The crystal structure described by CsVSO6 crystallizes in the orthorhombic Pbca space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(4), two equivalent O(3), two equivalent O(6), and three equivalent O(5) atoms. V(1) is bonded to one O(1), one O(4), one O(6), and two equivalent O(2) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent V(1)O5 trigonal bipyramids. S(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form SO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to two equivalent Cs(1) and one V(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1) and two equivalent V(1) atoms. In the fifth O site, O(3) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one S(1) atom. is represented by the CIF file [CIF]
data_CsVSO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.436
_cell_length_b   6.691
_cell_length_c   17.876
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   650.152
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.042  0.250  0.589  1.0
  Cs  Cs1  1  0.042  0.750  0.911  1.0
  Cs  Cs2  1  0.958  0.750  0.411  1.0
  Cs  Cs3  1  0.958  0.250  0.089  1.0
  O  O4  1  0.516  0.566  0.144  1.0
  O  O5  1  0.437  0.250  0.727  1.0
  O  O6  1  0.563  0.250  0.227  1.0
  O  O7  1  0.587  0.750  0.029  1.0
  O  O8  1  0.516  0.066  0.356  1.0
  O  O9  1  0.413  0.750  0.529  1.0
  O  O10  1  0.563  0.750  0.273  1.0
  O  O11  1  0.413  0.250  0.971  1.0
  O  O12  1  0.825  0.750  0.586  1.0
  O  O13  1  0.587  0.250  0.471  1.0
  O  O14  1  0.150  0.500  0.250  1.0
  O  O15  1  0.437  0.750  0.773  1.0
  O  O16  1  0.150  0.000  0.250  1.0
  O  O17  1  0.484  0.934  0.644  1.0
  O  O18  1  0.850  0.500  0.750  1.0
  O  O19  1  0.825  0.250  0.914  1.0
  O  O20  1  0.516  0.434  0.356  1.0
  O  O21  1  0.850  0.000  0.750  1.0
  O  O22  1  0.516  0.934  0.144  1.0
  O  O23  1  0.484  0.066  0.856  1.0
  O  O24  1  0.175  0.250  0.414  1.0
  O  O25  1  0.484  0.434  0.856  1.0
  O  O26  1  0.175  0.750  0.086  1.0
  O  O27  1  0.484  0.566  0.644  1.0
  S  S28  1  0.559  0.750  0.597  1.0
  S  S29  1  0.441  0.750  0.097  1.0
  S  S30  1  0.441  0.250  0.403  1.0
  S  S31  1  0.559  0.250  0.903  1.0
  V  V32  1  0.552  0.000  0.750  1.0
  V  V33  1  0.552  0.500  0.750  1.0
  V  V34  1  0.448  1.000  0.250  1.0
  V  V35  1  0.448  0.500  0.250  1.0
[/CIF]
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The crystal structure described by CsVSO6 crystallizes in the orthorhombic Pbca space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(4), two equivalent O(3), two equivalent O(6), and three equivalent O(5) atoms. V(1) is bonded to one O(1), one O(4), one O(6), and two equivalent O(2) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent V(1)O5 trigonal bipyramids. S(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form SO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to two equivalent Cs(1) and one V(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1) and two equivalent V(1) atoms. In the fifth O site, O(3) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one S(1) atom. is represented by the CIF file [CIF]
data_CsVSO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.436
_cell_length_b   6.691
_cell_length_c   17.876
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   650.152
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.042  0.250  0.589  1.0
  Cs  Cs1  1  0.042  0.750  0.911  1.0
  Cs  Cs2  1  0.958  0.750  0.411  1.0
  Cs  Cs3  1  0.958  0.250  0.089  1.0
  O  O4  1  0.516  0.566  0.144  1.0
  O  O5  1  0.437  0.250  0.727  1.0
  O  O6  1  0.563  0.250  0.227  1.0
  O  O7  1  0.587  0.750  0.029  1.0
  O  O8  1  0.516  0.066  0.356  1.0
  O  O9  1  0.413  0.750  0.529  1.0
  O  O10  1  0.563  0.750  0.273  1.0
  O  O11  1  0.413  0.250  0.971  1.0
  O  O12  1  0.825  0.750  0.586  1.0
  O  O13  1  0.587  0.250  0.471  1.0
  O  O14  1  0.150  0.500  0.250  1.0
  O  O15  1  0.437  0.750  0.773  1.0
  O  O16  1  0.150  0.000  0.250  1.0
  O  O17  1  0.484  0.934  0.644  1.0
  O  O18  1  0.850  0.500  0.750  1.0
  O  O19  1  0.825  0.250  0.914  1.0
  O  O20  1  0.516  0.434  0.356  1.0
  O  O21  1  0.850  0.000  0.750  1.0
  O  O22  1  0.516  0.934  0.144  1.0
  O  O23  1  0.484  0.066  0.856  1.0
  O  O24  1  0.175  0.250  0.414  1.0
  O  O25  1  0.484  0.434  0.856  1.0
  O  O26  1  0.175  0.750  0.086  1.0
  O  O27  1  0.484  0.566  0.644  1.0
  S  S28  1  0.559  0.750  0.597  1.0
  S  S29  1  0.441  0.750  0.097  1.0
  S  S30  1  0.441  0.250  0.403  1.0
  S  S31  1  0.559  0.250  0.903  1.0
  V  V32  1  0.552  0.000  0.750  1.0
  V  V33  1  0.552  0.500  0.750  1.0
  V  V34  1  0.448  1.000  0.250  1.0
  V  V35  1  0.448  0.500  0.250  1.0
[/CIF]
.