The structure described by Pb3C6(N3O4)2 crystallizes in the monoclinic Cc space group. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 5-coordinate geometry to one N(5), one O(4), one O(6), one O(7), and one O(8) atom. In the second Pb site, Pb(2) is bonded in a 5-coordinate geometry to one N(3), one O(2), one O(3), one O(7), and one O(8) atom. In the third Pb site, Pb(3) is bonded in a 8-coordinate geometry to one N(2), one N(6), one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(2) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(2), one N(3), and one O(3) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(5), and one O(4) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(4), one N(6), and one O(5) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(5), one N(6), and one O(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Pb(3), one C(1), and one C(3) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Pb(2), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(4) and one C(5) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(4), and one C(6) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Pb(3), one C(5), and one C(6) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Pb(3) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(2), one Pb(3), and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Pb(2) and one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1), one Pb(3), and one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Pb(3) and one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Pb(1) and one C(6) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Pb(1), one Pb(2), and one Pb(3) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Pb(1), one Pb(2), and one Pb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pb3C6(N3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.754
_cell_length_b   8.754
_cell_length_c   11.997
_cell_angle_alpha   62.734
_cell_angle_beta   62.734
_cell_angle_gamma   47.383
_symmetry_Int_Tables_number   1
_cell_volume   585.832
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.701  0.054  0.063  1.0
  Pb  Pb1  1  0.054  0.701  0.563  1.0
  Pb  Pb2  1  0.917  0.541  0.290  1.0
  Pb  Pb3  1  0.541  0.917  0.790  1.0
  Pb  Pb4  1  0.563  0.034  0.427  1.0
  Pb  Pb5  1  0.034  0.563  0.927  1.0
  C  C6  1  0.464  0.429  0.236  1.0
  C  C7  1  0.429  0.464  0.736  1.0
  C  C8  1  0.595  0.627  0.127  1.0
  C  C9  1  0.627  0.595  0.627  1.0
  C  C10  1  0.682  0.389  0.327  1.0
  C  C11  1  0.389  0.682  0.827  1.0
  C  C12  1  0.035  0.947  0.227  1.0
  C  C13  1  0.947  0.035  0.727  1.0
  C  C14  1  0.168  0.147  0.122  1.0
  C  C15  1  0.147  0.168  0.622  1.0
  C  C16  1  0.945  0.195  0.029  1.0
  C  C17  1  0.195  0.945  0.529  1.0
  N  N18  1  0.472  0.579  0.136  1.0
  N  N19  1  0.579  0.472  0.636  1.0
  N  N20  1  0.562  0.335  0.336  1.0
  N  N21  1  0.335  0.562  0.836  1.0
  N  N22  1  0.694  0.540  0.222  1.0
  N  N23  1  0.540  0.694  0.722  1.0
  N  N24  1  0.160  0.992  0.219  1.0
  N  N25  1  0.992  0.160  0.719  1.0
  N  N26  1  0.934  0.042  0.131  1.0
  N  N27  1  0.042  0.934  0.631  1.0
  N  N28  1  0.067  0.246  0.022  1.0
  N  N29  1  0.246  0.067  0.522  1.0
  O  O30  1  0.375  0.350  0.245  1.0
  O  O31  1  0.350  0.375  0.745  1.0
  O  O32  1  0.629  0.751  0.023  1.0
  O  O33  1  0.751  0.629  0.523  1.0
  O  O34  1  0.789  0.302  0.408  1.0
  O  O35  1  0.302  0.789  0.908  1.0
  O  O36  1  0.000  0.821  0.328  1.0
  O  O37  1  0.821  0.000  0.828  1.0
  O  O38  1  0.256  0.222  0.117  1.0
  O  O39  1  0.222  0.256  0.617  1.0
  O  O40  1  0.836  0.289  0.948  1.0
  O  O41  1  0.289  0.836  0.448  1.0
  O  O42  1  0.895  0.658  0.779  1.0
  O  O43  1  0.658  0.895  0.279  1.0
  O  O44  1  0.702  0.954  0.572  1.0
  O  O45  1  0.954  0.702  0.072  1.0
[/CIF]
.
