The compound described by Ni10SbP3 crystallizes in the trigonal P-3m1 space group. There are seven inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Sb(1) and two equivalent P(2) atoms. In the second Ni site, Ni(2) is bonded in a 3-coordinate geometry to three equivalent P(2) atoms. In the third Ni site, Ni(3) is bonded in a 3-coordinate geometry to one Sb(2), one P(2), and two equivalent P(1) atoms. In the fourth Ni site, Ni(4) is bonded in a 4-coordinate geometry to one Sb(1) and three equivalent P(1) atoms. In the fifth Ni site, Ni(5) is bonded in a 4-coordinate geometry to one Sb(1), one P(1), and two equivalent P(2) atoms. In the sixth Ni site, Ni(6) is bonded in a distorted tetrahedral geometry to one Sb(1) and three equivalent P(2) atoms. In the seventh Ni site, Ni(7) is bonded in a 2-coordinate geometry to one Sb(1), one Sb(2), and two equivalent P(2) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(2) is bonded in a cuboctahedral geometry to six equivalent Ni(3) and six equivalent Ni(7) atoms. In the second Sb site, Sb(1) is bonded in a 14-coordinate geometry to one Ni(4), one Ni(6), three equivalent Ni(5), three equivalent Ni(7), and six equivalent Ni(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a body-centered cubic geometry to two equivalent Ni(4), two equivalent Ni(5), and four equivalent Ni(3) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to one Ni(2), one Ni(3), one Ni(6), two equivalent Ni(1), two equivalent Ni(5), and two equivalent Ni(7) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ni10SbP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.662
_cell_length_b   7.662
_cell_length_c   9.640
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   490.078
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.337  0.000  0.500  1.0
  Ni  Ni1  1  0.663  0.000  0.500  1.0
  Ni  Ni2  1  0.000  0.337  0.500  1.0
  Ni  Ni3  1  0.000  0.663  0.500  1.0
  Ni  Ni4  1  0.663  0.663  0.500  1.0
  Ni  Ni5  1  0.337  0.337  0.500  1.0
  Ni  Ni6  1  0.000  0.000  0.380  1.0
  Ni  Ni7  1  0.000  0.000  0.620  1.0
  Ni  Ni8  1  0.811  0.189  0.072  1.0
  Ni  Ni9  1  0.189  0.811  0.928  1.0
  Ni  Ni10  1  0.811  0.623  0.072  1.0
  Ni  Ni11  1  0.189  0.377  0.928  1.0
  Ni  Ni12  1  0.377  0.189  0.072  1.0
  Ni  Ni13  1  0.623  0.811  0.928  1.0
  Ni  Ni14  1  0.333  0.667  0.097  1.0
  Ni  Ni15  1  0.667  0.333  0.903  1.0
  Ni  Ni16  1  0.508  0.492  0.240  1.0
  Ni  Ni17  1  0.492  0.508  0.760  1.0
  Ni  Ni18  1  0.508  0.016  0.240  1.0
  Ni  Ni19  1  0.492  0.984  0.760  1.0
  Ni  Ni20  1  0.984  0.492  0.240  1.0
  Ni  Ni21  1  0.016  0.508  0.760  1.0
  Ni  Ni22  1  0.333  0.667  0.612  1.0
  Ni  Ni23  1  0.667  0.333  0.388  1.0
  Ni  Ni24  1  0.137  0.863  0.198  1.0
  Ni  Ni25  1  0.863  0.137  0.802  1.0
  Ni  Ni26  1  0.137  0.273  0.198  1.0
  Ni  Ni27  1  0.863  0.727  0.802  1.0
  Ni  Ni28  1  0.727  0.863  0.198  1.0
  Ni  Ni29  1  0.273  0.137  0.802  1.0
  Sb  Sb30  1  0.333  0.667  0.360  1.0
  Sb  Sb31  1  0.667  0.333  0.640  1.0
  Sb  Sb32  1  0.000  0.000  0.000  1.0
  P  P33  1  0.500  0.000  0.000  1.0
  P  P34  1  0.000  0.500  0.000  1.0
  P  P35  1  0.500  0.500  0.000  1.0
  P  P36  1  0.835  0.165  0.309  1.0
  P  P37  1  0.165  0.835  0.691  1.0
  P  P38  1  0.835  0.671  0.309  1.0
  P  P39  1  0.165  0.329  0.691  1.0
  P  P40  1  0.329  0.165  0.309  1.0
  P  P41  1  0.671  0.835  0.691  1.0
[/CIF]
.
