The material described by KNaWMoO6 is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4mm space group. K(1) is bonded to one O(5), one O(9), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(7) atoms to form KO12 cuboctahedra that share corners with four equivalent K(1)O12 cuboctahedra, corners with eight equivalent Na(1)O12 cuboctahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with four equivalent K(1)O12 cuboctahedra,  a faceface with one W(1)O6 octahedra,  a faceface with one W(2)O6 octahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Mo(3)O6 octahedra, faces with two equivalent W(3)O6 octahedra, and faces with two equivalent Mo(1)O6 octahedra. Na(1) is bonded to one O(10), one O(6), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(8) atoms to form NaO12 cuboctahedra that share corners with four equivalent Na(1)O12 cuboctahedra, corners with eight equivalent K(1)O12 cuboctahedra, faces with two equivalent K(1)O12 cuboctahedra, faces with four equivalent Na(1)O12 cuboctahedra,  a faceface with one W(1)O6 octahedra,  a faceface with one W(2)O6 octahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Mo(3)O6 octahedra, faces with two equivalent W(3)O6 octahedra, and faces with two equivalent Mo(1)O6 octahedra. There are three inequivalent W sites. In the first W site, W(1) is bonded to one O(5), one O(6), and four equivalent O(1) atoms to form WO6 octahedra that share corners with two equivalent W(2)O6 octahedra, corners with four equivalent W(3)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second W site, W(2) is bonded to one O(5), one O(6), and four equivalent O(2) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third W site, W(3) is bonded to one O(7), one O(8), two equivalent O(1), and two equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(7), one O(8), two equivalent O(2), and two equivalent O(4) atoms to form MoO6 octahedra that share corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(3)O6 octahedra, corners with two equivalent Mo(3)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Mo site, Mo(2) is bonded to one O(10), one O(9), and four equivalent O(3) atoms to form MoO6 octahedra that share corners with two equivalent Mo(3)O6 octahedra, corners with four equivalent W(3)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Mo site, Mo(3) is bonded to one O(10), one O(9), and four equivalent O(4) atoms to form MoO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are ten inequivalent O sites. In the first O site, O(5) is bonded to four equivalent K(1), one W(1), and one W(2) atom to form distorted OK4W2 octahedra that share corners with four equivalent O(9)K4Mo2 octahedra, corners with eight equivalent O(4)K2Na2Mo2 octahedra, corners with eight equivalent O(3)K2Na2MoW octahedra, edges with four equivalent O(7)K4MoW octahedra, faces with four equivalent O(2)K2Na2MoW octahedra, and faces with four equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 4-63°. In the second O site, O(6) is bonded in a distorted linear geometry to four equivalent Na(1), one W(1), and one W(2) atom. In the third O site, O(7) is bonded to four equivalent K(1), one W(3), and one Mo(1) atom to form distorted OK4MoW octahedra that share corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(4)K2Na2Mo2 octahedra, corners with four equivalent O(2)K2Na2MoW octahedra, corners with four equivalent O(3)K2Na2MoW octahedra, corners with four equivalent O(1)K2Na2W2 octahedra, corners with four equivalent O(7)K4MoW octahedra, edges with two equivalent O(9)K4Mo2 octahedra, edges with two equivalent