The material structure described by Cd(CoO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Co(1) is bonded to six equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent Cd(1)O4 tetrahedra and edges with six equivalent Co(1)O6 octahedra. Cd(1) is bonded to four equivalent O(1) atoms to form CdO4 tetrahedra that share corners with twelve equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-62°. O(1) is bonded to three equivalent Co(1) and one Cd(1) atom to form a mixture of distorted corner and edge-sharing OCdCo3 tetrahedra. is represented by the CIF file [CIF]
data_Cd(CoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.288
_cell_length_b   6.135
_cell_length_c   6.290
_cell_angle_alpha   59.111
_cell_angle_beta   89.914
_cell_angle_gamma   59.123
_symmetry_Int_Tables_number   1
_cell_volume   167.031
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  1.000  0.000  1.0
  Cd  Cd1  1  0.250  0.500  0.750  1.0
  Co  Co2  1  0.625  0.750  0.375  1.0
  Co  Co3  1  0.625  0.750  0.875  1.0
  Co  Co4  1  0.125  0.250  0.375  1.0
  Co  Co5  1  0.625  0.250  0.375  1.0
  O  O6  1  0.855  0.290  0.141  1.0
  O  O7  1  0.395  0.210  0.181  1.0
  O  O8  1  0.859  0.710  0.145  1.0
  O  O9  1  0.431  0.710  0.145  1.0
  O  O10  1  0.395  0.210  0.609  1.0
  O  O11  1  0.855  0.290  0.569  1.0
  O  O12  1  0.391  0.790  0.605  1.0
  O  O13  1  0.819  0.790  0.605  1.0
[/CIF]
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The material structure described by Cd(CoO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Co(1) is bonded to six equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent Cd(1)O4 tetrahedra and edges with six equivalent Co(1)O6 octahedra. Cd(1) is bonded to four equivalent O(1) atoms to form CdO4 tetrahedra that share corners with twelve equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-62°. O(1) is bonded to three equivalent Co(1) and one Cd(1) atom to form a mixture of distorted corner and edge-sharing OCdCo3 tetrahedra. is represented by the CIF file [CIF]
data_Cd(CoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.288
_cell_length_b   6.135
_cell_length_c   6.290
_cell_angle_alpha   59.111
_cell_angle_beta   89.914
_cell_angle_gamma   59.123
_symmetry_Int_Tables_number   1
_cell_volume   167.031
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  1.000  0.000  1.0
  Cd  Cd1  1  0.250  0.500  0.750  1.0
  Co  Co2  1  0.625  0.750  0.375  1.0
  Co  Co3  1  0.625  0.750  0.875  1.0
  Co  Co4  1  0.125  0.250  0.375  1.0
  Co  Co5  1  0.625  0.250  0.375  1.0
  O  O6  1  0.855  0.290  0.141  1.0
  O  O7  1  0.395  0.210  0.181  1.0
  O  O8  1  0.859  0.710  0.145  1.0
  O  O9  1  0.431  0.710  0.145  1.0
  O  O10  1  0.395  0.210  0.609  1.0
  O  O11  1  0.855  0.290  0.569  1.0
  O  O12  1  0.391  0.790  0.605  1.0
  O  O13  1  0.819  0.790  0.605  1.0
[/CIF]
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