The crystal structure described by Rb4PS3O16 crystallizes in the orthorhombic P2_12_12 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(2), one O(3), one O(5), one O(6), one O(8), two equivalent O(1), and two equivalent O(4) atoms. In the third Rb site, Rb(3) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(7) and two equivalent O(8) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to two equivalent O(5) and two equivalent O(6) atoms. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one S(2) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Rb(2), one Rb(3), and one S(2) atom. In the third O site, O(7) is bonded in a single-bond geometry to one Rb(1), one Rb(3), and one P(1) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one S(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one S(1) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one S(1) atom. In the eighth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one S(1) atom. is represented by the CIF card [CIF]
data_Rb4PS3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.508
_cell_length_b   7.925
_cell_length_c   14.877
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   885.253
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.232  0.500  0.500  1.0
  Rb  Rb1  1  0.768  0.000  0.000  1.0
  Rb  Rb2  1  0.644  0.344  0.242  1.0
  Rb  Rb3  1  0.644  0.656  0.758  1.0
  Rb  Rb4  1  0.356  0.844  0.258  1.0
  Rb  Rb5  1  0.356  0.156  0.742  1.0
  Rb  Rb6  1  0.936  0.000  0.500  1.0
  Rb  Rb7  1  0.064  0.500  0.000  1.0
  P  P8  1  0.731  0.500  0.500  1.0
  P  P9  1  0.269  0.000  0.000  1.0
  S  S10  1  0.146  0.345  0.262  1.0
  S  S11  1  0.146  0.655  0.738  1.0
  S  S12  1  0.854  0.845  0.238  1.0
  S  S13  1  0.854  0.155  0.762  1.0
  S  S14  1  0.561  0.500  0.000  1.0
  S  S15  1  0.439  0.000  0.500  1.0
  O  O16  1  0.261  0.484  0.297  1.0
  O  O17  1  0.261  0.516  0.703  1.0
  O  O18  1  0.739  0.984  0.203  1.0
  O  O19  1  0.739  0.016  0.797  1.0
  O  O20  1  0.046  0.270  0.338  1.0
  O  O21  1  0.046  0.730  0.662  1.0
  O  O22  1  0.954  0.770  0.162  1.0
  O  O23  1  0.954  0.230  0.838  1.0
  O  O24  1  0.023  0.411  0.192  1.0
  O  O25  1  0.023  0.589  0.808  1.0
  O  O26  1  0.977  0.911  0.308  1.0
  O  O27  1  0.977  0.089  0.692  1.0
  O  O28  1  0.261  0.212  0.219  1.0
  O  O29  1  0.261  0.788  0.781  1.0
  O  O30  1  0.739  0.712  0.281  1.0
  O  O31  1  0.739  0.288  0.719  1.0
  O  O32  1  0.325  0.137  0.537  1.0
  O  O33  1  0.325  0.863  0.463  1.0
  O  O34  1  0.675  0.637  0.963  1.0
  O  O35  1  0.675  0.363  0.037  1.0
  O  O36  1  0.449  0.564  0.075  1.0
  O  O37  1  0.449  0.436  0.925  1.0
  O  O38  1  0.551  0.064  0.425  1.0
  O  O39  1  0.551  0.936  0.575  1.0
  O  O40  1  0.858  0.372  0.544  1.0
  O  O41  1  0.858  0.628  0.456  1.0
  O  O42  1  0.142  0.872  0.956  1.0
  O  O43  1  0.142  0.128  0.044  1.0
  O  O44  1  0.606  0.415  0.431  1.0
  O  O45  1  0.606  0.585  0.569  1.0
  O  O46  1  0.394  0.915  0.069  1.0
  O  O47  1  0.394  0.085  0.931  1.0
[/CIF]
.
The crystal structure described by Rb4PS3O16 crystallizes in the orthorhombic P2_12_12 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(2), one O(3), one O(5), one O(6), one O(8), two equivalent O(1), and two equivalent O(4) atoms. In the third Rb site, Rb(3) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(7) and two equivalent O(8) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to two equivalent O(5) and two equivalent O(6) atoms. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one S(2) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Rb(2), one Rb(3), and one S(2) atom. In the third O site, O(7) is bonded in a single-bond geometry to one Rb(1), one Rb(3), and one P(1) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one S(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one S(1) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one S(1) atom. In the eighth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one S(1) atom. is represented by the CIF card [CIF]
data_Rb4PS3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.508
_cell_length_b   7.925
_cell_length_c   14.877
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   885.253
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.232  0.500  0.500  1.0
  Rb  Rb1  1  0.768  0.000  0.000  1.0
  Rb  Rb2  1  0.644  0.344  0.242  1.0
  Rb  Rb3  1  0.644  0.656  0.758  1.0
  Rb  Rb4  1  0.356  0.844  0.258  1.0
  Rb  Rb5  1  0.356  0.156  0.742  1.0
  Rb  Rb6  1  0.936  0.000  0.500  1.0
  Rb  Rb7  1  0.064  0.500  0.000  1.0
  P  P8  1  0.731  0.500  0.500  1.0
  P  P9  1  0.269  0.000  0.000  1.0
  S  S10  1  0.146  0.345  0.262  1.0
  S  S11  1  0.146  0.655  0.738  1.0
  S  S12  1  0.854  0.845  0.238  1.0
  S  S13  1  0.854  0.155  0.762  1.0
  S  S14  1  0.561  0.500  0.000  1.0
  S  S15  1  0.439  0.000  0.500  1.0
  O  O16  1  0.261  0.484  0.297  1.0
  O  O17  1  0.261  0.516  0.703  1.0
  O  O18  1  0.739  0.984  0.203  1.0
  O  O19  1  0.739  0.016  0.797  1.0
  O  O20  1  0.046  0.270  0.338  1.0
  O  O21  1  0.046  0.730  0.662  1.0
  O  O22  1  0.954  0.770  0.162  1.0
  O  O23  1  0.954  0.230  0.838  1.0
  O  O24  1  0.023  0.411  0.192  1.0
  O  O25  1  0.023  0.589  0.808  1.0
  O  O26  1  0.977  0.911  0.308  1.0
  O  O27  1  0.977  0.089  0.692  1.0
  O  O28  1  0.261  0.212  0.219  1.0
  O  O29  1  0.261  0.788  0.781  1.0
  O  O30  1  0.739  0.712  0.281  1.0
  O  O31  1  0.739  0.288  0.719  1.0
  O  O32  1  0.325  0.137  0.537  1.0
  O  O33  1  0.325  0.863  0.463  1.0
  O  O34  1  0.675  0.637  0.963  1.0
  O  O35  1  0.675  0.363  0.037  1.0
  O  O36  1  0.449  0.564  0.075  1.0
  O  O37  1  0.449  0.436  0.925  1.0
  O  O38  1  0.551  0.064  0.425  1.0
  O  O39  1  0.551  0.936  0.575  1.0
  O  O40  1  0.858  0.372  0.544  1.0
  O  O41  1  0.858  0.628  0.456  1.0
  O  O42  1  0.142  0.872  0.956  1.0
  O  O43  1  0.142  0.128  0.044  1.0
  O  O44  1  0.606  0.415  0.431  1.0
  O  O45  1  0.606  0.585  0.569  1.0
  O  O46  1  0.394  0.915  0.069  1.0
  O  O47  1  0.394  0.085  0.931  1.0
[/CIF]
.