O(5)K4W2 octahedra, faces with two equivalent O(4)K2Na2Mo2 octahedra, faces with two equivalent O(2)K2Na2MoW octahedra, faces with two equivalent O(3)K2Na2MoW octahedra, and faces with two equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fourth O site, O(8) is bonded to four equivalent Na(1), one W(3), and one Mo(1) atom to form distorted ONa4MoW octahedra that share corners with two equivalent O(7)K4MoW octahedra, corners with four equivalent O(4)K2Na2Mo2 octahedra, corners with four equivalent O(2)K2Na2MoW octahedra, corners with four equivalent O(3)K2Na2MoW octahedra, corners with four equivalent O(1)K2Na2W2 octahedra, corners with four equivalent O(8)Na4MoW octahedra, edges with two equivalent O(10)Na4Mo2 octahedra, faces with two equivalent O(4)K2Na2Mo2 octahedra, faces with two equivalent O(2)K2Na2MoW octahedra, faces with two equivalent O(3)K2Na2MoW octahedra, and faces with two equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(9) is bonded to four equivalent K(1), one Mo(2), and one Mo(3) atom to form distorted OK4Mo2 octahedra that share corners with two equivalent O(10)Na4Mo2 octahedra, corners with four equivalent O(5)K4W2 octahedra, corners with eight equivalent O(2)K2Na2MoW octahedra, corners with eight equivalent O(1)K2Na2W2 octahedra, edges with four equivalent O(7)K4MoW octahedra, faces with four equivalent O(4)K2Na2Mo2 octahedra, and faces with four equivalent O(3)K2Na2MoW octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the sixth O site, O(10) is bonded to four equivalent Na(1), one Mo(2), and one Mo(3) atom to form distorted ONa4Mo2 octahedra that share corners with two equivalent O(9)K4Mo2 octahedra, corners with eight equivalent O(2)K2Na2MoW octahedra, corners with eight equivalent O(1)K2Na2W2 octahedra, edges with four equivalent O(8)Na4MoW octahedra, faces with four equivalent O(4)K2Na2Mo2 octahedra, and faces with four equivalent O(3)K2Na2MoW octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the seventh O site, O(1) is bonded to two equivalent K(1), two equivalent Na(1), one W(1), and one W(3) atom to form distorted OK2Na2W2 octahedra that share corners with two equivalent O(1)K2Na2W2 octahedra, corners with two equivalent O(9)K4Mo2 octahedra, corners with two equivalent O(7)K4MoW octahedra, corners with two equivalent O(10)Na4Mo2 octahedra, corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(2)K2Na2MoW octahedra, corners with eight equivalent O(4)K2Na2Mo2 octahedra, edges with two equivalent O(2)K2Na2MoW octahedra, edges with two equivalent O(3)K2Na2MoW octahedra,  a faceface with one O(7)K4MoW octahedra,  a faceface with one O(5)K4W2 octahedra,  a faceface with one O(8)Na4MoW octahedra, faces with two equivalent O(3)K2Na2MoW octahedra, and faces with two equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the eighth O site, O(2) is bonded to two equivalent K(1), two equivalent Na(1), one W(2), and one Mo(1) atom to form distorted OK2Na2MoW octahedra that share corners with two equivalent O(2)K2Na2MoW octahedra, corners with two equivalent O(9)K4Mo2 octahedra, corners with two equivalent O(7)K4MoW octahedra, corners with two equivalent O(10)Na4Mo2 octahedra, corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(1)K2Na2W2 octahedra, corners with eight equivalent O(3)K2Na2MoW octahedra, edges with two equivalent O(4)K2Na2Mo2 octahedra, edges with two equivalent O(1)K2Na2W2 octahedra,  a faceface with one O(7)K4MoW octahedra,  a faceface with one O(5)K4W2 octahedra,  a faceface with one O(8)Na4MoW octahedra, faces with two equivalent O(4)K2Na2Mo2 octahedra, and faces