The structure described by Li5V3Mn2O10 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(7), one O(9), and two equivalent O(5) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the third Li site, Li(3) is bonded to one O(10), one O(2), one O(8), one O(9), and two equivalent O(6) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the fifth Li site, Li(5) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with four equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(8), one O(9), and two equivalent O(2) atoms to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the third V site, V(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the fourth V site, V(4) is bonded to one O(10), one O(3), one O(4), one O(7), and two equivalent O(1) atoms to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(2), one O(4), one O(8), and two equivalent O(6) atoms to form distorted MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(7), one O(9), and two equivalent O(5) atoms to form distorted MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one V(1), two equivalent V(4), and one Mn(2) atom to form OLi2MnV3 octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(1)Li2MnV3 octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(10)Li4MnV octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, edges with three equivalent O(3)Li2MnV3 octahedra, and edges with three equivalent O(7)Li3MnV2 octahedra. The corner-sharing octahedral tilt angles range from 0-22°. In the second O site, O(2) is bonded to one Li(3), one Li(5), one V(3), two equivalent V(2), and one Mn(1) atom to form OLi2MnV3 octahedra that share  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(2)Li2MnV3 octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(10)Li4MnV octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(6)Li4Mn2 octahedra, edges with three equivalent O(4)Li2MnV3 octahedra, and edges with three equivalent O(8)Li3MnV2 octahedra. The corner-sharing octahedral tilt angles range from 0-22°. In the third O site, O(3) is bonded to one Li(4), one Li(5), one V(1), one V(2), one V(4), and one Mn(2) atom to form OLi2MnV3 octahedra that share  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(2)Li2MnV3 octahedra,  an edgeedge with one O(8)Li3MnV2 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(4)Li2MnV3 octahedra, edges with two equivalent O(7)Li3MnV2 octahedra, and edges with three equivalent O(1)Li2MnV3 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one V(2), one V(3), one V(4), and one Mn(1) atom to form OLi2MnV3 octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  an edgeedge with one O(1)Li2MnV3 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(6)Li4Mn2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(3)Li2MnV3 octahedra, edges with two equivalent O(8)Li3MnV2 octahedra, and edges with three equivalent O(2)Li2MnV3 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the fifth O site, O(5) is bonded to one Li(1), one Li(4), two equivalent Li(2), and two equivalent Mn(2) atoms to form OLi4Mn2 octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(8)Li3MnV2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra, edges with two equivalent O(1)Li2MnV3 octahedra, edges with two equivalent O(7)Li3MnV2 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, and edges with three equivalent O(9)Li4MnV octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the sixth O site, O(6) is bonded to one Li(1), one Li(5), two equivalent Li(3), and two equivalent Mn(1) atoms to form OLi4Mn2 octahedra that share  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(2)Li2MnV3 octahedra, edges with two equivalent O(8)Li3MnV2 octahedra, edges with two equivalent O(6)Li4Mn2 octahedra, and edges with three equivalent O(10)Li4MnV octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(5), one V(1), one V(4), and one Mn(2) atom to form distorted OLi3MnV2 octahedra that share  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(6)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(3)Li2MnV3 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, edges with two equivalent O(10)Li4MnV octahedra, and edges with three equivalent O(1)Li2MnV3 octahedra. The corner-sharing octahedral tilt angles range from 0-22°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one V(2), one V(3), and one Mn(1) atom to form distorted OLi3MnV2 octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra, edges with two equivalent O(4)Li2MnV3 octahedra, edges with two equivalent O(6)Li4Mn2 octahedra, edges with two equivalent O(9)Li4MnV octahedra, and edges with three equivalent O(2)Li2MnV3 octahedra. The corner-sharing octahedral tilt angles range from 0-22°. