The material structure described by CsO2Cl crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded to eight equivalent O(1) atoms to form a mixture of corner, edge, and face-sharing CsO8 hexagonal bipyramids. O(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms. is represented by the CIF file [CIF]
data_CsClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.813
_cell_length_b   4.813
_cell_length_c   8.574
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.639
_symmetry_Int_Tables_number   1
_cell_volume   198.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.500  0.000  1.0
  Cs  Cs1  1  0.500  0.500  0.500  1.0
  Cl  Cl2  1  0.976  0.024  0.250  1.0
  Cl  Cl3  1  0.024  0.976  0.750  1.0
  O  O4  1  0.035  0.349  0.250  1.0
  O  O5  1  0.651  0.965  0.250  1.0
  O  O6  1  0.349  0.035  0.750  1.0
  O  O7  1  0.965  0.651  0.750  1.0
[/CIF]
.
The material structure described by CsO2Cl crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded to eight equivalent O(1) atoms to form a mixture of corner, edge, and face-sharing CsO8 hexagonal bipyramids. O(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms. is represented by the CIF file [CIF]
data_CsClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.813
_cell_length_b   4.813
_cell_length_c   8.574
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.639
_symmetry_Int_Tables_number   1
_cell_volume   198.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.500  0.000  1.0
  Cs  Cs1  1  0.500  0.500  0.500  1.0
  Cl  Cl2  1  0.976  0.024  0.250  1.0
  Cl  Cl3  1  0.024  0.976  0.750  1.0
  O  O4  1  0.035  0.349  0.250  1.0
  O  O5  1  0.651  0.965  0.250  1.0
  O  O6  1  0.349  0.035  0.750  1.0
  O  O7  1  0.965  0.651  0.750  1.0
[/CIF]
.