The structure described by Sr6La4Zn3(RuO10)2 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(11), one O(14), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(10) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(12), one O(4), one O(5), one O(7), one O(9), and two equivalent O(8) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(15), one O(18), one O(9), and two equivalent O(14) atoms. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(17), one O(19), one O(2), and two equivalent O(18) atoms. In the fifth Sr site, Sr(5) is bonded in a 9-coordinate geometry to one O(12), one O(13), one O(15), one O(17), one O(18), one O(19), one O(20), and two equivalent O(16) atoms. In the sixth Sr site, Sr(6) is bonded in a 9-coordinate geometry to one O(1), one O(16), one O(17), one O(19), one O(2), one O(3), one O(4), and two equivalent O(20) atoms. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(5), one O(7), and two equivalent O(6) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(1), one O(20), one O(3), one O(5), one O(6), one O(7), one O(8), and two equivalent O(4) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(14), one O(15), one O(16), one O(8), one O(9), and two equivalent O(12) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(1), one O(17), one O(18), one O(19), one O(20), one O(3), one O(6), and two equivalent O(2) atoms. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(10), one O(11), one O(5), one O(7), one O(8), and one O(9) atom to form RuO6 octahedra that share corners with two equivalent Zn(2)O6 octahedra and corners with two equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the second Ru site, Ru(2) is bonded to one O(13), one O(15), one O(16), one O(17), one O(18), and one O(19) atom to form RuO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with two equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(17), one O(19), one O(2), one O(20), and one O(3) atom to form ZnO6 octahedra that share corners with two equivalent Ru(2)O6 octahedra and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form ZnO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the third Zn site, Zn(3) is bonded to one O(11), one O(12), one O(13), one O(14), one O(15), and one O(9) atom to form ZnO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with two equivalent Ru(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Sr(6), one La(1), one La(2), one La(4), one Zn(1), and one Zn(2) atom to form distorted OSrLa3Zn2 octahedra that share  a cornercorner with one O(5)Sr2La2ZnRu octahedra,  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(17)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra,  an edgeedge with one O(5)Sr2La2ZnRu octahedra,  an edgeedge with one O(17)Sr3LaZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(19)Sr3LaZnRu octahedra, and faces with two equivalent O(3)SrLa3Zn2 octahedra. The corner-sharing octahedral tilt angles range from 4-60°. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Sr(4), one Sr(6), one La(1), two equivalent La(4), and one Zn(1) atom. In the third O site, O(3) is bonded to one Sr(6), one La(1), one La(2), one La(4), one Zn(1), and one Zn(2) atom to form distorted OSrLa3Zn2 octahedra that share  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(19)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra,  an edgeedge with one O(7)Sr2La2ZnRu octahedra,  an edgeedge with one O(19)Sr3LaZnRu octahedra,  a faceface with one O(5)Sr2La2ZnRu octahedra,  a faceface with one O(17)Sr3LaZnRu octahedra, and faces with two equivalent O(1)SrLa3Zn2 octahedra. The corner-sharing octahedral tilt angles range from 3-60°. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Sr(2), one Sr(6), one La(1), two equivalent La(2), and one Zn(2) atom. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(2), one La(1), one La(2), one Ru(1), and one Zn(2) atom to form distorted OSr2La2ZnRu octahedra that share  a cornercorner with one O(9)Sr3LaZnRu octahedra,  a cornercorner with one O(14)Sr4LaZn octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(10)Sr4LaRu octahedra,  an edgeedge with one O(9)Sr3LaZnRu octahedra,  an edgeedge with one O(1)SrLa3Zn2 octahedra,  a faceface with one O(8)Sr3La2Ru octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra,  a faceface with one O(10)Sr4LaRu octahedra,  a faceface with one O(3)SrLa3Zn2 octahedra, and faces with two equivalent O(7)Sr2La2ZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Sr(1), one La(2), one La(4), two equivalent La(1), and one Zn(2) atom. In the seventh O site, O(7) is bonded to one Sr(1), one Sr(2), one La(1), one La(2), one Ru(1), and one Zn(2) atom to form distorted OSr2La2ZnRu octahedra that share  a cornercorner with one O(11)Sr3LaZnRu octahedra,  a cornercorner with one O(14)Sr4LaZn octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(10)Sr4LaRu octahedra,  an edgeedge with one O(11)Sr3LaZnRu octahedra,  an edgeedge with one O(3)SrLa3Zn2 octahedra,  a faceface with one O(8)Sr3La2Ru octahedra,  a faceface with one O(9)Sr3LaZnRu octahedra,  a faceface with one O(10)Sr4LaRu octahedra,  a faceface with one O(1)SrLa3Zn2 octahedra, and faces with two equivalent O(5)Sr2La2ZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the eighth O site, O(8) is bonded to one Sr(1), two equivalent Sr(2), one La(2), one La(3), and one Ru(1) atom to form distorted OSr3La2Ru octahedra that share  a cornercorner with one O(13)Sr3LaZnRu octahedra,  a cornercorner with one O(15)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(5)Sr2La2ZnRu octahedra, corners with two equivalent O(7)Sr2La2ZnRu octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(11)Sr3LaZnRu octahedra, corners with two equivalent O(9)Sr3LaZnRu octahedra,  an edgeedge with one O(14)Sr4LaZn octahedra, edges with two equivalent O(10)Sr4LaRu octahedra,  a faceface with one O(5)Sr2La2ZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra, and  a faceface with one O(9)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ru(1), and one Zn(3) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(5)Sr2La2ZnRu octahedra,  a cornercorner with one O(13)Sr3LaZnRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(10)Sr4LaRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(5)Sr2La2ZnRu octahedra,  an edgeedge with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(8)Sr3La2Ru octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(10)Sr4LaRu octahedra,  a faceface with one O(14)Sr4LaZn octahedra, and faces with two equivalent O(11)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the tenth O site, O(10) is bonded to one Sr(2), one Sr(3), two equivalent Sr(1), one La(1), and one Ru(1) atom to form distorted OSr4LaRu octahedra that share  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(13)Sr3LaZnRu octahedra,  a cornercorner with one O(15)Sr3LaZnRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(5)Sr2La2ZnRu octahedra, corners with two equivalent O(7)Sr2La2ZnRu octahedra, corners with two equivalent O(11)Sr3LaZnRu octahedra, corners with two equivalent O(9)Sr3LaZnRu octahedra, corners with two equivalent O(10)Sr4LaRu octahedra, edges with two equivalent O(8)Sr3La2Ru octahedra, edges with two equivalent O(14)Sr4LaZn octahedra,  a faceface with one O(5)Sr2La2ZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra, and  a faceface with one O(9)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the eleventh O site, O(11) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ru(1), and one Zn(3) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(15)Sr3LaZnRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(10)Sr4LaRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(7)Sr2La2ZnRu