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(2), and one Mn(2) atom to form OLi4MnV octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  an edgeedge with one O(1)Li2MnV3 octahedra,  an edgeedge with one O(2)Li2MnV3 octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(6)Li4Mn2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra, edges with two equivalent O(8)Li3MnV2 octahedra, and edges with three equivalent O(5)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(4), and one Mn(1) atom to form OLi4MnV octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(1)Li2MnV3 octahedra,  an edgeedge with one O(2)Li2MnV3 octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(8)Li3MnV2 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(7)Li3MnV2 octahedra, and edges with three equivalent O(6)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. is represented by the CIF file [CIF]
data_Li5Mn2V3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.172
_cell_length_b   5.274
_cell_length_c   7.883
_cell_angle_alpha   106.158
_cell_angle_beta   103.465
_cell_angle_gamma   101.241
_symmetry_Int_Tables_number   1
_cell_volume   192.914
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  Li  Li1  1  0.209  0.929  0.420  1.0
  Li  Li2  1  0.791  0.071  0.580  1.0
  Li  Li3  1  0.378  0.280  0.764  1.0
  Li  Li4  1  0.622  0.720  0.236  1.0
  Mn  Mn5  1  0.095  0.697  0.688  1.0
  Mn  Mn6  1  0.905  0.303  0.312  1.0
  O  O7  1  0.051  0.128  0.869  1.0
  O  O8  1  0.949  0.872  0.131  1.0
  O  O9  1  0.326  0.723  0.940  1.0
  O  O10  1  0.674  0.277  0.060  1.0
  O  O11  1  0.135  0.301  0.537  1.0
  O  O12  1  0.865  0.699  0.463  1.0
  O  O13  1  0.234  0.458  0.233  1.0
  O  O14  1  0.766  0.542  0.767  1.0
  O  O15  1  0.442  0.905  0.665  1.0
  O  O16  1  0.558  0.095  0.335  1.0
  V  V17  1  0.000  0.500  0.000  1.0
  V  V18  1  0.690  0.899  0.893  1.0
  V  V19  1  0.310  0.101  0.107  1.0
[/CIF]
.
The structure described by Li5V3Mn2O10 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(7), one O(9), and two equivalent O(5) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the third Li site, Li(3) is bonded to one O(10), one O(2), one O(8), one O(9), and two equivalent O(6) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the fifth Li site, Li(5) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with four equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(8), one O(9), and two equivalent O(2) atoms to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the third V site, V(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the fourth V site, V(4) is bonded to one O(10), one O(3), one O(4), one O(7), and two equivalent O(1) atoms to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(2), one O(4), one O(8), and two equivalent O(6) atoms to form distorted MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(7), one O(9), and two equivalent O(5) atoms to form distorted MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one V(1), two equivalent V(4), and one Mn(2) atom to form OLi2MnV3 octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(1)Li2MnV3 octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(10)Li4MnV octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, edges with three equivalent O(3)Li2MnV3 octahedra, and edges with three equivalent O(7)Li3MnV2 octahedra. The corner-sharing octahedral tilt angles range from 0-22°. In the second O site, O(2) is bonded to one Li(3), one Li(5), one V(3), two equivalent V(2), and one Mn(1) atom to form OLi2MnV3 octahedra that share  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(2)Li2MnV3 octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(10)Li4MnV octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(6)Li4Mn2 octahedra, edges with three equivalent O(4)Li2MnV3 octahedra, and edges with three equivalent O(8)Li3MnV2 octahedra. The corner-sharing octahedral tilt angles range from 0-22°. In the third O site, O(3) is bonded to one Li(4), one Li(5), one V(1), one V(2), one V(4), and one Mn(2) atom to form OLi2MnV3 octahedra that share  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(2)Li2MnV3 octahedra,  an edgeedge with one O(8)Li3MnV2 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(4)Li2MnV3 octahedra, edges with two equivalent O(7)Li3MnV2 octahedra, and edges with three equivalent O(1)Li2MnV3 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one V(2), one V(3), one V(4), and one Mn(1) atom to form OLi2MnV3 octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  an edgeedge with one O(1)Li2MnV3 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(6)Li4Mn2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(3)Li2MnV3 octahedra, edges with two equivalent O(8)Li3MnV2 octahedra, and edges with three equivalent O(2)Li2MnV3 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the fifth O site, O(5) is bonded to one Li(1), one Li(4), two equivalent Li(2), and two equivalent Mn(2) atoms to form OLi4Mn2 octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(8)Li3MnV2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra, edges with two equivalent O(1)Li2MnV3 octahedra, edges with two equivalent O(7)Li3MnV2 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, and edges with three equivalent O(9)Li4MnV octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the sixth O site, O(6) is bonded to one Li(1), one Li(5), two equivalent Li(3), and two equivalent Mn(1) atoms to form OLi4Mn2 octahedra that share  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(2)Li2MnV3 octahedra, edges with two equivalent O(8)Li3MnV2 octahedra, edges with two equivalent O(6)Li4Mn2 octahedra, and edges with three equivalent O(10)Li4MnV octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(5), one V(1), one V(4), and one Mn(2) atom to form distorted OLi3MnV2 octahedra that share  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(6)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(3)Li2MnV3 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, edges with two equivalent O(10)Li4MnV octahedra, and edges with three equivalent O(1)Li2MnV3 octahedra. The corner-sharing octahedral tilt angles range from 0-22°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one V(2), one V(3), and one Mn(1) atom to form distorted OLi3MnV2 octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra, edges with two equivalent O(4)Li2MnV3 octahedra, edges with two equivalent O(6)Li4Mn2 octahedra, edges with two equivalent O(9)Li4MnV octahedra, and edges with three equivalent O(2)Li2MnV3 octahedra. The corner-sharing octahedral tilt angles range from 0-22°. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(2), and one Mn(2) atom to form OLi4MnV octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(3)Li2MnV3 octahedra,  a cornercorner with one O(7)Li3MnV2 octahedra,  a cornercorner with one O(6)Li4Mn2 octahedra,  a cornercorner with one O(10)Li4MnV octahedra,  an edgeedge with one O(1)Li2MnV3 octahedra,  an edgeedge with one O(2)Li2MnV3 octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(6)Li4Mn2 octahedra,  an edgeedge with one O(10)Li4MnV octahedra, edges with two equivalent O(8)Li3MnV2 octahedra, and edges with three equivalent O(5)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(4), and one Mn(1) atom to form OLi4MnV octahedra that share  a cornercorner with one O(1)Li2MnV3 octahedra,  a cornercorner with one O(2)Li2MnV3 octahedra,  a cornercorner with one O(4)Li2MnV3 octahedra,  a cornercorner with one O(8)Li3MnV2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4MnV octahedra,  an edgeedge with one O(1)Li2MnV3 octahedra,  an edgeedge with one O(2)Li2MnV3 octahedra,  an edgeedge with one O(3)Li2MnV3 octahedra,  an edgeedge with one O(4)Li2MnV3 octahedra,  an edgeedge with one O(8)Li3MnV2 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4MnV octahedra, edges with two equivalent O(7)Li3MnV2 octahedra, and edges with three equivalent O(6)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. is represented by the CIF file [CIF]
data_Li5Mn2V3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.172
_cell_length_b   5.274
_cell_length_c   7.883
_cell_angle_alpha   106.158
_cell_angle_beta   103.465
_cell_angle_gamma   101.241
_symmetry_Int_Tables_number   1
_cell_volume   192.914
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  Li  Li1  1  0.209  0.929  0.420  1.0
  Li  Li2  1  0.791  0.071  0.580  1.0
  Li  Li3  1  0.378  0.280  0.764  1.0
  Li  Li4  1  0.622  0.720  0.236  1.0
  Mn  Mn5  1  0.095  0.697  0.688  1.0
  Mn  Mn6  1  0.905  0.303  0.312  1.0
  O  O7  1  0.051  0.128  0.869  1.0
  O  O8  1  0.949  0.872  0.131  1.0
  O  O9  1  0.326  0.723  0.940  1.0
  O  O10  1  0.674  0.277  0.060  1.0
  O  O11  1  0.135  0.301  0.537  1.0
  O  O12  1  0.865  0.699  0.463  1.0
  O  O13  1  0.234  0.458  0.233  1.0
  O  O14  1  0.766  0.542  0.767  1.0
  O  O15  1  0.442  0.905  0.665  1.0
  O  O16  1  0.558  0.095  0.335  1.0
  V  V17  1  0.000  0.500  0.000  1.0
  V  V18  1  0.690  0.899  0.893  1.0
  V  V19  1  0.310  0.101  0.107  1.0
[/CIF]
.