The compound described by Ni10SbP3 crystallizes in the trigonal P-3m1 space group. There are seven inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Sb(1) and two equivalent P(2) atoms. In the second Ni site, Ni(2) is bonded in a 3-coordinate geometry to three equivalent P(2) atoms. In the third Ni site, Ni(3) is bonded in a 3-coordinate geometry to one Sb(2), one P(2), and two equivalent P(1) atoms. In the fourth Ni site, Ni(4) is bonded in a 4-coordinate geometry to one Sb(1) and three equivalent P(1) atoms. In the fifth Ni site, Ni(5) is bonded in a 4-coordinate geometry to one Sb(1), one P(1), and two equivalent P(2) atoms. In the sixth Ni site, Ni(6) is bonded in a distorted tetrahedral geometry to one Sb(1) and three equivalent P(2) atoms. In the seventh Ni site, Ni(7) is bonded in a 2-coordinate geometry to one Sb(1), one Sb(2), and two equivalent P(2) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(2) is bonded in a cuboctahedral geometry to six equivalent Ni(3) and six equivalent Ni(7) atoms. In the second Sb site, Sb(1) is bonded in a 14-coordinate geometry to one Ni(4), one Ni(6), three equivalent Ni(5), three equivalent Ni(7), and six equivalent Ni(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a body-centered cubic geometry to two equivalent Ni(4), two equivalent Ni(5), and four equivalent Ni(3) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to one Ni(2), one Ni(3), one Ni(6), two equivalent Ni(1), two equivalent Ni(5), and two equivalent Ni(7) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ni10SbP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.662
_cell_length_b   7.662
_cell_length_c   9.640
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   490.078
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.337  0.000  0.500  1.0
  Ni  Ni1  1  0.663  0.000  0.500  1.0
  Ni  Ni2  1  0.000  0.337  0.500  1.0
  Ni  Ni3  1  0.000  0.663  0.500  1.0
  Ni  Ni4  1  0.663  0.663  0.500  1.0
  Ni  Ni5  1  0.337  0.337  0.500  1.0
  Ni  Ni6  1  0.000  0.000  0.380  1.0
  Ni  Ni7  1  0.000  0.000  0.620  1.0
  Ni  Ni8  1  0.811  0.189  0.072  1.0
  Ni  Ni9  1  0.189  0.811  0.928  1.0
  Ni  Ni10  1  0.811  0.623  0.072  1.0
  Ni  Ni11  1  0.189  0.377  0.928  1.0
  Ni  Ni12  1  0.377  0.189  0.072  1.0
  Ni  Ni13  1  0.623  0.811  0.928  1.0
  Ni  Ni14  1  0.333  0.667  0.097  1.0
  Ni  Ni15  1  0.667  0.333  0.903  1.0
  Ni  Ni16  1  0.508  0.492  0.240  1.0
  Ni  Ni17  1  0.492  0.508  0.760  1.0
  Ni  Ni18  1  0.508  0.016  0.240  1.0
  Ni  Ni19  1  0.492  0.984  0.760  1.0
  Ni  Ni20  1  0.984  0.492  0.240  1.0
  Ni  Ni21  1  0.016  0.508  0.760  1.0
  Ni  Ni22  1  0.333  0.667  0.612  1.0
  Ni  Ni23  1  0.667  0.333  0.388  1.0
  Ni  Ni24  1  0.137  0.863  0.198  1.0
  Ni  Ni25  1  0.863  0.137  0.802  1.0
  Ni  Ni26  1  0.137  0.273  0.198  1.0
  Ni  Ni27  1  0.863  0.727  0.802  1.0
  Ni  Ni28  1  0.727  0.863  0.198  1.0
  Ni  Ni29  1  0.273  0.137  0.802  1.0
  Sb  Sb30  1  0.333  0.667  0.360  1.0
  Sb  Sb31  1  0.667  0.333  0.640  1.0
  Sb  Sb32  1  0.000  0.000  0.000  1.0
  P  P33  1  0.500  0.000  0.000  1.0
  P  P34  1  0.000  0.500  0.000  1.0
  P  P35  1  0.500  0.500  0.000  1.0
  P  P36  1  0.835  0.165  0.309  1.0
  P  P37  1  0.165  0.835  0.691  1.0
  P  P38  1  0.835  0.671  0.309  1.0
  P  P39  1  0.165  0.329  0.691  1.0
  P  P40  1  0.329  0.165  0.309  1.0
  P  P41  1  0.671  0.835  0.691  1.0
[/CIF]
.