The compound described by CrN5ClPtCl4 is Modderite structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four platinum(iv) chloride molecules and four CrN5Cl clusters. In each CrN5Cl cluster, Cr(1) is bonded in a 5-coordinate geometry to two equivalent N(1), two equivalent N(2), and one Cl(4) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cr(1), one N(2), and one N(3) atom. In the third N site, N(3) is bonded in an L-shaped geometry to two equivalent N(2) atoms. Cl(4) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF card [CIF]
data_CrPt(NCl)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.882
_cell_length_b   11.310
_cell_length_c   14.349
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1279.240
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.250  0.917  0.907  1.0
  Cr  Cr1  1  0.250  0.583  0.407  1.0
  Cr  Cr2  1  0.750  0.083  0.093  1.0
  Cr  Cr3  1  0.750  0.417  0.593  1.0
  Pt  Pt4  1  0.250  0.337  0.846  1.0
  Pt  Pt5  1  0.250  0.163  0.346  1.0
  Pt  Pt6  1  0.750  0.663  0.154  1.0
  Pt  Pt7  1  0.750  0.837  0.654  1.0
  N  N8  1  0.099  0.951  0.837  1.0
  N  N9  1  0.401  0.549  0.337  1.0
  N  N10  1  0.599  0.049  0.163  1.0
  N  N11  1  0.901  0.451  0.663  1.0
  N  N12  1  0.901  0.049  0.163  1.0
  N  N13  1  0.599  0.451  0.663  1.0
  N  N14  1  0.401  0.951  0.837  1.0
  N  N15  1  0.099  0.549  0.337  1.0
  N  N16  1  0.145  0.729  0.897  1.0
  N  N17  1  0.355  0.771  0.397  1.0
  N  N18  1  0.645  0.271  0.103  1.0
  N  N19  1  0.855  0.229  0.603  1.0
  N  N20  1  0.855  0.271  0.103  1.0
  N  N21  1  0.645  0.229  0.603  1.0
  N  N22  1  0.355  0.729  0.897  1.0
  N  N23  1  0.145  0.771  0.397  1.0
  N  N24  1  0.250  0.652  0.860  1.0
  N  N25  1  0.250  0.848  0.360  1.0
  N  N26  1  0.750  0.348  0.140  1.0
  N  N27  1  0.750  0.152  0.640  1.0
  Cl  Cl28  1  0.250  0.425  0.987  1.0
  Cl  Cl29  1  0.250  0.075  0.487  1.0
  Cl  Cl30  1  0.750  0.575  0.013  1.0
  Cl  Cl31  1  0.750  0.925  0.513  1.0
  Cl  Cl32  1  0.963  0.342  0.845  1.0
  Cl  Cl33  1  0.537  0.158  0.345  1.0
  Cl  Cl34  1  0.463  0.658  0.155  1.0
  Cl  Cl35  1  0.037  0.842  0.655  1.0
  Cl  Cl36  1  0.037  0.658  0.155  1.0
  Cl  Cl37  1  0.463  0.842  0.655  1.0
  Cl  Cl38  1  0.537  0.342  0.845  1.0
  Cl  Cl39  1  0.963  0.158  0.345  1.0
  Cl  Cl40  1  0.250  0.231  0.713  1.0
  Cl  Cl41  1  0.250  0.269  0.213  1.0
  Cl  Cl42  1  0.750  0.769  0.287  1.0
  Cl  Cl43  1  0.750  0.731  0.787  1.0
  Cl  Cl44  1  0.250  0.039  0.024  1.0
  Cl  Cl45  1  0.250  0.461  0.524  1.0
  Cl  Cl46  1  0.750  0.961  0.976  1.0
  Cl  Cl47  1  0.750  0.539  0.476  1.0
[/CIF]
.
The compound described by CrN5ClPtCl4 is Modderite structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four platinum(iv) chloride molecules and four CrN5Cl clusters. In each CrN5Cl cluster, Cr(1) is bonded in a 5-coordinate geometry to two equivalent N(1), two equivalent N(2), and one Cl(4) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cr(1), one N(2), and one N(3) atom. In the third N site, N(3) is bonded in an L-shaped geometry to two equivalent N(2) atoms. Cl(4) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF card [CIF]
data_CrPt(NCl)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.882
_cell_length_b   11.310
_cell_length_c   14.349
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1279.240
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.250  0.917  0.907  1.0
  Cr  Cr1  1  0.250  0.583  0.407  1.0
  Cr  Cr2  1  0.750  0.083  0.093  1.0
  Cr  Cr3  1  0.750  0.417  0.593  1.0
  Pt  Pt4  1  0.250  0.337  0.846  1.0
  Pt  Pt5  1  0.250  0.163  0.346  1.0
  Pt  Pt6  1  0.750  0.663  0.154  1.0
  Pt  Pt7  1  0.750  0.837  0.654  1.0
  N  N8  1  0.099  0.951  0.837  1.0
  N  N9  1  0.401  0.549  0.337  1.0
  N  N10  1  0.599  0.049  0.163  1.0
  N  N11  1  0.901  0.451  0.663  1.0
  N  N12  1  0.901  0.049  0.163  1.0
  N  N13  1  0.599  0.451  0.663  1.0
  N  N14  1  0.401  0.951  0.837  1.0
  N  N15  1  0.099  0.549  0.337  1.0
  N  N16  1  0.145  0.729  0.897  1.0
  N  N17  1  0.355  0.771  0.397  1.0
  N  N18  1  0.645  0.271  0.103  1.0
  N  N19  1  0.855  0.229  0.603  1.0
  N  N20  1  0.855  0.271  0.103  1.0
  N  N21  1  0.645  0.229  0.603  1.0
  N  N22  1  0.355  0.729  0.897  1.0
  N  N23  1  0.145  0.771  0.397  1.0
  N  N24  1  0.250  0.652  0.860  1.0
  N  N25  1  0.250  0.848  0.360  1.0
  N  N26  1  0.750  0.348  0.140  1.0
  N  N27  1  0.750  0.152  0.640  1.0
  Cl  Cl28  1  0.250  0.425  0.987  1.0
  Cl  Cl29  1  0.250  0.075  0.487  1.0
  Cl  Cl30  1  0.750  0.575  0.013  1.0
  Cl  Cl31  1  0.750  0.925  0.513  1.0
  Cl  Cl32  1  0.963  0.342  0.845  1.0
  Cl  Cl33  1  0.537  0.158  0.345  1.0
  Cl  Cl34  1  0.463  0.658  0.155  1.0
  Cl  Cl35  1  0.037  0.842  0.655  1.0
  Cl  Cl36  1  0.037  0.658  0.155  1.0
  Cl  Cl37  1  0.463  0.842  0.655  1.0
  Cl  Cl38  1  0.537  0.342  0.845  1.0
  Cl  Cl39  1  0.963  0.158  0.345  1.0
  Cl  Cl40  1  0.250  0.231  0.713  1.0
  Cl  Cl41  1  0.250  0.269  0.213  1.0
  Cl  Cl42  1  0.750  0.769  0.287  1.0
  Cl  Cl43  1  0.750  0.731  0.787  1.0
  Cl  Cl44  1  0.250  0.039  0.024  1.0
  Cl  Cl45  1  0.250  0.461  0.524  1.0
  Cl  Cl46  1  0.750  0.961  0.976  1.0
  Cl  Cl47  1  0.750  0.539  0.476  1.0
[/CIF]
.