The material structure described by VOF is Hydrophilite-derived structured and crystallizes in the monoclinic Pm space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(5), two equivalent O(1), one F(4), and two equivalent F(6) atoms to form VO3F3 octahedra that share corners with four equivalent V(5)O2F4 octahedra, corners with four equivalent V(7)O4F2 octahedra, and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(8), one F(3), and one F(5) atom to form VO4F2 octahedra that share corners with four equivalent V(5)O2F4 octahedra, corners with four equivalent V(6)O3F3 octahedra, and edges with two equivalent V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the third V site, V(3) is bonded to one O(4), one O(6), two equivalent F(1), and two equivalent F(7) atoms to form VO2F4 octahedra that share corners with four equivalent V(7)O4F2 octahedra, corners with four equivalent V(8)O4F2 octahedra, and edges with two equivalent V(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the fourth V site, V(4) is bonded to one O(3), one O(7), two equivalent F(2), and two equivalent F(8) atoms to form VO2F4 octahedra that share corners with four equivalent V(6)O3F3 octahedra, corners with four equivalent V(8)O4F2 octahedra, and edges with two equivalent V(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the fifth V site, V(5) is bonded to one O(1), one O(8), two equivalent F(3), and two equivalent F(4) atoms to form VO2F4 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(2)O4F2 octahedra, and edges with two equivalent V(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the sixth V site, V(6) is bonded to one O(2), two equivalent O(3), one F(8), and two equivalent F(5) atoms to form VO3F3 octahedra that share corners with four equivalent V(4)O2F4 octahedra, corners with four equivalent V(2)O4F2 octahedra, and edges with two equivalent V(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the seventh V site, V(7) is bonded to two equivalent O(5), two equivalent O(6), one F(1), and one F(6) atom to form VO4F2 octahedra that share corners with four equivalent V(3)O2F4 octahedra, corners with four equivalent V(1)O3F3 octahedra, and edges with two equivalent V(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the eighth V site, V(8) is bonded to two equivalent O(4), two equivalent O(7), one F(2), and one F(7) atom to form VO4F2 octahedra that share corners with four equivalent V(3)O2F4 octahedra, corners with four equivalent V(4)O2F4 octahedra, and edges with two equivalent V(8)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(5) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(6) and two equivalent V(2) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(4) and two equivalent V(6) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(8) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(7) atoms. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(7) atoms. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one V(4) and two equivalent V(8) atoms. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one V(5) and two equivalent V(2) atoms. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(3) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(4) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(5) atoms. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(5) atoms. In the fifth F site, F(5) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(6) atoms. In the sixth F site, F(6) is bonded in a distorted T-shaped geometry to one V(7) and two equivalent V(1) atoms. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(3) atoms. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one V(6) and two equivalent V(4) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.102
_cell_length_b   4.746
_cell_length_c   18.937
_cell_angle_alpha   88.733
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   278.699
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.911  0.249  1.0
  V  V1  1  0.000  0.027  0.000  1.0
  V  V2  1  0.000  0.986  0.500  1.0
  V  V3  1  0.000  0.041  0.750  1.0
  V  V4  1  0.500  0.477  0.125  1.0
  V  V5  1  0.500  0.590  0.875  1.0
  V  V6  1  0.500  0.456  0.375  1.0
  V  V7  1  0.500  0.514  0.625  1.0
  O  O8  1  0.500  0.753  0.199  1.0
  O  O9  1  0.500  0.838  0.952  1.0
  O  O10  1  0.000  0.753  0.824  1.0
  O  O11  1  0.000  0.703  0.575  1.0
  O  O12  1  0.000  0.651  0.327  1.0
  O  O13  1  0.000  0.268  0.425  1.0
  O  O14  1  0.000  0.324  0.675  1.0
  O  O15  1  0.500  0.207  0.050  1.0
  F  F16  1  0.500  0.780  0.452  1.0
  F  F17  1  0.500  0.834  0.701  1.0
  F  F18  1  0.000  0.691  0.077  1.0
  F  F19  1  0.000  0.265  0.176  1.0
  F  F20  1  0.000  0.342  0.921  1.0
  F  F21  1  0.500  0.152  0.296  1.0
  F  F22  1  0.500  0.192  0.549  1.0
  F  F23  1  0.500  0.244  0.801  1.0
[/CIF]
.
