The structure described by Pb2C(SO3)2 crystallizes in the orthorhombic Pnma space group. Pb(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(4) and two equivalent O(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one S(2), one O(1), and two equivalent O(3) atoms. In the second S site, S(2) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to two equivalent Pb(1) and one S(1) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one C(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pb2C(SO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.677
_cell_length_b   8.908
_cell_length_c   16.583
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   690.809
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.415  0.986  0.137  1.0
  Pb  Pb1  1  0.085  0.514  0.637  1.0
  Pb  Pb2  1  0.585  0.486  0.863  1.0
  Pb  Pb3  1  0.915  0.014  0.363  1.0
  Pb  Pb4  1  0.585  0.014  0.863  1.0
  Pb  Pb5  1  0.915  0.486  0.363  1.0
  Pb  Pb6  1  0.415  0.514  0.137  1.0
  Pb  Pb7  1  0.085  0.986  0.637  1.0
  C  C8  1  0.621  0.750  0.712  1.0
  C  C9  1  0.879  0.750  0.212  1.0
  C  C10  1  0.379  0.250  0.288  1.0
  C  C11  1  0.121  0.250  0.788  1.0
  S  S12  1  0.925  0.750  0.003  1.0
  S  S13  1  0.575  0.750  0.503  1.0
  S  S14  1  0.075  0.250  0.997  1.0
  S  S15  1  0.425  0.250  0.497  1.0
  S  S16  1  0.070  0.750  0.887  1.0
  S  S17  1  0.430  0.750  0.387  1.0
  S  S18  1  0.930  0.250  0.113  1.0
  S  S19  1  0.570  0.250  0.613  1.0
  O  O20  1  0.170  0.750  0.061  1.0
  O  O21  1  0.330  0.750  0.561  1.0
  O  O22  1  0.830  0.250  0.939  1.0
  O  O23  1  0.670  0.250  0.439  1.0
  O  O24  1  0.502  0.122  0.275  1.0
  O  O25  1  0.998  0.378  0.775  1.0
  O  O26  1  0.498  0.622  0.725  1.0
  O  O27  1  0.002  0.878  0.225  1.0
  O  O28  1  0.498  0.878  0.725  1.0
  O  O29  1  0.002  0.622  0.225  1.0
  O  O30  1  0.502  0.378  0.275  1.0
  O  O31  1  0.998  0.122  0.775  1.0
  O  O32  1  0.752  0.611  0.013  1.0
  O  O33  1  0.748  0.889  0.513  1.0
  O  O34  1  0.248  0.111  0.987  1.0
  O  O35  1  0.252  0.389  0.487  1.0
  O  O36  1  0.248  0.389  0.987  1.0
  O  O37  1  0.252  0.111  0.487  1.0
  O  O38  1  0.752  0.889  0.013  1.0
  O  O39  1  0.748  0.611  0.513  1.0
  O  O40  1  0.614  0.750  0.187  1.0
  O  O41  1  0.886  0.750  0.687  1.0
  O  O42  1  0.386  0.250  0.813  1.0
  O  O43  1  0.114  0.250  0.313  1.0
[/CIF]
.
The structure described by Pb2C(SO3)2 crystallizes in the orthorhombic Pnma space group. Pb(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(4) and two equivalent O(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one S(2), one O(1), and two equivalent O(3) atoms. In the second S site, S(2) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to two equivalent Pb(1) and one S(1) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one C(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pb2C(SO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.677
_cell_length_b   8.908
_cell_length_c   16.583
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   690.809
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.415  0.986  0.137  1.0
  Pb  Pb1  1  0.085  0.514  0.637  1.0
  Pb  Pb2  1  0.585  0.486  0.863  1.0
  Pb  Pb3  1  0.915  0.014  0.363  1.0
  Pb  Pb4  1  0.585  0.014  0.863  1.0
  Pb  Pb5  1  0.915  0.486  0.363  1.0
  Pb  Pb6  1  0.415  0.514  0.137  1.0
  Pb  Pb7  1  0.085  0.986  0.637  1.0
  C  C8  1  0.621  0.750  0.712  1.0
  C  C9  1  0.879  0.750  0.212  1.0
  C  C10  1  0.379  0.250  0.288  1.0
  C  C11  1  0.121  0.250  0.788  1.0
  S  S12  1  0.925  0.750  0.003  1.0
  S  S13  1  0.575  0.750  0.503  1.0
  S  S14  1  0.075  0.250  0.997  1.0
  S  S15  1  0.425  0.250  0.497  1.0
  S  S16  1  0.070  0.750  0.887  1.0
  S  S17  1  0.430  0.750  0.387  1.0
  S  S18  1  0.930  0.250  0.113  1.0
  S  S19  1  0.570  0.250  0.613  1.0
  O  O20  1  0.170  0.750  0.061  1.0
  O  O21  1  0.330  0.750  0.561  1.0
  O  O22  1  0.830  0.250  0.939  1.0
  O  O23  1  0.670  0.250  0.439  1.0
  O  O24  1  0.502  0.122  0.275  1.0
  O  O25  1  0.998  0.378  0.775  1.0
  O  O26  1  0.498  0.622  0.725  1.0
  O  O27  1  0.002  0.878  0.225  1.0
  O  O28  1  0.498  0.878  0.725  1.0
  O  O29  1  0.002  0.622  0.225  1.0
  O  O30  1  0.502  0.378  0.275  1.0
  O  O31  1  0.998  0.122  0.775  1.0
  O  O32  1  0.752  0.611  0.013  1.0
  O  O33  1  0.748  0.889  0.513  1.0
  O  O34  1  0.248  0.111  0.987  1.0
  O  O35  1  0.252  0.389  0.487  1.0
  O  O36  1  0.248  0.389  0.987  1.0
  O  O37  1  0.252  0.111  0.487  1.0
  O  O38  1  0.752  0.889  0.013  1.0
  O  O39  1  0.748  0.611  0.513  1.0
  O  O40  1  0.614  0.750  0.187  1.0
  O  O41  1  0.886  0.750  0.687  1.0
  O  O42  1  0.386  0.250  0.813  1.0
  O  O43  1  0.114  0.250  0.313  1.0
[/CIF]
.