The structure described by Cs2MnOF5 crystallizes in the orthorhombic Cmm2 space group. Cs(1) is bonded to two equivalent O(1), two equivalent F(1), four equivalent F(2), and four equivalent F(3) atoms to form distorted CsO2F10 cuboctahedra that share corners with twelve equivalent Cs(1)O2F10 cuboctahedra, faces with six equivalent Cs(1)O2F10 cuboctahedra, and faces with four equivalent Mn(1)F6 octahedra. Mn(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form MnF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra and faces with eight equivalent Cs(1)O2F10 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Cs(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to four equivalent Cs(1) and two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to four equivalent Cs(1) and one Mn(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to four equivalent Cs(1) and one Mn(1) atom. is represented by the CIF file [CIF]
data_Cs2MnOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.172
_cell_length_b   6.765
_cell_length_c   6.765
_cell_angle_alpha   94.876
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   190.199
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.493  0.500  0.000  1.0
  Cs  Cs1  1  0.493  0.000  0.500  1.0
  Mn  Mn2  1  0.994  0.000  0.000  1.0
  O  O3  1  0.686  0.500  0.500  1.0
  F  F4  1  0.494  0.000  0.000  1.0
  F  F5  1  0.994  0.188  0.812  1.0
  F  F6  1  0.994  0.812  0.188  1.0
  F  F7  1  0.994  0.796  0.796  1.0
  F  F8  1  0.994  0.204  0.204  1.0
[/CIF]
.
The structure described by Cs2MnOF5 crystallizes in the orthorhombic Cmm2 space group. Cs(1) is bonded to two equivalent O(1), two equivalent F(1), four equivalent F(2), and four equivalent F(3) atoms to form distorted CsO2F10 cuboctahedra that share corners with twelve equivalent Cs(1)O2F10 cuboctahedra, faces with six equivalent Cs(1)O2F10 cuboctahedra, and faces with four equivalent Mn(1)F6 octahedra. Mn(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form MnF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra and faces with eight equivalent Cs(1)O2F10 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Cs(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to four equivalent Cs(1) and two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to four equivalent Cs(1) and one Mn(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to four equivalent Cs(1) and one Mn(1) atom. is represented by the CIF file [CIF]
data_Cs2MnOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.172
_cell_length_b   6.765
_cell_length_c   6.765
_cell_angle_alpha   94.876
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   190.199
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.493  0.500  0.000  1.0
  Cs  Cs1  1  0.493  0.000  0.500  1.0
  Mn  Mn2  1  0.994  0.000  0.000  1.0
  O  O3  1  0.686  0.500  0.500  1.0
  F  F4  1  0.494  0.000  0.000  1.0
  F  F5  1  0.994  0.188  0.812  1.0
  F  F6  1  0.994  0.812  0.188  1.0
  F  F7  1  0.994  0.796  0.796  1.0
  F  F8  1  0.994  0.204  0.204  1.0
[/CIF]
.