The material described by V12Ag5O32 crystallizes in the monoclinic Cm space group. There are nine inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(11), one O(19), one O(4), and two equivalent O(12) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(10), one O(20), one O(5), and two equivalent O(12) atoms. In the third V site, V(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(21), and one O(6) atom. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(1), one O(17), one O(5), one O(7), and two equivalent O(15) atoms. In the fifth V site, V(5) is bonded in a 6-coordinate geometry to one O(16), one O(2), one O(4), one O(8), and two equivalent O(15) atoms. In the sixth V site, V(6) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(18), one O(3), one O(6), and one O(9) atom. In the seventh V site, V(7) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(22), one O(8), and two equivalent O(18) atoms. In the eighth V site, V(8) is bonded in a 6-coordinate geometry to one O(13), one O(17), one O(23), one O(7), and two equivalent O(18) atoms. In the ninth V site, V(9) is bonded in a 6-coordinate geometry to one O(15), one O(16), one O(17), one O(18), one O(24), and one O(9) atom. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(4), two equivalent O(21), and two equivalent O(24) atoms to form edge-sharing AgO6 octahedra. In the second Ag site, Ag(2) is bonded to one O(2), one O(5), two equivalent O(21), and two equivalent O(24) atoms to form edge-sharing AgO6 octahedra. In the third Ag site, Ag(3) is bonded to one O(19), one O(20), one O(22), one O(23), one O(3), and one O(6) atom to form edge-sharing AgO6 octahedra. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to one O(23), one O(7), and two equivalent O(9) atoms. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(4) and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(5) and one Ag(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(6) and one Ag(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(5), and one Ag(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one Ag(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(3), one V(6), and one Ag(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(4), one V(8), and one Ag(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(5) and one V(7) atom. In the ninth O site, O(9) is bonded in a trigonal non-coplanar geometry to one V(6), one V(9), and one Ag(4) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent V(3) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(3) atoms. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(2), and one V(3) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(6) atoms. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(6) atoms. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one V(4), one V(5), and one V(9) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one V(5), one V(7), and two equivalent V(9) atoms. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one V(4), one V(8), and two equivalent V(9) atoms. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one V(6), one V(7), one V(8), and one V(9) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Ag(3) atoms. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one V(2) and two equivalent Ag(3) atoms. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one V(3), one Ag(1), and one Ag(2) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one V(7) and two equivalent Ag(3) atoms. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one V(8), one Ag(4), and two equivalent Ag(3) atoms. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one V(9), one Ag(1), and one Ag(2) atom. is represented by the CIF file [CIF]
data_V12Ag5O32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.408
_cell_length_b   8.408
_cell_length_c   12.442
_cell_angle_alpha   74.048
_cell_angle_beta   74.048
_cell_angle_gamma   51.457
