The crystal structure described by MoTe2O7 crystallizes in the monoclinic P2_1/c space group. Mo(1) is bonded in a 6-coordinate geometry to one O(4), one O(7), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(7) atom. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(6), and two equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a trigonal non-coplanar geometry to two equivalent Mo(1) and one Te(2) atom. In the second O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(1) and one Te(1) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the fifth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Te(1) and two equivalent Te(2) atoms. In the sixth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to two equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_Te2MoO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.766
_cell_length_b   4.277
_cell_length_c   15.866
_cell_angle_alpha   84.421
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   592.069
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.038  0.155  0.225  1.0
  Te  Te1  1  0.538  0.845  0.275  1.0
  Te  Te2  1  0.962  0.845  0.775  1.0
  Te  Te3  1  0.462  0.155  0.725  1.0
  Te  Te4  1  0.298  0.307  0.391  1.0
  Te  Te5  1  0.798  0.693  0.109  1.0
  Te  Te6  1  0.702  0.693  0.609  1.0
  Te  Te7  1  0.202  0.307  0.891  1.0
  Mo  Mo8  1  0.365  0.878  0.068  1.0
  Mo  Mo9  1  0.865  0.122  0.432  1.0
  Mo  Mo10  1  0.635  0.122  0.932  1.0
  Mo  Mo11  1  0.135  0.878  0.568  1.0
  O  O12  1  0.158  0.423  0.305  1.0
  O  O13  1  0.658  0.577  0.195  1.0
  O  O14  1  0.842  0.577  0.695  1.0
  O  O15  1  0.342  0.423  0.805  1.0
  O  O16  1  0.474  0.428  0.311  1.0
  O  O17  1  0.974  0.572  0.189  1.0
  O  O18  1  0.526  0.572  0.689  1.0
  O  O19  1  0.026  0.428  0.811  1.0
  O  O20  1  0.354  0.907  0.357  1.0
  O  O21  1  0.854  0.093  0.143  1.0
  O  O22  1  0.646  0.093  0.643  1.0
  O  O23  1  0.146  0.907  0.857  1.0
  O  O24  1  0.326  0.966  0.564  1.0
  O  O25  1  0.826  0.034  0.936  1.0
  O  O26  1  0.674  0.034  0.436  1.0
  O  O27  1  0.174  0.966  0.064  1.0
  O  O28  1  0.126  0.479  0.568  1.0
  O  O29  1  0.626  0.521  0.932  1.0
  O  O30  1  0.874  0.521  0.432  1.0
  O  O31  1  0.374  0.479  0.068  1.0
  O  O32  1  0.394  0.030  0.950  1.0
  O  O33  1  0.894  0.970  0.550  1.0
  O  O34  1  0.606  0.970  0.050  1.0
  O  O35  1  0.106  0.030  0.450  1.0
  O  O36  1  0.102  0.942  0.685  1.0
  O  O37  1  0.602  0.058  0.815  1.0
  O  O38  1  0.898  0.058  0.315  1.0
  O  O39  1  0.398  0.942  0.185  1.0
[/CIF]
.
The crystal structure described by MoTe2O7 crystallizes in the monoclinic P2_1/c space group. Mo(1) is bonded in a 6-coordinate geometry to one O(4), one O(7), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(7) atom. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(6), and two equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a trigonal non-coplanar geometry to two equivalent Mo(1) and one Te(2) atom. In the second O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(1) and one Te(1) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the fifth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Te(1) and two equivalent Te(2) atoms. In the sixth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to two equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_Te2MoO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.766
_cell_length_b   4.277
_cell_length_c   15.866
_cell_angle_alpha   84.421
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   592.069
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.038  0.155  0.225  1.0
  Te  Te1  1  0.538  0.845  0.275  1.0
  Te  Te2  1  0.962  0.845  0.775  1.0
  Te  Te3  1  0.462  0.155  0.725  1.0
  Te  Te4  1  0.298  0.307  0.391  1.0
  Te  Te5  1  0.798  0.693  0.109  1.0
  Te  Te6  1  0.702  0.693  0.609  1.0
  Te  Te7  1  0.202  0.307  0.891  1.0
  Mo  Mo8  1  0.365  0.878  0.068  1.0
  Mo  Mo9  1  0.865  0.122  0.432  1.0
  Mo  Mo10  1  0.635  0.122  0.932  1.0
  Mo  Mo11  1  0.135  0.878  0.568  1.0
  O  O12  1  0.158  0.423  0.305  1.0
  O  O13  1  0.658  0.577  0.195  1.0
  O  O14  1  0.842  0.577  0.695  1.0
  O  O15  1  0.342  0.423  0.805  1.0
  O  O16  1  0.474  0.428  0.311  1.0
  O  O17  1  0.974  0.572  0.189  1.0
  O  O18  1  0.526  0.572  0.689  1.0
  O  O19  1  0.026  0.428  0.811  1.0
  O  O20  1  0.354  0.907  0.357  1.0
  O  O21  1  0.854  0.093  0.143  1.0
  O  O22  1  0.646  0.093  0.643  1.0
  O  O23  1  0.146  0.907  0.857  1.0
  O  O24  1  0.326  0.966  0.564  1.0
  O  O25  1  0.826  0.034  0.936  1.0
  O  O26  1  0.674  0.034  0.436  1.0
  O  O27  1  0.174  0.966  0.064  1.0
  O  O28  1  0.126  0.479  0.568  1.0
  O  O29  1  0.626  0.521  0.932  1.0
  O  O30  1  0.874  0.521  0.432  1.0
  O  O31  1  0.374  0.479  0.068  1.0
  O  O32  1  0.394  0.030  0.950  1.0
  O  O33  1  0.894  0.970  0.550  1.0
  O  O34  1  0.606  0.970  0.050  1.0
  O  O35  1  0.106  0.030  0.450  1.0
  O  O36  1  0.102  0.942  0.685  1.0
  O  O37  1  0.602  0.058  0.815  1.0
  O  O38  1  0.898  0.058  0.315  1.0
  O  O39  1  0.398  0.942  0.185  1.0
[/CIF]
.