The material structure described by Na24In5O15 crystallizes in the cubic I-43m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(2) and three equivalent O(1) atoms to form a mixture of edge and corner-sharing NaO4 tetrahedra. In the second Na site, Na(2) is bonded to one O(2) and three equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing NaO4 trigonal pyramids. There are two inequivalent In sites. In the first In site, In(1) is bonded in a trigonal non-coplanar geometry to one In(2) and three equivalent O(1) atoms. In the second In site, In(2) is bonded to four equivalent In(1) atoms to form InIn4 tetrahedra that share corners with twelve equivalent O(1)Na6In pentagonal bipyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Na(1), three equivalent Na(2), and one In(1) atom to form distorted ONa6In pentagonal bipyramids that share corners with two equivalent O(1)Na6In pentagonal bipyramids,  a cornercorner with one In(2)In4 tetrahedra, and edges with six equivalent O(1)Na6In pentagonal bipyramids. In the second O site, O(2) is bonded in a 8-coordinate geometry to four equivalent Na(1) and four equivalent Na(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na24In5O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.762
_cell_length_b   9.762
_cell_length_c   9.762
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   716.096
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.282  0.547  1.0
  Na  Na1  1  0.784  0.567  0.000  1.0
  Na  Na2  1  0.217  0.433  0.433  1.0
  Na  Na3  1  0.784  0.000  0.567  1.0
  Na  Na4  1  0.783  0.216  0.216  1.0
  Na  Na5  1  0.216  0.216  0.783  1.0
  Na  Na6  1  0.433  0.217  0.433  1.0
  Na  Na7  1  0.567  0.000  0.784  1.0
  Na  Na8  1  0.000  0.784  0.567  1.0
  Na  Na9  1  0.000  0.567  0.784  1.0
  Na  Na10  1  0.282  0.547  0.000  1.0
  Na  Na11  1  0.265  0.718  0.718  1.0
  Na  Na12  1  0.453  0.735  0.453  1.0
  Na  Na13  1  0.000  0.547  0.282  1.0
  Na  Na14  1  0.718  0.718  0.265  1.0
  Na  Na15  1  0.216  0.783  0.216  1.0
  Na  Na16  1  0.547  0.000  0.282  1.0
  Na  Na17  1  0.718  0.265  0.718  1.0
  Na  Na18  1  0.567  0.784  0.000  1.0
  Na  Na19  1  0.433  0.433  0.217  1.0
  Na  Na20  1  0.547  0.282  0.000  1.0
  Na  Na21  1  0.453  0.453  0.735  1.0
  Na  Na22  1  0.282  0.000  0.547  1.0
  Na  Na23  1  0.735  0.453  0.453  1.0
  In  In24  1  0.713  0.713  0.713  1.0
  In  In25  1  0.000  0.287  0.000  1.0
  In  In26  1  0.000  0.000  0.287  1.0
  In  In27  1  0.000  0.000  0.000  1.0
  In  In28  1  0.287  0.000  0.000  1.0
  O  O29  1  0.214  0.214  0.522  1.0
  O  O30  1  0.786  0.308  0.000  1.0
  O  O31  1  0.000  0.500  0.500  1.0
  O  O32  1  0.478  0.692  0.692  1.0
  O  O33  1  0.692  0.478  0.692  1.0
  O  O34  1  0.522  0.214  0.214  1.0
  O  O35  1  0.308  0.000  0.786  1.0
  O  O36  1  0.000  0.786  0.308  1.0
  O  O37  1  0.308  0.786  0.000  1.0
  O  O38  1  0.000  0.308  0.786  1.0
  O  O39  1  0.786  0.000  0.308  1.0
  O  O40  1  0.692  0.692  0.478  1.0
  O  O41  1  0.214  0.522  0.214  1.0
  O  O42  1  0.500  0.500  0.000  1.0
  O  O43  1  0.500  0.000  0.500  1.0
[/CIF]
.