octahedra,  an edgeedge with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(5)Sr2La2ZnRu octahedra,  a faceface with one O(8)Sr3La2Ru octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(10)Sr4LaRu octahedra,  a faceface with one O(14)Sr4LaZn octahedra, and faces with two equivalent O(9)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one Sr(2), one Sr(3), one Sr(5), two equivalent La(3), and one Zn(3) atom. In the thirteenth O site, O(13) is bonded to one Sr(3), one Sr(4), one Sr(5), one La(3), one Ru(2), and one Zn(3) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(17)Sr3LaZnRu octahedra,  a cornercorner with one O(9)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra, corners with two equivalent O(16)Sr4LaRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(17)Sr3LaZnRu octahedra,  an edgeedge with one O(9)Sr3LaZnRu octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra,  a faceface with one O(19)Sr3LaZnRu octahedra,  a faceface with one O(16)Sr4LaRu octahedra,  a faceface with one O(18)Sr4LaRu octahedra,  a faceface with one O(14)Sr4LaZn octahedra, and faces with two equivalent O(15)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-59°. In the fourteenth O site, O(14) is bonded to one Sr(1), one Sr(4), two equivalent Sr(3), one La(3), and one Zn(3) atom to form distorted OSr4LaZn octahedra that share  a cornercorner with one O(5)Sr2La2ZnRu octahedra,  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(17)Sr3LaZnRu octahedra,  a cornercorner with one O(19)Sr3LaZnRu octahedra, corners with two equivalent O(11)Sr3LaZnRu octahedra, corners with two equivalent O(13)Sr3LaZnRu octahedra, corners with two equivalent O(15)Sr3LaZnRu octahedra, corners with two equivalent O(9)Sr3LaZnRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(8)Sr3La2Ru octahedra,  an edgeedge with one O(16)Sr4LaRu octahedra, edges with two equivalent O(10)Sr4LaRu octahedra, edges with two equivalent O(18)Sr4LaRu octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra, and  a faceface with one O(9)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 18-54°. In the fifteenth O site, O(15) is bonded to one Sr(3), one Sr(4), one Sr(5), one La(3), one Ru(2), and one Zn(3) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(11)Sr3LaZnRu octahedra,  a cornercorner with one O(19)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra, corners with two equivalent O(16)Sr4LaRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(11)Sr3LaZnRu octahedra,  an edgeedge with one O(19)Sr3LaZnRu octahedra,  a faceface with one O(17)Sr3LaZnRu octahedra,  a faceface with one O(9)Sr3LaZnRu octahedra,  a faceface with one O(16)Sr4LaRu octahedra,  a faceface with one O(18)Sr4LaRu octahedra,  a faceface with one O(14)Sr4LaZn octahedra, and faces with two equivalent O(13)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the sixteenth O site, O(16) is bonded to one Sr(4), one Sr(6), two equivalent Sr(5), one La(3), and one Ru(2) atom to form distorted OSr4LaRu octahedra that share  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(11)Sr3LaZnRu octahedra,  a cornercorner with one O(9)Sr3LaZnRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(13)Sr3LaZnRu octahedra, corners with two equivalent O(15)Sr3LaZnRu octahedra, corners with two equivalent O(17)Sr3LaZnRu octahedra, corners with two equivalent O(19)Sr3LaZnRu octahedra, corners with two equivalent O(16)Sr4LaRu octahedra,  an edgeedge with one O(14)Sr4LaZn octahedra, edges with two equivalent O(18)Sr4LaRu octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(17)Sr3LaZnRu octahedra, and  a faceface with one O(19)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the seventeenth O site, O(17) is bonded to one Sr(4), one Sr(5), one Sr(6), one La(4), one Ru(2), and one Zn(1) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(13)Sr3LaZnRu