The material structure described by NaO12Sb is Zintl Phase structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight 7440-36-0 atoms and eight NaO12 clusters. In each NaO12 cluster, Na(1) is bonded in a distorted cuboctahedral geometry to twelve equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to one Na(1) and two equivalent O(1) atoms. is represented by the CIF card [CIF]
data_NaSbO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.969
_cell_length_b   8.969
_cell_length_c   8.969
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   510.217
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Na  Na1  1  0.250  0.250  0.250  1.0
  Sb  Sb2  1  0.500  0.500  0.500  1.0
  Sb  Sb3  1  0.750  0.750  0.750  1.0
  O  O4  1  0.928  0.301  0.301  1.0
  O  O5  1  0.301  0.928  0.470  1.0
  O  O6  1  0.301  0.470  0.928  1.0
  O  O7  1  0.301  0.928  0.301  1.0
  O  O8  1  0.322  0.949  0.780  1.0
  O  O9  1  0.322  0.949  0.949  1.0
  O  O10  1  0.470  0.301  0.301  1.0
  O  O11  1  0.470  0.301  0.928  1.0
  O  O12  1  0.949  0.322  0.949  1.0
  O  O13  1  0.949  0.322  0.780  1.0
  O  O14  1  0.928  0.301  0.470  1.0
  O  O15  1  0.949  0.780  0.949  1.0
  O  O16  1  0.949  0.780  0.322  1.0
  O  O17  1  0.301  0.470  0.301  1.0
  O  O18  1  0.780  0.949  0.322  1.0
  O  O19  1  0.780  0.949  0.949  1.0
  O  O20  1  0.301  0.301  0.928  1.0
  O  O21  1  0.470  0.928  0.301  1.0
  O  O22  1  0.301  0.301  0.470  1.0
  O  O23  1  0.928  0.470  0.301  1.0
  O  O24  1  0.780  0.322  0.949  1.0
  O  O25  1  0.949  0.949  0.322  1.0
  O  O26  1  0.322  0.780  0.949  1.0
  O  O27  1  0.949  0.949  0.780  1.0
[/CIF]
.
The material structure described by NaO12Sb is Zintl Phase structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight 7440-36-0 atoms and eight NaO12 clusters. In each NaO12 cluster, Na(1) is bonded in a distorted cuboctahedral geometry to twelve equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to one Na(1) and two equivalent O(1) atoms. is represented by the CIF card [CIF]
data_NaSbO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.969
_cell_length_b   8.969
_cell_length_c   8.969
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   510.217
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Na  Na1  1  0.250  0.250  0.250  1.0
  Sb  Sb2  1  0.500  0.500  0.500  1.0
  Sb  Sb3  1  0.750  0.750  0.750  1.0
  O  O4  1  0.928  0.301  0.301  1.0
  O  O5  1  0.301  0.928  0.470  1.0
  O  O6  1  0.301  0.470  0.928  1.0
  O  O7  1  0.301  0.928  0.301  1.0
  O  O8  1  0.322  0.949  0.780  1.0
  O  O9  1  0.322  0.949  0.949  1.0
  O  O10  1  0.470  0.301  0.301  1.0
  O  O11  1  0.470  0.301  0.928  1.0
  O  O12  1  0.949  0.322  0.949  1.0
  O  O13  1  0.949  0.322  0.780  1.0
  O  O14  1  0.928  0.301  0.470  1.0
  O  O15  1  0.949  0.780  0.949  1.0
  O  O16  1  0.949  0.780  0.322  1.0
  O  O17  1  0.301  0.470  0.301  1.0
  O  O18  1  0.780  0.949  0.322  1.0
  O  O19  1  0.780  0.949  0.949  1.0
  O  O20  1  0.301  0.301  0.928  1.0
  O  O21  1  0.470  0.928  0.301  1.0
  O  O22  1  0.301  0.301  0.470  1.0
  O  O23  1  0.928  0.470  0.301  1.0
  O  O24  1  0.780  0.322  0.949  1.0
  O  O25  1  0.949  0.949  0.322  1.0
  O  O26  1  0.322  0.780  0.949  1.0
  O  O27  1  0.949  0.949  0.780  1.0
[/CIF]
.