The material structure described by OsF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two OsF5 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded to one F(1), one F(10), one F(2), one F(5), one F(6), and one F(7) atom to form corner-sharing OsF6 octahedra. The corner-sharing octahedral tilt angles range from 43-46°. In the second Os site, Os(2) is bonded to one F(1), one F(3), one F(4), one F(6), one F(8), and one F(9) atom to form corner-sharing OsF6 octahedra. The corner-sharing octahedral tilt angles range from 43-46°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Os(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Os(2) atom. In the third F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Os(1) and one Os(2) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Os(2) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Os(1) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Os(1) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Os(2) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Os(2) atom. In the ninth F site, F(5) is bonded in a single-bond geometry to one Os(1) atom. In the tenth F site, F(6) is bonded in a bent 150 degrees geometry to one Os(1) and one Os(2) atom. is represented by the CIF card [CIF]
data_OsF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.418
_cell_length_b   9.879
_cell_length_c   12.377
_cell_angle_alpha   90.000
_cell_angle_beta   99.228
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   653.838
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.996  0.257  0.002  1.0
  Os  Os1  1  0.004  0.757  0.498  1.0
  Os  Os2  1  0.004  0.743  0.998  1.0
  Os  Os3  1  0.996  0.243  0.502  1.0
  Os  Os4  1  0.310  0.003  0.203  1.0
  Os  Os5  1  0.690  0.503  0.297  1.0
  Os  Os6  1  0.690  0.997  0.797  1.0
  Os  Os7  1  0.310  0.497  0.703  1.0
  F  F8  1  0.203  0.090  0.054  1.0
  F  F9  1  0.797  0.590  0.446  1.0
  F  F10  1  0.797  0.910  0.946  1.0
  F  F11  1  0.203  0.410  0.554  1.0
  F  F12  1  0.095  0.334  0.138  1.0
  F  F13  1  0.905  0.834  0.362  1.0
  F  F14  1  0.905  0.666  0.862  1.0
  F  F15  1  0.095  0.166  0.638  1.0
  F  F16  1  0.393  0.913  0.335  1.0
  F  F17  1  0.607  0.413  0.165  1.0
  F  F18  1  0.607  0.087  0.665  1.0
  F  F19  1  0.393  0.587  0.835  1.0
  F  F20  1  0.493  0.155  0.249  1.0
  F  F21  1  0.507  0.655  0.251  1.0
  F  F22  1  0.507  0.845  0.751  1.0
  F  F23  1  0.493  0.345  0.749  1.0
  F  F24  1  0.804  0.403  0.948  1.0
  F  F25  1  0.196  0.903  0.552  1.0
  F  F26  1  0.196  0.597  0.052  1.0
  F  F27  1  0.804  0.097  0.448  1.0
  F  F28  1  0.904  0.159  0.856  1.0
  F  F29  1  0.096  0.659  0.644  1.0
  F  F30  1  0.096  0.841  0.144  1.0
  F  F31  1  0.904  0.341  0.356  1.0
  F  F32  1  0.723  0.169  0.047  1.0
  F  F33  1  0.277  0.669  0.453  1.0
  F  F34  1  0.277  0.831  0.953  1.0
  F  F35  1  0.723  0.331  0.547  1.0
  F  F36  1  0.577  0.923  0.147  1.0
  F  F37  1  0.423  0.423  0.353  1.0
  F  F38  1  0.423  0.077  0.853  1.0
  F  F39  1  0.577  0.577  0.647  1.0
  F  F40  1  0.020  0.077  0.244  1.0
  F  F41  1  0.980  0.577  0.256  1.0
  F  F42  1  0.980  0.923  0.756  1.0
  F  F43  1  0.020  0.423  0.744  1.0
  F  F44  1  0.277  0.326  0.950  1.0
  F  F45  1  0.723  0.826  0.550  1.0
  F  F46  1  0.723  0.674  0.050  1.0
  F  F47  1  0.277  0.174  0.450  1.0
[/CIF]
.
