The material structure described by Co4(CuO4)3 crystallizes in the cubic Im-3 space group. Co(1) is bonded to six equivalent O(1) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 41°. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one Cu(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co4(CuO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.184
_cell_length_b   6.185
_cell_length_c   6.185
_cell_angle_alpha   109.480
_cell_angle_beta   109.447
_cell_angle_gamma   109.485
_symmetry_Int_Tables_number   1
_cell_volume   182.114
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  1.000  0.500  0.000  1.0
  Co  Co1  1  0.500  0.000  1.000  1.0
  Co  Co2  1  0.000  0.000  0.500  1.0
  Co  Co3  1  0.500  0.500  0.500  1.0
  Cu  Cu4  1  0.000  0.500  0.500  1.0
  Cu  Cu5  1  0.500  0.500  0.000  1.0
  Cu  Cu6  1  0.500  1.000  0.500  1.0
  O  O7  1  0.504  0.685  0.818  1.0
  O  O8  1  0.496  0.315  0.182  1.0
  O  O9  1  0.133  0.315  0.819  1.0
  O  O10  1  0.818  0.133  0.315  1.0
  O  O11  1  0.315  0.181  0.496  1.0
  O  O12  1  0.315  0.819  0.133  1.0
  O  O13  1  0.818  0.504  0.685  1.0
  O  O14  1  0.685  0.819  0.504  1.0
  O  O15  1  0.867  0.685  0.181  1.0
  O  O16  1  0.182  0.867  0.685  1.0
  O  O17  1  0.685  0.181  0.867  1.0
  O  O18  1  0.182  0.496  0.315  1.0
[/CIF]
.
The material structure described by Co4(CuO4)3 crystallizes in the cubic Im-3 space group. Co(1) is bonded to six equivalent O(1) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 41°. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one Cu(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co4(CuO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.184
_cell_length_b   6.185
_cell_length_c   6.185
_cell_angle_alpha   109.480
_cell_angle_beta   109.447
_cell_angle_gamma   109.485
_symmetry_Int_Tables_number   1
_cell_volume   182.114
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  1.000  0.500  0.000  1.0
  Co  Co1  1  0.500  0.000  1.000  1.0
  Co  Co2  1  0.000  0.000  0.500  1.0
  Co  Co3  1  0.500  0.500  0.500  1.0
  Cu  Cu4  1  0.000  0.500  0.500  1.0
  Cu  Cu5  1  0.500  0.500  0.000  1.0
  Cu  Cu6  1  0.500  1.000  0.500  1.0
  O  O7  1  0.504  0.685  0.818  1.0
  O  O8  1  0.496  0.315  0.182  1.0
  O  O9  1  0.133  0.315  0.819  1.0
  O  O10  1  0.818  0.133  0.315  1.0
  O  O11  1  0.315  0.181  0.496  1.0
  O  O12  1  0.315  0.819  0.133  1.0
  O  O13  1  0.818  0.504  0.685  1.0
  O  O14  1  0.685  0.819  0.504  1.0
  O  O15  1  0.867  0.685  0.181  1.0
  O  O16  1  0.182  0.867  0.685  1.0
  O  O17  1  0.685  0.181  0.867  1.0
  O  O18  1  0.182  0.496  0.315  1.0
[/CIF]
.