The compound described by RbMnHP3O10 crystallizes in the monoclinic C2 space group. Rb(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(3), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(9) atoms to form MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 35-47°. In the third P site, P(3) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to two equivalent O(10) atoms. In the second H site, H(2) is bonded in a linear geometry to two equivalent O(1) atoms. There are ten inequivalent O sites. In the first O site, O(5) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(2), and one P(1) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Mn(1), and one P(1) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Rb(1), one P(1), and one P(3) atom. In the fourth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Mn(1), and one P(3) atom. In the fifth O site, O(9) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(2), and one P(3) atom. In the sixth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(3), and one H(1) atom. In the seventh O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(2), and one H(2) atom. In the eighth O site, O(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the ninth O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(2), and one P(2) atom. In the tenth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF file [CIF]
data_RbMnP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.451
_cell_length_b   7.449
_cell_length_c   8.815
_cell_angle_alpha   76.236
_cell_angle_beta   103.764
_cell_angle_gamma   109.879
_symmetry_Int_Tables_number   1
_cell_volume   440.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.629  0.098  0.244  1.0
  Rb  Rb1  1  0.098  0.629  0.757  1.0
  Mn  Mn2  1  0.199  0.199  0.500  1.0
  Mn  Mn3  1  0.709  0.709  0.000  1.0
  P  P4  1  0.068  0.535  0.208  1.0
  P  P5  1  0.535  0.068  0.792  1.0
  P  P6  1  0.067  0.917  0.235  1.0
  P  P7  1  0.917  0.067  0.765  1.0
  P  P8  1  0.457  0.514  0.270  1.0
  P  P9  1  0.514  0.458  0.730  1.0
  H  H10  1  0.619  0.619  0.500  1.0
  H  H11  1  0.128  0.129  1.000  1.0
  O  O12  1  0.202  0.050  0.123  1.0
  O  O13  1  0.051  0.202  0.877  1.0
  O  O14  1  0.090  0.983  0.389  1.0
  O  O15  1  0.984  0.090  0.611  1.0
  O  O16  1  0.856  0.867  0.156  1.0
  O  O17  1  0.867  0.856  0.844  1.0
  O  O18  1  0.123  0.719  0.292  1.0
  O  O19  1  0.719  0.123  0.708  1.0
  O  O20  1  0.925  0.550  0.059  1.0
  O  O21  1  0.550  0.925  0.941  1.0
  O  O22  1  0.021  0.359  0.331  1.0
  O  O23  1  0.359  0.021  0.669  1.0
  O  O24  1  0.268  0.557  0.157  1.0
  O  O25  1  0.558  0.268  0.843  1.0
  O  O26  1  0.399  0.314  0.371  1.0
  O  O27  1  0.314  0.399  0.629  1.0
  O  O28  1  0.581  0.512  0.158  1.0
  O  O29  1  0.512  0.581  0.842  1.0
  O  O30  1  0.548  0.675  0.368  1.0
  O  O31  1  0.675  0.548  0.632  1.0
[/CIF]
.
The compound described by RbMnHP3O10 crystallizes in the monoclinic C2 space group. Rb(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(3), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(9) atoms to form MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 35-47°. In the third P site, P(3) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to two equivalent O(10) atoms. In the second H site, H(2) is bonded in a linear geometry to two equivalent O(1) atoms. There are ten inequivalent O sites. In the first O site, O(5) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(2), and one P(1) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Mn(1), and one P(1) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Rb(1), one P(1), and one P(3) atom. In the fourth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Mn(1), and one P(3) atom. In the fifth O site, O(9) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(2), and one P(3) atom. In the sixth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(3), and one H(1) atom. In the seventh O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(2), and one H(2) atom. In the eighth O site, O(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the ninth O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(2), and one P(2) atom. In the tenth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF file [CIF]
data_RbMnP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.451
_cell_length_b   7.449
_cell_length_c   8.815
_cell_angle_alpha   76.236
_cell_angle_beta   103.764
_cell_angle_gamma   109.879
_symmetry_Int_Tables_number   1
_cell_volume   440.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.629  0.098  0.244  1.0
  Rb  Rb1  1  0.098  0.629  0.757  1.0
  Mn  Mn2  1  0.199  0.199  0.500  1.0
  Mn  Mn3  1  0.709  0.709  0.000  1.0
  P  P4  1  0.068  0.535  0.208  1.0
  P  P5  1  0.535  0.068  0.792  1.0
  P  P6  1  0.067  0.917  0.235  1.0
  P  P7  1  0.917  0.067  0.765  1.0
  P  P8  1  0.457  0.514  0.270  1.0
  P  P9  1  0.514  0.458  0.730  1.0
  H  H10  1  0.619  0.619  0.500  1.0
  H  H11  1  0.128  0.129  1.000  1.0
  O  O12  1  0.202  0.050  0.123  1.0
  O  O13  1  0.051  0.202  0.877  1.0
  O  O14  1  0.090  0.983  0.389  1.0
  O  O15  1  0.984  0.090  0.611  1.0
  O  O16  1  0.856  0.867  0.156  1.0
  O  O17  1  0.867  0.856  0.844  1.0
  O  O18  1  0.123  0.719  0.292  1.0
  O  O19  1  0.719  0.123  0.708  1.0
  O  O20  1  0.925  0.550  0.059  1.0
  O  O21  1  0.550  0.925  0.941  1.0
  O  O22  1  0.021  0.359  0.331  1.0
  O  O23  1  0.359  0.021  0.669  1.0
  O  O24  1  0.268  0.557  0.157  1.0
  O  O25  1  0.558  0.268  0.843  1.0
  O  O26  1  0.399  0.314  0.371  1.0
  O  O27  1  0.314  0.399  0.629  1.0
  O  O28  1  0.581  0.512  0.158  1.0
  O  O29  1  0.512  0.581  0.842  1.0
  O  O30  1  0.548  0.675  0.368  1.0
  O  O31  1  0.675  0.548  0.632  1.0
[/CIF]
.