with two equivalent O(2)K2Na2MoW octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the ninth O site, O(3) is bonded to two equivalent K(1), two equivalent Na(1), one W(3), and one Mo(2) atom to form distorted OK2Na2MoW octahedra that share corners with two equivalent O(3)K2Na2MoW octahedra, corners with two equivalent O(7)K4MoW octahedra, corners with two equivalent O(5)K4W2 octahedra, corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(4)K2Na2Mo2 octahedra, corners with eight equivalent O(2)K2Na2MoW octahedra, edges with two equivalent O(4)K2Na2Mo2 octahedra, edges with two equivalent O(1)K2Na2W2 octahedra,  a faceface with one O(9)K4Mo2 octahedra,  a faceface with one O(7)K4MoW octahedra,  a faceface with one O(10)Na4Mo2 octahedra,  a faceface with one O(8)Na4MoW octahedra, faces with two equivalent O(3)K2Na2MoW octahedra, and faces with two equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the tenth O site, O(4) is bonded to two equivalent K(1), two equivalent Na(1), one Mo(1), and one Mo(3) atom to form distorted OK2Na2Mo2 octahedra that share corners with two equivalent O(4)K2Na2Mo2 octahedra, corners with two equivalent O(7)K4MoW octahedra, corners with two equivalent O(5)K4W2 octahedra, corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(3)K2Na2MoW octahedra, corners with eight equivalent O(1)K2Na2W2 octahedra, edges with two equivalent O(2)K2Na2MoW octahedra, edges with two equivalent O(3)K2Na2MoW octahedra,  a faceface with one O(9)K4Mo2 octahedra,  a faceface with one O(7)K4MoW octahedra,  a faceface with one O(10)Na4Mo2 octahedra,  a faceface with one O(8)Na4MoW octahedra, faces with two equivalent O(4)K2Na2Mo2 octahedra, and faces with two equivalent O(2)K2Na2MoW octahedra. The corner-sharing octahedral tilt angles range from 0-62°. is represented by the CIF file [CIF]
data_KNaMoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.027
_cell_length_b   8.027
_cell_length_c   7.980
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   514.145
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.253  0.253  0.254  1.0
  K  K1  1  0.747  0.253  0.254  1.0
  K  K2  1  0.253  0.747  0.254  1.0
  K  K3  1  0.747  0.747  0.254  1.0
  Na  Na4  1  0.253  0.253  0.746  1.0
  Na  Na5  1  0.747  0.253  0.746  1.0
  Na  Na6  1  0.253  0.747  0.746  1.0
  Na  Na7  1  0.747  0.747  0.746  1.0
  Mo  Mo8  1  0.500  0.000  0.502  1.0
  Mo  Mo9  1  0.000  0.500  0.502  1.0
  Mo  Mo10  1  0.500  0.500  0.998  1.0
  Mo  Mo11  1  0.500  0.500  0.504  1.0
  W  W12  1  0.000  0.000  1.000  1.0
  W  W13  1  0.000  0.000  0.505  1.0
  W  W14  1  0.500  0.000  0.997  1.0
  W  W15  1  0.000  0.500  0.997  1.0
  O  O16  1  0.000  0.254  0.995  1.0
  O  O17  1  0.000  0.238  0.505  1.0
  O  O18  1  0.500  0.243  0.995  1.0
  O  O19  1  0.500  0.249  0.506  1.0
  O  O20  1  0.000  0.746  0.995  1.0
  O  O21  1  0.000  0.762  0.505  1.0
  O  O22  1  0.500  0.757  0.995  1.0
  O  O23  1  0.500  0.751  0.506  1.0
  O  O24  1  0.254  0.000  0.995  1.0
  O  O25  1  0.238  0.000  0.505  1.0
  O  O26  1  0.746  0.000  0.995  1.0
  O  O27  1  0.762  0.000  0.505  1.0
  O  O28  1  0.243  0.500  0.995  1.0
  O  O29  1  0.249  0.500  0.506  1.0
  O  O30  1  0.757  0.500  0.995  1.0
  O  O31  1  0.751  0.500  0.506  1.0
  O  O32  1  0.000  0.000  0.245  1.0
  O  O33  1  0.000  0.000  0.756  1.0
  O  O34  1  0.500  0.000  0.240  1.0
  O  O35  1  0.500  0.000  0.757  1.0
  O  O36  1  0.000  0.500  0.240  1.0
  O  O37  1  0.000  0.500  0.757  1.0
  O  O38  1  0.500  0.500  0.236  1.0
  O  O39  1  0.500  0.500  0.762  1.0
[/CIF]
.
