The crystal structure described by Mn2Hg(CO)10 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Mn2Hg(CO)10 clusters. Mn(1) is bonded to one Hg(1), one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form distorted corner-sharing MnHgC5 square pyramids. Hg(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2,3) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(2,3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Mn(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(5) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(2,3) is bonded in a single-bond geometry to one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2Hg(CO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.407
_cell_length_b   6.608
_cell_length_c   19.224
_cell_angle_alpha   84.412
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   810.070
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.152  0.188  0.879  1.0
  Mn  Mn1  1  0.652  0.812  0.621  1.0
  Mn  Mn2  1  0.848  0.812  0.121  1.0
  Mn  Mn3  1  0.348  0.188  0.379  1.0
  Hg  Hg4  1  0.000  0.000  0.000  1.0
  Hg  Hg5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.256  0.317  0.799  1.0
  C  C7  1  0.756  0.683  0.701  1.0
  C  C8  1  0.744  0.683  0.201  1.0
  C  C9  1  0.244  0.317  0.299  1.0
  C  C10  1  0.375  0.240  0.935  1.0
  C  C11  1  0.875  0.760  0.565  1.0
  C  C12  1  0.625  0.760  0.065  1.0
  C  C13  1  0.125  0.240  0.435  1.0
  C  C14  1  0.269  0.937  0.867  1.0
  C  C15  1  0.769  0.063  0.633  1.0
  C  C16  1  0.731  0.063  0.133  1.0
  C  C17  1  0.231  0.937  0.367  1.0
  C  C18  1  0.906  0.106  0.840  1.0
  C  C19  1  0.406  0.894  0.660  1.0
  C  C20  1  0.094  0.894  0.160  1.0
  C  C21  1  0.594  0.106  0.340  1.0
  C  C22  1  0.012  0.413  0.905  1.0
  C  C23  1  0.512  0.587  0.595  1.0
  C  C24  1  0.988  0.587  0.095  1.0
  C  C25  1  0.488  0.413  0.405  1.0
  O  O26  1  0.323  0.400  0.748  1.0
  O  O27  1  0.823  0.600  0.752  1.0
  O  O28  1  0.677  0.600  0.252  1.0
  O  O29  1  0.177  0.400  0.248  1.0
  O  O30  1  0.516  0.271  0.971  1.0
  O  O31  1  0.016  0.729  0.529  1.0
  O  O32  1  0.484  0.729  0.029  1.0
  O  O33  1  0.984  0.271  0.471  1.0
  O  O34  1  0.345  0.782  0.859  1.0
  O  O35  1  0.845  0.218  0.641  1.0
  O  O36  1  0.655  0.218  0.141  1.0
  O  O37  1  0.155  0.782  0.359  1.0
  O  O38  1  0.752  0.057  0.814  1.0
  O  O39  1  0.252  0.943  0.686  1.0
  O  O40  1  0.248  0.943  0.186  1.0
  O  O41  1  0.748  0.057  0.314  1.0
  O  O42  1  0.922  0.555  0.921  1.0
  O  O43  1  0.422  0.445  0.579  1.0
  O  O44  1  0.078  0.445  0.079  1.0
  O  O45  1  0.578  0.555  0.421  1.0
[/CIF]
.
The crystal structure described by Mn2Hg(CO)10 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Mn2Hg(CO)10 clusters. Mn(1) is bonded to one Hg(1), one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form distorted corner-sharing MnHgC5 square pyramids. Hg(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2,3) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(2,3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Mn(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(5) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(2,3) is bonded in a single-bond geometry to one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2Hg(CO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.407
_cell_length_b   6.608
_cell_length_c   19.224
_cell_angle_alpha   84.412
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   810.070
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.152  0.188  0.879  1.0
  Mn  Mn1  1  0.652  0.812  0.621  1.0
  Mn  Mn2  1  0.848  0.812  0.121  1.0
  Mn  Mn3  1  0.348  0.188  0.379  1.0
  Hg  Hg4  1  0.000  0.000  0.000  1.0
  Hg  Hg5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.256  0.317  0.799  1.0
  C  C7  1  0.756  0.683  0.701  1.0
  C  C8  1  0.744  0.683  0.201  1.0
  C  C9  1  0.244  0.317  0.299  1.0
  C  C10  1  0.375  0.240  0.935  1.0
  C  C11  1  0.875  0.760  0.565  1.0
  C  C12  1  0.625  0.760  0.065  1.0
  C  C13  1  0.125  0.240  0.435  1.0
  C  C14  1  0.269  0.937  0.867  1.0
  C  C15  1  0.769  0.063  0.633  1.0
  C  C16  1  0.731  0.063  0.133  1.0
  C  C17  1  0.231  0.937  0.367  1.0
  C  C18  1  0.906  0.106  0.840  1.0
  C  C19  1  0.406  0.894  0.660  1.0
  C  C20  1  0.094  0.894  0.160  1.0
  C  C21  1  0.594  0.106  0.340  1.0
  C  C22  1  0.012  0.413  0.905  1.0
  C  C23  1  0.512  0.587  0.595  1.0
  C  C24  1  0.988  0.587  0.095  1.0
  C  C25  1  0.488  0.413  0.405  1.0
  O  O26  1  0.323  0.400  0.748  1.0
  O  O27  1  0.823  0.600  0.752  1.0
  O  O28  1  0.677  0.600  0.252  1.0
  O  O29  1  0.177  0.400  0.248  1.0
  O  O30  1  0.516  0.271  0.971  1.0
  O  O31  1  0.016  0.729  0.529  1.0
  O  O32  1  0.484  0.729  0.029  1.0
  O  O33  1  0.984  0.271  0.471  1.0
  O  O34  1  0.345  0.782  0.859  1.0
  O  O35  1  0.845  0.218  0.641  1.0
  O  O36  1  0.655  0.218  0.141  1.0
  O  O37  1  0.155  0.782  0.359  1.0
  O  O38  1  0.752  0.057  0.814  1.0
  O  O39  1  0.252  0.943  0.686  1.0
  O  O40  1  0.248  0.943  0.186  1.0
  O  O41  1  0.748  0.057  0.314  1.0
  O  O42  1  0.922  0.555  0.921  1.0
  O  O43  1  0.422  0.445  0.579  1.0
  O  O44  1  0.078  0.445  0.079  1.0
  O  O45  1  0.578  0.555  0.421  1.0
[/CIF]
.