The structure described by RbV2Fe(AgO4)2 crystallizes in the trigonal P-3 space group. Rb(1) is bonded to six equivalent O(1) and six equivalent O(2) atoms to form RbO12 cuboctahedra that share edges with six equivalent Rb(1)O12 cuboctahedra, edges with six equivalent V(1)O4 tetrahedra, edges with six equivalent Ag(1)O4 tetrahedra, and faces with two equivalent Fe(1)O6 octahedra. V(1) is bonded to one O(1) and three equivalent O(2) atoms to form VO4 tetrahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with four equivalent Ag(1)O4 tetrahedra, and edges with three equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 35°. Fe(1) is bonded to six equivalent O(2) atoms to form FeO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra, corners with six equivalent Ag(1)O4 tetrahedra, and faces with two equivalent Rb(1)O12 cuboctahedra. Ag(1) is bonded to one O(1) and three equivalent O(2) atoms to form AgO4 tetrahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with four equivalent V(1)O4 tetrahedra, and edges with three equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 67°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to three equivalent Rb(1), one V(1), and one Ag(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Rb(1), one V(1), one Fe(1), and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbV2Fe(AgO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.542
_cell_length_b   5.542
_cell_length_c   7.577
_cell_angle_alpha   90.002
_cell_angle_beta   89.996
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   201.518
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.333  0.667  0.734  1.0
  Ag  Ag1  1  0.667  0.333  0.266  1.0
  Fe  Fe2  1  0.000  1.000  0.500  1.0
  O  O3  1  0.333  0.667  0.047  1.0
  O  O4  1  0.667  0.333  0.953  1.0
  O  O5  1  0.077  0.746  0.343  1.0
  O  O6  1  0.670  0.924  0.343  1.0
  O  O7  1  0.254  0.330  0.343  1.0
  O  O8  1  0.923  0.254  0.657  1.0
  O  O9  1  0.330  0.076  0.657  1.0
  O  O10  1  0.746  0.670  0.657  1.0
  Rb  Rb11  1  1.000  1.000  0.000  1.0
  V  V12  1  0.667  0.333  0.729  1.0
  V  V13  1  0.333  0.667  0.271  1.0
[/CIF]
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The structure described by RbV2Fe(AgO4)2 crystallizes in the trigonal P-3 space group. Rb(1) is bonded to six equivalent O(1) and six equivalent O(2) atoms to form RbO12 cuboctahedra that share edges with six equivalent Rb(1)O12 cuboctahedra, edges with six equivalent V(1)O4 tetrahedra, edges with six equivalent Ag(1)O4 tetrahedra, and faces with two equivalent Fe(1)O6 octahedra. V(1) is bonded to one O(1) and three equivalent O(2) atoms to form VO4 tetrahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with four equivalent Ag(1)O4 tetrahedra, and edges with three equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 35°. Fe(1) is bonded to six equivalent O(2) atoms to form FeO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra, corners with six equivalent Ag(1)O4 tetrahedra, and faces with two equivalent Rb(1)O12 cuboctahedra. Ag(1) is bonded to one O(1) and three equivalent O(2) atoms to form AgO4 tetrahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with four equivalent V(1)O4 tetrahedra, and edges with three equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 67°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to three equivalent Rb(1), one V(1), and one Ag(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Rb(1), one V(1), one Fe(1), and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbV2Fe(AgO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.542
_cell_length_b   5.542
_cell_length_c   7.577
_cell_angle_alpha   90.002
_cell_angle_beta   89.996
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   201.518
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.333  0.667  0.734  1.0
  Ag  Ag1  1  0.667  0.333  0.266  1.0
  Fe  Fe2  1  0.000  1.000  0.500  1.0
  O  O3  1  0.333  0.667  0.047  1.0
  O  O4  1  0.667  0.333  0.953  1.0
  O  O5  1  0.077  0.746  0.343  1.0
  O  O6  1  0.670  0.924  0.343  1.0
  O  O7  1  0.254  0.330  0.343  1.0
  O  O8  1  0.923  0.254  0.657  1.0
  O  O9  1  0.330  0.076  0.657  1.0
  O  O10  1  0.746  0.670  0.657  1.0
  Rb  Rb11  1  1.000  1.000  0.000  1.0
  V  V12  1  0.667  0.333  0.729  1.0
  V  V13  1  0.333  0.667  0.271  1.0
[/CIF]
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