The material described by KNaWMoO6 is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4mm space group. K(1) is bonded to one O(5), one O(9), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(7) atoms to form KO12 cuboctahedra that share corners with four equivalent K(1)O12 cuboctahedra, corners with eight equivalent Na(1)O12 cuboctahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with four equivalent K(1)O12 cuboctahedra,  a faceface with one W(1)O6 octahedra,  a faceface with one W(2)O6 octahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Mo(3)O6 octahedra, faces with two equivalent W(3)O6 octahedra, and faces with two equivalent Mo(1)O6 octahedra. Na(1) is bonded to one O(10), one O(6), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(8) atoms to form NaO12 cuboctahedra that share corners with four equivalent Na(1)O12 cuboctahedra, corners with eight equivalent K(1)O12 cuboctahedra, faces with two equivalent K(1)O12 cuboctahedra, faces with four equivalent Na(1)O12 cuboctahedra,  a faceface with one W(1)O6 octahedra,  a faceface with one W(2)O6 octahedra,  a faceface with one Mo(2)O6 octahedra,  a faceface with one Mo(3)O6 octahedra, faces with two equivalent W(3)O6 octahedra, and faces with two equivalent Mo(1)O6 octahedra. There are three inequivalent W sites. In the first W site, W(1) is bonded to one O(5), one O(6), and four equivalent O(1) atoms to form WO6 octahedra that share corners with two equivalent W(2)O6 octahedra, corners with four equivalent W(3)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second W site, W(2) is bonded to one O(5), one O(6), and four equivalent O(2) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third W site, W(3) is bonded to one O(7), one O(8), two equivalent O(1), and two equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(7), one O(8), two equivalent O(2), and two equivalent O(4) atoms to form MoO6 octahedra that share corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(3)O6 octahedra, corners with two equivalent Mo(3)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Mo site, Mo(2) is bonded to one O(10), one O(9), and four equivalent O(3) atoms to form MoO6 octahedra that share corners with two equivalent Mo(3)O6 octahedra, corners with four equivalent W(3)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Mo site, Mo(3) is bonded to one O(10), one O(9), and four equivalent O(4) atoms to form MoO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are ten inequivalent O sites. In the first O site, O(5) is bonded to four equivalent K(1), one W(1), and one W(2) atom to form distorted OK4W2 octahedra that share corners with four equivalent O(9)K4Mo2 octahedra, corners with eight equivalent O(4)K2Na2Mo2 octahedra, corners with eight equivalent O(3)K2Na2MoW octahedra, edges with four equivalent O(7)K4MoW octahedra, faces with four equivalent O(2)K2Na2MoW octahedra, and faces with four equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 4-63°. In the second O site, O(6) is bonded in a distorted linear geometry to four equivalent Na(1), one W(1), and one W(2) atom. In the third O site, O(7) is bonded to four equivalent K(1), one W(3), and one Mo(1) atom to form distorted OK4MoW octahedra that share corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(4)K2Na2Mo2 octahedra, corners with four equivalent O(2)K2Na2MoW octahedra, corners with four equivalent O(3)K2Na2MoW octahedra, corners with four equivalent O(1)K2Na2W2 octahedra, corners with four equivalent O(7)K4MoW octahedra, edges with two equivalent O(9)K4Mo2 octahedra, edges with two equivalent O(5)K4W2 