The structure described by CN5S3Cl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CN5S3Cl clusters. C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(1) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one S(3) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(2), one N(4), and one N(5) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(4) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one N(1), one N(3), and one N(5) atom. Cl(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CS3N5Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.973
_cell_length_b   5.011
_cell_length_c   14.765
_cell_angle_alpha   74.977
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   784.072
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.361  0.944  0.809  1.0
  C  C1  1  0.639  0.056  0.191  1.0
  C  C2  1  0.139  0.944  0.309  1.0
  C  C3  1  0.861  0.056  0.691  1.0
  S  S4  1  0.778  0.717  0.304  1.0
  S  S5  1  0.222  0.283  0.696  1.0
  S  S6  1  0.332  0.104  0.545  1.0
  S  S7  1  0.722  0.717  0.804  1.0
  S  S8  1  0.970  0.702  0.821  1.0
  S  S9  1  0.030  0.298  0.179  1.0
  S  S10  1  0.832  0.896  0.955  1.0
  S  S11  1  0.278  0.283  0.196  1.0
  S  S12  1  0.470  0.298  0.679  1.0
  S  S13  1  0.168  0.104  0.045  1.0
  S  S14  1  0.668  0.896  0.455  1.0
  S  S15  1  0.530  0.702  0.321  1.0
  N  N16  1  0.040  0.155  0.083  1.0
  N  N17  1  0.754  0.979  0.212  1.0
  N  N18  1  0.960  0.845  0.917  1.0
  N  N19  1  0.746  0.979  0.712  1.0
  N  N20  1  0.033  0.025  0.269  1.0
  N  N21  1  0.254  0.021  0.288  1.0
  N  N22  1  0.467  0.025  0.769  1.0
  N  N23  1  0.285  0.131  0.102  1.0
  N  N24  1  0.246  0.021  0.788  1.0
  N  N25  1  0.845  0.523  0.823  1.0
  N  N26  1  0.715  0.869  0.898  1.0
  N  N27  1  0.155  0.477  0.177  1.0
  N  N28  1  0.533  0.975  0.231  1.0
  N  N29  1  0.785  0.869  0.398  1.0
  N  N30  1  0.540  0.845  0.417  1.0
  N  N31  1  0.460  0.155  0.583  1.0
  N  N32  1  0.655  0.523  0.323  1.0
  N  N33  1  0.345  0.477  0.677  1.0
  N  N34  1  0.967  0.975  0.731  1.0
  N  N35  1  0.215  0.131  0.602  1.0
  Cl  Cl36  1  0.374  0.685  0.913  1.0
  Cl  Cl37  1  0.874  0.315  0.587  1.0
  Cl  Cl38  1  0.126  0.685  0.413  1.0
  Cl  Cl39  1  0.626  0.315  0.087  1.0
[/CIF]
.
The structure described by CN5S3Cl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CN5S3Cl clusters. C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(1) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one S(3) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(2), one N(4), and one N(5) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(4) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one N(1), one N(3), and one N(5) atom. Cl(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CS3N5Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.973
_cell_length_b   5.011
_cell_length_c   14.765
_cell_angle_alpha   74.977
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   784.072
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.361  0.944  0.809  1.0
  C  C1  1  0.639  0.056  0.191  1.0
  C  C2  1  0.139  0.944  0.309  1.0
  C  C3  1  0.861  0.056  0.691  1.0
  S  S4  1  0.778  0.717  0.304  1.0
  S  S5  1  0.222  0.283  0.696  1.0
  S  S6  1  0.332  0.104  0.545  1.0
  S  S7  1  0.722  0.717  0.804  1.0
  S  S8  1  0.970  0.702  0.821  1.0
  S  S9  1  0.030  0.298  0.179  1.0
  S  S10  1  0.832  0.896  0.955  1.0
  S  S11  1  0.278  0.283  0.196  1.0
  S  S12  1  0.470  0.298  0.679  1.0
  S  S13  1  0.168  0.104  0.045  1.0
  S  S14  1  0.668  0.896  0.455  1.0
  S  S15  1  0.530  0.702  0.321  1.0
  N  N16  1  0.040  0.155  0.083  1.0
  N  N17  1  0.754  0.979  0.212  1.0
  N  N18  1  0.960  0.845  0.917  1.0
  N  N19  1  0.746  0.979  0.712  1.0
  N  N20  1  0.033  0.025  0.269  1.0
  N  N21  1  0.254  0.021  0.288  1.0
  N  N22  1  0.467  0.025  0.769  1.0
  N  N23  1  0.285  0.131  0.102  1.0
  N  N24  1  0.246  0.021  0.788  1.0
  N  N25  1  0.845  0.523  0.823  1.0
  N  N26  1  0.715  0.869  0.898  1.0
  N  N27  1  0.155  0.477  0.177  1.0
  N  N28  1  0.533  0.975  0.231  1.0
  N  N29  1  0.785  0.869  0.398  1.0
  N  N30  1  0.540  0.845  0.417  1.0
  N  N31  1  0.460  0.155  0.583  1.0
  N  N32  1  0.655  0.523  0.323  1.0
  N  N33  1  0.345  0.477  0.677  1.0
  N  N34  1  0.967  0.975  0.731  1.0
  N  N35  1  0.215  0.131  0.602  1.0
  Cl  Cl36  1  0.374  0.685  0.913  1.0
  Cl  Cl37  1  0.874  0.315  0.587  1.0
  Cl  Cl38  1  0.126  0.685  0.413  1.0
  Cl  Cl39  1  0.626  0.315  0.087  1.0
[/CIF]
.