octahedra,  a cornercorner with one O(14)Sr4LaZn octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra, corners with two equivalent O(16)Sr4LaRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra,  an edgeedge with one O(13)Sr3LaZnRu octahedra,  an edgeedge with one O(1)SrLa3Zn2 octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(16)Sr4LaRu octahedra,  a faceface with one O(18)Sr4LaRu octahedra,  a faceface with one O(3)SrLa3Zn2 octahedra, and faces with two equivalent O(19)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the eighteenth O site, O(18) is bonded to one Sr(3), one Sr(5), two equivalent Sr(4), one La(4), and one Ru(2) atom to form distorted OSr4LaRu octahedra that share  a cornercorner with one O(11)Sr3LaZnRu octahedra,  a cornercorner with one O(9)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(13)Sr3LaZnRu octahedra, corners with two equivalent O(15)Sr3LaZnRu octahedra, corners with two equivalent O(17)Sr3LaZnRu octahedra, corners with two equivalent O(19)Sr3LaZnRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra, edges with two equivalent O(16)Sr4LaRu octahedra, edges with two equivalent O(14)Sr4LaZn octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(17)Sr3LaZnRu octahedra, and  a faceface with one O(19)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-59°. In the nineteenth O site, O(19) is bonded to one Sr(4), one Sr(5), one Sr(6), one La(4), one Ru(2), and one Zn(1) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(15)Sr3LaZnRu octahedra,  a cornercorner with one O(14)Sr4LaZn octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(16)Sr4LaRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra,  an edgeedge with one O(15)Sr3LaZnRu octahedra,  an edgeedge with one O(3)SrLa3Zn2 octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(16)Sr4LaRu octahedra,  a faceface with one O(18)Sr4LaRu octahedra,  a faceface with one O(1)SrLa3Zn2 octahedra, and faces with two equivalent O(17)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the twentieth O site, O(20) is bonded in a 6-coordinate geometry to one Sr(5), two equivalent Sr(6), one La(2), one La(4), and one Zn(1) atom. is represented by the CIF file [CIF]
data_Sr6La4Zn3(RuO10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   19.885
_cell_length_b   5.646
_cell_length_c   6.953
_cell_angle_alpha   114.012
_cell_angle_beta   106.681
_cell_angle_gamma   44.836
_symmetry_Int_Tables_number   1
_cell_volume   502.814
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.399  0.357  0.714  1.0
  Sr  Sr1  1  0.400  0.646  0.287  1.0
  Sr  Sr2  1  0.600  0.353  0.713  1.0
  Sr  Sr3  1  0.803  0.348  0.715  1.0
  Sr  Sr4  1  0.799  0.647  0.285  1.0
  Sr  Sr5  1  0.005  0.635  0.279  1.0
  La  La6  1  0.190  0.366  0.721  1.0
  La  La7  1  0.190  0.686  0.279  1.0
  La  La8  1  0.601  0.672  0.287  1.0
  La  La9  1  0.007  0.316  0.722  1.0
  Zn  Zn10  1  0.999  0.003  0.007  1.0
  Zn  Zn11  1  0.200  0.007  0.012  1.0
  Zn  Zn12  1  0.600  0.999  0.992  1.0
  Ru  Ru13  1  0.400  1.000  0.998  1.0
  Ru  Ru14  1  0.800  0.999  0.999  1.0
  O  O15  1  0.103  0.987  0.996  1.0
  O  O16  1  0.006  0.849  0.656  1.0
  O  O17  1  0.102  0.495  0.995  1.0
  O  O18  1  0.202  0.142  0.361  1.0
  O  O19  1  0.300  0.007  0.001  1.0
  O  O20  1  0.194  0.852  0.637  1.0
  O  O21  1  0.300  0.489  0.997  1.0
  O  O22  1  0.401  0.157  0.320  1.0
  O  O23  1  0.497  0.002  0.999  1.0
  O  O24  1  0.397  0.850  0.681  1.0
  O  O25  1  0.498  0.514  0.004  1.0
  O  O26  1  0.600  0.126  0.336  1.0
  O  O27  1  0.700  0.009  0.002  1.0
  O  O28  1  0.598  0.829  0.643  1.0
  O  O29  1  0.702  0.487  0.995  1.0
  O  O30  1  0.792  0.180  0.321  1.0
  O  O31  1  0.898  0.995  0.999  1.0
  O  O32  1  0.805  0.827  0.680  1.0
  O  O33  1  0.897  0.513  0.004  1.0
  O  O34  1  0.008  0.157  0.362  1.0
[/CIF]
.
