The crystal structure described by TlSbS2 crystallizes in the tetragonal I4_1/amd space group. Tl(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. Sb(1) is bonded to six equivalent S(1) atoms to form a mixture of edge and corner-sharing SbS6 octahedra. The corner-sharing octahedral tilt angles are 11°. S(1) is bonded to two equivalent Tl(1) and three equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing STl2Sb3 square pyramids. is represented by the CIF card [CIF]
data_TlSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.304
_cell_length_b   11.052
_cell_length_c   7.293
_cell_angle_alpha   29.100
_cell_angle_beta   55.298
_cell_angle_gamma   41.291
_symmetry_Int_Tables_number   1
_cell_volume   206.756
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.000  0.000  0.000  1.0
  Tl  Tl1  1  0.750  0.500  0.000  1.0
  Sb  Sb2  1  0.500  0.000  0.000  1.0
  Sb  Sb3  1  0.250  0.500  0.000  1.0
  S  S4  1  0.023  0.500  0.453  1.0
  S  S5  1  0.727  0.000  0.547  1.0
  S  S6  1  0.477  0.500  0.547  1.0
  S  S7  1  0.273  0.000  0.453  1.0
[/CIF]
.
The crystal structure described by TlSbS2 crystallizes in the tetragonal I4_1/amd space group. Tl(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. Sb(1) is bonded to six equivalent S(1) atoms to form a mixture of edge and corner-sharing SbS6 octahedra. The corner-sharing octahedral tilt angles are 11°. S(1) is bonded to two equivalent Tl(1) and three equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing STl2Sb3 square pyramids. is represented by the CIF card [CIF]
data_TlSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.304
_cell_length_b   11.052
_cell_length_c   7.293
_cell_angle_alpha   29.100
_cell_angle_beta   55.298
_cell_angle_gamma   41.291
_symmetry_Int_Tables_number   1
_cell_volume   206.756
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.000  0.000  0.000  1.0
  Tl  Tl1  1  0.750  0.500  0.000  1.0
  Sb  Sb2  1  0.500  0.000  0.000  1.0
  Sb  Sb3  1  0.250  0.500  0.000  1.0
  S  S4  1  0.023  0.500  0.453  1.0
  S  S5  1  0.727  0.000  0.547  1.0
  S  S6  1  0.477  0.500  0.547  1.0
  S  S7  1  0.273  0.000  0.453  1.0
[/CIF]
.