The compound described by Li2AgF3 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form a mixture of distorted edge, face, and corner-sharing LiF6 pentagonal pyramids. Ag(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and one F(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded to four equivalent Li(1) and one Ag(1) atom to form a mixture of edge, face, and corner-sharing FLi4Ag square pyramids. In the second F site, F(2) is bonded to four equivalent Li(1) and one Ag(1) atom to form a mixture of distorted edge and corner-sharing FLi4Ag square pyramids. In the third F site, F(3) is bonded to four equivalent Li(1) and one Ag(1) atom to form a mixture of distorted edge, face, and corner-sharing FLi4Ag trigonal bipyramids. is represented by the CIF card [CIF]
data_Li2AgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.449
_cell_length_b   5.499
_cell_length_c   9.218
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   276.188
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.463  0.997  0.663  1.0
  Li  Li1  1  0.463  0.503  0.663  1.0
  Li  Li2  1  0.963  0.497  0.837  1.0
  Li  Li3  1  0.963  0.003  0.837  1.0
  Li  Li4  1  0.037  0.997  0.163  1.0
  Li  Li5  1  0.037  0.503  0.163  1.0
  Li  Li6  1  0.537  0.497  0.337  1.0
  Li  Li7  1  0.537  0.003  0.337  1.0
  Ag  Ag8  1  0.959  0.750  0.511  1.0
  Ag  Ag9  1  0.459  0.250  0.989  1.0
  Ag  Ag10  1  0.541  0.750  0.011  1.0
  Ag  Ag11  1  0.041  0.250  0.489  1.0
  F  F12  1  0.493  0.250  0.503  1.0
  F  F13  1  0.164  0.750  0.714  1.0
  F  F14  1  0.164  0.250  0.722  1.0
  F  F15  1  0.664  0.750  0.778  1.0
  F  F16  1  0.664  0.250  0.786  1.0
  F  F17  1  0.993  0.750  0.997  1.0
  F  F18  1  0.007  0.250  0.003  1.0
  F  F19  1  0.336  0.750  0.214  1.0
  F  F20  1  0.336  0.250  0.222  1.0
  F  F21  1  0.836  0.750  0.278  1.0
  F  F22  1  0.836  0.250  0.286  1.0
  F  F23  1  0.507  0.750  0.497  1.0
[/CIF]
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The compound described by Li2AgF3 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form a mixture of distorted edge, face, and corner-sharing LiF6 pentagonal pyramids. Ag(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and one F(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded to four equivalent Li(1) and one Ag(1) atom to form a mixture of edge, face, and corner-sharing FLi4Ag square pyramids. In the second F site, F(2) is bonded to four equivalent Li(1) and one Ag(1) atom to form a mixture of distorted edge and corner-sharing FLi4Ag square pyramids. In the third F site, F(3) is bonded to four equivalent Li(1) and one Ag(1) atom to form a mixture of distorted edge, face, and corner-sharing FLi4Ag trigonal bipyramids. is represented by the CIF card [CIF]
data_Li2AgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.449
_cell_length_b   5.499
_cell_length_c   9.218
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   276.188
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.463  0.997  0.663  1.0
  Li  Li1  1  0.463  0.503  0.663  1.0
  Li  Li2  1  0.963  0.497  0.837  1.0
  Li  Li3  1  0.963  0.003  0.837  1.0
  Li  Li4  1  0.037  0.997  0.163  1.0
  Li  Li5  1  0.037  0.503  0.163  1.0
  Li  Li6  1  0.537  0.497  0.337  1.0
  Li  Li7  1  0.537  0.003  0.337  1.0
  Ag  Ag8  1  0.959  0.750  0.511  1.0
  Ag  Ag9  1  0.459  0.250  0.989  1.0
  Ag  Ag10  1  0.541  0.750  0.011  1.0
  Ag  Ag11  1  0.041  0.250  0.489  1.0
  F  F12  1  0.493  0.250  0.503  1.0
  F  F13  1  0.164  0.750  0.714  1.0
  F  F14  1  0.164  0.250  0.722  1.0
  F  F15  1  0.664  0.750  0.778  1.0
  F  F16  1  0.664  0.250  0.786  1.0
  F  F17  1  0.993  0.750  0.997  1.0
  F  F18  1  0.007  0.250  0.003  1.0
  F  F19  1  0.336  0.750  0.214  1.0
  F  F20  1  0.336  0.250  0.222  1.0
  F  F21  1  0.836  0.750  0.278  1.0
  F  F22  1  0.836  0.250  0.286  1.0
  F  F23  1  0.507  0.750  0.497  1.0
[/CIF]
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