The compound described by NaCdVO4 crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. V(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form VO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. Cd(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CdO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with two equivalent Cd(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one V(1), and two equivalent Cd(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one V(1), and one Cd(1) atom. is represented by the CIF card [CIF]
data_NaVCdO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.421
_cell_length_b   5.421
_cell_length_c   7.034
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   115.008
_symmetry_Int_Tables_number   1
_cell_volume   187.336
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.318  0.682  0.250  1.0
  Na  Na1  1  0.682  0.318  0.750  1.0
  V  V2  1  0.350  0.650  0.750  1.0
  V  V3  1  0.650  0.350  0.250  1.0
  Cd  Cd4  1  0.000  0.000  0.500  1.0
  Cd  Cd5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.779  0.706  0.250  1.0
  O  O7  1  0.221  0.294  0.750  1.0
  O  O8  1  0.706  0.779  0.750  1.0
  O  O9  1  0.294  0.221  0.250  1.0
  O  O10  1  0.243  0.757  0.555  1.0
  O  O11  1  0.757  0.243  0.055  1.0
  O  O12  1  0.243  0.757  0.945  1.0
  O  O13  1  0.757  0.243  0.445  1.0
[/CIF]
.
The compound described by NaCdVO4 crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. V(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form VO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. Cd(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CdO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with two equivalent Cd(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one V(1), and two equivalent Cd(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one V(1), and one Cd(1) atom. is represented by the CIF card [CIF]
data_NaVCdO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.421
_cell_length_b   5.421
_cell_length_c   7.034
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   115.008
_symmetry_Int_Tables_number   1
_cell_volume   187.336
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.318  0.682  0.250  1.0
  Na  Na1  1  0.682  0.318  0.750  1.0
  V  V2  1  0.350  0.650  0.750  1.0
  V  V3  1  0.650  0.350  0.250  1.0
  Cd  Cd4  1  0.000  0.000  0.500  1.0
  Cd  Cd5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.779  0.706  0.250  1.0
  O  O7  1  0.221  0.294  0.750  1.0
  O  O8  1  0.706  0.779  0.750  1.0
  O  O9  1  0.294  0.221  0.250  1.0
  O  O10  1  0.243  0.757  0.555  1.0
  O  O11  1  0.757  0.243  0.055  1.0
  O  O12  1  0.243  0.757  0.945  1.0
  O  O13  1  0.757  0.243  0.445  1.0
[/CIF]
.