The structure described by BaZnOS crystallizes in the orthorhombic Cmcm space group. Ba(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. Zn(1) is bonded to two equivalent S(1) and two equivalent O(1) atoms to form corner-sharing ZnS2O2 tetrahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent Ba(1) and two equivalent Zn(1) atoms. O(1) is bonded to four equivalent Ba(1) and two equivalent Zn(1) atoms to form a mixture of distorted edge, face, and corner-sharing OBa4Zn2 octahedra. The corner-sharing octahedral tilt angles are 58°. is represented by the CIF card [CIF]
data_BaZnSO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.992
_cell_length_b   6.196
_cell_length_c   6.818
_cell_angle_alpha   90.000
_cell_angle_beta   107.021
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   161.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.892  0.250  0.784  1.0
  Ba  Ba1  1  0.108  0.750  0.216  1.0
  Zn  Zn2  1  0.402  0.750  0.803  1.0
  Zn  Zn3  1  0.598  0.250  0.197  1.0
  S  S4  1  0.807  0.750  0.613  1.0
  S  S5  1  0.193  0.250  0.387  1.0
  O  O6  1  0.500  0.500  0.000  1.0
  O  O7  1  0.500  0.000  0.000  1.0
[/CIF]
.
The structure described by BaZnOS crystallizes in the orthorhombic Cmcm space group. Ba(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. Zn(1) is bonded to two equivalent S(1) and two equivalent O(1) atoms to form corner-sharing ZnS2O2 tetrahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent Ba(1) and two equivalent Zn(1) atoms. O(1) is bonded to four equivalent Ba(1) and two equivalent Zn(1) atoms to form a mixture of distorted edge, face, and corner-sharing OBa4Zn2 octahedra. The corner-sharing octahedral tilt angles are 58°. is represented by the CIF card [CIF]
data_BaZnSO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.992
_cell_length_b   6.196
_cell_length_c   6.818
_cell_angle_alpha   90.000
_cell_angle_beta   107.021
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   161.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.892  0.250  0.784  1.0
  Ba  Ba1  1  0.108  0.750  0.216  1.0
  Zn  Zn2  1  0.402  0.750  0.803  1.0
  Zn  Zn3  1  0.598  0.250  0.197  1.0
  S  S4  1  0.807  0.750  0.613  1.0
  S  S5  1  0.193  0.250  0.387  1.0
  O  O6  1  0.500  0.500  0.000  1.0
  O  O7  1  0.500  0.000  0.000  1.0
[/CIF]
.