The compound described by Rh2Ge3S3 crystallizes in the cubic Pm-3 space group. Rh(1) is bonded to three equivalent Ge(1) and three equivalent S(1) atoms to form corner-sharing RhGe3S3 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. Ge(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent Ge(1) atoms. S(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rh(1) and one S(1) atom. is represented by the CIF card [CIF]
data_Ge3Rh2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.447
_cell_length_b   8.447
_cell_length_c   8.447
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   602.807
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.670  0.000  0.147  1.0
  Ge  Ge1  1  0.330  0.000  0.853  1.0
  Ge  Ge2  1  0.330  0.000  0.147  1.0
  Ge  Ge3  1  0.670  0.000  0.853  1.0
  Ge  Ge4  1  0.147  0.670  0.000  1.0
  Ge  Ge5  1  0.853  0.330  0.000  1.0
  Ge  Ge6  1  0.147  0.330  0.000  1.0
  Ge  Ge7  1  0.853  0.670  0.000  1.0
  Ge  Ge8  1  0.000  0.147  0.670  1.0
  Ge  Ge9  1  0.000  0.853  0.330  1.0
  Ge  Ge10  1  0.000  0.147  0.330  1.0
  Ge  Ge11  1  0.000  0.853  0.670  1.0
  Rh  Rh12  1  0.736  0.264  0.264  1.0
  Rh  Rh13  1  0.264  0.264  0.736  1.0
  Rh  Rh14  1  0.264  0.736  0.264  1.0
  Rh  Rh15  1  0.736  0.736  0.736  1.0
  Rh  Rh16  1  0.264  0.736  0.736  1.0
  Rh  Rh17  1  0.736  0.736  0.264  1.0
  Rh  Rh18  1  0.736  0.264  0.736  1.0
  Rh  Rh19  1  0.264  0.264  0.264  1.0
  S  S20  1  0.170  0.500  0.624  1.0
  S  S21  1  0.830  0.500  0.376  1.0
  S  S22  1  0.830  0.500  0.624  1.0
  S  S23  1  0.170  0.500  0.376  1.0
  S  S24  1  0.624  0.170  0.500  1.0
  S  S25  1  0.376  0.830  0.500  1.0
  S  S26  1  0.624  0.830  0.500  1.0
  S  S27  1  0.376  0.170  0.500  1.0
  S  S28  1  0.500  0.624  0.170  1.0
  S  S29  1  0.500  0.376  0.830  1.0
  S  S30  1  0.500  0.624  0.830  1.0
  S  S31  1  0.500  0.376  0.170  1.0
[/CIF]
.
The compound described by Rh2Ge3S3 crystallizes in the cubic Pm-3 space group. Rh(1) is bonded to three equivalent Ge(1) and three equivalent S(1) atoms to form corner-sharing RhGe3S3 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. Ge(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent Ge(1) atoms. S(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rh(1) and one S(1) atom. is represented by the CIF card [CIF]
data_Ge3Rh2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.447
_cell_length_b   8.447
_cell_length_c   8.447
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   602.807
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.670  0.000  0.147  1.0
  Ge  Ge1  1  0.330  0.000  0.853  1.0
  Ge  Ge2  1  0.330  0.000  0.147  1.0
  Ge  Ge3  1  0.670  0.000  0.853  1.0
  Ge  Ge4  1  0.147  0.670  0.000  1.0
  Ge  Ge5  1  0.853  0.330  0.000  1.0
  Ge  Ge6  1  0.147  0.330  0.000  1.0
  Ge  Ge7  1  0.853  0.670  0.000  1.0
  Ge  Ge8  1  0.000  0.147  0.670  1.0
  Ge  Ge9  1  0.000  0.853  0.330  1.0
  Ge  Ge10  1  0.000  0.147  0.330  1.0
  Ge  Ge11  1  0.000  0.853  0.670  1.0
  Rh  Rh12  1  0.736  0.264  0.264  1.0
  Rh  Rh13  1  0.264  0.264  0.736  1.0
  Rh  Rh14  1  0.264  0.736  0.264  1.0
  Rh  Rh15  1  0.736  0.736  0.736  1.0
  Rh  Rh16  1  0.264  0.736  0.736  1.0
  Rh  Rh17  1  0.736  0.736  0.264  1.0
  Rh  Rh18  1  0.736  0.264  0.736  1.0
  Rh  Rh19  1  0.264  0.264  0.264  1.0
  S  S20  1  0.170  0.500  0.624  1.0
  S  S21  1  0.830  0.500  0.376  1.0
  S  S22  1  0.830  0.500  0.624  1.0
  S  S23  1  0.170  0.500  0.376  1.0
  S  S24  1  0.624  0.170  0.500  1.0
  S  S25  1  0.376  0.830  0.500  1.0
  S  S26  1  0.624  0.830  0.500  1.0
  S  S27  1  0.376  0.170  0.500  1.0
  S  S28  1  0.500  0.624  0.170  1.0
  S  S29  1  0.500  0.376  0.830  1.0
  S  S30  1  0.500  0.624  0.830  1.0
  S  S31  1  0.500  0.376  0.170  1.0
[/CIF]
.