The material described by Na6Cd(SnS3)4 crystallizes in the monoclinic C2/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one S(1), one S(2), two equivalent S(3), and two equivalent S(4) atoms to form NaS6 octahedra that share  a cornercorner with one Cd(1)S6 octahedra, corners with two equivalent Sn(1)S6 octahedra, corners with two equivalent Sn(2)S6 octahedra,  an edgeedge with one Cd(1)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, edges with three equivalent Na(1)S6 octahedra, and edges with three equivalent Na(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the second Na site, Na(2) is bonded to one S(1), one S(2), two equivalent S(3), and two equivalent S(4) atoms to form NaS6 octahedra that share  a cornercorner with one Cd(1)S6 octahedra, corners with two equivalent Sn(1)S6 octahedra, corners with two equivalent Sn(2)S6 octahedra,  an edgeedge with one Cd(1)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, and edges with six equivalent Na(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. Cd(1) is bonded to two equivalent S(1) and four equivalent S(4) atoms to form CdS6 octahedra that share corners with two equivalent Na(2)S6 octahedra, corners with four equivalent Na(1)S6 octahedra, edges with two equivalent Na(2)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with four equivalent Na(1)S6 octahedra, and edges with four equivalent Sn(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent S(2), two equivalent S(3), and two equivalent S(4) atoms to form SnS6 octahedra that share corners with two equivalent Na(2)S6 octahedra, corners with four equivalent Na(1)S6 octahedra,  an edgeedge with one Cd(1)S6 octahedra,  an edgeedge with one Sn(1)S6 octahedra, edges with two equivalent Na(2)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, and edges with four equivalent Na(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the second Sn site, Sn(2) is bonded to two equivalent S(1), two equivalent S(3), and two equivalent S(4) atoms to form SnS6 octahedra that share corners with two equivalent Na(2)S6 octahedra, corners with four equivalent Na(1)S6 octahedra,  an edgeedge with one Sn(2)S6 octahedra, edges with two equivalent Na(2)S6 octahedra, edges with two equivalent Cd(1)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with four equivalent Na(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. There are four inequivalent S sites. In the first S site, S(1) is bonded to one Na(2), two equivalent Na(1), one Cd(1), and two equivalent Sn(2) atoms to form SNa3CdSn2 octahedra that share  a cornercorner with one S(1)Na3CdSn2 octahedra, corners with two equivalent S(4)Na3CdSn2 octahedra,  a cornercorner with one S(2)Na3Sn2 square pyramid, corners with two equivalent S(3)Na3Sn2 square pyramids,  an edgeedge with one S(1)Na3CdSn2 octahedra, edges with six equivalent S(4)Na3CdSn2 octahedra,  an edgeedge with one S(2)Na3Sn2 square pyramid, and edges with four equivalent S(3)Na3Sn2 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the second S site, S(2) is bonded to one Na(2), two equivalent Na(1), and two equivalent Sn(1) atoms to form SNa3Sn2 square pyramids that share  a cornercorner with one S(1)Na3CdSn2 octahedra, corners with two equivalent S(4)Na3CdSn2 octahedra, corners with six equivalent S(3)Na3Sn2 square pyramids,  an edgeedge with one S(1)Na3CdSn2 octahedra, edges with four equivalent S(4)Na3CdSn2 octahedra,  an edgeedge with one S(2)Na3Sn2 square pyramid, and edges with two equivalent S(3)Na3Sn2 square pyramids. The corner-sharing octahedral tilt angles range from 2-4°. In the third S site, S(3) is bonded to one Na(2), two equivalent Na(1), one Sn(1), and one Sn(2) atom to form SNa3Sn2 square pyramids that share  a cornercorner with one S(1)Na3CdSn2 octahedra, corners with two equivalent S(4)Na3CdSn2 octahedra, corners with three equivalent S(2)Na3Sn2 square pyramids, corners with three equivalent S(3)Na3Sn2 square pyramids, edges with two equivalent S(1)Na3CdSn2 octahedra, edges with four equivalent