The structure described by Ba4Y2PdCu5O14 crystallizes in the orthorhombic Pmmm space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 10-coordinate geometry to two equivalent O(3), two equivalent O(5), two equivalent O(7), and four equivalent O(1) atoms. In the second Ba site, Ba(2) is bonded in a 10-coordinate geometry to two equivalent O(4), two equivalent O(6), two equivalent O(8), and four equivalent O(2) atoms. Y(1) is bonded in a body-centered cubic geometry to two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), two equivalent O(5), and two equivalent O(7) atoms to form corner-sharing CuO5 square pyramids. In the second Cu site, Cu(2) is bonded to one O(2), two equivalent O(6), and two equivalent O(8) atoms to form corner-sharing CuO5 square pyramids. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(3) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Ba(1), one Cu(1), and one Cu(3) atom to form a mixture of distorted edge, face, and corner-sharing OBa4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the second O site, O(2) is bonded to four equivalent Ba(2), one Pd(1), and one Cu(2) atom to form OBa4CuPd octahedra that share corners with four equivalent O(4)Ba4Pd2 octahedra, corners with five equivalent O(2)Ba4CuPd octahedra, edges with four equivalent O(2)Ba4CuPd octahedra, and faces with two equivalent O(4)Ba4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the third O site, O(3) is bonded to four equivalent Ba(1) and two equivalent Cu(3) atoms to form a mixture of distorted edge, face, and corner-sharing OBa4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the fourth O site, O(4) is bonded to four equivalent Ba(2) and two equivalent Pd(1) atoms to form distorted OBa4Pd2 octahedra that share corners with two equivalent O(4)Ba4Pd2 octahedra, corners with eight equivalent O(2)Ba4CuPd octahedra, edges with two equivalent O(4)Ba4Pd2 octahedra, and faces with four equivalent O(2)Ba4CuPd octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ba(1), two equivalent Y(1), and two equivalent Cu(1) atoms. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ba(2), two equivalent Y(1), and two equivalent Cu(2) atoms. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent Y(1), and two equivalent Cu(1) atoms. In the eighth O site, O(8) is bonded in a 6-coordinate geometry to two equivalent Ba(2), two equivalent Y(1), and two equivalent Cu(2) atoms. is represented by the CIF file [CIF]
data_Ba4Y2Cu5PdO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.832
_cell_length_b   3.949
_cell_length_c   24.021
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   363.488
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.500  0.500  0.090  1.0
  Ba  Ba1  1  0.500  0.500  0.594  1.0
  Ba  Ba2  1  0.500  0.500  0.406  1.0
  Ba  Ba3  1  0.500  0.500  0.910  1.0
  Y  Y4  1  0.500  0.500  0.248  1.0
  Y  Y5  1  0.500  0.500  0.752  1.0
  Cu  Cu6  1  0.000  0.000  0.177  1.0
  Cu  Cu7  1  0.000  0.000  0.679  1.0
  Cu  Cu8  1  0.000  0.000  0.321  1.0
  Cu  Cu9  1  0.000  0.000  0.823  1.0
  Cu  Cu10  1  0.000  0.000  0.000  1.0
  Pd  Pd11  1  0.000  0.000  0.500  1.0
  O  O12  1  0.000  0.000  0.078  1.0
  O  O13  1  0.000  0.000  0.585  1.0
  O  O14  1  0.000  0.000  0.415  1.0
  O  O15  1  0.000  0.000  0.922  1.0
  O  O16  1  0.000  0.500  0.000  1.0
  O  O17  1  0.000  0.500  0.500  1.0
  O  O18  1  0.500  0.000  0.190  1.0
  O  O19  1  0.500  0.000  0.693  1.0
  O  O20  1  0.500  0.000  0.307  1.0
  O  O21  1  0.500  0.000  0.810  1.0
  O  O22  1  0.000  0.500  0.189  1.0
  O  O23  1  0.000  0.500  0.691  1.0
  O  O24  1  0.000  0.500  0.309  1.0
  O  O25  1  0.000  0.500  0.811  1.0
[/CIF]
