The crystal structure described by NaUVO6 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(5), one O(6), and two equivalent O(4) atoms. U(1) is bonded to one O(1), one O(4), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent V(1)O5 trigonal bipyramids,  an edgeedge with one U(1)O7 pentagonal bipyramid, and edges with two equivalent V(1)O5 trigonal bipyramids. V(1) is bonded to one O(2), one O(3), one O(6), and two equivalent O(1) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, edges with two equivalent U(1)O7 pentagonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one V(1) atom. In the second O site, O(1) is bonded to one Na(1), one U(1), and two equivalent V(1) atoms to form distorted ONaUV2 tetrahedra that share corners with three equivalent O(3)NaU2V tetrahedra,  an edgeedge with one O(3)NaU2V tetrahedra, and  an edgeedge with one O(1)NaUV2 tetrahedra. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent U(1) and one V(1) atom. In the fourth O site, O(3) is bonded to one Na(1), two equivalent U(1), and one V(1) atom to form distorted ONaU2V tetrahedra that share corners with two equivalent O(3)NaU2V tetrahedra, corners with three equivalent O(1)NaUV2 tetrahedra, and  an edgeedge with one O(1)NaUV2 tetrahedra. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one U(1) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to one Na(1) and one U(1) atom. is represented by the CIF card [CIF]
data_NaUVO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.270
_cell_length_b   8.409
_cell_length_c   10.486
_cell_angle_alpha   90.000
_cell_angle_beta   99.054
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   546.035
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.966  0.293  0.677  1.0
  Na  Na1  1  0.034  0.793  0.823  1.0
  Na  Na2  1  0.034  0.707  0.323  1.0
  Na  Na3  1  0.966  0.207  0.177  1.0
  U  U4  1  0.514  0.480  0.818  1.0
  U  U5  1  0.486  0.980  0.682  1.0
  U  U6  1  0.486  0.520  0.182  1.0
  U  U7  1  0.514  0.020  0.318  1.0
  V  V8  1  0.371  0.148  0.955  1.0
  V  V9  1  0.629  0.648  0.545  1.0
  V  V10  1  0.629  0.852  0.045  1.0
  V  V11  1  0.371  0.352  0.455  1.0
  O  O12  1  0.557  0.064  0.104  1.0
  O  O13  1  0.443  0.564  0.396  1.0
  O  O14  1  0.443  0.936  0.896  1.0
  O  O15  1  0.557  0.436  0.604  1.0
  O  O16  1  0.458  0.348  0.008  1.0
  O  O17  1  0.542  0.848  0.492  1.0
  O  O18  1  0.542  0.652  0.992  1.0
  O  O19  1  0.458  0.152  0.508  1.0
  O  O20  1  0.381  0.211  0.786  1.0
  O  O21  1  0.619  0.711  0.714  1.0
  O  O22  1  0.619  0.789  0.214  1.0
  O  O23  1  0.381  0.289  0.286  1.0
  O  O24  1  0.230  0.540  0.774  1.0
  O  O25  1  0.770  0.040  0.726  1.0
  O  O26  1  0.770  0.460  0.226  1.0
  O  O27  1  0.230  0.960  0.274  1.0
  O  O28  1  0.797  0.420  0.855  1.0
  O  O29  1  0.203  0.920  0.645  1.0
  O  O30  1  0.203  0.580  0.145  1.0
  O  O31  1  0.797  0.080  0.355  1.0
  O  O32  1  0.120  0.139  0.978  1.0
  O  O33  1  0.880  0.639  0.522  1.0
  O  O34  1  0.880  0.861  0.022  1.0
  O  O35  1  0.120  0.361  0.478  1.0
[/CIF]
.
The crystal structure described by NaUVO6 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(5), one O(6), and two equivalent O(4) atoms. U(1) is bonded to one O(1), one O(4), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent V(1)O5 trigonal bipyramids,  an edgeedge with one U(1)O7 pentagonal bipyramid, and edges with two equivalent V(1)O5 trigonal bipyramids. V(1) is bonded to one O(2), one O(3), one O(6), and two equivalent O(1) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, edges with two equivalent U(1)O7 pentagonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one V(1) atom. In the second O site, O(1) is bonded to one Na(1), one U(1), and two equivalent V(1) atoms to form distorted ONaUV2 tetrahedra that share corners with three equivalent O(3)NaU2V tetrahedra,  an edgeedge with one O(3)NaU2V tetrahedra, and  an edgeedge with one O(1)NaUV2 tetrahedra. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent U(1) and one V(1) atom. In the fourth O site, O(3) is bonded to one Na(1), two equivalent U(1), and one V(1) atom to form distorted ONaU2V tetrahedra that share corners with two equivalent O(3)NaU2V tetrahedra, corners with three equivalent O(1)NaUV2 tetrahedra, and  an edgeedge with one O(1)NaUV2 tetrahedra. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one U(1) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to one Na(1) and one U(1) atom. is represented by the CIF card [CIF]
data_NaUVO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.270
_cell_length_b   8.409
_cell_length_c   10.486
_cell_angle_alpha   90.000
_cell_angle_beta   99.054
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   546.035
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.966  0.293  0.677  1.0
  Na  Na1  1  0.034  0.793  0.823  1.0
  Na  Na2  1  0.034  0.707  0.323  1.0
  Na  Na3  1  0.966  0.207  0.177  1.0
  U  U4  1  0.514  0.480  0.818  1.0
  U  U5  1  0.486  0.980  0.682  1.0
  U  U6  1  0.486  0.520  0.182  1.0
  U  U7  1  0.514  0.020  0.318  1.0
  V  V8  1  0.371  0.148  0.955  1.0
  V  V9  1  0.629  0.648  0.545  1.0
  V  V10  1  0.629  0.852  0.045  1.0
  V  V11  1  0.371  0.352  0.455  1.0
  O  O12  1  0.557  0.064  0.104  1.0
  O  O13  1  0.443  0.564  0.396  1.0
  O  O14  1  0.443  0.936  0.896  1.0
  O  O15  1  0.557  0.436  0.604  1.0
  O  O16  1  0.458  0.348  0.008  1.0
  O  O17  1  0.542  0.848  0.492  1.0
  O  O18  1  0.542  0.652  0.992  1.0
  O  O19  1  0.458  0.152  0.508  1.0
  O  O20  1  0.381  0.211  0.786  1.0
  O  O21  1  0.619  0.711  0.714  1.0
  O  O22  1  0.619  0.789  0.214  1.0
  O  O23  1  0.381  0.289  0.286  1.0
  O  O24  1  0.230  0.540  0.774  1.0
  O  O25  1  0.770  0.040  0.726  1.0
  O  O26  1  0.770  0.460  0.226  1.0
  O  O27  1  0.230  0.960  0.274  1.0
  O  O28  1  0.797  0.420  0.855  1.0
  O  O29  1  0.203  0.920  0.645  1.0
  O  O30  1  0.203  0.580  0.145  1.0
  O  O31  1  0.797  0.080  0.355  1.0
  O  O32  1  0.120  0.139  0.978  1.0
  O  O33  1  0.880  0.639  0.522  1.0
  O  O34  1  0.880  0.861  0.022  1.0
  O  O35  1  0.120  0.361  0.478  1.0
[/CIF]
.