0.497  0.253  1.0
  O  O39  1  0.508  0.499  0.747  1.0
[/CIF]
.