The material described by RbSO4 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and three equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.920
_cell_length_b   7.470
_cell_length_c   9.798
_cell_angle_alpha   50.537
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   447.538
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.317  0.629  0.770  1.0
  Rb  Rb1  1  0.683  0.371  0.230  1.0
  Rb  Rb2  1  0.817  0.371  0.730  1.0
  Rb  Rb3  1  0.183  0.629  0.270  1.0
  S  S4  1  0.186  0.151  0.245  1.0
  S  S5  1  0.814  0.849  0.755  1.0
  S  S6  1  0.686  0.849  0.255  1.0
  S  S7  1  0.314  0.151  0.745  1.0
  O  O8  1  0.047  0.191  0.326  1.0
  O  O9  1  0.953  0.809  0.674  1.0
  O  O10  1  0.547  0.809  0.174  1.0
  O  O11  1  0.453  0.191  0.826  1.0
  O  O12  1  0.683  0.667  0.829  1.0
  O  O13  1  0.317  0.333  0.171  1.0
  O  O14  1  0.183  0.333  0.671  1.0
  O  O15  1  0.817  0.667  0.329  1.0
  O  O16  1  0.388  0.161  0.601  1.0
  O  O17  1  0.612  0.839  0.399  1.0
  O  O18  1  0.888  0.839  0.899  1.0
  O  O19  1  0.112  0.161  0.101  1.0
  O  O20  1  0.243  0.916  0.885  1.0
  O  O21  1  0.757  0.084  0.115  1.0
  O  O22  1  0.743  0.084  0.615  1.0
  O  O23  1  0.257  0.916  0.385  1.0
[/CIF]
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The material described by RbSO4 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and three equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.920
_cell_length_b   7.470
_cell_length_c   9.798
_cell_angle_alpha   50.537
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   447.538
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.317  0.629  0.770  1.0
  Rb  Rb1  1  0.683  0.371  0.230  1.0
  Rb  Rb2  1  0.817  0.371  0.730  1.0
  Rb  Rb3  1  0.183  0.629  0.270  1.0
  S  S4  1  0.186  0.151  0.245  1.0
  S  S5  1  0.814  0.849  0.755  1.0
  S  S6  1  0.686  0.849  0.255  1.0
  S  S7  1  0.314  0.151  0.745  1.0
  O  O8  1  0.047  0.191  0.326  1.0
  O  O9  1  0.953  0.809  0.674  1.0
  O  O10  1  0.547  0.809  0.174  1.0
  O  O11  1  0.453  0.191  0.826  1.0
  O  O12  1  0.683  0.667  0.829  1.0
  O  O13  1  0.317  0.333  0.171  1.0
  O  O14  1  0.183  0.333  0.671  1.0
  O  O15  1  0.817  0.667  0.329  1.0
  O  O16  1  0.388  0.161  0.601  1.0
  O  O17  1  0.612  0.839  0.399  1.0
  O  O18  1  0.888  0.839  0.899  1.0
  O  O19  1  0.112  0.161  0.101  1.0
  O  O20  1  0.243  0.916  0.885  1.0
  O  O21  1  0.757  0.084  0.115  1.0
  O  O22  1  0.743  0.084  0.615  1.0
  O  O23  1  0.257  0.916  0.385  1.0
[/CIF]
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