S(4)Na3CdSn2 octahedra,  an edgeedge with one S(2)Na3Sn2 square pyramid, and  an edgeedge with one S(3)Na3Sn2 square pyramid. The corner-sharing octahedral tilt angles range from 3-9°. In the fourth S site, S(4) is bonded to one Na(2), two equivalent Na(1), one Cd(1), one Sn(1), and one Sn(2) atom to form SNa3CdSn2 octahedra that share  a cornercorner with one S(1)Na3CdSn2 octahedra, corners with two equivalent S(4)Na3CdSn2 octahedra,  a cornercorner with one S(2)Na3Sn2 square pyramid, corners with two equivalent S(3)Na3Sn2 square pyramids, edges with three equivalent S(1)Na3CdSn2 octahedra, edges with three equivalent S(4)Na3CdSn2 octahedra, edges with two equivalent S(2)Na3Sn2 square pyramids, and edges with four equivalent S(3)Na3Sn2 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na6Cd(SnS3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.912
_cell_length_b   8.912
_cell_length_c   6.657
_cell_angle_alpha   82.787
_cell_angle_beta   82.787
_cell_angle_gamma   80.924
_symmetry_Int_Tables_number   1
_cell_volume   514.958
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.589  0.908  0.752  1.0
  Na  Na1  1  0.092  0.411  0.248  1.0
  Na  Na2  1  0.908  0.589  0.752  1.0
  Na  Na3  1  0.411  0.092  0.248  1.0
  Na  Na4  1  0.747  0.747  0.248  1.0
  Na  Na5  1  0.253  0.253  0.752  1.0
  Cd  Cd6  1  0.000  0.000  0.500  1.0
  Sn  Sn7  1  0.339  0.661  0.500  1.0
  Sn  Sn8  1  0.826  0.174  0.000  1.0
  Sn  Sn9  1  0.174  0.826  0.000  1.0
  Sn  Sn10  1  0.661  0.339  0.500  1.0
  S  S11  1  0.107  0.107  0.112  1.0
  S  S12  1  0.612  0.612  0.606  1.0
  S  S13  1  0.388  0.388  0.394  1.0
  S  S14  1  0.893  0.893  0.888  1.0
  S  S15  1  0.208  0.570  0.853  1.0
  S  S16  1  0.716  0.065  0.361  1.0
  S  S17  1  0.065  0.716  0.361  1.0
  S  S18  1  0.570  0.208  0.853  1.0
  S  S19  1  0.284  0.935  0.639  1.0
  S  S20  1  0.792  0.430  0.147  1.0
  S  S21  1  0.430  0.792  0.147  1.0
  S  S22  1  0.935  0.284  0.639  1.0
[/CIF]
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The material described by Na6Cd(SnS3)4 crystallizes in the monoclinic C2/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one S(1), one S(2), two equivalent S(3), and two equivalent S(4) atoms to form NaS6 octahedra that share  a cornercorner with one Cd(1)S6 octahedra, corners with two equivalent Sn(1)S6 octahedra, corners with two equivalent Sn(2)S6 octahedra,  an edgeedge with one Cd(1)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, edges with three equivalent Na(1)S6 octahedra, and edges with three equivalent Na(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the second Na site, Na(2) is bonded to one S(1), one S(2), two equivalent S(3), and two equivalent S(4) atoms to form NaS6 octahedra that share  a cornercorner with one Cd(1)S6 octahedra, corners with two equivalent Sn(1)S6 octahedra, corners with two equivalent Sn(2)S6 octahedra,  an edgeedge with one Cd(1)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, and edges with six equivalent Na(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. Cd(1) is bonded to two equivalent S(1) and four equivalent S(4) atoms to form CdS6 octahedra that share corners with two equivalent Na(2)S6 octahedra, corners with four equivalent Na(1)S6 octahedra, edges with two equivalent Na(2)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with four equivalent Na(1)S6 octahedra, and edges with four equivalent Sn(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent S(2), two equivalent S(3), and two equivalent S(4) atoms to form SnS6 octahedra that share corners with two equivalent Na(2)S6 octahedra, corners with four equivalent Na(1)S6 octahedra,  an edgeedge with one Cd(1)S6 octahedra,  an edgeedge with one Sn(1)S6 octahedra, edges with two equivalent Na(2)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, and edges with four equivalent Na(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the second Sn site, Sn(2) is bonded to two equivalent S(1), two equivalent S(3), and two