The structure described by NaMg14WO16 is alpha Po-derived structured and crystallizes in the tetragonal P4/mmm space group. Na(1) is bonded to two equivalent O(4) and four equivalent O(1) atoms to form NaO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with four equivalent Mg(1)O6 octahedra, edges with four equivalent Mg(4)O6 octahedra, and edges with eight equivalent Mg(2)O6 octahedra. The corner-sharing octahedra are not tilted. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form MgO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent W(1)O6 octahedra, edges with four equivalent Mg(2)O6 octahedra, edges with four equivalent Mg(3)O6 octahedra, and edges with four equivalent Mg(4)O6 octahedra. The corner-sharing octahedra are not tilted. In the second Mg site, Mg(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms to form MgO6 octahedra that share corners with two equivalent Mg(3)O6 octahedra, corners with four equivalent Mg(2)O6 octahedra, edges with two equivalent Na(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mg(2)O6 octahedra, edges with two equivalent Mg(3)O6 octahedra, and edges with four equivalent Mg(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the third Mg site, Mg(3) is bonded to one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms to form MgO6 octahedra that share corners with two equivalent Mg(2)O6 octahedra, corners with four equivalent Mg(3)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mg(2)O6 octahedra, edges with two equivalent Mg(3)O6 octahedra, edges with two equivalent W(1)O6 octahedra, and edges with four equivalent Mg(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fourth Mg site, Mg(4) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MgO6 octahedra that share corners with six equivalent Mg(4)O6 octahedra,  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with four equivalent Mg(2)O6 octahedra, and edges with four equivalent Mg(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. W(1) is bonded to two equivalent O(6) and four equivalent O(2) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Mg(1)O6 octahedra, edges with four equivalent Mg(4)O6 octahedra, and edges with eight equivalent Mg(3)O6 octahedra. The corner-sharing octahedra are not tilted. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Mg(1), two equivalent Mg(2), and two equivalent Mg(4) atoms to form ONaMg5 octahedra that share corners with two equivalent O(2)Mg5W octahedra, corners with four equivalent O(1)NaMg5 octahedra, edges with two equivalent O(2)Mg5W octahedra, edges with two equivalent O(5)Mg6 octahedra, edges with two equivalent O(4)Na2Mg4 octahedra, edges with two equivalent O(1)NaMg5 octahedra, and edges with four equivalent O(3)Mg6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Mg(1), two equivalent Mg(3), two equivalent Mg(4), and one W(1) atom to form OMg5W octahedra that share corners with two equivalent O(1)NaMg5 octahedra, corners with four equivalent O(2)Mg5W octahedra, edges with two equivalent O(6)Mg4W2 octahedra, edges with two equivalent O(2)Mg5W octahedra, edges with two equivalent O(5)Mg6 octahedra, edges with two equivalent O(1)NaMg5 octahedra, and edges with four equivalent O(3)Mg6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(3) is bonded to two equivalent Mg(2), two equivalent Mg(3), and two equivalent Mg(4) atoms to form OMg6 octahedra that share corners with six equivalent O(3)Mg6 octahedra,  an edgeedge with one O(6)Mg4W2 octahedra,  an edgeedge with one O(4)Na2Mg4 octahedra, edges with two equivalent O(5)Mg6 octahedra, edges with four equivalent O(2)Mg5W octahedra, and edges with four equivalent O(1)NaMg5 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth O site, O(4) is bonded to two equivalent Na(1) and four equivalent Mg(2) atoms to form ONa2Mg4 octahedra that share corners with two equivalent O(4)Na2Mg4 octahedra, corners with four equivalent O(5)Mg6 octahedra, edges with four equivalent O(3)Mg6 octahedra, and edges with eight equivalent O(1)NaMg5 octahedra. The corner-sharing octahedra are not tilted. In the fifth O site, O(5) is bonded to two equivalent Mg(1), two equivalent Mg(2), and two equivalent Mg(3) atoms to form OMg6 octahedra that share corners with two