The compound described by Li2AgF5 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one F(2), one F(3), one F(4), and two equivalent F(1) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one F(2), one F(3), one F(4), and two equivalent F(5) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in an octahedral geometry to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one Li(1), one Li(2), and one Ag(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), one Ag(1), and one Ag(2) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to two equivalent Li(2) and one Ag(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2AgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.221
_cell_length_b   8.232
_cell_length_c   10.171
_cell_angle_alpha   68.507
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   406.704
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.469  0.863  0.872  1.0
  Li  Li1  1  0.031  0.863  0.372  1.0
  Li  Li2  1  0.008  0.648  0.669  1.0
  Li  Li3  1  0.508  0.352  0.831  1.0
  Li  Li4  1  0.492  0.648  0.169  1.0
  Li  Li5  1  0.992  0.352  0.331  1.0
  Li  Li6  1  0.969  0.137  0.628  1.0
  Li  Li7  1  0.531  0.137  0.128  1.0
  Ag  Ag8  1  0.500  0.000  0.500  1.0
  Ag  Ag9  1  0.000  0.000  0.000  1.0
  Ag  Ag10  1  0.500  0.500  0.500  1.0
  Ag  Ag11  1  0.000  0.500  0.000  1.0
  F  F12  1  0.655  0.959  0.690  1.0
  F  F13  1  0.180  0.876  0.577  1.0
  F  F14  1  0.226  0.671  0.864  1.0
  F  F15  1  0.845  0.959  0.190  1.0
  F  F16  1  0.790  0.732  0.511  1.0
  F  F17  1  0.320  0.876  0.077  1.0
  F  F18  1  0.793  0.510  0.830  1.0
  F  F19  1  0.274  0.671  0.364  1.0
  F  F20  1  0.293  0.490  0.670  1.0
  F  F21  1  0.710  0.732  0.011  1.0
  F  F22  1  0.290  0.268  0.989  1.0
  F  F23  1  0.707  0.510  0.330  1.0
  F  F24  1  0.726  0.329  0.636  1.0
  F  F25  1  0.207  0.490  0.170  1.0
  F  F26  1  0.680  0.124  0.923  1.0
  F  F27  1  0.210  0.268  0.489  1.0
  F  F28  1  0.155  0.041  0.810  1.0
  F  F29  1  0.774  0.329  0.136  1.0
  F  F30  1  0.820  0.124  0.423  1.0
  F  F31  1  0.345  0.041  0.310  1.0
[/CIF]
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The compound described by Li2AgF5 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one F(2), one F(3), one F(4), and two equivalent F(1) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one F(2), one F(3), one F(4), and two equivalent F(5) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in an octahedral geometry to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one Li(1), one Li(2), and one Ag(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), one Ag(1), and one Ag(2) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to two equivalent Li(2) and one Ag(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2AgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.221
_cell_length_b   8.232
_cell_length_c   10.171
_cell_angle_alpha   68.507
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   406.704
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.469  0.863  0.872  1.0
  Li  Li1  1  0.031  0.863  0.372  1.0
  Li  Li2  1  0.008  0.648  0.669  1.0
  Li  Li3  1  0.508  0.352  0.831  1.0
  Li  Li4  1  0.492  0.648  0.169  1.0
  Li  Li5  1  0.992  0.352  0.331  1.0
  Li  Li6  1  0.969  0.137  0.628  1.0
  Li  Li7  1  0.531  0.137  0.128  1.0
  Ag  Ag8  1  0.500  0.000  0.500  1.0
  Ag  Ag9  1  0.000  0.000  0.000  1.0
  Ag  Ag10  1  0.500  0.500  0.500  1.0
  Ag  Ag11  1  0.000  0.500  0.000  1.0
  F  F12  1  0.655  0.959  0.690  1.0
  F  F13  1  0.180  0.876  0.577  1.0
  F  F14  1  0.226  0.671  0.864  1.0
  F  F15  1  0.845  0.959  0.190  1.0
  F  F16  1  0.790  0.732  0.511  1.0
  F  F17  1  0.320  0.876  0.077  1.0
  F  F18  1  0.793  0.510  0.830  1.0
  F  F19  1  0.274  0.671  0.364  1.0
  F  F20  1  0.293  0.490  0.670  1.0
  F  F21  1  0.710  0.732  0.011  1.0
  F  F22  1  0.290  0.268  0.989  1.0
  F  F23  1  0.707  0.510  0.330  1.0
  F  F24  1  0.726  0.329  0.636  1.0
  F  F25  1  0.207  0.490  0.170  1.0
  F  F26  1  0.680  0.124  0.923  1.0
  F  F27  1  0.210  0.268  0.489  1.0
  F  F28  1  0.155  0.041  0.810  1.0
  F  F29  1  0.774  0.329  0.136  1.0
  F  F30  1  0.820  0.124  0.423  1.0
  F  F31  1  0.345  0.041  0.310  1.0
[/CIF]
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