The structure described by Sr6La4Zn3(RuO10)2 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(11), one O(14), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(10) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(12), one O(4), one O(5), one O(7), one O(9), and two equivalent O(8) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(15), one O(18), one O(9), and two equivalent O(14) atoms. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(17), one O(19), one O(2), and two equivalent O(18) atoms. In the fifth Sr site, Sr(5) is bonded in a 9-coordinate geometry to one O(12), one O(13), one O(15), one O(17), one O(18), one O(19), one O(20), and two equivalent O(16) atoms. In the sixth Sr site, Sr(6) is bonded in a 9-coordinate geometry to one O(1), one O(16), one O(17), one O(19), one O(2), one O(3), one O(4), and two equivalent O(20) atoms. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(5), one O(7), and two equivalent O(6) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(1), one O(20), one O(3), one O(5), one O(6), one O(7), one O(8), and two equivalent O(4) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(14), one O(15), one O(16), one O(8), one O(9), and two equivalent O(12) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(1), one O(17), one O(18), one O(19), one O(20), one O(3), one O(6), and two equivalent O(2) atoms. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(10), one O(11), one O(5), one O(7), one O(8), and one O(9) atom to form RuO6 octahedra that share corners with two equivalent Zn(2)O6 octahedra and corners with two equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the second Ru site, Ru(2) is bonded to one O(13), one O(15), one O(16), one O(17), one O(18), and one O(19) atom to form RuO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with two equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(17), one O(19), one O(2), one O(20), and one O(3) atom to form ZnO6 octahedra that share corners with two equivalent Ru(2)O6 octahedra and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form ZnO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the third Zn site, Zn(3) is bonded to one O(11), one O(12), one O(13), one O(14), one O(15), and one O(9) atom to form ZnO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with two equivalent Ru(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Sr(6), one La(1), one La(2), one La(4), one Zn(1), and one Zn(2) atom to form distorted OSrLa3Zn2 octahedra that share  a cornercorner with one O(5)Sr2La2ZnRu octahedra,  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(17)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra,  an edgeedge with one O(5)Sr2La2ZnRu octahedra,  an edgeedge with one O(17)Sr3LaZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(19)Sr3LaZnRu octahedra, and faces with two equivalent O(3)SrLa3Zn2 octahedra. The corner-sharing octahedral tilt angles range from 4-60°. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Sr(4), one Sr(6), one La(1), two equivalent La(4), and one Zn(1) atom. In the third O site, O(3) is bonded to one Sr(6), one La(1), one La(2), one La(4), one Zn(1), and one Zn(2) atom to form distorted OSrLa3Zn2 octahedra that share  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(19)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra,  an edgeedge with one O(7)Sr2La2ZnRu octahedra,  an edgeedge with one O(19)Sr3LaZnRu octahedra,  a faceface with one O(5)Sr2La2ZnRu octahedra,  a faceface with one O(17)Sr3LaZnRu octahedra, and faces with two equivalent O(1)SrLa3Zn2 octahedra. The corner-sharing octahedral tilt angles range from 3-60°. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Sr(2), one Sr(6), one La(1), two equivalent La(2), and one Zn(2) atom. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(2), one La(1), one La(2), one Ru(1), and one Zn(2) atom to form distorted OSr2La2ZnRu octahedra that share  a cornercorner with one O(9)Sr3LaZnRu octahedra,  a cornercorner with one O(14)Sr4LaZn octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(10)Sr4LaRu octahedra,  an edgeedge with one O(9)Sr3LaZnRu octahedra,  an edgeedge with one O(1)SrLa3Zn2 octahedra,  a faceface with one O(8)Sr3La2Ru octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra,  a faceface with one O(10)Sr4LaRu octahedra,  a faceface with one O(3)SrLa3Zn2 octahedra, and faces with two equivalent O(7)Sr2La2ZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Sr(1), one La(2), one La(4), two equivalent La(1), and one Zn(2) atom. In the seventh O site, O(7) is bonded to one Sr(1), one Sr(2), one La(1), one La(2), one Ru(1), and one Zn(2) atom to form distorted OSr2La2ZnRu octahedra that share  a cornercorner with one O(11)Sr3LaZnRu octahedra,  a cornercorner with one O(14)Sr4LaZn octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(10)Sr4LaRu octahedra,  an edgeedge with one O(11)Sr3LaZnRu octahedra,  an edgeedge with one O(3)SrLa3Zn2 octahedra,  a faceface with one O(8)Sr3La2Ru octahedra,  a faceface with one O(9)Sr3LaZnRu octahedra,  a faceface with one O(10)Sr4LaRu octahedra,  a faceface with one O(1)SrLa3Zn2 octahedra, and faces with two equivalent O(5)Sr2La2ZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the eighth O site, O(8) is bonded to one Sr(1), two equivalent Sr(2), one La(2), one La(3), and one Ru(1) atom to form distorted OSr3La2Ru octahedra that share  a cornercorner with one O(13)Sr3LaZnRu octahedra,  a cornercorner with one O(15)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(5)Sr2La2ZnRu octahedra, corners with two equivalent O(7)Sr2La2ZnRu octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(11)Sr3LaZnRu octahedra, corners with two equivalent O(9)Sr3LaZnRu octahedra,  an edgeedge with one O(14)Sr4LaZn octahedra, edges with two equivalent O(10)Sr4LaRu octahedra,  a faceface with one O(5)Sr2La2ZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra, and  a faceface with one O(9)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ru(1), and one Zn(3) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(5)Sr2La2ZnRu octahedra,  a cornercorner with one O(13)Sr3LaZnRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(10)Sr4LaRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(5)Sr2La2ZnRu octahedra,  an edgeedge with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(8)Sr3La2Ru octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(10)Sr4LaRu octahedra,  a faceface with one O(14)Sr4LaZn octahedra, and faces with two equivalent O(11)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the tenth O site, O(10) is bonded to one Sr(2), one Sr(3), two equivalent Sr(1), one La(1), and one Ru(1) atom to form distorted OSr4LaRu octahedra that share  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(13)Sr3LaZnRu octahedra,  a cornercorner with one O(15)Sr3LaZnRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(5)Sr2La2ZnRu octahedra, corners with two equivalent O(7)Sr2La2ZnRu octahedra, corners with two equivalent O(11)Sr3LaZnRu octahedra, corners with two equivalent O(9)Sr3LaZnRu octahedra, corners with two equivalent O(10)Sr4LaRu octahedra, edges with two equivalent O(8)Sr3La2Ru octahedra, edges with two equivalent O(14)Sr4LaZn octahedra,  a faceface with one O(5)Sr2La2ZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra, and  a faceface with one O(9)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the eleventh O site, O(11) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ru(1), and one Zn(3) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(15)Sr3LaZnRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra, corners with two equivalent O(8)Sr3La2Ru octahedra, corners with two equivalent O(10)Sr4LaRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(7)Sr2La2ZnRu octahedra,  an edgeedge with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(5)Sr2La2ZnRu octahedra,  a faceface with one O(8)Sr3La2Ru octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(10)Sr4LaRu octahedra,  a