The structure described by TmMoO4F crystallizes in the monoclinic P2_1/c space group. Tm(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Tm(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Tm(1) and one Mo(1) atom. F(1) is bonded in a distorted water-like geometry to two equivalent Tm(1) atoms. is represented by the CIF file [CIF]
data_TmMoO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.324
_cell_length_b   5.215
_cell_length_c   6.648
_cell_angle_alpha   66.660
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   392.311
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.050  0.361  0.801  1.0
  Tm  Tm1  1  0.950  0.639  0.199  1.0
  Tm  Tm2  1  0.550  0.639  0.699  1.0
  Tm  Tm3  1  0.450  0.361  0.301  1.0
  Mo  Mo4  1  0.856  0.921  0.630  1.0
  Mo  Mo5  1  0.644  0.921  0.130  1.0
  Mo  Mo6  1  0.356  0.079  0.870  1.0
  Mo  Mo7  1  0.144  0.079  0.370  1.0
  O  O8  1  0.069  0.001  0.160  1.0
  O  O9  1  0.564  0.689  0.037  1.0
  O  O10  1  0.347  0.758  0.096  1.0
  O  O11  1  0.279  0.194  0.295  1.0
  O  O12  1  0.653  0.242  0.904  1.0
  O  O13  1  0.779  0.806  0.205  1.0
  O  O14  1  0.569  0.999  0.340  1.0
  O  O15  1  0.436  0.311  0.963  1.0
  O  O16  1  0.931  0.999  0.840  1.0
  O  O17  1  0.721  0.806  0.705  1.0
  O  O18  1  0.064  0.311  0.463  1.0
  O  O19  1  0.221  0.194  0.795  1.0
  O  O20  1  0.153  0.758  0.596  1.0
  O  O21  1  0.936  0.689  0.537  1.0
  O  O22  1  0.431  0.001  0.660  1.0
  O  O23  1  0.847  0.242  0.404  1.0
  F  F24  1  0.097  0.543  0.036  1.0
  F  F25  1  0.403  0.543  0.536  1.0
  F  F26  1  0.597  0.457  0.464  1.0
  F  F27  1  0.903  0.457  0.964  1.0
[/CIF]
.
The structure described by TmMoO4F crystallizes in the monoclinic P2_1/c space group. Tm(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Tm(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Tm(1) and one Mo(1) atom. F(1) is bonded in a distorted water-like geometry to two equivalent Tm(1) atoms. is represented by the CIF file [CIF]
data_TmMoO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.324
_cell_length_b   5.215
_cell_length_c   6.648
_cell_angle_alpha   66.660
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   392.311
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.050  0.361  0.801  1.0
  Tm  Tm1  1  0.950  0.639  0.199  1.0
  Tm  Tm2  1  0.550  0.639  0.699  1.0
  Tm  Tm3  1  0.450  0.361  0.301  1.0
  Mo  Mo4  1  0.856  0.921  0.630  1.0
  Mo  Mo5  1  0.644  0.921  0.130  1.0
  Mo  Mo6  1  0.356  0.079  0.870  1.0
  Mo  Mo7  1  0.144  0.079  0.370  1.0
  O  O8  1  0.069  0.001  0.160  1.0
  O  O9  1  0.564  0.689  0.037  1.0
  O  O10  1  0.347  0.758  0.096  1.0
  O  O11  1  0.279  0.194  0.295  1.0
  O  O12  1  0.653  0.242  0.904  1.0
  O  O13  1  0.779  0.806  0.205  1.0
  O  O14  1  0.569  0.999  0.340  1.0
  O  O15  1  0.436  0.311  0.963  1.0
  O  O16  1  0.931  0.999  0.840  1.0
  O  O17  1  0.721  0.806  0.705  1.0
  O  O18  1  0.064  0.311  0.463  1.0
  O  O19  1  0.221  0.194  0.795  1.0
  O  O20  1  0.153  0.758  0.596  1.0
  O  O21  1  0.936  0.689  0.537  1.0
  O  O22  1  0.431  0.001  0.660  1.0
  O  O23  1  0.847  0.242  0.404  1.0
  F  F24  1  0.097  0.543  0.036  1.0
  F  F25  1  0.403  0.543  0.536  1.0
  F  F26  1  0.597  0.457  0.464  1.0
  F  F27  1  0.903  0.457  0.964  1.0
[/CIF]
.