The material structure described by Na24In5O15 crystallizes in the cubic I-43m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(2) and three equivalent O(1) atoms to form a mixture of edge and corner-sharing NaO4 tetrahedra. In the second Na site, Na(2) is bonded to one O(2) and three equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing NaO4 trigonal pyramids. There are two inequivalent In sites. In the first In site, In(1) is bonded in a trigonal non-coplanar geometry to one In(2) and three equivalent O(1) atoms. In the second In site, In(2) is bonded to four equivalent In(1) atoms to form InIn4 tetrahedra that share corners with twelve equivalent O(1)Na6In pentagonal bipyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Na(1), three equivalent Na(2), and one In(1) atom to form distorted ONa6In pentagonal bipyramids that share corners with two equivalent O(1)Na6In pentagonal bipyramids,  a cornercorner with one In(2)In4 tetrahedra, and edges with six equivalent O(1)Na6In pentagonal bipyramids. In the second O site, O(2) is bonded in a 8-coordinate geometry to four equivalent Na(1) and four equivalent Na(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na24In5O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.762
_cell_length_b   9.762
_cell_length_c   9.762
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   716.096
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.282  0.547  1.0
  Na  Na1  1  0.784  0.567  0.000  1.0
  Na  Na2  1  0.217  0.433  0.433  1.0
  Na  Na3  1  0.784  0.000  0.567  1.0
  Na  Na4  1  0.783  0.216  0.216  1.0
  Na  Na5  1  0.216  0.216  0.783  1.0
  Na  Na6  1  0.433  0.217  0.433  1.0
  Na  Na7  1  0.567  0.000  0.784  1.0
  Na  Na8  1  0.000  0.784  0.567  1.0
  Na  Na9  1  0.000  0.567  0.784  1.0
  Na  Na10  1  0.282  0.547  0.000  1.0
  Na  Na11  1  0.265  0.718  0.718  1.0
  Na  Na12  1  0.453  0.735  0.453  1.0
  Na  Na13  1  0.000  0.547  0.282  1.0
  Na  Na14  1  0.718  0.718  0.265  1.0
  Na  Na15  1  0.216  0.783  0.216  1.0
  Na  Na16  1  0.547  0.000  0.282  1.0
  Na  Na17  1  0.718  0.265  0.718  1.0
  Na  Na18  1  0.567  0.784  0.000  1.0
  Na  Na19  1  0.433  0.433  0.217  1.0
  Na  Na20  1  0.547  0.282  0.000  1.0
  Na  Na21  1  0.453  0.453  0.735  1.0
  Na  Na22  1  0.282  0.000  0.547  1.0
  Na  Na23  1  0.735  0.453  0.453  1.0
  In  In24  1  0.713  0.713  0.713  1.0
  In  In25  1  0.000  0.287  0.000  1.0
  In  In26  1  0.000  0.000  0.287  1.0
  In  In27  1  0.000  0.000  0.000  1.0
  In  In28  1  0.287  0.000  0.000  1.0
  O  O29  1  0.214  0.214  0.522  1.0
  O  O30  1  0.786  0.308  0.000  1.0
  O  O31  1  0.000  0.500  0.500  1.0
  O  O32  1  0.478  0.692  0.692  1.0
  O  O33  1  0.692  0.478  0.692  1.0
  O  O34  1  0.522  0.214  0.214  1.0
  O  O35  1  0.308  0.000  0.786  1.0
  O  O36  1  0.000  0.786  0.308  1.0
  O  O37  1  0.308  0.786  0.000  1.0
  O  O38  1  0.000  0.308  0.786  1.0
  O  O39  1  0.786  0.000  0.308  1.0
  O  O40  1  0.692  0.692  0.478  1.0
  O  O41  1  0.214  0.522  0.214  1.0
  O  O42  1  0.500  0.500  0.000  1.0
  O  O43  1  0.500  0.000  0.500  1.0
[/CIF]
.