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The structure described by Ba4Y2PdCu5O14 crystallizes in the orthorhombic Pmmm space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 10-coordinate geometry to two equivalent O(3), two equivalent O(5), two equivalent O(7), and four equivalent O(1) atoms. In the second Ba site, Ba(2) is bonded in a 10-coordinate geometry to two equivalent O(4), two equivalent O(6), two equivalent O(8), and four equivalent O(2) atoms. Y(1) is bonded in a body-centered cubic geometry to two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), two equivalent O(5), and two equivalent O(7) atoms to form corner-sharing CuO5 square pyramids. In the second Cu site, Cu(2) is bonded to one O(2), two equivalent O(6), and two equivalent O(8) atoms to form corner-sharing CuO5 square pyramids. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(3) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Ba(1), one Cu(1), and one Cu(3) atom to form a mixture of distorted edge, face, and corner-sharing OBa4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the second O site, O(2) is bonded to four equivalent Ba(2), one Pd(1), and one Cu(2) atom to form OBa4CuPd octahedra that share corners with four equivalent O(4)Ba4Pd2 octahedra, corners with five equivalent O(2)Ba4CuPd octahedra, edges with four equivalent O(2)Ba4CuPd octahedra, and faces with two equivalent O(4)Ba4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the third O site, O(3) is bonded to four equivalent Ba(1) and two equivalent Cu(3) atoms to form a mixture of distorted edge, face, and corner-sharing OBa4Cu2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the fourth O site, O(4) is bonded to four equivalent Ba(2) and two equivalent Pd(1) atoms to form distorted OBa4Pd2 octahedra that share corners with two equivalent O(4)Ba4Pd2 octahedra, corners with eight equivalent O(2)Ba4CuPd octahedra, edges with two equivalent O(4)Ba4Pd2 octahedra, and faces with four equivalent O(2)Ba4CuPd octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ba(1), two equivalent Y(1), and two equivalent Cu(1) atoms. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ba(2), two equivalent Y(1), and two equivalent Cu(2) atoms. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent Y(1), and two equivalent Cu(1) atoms. In the eighth O site, O(8) is bonded in a 6-coordinate geometry to two equivalent Ba(2), two equivalent Y(1), and two equivalent Cu(2) atoms. is represented by the CIF file [CIF]
data_Ba4Y2Cu5PdO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.832
_cell_length_b   3.949
_cell_length_c   24.021
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   363.488
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.500  0.500  0.090  1.0
  Ba  Ba1  1  0.500  0.500  0.594  1.0
  Ba  Ba2  1  0.500  0.500  0.406  1.0
  Ba  Ba3  1  0.500  0.500  0.910  1.0
  Y  Y4  1  0.500  0.500  0.248  1.0
  Y  Y5  1  0.500  0.500  0.752  1.0
  Cu  Cu6  1  0.000  0.000  0.177  1.0
  Cu  Cu7  1  0.000  0.000  0.679  1.0
  Cu  Cu8  1  0.000  0.000  0.321  1.0
  Cu  Cu9  1  0.000  0.000  0.823  1.0
  Cu  Cu10  1  0.000  0.000  0.000  1.0
  Pd  Pd11  1  0.000  0.000  0.500  1.0
  O  O12  1  0.000  0.000  0.078  1.0
  O  O13  1  0.000  0.000  0.585  1.0
  O  O14  1  0.000  0.000  0.415  1.0
  O  O15  1  0.000  0.000  0.922  1.0
  O  O16  1  0.000  0.500  0.000  1.0
  O  O17  1  0.000  0.500  0.500  1.0
  O  O18  1  0.500  0.000  0.190  1.0
  O  O19  1  0.500  0.000  0.693  1.0
  O  O20  1  0.500  0.000  0.307  1.0
  O  O21  1  0.500  0.000  0.810  1.0
  O  O22  1  0.000  0.500  0.189  1.0
  O  O23  1  0.000  0.500  0.691  1.0
  O  O24  1  0.000  0.500  0.309  1.0
  O  O25  1  0.000  0.500  0.811  1.0
[/CIF]
.