_symmetry_Int_Tables_number   1
_cell_volume   655.212
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.964  0.964  0.459  1.0
  V  V1  1  0.463  0.463  0.460  1.0
  V  V2  1  0.537  0.036  0.540  1.0
  V  V3  1  0.036  0.537  0.540  1.0
  V  V4  1  0.494  0.494  0.193  1.0
  V  V5  1  0.993  0.993  0.189  1.0
  V  V6  1  0.006  0.505  0.805  1.0
  V  V7  1  0.505  0.006  0.805  1.0
  V  V8  1  0.075  0.075  0.921  1.0
  V  V9  1  0.579  0.579  0.919  1.0
  V  V10  1  0.427  0.925  0.080  1.0
  V  V11  1  0.925  0.427  0.080  1.0
  Ag  Ag12  1  0.213  0.213  0.321  1.0
  Ag  Ag13  1  0.713  0.713  0.320  1.0
  Ag  Ag14  1  0.285  0.787  0.680  1.0
  Ag  Ag15  1  0.787  0.285  0.680  1.0
  Ag  Ag16  1  0.357  0.357  0.979  1.0
  O  O17  1  0.385  0.385  0.267  1.0
  O  O18  1  0.885  0.885  0.268  1.0
  O  O19  1  0.117  0.615  0.731  1.0
  O  O20  1  0.615  0.117  0.731  1.0
  O  O21  1  0.044  0.044  0.324  1.0
  O  O22  1  0.544  0.544  0.324  1.0
  O  O23  1  0.455  0.954  0.674  1.0
  O  O24  1  0.954  0.455  0.674  1.0
  O  O25  1  0.478  0.478  0.046  1.0
  O  O26  1  0.977  0.977  0.046  1.0
  O  O27  1  0.026  0.522  0.957  1.0
  O  O28  1  0.522  0.026  0.957  1.0
  O  O29  1  0.326  0.326  0.538  1.0
  O  O30  1  0.826  0.826  0.538  1.0
  O  O31  1  0.175  0.675  0.461  1.0
  O  O32  1  0.675  0.175  0.461  1.0
  O  O33  1  0.715  0.715  0.831  1.0
  O  O34  1  0.216  0.216  0.830  1.0
  O  O35  1  0.782  0.283  0.173  1.0
  O  O36  1  0.283  0.782  0.173  1.0
  O  O37  1  0.142  0.142  0.072  1.0
  O  O38  1  0.642  0.642  0.071  1.0
  O  O39  1  0.357  0.857  0.929  1.0
  O  O40  1  0.857  0.357  0.929  1.0
  O  O41  1  0.024  0.024  0.550  1.0
  O  O42  1  0.524  0.524  0.550  1.0
  O  O43  1  0.476  0.976  0.449  1.0
  O  O44  1  0.976  0.476  0.449  1.0
  O  O45  1  0.029  0.029  0.816  1.0
  O  O46  1  0.529  0.529  0.816  1.0
  O  O47  1  0.471  0.971  0.186  1.0
  O  O48  1  0.971  0.471  0.186  1.0
[/CIF]
.
The material described by V12Ag5O32 crystallizes in the monoclinic Cm space group. There are nine inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(11), one O(19), one O(4), and two equivalent O(12) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(10), one O(20), one O(5), and two equivalent O(12) atoms. In the third V site, V(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(21), and one O(6) atom. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(1), one O(17), one O(5), one O(7), and two equivalent O(15) atoms. In the fifth V site, V(5) is bonded in a 6-coordinate geometry to one O(16), one O(2), one O(4), one O(8), and two equivalent O(15) atoms. In the sixth V site, V(6) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(18), one O(3), one O(6), and one O(9) atom. In the seventh V site, V(7) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(22), one O(8), and two equivalent O(18) atoms. In the eighth V site, V(8) is bonded in a 6-coordinate geometry to one O(13), one O(17), one O(23), one O(7), and two equivalent O(18) atoms. In the ninth V site, V(9) is bonded in a 6-coordinate geometry to one O(15), one O(16), one O(17), one O(18), one O(24), and one O(9) atom. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(4), two equivalent O(21), and two equivalent O(24) atoms to form edge-sharing AgO6 octahedra. In the second Ag site, Ag(2) is bonded to one O(2), one O(5), two equivalent O(21), and two equivalent O(24) atoms to form edge-sharing AgO6 octahedra. In the third Ag site, Ag(3) is bonded to one O(19), one O(20), one O(22), one O(23), one O(3), and one O(6) atom to form edge-sharing AgO6 octahedra. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to one O(23), one O(7), and two equivalent O(9) atoms. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(4) and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(5) and one Ag(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(6) and one Ag(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(5), and one Ag(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one Ag(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(3), one V(6), and one Ag(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(4), one V(8), and one Ag(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(5) and one V(7) atom. In the ninth O site, O(9) is bonded in a trigonal non-coplanar geometry to one V(6), one V(9), and one Ag(4) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent V(3) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(3) atoms. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(2), and one V(3) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(6) atoms. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(6) atoms. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one V(4), one V(5), and one V(9) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one V(5), one V(7), and two equivalent V(9) atoms. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one V(4), one V(8), and two equivalent V(9) atoms. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one V(6), one V(7), one V(8), and one V(9) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Ag(3) atoms. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one V(2) and two equivalent Ag(3) atoms. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one V(3), one Ag(1), and one Ag(2) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one V(7) and two equivalent Ag(3) atoms. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one V(8), one Ag(4), and two equivalent Ag(3) atoms. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one V(9), one Ag(1), and one Ag(2) atom. is represented by the CIF file [CIF]
data_V12Ag5O32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.408
_cell_length_b   8.408
_cell_length_c   12.442
_cell_angle_alpha   74.048
_cell_angle_beta   74.048
_cell_angle_gamma   51.457
_symmetry_Int_Tables_number   1
_cell_volume   655.212
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.964  0.964  0.459  1.0
  V  V1  1  0.463  0.463  0.460  1.0
  V  V2  1  0.537  0.036  0.540  1.0
  V  V3  1  0.036  0.537  0.540  1.0
  V  V4  1  0.494  0.494  0.193  1.0
  V  V5  1  0.993  0.993  0.189  1.0
  V  V6  1  0.006  0.505  0.805  1.0
  V  V7  1  0.505  0.006  0.805  1.0
  V  V8  1  0.075  0.075  0.921  1.0
  V  V9  1  0.579  0.579  0.919  1.0
  V  V10  1  0.427  0.925  0.080  1.0
  V  V11  1  0.925  0.427  0.080  1.0
  Ag  Ag12  1  0.213  0.213  0.321  1.0
  Ag  Ag13  1  0.713  0.713  0.320  1.0
  Ag  Ag14  1  0.285  0.787  0.680  1.0
  Ag  Ag15  1  0.787  0.285  0.680  1.0
  Ag  Ag16  1  0.357  0.357  0.979  1.0
  O  O17  1  0.385  0.385  0.267  1.0
  O  O18  1  0.885  0.885  0.268  1.0
  O  O19  1  0.117  0.615  0.731  1.0
  O  O20  1  0.615  0.117  0.731  1.0
  O  O21  1  0.044  0.044  0.324  1.0
  O  O22  1  0.544  0.544  0.324  1.0
  O  O23  1  0.455  0.954  0.674  1.0
  O  O24  1  0.954  0.455  0.674  1.0
  O  O25  1  0.478  0.478  0.046  1.0
  O  O26  1  0.977  0.977  0.046  1.0
  O  O27  1  0.026  0.522  0.957  1.0
  O  O28  1  0.522  0.026  0.957  1.0
  O  O29  1  0.326  0.326  0.538  1.0
  O  O30  1  0.826  0.826  0.538  1.0
  O  O31  1  0.175  0.675  0.461  1.0
  O  O32  1  0.675  0.175  0.461  1.0
  O  O33  1  0.715  0.715  0.831  1.0
  O  O34  1  0.216  0.216  0.830  1.0
  O  O35  1  0.782  0.283  0.173  1.0
  O  O36  1  0.283  0.782  0.173  1.0
  O  O37  1  0.142  0.142  0.072  1.0
  O  O38  1  0.642  0.642  0.071  1.0
  O  O39  1  0.357  0.857  0.929  1.0
  O  O40  1  0.857  0.357  0.929  1.0
  O  O41  1  0.024  0.024  0.550  1.0
  O  O42  1  0.524  0.524  0.550  1.0
  O  O43  1  0.476  0.976  0.449  1.0
  O  O44  1  0.976  0.476  0.449  1.0
  O  O45  1  0.029  0.029  0.816  1.0
  O  O46  1  0.529  0.529  0.816  1.0
  O  O47  1  0.471  0.971  0.186  1.0
  O  O48  1  0.971  0.471  0.186  1.0
[/CIF]
.