The structure described by Li2V(CO3)2 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. V(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.904
_cell_length_b   6.384
_cell_length_c   8.330
_cell_angle_alpha   90.007
_cell_angle_beta   87.531
_cell_angle_gamma   89.996
_symmetry_Int_Tables_number   1
_cell_volume   260.559
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.018  0.281  0.673  1.0
  Li  Li1  1  0.482  0.781  0.827  1.0
  Li  Li2  1  0.518  0.219  0.173  1.0
  Li  Li3  1  0.982  0.719  0.327  1.0
  V  V4  1  0.500  0.500  0.500  1.0
  V  V5  1  1.000  1.000  1.000  1.0
  C  C6  1  0.015  0.267  0.329  1.0
  C  C7  1  0.485  0.767  0.171  1.0
  C  C8  1  0.515  0.233  0.829  1.0
  C  C9  1  0.985  0.733  0.671  1.0
  O  O10  1  0.131  0.178  0.204  1.0
  O  O11  1  0.369  0.678  0.296  1.0
  O  O12  1  0.631  0.322  0.704  1.0
  O  O13  1  0.869  0.822  0.796  1.0
  O  O14  1  0.154  0.298  0.456  1.0
  O  O15  1  0.346  0.798  0.044  1.0
  O  O16  1  0.655  0.202  0.956  1.0
  O  O17  1  0.846  0.702  0.544  1.0
  O  O18  1  0.261  0.175  0.828  1.0
  O  O19  1  0.239  0.675  0.672  1.0
  O  O20  1  0.761  0.325  0.328  1.0
  O  O21  1  0.739  0.825  0.172  1.0
[/CIF]
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The structure described by Li2V(CO3)2 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. V(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.904
_cell_length_b   6.384
_cell_length_c   8.330
_cell_angle_alpha   90.007
_cell_angle_beta   87.531
_cell_angle_gamma   89.996
_symmetry_Int_Tables_number   1
_cell_volume   260.559
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.018  0.281  0.673  1.0
  Li  Li1  1  0.482  0.781  0.827  1.0
  Li  Li2  1  0.518  0.219  0.173  1.0
  Li  Li3  1  0.982  0.719  0.327  1.0
  V  V4  1  0.500  0.500  0.500  1.0
  V  V5  1  1.000  1.000  1.000  1.0
  C  C6  1  0.015  0.267  0.329  1.0
  C  C7  1  0.485  0.767  0.171  1.0
  C  C8  1  0.515  0.233  0.829  1.0
  C  C9  1  0.985  0.733  0.671  1.0
  O  O10  1  0.131  0.178  0.204  1.0
  O  O11  1  0.369  0.678  0.296  1.0
  O  O12  1  0.631  0.322  0.704  1.0
  O  O13  1  0.869  0.822  0.796  1.0
  O  O14  1  0.154  0.298  0.456  1.0
  O  O15  1  0.346  0.798  0.044  1.0
  O  O16  1  0.655  0.202  0.956  1.0
  O  O17  1  0.846  0.702  0.544  1.0
  O  O18  1  0.261  0.175  0.828  1.0
  O  O19  1  0.239  0.675  0.672  1.0
  O  O20  1  0.761  0.325  0.328  1.0
  O  O21  1  0.739  0.825  0.172  1.0
[/CIF]
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