The material structure described by OsF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two OsF5 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded to one F(1), one F(10), one F(2), one F(5), one F(6), and one F(7) atom to form corner-sharing OsF6 octahedra. The corner-sharing octahedral tilt angles range from 43-46°. In the second Os site, Os(2) is bonded to one F(1), one F(3), one F(4), one F(6), one F(8), and one F(9) atom to form corner-sharing OsF6 octahedra. The corner-sharing octahedral tilt angles range from 43-46°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Os(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Os(2) atom. In the third F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Os(1) and one Os(2) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Os(2) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Os(1) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Os(1) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Os(2) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Os(2) atom. In the ninth F site, F(5) is bonded in a single-bond geometry to one Os(1) atom. In the tenth F site, F(6) is bonded in a bent 150 degrees geometry to one Os(1) and one Os(2) atom. is represented by the CIF card [CIF]
data_OsF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.418
_cell_length_b   9.879
_cell_length_c   12.377
_cell_angle_alpha   90.000
_cell_angle_beta   99.228
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   653.838
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.996  0.257  0.002  1.0
  Os  Os1  1  0.004  0.757  0.498  1.0
  Os  Os2  1  0.004  0.743  0.998  1.0
  Os  Os3  1  0.996  0.243  0.502  1.0
  Os  Os4  1  0.310  0.003  0.203  1.0
  Os  Os5  1  0.690  0.503  0.297  1.0
  Os  Os6  1  0.690  0.997  0.797  1.0
  Os  Os7  1  0.310  0.497  0.703  1.0
  F  F8  1  0.203  0.090  0.054  1.0
  F  F9  1  0.797  0.590  0.446  1.0
  F  F10  1  0.797  0.910  0.946  1.0
  F  F11  1  0.203  0.410  0.554  1.0
  F  F12  1  0.095  0.334  0.138  1.0
  F  F13  1  0.905  0.834  0.362  1.0
  F  F14  1  0.905  0.666  0.862  1.0
  F  F15  1  0.095  0.166  0.638  1.0
  F  F16  1  0.393  0.913  0.335  1.0
  F  F17  1  0.607  0.413  0.165  1.0
  F  F18  1  0.607  0.087  0.665  1.0
  F  F19  1  0.393  0.587  0.835  1.0
  F  F20  1  0.493  0.155  0.249  1.0
  F  F21  1  0.507  0.655  0.251  1.0
  F  F22  1  0.507  0.845  0.751  1.0
  F  F23  1  0.493  0.345  0.749  1.0
  F  F24  1  0.804  0.403  0.948  1.0
  F  F25  1  0.196  0.903  0.552  1.0
  F  F26  1  0.196  0.597  0.052  1.0
  F  F27  1  0.804  0.097  0.448  1.0
  F  F28  1  0.904  0.159  0.856  1.0
  F  F29  1  0.096  0.659  0.644  1.0
  F  F30  1  0.096  0.841  0.144  1.0
  F  F31  1  0.904  0.341  0.356  1.0
  F  F32  1  0.723  0.169  0.047  1.0
  F  F33  1  0.277  0.669  0.453  1.0
  F  F34  1  0.277  0.831  0.953  1.0
  F  F35  1  0.723  0.331  0.547  1.0
  F  F36  1  0.577  0.923  0.147  1.0
  F  F37  1  0.423  0.423  0.353  1.0
  F  F38  1  0.423  0.077  0.853  1.0
  F  F39  1  0.577  0.577  0.647  1.0
  F  F40  1  0.020  0.077  0.244  1.0
  F  F41  1  0.980  0.577  0.256  1.0
  F  F42  1  0.980  0.923  0.756  1.0
  F  F43  1  0.020  0.423  0.744  1.0
  F  F44  1  0.277  0.326  0.950  1.0
  F  F45  1  0.723  0.826  0.550  1.0
  F  F46  1  0.723  0.674  0.050  1.0
  F  F47  1  0.277  0.174  0.450  1.0
[/CIF]
.