faceface with one O(14)Sr4LaZn octahedra, and faces with two equivalent O(9)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one Sr(2), one Sr(3), one Sr(5), two equivalent La(3), and one Zn(3) atom. In the thirteenth O site, O(13) is bonded to one Sr(3), one Sr(4), one Sr(5), one La(3), one Ru(2), and one Zn(3) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(17)Sr3LaZnRu octahedra,  a cornercorner with one O(9)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra, corners with two equivalent O(16)Sr4LaRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(17)Sr3LaZnRu octahedra,  an edgeedge with one O(9)Sr3LaZnRu octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra,  a faceface with one O(19)Sr3LaZnRu octahedra,  a faceface with one O(16)Sr4LaRu octahedra,  a faceface with one O(18)Sr4LaRu octahedra,  a faceface with one O(14)Sr4LaZn octahedra, and faces with two equivalent O(15)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-59°. In the fourteenth O site, O(14) is bonded to one Sr(1), one Sr(4), two equivalent Sr(3), one La(3), and one Zn(3) atom to form distorted OSr4LaZn octahedra that share  a cornercorner with one O(5)Sr2La2ZnRu octahedra,  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(17)Sr3LaZnRu octahedra,  a cornercorner with one O(19)Sr3LaZnRu octahedra, corners with two equivalent O(11)Sr3LaZnRu octahedra, corners with two equivalent O(13)Sr3LaZnRu octahedra, corners with two equivalent O(15)Sr3LaZnRu octahedra, corners with two equivalent O(9)Sr3LaZnRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(8)Sr3La2Ru octahedra,  an edgeedge with one O(16)Sr4LaRu octahedra, edges with two equivalent O(10)Sr4LaRu octahedra, edges with two equivalent O(18)Sr4LaRu octahedra,  a faceface with one O(11)Sr3LaZnRu octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra, and  a faceface with one O(9)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 18-54°. In the fifteenth O site, O(15) is bonded to one Sr(3), one Sr(4), one Sr(5), one La(3), one Ru(2), and one Zn(3) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(11)Sr3LaZnRu octahedra,  a cornercorner with one O(19)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra, corners with two equivalent O(16)Sr4LaRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra, corners with two equivalent O(14)Sr4LaZn octahedra,  an edgeedge with one O(11)Sr3LaZnRu octahedra,  an edgeedge with one O(19)Sr3LaZnRu octahedra,  a faceface with one O(17)Sr3LaZnRu octahedra,  a faceface with one O(9)Sr3LaZnRu octahedra,  a faceface with one O(16)Sr4LaRu octahedra,  a faceface with one O(18)Sr4LaRu octahedra,  a faceface with one O(14)Sr4LaZn octahedra, and faces with two equivalent O(13)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the sixteenth O site, O(16) is bonded to one Sr(4), one Sr(6), two equivalent Sr(5), one La(3), and one Ru(2) atom to form distorted OSr4LaRu octahedra that share  a cornercorner with one O(8)Sr3La2Ru octahedra,  a cornercorner with one O(11)Sr3LaZnRu octahedra,  a cornercorner with one O(9)Sr3LaZnRu octahedra,  a cornercorner with one O(18)Sr4LaRu octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(13)Sr3LaZnRu octahedra, corners with two equivalent O(15)Sr3LaZnRu octahedra, corners with two equivalent O(17)Sr3LaZnRu octahedra, corners with two equivalent O(19)Sr3LaZnRu octahedra, corners with two equivalent O(16)Sr4LaRu octahedra,  an edgeedge with one O(14)Sr4LaZn octahedra, edges with two equivalent O(18)Sr4LaRu octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(17)Sr3LaZnRu octahedra, and  a faceface with one O(19)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the seventeenth O site, O(17) is bonded to one Sr(4), one Sr(5), one Sr(6), one La(4), one Ru(2), and one Zn(1) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(13)Sr3LaZnRu octahedra,  a cornercorner with one O(14)Sr4LaZn octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra, corners with two equivalent O(16)Sr4LaRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra,  