The structure described by CoPO4 crystallizes in the monoclinic P2_1/c space group. Co(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form CoO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with four equivalent Co(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.832
_cell_length_b   5.247
_cell_length_c   8.334
_cell_angle_alpha   57.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   364.172
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.821  0.188  0.510  1.0
  Co  Co1  1  0.679  0.188  0.010  1.0
  Co  Co2  1  0.321  0.812  0.990  1.0
  Co  Co3  1  0.179  0.812  0.490  1.0
  P  P4  1  0.092  0.127  0.706  1.0
  P  P5  1  0.592  0.873  0.794  1.0
  P  P6  1  0.908  0.873  0.294  1.0
  P  P7  1  0.408  0.127  0.206  1.0
  O  O8  1  0.357  0.107  0.038  1.0
  O  O9  1  0.936  0.120  0.708  1.0
  O  O10  1  0.145  0.870  0.896  1.0
  O  O11  1  0.143  0.426  0.677  1.0
  O  O12  1  0.564  0.120  0.208  1.0
  O  O13  1  0.643  0.574  0.823  1.0
  O  O14  1  0.857  0.574  0.323  1.0
  O  O15  1  0.355  0.870  0.396  1.0
  O  O16  1  0.143  0.107  0.538  1.0
  O  O17  1  0.855  0.130  0.104  1.0
  O  O18  1  0.643  0.893  0.962  1.0
  O  O19  1  0.064  0.880  0.292  1.0
  O  O20  1  0.357  0.426  0.177  1.0
  O  O21  1  0.857  0.893  0.462  1.0
  O  O22  1  0.436  0.880  0.792  1.0
  O  O23  1  0.645  0.130  0.604  1.0
[/CIF]
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The structure described by CoPO4 crystallizes in the monoclinic P2_1/c space group. Co(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form CoO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with four equivalent Co(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.832
_cell_length_b   5.247
_cell_length_c   8.334
_cell_angle_alpha   57.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   364.172
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.821  0.188  0.510  1.0
  Co  Co1  1  0.679  0.188  0.010  1.0
  Co  Co2  1  0.321  0.812  0.990  1.0
  Co  Co3  1  0.179  0.812  0.490  1.0
  P  P4  1  0.092  0.127  0.706  1.0
  P  P5  1  0.592  0.873  0.794  1.0
  P  P6  1  0.908  0.873  0.294  1.0
  P  P7  1  0.408  0.127  0.206  1.0
  O  O8  1  0.357  0.107  0.038  1.0
  O  O9  1  0.936  0.120  0.708  1.0
  O  O10  1  0.145  0.870  0.896  1.0
  O  O11  1  0.143  0.426  0.677  1.0
  O  O12  1  0.564  0.120  0.208  1.0
  O  O13  1  0.643  0.574  0.823  1.0
  O  O14  1  0.857  0.574  0.323  1.0
  O  O15  1  0.355  0.870  0.396  1.0
  O  O16  1  0.143  0.107  0.538  1.0
  O  O17  1  0.855  0.130  0.104  1.0
  O  O18  1  0.643  0.893  0.962  1.0
  O  O19  1  0.064  0.880  0.292  1.0
  O  O20  1  0.357  0.426  0.177  1.0
  O  O21  1  0.857  0.893  0.462  1.0
  O  O22  1  0.436  0.880  0.792  1.0
  O  O23  1  0.645  0.130  0.604  1.0
[/CIF]
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