The structure described by Li4Mn3OF11 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted octahedral geometry to one F(1), one F(10), one F(11), one F(2), one F(4), and one F(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(3), one F(6), one F(7), and one F(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one F(10), one F(4), one F(5), one F(6), one F(7), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one F(10), one F(11), one F(2), one F(3), one F(6), and one F(8) atom. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(10), one F(3), one F(5), and one F(8) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. In the third Mn site, Mn(3) is bonded in a 6-coordinate geometry to one O(1), one F(11), one F(4), one F(5), one F(8), and one F(9) atom. O(1) is bonded to one Li(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLiMn3 trigonal pyramids that share corners with two equivalent F(4)Li2Mn2 trigonal pyramids and  an edgeedge with one F(7)Li3Mn tetrahedra. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(2), and one Mn(1) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Li(1), one Li(4), and one Mn(2) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(2), one Li(4), and one Mn(1) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(3), one Mn(2), and one Mn(3) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(7)Li3Mn tetrahedra, corners with two equivalent O(1)LiMn3 trigonal pyramids, and  an edgeedge with one F(7)Li3Mn tetrahedra. In the fifth F site, F(5) is bonded in a 4-coordinate geometry to one Li(3), one Mn(1), one Mn(2), and one Mn(3) atom. In the sixth F site, F(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Li(4), and one Mn(2) atom. In the seventh F site, F(7) is bonded to one Li(1), one Li(2), one Li(3), and one Mn(2) atom to form distorted FLi3Mn tetrahedra that share  a cornercorner with one F(4)Li2Mn2 trigonal pyramid,  an edgeedge with one O(1)LiMn3 trigonal pyramid, and  an edgeedge with one F(4)Li2Mn2 trigonal pyramid. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Li(4), one Mn(1), and one Mn(3) atom. In the ninth F site, F(9) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one Li(3), and one Mn(3) atom. In the tenth F site, F(10) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Li(4), and one Mn(1) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Li(1), one Li(4), and one Mn(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Mn3OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.780
_cell_length_b   6.119
_cell_length_c   6.162
_cell_angle_alpha   98.594
_cell_angle_beta   98.495
_cell_angle_gamma   97.580
_symmetry_Int_Tables_number   1
_cell_volume   210.465
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.990  0.997  0.022  1.0
  Li  Li1  1  0.122  0.602  0.326  1.0
  Li  Li2  1  0.293  0.094  0.607  1.0
  Li  Li3  1  0.418  0.728  0.863  1.0
  Mn  Mn4  1  0.596  0.363  0.151  1.0
  Mn  Mn5  1  0.713  0.865  0.406  1.0
  Mn  Mn6  1  0.897  0.418  0.683  1.0
  O  O7  1  0.776  0.572  0.406  1.0
  F  F8  1  0.903  0.297  0.112  1.0
  F  F9  1  0.688  0.845  0.077  1.0
  F  F10  1  0.352  0.543  0.147  1.0
  F  F11  1  0.899  0.102  0.712  1.0
  F  F12  1  0.594  0.152  0.397  1.0
  F  F13  1  0.460  0.817  0.580  1.0
  F  F14  1  0.065  0.925  0.352  1.0
  F  F15  1  0.625  0.449  0.804  1.0
  F  F16  1  0.171  0.391  0.562  1.0
  F  F17  1  0.375  0.129  0.953  1.0
  F  F18  1  0.062  0.710  0.839  1.0
[/CIF]
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The structure described by Li4Mn3OF11 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted octahedral geometry to one F(1), one F(10), one F(11), one F(2), one F(4), and one F(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(3), one F(6), one F(7), and one F(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one F(10), one F(4), one F(5), one F(6), one F(7), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one F(10), one F(11), one F(2), one F(3), one F(6), and one F(8) atom. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(10), one F(3), one F(5), and one F(8) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. In the third Mn site, Mn(3) is bonded in a 6-coordinate geometry to one O(1), one F(11), one F(4), one F(5), one F(8), and one F(9) atom. O(1) is bonded to one Li(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLiMn3 trigonal pyramids that share corners with two equivalent F(4)Li2Mn2 trigonal pyramids and  an edgeedge with one F(7)Li3Mn tetrahedra. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(2), and one Mn(1) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Li(1), one Li(4), and one Mn(2) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(2), one Li(4), and one Mn(1) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(3), one Mn(2), and one Mn(3) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(7)Li3Mn tetrahedra, corners with two equivalent O(1)LiMn3 trigonal pyramids, and  an edgeedge with one F(7)Li3Mn tetrahedra. In the fifth F site, F(5) is bonded in a 4-coordinate geometry to one Li(3), one Mn(1), one Mn(2), and one Mn(3) atom. In the sixth F site, F(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Li(4), and one Mn(2) atom. In the seventh F site, F(7) is bonded to one Li(1), one Li(2), one Li(3), and one Mn(2) atom to form distorted FLi3Mn tetrahedra that share  a cornercorner with one F(4)Li2Mn2 trigonal pyramid,  an edgeedge with one O(1)LiMn3 trigonal pyramid, and  an edgeedge with one F(4)Li2Mn2 trigonal pyramid. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Li(4), one Mn(1), and one Mn(3) atom. In the ninth F site, F(9) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one Li(3), and one Mn(3) atom. In the tenth F site, F(10) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Li(4), and one Mn(1) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Li(1), one Li(4), and one Mn(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Mn3OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.780
_cell_length_b   6.119
_cell_length_c   6.162
_cell_angle_alpha   98.594
_cell_angle_beta   98.495
_cell_angle_gamma   97.580
_symmetry_Int_Tables_number   1
_cell_volume   210.465
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.990  0.997  0.022  1.0
  Li  Li1  1  0.122  0.602  0.326  1.0
  Li  Li2  1  0.293  0.094  0.607  1.0
  Li  Li3  1  0.418  0.728  0.863  1.0
  Mn  Mn4  1  0.596  0.363  0.151  1.0
  Mn  Mn5  1  0.713  0.865  0.406  1.0
  Mn  Mn6  1  0.897  0.418  0.683  1.0
  O  O7  1  0.776  0.572  0.406  1.0
  F  F8  1  0.903  0.297  0.112  1.0
  F  F9  1  0.688  0.845  0.077  1.0
  F  F10  1  0.352  0.543  0.147  1.0
  F  F11  1  0.899  0.102  0.712  1.0
  F  F12  1  0.594  0.152  0.397  1.0
  F  F13  1  0.460  0.817  0.580  1.0
  F  F14  1  0.065  0.925  0.352  1.0
  F  F15  1  0.625  0.449  0.804  1.0
  F  F16  1  0.171  0.391  0.562  1.0
  F  F17  1  0.375  0.129  0.953  1.0
  F  F18  1  0.062  0.710  0.839  1.0
[/CIF]
.