equivalent S(4) atoms to form SnS6 octahedra that share corners with two equivalent Na(2)S6 octahedra, corners with four equivalent Na(1)S6 octahedra,  an edgeedge with one Sn(2)S6 octahedra, edges with two equivalent Na(2)S6 octahedra, edges with two equivalent Cd(1)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with four equivalent Na(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. There are four inequivalent S sites. In the first S site, S(1) is bonded to one Na(2), two equivalent Na(1), one Cd(1), and two equivalent Sn(2) atoms to form SNa3CdSn2 octahedra that share  a cornercorner with one S(1)Na3CdSn2 octahedra, corners with two equivalent S(4)Na3CdSn2 octahedra,  a cornercorner with one S(2)Na3Sn2 square pyramid, corners with two equivalent S(3)Na3Sn2 square pyramids,  an edgeedge with one S(1)Na3CdSn2 octahedra, edges with six equivalent S(4)Na3CdSn2 octahedra,  an edgeedge with one S(2)Na3Sn2 square pyramid, and edges with four equivalent S(3)Na3Sn2 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the second S site, S(2) is bonded to one Na(2), two equivalent Na(1), and two equivalent Sn(1) atoms to form SNa3Sn2 square pyramids that share  a cornercorner with one S(1)Na3CdSn2 octahedra, corners with two equivalent S(4)Na3CdSn2 octahedra, corners with six equivalent S(3)Na3Sn2 square pyramids,  an edgeedge with one S(1)Na3CdSn2 octahedra, edges with four equivalent S(4)Na3CdSn2 octahedra,  an edgeedge with one S(2)Na3Sn2 square pyramid, and edges with two equivalent S(3)Na3Sn2 square pyramids. The corner-sharing octahedral tilt angles range from 2-4°. In the third S site, S(3) is bonded to one Na(2), two equivalent Na(1), one Sn(1), and one Sn(2) atom to form SNa3Sn2 square pyramids that share  a cornercorner with one S(1)Na3CdSn2 octahedra, corners with two equivalent S(4)Na3CdSn2 octahedra, corners with three equivalent S(2)Na3Sn2 square pyramids, corners with three equivalent S(3)Na3Sn2 square pyramids, edges with two equivalent S(1)Na3CdSn2 octahedra, edges with four equivalent S(4)Na3CdSn2 octahedra,  an edgeedge with one S(2)Na3Sn2 square pyramid, and  an edgeedge with one S(3)Na3Sn2 square pyramid. The corner-sharing octahedral tilt angles range from 3-9°. In the fourth S site, S(4) is bonded to one Na(2), two equivalent Na(1), one Cd(1), one Sn(1), and one Sn(2) atom to form SNa3CdSn2 octahedra that share  a cornercorner with one S(1)Na3CdSn2 octahedra, corners with two equivalent S(4)Na3CdSn2 octahedra,  a cornercorner with one S(2)Na3Sn2 square pyramid, corners with two equivalent S(3)Na3Sn2 square pyramids, edges with three equivalent S(1)Na3CdSn2 octahedra, edges with three equivalent S(4)Na3CdSn2 octahedra, edges with two equivalent S(2)Na3Sn2 square pyramids, and edges with four equivalent S(3)Na3Sn2 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na6Cd(SnS3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.912
_cell_length_b   8.912
_cell_length_c   6.657
_cell_angle_alpha   82.787
_cell_angle_beta   82.787
_cell_angle_gamma   80.924
_symmetry_Int_Tables_number   1
_cell_volume   514.958
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.589  0.908  0.752  1.0
  Na  Na1  1  0.092  0.411  0.248  1.0
  Na  Na2  1  0.908  0.589  0.752  1.0
  Na  Na3  1  0.411  0.092  0.248  1.0
  Na  Na4  1  0.747  0.747  0.248  1.0
  Na  Na5  1  0.253  0.253  0.752  1.0
  Cd  Cd6  1  0.000  0.000  0.500  1.0
  Sn  Sn7  1  0.339  0.661  0.500  1.0
  Sn  Sn8  1  0.826  0.174  0.000  1.0
  Sn  Sn9  1  0.174  0.826  0.000  1.0
  Sn  Sn10  1  0.661  0.339  0.500  1.0
  S  S11  1  0.107  0.107  0.112  1.0
  S  S12  1  0.612  0.612  0.606  1.0
  S  S13  1  0.388  0.388  0.394  1.0
  S  S14  1  0.893  0.893  0.888  1.0
  S  S15  1  0.208  0.570  0.853  1.0
  S  S16  1  0.716  0.065  0.361  1.0
  S  S17  1  0.065  0.716  0.361  1.0
  S  S18  1  0.570  0.208  0.853  1.0
  S  S19  1  0.284  0.935  0.639  1.0
  S  S20  1  0.792  0.430  0.147  1.0
  S  S21  1  0.430  0.792  0.147  1.0
  S  S22  1  0.935  0.284  0.639  1.0
[/CIF]
.