The material structure described by VOF is Hydrophilite-derived structured and crystallizes in the monoclinic Pm space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(5), two equivalent O(1), one F(4), and two equivalent F(6) atoms to form VO3F3 octahedra that share corners with four equivalent V(5)O2F4 octahedra, corners with four equivalent V(7)O4F2 octahedra, and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(8), one F(3), and one F(5) atom to form VO4F2 octahedra that share corners with four equivalent V(5)O2F4 octahedra, corners with four equivalent V(6)O3F3 octahedra, and edges with two equivalent V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the third V site, V(3) is bonded to one O(4), one O(6), two equivalent F(1), and two equivalent F(7) atoms to form VO2F4 octahedra that share corners with four equivalent V(7)O4F2 octahedra, corners with four equivalent V(8)O4F2 octahedra, and edges with two equivalent V(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the fourth V site, V(4) is bonded to one O(3), one O(7), two equivalent F(2), and two equivalent F(8) atoms to form VO2F4 octahedra that share corners with four equivalent V(6)O3F3 octahedra, corners with four equivalent V(8)O4F2 octahedra, and edges with two equivalent V(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the fifth V site, V(5) is bonded to one O(1), one O(8), two equivalent F(3), and two equivalent F(4) atoms to form VO2F4 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(2)O4F2 octahedra, and edges with two equivalent V(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the sixth V site, V(6) is bonded to one O(2), two equivalent O(3), one F(8), and two equivalent F(5) atoms to form VO3F3 octahedra that share corners with four equivalent V(4)O2F4 octahedra, corners with four equivalent V(2)O4F2 octahedra, and edges with two equivalent V(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the seventh V site, V(7) is bonded to two equivalent O(5), two equivalent O(6), one F(1), and one F(6) atom to form VO4F2 octahedra that share corners with four equivalent V(3)O2F4 octahedra, corners with four equivalent V(1)O3F3 octahedra, and edges with two equivalent V(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the eighth V site, V(8) is bonded to two equivalent O(4), two equivalent O(7), one F(2), and one F(7) atom to form VO4F2 octahedra that share corners with four equivalent V(3)O2F4 octahedra, corners with four equivalent V(4)O2F4 octahedra, and edges with two equivalent V(8)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(5) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(6) and two equivalent V(2) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(4) and two equivalent V(6) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(8) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(7) atoms. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(7) atoms. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one V(4) and two equivalent V(8) atoms. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one V(5) and two equivalent V(2) atoms. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(3) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(4) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(5) atoms. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(5) atoms. In the fifth F site, F(5) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(6) atoms. In the sixth F site, F(6) is bonded in a distorted T-shaped geometry to one V(7) and two equivalent V(1) atoms. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(3) atoms. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one V(6) and two equivalent V(4) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.102
_cell_length_b   4.746
_cell_length_c   18.937
_cell_angle_alpha   88.733
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   278.699
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.911  0.249  1.0
  V  V1  1  0.000  0.027  0.000  1.0
  V  V2  1  0.000  0.986  0.500  1.0
  V  V3  1  0.000  0.041  0.750  1.0
  V  V4  1  0.500  0.477  0.125  1.0
  V  V5  1  0.500  0.590  0.875  1.0
  V  V6  1  0.500  0.456  0.375  1.0
  V  V7  1  0.500  0.514  0.625  1.0
  O  O8  1  0.500  0.753  0.199  1.0
  O  O9  1  0.500  0.838  0.952  1.0
  O  O10  1  0.000  0.753  0.824  1.0
  O  O11  1  0.000  0.703  0.575  1.0
  O  O12  1  0.000  0.651  0.327  1.0
  O  O13  1  0.000  0.268  0.425  1.0
  O  O14  1  0.000  0.324  0.675  1.0
  O  O15  1  0.500  0.207  0.050  1.0
  F  F16  1  0.500  0.780  0.452  1.0
  F  F17  1  0.500  0.834  0.701  1.0
  F  F18  1  0.000  0.691  0.077  1.0
  F  F19  1  0.000  0.265  0.176  1.0
  F  F20  1  0.000  0.342  0.921  1.0
  F  F21  1  0.500  0.152  0.296  1.0
  F  F22  1  0.500  0.192  0.549  1.0
  F  F23  1  0.500  0.244  0.801  1.0
[/CIF]
.