octahedra, faces with two equivalent O(4)K2Na2Mo2 octahedra, faces with two equivalent O(2)K2Na2MoW octahedra, faces with two equivalent O(3)K2Na2MoW octahedra, and faces with two equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fourth O site, O(8) is bonded to four equivalent Na(1), one W(3), and one Mo(1) atom to form distorted ONa4MoW octahedra that share corners with two equivalent O(7)K4MoW octahedra, corners with four equivalent O(4)K2Na2Mo2 octahedra, corners with four equivalent O(2)K2Na2MoW octahedra, corners with four equivalent O(3)K2Na2MoW octahedra, corners with four equivalent O(1)K2Na2W2 octahedra, corners with four equivalent O(8)Na4MoW octahedra, edges with two equivalent O(10)Na4Mo2 octahedra, faces with two equivalent O(4)K2Na2Mo2 octahedra, faces with two equivalent O(2)K2Na2MoW octahedra, faces with two equivalent O(3)K2Na2MoW octahedra, and faces with two equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the fifth O site, O(9) is bonded to four equivalent K(1), one Mo(2), and one Mo(3) atom to form distorted OK4Mo2 octahedra that share corners with two equivalent O(10)Na4Mo2 octahedra, corners with four equivalent O(5)K4W2 octahedra, corners with eight equivalent O(2)K2Na2MoW octahedra, corners with eight equivalent O(1)K2Na2W2 octahedra, edges with four equivalent O(7)K4MoW octahedra, faces with four equivalent O(4)K2Na2Mo2 octahedra, and faces with four equivalent O(3)K2Na2MoW octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the sixth O site, O(10) is bonded to four equivalent Na(1), one Mo(2), and one Mo(3) atom to form distorted ONa4Mo2 octahedra that share corners with two equivalent O(9)K4Mo2 octahedra, corners with eight equivalent O(2)K2Na2MoW octahedra, corners with eight equivalent O(1)K2Na2W2 octahedra, edges with four equivalent O(8)Na4MoW octahedra, faces with four equivalent O(4)K2Na2Mo2 octahedra, and faces with four equivalent O(3)K2Na2MoW octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the seventh O site, O(1) is bonded to two equivalent K(1), two equivalent Na(1), one W(1), and one W(3) atom to form distorted OK2Na2W2 octahedra that share corners with two equivalent O(1)K2Na2W2 octahedra, corners with two equivalent O(9)K4Mo2 octahedra, corners with two equivalent O(7)K4MoW octahedra, corners with two equivalent O(10)Na4Mo2 octahedra, corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(2)K2Na2MoW octahedra, corners with eight equivalent O(4)K2Na2Mo2 octahedra, edges with two equivalent O(2)K2Na2MoW octahedra, edges with two equivalent O(3)K2Na2MoW octahedra,  a faceface with one O(7)K4MoW octahedra,  a faceface with one O(5)K4W2 octahedra,  a faceface with one O(8)Na4MoW octahedra, faces with two equivalent O(3)K2Na2MoW octahedra, and faces with two equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the eighth O site, O(2) is bonded to two equivalent K(1), two equivalent Na(1), one W(2), and one Mo(1) atom to form distorted OK2Na2MoW octahedra that share corners with two equivalent O(2)K2Na2MoW octahedra, corners with two equivalent O(9)K4Mo2 octahedra, corners with two equivalent O(7)K4MoW octahedra, corners with two equivalent O(10)Na4Mo2 octahedra, corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(1)K2Na2W2 octahedra, corners with eight equivalent O(3)K2Na2MoW octahedra, edges with two equivalent O(4)K2Na2Mo2 octahedra, edges with two equivalent O(1)K2Na2W2 octahedra,  a faceface with one O(7)K4MoW octahedra,  a faceface with one O(5)K4W2 octahedra,  a faceface with one O(8)Na4MoW octahedra, faces with two equivalent O(4)K2Na2Mo2 octahedra, and faces with two equivalent