equivalent O(6)Mg4W2 octahedra, corners with two equivalent O(5)Mg6 octahedra, corners with two equivalent O(4)Na2Mg4 octahedra, edges with four equivalent O(2)Mg5W octahedra, edges with four equivalent O(3)Mg6 octahedra, and edges with four equivalent O(1)NaMg5 octahedra. The corner-sharing octahedra are not tilted. In the sixth O site, O(6) is bonded to four equivalent Mg(3) and two equivalent W(1) atoms to form OMg4W2 octahedra that share corners with two equivalent O(6)Mg4W2 octahedra, corners with four equivalent O(5)Mg6 octahedra, edges with four equivalent O(3)Mg6 octahedra, and edges with eight equivalent O(2)Mg5W octahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaMg14WO16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.615
_cell_length_b   8.615
_cell_length_c   4.312
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   320.003
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Mg  Mg1  1  0.000  0.500  0.000  1.0
  Mg  Mg2  1  0.500  0.000  0.000  1.0
  Mg  Mg3  1  0.000  0.245  0.500  1.0
  Mg  Mg4  1  0.000  0.755  0.500  1.0
  Mg  Mg5  1  0.500  0.239  0.500  1.0
  Mg  Mg6  1  0.500  0.761  0.500  1.0
  Mg  Mg7  1  0.245  0.000  0.500  1.0
  Mg  Mg8  1  0.239  0.500  0.500  1.0
  Mg  Mg9  1  0.755  0.000  0.500  1.0
  Mg  Mg10  1  0.761  0.500  0.500  1.0
  Mg  Mg11  1  0.242  0.242  0.000  1.0
  Mg  Mg12  1  0.242  0.758  0.000  1.0
  Mg  Mg13  1  0.758  0.242  0.000  1.0
  Mg  Mg14  1  0.758  0.758  0.000  1.0
  W  W15  1  0.500  0.500  0.000  1.0
  O  O16  1  0.265  0.000  0.000  1.0
  O  O17  1  0.249  0.500  0.000  1.0
  O  O18  1  0.735  0.000  0.000  1.0
  O  O19  1  0.751  0.500  0.000  1.0
  O  O20  1  0.252  0.252  0.500  1.0
  O  O21  1  0.252  0.748  0.500  1.0
  O  O22  1  0.748  0.252  0.500  1.0
  O  O23  1  0.748  0.748  0.500  1.0
  O  O24  1  0.000  0.000  0.500  1.0
  O  O25  1  0.000  0.500  0.500  1.0
  O  O26  1  0.500  0.000  0.500  1.0
  O  O27  1  0.500  0.500  0.500  1.0
  O  O28  1  0.000  0.265  0.000  1.0
  O  O29  1  0.000  0.735  0.000  1.0
  O  O30  1  0.500  0.249  0.000  1.0
  O  O31  1  0.500  0.751  0.000  1.0
[/CIF]
.
The structure described by NaMg14WO16 is alpha Po-derived structured and crystallizes in the tetragonal P4/mmm space group. Na(1) is bonded to two equivalent O(4) and four equivalent O(1) atoms to form NaO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with four equivalent Mg(1)O6 octahedra, edges with four equivalent Mg(4)O6 octahedra, and edges with eight equivalent Mg(2)O6 octahedra. The corner-sharing octahedra are not tilted. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form MgO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent W(1)O6 octahedra, edges with four equivalent Mg(2)O6 octahedra, edges with four equivalent Mg(3)O6 octahedra, and edges with four equivalent Mg(4)O6 octahedra. The corner-sharing octahedra are not tilted. In the second Mg site, Mg(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms to form MgO6 octahedra that share corners with two equivalent Mg(3)O6 octahedra, corners with four equivalent Mg(2)O6 octahedra, edges with two equivalent Na(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mg(2)O6 octahedra, edges with two equivalent Mg(3)O6 octahedra, and edges with four equivalent Mg(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the third Mg site, Mg(3) is bonded to one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms to form MgO6 octahedra that share corners with two equivalent Mg(2)O6 octahedra, corners with four equivalent Mg(3)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mg(2)O6 octahedra, edges with two equivalent Mg(3)O6 octahedra, edges with two equivalent W(1)O6 octahedra, and edges with four equivalent Mg(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fourth Mg site, Mg(4) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MgO6 octahedra that share corners with six equivalent Mg(4)O6 octahedra,  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with four equivalent Mg(2)O6 octahedra, and edges with four equivalent Mg(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. W(1) is bonded to two equivalent O(6) and four equivalent O(2) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Mg(1)O6 octahedra, edges with four equivalent Mg(4)O6 octahedra, and edges with eight equivalent Mg(3)O6 octahedra. The corner-sharing octahedra are not tilted. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Mg(1), two equivalent Mg(2), and two equivalent Mg(4) atoms to form ONaMg5 octahedra that share corners with two equivalent O(2)Mg5W octahedra, corners with four equivalent O(1)NaMg5 octahedra, edges with two equivalent O(2)Mg5W octahedra, edges with two equivalent O(5)Mg6 octahedra, edges with two equivalent O(4)Na2Mg4 octahedra, edges with two equivalent O(1)NaMg5 octahedra, and edges with four equivalent O(3)Mg6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Mg(1), two equivalent Mg(3), two equivalent Mg(4), and one W(1) atom to form OMg5W octahedra that share corners with two equivalent O(1)NaMg5 octahedra, corners with four equivalent O(2)Mg5W octahedra, edges with two equivalent O(6)Mg4W2 octahedra, edges with two equivalent O(2)Mg5W octahedra, edges with two equivalent O(5)Mg6 octahedra, edges with two equivalent O(1)NaMg5 octahedra, and edges with four equivalent O(3)Mg6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(3) is bonded to two equivalent Mg(2), two equivalent Mg(3), and two equivalent Mg(4) atoms to form OMg6 octahedra that share corners with six equivalent O(3)Mg6 octahedra,  an edgeedge with one O(6)Mg4W2 octahedra,  an edgeedge with one O(4)Na2Mg4 octahedra, edges with two equivalent O(5)Mg6 octahedra, edges with four equivalent O(2)Mg5W octahedra, and edges with four equivalent O(1)NaMg5 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth O site, O(4) is bonded to two equivalent Na(1) and four equivalent Mg(2) atoms to form ONa2Mg4 octahedra that share corners with two equivalent O(4)Na2Mg4 octahedra, corners with four equivalent O(5)Mg6 octahedra, edges with four equivalent O(3)Mg6 octahedra, and edges with eight equivalent O(1)NaMg5 octahedra. The corner-sharing octahedra are not tilted. In the fifth O site, O(5) is bonded to two equivalent Mg(1), two equivalent Mg(2), and two equivalent Mg(3) atoms to form OMg6 octahedra that share corners with two equivalent O(6)Mg4W2 octahedra, corners with two equivalent O(5)Mg6 octahedra, corners with two equivalent O(4)Na2Mg4 octahedra, edges with four equivalent O(2)Mg5W octahedra, edges with four equivalent O(3)Mg6 octahedra, and edges with four equivalent O(1)NaMg5 octahedra. The corner-sharing octahedra are not tilted. In the sixth O site, O(6) is bonded to four equivalent Mg(3) and two equivalent W(1) atoms to form OMg4W2 octahedra that share corners with two equivalent O(6)Mg4W2 octahedra, corners with four equivalent O(5)Mg6 octahedra, edges with four equivalent O(3)Mg6 octahedra, and edges with eight equivalent O(2)Mg5W octahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaMg14WO16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.615
_cell_length_b   8.615
_cell_length_c   4.312
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   320.003
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Mg  Mg1  1  0.000  0.500  0.000  1.0
  Mg  Mg2  1  0.500  0.000  0.000  1.0
  Mg  Mg3  1  0.000  0.245  0.500  1.0
  Mg  Mg4  1  0.000  0.755  0.500  1.0
  Mg  Mg5  1  0.500  0.239  0.500  1.0
  Mg  Mg6  1  0.500  0.761  0.500  1.0
  Mg  Mg7  1  0.245  0.000  0.500  1.0
  Mg  Mg8  1  0.239  0.500  0.500  1.0
  Mg  Mg9  1  0.755  0.000  0.500  1.0
  Mg  Mg10  1  0.761  0.500  0.500  1.0
  Mg  Mg11  1  0.242  0.242  0.000  1.0
  Mg  Mg12  1  0.242  0.758  0.000  1.0
  Mg  Mg13  1  0.758  0.242  0.000  1.0
  Mg  Mg14  1  0.758  0.758  0.000  1.0
  W  W15  1  0.500  0.500  0.000  1.0
  O  O16  1  0.265  0.000  0.000  1.0
  O  O17  1  0.249  0.500  0.000  1.0
  O  O18  1  0.735  0.000  0.000  1.0
  O  O19  1  0.751  0.500  0.000  1.0
  O  O20  1  0.252  0.252  0.500  1.0
  O  O21  1  0.252  0.748  0.500  1.0
  O  O22  1  0.748  0.252  0.500  1.0
  O  O23  1  0.748  0.748  0.500  1.0
  O  O24  1  0.000  0.000  0.500  1.0
  O  O25  1  0.000  0.500  0.500  1.0
  O  O26  1  0.500  0.000  0.500  1.0
  O  O27  1  0.500  0.500  0.500  1.0
  O  O28  1  0.000  0.265  0.000  1.0
  O  O29  1  0.000  0.735  0.000  1.0
  O  O30  1  0.500  0.249  0.000  1.0
  O  O31  1  0.500  0.751  0.000  1.0
[/CIF]
.