The structure described by LiCO2 is Antimony trioxide-derived structured and crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(1) and one C(1) atom. is represented by the CIF file [CIF]
data_LiCO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.572
_cell_length_b   5.200
_cell_length_c   9.132
_cell_angle_alpha   90.000
_cell_angle_beta   94.639
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   169.064
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.548  0.487  0.209  1.0
  Li  Li1  1  0.048  0.013  0.709  1.0
  Li  Li2  1  0.452  0.513  0.791  1.0
  Li  Li3  1  0.952  0.987  0.291  1.0
  C  C4  1  0.393  0.631  0.493  1.0
  C  C5  1  0.893  0.869  0.993  1.0
  C  C6  1  0.607  0.369  0.507  1.0
  C  C7  1  0.107  0.131  0.007  1.0
  O  O8  1  0.360  0.734  0.366  1.0
  O  O9  1  0.860  0.766  0.866  1.0
  O  O10  1  0.640  0.266  0.634  1.0
  O  O11  1  0.140  0.234  0.134  1.0
  O  O12  1  0.269  0.719  0.609  1.0
  O  O13  1  0.769  0.781  0.109  1.0
  O  O14  1  0.731  0.281  0.391  1.0
  O  O15  1  0.231  0.219  0.891  1.0
[/CIF]
.
The structure described by LiCO2 is Antimony trioxide-derived structured and crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(1) and one C(1) atom. is represented by the CIF file [CIF]
data_LiCO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.572
_cell_length_b   5.200
_cell_length_c   9.132
_cell_angle_alpha   90.000
_cell_angle_beta   94.639
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   169.064
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.548  0.487  0.209  1.0
  Li  Li1  1  0.048  0.013  0.709  1.0
  Li  Li2  1  0.452  0.513  0.791  1.0
  Li  Li3  1  0.952  0.987  0.291  1.0
  C  C4  1  0.393  0.631  0.493  1.0
  C  C5  1  0.893  0.869  0.993  1.0
  C  C6  1  0.607  0.369  0.507  1.0
  C  C7  1  0.107  0.131  0.007  1.0
  O  O8  1  0.360  0.734  0.366  1.0
  O  O9  1  0.860  0.766  0.866  1.0
  O  O10  1  0.640  0.266  0.634  1.0
  O  O11  1  0.140  0.234  0.134  1.0
  O  O12  1  0.269  0.719  0.609  1.0
  O  O13  1  0.769  0.781  0.109  1.0
  O  O14  1  0.731  0.281  0.391  1.0
  O  O15  1  0.231  0.219  0.891  1.0
[/CIF]
.