The material structure described by KN3O4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 11-coordinate geometry to two equivalent N(2), two equivalent O(1), two equivalent O(2), two equivalent O(4), and three equivalent O(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(2), one O(3), and one O(4) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to two equivalent K(1), one N(1), and one N(3) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one N(2), one O(1), and one O(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent K(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. is represented by the CIF card [CIF]
data_KN3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.604
_cell_length_b   6.729
_cell_length_c   9.429
_cell_angle_alpha   51.152
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   474.579
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.158  0.026  0.326  1.0
  K  K1  1  0.658  0.974  0.174  1.0
  K  K2  1  0.842  0.974  0.674  1.0
  K  K3  1  0.342  0.026  0.826  1.0
  N  N4  1  0.658  0.421  0.636  1.0
  N  N5  1  0.842  0.421  0.136  1.0
  N  N6  1  0.342  0.579  0.364  1.0
  N  N7  1  0.123  0.356  0.899  1.0
  N  N8  1  0.623  0.644  0.601  1.0
  N  N9  1  0.877  0.644  0.101  1.0
  N  N10  1  0.377  0.356  0.399  1.0
  N  N11  1  0.158  0.579  0.864  1.0
  N  N12  1  0.039  0.381  0.769  1.0
  N  N13  1  0.539  0.619  0.731  1.0
  N  N14  1  0.461  0.381  0.269  1.0
  N  N15  1  0.961  0.619  0.231  1.0
  O  O16  1  0.461  0.433  0.835  1.0
  O  O17  1  0.961  0.567  0.665  1.0
  O  O18  1  0.039  0.433  0.335  1.0
  O  O19  1  0.539  0.567  0.165  1.0
  O  O20  1  0.457  0.188  0.277  1.0
  O  O21  1  0.957  0.812  0.223  1.0
  O  O22  1  0.543  0.812  0.723  1.0
  O  O23  1  0.043  0.188  0.777  1.0
  O  O24  1  0.657  0.205  0.791  1.0
  O  O25  1  0.843  0.205  0.291  1.0
  O  O26  1  0.343  0.795  0.209  1.0
  O  O27  1  0.298  0.549  0.502  1.0
  O  O28  1  0.798  0.451  0.998  1.0
  O  O29  1  0.702  0.451  0.498  1.0
  O  O30  1  0.202  0.549  0.002  1.0
  O  O31  1  0.157  0.795  0.709  1.0
[/CIF]
.
The material structure described by KN3O4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 11-coordinate geometry to two equivalent N(2), two equivalent O(1), two equivalent O(2), two equivalent O(4), and three equivalent O(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(2), one O(3), and one O(4) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to two equivalent K(1), one N(1), and one N(3) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one N(2), one O(1), and one O(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent K(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. is represented by the CIF card [CIF]
data_KN3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.604
_cell_length_b   6.729
_cell_length_c   9.429
_cell_angle_alpha   51.152
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   474.579
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.158  0.026  0.326  1.0
  K  K1  1  0.658  0.974  0.174  1.0
  K  K2  1  0.842  0.974  0.674  1.0
  K  K3  1  0.342  0.026  0.826  1.0
  N  N4  1  0.658  0.421  0.636  1.0
  N  N5  1  0.842  0.421  0.136  1.0
  N  N6  1  0.342  0.579  0.364  1.0
  N  N7  1  0.123  0.356  0.899  1.0
  N  N8  1  0.623  0.644  0.601  1.0
  N  N9  1  0.877  0.644  0.101  1.0
  N  N10  1  0.377  0.356  0.399  1.0
  N  N11  1  0.158  0.579  0.864  1.0
  N  N12  1  0.039  0.381  0.769  1.0
  N  N13  1  0.539  0.619  0.731  1.0
  N  N14  1  0.461  0.381  0.269  1.0
  N  N15  1  0.961  0.619  0.231  1.0
  O  O16  1  0.461  0.433  0.835  1.0
  O  O17  1  0.961  0.567  0.665  1.0
  O  O18  1  0.039  0.433  0.335  1.0
  O  O19  1  0.539  0.567  0.165  1.0
  O  O20  1  0.457  0.188  0.277  1.0
  O  O21  1  0.957  0.812  0.223  1.0
  O  O22  1  0.543  0.812  0.723  1.0
  O  O23  1  0.043  0.188  0.777  1.0
  O  O24  1  0.657  0.205  0.791  1.0
  O  O25  1  0.843  0.205  0.291  1.0
  O  O26  1  0.343  0.795  0.209  1.0
  O  O27  1  0.298  0.549  0.502  1.0
  O  O28  1  0.798  0.451  0.998  1.0
  O  O29  1  0.702  0.451  0.498  1.0
  O  O30  1  0.202  0.549  0.002  1.0
  O  O31  1  0.157  0.795  0.709  1.0
[/CIF]
.