O(2)K2Na2MoW octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the ninth O site, O(3) is bonded to two equivalent K(1), two equivalent Na(1), one W(3), and one Mo(2) atom to form distorted OK2Na2MoW octahedra that share corners with two equivalent O(3)K2Na2MoW octahedra, corners with two equivalent O(7)K4MoW octahedra, corners with two equivalent O(5)K4W2 octahedra, corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(4)K2Na2Mo2 octahedra, corners with eight equivalent O(2)K2Na2MoW octahedra, edges with two equivalent O(4)K2Na2Mo2 octahedra, edges with two equivalent O(1)K2Na2W2 octahedra,  a faceface with one O(9)K4Mo2 octahedra,  a faceface with one O(7)K4MoW octahedra,  a faceface with one O(10)Na4Mo2 octahedra,  a faceface with one O(8)Na4MoW octahedra, faces with two equivalent O(3)K2Na2MoW octahedra, and faces with two equivalent O(1)K2Na2W2 octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the tenth O site, O(4) is bonded to two equivalent K(1), two equivalent Na(1), one Mo(1), and one Mo(3) atom to form distorted OK2Na2Mo2 octahedra that share corners with two equivalent O(4)K2Na2Mo2 octahedra, corners with two equivalent O(7)K4MoW octahedra, corners with two equivalent O(5)K4W2 octahedra, corners with two equivalent O(8)Na4MoW octahedra, corners with four equivalent O(3)K2Na2MoW octahedra, corners with eight equivalent O(1)K2Na2W2 octahedra, edges with two equivalent O(2)K2Na2MoW octahedra, edges with two equivalent O(3)K2Na2MoW octahedra,  a faceface with one O(9)K4Mo2 octahedra,  a faceface with one O(7)K4MoW octahedra,  a faceface with one O(10)Na4Mo2 octahedra,  a faceface with one O(8)Na4MoW octahedra, faces with two equivalent O(4)K2Na2Mo2 octahedra, and faces with two equivalent O(2)K2Na2MoW octahedra. The corner-sharing octahedral tilt angles range from 0-62°. is represented by the CIF file [CIF]
data_KNaMoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.027
_cell_length_b   8.027
_cell_length_c   7.980
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   514.145
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.253  0.253  0.254  1.0
  K  K1  1  0.747  0.253  0.254  1.0
  K  K2  1  0.253  0.747  0.254  1.0
  K  K3  1  0.747  0.747  0.254  1.0
  Na  Na4  1  0.253  0.253  0.746  1.0
  Na  Na5  1  0.747  0.253  0.746  1.0
  Na  Na6  1  0.253  0.747  0.746  1.0
  Na  Na7  1  0.747  0.747  0.746  1.0
  Mo  Mo8  1  0.500  0.000  0.502  1.0
  Mo  Mo9  1  0.000  0.500  0.502  1.0
  Mo  Mo10  1  0.500  0.500  0.998  1.0
  Mo  Mo11  1  0.500  0.500  0.504  1.0
  W  W12  1  0.000  0.000  1.000  1.0
  W  W13  1  0.000  0.000  0.505  1.0
  W  W14  1  0.500  0.000  0.997  1.0
  W  W15  1  0.000  0.500  0.997  1.0
  O  O16  1  0.000  0.254  0.995  1.0
  O  O17  1  0.000  0.238  0.505  1.0
  O  O18  1  0.500  0.243  0.995  1.0
  O  O19  1  0.500  0.249  0.506  1.0
  O  O20  1  0.000  0.746  0.995  1.0
  O  O21  1  0.000  0.762  0.505  1.0
  O  O22  1  0.500  0.757  0.995  1.0
  O  O23  1  0.500  0.751  0.506  1.0
  O  O24  1  0.254  0.000  0.995  1.0
  O  O25  1  0.238  0.000  0.505  1.0
  O  O26  1  0.746  0.000  0.995  1.0
  O  O27  1  0.762  0.000  0.505  1.0
  O  O28  1  0.243  0.500  0.995  1.0
  O  O29  1  0.249  0.500  0.506  1.0
  O  O30  1  0.757  0.500  0.995  1.0
  O  O31  1  0.751  0.500  0.506  1.0
  O  O32  1  0.000  0.000  0.245  1.0
  O  O33  1  0.000  0.000  0.756  1.0
  O  O34  1  0.500  0.000  0.240  1.0
  O  O35  1  0.500  0.000  0.757  1.0
  O  O36  1  0.000  0.500  0.240  1.0
  O  O37  1  0.000  0.500  0.757  1.0
  O  O38  1  0.500  0.500  0.236  1.0
  O  O39  1  0.500  0.500  0.762  1.0
[/CIF]
.