an edgeedge with one O(13)Sr3LaZnRu octahedra,  an edgeedge with one O(1)SrLa3Zn2 octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(16)Sr4LaRu octahedra,  a faceface with one O(18)Sr4LaRu octahedra,  a faceface with one O(3)SrLa3Zn2 octahedra, and faces with two equivalent O(19)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the eighteenth O site, O(18) is bonded to one Sr(3), one Sr(5), two equivalent Sr(4), one La(4), and one Ru(2) atom to form distorted OSr4LaRu octahedra that share  a cornercorner with one O(11)Sr3LaZnRu octahedra,  a cornercorner with one O(9)Sr3LaZnRu octahedra,  a cornercorner with one O(10)Sr4LaRu octahedra,  a cornercorner with one O(16)Sr4LaRu octahedra,  a cornercorner with one O(1)SrLa3Zn2 octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(13)Sr3LaZnRu octahedra, corners with two equivalent O(15)Sr3LaZnRu octahedra, corners with two equivalent O(17)Sr3LaZnRu octahedra, corners with two equivalent O(19)Sr3LaZnRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra, edges with two equivalent O(16)Sr4LaRu octahedra, edges with two equivalent O(14)Sr4LaZn octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(15)Sr3LaZnRu octahedra,  a faceface with one O(17)Sr3LaZnRu octahedra, and  a faceface with one O(19)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-59°. In the nineteenth O site, O(19) is bonded to one Sr(4), one Sr(5), one Sr(6), one La(4), one Ru(2), and one Zn(1) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(15)Sr3LaZnRu octahedra,  a cornercorner with one O(14)Sr4LaZn octahedra,  a cornercorner with one O(3)SrLa3Zn2 octahedra, corners with two equivalent O(16)Sr4LaRu octahedra, corners with two equivalent O(18)Sr4LaRu octahedra,  an edgeedge with one O(15)Sr3LaZnRu octahedra,  an edgeedge with one O(3)SrLa3Zn2 octahedra,  a faceface with one O(13)Sr3LaZnRu octahedra,  a faceface with one O(16)Sr4LaRu octahedra,  a faceface with one O(18)Sr4LaRu octahedra,  a faceface with one O(1)SrLa3Zn2 octahedra, and faces with two equivalent O(17)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the twentieth O site, O(20) is bonded in a 6-coordinate geometry to one Sr(5), two equivalent Sr(6), one La(2), one La(4), and one Zn(1) atom. is represented by the CIF file [CIF]
data_Sr6La4Zn3(RuO10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   19.885
_cell_length_b   5.646
_cell_length_c   6.953
_cell_angle_alpha   114.012
_cell_angle_beta   106.681
_cell_angle_gamma   44.836
_symmetry_Int_Tables_number   1
_cell_volume   502.814
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.399  0.357  0.714  1.0
  Sr  Sr1  1  0.400  0.646  0.287  1.0
  Sr  Sr2  1  0.600  0.353  0.713  1.0
  Sr  Sr3  1  0.803  0.348  0.715  1.0
  Sr  Sr4  1  0.799  0.647  0.285  1.0
  Sr  Sr5  1  0.005  0.635  0.279  1.0
  La  La6  1  0.190  0.366  0.721  1.0
  La  La7  1  0.190  0.686  0.279  1.0
  La  La8  1  0.601  0.672  0.287  1.0
  La  La9  1  0.007  0.316  0.722  1.0
  Zn  Zn10  1  0.999  0.003  0.007  1.0
  Zn  Zn11  1  0.200  0.007  0.012  1.0
  Zn  Zn12  1  0.600  0.999  0.992  1.0
  Ru  Ru13  1  0.400  1.000  0.998  1.0
  Ru  Ru14  1  0.800  0.999  0.999  1.0
  O  O15  1  0.103  0.987  0.996  1.0
  O  O16  1  0.006  0.849  0.656  1.0
  O  O17  1  0.102  0.495  0.995  1.0
  O  O18  1  0.202  0.142  0.361  1.0
  O  O19  1  0.300  0.007  0.001  1.0
  O  O20  1  0.194  0.852  0.637  1.0
  O  O21  1  0.300  0.489  0.997  1.0
  O  O22  1  0.401  0.157  0.320  1.0
  O  O23  1  0.497  0.002  0.999  1.0
  O  O24  1  0.397  0.850  0.681  1.0
  O  O25  1  0.498  0.514  0.004  1.0
  O  O26  1  0.600  0.126  0.336  1.0
  O  O27  1  0.700  0.009  0.002  1.0
  O  O28  1  0.598  0.829  0.643  1.0
  O  O29  1  0.702  0.487  0.995  1.0
  O  O30  1  0.792  0.180  0.321  1.0
  O  O31  1  0.898  0.995  0.999  1.0
  O  O32  1  0.805  0.827  0.680  1.0
  O  O33  1  0.897  0.513  0.004  1.0
  O  O34  1  0.008  0.157  0.362  1.0
[/CIF]
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