The material structure described by V2CdO8O2 crystallizes in the monoclinic Cc space group. The structure consists of four 7782-44-7 molecules inside a V2CdO8 framework. In the V2CdO8 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), and two equivalent O(3) atoms. Cd(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(2) and one Cd(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Cd(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Cd(1) and one O(9) atom. In the eighth O site, O(9) is bonded in a bent 150 degrees geometry to one Cd(1) and one O(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.494
_cell_length_b   8.494
_cell_length_c   7.001
_cell_angle_alpha   70.728
_cell_angle_beta   70.728
_cell_angle_gamma   75.944
_symmetry_Int_Tables_number   1
_cell_volume   444.971
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.611  0.677  0.458  1.0
  V  V1  1  0.677  0.611  0.958  1.0
  V  V2  1  0.889  0.825  0.051  1.0
  V  V3  1  0.825  0.889  0.551  1.0
  Cd  Cd4  1  0.252  0.753  0.251  1.0
  Cd  Cd5  1  0.753  0.252  0.751  1.0
  O  O6  1  0.417  0.770  0.438  1.0
  O  O7  1  0.770  0.417  0.938  1.0
  O  O8  1  0.469  0.605  0.089  1.0
  O  O9  1  0.605  0.469  0.589  1.0
  O  O10  1  0.769  0.851  0.325  1.0
  O  O11  1  0.851  0.769  0.825  1.0
  O  O12  1  0.732  0.648  0.185  1.0
  O  O13  1  0.648  0.732  0.685  1.0
  O  O14  1  0.033  0.892  0.422  1.0
  O  O15  1  0.892  0.033  0.922  1.0
  O  O16  1  0.085  0.734  0.068  1.0
  O  O17  1  0.734  0.085  0.568  1.0
  O  O18  1  0.343  0.064  0.020  1.0
  O  O19  1  0.064  0.343  0.520  1.0
  O  O20  1  0.143  0.272  0.030  1.0
  O  O21  1  0.272  0.143  0.530  1.0
  O  O22  1  0.161  0.445  0.476  1.0
  O  O23  1  0.445  0.161  0.976  1.0
  O  O24  1  0.368  0.245  0.483  1.0
  O  O25  1  0.245  0.368  0.983  1.0
[/CIF]
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The material structure described by V2CdO8O2 crystallizes in the monoclinic Cc space group. The structure consists of four 7782-44-7 molecules inside a V2CdO8 framework. In the V2CdO8 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), and two equivalent O(3) atoms. Cd(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(2) and one Cd(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Cd(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Cd(1) and one O(9) atom. In the eighth O site, O(9) is bonded in a bent 150 degrees geometry to one Cd(1) and one O(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.494
_cell_length_b   8.494
_cell_length_c   7.001
_cell_angle_alpha   70.728
_cell_angle_beta   70.728
_cell_angle_gamma   75.944
_symmetry_Int_Tables_number   1
_cell_volume   444.971
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.611  0.677  0.458  1.0
  V  V1  1  0.677  0.611  0.958  1.0
  V  V2  1  0.889  0.825  0.051  1.0
  V  V3  1  0.825  0.889  0.551  1.0
  Cd  Cd4  1  0.252  0.753  0.251  1.0
  Cd  Cd5  1  0.753  0.252  0.751  1.0
  O  O6  1  0.417  0.770  0.438  1.0
  O  O7  1  0.770  0.417  0.938  1.0
  O  O8  1  0.469  0.605  0.089  1.0
  O  O9  1  0.605  0.469  0.589  1.0
  O  O10  1  0.769  0.851  0.325  1.0
  O  O11  1  0.851  0.769  0.825  1.0
  O  O12  1  0.732  0.648  0.185  1.0
  O  O13  1  0.648  0.732  0.685  1.0
  O  O14  1  0.033  0.892  0.422  1.0
  O  O15  1  0.892  0.033  0.922  1.0
  O  O16  1  0.085  0.734  0.068  1.0
  O  O17  1  0.734  0.085  0.568  1.0
  O  O18  1  0.343  0.064  0.020  1.0
  O  O19  1  0.064  0.343  0.520  1.0
  O  O20  1  0.143  0.272  0.030  1.0
  O  O21  1  0.272  0.143  0.530  1.0
  O  O22  1  0.161  0.445  0.476  1.0
  O  O23  1  0.445  0.161  0.976  1.0
  O  O24  1  0.368  0.245  0.483  1.0
  O  O25  1  0.245  0.368  0.983  1.0
[/CIF]
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