The structure described by Pb3C6(N3O4)2 crystallizes in the monoclinic Cc space group. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 5-coordinate geometry to one N(5), one O(4), one O(6), one O(7), and one O(8) atom. In the second Pb site, Pb(2) is bonded in a 5-coordinate geometry to one N(3), one O(2), one O(3), one O(7), and one O(8) atom. In the third Pb site, Pb(3) is bonded in a 8-coordinate geometry to one N(2), one N(6), one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(2) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(2), one N(3), and one O(3) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(5), and one O(4) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(4), one N(6), and one O(5) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(5), one N(6), and one O(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Pb(3), one C(1), and one C(3) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Pb(2), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(4) and one C(5) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(4), and one C(6) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Pb(3), one C(5), and one C(6) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Pb(3) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(2), one Pb(3), and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Pb(2) and one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1), one Pb(3), and one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Pb(3) and one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Pb(1) and one C(6) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Pb(1), one Pb(2), and one Pb(3) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Pb(1), one Pb(2), and one Pb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pb3C6(N3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.754
_cell_length_b   8.754
_cell_length_c   11.997
_cell_angle_alpha   62.734
_cell_angle_beta   62.734
_cell_angle_gamma   47.383
_symmetry_Int_Tables_number   1
_cell_volume   585.832
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.701  0.054  0.063  1.0
  Pb  Pb1  1  0.054  0.701  0.563  1.0
  Pb  Pb2  1  0.917  0.541  0.290  1.0
  Pb  Pb3  1  0.541  0.917  0.790  1.0
  Pb  Pb4  1  0.563  0.034  0.427  1.0
  Pb  Pb5  1  0.034  0.563  0.927  1.0
  C  C6  1  0.464  0.429  0.236  1.0
  C  C7  1  0.429  0.464  0.736  1.0
  C  C8  1  0.595  0.627  0.127  1.0
  C  C9  1  0.627  0.595  0.627  1.0
  C  C10  1  0.682  0.389  0.327  1.0
  C  C11  1  0.389  0.682  0.827  1.0
  C  C12  1  0.035  0.947  0.227  1.0
  C  C13  1  0.947  0.035  0.727  1.0
  C  C14  1  0.168  0.147  0.122  1.0
  C  C15  1  0.147  0.168  0.622  1.0
  C  C16  1  0.945  0.195  0.029  1.0
  C  C17  1  0.195  0.945  0.529  1.0
  N  N18  1  0.472  0.579  0.136  1.0
  N  N19  1  0.579  0.472  0.636  1.0
  N  N20  1  0.562  0.335  0.336  1.0
  N  N21  1  0.335  0.562  0.836  1.0
  N  N22  1  0.694  0.540  0.222  1.0
  N  N23  1  0.540  0.694  0.722  1.0
  N  N24  1  0.160  0.992  0.219  1.0
  N  N25  1  0.992  0.160  0.719  1.0
  N  N26  1  0.934  0.042  0.131  1.0
  N  N27  1  0.042  0.934  0.631  1.0
  N  N28  1  0.067  0.246  0.022  1.0
  N  N29  1  0.246  0.067  0.522  1.0
  O  O30  1  0.375  0.350  0.245  1.0
  O  O31  1  0.350  0.375  0.745  1.0
  O  O32  1  0.629  0.751  0.023  1.0
  O  O33  1  0.751  0.629  0.523  1.0
  O  O34  1  0.789  0.302  0.408  1.0
  O  O35  1  0.302  0.789  0.908  1.0
  O  O36  1  0.000  0.821  0.328  1.0
  O  O37  1  0.821  0.000  0.828  1.0
  O  O38  1  0.256  0.222  0.117  1.0
  O  O39  1  0.222  0.256  0.617  1.0
  O  O40  1  0.836  0.289  0.948  1.0
  O  O41  1  0.289  0.836  0.448  1.0
  O  O42  1  0.895  0.658  0.779  1.0
  O  O43  1  0.658  0.895  0.279  1.0
  O  O44  1  0.702  0.954  0.572  1.0
  O  O45  1  0.954  0.702  0.072  1.0
[/CIF]
.