The structure described by Bi(MoO5)2 crystallizes in the monoclinic P2_1/m space group. Mo(1) is bonded in a 5-coordinate geometry to one O(2), one O(5), one O(6), and two equivalent O(3) atoms. Bi(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent O(4) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Mo(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Mo(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Bi(1) and one O(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Bi(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(1) and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi(MoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.869
_cell_length_b   11.685
_cell_length_c   6.479
_cell_angle_alpha   90.000
_cell_angle_beta   118.483
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   390.516
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.404  0.250  0.656  1.0
  Bi  Bi1  1  0.596  0.750  0.344  1.0
  Mo  Mo2  1  0.620  0.405  0.207  1.0
  Mo  Mo3  1  0.380  0.905  0.793  1.0
  Mo  Mo4  1  0.380  0.595  0.793  1.0
  Mo  Mo5  1  0.620  0.095  0.207  1.0
  O  O6  1  0.971  0.250  0.940  1.0
  O  O7  1  0.029  0.750  0.060  1.0
  O  O8  1  0.534  0.250  0.057  1.0
  O  O9  1  0.466  0.750  0.943  1.0
  O  O10  1  0.381  0.432  0.841  1.0
  O  O11  1  0.619  0.932  0.159  1.0
  O  O12  1  0.619  0.568  0.159  1.0
  O  O13  1  0.381  0.068  0.841  1.0
  O  O14  1  0.821  0.346  0.858  1.0
  O  O15  1  0.179  0.846  0.142  1.0
  O  O16  1  0.179  0.654  0.142  1.0
  O  O17  1  0.821  0.154  0.858  1.0
  O  O18  1  0.466  0.385  0.379  1.0
  O  O19  1  0.534  0.885  0.621  1.0
  O  O20  1  0.534  0.615  0.621  1.0
  O  O21  1  0.466  0.115  0.379  1.0
  O  O22  1  0.947  0.375  0.386  1.0
  O  O23  1  0.053  0.875  0.614  1.0
  O  O24  1  0.053  0.625  0.614  1.0
  O  O25  1  0.947  0.125  0.386  1.0
[/CIF]
.
The structure described by Bi(MoO5)2 crystallizes in the monoclinic P2_1/m space group. Mo(1) is bonded in a 5-coordinate geometry to one O(2), one O(5), one O(6), and two equivalent O(3) atoms. Bi(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent O(4) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Mo(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Mo(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Bi(1) and one O(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Bi(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(1) and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi(MoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.869
_cell_length_b   11.685
_cell_length_c   6.479
_cell_angle_alpha   90.000
_cell_angle_beta   118.483
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   390.516
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.404  0.250  0.656  1.0
  Bi  Bi1  1  0.596  0.750  0.344  1.0
  Mo  Mo2  1  0.620  0.405  0.207  1.0
  Mo  Mo3  1  0.380  0.905  0.793  1.0
  Mo  Mo4  1  0.380  0.595  0.793  1.0
  Mo  Mo5  1  0.620  0.095  0.207  1.0
  O  O6  1  0.971  0.250  0.940  1.0
  O  O7  1  0.029  0.750  0.060  1.0
  O  O8  1  0.534  0.250  0.057  1.0
  O  O9  1  0.466  0.750  0.943  1.0
  O  O10  1  0.381  0.432  0.841  1.0
  O  O11  1  0.619  0.932  0.159  1.0
  O  O12  1  0.619  0.568  0.159  1.0
  O  O13  1  0.381  0.068  0.841  1.0
  O  O14  1  0.821  0.346  0.858  1.0
  O  O15  1  0.179  0.846  0.142  1.0
  O  O16  1  0.179  0.654  0.142  1.0
  O  O17  1  0.821  0.154  0.858  1.0
  O  O18  1  0.466  0.385  0.379  1.0
  O  O19  1  0.534  0.885  0.621  1.0
  O  O20  1  0.534  0.615  0.621  1.0
  O  O21  1  0.466  0.115  0.379  1.0
  O  O22  1  0.947  0.375  0.386  1.0
  O  O23  1  0.053  0.875  0.614  1.0
  O  O24  1  0.053  0.625  0.614  1.0
  O  O25  1  0.947  0.125  0.386  1.0
[/CIF]
.